The material structure described by Li(N2O)2(NO2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four nitrous acid molecules and two Li(N2O)2 clusters. In each Li(N2O)2 cluster, Li(1) is bonded in a linear geometry to four equivalent N(2) and two equivalent O(2) atoms. N(2) is bonded in a distorted L-shaped geometry to one Li(1) and one N(2) atom. O(2) is bonded in a single-bond geometry to one Li(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li(NO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.662
_cell_length_b   7.662
_cell_length_c   12.404
_cell_angle_alpha   83.014
_cell_angle_beta   83.014
_cell_angle_gamma   125.365
_symmetry_Int_Tables_number   1
_cell_volume   572.669
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  N  N1  1  0.750  0.750  0.506  1.0
  N  N2  1  0.250  0.250  0.494  1.0
  N  N3  1  0.895  0.264  0.000  1.0
  N  N4  1  0.105  0.736  1.000  1.0
  N  N5  1  0.264  0.895  0.000  1.0
  N  N6  1  0.736  0.105  1.000  1.0
  O  O7  1  0.741  0.904  0.504  1.0
  O  O8  1  0.259  0.096  0.496  1.0
  O  O9  1  0.265  0.265  0.000  1.0
  O  O10  1  0.096  0.259  0.496  1.0
  O  O11  1  0.735  0.735  1.000  1.0
  O  O12  1  0.904  0.741  0.504  1.0
[/CIF]
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The material structure described by Li(N2O)2(NO2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four nitrous acid molecules and two Li(N2O)2 clusters. In each Li(N2O)2 cluster, Li(1) is bonded in a linear geometry to four equivalent N(2) and two equivalent O(2) atoms. N(2) is bonded in a distorted L-shaped geometry to one Li(1) and one N(2) atom. O(2) is bonded in a single-bond geometry to one Li(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li(NO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.662
_cell_length_b   7.662
_cell_length_c   12.404
_cell_angle_alpha   83.014
_cell_angle_beta   83.014
_cell_angle_gamma   125.365
_symmetry_Int_Tables_number   1
_cell_volume   572.669
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  N  N1  1  0.750  0.750  0.506  1.0
  N  N2  1  0.250  0.250  0.494  1.0
  N  N3  1  0.895  0.264  0.000  1.0
  N  N4  1  0.105  0.736  1.000  1.0
  N  N5  1  0.264  0.895  0.000  1.0
  N  N6  1  0.736  0.105  1.000  1.0
  O  O7  1  0.741  0.904  0.504  1.0
  O  O8  1  0.259  0.096  0.496  1.0
  O  O9  1  0.265  0.265  0.000  1.0
  O  O10  1  0.096  0.259  0.496  1.0
  O  O11  1  0.735  0.735  1.000  1.0
  O  O12  1  0.904  0.741  0.504  1.0
[/CIF]
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