The material described by CsAuO crystallizes in the tetragonal I4/mmm space group. Cs(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. Au(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to four equivalent Cs(1) and two equivalent Au(1) atoms to form a mixture of edge and corner-sharing OCs4Au2 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. is represented by the CIF card [CIF]
data_CsAuO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.225
_cell_length_b   7.867
_cell_length_c   7.867
_cell_angle_alpha   80.995
_cell_angle_beta   66.682
_cell_angle_gamma   66.682
_symmetry_Int_Tables_number   1
_cell_volume   324.864
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.200  0.300  0.300  1.0
  Cs  Cs1  1  0.500  0.700  0.300  1.0
  Cs  Cs2  1  0.500  0.300  0.700  1.0
  Cs  Cs3  1  0.800  0.700  0.700  1.0
  Au  Au4  1  0.854  0.000  0.291  1.0
  Au  Au5  1  0.146  0.709  1.000  1.0
  Au  Au6  1  0.854  0.291  0.000  1.0
  Au  Au7  1  0.146  1.000  0.709  1.0
  O  O8  1  0.719  0.281  0.281  1.0
  O  O9  1  0.000  0.719  0.281  1.0
  O  O10  1  0.000  0.281  0.719  1.0
  O  O11  1  0.281  0.719  0.719  1.0
[/CIF]
.
The material described by CsAuO crystallizes in the tetragonal I4/mmm space group. Cs(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. Au(1) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to four equivalent Cs(1) and two equivalent Au(1) atoms to form a mixture of edge and corner-sharing OCs4Au2 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. is represented by the CIF card [CIF]
data_CsAuO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.225
_cell_length_b   7.867
_cell_length_c   7.867
_cell_angle_alpha   80.995
_cell_angle_beta   66.682
_cell_angle_gamma   66.682
_symmetry_Int_Tables_number   1
_cell_volume   324.864
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.200  0.300  0.300  1.0
  Cs  Cs1  1  0.500  0.700  0.300  1.0
  Cs  Cs2  1  0.500  0.300  0.700  1.0
  Cs  Cs3  1  0.800  0.700  0.700  1.0
  Au  Au4  1  0.854  0.000  0.291  1.0
  Au  Au5  1  0.146  0.709  1.000  1.0
  Au  Au6  1  0.854  0.291  0.000  1.0
  Au  Au7  1  0.146  1.000  0.709  1.0
  O  O8  1  0.719  0.281  0.281  1.0
  O  O9  1  0.000  0.719  0.281  1.0
  O  O10  1  0.000  0.281  0.719  1.0
  O  O11  1  0.281  0.719  0.719  1.0
[/CIF]
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