The structure described by CAsF3 is Indium-like structured and crystallizes in the tetragonal P4_2/nmc space group. The structure is zero-dimensional and consists of eight (trifluoromethyl)arsine molecules. C(1) is bonded in a distorted trigonal non-coplanar geometry to one As(1), one F(2), and two equivalent F(1) atoms. As(1) is bonded in a distorted single-bond geometry to one C(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF file [CIF]
data_AsCF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.714
_cell_length_b   10.714
_cell_length_c   6.487
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   744.610
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.500  0.655  0.065  1.0
  As  As1  1  0.500  0.345  0.065  1.0
  As  As2  1  0.845  0.000  0.565  1.0
  As  As3  1  0.155  0.000  0.565  1.0
  As  As4  1  0.655  0.500  0.935  1.0
  As  As5  1  0.000  0.845  0.435  1.0
  As  As6  1  0.000  0.155  0.435  1.0
  As  As7  1  0.345  0.500  0.935  1.0
  C  C8  1  0.500  0.761  0.801  1.0
  C  C9  1  0.500  0.239  0.801  1.0
  C  C10  1  0.739  0.000  0.301  1.0
  C  C11  1  0.261  0.000  0.301  1.0
  C  C12  1  0.761  0.500  0.199  1.0
  C  C13  1  0.000  0.739  0.699  1.0
  C  C14  1  0.000  0.261  0.699  1.0
  C  C15  1  0.239  0.500  0.199  1.0
  F  F16  1  0.337  0.897  0.299  1.0
  F  F17  1  0.397  0.163  0.799  1.0
  F  F18  1  0.603  0.837  0.799  1.0
  F  F19  1  0.663  0.103  0.299  1.0
  F  F20  1  0.163  0.397  0.201  1.0
  F  F21  1  0.837  0.603  0.201  1.0
  F  F22  1  0.897  0.337  0.701  1.0
  F  F23  1  0.103  0.663  0.701  1.0
  F  F24  1  0.304  0.500  0.380  1.0
  F  F25  1  0.000  0.196  0.880  1.0
  F  F26  1  0.000  0.804  0.880  1.0
  F  F27  1  0.696  0.500  0.380  1.0
  F  F28  1  0.196  0.000  0.120  1.0
  F  F29  1  0.804  0.000  0.120  1.0
  F  F30  1  0.500  0.304  0.620  1.0
  F  F31  1  0.500  0.696  0.620  1.0
  F  F32  1  0.163  0.603  0.201  1.0
  F  F33  1  0.103  0.337  0.701  1.0
  F  F34  1  0.897  0.663  0.701  1.0
  F  F35  1  0.837  0.397  0.201  1.0
  F  F36  1  0.337  0.103  0.299  1.0
  F  F37  1  0.663  0.897  0.299  1.0
  F  F38  1  0.603  0.163  0.799  1.0
  F  F39  1  0.397  0.837  0.799  1.0
[/CIF]
.
The structure described by CAsF3 is Indium-like structured and crystallizes in the tetragonal P4_2/nmc space group. The structure is zero-dimensional and consists of eight (trifluoromethyl)arsine molecules. C(1) is bonded in a distorted trigonal non-coplanar geometry to one As(1), one F(2), and two equivalent F(1) atoms. As(1) is bonded in a distorted single-bond geometry to one C(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF file [CIF]
data_AsCF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.714
_cell_length_b   10.714
_cell_length_c   6.487
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   744.610
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.500  0.655  0.065  1.0
  As  As1  1  0.500  0.345  0.065  1.0
  As  As2  1  0.845  0.000  0.565  1.0
  As  As3  1  0.155  0.000  0.565  1.0
  As  As4  1  0.655  0.500  0.935  1.0
  As  As5  1  0.000  0.845  0.435  1.0
  As  As6  1  0.000  0.155  0.435  1.0
  As  As7  1  0.345  0.500  0.935  1.0
  C  C8  1  0.500  0.761  0.801  1.0
  C  C9  1  0.500  0.239  0.801  1.0
  C  C10  1  0.739  0.000  0.301  1.0
  C  C11  1  0.261  0.000  0.301  1.0
  C  C12  1  0.761  0.500  0.199  1.0
  C  C13  1  0.000  0.739  0.699  1.0
  C  C14  1  0.000  0.261  0.699  1.0
  C  C15  1  0.239  0.500  0.199  1.0
  F  F16  1  0.337  0.897  0.299  1.0
  F  F17  1  0.397  0.163  0.799  1.0
  F  F18  1  0.603  0.837  0.799  1.0
  F  F19  1  0.663  0.103  0.299  1.0
  F  F20  1  0.163  0.397  0.201  1.0
  F  F21  1  0.837  0.603  0.201  1.0
  F  F22  1  0.897  0.337  0.701  1.0
  F  F23  1  0.103  0.663  0.701  1.0
  F  F24  1  0.304  0.500  0.380  1.0
  F  F25  1  0.000  0.196  0.880  1.0
  F  F26  1  0.000  0.804  0.880  1.0
  F  F27  1  0.696  0.500  0.380  1.0
  F  F28  1  0.196  0.000  0.120  1.0
  F  F29  1  0.804  0.000  0.120  1.0
  F  F30  1  0.500  0.304  0.620  1.0
  F  F31  1  0.500  0.696  0.620  1.0
  F  F32  1  0.163  0.603  0.201  1.0
  F  F33  1  0.103  0.337  0.701  1.0
  F  F34  1  0.897  0.663  0.701  1.0
  F  F35  1  0.837  0.397  0.201  1.0
  F  F36  1  0.337  0.103  0.299  1.0
  F  F37  1  0.663  0.897  0.299  1.0
  F  F38  1  0.603  0.163  0.799  1.0
  F  F39  1  0.397  0.837  0.799  1.0
[/CIF]
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