The structure described by H5O2(H2O)4(HClO4)2H5O6ClClO4 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one hypochlorous acid;trihydrate molecule, two hypochlorous acid;trihydrate molecules, one molecular hydrogen;dihydrate molecule, four water molecules, and one H5O6Cl cluster. In the H5O6Cl cluster, there are five inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one O(15) and one O(19) atom. In the second H site, H(12) is bonded in a linear geometry to one O(19) and one O(23) atom. In the third H site, H(11) is bonded in a single-bond geometry to one O(19) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one O(23) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one O(23) atom. There are six inequivalent O sites. In the first O site, O(9) is bonded in a distorted single-bond geometry to one Cl(1) atom. In the second O site, O(15) is bonded in a distorted bent 120 degrees geometry to one H(6) and one Cl(1) atom. In the third O site, O(19) is bonded in a trigonal non-coplanar geometry to one H(11), one H(12), and one H(6) atom. In the fourth O site, O(23) is bonded in a trigonal non-coplanar geometry to one H(12), one H(17), and one H(18) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(15), one O(5), and one O(9) atom. is represented by the CIF card [CIF]
data_H5ClO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.053
_cell_length_b   7.470
_cell_length_c   11.419
_cell_angle_alpha   89.875
_cell_angle_beta   89.948
_cell_angle_gamma   88.530
_symmetry_Int_Tables_number   1
_cell_volume   516.157
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.996  0.710  0.249  1.0
  H  H1  1  0.187  0.707  0.750  1.0
  H  H2  1  0.499  0.250  0.053  1.0
  H  H3  1  0.011  0.238  0.462  1.0
  H  H4  1  0.536  0.783  0.960  1.0
  H  H5  1  0.506  0.263  0.443  1.0
  H  H6  1  0.011  0.237  0.038  1.0
  H  H7  1  0.520  0.800  0.097  1.0
  H  H8  1  0.989  0.744  0.521  1.0
  H  H9  1  0.976  0.541  0.488  1.0
  H  H10  1  0.462  0.214  0.577  1.0
  H  H11  1  0.506  0.023  0.483  1.0
  H  H12  1  0.994  0.278  0.906  1.0
  H  H13  1  0.503  0.007  0.012  1.0
  H  H14  1  0.463  0.206  0.919  1.0
  H  H15  1  0.993  0.278  0.594  1.0
  H  H16  1  0.517  0.810  0.397  1.0
  H  H17  1  0.525  0.792  0.533  1.0
  H  H18  1  0.976  0.540  0.012  1.0
  H  H19  1  0.990  0.743  0.979  1.0
  Cl  Cl20  1  0.583  0.491  0.250  1.0
  Cl  Cl21  1  0.063  0.992  0.249  1.0
  Cl  Cl22  1  0.432  0.492  0.749  1.0
  Cl  Cl23  1  0.918  0.997  0.750  1.0
  O  O24  1  0.606  0.688  0.247  1.0
  O  O25  1  0.133  0.781  0.249  1.0
  O  O26  1  0.392  0.304  0.748  1.0
  O  O27  1  0.897  0.194  0.750  1.0
  O  O28  1  0.799  0.403  0.252  1.0
  O  O29  1  0.275  0.072  0.248  1.0
  O  O30  1  0.177  0.574  0.753  1.0
  O  O31  1  0.700  0.920  0.750  1.0
  O  O32  1  0.459  0.439  0.146  1.0
  O  O33  1  0.939  0.025  0.354  1.0
  O  O34  1  0.529  0.555  0.643  1.0
  O  O35  1  0.043  0.940  0.855  1.0
  O  O36  1  0.538  0.549  0.854  1.0
  O  O37  1  0.044  0.938  0.647  1.0
  O  O38  1  0.457  0.446  0.356  1.0
  O  O39  1  0.936  0.025  0.145  1.0
  O  O40  1  0.462  0.853  0.022  1.0
  O  O41  1  0.906  0.660  0.474  1.0
  O  O42  1  0.545  0.175  0.507  1.0
  O  O43  1  0.069  0.315  0.978  1.0
  O  O44  1  0.543  0.166  0.989  1.0
  O  O45  1  0.069  0.315  0.522  1.0
  O  O46  1  0.459  0.865  0.469  1.0
  O  O47  1  0.907  0.659  0.026  1.0
[/CIF]
.
The structure described by H5O2(H2O)4(HClO4)2H5O6ClClO4 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one hypochlorous acid;trihydrate molecule, two hypochlorous acid;trihydrate molecules, one molecular hydrogen;dihydrate molecule, four water molecules, and one H5O6Cl cluster. In the H5O6Cl cluster, there are five inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one O(15) and one O(19) atom. In the second H site, H(12) is bonded in a linear geometry to one O(19) and one O(23) atom. In the third H site, H(11) is bonded in a single-bond geometry to one O(19) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one O(23) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one O(23) atom. There are six inequivalent O sites. In the first O site, O(9) is bonded in a distorted single-bond geometry to one Cl(1) atom. In the second O site, O(15) is bonded in a distorted bent 120 degrees geometry to one H(6) and one Cl(1) atom. In the third O site, O(19) is bonded in a trigonal non-coplanar geometry to one H(11), one H(12), and one H(6) atom. In the fourth O site, O(23) is bonded in a trigonal non-coplanar geometry to one H(12), one H(17), and one H(18) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one Cl(1) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(15), one O(5), and one O(9) atom. is represented by the CIF card [CIF]
data_H5ClO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.053
_cell_length_b   7.470
_cell_length_c   11.419
_cell_angle_alpha   89.875
_cell_angle_beta   89.948
_cell_angle_gamma   88.530
_symmetry_Int_Tables_number   1
_cell_volume   516.157
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.996  0.710  0.249  1.0
  H  H1  1  0.187  0.707  0.750  1.0
  H  H2  1  0.499  0.250  0.053  1.0
  H  H3  1  0.011  0.238  0.462  1.0
  H  H4  1  0.536  0.783  0.960  1.0
  H  H5  1  0.506  0.263  0.443  1.0
  H  H6  1  0.011  0.237  0.038  1.0
  H  H7  1  0.520  0.800  0.097  1.0
  H  H8  1  0.989  0.744  0.521  1.0
  H  H9  1  0.976  0.541  0.488  1.0
  H  H10  1  0.462  0.214  0.577  1.0
  H  H11  1  0.506  0.023  0.483  1.0
  H  H12  1  0.994  0.278  0.906  1.0
  H  H13  1  0.503  0.007  0.012  1.0
  H  H14  1  0.463  0.206  0.919  1.0
  H  H15  1  0.993  0.278  0.594  1.0
  H  H16  1  0.517  0.810  0.397  1.0
  H  H17  1  0.525  0.792  0.533  1.0
  H  H18  1  0.976  0.540  0.012  1.0
  H  H19  1  0.990  0.743  0.979  1.0
  Cl  Cl20  1  0.583  0.491  0.250  1.0
  Cl  Cl21  1  0.063  0.992  0.249  1.0
  Cl  Cl22  1  0.432  0.492  0.749  1.0
  Cl  Cl23  1  0.918  0.997  0.750  1.0
  O  O24  1  0.606  0.688  0.247  1.0
  O  O25  1  0.133  0.781  0.249  1.0
  O  O26  1  0.392  0.304  0.748  1.0
  O  O27  1  0.897  0.194  0.750  1.0
  O  O28  1  0.799  0.403  0.252  1.0
  O  O29  1  0.275  0.072  0.248  1.0
  O  O30  1  0.177  0.574  0.753  1.0
  O  O31  1  0.700  0.920  0.750  1.0
  O  O32  1  0.459  0.439  0.146  1.0
  O  O33  1  0.939  0.025  0.354  1.0
  O  O34  1  0.529  0.555  0.643  1.0
  O  O35  1  0.043  0.940  0.855  1.0
  O  O36  1  0.538  0.549  0.854  1.0
  O  O37  1  0.044  0.938  0.647  1.0
  O  O38  1  0.457  0.446  0.356  1.0
  O  O39  1  0.936  0.025  0.145  1.0
  O  O40  1  0.462  0.853  0.022  1.0
  O  O41  1  0.906  0.660  0.474  1.0
  O  O42  1  0.545  0.175  0.507  1.0
  O  O43  1  0.069  0.315  0.978  1.0
  O  O44  1  0.543  0.166  0.989  1.0
  O  O45  1  0.069  0.315  0.522  1.0
  O  O46  1  0.459  0.865  0.469  1.0
  O  O47  1  0.907  0.659  0.026  1.0
[/CIF]
.