The material described by VW2C3 is Caswellsilverite-like structured and crystallizes in the orthorhombic Immm space group. V(1) is bonded to two equivalent C(1) and four equivalent C(2) atoms to form VC6 octahedra that share corners with two equivalent V(1)C6 octahedra, corners with four equivalent W(1)C6 octahedra, edges with two equivalent V(1)C6 octahedra, and edges with ten equivalent W(1)C6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. W(1) is bonded to two equivalent C(1) and four equivalent C(2) atoms to form WC6 octahedra that share corners with two equivalent V(1)C6 octahedra, corners with four equivalent W(1)C6 octahedra, edges with five equivalent V(1)C6 octahedra, and edges with seven equivalent W(1)C6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are two inequivalent C sites. In the first C site, C(1) is bonded to two equivalent V(1) and four equivalent W(1) atoms to form a mixture of corner and edge-sharing CV2W4 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second C site, C(2) is bonded to two equivalent V(1) and four equivalent W(1) atoms to form a mixture of corner and edge-sharing CV2W4 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. is represented by the Crystallographic Information File (CIF) [CIF]
data_VW2C3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.293
_cell_length_b   5.293
_cell_length_c   5.293
_cell_angle_alpha   146.524
_cell_angle_beta   131.789
_cell_angle_gamma   59.966
_symmetry_Int_Tables_number   1
_cell_volume   60.446
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.000  0.500  1.0
  W  W1  1  0.166  0.666  0.500  1.0
  W  W2  1  0.834  0.334  0.500  1.0
  C  C3  1  0.000  0.000  0.000  1.0
  C  C4  1  0.661  0.661  0.000  1.0
  C  C5  1  0.339  0.339  0.000  1.0
[/CIF]
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The material described by VW2C3 is Caswellsilverite-like structured and crystallizes in the orthorhombic Immm space group. V(1) is bonded to two equivalent C(1) and four equivalent C(2) atoms to form VC6 octahedra that share corners with two equivalent V(1)C6 octahedra, corners with four equivalent W(1)C6 octahedra, edges with two equivalent V(1)C6 octahedra, and edges with ten equivalent W(1)C6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. W(1) is bonded to two equivalent C(1) and four equivalent C(2) atoms to form WC6 octahedra that share corners with two equivalent V(1)C6 octahedra, corners with four equivalent W(1)C6 octahedra, edges with five equivalent V(1)C6 octahedra, and edges with seven equivalent W(1)C6 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are two inequivalent C sites. In the first C site, C(1) is bonded to two equivalent V(1) and four equivalent W(1) atoms to form a mixture of corner and edge-sharing CV2W4 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second C site, C(2) is bonded to two equivalent V(1) and four equivalent W(1) atoms to form a mixture of corner and edge-sharing CV2W4 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. is represented by the Crystallographic Information File (CIF) [CIF]
data_VW2C3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.293
_cell_length_b   5.293
_cell_length_c   5.293
_cell_angle_alpha   146.524
_cell_angle_beta   131.789
_cell_angle_gamma   59.966
_symmetry_Int_Tables_number   1
_cell_volume   60.446
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.000  0.500  1.0
  W  W1  1  0.166  0.666  0.500  1.0
  W  W2  1  0.834  0.334  0.500  1.0
  C  C3  1  0.000  0.000  0.000  1.0
  C  C4  1  0.661  0.661  0.000  1.0
  C  C5  1  0.339  0.339  0.000  1.0
[/CIF]
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