The crystal structure described by WAgC5(NS2)2C4N is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two C4N clusters and two WAgC5(NS2)2 clusters. In each C4N cluster, there are four inequivalent C sites. In the first C site, C(6) is bonded in a distorted single-bond geometry to one C(9) and one N(3) atom. In the second C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(8), one C(9), and one N(3) atom. In the third C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one N(3) atom. In the fourth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one C(7), and one N(3) atom. N(3) is bonded in a 4-coordinate geometry to one C(6), one C(7), one C(8), and one C(9) atom. In each WAgC5(NS2)2 cluster, W(1) is bonded in a distorted tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. Ag(1) is bonded in a 3-coordinate geometry to one C(1), one S(1), and one S(2) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one N(2) atom. In the third C site, C(3) is bonded in a 2-coordinate geometry to one C(2) and one N(2) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one C(5) and one N(2) atom. In the fifth C site, C(5) is bonded in a linear geometry to one C(4) and one S(4) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a 3-coordinate geometry to one C(2), one C(3), and one C(4) atom. In the second N site, N(1) is bonded in a single-bond geometry to one C(1) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted L-shaped geometry to one W(1) and one Ag(1) atom. In the second S site, S(2) is bonded in a distorted L-shaped geometry to one W(1) and one Ag(1) atom. In the third S site, S(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one W(1) and one C(5) atom. is represented by the CIF file [CIF]
data_AgWC9S4N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.290
_cell_length_b   6.485
_cell_length_c   20.423
_cell_angle_alpha   85.855
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   962.886
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.715  0.494  0.686  1.0
  Ag  Ag1  1  0.215  0.506  0.314  1.0
  W  W2  1  0.716  0.239  0.809  1.0
  W  W3  1  0.216  0.761  0.191  1.0
  C  C4  1  0.712  0.656  0.595  1.0
  C  C5  1  0.212  0.344  0.405  1.0
  C  C6  1  0.133  0.984  0.940  1.0
  C  C7  1  0.633  0.016  0.060  1.0
  C  C8  1  0.067  0.781  0.926  1.0
  C  C9  1  0.567  0.219  0.074  1.0
  C  C10  1  0.392  0.824  0.876  1.0
  C  C11  1  0.892  0.176  0.124  1.0
  C  C12  1  0.534  0.841  0.842  1.0
  C  C13  1  0.034  0.159  0.158  1.0
  C  C14  1  0.167  0.877  0.547  1.0
  C  C15  1  0.667  0.123  0.453  1.0
  C  C16  1  0.211  0.972  0.653  1.0
  C  C17  1  0.711  0.028  0.347  1.0
  C  C18  1  0.392  0.056  0.628  1.0
  C  C19  1  0.892  0.944  0.372  1.0
  C  C20  1  0.089  0.992  0.599  1.0
  C  C21  1  0.589  0.008  0.401  1.0
  S  S22  1  0.967  0.350  0.759  1.0
  S  S23  1  0.467  0.650  0.241  1.0
  S  S24  1  0.466  0.377  0.764  1.0
  S  S25  1  0.966  0.623  0.236  1.0
  S  S26  1  0.729  0.313  0.910  1.0
  S  S27  1  0.229  0.687  0.090  1.0
  S  S28  1  0.724  0.872  0.799  1.0
  S  S29  1  0.224  0.128  0.201  1.0
  N  N30  1  0.700  0.739  0.543  1.0
  N  N31  1  0.200  0.261  0.457  1.0
  N  N32  1  0.239  0.847  0.906  1.0
  N  N33  1  0.739  0.153  0.094  1.0
  N  N34  1  0.314  0.963  0.578  1.0
  N  N35  1  0.814  0.037  0.422  1.0
[/CIF]
.
The crystal structure described by WAgC5(NS2)2C4N is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two C4N clusters and two WAgC5(NS2)2 clusters. In each C4N cluster, there are four inequivalent C sites. In the first C site, C(6) is bonded in a distorted single-bond geometry to one C(9) and one N(3) atom. In the second C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(8), one C(9), and one N(3) atom. In the third C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one N(3) atom. In the fourth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one C(7), and one N(3) atom. N(3) is bonded in a 4-coordinate geometry to one C(6), one C(7), one C(8), and one C(9) atom. In each WAgC5(NS2)2 cluster, W(1) is bonded in a distorted tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. Ag(1) is bonded in a 3-coordinate geometry to one C(1), one S(1), and one S(2) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Ag(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one N(2) atom. In the third C site, C(3) is bonded in a 2-coordinate geometry to one C(2) and one N(2) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one C(5) and one N(2) atom. In the fifth C site, C(5) is bonded in a linear geometry to one C(4) and one S(4) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a 3-coordinate geometry to one C(2), one C(3), and one C(4) atom. In the second N site, N(1) is bonded in a single-bond geometry to one C(1) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted L-shaped geometry to one W(1) and one Ag(1) atom. In the second S site, S(2) is bonded in a distorted L-shaped geometry to one W(1) and one Ag(1) atom. In the third S site, S(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one W(1) and one C(5) atom. is represented by the CIF file [CIF]
data_AgWC9S4N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.290
_cell_length_b   6.485
_cell_length_c   20.423
_cell_angle_alpha   85.855
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   962.886
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.715  0.494  0.686  1.0
  Ag  Ag1  1  0.215  0.506  0.314  1.0
  W  W2  1  0.716  0.239  0.809  1.0
  W  W3  1  0.216  0.761  0.191  1.0
  C  C4  1  0.712  0.656  0.595  1.0
  C  C5  1  0.212  0.344  0.405  1.0
  C  C6  1  0.133  0.984  0.940  1.0
  C  C7  1  0.633  0.016  0.060  1.0
  C  C8  1  0.067  0.781  0.926  1.0
  C  C9  1  0.567  0.219  0.074  1.0
  C  C10  1  0.392  0.824  0.876  1.0
  C  C11  1  0.892  0.176  0.124  1.0
  C  C12  1  0.534  0.841  0.842  1.0
  C  C13  1  0.034  0.159  0.158  1.0
  C  C14  1  0.167  0.877  0.547  1.0
  C  C15  1  0.667  0.123  0.453  1.0
  C  C16  1  0.211  0.972  0.653  1.0
  C  C17  1  0.711  0.028  0.347  1.0
  C  C18  1  0.392  0.056  0.628  1.0
  C  C19  1  0.892  0.944  0.372  1.0
  C  C20  1  0.089  0.992  0.599  1.0
  C  C21  1  0.589  0.008  0.401  1.0
  S  S22  1  0.967  0.350  0.759  1.0
  S  S23  1  0.467  0.650  0.241  1.0
  S  S24  1  0.466  0.377  0.764  1.0
  S  S25  1  0.966  0.623  0.236  1.0
  S  S26  1  0.729  0.313  0.910  1.0
  S  S27  1  0.229  0.687  0.090  1.0
  S  S28  1  0.724  0.872  0.799  1.0
  S  S29  1  0.224  0.128  0.201  1.0
  N  N30  1  0.700  0.739  0.543  1.0
  N  N31  1  0.200  0.261  0.457  1.0
  N  N32  1  0.239  0.847  0.906  1.0
  N  N33  1  0.739  0.153  0.094  1.0
  N  N34  1  0.314  0.963  0.578  1.0
  N  N35  1  0.814  0.037  0.422  1.0
[/CIF]
.