The compound described by TiF6(NH3OH)2(H2O)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four hydroxyammonium molecules, four water molecules, and two TiF6 clusters. In each TiF6 cluster, Ti(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Ti(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ti(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Ti(1) atom. is represented by the CIF file [CIF]
data_TiH12N2(O2F3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.131
_cell_length_b   6.272
_cell_length_c   7.495
_cell_angle_alpha   69.522
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   446.162
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.500  0.000  0.500  1.0
  Ti  Ti1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.773  0.485  0.321  1.0
  H  H3  1  0.273  0.515  0.179  1.0
  H  H4  1  0.227  0.515  0.679  1.0
  H  H5  1  0.727  0.485  0.821  1.0
  H  H6  1  0.621  0.556  0.381  1.0
  H  H7  1  0.121  0.444  0.119  1.0
  H  H8  1  0.379  0.444  0.619  1.0
  H  H9  1  0.879  0.556  0.881  1.0
  H  H10  1  0.737  0.764  0.279  1.0
  H  H11  1  0.237  0.236  0.221  1.0
  H  H12  1  0.263  0.236  0.721  1.0
  H  H13  1  0.763  0.764  0.779  1.0
  H  H14  1  0.555  0.671  0.099  1.0
  H  H15  1  0.055  0.329  0.401  1.0
  H  H16  1  0.445  0.329  0.901  1.0
  H  H17  1  0.945  0.671  0.599  1.0
  H  H18  1  0.626  0.157  0.834  1.0
  H  H19  1  0.126  0.843  0.666  1.0
  H  H20  1  0.374  0.843  0.166  1.0
  H  H21  1  0.874  0.157  0.334  1.0
  H  H22  1  0.627  0.180  0.040  1.0
  H  H23  1  0.127  0.820  0.460  1.0
  H  H24  1  0.373  0.820  0.960  1.0
  H  H25  1  0.873  0.180  0.540  1.0
  N  N26  1  0.698  0.609  0.283  1.0
  N  N27  1  0.198  0.391  0.217  1.0
  N  N28  1  0.302  0.391  0.717  1.0
  N  N29  1  0.802  0.609  0.783  1.0
  O  O30  1  0.652  0.631  0.099  1.0
  O  O31  1  0.152  0.369  0.401  1.0
  O  O32  1  0.348  0.369  0.901  1.0
  O  O33  1  0.848  0.631  0.599  1.0
  O  O34  1  0.607  0.262  0.903  1.0
  O  O35  1  0.107  0.738  0.597  1.0
  O  O36  1  0.393  0.738  0.097  1.0
  O  O37  1  0.893  0.262  0.403  1.0
  F  F38  1  0.382  0.943  0.707  1.0
  F  F39  1  0.882  0.057  0.793  1.0
  F  F40  1  0.618  0.057  0.293  1.0
  F  F41  1  0.118  0.943  0.207  1.0
  F  F42  1  0.640  0.006  0.669  1.0
  F  F43  1  0.140  0.994  0.831  1.0
  F  F44  1  0.360  0.994  0.331  1.0
  F  F45  1  0.860  0.006  0.169  1.0
  F  F46  1  0.522  0.683  0.559  1.0
  F  F47  1  0.022  0.317  0.941  1.0
  F  F48  1  0.478  0.317  0.441  1.0
  F  F49  1  0.978  0.683  0.059  1.0
[/CIF]
.
The compound described by TiF6(NH3OH)2(H2O)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four hydroxyammonium molecules, four water molecules, and two TiF6 clusters. In each TiF6 cluster, Ti(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Ti(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ti(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Ti(1) atom. is represented by the CIF file [CIF]
data_TiH12N2(O2F3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.131
_cell_length_b   6.272
_cell_length_c   7.495
_cell_angle_alpha   69.522
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   446.162
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.500  0.000  0.500  1.0
  Ti  Ti1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.773  0.485  0.321  1.0
  H  H3  1  0.273  0.515  0.179  1.0
  H  H4  1  0.227  0.515  0.679  1.0
  H  H5  1  0.727  0.485  0.821  1.0
  H  H6  1  0.621  0.556  0.381  1.0
  H  H7  1  0.121  0.444  0.119  1.0
  H  H8  1  0.379  0.444  0.619  1.0
  H  H9  1  0.879  0.556  0.881  1.0
  H  H10  1  0.737  0.764  0.279  1.0
  H  H11  1  0.237  0.236  0.221  1.0
  H  H12  1  0.263  0.236  0.721  1.0
  H  H13  1  0.763  0.764  0.779  1.0
  H  H14  1  0.555  0.671  0.099  1.0
  H  H15  1  0.055  0.329  0.401  1.0
  H  H16  1  0.445  0.329  0.901  1.0
  H  H17  1  0.945  0.671  0.599  1.0
  H  H18  1  0.626  0.157  0.834  1.0
  H  H19  1  0.126  0.843  0.666  1.0
  H  H20  1  0.374  0.843  0.166  1.0
  H  H21  1  0.874  0.157  0.334  1.0
  H  H22  1  0.627  0.180  0.040  1.0
  H  H23  1  0.127  0.820  0.460  1.0
  H  H24  1  0.373  0.820  0.960  1.0
  H  H25  1  0.873  0.180  0.540  1.0
  N  N26  1  0.698  0.609  0.283  1.0
  N  N27  1  0.198  0.391  0.217  1.0
  N  N28  1  0.302  0.391  0.717  1.0
  N  N29  1  0.802  0.609  0.783  1.0
  O  O30  1  0.652  0.631  0.099  1.0
  O  O31  1  0.152  0.369  0.401  1.0
  O  O32  1  0.348  0.369  0.901  1.0
  O  O33  1  0.848  0.631  0.599  1.0
  O  O34  1  0.607  0.262  0.903  1.0
  O  O35  1  0.107  0.738  0.597  1.0
  O  O36  1  0.393  0.738  0.097  1.0
  O  O37  1  0.893  0.262  0.403  1.0
  F  F38  1  0.382  0.943  0.707  1.0
  F  F39  1  0.882  0.057  0.793  1.0
  F  F40  1  0.618  0.057  0.293  1.0
  F  F41  1  0.118  0.943  0.207  1.0
  F  F42  1  0.640  0.006  0.669  1.0
  F  F43  1  0.140  0.994  0.831  1.0
  F  F44  1  0.360  0.994  0.331  1.0
  F  F45  1  0.860  0.006  0.169  1.0
  F  F46  1  0.522  0.683  0.559  1.0
  F  F47  1  0.022  0.317  0.941  1.0
  F  F48  1  0.478  0.317  0.441  1.0
  F  F49  1  0.978  0.683  0.059  1.0
[/CIF]
.