The crystal structure described by (CuCl3)2N2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms and two CuCl3 clusters. In each CuCl3 cluster, Cu(1) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cu(1) atom. In the third Cl site, Cl(3) is bonded in an L-shaped geometry to two equivalent Cu(1) atoms. is represented by the CIF file [CIF]
data_CuNCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.021
_cell_length_b   4.254
_cell_length_c   9.566
_cell_angle_alpha   75.127
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   551.448
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.547  0.770  0.651  1.0
  Cu  Cu1  1  0.047  0.230  0.849  1.0
  Cu  Cu2  1  0.453  0.230  0.349  1.0
  Cu  Cu3  1  0.953  0.770  0.151  1.0
  N  N4  1  0.675  0.211  0.062  1.0
  N  N5  1  0.175  0.789  0.438  1.0
  N  N6  1  0.325  0.789  0.938  1.0
  N  N7  1  0.825  0.211  0.562  1.0
  Cl  Cl8  1  0.686  0.733  0.744  1.0
  Cl  Cl9  1  0.186  0.267  0.756  1.0
  Cl  Cl10  1  0.314  0.267  0.256  1.0
  Cl  Cl11  1  0.814  0.733  0.244  1.0
  Cl  Cl12  1  0.495  0.357  0.812  1.0
  Cl  Cl13  1  0.995  0.643  0.688  1.0
  Cl  Cl14  1  0.505  0.643  0.188  1.0
  Cl  Cl15  1  0.005  0.357  0.312  1.0
  Cl  Cl16  1  0.594  0.170  0.462  1.0
  Cl  Cl17  1  0.094  0.830  0.038  1.0
  Cl  Cl18  1  0.406  0.830  0.538  1.0
  Cl  Cl19  1  0.906  0.170  0.962  1.0
[/CIF]
.
The crystal structure described by (CuCl3)2N2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms and two CuCl3 clusters. In each CuCl3 cluster, Cu(1) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cu(1) atom. In the third Cl site, Cl(3) is bonded in an L-shaped geometry to two equivalent Cu(1) atoms. is represented by the CIF file [CIF]
data_CuNCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.021
_cell_length_b   4.254
_cell_length_c   9.566
_cell_angle_alpha   75.127
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   551.448
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.547  0.770  0.651  1.0
  Cu  Cu1  1  0.047  0.230  0.849  1.0
  Cu  Cu2  1  0.453  0.230  0.349  1.0
  Cu  Cu3  1  0.953  0.770  0.151  1.0
  N  N4  1  0.675  0.211  0.062  1.0
  N  N5  1  0.175  0.789  0.438  1.0
  N  N6  1  0.325  0.789  0.938  1.0
  N  N7  1  0.825  0.211  0.562  1.0
  Cl  Cl8  1  0.686  0.733  0.744  1.0
  Cl  Cl9  1  0.186  0.267  0.756  1.0
  Cl  Cl10  1  0.314  0.267  0.256  1.0
  Cl  Cl11  1  0.814  0.733  0.244  1.0
  Cl  Cl12  1  0.495  0.357  0.812  1.0
  Cl  Cl13  1  0.995  0.643  0.688  1.0
  Cl  Cl14  1  0.505  0.643  0.188  1.0
  Cl  Cl15  1  0.005  0.357  0.312  1.0
  Cl  Cl16  1  0.594  0.170  0.462  1.0
  Cl  Cl17  1  0.094  0.830  0.038  1.0
  Cl  Cl18  1  0.406  0.830  0.538  1.0
  Cl  Cl19  1  0.906  0.170  0.962  1.0
[/CIF]
.