The crystal structure described by P2N7H12NO3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules and two P2N7H12 clusters. In each P2N7H12 cluster, there are two inequivalent P sites. In the first P site, P(1) is bonded to one N(4), one N(5), one N(6), and one N(7) atom to form corner-sharing PN4 tetrahedra. In the second P site, P(2) is bonded to one N(1), one N(2), one N(3), and one N(7) atom to form corner-sharing PN4 tetrahedra. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one P(2), one H(1), and one H(2) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one P(2) and two equivalent H(3,4) atoms. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one P(2), one H(5), and one H(6) atom. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one P(1), one H(7), and one H(8) atom. In the fifth N site, N(5) is bonded in a distorted trigonal non-coplanar geometry to one P(1), one H(10), and one H(9) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one P(1), one H(11), and one H(12) atom. In the seventh N site, N(7) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one N(5) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one N(5) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one N(6) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one N(6) atom. is represented by the CIF card [CIF]
data_P2H12N8O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.635
_cell_length_b   8.155
_cell_length_c   11.276
_cell_angle_alpha   94.891
_cell_angle_beta   98.590
_cell_angle_gamma   101.054
_symmetry_Int_Tables_number   1
_cell_volume   499.392
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.003  0.757  0.871  1.0
  P  P1  1  0.997  0.243  0.129  1.0
  P  P2  1  0.701  0.805  0.652  1.0
  P  P3  1  0.299  0.195  0.348  1.0
  H  H4  1  0.765  0.551  0.582  1.0
  H  H5  1  0.235  0.449  0.418  1.0
  H  H6  1  0.753  0.679  0.469  1.0
  H  H7  1  0.247  0.321  0.531  1.0
  H  H8  1  0.016  0.008  0.616  1.0
  H  H9  1  0.984  0.992  0.384  1.0
  H  H10  1  0.784  0.092  0.654  1.0
  H  H11  1  0.216  0.908  0.346  1.0
  H  H12  1  0.342  0.838  0.541  1.0
  H  H13  1  0.658  0.162  0.459  1.0
  H  H14  1  0.288  0.723  0.657  1.0
  H  H15  1  0.712  0.277  0.343  1.0
  H  H16  1  0.066  0.733  0.072  1.0
  H  H17  1  0.934  0.267  0.928  1.0
  H  H18  1  0.762  0.681  0.015  1.0
  H  H19  1  0.238  0.319  0.985  1.0
  H  H20  1  0.286  0.587  0.854  1.0
  H  H21  1  0.714  0.413  0.146  1.0
  H  H22  1  0.001  0.495  0.779  1.0
  H  H23  1  0.999  0.505  0.221  1.0
  H  H24  1  0.359  0.918  0.836  1.0
  H  H25  1  0.641  0.082  0.164  1.0
  H  H26  1  0.223  0.027  0.935  1.0
  H  H27  1  0.777  0.973  0.065  1.0
  N  N28  1  0.796  0.671  0.560  1.0
  N  N29  1  0.204  0.329  0.440  1.0
  N  N30  1  0.831  0.989  0.613  1.0
  N  N31  1  0.169  0.011  0.387  1.0
  N  N32  1  0.408  0.814  0.625  1.0
  N  N33  1  0.592  0.186  0.375  1.0
  N  N34  1  0.929  0.751  0.008  1.0
  N  N35  1  0.071  0.249  0.992  1.0
  N  N36  1  0.122  0.606  0.811  1.0
  N  N37  1  0.878  0.394  0.189  1.0
  N  N38  1  0.242  0.913  0.897  1.0
  N  N39  1  0.758  0.087  0.103  1.0
  N  N40  1  0.750  0.763  0.787  1.0
  N  N41  1  0.250  0.237  0.213  1.0
  N  N42  1  0.510  0.320  0.761  1.0
  N  N43  1  0.490  0.680  0.239  1.0
  O  O44  1  0.556  0.355  0.875  1.0
  O  O45  1  0.444  0.645  0.125  1.0
  O  O46  1  0.687  0.314  0.703  1.0
  O  O47  1  0.313  0.686  0.297  1.0
  O  O48  1  0.292  0.292  0.705  1.0
  O  O49  1  0.708  0.708  0.295  1.0
[/CIF]
.
The crystal structure described by P2N7H12NO3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules and two P2N7H12 clusters. In each P2N7H12 cluster, there are two inequivalent P sites. In the first P site, P(1) is bonded to one N(4), one N(5), one N(6), and one N(7) atom to form corner-sharing PN4 tetrahedra. In the second P site, P(2) is bonded to one N(1), one N(2), one N(3), and one N(7) atom to form corner-sharing PN4 tetrahedra. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one P(2), one H(1), and one H(2) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one P(2) and two equivalent H(3,4) atoms. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one P(2), one H(5), and one H(6) atom. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one P(1), one H(7), and one H(8) atom. In the fifth N site, N(5) is bonded in a distorted trigonal non-coplanar geometry to one P(1), one H(10), and one H(9) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one P(1), one H(11), and one H(12) atom. In the seventh N site, N(7) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one N(5) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one N(5) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one N(6) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one N(6) atom. is represented by the CIF card [CIF]
data_P2H12N8O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.635
_cell_length_b   8.155
_cell_length_c   11.276
_cell_angle_alpha   94.891
_cell_angle_beta   98.590
_cell_angle_gamma   101.054
_symmetry_Int_Tables_number   1
_cell_volume   499.392
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.003  0.757  0.871  1.0
  P  P1  1  0.997  0.243  0.129  1.0
  P  P2  1  0.701  0.805  0.652  1.0
  P  P3  1  0.299  0.195  0.348  1.0
  H  H4  1  0.765  0.551  0.582  1.0
  H  H5  1  0.235  0.449  0.418  1.0
  H  H6  1  0.753  0.679  0.469  1.0
  H  H7  1  0.247  0.321  0.531  1.0
  H  H8  1  0.016  0.008  0.616  1.0
  H  H9  1  0.984  0.992  0.384  1.0
  H  H10  1  0.784  0.092  0.654  1.0
  H  H11  1  0.216  0.908  0.346  1.0
  H  H12  1  0.342  0.838  0.541  1.0
  H  H13  1  0.658  0.162  0.459  1.0
  H  H14  1  0.288  0.723  0.657  1.0
  H  H15  1  0.712  0.277  0.343  1.0
  H  H16  1  0.066  0.733  0.072  1.0
  H  H17  1  0.934  0.267  0.928  1.0
  H  H18  1  0.762  0.681  0.015  1.0
  H  H19  1  0.238  0.319  0.985  1.0
  H  H20  1  0.286  0.587  0.854  1.0
  H  H21  1  0.714  0.413  0.146  1.0
  H  H22  1  0.001  0.495  0.779  1.0
  H  H23  1  0.999  0.505  0.221  1.0
  H  H24  1  0.359  0.918  0.836  1.0
  H  H25  1  0.641  0.082  0.164  1.0
  H  H26  1  0.223  0.027  0.935  1.0
  H  H27  1  0.777  0.973  0.065  1.0
  N  N28  1  0.796  0.671  0.560  1.0
  N  N29  1  0.204  0.329  0.440  1.0
  N  N30  1  0.831  0.989  0.613  1.0
  N  N31  1  0.169  0.011  0.387  1.0
  N  N32  1  0.408  0.814  0.625  1.0
  N  N33  1  0.592  0.186  0.375  1.0
  N  N34  1  0.929  0.751  0.008  1.0
  N  N35  1  0.071  0.249  0.992  1.0
  N  N36  1  0.122  0.606  0.811  1.0
  N  N37  1  0.878  0.394  0.189  1.0
  N  N38  1  0.242  0.913  0.897  1.0
  N  N39  1  0.758  0.087  0.103  1.0
  N  N40  1  0.750  0.763  0.787  1.0
  N  N41  1  0.250  0.237  0.213  1.0
  N  N42  1  0.510  0.320  0.761  1.0
  N  N43  1  0.490  0.680  0.239  1.0
  O  O44  1  0.556  0.355  0.875  1.0
  O  O45  1  0.444  0.645  0.125  1.0
  O  O46  1  0.687  0.314  0.703  1.0
  O  O47  1  0.313  0.686  0.297  1.0
  O  O48  1  0.292  0.292  0.705  1.0
  O  O49  1  0.708  0.708  0.295  1.0
[/CIF]
.