The structure described by Sn5(TeO6)3 crystallizes in the monoclinic C2/c space group. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(1), one O(2), one O(4), one O(7), one O(8), and one O(9) atom to form distorted SnO6 octahedra that share  a cornercorner with one Sn(3)O6 octahedra, corners with two equivalent Te(2)O6 octahedra, edges with two equivalent Sn(2)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. In the second Sn site, Sn(2) is bonded to one O(2), one O(3), one O(5), one O(7), and two equivalent O(9) atoms to form distorted SnO6 octahedra that share  a cornercorner with one Sn(3)O6 octahedra,  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-55°. In the third Sn site, Sn(3) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms to form SnO6 octahedra that share corners with two equivalent Sn(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, corners with two equivalent Te(1)O6 octahedra, and edges with two equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(3), one O(5), one O(7), one O(8), and one O(9) atom to form TeO6 octahedra that share  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-49°. In the second Te site, Te(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Sn(2)O6 octahedra, corners with four equivalent Sn(1)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Sn(1) and one Te(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Sn(1), one Sn(2), and one Te(2) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Sn(2), one Sn(3), and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Sn(1), one Sn(3), and one Te(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Sn(2) and one Te(1) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Sn(3) and one Te(2) atom. In the seventh O site, O(7) is bonded in a trigonal non-coplanar geometry to one Sn(1), one Sn(2), and one Te(1) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Sn(1) and one Te(1) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Sn(1), two equivalent Sn(2), and one Te(1) atom. is represented by the CIF file [CIF]
data_Sn5(TeO6)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.013
_cell_length_b   9.013
_cell_length_c   11.110
_cell_angle_alpha   84.002
_cell_angle_beta   84.002
_cell_angle_gamma   60.292
_symmetry_Int_Tables_number   1
_cell_volume   778.176
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.307  0.003  0.730  1.0
  Sn  Sn1  1  0.003  0.307  0.230  1.0
  Sn  Sn2  1  0.172  0.518  0.035  1.0
  Sn  Sn3  1  0.518  0.172  0.535  1.0
  Sn  Sn4  1  0.482  0.828  0.465  1.0
  Sn  Sn5  1  0.820  0.180  0.750  1.0
  Sn  Sn6  1  0.180  0.820  0.250  1.0
  Sn  Sn7  1  0.828  0.482  0.965  1.0
  Sn  Sn8  1  0.693  0.997  0.270  1.0
  Sn  Sn9  1  0.997  0.693  0.770  1.0
  Te  Te10  1  0.679  0.659  0.707  1.0
  Te  Te11  1  0.000  0.000  0.000  1.0
  Te  Te12  1  0.000  0.000  0.500  1.0
  Te  Te13  1  0.659  0.679  0.207  1.0
  Te  Te14  1  0.321  0.341  0.293  1.0
  Te  Te15  1  0.341  0.321  0.793  1.0
  O  O16  1  0.898  0.615  0.640  1.0
  O  O17  1  0.254  0.937  0.566  1.0
  O  O18  1  0.436  0.752  0.306  1.0
  O  O19  1  0.925  0.924  0.182  1.0
  O  O20  1  0.063  0.746  0.934  1.0
  O  O21  1  0.076  0.075  0.318  1.0
  O  O22  1  0.603  0.607  0.071  1.0
  O  O23  1  0.885  0.230  0.583  1.0
  O  O24  1  0.115  0.770  0.417  1.0
  O  O25  1  0.237  0.288  0.145  1.0
  O  O26  1  0.459  0.756  0.793  1.0
  O  O27  1  0.763  0.712  0.855  1.0
  O  O28  1  0.746  0.063  0.434  1.0
  O  O29  1  0.560  0.917  0.612  1.0
  O  O30  1  0.244  0.541  0.707  1.0
  O  O31  1  0.397  0.393  0.929  1.0
  O  O32  1  0.541  0.244  0.207  1.0
  O  O33  1  0.083  0.440  0.888  1.0
  O  O34  1  0.248  0.564  0.194  1.0
  O  O35  1  0.756  0.459  0.293  1.0
  O  O36  1  0.615  0.898  0.140  1.0
  O  O37  1  0.440  0.083  0.388  1.0
  O  O38  1  0.770  0.115  0.917  1.0
  O  O39  1  0.607  0.603  0.571  1.0
  O  O40  1  0.564  0.248  0.694  1.0
  O  O41  1  0.924  0.925  0.682  1.0
  O  O42  1  0.288  0.237  0.645  1.0
  O  O43  1  0.393  0.397  0.429  1.0
  O  O44  1  0.937  0.254  0.066  1.0
  O  O45  1  0.917  0.560  0.112  1.0
  O  O46  1  0.102  0.385  0.360  1.0
  O  O47  1  0.075  0.076  0.818  1.0
  O  O48  1  0.230  0.885  0.083  1.0
  O  O49  1  0.712  0.763  0.355  1.0
  O  O50  1  0.752  0.436  0.806  1.0
  O  O51  1  0.385  0.102  0.860  1.0
[/CIF]
.
The structure described by Sn5(TeO6)3 crystallizes in the monoclinic C2/c space group. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(1), one O(2), one O(4), one O(7), one O(8), and one O(9) atom to form distorted SnO6 octahedra that share  a cornercorner with one Sn(3)O6 octahedra, corners with two equivalent Te(2)O6 octahedra, edges with two equivalent Sn(2)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. In the second Sn site, Sn(2) is bonded to one O(2), one O(3), one O(5), one O(7), and two equivalent O(9) atoms to form distorted SnO6 octahedra that share  a cornercorner with one Sn(3)O6 octahedra,  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and edges with two equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-55°. In the third Sn site, Sn(3) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms to form SnO6 octahedra that share corners with two equivalent Sn(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, corners with two equivalent Te(1)O6 octahedra, and edges with two equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-55°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(3), one O(5), one O(7), one O(8), and one O(9) atom to form TeO6 octahedra that share  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-49°. In the second Te site, Te(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Sn(2)O6 octahedra, corners with four equivalent Sn(1)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Sn(1) and one Te(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Sn(1), one Sn(2), and one Te(2) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Sn(2), one Sn(3), and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Sn(1), one Sn(3), and one Te(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Sn(2) and one Te(1) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Sn(3) and one Te(2) atom. In the seventh O site, O(7) is bonded in a trigonal non-coplanar geometry to one Sn(1), one Sn(2), and one Te(1) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Sn(1) and one Te(1) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Sn(1), two equivalent Sn(2), and one Te(1) atom. is represented by the CIF file [CIF]
data_Sn5(TeO6)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.013
_cell_length_b   9.013
_cell_length_c   11.110
_cell_angle_alpha   84.002
_cell_angle_beta   84.002
_cell_angle_gamma   60.292
_symmetry_Int_Tables_number   1
_cell_volume   778.176
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.307  0.003  0.730  1.0
  Sn  Sn1  1  0.003  0.307  0.230  1.0
  Sn  Sn2  1  0.172  0.518  0.035  1.0
  Sn  Sn3  1  0.518  0.172  0.535  1.0
  Sn  Sn4  1  0.482  0.828  0.465  1.0
  Sn  Sn5  1  0.820  0.180  0.750  1.0
  Sn  Sn6  1  0.180  0.820  0.250  1.0
  Sn  Sn7  1  0.828  0.482  0.965  1.0
  Sn  Sn8  1  0.693  0.997  0.270  1.0
  Sn  Sn9  1  0.997  0.693  0.770  1.0
  Te  Te10  1  0.679  0.659  0.707  1.0
  Te  Te11  1  0.000  0.000  0.000  1.0
  Te  Te12  1  0.000  0.000  0.500  1.0
  Te  Te13  1  0.659  0.679  0.207  1.0
  Te  Te14  1  0.321  0.341  0.293  1.0
  Te  Te15  1  0.341  0.321  0.793  1.0
  O  O16  1  0.898  0.615  0.640  1.0
  O  O17  1  0.254  0.937  0.566  1.0
  O  O18  1  0.436  0.752  0.306  1.0
  O  O19  1  0.925  0.924  0.182  1.0
  O  O20  1  0.063  0.746  0.934  1.0
  O  O21  1  0.076  0.075  0.318  1.0
  O  O22  1  0.603  0.607  0.071  1.0
  O  O23  1  0.885  0.230  0.583  1.0
  O  O24  1  0.115  0.770  0.417  1.0
  O  O25  1  0.237  0.288  0.145  1.0
  O  O26  1  0.459  0.756  0.793  1.0
  O  O27  1  0.763  0.712  0.855  1.0
  O  O28  1  0.746  0.063  0.434  1.0
  O  O29  1  0.560  0.917  0.612  1.0
  O  O30  1  0.244  0.541  0.707  1.0
  O  O31  1  0.397  0.393  0.929  1.0
  O  O32  1  0.541  0.244  0.207  1.0
  O  O33  1  0.083  0.440  0.888  1.0
  O  O34  1  0.248  0.564  0.194  1.0
  O  O35  1  0.756  0.459  0.293  1.0
  O  O36  1  0.615  0.898  0.140  1.0
  O  O37  1  0.440  0.083  0.388  1.0
  O  O38  1  0.770  0.115  0.917  1.0
  O  O39  1  0.607  0.603  0.571  1.0
  O  O40  1  0.564  0.248  0.694  1.0
  O  O41  1  0.924  0.925  0.682  1.0
  O  O42  1  0.288  0.237  0.645  1.0
  O  O43  1  0.393  0.397  0.429  1.0
  O  O44  1  0.937  0.254  0.066  1.0
  O  O45  1  0.917  0.560  0.112  1.0
  O  O46  1  0.102  0.385  0.360  1.0
  O  O47  1  0.075  0.076  0.818  1.0
  O  O48  1  0.230  0.885  0.083  1.0
  O  O49  1  0.712  0.763  0.355  1.0
  O  O50  1  0.752  0.436  0.806  1.0
  O  O51  1  0.385  0.102  0.860  1.0
[/CIF]
.