The structure described by Li5Ni3(SbO5)2 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 1-coordinate geometry to one O(2), one O(4), and one O(5) atom. In the second Li site, Li(2) is bonded in a 2-coordinate geometry to one Ni(1), one O(2), and one O(5) atom. In the third Li site, Li(3) is bonded in a 8-coordinate geometry to two equivalent Sb(1), two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 4-coordinate geometry to two equivalent Li(2), two equivalent O(1), and two equivalent O(2) atoms. In the second Ni site, Ni(2) is bonded in a 3-coordinate geometry to one O(4) and two equivalent O(2) atoms. Sb(1) is bonded in a 2-coordinate geometry to one Li(3), one O(1), one O(3), one O(5), and two equivalent O(2) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Li(3), one Ni(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 7-coordinate geometry to one Li(1), one Li(2), one Ni(1), two equivalent Ni(2), and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Li(3) and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Li(1) and one Ni(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Li(3), and one Sb(1) atom. is represented by the CIF card [CIF]
data_Li5Ni3(SbO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.240
_cell_length_b   5.363
_cell_length_c   7.923
_cell_angle_alpha   106.907
_cell_angle_beta   102.757
_cell_angle_gamma   101.801
_symmetry_Int_Tables_number   1
_cell_volume   198.944
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.843  0.500  0.385  1.0
  Li  Li1  1  0.611  0.492  0.808  1.0
  Li  Li2  1  0.000  0.000  0.500  1.0
  Li  Li3  1  0.389  0.508  0.192  1.0
  Li  Li4  1  0.157  0.500  0.616  1.0
  Ni  Ni5  1  0.000  0.500  0.000  1.0
  Ni  Ni6  1  0.807  0.997  0.898  1.0
  Ni  Ni7  1  0.193  0.003  0.102  1.0
  Sb  Sb8  1  0.405  0.003  0.702  1.0
  Sb  Sb9  1  0.595  0.997  0.298  1.0
  O  O10  1  0.217  0.224  0.835  1.0
  O  O11  1  0.409  0.766  0.939  1.0
  O  O12  1  0.580  0.779  0.553  1.0
  O  O13  1  0.982  0.235  0.246  1.0
  O  O14  1  0.785  0.236  0.656  1.0
  O  O15  1  0.215  0.764  0.344  1.0
  O  O16  1  0.018  0.765  0.754  1.0
  O  O17  1  0.420  0.221  0.447  1.0
  O  O18  1  0.591  0.234  0.061  1.0
  O  O19  1  0.783  0.776  0.165  1.0
[/CIF]
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The structure described by Li5Ni3(SbO5)2 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 1-coordinate geometry to one O(2), one O(4), and one O(5) atom. In the second Li site, Li(2) is bonded in a 2-coordinate geometry to one Ni(1), one O(2), and one O(5) atom. In the third Li site, Li(3) is bonded in a 8-coordinate geometry to two equivalent Sb(1), two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 4-coordinate geometry to two equivalent Li(2), two equivalent O(1), and two equivalent O(2) atoms. In the second Ni site, Ni(2) is bonded in a 3-coordinate geometry to one O(4) and two equivalent O(2) atoms. Sb(1) is bonded in a 2-coordinate geometry to one Li(3), one O(1), one O(3), one O(5), and two equivalent O(2) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Li(3), one Ni(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 7-coordinate geometry to one Li(1), one Li(2), one Ni(1), two equivalent Ni(2), and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a 1-coordinate geometry to one Li(3) and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Li(1) and one Ni(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Li(3), and one Sb(1) atom. is represented by the CIF card [CIF]
data_Li5Ni3(SbO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.240
_cell_length_b   5.363
_cell_length_c   7.923
_cell_angle_alpha   106.907
_cell_angle_beta   102.757
_cell_angle_gamma   101.801
_symmetry_Int_Tables_number   1
_cell_volume   198.944
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.843  0.500  0.385  1.0
  Li  Li1  1  0.611  0.492  0.808  1.0
  Li  Li2  1  0.000  0.000  0.500  1.0
  Li  Li3  1  0.389  0.508  0.192  1.0
  Li  Li4  1  0.157  0.500  0.616  1.0
  Ni  Ni5  1  0.000  0.500  0.000  1.0
  Ni  Ni6  1  0.807  0.997  0.898  1.0
  Ni  Ni7  1  0.193  0.003  0.102  1.0
  Sb  Sb8  1  0.405  0.003  0.702  1.0
  Sb  Sb9  1  0.595  0.997  0.298  1.0
  O  O10  1  0.217  0.224  0.835  1.0
  O  O11  1  0.409  0.766  0.939  1.0
  O  O12  1  0.580  0.779  0.553  1.0
  O  O13  1  0.982  0.235  0.246  1.0
  O  O14  1  0.785  0.236  0.656  1.0
  O  O15  1  0.215  0.764  0.344  1.0
  O  O16  1  0.018  0.765  0.754  1.0
  O  O17  1  0.420  0.221  0.447  1.0
  O  O18  1  0.591  0.234  0.061  1.0
  O  O19  1  0.783  0.776  0.165  1.0
[/CIF]
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