The crystal structure described by K2RuN3O5Cl3 crystallizes in the triclinic P-1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one O(1), one O(5), one Cl(2), two equivalent Cl(1), and two equivalent Cl(3) atoms. In the second K site, K(2) is bonded in a 8-coordinate geometry to one O(1), one O(5), two equivalent O(2), two equivalent O(3), one Cl(1), and one Cl(3) atom. Ru(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ru(1), one O(3), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ru(1), one O(1), and one O(2) atom. In the third N site, N(3) is bonded in a linear geometry to one Ru(1) and one O(4) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one N(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(2) and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent K(2) and one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one N(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to one K(2), two equivalent K(1), and one Ru(1) atom to form a mixture of distorted edge and corner-sharing ClK3Ru trigonal pyramids. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one K(1) and one Ru(1) atom. In the third Cl site, Cl(3) is bonded to one K(2), two equivalent K(1), and one Ru(1) atom to form a mixture of distorted edge and corner-sharing ClK3Ru tetrahedra. is represented by the CIF card [CIF]
data_K2RuN3Cl3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.195
_cell_length_b   7.689
_cell_length_c   10.467
_cell_angle_alpha   90.407
_cell_angle_beta   102.118
_cell_angle_gamma   90.538
_symmetry_Int_Tables_number   1
_cell_volume   566.061
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.770  0.748  0.022  1.0
  K  K1  1  0.619  0.254  0.636  1.0
  K  K2  1  0.381  0.746  0.364  1.0
  K  K3  1  0.230  0.252  0.978  1.0
  Ru  Ru4  1  0.129  0.754  0.739  1.0
  Ru  Ru5  1  0.871  0.246  0.261  1.0
  N  N6  1  0.308  0.953  0.697  1.0
  N  N7  1  0.676  0.434  0.295  1.0
  N  N8  1  0.986  0.255  0.426  1.0
  N  N9  1  0.324  0.566  0.705  1.0
  N  N10  1  0.692  0.047  0.303  1.0
  N  N11  1  0.014  0.745  0.574  1.0
  Cl  Cl12  1  0.088  0.028  0.207  1.0
  Cl  Cl13  1  0.291  0.769  0.957  1.0
  Cl  Cl14  1  0.912  0.972  0.793  1.0
  Cl  Cl15  1  0.071  0.477  0.200  1.0
  Cl  Cl16  1  0.709  0.231  0.043  1.0
  Cl  Cl17  1  0.929  0.523  0.800  1.0
  O  O18  1  0.598  0.533  0.207  1.0
  O  O19  1  0.643  0.447  0.407  1.0
  O  O20  1  0.347  0.956  0.586  1.0
  O  O21  1  0.357  0.553  0.593  1.0
  O  O22  1  0.653  0.044  0.414  1.0
  O  O23  1  0.055  0.260  0.538  1.0
  O  O24  1  0.373  0.067  0.779  1.0
  O  O25  1  0.402  0.467  0.793  1.0
  O  O26  1  0.945  0.740  0.462  1.0
  O  O27  1  0.627  0.933  0.221  1.0
[/CIF]
.
The crystal structure described by K2RuN3O5Cl3 crystallizes in the triclinic P-1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 7-coordinate geometry to one O(1), one O(5), one Cl(2), two equivalent Cl(1), and two equivalent Cl(3) atoms. In the second K site, K(2) is bonded in a 8-coordinate geometry to one O(1), one O(5), two equivalent O(2), two equivalent O(3), one Cl(1), and one Cl(3) atom. Ru(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ru(1), one O(3), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ru(1), one O(1), and one O(2) atom. In the third N site, N(3) is bonded in a linear geometry to one Ru(1) and one O(4) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one N(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(2) and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent K(2) and one N(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one N(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to one K(2), two equivalent K(1), and one Ru(1) atom to form a mixture of distorted edge and corner-sharing ClK3Ru trigonal pyramids. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one K(1) and one Ru(1) atom. In the third Cl site, Cl(3) is bonded to one K(2), two equivalent K(1), and one Ru(1) atom to form a mixture of distorted edge and corner-sharing ClK3Ru tetrahedra. is represented by the CIF card [CIF]
data_K2RuN3Cl3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.195
_cell_length_b   7.689
_cell_length_c   10.467
_cell_angle_alpha   90.407
_cell_angle_beta   102.118
_cell_angle_gamma   90.538
_symmetry_Int_Tables_number   1
_cell_volume   566.061
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.770  0.748  0.022  1.0
  K  K1  1  0.619  0.254  0.636  1.0
  K  K2  1  0.381  0.746  0.364  1.0
  K  K3  1  0.230  0.252  0.978  1.0
  Ru  Ru4  1  0.129  0.754  0.739  1.0
  Ru  Ru5  1  0.871  0.246  0.261  1.0
  N  N6  1  0.308  0.953  0.697  1.0
  N  N7  1  0.676  0.434  0.295  1.0
  N  N8  1  0.986  0.255  0.426  1.0
  N  N9  1  0.324  0.566  0.705  1.0
  N  N10  1  0.692  0.047  0.303  1.0
  N  N11  1  0.014  0.745  0.574  1.0
  Cl  Cl12  1  0.088  0.028  0.207  1.0
  Cl  Cl13  1  0.291  0.769  0.957  1.0
  Cl  Cl14  1  0.912  0.972  0.793  1.0
  Cl  Cl15  1  0.071  0.477  0.200  1.0
  Cl  Cl16  1  0.709  0.231  0.043  1.0
  Cl  Cl17  1  0.929  0.523  0.800  1.0
  O  O18  1  0.598  0.533  0.207  1.0
  O  O19  1  0.643  0.447  0.407  1.0
  O  O20  1  0.347  0.956  0.586  1.0
  O  O21  1  0.357  0.553  0.593  1.0
  O  O22  1  0.653  0.044  0.414  1.0
  O  O23  1  0.055  0.260  0.538  1.0
  O  O24  1  0.373  0.067  0.779  1.0
  O  O25  1  0.402  0.467  0.793  1.0
  O  O26  1  0.945  0.740  0.462  1.0
  O  O27  1  0.627  0.933  0.221  1.0
[/CIF]
.