The compound described by In(OH)3 crystallizes in the triclinic P1 space group. There are four inequivalent In sites. In the first In site, In(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(4), and one O(9) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 41-57°. In the second In site, In(2) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 41-55°. In the third In site, In(3) is bonded to one O(1), one O(12), one O(4), one O(5), one O(8), and one O(9) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 35-58°. In the fourth In site, In(4) is bonded to one O(1), one O(11), one O(12), one O(2), one O(6), and one O(7) atom to form distorted corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 35-58°. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(3) atom. In the second H site, H(2) is bonded in a linear geometry to one O(4) and one O(6) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(2) and one O(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) and one O(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(7) atom. In the seventh H site, H(7) is bonded in a distorted linear geometry to one O(11) and one O(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(11) atom. In the ninth H site, H(9) is bonded in a distorted linear geometry to one O(1) and one O(10) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(12) atom. In the twelfth H site, H(12) is bonded in a linear geometry to one O(12) and one O(3) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one In(3), one In(4), one H(1), and one H(9) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one In(1), one In(4), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one In(1), one In(2), one H(1), and one H(12) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one In(1), one In(3), and one H(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one In(2), one In(3), and one H(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one In(2), one In(4), and one H(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one In(2), one In(4), and one H(6) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one In(2), one In(3), one H(4), and one H(7) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one In(1), one In(3), and one H(5) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one In(1), one In(2), one H(10), and one H(9) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one In(1), one In(4), one H(7), and one H(8) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one In(3), one In(4), one H(11), and one H(12) atom. is represented by the CIF file [CIF]
data_In(HO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.964
_cell_length_b   6.998
_cell_length_c   7.005
_cell_angle_alpha   108.719
_cell_angle_beta   112.387
_cell_angle_gamma   106.869
_symmetry_Int_Tables_number   1
_cell_volume   263.764
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.500  0.516  0.498  1.0
  In  In1  1  0.012  0.997  0.502  1.0
  In  In2  1  0.992  0.491  0.010  1.0
  In  In3  1  0.513  0.012  0.975  1.0
  H  H4  1  0.838  0.534  0.374  1.0
  H  H5  1  0.302  0.327  0.019  1.0
  H  H6  1  0.298  0.826  0.454  1.0
  H  H7  1  0.723  0.033  0.671  1.0
  H  H8  1  0.542  0.370  0.817  1.0
  H  H9  1  0.694  0.743  0.045  1.0
  H  H10  1  0.640  0.162  0.458  1.0
  H  H11  1  0.354  0.030  0.306  1.0
  H  H12  1  0.961  0.316  0.285  1.0
  H  H13  1  0.205  0.417  0.623  1.0
  H  H14  1  0.231  0.603  0.832  1.0
  H  H15  1  0.988  0.676  0.671  1.0
  O  O16  1  0.834  0.341  0.178  1.0
  O  O17  1  0.512  0.830  0.664  1.0
  O  O18  1  0.849  0.658  0.514  1.0
  O  O19  1  0.297  0.448  0.147  1.0
  O  O20  1  0.167  0.830  0.323  1.0
  O  O21  1  0.323  0.163  0.832  1.0
  O  O22  1  0.704  0.874  0.167  1.0
  O  O23  1  0.834  0.161  0.664  1.0
  O  O24  1  0.665  0.501  0.830  1.0
  O  O25  1  0.169  0.307  0.473  1.0
  O  O26  1  0.495  0.157  0.330  1.0
  O  O27  1  0.163  0.701  0.873  1.0
[/CIF]
.
The compound described by In(OH)3 crystallizes in the triclinic P1 space group. There are four inequivalent In sites. In the first In site, In(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(4), and one O(9) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 41-57°. In the second In site, In(2) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 41-55°. In the third In site, In(3) is bonded to one O(1), one O(12), one O(4), one O(5), one O(8), and one O(9) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 35-58°. In the fourth In site, In(4) is bonded to one O(1), one O(11), one O(12), one O(2), one O(6), and one O(7) atom to form distorted corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 35-58°. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(3) atom. In the second H site, H(2) is bonded in a linear geometry to one O(4) and one O(6) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(2) and one O(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) and one O(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(7) atom. In the seventh H site, H(7) is bonded in a distorted linear geometry to one O(11) and one O(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(11) atom. In the ninth H site, H(9) is bonded in a distorted linear geometry to one O(1) and one O(10) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(12) atom. In the twelfth H site, H(12) is bonded in a linear geometry to one O(12) and one O(3) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one In(3), one In(4), one H(1), and one H(9) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one In(1), one In(4), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one In(1), one In(2), one H(1), and one H(12) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one In(1), one In(3), and one H(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one In(2), one In(3), and one H(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one In(2), one In(4), and one H(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one In(2), one In(4), and one H(6) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one In(2), one In(3), one H(4), and one H(7) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one In(1), one In(3), and one H(5) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one In(1), one In(2), one H(10), and one H(9) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one In(1), one In(4), one H(7), and one H(8) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one In(3), one In(4), one H(11), and one H(12) atom. is represented by the CIF file [CIF]
data_In(HO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.964
_cell_length_b   6.998
_cell_length_c   7.005
_cell_angle_alpha   108.719
_cell_angle_beta   112.387
_cell_angle_gamma   106.869
_symmetry_Int_Tables_number   1
_cell_volume   263.764
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.500  0.516  0.498  1.0
  In  In1  1  0.012  0.997  0.502  1.0
  In  In2  1  0.992  0.491  0.010  1.0
  In  In3  1  0.513  0.012  0.975  1.0
  H  H4  1  0.838  0.534  0.374  1.0
  H  H5  1  0.302  0.327  0.019  1.0
  H  H6  1  0.298  0.826  0.454  1.0
  H  H7  1  0.723  0.033  0.671  1.0
  H  H8  1  0.542  0.370  0.817  1.0
  H  H9  1  0.694  0.743  0.045  1.0
  H  H10  1  0.640  0.162  0.458  1.0
  H  H11  1  0.354  0.030  0.306  1.0
  H  H12  1  0.961  0.316  0.285  1.0
  H  H13  1  0.205  0.417  0.623  1.0
  H  H14  1  0.231  0.603  0.832  1.0
  H  H15  1  0.988  0.676  0.671  1.0
  O  O16  1  0.834  0.341  0.178  1.0
  O  O17  1  0.512  0.830  0.664  1.0
  O  O18  1  0.849  0.658  0.514  1.0
  O  O19  1  0.297  0.448  0.147  1.0
  O  O20  1  0.167  0.830  0.323  1.0
  O  O21  1  0.323  0.163  0.832  1.0
  O  O22  1  0.704  0.874  0.167  1.0
  O  O23  1  0.834  0.161  0.664  1.0
  O  O24  1  0.665  0.501  0.830  1.0
  O  O25  1  0.169  0.307  0.473  1.0
  O  O26  1  0.495  0.157  0.330  1.0
  O  O27  1  0.163  0.701  0.873  1.0
[/CIF]
.