The material described by Y6RhI10 crystallizes in the triclinic P-1 space group. There are three inequivalent Y sites. In the first Y site, Y(1) is bonded to one Rh(1), one I(1), one I(3), one I(4), and two equivalent I(5) atoms to form a mixture of distorted corner and edge-sharing YRhI5 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the second Y site, Y(2) is bonded to one Rh(1), one I(1), one I(2), one I(3), and two equivalent I(4) atoms to form a mixture of corner and edge-sharing YRhI5 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third Y site, Y(3) is bonded to one Rh(1), one I(3), one I(4), one I(5), and two equivalent I(2) atoms to form a mixture of corner and edge-sharing YRhI5 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. Rh(1) is bonded in an octahedral geometry to two equivalent Y(1), two equivalent Y(2), and two equivalent Y(3) atoms. There are five inequivalent I sites. In the first I site, I(1) is bonded in a distorted L-shaped geometry to one Y(1) and one Y(2) atom. In the second I site, I(2) is bonded in a distorted T-shaped geometry to one Y(2) and two equivalent Y(3) atoms. In the third I site, I(3) is bonded in a distorted T-shaped geometry to one Y(1), one Y(2), and one Y(3) atom. In the fourth I site, I(4) is bonded in a rectangular see-saw-like geometry to one Y(1), one Y(3), and two equivalent Y(2) atoms. In the fifth I site, I(5) is bonded in a distorted T-shaped geometry to one Y(3) and two equivalent Y(1) atoms. is represented by the CIF card [CIF]
data_Y6RhI10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.698
_cell_length_b   9.613
_cell_length_c   9.724
_cell_angle_alpha   107.330
_cell_angle_beta   97.041
_cell_angle_gamma   104.743
_symmetry_Int_Tables_number   1
_cell_volume   648.798
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.532  0.222  0.418  1.0
  Y  Y1  1  0.468  0.778  0.582  1.0
  Y  Y2  1  0.147  0.374  0.332  1.0
  Y  Y3  1  0.853  0.626  0.668  1.0
  Y  Y4  1  0.615  0.542  0.256  1.0
  Y  Y5  1  0.385  0.458  0.744  1.0
  Rh  Rh6  1  0.500  0.500  0.500  1.0
  I  I7  1  0.148  0.046  0.226  1.0
  I  I8  1  0.852  0.954  0.774  1.0
  I  I9  1  0.236  0.409  0.033  1.0
  I  I10  1  0.764  0.591  0.967  1.0
  I  I11  1  0.717  0.239  0.150  1.0
  I  I12  1  0.283  0.761  0.850  1.0
  I  I13  1  0.048  0.688  0.409  1.0
  I  I14  1  0.952  0.312  0.591  1.0
  I  I15  1  0.411  0.126  0.680  1.0
  I  I16  1  0.589  0.874  0.320  1.0
[/CIF]
.
The material described by Y6RhI10 crystallizes in the triclinic P-1 space group. There are three inequivalent Y sites. In the first Y site, Y(1) is bonded to one Rh(1), one I(1), one I(3), one I(4), and two equivalent I(5) atoms to form a mixture of distorted corner and edge-sharing YRhI5 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. In the second Y site, Y(2) is bonded to one Rh(1), one I(1), one I(2), one I(3), and two equivalent I(4) atoms to form a mixture of corner and edge-sharing YRhI5 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third Y site, Y(3) is bonded to one Rh(1), one I(3), one I(4), one I(5), and two equivalent I(2) atoms to form a mixture of corner and edge-sharing YRhI5 octahedra. The corner-sharing octahedral tilt angles range from 0-11°. Rh(1) is bonded in an octahedral geometry to two equivalent Y(1), two equivalent Y(2), and two equivalent Y(3) atoms. There are five inequivalent I sites. In the first I site, I(1) is bonded in a distorted L-shaped geometry to one Y(1) and one Y(2) atom. In the second I site, I(2) is bonded in a distorted T-shaped geometry to one Y(2) and two equivalent Y(3) atoms. In the third I site, I(3) is bonded in a distorted T-shaped geometry to one Y(1), one Y(2), and one Y(3) atom. In the fourth I site, I(4) is bonded in a rectangular see-saw-like geometry to one Y(1), one Y(3), and two equivalent Y(2) atoms. In the fifth I site, I(5) is bonded in a distorted T-shaped geometry to one Y(3) and two equivalent Y(1) atoms. is represented by the CIF card [CIF]
data_Y6RhI10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.698
_cell_length_b   9.613
_cell_length_c   9.724
_cell_angle_alpha   107.330
_cell_angle_beta   97.041
_cell_angle_gamma   104.743
_symmetry_Int_Tables_number   1
_cell_volume   648.798
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.532  0.222  0.418  1.0
  Y  Y1  1  0.468  0.778  0.582  1.0
  Y  Y2  1  0.147  0.374  0.332  1.0
  Y  Y3  1  0.853  0.626  0.668  1.0
  Y  Y4  1  0.615  0.542  0.256  1.0
  Y  Y5  1  0.385  0.458  0.744  1.0
  Rh  Rh6  1  0.500  0.500  0.500  1.0
  I  I7  1  0.148  0.046  0.226  1.0
  I  I8  1  0.852  0.954  0.774  1.0
  I  I9  1  0.236  0.409  0.033  1.0
  I  I10  1  0.764  0.591  0.967  1.0
  I  I11  1  0.717  0.239  0.150  1.0
  I  I12  1  0.283  0.761  0.850  1.0
  I  I13  1  0.048  0.688  0.409  1.0
  I  I14  1  0.952  0.312  0.591  1.0
  I  I15  1  0.411  0.126  0.680  1.0
  I  I16  1  0.589  0.874  0.320  1.0
[/CIF]
.