The compound described by V(ZnN)4 crystallizes in the triclinic P-1 space group. V(1) is bonded to one N(1), one N(2), one N(3), and one N(4) atom to form VN4 tetrahedra that share corners with four equivalent Zn(1)N4 tetrahedra. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(1), one N(2), one N(3), and one N(4) atom to form distorted ZnN4 tetrahedra that share corners with four equivalent V(1)N4 tetrahedra. In the second Zn site, Zn(2) is bonded in a 4-coordinate geometry to two equivalent N(2) and two equivalent N(3) atoms. In the third Zn site, Zn(3) is bonded in a distorted T-shaped geometry to one N(1) and two equivalent N(4) atoms. In the fourth Zn site, Zn(4) is bonded in a distorted see-saw-like geometry to one N(3), one N(4), and two equivalent N(1) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded to one V(1), one Zn(1), one Zn(3), and two equivalent Zn(4) atoms to form distorted NVZn4 trigonal bipyramids that share corners with two equivalent N(3)VZn4 square pyramids, corners with two equivalent N(2)VZn3 tetrahedra,  an edgeedge with one N(3)VZn4 square pyramid, and  an edgeedge with one N(1)VZn4 trigonal bipyramid. In the second N site, N(2) is bonded to one V(1), one Zn(1), and two equivalent Zn(2) atoms to form distorted NVZn3 tetrahedra that share corners with six equivalent N(3)VZn4 square pyramids, corners with two equivalent N(1)VZn4 trigonal bipyramids, and  an edgeedge with one N(2)VZn3 tetrahedra. In the third N site, N(3) is bonded to one V(1), one Zn(1), one Zn(4), and two equivalent Zn(2) atoms to form distorted NVZn4 square pyramids that share corners with six equivalent N(2)VZn3 tetrahedra, corners with two equivalent N(1)VZn4 trigonal bipyramids,  an edgeedge with one N(3)VZn4 square pyramid, and  an edgeedge with one N(1)VZn4 trigonal bipyramid. In the fourth N site, N(4) is bonded in a 5-coordinate geometry to one V(1), one Zn(1), one Zn(4), and two equivalent Zn(3) atoms. is represented by the CIF file [CIF]
data_V(ZnN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.391
_cell_length_b   5.344
_cell_length_c   8.874
_cell_angle_alpha   65.268
_cell_angle_beta   91.415
_cell_angle_gamma   71.427
_symmetry_Int_Tables_number   1
_cell_volume   216.350
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.664  0.897  0.776  1.0
  V  V1  1  0.336  0.103  0.224  1.0
  Zn  Zn2  1  0.780  0.579  0.200  1.0
  Zn  Zn3  1  0.220  0.421  0.800  1.0
  Zn  Zn4  1  0.761  0.236  0.998  1.0
  Zn  Zn5  1  0.239  0.764  0.002  1.0
  Zn  Zn6  1  0.715  0.495  0.605  1.0
  Zn  Zn7  1  0.285  0.505  0.395  1.0
  Zn  Zn8  1  0.138  0.040  0.619  1.0
  Zn  Zn9  1  0.862  0.960  0.381  1.0
  N  N10  1  0.888  0.778  0.643  1.0
  N  N11  1  0.112  0.222  0.357  1.0
  N  N12  1  0.833  0.849  0.974  1.0
  N  N13  1  0.167  0.151  0.026  1.0
  N  N14  1  0.446  0.677  0.821  1.0
  N  N15  1  0.554  0.323  0.179  1.0
  N  N16  1  0.559  0.722  0.349  1.0
  N  N17  1  0.441  0.278  0.651  1.0
[/CIF]
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The compound described by V(ZnN)4 crystallizes in the triclinic P-1 space group. V(1) is bonded to one N(1), one N(2), one N(3), and one N(4) atom to form VN4 tetrahedra that share corners with four equivalent Zn(1)N4 tetrahedra. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(1), one N(2), one N(3), and one N(4) atom to form distorted ZnN4 tetrahedra that share corners with four equivalent V(1)N4 tetrahedra. In the second Zn site, Zn(2) is bonded in a 4-coordinate geometry to two equivalent N(2) and two equivalent N(3) atoms. In the third Zn site, Zn(3) is bonded in a distorted T-shaped geometry to one N(1) and two equivalent N(4) atoms. In the fourth Zn site, Zn(4) is bonded in a distorted see-saw-like geometry to one N(3), one N(4), and two equivalent N(1) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded to one V(1), one Zn(1), one Zn(3), and two equivalent Zn(4) atoms to form distorted NVZn4 trigonal bipyramids that share corners with two equivalent N(3)VZn4 square pyramids, corners with two equivalent N(2)VZn3 tetrahedra,  an edgeedge with one N(3)VZn4 square pyramid, and  an edgeedge with one N(1)VZn4 trigonal bipyramid. In the second N site, N(2) is bonded to one V(1), one Zn(1), and two equivalent Zn(2) atoms to form distorted NVZn3 tetrahedra that share corners with six equivalent N(3)VZn4 square pyramids, corners with two equivalent N(1)VZn4 trigonal bipyramids, and  an edgeedge with one N(2)VZn3 tetrahedra. In the third N site, N(3) is bonded to one V(1), one Zn(1), one Zn(4), and two equivalent Zn(2) atoms to form distorted NVZn4 square pyramids that share corners with six equivalent N(2)VZn3 tetrahedra, corners with two equivalent N(1)VZn4 trigonal bipyramids,  an edgeedge with one N(3)VZn4 square pyramid, and  an edgeedge with one N(1)VZn4 trigonal bipyramid. In the fourth N site, N(4) is bonded in a 5-coordinate geometry to one V(1), one Zn(1), one Zn(4), and two equivalent Zn(3) atoms. is represented by the CIF file [CIF]
data_V(ZnN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.391
_cell_length_b   5.344
_cell_length_c   8.874
_cell_angle_alpha   65.268
_cell_angle_beta   91.415
_cell_angle_gamma   71.427
_symmetry_Int_Tables_number   1
_cell_volume   216.350
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.664  0.897  0.776  1.0
  V  V1  1  0.336  0.103  0.224  1.0
  Zn  Zn2  1  0.780  0.579  0.200  1.0
  Zn  Zn3  1  0.220  0.421  0.800  1.0
  Zn  Zn4  1  0.761  0.236  0.998  1.0
  Zn  Zn5  1  0.239  0.764  0.002  1.0
  Zn  Zn6  1  0.715  0.495  0.605  1.0
  Zn  Zn7  1  0.285  0.505  0.395  1.0
  Zn  Zn8  1  0.138  0.040  0.619  1.0
  Zn  Zn9  1  0.862  0.960  0.381  1.0
  N  N10  1  0.888  0.778  0.643  1.0
  N  N11  1  0.112  0.222  0.357  1.0
  N  N12  1  0.833  0.849  0.974  1.0
  N  N13  1  0.167  0.151  0.026  1.0
  N  N14  1  0.446  0.677  0.821  1.0
  N  N15  1  0.554  0.323  0.179  1.0
  N  N16  1  0.559  0.722  0.349  1.0
  N  N17  1  0.441  0.278  0.651  1.0
[/CIF]
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