The crystal structure described by KSn4S3O12Cl crystallizes in the hexagonal P6_3 space group. K(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(4) atoms. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 3-coordinate geometry to three equivalent O(2) atoms. In the second Sn site, Sn(2) is bonded in a 4-coordinate geometry to one O(3), one O(4), and two equivalent Cl(1) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one K(1), one Sn(2), and one S(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one S(1) atom. In the third O site, O(2) is bonded in a 1-coordinate geometry to one K(1), one Sn(1), and one S(1) atom. In the fourth O site, O(3) is bonded in a distorted water-like geometry to one Sn(2) and one S(1) atom. Cl(1) is bonded to six equivalent Sn(2) atoms to form distorted face-sharing ClSn6 octahedra. is represented by the CIF file [CIF]
data_KSn4S3ClO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.198
_cell_length_b   10.198
_cell_length_c   8.353
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   752.425
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.333  0.667  0.973  1.0
  K  K1  1  0.667  0.333  0.473  1.0
  Sn  Sn2  1  0.333  0.667  0.456  1.0
  Sn  Sn3  1  0.667  0.333  0.956  1.0
  Sn  Sn4  1  0.198  0.216  0.247  1.0
  Sn  Sn5  1  0.784  0.982  0.247  1.0
  Sn  Sn6  1  0.802  0.784  0.747  1.0
  Sn  Sn7  1  0.018  0.802  0.247  1.0
  Sn  Sn8  1  0.216  0.018  0.747  1.0
  Sn  Sn9  1  0.982  0.198  0.747  1.0
  S  S10  1  0.046  0.409  0.254  1.0
  S  S11  1  0.591  0.636  0.254  1.0
  S  S12  1  0.954  0.591  0.754  1.0
  S  S13  1  0.364  0.954  0.254  1.0
  S  S14  1  0.409  0.364  0.754  1.0
  S  S15  1  0.636  0.046  0.754  1.0
  Cl  Cl16  1  0.000  0.000  0.996  1.0
  Cl  Cl17  1  0.000  0.000  0.496  1.0
  O  O18  1  0.474  0.116  0.251  1.0
  O  O19  1  0.884  0.358  0.251  1.0
  O  O20  1  0.526  0.884  0.751  1.0
  O  O21  1  0.642  0.526  0.251  1.0
  O  O22  1  0.116  0.642  0.751  1.0
  O  O23  1  0.358  0.474  0.751  1.0
  O  O24  1  0.138  0.581  0.270  1.0
  O  O25  1  0.419  0.557  0.270  1.0
  O  O26  1  0.862  0.419  0.770  1.0
  O  O27  1  0.443  0.862  0.270  1.0
  O  O28  1  0.581  0.443  0.770  1.0
  O  O29  1  0.557  0.138  0.770  1.0
  O  O30  1  0.090  0.346  0.397  1.0
  O  O31  1  0.654  0.743  0.397  1.0
  O  O32  1  0.910  0.654  0.897  1.0
  O  O33  1  0.257  0.910  0.397  1.0
  O  O34  1  0.346  0.257  0.897  1.0
  O  O35  1  0.743  0.090  0.897  1.0
  O  O36  1  0.096  0.362  0.106  1.0
  O  O37  1  0.638  0.734  0.106  1.0
  O  O38  1  0.904  0.638  0.606  1.0
  O  O39  1  0.266  0.904  0.106  1.0
  O  O40  1  0.362  0.266  0.606  1.0
  O  O41  1  0.734  0.096  0.606  1.0
[/CIF]
.
The crystal structure described by KSn4S3O12Cl crystallizes in the hexagonal P6_3 space group. K(1) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(4) atoms. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 3-coordinate geometry to three equivalent O(2) atoms. In the second Sn site, Sn(2) is bonded in a 4-coordinate geometry to one O(3), one O(4), and two equivalent Cl(1) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one K(1), one Sn(2), and one S(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one S(1) atom. In the third O site, O(2) is bonded in a 1-coordinate geometry to one K(1), one Sn(1), and one S(1) atom. In the fourth O site, O(3) is bonded in a distorted water-like geometry to one Sn(2) and one S(1) atom. Cl(1) is bonded to six equivalent Sn(2) atoms to form distorted face-sharing ClSn6 octahedra. is represented by the CIF file [CIF]
data_KSn4S3ClO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.198
_cell_length_b   10.198
_cell_length_c   8.353
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   752.425
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.333  0.667  0.973  1.0
  K  K1  1  0.667  0.333  0.473  1.0
  Sn  Sn2  1  0.333  0.667  0.456  1.0
  Sn  Sn3  1  0.667  0.333  0.956  1.0
  Sn  Sn4  1  0.198  0.216  0.247  1.0
  Sn  Sn5  1  0.784  0.982  0.247  1.0
  Sn  Sn6  1  0.802  0.784  0.747  1.0
  Sn  Sn7  1  0.018  0.802  0.247  1.0
  Sn  Sn8  1  0.216  0.018  0.747  1.0
  Sn  Sn9  1  0.982  0.198  0.747  1.0
  S  S10  1  0.046  0.409  0.254  1.0
  S  S11  1  0.591  0.636  0.254  1.0
  S  S12  1  0.954  0.591  0.754  1.0
  S  S13  1  0.364  0.954  0.254  1.0
  S  S14  1  0.409  0.364  0.754  1.0
  S  S15  1  0.636  0.046  0.754  1.0
  Cl  Cl16  1  0.000  0.000  0.996  1.0
  Cl  Cl17  1  0.000  0.000  0.496  1.0
  O  O18  1  0.474  0.116  0.251  1.0
  O  O19  1  0.884  0.358  0.251  1.0
  O  O20  1  0.526  0.884  0.751  1.0
  O  O21  1  0.642  0.526  0.251  1.0
  O  O22  1  0.116  0.642  0.751  1.0
  O  O23  1  0.358  0.474  0.751  1.0
  O  O24  1  0.138  0.581  0.270  1.0
  O  O25  1  0.419  0.557  0.270  1.0
  O  O26  1  0.862  0.419  0.770  1.0
  O  O27  1  0.443  0.862  0.270  1.0
  O  O28  1  0.581  0.443  0.770  1.0
  O  O29  1  0.557  0.138  0.770  1.0
  O  O30  1  0.090  0.346  0.397  1.0
  O  O31  1  0.654  0.743  0.397  1.0
  O  O32  1  0.910  0.654  0.897  1.0
  O  O33  1  0.257  0.910  0.397  1.0
  O  O34  1  0.346  0.257  0.897  1.0
  O  O35  1  0.743  0.090  0.897  1.0
  O  O36  1  0.096  0.362  0.106  1.0
  O  O37  1  0.638  0.734  0.106  1.0
  O  O38  1  0.904  0.638  0.606  1.0
  O  O39  1  0.266  0.904  0.106  1.0
  O  O40  1  0.362  0.266  0.606  1.0
  O  O41  1  0.734  0.096  0.606  1.0
[/CIF]
.