The compound described by RbBi(MoO4)2 is Zircon-derived structured and crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 8-coordinate geometry to one O(3), one O(7), two equivalent O(5), two equivalent O(6), and two equivalent O(8) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a distorted tetrahedral geometry to one O(3), one O(4), one O(5), and one O(8) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(6), and one O(7) atom. Bi(1) is bonded in a 8-coordinate geometry to one O(3), one O(7), two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. There are eight inequivalent O sites. In the first O site, O(8) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(1) atom. In the second O site, O(1) is bonded in a 1-coordinate geometry to one Mo(2) and two equivalent Bi(1) atoms. In the third O site, O(2) is bonded in a distorted single-bond geometry to one Mo(2) and two equivalent Bi(1) atoms. In the fourth O site, O(3) is bonded in a distorted trigonal planar geometry to one Rb(1), one Mo(1), and one Bi(1) atom. In the fifth O site, O(4) is bonded in a 3-coordinate geometry to one Mo(1) and two equivalent Bi(1) atoms. In the sixth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(1) atom. In the seventh O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(2) atom. In the eighth O site, O(7) is bonded in a 3-coordinate geometry to one Rb(1), one Mo(2), and one Bi(1) atom. is represented by the CIF file [CIF]
data_RbBi(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.313
_cell_length_b   5.378
_cell_length_c   11.819
_cell_angle_alpha   87.787
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   782.071
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.376  0.017  0.622  1.0
  Rb  Rb1  1  0.124  0.517  0.622  1.0
  Rb  Rb2  1  0.876  0.483  0.378  1.0
  Rb  Rb3  1  0.624  0.983  0.378  1.0
  Bi  Bi4  1  0.876  0.509  0.879  1.0
  Bi  Bi5  1  0.376  0.991  0.121  1.0
  Bi  Bi6  1  0.124  0.491  0.121  1.0
  Bi  Bi7  1  0.624  0.009  0.879  1.0
  Mo  Mo8  1  0.146  0.996  0.342  1.0
  Mo  Mo9  1  0.113  0.023  0.887  1.0
  Mo  Mo10  1  0.887  0.977  0.113  1.0
  Mo  Mo11  1  0.387  0.523  0.887  1.0
  Mo  Mo12  1  0.854  0.004  0.658  1.0
  Mo  Mo13  1  0.354  0.496  0.342  1.0
  Mo  Mo14  1  0.613  0.477  0.113  1.0
  Mo  Mo15  1  0.646  0.504  0.658  1.0
  O  O16  1  0.804  0.845  0.001  1.0
  O  O17  1  0.540  0.748  0.051  1.0
  O  O18  1  0.936  0.758  0.731  1.0
  O  O19  1  0.710  0.684  0.778  1.0
  O  O20  1  0.052  0.816  0.419  1.0
  O  O21  1  0.436  0.742  0.269  1.0
  O  O22  1  0.696  0.578  0.222  1.0
  O  O23  1  0.196  0.922  0.778  1.0
  O  O24  1  0.552  0.684  0.581  1.0
  O  O25  1  0.696  0.345  0.001  1.0
  O  O26  1  0.025  0.259  0.824  1.0
  O  O27  1  0.564  0.258  0.731  1.0
  O  O28  1  0.460  0.252  0.949  1.0
  O  O29  1  0.975  0.741  0.176  1.0
  O  O30  1  0.448  0.316  0.419  1.0
  O  O31  1  0.525  0.241  0.176  1.0
  O  O32  1  0.304  0.655  0.999  1.0
  O  O33  1  0.774  0.842  0.560  1.0
  O  O34  1  0.290  0.316  0.222  1.0
  O  O35  1  0.790  0.184  0.778  1.0
  O  O36  1  0.726  0.342  0.560  1.0
  O  O37  1  0.274  0.658  0.440  1.0
  O  O38  1  0.960  0.248  0.051  1.0
  O  O39  1  0.804  0.078  0.222  1.0
  O  O40  1  0.196  0.155  0.999  1.0
  O  O41  1  0.226  0.158  0.440  1.0
  O  O42  1  0.304  0.422  0.778  1.0
  O  O43  1  0.948  0.184  0.581  1.0
  O  O44  1  0.475  0.759  0.824  1.0
  O  O45  1  0.064  0.242  0.269  1.0
  O  O46  1  0.210  0.816  0.222  1.0
  O  O47  1  0.040  0.752  0.949  1.0
[/CIF]
.
The compound described by RbBi(MoO4)2 is Zircon-derived structured and crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 8-coordinate geometry to one O(3), one O(7), two equivalent O(5), two equivalent O(6), and two equivalent O(8) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a distorted tetrahedral geometry to one O(3), one O(4), one O(5), and one O(8) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(6), and one O(7) atom. Bi(1) is bonded in a 8-coordinate geometry to one O(3), one O(7), two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. There are eight inequivalent O sites. In the first O site, O(8) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(1) atom. In the second O site, O(1) is bonded in a 1-coordinate geometry to one Mo(2) and two equivalent Bi(1) atoms. In the third O site, O(2) is bonded in a distorted single-bond geometry to one Mo(2) and two equivalent Bi(1) atoms. In the fourth O site, O(3) is bonded in a distorted trigonal planar geometry to one Rb(1), one Mo(1), and one Bi(1) atom. In the fifth O site, O(4) is bonded in a 3-coordinate geometry to one Mo(1) and two equivalent Bi(1) atoms. In the sixth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(1) atom. In the seventh O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Mo(2) atom. In the eighth O site, O(7) is bonded in a 3-coordinate geometry to one Rb(1), one Mo(2), and one Bi(1) atom. is represented by the CIF file [CIF]
data_RbBi(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.313
_cell_length_b   5.378
_cell_length_c   11.819
_cell_angle_alpha   87.787
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   782.071
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.376  0.017  0.622  1.0
  Rb  Rb1  1  0.124  0.517  0.622  1.0
  Rb  Rb2  1  0.876  0.483  0.378  1.0
  Rb  Rb3  1  0.624  0.983  0.378  1.0
  Bi  Bi4  1  0.876  0.509  0.879  1.0
  Bi  Bi5  1  0.376  0.991  0.121  1.0
  Bi  Bi6  1  0.124  0.491  0.121  1.0
  Bi  Bi7  1  0.624  0.009  0.879  1.0
  Mo  Mo8  1  0.146  0.996  0.342  1.0
  Mo  Mo9  1  0.113  0.023  0.887  1.0
  Mo  Mo10  1  0.887  0.977  0.113  1.0
  Mo  Mo11  1  0.387  0.523  0.887  1.0
  Mo  Mo12  1  0.854  0.004  0.658  1.0
  Mo  Mo13  1  0.354  0.496  0.342  1.0
  Mo  Mo14  1  0.613  0.477  0.113  1.0
  Mo  Mo15  1  0.646  0.504  0.658  1.0
  O  O16  1  0.804  0.845  0.001  1.0
  O  O17  1  0.540  0.748  0.051  1.0
  O  O18  1  0.936  0.758  0.731  1.0
  O  O19  1  0.710  0.684  0.778  1.0
  O  O20  1  0.052  0.816  0.419  1.0
  O  O21  1  0.436  0.742  0.269  1.0
  O  O22  1  0.696  0.578  0.222  1.0
  O  O23  1  0.196  0.922  0.778  1.0
  O  O24  1  0.552  0.684  0.581  1.0
  O  O25  1  0.696  0.345  0.001  1.0
  O  O26  1  0.025  0.259  0.824  1.0
  O  O27  1  0.564  0.258  0.731  1.0
  O  O28  1  0.460  0.252  0.949  1.0
  O  O29  1  0.975  0.741  0.176  1.0
  O  O30  1  0.448  0.316  0.419  1.0
  O  O31  1  0.525  0.241  0.176  1.0
  O  O32  1  0.304  0.655  0.999  1.0
  O  O33  1  0.774  0.842  0.560  1.0
  O  O34  1  0.290  0.316  0.222  1.0
  O  O35  1  0.790  0.184  0.778  1.0
  O  O36  1  0.726  0.342  0.560  1.0
  O  O37  1  0.274  0.658  0.440  1.0
  O  O38  1  0.960  0.248  0.051  1.0
  O  O39  1  0.804  0.078  0.222  1.0
  O  O40  1  0.196  0.155  0.999  1.0
  O  O41  1  0.226  0.158  0.440  1.0
  O  O42  1  0.304  0.422  0.778  1.0
  O  O43  1  0.948  0.184  0.581  1.0
  O  O44  1  0.475  0.759  0.824  1.0
  O  O45  1  0.064  0.242  0.269  1.0
  O  O46  1  0.210  0.816  0.222  1.0
  O  O47  1  0.040  0.752  0.949  1.0
[/CIF]
.