The structure described by Co3C9SeO9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Co3C9SeO9 clusters. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a 4-coordinate geometry to one C(1), one C(4), one C(5), and one Se(1) atom. In the second Co site, Co(2) is bonded in a 4-coordinate geometry to one C(3), one C(8), one C(9), and one Se(1) atom. In the third Co site, Co(3) is bonded in a 4-coordinate geometry to one C(2), one C(6), one C(7), and one Se(1) atom. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(3) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(2) and one O(3) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Co(1) and one O(4) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Co(1) and one O(5) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Co(3) and one O(6) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Co(3) and one O(7) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Co(2) and one O(8) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Co(2) and one O(9) atom. Se(1) is bonded in a 3-coordinate geometry to one Co(1), one Co(2), and one Co(3) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co3C9SeO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.076
_cell_length_b   8.820
_cell_length_c   11.574
_cell_angle_alpha   86.799
_cell_angle_beta   100.353
_cell_angle_gamma   111.427
_symmetry_Int_Tables_number   1
_cell_volume   754.845
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.956  0.729  0.692  1.0
  Co  Co1  1  0.044  0.271  0.308  1.0
  Co  Co2  1  0.852  0.938  0.790  1.0
  Co  Co3  1  0.148  0.062  0.210  1.0
  Co  Co4  1  0.636  0.623  0.765  1.0
  Co  Co5  1  0.364  0.377  0.235  1.0
  C  C6  1  0.871  0.767  0.546  1.0
  C  C7  1  0.129  0.233  0.454  1.0
  C  C8  1  0.508  0.642  0.628  1.0
  C  C9  1  0.492  0.358  0.372  1.0
  C  C10  1  0.755  0.001  0.655  1.0
  C  C11  1  0.245  0.999  0.345  1.0
  C  C12  1  0.188  0.857  0.707  1.0
  C  C13  1  0.812  0.143  0.293  1.0
  C  C14  1  0.970  0.535  0.673  1.0
  C  C15  1  0.030  0.465  0.327  1.0
  C  C16  1  0.609  0.412  0.760  1.0
  C  C17  1  0.391  0.588  0.240  1.0
  C  C18  1  0.488  0.625  0.862  1.0
  C  C19  1  0.512  0.375  0.138  1.0
  C  C20  1  0.736  0.988  0.891  1.0
  C  C21  1  0.264  0.012  0.109  1.0
  C  C22  1  0.068  0.098  0.817  1.0
  C  C23  1  0.932  0.902  0.183  1.0
  Se  Se24  1  0.913  0.721  0.883  1.0
  Se  Se25  1  0.087  0.279  0.117  1.0
  O  O26  1  0.819  0.790  0.448  1.0
  O  O27  1  0.181  0.210  0.552  1.0
  O  O28  1  0.416  0.647  0.539  1.0
  O  O29  1  0.584  0.353  0.461  1.0
  O  O30  1  0.697  0.049  0.568  1.0
  O  O31  1  0.303  0.951  0.432  1.0
  O  O32  1  0.341  0.933  0.716  1.0
  O  O33  1  0.659  0.067  0.284  1.0
  O  O34  1  0.990  0.414  0.659  1.0
  O  O35  1  0.010  0.586  0.341  1.0
  O  O36  1  0.593  0.276  0.759  1.0
  O  O37  1  0.407  0.724  0.241  1.0
  O  O38  1  0.388  0.620  0.924  1.0
  O  O39  1  0.612  0.380  0.076  1.0
  O  O40  1  0.666  0.026  0.957  1.0
  O  O41  1  0.334  0.974  0.043  1.0
  O  O42  1  0.205  0.207  0.837  1.0
  O  O43  1  0.795  0.793  0.163  1.0
[/CIF]
.
The structure described by Co3C9SeO9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Co3C9SeO9 clusters. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a 4-coordinate geometry to one C(1), one C(4), one C(5), and one Se(1) atom. In the second Co site, Co(2) is bonded in a 4-coordinate geometry to one C(3), one C(8), one C(9), and one Se(1) atom. In the third Co site, Co(3) is bonded in a 4-coordinate geometry to one C(2), one C(6), one C(7), and one Se(1) atom. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(3) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(2) and one O(3) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Co(1) and one O(4) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Co(1) and one O(5) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Co(3) and one O(6) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Co(3) and one O(7) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Co(2) and one O(8) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Co(2) and one O(9) atom. Se(1) is bonded in a 3-coordinate geometry to one Co(1), one Co(2), and one Co(3) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co3C9SeO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.076
_cell_length_b   8.820
_cell_length_c   11.574
_cell_angle_alpha   86.799
_cell_angle_beta   100.353
_cell_angle_gamma   111.427
_symmetry_Int_Tables_number   1
_cell_volume   754.845
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.956  0.729  0.692  1.0
  Co  Co1  1  0.044  0.271  0.308  1.0
  Co  Co2  1  0.852  0.938  0.790  1.0
  Co  Co3  1  0.148  0.062  0.210  1.0
  Co  Co4  1  0.636  0.623  0.765  1.0
  Co  Co5  1  0.364  0.377  0.235  1.0
  C  C6  1  0.871  0.767  0.546  1.0
  C  C7  1  0.129  0.233  0.454  1.0
  C  C8  1  0.508  0.642  0.628  1.0
  C  C9  1  0.492  0.358  0.372  1.0
  C  C10  1  0.755  0.001  0.655  1.0
  C  C11  1  0.245  0.999  0.345  1.0
  C  C12  1  0.188  0.857  0.707  1.0
  C  C13  1  0.812  0.143  0.293  1.0
  C  C14  1  0.970  0.535  0.673  1.0
  C  C15  1  0.030  0.465  0.327  1.0
  C  C16  1  0.609  0.412  0.760  1.0
  C  C17  1  0.391  0.588  0.240  1.0
  C  C18  1  0.488  0.625  0.862  1.0
  C  C19  1  0.512  0.375  0.138  1.0
  C  C20  1  0.736  0.988  0.891  1.0
  C  C21  1  0.264  0.012  0.109  1.0
  C  C22  1  0.068  0.098  0.817  1.0
  C  C23  1  0.932  0.902  0.183  1.0
  Se  Se24  1  0.913  0.721  0.883  1.0
  Se  Se25  1  0.087  0.279  0.117  1.0
  O  O26  1  0.819  0.790  0.448  1.0
  O  O27  1  0.181  0.210  0.552  1.0
  O  O28  1  0.416  0.647  0.539  1.0
  O  O29  1  0.584  0.353  0.461  1.0
  O  O30  1  0.697  0.049  0.568  1.0
  O  O31  1  0.303  0.951  0.432  1.0
  O  O32  1  0.341  0.933  0.716  1.0
  O  O33  1  0.659  0.067  0.284  1.0
  O  O34  1  0.990  0.414  0.659  1.0
  O  O35  1  0.010  0.586  0.341  1.0
  O  O36  1  0.593  0.276  0.759  1.0
  O  O37  1  0.407  0.724  0.241  1.0
  O  O38  1  0.388  0.620  0.924  1.0
  O  O39  1  0.612  0.380  0.076  1.0
  O  O40  1  0.666  0.026  0.957  1.0
  O  O41  1  0.334  0.974  0.043  1.0
  O  O42  1  0.205  0.207  0.837  1.0
  O  O43  1  0.795  0.793  0.163  1.0
[/CIF]
.