The material described by ZnV2O4 is Spinel-like structured and crystallizes in the monoclinic Cm space group. There are nine inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(5), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one V(2)O4 tetrahedra,  a cornercorner with one V(9)O4 tetrahedra, corners with two equivalent V(7)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Zn(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Zn(3)O6 octahedra. In the second V site, V(2) is bonded to one O(2), one O(9), and two equivalent O(4) atoms to form VO4 tetrahedra that share  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Zn(5)O6 octahedra, corners with three equivalent Zn(2)O6 octahedra, and corners with four equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-58°. In the third V site, V(3) is bonded to one O(16), one O(3), two equivalent O(1), and two equivalent O(17) atoms to form VO6 octahedra that share corners with three equivalent V(9)O4 tetrahedra, corners with three equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(6)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. In the fourth V site, V(4) is bonded to one O(11), one O(12), one O(14), one O(4), one O(6), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one V(5)O4 tetrahedra,  a cornercorner with one V(7)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, corners with two equivalent V(8)O4 tetrahedra,  an edgeedge with one Zn(2)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent Zn(5)O6 octahedra. In the fifth V site, V(5) is bonded to one O(15), one O(6), and two equivalent O(10) atoms to form VO4 tetrahedra that share  a cornercorner with one Zn(5)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent Zn(6)O6 octahedra, corners with three equivalent Zn(4)O6 octahedra, and corners with four equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-59°. In the sixth V site, V(6) is bonded to one O(10), one O(13), one O(15), one O(16), one O(17), and one O(18) atom to form VO6 octahedra that share  a cornercorner with one V(8)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent V(5)O4 tetrahedra, corners with two equivalent V(9)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent V(6)O6 octahedra, and edges with two equivalent Zn(6)O6 octahedra. In the seventh V site, V(7) is bonded to one O(14), one O(5), and two equivalent O(7) atoms to form VO4 tetrahedra that share  a cornercorner with one Zn(5)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, corners with three equivalent Zn(2)O6 octahedra, and corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-59°. In the eighth V site, V(8) is bonded to one O(11), one O(18), and two equivalent O(12) atoms to form VO4 tetrahedra that share  a cornercorner with one Zn(6)O6 octahedra, corners with two equivalent V(6)O6 octahedra, corners with two equivalent Zn(5)O6 octahedra, corners with three equivalent Zn(4)O6 octahedra, and corners with four equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-58°. In the ninth V site, V(9) is bonded to one O(16), one O(8), and two equivalent O(17) atoms to form VO4 tetrahedra that share  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Zn(6)O6 octahedra, corners with three equivalent V(3)O6 octahedra, and corners with four equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-59°. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(13), one O(3), and two equivalent O(1) atoms to form ZnO4 tetrahedra that share  a cornercorner with one Zn(6)O6 octahedra, corners with two equivalent V(6)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, corners with three equivalent V(3)O6 octahedra, and corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-59°. In the second Zn site, Zn(2) is bonded to one O(5), one O(9), two equivalent O(4), and two equivalent O(7) atoms to form ZnO6 octahedra that share corners with three equivalent V(2)O4 tetrahedra, corners with three equivalent V(7)O4 tetrahedra,  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(4)O6 octahedra. In the third Zn site, Zn(3) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(7) atoms to form ZnO6 octahedra that share  a cornercorner with one V(2)O4 tetrahedra,  a cornercorner with one V(9)O4 tetrahedra, corners with two equivalent V(7)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Zn(2)O6 octahedra, and edges with four equivalent V(1)O6 octahedra. In the fourth Zn site, Zn(4) is bonded to one O(11), one O(15), two equivalent O(10), and two equivalent O(12) atoms to form ZnO6 octahedra that share corners with three equivalent V(5)O4 tetrahedra, corners with three equivalent V(8)O4 tetrahedra,  an edgeedge with one Zn(5)O6 octahedra,  an edgeedge with one Zn(6)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. In the fifth Zn site, Zn(5) is bonded to one O(14), one O(6), two equivalent O(12), and two equivalent O(4) atoms to form ZnO6 octahedra that share  a cornercorner with one V(5)O4 tetrahedra,  a cornercorner with one V(7)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, corners with two equivalent V(8)O4 tetrahedra,  an edgeedge with one Zn(2)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, and edges with four equivalent V(4)O6 octahedra. In the sixth Zn site, Zn(6) is bonded to one O(13), one O(18), two equivalent O(10), and two equivalent O(17) atoms to form ZnO6 octahedra that share  a cornercorner with one V(8)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent V(5)O4 tetrahedra, corners with two equivalent V(9)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, and edges with four equivalent V(6)O6 octahedra. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one V(1), one V(3), one Zn(1), and one Zn(3) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one V(2), two equivalent V(1), and one Zn(3) atom. In the third O site, O(3) is bonded to one V(3), two equivalent V(1), and one Zn(1) atom to form distorted corner-sharing OV3Zn trigonal pyramids. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one V(2), one V(4), one Zn(2), and one Zn(5) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one V(7), two equivalent V(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one V(5), two equivalent V(4), and one Zn(5) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one V(1), one V(7), one Zn(2), and one Zn(3) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one V(9), two equivalent V(1), and one Zn(3) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one V(2), two equivalent V(4), and one Zn(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one V(5), one V(6), one Zn(4), and one Zn(6) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one V(8), two equivalent V(4), and one Zn(4) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one V(4), one V(8), one Zn(4), and one Zn(5) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to two equivalent V(6), one Zn(1), and one Zn(6) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one V(7), two equivalent V(4), and one Zn(5) atom. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one V(5), two equivalent V(6), and one Zn(4) atom. In the sixteenth O site, O(16) is bonded to one V(3), one V(9), and two equivalent V(6) atoms to form distorted corner-sharing OV4 trigonal pyramids. In the seventeenth O site, O(17) is bonded in a rectangular see-saw-like geometry to one V(3), one V(6), one V(9), and one Zn(6) atom. In the eighteenth O site, O(18) is bonded in a rectangular see-saw-like geometry to one V(8), two equivalent V(6), and one Zn(6) atom. is represented by the CIF file [CIF]
data_V2ZnO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.093
_cell_length_b   6.093
_cell_length_c   14.871
_cell_angle_alpha   89.148
_cell_angle_beta   89.148
_cell_angle_gamma   59.770
_symmetry_Int_Tables_number   1
_cell_volume   476.981
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.170  0.668  0.833  1.0
  V  V1  1  0.496  0.496  0.623  1.0
  V  V2  1  0.500  0.500  0.998  1.0
  V  V3  1  0.668  0.170  0.833  1.0
  V  V4  1  0.500  0.000  0.501  1.0
  V  V5  1  0.829  0.829  0.291  1.0
  V  V6  1  0.000  0.500  0.501  1.0
  V  V7  1  0.833  0.332  0.167  1.0
  V  V8  1  0.172  0.172  0.712  1.0
  V  V9  1  0.332  0.833  0.167  1.0
  V  V10  1  0.504  0.504  0.377  1.0
  V  V11  1  0.835  0.835  0.041  1.0
  Zn  Zn12  1  0.162  0.162  0.958  1.0
  Zn  Zn13  1  0.833  0.833  0.667  1.0
  Zn  Zn14  1  0.668  0.668  0.833  1.0
  Zn  Zn15  1  0.168  0.168  0.333  1.0
  Zn  Zn16  1  0.000  0.000  0.501  1.0
  Zn  Zn17  1  0.331  0.331  0.166  1.0
  O  O18  1  0.343  0.803  0.916  1.0
  O  O19  1  0.496  0.496  0.754  1.0
  O  O20  1  0.803  0.343  0.916  1.0
  O  O21  1  0.347  0.347  0.913  1.0
  O  O22  1  0.670  0.149  0.579  1.0
  O  O23  1  0.996  0.996  0.758  1.0
  O  O24  1  0.825  0.825  0.423  1.0
  O  O25  1  0.518  0.005  0.756  1.0
  O  O26  1  0.149  0.670  0.579  1.0
  O  O27  1  0.840  0.840  0.911  1.0
  O  O28  1  0.672  0.672  0.577  1.0
  O  O29  1  0.005  0.518  0.756  1.0
  O  O30  1  0.998  0.485  0.246  1.0
  O  O31  1  0.328  0.328  0.422  1.0
  O  O32  1  0.851  0.333  0.421  1.0
  O  O33  1  0.485  0.998  0.246  1.0
  O  O34  1  0.159  0.159  0.094  1.0
  O  O35  1  0.175  0.175  0.578  1.0
  O  O36  1  0.004  0.004  0.244  1.0
  O  O37  1  0.333  0.851  0.421  1.0
  O  O38  1  0.656  0.656  0.085  1.0
  O  O39  1  0.186  0.664  0.084  1.0
  O  O40  1  0.505  0.505  0.243  1.0
  O  O41  1  0.664  0.186  0.084  1.0
[/CIF]
.
The material described by ZnV2O4 is Spinel-like structured and crystallizes in the monoclinic Cm space group. There are nine inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(5), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one V(2)O4 tetrahedra,  a cornercorner with one V(9)O4 tetrahedra, corners with two equivalent V(7)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Zn(2)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Zn(3)O6 octahedra. In the second V site, V(2) is bonded to one O(2), one O(9), and two equivalent O(4) atoms to form VO4 tetrahedra that share  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Zn(5)O6 octahedra, corners with three equivalent Zn(2)O6 octahedra, and corners with four equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-58°. In the third V site, V(3) is bonded to one O(16), one O(3), two equivalent O(1), and two equivalent O(17) atoms to form VO6 octahedra that share corners with three equivalent V(9)O4 tetrahedra, corners with three equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(6)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. In the fourth V site, V(4) is bonded to one O(11), one O(12), one O(14), one O(4), one O(6), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one V(5)O4 tetrahedra,  a cornercorner with one V(7)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, corners with two equivalent V(8)O4 tetrahedra,  an edgeedge with one Zn(2)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent Zn(5)O6 octahedra. In the fifth V site, V(5) is bonded to one O(15), one O(6), and two equivalent O(10) atoms to form VO4 tetrahedra that share  a cornercorner with one Zn(5)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent Zn(6)O6 octahedra, corners with three equivalent Zn(4)O6 octahedra, and corners with four equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-59°. In the sixth V site, V(6) is bonded to one O(10), one O(13), one O(15), one O(16), one O(17), and one O(18) atom to form VO6 octahedra that share  a cornercorner with one V(8)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent V(5)O4 tetrahedra, corners with two equivalent V(9)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, edges with two equivalent V(6)O6 octahedra, and edges with two equivalent Zn(6)O6 octahedra. In the seventh V site, V(7) is bonded to one O(14), one O(5), and two equivalent O(7) atoms to form VO4 tetrahedra that share  a cornercorner with one Zn(5)O6 octahedra, corners with two equivalent V(4)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, corners with three equivalent Zn(2)O6 octahedra, and corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-59°. In the eighth V site, V(8) is bonded to one O(11), one O(18), and two equivalent O(12) atoms to form VO4 tetrahedra that share  a cornercorner with one Zn(6)O6 octahedra, corners with two equivalent V(6)O6 octahedra, corners with two equivalent Zn(5)O6 octahedra, corners with three equivalent Zn(4)O6 octahedra, and corners with four equivalent V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-58°. In the ninth V site, V(9) is bonded to one O(16), one O(8), and two equivalent O(17) atoms to form VO4 tetrahedra that share  a cornercorner with one Zn(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Zn(6)O6 octahedra, corners with three equivalent V(3)O6 octahedra, and corners with four equivalent V(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-59°. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(13), one O(3), and two equivalent O(1) atoms to form ZnO4 tetrahedra that share  a cornercorner with one Zn(6)O6 octahedra, corners with two equivalent V(6)O6 octahedra, corners with two equivalent Zn(3)O6 octahedra, corners with three equivalent V(3)O6 octahedra, and corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-59°. In the second Zn site, Zn(2) is bonded to one O(5), one O(9), two equivalent O(4), and two equivalent O(7) atoms to form ZnO6 octahedra that share corners with three equivalent V(2)O4 tetrahedra, corners with three equivalent V(7)O4 tetrahedra,  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(4)O6 octahedra. In the third Zn site, Zn(3) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(7) atoms to form ZnO6 octahedra that share  a cornercorner with one V(2)O4 tetrahedra,  a cornercorner with one V(9)O4 tetrahedra, corners with two equivalent V(7)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Zn(2)O6 octahedra, and edges with four equivalent V(1)O6 octahedra. In the fourth Zn site, Zn(4) is bonded to one O(11), one O(15), two equivalent O(10), and two equivalent O(12) atoms to form ZnO6 octahedra that share corners with three equivalent V(5)O4 tetrahedra, corners with three equivalent V(8)O4 tetrahedra,  an edgeedge with one Zn(5)O6 octahedra,  an edgeedge with one Zn(6)O6 octahedra, edges with two equivalent V(4)O6 octahedra, and edges with two equivalent V(6)O6 octahedra. In the fifth Zn site, Zn(5) is bonded to one O(14), one O(6), two equivalent O(12), and two equivalent O(4) atoms to form ZnO6 octahedra that share  a cornercorner with one V(5)O4 tetrahedra,  a cornercorner with one V(7)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, corners with two equivalent V(8)O4 tetrahedra,  an edgeedge with one Zn(2)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, and edges with four equivalent V(4)O6 octahedra. In the sixth Zn site, Zn(6) is bonded to one O(13), one O(18), two equivalent O(10), and two equivalent O(17) atoms to form ZnO6 octahedra that share  a cornercorner with one V(8)O4 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent V(5)O4 tetrahedra, corners with two equivalent V(9)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Zn(4)O6 octahedra, and edges with four equivalent V(6)O6 octahedra. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one V(1), one V(3), one Zn(1), and one Zn(3) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one V(2), two equivalent V(1), and one Zn(3) atom. In the third O site, O(3) is bonded to one V(3), two equivalent V(1), and one Zn(1) atom to form distorted corner-sharing OV3Zn trigonal pyramids. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one V(2), one V(4), one Zn(2), and one Zn(5) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one V(7), two equivalent V(1), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one V(5), two equivalent V(4), and one Zn(5) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one V(1), one V(7), one Zn(2), and one Zn(3) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one V(9), two equivalent V(1), and one Zn(3) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one V(2), two equivalent V(4), and one Zn(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one V(5), one V(6), one Zn(4), and one Zn(6) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one V(8), two equivalent V(4), and one Zn(4) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one V(4), one V(8), one Zn(4), and one Zn(5) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to two equivalent V(6), one Zn(1), and one Zn(6) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one V(7), two equivalent V(4), and one Zn(5) atom. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one V(5), two equivalent V(6), and one Zn(4) atom. In the sixteenth O site, O(16) is bonded to one V(3), one V(9), and two equivalent V(6) atoms to form distorted corner-sharing OV4 trigonal pyramids. In the seventeenth O site, O(17) is bonded in a rectangular see-saw-like geometry to one V(3), one V(6), one V(9), and one Zn(6) atom. In the eighteenth O site, O(18) is bonded in a rectangular see-saw-like geometry to one V(8), two equivalent V(6), and one Zn(6) atom. is represented by the CIF file [CIF]
data_V2ZnO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.093
_cell_length_b   6.093
_cell_length_c   14.871
_cell_angle_alpha   89.148
_cell_angle_beta   89.148
_cell_angle_gamma   59.770
_symmetry_Int_Tables_number   1
_cell_volume   476.981
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.170  0.668  0.833  1.0
  V  V1  1  0.496  0.496  0.623  1.0
  V  V2  1  0.500  0.500  0.998  1.0
  V  V3  1  0.668  0.170  0.833  1.0
  V  V4  1  0.500  0.000  0.501  1.0
  V  V5  1  0.829  0.829  0.291  1.0
  V  V6  1  0.000  0.500  0.501  1.0
  V  V7  1  0.833  0.332  0.167  1.0
  V  V8  1  0.172  0.172  0.712  1.0
  V  V9  1  0.332  0.833  0.167  1.0
  V  V10  1  0.504  0.504  0.377  1.0
  V  V11  1  0.835  0.835  0.041  1.0
  Zn  Zn12  1  0.162  0.162  0.958  1.0
  Zn  Zn13  1  0.833  0.833  0.667  1.0
  Zn  Zn14  1  0.668  0.668  0.833  1.0
  Zn  Zn15  1  0.168  0.168  0.333  1.0
  Zn  Zn16  1  0.000  0.000  0.501  1.0
  Zn  Zn17  1  0.331  0.331  0.166  1.0
  O  O18  1  0.343  0.803  0.916  1.0
  O  O19  1  0.496  0.496  0.754  1.0
  O  O20  1  0.803  0.343  0.916  1.0
  O  O21  1  0.347  0.347  0.913  1.0
  O  O22  1  0.670  0.149  0.579  1.0
  O  O23  1  0.996  0.996  0.758  1.0
  O  O24  1  0.825  0.825  0.423  1.0
  O  O25  1  0.518  0.005  0.756  1.0
  O  O26  1  0.149  0.670  0.579  1.0
  O  O27  1  0.840  0.840  0.911  1.0
  O  O28  1  0.672  0.672  0.577  1.0
  O  O29  1  0.005  0.518  0.756  1.0
  O  O30  1  0.998  0.485  0.246  1.0
  O  O31  1  0.328  0.328  0.422  1.0
  O  O32  1  0.851  0.333  0.421  1.0
  O  O33  1  0.485  0.998  0.246  1.0
  O  O34  1  0.159  0.159  0.094  1.0
  O  O35  1  0.175  0.175  0.578  1.0
  O  O36  1  0.004  0.004  0.244  1.0
  O  O37  1  0.333  0.851  0.421  1.0
  O  O38  1  0.656  0.656  0.085  1.0
  O  O39  1  0.186  0.664  0.084  1.0
  O  O40  1  0.505  0.505  0.243  1.0
  O  O41  1  0.664  0.186  0.084  1.0
[/CIF]
.