The material structure described by Li5SbS crystallizes in the orthorhombic Pnma space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 2-coordinate geometry to two equivalent Sb(1) and two equivalent S(1) atoms. In the second Li site, Li(2) is bonded in a 2-coordinate geometry to two equivalent Sb(1) and two equivalent S(1) atoms. In the third Li site, Li(3) is bonded in a distorted single-bond geometry to three equivalent Sb(1) and one S(1) atom. Sb(1) is bonded in a 12-coordinate geometry to two equivalent Li(1), four equivalent Li(2), and six equivalent Li(3) atoms. S(1) is bonded in a 8-coordinate geometry to two equivalent Li(1), two equivalent Li(3), and four equivalent Li(2) atoms. is represented by the CIF file [CIF]
data_Li5SbS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.159
_cell_length_b   8.185
_cell_length_c   9.750
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   491.459
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.750  0.325  0.815  1.0
  Li  Li1  1  0.502  0.951  0.130  1.0
  Li  Li2  1  0.498  0.451  0.370  1.0
  Li  Li3  1  0.486  0.338  0.083  1.0
  Li  Li4  1  0.514  0.838  0.417  1.0
  Li  Li5  1  0.486  0.162  0.583  1.0
  Li  Li6  1  0.514  0.662  0.917  1.0
  Li  Li7  1  0.498  0.049  0.870  1.0
  Li  Li8  1  0.502  0.549  0.630  1.0
  Li  Li9  1  0.250  0.825  0.685  1.0
  Li  Li10  1  0.250  0.675  0.185  1.0
  Li  Li11  1  0.998  0.951  0.130  1.0
  Li  Li12  1  0.002  0.451  0.370  1.0
  Li  Li13  1  0.986  0.838  0.417  1.0
  Li  Li14  1  0.014  0.338  0.083  1.0
  Li  Li15  1  0.986  0.662  0.917  1.0
  Li  Li16  1  0.014  0.162  0.583  1.0
  Li  Li17  1  0.002  0.049  0.870  1.0
  Li  Li18  1  0.998  0.549  0.630  1.0
  Li  Li19  1  0.750  0.175  0.315  1.0
  Sb  Sb20  1  0.750  0.867  0.673  1.0
  Sb  Sb21  1  0.250  0.133  0.327  1.0
  Sb  Sb22  1  0.250  0.367  0.827  1.0
  Sb  Sb23  1  0.750  0.633  0.173  1.0
  S  S24  1  0.750  0.143  0.037  1.0
  S  S25  1  0.250  0.643  0.463  1.0
  S  S26  1  0.250  0.857  0.963  1.0
  S  S27  1  0.750  0.357  0.537  1.0
[/CIF]
.
The material structure described by Li5SbS crystallizes in the orthorhombic Pnma space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 2-coordinate geometry to two equivalent Sb(1) and two equivalent S(1) atoms. In the second Li site, Li(2) is bonded in a 2-coordinate geometry to two equivalent Sb(1) and two equivalent S(1) atoms. In the third Li site, Li(3) is bonded in a distorted single-bond geometry to three equivalent Sb(1) and one S(1) atom. Sb(1) is bonded in a 12-coordinate geometry to two equivalent Li(1), four equivalent Li(2), and six equivalent Li(3) atoms. S(1) is bonded in a 8-coordinate geometry to two equivalent Li(1), two equivalent Li(3), and four equivalent Li(2) atoms. is represented by the CIF file [CIF]
data_Li5SbS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.159
_cell_length_b   8.185
_cell_length_c   9.750
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   491.459
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.750  0.325  0.815  1.0
  Li  Li1  1  0.502  0.951  0.130  1.0
  Li  Li2  1  0.498  0.451  0.370  1.0
  Li  Li3  1  0.486  0.338  0.083  1.0
  Li  Li4  1  0.514  0.838  0.417  1.0
  Li  Li5  1  0.486  0.162  0.583  1.0
  Li  Li6  1  0.514  0.662  0.917  1.0
  Li  Li7  1  0.498  0.049  0.870  1.0
  Li  Li8  1  0.502  0.549  0.630  1.0
  Li  Li9  1  0.250  0.825  0.685  1.0
  Li  Li10  1  0.250  0.675  0.185  1.0
  Li  Li11  1  0.998  0.951  0.130  1.0
  Li  Li12  1  0.002  0.451  0.370  1.0
  Li  Li13  1  0.986  0.838  0.417  1.0
  Li  Li14  1  0.014  0.338  0.083  1.0
  Li  Li15  1  0.986  0.662  0.917  1.0
  Li  Li16  1  0.014  0.162  0.583  1.0
  Li  Li17  1  0.002  0.049  0.870  1.0
  Li  Li18  1  0.998  0.549  0.630  1.0
  Li  Li19  1  0.750  0.175  0.315  1.0
  Sb  Sb20  1  0.750  0.867  0.673  1.0
  Sb  Sb21  1  0.250  0.133  0.327  1.0
  Sb  Sb22  1  0.250  0.367  0.827  1.0
  Sb  Sb23  1  0.750  0.633  0.173  1.0
  S  S24  1  0.750  0.143  0.037  1.0
  S  S25  1  0.250  0.643  0.463  1.0
  S  S26  1  0.250  0.857  0.963  1.0
  S  S27  1  0.750  0.357  0.537  1.0
[/CIF]
.