The material structure described by CeCl3(H2O)7 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of three hydrochloric acid atoms and one Ce2H28O14Cl3 cluster. In the Ce2H28O14Cl3 cluster, there are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(13), one O(3), one O(5), one O(7), one O(9), one Cl(1), and one Cl(2) atom. In the second Ce site, Ce(2) is bonded in a 9-coordinate geometry to one O(10), one O(12), one O(14), one O(2), one O(4), one O(6), one O(8), one Cl(1), and one Cl(2) atom. There are twenty-eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(5) and one Cl(6) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(6) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one O(7) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one O(7) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one O(8) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one O(8) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one O(9) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one O(9) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one O(10) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one O(10) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one O(11) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one O(11) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one O(12) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one O(12) atom. In the twenty-fifth H site, H(25) is bonded in a single-bond geometry to one O(13) atom. In the twenty-sixth H site, H(26) is bonded in a single-bond geometry to one O(13) atom. In the twenty-seventh H site, H(27) is bonded in a single-bond geometry to one O(14) atom. In the twenty-eighth H site, H(28) is bonded in a single-bond geometry to one O(14) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Ce(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Ce(2), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one Ce(1), one H(5), and one H(6) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Ce(2), one H(7), and one H(8) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Ce(1), one H(10), and one H(9) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Ce(2), one H(11), and one H(12) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Ce(1), one H(13), and one H(14) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Ce(2), one H(15), and one H(16) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Ce(1), one H(17), and one H(18) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Ce(2), one H(19), and one H(20) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Ce(1), one H(21), and one H(22) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one Ce(2), one H(23), and one H(24) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one Ce(1), one H(25), and one H(26) atom. In the fourteenth O site, O(14) is bonded in a water-like geometry to one Ce(2), one H(27), and one H(28) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to one Ce(1) and one Ce(2) atom. In the second Cl site, Cl(2) is bonded in a water-like geometry to one Ce(1) and one Ce(2) atom. In the third Cl site, Cl(6) is bonded in a distorted single-bond geometry to one H(9) atom. is represented by the CIF card [CIF]
data_CeH14Cl3O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.268
_cell_length_b   9.378
_cell_length_c   8.136
_cell_angle_alpha   104.969
_cell_angle_beta   98.564
_cell_angle_gamma   70.369
_symmetry_Int_Tables_number   1
_cell_volume   572.646
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.306  0.180  0.214  1.0
  Ce  Ce1  1  0.671  0.834  0.778  1.0
  H  H2  1  0.198  0.460  0.508  1.0
  H  H3  1  0.137  0.554  0.364  1.0
  H  H4  1  0.838  0.467  0.645  1.0
  H  H5  1  0.973  0.541  0.617  1.0
  H  H6  1  0.641  0.260  0.484  1.0
  H  H7  1  0.466  0.383  0.540  1.0
  H  H8  1  0.370  0.741  0.497  1.0
  H  H9  1  0.557  0.636  0.438  1.0
  H  H10  1  0.512  0.390  0.128  1.0
  H  H11  1  0.345  0.408  1.000  1.0
  H  H12  1  0.635  0.600  0.985  1.0
  H  H13  1  0.478  0.616  0.844  1.0
  H  H14  1  0.021  0.296  0.924  1.0
  H  H15  1  0.951  0.406  0.098  1.0
  H  H16  1  0.980  0.766  0.024  1.0
  H  H17  1  0.997  0.598  0.925  1.0
  H  H18  1  0.369  0.166  0.611  1.0
  H  H19  1  0.184  0.150  0.565  1.0
  H  H20  1  0.673  0.861  0.393  1.0
  H  H21  1  0.861  0.847  0.468  1.0
  H  H22  1  0.284  0.842  0.238  1.0
  H  H23  1  0.464  0.818  0.168  1.0
  H  H24  1  0.552  0.199  0.886  1.0
  H  H25  1  0.690  0.161  0.748  1.0
  H  H26  1  0.914  0.192  0.219  1.0
  H  H27  1  0.019  0.036  0.275  1.0
  H  H28  1  0.077  0.798  0.767  1.0
  H  H29  1  0.008  0.978  0.820  1.0
  Cl  Cl30  1  0.657  0.993  0.146  1.0
  Cl  Cl31  1  0.307  0.010  0.853  1.0
  Cl  Cl32  1  0.878  0.239  0.674  1.0
  Cl  Cl33  1  0.112  0.795  0.377  1.0
  Cl  Cl34  1  0.263  0.531  0.770  1.0
  Cl  Cl35  1  0.696  0.498  0.206  1.0
  O  O36  1  0.158  0.450  0.386  1.0
  O  O37  1  0.850  0.566  0.632  1.0
  O  O38  1  0.518  0.298  0.445  1.0
  O  O39  1  0.494  0.711  0.536  1.0
  O  O40  1  0.425  0.337  0.067  1.0
  O  O41  1  0.580  0.650  0.888  1.0
  O  O42  1  0.059  0.343  0.041  1.0
  O  O43  1  0.913  0.694  0.982  1.0
  O  O44  1  0.277  0.169  0.520  1.0
  O  O45  1  0.744  0.864  0.500  1.0
  O  O46  1  0.361  0.896  0.218  1.0
  O  O47  1  0.601  0.125  0.781  1.0
  O  O48  1  0.028  0.115  0.220  1.0
  O  O49  1  0.975  0.884  0.808  1.0
[/CIF]
.
The material structure described by CeCl3(H2O)7 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of three hydrochloric acid atoms and one Ce2H28O14Cl3 cluster. In the Ce2H28O14Cl3 cluster, there are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 9-coordinate geometry to one O(1), one O(11), one O(13), one O(3), one O(5), one O(7), one O(9), one Cl(1), and one Cl(2) atom. In the second Ce site, Ce(2) is bonded in a 9-coordinate geometry to one O(10), one O(12), one O(14), one O(2), one O(4), one O(6), one O(8), one Cl(1), and one Cl(2) atom. There are twenty-eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(5) and one Cl(6) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(6) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one O(7) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one O(7) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one O(8) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one O(8) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one O(9) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one O(9) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one O(10) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one O(10) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one O(11) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one O(11) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one O(12) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one O(12) atom. In the twenty-fifth H site, H(25) is bonded in a single-bond geometry to one O(13) atom. In the twenty-sixth H site, H(26) is bonded in a single-bond geometry to one O(13) atom. In the twenty-seventh H site, H(27) is bonded in a single-bond geometry to one O(14) atom. In the twenty-eighth H site, H(28) is bonded in a single-bond geometry to one O(14) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Ce(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Ce(2), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one Ce(1), one H(5), and one H(6) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Ce(2), one H(7), and one H(8) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Ce(1), one H(10), and one H(9) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Ce(2), one H(11), and one H(12) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Ce(1), one H(13), and one H(14) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Ce(2), one H(15), and one H(16) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Ce(1), one H(17), and one H(18) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Ce(2), one H(19), and one H(20) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Ce(1), one H(21), and one H(22) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one Ce(2), one H(23), and one H(24) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one Ce(1), one H(25), and one H(26) atom. In the fourteenth O site, O(14) is bonded in a water-like geometry to one Ce(2), one H(27), and one H(28) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to one Ce(1) and one Ce(2) atom. In the second Cl site, Cl(2) is bonded in a water-like geometry to one Ce(1) and one Ce(2) atom. In the third Cl site, Cl(6) is bonded in a distorted single-bond geometry to one H(9) atom. is represented by the CIF card [CIF]
data_CeH14Cl3O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.268
_cell_length_b   9.378
_cell_length_c   8.136
_cell_angle_alpha   104.969
_cell_angle_beta   98.564
_cell_angle_gamma   70.369
_symmetry_Int_Tables_number   1
_cell_volume   572.646
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.306  0.180  0.214  1.0
  Ce  Ce1  1  0.671  0.834  0.778  1.0
  H  H2  1  0.198  0.460  0.508  1.0
  H  H3  1  0.137  0.554  0.364  1.0
  H  H4  1  0.838  0.467  0.645  1.0
  H  H5  1  0.973  0.541  0.617  1.0
  H  H6  1  0.641  0.260  0.484  1.0
  H  H7  1  0.466  0.383  0.540  1.0
  H  H8  1  0.370  0.741  0.497  1.0
  H  H9  1  0.557  0.636  0.438  1.0
  H  H10  1  0.512  0.390  0.128  1.0
  H  H11  1  0.345  0.408  1.000  1.0
  H  H12  1  0.635  0.600  0.985  1.0
  H  H13  1  0.478  0.616  0.844  1.0
  H  H14  1  0.021  0.296  0.924  1.0
  H  H15  1  0.951  0.406  0.098  1.0
  H  H16  1  0.980  0.766  0.024  1.0
  H  H17  1  0.997  0.598  0.925  1.0
  H  H18  1  0.369  0.166  0.611  1.0
  H  H19  1  0.184  0.150  0.565  1.0
  H  H20  1  0.673  0.861  0.393  1.0
  H  H21  1  0.861  0.847  0.468  1.0
  H  H22  1  0.284  0.842  0.238  1.0
  H  H23  1  0.464  0.818  0.168  1.0
  H  H24  1  0.552  0.199  0.886  1.0
  H  H25  1  0.690  0.161  0.748  1.0
  H  H26  1  0.914  0.192  0.219  1.0
  H  H27  1  0.019  0.036  0.275  1.0
  H  H28  1  0.077  0.798  0.767  1.0
  H  H29  1  0.008  0.978  0.820  1.0
  Cl  Cl30  1  0.657  0.993  0.146  1.0
  Cl  Cl31  1  0.307  0.010  0.853  1.0
  Cl  Cl32  1  0.878  0.239  0.674  1.0
  Cl  Cl33  1  0.112  0.795  0.377  1.0
  Cl  Cl34  1  0.263  0.531  0.770  1.0
  Cl  Cl35  1  0.696  0.498  0.206  1.0
  O  O36  1  0.158  0.450  0.386  1.0
  O  O37  1  0.850  0.566  0.632  1.0
  O  O38  1  0.518  0.298  0.445  1.0
  O  O39  1  0.494  0.711  0.536  1.0
  O  O40  1  0.425  0.337  0.067  1.0
  O  O41  1  0.580  0.650  0.888  1.0
  O  O42  1  0.059  0.343  0.041  1.0
  O  O43  1  0.913  0.694  0.982  1.0
  O  O44  1  0.277  0.169  0.520  1.0
  O  O45  1  0.744  0.864  0.500  1.0
  O  O46  1  0.361  0.896  0.218  1.0
  O  O47  1  0.601  0.125  0.781  1.0
  O  O48  1  0.028  0.115  0.220  1.0
  O  O49  1  0.975  0.884  0.808  1.0
[/CIF]
.