The crystal structure described by Li3VS3 is Ilmenite-like structured and crystallizes in the trigonal R3c space group. Li(1) is bonded in a distorted see-saw-like geometry to four equivalent S(1) atoms. V(1) is bonded to six equivalent S(1) atoms to form face-sharing VS6 octahedra. S(1) is bonded in a 6-coordinate geometry to four equivalent Li(1) and two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_Li3VS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.762
_cell_length_b   6.762
_cell_length_c   6.762
_cell_angle_alpha   111.520
_cell_angle_beta   111.520
_cell_angle_gamma   111.520
_symmetry_Int_Tables_number   1
_cell_volume   218.134
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.600  0.700  0.142  1.0
  Li  Li1  1  0.100  0.642  0.200  1.0
  Li  Li2  1  0.642  0.200  0.100  1.0
  Li  Li3  1  0.142  0.600  0.700  1.0
  Li  Li4  1  0.700  0.142  0.600  1.0
  Li  Li5  1  0.200  0.100  0.642  1.0
  V  V6  1  0.398  0.398  0.398  1.0
  V  V7  1  0.898  0.898  0.898  1.0
  S  S8  1  0.320  0.972  0.152  1.0
  S  S9  1  0.820  0.652  0.472  1.0
  S  S10  1  0.472  0.820  0.652  1.0
  S  S11  1  0.972  0.152  0.320  1.0
  S  S12  1  0.652  0.472  0.820  1.0
  S  S13  1  0.152  0.320  0.972  1.0
[/CIF]
.
The crystal structure described by Li3VS3 is Ilmenite-like structured and crystallizes in the trigonal R3c space group. Li(1) is bonded in a distorted see-saw-like geometry to four equivalent S(1) atoms. V(1) is bonded to six equivalent S(1) atoms to form face-sharing VS6 octahedra. S(1) is bonded in a 6-coordinate geometry to four equivalent Li(1) and two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_Li3VS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.762
_cell_length_b   6.762
_cell_length_c   6.762
_cell_angle_alpha   111.520
_cell_angle_beta   111.520
_cell_angle_gamma   111.520
_symmetry_Int_Tables_number   1
_cell_volume   218.134
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.600  0.700  0.142  1.0
  Li  Li1  1  0.100  0.642  0.200  1.0
  Li  Li2  1  0.642  0.200  0.100  1.0
  Li  Li3  1  0.142  0.600  0.700  1.0
  Li  Li4  1  0.700  0.142  0.600  1.0
  Li  Li5  1  0.200  0.100  0.642  1.0
  V  V6  1  0.398  0.398  0.398  1.0
  V  V7  1  0.898  0.898  0.898  1.0
  S  S8  1  0.320  0.972  0.152  1.0
  S  S9  1  0.820  0.652  0.472  1.0
  S  S10  1  0.472  0.820  0.652  1.0
  S  S11  1  0.972  0.152  0.320  1.0
  S  S12  1  0.652  0.472  0.820  1.0
  S  S13  1  0.152  0.320  0.972  1.0
[/CIF]
.