The structure described by Ba2Mo2CuF14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(4), one F(6), one F(7), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. Mo(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom. Cu(1) is bonded in a square co-planar geometry to two equivalent F(4) and two equivalent F(7) atoms. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a 2-coordinate geometry to one Ba(1), one Mo(1), and one Cu(1) atom. In the second F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Ba(1) and one Mo(1) atom. In the third F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one Mo(1) atom. In the fourth F site, F(3) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1) and one Mo(1) atom. In the fifth F site, F(4) is bonded in a bent 120 degrees geometry to one Ba(1) and one Cu(1) atom. In the sixth F site, F(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ba(1) and one Mo(1) atom. In the seventh F site, F(6) is bonded in a distorted single-bond geometry to one Ba(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_Ba2CuMo2F14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.825
_cell_length_b   7.825
_cell_length_c   15.688
_cell_angle_alpha   87.040
_cell_angle_beta   87.040
_cell_angle_gamma   40.377
_symmetry_Int_Tables_number   1
_cell_volume   621.276
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.748  0.897  0.628  1.0
  Ba  Ba1  1  0.897  0.748  0.128  1.0
  Ba  Ba2  1  0.252  0.103  0.372  1.0
  Ba  Ba3  1  0.103  0.252  0.872  1.0
  Cu  Cu4  1  0.500  0.500  0.000  1.0
  Cu  Cu5  1  0.500  0.500  0.500  1.0
  Mo  Mo6  1  0.852  0.903  0.872  1.0
  Mo  Mo7  1  0.148  0.097  0.128  1.0
  Mo  Mo8  1  0.903  0.852  0.372  1.0
  Mo  Mo9  1  0.097  0.148  0.628  1.0
  F  F10  1  0.928  0.077  0.345  1.0
  F  F11  1  0.587  0.111  0.451  1.0
  F  F12  1  0.413  0.889  0.549  1.0
  F  F13  1  0.134  0.368  0.590  1.0
  F  F14  1  0.512  0.364  0.602  1.0
  F  F15  1  0.636  0.488  0.898  1.0
  F  F16  1  0.111  0.587  0.951  1.0
  F  F17  1  0.923  0.072  0.155  1.0
  F  F18  1  0.999  0.643  0.779  1.0
  F  F19  1  0.866  0.632  0.410  1.0
  F  F20  1  0.574  0.171  0.791  1.0
  F  F21  1  0.632  0.866  0.910  1.0
  F  F22  1  0.171  0.574  0.291  1.0
  F  F23  1  0.426  0.829  0.209  1.0
  F  F24  1  0.364  0.512  0.102  1.0
  F  F25  1  0.001  0.357  0.221  1.0
  F  F26  1  0.285  0.880  0.018  1.0
  F  F27  1  0.072  0.923  0.655  1.0
  F  F28  1  0.715  0.120  0.982  1.0
  F  F29  1  0.880  0.285  0.518  1.0
  F  F30  1  0.889  0.413  0.049  1.0
  F  F31  1  0.829  0.426  0.709  1.0
  F  F32  1  0.643  0.999  0.279  1.0
  F  F33  1  0.120  0.715  0.482  1.0
  F  F34  1  0.488  0.636  0.398  1.0
  F  F35  1  0.077  0.928  0.845  1.0
  F  F36  1  0.357  0.001  0.721  1.0
  F  F37  1  0.368  0.134  0.090  1.0
[/CIF]
.
The structure described by Ba2Mo2CuF14 crystallizes in the monoclinic C2/c space group. Ba(1) is bonded in a 10-coordinate geometry to one F(1), one F(4), one F(6), one F(7), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. Mo(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom. Cu(1) is bonded in a square co-planar geometry to two equivalent F(4) and two equivalent F(7) atoms. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a 2-coordinate geometry to one Ba(1), one Mo(1), and one Cu(1) atom. In the second F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Ba(1) and one Mo(1) atom. In the third F site, F(2) is bonded in a distorted single-bond geometry to two equivalent Ba(1) and one Mo(1) atom. In the fourth F site, F(3) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1) and one Mo(1) atom. In the fifth F site, F(4) is bonded in a bent 120 degrees geometry to one Ba(1) and one Cu(1) atom. In the sixth F site, F(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ba(1) and one Mo(1) atom. In the seventh F site, F(6) is bonded in a distorted single-bond geometry to one Ba(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_Ba2CuMo2F14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.825
_cell_length_b   7.825
_cell_length_c   15.688
_cell_angle_alpha   87.040
_cell_angle_beta   87.040
_cell_angle_gamma   40.377
_symmetry_Int_Tables_number   1
_cell_volume   621.276
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.748  0.897  0.628  1.0
  Ba  Ba1  1  0.897  0.748  0.128  1.0
  Ba  Ba2  1  0.252  0.103  0.372  1.0
  Ba  Ba3  1  0.103  0.252  0.872  1.0
  Cu  Cu4  1  0.500  0.500  0.000  1.0
  Cu  Cu5  1  0.500  0.500  0.500  1.0
  Mo  Mo6  1  0.852  0.903  0.872  1.0
  Mo  Mo7  1  0.148  0.097  0.128  1.0
  Mo  Mo8  1  0.903  0.852  0.372  1.0
  Mo  Mo9  1  0.097  0.148  0.628  1.0
  F  F10  1  0.928  0.077  0.345  1.0
  F  F11  1  0.587  0.111  0.451  1.0
  F  F12  1  0.413  0.889  0.549  1.0
  F  F13  1  0.134  0.368  0.590  1.0
  F  F14  1  0.512  0.364  0.602  1.0
  F  F15  1  0.636  0.488  0.898  1.0
  F  F16  1  0.111  0.587  0.951  1.0
  F  F17  1  0.923  0.072  0.155  1.0
  F  F18  1  0.999  0.643  0.779  1.0
  F  F19  1  0.866  0.632  0.410  1.0
  F  F20  1  0.574  0.171  0.791  1.0
  F  F21  1  0.632  0.866  0.910  1.0
  F  F22  1  0.171  0.574  0.291  1.0
  F  F23  1  0.426  0.829  0.209  1.0
  F  F24  1  0.364  0.512  0.102  1.0
  F  F25  1  0.001  0.357  0.221  1.0
  F  F26  1  0.285  0.880  0.018  1.0
  F  F27  1  0.072  0.923  0.655  1.0
  F  F28  1  0.715  0.120  0.982  1.0
  F  F29  1  0.880  0.285  0.518  1.0
  F  F30  1  0.889  0.413  0.049  1.0
  F  F31  1  0.829  0.426  0.709  1.0
  F  F32  1  0.643  0.999  0.279  1.0
  F  F33  1  0.120  0.715  0.482  1.0
  F  F34  1  0.488  0.636  0.398  1.0
  F  F35  1  0.077  0.928  0.845  1.0
  F  F36  1  0.357  0.001  0.721  1.0
  F  F37  1  0.368  0.134  0.090  1.0
[/CIF]
.