The material described by LaVO4 crystallizes in the monoclinic P2_1/c space group. La(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and three equivalent O(4) atoms. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent La(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent La(1) and one V(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent La(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to three equivalent La(1) and one V(1) atom. is represented by the CIF card [CIF]
data_LaVO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.719
_cell_length_b   7.047
_cell_length_c   7.269
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   105.128
_symmetry_Int_Tables_number   1
_cell_volume   332.291
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.603  0.778  0.343  1.0
  La  La1  1  0.897  0.722  0.843  1.0
  La  La2  1  0.397  0.222  0.657  1.0
  La  La3  1  0.103  0.278  0.157  1.0
  V  V4  1  0.115  0.801  0.335  1.0
  V  V5  1  0.385  0.699  0.835  1.0
  V  V6  1  0.885  0.199  0.665  1.0
  V  V7  1  0.615  0.301  0.165  1.0
  O  O8  1  0.228  0.617  0.280  1.0
  O  O9  1  0.272  0.883  0.780  1.0
  O  O10  1  0.772  0.383  0.720  1.0
  O  O11  1  0.728  0.117  0.220  1.0
  O  O12  1  0.326  0.983  0.394  1.0
  O  O13  1  0.174  0.517  0.894  1.0
  O  O14  1  0.674  0.017  0.606  1.0
  O  O15  1  0.826  0.483  0.106  1.0
  O  O16  1  0.427  0.246  0.998  1.0
  O  O17  1  0.073  0.254  0.498  1.0
  O  O18  1  0.573  0.754  0.002  1.0
  O  O19  1  0.927  0.746  0.502  1.0
  O  O20  1  0.497  0.387  0.345  1.0
  O  O21  1  0.003  0.113  0.845  1.0
  O  O22  1  0.503  0.613  0.655  1.0
  O  O23  1  0.997  0.887  0.155  1.0
[/CIF]
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The material described by LaVO4 crystallizes in the monoclinic P2_1/c space group. La(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and three equivalent O(4) atoms. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent La(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent La(1) and one V(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent La(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to three equivalent La(1) and one V(1) atom. is represented by the CIF card [CIF]
data_LaVO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.719
_cell_length_b   7.047
_cell_length_c   7.269
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   105.128
_symmetry_Int_Tables_number   1
_cell_volume   332.291
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.603  0.778  0.343  1.0
  La  La1  1  0.897  0.722  0.843  1.0
  La  La2  1  0.397  0.222  0.657  1.0
  La  La3  1  0.103  0.278  0.157  1.0
  V  V4  1  0.115  0.801  0.335  1.0
  V  V5  1  0.385  0.699  0.835  1.0
  V  V6  1  0.885  0.199  0.665  1.0
  V  V7  1  0.615  0.301  0.165  1.0
  O  O8  1  0.228  0.617  0.280  1.0
  O  O9  1  0.272  0.883  0.780  1.0
  O  O10  1  0.772  0.383  0.720  1.0
  O  O11  1  0.728  0.117  0.220  1.0
  O  O12  1  0.326  0.983  0.394  1.0
  O  O13  1  0.174  0.517  0.894  1.0
  O  O14  1  0.674  0.017  0.606  1.0
  O  O15  1  0.826  0.483  0.106  1.0
  O  O16  1  0.427  0.246  0.998  1.0
  O  O17  1  0.073  0.254  0.498  1.0
  O  O18  1  0.573  0.754  0.002  1.0
  O  O19  1  0.927  0.746  0.502  1.0
  O  O20  1  0.497  0.387  0.345  1.0
  O  O21  1  0.003  0.113  0.845  1.0
  O  O22  1  0.503  0.613  0.655  1.0
  O  O23  1  0.997  0.887  0.155  1.0
[/CIF]
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