The compound described by Y6Ge2O13F3 crystallizes in the triclinic P1 space group. There are six inequivalent Y sites. In the first Y site, Y(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(13), one O(2), one O(3), one O(6), one O(7), and one F(3) atom. In the second Y site, Y(2) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(4), one O(5), one O(8), one O(9), one F(1), and one F(2) atom. In the third Y site, Y(3) is bonded to one O(1), one O(11), one O(13), one O(3), one O(5), one O(7), and one F(2) atom to form distorted YO6F pentagonal bipyramids that share corners with two equivalent Ge(2)O5 trigonal bipyramids and  an edgeedge with one Ge(1)O5 trigonal bipyramid. In the fourth Y site, Y(4) is bonded in a 7-coordinate geometry to one O(12), one O(2), one O(4), one O(6), one O(8), one F(1), and one F(3) atom. In the fifth Y site, Y(5) is bonded in a 7-coordinate geometry to one O(1), one O(12), one O(13), one O(3), one O(5), one O(7), and one F(2) atom. In the sixth Y site, Y(6) is bonded in a 7-coordinate geometry to one O(11), one O(2), one O(4), one O(6), one O(8), one F(1), and one F(3) atom. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one O(1), one O(4), one O(5), one O(8), and one O(9) atom to form distorted GeO5 trigonal bipyramids that share  an edgeedge with one Y(3)O6F pentagonal bipyramid. In the second Ge site, Ge(2) is bonded to one O(10), one O(2), one O(3), one O(6), and one O(7) atom to form distorted GeO5 trigonal bipyramids that share corners with two equivalent Y(3)O6F pentagonal bipyramids. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded to one Y(2), one Y(3), one Y(5), and one Ge(1) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the second O site, O(2) is bonded to one Y(1), one Y(4), one Y(6), and one Ge(2) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the third O site, O(3) is bonded to one Y(1), one Y(3), one Y(5), and one Ge(2) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the fourth O site, O(4) is bonded to one Y(2), one Y(4), one Y(6), and one Ge(1) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the fifth O site, O(5) is bonded to one Y(2), one Y(3), one Y(5), and one Ge(1) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the sixth O site, O(6) is bonded to one Y(1), one Y(4), one Y(6), and one Ge(2) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the seventh O site, O(7) is bonded to one Y(1), one Y(3), one Y(5), and one Ge(2) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the eighth O site, O(8) is bonded to one Y(2), one Y(4), one Y(6), and one Ge(1) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Y(2) and one Ge(1) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Y(1) and one Ge(2) atom. In the eleventh O site, O(11) is bonded in a trigonal non-coplanar geometry to one Y(1), one Y(3), and one Y(6) atom. In the twelfth O site, O(12) is bonded in a trigonal non-coplanar geometry to one Y(2), one Y(4), and one Y(5) atom. In the thirteenth O site, O(13) is bonded in a trigonal non-coplanar geometry to one Y(1), one Y(3), and one Y(5) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a trigonal non-coplanar geometry to one Y(2), one Y(4), and one Y(6) atom. In the second F site, F(2) is bonded in a trigonal non-coplanar geometry to one Y(2), one Y(3), and one Y(5) atom. In the third F site, F(3) is bonded in a trigonal non-coplanar geometry to one Y(1), one Y(4), and one Y(6) atom. is represented by the CIF card [CIF]
data_Y6Ge2O13F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.451
_cell_length_b   6.017
_cell_length_c   10.356
_cell_angle_alpha   89.048
_cell_angle_beta   89.550
_cell_angle_gamma   74.300
_symmetry_Int_Tables_number   1
_cell_volume   326.915
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.713  0.807  0.752  1.0
  Y  Y1  1  0.283  0.189  0.252  1.0
  Y  Y2  1  0.812  0.304  0.960  1.0
  Y  Y3  1  0.184  0.701  0.452  1.0
  Y  Y4  1  0.180  0.709  0.044  1.0
  Y  Y5  1  0.807  0.299  0.550  1.0
  Ge  Ge6  1  0.693  0.517  0.252  1.0
  Ge  Ge7  1  0.304  0.481  0.748  1.0
  O  O8  1  0.510  0.395  0.129  1.0
  O  O9  1  0.485  0.611  0.625  1.0
  O  O10  1  0.488  0.602  0.874  1.0
  O  O11  1  0.508  0.392  0.378  1.0
  O  O12  1  0.958  0.464  0.132  1.0
  O  O13  1  0.038  0.536  0.629  1.0
  O  O14  1  0.047  0.530  0.870  1.0
  O  O15  1  0.955  0.459  0.373  1.0
  O  O16  1  0.529  0.818  0.251  1.0
  O  O17  1  0.479  0.184  0.734  1.0
  O  O18  1  0.903  0.115  0.761  1.0
  O  O19  1  0.103  0.874  0.249  1.0
  O  O20  1  0.795  0.938  0.957  1.0
  F  F21  1  0.212  0.066  0.478  1.0
  F  F22  1  0.223  0.073  0.026  1.0
  F  F23  1  0.791  0.934  0.525  1.0
[/CIF]
.
The compound described by Y6Ge2O13F3 crystallizes in the triclinic P1 space group. There are six inequivalent Y sites. In the first Y site, Y(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(13), one O(2), one O(3), one O(6), one O(7), and one F(3) atom. In the second Y site, Y(2) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(4), one O(5), one O(8), one O(9), one F(1), and one F(2) atom. In the third Y site, Y(3) is bonded to one O(1), one O(11), one O(13), one O(3), one O(5), one O(7), and one F(2) atom to form distorted YO6F pentagonal bipyramids that share corners with two equivalent Ge(2)O5 trigonal bipyramids and  an edgeedge with one Ge(1)O5 trigonal bipyramid. In the fourth Y site, Y(4) is bonded in a 7-coordinate geometry to one O(12), one O(2), one O(4), one O(6), one O(8), one F(1), and one F(3) atom. In the fifth Y site, Y(5) is bonded in a 7-coordinate geometry to one O(1), one O(12), one O(13), one O(3), one O(5), one O(7), and one F(2) atom. In the sixth Y site, Y(6) is bonded in a 7-coordinate geometry to one O(11), one O(2), one O(4), one O(6), one O(8), one F(1), and one F(3) atom. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one O(1), one O(4), one O(5), one O(8), and one O(9) atom to form distorted GeO5 trigonal bipyramids that share  an edgeedge with one Y(3)O6F pentagonal bipyramid. In the second Ge site, Ge(2) is bonded to one O(10), one O(2), one O(3), one O(6), and one O(7) atom to form distorted GeO5 trigonal bipyramids that share corners with two equivalent Y(3)O6F pentagonal bipyramids. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded to one Y(2), one Y(3), one Y(5), and one Ge(1) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the second O site, O(2) is bonded to one Y(1), one Y(4), one Y(6), and one Ge(2) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the third O site, O(3) is bonded to one Y(1), one Y(3), one Y(5), and one Ge(2) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the fourth O site, O(4) is bonded to one Y(2), one Y(4), one Y(6), and one Ge(1) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the fifth O site, O(5) is bonded to one Y(2), one Y(3), one Y(5), and one Ge(1) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the sixth O site, O(6) is bonded to one Y(1), one Y(4), one Y(6), and one Ge(2) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the seventh O site, O(7) is bonded to one Y(1), one Y(3), one Y(5), and one Ge(2) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the eighth O site, O(8) is bonded to one Y(2), one Y(4), one Y(6), and one Ge(1) atom to form a mixture of edge and corner-sharing OY3Ge tetrahedra. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Y(2) and one Ge(1) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Y(1) and one Ge(2) atom. In the eleventh O site, O(11) is bonded in a trigonal non-coplanar geometry to one Y(1), one Y(3), and one Y(6) atom. In the twelfth O site, O(12) is bonded in a trigonal non-coplanar geometry to one Y(2), one Y(4), and one Y(5) atom. In the thirteenth O site, O(13) is bonded in a trigonal non-coplanar geometry to one Y(1), one Y(3), and one Y(5) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a trigonal non-coplanar geometry to one Y(2), one Y(4), and one Y(6) atom. In the second F site, F(2) is bonded in a trigonal non-coplanar geometry to one Y(2), one Y(3), and one Y(5) atom. In the third F site, F(3) is bonded in a trigonal non-coplanar geometry to one Y(1), one Y(4), and one Y(6) atom. is represented by the CIF card [CIF]
data_Y6Ge2O13F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.451
_cell_length_b   6.017
_cell_length_c   10.356
_cell_angle_alpha   89.048
_cell_angle_beta   89.550
_cell_angle_gamma   74.300
_symmetry_Int_Tables_number   1
_cell_volume   326.915
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.713  0.807  0.752  1.0
  Y  Y1  1  0.283  0.189  0.252  1.0
  Y  Y2  1  0.812  0.304  0.960  1.0
  Y  Y3  1  0.184  0.701  0.452  1.0
  Y  Y4  1  0.180  0.709  0.044  1.0
  Y  Y5  1  0.807  0.299  0.550  1.0
  Ge  Ge6  1  0.693  0.517  0.252  1.0
  Ge  Ge7  1  0.304  0.481  0.748  1.0
  O  O8  1  0.510  0.395  0.129  1.0
  O  O9  1  0.485  0.611  0.625  1.0
  O  O10  1  0.488  0.602  0.874  1.0
  O  O11  1  0.508  0.392  0.378  1.0
  O  O12  1  0.958  0.464  0.132  1.0
  O  O13  1  0.038  0.536  0.629  1.0
  O  O14  1  0.047  0.530  0.870  1.0
  O  O15  1  0.955  0.459  0.373  1.0
  O  O16  1  0.529  0.818  0.251  1.0
  O  O17  1  0.479  0.184  0.734  1.0
  O  O18  1  0.903  0.115  0.761  1.0
  O  O19  1  0.103  0.874  0.249  1.0
  O  O20  1  0.795  0.938  0.957  1.0
  F  F21  1  0.212  0.066  0.478  1.0
  F  F22  1  0.223  0.073  0.026  1.0
  F  F23  1  0.791  0.934  0.525  1.0
[/CIF]
.