The structure described by LaBiO4 crystallizes in the monoclinic P2_1/c space group. La(1) is bonded in a 8-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(3), and three equivalent O(4) atoms. Bi(1) is bonded to one O(1), one O(3), one O(4), and two equivalent O(2) atoms to form distorted corner-sharing BiO5 trigonal bipyramids. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent La(1) and one Bi(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one La(1) and two equivalent Bi(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent La(1) and one Bi(1) atom. In the fourth O site, O(4) is bonded to three equivalent La(1) and one Bi(1) atom to form a mixture of distorted corner and edge-sharing OLa3Bi tetrahedra. is represented by the CIF file [CIF]
data_LaBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.360
_cell_length_b   7.585
_cell_length_c   7.865
_cell_angle_alpha   60.344
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   381.591
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.843  0.139  0.725  1.0
  La  La1  1  0.343  0.861  0.775  1.0
  La  La2  1  0.657  0.139  0.225  1.0
  La  La3  1  0.157  0.861  0.275  1.0
  Bi  Bi4  1  0.807  0.672  0.731  1.0
  Bi  Bi5  1  0.307  0.328  0.769  1.0
  Bi  Bi6  1  0.693  0.672  0.231  1.0
  Bi  Bi7  1  0.193  0.328  0.269  1.0
  O  O8  1  0.251  0.631  0.642  1.0
  O  O9  1  0.130  0.310  0.542  1.0
  O  O10  1  0.511  0.174  0.723  1.0
  O  O11  1  0.663  0.940  0.582  1.0
  O  O12  1  0.751  0.369  0.858  1.0
  O  O13  1  0.163  0.060  0.918  1.0
  O  O14  1  0.011  0.826  0.777  1.0
  O  O15  1  0.370  0.310  0.042  1.0
  O  O16  1  0.630  0.690  0.958  1.0
  O  O17  1  0.989  0.174  0.223  1.0
  O  O18  1  0.837  0.940  0.082  1.0
  O  O19  1  0.249  0.631  0.142  1.0
  O  O20  1  0.337  0.060  0.418  1.0
  O  O21  1  0.489  0.826  0.277  1.0
  O  O22  1  0.870  0.690  0.458  1.0
  O  O23  1  0.749  0.369  0.358  1.0
[/CIF]
.
The structure described by LaBiO4 crystallizes in the monoclinic P2_1/c space group. La(1) is bonded in a 8-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(3), and three equivalent O(4) atoms. Bi(1) is bonded to one O(1), one O(3), one O(4), and two equivalent O(2) atoms to form distorted corner-sharing BiO5 trigonal bipyramids. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent La(1) and one Bi(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one La(1) and two equivalent Bi(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent La(1) and one Bi(1) atom. In the fourth O site, O(4) is bonded to three equivalent La(1) and one Bi(1) atom to form a mixture of distorted corner and edge-sharing OLa3Bi tetrahedra. is represented by the CIF file [CIF]
data_LaBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.360
_cell_length_b   7.585
_cell_length_c   7.865
_cell_angle_alpha   60.344
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   381.591
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.843  0.139  0.725  1.0
  La  La1  1  0.343  0.861  0.775  1.0
  La  La2  1  0.657  0.139  0.225  1.0
  La  La3  1  0.157  0.861  0.275  1.0
  Bi  Bi4  1  0.807  0.672  0.731  1.0
  Bi  Bi5  1  0.307  0.328  0.769  1.0
  Bi  Bi6  1  0.693  0.672  0.231  1.0
  Bi  Bi7  1  0.193  0.328  0.269  1.0
  O  O8  1  0.251  0.631  0.642  1.0
  O  O9  1  0.130  0.310  0.542  1.0
  O  O10  1  0.511  0.174  0.723  1.0
  O  O11  1  0.663  0.940  0.582  1.0
  O  O12  1  0.751  0.369  0.858  1.0
  O  O13  1  0.163  0.060  0.918  1.0
  O  O14  1  0.011  0.826  0.777  1.0
  O  O15  1  0.370  0.310  0.042  1.0
  O  O16  1  0.630  0.690  0.958  1.0
  O  O17  1  0.989  0.174  0.223  1.0
  O  O18  1  0.837  0.940  0.082  1.0
  O  O19  1  0.249  0.631  0.142  1.0
  O  O20  1  0.337  0.060  0.418  1.0
  O  O21  1  0.489  0.826  0.277  1.0
  O  O22  1  0.870  0.690  0.458  1.0
  O  O23  1  0.749  0.369  0.358  1.0
[/CIF]
.