The crystal structure described by CoRh2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Rh(1) is bonded to six equivalent S(1) atoms to form RhS6 octahedra that share corners with six equivalent Co(1)S4 tetrahedra and edges with six equivalent Rh(1)S6 octahedra. Co(1) is bonded to four equivalent S(1) atoms to form CoS4 tetrahedra that share corners with twelve equivalent Rh(1)S6 octahedra. The corner-sharing octahedral tilt angles are 56°. S(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Rh(1) and one Co(1) atom. is represented by the CIF file [CIF]
data_Co(RhS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.848
_cell_length_b   6.848
_cell_length_c   6.848
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   227.094
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.375  0.375  0.375  1.0
  Co  Co1  1  0.625  0.625  0.625  1.0
  Rh  Rh2  1  0.000  0.000  0.500  1.0
  Rh  Rh3  1  0.000  0.500  0.000  1.0
  Rh  Rh4  1  0.500  0.000  0.000  1.0
  Rh  Rh5  1  0.000  0.000  0.000  1.0
  S  S6  1  0.247  0.247  0.758  1.0
  S  S7  1  0.247  0.758  0.247  1.0
  S  S8  1  0.758  0.247  0.247  1.0
  S  S9  1  0.247  0.247  0.247  1.0
  S  S10  1  0.753  0.753  0.242  1.0
  S  S11  1  0.753  0.242  0.753  1.0
  S  S12  1  0.242  0.753  0.753  1.0
  S  S13  1  0.753  0.753  0.753  1.0
[/CIF]
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The crystal structure described by CoRh2S4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Rh(1) is bonded to six equivalent S(1) atoms to form RhS6 octahedra that share corners with six equivalent Co(1)S4 tetrahedra and edges with six equivalent Rh(1)S6 octahedra. Co(1) is bonded to four equivalent S(1) atoms to form CoS4 tetrahedra that share corners with twelve equivalent Rh(1)S6 octahedra. The corner-sharing octahedral tilt angles are 56°. S(1) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Rh(1) and one Co(1) atom. is represented by the CIF file [CIF]
data_Co(RhS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.848
_cell_length_b   6.848
_cell_length_c   6.848
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   227.094
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.375  0.375  0.375  1.0
  Co  Co1  1  0.625  0.625  0.625  1.0
  Rh  Rh2  1  0.000  0.000  0.500  1.0
  Rh  Rh3  1  0.000  0.500  0.000  1.0
  Rh  Rh4  1  0.500  0.000  0.000  1.0
  Rh  Rh5  1  0.000  0.000  0.000  1.0
  S  S6  1  0.247  0.247  0.758  1.0
  S  S7  1  0.247  0.758  0.247  1.0
  S  S8  1  0.758  0.247  0.247  1.0
  S  S9  1  0.247  0.247  0.247  1.0
  S  S10  1  0.753  0.753  0.242  1.0
  S  S11  1  0.753  0.242  0.753  1.0
  S  S12  1  0.242  0.753  0.753  1.0
  S  S13  1  0.753  0.753  0.753  1.0
[/CIF]
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