The crystal structure described by P4S5 is alpha U structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two P4S5 clusters. There are four inequivalent P sites. In the first P site, P(1) is bonded in a distorted water-like geometry to one P(2), one S(1), and one S(4) atom. In the second P site, P(2) is bonded in a distorted single-bond geometry to one P(1), one P(3), and one S(2) atom. In the third P site, P(3) is bonded in a distorted trigonal non-coplanar geometry to one P(2), one S(3), one S(4), and one S(5) atom. In the fourth P site, P(4) is bonded in a trigonal non-coplanar geometry to one S(1), one S(2), and one S(3) atom. There are five inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one P(1) and one P(4) atom. In the second S site, S(2) is bonded in a water-like geometry to one P(2) and one P(4) atom. In the third S site, S(3) is bonded in a water-like geometry to one P(3) and one P(4) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one P(1) and one P(3) atom. In the fifth S site, S(5) is bonded in a single-bond geometry to one P(3) atom. is represented by the CIF file [CIF]
data_P4S5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.554
_cell_length_b   6.901
_cell_length_c   11.162
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   111.722
_symmetry_Int_Tables_number   1
_cell_volume   469.002
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.318  0.604  0.992  1.0
  P  P1  1  0.682  0.396  0.492  1.0
  P  P2  1  0.539  0.514  0.865  1.0
  P  P3  1  0.461  0.486  0.365  1.0
  P  P4  1  0.250  0.435  0.742  1.0
  P  P5  1  0.750  0.565  0.242  1.0
  P  P6  1  0.521  0.946  0.762  1.0
  P  P7  1  0.479  0.054  0.262  1.0
  S  S8  1  0.371  0.911  0.933  1.0
  S  S9  1  0.629  0.089  0.433  1.0
  S  S10  1  0.747  0.793  0.795  1.0
  S  S11  1  0.253  0.207  0.295  1.0
  S  S12  1  0.287  0.717  0.655  1.0
  S  S13  1  0.713  0.283  0.155  1.0
  S  S14  1  0.045  0.391  0.891  1.0
  S  S15  1  0.955  0.609  0.391  1.0
  S  S16  1  0.158  0.212  0.626  1.0
  S  S17  1  0.842  0.788  0.126  1.0
[/CIF]
.
The crystal structure described by P4S5 is alpha U structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two P4S5 clusters. There are four inequivalent P sites. In the first P site, P(1) is bonded in a distorted water-like geometry to one P(2), one S(1), and one S(4) atom. In the second P site, P(2) is bonded in a distorted single-bond geometry to one P(1), one P(3), and one S(2) atom. In the third P site, P(3) is bonded in a distorted trigonal non-coplanar geometry to one P(2), one S(3), one S(4), and one S(5) atom. In the fourth P site, P(4) is bonded in a trigonal non-coplanar geometry to one S(1), one S(2), and one S(3) atom. There are five inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one P(1) and one P(4) atom. In the second S site, S(2) is bonded in a water-like geometry to one P(2) and one P(4) atom. In the third S site, S(3) is bonded in a water-like geometry to one P(3) and one P(4) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one P(1) and one P(3) atom. In the fifth S site, S(5) is bonded in a single-bond geometry to one P(3) atom. is represented by the CIF file [CIF]
data_P4S5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.554
_cell_length_b   6.901
_cell_length_c   11.162
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   111.722
_symmetry_Int_Tables_number   1
_cell_volume   469.002
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.318  0.604  0.992  1.0
  P  P1  1  0.682  0.396  0.492  1.0
  P  P2  1  0.539  0.514  0.865  1.0
  P  P3  1  0.461  0.486  0.365  1.0
  P  P4  1  0.250  0.435  0.742  1.0
  P  P5  1  0.750  0.565  0.242  1.0
  P  P6  1  0.521  0.946  0.762  1.0
  P  P7  1  0.479  0.054  0.262  1.0
  S  S8  1  0.371  0.911  0.933  1.0
  S  S9  1  0.629  0.089  0.433  1.0
  S  S10  1  0.747  0.793  0.795  1.0
  S  S11  1  0.253  0.207  0.295  1.0
  S  S12  1  0.287  0.717  0.655  1.0
  S  S13  1  0.713  0.283  0.155  1.0
  S  S14  1  0.045  0.391  0.891  1.0
  S  S15  1  0.955  0.609  0.391  1.0
  S  S16  1  0.158  0.212  0.626  1.0
  S  S17  1  0.842  0.788  0.126  1.0
[/CIF]
.