The material structure described by Rh4P3 crystallizes in the orthorhombic Pnma space group. There are four inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 5-coordinate geometry to one P(3), two equivalent P(1), and two equivalent P(2) atoms. In the second Rh site, Rh(2) is bonded in a 5-coordinate geometry to two equivalent P(3) and three equivalent P(1) atoms. In the third Rh site, Rh(3) is bonded in a 5-coordinate geometry to two equivalent P(3) and three equivalent P(2) atoms. In the fourth Rh site, Rh(4) is bonded in a 5-coordinate geometry to one P(1), two equivalent P(2), and two equivalent P(3) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to one Rh(4), two equivalent Rh(1), and three equivalent Rh(2) atoms. In the second P site, P(2) is bonded in a 7-coordinate geometry to two equivalent Rh(1), two equivalent Rh(4), and three equivalent Rh(3) atoms. In the third P site, P(3) is bonded in a 7-coordinate geometry to one Rh(1), two equivalent Rh(2), two equivalent Rh(3), and two equivalent Rh(4) atoms. is represented by the CIF card [CIF]
data_P3Rh4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.336
_cell_length_b   10.024
_cell_length_c   11.712
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   391.639
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.750  0.920  0.630  1.0
  P  P1  1  0.750  0.080  0.873  1.0
  P  P2  1  0.750  0.241  0.623  1.0
  P  P3  1  0.250  0.080  0.370  1.0
  P  P4  1  0.250  0.741  0.877  1.0
  P  P5  1  0.250  0.580  0.627  1.0
  P  P6  1  0.250  0.920  0.127  1.0
  P  P7  1  0.750  0.580  0.130  1.0
  P  P8  1  0.250  0.420  0.870  1.0
  P  P9  1  0.750  0.259  0.123  1.0
  P  P10  1  0.750  0.420  0.373  1.0
  P  P11  1  0.250  0.759  0.377  1.0
  Rh  Rh12  1  0.250  0.929  0.769  1.0
  Rh  Rh13  1  0.250  0.403  0.064  1.0
  Rh  Rh14  1  0.750  0.883  0.971  1.0
  Rh  Rh15  1  0.750  0.597  0.936  1.0
  Rh  Rh16  1  0.250  0.293  0.298  1.0
  Rh  Rh17  1  0.250  0.383  0.529  1.0
  Rh  Rh18  1  0.750  0.071  0.231  1.0
  Rh  Rh19  1  0.250  0.097  0.564  1.0
  Rh  Rh20  1  0.250  0.571  0.269  1.0
  Rh  Rh21  1  0.750  0.617  0.471  1.0
  Rh  Rh22  1  0.750  0.903  0.436  1.0
  Rh  Rh23  1  0.750  0.429  0.731  1.0
  Rh  Rh24  1  0.250  0.117  0.029  1.0
  Rh  Rh25  1  0.750  0.793  0.202  1.0
  Rh  Rh26  1  0.750  0.707  0.702  1.0
  Rh  Rh27  1  0.250  0.207  0.798  1.0
[/CIF]
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The material structure described by Rh4P3 crystallizes in the orthorhombic Pnma space group. There are four inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 5-coordinate geometry to one P(3), two equivalent P(1), and two equivalent P(2) atoms. In the second Rh site, Rh(2) is bonded in a 5-coordinate geometry to two equivalent P(3) and three equivalent P(1) atoms. In the third Rh site, Rh(3) is bonded in a 5-coordinate geometry to two equivalent P(3) and three equivalent P(2) atoms. In the fourth Rh site, Rh(4) is bonded in a 5-coordinate geometry to one P(1), two equivalent P(2), and two equivalent P(3) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded in a 6-coordinate geometry to one Rh(4), two equivalent Rh(1), and three equivalent Rh(2) atoms. In the second P site, P(2) is bonded in a 7-coordinate geometry to two equivalent Rh(1), two equivalent Rh(4), and three equivalent Rh(3) atoms. In the third P site, P(3) is bonded in a 7-coordinate geometry to one Rh(1), two equivalent Rh(2), two equivalent Rh(3), and two equivalent Rh(4) atoms. is represented by the CIF card [CIF]
data_P3Rh4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.336
_cell_length_b   10.024
_cell_length_c   11.712
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   391.639
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.750  0.920  0.630  1.0
  P  P1  1  0.750  0.080  0.873  1.0
  P  P2  1  0.750  0.241  0.623  1.0
  P  P3  1  0.250  0.080  0.370  1.0
  P  P4  1  0.250  0.741  0.877  1.0
  P  P5  1  0.250  0.580  0.627  1.0
  P  P6  1  0.250  0.920  0.127  1.0
  P  P7  1  0.750  0.580  0.130  1.0
  P  P8  1  0.250  0.420  0.870  1.0
  P  P9  1  0.750  0.259  0.123  1.0
  P  P10  1  0.750  0.420  0.373  1.0
  P  P11  1  0.250  0.759  0.377  1.0
  Rh  Rh12  1  0.250  0.929  0.769  1.0
  Rh  Rh13  1  0.250  0.403  0.064  1.0
  Rh  Rh14  1  0.750  0.883  0.971  1.0
  Rh  Rh15  1  0.750  0.597  0.936  1.0
  Rh  Rh16  1  0.250  0.293  0.298  1.0
  Rh  Rh17  1  0.250  0.383  0.529  1.0
  Rh  Rh18  1  0.750  0.071  0.231  1.0
  Rh  Rh19  1  0.250  0.097  0.564  1.0
  Rh  Rh20  1  0.250  0.571  0.269  1.0
  Rh  Rh21  1  0.750  0.617  0.471  1.0
  Rh  Rh22  1  0.750  0.903  0.436  1.0
  Rh  Rh23  1  0.750  0.429  0.731  1.0
  Rh  Rh24  1  0.250  0.117  0.029  1.0
  Rh  Rh25  1  0.750  0.793  0.202  1.0
  Rh  Rh26  1  0.750  0.707  0.702  1.0
  Rh  Rh27  1  0.250  0.207  0.798  1.0
[/CIF]
.