The structure described by CrTe(WO6)2 crystallizes in the triclinic P1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form distorted WO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-39°. In the second W site, W(2) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form distorted WO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-37°. Cr(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form distorted CrO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-37°. Te(1) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent W(2)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-39°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one W(1) and one Cr(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(2) and one Cr(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one W(2) and one Cr(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one W(2) and one Te(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one W(2) and one Te(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one W(2) and one Cr(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one W(2) and one Cr(1) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one W(1) and one Cr(1) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. is represented by the CIF file [CIF]
data_CrTe(WO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.132
_cell_length_b   5.333
_cell_length_c   7.415
_cell_angle_alpha   92.688
_cell_angle_beta   90.038
_cell_angle_gamma   90.148
_symmetry_Int_Tables_number   1
_cell_volume   202.716
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.002  0.056  0.968  1.0
  Te  Te1  1  0.500  0.497  0.504  1.0
  W  W2  1  0.988  0.998  0.469  1.0
  W  W3  1  0.510  0.554  0.003  1.0
  O  O4  1  0.301  0.197  0.448  1.0
  O  O5  1  0.102  0.010  0.758  1.0
  O  O6  1  0.295  0.811  0.049  1.0
  O  O7  1  0.199  0.699  0.452  1.0
  O  O8  1  0.808  0.714  0.952  1.0
  O  O9  1  0.393  0.491  0.754  1.0
  O  O10  1  0.599  0.491  0.251  1.0
  O  O11  1  0.192  0.292  0.044  1.0
  O  O12  1  0.804  0.298  0.556  1.0
  O  O13  1  0.717  0.200  0.944  1.0
  O  O14  1  0.894  0.999  0.239  1.0
  O  O15  1  0.697  0.800  0.555  1.0
[/CIF]
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The structure described by CrTe(WO6)2 crystallizes in the triclinic P1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form distorted WO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-39°. In the second W site, W(2) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form distorted WO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-37°. Cr(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form distorted CrO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 29-37°. Te(1) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent W(2)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-39°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one W(1) and one Cr(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(2) and one Cr(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one W(2) and one Cr(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one W(2) and one Te(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one W(2) and one Te(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one W(2) and one Cr(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one W(2) and one Cr(1) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one W(1) and one Cr(1) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. is represented by the CIF file [CIF]
data_CrTe(WO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.132
_cell_length_b   5.333
_cell_length_c   7.415
_cell_angle_alpha   92.688
_cell_angle_beta   90.038
_cell_angle_gamma   90.148
_symmetry_Int_Tables_number   1
_cell_volume   202.716
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.002  0.056  0.968  1.0
  Te  Te1  1  0.500  0.497  0.504  1.0
  W  W2  1  0.988  0.998  0.469  1.0
  W  W3  1  0.510  0.554  0.003  1.0
  O  O4  1  0.301  0.197  0.448  1.0
  O  O5  1  0.102  0.010  0.758  1.0
  O  O6  1  0.295  0.811  0.049  1.0
  O  O7  1  0.199  0.699  0.452  1.0
  O  O8  1  0.808  0.714  0.952  1.0
  O  O9  1  0.393  0.491  0.754  1.0
  O  O10  1  0.599  0.491  0.251  1.0
  O  O11  1  0.192  0.292  0.044  1.0
  O  O12  1  0.804  0.298  0.556  1.0
  O  O13  1  0.717  0.200  0.944  1.0
  O  O14  1  0.894  0.999  0.239  1.0
  O  O15  1  0.697  0.800  0.555  1.0
[/CIF]
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