The structure described by Te3(Rh2N)2 crystallizes in the orthorhombic Pnma space group. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted L-shaped geometry to two equivalent N(1), one Te(1), and four equivalent Te(2) atoms. In the second Rh site, Rh(2) is bonded in a distorted L-shaped geometry to two equivalent N(1) and two equivalent Te(1) atoms. In the third Rh site, Rh(3) is bonded in a 2-coordinate geometry to two equivalent N(1), one Te(1), and three equivalent Te(2) atoms. N(1) is bonded to one Rh(1), one Rh(2), and two equivalent Rh(3) atoms to form distorted NRh4 trigonal pyramids that share corners with six equivalent Te(2)Rh5 trigonal bipyramids, edges with two equivalent Te(2)Rh5 trigonal bipyramids, and edges with two equivalent N(1)Rh4 trigonal pyramids. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one Rh(1), two equivalent Rh(2), and two equivalent Rh(3) atoms. In the second Te site, Te(2) is bonded to two equivalent Rh(1) and three equivalent Rh(3) atoms to form distorted TeRh5 trigonal bipyramids that share corners with four equivalent Te(2)Rh5 trigonal bipyramids, corners with six equivalent N(1)Rh4 trigonal pyramids, edges with four equivalent Te(2)Rh5 trigonal bipyramids, and edges with two equivalent N(1)Rh4 trigonal pyramids. is represented by the CIF card [CIF]
data_Te3(Rh2N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.655
_cell_length_b   10.333
_cell_length_c   9.468
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   651.029
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.883  0.250  0.162  1.0
  Te  Te1  1  0.383  0.250  0.338  1.0
  Te  Te2  1  0.117  0.750  0.838  1.0
  Te  Te3  1  0.617  0.750  0.662  1.0
  Te  Te4  1  0.558  0.580  0.317  1.0
  Te  Te5  1  0.058  0.920  0.183  1.0
  Te  Te6  1  0.442  0.080  0.683  1.0
  Te  Te7  1  0.942  0.420  0.817  1.0
  Te  Te8  1  0.442  0.420  0.683  1.0
  Te  Te9  1  0.942  0.080  0.817  1.0
  Te  Te10  1  0.558  0.920  0.317  1.0
  Te  Te11  1  0.058  0.580  0.183  1.0
  Rh  Rh12  1  0.629  0.250  0.895  1.0
  Rh  Rh13  1  0.129  0.250  0.605  1.0
  Rh  Rh14  1  0.371  0.750  0.105  1.0
  Rh  Rh15  1  0.871  0.750  0.395  1.0
  Rh  Rh16  1  0.775  0.250  0.423  1.0
  Rh  Rh17  1  0.275  0.250  0.077  1.0
  Rh  Rh18  1  0.225  0.750  0.577  1.0
  Rh  Rh19  1  0.725  0.750  0.923  1.0
  Rh  Rh20  1  0.706  0.469  0.075  1.0
  Rh  Rh21  1  0.206  0.031  0.425  1.0
  Rh  Rh22  1  0.294  0.969  0.925  1.0
  Rh  Rh23  1  0.794  0.531  0.575  1.0
  Rh  Rh24  1  0.294  0.531  0.925  1.0
  Rh  Rh25  1  0.794  0.969  0.575  1.0
  Rh  Rh26  1  0.706  0.031  0.075  1.0
  Rh  Rh27  1  0.206  0.469  0.425  1.0
  N  N28  1  0.544  0.619  0.995  1.0
  N  N29  1  0.044  0.881  0.505  1.0
  N  N30  1  0.456  0.119  0.005  1.0
  N  N31  1  0.956  0.381  0.495  1.0
  N  N32  1  0.456  0.381  0.005  1.0
  N  N33  1  0.956  0.119  0.495  1.0
  N  N34  1  0.544  0.881  0.995  1.0
  N  N35  1  0.044  0.619  0.505  1.0
[/CIF]
.
The structure described by Te3(Rh2N)2 crystallizes in the orthorhombic Pnma space group. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted L-shaped geometry to two equivalent N(1), one Te(1), and four equivalent Te(2) atoms. In the second Rh site, Rh(2) is bonded in a distorted L-shaped geometry to two equivalent N(1) and two equivalent Te(1) atoms. In the third Rh site, Rh(3) is bonded in a 2-coordinate geometry to two equivalent N(1), one Te(1), and three equivalent Te(2) atoms. N(1) is bonded to one Rh(1), one Rh(2), and two equivalent Rh(3) atoms to form distorted NRh4 trigonal pyramids that share corners with six equivalent Te(2)Rh5 trigonal bipyramids, edges with two equivalent Te(2)Rh5 trigonal bipyramids, and edges with two equivalent N(1)Rh4 trigonal pyramids. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one Rh(1), two equivalent Rh(2), and two equivalent Rh(3) atoms. In the second Te site, Te(2) is bonded to two equivalent Rh(1) and three equivalent Rh(3) atoms to form distorted TeRh5 trigonal bipyramids that share corners with four equivalent Te(2)Rh5 trigonal bipyramids, corners with six equivalent N(1)Rh4 trigonal pyramids, edges with four equivalent Te(2)Rh5 trigonal bipyramids, and edges with two equivalent N(1)Rh4 trigonal pyramids. is represented by the CIF card [CIF]
data_Te3(Rh2N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.655
_cell_length_b   10.333
_cell_length_c   9.468
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   651.029
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.883  0.250  0.162  1.0
  Te  Te1  1  0.383  0.250  0.338  1.0
  Te  Te2  1  0.117  0.750  0.838  1.0
  Te  Te3  1  0.617  0.750  0.662  1.0
  Te  Te4  1  0.558  0.580  0.317  1.0
  Te  Te5  1  0.058  0.920  0.183  1.0
  Te  Te6  1  0.442  0.080  0.683  1.0
  Te  Te7  1  0.942  0.420  0.817  1.0
  Te  Te8  1  0.442  0.420  0.683  1.0
  Te  Te9  1  0.942  0.080  0.817  1.0
  Te  Te10  1  0.558  0.920  0.317  1.0
  Te  Te11  1  0.058  0.580  0.183  1.0
  Rh  Rh12  1  0.629  0.250  0.895  1.0
  Rh  Rh13  1  0.129  0.250  0.605  1.0
  Rh  Rh14  1  0.371  0.750  0.105  1.0
  Rh  Rh15  1  0.871  0.750  0.395  1.0
  Rh  Rh16  1  0.775  0.250  0.423  1.0
  Rh  Rh17  1  0.275  0.250  0.077  1.0
  Rh  Rh18  1  0.225  0.750  0.577  1.0
  Rh  Rh19  1  0.725  0.750  0.923  1.0
  Rh  Rh20  1  0.706  0.469  0.075  1.0
  Rh  Rh21  1  0.206  0.031  0.425  1.0
  Rh  Rh22  1  0.294  0.969  0.925  1.0
  Rh  Rh23  1  0.794  0.531  0.575  1.0
  Rh  Rh24  1  0.294  0.531  0.925  1.0
  Rh  Rh25  1  0.794  0.969  0.575  1.0
  Rh  Rh26  1  0.706  0.031  0.075  1.0
  Rh  Rh27  1  0.206  0.469  0.425  1.0
  N  N28  1  0.544  0.619  0.995  1.0
  N  N29  1  0.044  0.881  0.505  1.0
  N  N30  1  0.456  0.119  0.005  1.0
  N  N31  1  0.956  0.381  0.495  1.0
  N  N32  1  0.456  0.381  0.005  1.0
  N  N33  1  0.956  0.119  0.495  1.0
  N  N34  1  0.544  0.881  0.995  1.0
  N  N35  1  0.044  0.619  0.505  1.0
[/CIF]
.