The structure described by V6C5 crystallizes in the trigonal P3_112 space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one C(1), one C(2), one C(3), one C(4), and one C(5) atom to form a mixture of corner and edge-sharing VC5 square pyramids. In the second V site, V(2) is bonded to one C(1), one C(2), one C(3), one C(4), and one C(5) atom to form a mixture of corner and edge-sharing VC5 square pyramids. In the third V site, V(3) is bonded to one C(1), one C(2), one C(3), one C(4), and one C(5) atom to form a mixture of corner and edge-sharing VC5 square pyramids. There are five inequivalent C sites. In the first C site, C(1) is bonded to two equivalent V(1), two equivalent V(2), and two equivalent V(3) atoms to form a mixture of corner and edge-sharing CV6 octahedra. The corner-sharing octahedral tilt angles range from 8-9°. In the second C site, C(2) is bonded to two equivalent V(1), two equivalent V(2), and two equivalent V(3) atoms to form a mixture of corner and edge-sharing CV6 octahedra. The corner-sharing octahedral tilt angles are 7°. In the third C site, C(3) is bonded to two equivalent V(1), two equivalent V(2), and two equivalent V(3) atoms to form a mixture of corner and edge-sharing CV6 octahedra. The corner-sharing octahedral tilt angles range from 8-9°. In the fourth C site, C(4) is bonded to two equivalent V(1), two equivalent V(2), and two equivalent V(3) atoms to form a mixture of corner and edge-sharing CV6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. In the fifth C site, C(5) is bonded to two equivalent V(1), two equivalent V(2), and two equivalent V(3) atoms to form a mixture of corner and edge-sharing CV6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. is represented by the CIF file [CIF]
data_V6C5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.090
_cell_length_b   5.090
_cell_length_c   14.326
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   321.488
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.778  0.529  0.415  1.0
  V  V1  1  0.751  0.222  0.082  1.0
  V  V2  1  0.471  0.249  0.748  1.0
  V  V3  1  0.751  0.529  0.918  1.0
  V  V4  1  0.778  0.249  0.585  1.0
  V  V5  1  0.471  0.222  0.252  1.0
  V  V6  1  0.111  0.528  0.749  1.0
  V  V7  1  0.472  0.583  0.082  1.0
  V  V8  1  0.417  0.889  0.416  1.0
  V  V9  1  0.472  0.889  0.918  1.0
  V  V10  1  0.417  0.528  0.584  1.0
  V  V11  1  0.111  0.583  0.251  1.0
  V  V12  1  0.135  0.889  0.590  1.0
  V  V13  1  0.111  0.247  0.924  1.0
  V  V14  1  0.753  0.865  0.257  1.0
  V  V15  1  0.111  0.865  0.076  1.0
  V  V16  1  0.753  0.889  0.743  1.0
  V  V17  1  0.135  0.247  0.410  1.0
  C  C18  1  0.440  0.220  1.000  1.0
  C  C19  1  0.780  0.560  0.667  1.0
  C  C20  1  0.780  0.220  0.333  1.0
  C  C21  1  0.112  0.556  1.000  1.0
  C  C22  1  0.444  0.888  0.667  1.0
  C  C23  1  0.444  0.556  0.333  1.0
  C  C24  1  0.784  0.892  1.000  1.0
  C  C25  1  0.108  0.216  0.667  1.0
  C  C26  1  0.108  0.892  0.333  1.0
  C  C27  1  0.441  0.221  0.500  1.0
  C  C28  1  0.779  0.559  0.167  1.0
  C  C29  1  0.779  0.221  0.833  1.0
  C  C30  1  0.109  0.554  0.500  1.0
  C  C31  1  0.446  0.891  0.167  1.0
  C  C32  1  0.446  0.554  0.833  1.0
[/CIF]
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The structure described by V6C5 crystallizes in the trigonal P3_112 space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one C(1), one C(2), one C(3), one C(4), and one C(5) atom to form a mixture of corner and edge-sharing VC5 square pyramids. In the second V site, V(2) is bonded to one C(1), one C(2), one C(3), one C(4), and one C(5) atom to form a mixture of corner and edge-sharing VC5 square pyramids. In the third V site, V(3) is bonded to one C(1), one C(2), one C(3), one C(4), and one C(5) atom to form a mixture of corner and edge-sharing VC5 square pyramids. There are five inequivalent C sites. In the first C site, C(1) is bonded to two equivalent V(1), two equivalent V(2), and two equivalent V(3) atoms to form a mixture of corner and edge-sharing CV6 octahedra. The corner-sharing octahedral tilt angles range from 8-9°. In the second C site, C(2) is bonded to two equivalent V(1), two equivalent V(2), and two equivalent V(3) atoms to form a mixture of corner and edge-sharing CV6 octahedra. The corner-sharing octahedral tilt angles are 7°. In the third C site, C(3) is bonded to two equivalent V(1), two equivalent V(2), and two equivalent V(3) atoms to form a mixture of corner and edge-sharing CV6 octahedra. The corner-sharing octahedral tilt angles range from 8-9°. In the fourth C site, C(4) is bonded to two equivalent V(1), two equivalent V(2), and two equivalent V(3) atoms to form a mixture of corner and edge-sharing CV6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. In the fifth C site, C(5) is bonded to two equivalent V(1), two equivalent V(2), and two equivalent V(3) atoms to form a mixture of corner and edge-sharing CV6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. is represented by the CIF file [CIF]
data_V6C5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.090
_cell_length_b   5.090
_cell_length_c   14.326
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   321.488
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.778  0.529  0.415  1.0
  V  V1  1  0.751  0.222  0.082  1.0
  V  V2  1  0.471  0.249  0.748  1.0
  V  V3  1  0.751  0.529  0.918  1.0
  V  V4  1  0.778  0.249  0.585  1.0
  V  V5  1  0.471  0.222  0.252  1.0
  V  V6  1  0.111  0.528  0.749  1.0
  V  V7  1  0.472  0.583  0.082  1.0
  V  V8  1  0.417  0.889  0.416  1.0
  V  V9  1  0.472  0.889  0.918  1.0
  V  V10  1  0.417  0.528  0.584  1.0
  V  V11  1  0.111  0.583  0.251  1.0
  V  V12  1  0.135  0.889  0.590  1.0
  V  V13  1  0.111  0.247  0.924  1.0
  V  V14  1  0.753  0.865  0.257  1.0
  V  V15  1  0.111  0.865  0.076  1.0
  V  V16  1  0.753  0.889  0.743  1.0
  V  V17  1  0.135  0.247  0.410  1.0
  C  C18  1  0.440  0.220  1.000  1.0
  C  C19  1  0.780  0.560  0.667  1.0
  C  C20  1  0.780  0.220  0.333  1.0
  C  C21  1  0.112  0.556  1.000  1.0
  C  C22  1  0.444  0.888  0.667  1.0
  C  C23  1  0.444  0.556  0.333  1.0
  C  C24  1  0.784  0.892  1.000  1.0
  C  C25  1  0.108  0.216  0.667  1.0
  C  C26  1  0.108  0.892  0.333  1.0
  C  C27  1  0.441  0.221  0.500  1.0
  C  C28  1  0.779  0.559  0.167  1.0
  C  C29  1  0.779  0.221  0.833  1.0
  C  C30  1  0.109  0.554  0.500  1.0
  C  C31  1  0.446  0.891  0.167  1.0
  C  C32  1  0.446  0.554  0.833  1.0
[/CIF]
.