The compound described by TlO2(CO2)4 is Cyanogen Chloride-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight carbon dioxide molecules and two TlO2 clusters. In each TlO2 cluster, Tl(1) is bonded in a 2-coordinate geometry to one O(10) and one O(9) atom. There are two inequivalent O sites. In the first O site, O(9) is bonded in a 2-coordinate geometry to one Tl(1) and one O(10) atom. In the second O site, O(10) is bonded in a distorted L-shaped geometry to one Tl(1) and one O(9) atom. is represented by the CIF card [CIF]
data_Tl(C2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.775
_cell_length_b   8.391
_cell_length_c   12.769
_cell_angle_alpha   105.701
_cell_angle_beta   89.580
_cell_angle_gamma   95.025
_symmetry_Int_Tables_number   1
_cell_volume   695.967
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.650  0.611  0.773  1.0
  Tl  Tl1  1  0.350  0.389  0.227  1.0
  C  C2  1  0.144  0.496  0.622  1.0
  C  C3  1  0.856  0.504  0.378  1.0
  C  C4  1  0.989  0.918  0.617  1.0
  C  C5  1  0.011  0.082  0.383  1.0
  C  C6  1  0.216  0.973  0.900  1.0
  C  C7  1  0.784  0.027  0.100  1.0
  C  C8  1  0.261  0.784  0.135  1.0
  C  C9  1  0.739  0.216  0.865  1.0
  O  O10  1  0.272  0.583  0.599  1.0
  O  O11  1  0.728  0.417  0.401  1.0
  O  O12  1  0.012  0.411  0.645  1.0
  O  O13  1  0.988  0.589  0.355  1.0
  O  O14  1  0.860  0.812  0.588  1.0
  O  O15  1  0.140  0.188  0.412  1.0
  O  O16  1  0.118  0.023  0.646  1.0
  O  O17  1  0.882  0.977  0.354  1.0
  O  O18  1  0.173  0.841  0.840  1.0
  O  O19  1  0.827  0.159  0.160  1.0
  O  O20  1  0.258  0.103  0.962  1.0
  O  O21  1  0.742  0.897  0.038  1.0
  O  O22  1  0.296  0.927  0.177  1.0
  O  O23  1  0.704  0.073  0.823  1.0
  O  O24  1  0.222  0.643  0.090  1.0
  O  O25  1  0.778  0.357  0.910  1.0
  O  O26  1  0.375  0.403  0.799  1.0
  O  O27  1  0.625  0.597  0.201  1.0
  O  O28  1  0.488  0.330  0.715  1.0
  O  O29  1  0.512  0.670  0.285  1.0
[/CIF]
.
The compound described by TlO2(CO2)4 is Cyanogen Chloride-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight carbon dioxide molecules and two TlO2 clusters. In each TlO2 cluster, Tl(1) is bonded in a 2-coordinate geometry to one O(10) and one O(9) atom. There are two inequivalent O sites. In the first O site, O(9) is bonded in a 2-coordinate geometry to one Tl(1) and one O(10) atom. In the second O site, O(10) is bonded in a distorted L-shaped geometry to one Tl(1) and one O(9) atom. is represented by the CIF card [CIF]
data_Tl(C2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.775
_cell_length_b   8.391
_cell_length_c   12.769
_cell_angle_alpha   105.701
_cell_angle_beta   89.580
_cell_angle_gamma   95.025
_symmetry_Int_Tables_number   1
_cell_volume   695.967
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.650  0.611  0.773  1.0
  Tl  Tl1  1  0.350  0.389  0.227  1.0
  C  C2  1  0.144  0.496  0.622  1.0
  C  C3  1  0.856  0.504  0.378  1.0
  C  C4  1  0.989  0.918  0.617  1.0
  C  C5  1  0.011  0.082  0.383  1.0
  C  C6  1  0.216  0.973  0.900  1.0
  C  C7  1  0.784  0.027  0.100  1.0
  C  C8  1  0.261  0.784  0.135  1.0
  C  C9  1  0.739  0.216  0.865  1.0
  O  O10  1  0.272  0.583  0.599  1.0
  O  O11  1  0.728  0.417  0.401  1.0
  O  O12  1  0.012  0.411  0.645  1.0
  O  O13  1  0.988  0.589  0.355  1.0
  O  O14  1  0.860  0.812  0.588  1.0
  O  O15  1  0.140  0.188  0.412  1.0
  O  O16  1  0.118  0.023  0.646  1.0
  O  O17  1  0.882  0.977  0.354  1.0
  O  O18  1  0.173  0.841  0.840  1.0
  O  O19  1  0.827  0.159  0.160  1.0
  O  O20  1  0.258  0.103  0.962  1.0
  O  O21  1  0.742  0.897  0.038  1.0
  O  O22  1  0.296  0.927  0.177  1.0
  O  O23  1  0.704  0.073  0.823  1.0
  O  O24  1  0.222  0.643  0.090  1.0
  O  O25  1  0.778  0.357  0.910  1.0
  O  O26  1  0.375  0.403  0.799  1.0
  O  O27  1  0.625  0.597  0.201  1.0
  O  O28  1  0.488  0.330  0.715  1.0
  O  O29  1  0.512  0.670  0.285  1.0
[/CIF]
.