The structure described by (CeP5NO15)2N2 crystallizes in the monoclinic Cc space group. The structure consists of four ammonia atoms inside a CeP5NO15 framework. In the CeP5NO15 framework, Ce(1) is bonded in a 8-coordinate geometry to one O(10), one O(13), one O(14), one O(15), one O(2), one O(4), one O(5), and one O(9) atom. There are five inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(12), one O(15), and one O(7) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(13), one O(14), one O(3), and one O(8) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(1), one O(2), one O(7), and one O(9) atom to form corner-sharing PO4 tetrahedra. In the fourth P site, P(4) is bonded to one O(1), one O(10), one O(6), and one O(8) atom to form corner-sharing PO4 tetrahedra. In the fifth P site, P(5) is bonded to one O(12), one O(3), one O(4), and one O(5) atom to form corner-sharing PO4 tetrahedra. N(1) is bonded in a single-bond geometry to one O(6) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(3) and one P(4) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Ce(1) and one P(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(2) and one P(5) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one P(5) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one P(5) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one P(4) and one N(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one P(2) and one P(4) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Ce(1) and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Ce(1) and one P(4) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one P(1) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one P(1) and one P(5) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one P(2) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one Ce(1) and one P(2) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Ce(1) and one P(1) atom. is represented by the CIF card [CIF]
data_CeP5N2O15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.224
_cell_length_b   7.224
_cell_length_c   13.161
_cell_angle_alpha   91.829
_cell_angle_beta   91.829
_cell_angle_gamma   107.842
_symmetry_Int_Tables_number   1
_cell_volume   652.777
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.084  0.892  0.251  1.0
  Ce  Ce1  1  0.892  0.084  0.751  1.0
  P  P2  1  1.000  0.603  0.012  1.0
  P  P3  1  0.603  1.000  0.512  1.0
  P  P4  1  0.203  0.448  0.336  1.0
  P  P5  1  0.448  0.203  0.836  1.0
  P  P6  1  0.979  0.187  0.032  1.0
  P  P7  1  0.187  0.979  0.532  1.0
  P  P8  1  0.380  0.202  0.060  1.0
  P  P9  1  0.202  0.380  0.560  1.0
  P  P10  1  0.557  0.775  0.325  1.0
  P  P11  1  0.775  0.557  0.825  1.0
  N  N12  1  0.630  0.332  0.208  1.0
  N  N13  1  0.332  0.630  0.708  1.0
  N  N14  1  0.526  0.746  0.056  1.0
  N  N15  1  0.746  0.526  0.556  1.0
  O  O16  1  0.218  0.293  0.029  1.0
  O  O17  1  0.293  0.218  0.529  1.0
  O  O18  1  0.088  0.908  0.429  1.0
  O  O19  1  0.908  0.088  0.929  1.0
  O  O20  1  0.433  0.544  0.324  1.0
  O  O21  1  0.544  0.433  0.824  1.0
  O  O22  1  0.421  0.884  0.292  1.0
  O  O23  1  0.884  0.421  0.792  1.0
  O  O24  1  0.743  0.792  0.273  1.0
  O  O25  1  0.792  0.743  0.773  1.0
  O  O26  1  0.540  0.378  0.126  1.0
  O  O27  1  0.378  0.540  0.626  1.0
  O  O28  1  0.915  0.376  0.043  1.0
  O  O29  1  0.376  0.915  0.543  1.0
  O  O30  1  0.182  0.484  0.461  1.0
  O  O31  1  0.484  0.182  0.961  1.0
  O  O32  1  0.937  0.072  0.125  1.0
  O  O33  1  0.072  0.937  0.625  1.0
  O  O34  1  0.317  0.028  0.121  1.0
  O  O35  1  0.028  0.317  0.621  1.0
  O  O36  1  0.652  0.179  0.455  1.0
  O  O37  1  0.179  0.652  0.955  1.0
  O  O38  1  0.616  0.814  0.445  1.0
  O  O39  1  0.814  0.616  0.945  1.0
  O  O40  1  0.088  0.565  0.288  1.0
  O  O41  1  0.565  0.088  0.788  1.0
  O  O42  1  0.159  0.236  0.310  1.0
  O  O43  1  0.236  0.159  0.810  1.0
  O  O44  1  0.990  0.710  0.112  1.0
  O  O45  1  0.710  0.990  0.612  1.0
[/CIF]
.
The structure described by (CeP5NO15)2N2 crystallizes in the monoclinic Cc space group. The structure consists of four ammonia atoms inside a CeP5NO15 framework. In the CeP5NO15 framework, Ce(1) is bonded in a 8-coordinate geometry to one O(10), one O(13), one O(14), one O(15), one O(2), one O(4), one O(5), and one O(9) atom. There are five inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(12), one O(15), and one O(7) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(13), one O(14), one O(3), and one O(8) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(1), one O(2), one O(7), and one O(9) atom to form corner-sharing PO4 tetrahedra. In the fourth P site, P(4) is bonded to one O(1), one O(10), one O(6), and one O(8) atom to form corner-sharing PO4 tetrahedra. In the fifth P site, P(5) is bonded to one O(12), one O(3), one O(4), and one O(5) atom to form corner-sharing PO4 tetrahedra. N(1) is bonded in a single-bond geometry to one O(6) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(3) and one P(4) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Ce(1) and one P(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(2) and one P(5) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one P(5) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one P(5) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one P(4) and one N(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one P(2) and one P(4) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Ce(1) and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Ce(1) and one P(4) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one P(1) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one P(1) and one P(5) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one P(2) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one Ce(1) and one P(2) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Ce(1) and one P(1) atom. is represented by the CIF card [CIF]
data_CeP5N2O15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.224
_cell_length_b   7.224
_cell_length_c   13.161
_cell_angle_alpha   91.829
_cell_angle_beta   91.829
_cell_angle_gamma   107.842
_symmetry_Int_Tables_number   1
_cell_volume   652.777
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.084  0.892  0.251  1.0
  Ce  Ce1  1  0.892  0.084  0.751  1.0
  P  P2  1  1.000  0.603  0.012  1.0
  P  P3  1  0.603  1.000  0.512  1.0
  P  P4  1  0.203  0.448  0.336  1.0
  P  P5  1  0.448  0.203  0.836  1.0
  P  P6  1  0.979  0.187  0.032  1.0
  P  P7  1  0.187  0.979  0.532  1.0
  P  P8  1  0.380  0.202  0.060  1.0
  P  P9  1  0.202  0.380  0.560  1.0
  P  P10  1  0.557  0.775  0.325  1.0
  P  P11  1  0.775  0.557  0.825  1.0
  N  N12  1  0.630  0.332  0.208  1.0
  N  N13  1  0.332  0.630  0.708  1.0
  N  N14  1  0.526  0.746  0.056  1.0
  N  N15  1  0.746  0.526  0.556  1.0
  O  O16  1  0.218  0.293  0.029  1.0
  O  O17  1  0.293  0.218  0.529  1.0
  O  O18  1  0.088  0.908  0.429  1.0
  O  O19  1  0.908  0.088  0.929  1.0
  O  O20  1  0.433  0.544  0.324  1.0
  O  O21  1  0.544  0.433  0.824  1.0
  O  O22  1  0.421  0.884  0.292  1.0
  O  O23  1  0.884  0.421  0.792  1.0
  O  O24  1  0.743  0.792  0.273  1.0
  O  O25  1  0.792  0.743  0.773  1.0
  O  O26  1  0.540  0.378  0.126  1.0
  O  O27  1  0.378  0.540  0.626  1.0
  O  O28  1  0.915  0.376  0.043  1.0
  O  O29  1  0.376  0.915  0.543  1.0
  O  O30  1  0.182  0.484  0.461  1.0
  O  O31  1  0.484  0.182  0.961  1.0
  O  O32  1  0.937  0.072  0.125  1.0
  O  O33  1  0.072  0.937  0.625  1.0
  O  O34  1  0.317  0.028  0.121  1.0
  O  O35  1  0.028  0.317  0.621  1.0
  O  O36  1  0.652  0.179  0.455  1.0
  O  O37  1  0.179  0.652  0.955  1.0
  O  O38  1  0.616  0.814  0.445  1.0
  O  O39  1  0.814  0.616  0.945  1.0
  O  O40  1  0.088  0.565  0.288  1.0
  O  O41  1  0.565  0.088  0.788  1.0
  O  O42  1  0.159  0.236  0.310  1.0
  O  O43  1  0.236  0.159  0.810  1.0
  O  O44  1  0.990  0.710  0.112  1.0
  O  O45  1  0.710  0.990  0.612  1.0
[/CIF]
.