The crystal structure described by ThP2(NO4)2 crystallizes in the orthorhombic Fdd2 space group. Th(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. N(1) is bonded in a single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Th(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Th(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Th(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Th(1), one P(1), and one N(1) atom. is represented by the CIF file [CIF]
data_ThP2(NO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.902
_cell_length_b   10.699
_cell_length_c   6.990
_cell_angle_alpha   72.700
_cell_angle_beta   69.552
_cell_angle_gamma   37.748
_symmetry_Int_Tables_number   1
_cell_volume   467.398
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.358  0.142  0.358  1.0
  Th  Th1  1  0.108  0.892  0.108  1.0
  P  P2  1  0.308  0.043  0.932  1.0
  P  P3  1  0.533  0.318  0.207  1.0
  P  P4  1  0.207  0.942  0.533  1.0
  P  P5  1  0.932  0.717  0.308  1.0
  N  N6  1  0.893  0.821  0.655  1.0
  N  N7  1  0.620  0.595  0.429  1.0
  N  N8  1  0.429  0.357  0.620  1.0
  N  N9  1  0.655  0.630  0.893  1.0
  O  O10  1  0.356  0.083  0.708  1.0
  O  O11  1  0.397  0.542  0.167  1.0
  O  O12  1  0.757  0.181  0.179  1.0
  O  O13  1  0.367  0.071  0.069  1.0
  O  O14  1  0.179  0.883  0.757  1.0
  O  O15  1  0.069  0.493  0.367  1.0
  O  O16  1  0.708  0.853  0.356  1.0
  O  O17  1  0.167  0.894  0.397  1.0
  O  O18  1  0.105  0.128  0.008  1.0
  O  O19  1  0.455  0.790  0.962  1.0
  O  O20  1  0.491  0.242  0.122  1.0
  O  O21  1  0.457  0.288  0.460  1.0
  O  O22  1  0.460  0.795  0.457  1.0
  O  O23  1  0.122  0.145  0.491  1.0
  O  O24  1  0.962  0.793  0.455  1.0
  O  O25  1  0.008  0.759  0.105  1.0
[/CIF]
.
The crystal structure described by ThP2(NO4)2 crystallizes in the orthorhombic Fdd2 space group. Th(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. N(1) is bonded in a single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Th(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Th(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Th(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Th(1), one P(1), and one N(1) atom. is represented by the CIF file [CIF]
data_ThP2(NO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.902
_cell_length_b   10.699
_cell_length_c   6.990
_cell_angle_alpha   72.700
_cell_angle_beta   69.552
_cell_angle_gamma   37.748
_symmetry_Int_Tables_number   1
_cell_volume   467.398
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.358  0.142  0.358  1.0
  Th  Th1  1  0.108  0.892  0.108  1.0
  P  P2  1  0.308  0.043  0.932  1.0
  P  P3  1  0.533  0.318  0.207  1.0
  P  P4  1  0.207  0.942  0.533  1.0
  P  P5  1  0.932  0.717  0.308  1.0
  N  N6  1  0.893  0.821  0.655  1.0
  N  N7  1  0.620  0.595  0.429  1.0
  N  N8  1  0.429  0.357  0.620  1.0
  N  N9  1  0.655  0.630  0.893  1.0
  O  O10  1  0.356  0.083  0.708  1.0
  O  O11  1  0.397  0.542  0.167  1.0
  O  O12  1  0.757  0.181  0.179  1.0
  O  O13  1  0.367  0.071  0.069  1.0
  O  O14  1  0.179  0.883  0.757  1.0
  O  O15  1  0.069  0.493  0.367  1.0
  O  O16  1  0.708  0.853  0.356  1.0
  O  O17  1  0.167  0.894  0.397  1.0
  O  O18  1  0.105  0.128  0.008  1.0
  O  O19  1  0.455  0.790  0.962  1.0
  O  O20  1  0.491  0.242  0.122  1.0
  O  O21  1  0.457  0.288  0.460  1.0
  O  O22  1  0.460  0.795  0.457  1.0
  O  O23  1  0.122  0.145  0.491  1.0
  O  O24  1  0.962  0.793  0.455  1.0
  O  O25  1  0.008  0.759  0.105  1.0
[/CIF]
.