The structure described by PdCd2P4O8 crystallizes in the orthorhombic Fddd space group. Pd(1) is bonded in a distorted trigonal pyramidal geometry to four equivalent P(1) atoms. Cd(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. P(1) is bonded in a bent 120 degrees geometry to one Pd(1), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 150 degrees geometry to one Cd(1) and one P(1) atom. In the second O site, O(1) is bonded in a bent 150 degrees geometry to one Cd(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Cd2P4PdO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.539
_cell_length_b   10.517
_cell_length_c   9.172
_cell_angle_alpha   64.299
_cell_angle_beta   64.055
_cell_angle_gamma   51.646
_symmetry_Int_Tables_number   1
_cell_volume   697.630
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.125  0.625  0.125  1.0
  Cd  Cd1  1  0.125  0.125  0.625  1.0
  Cd  Cd2  1  0.125  0.125  0.125  1.0
  Cd  Cd3  1  0.625  0.125  0.125  1.0
  P  P4  1  0.448  0.440  0.787  1.0
  P  P5  1  0.324  0.787  0.440  1.0
  P  P6  1  0.787  0.324  0.448  1.0
  P  P7  1  0.802  0.810  0.463  1.0
  P  P8  1  0.440  0.448  0.324  1.0
  P  P9  1  0.926  0.463  0.810  1.0
  P  P10  1  0.463  0.926  0.802  1.0
  P  P11  1  0.810  0.802  0.926  1.0
  Pd  Pd12  1  0.750  0.750  0.750  1.0
  Pd  Pd13  1  0.500  0.500  0.500  1.0
  O  O14  1  0.569  0.321  0.218  1.0
  O  O15  1  0.892  0.218  0.321  1.0
  O  O16  1  0.218  0.892  0.569  1.0
  O  O17  1  0.681  0.929  0.032  1.0
  O  O18  1  0.321  0.569  0.892  1.0
  O  O19  1  0.358  0.032  0.929  1.0
  O  O20  1  0.032  0.358  0.681  1.0
  O  O21  1  0.929  0.681  0.358  1.0
  O  O22  1  0.568  0.271  0.881  1.0
  O  O23  1  0.281  0.881  0.271  1.0
  O  O24  1  0.881  0.281  0.568  1.0
  O  O25  1  0.682  0.979  0.369  1.0
  O  O26  1  0.271  0.568  0.281  1.0
  O  O27  1  0.969  0.369  0.979  1.0
  O  O28  1  0.369  0.969  0.682  1.0
  O  O29  1  0.979  0.682  0.969  1.0
[/CIF]
.
The structure described by PdCd2P4O8 crystallizes in the orthorhombic Fddd space group. Pd(1) is bonded in a distorted trigonal pyramidal geometry to four equivalent P(1) atoms. Cd(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. P(1) is bonded in a bent 120 degrees geometry to one Pd(1), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 150 degrees geometry to one Cd(1) and one P(1) atom. In the second O site, O(1) is bonded in a bent 150 degrees geometry to one Cd(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Cd2P4PdO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.539
_cell_length_b   10.517
_cell_length_c   9.172
_cell_angle_alpha   64.299
_cell_angle_beta   64.055
_cell_angle_gamma   51.646
_symmetry_Int_Tables_number   1
_cell_volume   697.630
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.125  0.625  0.125  1.0
  Cd  Cd1  1  0.125  0.125  0.625  1.0
  Cd  Cd2  1  0.125  0.125  0.125  1.0
  Cd  Cd3  1  0.625  0.125  0.125  1.0
  P  P4  1  0.448  0.440  0.787  1.0
  P  P5  1  0.324  0.787  0.440  1.0
  P  P6  1  0.787  0.324  0.448  1.0
  P  P7  1  0.802  0.810  0.463  1.0
  P  P8  1  0.440  0.448  0.324  1.0
  P  P9  1  0.926  0.463  0.810  1.0
  P  P10  1  0.463  0.926  0.802  1.0
  P  P11  1  0.810  0.802  0.926  1.0
  Pd  Pd12  1  0.750  0.750  0.750  1.0
  Pd  Pd13  1  0.500  0.500  0.500  1.0
  O  O14  1  0.569  0.321  0.218  1.0
  O  O15  1  0.892  0.218  0.321  1.0
  O  O16  1  0.218  0.892  0.569  1.0
  O  O17  1  0.681  0.929  0.032  1.0
  O  O18  1  0.321  0.569  0.892  1.0
  O  O19  1  0.358  0.032  0.929  1.0
  O  O20  1  0.032  0.358  0.681  1.0
  O  O21  1  0.929  0.681  0.358  1.0
  O  O22  1  0.568  0.271  0.881  1.0
  O  O23  1  0.281  0.881  0.271  1.0
  O  O24  1  0.881  0.281  0.568  1.0
  O  O25  1  0.682  0.979  0.369  1.0
  O  O26  1  0.271  0.568  0.281  1.0
  O  O27  1  0.969  0.369  0.979  1.0
  O  O28  1  0.369  0.969  0.682  1.0
  O  O29  1  0.979  0.682  0.969  1.0
[/CIF]
.