The compound described by NaIO4 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one NaIO4 cluster. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(6) atom. In the second Na site, Na(2) is bonded in a 4-coordinate geometry to one O(3), one O(5), one O(6), and one O(7) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Na(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Na(1) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Na(1), one Na(2), and one I(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one I(2) atom. In the fifth O site, O(5) is bonded in a distorted L-shaped geometry to one Na(2) and one I(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Na(1) and one Na(2) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Na(2) and one I(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one I(2) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a distorted water-like geometry to one O(5) and one O(7) atom. In the second I site, I(2) is bonded in a distorted water-like geometry to one O(3), one O(4), and one O(8) atom. is represented by the CIF file [CIF]
data_NaIO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.530
_cell_length_b   5.549
_cell_length_c   7.341
_cell_angle_alpha   112.121
_cell_angle_beta   111.796
_cell_angle_gamma   90.393
_symmetry_Int_Tables_number   1
_cell_volume   190.907
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.870  0.375  0.738  1.0
  Na  Na1  1  0.118  0.632  0.236  1.0
  I  I2  1  0.326  0.922  0.652  1.0
  I  I3  1  0.580  0.178  0.153  1.0
  O  O4  1  0.510  0.198  0.539  1.0
  O  O5  1  0.070  0.229  0.507  1.0
  O  O6  1  0.750  0.431  0.010  1.0
  O  O7  1  0.269  0.066  0.009  1.0
  O  O8  1  0.035  0.748  0.546  1.0
  O  O9  1  0.304  0.469  0.045  1.0
  O  O10  1  0.436  0.749  0.512  1.0
  O  O11  1  0.750  0.995  0.044  1.0
[/CIF]
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The compound described by NaIO4 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one NaIO4 cluster. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(6) atom. In the second Na site, Na(2) is bonded in a 4-coordinate geometry to one O(3), one O(5), one O(6), and one O(7) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Na(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Na(1) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Na(1), one Na(2), and one I(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one I(2) atom. In the fifth O site, O(5) is bonded in a distorted L-shaped geometry to one Na(2) and one I(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Na(1) and one Na(2) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Na(2) and one I(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one I(2) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a distorted water-like geometry to one O(5) and one O(7) atom. In the second I site, I(2) is bonded in a distorted water-like geometry to one O(3), one O(4), and one O(8) atom. is represented by the CIF file [CIF]
data_NaIO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.530
_cell_length_b   5.549
_cell_length_c   7.341
_cell_angle_alpha   112.121
_cell_angle_beta   111.796
_cell_angle_gamma   90.393
_symmetry_Int_Tables_number   1
_cell_volume   190.907
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.870  0.375  0.738  1.0
  Na  Na1  1  0.118  0.632  0.236  1.0
  I  I2  1  0.326  0.922  0.652  1.0
  I  I3  1  0.580  0.178  0.153  1.0
  O  O4  1  0.510  0.198  0.539  1.0
  O  O5  1  0.070  0.229  0.507  1.0
  O  O6  1  0.750  0.431  0.010  1.0
  O  O7  1  0.269  0.066  0.009  1.0
  O  O8  1  0.035  0.748  0.546  1.0
  O  O9  1  0.304  0.469  0.045  1.0
  O  O10  1  0.436  0.749  0.512  1.0
  O  O11  1  0.750  0.995  0.044  1.0
[/CIF]
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