The material described by SbNS2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two SbNS2 clusters. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted T-shaped geometry to one S(1), one S(3), and one S(4) atom. In the second Sb site, Sb(2) is bonded in a 3-coordinate geometry to one N(2), one S(3), and one S(4) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one S(2) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one Sb(2), one S(1), and one S(2) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Sb(1) and one N(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one Sb(1) and one Sb(2) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one Sb(1) and one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbS2N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.122
_cell_length_b   7.324
_cell_length_c   10.502
_cell_angle_alpha   81.507
_cell_angle_beta   76.741
_cell_angle_gamma   74.409
_symmetry_Int_Tables_number   1
_cell_volume   439.605
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.166  0.178  0.372  1.0
  Sb  Sb1  1  0.834  0.822  0.628  1.0
  Sb  Sb2  1  0.572  0.165  0.099  1.0
  Sb  Sb3  1  0.428  0.835  0.901  1.0
  S  S4  1  0.616  0.161  0.669  1.0
  S  S5  1  0.384  0.839  0.331  1.0
  S  S6  1  0.123  0.231  0.797  1.0
  S  S7  1  0.877  0.769  0.203  1.0
  S  S8  1  0.529  0.282  0.314  1.0
  S  S9  1  0.471  0.718  0.686  1.0
  S  S10  1  0.149  0.237  0.132  1.0
  S  S11  1  0.851  0.763  0.868  1.0
  N  N12  1  0.070  0.330  0.670  1.0
  N  N13  1  0.930  0.670  0.330  1.0
  N  N14  1  0.413  0.124  0.804  1.0
  N  N15  1  0.587  0.876  0.196  1.0
[/CIF]
.
The material described by SbNS2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two SbNS2 clusters. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted T-shaped geometry to one S(1), one S(3), and one S(4) atom. In the second Sb site, Sb(2) is bonded in a 3-coordinate geometry to one N(2), one S(3), and one S(4) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one S(2) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one Sb(2), one S(1), and one S(2) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Sb(1) and one N(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one Sb(1) and one Sb(2) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one Sb(1) and one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbS2N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.122
_cell_length_b   7.324
_cell_length_c   10.502
_cell_angle_alpha   81.507
_cell_angle_beta   76.741
_cell_angle_gamma   74.409
_symmetry_Int_Tables_number   1
_cell_volume   439.605
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.166  0.178  0.372  1.0
  Sb  Sb1  1  0.834  0.822  0.628  1.0
  Sb  Sb2  1  0.572  0.165  0.099  1.0
  Sb  Sb3  1  0.428  0.835  0.901  1.0
  S  S4  1  0.616  0.161  0.669  1.0
  S  S5  1  0.384  0.839  0.331  1.0
  S  S6  1  0.123  0.231  0.797  1.0
  S  S7  1  0.877  0.769  0.203  1.0
  S  S8  1  0.529  0.282  0.314  1.0
  S  S9  1  0.471  0.718  0.686  1.0
  S  S10  1  0.149  0.237  0.132  1.0
  S  S11  1  0.851  0.763  0.868  1.0
  N  N12  1  0.070  0.330  0.670  1.0
  N  N13  1  0.930  0.670  0.330  1.0
  N  N14  1  0.413  0.124  0.804  1.0
  N  N15  1  0.587  0.876  0.196  1.0
[/CIF]
.