The structure described by TlSbS2 crystallizes in the triclinic P-1 space group. Tl(1) is bonded in a 6-coordinate geometry to three equivalent S(1) and three equivalent S(2) atoms. Sb(1) is bonded in a see-saw-like geometry to two equivalent S(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted L-shaped geometry to three equivalent Tl(1) and two equivalent Sb(1) atoms. In the second S site, S(2) is bonded in a 5-coordinate geometry to three equivalent Tl(1) and two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_TlSbS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.351
_cell_length_b   6.477
_cell_length_c   7.030
_cell_angle_alpha   114.002
_cell_angle_beta   110.750
_cell_angle_gamma   88.806
_symmetry_Int_Tables_number   1
_cell_volume   244.453
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.129  0.386  0.744  1.0
  Tl  Tl1  1  0.871  0.614  0.256  1.0
  Sb  Sb2  1  0.591  0.914  0.751  1.0
  Sb  Sb3  1  0.409  0.086  0.249  1.0
  S  S4  1  0.218  0.908  0.790  1.0
  S  S5  1  0.782  0.092  0.210  1.0
  S  S6  1  0.629  0.279  0.730  1.0
  S  S7  1  0.371  0.721  0.270  1.0
[/CIF]
.
The structure described by TlSbS2 crystallizes in the triclinic P-1 space group. Tl(1) is bonded in a 6-coordinate geometry to three equivalent S(1) and three equivalent S(2) atoms. Sb(1) is bonded in a see-saw-like geometry to two equivalent S(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted L-shaped geometry to three equivalent Tl(1) and two equivalent Sb(1) atoms. In the second S site, S(2) is bonded in a 5-coordinate geometry to three equivalent Tl(1) and two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_TlSbS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.351
_cell_length_b   6.477
_cell_length_c   7.030
_cell_angle_alpha   114.002
_cell_angle_beta   110.750
_cell_angle_gamma   88.806
_symmetry_Int_Tables_number   1
_cell_volume   244.453
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.129  0.386  0.744  1.0
  Tl  Tl1  1  0.871  0.614  0.256  1.0
  Sb  Sb2  1  0.591  0.914  0.751  1.0
  Sb  Sb3  1  0.409  0.086  0.249  1.0
  S  S4  1  0.218  0.908  0.790  1.0
  S  S5  1  0.782  0.092  0.210  1.0
  S  S6  1  0.629  0.279  0.730  1.0
  S  S7  1  0.371  0.721  0.270  1.0
[/CIF]
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