The structure described by Os3B(CO)10 is beta Sn structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Os3B(CO)10 clusters. There are three inequivalent Os sites. In the first Os site, Os(1) is bonded in a distorted rectangular see-saw-like geometry to one B(1), one C(2), one C(3), and one C(4) atom. In the second Os site, Os(2) is bonded in a 3-coordinate geometry to one B(1), one C(5), one C(6), and one C(7) atom. In the third Os site, Os(3) is bonded in a distorted trigonal pyramidal geometry to one B(1), one C(10), one C(8), and one C(9) atom. B(1) is bonded in a distorted single-bond geometry to one Os(1), one Os(2), one Os(3), and one C(1) atom. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one B(1) and one O(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Os(1) and one O(2) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one Os(1) and one O(3) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one Os(1) and one O(4) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Os(2) and one O(5) atom. In the sixth C site, C(6) is bonded in a distorted linear geometry to one Os(2) and one O(6) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Os(2) and one O(7) atom. In the eighth C site, C(8) is bonded in a distorted linear geometry to one Os(3) and one O(8) atom. In the ninth C site, C(9) is bonded in a distorted linear geometry to one Os(3) and one O(9) atom. In the tenth C site, C(10) is bonded in a linear geometry to one Os(3) and one O(10) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(10) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BOs3(CO)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.690
_cell_length_b   9.491
_cell_length_c   13.116
_cell_angle_alpha   80.621
_cell_angle_beta   72.984
_cell_angle_gamma   73.582
_symmetry_Int_Tables_number   1
_cell_volume   874.784
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.681  0.747  0.345  1.0
  B  B1  1  0.319  0.253  0.655  1.0
  Os  Os2  1  0.703  0.961  0.264  1.0
  Os  Os3  1  0.297  0.039  0.736  1.0
  Os  Os4  1  0.645  0.756  0.171  1.0
  Os  Os5  1  0.355  0.244  0.829  1.0
  Os  Os6  1  0.936  0.614  0.250  1.0
  Os  Os7  1  0.064  0.386  0.750  1.0
  C  C8  1  0.566  0.702  0.449  1.0
  C  C9  1  0.434  0.298  0.551  1.0
  C  C10  1  0.834  0.085  0.153  1.0
  C  C11  1  0.166  0.915  0.847  1.0
  C  C12  1  0.491  0.115  0.310  1.0
  C  C13  1  0.509  0.885  0.690  1.0
  C  C14  1  0.791  0.984  0.381  1.0
  C  C15  1  0.209  0.016  0.619  1.0
  C  C16  1  0.647  0.779  0.024  1.0
  C  C17  1  0.353  0.221  0.976  1.0
  C  C18  1  0.599  0.565  0.193  1.0
  C  C19  1  0.401  0.435  0.807  1.0
  C  C20  1  0.392  0.870  0.212  1.0
  C  C21  1  0.608  0.130  0.788  1.0
  C  C22  1  0.956  0.411  0.287  1.0
  C  C23  1  0.044  0.589  0.713  1.0
  C  C24  1  0.149  0.592  0.124  1.0
  C  C25  1  0.851  0.408  0.876  1.0
  C  C26  1  0.060  0.611  0.357  1.0
  C  C27  1  0.940  0.389  0.643  1.0
  O  O28  1  0.472  0.665  0.531  1.0
  O  O29  1  0.528  0.335  0.469  1.0
  O  O30  1  0.919  0.163  0.094  1.0
  O  O31  1  0.081  0.837  0.906  1.0
  O  O32  1  0.353  0.205  0.338  1.0
  O  O33  1  0.647  0.795  0.662  1.0
  O  O34  1  0.838  0.995  0.455  1.0
  O  O35  1  0.162  0.005  0.545  1.0
  O  O36  1  0.647  0.794  0.933  1.0
  O  O37  1  0.353  0.206  0.067  1.0
  O  O38  1  0.552  0.455  0.217  1.0
  O  O39  1  0.448  0.545  0.783  1.0
  O  O40  1  0.233  0.925  0.248  1.0
  O  O41  1  0.767  0.075  0.752  1.0
  O  O42  1  0.955  0.287  0.308  1.0
  O  O43  1  0.045  0.713  0.692  1.0
  O  O44  1  0.286  0.580  0.056  1.0
  O  O45  1  0.714  0.420  0.944  1.0
  O  O46  1  0.131  0.609  0.424  1.0
  O  O47  1  0.869  0.391  0.576  1.0
[/CIF]
.
The structure described by Os3B(CO)10 is beta Sn structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Os3B(CO)10 clusters. There are three inequivalent Os sites. In the first Os site, Os(1) is bonded in a distorted rectangular see-saw-like geometry to one B(1), one C(2), one C(3), and one C(4) atom. In the second Os site, Os(2) is bonded in a 3-coordinate geometry to one B(1), one C(5), one C(6), and one C(7) atom. In the third Os site, Os(3) is bonded in a distorted trigonal pyramidal geometry to one B(1), one C(10), one C(8), and one C(9) atom. B(1) is bonded in a distorted single-bond geometry to one Os(1), one Os(2), one Os(3), and one C(1) atom. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one B(1) and one O(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Os(1) and one O(2) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one Os(1) and one O(3) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one Os(1) and one O(4) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Os(2) and one O(5) atom. In the sixth C site, C(6) is bonded in a distorted linear geometry to one Os(2) and one O(6) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Os(2) and one O(7) atom. In the eighth C site, C(8) is bonded in a distorted linear geometry to one Os(3) and one O(8) atom. In the ninth C site, C(9) is bonded in a distorted linear geometry to one Os(3) and one O(9) atom. In the tenth C site, C(10) is bonded in a linear geometry to one Os(3) and one O(10) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(10) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BOs3(CO)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.690
_cell_length_b   9.491
_cell_length_c   13.116
_cell_angle_alpha   80.621
_cell_angle_beta   72.984
_cell_angle_gamma   73.582
_symmetry_Int_Tables_number   1
_cell_volume   874.784
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.681  0.747  0.345  1.0
  B  B1  1  0.319  0.253  0.655  1.0
  Os  Os2  1  0.703  0.961  0.264  1.0
  Os  Os3  1  0.297  0.039  0.736  1.0
  Os  Os4  1  0.645  0.756  0.171  1.0
  Os  Os5  1  0.355  0.244  0.829  1.0
  Os  Os6  1  0.936  0.614  0.250  1.0
  Os  Os7  1  0.064  0.386  0.750  1.0
  C  C8  1  0.566  0.702  0.449  1.0
  C  C9  1  0.434  0.298  0.551  1.0
  C  C10  1  0.834  0.085  0.153  1.0
  C  C11  1  0.166  0.915  0.847  1.0
  C  C12  1  0.491  0.115  0.310  1.0
  C  C13  1  0.509  0.885  0.690  1.0
  C  C14  1  0.791  0.984  0.381  1.0
  C  C15  1  0.209  0.016  0.619  1.0
  C  C16  1  0.647  0.779  0.024  1.0
  C  C17  1  0.353  0.221  0.976  1.0
  C  C18  1  0.599  0.565  0.193  1.0
  C  C19  1  0.401  0.435  0.807  1.0
  C  C20  1  0.392  0.870  0.212  1.0
  C  C21  1  0.608  0.130  0.788  1.0
  C  C22  1  0.956  0.411  0.287  1.0
  C  C23  1  0.044  0.589  0.713  1.0
  C  C24  1  0.149  0.592  0.124  1.0
  C  C25  1  0.851  0.408  0.876  1.0
  C  C26  1  0.060  0.611  0.357  1.0
  C  C27  1  0.940  0.389  0.643  1.0
  O  O28  1  0.472  0.665  0.531  1.0
  O  O29  1  0.528  0.335  0.469  1.0
  O  O30  1  0.919  0.163  0.094  1.0
  O  O31  1  0.081  0.837  0.906  1.0
  O  O32  1  0.353  0.205  0.338  1.0
  O  O33  1  0.647  0.795  0.662  1.0
  O  O34  1  0.838  0.995  0.455  1.0
  O  O35  1  0.162  0.005  0.545  1.0
  O  O36  1  0.647  0.794  0.933  1.0
  O  O37  1  0.353  0.206  0.067  1.0
  O  O38  1  0.552  0.455  0.217  1.0
  O  O39  1  0.448  0.545  0.783  1.0
  O  O40  1  0.233  0.925  0.248  1.0
  O  O41  1  0.767  0.075  0.752  1.0
  O  O42  1  0.955  0.287  0.308  1.0
  O  O43  1  0.045  0.713  0.692  1.0
  O  O44  1  0.286  0.580  0.056  1.0
  O  O45  1  0.714  0.420  0.944  1.0
  O  O46  1  0.131  0.609  0.424  1.0
  O  O47  1  0.869  0.391  0.576  1.0
[/CIF]
.