The structure described by K(Mo2O3)4 crystallizes in the monoclinic P2 space group. K(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. There are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(2), one O(3), and two equivalent O(6) atoms to form MoO4 tetrahedra that share corners with two equivalent Mo(3)O5 square pyramids, corners with four equivalent Mo(4)O5 square pyramids, and corners with two equivalent Mo(1)O4 tetrahedra. In the second Mo site, Mo(2) is bonded to one O(1), one O(4), and two equivalent O(5) atoms to form MoO4 tetrahedra that share corners with two equivalent Mo(4)O5 square pyramids, corners with four equivalent Mo(3)O5 square pyramids, and corners with two equivalent Mo(2)O4 tetrahedra. In the third Mo site, Mo(3) is bonded to one O(6), two equivalent O(1), and two equivalent O(4) atoms to form MoO5 square pyramids that share corners with two equivalent Mo(1)O4 tetrahedra, corners with four equivalent Mo(2)O4 tetrahedra, and edges with two equivalent Mo(3)O5 square pyramids. In the fourth Mo site, Mo(4) is bonded to one O(5), two equivalent O(2), and two equivalent O(3) atoms to form MoO5 square pyramids that share corners with two equivalent Mo(2)O4 tetrahedra, corners with four equivalent Mo(1)O4 tetrahedra, and edges with two equivalent Mo(4)O5 square pyramids. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to one Mo(2) and two equivalent Mo(3) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one K(1), one Mo(1), and two equivalent Mo(4) atoms. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Mo(1) and two equivalent Mo(4) atoms. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one K(1), one Mo(2), and two equivalent Mo(3) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one K(1), one Mo(4), and two equivalent Mo(2) atoms. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mo(3) and two equivalent Mo(1) atoms. is represented by the CIF file [CIF]
data_K(Mo2O3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.309
_cell_length_b   10.249
_cell_length_c   10.260
_cell_angle_alpha   89.730
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   347.928
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.099  0.500  0.500  1.0
  Mo  Mo1  1  0.504  0.336  0.866  1.0
  Mo  Mo2  1  0.504  0.664  0.134  1.0
  Mo  Mo3  1  0.503  0.159  0.361  1.0
  Mo  Mo4  1  0.503  0.841  0.639  1.0
  Mo  Mo5  1  0.001  0.117  0.627  1.0
  Mo  Mo6  1  0.001  0.883  0.373  1.0
  Mo  Mo7  1  0.000  0.394  0.135  1.0
  Mo  Mo8  1  0.000  0.606  0.865  1.0
  O  O9  1  0.501  0.016  0.712  1.0
  O  O10  1  0.501  0.984  0.288  1.0
  O  O11  1  0.500  0.493  0.229  1.0
  O  O12  1  0.500  0.507  0.771  1.0
  O  O13  1  0.500  0.707  0.948  1.0
  O  O14  1  0.500  0.293  0.052  1.0
  O  O15  1  0.501  0.774  0.456  1.0
  O  O16  1  0.501  0.226  0.544  1.0
  O  O17  1  0.002  0.737  0.700  1.0
  O  O18  1  0.002  0.263  0.300  1.0
  O  O19  1  0.002  0.750  0.213  1.0
  O  O20  1  0.002  0.250  0.787  1.0
[/CIF]
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The structure described by K(Mo2O3)4 crystallizes in the monoclinic P2 space group. K(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. There are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(2), one O(3), and two equivalent O(6) atoms to form MoO4 tetrahedra that share corners with two equivalent Mo(3)O5 square pyramids, corners with four equivalent Mo(4)O5 square pyramids, and corners with two equivalent Mo(1)O4 tetrahedra. In the second Mo site, Mo(2) is bonded to one O(1), one O(4), and two equivalent O(5) atoms to form MoO4 tetrahedra that share corners with two equivalent Mo(4)O5 square pyramids, corners with four equivalent Mo(3)O5 square pyramids, and corners with two equivalent Mo(2)O4 tetrahedra. In the third Mo site, Mo(3) is bonded to one O(6), two equivalent O(1), and two equivalent O(4) atoms to form MoO5 square pyramids that share corners with two equivalent Mo(1)O4 tetrahedra, corners with four equivalent Mo(2)O4 tetrahedra, and edges with two equivalent Mo(3)O5 square pyramids. In the fourth Mo site, Mo(4) is bonded to one O(5), two equivalent O(2), and two equivalent O(3) atoms to form MoO5 square pyramids that share corners with two equivalent Mo(2)O4 tetrahedra, corners with four equivalent Mo(1)O4 tetrahedra, and edges with two equivalent Mo(4)O5 square pyramids. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to one Mo(2) and two equivalent Mo(3) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one K(1), one Mo(1), and two equivalent Mo(4) atoms. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Mo(1) and two equivalent Mo(4) atoms. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one K(1), one Mo(2), and two equivalent Mo(3) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one K(1), one Mo(4), and two equivalent Mo(2) atoms. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mo(3) and two equivalent Mo(1) atoms. is represented by the CIF file [CIF]
data_K(Mo2O3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.309
_cell_length_b   10.249
_cell_length_c   10.260
_cell_angle_alpha   89.730
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   347.928
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.099  0.500  0.500  1.0
  Mo  Mo1  1  0.504  0.336  0.866  1.0
  Mo  Mo2  1  0.504  0.664  0.134  1.0
  Mo  Mo3  1  0.503  0.159  0.361  1.0
  Mo  Mo4  1  0.503  0.841  0.639  1.0
  Mo  Mo5  1  0.001  0.117  0.627  1.0
  Mo  Mo6  1  0.001  0.883  0.373  1.0
  Mo  Mo7  1  0.000  0.394  0.135  1.0
  Mo  Mo8  1  0.000  0.606  0.865  1.0
  O  O9  1  0.501  0.016  0.712  1.0
  O  O10  1  0.501  0.984  0.288  1.0
  O  O11  1  0.500  0.493  0.229  1.0
  O  O12  1  0.500  0.507  0.771  1.0
  O  O13  1  0.500  0.707  0.948  1.0
  O  O14  1  0.500  0.293  0.052  1.0
  O  O15  1  0.501  0.774  0.456  1.0
  O  O16  1  0.501  0.226  0.544  1.0
  O  O17  1  0.002  0.737  0.700  1.0
  O  O18  1  0.002  0.263  0.300  1.0
  O  O19  1  0.002  0.750  0.213  1.0
  O  O20  1  0.002  0.250  0.787  1.0
[/CIF]
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