The compound described by ReO2F3 is Indium-like structured and crystallizes in the orthorhombic Cmce space group. The structure is zero-dimensional and consists of four ReO2F3 clusters. Re(1,2) is bonded to two equivalent O(2), two equivalent F(2), and two equivalent F(3) atoms to form distorted corner-sharing ReO2F4 octahedra. The corner-sharing octahedral tilt angles are 14°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1,2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1,2) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Re(1,2) atom. In the second F site, F(2) is bonded in a linear geometry to two equivalent Re(1,2) atoms. In the third F site, F(3) is bonded in a single-bond geometry to one Re(1,2) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Re(1,2) atom. is represented by the CIF file [CIF]
data_ReO2F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.469
_cell_length_b   7.469
_cell_length_c   13.548
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   96.418
_symmetry_Int_Tables_number   1
_cell_volume   751.036
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.234  0.766  0.500  1.0
  Re  Re1  1  0.734  0.266  0.000  1.0
  Re  Re2  1  0.672  0.672  0.679  1.0
  Re  Re3  1  0.766  0.234  0.500  1.0
  Re  Re4  1  0.828  0.828  0.179  1.0
  Re  Re5  1  0.266  0.734  0.000  1.0
  Re  Re6  1  0.172  0.172  0.821  1.0
  Re  Re7  1  0.328  0.328  0.321  1.0
  O  O8  1  0.145  0.381  0.260  1.0
  O  O9  1  0.930  0.208  0.583  1.0
  O  O10  1  0.855  0.619  0.740  1.0
  O  O11  1  0.645  0.881  0.240  1.0
  O  O12  1  0.430  0.708  0.917  1.0
  O  O13  1  0.619  0.855  0.740  1.0
  O  O14  1  0.070  0.792  0.417  1.0
  O  O15  1  0.208  0.930  0.583  1.0
  O  O16  1  0.708  0.430  0.917  1.0
  O  O17  1  0.355  0.119  0.760  1.0
  O  O18  1  0.792  0.070  0.417  1.0
  O  O19  1  0.881  0.645  0.240  1.0
  O  O20  1  0.119  0.355  0.760  1.0
  O  O21  1  0.381  0.145  0.260  1.0
  O  O22  1  0.292  0.570  0.083  1.0
  O  O23  1  0.570  0.292  0.083  1.0
  F  F24  1  0.791  0.791  0.573  1.0
  F  F25  1  0.688  0.453  0.581  1.0
  F  F26  1  0.812  0.047  0.081  1.0
  F  F27  1  0.426  0.881  0.429  1.0
  F  F28  1  0.998  0.998  0.235  1.0
  F  F29  1  0.498  0.498  0.265  1.0
  F  F30  1  0.209  0.209  0.427  1.0
  F  F31  1  0.381  0.926  0.071  1.0
  F  F32  1  0.881  0.426  0.429  1.0
  F  F33  1  0.074  0.619  0.929  1.0
  F  F34  1  0.291  0.291  0.927  1.0
  F  F35  1  0.002  0.002  0.765  1.0
  F  F36  1  0.547  0.312  0.419  1.0
  F  F37  1  0.502  0.502  0.735  1.0
  F  F38  1  0.188  0.953  0.919  1.0
  F  F39  1  0.119  0.574  0.571  1.0
  F  F40  1  0.926  0.381  0.071  1.0
  F  F41  1  0.953  0.188  0.919  1.0
  F  F42  1  0.709  0.709  0.073  1.0
  F  F43  1  0.453  0.688  0.581  1.0
  F  F44  1  0.619  0.074  0.929  1.0
  F  F45  1  0.574  0.119  0.571  1.0
  F  F46  1  0.312  0.547  0.419  1.0
  F  F47  1  0.047  0.812  0.081  1.0
[/CIF]
.
The compound described by ReO2F3 is Indium-like structured and crystallizes in the orthorhombic Cmce space group. The structure is zero-dimensional and consists of four ReO2F3 clusters. Re(1,2) is bonded to two equivalent O(2), two equivalent F(2), and two equivalent F(3) atoms to form distorted corner-sharing ReO2F4 octahedra. The corner-sharing octahedral tilt angles are 14°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1,2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1,2) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Re(1,2) atom. In the second F site, F(2) is bonded in a linear geometry to two equivalent Re(1,2) atoms. In the third F site, F(3) is bonded in a single-bond geometry to one Re(1,2) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Re(1,2) atom. is represented by the CIF file [CIF]
data_ReO2F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.469
_cell_length_b   7.469
_cell_length_c   13.548
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   96.418
_symmetry_Int_Tables_number   1
_cell_volume   751.036
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.234  0.766  0.500  1.0
  Re  Re1  1  0.734  0.266  0.000  1.0
  Re  Re2  1  0.672  0.672  0.679  1.0
  Re  Re3  1  0.766  0.234  0.500  1.0
  Re  Re4  1  0.828  0.828  0.179  1.0
  Re  Re5  1  0.266  0.734  0.000  1.0
  Re  Re6  1  0.172  0.172  0.821  1.0
  Re  Re7  1  0.328  0.328  0.321  1.0
  O  O8  1  0.145  0.381  0.260  1.0
  O  O9  1  0.930  0.208  0.583  1.0
  O  O10  1  0.855  0.619  0.740  1.0
  O  O11  1  0.645  0.881  0.240  1.0
  O  O12  1  0.430  0.708  0.917  1.0
  O  O13  1  0.619  0.855  0.740  1.0
  O  O14  1  0.070  0.792  0.417  1.0
  O  O15  1  0.208  0.930  0.583  1.0
  O  O16  1  0.708  0.430  0.917  1.0
  O  O17  1  0.355  0.119  0.760  1.0
  O  O18  1  0.792  0.070  0.417  1.0
  O  O19  1  0.881  0.645  0.240  1.0
  O  O20  1  0.119  0.355  0.760  1.0
  O  O21  1  0.381  0.145  0.260  1.0
  O  O22  1  0.292  0.570  0.083  1.0
  O  O23  1  0.570  0.292  0.083  1.0
  F  F24  1  0.791  0.791  0.573  1.0
  F  F25  1  0.688  0.453  0.581  1.0
  F  F26  1  0.812  0.047  0.081  1.0
  F  F27  1  0.426  0.881  0.429  1.0
  F  F28  1  0.998  0.998  0.235  1.0
  F  F29  1  0.498  0.498  0.265  1.0
  F  F30  1  0.209  0.209  0.427  1.0
  F  F31  1  0.381  0.926  0.071  1.0
  F  F32  1  0.881  0.426  0.429  1.0
  F  F33  1  0.074  0.619  0.929  1.0
  F  F34  1  0.291  0.291  0.927  1.0
  F  F35  1  0.002  0.002  0.765  1.0
  F  F36  1  0.547  0.312  0.419  1.0
  F  F37  1  0.502  0.502  0.735  1.0
  F  F38  1  0.188  0.953  0.919  1.0
  F  F39  1  0.119  0.574  0.571  1.0
  F  F40  1  0.926  0.381  0.071  1.0
  F  F41  1  0.953  0.188  0.919  1.0
  F  F42  1  0.709  0.709  0.073  1.0
  F  F43  1  0.453  0.688  0.581  1.0
  F  F44  1  0.619  0.074  0.929  1.0
  F  F45  1  0.574  0.119  0.571  1.0
  F  F46  1  0.312  0.547  0.419  1.0
  F  F47  1  0.047  0.812  0.081  1.0
[/CIF]
.