The compound described by Na5Mn2P2(CO7)2 crystallizes in the monoclinic P2_1/m space group. There are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a distorted hexagonal planar geometry to one O(1), one O(2), one O(4), one O(5), and two equivalent O(7) atoms. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(4), one O(5), one O(8), and one O(9) atom. In the third Na site, Na(3) is bonded in a 7-coordinate geometry to one O(11), one O(12), one O(2), one O(3), one O(6), one O(7), and one O(8) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(12), one O(3), one O(5), one O(9), and two equivalent O(7) atoms to form distorted MnO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra and corners with three equivalent P(1)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to one O(10), one O(11), one O(4), one O(6), and two equivalent O(8) atoms to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(5) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(6) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(9), and two equivalent O(7) atoms to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra and corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-54°. In the second P site, P(2) is bonded to one O(11), one O(12), and two equivalent O(8) atoms to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra and corners with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-56°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), two equivalent Na(2), and one C(1) atom to form distorted ONa3C trigonal pyramids that share corners with two equivalent O(5)Na3MnC trigonal bipyramids, corners with three equivalent O(4)Na3MnC trigonal bipyramids,  a cornercorner with one O(2)Na3C trigonal pyramid, and  an edgeedge with one O(5)Na3MnC trigonal bipyramid. In the second O site, O(2) is bonded to one Na(1), two equivalent Na(3), and one C(2) atom to form distorted ONa3C trigonal pyramids that share  a cornercorner with one O(5)Na3MnC trigonal bipyramid,  a cornercorner with one O(1)Na3C trigonal pyramid, and  an edgeedge with one O(4)Na3MnC trigonal bipyramid. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Na(3), one Mn(1), and one C(1) atom. In the fourth O site, O(4) is bonded to one Na(1), two equivalent Na(2), one Mn(2), and one C(2) atom to form distorted ONa3MnC trigonal bipyramids that share corners with three equivalent O(1)Na3C trigonal pyramids,  an edgeedge with one O(2)Na3C trigonal pyramid, and  a faceface with one O(5)Na3MnC trigonal bipyramid. In the fifth O site, O(5) is bonded to one Na(1), two equivalent Na(2), one Mn(1), and one C(1) atom to form distorted ONa3MnC trigonal bipyramids that share  a cornercorner with one O(2)Na3C trigonal pyramid, corners with two equivalent O(1)Na3C trigonal pyramids,  an edgeedge with one O(1)Na3C trigonal pyramid, and  a faceface with one O(4)Na3MnC trigonal bipyramid. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Na(3), one Mn(2), and one C(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Na(1), one Na(3), one Mn(1), and one P(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one Mn(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to two equivalent Na(2), one Mn(1), and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Na(2), one Mn(2), and one P(1) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to two equivalent Na(3), one Mn(2), and one P(2) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to two equivalent Na(3), one Mn(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na5Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.033
_cell_length_b   6.604
_cell_length_c   10.557
_cell_angle_alpha   90.000
_cell_angle_beta   88.803
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   629.574
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.077  0.250  0.885  1.0
  Na  Na1  1  0.254  0.007  0.615  1.0
  Na  Na2  1  0.254  0.493  0.615  1.0
  Na  Na3  1  0.242  1.000  0.132  1.0
  Na  Na4  1  0.242  0.500  0.132  1.0
  Na  Na5  1  0.746  0.507  0.885  1.0
  Na  Na6  1  0.746  0.993  0.885  1.0
  Na  Na7  1  0.758  0.500  0.368  1.0
  Na  Na8  1  0.758  0.000  0.368  1.0
  Na  Na9  1  0.923  0.750  0.615  1.0
  Mn  Mn10  1  0.354  0.750  0.890  1.0
  Mn  Mn11  1  0.357  0.750  0.388  1.0
  Mn  Mn12  1  0.646  0.250  0.610  1.0
  Mn  Mn13  1  0.643  0.250  0.112  1.0
  P  P14  1  0.419  0.250  0.850  1.0
  P  P15  1  0.424  0.250  0.351  1.0
  P  P16  1  0.581  0.750  0.650  1.0
  P  P17  1  0.576  0.750  0.149  1.0
  C  C18  1  0.066  0.750  0.860  1.0
  C  C19  1  0.070  0.750  0.369  1.0
  C  C20  1  0.934  0.250  0.640  1.0
  C  C21  1  0.930  0.250  0.131  1.0
  O  O22  1  0.075  0.250  0.648  1.0
  O  O23  1  0.071  0.250  0.124  1.0
  O  O24  1  0.134  0.750  0.968  1.0
  O  O25  1  0.145  0.750  0.476  1.0
  O  O26  1  0.149  0.750  0.757  1.0
  O  O27  1  0.148  0.750  0.266  1.0
  O  O28  1  0.323  0.063  0.888  1.0
  O  O29  1  0.323  0.437  0.888  1.0
  O  O30  1  0.333  0.059  0.390  1.0
  O  O31  1  0.333  0.441  0.390  1.0
  O  O32  1  0.445  0.250  0.702  1.0
  O  O33  1  0.430  0.750  0.584  1.0
  O  O34  1  0.446  0.250  0.203  1.0
  O  O35  1  0.423  0.750  0.086  1.0
  O  O36  1  0.570  0.250  0.916  1.0
  O  O37  1  0.555  0.750  0.798  1.0
  O  O38  1  0.577  0.250  0.414  1.0
  O  O39  1  0.554  0.750  0.297  1.0
  O  O40  1  0.677  0.563  0.612  1.0
  O  O41  1  0.677  0.937  0.612  1.0
  O  O42  1  0.667  0.559  0.110  1.0
  O  O43  1  0.667  0.941  0.110  1.0
  O  O44  1  0.851  0.250  0.743  1.0
  O  O45  1  0.852  0.250  0.234  1.0
  O  O46  1  0.866  0.250  0.532  1.0
  O  O47  1  0.855  0.250  0.024  1.0
  O  O48  1  0.925  0.750  0.852  1.0
  O  O49  1  0.929  0.750  0.376  1.0
[/CIF]
.
The compound described by Na5Mn2P2(CO7)2 crystallizes in the monoclinic P2_1/m space group. There are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a distorted hexagonal planar geometry to one O(1), one O(2), one O(4), one O(5), and two equivalent O(7) atoms. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(4), one O(5), one O(8), and one O(9) atom. In the third Na site, Na(3) is bonded in a 7-coordinate geometry to one O(11), one O(12), one O(2), one O(3), one O(6), one O(7), and one O(8) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(12), one O(3), one O(5), one O(9), and two equivalent O(7) atoms to form distorted MnO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra and corners with three equivalent P(1)O4 tetrahedra. In the second Mn site, Mn(2) is bonded to one O(10), one O(11), one O(4), one O(6), and two equivalent O(8) atoms to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra and corners with three equivalent P(2)O4 tetrahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(5) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(6) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(9), and two equivalent O(7) atoms to form PO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra and corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-54°. In the second P site, P(2) is bonded to one O(11), one O(12), and two equivalent O(8) atoms to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra and corners with three equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-56°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), two equivalent Na(2), and one C(1) atom to form distorted ONa3C trigonal pyramids that share corners with two equivalent O(5)Na3MnC trigonal bipyramids, corners with three equivalent O(4)Na3MnC trigonal bipyramids,  a cornercorner with one O(2)Na3C trigonal pyramid, and  an edgeedge with one O(5)Na3MnC trigonal bipyramid. In the second O site, O(2) is bonded to one Na(1), two equivalent Na(3), and one C(2) atom to form distorted ONa3C trigonal pyramids that share  a cornercorner with one O(5)Na3MnC trigonal bipyramid,  a cornercorner with one O(1)Na3C trigonal pyramid, and  an edgeedge with one O(4)Na3MnC trigonal bipyramid. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Na(3), one Mn(1), and one C(1) atom. In the fourth O site, O(4) is bonded to one Na(1), two equivalent Na(2), one Mn(2), and one C(2) atom to form distorted ONa3MnC trigonal bipyramids that share corners with three equivalent O(1)Na3C trigonal pyramids,  an edgeedge with one O(2)Na3C trigonal pyramid, and  a faceface with one O(5)Na3MnC trigonal bipyramid. In the fifth O site, O(5) is bonded to one Na(1), two equivalent Na(2), one Mn(1), and one C(1) atom to form distorted ONa3MnC trigonal bipyramids that share  a cornercorner with one O(2)Na3C trigonal pyramid, corners with two equivalent O(1)Na3C trigonal pyramids,  an edgeedge with one O(1)Na3C trigonal pyramid, and  a faceface with one O(4)Na3MnC trigonal bipyramid. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Na(3), one Mn(2), and one C(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Na(1), one Na(3), one Mn(1), and one P(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one Mn(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to two equivalent Na(2), one Mn(1), and one P(1) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Na(2), one Mn(2), and one P(1) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to two equivalent Na(3), one Mn(2), and one P(2) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to two equivalent Na(3), one Mn(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na5Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.033
_cell_length_b   6.604
_cell_length_c   10.557
_cell_angle_alpha   90.000
_cell_angle_beta   88.803
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   629.574
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.077  0.250  0.885  1.0
  Na  Na1  1  0.254  0.007  0.615  1.0
  Na  Na2  1  0.254  0.493  0.615  1.0
  Na  Na3  1  0.242  1.000  0.132  1.0
  Na  Na4  1  0.242  0.500  0.132  1.0
  Na  Na5  1  0.746  0.507  0.885  1.0
  Na  Na6  1  0.746  0.993  0.885  1.0
  Na  Na7  1  0.758  0.500  0.368  1.0
  Na  Na8  1  0.758  0.000  0.368  1.0
  Na  Na9  1  0.923  0.750  0.615  1.0
  Mn  Mn10  1  0.354  0.750  0.890  1.0
  Mn  Mn11  1  0.357  0.750  0.388  1.0
  Mn  Mn12  1  0.646  0.250  0.610  1.0
  Mn  Mn13  1  0.643  0.250  0.112  1.0
  P  P14  1  0.419  0.250  0.850  1.0
  P  P15  1  0.424  0.250  0.351  1.0
  P  P16  1  0.581  0.750  0.650  1.0
  P  P17  1  0.576  0.750  0.149  1.0
  C  C18  1  0.066  0.750  0.860  1.0
  C  C19  1  0.070  0.750  0.369  1.0
  C  C20  1  0.934  0.250  0.640  1.0
  C  C21  1  0.930  0.250  0.131  1.0
  O  O22  1  0.075  0.250  0.648  1.0
  O  O23  1  0.071  0.250  0.124  1.0
  O  O24  1  0.134  0.750  0.968  1.0
  O  O25  1  0.145  0.750  0.476  1.0
  O  O26  1  0.149  0.750  0.757  1.0
  O  O27  1  0.148  0.750  0.266  1.0
  O  O28  1  0.323  0.063  0.888  1.0
  O  O29  1  0.323  0.437  0.888  1.0
  O  O30  1  0.333  0.059  0.390  1.0
  O  O31  1  0.333  0.441  0.390  1.0
  O  O32  1  0.445  0.250  0.702  1.0
  O  O33  1  0.430  0.750  0.584  1.0
  O  O34  1  0.446  0.250  0.203  1.0
  O  O35  1  0.423  0.750  0.086  1.0
  O  O36  1  0.570  0.250  0.916  1.0
  O  O37  1  0.555  0.750  0.798  1.0
  O  O38  1  0.577  0.250  0.414  1.0
  O  O39  1  0.554  0.750  0.297  1.0
  O  O40  1  0.677  0.563  0.612  1.0
  O  O41  1  0.677  0.937  0.612  1.0
  O  O42  1  0.667  0.559  0.110  1.0
  O  O43  1  0.667  0.941  0.110  1.0
  O  O44  1  0.851  0.250  0.743  1.0
  O  O45  1  0.852  0.250  0.234  1.0
  O  O46  1  0.866  0.250  0.532  1.0
  O  O47  1  0.855  0.250  0.024  1.0
  O  O48  1  0.925  0.750  0.852  1.0
  O  O49  1  0.929  0.750  0.376  1.0
[/CIF]
.