The compound described by UGeS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. U(1) is bonded in a 9-coordinate geometry to five equivalent Ge(1) and four equivalent S(1) atoms. Ge(1) is bonded to five equivalent U(1) atoms to form distorted GeU5 trigonal bipyramids that share corners with twelve equivalent S(1)U4 tetrahedra, corners with four equivalent Ge(1)U5 trigonal bipyramids, edges with four equivalent S(1)U4 tetrahedra, and edges with eight equivalent Ge(1)U5 trigonal bipyramids. S(1) is bonded to four equivalent U(1) atoms to form SU4 tetrahedra that share corners with four equivalent S(1)U4 tetrahedra, corners with twelve equivalent Ge(1)U5 trigonal bipyramids, edges with four equivalent S(1)U4 tetrahedra, and edges with four equivalent Ge(1)U5 trigonal bipyramids. is represented by the CIF card [CIF]
data_UGeS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.149
_cell_length_b   4.149
_cell_length_c   7.239
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   124.632
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.500  0.000  0.760  1.0
  U  U1  1  0.000  0.500  0.240  1.0
  Ge  Ge2  1  0.000  0.500  0.633  1.0
  Ge  Ge3  1  0.500  0.000  0.367  1.0
  S  S4  1  0.500  0.500  0.000  1.0
  S  S5  1  0.000  0.000  0.000  1.0
[/CIF]
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The compound described by UGeS is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. U(1) is bonded in a 9-coordinate geometry to five equivalent Ge(1) and four equivalent S(1) atoms. Ge(1) is bonded to five equivalent U(1) atoms to form distorted GeU5 trigonal bipyramids that share corners with twelve equivalent S(1)U4 tetrahedra, corners with four equivalent Ge(1)U5 trigonal bipyramids, edges with four equivalent S(1)U4 tetrahedra, and edges with eight equivalent Ge(1)U5 trigonal bipyramids. S(1) is bonded to four equivalent U(1) atoms to form SU4 tetrahedra that share corners with four equivalent S(1)U4 tetrahedra, corners with twelve equivalent Ge(1)U5 trigonal bipyramids, edges with four equivalent S(1)U4 tetrahedra, and edges with four equivalent Ge(1)U5 trigonal bipyramids. is represented by the CIF card [CIF]
data_UGeS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.149
_cell_length_b   4.149
_cell_length_c   7.239
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   124.632
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.500  0.000  0.760  1.0
  U  U1  1  0.000  0.500  0.240  1.0
  Ge  Ge2  1  0.000  0.500  0.633  1.0
  Ge  Ge3  1  0.500  0.000  0.367  1.0
  S  S4  1  0.500  0.500  0.000  1.0
  S  S5  1  0.000  0.000  0.000  1.0
[/CIF]
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