The material structure described by SbF6(I)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four hydriodic acid atoms and two SbF6 clusters. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_Sb(IF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.963
_cell_length_b   7.918
_cell_length_c   8.159
_cell_angle_alpha   77.332
_cell_angle_beta   79.885
_cell_angle_gamma   80.807
_symmetry_Int_Tables_number   1
_cell_volume   367.114
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.554  0.701  0.684  1.0
  Sb  Sb1  1  0.446  0.299  0.316  1.0
  I  I2  1  0.113  0.897  0.233  1.0
  I  I3  1  0.887  0.103  0.767  1.0
  I  I4  1  0.891  0.753  0.065  1.0
  I  I5  1  0.109  0.247  0.935  1.0
  F  F6  1  0.716  0.524  0.573  1.0
  F  F7  1  0.284  0.476  0.427  1.0
  F  F8  1  0.433  0.823  0.486  1.0
  F  F9  1  0.567  0.177  0.514  1.0
  F  F10  1  0.409  0.876  0.808  1.0
  F  F11  1  0.591  0.124  0.192  1.0
  F  F12  1  0.187  0.172  0.380  1.0
  F  F13  1  0.813  0.828  0.620  1.0
  F  F14  1  0.705  0.421  0.241  1.0
  F  F15  1  0.295  0.579  0.759  1.0
  F  F16  1  0.314  0.414  0.116  1.0
  F  F17  1  0.686  0.586  0.884  1.0
[/CIF]
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The material structure described by SbF6(I)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four hydriodic acid atoms and two SbF6 clusters. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_Sb(IF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.963
_cell_length_b   7.918
_cell_length_c   8.159
_cell_angle_alpha   77.332
_cell_angle_beta   79.885
_cell_angle_gamma   80.807
_symmetry_Int_Tables_number   1
_cell_volume   367.114
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.554  0.701  0.684  1.0
  Sb  Sb1  1  0.446  0.299  0.316  1.0
  I  I2  1  0.113  0.897  0.233  1.0
  I  I3  1  0.887  0.103  0.767  1.0
  I  I4  1  0.891  0.753  0.065  1.0
  I  I5  1  0.109  0.247  0.935  1.0
  F  F6  1  0.716  0.524  0.573  1.0
  F  F7  1  0.284  0.476  0.427  1.0
  F  F8  1  0.433  0.823  0.486  1.0
  F  F9  1  0.567  0.177  0.514  1.0
  F  F10  1  0.409  0.876  0.808  1.0
  F  F11  1  0.591  0.124  0.192  1.0
  F  F12  1  0.187  0.172  0.380  1.0
  F  F13  1  0.813  0.828  0.620  1.0
  F  F14  1  0.705  0.421  0.241  1.0
  F  F15  1  0.295  0.579  0.759  1.0
  F  F16  1  0.314  0.414  0.116  1.0
  F  F17  1  0.686  0.586  0.884  1.0
[/CIF]
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