The structure described by Ba2GaSbTe5 crystallizes in the orthorhombic Pnma space group. Ba(1) is bonded in a 8-coordinate geometry to two equivalent Te(1), two equivalent Te(2), two equivalent Te(3), and two equivalent Te(4) atoms. Ga(1) is bonded in a tetrahedral geometry to one Te(3), one Te(4), and two equivalent Te(1) atoms. Sb(1) is bonded in a 3-coordinate geometry to one Te(2) and four equivalent Te(1) atoms. There are four inequivalent Te sites. In the first Te site, Te(4) is bonded to four equivalent Ba(1) and one Ga(1) atom to form distorted TeBa4Ga square pyramids that share corners with four equivalent Te(2)Ba4Sb square pyramids, edges with two equivalent Te(4)Ba4Ga square pyramids, and edges with two equivalent Te(2)Ba4Sb square pyramids. In the second Te site, Te(1) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Ga(1), and two equivalent Sb(1) atoms. In the third Te site, Te(2) is bonded to four equivalent Ba(1) and one Sb(1) atom to form TeBa4Sb square pyramids that share corners with four equivalent Te(4)Ba4Ga square pyramids, corners with four equivalent Te(2)Ba4Sb square pyramids, and edges with two equivalent Te(4)Ba4Ga square pyramids. In the fourth Te site, Te(3) is bonded in a 5-coordinate geometry to four equivalent Ba(1) and one Ga(1) atom. is represented by the CIF card [CIF]
data_Ba2GaSbTe5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.785
_cell_length_b   9.994
_cell_length_c   13.674
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1337.234
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.007  0.122  0.826  1.0
  Ba  Ba1  1  0.493  0.378  0.326  1.0
  Ba  Ba2  1  0.507  0.878  0.174  1.0
  Ba  Ba3  1  0.993  0.622  0.674  1.0
  Ba  Ba4  1  0.993  0.878  0.174  1.0
  Ba  Ba5  1  0.507  0.622  0.674  1.0
  Ba  Ba6  1  0.493  0.122  0.826  1.0
  Ba  Ba7  1  0.007  0.378  0.326  1.0
  Ga  Ga8  1  0.250  0.335  0.600  1.0
  Ga  Ga9  1  0.250  0.165  0.100  1.0
  Ga  Ga10  1  0.750  0.665  0.400  1.0
  Ga  Ga11  1  0.750  0.835  0.900  1.0
  Sb  Sb12  1  0.250  0.983  0.529  1.0
  Sb  Sb13  1  0.250  0.517  0.029  1.0
  Sb  Sb14  1  0.750  0.017  0.471  1.0
  Sb  Sb15  1  0.750  0.483  0.971  1.0
  Te  Te16  1  0.035  0.177  0.561  1.0
  Te  Te17  1  0.465  0.323  0.061  1.0
  Te  Te18  1  0.535  0.823  0.439  1.0
  Te  Te19  1  0.965  0.677  0.939  1.0
  Te  Te20  1  0.965  0.823  0.439  1.0
  Te  Te21  1  0.535  0.677  0.939  1.0
  Te  Te22  1  0.465  0.177  0.561  1.0
  Te  Te23  1  0.035  0.323  0.061  1.0
  Te  Te24  1  0.250  0.881  0.724  1.0
  Te  Te25  1  0.250  0.619  0.224  1.0
  Te  Te26  1  0.750  0.119  0.276  1.0
  Te  Te27  1  0.750  0.381  0.776  1.0
  Te  Te28  1  0.250  0.397  0.788  1.0
  Te  Te29  1  0.250  0.103  0.288  1.0
  Te  Te30  1  0.750  0.603  0.212  1.0
  Te  Te31  1  0.750  0.897  0.712  1.0
  Te  Te32  1  0.250  0.952  0.990  1.0
  Te  Te33  1  0.250  0.548  0.490  1.0
  Te  Te34  1  0.750  0.048  0.010  1.0
  Te  Te35  1  0.750  0.452  0.510  1.0
[/CIF]
.
The structure described by Ba2GaSbTe5 crystallizes in the orthorhombic Pnma space group. Ba(1) is bonded in a 8-coordinate geometry to two equivalent Te(1), two equivalent Te(2), two equivalent Te(3), and two equivalent Te(4) atoms. Ga(1) is bonded in a tetrahedral geometry to one Te(3), one Te(4), and two equivalent Te(1) atoms. Sb(1) is bonded in a 3-coordinate geometry to one Te(2) and four equivalent Te(1) atoms. There are four inequivalent Te sites. In the first Te site, Te(4) is bonded to four equivalent Ba(1) and one Ga(1) atom to form distorted TeBa4Ga square pyramids that share corners with four equivalent Te(2)Ba4Sb square pyramids, edges with two equivalent Te(4)Ba4Ga square pyramids, and edges with two equivalent Te(2)Ba4Sb square pyramids. In the second Te site, Te(1) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Ga(1), and two equivalent Sb(1) atoms. In the third Te site, Te(2) is bonded to four equivalent Ba(1) and one Sb(1) atom to form TeBa4Sb square pyramids that share corners with four equivalent Te(4)Ba4Ga square pyramids, corners with four equivalent Te(2)Ba4Sb square pyramids, and edges with two equivalent Te(4)Ba4Ga square pyramids. In the fourth Te site, Te(3) is bonded in a 5-coordinate geometry to four equivalent Ba(1) and one Ga(1) atom. is represented by the CIF card [CIF]
data_Ba2GaSbTe5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.785
_cell_length_b   9.994
_cell_length_c   13.674
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1337.234
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.007  0.122  0.826  1.0
  Ba  Ba1  1  0.493  0.378  0.326  1.0
  Ba  Ba2  1  0.507  0.878  0.174  1.0
  Ba  Ba3  1  0.993  0.622  0.674  1.0
  Ba  Ba4  1  0.993  0.878  0.174  1.0
  Ba  Ba5  1  0.507  0.622  0.674  1.0
  Ba  Ba6  1  0.493  0.122  0.826  1.0
  Ba  Ba7  1  0.007  0.378  0.326  1.0
  Ga  Ga8  1  0.250  0.335  0.600  1.0
  Ga  Ga9  1  0.250  0.165  0.100  1.0
  Ga  Ga10  1  0.750  0.665  0.400  1.0
  Ga  Ga11  1  0.750  0.835  0.900  1.0
  Sb  Sb12  1  0.250  0.983  0.529  1.0
  Sb  Sb13  1  0.250  0.517  0.029  1.0
  Sb  Sb14  1  0.750  0.017  0.471  1.0
  Sb  Sb15  1  0.750  0.483  0.971  1.0
  Te  Te16  1  0.035  0.177  0.561  1.0
  Te  Te17  1  0.465  0.323  0.061  1.0
  Te  Te18  1  0.535  0.823  0.439  1.0
  Te  Te19  1  0.965  0.677  0.939  1.0
  Te  Te20  1  0.965  0.823  0.439  1.0
  Te  Te21  1  0.535  0.677  0.939  1.0
  Te  Te22  1  0.465  0.177  0.561  1.0
  Te  Te23  1  0.035  0.323  0.061  1.0
  Te  Te24  1  0.250  0.881  0.724  1.0
  Te  Te25  1  0.250  0.619  0.224  1.0
  Te  Te26  1  0.750  0.119  0.276  1.0
  Te  Te27  1  0.750  0.381  0.776  1.0
  Te  Te28  1  0.250  0.397  0.788  1.0
  Te  Te29  1  0.250  0.103  0.288  1.0
  Te  Te30  1  0.750  0.603  0.212  1.0
  Te  Te31  1  0.750  0.897  0.712  1.0
  Te  Te32  1  0.250  0.952  0.990  1.0
  Te  Te33  1  0.250  0.548  0.490  1.0
  Te  Te34  1  0.750  0.048  0.010  1.0
  Te  Te35  1  0.750  0.452  0.510  1.0
[/CIF]
.