The structure described by YCo(WO4)2 is Hydrophilite-derived structured and crystallizes in the monoclinic P2 space group. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms to form distorted YO6 octahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent W(2)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-61°. In the second Y site, Y(2) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(8) atoms to form YO6 octahedra that share corners with four equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-57°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(3), one O(4), one O(6), one O(7), and one O(8) atom to form WO6 octahedra that share corners with two equivalent Y(1)O6 octahedra, corners with two equivalent Y(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, and edges with two equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. In the second W site, W(2) is bonded to one O(2), one O(3), one O(4), one O(5), one O(7), and one O(8) atom to form distorted WO6 octahedra that share corners with two equivalent Y(1)O6 octahedra, corners with two equivalent Y(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-61°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent W(2)O6 octahedra, and edges with two equivalent Y(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-57°. In the second Co site, Co(2) is bonded in a 4-coordinate geometry to two equivalent O(2) and two equivalent O(3) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one Co(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Y(2), one W(2), and one Co(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1), one W(2), and one Co(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one W(2), and one Co(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Y(1), one W(2), and one Co(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Y(2) and one W(1) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Y(1), one W(1), and one W(2) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Y(2), one W(1), and one W(2) atom. is represented by the CIF card [CIF]
data_YCo(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.899
_cell_length_b   5.190
_cell_length_c   9.955
_cell_angle_alpha   86.551
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   304.231
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.329  0.000  0.000  1.0
  Y  Y1  1  0.652  0.500  0.500  1.0
  Co  Co2  1  0.674  0.500  0.000  1.0
  Co  Co3  1  0.270  0.000  0.500  1.0
  W  W4  1  0.839  0.001  0.242  1.0
  W  W5  1  0.839  0.999  0.758  1.0
  W  W6  1  0.170  0.504  0.252  1.0
  W  W7  1  0.170  0.496  0.748  1.0
  O  O8  1  0.651  0.843  0.889  1.0
  O  O9  1  0.651  0.157  0.111  1.0
  O  O10  1  0.359  0.673  0.609  1.0
  O  O11  1  0.359  0.327  0.391  1.0
  O  O12  1  0.087  0.804  0.361  1.0
  O  O13  1  0.087  0.196  0.639  1.0
  O  O14  1  0.909  0.700  0.139  1.0
  O  O15  1  0.909  0.300  0.861  1.0
  O  O16  1  0.390  0.377  0.873  1.0
  O  O17  1  0.390  0.623  0.127  1.0
  O  O18  1  0.625  0.141  0.641  1.0
  O  O19  1  0.625  0.859  0.359  1.0
  O  O20  1  0.120  0.827  0.847  1.0
  O  O21  1  0.888  0.692  0.654  1.0
  O  O22  1  0.120  0.173  0.153  1.0
  O  O23  1  0.888  0.308  0.346  1.0
[/CIF]
.
The structure described by YCo(WO4)2 is Hydrophilite-derived structured and crystallizes in the monoclinic P2 space group. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms to form distorted YO6 octahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent W(2)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-61°. In the second Y site, Y(2) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(8) atoms to form YO6 octahedra that share corners with four equivalent W(1)O6 octahedra and corners with four equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-57°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(3), one O(4), one O(6), one O(7), and one O(8) atom to form WO6 octahedra that share corners with two equivalent Y(1)O6 octahedra, corners with two equivalent Y(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, and edges with two equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. In the second W site, W(2) is bonded to one O(2), one O(3), one O(4), one O(5), one O(7), and one O(8) atom to form distorted WO6 octahedra that share corners with two equivalent Y(1)O6 octahedra, corners with two equivalent Y(2)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-61°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms to form CoO6 octahedra that share corners with four equivalent W(1)O6 octahedra, corners with four equivalent W(2)O6 octahedra, and edges with two equivalent Y(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-57°. In the second Co site, Co(2) is bonded in a 4-coordinate geometry to two equivalent O(2) and two equivalent O(3) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one Co(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Y(2), one W(2), and one Co(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1), one W(2), and one Co(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one W(2), and one Co(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Y(1), one W(2), and one Co(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Y(2) and one W(1) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Y(1), one W(1), and one W(2) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Y(2), one W(1), and one W(2) atom. is represented by the CIF card [CIF]
data_YCo(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.899
_cell_length_b   5.190
_cell_length_c   9.955
_cell_angle_alpha   86.551
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   304.231
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.329  0.000  0.000  1.0
  Y  Y1  1  0.652  0.500  0.500  1.0
  Co  Co2  1  0.674  0.500  0.000  1.0
  Co  Co3  1  0.270  0.000  0.500  1.0
  W  W4  1  0.839  0.001  0.242  1.0
  W  W5  1  0.839  0.999  0.758  1.0
  W  W6  1  0.170  0.504  0.252  1.0
  W  W7  1  0.170  0.496  0.748  1.0
  O  O8  1  0.651  0.843  0.889  1.0
  O  O9  1  0.651  0.157  0.111  1.0
  O  O10  1  0.359  0.673  0.609  1.0
  O  O11  1  0.359  0.327  0.391  1.0
  O  O12  1  0.087  0.804  0.361  1.0
  O  O13  1  0.087  0.196  0.639  1.0
  O  O14  1  0.909  0.700  0.139  1.0
  O  O15  1  0.909  0.300  0.861  1.0
  O  O16  1  0.390  0.377  0.873  1.0
  O  O17  1  0.390  0.623  0.127  1.0
  O  O18  1  0.625  0.141  0.641  1.0
  O  O19  1  0.625  0.859  0.359  1.0
  O  O20  1  0.120  0.827  0.847  1.0
  O  O21  1  0.888  0.692  0.654  1.0
  O  O22  1  0.120  0.173  0.153  1.0
  O  O23  1  0.888  0.308  0.346  1.0
[/CIF]
.