The material structure described by NiV crystallizes in the trigonal R-3m space group. V(1) is bonded to six equivalent V(1) and six equivalent Ni(1) atoms to form VV6Ni6 cuboctahedra that share corners with twelve equivalent V(1)V6Ni6 cuboctahedra, edges with twelve equivalent V(1)V6Ni6 cuboctahedra, edges with twelve equivalent Ni(1)V6Ni6 cuboctahedra, faces with six equivalent V(1)V6Ni6 cuboctahedra, and faces with twelve equivalent Ni(1)V6Ni6 cuboctahedra. Ni(1) is bonded to six equivalent V(1) and six equivalent Ni(1) atoms to form NiV6Ni6 cuboctahedra that share corners with twelve equivalent Ni(1)V6Ni6 cuboctahedra, edges with twelve equivalent V(1)V6Ni6 cuboctahedra, edges with twelve equivalent Ni(1)V6Ni6 cuboctahedra, faces with six equivalent Ni(1)V6Ni6 cuboctahedra, and faces with twelve equivalent V(1)V6Ni6 cuboctahedra. is represented by the CIF file [CIF]
data_VNi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.497
_cell_length_b   4.497
_cell_length_c   4.497
_cell_angle_alpha   32.968
_cell_angle_beta   32.968
_cell_angle_gamma   32.968
_symmetry_Int_Tables_number   1
_cell_volume   23.963
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.500  1.0
  Ni  Ni1  1  0.000  0.000  0.000  1.0
[/CIF]
.
The material structure described by NiV crystallizes in the trigonal R-3m space group. V(1) is bonded to six equivalent V(1) and six equivalent Ni(1) atoms to form VV6Ni6 cuboctahedra that share corners with twelve equivalent V(1)V6Ni6 cuboctahedra, edges with twelve equivalent V(1)V6Ni6 cuboctahedra, edges with twelve equivalent Ni(1)V6Ni6 cuboctahedra, faces with six equivalent V(1)V6Ni6 cuboctahedra, and faces with twelve equivalent Ni(1)V6Ni6 cuboctahedra. Ni(1) is bonded to six equivalent V(1) and six equivalent Ni(1) atoms to form NiV6Ni6 cuboctahedra that share corners with twelve equivalent Ni(1)V6Ni6 cuboctahedra, edges with twelve equivalent V(1)V6Ni6 cuboctahedra, edges with twelve equivalent Ni(1)V6Ni6 cuboctahedra, faces with six equivalent Ni(1)V6Ni6 cuboctahedra, and faces with twelve equivalent V(1)V6Ni6 cuboctahedra. is represented by the CIF file [CIF]
data_VNi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.497
_cell_length_b   4.497
_cell_length_c   4.497
_cell_angle_alpha   32.968
_cell_angle_beta   32.968
_cell_angle_gamma   32.968
_symmetry_Int_Tables_number   1
_cell_volume   23.963
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.500  1.0
  Ni  Ni1  1  0.000  0.000  0.000  1.0
[/CIF]
.