The structure described by RhN5Cl(NO3)2 is Fluorite structured and crystallizes in the tetragonal I4 space group. The structure is zero-dimensional and consists of four nitric acid molecules and two RhN5Cl clusters. In each RhN5Cl cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(1), four equivalent N(2), and one Cl(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Rh(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Rh(1) atom. Cl(1) is bonded in a single-bond geometry to one Rh(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RhN7ClO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.470
_cell_length_b   7.470
_cell_length_c   7.470
_cell_angle_alpha   120.291
_cell_angle_beta   120.291
_cell_angle_gamma   89.497
_symmetry_Int_Tables_number   1
_cell_volume   293.433
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.818  0.818  0.000  1.0
  N  N1  1  0.658  0.658  0.000  1.0
  N  N2  1  0.706  0.064  0.019  1.0
  N  N3  1  0.046  0.687  0.981  1.0
  N  N4  1  0.687  0.706  0.641  1.0
  N  N5  1  0.064  0.046  0.359  1.0
  N  N6  1  0.620  0.120  0.500  1.0
  N  N7  1  0.120  0.620  0.500  1.0
  Cl  Cl8  1  0.060  0.060  0.000  1.0
  O  O9  1  0.738  0.238  0.500  1.0
  O  O10  1  0.238  0.738  0.500  1.0
  O  O11  1  0.495  0.931  0.303  1.0
  O  O12  1  0.628  0.192  0.697  1.0
  O  O13  1  0.192  0.495  0.564  1.0
  O  O14  1  0.931  0.628  0.436  1.0
[/CIF]
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The structure described by RhN5Cl(NO3)2 is Fluorite structured and crystallizes in the tetragonal I4 space group. The structure is zero-dimensional and consists of four nitric acid molecules and two RhN5Cl clusters. In each RhN5Cl cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(1), four equivalent N(2), and one Cl(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Rh(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Rh(1) atom. Cl(1) is bonded in a single-bond geometry to one Rh(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RhN7ClO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.470
_cell_length_b   7.470
_cell_length_c   7.470
_cell_angle_alpha   120.291
_cell_angle_beta   120.291
_cell_angle_gamma   89.497
_symmetry_Int_Tables_number   1
_cell_volume   293.433
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.818  0.818  0.000  1.0
  N  N1  1  0.658  0.658  0.000  1.0
  N  N2  1  0.706  0.064  0.019  1.0
  N  N3  1  0.046  0.687  0.981  1.0
  N  N4  1  0.687  0.706  0.641  1.0
  N  N5  1  0.064  0.046  0.359  1.0
  N  N6  1  0.620  0.120  0.500  1.0
  N  N7  1  0.120  0.620  0.500  1.0
  Cl  Cl8  1  0.060  0.060  0.000  1.0
  O  O9  1  0.738  0.238  0.500  1.0
  O  O10  1  0.238  0.738  0.500  1.0
  O  O11  1  0.495  0.931  0.303  1.0
  O  O12  1  0.628  0.192  0.697  1.0
  O  O13  1  0.192  0.495  0.564  1.0
  O  O14  1  0.931  0.628  0.436  1.0
[/CIF]
.