The structure described by NaClO3 crystallizes in the cubic P2_13 space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. O(1) is bonded in a distorted T-shaped geometry to two equivalent Na(1) and one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.240
_cell_length_b   7.240
_cell_length_c   7.240
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   379.502
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.082  0.418  0.582  1.0
  Na  Na1  1  0.418  0.582  0.082  1.0
  Na  Na2  1  0.918  0.918  0.918  1.0
  Na  Na3  1  0.582  0.082  0.418  1.0
  Cl  Cl4  1  0.266  0.766  0.734  1.0
  Cl  Cl5  1  0.766  0.734  0.266  1.0
  Cl  Cl6  1  0.734  0.266  0.766  1.0
  Cl  Cl7  1  0.234  0.234  0.234  1.0
  O  O8  1  0.250  0.839  0.929  1.0
  O  O9  1  0.429  0.250  0.161  1.0
  O  O10  1  0.750  0.339  0.571  1.0
  O  O11  1  0.929  0.250  0.839  1.0
  O  O12  1  0.071  0.750  0.661  1.0
  O  O13  1  0.839  0.929  0.250  1.0
  O  O14  1  0.339  0.571  0.750  1.0
  O  O15  1  0.750  0.661  0.071  1.0
  O  O16  1  0.661  0.071  0.750  1.0
  O  O17  1  0.571  0.750  0.339  1.0
  O  O18  1  0.161  0.429  0.250  1.0
  O  O19  1  0.250  0.161  0.429  1.0
[/CIF]
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The structure described by NaClO3 crystallizes in the cubic P2_13 space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. O(1) is bonded in a distorted T-shaped geometry to two equivalent Na(1) and one Cl(1) atom. Cl(1) is bonded in a trigonal non-coplanar geometry to three equivalent O(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.240
_cell_length_b   7.240
_cell_length_c   7.240
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   379.502
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.082  0.418  0.582  1.0
  Na  Na1  1  0.418  0.582  0.082  1.0
  Na  Na2  1  0.918  0.918  0.918  1.0
  Na  Na3  1  0.582  0.082  0.418  1.0
  Cl  Cl4  1  0.266  0.766  0.734  1.0
  Cl  Cl5  1  0.766  0.734  0.266  1.0
  Cl  Cl6  1  0.734  0.266  0.766  1.0
  Cl  Cl7  1  0.234  0.234  0.234  1.0
  O  O8  1  0.250  0.839  0.929  1.0
  O  O9  1  0.429  0.250  0.161  1.0
  O  O10  1  0.750  0.339  0.571  1.0
  O  O11  1  0.929  0.250  0.839  1.0
  O  O12  1  0.071  0.750  0.661  1.0
  O  O13  1  0.839  0.929  0.250  1.0
  O  O14  1  0.339  0.571  0.750  1.0
  O  O15  1  0.750  0.661  0.071  1.0
  O  O16  1  0.661  0.071  0.750  1.0
  O  O17  1  0.571  0.750  0.339  1.0
  O  O18  1  0.161  0.429  0.250  1.0
  O  O19  1  0.250  0.161  0.429  1.0
[/CIF]
.