The material described by MgWMn2FeO6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MgO6 octahedra that share corners with three equivalent W(1)O6 octahedra and  a faceface with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-43°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra and  a faceface with one Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-43°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. Fe(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom. In the fourth O site, O(4) is bonded to one Mg(1), one W(1), one Mn(1), and one Mn(2) atom to form a mixture of distorted corner and edge-sharing OMgMn2W trigonal pyramids. In the fifth O site, O(5) is bonded to one Mg(1), one W(1), one Mn(1), and one Mn(2) atom to form a mixture of distorted corner and edge-sharing OMgMn2W trigonal pyramids. In the sixth O site, O(6) is bonded to one Mg(1), one W(1), one Mn(1), and one Mn(2) atom to form a mixture of distorted corner and edge-sharing OMgMn2W trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgMn2FeWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.466
_cell_length_b   5.409
_cell_length_c   6.038
_cell_angle_alpha   63.359
_cell_angle_beta   65.104
_cell_angle_gamma   60.460
_symmetry_Int_Tables_number   1
_cell_volume   134.160
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.156  0.147  0.549  1.0
  Mn  Mn1  1  0.763  0.768  0.688  1.0
  Mn  Mn2  1  0.346  0.331  0.988  1.0
  Fe  Fe3  1  0.547  0.550  0.355  1.0
  W  W4  1  0.970  0.968  0.091  1.0
  O  O5  1  0.196  0.927  0.319  1.0
  O  O6  1  0.907  0.572  0.340  1.0
  O  O7  1  0.557  0.194  0.330  1.0
  O  O8  1  0.059  0.343  0.834  1.0
  O  O9  1  0.347  0.759  0.831  1.0
  O  O10  1  0.766  0.055  0.831  1.0
[/CIF]
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The material described by MgWMn2FeO6 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form MgO6 octahedra that share corners with three equivalent W(1)O6 octahedra and  a faceface with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-43°. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with three equivalent Mg(1)O6 octahedra and  a faceface with one Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-43°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. Fe(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Mg(1), one W(1), one Mn(1), one Mn(2), and one Fe(1) atom. In the fourth O site, O(4) is bonded to one Mg(1), one W(1), one Mn(1), and one Mn(2) atom to form a mixture of distorted corner and edge-sharing OMgMn2W trigonal pyramids. In the fifth O site, O(5) is bonded to one Mg(1), one W(1), one Mn(1), and one Mn(2) atom to form a mixture of distorted corner and edge-sharing OMgMn2W trigonal pyramids. In the sixth O site, O(6) is bonded to one Mg(1), one W(1), one Mn(1), and one Mn(2) atom to form a mixture of distorted corner and edge-sharing OMgMn2W trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgMn2FeWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.466
_cell_length_b   5.409
_cell_length_c   6.038
_cell_angle_alpha   63.359
_cell_angle_beta   65.104
_cell_angle_gamma   60.460
_symmetry_Int_Tables_number   1
_cell_volume   134.160
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.156  0.147  0.549  1.0
  Mn  Mn1  1  0.763  0.768  0.688  1.0
  Mn  Mn2  1  0.346  0.331  0.988  1.0
  Fe  Fe3  1  0.547  0.550  0.355  1.0
  W  W4  1  0.970  0.968  0.091  1.0
  O  O5  1  0.196  0.927  0.319  1.0
  O  O6  1  0.907  0.572  0.340  1.0
  O  O7  1  0.557  0.194  0.330  1.0
  O  O8  1  0.059  0.343  0.834  1.0
  O  O9  1  0.347  0.759  0.831  1.0
  O  O10  1  0.766  0.055  0.831  1.0
[/CIF]
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