The structure described by Os3Pb2N5Pb crystallizes in the triclinic P-1 space group. The structure consists of two 7439-92-1 atoms inside a Os3Pb2N5 framework. In the Os3Pb2N5 framework, there are three inequivalent Os sites. In the first Os site, Os(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(5), and two equivalent N(3) atoms. In the second Os site, Os(2) is bonded to one N(1), one N(2), and two equivalent N(4) atoms to form a mixture of distorted edge and corner-sharing OsN4 trigonal pyramids. In the third Os site, Os(3) is bonded to one N(1), one N(2), one N(4), and one N(5) atom to form a mixture of edge and corner-sharing OsN4 tetrahedra. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a distorted water-like geometry to one N(2) and one N(3) atom. In the second Pb site, Pb(3) is bonded in a single-bond geometry to one N(3) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Os(1), one Os(2), and one Os(3) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Os(2), one Os(3), and one Pb(1) atom. In the third N site, N(3) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Os(1), one Pb(1), and one Pb(3) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Os(3) and two equivalent Os(2) atoms. In the fifth N site, N(5) is bonded in a bent 150 degrees geometry to one Os(1) and one Os(3) atom. is represented by the CIF file [CIF]
data_Os3Pb3N5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.226
_cell_length_b   7.594
_cell_length_c   8.438
_cell_angle_alpha   101.223
_cell_angle_beta   97.537
_cell_angle_gamma   86.997
_symmetry_Int_Tables_number   1
_cell_volume   387.789
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.908  0.296  0.963  1.0
  Os  Os1  1  0.092  0.704  0.037  1.0
  Os  Os2  1  0.656  0.956  0.607  1.0
  Os  Os3  1  0.344  0.044  0.393  1.0
  Os  Os4  1  0.080  0.929  0.699  1.0
  Os  Os5  1  0.920  0.071  0.301  1.0
  Pb  Pb6  1  0.782  0.487  0.599  1.0
  Pb  Pb7  1  0.218  0.513  0.401  1.0
  Pb  Pb8  1  0.632  0.821  0.916  1.0
  Pb  Pb9  1  0.368  0.179  0.084  1.0
  Pb  Pb10  1  0.650  0.589  0.184  1.0
  Pb  Pb11  1  0.350  0.411  0.816  1.0
  N  N12  1  0.853  0.116  0.768  1.0
  N  N13  1  0.147  0.884  0.232  1.0
  N  N14  1  0.895  0.775  0.539  1.0
  N  N15  1  0.105  0.225  0.461  1.0
  N  N16  1  0.975  0.497  0.850  1.0
  N  N17  1  0.025  0.503  0.150  1.0
  N  N18  1  0.345  0.955  0.610  1.0
  N  N19  1  0.655  0.045  0.390  1.0
  N  N20  1  0.144  0.843  0.886  1.0
  N  N21  1  0.856  0.157  0.114  1.0
[/CIF]
.
The structure described by Os3Pb2N5Pb crystallizes in the triclinic P-1 space group. The structure consists of two 7439-92-1 atoms inside a Os3Pb2N5 framework. In the Os3Pb2N5 framework, there are three inequivalent Os sites. In the first Os site, Os(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(5), and two equivalent N(3) atoms. In the second Os site, Os(2) is bonded to one N(1), one N(2), and two equivalent N(4) atoms to form a mixture of distorted edge and corner-sharing OsN4 trigonal pyramids. In the third Os site, Os(3) is bonded to one N(1), one N(2), one N(4), and one N(5) atom to form a mixture of edge and corner-sharing OsN4 tetrahedra. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a distorted water-like geometry to one N(2) and one N(3) atom. In the second Pb site, Pb(3) is bonded in a single-bond geometry to one N(3) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Os(1), one Os(2), and one Os(3) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Os(2), one Os(3), and one Pb(1) atom. In the third N site, N(3) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Os(1), one Pb(1), and one Pb(3) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Os(3) and two equivalent Os(2) atoms. In the fifth N site, N(5) is bonded in a bent 150 degrees geometry to one Os(1) and one Os(3) atom. is represented by the CIF file [CIF]
data_Os3Pb3N5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.226
_cell_length_b   7.594
_cell_length_c   8.438
_cell_angle_alpha   101.223
_cell_angle_beta   97.537
_cell_angle_gamma   86.997
_symmetry_Int_Tables_number   1
_cell_volume   387.789
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.908  0.296  0.963  1.0
  Os  Os1  1  0.092  0.704  0.037  1.0
  Os  Os2  1  0.656  0.956  0.607  1.0
  Os  Os3  1  0.344  0.044  0.393  1.0
  Os  Os4  1  0.080  0.929  0.699  1.0
  Os  Os5  1  0.920  0.071  0.301  1.0
  Pb  Pb6  1  0.782  0.487  0.599  1.0
  Pb  Pb7  1  0.218  0.513  0.401  1.0
  Pb  Pb8  1  0.632  0.821  0.916  1.0
  Pb  Pb9  1  0.368  0.179  0.084  1.0
  Pb  Pb10  1  0.650  0.589  0.184  1.0
  Pb  Pb11  1  0.350  0.411  0.816  1.0
  N  N12  1  0.853  0.116  0.768  1.0
  N  N13  1  0.147  0.884  0.232  1.0
  N  N14  1  0.895  0.775  0.539  1.0
  N  N15  1  0.105  0.225  0.461  1.0
  N  N16  1  0.975  0.497  0.850  1.0
  N  N17  1  0.025  0.503  0.150  1.0
  N  N18  1  0.345  0.955  0.610  1.0
  N  N19  1  0.655  0.045  0.390  1.0
  N  N20  1  0.144  0.843  0.886  1.0
  N  N21  1  0.856  0.157  0.114  1.0
[/CIF]
.