The crystal structure described by Li4Ti3Mn3(WO8)2 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with three equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-67°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form LiO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with three equivalent W(1)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-65°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Ti(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with three equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-68°. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-51°. In the second Ti site, Ti(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. In the third Ti site, Ti(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form TiO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 48°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form WO6 octahedra that share corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-54°. In the second W site, W(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form WO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ti(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form distorted MnO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Ti(3)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form distorted MnO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Ti(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(3), one W(1), and one Mn(2) atom. In the second O site, O(2) is bonded to one Li(4), one Ti(1), one Ti(2), and one W(1) atom to form distorted OLiTi2W trigonal pyramids that share  a cornercorner with one O(7)LiTiMnW tetrahedra,  a cornercorner with one O(8)LiTiMnW tetrahedra, corners with two equivalent O(4)LiTi2Mn tetrahedra,  an edgeedge with one O(7)LiTiMnW tetrahedra,  an edgeedge with one O(8)LiTiMnW tetrahedra, and  an edgeedge with one O(3)LiTi2Mn trigonal pyramid. In the third O site, O(3) is bonded to one Li(1), one Ti(1), one Ti(2), and one Mn(1) atom to form distorted OLiTi2Mn trigonal pyramids that share  a cornercorner with one O(15)LiMn2W tetrahedra, corners with three equivalent O(4)LiTi2Mn tetrahedra,  an edgeedge with one O(7)LiTiMnW tetrahedra,  an edgeedge with one O(8)LiTiMnW tetrahedra, and  an edgeedge with one O(2)LiTi2W trigonal pyramid. In the fourth O site, O(4) is bonded to one Li(3), one Ti(1), one Ti(2), and one Mn(1) atom to form OLiTi2Mn tetrahedra that share corners with two equivalent O(7)LiTiMnW tetrahedra, corners with two equivalent O(8)LiTiMnW tetrahedra, corners with two equivalent O(2)LiTi2W trigonal pyramids, and corners with three equivalent O(3)LiTi2Mn trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Ti(3), one Mn(2), and one Mn(3) atom to form corner-sharing OLiTiMn2 tetrahedra. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(3), one W(1), and one Mn(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one Ti(1), one W(1), and one Mn(1) atom to form distorted OLiTiMnW tetrahedra that share  a cornercorner with one O(8)LiTiMnW tetrahedra, corners with two equivalent O(4)LiTi2Mn tetrahedra,  a cornercorner with one O(2)LiTi2W trigonal pyramid,  an edgeedge with one O(8)LiTiMnW tetrahedra,  an edgeedge with one O(3)LiTi2Mn trigonal pyramid, and  an edgeedge with one O(2)LiTi2W trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(4), one Ti(2), one W(1), and one Mn(1) atom to form distorted OLiTiMnW tetrahedra that share  a cornercorner with one O(7)LiTiMnW tetrahedra, corners with two equivalent O(4)LiTi2Mn tetrahedra,  a cornercorner with one O(2)LiTi2W trigonal pyramid,  an edgeedge with one O(7)LiTiMnW tetrahedra,  an edgeedge with one O(3)LiTi2Mn trigonal pyramid, and  an edgeedge with one O(2)LiTi2W trigonal pyramid. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(1), one Ti(2), and one W(2) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one W(1), one Mn(2), and one Mn(3) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Ti(3), one W(2), and one Mn(2) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Ti(3), one W(2), and one Mn(3) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one Ti(3), one Mn(2), and one Mn(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(1), one W(2), and one Mn(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one W(2), one Mn(2), and one Mn(3) atom to form distorted OLiMn2W tetrahedra that share corners with two equivalent O(5)LiTiMn2 tetrahedra and  a cornercorner with one O(3)LiTi2Mn trigonal pyramid. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(2), one W(2), and one Mn(1) atom. is represented by the CIF file [CIF]
data_Li4Ti3Mn3(WO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.151
_cell_length_b   6.041
_cell_length_c   9.869
_cell_angle_alpha   90.237
_cell_angle_beta   91.547
_cell_angle_gamma   119.710
_symmetry_Int_Tables_number   1
_cell_volume   318.345
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.313  0.658  0.905  1.0
  Li  Li1  1  0.003  0.001  0.984  1.0
  Li  Li2  1  0.021  0.010  0.493  1.0
  Li  Li3  1  0.651  0.328  0.409  1.0
  Ti  Ti4  1  0.192  0.852  0.215  1.0
  Ti  Ti5  1  0.169  0.341  0.217  1.0
  Ti  Ti6  1  0.345  0.190  0.723  1.0
  Mn  Mn7  1  0.665  0.825  0.208  1.0
  Mn  Mn8  1  0.846  0.660  0.705  1.0
  Mn  Mn9  1  0.832  0.170  0.708  1.0
  W  W10  1  0.341  0.671  0.489  1.0
  W  W11  1  0.681  0.340  0.985  1.0
  O  O12  1  0.181  0.835  0.589  1.0
  O  O13  1  0.047  0.521  0.340  1.0
  O  O14  1  0.301  0.651  0.110  1.0
  O  O15  1  0.020  0.007  0.304  1.0
  O  O16  1  0.024  0.010  0.799  1.0
  O  O17  1  0.188  0.347  0.596  1.0
  O  O18  1  0.459  0.963  0.341  1.0
  O  O19  1  0.454  0.495  0.340  1.0
  O  O20  1  0.332  0.163  0.107  1.0
  O  O21  1  0.664  0.830  0.569  1.0
  O  O22  1  0.498  0.468  0.854  1.0
  O  O23  1  0.496  0.041  0.860  1.0
  O  O24  1  0.623  0.308  0.608  1.0
  O  O25  1  0.846  0.658  0.093  1.0
  O  O26  1  0.954  0.475  0.857  1.0
  O  O27  1  0.853  0.182  0.097  1.0
[/CIF]
.
The crystal structure described by Li4Ti3Mn3(WO8)2 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with three equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-67°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form LiO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with three equivalent W(1)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-65°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Ti(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with three equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-68°. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-51°. In the second Ti site, Ti(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form TiO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. In the third Ti site, Ti(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form TiO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 48°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form WO6 octahedra that share corners with two equivalent Ti(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-54°. In the second W site, W(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form WO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ti(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent W(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one W(1)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form distorted MnO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Ti(3)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form distorted MnO6 octahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one W(2)O6 octahedra, edges with two equivalent Ti(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(3), one W(1), and one Mn(2) atom. In the second O site, O(2) is bonded to one Li(4), one Ti(1), one Ti(2), and one W(1) atom to form distorted OLiTi2W trigonal pyramids that share  a cornercorner with one O(7)LiTiMnW tetrahedra,  a cornercorner with one O(8)LiTiMnW tetrahedra, corners with two equivalent O(4)LiTi2Mn tetrahedra,  an edgeedge with one O(7)LiTiMnW tetrahedra,  an edgeedge with one O(8)LiTiMnW tetrahedra, and  an edgeedge with one O(3)LiTi2Mn trigonal pyramid. In the third O site, O(3) is bonded to one Li(1), one Ti(1), one Ti(2), and one Mn(1) atom to form distorted OLiTi2Mn trigonal pyramids that share  a cornercorner with one O(15)LiMn2W tetrahedra, corners with three equivalent O(4)LiTi2Mn tetrahedra,  an edgeedge with one O(7)LiTiMnW tetrahedra,  an edgeedge with one O(8)LiTiMnW tetrahedra, and  an edgeedge with one O(2)LiTi2W trigonal pyramid. In the fourth O site, O(4) is bonded to one Li(3), one Ti(1), one Ti(2), and one Mn(1) atom to form OLiTi2Mn tetrahedra that share corners with two equivalent O(7)LiTiMnW tetrahedra, corners with two equivalent O(8)LiTiMnW tetrahedra, corners with two equivalent O(2)LiTi2W trigonal pyramids, and corners with three equivalent O(3)LiTi2Mn trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Ti(3), one Mn(2), and one Mn(3) atom to form corner-sharing OLiTiMn2 tetrahedra. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(3), one W(1), and one Mn(3) atom. In the seventh O site, O(7) is bonded to one Li(4), one Ti(1), one W(1), and one Mn(1) atom to form distorted OLiTiMnW tetrahedra that share  a cornercorner with one O(8)LiTiMnW tetrahedra, corners with two equivalent O(4)LiTi2Mn tetrahedra,  a cornercorner with one O(2)LiTi2W trigonal pyramid,  an edgeedge with one O(8)LiTiMnW tetrahedra,  an edgeedge with one O(3)LiTi2Mn trigonal pyramid, and  an edgeedge with one O(2)LiTi2W trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(4), one Ti(2), one W(1), and one Mn(1) atom to form distorted OLiTiMnW tetrahedra that share  a cornercorner with one O(7)LiTiMnW tetrahedra, corners with two equivalent O(4)LiTi2Mn tetrahedra,  a cornercorner with one O(2)LiTi2W trigonal pyramid,  an edgeedge with one O(7)LiTiMnW tetrahedra,  an edgeedge with one O(3)LiTi2Mn trigonal pyramid, and  an edgeedge with one O(2)LiTi2W trigonal pyramid. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(1), one Ti(2), and one W(2) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one W(1), one Mn(2), and one Mn(3) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Ti(3), one W(2), and one Mn(2) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Ti(3), one W(2), and one Mn(3) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one Ti(3), one Mn(2), and one Mn(3) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(1), one W(2), and one Mn(1) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one W(2), one Mn(2), and one Mn(3) atom to form distorted OLiMn2W tetrahedra that share corners with two equivalent O(5)LiTiMn2 tetrahedra and  a cornercorner with one O(3)LiTi2Mn trigonal pyramid. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(2), one W(2), and one Mn(1) atom. is represented by the CIF file [CIF]
data_Li4Ti3Mn3(WO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.151
_cell_length_b   6.041
_cell_length_c   9.869
_cell_angle_alpha   90.237
_cell_angle_beta   91.547
_cell_angle_gamma   119.710
_symmetry_Int_Tables_number   1
_cell_volume   318.345
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.313  0.658  0.905  1.0
  Li  Li1  1  0.003  0.001  0.984  1.0
  Li  Li2  1  0.021  0.010  0.493  1.0
  Li  Li3  1  0.651  0.328  0.409  1.0
  Ti  Ti4  1  0.192  0.852  0.215  1.0
  Ti  Ti5  1  0.169  0.341  0.217  1.0
  Ti  Ti6  1  0.345  0.190  0.723  1.0
  Mn  Mn7  1  0.665  0.825  0.208  1.0
  Mn  Mn8  1  0.846  0.660  0.705  1.0
  Mn  Mn9  1  0.832  0.170  0.708  1.0
  W  W10  1  0.341  0.671  0.489  1.0
  W  W11  1  0.681  0.340  0.985  1.0
  O  O12  1  0.181  0.835  0.589  1.0
  O  O13  1  0.047  0.521  0.340  1.0
  O  O14  1  0.301  0.651  0.110  1.0
  O  O15  1  0.020  0.007  0.304  1.0
  O  O16  1  0.024  0.010  0.799  1.0
  O  O17  1  0.188  0.347  0.596  1.0
  O  O18  1  0.459  0.963  0.341  1.0
  O  O19  1  0.454  0.495  0.340  1.0
  O  O20  1  0.332  0.163  0.107  1.0
  O  O21  1  0.664  0.830  0.569  1.0
  O  O22  1  0.498  0.468  0.854  1.0
  O  O23  1  0.496  0.041  0.860  1.0
  O  O24  1  0.623  0.308  0.608  1.0
  O  O25  1  0.846  0.658  0.093  1.0
  O  O26  1  0.954  0.475  0.857  1.0
  O  O27  1  0.853  0.182  0.097  1.0
[/CIF]
.