The structure described by KTbRuC6(N3O2)2 crystallizes in the orthorhombic Cmcm space group. K(1) is bonded in a 12-coordinate geometry to two equivalent C(1), four equivalent C(2), two equivalent N(1), and four equivalent N(2) atoms. Tb(1) is bonded in a 6-coordinate geometry to two equivalent N(1), four equivalent N(2), and two equivalent O(1) atoms. Ru(1) is bonded in an octahedral geometry to two equivalent C(1) and four equivalent C(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one K(1), one Ru(1), and one N(1) atom. In the second C site, C(2) is bonded in a 2-coordinate geometry to one K(1), one Ru(1), and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one K(1), one Tb(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted linear geometry to one K(1), one Tb(1), and one C(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in an L-shaped geometry to two equivalent O(1) atoms. In the second O site, O(1) is bonded in a 3-coordinate geometry to one Tb(1) and two equivalent O(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_KTbRuC6(N3O2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.563
_cell_length_b   7.563
_cell_length_c   14.282
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   122.678
_symmetry_Int_Tables_number   1
_cell_volume   687.581
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.519  0.481  0.250  1.0
  K  K1  1  0.481  0.519  0.750  1.0
  Tb  Tb2  1  0.831  0.169  0.250  1.0
  Tb  Tb3  1  0.169  0.831  0.750  1.0
  Ru  Ru4  1  0.500  0.500  0.500  1.0
  Ru  Ru5  1  0.500  0.500  0.000  1.0
  C  C6  1  0.628  0.372  0.078  1.0
  C  C7  1  0.372  0.628  0.922  1.0
  C  C8  1  0.628  0.372  0.422  1.0
  C  C9  1  0.372  0.628  0.578  1.0
  C  C10  1  0.249  0.365  0.413  1.0
  C  C11  1  0.365  0.249  0.587  1.0
  C  C12  1  0.249  0.365  0.087  1.0
  C  C13  1  0.365  0.249  0.913  1.0
  C  C14  1  0.751  0.635  0.587  1.0
  C  C15  1  0.635  0.751  0.413  1.0
  C  C16  1  0.751  0.635  0.913  1.0
  C  C17  1  0.635  0.751  0.087  1.0
  N  N18  1  0.695  0.305  0.133  1.0
  N  N19  1  0.305  0.695  0.867  1.0
  N  N20  1  0.695  0.305  0.367  1.0
  N  N21  1  0.305  0.695  0.633  1.0
  N  N22  1  0.117  0.300  0.355  1.0
  N  N23  1  0.300  0.117  0.645  1.0
  N  N24  1  0.117  0.300  0.145  1.0
  N  N25  1  0.300  0.117  0.855  1.0
  N  N26  1  0.883  0.700  0.645  1.0
  N  N27  1  0.700  0.883  0.355  1.0
  N  N28  1  0.883  0.700  0.855  1.0
  N  N29  1  0.700  0.883  0.145  1.0
  O  O30  1  0.349  0.933  0.250  1.0
  O  O31  1  0.933  0.349  0.750  1.0
  O  O32  1  0.651  0.067  0.750  1.0
  O  O33  1  0.067  0.651  0.250  1.0
  O  O34  1  0.183  0.817  0.322  1.0
  O  O35  1  0.817  0.183  0.678  1.0
  O  O36  1  0.183  0.817  0.178  1.0
  O  O37  1  0.817  0.183  0.822  1.0
[/CIF]
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The structure described by KTbRuC6(N3O2)2 crystallizes in the orthorhombic Cmcm space group. K(1) is bonded in a 12-coordinate geometry to two equivalent C(1), four equivalent C(2), two equivalent N(1), and four equivalent N(2) atoms. Tb(1) is bonded in a 6-coordinate geometry to two equivalent N(1), four equivalent N(2), and two equivalent O(1) atoms. Ru(1) is bonded in an octahedral geometry to two equivalent C(1) and four equivalent C(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one K(1), one Ru(1), and one N(1) atom. In the second C site, C(2) is bonded in a 2-coordinate geometry to one K(1), one Ru(1), and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one K(1), one Tb(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted linear geometry to one K(1), one Tb(1), and one C(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in an L-shaped geometry to two equivalent O(1) atoms. In the second O site, O(1) is bonded in a 3-coordinate geometry to one Tb(1) and two equivalent O(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_KTbRuC6(N3O2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.563
_cell_length_b   7.563
_cell_length_c   14.282
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   122.678
_symmetry_Int_Tables_number   1
_cell_volume   687.581
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.519  0.481  0.250  1.0
  K  K1  1  0.481  0.519  0.750  1.0
  Tb  Tb2  1  0.831  0.169  0.250  1.0
  Tb  Tb3  1  0.169  0.831  0.750  1.0
  Ru  Ru4  1  0.500  0.500  0.500  1.0
  Ru  Ru5  1  0.500  0.500  0.000  1.0
  C  C6  1  0.628  0.372  0.078  1.0
  C  C7  1  0.372  0.628  0.922  1.0
  C  C8  1  0.628  0.372  0.422  1.0
  C  C9  1  0.372  0.628  0.578  1.0
  C  C10  1  0.249  0.365  0.413  1.0
  C  C11  1  0.365  0.249  0.587  1.0
  C  C12  1  0.249  0.365  0.087  1.0
  C  C13  1  0.365  0.249  0.913  1.0
  C  C14  1  0.751  0.635  0.587  1.0
  C  C15  1  0.635  0.751  0.413  1.0
  C  C16  1  0.751  0.635  0.913  1.0
  C  C17  1  0.635  0.751  0.087  1.0
  N  N18  1  0.695  0.305  0.133  1.0
  N  N19  1  0.305  0.695  0.867  1.0
  N  N20  1  0.695  0.305  0.367  1.0
  N  N21  1  0.305  0.695  0.633  1.0
  N  N22  1  0.117  0.300  0.355  1.0
  N  N23  1  0.300  0.117  0.645  1.0
  N  N24  1  0.117  0.300  0.145  1.0
  N  N25  1  0.300  0.117  0.855  1.0
  N  N26  1  0.883  0.700  0.645  1.0
  N  N27  1  0.700  0.883  0.355  1.0
  N  N28  1  0.883  0.700  0.855  1.0
  N  N29  1  0.700  0.883  0.145  1.0
  O  O30  1  0.349  0.933  0.250  1.0
  O  O31  1  0.933  0.349  0.750  1.0
  O  O32  1  0.651  0.067  0.750  1.0
  O  O33  1  0.067  0.651  0.250  1.0
  O  O34  1  0.183  0.817  0.322  1.0
  O  O35  1  0.817  0.183  0.678  1.0
  O  O36  1  0.183  0.817  0.178  1.0
  O  O37  1  0.817  0.183  0.822  1.0
[/CIF]
.