The crystal structure described by PdN3SO3 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules and four PdN3 clusters. In each PdN3 cluster, Pd(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are three inequivalent N sites. In the first N site, N(3) is bonded in a single-bond geometry to one Pd(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Pd(1) atom. In the third N site, N(1) is bonded in a single-bond geometry to one Pd(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PdS(NO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.871
_cell_length_b   7.502
_cell_length_c   14.627
_cell_angle_alpha   70.002
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   708.502
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.193  0.069  0.986  1.0
  Pd  Pd1  1  0.307  0.069  0.486  1.0
  Pd  Pd2  1  0.807  0.931  0.014  1.0
  Pd  Pd3  1  0.693  0.931  0.514  1.0
  S  S4  1  0.206  0.346  0.677  1.0
  S  S5  1  0.294  0.346  0.177  1.0
  S  S6  1  0.794  0.654  0.323  1.0
  S  S7  1  0.706  0.654  0.823  1.0
  N  N8  1  0.273  0.933  0.114  1.0
  N  N9  1  0.227  0.933  0.614  1.0
  N  N10  1  0.727  0.067  0.886  1.0
  N  N11  1  0.773  0.067  0.386  1.0
  N  N12  1  0.250  0.312  0.930  1.0
  N  N13  1  0.250  0.312  0.430  1.0
  N  N14  1  0.750  0.688  0.070  1.0
  N  N15  1  0.750  0.688  0.570  1.0
  N  N16  1  0.220  0.883  0.932  1.0
  N  N17  1  0.280  0.883  0.432  1.0
  N  N18  1  0.780  0.117  0.068  1.0
  N  N19  1  0.720  0.117  0.568  1.0
  O  O20  1  0.153  0.539  0.661  1.0
  O  O21  1  0.347  0.539  0.161  1.0
  O  O22  1  0.847  0.461  0.339  1.0
  O  O23  1  0.653  0.461  0.839  1.0
  O  O24  1  0.058  0.201  0.701  1.0
  O  O25  1  0.442  0.201  0.201  1.0
  O  O26  1  0.942  0.799  0.299  1.0
  O  O27  1  0.558  0.799  0.799  1.0
  O  O28  1  0.405  0.296  0.668  1.0
  O  O29  1  0.095  0.296  0.168  1.0
  O  O30  1  0.595  0.704  0.332  1.0
  O  O31  1  0.905  0.704  0.832  1.0
[/CIF]
.
The crystal structure described by PdN3SO3 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules and four PdN3 clusters. In each PdN3 cluster, Pd(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are three inequivalent N sites. In the first N site, N(3) is bonded in a single-bond geometry to one Pd(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Pd(1) atom. In the third N site, N(1) is bonded in a single-bond geometry to one Pd(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PdS(NO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.871
_cell_length_b   7.502
_cell_length_c   14.627
_cell_angle_alpha   70.002
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   708.502
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.193  0.069  0.986  1.0
  Pd  Pd1  1  0.307  0.069  0.486  1.0
  Pd  Pd2  1  0.807  0.931  0.014  1.0
  Pd  Pd3  1  0.693  0.931  0.514  1.0
  S  S4  1  0.206  0.346  0.677  1.0
  S  S5  1  0.294  0.346  0.177  1.0
  S  S6  1  0.794  0.654  0.323  1.0
  S  S7  1  0.706  0.654  0.823  1.0
  N  N8  1  0.273  0.933  0.114  1.0
  N  N9  1  0.227  0.933  0.614  1.0
  N  N10  1  0.727  0.067  0.886  1.0
  N  N11  1  0.773  0.067  0.386  1.0
  N  N12  1  0.250  0.312  0.930  1.0
  N  N13  1  0.250  0.312  0.430  1.0
  N  N14  1  0.750  0.688  0.070  1.0
  N  N15  1  0.750  0.688  0.570  1.0
  N  N16  1  0.220  0.883  0.932  1.0
  N  N17  1  0.280  0.883  0.432  1.0
  N  N18  1  0.780  0.117  0.068  1.0
  N  N19  1  0.720  0.117  0.568  1.0
  O  O20  1  0.153  0.539  0.661  1.0
  O  O21  1  0.347  0.539  0.161  1.0
  O  O22  1  0.847  0.461  0.339  1.0
  O  O23  1  0.653  0.461  0.839  1.0
  O  O24  1  0.058  0.201  0.701  1.0
  O  O25  1  0.442  0.201  0.201  1.0
  O  O26  1  0.942  0.799  0.299  1.0
  O  O27  1  0.558  0.799  0.799  1.0
  O  O28  1  0.405  0.296  0.668  1.0
  O  O29  1  0.095  0.296  0.168  1.0
  O  O30  1  0.595  0.704  0.332  1.0
  O  O31  1  0.905  0.704  0.832  1.0
[/CIF]
.