The compound described by (P4N3Cl10)2Cl2 is Tetraauricupride structured and crystallizes in the trigonal R3 space group. The structure is zero-dimensional and consists of three hydrochloric acid atoms and three P4N3Cl10 clusters. In each P4N3Cl10 cluster, there are two inequivalent P sites. In the first P site, P(1) is bonded to three equivalent N(1) and one Cl(1) atom to form corner-sharing PN3Cl tetrahedra. In the second P site, P(2) is bonded to one N(1), one Cl(2), one Cl(3), and one Cl(4) atom to form corner-sharing PNCl3 tetrahedra. N(1) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P4N3Cl11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.885
_cell_length_b   7.885
_cell_length_c   7.885
_cell_angle_alpha   86.224
_cell_angle_beta   86.224
_cell_angle_gamma   86.224
_symmetry_Int_Tables_number   1
_cell_volume   487.200
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.377  0.377  0.377  1.0
  P  P1  1  0.508  0.585  0.086  1.0
  P  P2  1  0.086  0.508  0.585  1.0
  P  P3  1  0.585  0.086  0.508  1.0
  N  N4  1  0.472  0.252  0.512  1.0
  N  N5  1  0.512  0.472  0.252  1.0
  N  N6  1  0.252  0.512  0.472  1.0
  Cl  Cl7  1  0.238  0.238  0.238  1.0
  Cl  Cl8  1  0.054  0.712  0.718  1.0
  Cl  Cl9  1  0.718  0.054  0.712  1.0
  Cl  Cl10  1  0.712  0.718  0.054  1.0
  Cl  Cl11  1  0.065  0.310  0.752  1.0
  Cl  Cl12  1  0.752  0.065  0.310  1.0
  Cl  Cl13  1  0.310  0.752  0.065  1.0
  Cl  Cl14  1  0.878  0.510  0.453  1.0
  Cl  Cl15  1  0.453  0.878  0.510  1.0
  Cl  Cl16  1  0.510  0.453  0.878  1.0
  Cl  Cl17  1  0.991  0.991  0.991  1.0
[/CIF]
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The compound described by (P4N3Cl10)2Cl2 is Tetraauricupride structured and crystallizes in the trigonal R3 space group. The structure is zero-dimensional and consists of three hydrochloric acid atoms and three P4N3Cl10 clusters. In each P4N3Cl10 cluster, there are two inequivalent P sites. In the first P site, P(1) is bonded to three equivalent N(1) and one Cl(1) atom to form corner-sharing PN3Cl tetrahedra. In the second P site, P(2) is bonded to one N(1), one Cl(2), one Cl(3), and one Cl(4) atom to form corner-sharing PNCl3 tetrahedra. N(1) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P4N3Cl11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.885
_cell_length_b   7.885
_cell_length_c   7.885
_cell_angle_alpha   86.224
_cell_angle_beta   86.224
_cell_angle_gamma   86.224
_symmetry_Int_Tables_number   1
_cell_volume   487.200
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.377  0.377  0.377  1.0
  P  P1  1  0.508  0.585  0.086  1.0
  P  P2  1  0.086  0.508  0.585  1.0
  P  P3  1  0.585  0.086  0.508  1.0
  N  N4  1  0.472  0.252  0.512  1.0
  N  N5  1  0.512  0.472  0.252  1.0
  N  N6  1  0.252  0.512  0.472  1.0
  Cl  Cl7  1  0.238  0.238  0.238  1.0
  Cl  Cl8  1  0.054  0.712  0.718  1.0
  Cl  Cl9  1  0.718  0.054  0.712  1.0
  Cl  Cl10  1  0.712  0.718  0.054  1.0
  Cl  Cl11  1  0.065  0.310  0.752  1.0
  Cl  Cl12  1  0.752  0.065  0.310  1.0
  Cl  Cl13  1  0.310  0.752  0.065  1.0
  Cl  Cl14  1  0.878  0.510  0.453  1.0
  Cl  Cl15  1  0.453  0.878  0.510  1.0
  Cl  Cl16  1  0.510  0.453  0.878  1.0
  Cl  Cl17  1  0.991  0.991  0.991  1.0
[/CIF]
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