The crystal structure described by K2CuS(O2Cl)2 crystallizes in the orthorhombic Pnma space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), two equivalent O(2), one Cl(2), and three equivalent Cl(1) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to four equivalent O(2), one Cl(1), and one Cl(2) atom. Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(3), one Cl(1), and one Cl(2) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one Cu(1), and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), two equivalent K(2), and one S(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one K(1), one Cu(1), and one S(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to one K(2), three equivalent K(1), and one Cu(1) atom to form a mixture of distorted corner and edge-sharing ClK4Cu trigonal bipyramids. In the second Cl site, Cl(2) is bonded in a 1-coordinate geometry to one K(1), one K(2), and one Cu(1) atom. is represented by the CIF card [CIF]
data_K2CuS(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.219
_cell_length_b   7.851
_cell_length_c   16.534
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   807.270
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.880  0.406  1.0
  K  K1  1  0.250  0.383  0.717  1.0
  K  K2  1  0.750  0.117  0.217  1.0
  K  K3  1  0.750  0.120  0.594  1.0
  K  K4  1  0.750  0.620  0.906  1.0
  K  K5  1  0.250  0.883  0.783  1.0
  K  K6  1  0.750  0.617  0.283  1.0
  K  K7  1  0.250  0.380  0.094  1.0
  Cu  Cu8  1  0.250  0.879  0.038  1.0
  Cu  Cu9  1  0.750  0.121  0.962  1.0
  Cu  Cu10  1  0.250  0.379  0.462  1.0
  Cu  Cu11  1  0.750  0.621  0.538  1.0
  S  S12  1  0.250  0.870  0.197  1.0
  S  S13  1  0.750  0.130  0.803  1.0
  S  S14  1  0.750  0.630  0.697  1.0
  S  S15  1  0.250  0.370  0.303  1.0
  Cl  Cl16  1  0.250  0.662  0.948  1.0
  Cl  Cl17  1  0.250  0.099  0.952  1.0
  Cl  Cl18  1  0.750  0.901  0.048  1.0
  Cl  Cl19  1  0.250  0.599  0.548  1.0
  Cl  Cl20  1  0.750  0.338  0.052  1.0
  Cl  Cl21  1  0.750  0.401  0.452  1.0
  Cl  Cl22  1  0.750  0.838  0.448  1.0
  Cl  Cl23  1  0.250  0.162  0.552  1.0
  O  O24  1  0.750  0.276  0.863  1.0
  O  O25  1  0.250  0.224  0.363  1.0
  O  O26  1  0.555  0.633  0.748  1.0
  O  O27  1  0.750  0.776  0.637  1.0
  O  O28  1  0.945  0.633  0.748  1.0
  O  O29  1  0.250  0.525  0.358  1.0
  O  O30  1  0.445  0.367  0.252  1.0
  O  O31  1  0.750  0.975  0.858  1.0
  O  O32  1  0.750  0.475  0.642  1.0
  O  O33  1  0.055  0.367  0.252  1.0
  O  O34  1  0.945  0.133  0.752  1.0
  O  O35  1  0.250  0.724  0.137  1.0
  O  O36  1  0.445  0.867  0.248  1.0
  O  O37  1  0.055  0.867  0.248  1.0
  O  O38  1  0.555  0.133  0.752  1.0
  O  O39  1  0.250  0.025  0.142  1.0
[/CIF]
.
The crystal structure described by K2CuS(O2Cl)2 crystallizes in the orthorhombic Pnma space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), two equivalent O(2), one Cl(2), and three equivalent Cl(1) atoms. In the second K site, K(2) is bonded in a 6-coordinate geometry to four equivalent O(2), one Cl(1), and one Cl(2) atom. Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(3), one Cl(1), and one Cl(2) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one Cu(1), and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), two equivalent K(2), and one S(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one K(1), one Cu(1), and one S(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to one K(2), three equivalent K(1), and one Cu(1) atom to form a mixture of distorted corner and edge-sharing ClK4Cu trigonal bipyramids. In the second Cl site, Cl(2) is bonded in a 1-coordinate geometry to one K(1), one K(2), and one Cu(1) atom. is represented by the CIF card [CIF]
data_K2CuS(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.219
_cell_length_b   7.851
_cell_length_c   16.534
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   807.270
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.880  0.406  1.0
  K  K1  1  0.250  0.383  0.717  1.0
  K  K2  1  0.750  0.117  0.217  1.0
  K  K3  1  0.750  0.120  0.594  1.0
  K  K4  1  0.750  0.620  0.906  1.0
  K  K5  1  0.250  0.883  0.783  1.0
  K  K6  1  0.750  0.617  0.283  1.0
  K  K7  1  0.250  0.380  0.094  1.0
  Cu  Cu8  1  0.250  0.879  0.038  1.0
  Cu  Cu9  1  0.750  0.121  0.962  1.0
  Cu  Cu10  1  0.250  0.379  0.462  1.0
  Cu  Cu11  1  0.750  0.621  0.538  1.0
  S  S12  1  0.250  0.870  0.197  1.0
  S  S13  1  0.750  0.130  0.803  1.0
  S  S14  1  0.750  0.630  0.697  1.0
  S  S15  1  0.250  0.370  0.303  1.0
  Cl  Cl16  1  0.250  0.662  0.948  1.0
  Cl  Cl17  1  0.250  0.099  0.952  1.0
  Cl  Cl18  1  0.750  0.901  0.048  1.0
  Cl  Cl19  1  0.250  0.599  0.548  1.0
  Cl  Cl20  1  0.750  0.338  0.052  1.0
  Cl  Cl21  1  0.750  0.401  0.452  1.0
  Cl  Cl22  1  0.750  0.838  0.448  1.0
  Cl  Cl23  1  0.250  0.162  0.552  1.0
  O  O24  1  0.750  0.276  0.863  1.0
  O  O25  1  0.250  0.224  0.363  1.0
  O  O26  1  0.555  0.633  0.748  1.0
  O  O27  1  0.750  0.776  0.637  1.0
  O  O28  1  0.945  0.633  0.748  1.0
  O  O29  1  0.250  0.525  0.358  1.0
  O  O30  1  0.445  0.367  0.252  1.0
  O  O31  1  0.750  0.975  0.858  1.0
  O  O32  1  0.750  0.475  0.642  1.0
  O  O33  1  0.055  0.367  0.252  1.0
  O  O34  1  0.945  0.133  0.752  1.0
  O  O35  1  0.250  0.724  0.137  1.0
  O  O36  1  0.445  0.867  0.248  1.0
  O  O37  1  0.055  0.867  0.248  1.0
  O  O38  1  0.555  0.133  0.752  1.0
  O  O39  1  0.250  0.025  0.142  1.0
[/CIF]
.