The structure described by MnPbN2 crystallizes in the orthorhombic Pna2_1 space group. Mn(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form corner-sharing MnN4 tetrahedra. Pb(1) is bonded in a 3-coordinate geometry to one N(2) and two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to two equivalent Mn(1) and two equivalent Pb(1) atoms. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Mn(1) and one Pb(1) atom. is represented by the CIF card [CIF]
data_MnPbN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.843
_cell_length_b   7.693
_cell_length_c   5.284
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   237.517
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.510  0.873  0.988  1.0
  Mn  Mn1  1  0.490  0.127  0.488  1.0
  Mn  Mn2  1  0.990  0.373  0.488  1.0
  Mn  Mn3  1  0.010  0.627  0.988  1.0
  Pb  Pb4  1  0.586  0.369  0.005  1.0
  Pb  Pb5  1  0.414  0.631  0.505  1.0
  Pb  Pb6  1  0.914  0.869  0.505  1.0
  Pb  Pb7  1  0.086  0.131  0.005  1.0
  N  N8  1  0.503  0.924  0.319  1.0
  N  N9  1  0.497  0.076  0.819  1.0
  N  N10  1  0.997  0.424  0.819  1.0
  N  N11  1  0.003  0.576  0.319  1.0
  N  N12  1  0.738  0.252  0.409  1.0
  N  N13  1  0.262  0.748  0.909  1.0
  N  N14  1  0.762  0.752  0.909  1.0
  N  N15  1  0.238  0.248  0.409  1.0
[/CIF]
.
The structure described by MnPbN2 crystallizes in the orthorhombic Pna2_1 space group. Mn(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form corner-sharing MnN4 tetrahedra. Pb(1) is bonded in a 3-coordinate geometry to one N(2) and two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to two equivalent Mn(1) and two equivalent Pb(1) atoms. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Mn(1) and one Pb(1) atom. is represented by the CIF card [CIF]
data_MnPbN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.843
_cell_length_b   7.693
_cell_length_c   5.284
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   237.517
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.510  0.873  0.988  1.0
  Mn  Mn1  1  0.490  0.127  0.488  1.0
  Mn  Mn2  1  0.990  0.373  0.488  1.0
  Mn  Mn3  1  0.010  0.627  0.988  1.0
  Pb  Pb4  1  0.586  0.369  0.005  1.0
  Pb  Pb5  1  0.414  0.631  0.505  1.0
  Pb  Pb6  1  0.914  0.869  0.505  1.0
  Pb  Pb7  1  0.086  0.131  0.005  1.0
  N  N8  1  0.503  0.924  0.319  1.0
  N  N9  1  0.497  0.076  0.819  1.0
  N  N10  1  0.997  0.424  0.819  1.0
  N  N11  1  0.003  0.576  0.319  1.0
  N  N12  1  0.738  0.252  0.409  1.0
  N  N13  1  0.262  0.748  0.909  1.0
  N  N14  1  0.762  0.752  0.909  1.0
  N  N15  1  0.238  0.248  0.409  1.0
[/CIF]
.