The structure described by KIn(TeO3)2 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(3) atoms. In(1) is bonded in an octahedral geometry to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted T-shaped geometry to one O(2) and two equivalent O(1) atoms. In the second Te site, Te(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4) and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one In(1) and one Te(2) atom. In the second O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one In(1), and one Te(1) atom. In the third O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent K(1), one In(1), and one Te(1) atom. In the fourth O site, O(3) is bonded to two equivalent K(1), one In(1), and one Te(2) atom to form a mixture of distorted corner and edge-sharing OK2InTe tetrahedra. is represented by the CIF file [CIF]
data_KIn(TeO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.938
_cell_length_b   8.457
_cell_length_c   13.611
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   683.469
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.004  0.630  1.0
  K  K1  1  0.250  0.496  0.130  1.0
  K  K2  1  0.750  0.996  0.370  1.0
  K  K3  1  0.750  0.504  0.870  1.0
  In  In4  1  0.250  0.789  0.906  1.0
  In  In5  1  0.250  0.711  0.406  1.0
  In  In6  1  0.750  0.211  0.094  1.0
  In  In7  1  0.750  0.289  0.594  1.0
  Te  Te8  1  0.750  0.010  0.803  1.0
  Te  Te9  1  0.750  0.490  0.303  1.0
  Te  Te10  1  0.250  0.990  0.197  1.0
  Te  Te11  1  0.250  0.510  0.697  1.0
  Te  Te12  1  0.750  0.713  0.574  1.0
  Te  Te13  1  0.750  0.787  0.074  1.0
  Te  Te14  1  0.250  0.287  0.426  1.0
  Te  Te15  1  0.250  0.213  0.926  1.0
  O  O16  1  0.995  0.866  0.798  1.0
  O  O17  1  0.505  0.634  0.298  1.0
  O  O18  1  0.495  0.134  0.202  1.0
  O  O19  1  0.005  0.366  0.702  1.0
  O  O20  1  0.005  0.134  0.202  1.0
  O  O21  1  0.495  0.366  0.702  1.0
  O  O22  1  0.505  0.866  0.798  1.0
  O  O23  1  0.995  0.634  0.298  1.0
  O  O24  1  0.750  0.053  0.665  1.0
  O  O25  1  0.750  0.447  0.165  1.0
  O  O26  1  0.250  0.947  0.335  1.0
  O  O27  1  0.250  0.553  0.835  1.0
  O  O28  1  0.993  0.806  0.506  1.0
  O  O29  1  0.507  0.694  0.006  1.0
  O  O30  1  0.493  0.194  0.494  1.0
  O  O31  1  0.007  0.306  0.994  1.0
  O  O32  1  0.007  0.194  0.494  1.0
  O  O33  1  0.493  0.306  0.994  1.0
  O  O34  1  0.507  0.806  0.506  1.0
  O  O35  1  0.993  0.694  0.006  1.0
  O  O36  1  0.750  0.511  0.513  1.0
  O  O37  1  0.750  0.989  0.013  1.0
  O  O38  1  0.250  0.489  0.487  1.0
  O  O39  1  0.250  0.011  0.987  1.0
[/CIF]
.
The structure described by KIn(TeO3)2 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(3) atoms. In(1) is bonded in an octahedral geometry to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted T-shaped geometry to one O(2) and two equivalent O(1) atoms. In the second Te site, Te(2) is bonded in a distorted trigonal non-coplanar geometry to one O(4) and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one In(1) and one Te(2) atom. In the second O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one In(1), and one Te(1) atom. In the third O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent K(1), one In(1), and one Te(1) atom. In the fourth O site, O(3) is bonded to two equivalent K(1), one In(1), and one Te(2) atom to form a mixture of distorted corner and edge-sharing OK2InTe tetrahedra. is represented by the CIF file [CIF]
data_KIn(TeO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.938
_cell_length_b   8.457
_cell_length_c   13.611
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   683.469
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.004  0.630  1.0
  K  K1  1  0.250  0.496  0.130  1.0
  K  K2  1  0.750  0.996  0.370  1.0
  K  K3  1  0.750  0.504  0.870  1.0
  In  In4  1  0.250  0.789  0.906  1.0
  In  In5  1  0.250  0.711  0.406  1.0
  In  In6  1  0.750  0.211  0.094  1.0
  In  In7  1  0.750  0.289  0.594  1.0
  Te  Te8  1  0.750  0.010  0.803  1.0
  Te  Te9  1  0.750  0.490  0.303  1.0
  Te  Te10  1  0.250  0.990  0.197  1.0
  Te  Te11  1  0.250  0.510  0.697  1.0
  Te  Te12  1  0.750  0.713  0.574  1.0
  Te  Te13  1  0.750  0.787  0.074  1.0
  Te  Te14  1  0.250  0.287  0.426  1.0
  Te  Te15  1  0.250  0.213  0.926  1.0
  O  O16  1  0.995  0.866  0.798  1.0
  O  O17  1  0.505  0.634  0.298  1.0
  O  O18  1  0.495  0.134  0.202  1.0
  O  O19  1  0.005  0.366  0.702  1.0
  O  O20  1  0.005  0.134  0.202  1.0
  O  O21  1  0.495  0.366  0.702  1.0
  O  O22  1  0.505  0.866  0.798  1.0
  O  O23  1  0.995  0.634  0.298  1.0
  O  O24  1  0.750  0.053  0.665  1.0
  O  O25  1  0.750  0.447  0.165  1.0
  O  O26  1  0.250  0.947  0.335  1.0
  O  O27  1  0.250  0.553  0.835  1.0
  O  O28  1  0.993  0.806  0.506  1.0
  O  O29  1  0.507  0.694  0.006  1.0
  O  O30  1  0.493  0.194  0.494  1.0
  O  O31  1  0.007  0.306  0.994  1.0
  O  O32  1  0.007  0.194  0.494  1.0
  O  O33  1  0.493  0.306  0.994  1.0
  O  O34  1  0.507  0.806  0.506  1.0
  O  O35  1  0.993  0.694  0.006  1.0
  O  O36  1  0.750  0.511  0.513  1.0
  O  O37  1  0.750  0.989  0.013  1.0
  O  O38  1  0.250  0.489  0.487  1.0
  O  O39  1  0.250  0.011  0.987  1.0
[/CIF]
.