The compound described by NaBiO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Na(1) is bonded to six equivalent O(1) atoms to form distorted NaO6 pentagonal pyramids that share corners with nine equivalent Bi(1)O6 octahedra, edges with three equivalent Na(1)O6 pentagonal pyramids, and  a faceface with one Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-62°. Bi(1) is bonded to six equivalent O(1) atoms to form BiO6 octahedra that share corners with nine equivalent Na(1)O6 pentagonal pyramids, edges with three equivalent Bi(1)O6 octahedra, and  a faceface with one Na(1)O6 pentagonal pyramid. O(1) is bonded in a distorted see-saw-like geometry to two equivalent Na(1) and two equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_NaBiO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.189
_cell_length_b   6.189
_cell_length_c   6.189
_cell_angle_alpha   53.826
_cell_angle_beta   53.826
_cell_angle_gamma   53.826
_symmetry_Int_Tables_number   1
_cell_volume   143.406
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.139  0.139  0.139  1.0
  Na  Na1  1  0.861  0.861  0.861  1.0
  Bi  Bi2  1  0.343  0.343  0.343  1.0
  Bi  Bi3  1  0.657  0.657  0.657  1.0
  O  O4  1  0.058  0.707  0.461  1.0
  O  O5  1  0.707  0.461  0.058  1.0
  O  O6  1  0.461  0.058  0.707  1.0
  O  O7  1  0.942  0.293  0.539  1.0
  O  O8  1  0.539  0.942  0.293  1.0
  O  O9  1  0.293  0.539  0.942  1.0
[/CIF]
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The compound described by NaBiO3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Na(1) is bonded to six equivalent O(1) atoms to form distorted NaO6 pentagonal pyramids that share corners with nine equivalent Bi(1)O6 octahedra, edges with three equivalent Na(1)O6 pentagonal pyramids, and  a faceface with one Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-62°. Bi(1) is bonded to six equivalent O(1) atoms to form BiO6 octahedra that share corners with nine equivalent Na(1)O6 pentagonal pyramids, edges with three equivalent Bi(1)O6 octahedra, and  a faceface with one Na(1)O6 pentagonal pyramid. O(1) is bonded in a distorted see-saw-like geometry to two equivalent Na(1) and two equivalent Bi(1) atoms. is represented by the CIF card [CIF]
data_NaBiO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.189
_cell_length_b   6.189
_cell_length_c   6.189
_cell_angle_alpha   53.826
_cell_angle_beta   53.826
_cell_angle_gamma   53.826
_symmetry_Int_Tables_number   1
_cell_volume   143.406
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.139  0.139  0.139  1.0
  Na  Na1  1  0.861  0.861  0.861  1.0
  Bi  Bi2  1  0.343  0.343  0.343  1.0
  Bi  Bi3  1  0.657  0.657  0.657  1.0
  O  O4  1  0.058  0.707  0.461  1.0
  O  O5  1  0.707  0.461  0.058  1.0
  O  O6  1  0.461  0.058  0.707  1.0
  O  O7  1  0.942  0.293  0.539  1.0
  O  O8  1  0.539  0.942  0.293  1.0
  O  O9  1  0.293  0.539  0.942  1.0
[/CIF]
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