The compound described by Na2Pd3O4 crystallizes in the orthorhombic Immm space group. Na(1) is bonded in a 4-coordinate geometry to six equivalent O(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. In the second Pd site, Pd(2) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded in a 6-coordinate geometry to three equivalent Na(1), one Pd(2), and two equivalent Pd(1) atoms. is represented by the CIF file [CIF]
data_Na2Pd3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.055
_cell_length_b   5.465
_cell_length_c   7.269
_cell_angle_alpha   112.082
_cell_angle_beta   102.130
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   109.524
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.798  0.298  0.597  1.0
  Na  Na1  1  0.202  0.702  0.403  1.0
  Pd  Pd2  1  0.107  0.107  0.214  1.0
  Pd  Pd3  1  0.893  0.893  0.786  1.0
  Pd  Pd4  1  0.500  0.500  0.000  1.0
  O  O5  1  0.616  0.869  0.232  1.0
  O  O6  1  0.384  0.131  0.768  1.0
  O  O7  1  0.384  0.637  0.768  1.0
  O  O8  1  0.616  0.363  0.232  1.0
[/CIF]
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The compound described by Na2Pd3O4 crystallizes in the orthorhombic Immm space group. Na(1) is bonded in a 4-coordinate geometry to six equivalent O(1) atoms. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. In the second Pd site, Pd(2) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded in a 6-coordinate geometry to three equivalent Na(1), one Pd(2), and two equivalent Pd(1) atoms. is represented by the CIF file [CIF]
data_Na2Pd3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.055
_cell_length_b   5.465
_cell_length_c   7.269
_cell_angle_alpha   112.082
_cell_angle_beta   102.130
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   109.524
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.798  0.298  0.597  1.0
  Na  Na1  1  0.202  0.702  0.403  1.0
  Pd  Pd2  1  0.107  0.107  0.214  1.0
  Pd  Pd3  1  0.893  0.893  0.786  1.0
  Pd  Pd4  1  0.500  0.500  0.000  1.0
  O  O5  1  0.616  0.869  0.232  1.0
  O  O6  1  0.384  0.131  0.768  1.0
  O  O7  1  0.384  0.637  0.768  1.0
  O  O8  1  0.616  0.363  0.232  1.0
[/CIF]
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