The material structure described by PuOF is Fluorite-derived structured and crystallizes in the tetragonal P4/nmm space group. Pu(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded to four equivalent Pu(1) atoms to form OPu4 tetrahedra that share corners with four equivalent O(1)Pu4 tetrahedra, corners with twelve equivalent F(1)Pu4 tetrahedra, edges with two equivalent F(1)Pu4 tetrahedra, and edges with four equivalent O(1)Pu4 tetrahedra. F(1) is bonded to four equivalent Pu(1) atoms to form FPu4 tetrahedra that share corners with four equivalent F(1)Pu4 tetrahedra, corners with twelve equivalent O(1)Pu4 tetrahedra, edges with two equivalent O(1)Pu4 tetrahedra, and edges with four equivalent F(1)Pu4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_PuOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.967
_cell_length_b   3.967
_cell_length_c   5.680
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   89.399
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.250  0.250  0.717  1.0
  Pu  Pu1  1  0.750  0.750  0.283  1.0
  O  O2  1  0.750  0.250  0.500  1.0
  O  O3  1  0.250  0.750  0.500  1.0
  F  F4  1  0.250  0.750  0.000  1.0
  F  F5  1  0.750  0.250  0.000  1.0
[/CIF]
.
The material structure described by PuOF is Fluorite-derived structured and crystallizes in the tetragonal P4/nmm space group. Pu(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded to four equivalent Pu(1) atoms to form OPu4 tetrahedra that share corners with four equivalent O(1)Pu4 tetrahedra, corners with twelve equivalent F(1)Pu4 tetrahedra, edges with two equivalent F(1)Pu4 tetrahedra, and edges with four equivalent O(1)Pu4 tetrahedra. F(1) is bonded to four equivalent Pu(1) atoms to form FPu4 tetrahedra that share corners with four equivalent F(1)Pu4 tetrahedra, corners with twelve equivalent O(1)Pu4 tetrahedra, edges with two equivalent O(1)Pu4 tetrahedra, and edges with four equivalent F(1)Pu4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_PuOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.967
_cell_length_b   3.967
_cell_length_c   5.680
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   89.399
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.250  0.250  0.717  1.0
  Pu  Pu1  1  0.750  0.750  0.283  1.0
  O  O2  1  0.750  0.250  0.500  1.0
  O  O3  1  0.250  0.750  0.500  1.0
  F  F4  1  0.250  0.750  0.000  1.0
  F  F5  1  0.750  0.250  0.000  1.0
[/CIF]
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