The material described by Pt(NS)4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four Pt(NS)4 clusters. Pt(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(3), one S(1), and one S(3) atom. There are four inequivalent N sites. In the first N site, N(4) is bonded in a bent 120 degrees geometry to one S(3) and one S(4) atom. In the second N site, N(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(2) atom. In the third N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the fourth N site, N(3) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Pt(1) and one N(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a water-like geometry to one Pt(1) and one N(4) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one N(3) and one N(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pt(SN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.287
_cell_length_b   8.858
_cell_length_c   11.725
_cell_angle_alpha   77.466
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   840.117
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.164  0.952  0.636  1.0
  Pt  Pt1  1  0.664  0.048  0.864  1.0
  Pt  Pt2  1  0.836  0.048  0.364  1.0
  Pt  Pt3  1  0.336  0.952  0.136  1.0
  S  S4  1  0.286  0.103  0.482  1.0
  S  S5  1  0.786  0.897  0.018  1.0
  S  S6  1  0.714  0.897  0.518  1.0
  S  S7  1  0.214  0.103  0.982  1.0
  S  S8  1  0.097  0.298  0.576  1.0
  S  S9  1  0.597  0.702  0.924  1.0
  S  S10  1  0.903  0.702  0.424  1.0
  S  S11  1  0.403  0.298  0.076  1.0
  S  S12  1  0.278  0.733  0.612  1.0
  S  S13  1  0.778  0.267  0.888  1.0
  S  S14  1  0.722  0.267  0.388  1.0
  S  S15  1  0.222  0.733  0.112  1.0
  S  S16  1  0.088  0.649  0.807  1.0
  S  S17  1  0.588  0.351  0.693  1.0
  S  S18  1  0.912  0.351  0.193  1.0
  S  S19  1  0.412  0.649  0.307  1.0
  N  N20  1  0.058  0.144  0.663  1.0
  N  N21  1  0.558  0.856  0.837  1.0
  N  N22  1  0.942  0.856  0.337  1.0
  N  N23  1  0.442  0.144  0.163  1.0
  N  N24  1  0.224  0.279  0.475  1.0
  N  N25  1  0.724  0.721  0.025  1.0
  N  N26  1  0.776  0.721  0.525  1.0
  N  N27  1  0.276  0.279  0.975  1.0
  N  N28  1  0.053  0.825  0.775  1.0
  N  N29  1  0.553  0.175  0.725  1.0
  N  N30  1  0.947  0.175  0.225  1.0
  N  N31  1  0.447  0.825  0.275  1.0
  N  N32  1  0.213  0.594  0.718  1.0
  N  N33  1  0.713  0.406  0.782  1.0
  N  N34  1  0.787  0.406  0.282  1.0
  N  N35  1  0.287  0.594  0.218  1.0
[/CIF]
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The material described by Pt(NS)4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four Pt(NS)4 clusters. Pt(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(3), one S(1), and one S(3) atom. There are four inequivalent N sites. In the first N site, N(4) is bonded in a bent 120 degrees geometry to one S(3) and one S(4) atom. In the second N site, N(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(2) atom. In the third N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the fourth N site, N(3) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Pt(1) and one N(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a water-like geometry to one Pt(1) and one N(4) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one N(3) and one N(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pt(SN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.287
_cell_length_b   8.858
_cell_length_c   11.725
_cell_angle_alpha   77.466
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   840.117
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.164  0.952  0.636  1.0
  Pt  Pt1  1  0.664  0.048  0.864  1.0
  Pt  Pt2  1  0.836  0.048  0.364  1.0
  Pt  Pt3  1  0.336  0.952  0.136  1.0
  S  S4  1  0.286  0.103  0.482  1.0
  S  S5  1  0.786  0.897  0.018  1.0
  S  S6  1  0.714  0.897  0.518  1.0
  S  S7  1  0.214  0.103  0.982  1.0
  S  S8  1  0.097  0.298  0.576  1.0
  S  S9  1  0.597  0.702  0.924  1.0
  S  S10  1  0.903  0.702  0.424  1.0
  S  S11  1  0.403  0.298  0.076  1.0
  S  S12  1  0.278  0.733  0.612  1.0
  S  S13  1  0.778  0.267  0.888  1.0
  S  S14  1  0.722  0.267  0.388  1.0
  S  S15  1  0.222  0.733  0.112  1.0
  S  S16  1  0.088  0.649  0.807  1.0
  S  S17  1  0.588  0.351  0.693  1.0
  S  S18  1  0.912  0.351  0.193  1.0
  S  S19  1  0.412  0.649  0.307  1.0
  N  N20  1  0.058  0.144  0.663  1.0
  N  N21  1  0.558  0.856  0.837  1.0
  N  N22  1  0.942  0.856  0.337  1.0
  N  N23  1  0.442  0.144  0.163  1.0
  N  N24  1  0.224  0.279  0.475  1.0
  N  N25  1  0.724  0.721  0.025  1.0
  N  N26  1  0.776  0.721  0.525  1.0
  N  N27  1  0.276  0.279  0.975  1.0
  N  N28  1  0.053  0.825  0.775  1.0
  N  N29  1  0.553  0.175  0.725  1.0
  N  N30  1  0.947  0.175  0.225  1.0
  N  N31  1  0.447  0.825  0.275  1.0
  N  N32  1  0.213  0.594  0.718  1.0
  N  N33  1  0.713  0.406  0.782  1.0
  N  N34  1  0.787  0.406  0.282  1.0
  N  N35  1  0.287  0.594  0.218  1.0
[/CIF]
.