The crystal structure described by Rb2Zn(SO6)2O2 crystallizes in the monoclinic P2_1/c space group. The structure consists of two hydrogen peroxide molecules inside a Rb2Zn(SO6)2 framework. In the Rb2Zn(SO6)2 framework, Rb(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), one O(4), one O(5), two equivalent O(2), and two equivalent O(7) atoms. Zn(1) is bonded in a distorted square co-planar geometry to two equivalent O(3) and two equivalent O(5) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(7) atom. There are six inequivalent O sites. In the first O site, O(7) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Rb(1) and one S(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one Rb(1), one Zn(1), and one O(5) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(1) and one S(1) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to one Rb(1), one Zn(1), and one O(3) atom. is represented by the CIF card [CIF]
data_Rb2Zn(SO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.995
_cell_length_b   8.814
_cell_length_c   13.572
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   101.108
_symmetry_Int_Tables_number   1
_cell_volume   703.667
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.835  0.626  0.152  1.0
  Rb  Rb1  1  0.165  0.374  0.848  1.0
  Rb  Rb2  1  0.165  0.874  0.652  1.0
  Rb  Rb3  1  0.835  0.126  0.348  1.0
  Zn  Zn4  1  0.500  0.000  0.000  1.0
  Zn  Zn5  1  0.500  0.500  0.500  1.0
  S  S6  1  0.752  0.606  0.861  1.0
  S  S7  1  0.248  0.394  0.139  1.0
  S  S8  1  0.248  0.894  0.361  1.0
  S  S9  1  0.752  0.106  0.639  1.0
  O  O10  1  0.535  0.646  0.830  1.0
  O  O11  1  0.465  0.354  0.170  1.0
  O  O12  1  0.465  0.854  0.330  1.0
  O  O13  1  0.535  0.146  0.670  1.0
  O  O14  1  0.713  0.948  0.594  1.0
  O  O15  1  0.287  0.052  0.406  1.0
  O  O16  1  0.287  0.552  0.094  1.0
  O  O17  1  0.713  0.448  0.906  1.0
  O  O18  1  0.345  0.917  0.867  1.0
  O  O19  1  0.655  0.083  0.133  1.0
  O  O20  1  0.655  0.583  0.367  1.0
  O  O21  1  0.345  0.417  0.633  1.0
  O  O22  1  0.853  0.712  0.943  1.0
  O  O23  1  0.147  0.288  0.057  1.0
  O  O24  1  0.147  0.788  0.443  1.0
  O  O25  1  0.853  0.212  0.557  1.0
  O  O26  1  0.413  0.572  0.624  1.0
  O  O27  1  0.587  0.428  0.376  1.0
  O  O28  1  0.587  0.928  0.124  1.0
  O  O29  1  0.413  0.072  0.876  1.0
  O  O30  1  0.935  0.007  0.966  1.0
  O  O31  1  0.065  0.993  0.034  1.0
  O  O32  1  0.065  0.493  0.466  1.0
  O  O33  1  0.935  0.507  0.534  1.0
  O  O34  1  0.914  0.614  0.778  1.0
  O  O35  1  0.086  0.386  0.222  1.0
  O  O36  1  0.086  0.886  0.278  1.0
  O  O37  1  0.914  0.114  0.722  1.0
[/CIF]
.
The crystal structure described by Rb2Zn(SO6)2O2 crystallizes in the monoclinic P2_1/c space group. The structure consists of two hydrogen peroxide molecules inside a Rb2Zn(SO6)2 framework. In the Rb2Zn(SO6)2 framework, Rb(1) is bonded in a 8-coordinate geometry to one O(1), one O(3), one O(4), one O(5), two equivalent O(2), and two equivalent O(7) atoms. Zn(1) is bonded in a distorted square co-planar geometry to two equivalent O(3) and two equivalent O(5) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(7) atom. There are six inequivalent O sites. In the first O site, O(7) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Rb(1) and one S(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one S(1) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one Rb(1), one Zn(1), and one O(5) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(1) and one S(1) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to one Rb(1), one Zn(1), and one O(3) atom. is represented by the CIF card [CIF]
data_Rb2Zn(SO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.995
_cell_length_b   8.814
_cell_length_c   13.572
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   101.108
_symmetry_Int_Tables_number   1
_cell_volume   703.667
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.835  0.626  0.152  1.0
  Rb  Rb1  1  0.165  0.374  0.848  1.0
  Rb  Rb2  1  0.165  0.874  0.652  1.0
  Rb  Rb3  1  0.835  0.126  0.348  1.0
  Zn  Zn4  1  0.500  0.000  0.000  1.0
  Zn  Zn5  1  0.500  0.500  0.500  1.0
  S  S6  1  0.752  0.606  0.861  1.0
  S  S7  1  0.248  0.394  0.139  1.0
  S  S8  1  0.248  0.894  0.361  1.0
  S  S9  1  0.752  0.106  0.639  1.0
  O  O10  1  0.535  0.646  0.830  1.0
  O  O11  1  0.465  0.354  0.170  1.0
  O  O12  1  0.465  0.854  0.330  1.0
  O  O13  1  0.535  0.146  0.670  1.0
  O  O14  1  0.713  0.948  0.594  1.0
  O  O15  1  0.287  0.052  0.406  1.0
  O  O16  1  0.287  0.552  0.094  1.0
  O  O17  1  0.713  0.448  0.906  1.0
  O  O18  1  0.345  0.917  0.867  1.0
  O  O19  1  0.655  0.083  0.133  1.0
  O  O20  1  0.655  0.583  0.367  1.0
  O  O21  1  0.345  0.417  0.633  1.0
  O  O22  1  0.853  0.712  0.943  1.0
  O  O23  1  0.147  0.288  0.057  1.0
  O  O24  1  0.147  0.788  0.443  1.0
  O  O25  1  0.853  0.212  0.557  1.0
  O  O26  1  0.413  0.572  0.624  1.0
  O  O27  1  0.587  0.428  0.376  1.0
  O  O28  1  0.587  0.928  0.124  1.0
  O  O29  1  0.413  0.072  0.876  1.0
  O  O30  1  0.935  0.007  0.966  1.0
  O  O31  1  0.065  0.993  0.034  1.0
  O  O32  1  0.065  0.493  0.466  1.0
  O  O33  1  0.935  0.507  0.534  1.0
  O  O34  1  0.914  0.614  0.778  1.0
  O  O35  1  0.086  0.386  0.222  1.0
  O  O36  1  0.086  0.886  0.278  1.0
  O  O37  1  0.914  0.114  0.722  1.0
[/CIF]
.