The structure described by (Na3H19O11)2(TlCl6)2(H2)4H2O2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, one water molecule, one Na3H19O11 cluster, and one TlCl6 cluster. In the Na3H19O11 cluster, there are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Na site, Na(2) is bonded in a distorted octahedral geometry to one O(1), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. In the third Na site, Na(3) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. There are nineteen inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(7) is bonded in a single-bond geometry to one O(1) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one O(4) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one O(3) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one O(6) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one O(5) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one O(3) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one O(4) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one O(5) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one O(6) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one O(7) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one O(8) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one O(8) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one O(7) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one O(11) atom. In the eighteenth H site, H(23) is bonded in a single-bond geometry to one O(9) atom. In the nineteenth H site, H(24) is bonded in a single-bond geometry to one O(10) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(6), and one H(7) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Na(1), one H(5), and one H(8) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(10), and one H(13) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(14), and one H(9) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Na(2), one Na(3), one H(12), and one H(15) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Na(2), one Na(3), one H(11), and one H(16) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Na(3), one H(17), and one H(20) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Na(2), one Na(3), one H(18), and one H(19) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Na(3) and one H(23) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Na(3) and one H(24) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Na(3) and one H(21) atom. In the TlCl6 cluster, Tl(1) is bonded in an octahedral geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), one Cl(5), and one Cl(6) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Tl(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Tl(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Tl(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Tl(1) atom. In the fifth Cl site, Cl(3) is bonded in a single-bond geometry to one Tl(1) atom. In the sixth Cl site, Cl(4) is bonded in a single-bond geometry to one Tl(1) atom. is represented by the CIF card [CIF]
data_Na3TlH24(ClO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.775
_cell_length_b   8.778
_cell_length_c   8.851
_cell_angle_alpha   71.403
_cell_angle_beta   73.614
_cell_angle_gamma   73.158
_symmetry_Int_Tables_number   1
_cell_volume   604.761
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.357  0.318  0.322  1.0
  Na  Na1  1  0.503  0.480  0.515  1.0
  Na  Na2  1  0.670  0.669  0.693  1.0
  Tl  Tl3  1  0.020  0.979  0.980  1.0
  H  H4  1  0.139  0.129  0.399  1.0
  H  H5  1  0.111  0.392  0.143  1.0
  H  H6  1  0.117  0.478  0.134  1.0
  H  H7  1  0.138  0.134  0.483  1.0
  H  H8  1  0.387  0.128  0.076  1.0
  H  H9  1  0.169  0.438  0.609  1.0
  H  H10  1  0.141  0.609  0.482  1.0
  H  H11  1  0.562  0.128  0.081  1.0
  H  H12  1  0.491  0.108  0.625  1.0
  H  H13  1  0.447  0.621  0.180  1.0
  H  H14  1  0.376  0.827  0.540  1.0
  H  H15  1  0.368  0.556  0.831  1.0
  H  H16  1  0.615  0.503  0.137  1.0
  H  H17  1  0.630  0.126  0.473  1.0
  H  H18  1  0.479  0.383  0.886  1.0
  H  H19  1  0.522  0.833  0.388  1.0
  H  H20  1  0.442  0.894  0.904  1.0
  H  H21  1  0.835  0.544  0.392  1.0
  H  H22  1  0.845  0.387  0.542  1.0
  H  H23  1  0.614  0.935  0.851  1.0
  H  H24  1  0.952  0.395  0.883  1.0
  H  H25  1  0.967  0.924  0.365  1.0
  H  H26  1  0.843  0.636  0.982  1.0
  H  H27  1  0.861  0.938  0.639  1.0
  Cl  Cl28  1  0.182  0.214  0.823  1.0
  Cl  Cl29  1  0.267  0.855  0.143  1.0
  Cl  Cl30  1  0.171  0.781  0.798  1.0
  Cl  Cl31  1  0.867  0.151  0.192  1.0
  Cl  Cl32  1  0.821  0.777  0.153  1.0
  Cl  Cl33  1  0.809  0.119  0.785  1.0
  O  O34  1  0.215  0.499  0.499  1.0
  O  O35  1  0.450  0.190  0.100  1.0
  O  O36  1  0.514  0.511  0.220  1.0
  O  O37  1  0.520  0.183  0.517  1.0
  O  O38  1  0.474  0.485  0.798  1.0
  O  O39  1  0.485  0.767  0.498  1.0
  O  O40  1  0.535  0.906  0.811  1.0
  O  O41  1  0.775  0.492  0.499  1.0
  O  O42  1  0.781  0.572  0.956  1.0
  O  O43  1  0.831  0.879  0.576  1.0
  O  O44  1  0.894  0.503  0.825  1.0
  O  O45  1  0.986  0.836  0.465  1.0
[/CIF]
.
The structure described by (Na3H19O11)2(TlCl6)2(H2)4H2O2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, one water molecule, one Na3H19O11 cluster, and one TlCl6 cluster. In the Na3H19O11 cluster, there are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Na site, Na(2) is bonded in a distorted octahedral geometry to one O(1), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. In the third Na site, Na(3) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. There are nineteen inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(7) is bonded in a single-bond geometry to one O(1) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one O(4) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one O(3) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one O(6) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one O(5) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one O(3) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one O(4) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one O(5) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one O(6) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one O(7) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one O(8) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one O(8) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one O(7) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one O(11) atom. In the eighteenth H site, H(23) is bonded in a single-bond geometry to one O(9) atom. In the nineteenth H site, H(24) is bonded in a single-bond geometry to one O(10) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(6), and one H(7) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Na(1), one H(5), and one H(8) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(10), and one H(13) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Na(1), one Na(2), one H(14), and one H(9) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Na(2), one Na(3), one H(12), and one H(15) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Na(2), one Na(3), one H(11), and one H(16) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Na(3), one H(17), and one H(20) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Na(2), one Na(3), one H(18), and one H(19) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Na(3) and one H(23) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Na(3) and one H(24) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Na(3) and one H(21) atom. In the TlCl6 cluster, Tl(1) is bonded in an octahedral geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), one Cl(5), and one Cl(6) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Tl(1) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Tl(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Tl(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Tl(1) atom. In the fifth Cl site, Cl(3) is bonded in a single-bond geometry to one Tl(1) atom. In the sixth Cl site, Cl(4) is bonded in a single-bond geometry to one Tl(1) atom. is represented by the CIF card [CIF]
data_Na3TlH24(ClO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.775
_cell_length_b   8.778
_cell_length_c   8.851
_cell_angle_alpha   71.403
_cell_angle_beta   73.614
_cell_angle_gamma   73.158
_symmetry_Int_Tables_number   1
_cell_volume   604.761
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.357  0.318  0.322  1.0
  Na  Na1  1  0.503  0.480  0.515  1.0
  Na  Na2  1  0.670  0.669  0.693  1.0
  Tl  Tl3  1  0.020  0.979  0.980  1.0
  H  H4  1  0.139  0.129  0.399  1.0
  H  H5  1  0.111  0.392  0.143  1.0
  H  H6  1  0.117  0.478  0.134  1.0
  H  H7  1  0.138  0.134  0.483  1.0
  H  H8  1  0.387  0.128  0.076  1.0
  H  H9  1  0.169  0.438  0.609  1.0
  H  H10  1  0.141  0.609  0.482  1.0
  H  H11  1  0.562  0.128  0.081  1.0
  H  H12  1  0.491  0.108  0.625  1.0
  H  H13  1  0.447  0.621  0.180  1.0
  H  H14  1  0.376  0.827  0.540  1.0
  H  H15  1  0.368  0.556  0.831  1.0
  H  H16  1  0.615  0.503  0.137  1.0
  H  H17  1  0.630  0.126  0.473  1.0
  H  H18  1  0.479  0.383  0.886  1.0
  H  H19  1  0.522  0.833  0.388  1.0
  H  H20  1  0.442  0.894  0.904  1.0
  H  H21  1  0.835  0.544  0.392  1.0
  H  H22  1  0.845  0.387  0.542  1.0
  H  H23  1  0.614  0.935  0.851  1.0
  H  H24  1  0.952  0.395  0.883  1.0
  H  H25  1  0.967  0.924  0.365  1.0
  H  H26  1  0.843  0.636  0.982  1.0
  H  H27  1  0.861  0.938  0.639  1.0
  Cl  Cl28  1  0.182  0.214  0.823  1.0
  Cl  Cl29  1  0.267  0.855  0.143  1.0
  Cl  Cl30  1  0.171  0.781  0.798  1.0
  Cl  Cl31  1  0.867  0.151  0.192  1.0
  Cl  Cl32  1  0.821  0.777  0.153  1.0
  Cl  Cl33  1  0.809  0.119  0.785  1.0
  O  O34  1  0.215  0.499  0.499  1.0
  O  O35  1  0.450  0.190  0.100  1.0
  O  O36  1  0.514  0.511  0.220  1.0
  O  O37  1  0.520  0.183  0.517  1.0
  O  O38  1  0.474  0.485  0.798  1.0
  O  O39  1  0.485  0.767  0.498  1.0
  O  O40  1  0.535  0.906  0.811  1.0
  O  O41  1  0.775  0.492  0.499  1.0
  O  O42  1  0.781  0.572  0.956  1.0
  O  O43  1  0.831  0.879  0.576  1.0
  O  O44  1  0.894  0.503  0.825  1.0
  O  O45  1  0.986  0.836  0.465  1.0
[/CIF]
.