The material structure described by LiEu(PO3)4 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(4) and two equivalent O(6) atoms. Eu(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form corner-sharing PO4 tetrahedra. There are six inequivalent O sites. In the first O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one Eu(1), and one P(2) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the third O site, O(2) is bonded in a 2-coordinate geometry to one Eu(1) and one P(2) atom. In the fourth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Eu(1) and one P(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Li(1), one Eu(1), and one P(1) atom. In the sixth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(2) atom. is represented by the CIF card [CIF]
data_LiEu(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.074
_cell_length_b   9.074
_cell_length_c   9.889
_cell_angle_alpha   57.050
_cell_angle_beta   57.050
_cell_angle_gamma   46.671
_symmetry_Int_Tables_number   1
_cell_volume   477.222
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.798  0.202  0.250  1.0
  Li  Li1  1  0.202  0.798  0.750  1.0
  Eu  Eu2  1  0.700  0.300  0.750  1.0
  Eu  Eu3  1  0.300  0.700  0.250  1.0
  P  P4  1  0.917  0.806  0.662  1.0
  P  P5  1  0.083  0.194  0.338  1.0
  P  P6  1  0.805  0.491  0.902  1.0
  P  P7  1  0.195  0.509  0.098  1.0
  P  P8  1  0.194  0.083  0.838  1.0
  P  P9  1  0.509  0.195  0.598  1.0
  P  P10  1  0.491  0.805  0.402  1.0
  P  P11  1  0.806  0.917  0.162  1.0
  O  O12  1  0.719  0.962  0.587  1.0
  O  O13  1  0.038  0.281  0.913  1.0
  O  O14  1  0.744  0.512  0.776  1.0
  O  O15  1  0.329  0.899  0.954  1.0
  O  O16  1  0.059  0.075  0.296  1.0
  O  O17  1  0.101  0.671  0.546  1.0
  O  O18  1  0.899  0.329  0.454  1.0
  O  O19  1  0.330  0.160  0.658  1.0
  O  O20  1  0.840  0.670  0.842  1.0
  O  O21  1  0.256  0.488  0.224  1.0
  O  O22  1  0.962  0.719  0.087  1.0
  O  O23  1  0.488  0.256  0.724  1.0
  O  O24  1  0.670  0.478  0.081  1.0
  O  O25  1  0.670  0.840  0.342  1.0
  O  O26  1  0.522  0.330  0.419  1.0
  O  O27  1  0.075  0.059  0.796  1.0
  O  O28  1  0.478  0.670  0.581  1.0
  O  O29  1  0.330  0.522  0.919  1.0
  O  O30  1  0.512  0.744  0.276  1.0
  O  O31  1  0.941  0.925  0.704  1.0
  O  O32  1  0.160  0.330  0.158  1.0
  O  O33  1  0.281  0.038  0.413  1.0
  O  O34  1  0.671  0.101  0.046  1.0
  O  O35  1  0.925  0.941  0.204  1.0
[/CIF]
.
The material structure described by LiEu(PO3)4 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(4) and two equivalent O(6) atoms. Eu(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(3), one O(4), and one O(5) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form corner-sharing PO4 tetrahedra. There are six inequivalent O sites. In the first O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one Eu(1), and one P(2) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the third O site, O(2) is bonded in a 2-coordinate geometry to one Eu(1) and one P(2) atom. In the fourth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Eu(1) and one P(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Li(1), one Eu(1), and one P(1) atom. In the sixth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one P(1) and one P(2) atom. is represented by the CIF card [CIF]
data_LiEu(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.074
_cell_length_b   9.074
_cell_length_c   9.889
_cell_angle_alpha   57.050
_cell_angle_beta   57.050
_cell_angle_gamma   46.671
_symmetry_Int_Tables_number   1
_cell_volume   477.222
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.798  0.202  0.250  1.0
  Li  Li1  1  0.202  0.798  0.750  1.0
  Eu  Eu2  1  0.700  0.300  0.750  1.0
  Eu  Eu3  1  0.300  0.700  0.250  1.0
  P  P4  1  0.917  0.806  0.662  1.0
  P  P5  1  0.083  0.194  0.338  1.0
  P  P6  1  0.805  0.491  0.902  1.0
  P  P7  1  0.195  0.509  0.098  1.0
  P  P8  1  0.194  0.083  0.838  1.0
  P  P9  1  0.509  0.195  0.598  1.0
  P  P10  1  0.491  0.805  0.402  1.0
  P  P11  1  0.806  0.917  0.162  1.0
  O  O12  1  0.719  0.962  0.587  1.0
  O  O13  1  0.038  0.281  0.913  1.0
  O  O14  1  0.744  0.512  0.776  1.0
  O  O15  1  0.329  0.899  0.954  1.0
  O  O16  1  0.059  0.075  0.296  1.0
  O  O17  1  0.101  0.671  0.546  1.0
  O  O18  1  0.899  0.329  0.454  1.0
  O  O19  1  0.330  0.160  0.658  1.0
  O  O20  1  0.840  0.670  0.842  1.0
  O  O21  1  0.256  0.488  0.224  1.0
  O  O22  1  0.962  0.719  0.087  1.0
  O  O23  1  0.488  0.256  0.724  1.0
  O  O24  1  0.670  0.478  0.081  1.0
  O  O25  1  0.670  0.840  0.342  1.0
  O  O26  1  0.522  0.330  0.419  1.0
  O  O27  1  0.075  0.059  0.796  1.0
  O  O28  1  0.478  0.670  0.581  1.0
  O  O29  1  0.330  0.522  0.919  1.0
  O  O30  1  0.512  0.744  0.276  1.0
  O  O31  1  0.941  0.925  0.704  1.0
  O  O32  1  0.160  0.330  0.158  1.0
  O  O33  1  0.281  0.038  0.413  1.0
  O  O34  1  0.671  0.101  0.046  1.0
  O  O35  1  0.925  0.941  0.204  1.0
[/CIF]
.