The material described by WIn2O6 crystallizes in the monoclinic P2/c space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted WO6 octahedra that share corners with four equivalent In(2)O6 octahedra and  an edgeedge with one In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. In the second In site, In(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form InO6 octahedra that share corners with four equivalent W(1)O6 octahedra and  an edgeedge with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. In the third In site, In(3) is bonded in a 6-coordinate geometry to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1), one In(1), and one In(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one W(1), one In(1), and one In(2) atom. In the third O site, O(3) is bonded to one W(1), one In(1), one In(2), and one In(3) atom to form a mixture of distorted corner and edge-sharing OIn3W tetrahedra. In the fourth O site, O(4) is bonded to one W(1), one In(1), one In(2), and one In(3) atom to form a mixture of distorted corner and edge-sharing OIn3W trigonal pyramids. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one W(1) and one In(2) atom. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one W(1), one In(2), and one In(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_In2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.194
_cell_length_b   7.504
_cell_length_c   11.882
_cell_angle_alpha   82.639
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   459.272
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.780  0.000  0.750  1.0
  In  In1  1  0.220  0.000  0.250  1.0
  In  In2  1  0.236  0.768  0.604  1.0
  In  In3  1  0.764  0.768  0.104  1.0
  In  In4  1  0.706  0.500  0.750  1.0
  In  In5  1  0.294  0.500  0.250  1.0
  In  In6  1  0.236  0.232  0.896  1.0
  In  In7  1  0.764  0.232  0.396  1.0
  W  W8  1  0.268  0.736  0.893  1.0
  W  W9  1  0.732  0.736  0.393  1.0
  W  W10  1  0.268  0.264  0.607  1.0
  W  W11  1  0.732  0.264  0.107  1.0
  O  O12  1  0.088  0.971  0.874  1.0
  O  O13  1  0.563  0.841  0.947  1.0
  O  O14  1  0.912  0.971  0.374  1.0
  O  O15  1  0.506  0.792  0.737  1.0
  O  O16  1  0.437  0.841  0.447  1.0
  O  O17  1  0.011  0.691  0.773  1.0
  O  O18  1  0.494  0.792  0.237  1.0
  O  O19  1  0.895  0.665  0.529  1.0
  O  O20  1  0.410  0.501  0.882  1.0
  O  O21  1  0.989  0.691  0.273  1.0
  O  O22  1  0.410  0.499  0.618  1.0
  O  O23  1  0.895  0.335  0.971  1.0
  O  O24  1  0.105  0.665  0.029  1.0
  O  O25  1  0.590  0.501  0.382  1.0
  O  O26  1  0.011  0.309  0.727  1.0
  O  O27  1  0.590  0.499  0.118  1.0
  O  O28  1  0.105  0.335  0.471  1.0
  O  O29  1  0.506  0.208  0.763  1.0
  O  O30  1  0.989  0.309  0.227  1.0
  O  O31  1  0.563  0.159  0.553  1.0
  O  O32  1  0.494  0.208  0.263  1.0
  O  O33  1  0.088  0.029  0.626  1.0
  O  O34  1  0.437  0.159  0.053  1.0
  O  O35  1  0.912  0.029  0.126  1.0
[/CIF]
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The material described by WIn2O6 crystallizes in the monoclinic P2/c space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted WO6 octahedra that share corners with four equivalent In(2)O6 octahedra and  an edgeedge with one In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. In the second In site, In(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form InO6 octahedra that share corners with four equivalent W(1)O6 octahedra and  an edgeedge with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. In the third In site, In(3) is bonded in a 6-coordinate geometry to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1), one In(1), and one In(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one W(1), one In(1), and one In(2) atom. In the third O site, O(3) is bonded to one W(1), one In(1), one In(2), and one In(3) atom to form a mixture of distorted corner and edge-sharing OIn3W tetrahedra. In the fourth O site, O(4) is bonded to one W(1), one In(1), one In(2), and one In(3) atom to form a mixture of distorted corner and edge-sharing OIn3W trigonal pyramids. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one W(1) and one In(2) atom. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one W(1), one In(2), and one In(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_In2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.194
_cell_length_b   7.504
_cell_length_c   11.882
_cell_angle_alpha   82.639
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   459.272
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.780  0.000  0.750  1.0
  In  In1  1  0.220  0.000  0.250  1.0
  In  In2  1  0.236  0.768  0.604  1.0
  In  In3  1  0.764  0.768  0.104  1.0
  In  In4  1  0.706  0.500  0.750  1.0
  In  In5  1  0.294  0.500  0.250  1.0
  In  In6  1  0.236  0.232  0.896  1.0
  In  In7  1  0.764  0.232  0.396  1.0
  W  W8  1  0.268  0.736  0.893  1.0
  W  W9  1  0.732  0.736  0.393  1.0
  W  W10  1  0.268  0.264  0.607  1.0
  W  W11  1  0.732  0.264  0.107  1.0
  O  O12  1  0.088  0.971  0.874  1.0
  O  O13  1  0.563  0.841  0.947  1.0
  O  O14  1  0.912  0.971  0.374  1.0
  O  O15  1  0.506  0.792  0.737  1.0
  O  O16  1  0.437  0.841  0.447  1.0
  O  O17  1  0.011  0.691  0.773  1.0
  O  O18  1  0.494  0.792  0.237  1.0
  O  O19  1  0.895  0.665  0.529  1.0
  O  O20  1  0.410  0.501  0.882  1.0
  O  O21  1  0.989  0.691  0.273  1.0
  O  O22  1  0.410  0.499  0.618  1.0
  O  O23  1  0.895  0.335  0.971  1.0
  O  O24  1  0.105  0.665  0.029  1.0
  O  O25  1  0.590  0.501  0.382  1.0
  O  O26  1  0.011  0.309  0.727  1.0
  O  O27  1  0.590  0.499  0.118  1.0
  O  O28  1  0.105  0.335  0.471  1.0
  O  O29  1  0.506  0.208  0.763  1.0
  O  O30  1  0.989  0.309  0.227  1.0
  O  O31  1  0.563  0.159  0.553  1.0
  O  O32  1  0.494  0.208  0.263  1.0
  O  O33  1  0.088  0.029  0.626  1.0
  O  O34  1  0.437  0.159  0.053  1.0
  O  O35  1  0.912  0.029  0.126  1.0
[/CIF]
.