The structure described by Nb(Te2I3)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Nb(Te2I3)2 cluster. Nb(1) is bonded in a 8-coordinate geometry to one Te(1), one Te(3), two equivalent Te(2), two equivalent Te(4), one I(1), and one I(6) atom. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one Nb(1), one I(1), one I(3), one I(5), and one I(6) atom. In the second Te site, Te(2) is bonded in a 3-coordinate geometry to two equivalent Nb(1) and one Te(4) atom. In the third Te site, Te(3) is bonded in a 5-coordinate geometry to one Nb(1), one I(1), one I(2), one I(4), and one I(6) atom. In the fourth Te site, Te(4) is bonded in a 3-coordinate geometry to two equivalent Nb(1) and one Te(2) atom. There are six inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one Nb(1), one Te(1), and one Te(3) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Te(3) atom. In the third I site, I(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth I site, I(4) is bonded in a single-bond geometry to one Te(3) atom. In the fifth I site, I(5) is bonded in a single-bond geometry to one Te(1) atom. In the sixth I site, I(6) is bonded in a 3-coordinate geometry to one Nb(1), one Te(1), and one Te(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Nb(Te2I3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.325
_cell_length_b   11.527
_cell_length_c   12.348
_cell_angle_alpha   111.464
_cell_angle_beta   107.389
_cell_angle_gamma   98.417
_symmetry_Int_Tables_number   1
_cell_volume   1007.783
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.487  0.354  0.459  1.0
  Nb  Nb1  1  0.513  0.646  0.541  1.0
  Te  Te2  1  0.583  0.837  0.801  1.0
  Te  Te3  1  0.719  0.523  0.416  1.0
  Te  Te4  1  0.281  0.477  0.584  1.0
  Te  Te5  1  0.525  0.218  0.623  1.0
  Te  Te6  1  0.785  0.557  0.656  1.0
  Te  Te7  1  0.475  0.782  0.377  1.0
  Te  Te8  1  0.417  0.163  0.199  1.0
  Te  Te9  1  0.215  0.443  0.344  1.0
  I  I10  1  0.793  0.896  0.639  1.0
  I  I11  1  0.159  0.650  0.158  1.0
  I  I12  1  0.207  0.104  0.361  1.0
  I  I13  1  0.669  0.232  0.108  1.0
  I  I14  1  0.703  0.743  0.248  1.0
  I  I15  1  0.297  0.257  0.752  1.0
  I  I16  1  0.862  0.804  0.973  1.0
  I  I17  1  0.841  0.350  0.842  1.0
  I  I18  1  0.271  0.814  0.562  1.0
  I  I19  1  0.138  0.196  0.027  1.0
  I  I20  1  0.331  0.768  0.892  1.0
  I  I21  1  0.729  0.186  0.438  1.0
[/CIF]
.
The structure described by Nb(Te2I3)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Nb(Te2I3)2 cluster. Nb(1) is bonded in a 8-coordinate geometry to one Te(1), one Te(3), two equivalent Te(2), two equivalent Te(4), one I(1), and one I(6) atom. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one Nb(1), one I(1), one I(3), one I(5), and one I(6) atom. In the second Te site, Te(2) is bonded in a 3-coordinate geometry to two equivalent Nb(1) and one Te(4) atom. In the third Te site, Te(3) is bonded in a 5-coordinate geometry to one Nb(1), one I(1), one I(2), one I(4), and one I(6) atom. In the fourth Te site, Te(4) is bonded in a 3-coordinate geometry to two equivalent Nb(1) and one Te(2) atom. There are six inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one Nb(1), one Te(1), and one Te(3) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Te(3) atom. In the third I site, I(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth I site, I(4) is bonded in a single-bond geometry to one Te(3) atom. In the fifth I site, I(5) is bonded in a single-bond geometry to one Te(1) atom. In the sixth I site, I(6) is bonded in a 3-coordinate geometry to one Nb(1), one Te(1), and one Te(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Nb(Te2I3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.325
_cell_length_b   11.527
_cell_length_c   12.348
_cell_angle_alpha   111.464
_cell_angle_beta   107.389
_cell_angle_gamma   98.417
_symmetry_Int_Tables_number   1
_cell_volume   1007.783
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.487  0.354  0.459  1.0
  Nb  Nb1  1  0.513  0.646  0.541  1.0
  Te  Te2  1  0.583  0.837  0.801  1.0
  Te  Te3  1  0.719  0.523  0.416  1.0
  Te  Te4  1  0.281  0.477  0.584  1.0
  Te  Te5  1  0.525  0.218  0.623  1.0
  Te  Te6  1  0.785  0.557  0.656  1.0
  Te  Te7  1  0.475  0.782  0.377  1.0
  Te  Te8  1  0.417  0.163  0.199  1.0
  Te  Te9  1  0.215  0.443  0.344  1.0
  I  I10  1  0.793  0.896  0.639  1.0
  I  I11  1  0.159  0.650  0.158  1.0
  I  I12  1  0.207  0.104  0.361  1.0
  I  I13  1  0.669  0.232  0.108  1.0
  I  I14  1  0.703  0.743  0.248  1.0
  I  I15  1  0.297  0.257  0.752  1.0
  I  I16  1  0.862  0.804  0.973  1.0
  I  I17  1  0.841  0.350  0.842  1.0
  I  I18  1  0.271  0.814  0.562  1.0
  I  I19  1  0.138  0.196  0.027  1.0
  I  I20  1  0.331  0.768  0.892  1.0
  I  I21  1  0.729  0.186  0.438  1.0
[/CIF]
.