The structure described by RbDy2Ag3Te5 crystallizes in the orthorhombic Cmcm space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent Te(2), two equivalent Te(3), and four equivalent Te(1) atoms. Dy(1) is bonded to one Te(3), two equivalent Te(1), and three equivalent Te(2) atoms to form distorted DyTe6 octahedra that share  a cornercorner with one Dy(1)Te6 octahedra, corners with four equivalent Ag(2)Te4 tetrahedra, edges with four equivalent Dy(1)Te6 octahedra, edges with two equivalent Ag(1)Te4 tetrahedra, and edges with three equivalent Ag(2)Te4 tetrahedra. The corner-sharing octahedral tilt angles are 43°. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent Te(1) and two equivalent Te(3) atoms to form distorted AgTe4 tetrahedra that share corners with two equivalent Ag(1)Te4 tetrahedra, corners with four equivalent Ag(2)Te4 tetrahedra, and edges with four equivalent Dy(1)Te6 octahedra. In the second Ag site, Ag(2) is bonded to two equivalent Te(1) and two equivalent Te(2) atoms to form distorted AgTe4 tetrahedra that share corners with four equivalent Dy(1)Te6 octahedra, corners with two equivalent Ag(1)Te4 tetrahedra, corners with two equivalent Ag(2)Te4 tetrahedra, edges with three equivalent Dy(1)Te6 octahedra, and  an edgeedge with one Ag(2)Te4 tetrahedra. The corner-sharing octahedral tilt angles range from 12-63°. There are three inequivalent Te sites. In the first Te site, Te(3) is bonded in a 6-coordinate geometry to two equivalent Rb(1), two equivalent Dy(1), and two equivalent Ag(1) atoms. In the second Te site, Te(1) is bonded to two equivalent Rb(1), two equivalent Dy(1), one Ag(1), and two equivalent Ag(2) atoms to form distorted TeRb2Dy2Ag3 pentagonal bipyramids that share corners with four equivalent Te(2)RbDy3Ag2 octahedra, corners with two equivalent Te(1)Rb2Dy2Ag3 pentagonal bipyramids, edges with five equivalent Te(2)RbDy3Ag2 octahedra, edges with three equivalent Te(1)Rb2Dy2Ag3 pentagonal bipyramids, and  a faceface with one Te(1)Rb2Dy2Ag3 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 2-37°. In the third Te site, Te(2) is bonded to one Rb(1), three equivalent Dy(1), and two equivalent Ag(2) atoms to form distorted TeRbDy3Ag2 octahedra that share  a cornercorner with one Te(2)RbDy3Ag2 octahedra, corners with four equivalent Te(1)Rb2Dy2Ag3 pentagonal bipyramids, edges with four equivalent Te(2)RbDy3Ag2 octahedra, and edges with five equivalent Te(1)Rb2Dy2Ag3 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 61°. is represented by the CIF card [CIF]
data_RbDy2Ag3Te5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.578
_cell_length_b   8.475
_cell_length_c   18.501
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   105.671
_symmetry_Int_Tables_number   1
_cell_volume   691.192
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.443  0.885  0.250  1.0
  Rb  Rb1  1  0.557  0.115  0.750  1.0
  Dy  Dy2  1  0.309  0.618  0.905  1.0
  Dy  Dy3  1  0.691  0.382  0.095  1.0
  Dy  Dy4  1  0.309  0.618  0.595  1.0
  Dy  Dy5  1  0.691  0.382  0.405  1.0
  Ag  Ag6  1  0.164  0.328  0.250  1.0
  Ag  Ag7  1  0.836  0.672  0.750  1.0
  Ag  Ag8  1  0.916  0.832  0.468  1.0
  Ag  Ag9  1  0.084  0.168  0.532  1.0
  Ag  Ag10  1  0.916  0.832  0.032  1.0
  Ag  Ag11  1  0.084  0.168  0.968  1.0
  Te  Te12  1  0.937  0.874  0.879  1.0
  Te  Te13  1  0.063  0.126  0.121  1.0
  Te  Te14  1  0.937  0.874  0.621  1.0
  Te  Te15  1  0.063  0.126  0.379  1.0
  Te  Te16  1  0.677  0.354  0.928  1.0
  Te  Te17  1  0.323  0.646  0.072  1.0
  Te  Te18  1  0.677  0.354  0.572  1.0
  Te  Te19  1  0.323  0.646  0.428  1.0
  Te  Te20  1  0.761  0.521  0.250  1.0
  Te  Te21  1  0.239  0.479  0.750  1.0
[/CIF]
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The structure described by RbDy2Ag3Te5 crystallizes in the orthorhombic Cmcm space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent Te(2), two equivalent Te(3), and four equivalent Te(1) atoms. Dy(1) is bonded to one Te(3), two equivalent Te(1), and three equivalent Te(2) atoms to form distorted DyTe6 octahedra that share  a cornercorner with one Dy(1)Te6 octahedra, corners with four equivalent Ag(2)Te4 tetrahedra, edges with four equivalent Dy(1)Te6 octahedra, edges with two equivalent Ag(1)Te4 tetrahedra, and edges with three equivalent Ag(2)Te4 tetrahedra. The corner-sharing octahedral tilt angles are 43°. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent Te(1) and two equivalent Te(3) atoms to form distorted AgTe4 tetrahedra that share corners with two equivalent Ag(1)Te4 tetrahedra, corners with four equivalent Ag(2)Te4 tetrahedra, and edges with four equivalent Dy(1)Te6 octahedra. In the second Ag site, Ag(2) is bonded to two equivalent Te(1) and two equivalent Te(2) atoms to form distorted AgTe4 tetrahedra that share corners with four equivalent Dy(1)Te6 octahedra, corners with two equivalent Ag(1)Te4 tetrahedra, corners with two equivalent Ag(2)Te4 tetrahedra, edges with three equivalent Dy(1)Te6 octahedra, and  an edgeedge with one Ag(2)Te4 tetrahedra. The corner-sharing octahedral tilt angles range from 12-63°. There are three inequivalent Te sites. In the first Te site, Te(3) is bonded in a 6-coordinate geometry to two equivalent Rb(1), two equivalent Dy(1), and two equivalent Ag(1) atoms. In the second Te site, Te(1) is bonded to two equivalent Rb(1), two equivalent Dy(1), one Ag(1), and two equivalent Ag(2) atoms to form distorted TeRb2Dy2Ag3 pentagonal bipyramids that share corners with four equivalent Te(2)RbDy3Ag2 octahedra, corners with two equivalent Te(1)Rb2Dy2Ag3 pentagonal bipyramids, edges with five equivalent Te(2)RbDy3Ag2 octahedra, edges with three equivalent Te(1)Rb2Dy2Ag3 pentagonal bipyramids, and  a faceface with one Te(1)Rb2Dy2Ag3 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 2-37°. In the third Te site, Te(2) is bonded to one Rb(1), three equivalent Dy(1), and two equivalent Ag(2) atoms to form distorted TeRbDy3Ag2 octahedra that share  a cornercorner with one Te(2)RbDy3Ag2 octahedra, corners with four equivalent Te(1)Rb2Dy2Ag3 pentagonal bipyramids, edges with four equivalent Te(2)RbDy3Ag2 octahedra, and edges with five equivalent Te(1)Rb2Dy2Ag3 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 61°. is represented by the CIF card [CIF]
data_RbDy2Ag3Te5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.578
_cell_length_b   8.475
_cell_length_c   18.501
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   105.671
_symmetry_Int_Tables_number   1
_cell_volume   691.192
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.443  0.885  0.250  1.0
  Rb  Rb1  1  0.557  0.115  0.750  1.0
  Dy  Dy2  1  0.309  0.618  0.905  1.0
  Dy  Dy3  1  0.691  0.382  0.095  1.0
  Dy  Dy4  1  0.309  0.618  0.595  1.0
  Dy  Dy5  1  0.691  0.382  0.405  1.0
  Ag  Ag6  1  0.164  0.328  0.250  1.0
  Ag  Ag7  1  0.836  0.672  0.750  1.0
  Ag  Ag8  1  0.916  0.832  0.468  1.0
  Ag  Ag9  1  0.084  0.168  0.532  1.0
  Ag  Ag10  1  0.916  0.832  0.032  1.0
  Ag  Ag11  1  0.084  0.168  0.968  1.0
  Te  Te12  1  0.937  0.874  0.879  1.0
  Te  Te13  1  0.063  0.126  0.121  1.0
  Te  Te14  1  0.937  0.874  0.621  1.0
  Te  Te15  1  0.063  0.126  0.379  1.0
  Te  Te16  1  0.677  0.354  0.928  1.0
  Te  Te17  1  0.323  0.646  0.072  1.0
  Te  Te18  1  0.677  0.354  0.572  1.0
  Te  Te19  1  0.323  0.646  0.428  1.0
  Te  Te20  1  0.761  0.521  0.250  1.0
  Te  Te21  1  0.239  0.479  0.750  1.0
[/CIF]
.