The material described by N2S3CF3SO3 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules, four trifluoromethane molecules, and four N2S3 clusters. In each N2S3 cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(3) and one S(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(4) atom. There are three inequivalent S sites. In the first S site, S(2) is bonded in a single-bond geometry to one N(2) atom. In the second S site, S(3) is bonded in a single-bond geometry to one N(1) atom. In the third S site, S(4) is bonded in a water-like geometry to one N(1) and one N(2) atom. is represented by the CIF file [CIF]
data_CS4N2(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.983
_cell_length_b   8.727
_cell_length_c   12.369
_cell_angle_alpha   45.504
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   845.703
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.986  0.791  0.771  1.0
  C  C1  1  0.486  0.209  0.729  1.0
  C  C2  1  0.514  0.791  0.271  1.0
  C  C3  1  0.014  0.209  0.229  1.0
  S  S4  1  0.634  0.069  0.771  1.0
  S  S5  1  0.098  0.614  0.549  1.0
  S  S6  1  0.402  0.614  0.049  1.0
  S  S7  1  0.575  0.436  0.161  1.0
  S  S8  1  0.129  0.215  0.843  1.0
  S  S9  1  0.871  0.785  0.157  1.0
  S  S10  1  0.366  0.931  0.229  1.0
  S  S11  1  0.629  0.785  0.657  1.0
  S  S12  1  0.598  0.386  0.951  1.0
  S  S13  1  0.902  0.386  0.451  1.0
  S  S14  1  0.134  0.931  0.729  1.0
  S  S15  1  0.866  0.069  0.271  1.0
  S  S16  1  0.925  0.436  0.661  1.0
  S  S17  1  0.425  0.564  0.839  1.0
  S  S18  1  0.075  0.564  0.339  1.0
  S  S19  1  0.371  0.215  0.343  1.0
  N  N20  1  0.514  0.231  0.320  1.0
  N  N21  1  0.014  0.769  0.180  1.0
  N  N22  1  0.683  0.566  0.808  1.0
  N  N23  1  0.317  0.434  0.192  1.0
  N  N24  1  0.986  0.231  0.820  1.0
  N  N25  1  0.486  0.769  0.680  1.0
  N  N26  1  0.183  0.434  0.692  1.0
  N  N27  1  0.817  0.566  0.308  1.0
  O  O28  1  0.173  0.844  0.876  1.0
  O  O29  1  0.597  0.841  0.877  1.0
  O  O30  1  0.403  0.159  0.123  1.0
  O  O31  1  0.209  0.877  0.663  1.0
  O  O32  1  0.327  0.844  0.376  1.0
  O  O33  1  0.673  0.156  0.624  1.0
  O  O34  1  0.791  0.123  0.337  1.0
  O  O35  1  0.097  0.159  0.623  1.0
  O  O36  1  0.709  0.123  0.837  1.0
  O  O37  1  0.827  0.156  0.124  1.0
  O  O38  1  0.903  0.841  0.377  1.0
  O  O39  1  0.291  0.877  0.163  1.0
  F  F40  1  0.571  0.878  0.140  1.0
  F  F41  1  0.506  0.420  0.647  1.0
  F  F42  1  0.494  0.580  0.353  1.0
  F  F43  1  0.429  0.122  0.860  1.0
  F  F44  1  0.994  0.420  0.147  1.0
  F  F45  1  0.006  0.580  0.853  1.0
  F  F46  1  0.910  0.805  0.849  1.0
  F  F47  1  0.590  0.805  0.349  1.0
  F  F48  1  0.071  0.122  0.360  1.0
  F  F49  1  0.929  0.878  0.640  1.0
  F  F50  1  0.090  0.195  0.151  1.0
  F  F51  1  0.410  0.195  0.651  1.0
[/CIF]
.
The material described by N2S3CF3SO3 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfur trioxide molecules, four trifluoromethane molecules, and four N2S3 clusters. In each N2S3 cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(3) and one S(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(4) atom. There are three inequivalent S sites. In the first S site, S(2) is bonded in a single-bond geometry to one N(2) atom. In the second S site, S(3) is bonded in a single-bond geometry to one N(1) atom. In the third S site, S(4) is bonded in a water-like geometry to one N(1) and one N(2) atom. is represented by the CIF file [CIF]
data_CS4N2(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.983
_cell_length_b   8.727
_cell_length_c   12.369
_cell_angle_alpha   45.504
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   845.703
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.986  0.791  0.771  1.0
  C  C1  1  0.486  0.209  0.729  1.0
  C  C2  1  0.514  0.791  0.271  1.0
  C  C3  1  0.014  0.209  0.229  1.0
  S  S4  1  0.634  0.069  0.771  1.0
  S  S5  1  0.098  0.614  0.549  1.0
  S  S6  1  0.402  0.614  0.049  1.0
  S  S7  1  0.575  0.436  0.161  1.0
  S  S8  1  0.129  0.215  0.843  1.0
  S  S9  1  0.871  0.785  0.157  1.0
  S  S10  1  0.366  0.931  0.229  1.0
  S  S11  1  0.629  0.785  0.657  1.0
  S  S12  1  0.598  0.386  0.951  1.0
  S  S13  1  0.902  0.386  0.451  1.0
  S  S14  1  0.134  0.931  0.729  1.0
  S  S15  1  0.866  0.069  0.271  1.0
  S  S16  1  0.925  0.436  0.661  1.0
  S  S17  1  0.425  0.564  0.839  1.0
  S  S18  1  0.075  0.564  0.339  1.0
  S  S19  1  0.371  0.215  0.343  1.0
  N  N20  1  0.514  0.231  0.320  1.0
  N  N21  1  0.014  0.769  0.180  1.0
  N  N22  1  0.683  0.566  0.808  1.0
  N  N23  1  0.317  0.434  0.192  1.0
  N  N24  1  0.986  0.231  0.820  1.0
  N  N25  1  0.486  0.769  0.680  1.0
  N  N26  1  0.183  0.434  0.692  1.0
  N  N27  1  0.817  0.566  0.308  1.0
  O  O28  1  0.173  0.844  0.876  1.0
  O  O29  1  0.597  0.841  0.877  1.0
  O  O30  1  0.403  0.159  0.123  1.0
  O  O31  1  0.209  0.877  0.663  1.0
  O  O32  1  0.327  0.844  0.376  1.0
  O  O33  1  0.673  0.156  0.624  1.0
  O  O34  1  0.791  0.123  0.337  1.0
  O  O35  1  0.097  0.159  0.623  1.0
  O  O36  1  0.709  0.123  0.837  1.0
  O  O37  1  0.827  0.156  0.124  1.0
  O  O38  1  0.903  0.841  0.377  1.0
  O  O39  1  0.291  0.877  0.163  1.0
  F  F40  1  0.571  0.878  0.140  1.0
  F  F41  1  0.506  0.420  0.647  1.0
  F  F42  1  0.494  0.580  0.353  1.0
  F  F43  1  0.429  0.122  0.860  1.0
  F  F44  1  0.994  0.420  0.147  1.0
  F  F45  1  0.006  0.580  0.853  1.0
  F  F46  1  0.910  0.805  0.849  1.0
  F  F47  1  0.590  0.805  0.349  1.0
  F  F48  1  0.071  0.122  0.360  1.0
  F  F49  1  0.929  0.878  0.640  1.0
  F  F50  1  0.090  0.195  0.151  1.0
  F  F51  1  0.410  0.195  0.651  1.0
[/CIF]
.