The crystal structure described by AlSO6(O2)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 7782-44-7 molecules inside a AlSO6 framework. In the AlSO6 framework, Al(1) is bonded to one O(1), one O(4), one O(6), and one O(8) atom to form AlO4 tetrahedra that share corners with two equivalent S(1)O4 tetrahedra. S(1) is bonded to one O(6), one O(7), one O(8), and one O(9) atom to form SO4 tetrahedra that share corners with two equivalent Al(1)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(8) is bonded in a bent 150 degrees geometry to one Al(1) and one S(1) atom. In the third O site, O(1) is bonded in a distorted water-like geometry to one Al(1) and one O(1) atom. In the fourth O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Al(1) and one O(4) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Al(1) and one S(1) atom. is represented by the CIF card [CIF]
data_AlSO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.940
_cell_length_b   10.496
_cell_length_c   8.747
_cell_angle_alpha   90.000
_cell_angle_beta   78.131
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   713.379
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.232  0.982  0.608  1.0
  Al  Al1  1  0.732  0.518  0.108  1.0
  Al  Al2  1  0.768  0.018  0.392  1.0
  Al  Al3  1  0.268  0.482  0.892  1.0
  S  S4  1  0.267  0.700  0.657  1.0
  S  S5  1  0.767  0.800  0.157  1.0
  S  S6  1  0.733  0.300  0.343  1.0
  S  S7  1  0.233  0.200  0.843  1.0
  O  O8  1  0.437  0.990  0.457  1.0
  O  O9  1  0.937  0.510  0.957  1.0
  O  O10  1  0.563  0.010  0.543  1.0
  O  O11  1  0.063  0.490  0.043  1.0
  O  O12  1  0.180  0.947  0.176  1.0
  O  O13  1  0.680  0.553  0.676  1.0
  O  O14  1  0.820  0.053  0.824  1.0
  O  O15  1  0.320  0.447  0.324  1.0
  O  O16  1  0.194  0.192  0.257  1.0
  O  O17  1  0.694  0.308  0.757  1.0
  O  O18  1  0.806  0.808  0.743  1.0
  O  O19  1  0.306  0.692  0.243  1.0
  O  O20  1  0.058  0.951  0.500  1.0
  O  O21  1  0.558  0.549  0.000  1.0
  O  O22  1  0.942  0.049  0.500  1.0
  O  O23  1  0.442  0.451  1.000  1.0
  O  O24  1  0.156  0.660  0.249  1.0
  O  O25  1  0.656  0.840  0.749  1.0
  O  O26  1  0.844  0.340  0.751  1.0
  O  O27  1  0.344  0.160  0.251  1.0
  O  O28  1  0.757  0.159  0.285  1.0
  O  O29  1  0.257  0.341  0.785  1.0
  O  O30  1  0.243  0.841  0.715  1.0
  O  O31  1  0.743  0.659  0.215  1.0
  O  O32  1  0.891  0.347  0.378  1.0
  O  O33  1  0.391  0.153  0.878  1.0
  O  O34  1  0.109  0.653  0.622  1.0
  O  O35  1  0.609  0.847  0.122  1.0
  O  O36  1  0.699  0.368  0.194  1.0
  O  O37  1  0.199  0.132  0.694  1.0
  O  O38  1  0.301  0.632  0.806  1.0
  O  O39  1  0.801  0.868  0.306  1.0
  O  O40  1  0.580  0.308  0.464  1.0
  O  O41  1  0.080  0.192  0.964  1.0
  O  O42  1  0.420  0.692  0.536  1.0
  O  O43  1  0.920  0.808  0.036  1.0
  O  O44  1  0.246  0.389  0.439  1.0
  O  O45  1  0.746  0.111  0.939  1.0
  O  O46  1  0.754  0.611  0.561  1.0
  O  O47  1  0.254  0.889  0.061  1.0
[/CIF]
.
The crystal structure described by AlSO6(O2)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 7782-44-7 molecules inside a AlSO6 framework. In the AlSO6 framework, Al(1) is bonded to one O(1), one O(4), one O(6), and one O(8) atom to form AlO4 tetrahedra that share corners with two equivalent S(1)O4 tetrahedra. S(1) is bonded to one O(6), one O(7), one O(8), and one O(9) atom to form SO4 tetrahedra that share corners with two equivalent Al(1)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(8) is bonded in a bent 150 degrees geometry to one Al(1) and one S(1) atom. In the third O site, O(1) is bonded in a distorted water-like geometry to one Al(1) and one O(1) atom. In the fourth O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Al(1) and one O(4) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Al(1) and one S(1) atom. is represented by the CIF card [CIF]
data_AlSO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.940
_cell_length_b   10.496
_cell_length_c   8.747
_cell_angle_alpha   90.000
_cell_angle_beta   78.131
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   713.379
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.232  0.982  0.608  1.0
  Al  Al1  1  0.732  0.518  0.108  1.0
  Al  Al2  1  0.768  0.018  0.392  1.0
  Al  Al3  1  0.268  0.482  0.892  1.0
  S  S4  1  0.267  0.700  0.657  1.0
  S  S5  1  0.767  0.800  0.157  1.0
  S  S6  1  0.733  0.300  0.343  1.0
  S  S7  1  0.233  0.200  0.843  1.0
  O  O8  1  0.437  0.990  0.457  1.0
  O  O9  1  0.937  0.510  0.957  1.0
  O  O10  1  0.563  0.010  0.543  1.0
  O  O11  1  0.063  0.490  0.043  1.0
  O  O12  1  0.180  0.947  0.176  1.0
  O  O13  1  0.680  0.553  0.676  1.0
  O  O14  1  0.820  0.053  0.824  1.0
  O  O15  1  0.320  0.447  0.324  1.0
  O  O16  1  0.194  0.192  0.257  1.0
  O  O17  1  0.694  0.308  0.757  1.0
  O  O18  1  0.806  0.808  0.743  1.0
  O  O19  1  0.306  0.692  0.243  1.0
  O  O20  1  0.058  0.951  0.500  1.0
  O  O21  1  0.558  0.549  0.000  1.0
  O  O22  1  0.942  0.049  0.500  1.0
  O  O23  1  0.442  0.451  1.000  1.0
  O  O24  1  0.156  0.660  0.249  1.0
  O  O25  1  0.656  0.840  0.749  1.0
  O  O26  1  0.844  0.340  0.751  1.0
  O  O27  1  0.344  0.160  0.251  1.0
  O  O28  1  0.757  0.159  0.285  1.0
  O  O29  1  0.257  0.341  0.785  1.0
  O  O30  1  0.243  0.841  0.715  1.0
  O  O31  1  0.743  0.659  0.215  1.0
  O  O32  1  0.891  0.347  0.378  1.0
  O  O33  1  0.391  0.153  0.878  1.0
  O  O34  1  0.109  0.653  0.622  1.0
  O  O35  1  0.609  0.847  0.122  1.0
  O  O36  1  0.699  0.368  0.194  1.0
  O  O37  1  0.199  0.132  0.694  1.0
  O  O38  1  0.301  0.632  0.806  1.0
  O  O39  1  0.801  0.868  0.306  1.0
  O  O40  1  0.580  0.308  0.464  1.0
  O  O41  1  0.080  0.192  0.964  1.0
  O  O42  1  0.420  0.692  0.536  1.0
  O  O43  1  0.920  0.808  0.036  1.0
  O  O44  1  0.246  0.389  0.439  1.0
  O  O45  1  0.746  0.111  0.939  1.0
  O  O46  1  0.754  0.611  0.561  1.0
  O  O47  1  0.254  0.889  0.061  1.0
[/CIF]
.