The structure described by Yb(SbS2)2 crystallizes in the orthorhombic Pnma space group. Yb(1) is bonded in a 7-coordinate geometry to two equivalent S(1), two equivalent S(2), two equivalent S(3), and two equivalent S(4) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one S(2), two equivalent S(1), and two equivalent S(4) atoms to form distorted edge-sharing SbS5 square pyramids. In the second Sb site, Sb(2) is bonded in a 7-coordinate geometry to one S(1), one S(4), two equivalent S(2), and three equivalent S(3) atoms. There are four inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Yb(1), one Sb(2), and two equivalent Sb(1) atoms to form a mixture of distorted face, corner, and edge-sharing SYb2Sb3 square pyramids. In the second S site, S(2) is bonded to two equivalent Yb(1), one Sb(1), and two equivalent Sb(2) atoms to form a mixture of distorted corner and edge-sharing SYb2Sb3 trigonal bipyramids. In the third S site, S(3) is bonded to two equivalent Yb(1) and three equivalent Sb(2) atoms to form a mixture of face, corner, and edge-sharing SYb2Sb3 square pyramids. In the fourth S site, S(4) is bonded in a 5-coordinate geometry to two equivalent Yb(1), one Sb(2), and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Yb(SbS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.955
_cell_length_b   11.543
_cell_length_c   14.246
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   650.306
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.250  0.265  0.349  1.0
  Yb  Yb1  1  0.250  0.765  0.151  1.0
  Yb  Yb2  1  0.750  0.735  0.651  1.0
  Yb  Yb3  1  0.750  0.235  0.849  1.0
  Sb  Sb4  1  0.250  0.068  0.610  1.0
  Sb  Sb5  1  0.250  0.568  0.890  1.0
  Sb  Sb6  1  0.750  0.932  0.390  1.0
  Sb  Sb7  1  0.750  0.432  0.110  1.0
  Sb  Sb8  1  0.250  0.114  0.089  1.0
  Sb  Sb9  1  0.250  0.614  0.411  1.0
  Sb  Sb10  1  0.750  0.886  0.911  1.0
  Sb  Sb11  1  0.750  0.386  0.589  1.0
  S  S12  1  0.250  0.312  0.987  1.0
  S  S13  1  0.250  0.812  0.513  1.0
  S  S14  1  0.750  0.688  0.013  1.0
  S  S15  1  0.750  0.188  0.487  1.0
  S  S16  1  0.250  0.254  0.702  1.0
  S  S17  1  0.250  0.754  0.798  1.0
  S  S18  1  0.750  0.746  0.298  1.0
  S  S19  1  0.750  0.246  0.202  1.0
  S  S20  1  0.250  0.056  0.910  1.0
  S  S21  1  0.250  0.556  0.590  1.0
  S  S22  1  0.750  0.944  0.090  1.0
  S  S23  1  0.750  0.444  0.410  1.0
  S  S24  1  0.250  0.018  0.291  1.0
  S  S25  1  0.250  0.518  0.209  1.0
  S  S26  1  0.750  0.982  0.709  1.0
  S  S27  1  0.750  0.482  0.791  1.0
[/CIF]
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The structure described by Yb(SbS2)2 crystallizes in the orthorhombic Pnma space group. Yb(1) is bonded in a 7-coordinate geometry to two equivalent S(1), two equivalent S(2), two equivalent S(3), and two equivalent S(4) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one S(2), two equivalent S(1), and two equivalent S(4) atoms to form distorted edge-sharing SbS5 square pyramids. In the second Sb site, Sb(2) is bonded in a 7-coordinate geometry to one S(1), one S(4), two equivalent S(2), and three equivalent S(3) atoms. There are four inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Yb(1), one Sb(2), and two equivalent Sb(1) atoms to form a mixture of distorted face, corner, and edge-sharing SYb2Sb3 square pyramids. In the second S site, S(2) is bonded to two equivalent Yb(1), one Sb(1), and two equivalent Sb(2) atoms to form a mixture of distorted corner and edge-sharing SYb2Sb3 trigonal bipyramids. In the third S site, S(3) is bonded to two equivalent Yb(1) and three equivalent Sb(2) atoms to form a mixture of face, corner, and edge-sharing SYb2Sb3 square pyramids. In the fourth S site, S(4) is bonded in a 5-coordinate geometry to two equivalent Yb(1), one Sb(2), and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Yb(SbS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.955
_cell_length_b   11.543
_cell_length_c   14.246
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   650.306
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.250  0.265  0.349  1.0
  Yb  Yb1  1  0.250  0.765  0.151  1.0
  Yb  Yb2  1  0.750  0.735  0.651  1.0
  Yb  Yb3  1  0.750  0.235  0.849  1.0
  Sb  Sb4  1  0.250  0.068  0.610  1.0
  Sb  Sb5  1  0.250  0.568  0.890  1.0
  Sb  Sb6  1  0.750  0.932  0.390  1.0
  Sb  Sb7  1  0.750  0.432  0.110  1.0
  Sb  Sb8  1  0.250  0.114  0.089  1.0
  Sb  Sb9  1  0.250  0.614  0.411  1.0
  Sb  Sb10  1  0.750  0.886  0.911  1.0
  Sb  Sb11  1  0.750  0.386  0.589  1.0
  S  S12  1  0.250  0.312  0.987  1.0
  S  S13  1  0.250  0.812  0.513  1.0
  S  S14  1  0.750  0.688  0.013  1.0
  S  S15  1  0.750  0.188  0.487  1.0
  S  S16  1  0.250  0.254  0.702  1.0
  S  S17  1  0.250  0.754  0.798  1.0
  S  S18  1  0.750  0.746  0.298  1.0
  S  S19  1  0.750  0.246  0.202  1.0
  S  S20  1  0.250  0.056  0.910  1.0
  S  S21  1  0.250  0.556  0.590  1.0
  S  S22  1  0.750  0.944  0.090  1.0
  S  S23  1  0.750  0.444  0.410  1.0
  S  S24  1  0.250  0.018  0.291  1.0
  S  S25  1  0.250  0.518  0.209  1.0
  S  S26  1  0.750  0.982  0.709  1.0
  S  S27  1  0.750  0.482  0.791  1.0
[/CIF]
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