The structure described by LiSbWO6 crystallizes in the tetragonal P4_122 space group. Li(1) is bonded in a hexagonal planar geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. W(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-44°. Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-50°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one W(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one W(1), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiSbWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.333
_cell_length_b   7.333
_cell_length_c   10.322
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   555.049
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.233  0.000  1.0
  Li  Li1  1  0.767  0.500  0.250  1.0
  Li  Li2  1  0.500  0.767  0.500  1.0
  Li  Li3  1  0.233  0.500  0.750  1.0
  Sb  Sb4  1  0.500  0.742  0.000  1.0
  Sb  Sb5  1  0.258  0.500  0.250  1.0
  Sb  Sb6  1  0.500  0.258  0.500  1.0
  Sb  Sb7  1  0.742  0.500  0.750  1.0
  W  W8  1  0.000  0.743  0.000  1.0
  W  W9  1  0.257  0.000  0.250  1.0
  W  W10  1  0.000  0.257  0.500  1.0
  W  W11  1  0.743  0.000  0.750  1.0
  O  O12  1  0.539  0.539  0.875  1.0
  O  O13  1  0.927  0.927  0.875  1.0
  O  O14  1  0.557  0.948  0.879  1.0
  O  O15  1  0.948  0.557  0.871  1.0
  O  O16  1  0.734  0.245  0.818  1.0
  O  O17  1  0.266  0.245  0.182  1.0
  O  O18  1  0.052  0.557  0.129  1.0
  O  O19  1  0.461  0.539  0.125  1.0
  O  O20  1  0.073  0.927  0.125  1.0
  O  O21  1  0.443  0.948  0.121  1.0
  O  O22  1  0.755  0.734  0.068  1.0
  O  O23  1  0.755  0.266  0.432  1.0
  O  O24  1  0.073  0.073  0.375  1.0
  O  O25  1  0.052  0.443  0.371  1.0
  O  O26  1  0.461  0.461  0.375  1.0
  O  O27  1  0.443  0.052  0.379  1.0
  O  O28  1  0.266  0.755  0.318  1.0
  O  O29  1  0.734  0.755  0.682  1.0
  O  O30  1  0.927  0.073  0.625  1.0
  O  O31  1  0.557  0.052  0.621  1.0
  O  O32  1  0.539  0.461  0.625  1.0
  O  O33  1  0.948  0.443  0.629  1.0
  O  O34  1  0.245  0.266  0.568  1.0
  O  O35  1  0.245  0.734  0.932  1.0
[/CIF]
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The structure described by LiSbWO6 crystallizes in the tetragonal P4_122 space group. Li(1) is bonded in a hexagonal planar geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms. W(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-44°. Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-50°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Li(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one W(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one W(1), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiSbWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.333
_cell_length_b   7.333
_cell_length_c   10.322
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   555.049
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.233  0.000  1.0
  Li  Li1  1  0.767  0.500  0.250  1.0
  Li  Li2  1  0.500  0.767  0.500  1.0
  Li  Li3  1  0.233  0.500  0.750  1.0
  Sb  Sb4  1  0.500  0.742  0.000  1.0
  Sb  Sb5  1  0.258  0.500  0.250  1.0
  Sb  Sb6  1  0.500  0.258  0.500  1.0
  Sb  Sb7  1  0.742  0.500  0.750  1.0
  W  W8  1  0.000  0.743  0.000  1.0
  W  W9  1  0.257  0.000  0.250  1.0
  W  W10  1  0.000  0.257  0.500  1.0
  W  W11  1  0.743  0.000  0.750  1.0
  O  O12  1  0.539  0.539  0.875  1.0
  O  O13  1  0.927  0.927  0.875  1.0
  O  O14  1  0.557  0.948  0.879  1.0
  O  O15  1  0.948  0.557  0.871  1.0
  O  O16  1  0.734  0.245  0.818  1.0
  O  O17  1  0.266  0.245  0.182  1.0
  O  O18  1  0.052  0.557  0.129  1.0
  O  O19  1  0.461  0.539  0.125  1.0
  O  O20  1  0.073  0.927  0.125  1.0
  O  O21  1  0.443  0.948  0.121  1.0
  O  O22  1  0.755  0.734  0.068  1.0
  O  O23  1  0.755  0.266  0.432  1.0
  O  O24  1  0.073  0.073  0.375  1.0
  O  O25  1  0.052  0.443  0.371  1.0
  O  O26  1  0.461  0.461  0.375  1.0
  O  O27  1  0.443  0.052  0.379  1.0
  O  O28  1  0.266  0.755  0.318  1.0
  O  O29  1  0.734  0.755  0.682  1.0
  O  O30  1  0.927  0.073  0.625  1.0
  O  O31  1  0.557  0.052  0.621  1.0
  O  O32  1  0.539  0.461  0.625  1.0
  O  O33  1  0.948  0.443  0.629  1.0
  O  O34  1  0.245  0.266  0.568  1.0
  O  O35  1  0.245  0.734  0.932  1.0
[/CIF]
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