The crystal structure described by RbTh3F13 crystallizes in the orthorhombic Pmc2_1 space group. Rb(1) is bonded in a 11-coordinate geometry to one F(2), two equivalent F(1), two equivalent F(3), two equivalent F(4), two equivalent F(7), and two equivalent F(8) atoms. There are two inequivalent Th sites. In the first Th site, Th(1) is bonded in a 9-coordinate geometry to one F(1), one F(2), one F(3), one F(4), one F(5), one F(8), one F(9), and two equivalent F(7) atoms. In the second Th site, Th(2) is bonded in a 9-coordinate geometry to one F(5), two equivalent F(1), two equivalent F(3), two equivalent F(4), and two equivalent F(6) atoms. There are nine inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Rb(1), one Th(1), and one Th(2) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Rb(1) and two equivalent Th(1) atoms. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Th(1), and one Th(2) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one Rb(1), one Th(1), and one Th(2) atom. In the fifth F site, F(5) is bonded in a trigonal non-coplanar geometry to one Th(2) and two equivalent Th(1) atoms. In the sixth F site, F(6) is bonded in a linear geometry to two equivalent Th(2) atoms. In the seventh F site, F(7) is bonded in a distorted bent 150 degrees geometry to one Rb(1) and two equivalent Th(1) atoms. In the eighth F site, F(8) is bonded to two equivalent Rb(1) and two equivalent Th(1) atoms to form corner-sharing FRb2Th2 tetrahedra. In the ninth F site, F(9) is bonded in a bent 120 degrees geometry to two equivalent Th(1) atoms. is represented by the CIF file [CIF]
data_RbTh3F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.447
_cell_length_b   8.162
_cell_length_c   8.660
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   526.359
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.894  0.500  0.693  1.0
  Rb  Rb1  1  0.106  0.500  0.193  1.0
  Th  Th2  1  0.603  0.253  0.335  1.0
  Th  Th3  1  0.603  0.747  0.335  1.0
  Th  Th4  1  0.397  0.747  0.835  1.0
  Th  Th5  1  0.397  0.253  0.835  1.0
  Th  Th6  1  0.108  0.000  0.500  1.0
  Th  Th7  1  0.892  0.000  0.000  1.0
  F  F8  1  0.696  0.826  0.865  1.0
  F  F9  1  0.563  0.500  0.847  1.0
  F  F10  1  0.115  0.804  0.957  1.0
  F  F11  1  0.826  0.744  0.144  1.0
  F  F12  1  0.362  0.000  0.679  1.0
  F  F13  1  0.032  0.000  0.237  1.0
  F  F14  1  0.885  0.196  0.457  1.0
  F  F15  1  0.437  0.500  0.347  1.0
  F  F16  1  0.968  0.000  0.737  1.0
  F  F17  1  0.452  0.696  0.097  1.0
  F  F18  1  0.773  0.500  0.368  1.0
  F  F19  1  0.452  0.304  0.097  1.0
  F  F20  1  0.548  0.696  0.597  1.0
  F  F21  1  0.598  0.000  0.460  1.0
  F  F22  1  0.304  0.826  0.365  1.0
  F  F23  1  0.227  0.500  0.868  1.0
  F  F24  1  0.826  0.256  0.144  1.0
  F  F25  1  0.174  0.744  0.644  1.0
  F  F26  1  0.174  0.256  0.644  1.0
  F  F27  1  0.304  0.174  0.365  1.0
  F  F28  1  0.696  0.174  0.865  1.0
  F  F29  1  0.638  0.000  0.179  1.0
  F  F30  1  0.402  0.000  0.960  1.0
  F  F31  1  0.115  0.196  0.957  1.0
  F  F32  1  0.548  0.304  0.597  1.0
  F  F33  1  0.885  0.804  0.457  1.0
[/CIF]
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The crystal structure described by RbTh3F13 crystallizes in the orthorhombic Pmc2_1 space group. Rb(1) is bonded in a 11-coordinate geometry to one F(2), two equivalent F(1), two equivalent F(3), two equivalent F(4), two equivalent F(7), and two equivalent F(8) atoms. There are two inequivalent Th sites. In the first Th site, Th(1) is bonded in a 9-coordinate geometry to one F(1), one F(2), one F(3), one F(4), one F(5), one F(8), one F(9), and two equivalent F(7) atoms. In the second Th site, Th(2) is bonded in a 9-coordinate geometry to one F(5), two equivalent F(1), two equivalent F(3), two equivalent F(4), and two equivalent F(6) atoms. There are nine inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Rb(1), one Th(1), and one Th(2) atom. In the second F site, F(2) is bonded in a trigonal planar geometry to one Rb(1) and two equivalent Th(1) atoms. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Th(1), and one Th(2) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to one Rb(1), one Th(1), and one Th(2) atom. In the fifth F site, F(5) is bonded in a trigonal non-coplanar geometry to one Th(2) and two equivalent Th(1) atoms. In the sixth F site, F(6) is bonded in a linear geometry to two equivalent Th(2) atoms. In the seventh F site, F(7) is bonded in a distorted bent 150 degrees geometry to one Rb(1) and two equivalent Th(1) atoms. In the eighth F site, F(8) is bonded to two equivalent Rb(1) and two equivalent Th(1) atoms to form corner-sharing FRb2Th2 tetrahedra. In the ninth F site, F(9) is bonded in a bent 120 degrees geometry to two equivalent Th(1) atoms. is represented by the CIF file [CIF]
data_RbTh3F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.447
_cell_length_b   8.162
_cell_length_c   8.660
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   526.359
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.894  0.500  0.693  1.0
  Rb  Rb1  1  0.106  0.500  0.193  1.0
  Th  Th2  1  0.603  0.253  0.335  1.0
  Th  Th3  1  0.603  0.747  0.335  1.0
  Th  Th4  1  0.397  0.747  0.835  1.0
  Th  Th5  1  0.397  0.253  0.835  1.0
  Th  Th6  1  0.108  0.000  0.500  1.0
  Th  Th7  1  0.892  0.000  0.000  1.0
  F  F8  1  0.696  0.826  0.865  1.0
  F  F9  1  0.563  0.500  0.847  1.0
  F  F10  1  0.115  0.804  0.957  1.0
  F  F11  1  0.826  0.744  0.144  1.0
  F  F12  1  0.362  0.000  0.679  1.0
  F  F13  1  0.032  0.000  0.237  1.0
  F  F14  1  0.885  0.196  0.457  1.0
  F  F15  1  0.437  0.500  0.347  1.0
  F  F16  1  0.968  0.000  0.737  1.0
  F  F17  1  0.452  0.696  0.097  1.0
  F  F18  1  0.773  0.500  0.368  1.0
  F  F19  1  0.452  0.304  0.097  1.0
  F  F20  1  0.548  0.696  0.597  1.0
  F  F21  1  0.598  0.000  0.460  1.0
  F  F22  1  0.304  0.826  0.365  1.0
  F  F23  1  0.227  0.500  0.868  1.0
  F  F24  1  0.826  0.256  0.144  1.0
  F  F25  1  0.174  0.744  0.644  1.0
  F  F26  1  0.174  0.256  0.644  1.0
  F  F27  1  0.304  0.174  0.365  1.0
  F  F28  1  0.696  0.174  0.865  1.0
  F  F29  1  0.638  0.000  0.179  1.0
  F  F30  1  0.402  0.000  0.960  1.0
  F  F31  1  0.115  0.196  0.957  1.0
  F  F32  1  0.548  0.304  0.597  1.0
  F  F33  1  0.885  0.804  0.457  1.0
[/CIF]
.