The crystal structure described by (NH4)3WO3F3 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one (NH4)3WO3F3 cluster. W(1) is bonded in a 5-coordinate geometry to one N(2), one O(1), one O(2), one O(3), and one F(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a tetrahedral geometry to one H(1), one H(2), one H(3), and one H(4) atom. In the second N site, N(2) is bonded in a water-like geometry to one W(1), one H(5), and one H(6) atom. In the third N site, N(3) is bonded in a tetrahedral geometry to one H(10), one H(11), one H(12), and one H(9) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one N(1) and one O(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(7) is bonded in a linear geometry to one O(2) and one F(3) atom. In the eighth H site, H(8) is bonded in a linear geometry to one F(1) and one F(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(3) and one O(1) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(3) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(3) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one W(1) and one H(9) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one W(1) and one H(7) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one H(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one H(8) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one H(7) and one H(8) atom. is represented by the CIF file [CIF]
data_H12WN3(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.467
_cell_length_b   6.773
_cell_length_c   6.870
_cell_angle_alpha   115.205
_cell_angle_beta   113.164
_cell_angle_gamma   93.764
_symmetry_Int_Tables_number   1
_cell_volume   240.307
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.795  0.222  0.586  1.0
  H  H1  1  0.825  0.315  0.398  1.0
  H  H2  1  0.851  0.514  0.669  1.0
  H  H3  1  0.590  0.317  0.449  1.0
  H  H4  1  0.644  0.282  0.082  1.0
  H  H5  1  0.802  0.432  0.041  1.0
  H  H6  1  0.253  0.403  0.963  1.0
  H  H7  1  0.443  0.596  0.872  1.0
  H  H8  1  0.390  0.856  0.539  1.0
  H  H9  1  0.145  0.624  0.381  1.0
  H  H10  1  0.174  0.856  0.623  1.0
  H  H11  1  0.121  0.865  0.366  1.0
  W  W12  1  0.924  0.049  0.922  1.0
  N  N13  1  0.767  0.339  0.526  1.0
  N  N14  1  0.814  0.330  0.120  1.0
  N  N15  1  0.208  0.799  0.477  1.0
  O  O16  1  0.673  0.992  0.646  1.0
  O  O17  1  0.166  0.216  0.936  1.0
  O  O18  1  0.976  0.772  0.824  1.0
  F  F19  1  0.520  0.619  0.779  1.0
  F  F20  1  0.007  0.051  0.241  1.0
  F  F21  1  0.338  0.570  0.006  1.0
[/CIF]
.
The crystal structure described by (NH4)3WO3F3 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one (NH4)3WO3F3 cluster. W(1) is bonded in a 5-coordinate geometry to one N(2), one O(1), one O(2), one O(3), and one F(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a tetrahedral geometry to one H(1), one H(2), one H(3), and one H(4) atom. In the second N site, N(2) is bonded in a water-like geometry to one W(1), one H(5), and one H(6) atom. In the third N site, N(3) is bonded in a tetrahedral geometry to one H(10), one H(11), one H(12), and one H(9) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one N(1) and one O(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(7) is bonded in a linear geometry to one O(2) and one F(3) atom. In the eighth H site, H(8) is bonded in a linear geometry to one F(1) and one F(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(3) and one O(1) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(3) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(3) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one W(1) and one H(9) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one W(1) and one H(7) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one H(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one H(8) atom. In the second F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one H(7) and one H(8) atom. is represented by the CIF file [CIF]
data_H12WN3(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.467
_cell_length_b   6.773
_cell_length_c   6.870
_cell_angle_alpha   115.205
_cell_angle_beta   113.164
_cell_angle_gamma   93.764
_symmetry_Int_Tables_number   1
_cell_volume   240.307
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.795  0.222  0.586  1.0
  H  H1  1  0.825  0.315  0.398  1.0
  H  H2  1  0.851  0.514  0.669  1.0
  H  H3  1  0.590  0.317  0.449  1.0
  H  H4  1  0.644  0.282  0.082  1.0
  H  H5  1  0.802  0.432  0.041  1.0
  H  H6  1  0.253  0.403  0.963  1.0
  H  H7  1  0.443  0.596  0.872  1.0
  H  H8  1  0.390  0.856  0.539  1.0
  H  H9  1  0.145  0.624  0.381  1.0
  H  H10  1  0.174  0.856  0.623  1.0
  H  H11  1  0.121  0.865  0.366  1.0
  W  W12  1  0.924  0.049  0.922  1.0
  N  N13  1  0.767  0.339  0.526  1.0
  N  N14  1  0.814  0.330  0.120  1.0
  N  N15  1  0.208  0.799  0.477  1.0
  O  O16  1  0.673  0.992  0.646  1.0
  O  O17  1  0.166  0.216  0.936  1.0
  O  O18  1  0.976  0.772  0.824  1.0
  F  F19  1  0.520  0.619  0.779  1.0
  F  F20  1  0.007  0.051  0.241  1.0
  F  F21  1  0.338  0.570  0.006  1.0
[/CIF]
.