The crystal structure described by LiVP3HO10 crystallizes in the monoclinic C2 space group. The structure consists of two 7439-93-2 atoms inside a VP3HO10 framework. In the VP3HO10 framework, V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form VO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(4), and one O(5) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 31-50°. In the second P site, P(2) is bonded to two equivalent O(3) and two equivalent O(4) atoms to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. H(1) is bonded in a linear geometry to two equivalent O(5) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiVP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.398
_cell_length_b   6.398
_cell_length_c   6.351
_cell_angle_alpha   72.445
_cell_angle_beta   72.445
_cell_angle_gamma   85.331
_symmetry_Int_Tables_number   1
_cell_volume   236.293
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.995  0.005  0.500  1.0
  V  V1  1  0.336  0.664  0.000  1.0
  P  P2  1  0.801  0.555  0.100  1.0
  P  P3  1  0.430  0.570  0.500  1.0
  P  P4  1  0.445  0.199  0.900  1.0
  H  H5  1  0.755  0.245  0.000  1.0
  O  O6  1  0.662  0.668  0.941  1.0
  O  O7  1  0.327  0.982  0.979  1.0
  O  O8  1  0.392  0.721  0.649  1.0
  O  O9  1  0.684  0.595  0.353  1.0
  O  O10  1  0.695  0.188  0.859  1.0
  O  O11  1  0.812  0.305  0.141  1.0
  O  O12  1  0.405  0.316  0.647  1.0
  O  O13  1  0.279  0.608  0.351  1.0
  O  O14  1  0.018  0.673  0.021  1.0
  O  O15  1  0.332  0.338  0.059  1.0
[/CIF]
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The crystal structure described by LiVP3HO10 crystallizes in the monoclinic C2 space group. The structure consists of two 7439-93-2 atoms inside a VP3HO10 framework. In the VP3HO10 framework, V(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form VO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra and corners with four equivalent P(1)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(4), and one O(5) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 31-50°. In the second P site, P(2) is bonded to two equivalent O(3) and two equivalent O(4) atoms to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. H(1) is bonded in a linear geometry to two equivalent O(5) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiVP3HO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.398
_cell_length_b   6.398
_cell_length_c   6.351
_cell_angle_alpha   72.445
_cell_angle_beta   72.445
_cell_angle_gamma   85.331
_symmetry_Int_Tables_number   1
_cell_volume   236.293
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.995  0.005  0.500  1.0
  V  V1  1  0.336  0.664  0.000  1.0
  P  P2  1  0.801  0.555  0.100  1.0
  P  P3  1  0.430  0.570  0.500  1.0
  P  P4  1  0.445  0.199  0.900  1.0
  H  H5  1  0.755  0.245  0.000  1.0
  O  O6  1  0.662  0.668  0.941  1.0
  O  O7  1  0.327  0.982  0.979  1.0
  O  O8  1  0.392  0.721  0.649  1.0
  O  O9  1  0.684  0.595  0.353  1.0
  O  O10  1  0.695  0.188  0.859  1.0
  O  O11  1  0.812  0.305  0.141  1.0
  O  O12  1  0.405  0.316  0.647  1.0
  O  O13  1  0.279  0.608  0.351  1.0
  O  O14  1  0.018  0.673  0.021  1.0
  O  O15  1  0.332  0.338  0.059  1.0
[/CIF]
.