The material described by LiZnBO3 crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(18), one O(2), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Zn(3)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra,  a cornercorner with one Zn(1)O4 trigonal pyramid, and corners with two equivalent Zn(8)O4 trigonal pyramids. In the second Li site, Li(2) is bonded in a distorted trigonal planar geometry to one O(22), one O(23), and one O(6) atom. In the third Li site, Li(3) is bonded in a distorted trigonal planar geometry to one O(1), one O(21), one O(3), and one O(7) atom. In the fourth Li site, Li(4) is bonded to one O(12), one O(15), one O(16), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra, corners with two equivalent Zn(4)O4 trigonal pyramids, and  an edgeedge with one Li(6)O4 trigonal pyramid. In the fifth Li site, Li(5) is bonded in a 4-coordinate geometry to one O(11), one O(13), one O(20), and one O(9) atom. In the sixth Li site, Li(6) is bonded to one O(10), one O(12), one O(16), and one O(17) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Zn(7)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra,  a cornercorner with one Zn(8)O4 trigonal pyramid,  an edgeedge with one Li(4)O4 tetrahedra, and  an edgeedge with one Zn(4)O4 trigonal pyramid. In the seventh Li site, Li(7) is bonded to one O(11), one O(16), one O(20), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Zn(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 trigonal pyramid,  a cornercorner with one Zn(2)O4 trigonal pyramid, and  a cornercorner with one Zn(4)O4 trigonal pyramid. In the eighth Li site, Li(8) is bonded to one O(19), one O(22), one O(24), and one O(4) atom to form LiO4 tetrahedra that share  a cornercorner with one Zn(5)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra,  a cornercorner with one Zn(1)O4 trigonal pyramid, and corners with two equivalent Zn(2)O4 trigonal pyramids. There are eight inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(22), one O(6), and one O(8) atom to form distorted ZnO4 trigonal pyramids that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra, and  an edgeedge with one Zn(3)O4 tetrahedra. In the second Zn site, Zn(2) is bonded to one O(11), one O(24), one O(4), and one O(7) atom to form distorted ZnO4 trigonal pyramids that share  a cornercorner with one Li(7)O4 tetrahedra, corners with two equivalent Li(8)O4 tetrahedra, and  a cornercorner with one Zn(4)O4 trigonal pyramid. In the third Zn site, Zn(3) is bonded to one O(10), one O(12), one O(2), and one O(8) atom to form ZnO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Zn(4)O4 trigonal pyramid, corners with two equivalent Li(6)O4 trigonal pyramids, and  an edgeedge with one Zn(1)O4 trigonal pyramid. In the fourth Zn site, Zn(4) is bonded to one O(10), one O(16), one O(5), and one O(7) atom to form ZnO4 trigonal pyramids that share  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Zn(2)O4 trigonal pyramid, and  an edgeedge with one Li(6)O4 trigonal pyramid. In the fifth Zn site, Zn(5) is bonded to one O(14), one O(19), one O(20), and one O(9) atom to form ZnO4 tetrahedra that share  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra,  a cornercorner with one Zn(7)O4 tetrahedra, and corners with two equivalent Li(7)O4 tetrahedra. In the sixth Zn site, Zn(6) is bonded to one O(1), one O(15), one O(19), and one O(21) atom to form ZnO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra, and  a cornercorner with one Zn(5)O4 tetrahedra. In the seventh Zn site, Zn(7) is bonded to one O(13), one O(14), one O(17), and one O(23) atom to form distorted ZnO4 tetrahedra that share  a cornercorner with one Zn(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 trigonal pyramid, and  an edgeedge with one Zn(8)O4 trigonal pyramid. In the eighth Zn site, Zn(8) is bonded to one O(17), one O(18), one O(23), and one O(3) atom to form distorted ZnO4 trigonal pyramids that share corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(6)O4 trigonal pyramid, and  an edgeedge with one Zn(7)O4 tetrahedra. There are eight inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(7) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(10), one O(2), and one O(3) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(11), one O(4), and one O(9) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(13), one O(6), and one O(8) atom. In the fifth B site, B(5) is bonded in a trigonal planar geometry to one O(12), one O(17), and one O(18) atom. In the sixth B site, B(6) is bonded in a trigonal planar geometry to one O(14), one O(22), and one O(23) atom. In the seventh B site, B(7) is bonded in a trigonal planar geometry to one O(15), one O(16), and one O(21) atom. In the eighth B site, B(8) is bonded in a trigonal planar geometry to one O(19), one O(20), and one O(24) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(3), one Zn(6), and one B(1) atom to form distorted corner-sharing OLi2ZnB trigonal pyramids. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(1), one Zn(1), one Zn(3), and one B(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Li(3), one Zn(8), and one B(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(8), one Zn(2), and one B(3) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Li(4), one Zn(4), and one B(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(2), one Zn(1), and one B(4) atom. In the seventh O site, O(7) is bonded to one Li(3), one Zn(2), one Zn(4), and one B(1) atom to form distorted OLiZn2B tetrahedra that share  a cornercorner with one O(16)Li3ZnB trigonal bipyramid and corners with two equivalent O(1)Li2ZnB trigonal pyramids. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(3), and one B(4) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Li(5), one Li(7), one Zn(5), and one B(3) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Zn(3), one Zn(4), and one B(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(5), one Li(7), one Zn(2), and one B(3) atom. In the twelfth O site, O(12) is bonded to one Li(4), one Li(6), one Zn(3), and one B(5) atom to form distorted OLi2ZnB trigonal pyramids that share corners with two equivalent O(17)LiZn2B tetrahedra and  an edgeedge with one O(16)Li3ZnB trigonal bipyramid. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one Li(5), one Zn(7), and one B(4) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal non-coplanar geometry to one Zn(5), one Zn(7), and one B(6) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(4), one Zn(6), and one B(7) atom. In the sixteenth O site, O(16) is bonded to one Li(4), one Li(6), one Li(7), one Zn(4), and one B(7) atom to form distorted OLi3ZnB trigonal bipyramids that share  a cornercorner with one O(20)Li2ZnB tetrahedra,  a cornercorner with one O(17)LiZn2B tetrahedra,  a cornercorner with one O(7)LiZn2B tetrahedra, and  an edgeedge with one O(12)Li2ZnB trigonal pyramid. In the seventeenth O site, O(17) is bonded to one Li(6), one Zn(7), one Zn(8), and one B(5) atom to form distorted OLiZn2B tetrahedra that share  a cornercorner with one O(16)Li3ZnB trigonal bipyramid and corners with two equivalent O(12)Li2ZnB trigonal pyramids. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Li(1), one Zn(8), and one B(5) atom. In the nineteenth O site, O(19) is bonded to one Li(8), one Zn(5), one Zn(6), and one B(8) atom to form distorted corner-sharing OLiZn2B tetrahedra. In the twentieth O site, O(20) is bonded to one Li(5), one Li(7), one Zn(5), and one B(8) atom to form distorted OLi2ZnB tetrahedra that share corners with two equivalent O(19)LiZn2B tetrahedra and  a cornercorner with one O(16)Li3ZnB trigonal bipyramid. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Li(3), one Zn(6), and one B(7) atom. In the twenty-second O site, O(22) is bonded to one Li(2), one Li(8), one Zn(1), and one B(6) atom to form distorted corner-sharing OLi2ZnB trigonal pyramids. In the twenty-third O site, O(23) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Zn(7), one Zn(8), and one B(6) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Li(8), one Zn(2), and one B(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiZnBO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.082
_cell_length_b   8.859
_cell_length_c   11.222
_cell_angle_alpha   90.013
_cell_angle_beta   90.415
_cell_angle_gamma   90.096
_symmetry_Int_Tables_number   1
_cell_volume   505.237
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.675  0.015  0.166  1.0
  Li  Li1  1  0.348  0.998  0.898  1.0
  Li  Li2  1  0.336  0.003  0.353  1.0
  Li  Li3  1  0.824  0.510  0.333  1.0
  Li  Li4  1  0.104  0.492  0.726  1.0
  Li  Li5  1  0.165  0.509  0.153  1.0
  Li  Li6  1  0.152  0.506  0.534  1.0
  Li  Li7  1  0.661  0.994  0.672  1.0
  Zn  Zn8  1  0.855  0.169  0.891  1.0
  Zn  Zn9  1  0.160  0.162  0.621  1.0
  Zn  Zn10  1  0.662  0.345  0.102  1.0
  Zn  Zn11  1  0.344  0.326  0.353  1.0
  Zn  Zn12  1  0.651  0.666  0.650  1.0
  Zn  Zn13  1  0.840  0.838  0.395  1.0
  Zn  Zn14  1  0.366  0.655  0.908  1.0
  Zn  Zn15  1  0.150  0.839  0.112  1.0
  B  B16  1  0.844  0.169  0.371  1.0
  B  B17  1  0.167  0.171  0.130  1.0
  B  B18  1  0.658  0.336  0.625  1.0
  B  B19  1  0.345  0.327  0.885  1.0
  B  B20  1  0.664  0.673  0.134  1.0
  B  B21  1  0.845  0.831  0.874  1.0
  B  B22  1  0.340  0.670  0.367  1.0
  B  B23  1  0.152  0.826  0.623  1.0
  O  O24  1  0.705  0.037  0.349  1.0
  O  O25  1  0.903  0.169  0.099  1.0
  O  O26  1  0.310  0.038  0.131  1.0
  O  O27  1  0.781  0.198  0.649  1.0
  O  O28  1  0.723  0.307  0.357  1.0
  O  O29  1  0.223  0.191  0.854  1.0
  O  O30  1  0.111  0.162  0.404  1.0
  O  O31  1  0.605  0.326  0.925  1.0
  O  O32  1  0.811  0.467  0.621  1.0
  O  O33  1  0.293  0.306  0.162  1.0
  O  O34  1  0.384  0.345  0.610  1.0
  O  O35  1  0.799  0.539  0.154  1.0
  O  O36  1  0.211  0.460  0.878  1.0
  O  O37  1  0.714  0.700  0.838  1.0
  O  O38  1  0.605  0.665  0.389  1.0
  O  O39  1  0.197  0.533  0.364  1.0
  O  O40  1  0.397  0.665  0.097  1.0
  O  O41  1  0.782  0.811  0.147  1.0
  O  O42  1  0.882  0.835  0.593  1.0
  O  O43  1  0.264  0.683  0.638  1.0
  O  O44  1  0.207  0.805  0.348  1.0
  O  O45  1  0.712  0.968  0.863  1.0
  O  O46  1  0.106  0.828  0.917  1.0
  O  O47  1  0.297  0.957  0.637  1.0
[/CIF]
.
The material described by LiZnBO3 crystallizes in the triclinic P1 space group. There are eight inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(18), one O(2), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Zn(3)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra,  a cornercorner with one Zn(1)O4 trigonal pyramid, and corners with two equivalent Zn(8)O4 trigonal pyramids. In the second Li site, Li(2) is bonded in a distorted trigonal planar geometry to one O(22), one O(23), and one O(6) atom. In the third Li site, Li(3) is bonded in a distorted trigonal planar geometry to one O(1), one O(21), one O(3), and one O(7) atom. In the fourth Li site, Li(4) is bonded to one O(12), one O(15), one O(16), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra, corners with two equivalent Zn(4)O4 trigonal pyramids, and  an edgeedge with one Li(6)O4 trigonal pyramid. In the fifth Li site, Li(5) is bonded in a 4-coordinate geometry to one O(11), one O(13), one O(20), and one O(9) atom. In the sixth Li site, Li(6) is bonded to one O(10), one O(12), one O(16), and one O(17) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Zn(7)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra,  a cornercorner with one Zn(8)O4 trigonal pyramid,  an edgeedge with one Li(4)O4 tetrahedra, and  an edgeedge with one Zn(4)O4 trigonal pyramid. In the seventh Li site, Li(7) is bonded to one O(11), one O(16), one O(20), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Zn(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 trigonal pyramid,  a cornercorner with one Zn(2)O4 trigonal pyramid, and  a cornercorner with one Zn(4)O4 trigonal pyramid. In the eighth Li site, Li(8) is bonded to one O(19), one O(22), one O(24), and one O(4) atom to form LiO4 tetrahedra that share  a cornercorner with one Zn(5)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra,  a cornercorner with one Zn(1)O4 trigonal pyramid, and corners with two equivalent Zn(2)O4 trigonal pyramids. There are eight inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(22), one O(6), and one O(8) atom to form distorted ZnO4 trigonal pyramids that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra, and  an edgeedge with one Zn(3)O4 tetrahedra. In the second Zn site, Zn(2) is bonded to one O(11), one O(24), one O(4), and one O(7) atom to form distorted ZnO4 trigonal pyramids that share  a cornercorner with one Li(7)O4 tetrahedra, corners with two equivalent Li(8)O4 tetrahedra, and  a cornercorner with one Zn(4)O4 trigonal pyramid. In the third Zn site, Zn(3) is bonded to one O(10), one O(12), one O(2), and one O(8) atom to form ZnO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Zn(4)O4 trigonal pyramid, corners with two equivalent Li(6)O4 trigonal pyramids, and  an edgeedge with one Zn(1)O4 trigonal pyramid. In the fourth Zn site, Zn(4) is bonded to one O(10), one O(16), one O(5), and one O(7) atom to form ZnO4 trigonal pyramids that share  a cornercorner with one Li(7)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Zn(2)O4 trigonal pyramid, and  an edgeedge with one Li(6)O4 trigonal pyramid. In the fifth Zn site, Zn(5) is bonded to one O(14), one O(19), one O(20), and one O(9) atom to form ZnO4 tetrahedra that share  a cornercorner with one Li(8)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra,  a cornercorner with one Zn(7)O4 tetrahedra, and corners with two equivalent Li(7)O4 tetrahedra. In the sixth Zn site, Zn(6) is bonded to one O(1), one O(15), one O(19), and one O(21) atom to form ZnO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(8)O4 tetrahedra, and  a cornercorner with one Zn(5)O4 tetrahedra. In the seventh Zn site, Zn(7) is bonded to one O(13), one O(14), one O(17), and one O(23) atom to form distorted ZnO4 tetrahedra that share  a cornercorner with one Zn(5)O4 tetrahedra,  a cornercorner with one Li(6)O4 trigonal pyramid, and  an edgeedge with one Zn(8)O4 trigonal pyramid. In the eighth Zn site, Zn(8) is bonded to one O(17), one O(18), one O(23), and one O(3) atom to form distorted ZnO4 trigonal pyramids that share corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(6)O4 trigonal pyramid, and  an edgeedge with one Zn(7)O4 tetrahedra. There are eight inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(7) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(10), one O(2), and one O(3) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(11), one O(4), and one O(9) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(13), one O(6), and one O(8) atom. In the fifth B site, B(5) is bonded in a trigonal planar geometry to one O(12), one O(17), and one O(18) atom. In the sixth B site, B(6) is bonded in a trigonal planar geometry to one O(14), one O(22), and one O(23) atom. In the seventh B site, B(7) is bonded in a trigonal planar geometry to one O(15), one O(16), and one O(21) atom. In the eighth B site, B(8) is bonded in a trigonal planar geometry to one O(19), one O(20), and one O(24) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(3), one Zn(6), and one B(1) atom to form distorted corner-sharing OLi2ZnB trigonal pyramids. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(1), one Zn(1), one Zn(3), and one B(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Li(3), one Zn(8), and one B(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(8), one Zn(2), and one B(3) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Li(4), one Zn(4), and one B(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(2), one Zn(1), and one B(4) atom. In the seventh O site, O(7) is bonded to one Li(3), one Zn(2), one Zn(4), and one B(1) atom to form distorted OLiZn2B tetrahedra that share  a cornercorner with one O(16)Li3ZnB trigonal bipyramid and corners with two equivalent O(1)Li2ZnB trigonal pyramids. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(3), and one B(4) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Li(5), one Li(7), one Zn(5), and one B(3) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Zn(3), one Zn(4), and one B(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(5), one Li(7), one Zn(2), and one B(3) atom. In the twelfth O site, O(12) is bonded to one Li(4), one Li(6), one Zn(3), and one B(5) atom to form distorted OLi2ZnB trigonal pyramids that share corners with two equivalent O(17)LiZn2B tetrahedra and  an edgeedge with one O(16)Li3ZnB trigonal bipyramid. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one Li(5), one Zn(7), and one B(4) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal non-coplanar geometry to one Zn(5), one Zn(7), and one B(6) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Li(4), one Zn(6), and one B(7) atom. In the sixteenth O site, O(16) is bonded to one Li(4), one Li(6), one Li(7), one Zn(4), and one B(7) atom to form distorted OLi3ZnB trigonal bipyramids that share  a cornercorner with one O(20)Li2ZnB tetrahedra,  a cornercorner with one O(17)LiZn2B tetrahedra,  a cornercorner with one O(7)LiZn2B tetrahedra, and  an edgeedge with one O(12)Li2ZnB trigonal pyramid. In the seventeenth O site, O(17) is bonded to one Li(6), one Zn(7), one Zn(8), and one B(5) atom to form distorted OLiZn2B tetrahedra that share  a cornercorner with one O(16)Li3ZnB trigonal bipyramid and corners with two equivalent O(12)Li2ZnB trigonal pyramids. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Li(1), one Zn(8), and one B(5) atom. In the nineteenth O site, O(19) is bonded to one Li(8), one Zn(5), one Zn(6), and one B(8) atom to form distorted corner-sharing OLiZn2B tetrahedra. In the twentieth O site, O(20) is bonded to one Li(5), one Li(7), one Zn(5), and one B(8) atom to form distorted OLi2ZnB tetrahedra that share corners with two equivalent O(19)LiZn2B tetrahedra and  a cornercorner with one O(16)Li3ZnB trigonal bipyramid. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Li(3), one Zn(6), and one B(7) atom. In the twenty-second O site, O(22) is bonded to one Li(2), one Li(8), one Zn(1), and one B(6) atom to form distorted corner-sharing OLi2ZnB trigonal pyramids. In the twenty-third O site, O(23) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Zn(7), one Zn(8), and one B(6) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Li(8), one Zn(2), and one B(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiZnBO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.082
_cell_length_b   8.859
_cell_length_c   11.222
_cell_angle_alpha   90.013
_cell_angle_beta   90.415
_cell_angle_gamma   90.096
_symmetry_Int_Tables_number   1
_cell_volume   505.237
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.675  0.015  0.166  1.0
  Li  Li1  1  0.348  0.998  0.898  1.0
  Li  Li2  1  0.336  0.003  0.353  1.0
  Li  Li3  1  0.824  0.510  0.333  1.0
  Li  Li4  1  0.104  0.492  0.726  1.0
  Li  Li5  1  0.165  0.509  0.153  1.0
  Li  Li6  1  0.152  0.506  0.534  1.0
  Li  Li7  1  0.661  0.994  0.672  1.0
  Zn  Zn8  1  0.855  0.169  0.891  1.0
  Zn  Zn9  1  0.160  0.162  0.621  1.0
  Zn  Zn10  1  0.662  0.345  0.102  1.0
  Zn  Zn11  1  0.344  0.326  0.353  1.0
  Zn  Zn12  1  0.651  0.666  0.650  1.0
  Zn  Zn13  1  0.840  0.838  0.395  1.0
  Zn  Zn14  1  0.366  0.655  0.908  1.0
  Zn  Zn15  1  0.150  0.839  0.112  1.0
  B  B16  1  0.844  0.169  0.371  1.0
  B  B17  1  0.167  0.171  0.130  1.0
  B  B18  1  0.658  0.336  0.625  1.0
  B  B19  1  0.345  0.327  0.885  1.0
  B  B20  1  0.664  0.673  0.134  1.0
  B  B21  1  0.845  0.831  0.874  1.0
  B  B22  1  0.340  0.670  0.367  1.0
  B  B23  1  0.152  0.826  0.623  1.0
  O  O24  1  0.705  0.037  0.349  1.0
  O  O25  1  0.903  0.169  0.099  1.0
  O  O26  1  0.310  0.038  0.131  1.0
  O  O27  1  0.781  0.198  0.649  1.0
  O  O28  1  0.723  0.307  0.357  1.0
  O  O29  1  0.223  0.191  0.854  1.0
  O  O30  1  0.111  0.162  0.404  1.0
  O  O31  1  0.605  0.326  0.925  1.0
  O  O32  1  0.811  0.467  0.621  1.0
  O  O33  1  0.293  0.306  0.162  1.0
  O  O34  1  0.384  0.345  0.610  1.0
  O  O35  1  0.799  0.539  0.154  1.0
  O  O36  1  0.211  0.460  0.878  1.0
  O  O37  1  0.714  0.700  0.838  1.0
  O  O38  1  0.605  0.665  0.389  1.0
  O  O39  1  0.197  0.533  0.364  1.0
  O  O40  1  0.397  0.665  0.097  1.0
  O  O41  1  0.782  0.811  0.147  1.0
  O  O42  1  0.882  0.835  0.593  1.0
  O  O43  1  0.264  0.683  0.638  1.0
  O  O44  1  0.207  0.805  0.348  1.0
  O  O45  1  0.712  0.968  0.863  1.0
  O  O46  1  0.106  0.828  0.917  1.0
  O  O47  1  0.297  0.957  0.637  1.0
[/CIF]
.