The compound described by Te(S2O7)2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two Te(S2O7)2 clusters. In one of the Te(S2O7)2 clusters, Te(1) is bonded in a 4-coordinate geometry to one O(11), one O(18), one O(3), and one O(9) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(23), one O(3), and one O(4) atom to form corner-sharing SO4 tetrahedra. In the second S site, S(3) is bonded to one O(11), one O(16), one O(21), and one O(4) atom to form corner-sharing SO4 tetrahedra. In the third S site, S(4) is bonded to one O(12), one O(19), one O(7), and one O(9) atom to form corner-sharing SO4 tetrahedra. In the fourth S site, S(7) is bonded to one O(15), one O(18), one O(19), and one O(26) atom to form corner-sharing SO4 tetrahedra. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Te(1) and one S(1) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. In the fourth O site, O(7) is bonded in a single-bond geometry to one S(4) atom. In the fifth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Te(1) and one S(4) atom. In the sixth O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Te(1) and one S(3) atom. In the seventh O site, O(12) is bonded in a single-bond geometry to one S(4) atom. In the eighth O site, O(15) is bonded in a single-bond geometry to one S(7) atom. In the ninth O site, O(16) is bonded in a single-bond geometry to one S(3) atom. In the tenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Te(1) and one S(7) atom. In the eleventh O site, O(19) is bonded in a bent 120 degrees geometry to one S(4) and one S(7) atom. In the twelfth O site, O(21) is bonded in a single-bond geometry to one S(3) atom. In the thirteenth O site, O(23) is bonded in a single-bond geometry to one S(1) atom. In the fourteenth O site, O(26) is bonded in a single-bond geometry to one S(7) atom. In one of the Te(S2O7)2 clusters, Te(2) is bonded in a distorted rectangular see-saw-like geometry to one O(17), one O(20), one O(24), and one O(8) atom. There are four inequivalent S sites. In the first S site, S(2) is bonded to one O(10), one O(2), one O(27), and one O(8) atom to form corner-sharing SO4 tetrahedra. In the second S site, S(5) is bonded to one O(10), one O(14), one O(20), and one O(22) atom to form corner-sharing SO4 tetrahedra. In the third S site, S(6) is bonded to one O(13), one O(17), one O(25), and one O(6) atom to form corner-sharing SO4 tetrahedra. In the fourth S site, S(8) is bonded to one O(24), one O(25), one O(28), and one O(5) atom to form corner-sharing SO4 tetrahedra. There are fourteen inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(5) is bonded in a single-bond geometry to one S(8) atom. In the third O site, O(6) is bonded in a single-bond geometry to one S(6) atom. In the fourth O site, O(8) is bonded in a bent 120 degrees geometry to one Te(2) and one S(2) atom. In the fifth O site, O(10) is bonded in a bent 120 degrees geometry to one S(2) and one S(5) atom. In the sixth O site, O(13) is bonded in a single-bond geometry to one S(6) atom. In the seventh O site, O(14) is bonded in a single-bond geometry to one S(5) atom. In the eighth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Te(2) and one S(6) atom. In the ninth O site, O(20) is bonded in a distorted bent 150 degrees geometry to one Te(2) and one S(5) atom. In the tenth O site, O(22) is bonded in a single-bond geometry to one S(5) atom. In the eleventh O site, O(24) is bonded in a bent 120 degrees geometry to one Te(2) and one S(8) atom. In the twelfth O site, O(25) is bonded in a bent 120 degrees geometry to one S(6) and one S(8) atom. In the thirteenth O site, O(27) is bonded in a single-bond geometry to one S(2) atom. In the fourteenth O site, O(28) is bonded in a single-bond geometry to one S(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Te(S2O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.834
_cell_length_b   6.835
_cell_length_c   12.024
_cell_angle_alpha   80.227
_cell_angle_beta   80.431
_cell_angle_gamma   77.478
_symmetry_Int_Tables_number   1
_cell_volume   535.398
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.065  0.946  0.751  1.0
  Te  Te1  1  0.940  0.055  0.250  1.0
  S  S2  1  0.468  0.922  0.856  1.0
  S  S3  1  0.928  0.456  0.353  1.0
  S  S4  1  0.198  0.688  0.999  1.0
  S  S5  1  0.310  0.805  0.506  1.0
  S  S6  1  0.699  0.187  0.502  1.0
  S  S7  1  0.802  0.306  0.004  1.0
  S  S8  1  0.218  0.491  0.684  1.0
  S  S9  1  0.532  0.075  0.151  1.0
  O  O10  1  0.677  0.881  0.816  1.0
  O  O11  1  0.883  0.666  0.315  1.0
  O  O12  1  0.358  0.919  0.751  1.0
  O  O13  1  0.427  0.719  0.933  1.0
  O  O14  1  0.622  0.901  0.099  1.0
  O  O15  1  0.825  0.238  0.897  1.0
  O  O16  1  0.511  0.769  0.528  1.0
  O  O17  1  0.908  0.349  0.250  1.0
  O  O18  1  0.166  0.951  0.579  1.0
  O  O19  1  0.732  0.416  0.438  1.0
  O  O20  1  0.062  0.842  0.925  1.0
  O  O21  1  0.262  0.848  0.393  1.0
  O  O22  1  0.797  0.510  0.012  1.0
  O  O23  1  0.773  0.159  0.609  1.0
  O  O24  1  0.412  0.460  0.717  1.0
  O  O25  1  0.203  0.485  0.989  1.0
  O  O26  1  0.940  0.154  0.079  1.0
  O  O27  1  0.067  0.657  0.747  1.0
  O  O28  1  0.219  0.594  0.554  1.0
  O  O29  1  0.841  0.049  0.425  1.0
  O  O30  1  0.177  0.752  0.108  1.0
  O  O31  1  0.492  0.198  0.499  1.0
  O  O32  1  0.374  0.092  0.910  1.0
  O  O33  1  0.645  0.081  0.254  1.0
  O  O34  1  0.574  0.275  0.070  1.0
  O  O35  1  0.115  0.330  0.691  1.0
  O  O36  1  0.106  0.361  0.400  1.0
  O  O37  1  0.322  0.122  0.190  1.0
[/CIF]
.
The compound described by Te(S2O7)2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two Te(S2O7)2 clusters. In one of the Te(S2O7)2 clusters, Te(1) is bonded in a 4-coordinate geometry to one O(11), one O(18), one O(3), and one O(9) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(23), one O(3), and one O(4) atom to form corner-sharing SO4 tetrahedra. In the second S site, S(3) is bonded to one O(11), one O(16), one O(21), and one O(4) atom to form corner-sharing SO4 tetrahedra. In the third S site, S(4) is bonded to one O(12), one O(19), one O(7), and one O(9) atom to form corner-sharing SO4 tetrahedra. In the fourth S site, S(7) is bonded to one O(15), one O(18), one O(19), and one O(26) atom to form corner-sharing SO4 tetrahedra. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Te(1) and one S(1) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one S(1) and one S(3) atom. In the fourth O site, O(7) is bonded in a single-bond geometry to one S(4) atom. In the fifth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Te(1) and one S(4) atom. In the sixth O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Te(1) and one S(3) atom. In the seventh O site, O(12) is bonded in a single-bond geometry to one S(4) atom. In the eighth O site, O(15) is bonded in a single-bond geometry to one S(7) atom. In the ninth O site, O(16) is bonded in a single-bond geometry to one S(3) atom. In the tenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Te(1) and one S(7) atom. In the eleventh O site, O(19) is bonded in a bent 120 degrees geometry to one S(4) and one S(7) atom. In the twelfth O site, O(21) is bonded in a single-bond geometry to one S(3) atom. In the thirteenth O site, O(23) is bonded in a single-bond geometry to one S(1) atom. In the fourteenth O site, O(26) is bonded in a single-bond geometry to one S(7) atom. In one of the Te(S2O7)2 clusters, Te(2) is bonded in a distorted rectangular see-saw-like geometry to one O(17), one O(20), one O(24), and one O(8) atom. There are four inequivalent S sites. In the first S site, S(2) is bonded to one O(10), one O(2), one O(27), and one O(8) atom to form corner-sharing SO4 tetrahedra. In the second S site, S(5) is bonded to one O(10), one O(14), one O(20), and one O(22) atom to form corner-sharing SO4 tetrahedra. In the third S site, S(6) is bonded to one O(13), one O(17), one O(25), and one O(6) atom to form corner-sharing SO4 tetrahedra. In the fourth S site, S(8) is bonded to one O(24), one O(25), one O(28), and one O(5) atom to form corner-sharing SO4 tetrahedra. There are fourteen inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(5) is bonded in a single-bond geometry to one S(8) atom. In the third O site, O(6) is bonded in a single-bond geometry to one S(6) atom. In the fourth O site, O(8) is bonded in a bent 120 degrees geometry to one Te(2) and one S(2) atom. In the fifth O site, O(10) is bonded in a bent 120 degrees geometry to one S(2) and one S(5) atom. In the sixth O site, O(13) is bonded in a single-bond geometry to one S(6) atom. In the seventh O site, O(14) is bonded in a single-bond geometry to one S(5) atom. In the eighth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Te(2) and one S(6) atom. In the ninth O site, O(20) is bonded in a distorted bent 150 degrees geometry to one Te(2) and one S(5) atom. In the tenth O site, O(22) is bonded in a single-bond geometry to one S(5) atom. In the eleventh O site, O(24) is bonded in a bent 120 degrees geometry to one Te(2) and one S(8) atom. In the twelfth O site, O(25) is bonded in a bent 120 degrees geometry to one S(6) and one S(8) atom. In the thirteenth O site, O(27) is bonded in a single-bond geometry to one S(2) atom. In the fourteenth O site, O(28) is bonded in a single-bond geometry to one S(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Te(S2O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.834
_cell_length_b   6.835
_cell_length_c   12.024
_cell_angle_alpha   80.227
_cell_angle_beta   80.431
_cell_angle_gamma   77.478
_symmetry_Int_Tables_number   1
_cell_volume   535.398
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.065  0.946  0.751  1.0
  Te  Te1  1  0.940  0.055  0.250  1.0
  S  S2  1  0.468  0.922  0.856  1.0
  S  S3  1  0.928  0.456  0.353  1.0
  S  S4  1  0.198  0.688  0.999  1.0
  S  S5  1  0.310  0.805  0.506  1.0
  S  S6  1  0.699  0.187  0.502  1.0
  S  S7  1  0.802  0.306  0.004  1.0
  S  S8  1  0.218  0.491  0.684  1.0
  S  S9  1  0.532  0.075  0.151  1.0
  O  O10  1  0.677  0.881  0.816  1.0
  O  O11  1  0.883  0.666  0.315  1.0
  O  O12  1  0.358  0.919  0.751  1.0
  O  O13  1  0.427  0.719  0.933  1.0
  O  O14  1  0.622  0.901  0.099  1.0
  O  O15  1  0.825  0.238  0.897  1.0
  O  O16  1  0.511  0.769  0.528  1.0
  O  O17  1  0.908  0.349  0.250  1.0
  O  O18  1  0.166  0.951  0.579  1.0
  O  O19  1  0.732  0.416  0.438  1.0
  O  O20  1  0.062  0.842  0.925  1.0
  O  O21  1  0.262  0.848  0.393  1.0
  O  O22  1  0.797  0.510  0.012  1.0
  O  O23  1  0.773  0.159  0.609  1.0
  O  O24  1  0.412  0.460  0.717  1.0
  O  O25  1  0.203  0.485  0.989  1.0
  O  O26  1  0.940  0.154  0.079  1.0
  O  O27  1  0.067  0.657  0.747  1.0
  O  O28  1  0.219  0.594  0.554  1.0
  O  O29  1  0.841  0.049  0.425  1.0
  O  O30  1  0.177  0.752  0.108  1.0
  O  O31  1  0.492  0.198  0.499  1.0
  O  O32  1  0.374  0.092  0.910  1.0
  O  O33  1  0.645  0.081  0.254  1.0
  O  O34  1  0.574  0.275  0.070  1.0
  O  O35  1  0.115  0.330  0.691  1.0
  O  O36  1  0.106  0.361  0.400  1.0
  O  O37  1  0.322  0.122  0.190  1.0
[/CIF]
.