The crystal structure described by Rb2Pd3S4 crystallizes in the triclinic P1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 14-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), two equivalent Pd(3), one S(2), one S(4), three equivalent S(1), and three equivalent S(3) atoms. In the second Rb site, Rb(2) is bonded in a 14-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), two equivalent Pd(3), one S(1), one S(3), three equivalent S(2), and three equivalent S(4) atoms. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted square co-planar geometry to two equivalent Rb(1), two equivalent Rb(2), one S(1), one S(2), one S(3), and one S(4) atom. In the second Pd site, Pd(2) is bonded in a distorted square co-planar geometry to two equivalent Rb(1), two equivalent Rb(2), one S(1), one S(2), one S(3), and one S(4) atom. In the third Pd site, Pd(3) is bonded in a distorted square co-planar geometry to two equivalent Rb(1), two equivalent Rb(2), one S(1), one S(2), one S(3), and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 7-coordinate geometry to one Rb(2), three equivalent Rb(1), one Pd(1), one Pd(2), and one Pd(3) atom. In the second S site, S(2) is bonded in a 7-coordinate geometry to one Rb(1), three equivalent Rb(2), one Pd(1), one Pd(2), and one Pd(3) atom. In the third S site, S(3) is bonded in a 7-coordinate geometry to one Rb(2), three equivalent Rb(1), one Pd(1), one Pd(2), and one Pd(3) atom. In the fourth S site, S(4) is bonded in a 7-coordinate geometry to one Rb(1), three equivalent Rb(2), one Pd(1), one Pd(2), and one Pd(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2Pd3S4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.720
_cell_length_b   7.581
_cell_length_c   6.236
_cell_angle_alpha   77.589
_cell_angle_beta   58.111
_cell_angle_gamma   44.301
_symmetry_Int_Tables_number   1
_cell_volume   235.053
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.839  0.841  0.166  1.0
  Rb  Rb1  1  0.149  0.167  0.847  1.0
  Pd  Pd2  1  0.991  0.005  0.503  1.0
  Pd  Pd3  1  0.499  0.497  0.508  1.0
  Pd  Pd4  1  0.507  0.497  0.002  1.0
  S  S5  1  0.227  0.557  0.437  1.0
  S  S6  1  0.450  0.771  0.213  1.0
  S  S7  1  0.565  0.214  0.771  1.0
  S  S8  1  0.785  0.440  0.561  1.0
[/CIF]
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The crystal structure described by Rb2Pd3S4 crystallizes in the triclinic P1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 14-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), two equivalent Pd(3), one S(2), one S(4), three equivalent S(1), and three equivalent S(3) atoms. In the second Rb site, Rb(2) is bonded in a 14-coordinate geometry to two equivalent Pd(1), two equivalent Pd(2), two equivalent Pd(3), one S(1), one S(3), three equivalent S(2), and three equivalent S(4) atoms. There are three inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted square co-planar geometry to two equivalent Rb(1), two equivalent Rb(2), one S(1), one S(2), one S(3), and one S(4) atom. In the second Pd site, Pd(2) is bonded in a distorted square co-planar geometry to two equivalent Rb(1), two equivalent Rb(2), one S(1), one S(2), one S(3), and one S(4) atom. In the third Pd site, Pd(3) is bonded in a distorted square co-planar geometry to two equivalent Rb(1), two equivalent Rb(2), one S(1), one S(2), one S(3), and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 7-coordinate geometry to one Rb(2), three equivalent Rb(1), one Pd(1), one Pd(2), and one Pd(3) atom. In the second S site, S(2) is bonded in a 7-coordinate geometry to one Rb(1), three equivalent Rb(2), one Pd(1), one Pd(2), and one Pd(3) atom. In the third S site, S(3) is bonded in a 7-coordinate geometry to one Rb(2), three equivalent Rb(1), one Pd(1), one Pd(2), and one Pd(3) atom. In the fourth S site, S(4) is bonded in a 7-coordinate geometry to one Rb(1), three equivalent Rb(2), one Pd(1), one Pd(2), and one Pd(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2Pd3S4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.720
_cell_length_b   7.581
_cell_length_c   6.236
_cell_angle_alpha   77.589
_cell_angle_beta   58.111
_cell_angle_gamma   44.301
_symmetry_Int_Tables_number   1
_cell_volume   235.053
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.839  0.841  0.166  1.0
  Rb  Rb1  1  0.149  0.167  0.847  1.0
  Pd  Pd2  1  0.991  0.005  0.503  1.0
  Pd  Pd3  1  0.499  0.497  0.508  1.0
  Pd  Pd4  1  0.507  0.497  0.002  1.0
  S  S5  1  0.227  0.557  0.437  1.0
  S  S6  1  0.450  0.771  0.213  1.0
  S  S7  1  0.565  0.214  0.771  1.0
  S  S8  1  0.785  0.440  0.561  1.0
[/CIF]
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