The structure described by In(OH)3 crystallizes in the triclinic P1 space group. There are four inequivalent In sites. In the first In site, In(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(5), and one O(8) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 37-56°. In the second In site, In(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(4), and one O(9) atom to form distorted corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 31-54°. In the third In site, In(3) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 37-54°. In the fourth In site, In(4) is bonded to one O(11), one O(2), one O(4), one O(6), one O(7), and one O(9) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 31-56°. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(6) atom. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one O(7) atom. In the sixth H site, H(6) is bonded in a linear geometry to one O(4) and one O(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(10) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(2) atom. In the eleventh H site, H(11) is bonded in a linear geometry to one O(12) and one O(7) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(12) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one In(1), one In(2), and one H(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one In(1), one In(4), and one H(10) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one In(2), one In(3), and one H(2) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one In(2), one In(4), and one H(6) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one In(1), one In(3), and one H(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one In(3), one In(4), and one H(4) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one In(3), one In(4), one H(11), and one H(5) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one In(1), one In(3), and one H(6) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one In(2), one In(4), and one H(7) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one In(2), one In(3), and one H(9) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one In(1), one In(4), and one H(8) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one In(1), one In(2), one H(11), and one H(12) atom. is represented by the CIF file [CIF]
data_In(HO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.024
_cell_length_b   7.004
_cell_length_c   7.054
_cell_angle_alpha   111.344
_cell_angle_beta   110.351
_cell_angle_gamma   106.901
_symmetry_Int_Tables_number   1
_cell_volume   266.198
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.512  0.011  0.008  1.0
  In  In1  1  0.003  0.480  0.012  1.0
  In  In2  1  0.998  0.002  0.500  1.0
  In  In3  1  0.479  0.488  0.476  1.0
  H  H4  1  0.822  0.457  0.282  1.0
  H  H5  1  0.706  0.166  0.551  1.0
  H  H6  1  0.559  0.726  0.168  1.0
  H  H7  1  0.900  0.719  0.636  1.0
  H  H8  1  0.037  0.325  0.370  1.0
  H  H9  1  0.289  0.259  0.967  1.0
  H  H10  1  0.716  0.657  0.943  1.0
  H  H11  1  0.633  0.948  0.682  1.0
  H  H12  1  0.278  0.832  0.456  1.0
  H  H13  1  0.350  0.031  0.311  1.0
  H  H14  1  0.181  0.509  0.692  1.0
  H  H15  1  0.077  0.694  0.791  1.0
  O  O16  1  0.833  0.326  0.171  1.0
  O  O17  1  0.478  0.153  0.322  1.0
  O  O18  1  0.826  0.156  0.670  1.0
  O  O19  1  0.310  0.471  0.156  1.0
  O  O20  1  0.679  0.840  0.162  1.0
  O  O21  1  0.802  0.665  0.471  1.0
  O  O22  1  0.163  0.338  0.509  1.0
  O  O23  1  0.269  0.107  0.837  1.0
  O  O24  1  0.745  0.561  0.822  1.0
  O  O25  1  0.158  0.834  0.329  1.0
  O  O26  1  0.507  0.833  0.681  1.0
  O  O27  1  0.199  0.655  0.850  1.0
[/CIF]
.
The structure described by In(OH)3 crystallizes in the triclinic P1 space group. There are four inequivalent In sites. In the first In site, In(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(5), and one O(8) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 37-56°. In the second In site, In(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(4), and one O(9) atom to form distorted corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 31-54°. In the third In site, In(3) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 37-54°. In the fourth In site, In(4) is bonded to one O(11), one O(2), one O(4), one O(6), one O(7), and one O(9) atom to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 31-56°. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(6) atom. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one O(7) atom. In the sixth H site, H(6) is bonded in a linear geometry to one O(4) and one O(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(10) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(2) atom. In the eleventh H site, H(11) is bonded in a linear geometry to one O(12) and one O(7) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(12) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one In(1), one In(2), and one H(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one In(1), one In(4), and one H(10) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one In(2), one In(3), and one H(2) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one In(2), one In(4), and one H(6) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one In(1), one In(3), and one H(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one In(3), one In(4), and one H(4) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one In(3), one In(4), one H(11), and one H(5) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one In(1), one In(3), and one H(6) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one In(2), one In(4), and one H(7) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one In(2), one In(3), and one H(9) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one In(1), one In(4), and one H(8) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one In(1), one In(2), one H(11), and one H(12) atom. is represented by the CIF file [CIF]
data_In(HO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.024
_cell_length_b   7.004
_cell_length_c   7.054
_cell_angle_alpha   111.344
_cell_angle_beta   110.351
_cell_angle_gamma   106.901
_symmetry_Int_Tables_number   1
_cell_volume   266.198
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.512  0.011  0.008  1.0
  In  In1  1  0.003  0.480  0.012  1.0
  In  In2  1  0.998  0.002  0.500  1.0
  In  In3  1  0.479  0.488  0.476  1.0
  H  H4  1  0.822  0.457  0.282  1.0
  H  H5  1  0.706  0.166  0.551  1.0
  H  H6  1  0.559  0.726  0.168  1.0
  H  H7  1  0.900  0.719  0.636  1.0
  H  H8  1  0.037  0.325  0.370  1.0
  H  H9  1  0.289  0.259  0.967  1.0
  H  H10  1  0.716  0.657  0.943  1.0
  H  H11  1  0.633  0.948  0.682  1.0
  H  H12  1  0.278  0.832  0.456  1.0
  H  H13  1  0.350  0.031  0.311  1.0
  H  H14  1  0.181  0.509  0.692  1.0
  H  H15  1  0.077  0.694  0.791  1.0
  O  O16  1  0.833  0.326  0.171  1.0
  O  O17  1  0.478  0.153  0.322  1.0
  O  O18  1  0.826  0.156  0.670  1.0
  O  O19  1  0.310  0.471  0.156  1.0
  O  O20  1  0.679  0.840  0.162  1.0
  O  O21  1  0.802  0.665  0.471  1.0
  O  O22  1  0.163  0.338  0.509  1.0
  O  O23  1  0.269  0.107  0.837  1.0
  O  O24  1  0.745  0.561  0.822  1.0
  O  O25  1  0.158  0.834  0.329  1.0
  O  O26  1  0.507  0.833  0.681  1.0
  O  O27  1  0.199  0.655  0.850  1.0
[/CIF]
.