The compound described by Cu(XeF2)6(SbF6)2 is Fluorite structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of three Cu(XeF2)6 clusters and six SbF6 clusters. In each Cu(XeF2)6 cluster, Xe(1) is bonded in a linear geometry to one F(3) and one F(4) atom. Cu(1) is bonded in an octahedral geometry to six equivalent F(3) atoms. There are two inequivalent F sites. In the first F site, F(3) is bonded in a bent 120 degrees geometry to one Xe(1) and one Cu(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Xe(1) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to three equivalent F(1) and three equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_CuSb2(XeF4)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.721
_cell_length_b   9.721
_cell_length_c   9.721
_cell_angle_alpha   63.985
_cell_angle_beta   63.985
_cell_angle_gamma   63.985
_symmetry_Int_Tables_number   1
_cell_volume   706.635
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.500  0.500  0.500  1.0
  Sb  Sb1  1  0.247  0.247  0.247  1.0
  Sb  Sb2  1  0.753  0.753  0.753  1.0
  Xe  Xe3  1  0.279  0.204  0.764  1.0
  Xe  Xe4  1  0.764  0.279  0.204  1.0
  Xe  Xe5  1  0.796  0.236  0.721  1.0
  Xe  Xe6  1  0.204  0.764  0.279  1.0
  Xe  Xe7  1  0.236  0.721  0.796  1.0
  Xe  Xe8  1  0.721  0.796  0.236  1.0
  F  F9  1  0.867  0.628  0.909  1.0
  F  F10  1  0.120  0.400  0.366  1.0
  F  F11  1  0.707  0.556  0.384  1.0
  F  F12  1  0.600  0.634  0.880  1.0
  F  F13  1  0.981  0.906  0.262  1.0
  F  F14  1  0.133  0.372  0.091  1.0
  F  F15  1  0.384  0.707  0.556  1.0
  F  F16  1  0.293  0.444  0.616  1.0
  F  F17  1  0.019  0.094  0.738  1.0
  F  F18  1  0.880  0.600  0.634  1.0
  F  F19  1  0.556  0.384  0.707  1.0
  F  F20  1  0.616  0.293  0.444  1.0
  F  F21  1  0.094  0.738  0.019  1.0
  F  F22  1  0.262  0.981  0.906  1.0
  F  F23  1  0.372  0.091  0.133  1.0
  F  F24  1  0.366  0.120  0.400  1.0
  F  F25  1  0.400  0.366  0.120  1.0
  F  F26  1  0.738  0.019  0.094  1.0
  F  F27  1  0.634  0.880  0.600  1.0
  F  F28  1  0.909  0.867  0.628  1.0
  F  F29  1  0.444  0.616  0.293  1.0
  F  F30  1  0.628  0.909  0.867  1.0
  F  F31  1  0.091  0.133  0.372  1.0
  F  F32  1  0.906  0.262  0.981  1.0
[/CIF]
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The compound described by Cu(XeF2)6(SbF6)2 is Fluorite structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of three Cu(XeF2)6 clusters and six SbF6 clusters. In each Cu(XeF2)6 cluster, Xe(1) is bonded in a linear geometry to one F(3) and one F(4) atom. Cu(1) is bonded in an octahedral geometry to six equivalent F(3) atoms. There are two inequivalent F sites. In the first F site, F(3) is bonded in a bent 120 degrees geometry to one Xe(1) and one Cu(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Xe(1) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to three equivalent F(1) and three equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_CuSb2(XeF4)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.721
_cell_length_b   9.721
_cell_length_c   9.721
_cell_angle_alpha   63.985
_cell_angle_beta   63.985
_cell_angle_gamma   63.985
_symmetry_Int_Tables_number   1
_cell_volume   706.635
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.500  0.500  0.500  1.0
  Sb  Sb1  1  0.247  0.247  0.247  1.0
  Sb  Sb2  1  0.753  0.753  0.753  1.0
  Xe  Xe3  1  0.279  0.204  0.764  1.0
  Xe  Xe4  1  0.764  0.279  0.204  1.0
  Xe  Xe5  1  0.796  0.236  0.721  1.0
  Xe  Xe6  1  0.204  0.764  0.279  1.0
  Xe  Xe7  1  0.236  0.721  0.796  1.0
  Xe  Xe8  1  0.721  0.796  0.236  1.0
  F  F9  1  0.867  0.628  0.909  1.0
  F  F10  1  0.120  0.400  0.366  1.0
  F  F11  1  0.707  0.556  0.384  1.0
  F  F12  1  0.600  0.634  0.880  1.0
  F  F13  1  0.981  0.906  0.262  1.0
  F  F14  1  0.133  0.372  0.091  1.0
  F  F15  1  0.384  0.707  0.556  1.0
  F  F16  1  0.293  0.444  0.616  1.0
  F  F17  1  0.019  0.094  0.738  1.0
  F  F18  1  0.880  0.600  0.634  1.0
  F  F19  1  0.556  0.384  0.707  1.0
  F  F20  1  0.616  0.293  0.444  1.0
  F  F21  1  0.094  0.738  0.019  1.0
  F  F22  1  0.262  0.981  0.906  1.0
  F  F23  1  0.372  0.091  0.133  1.0
  F  F24  1  0.366  0.120  0.400  1.0
  F  F25  1  0.400  0.366  0.120  1.0
  F  F26  1  0.738  0.019  0.094  1.0
  F  F27  1  0.634  0.880  0.600  1.0
  F  F28  1  0.909  0.867  0.628  1.0
  F  F29  1  0.444  0.616  0.293  1.0
  F  F30  1  0.628  0.909  0.867  1.0
  F  F31  1  0.091  0.133  0.372  1.0
  F  F32  1  0.906  0.262  0.981  1.0
[/CIF]
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