The structure described by RbClO4 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 10-coordinate geometry to one O(2), three equivalent O(3), and six equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Rb(1) and one Cl(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.756
_cell_length_b   7.451
_cell_length_c   9.206
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   394.760
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.338  0.683  1.0
  Rb  Rb1  1  0.750  0.662  0.317  1.0
  Rb  Rb2  1  0.750  0.838  0.817  1.0
  Rb  Rb3  1  0.250  0.162  0.183  1.0
  Cl  Cl4  1  0.250  0.808  0.566  1.0
  Cl  Cl5  1  0.750  0.192  0.434  1.0
  Cl  Cl6  1  0.750  0.308  0.934  1.0
  Cl  Cl7  1  0.250  0.692  0.066  1.0
  O  O8  1  0.545  0.304  0.421  1.0
  O  O9  1  0.045  0.696  0.579  1.0
  O  O10  1  0.455  0.804  0.079  1.0
  O  O11  1  0.955  0.196  0.921  1.0
  O  O12  1  0.455  0.696  0.579  1.0
  O  O13  1  0.955  0.304  0.421  1.0
  O  O14  1  0.545  0.196  0.921  1.0
  O  O15  1  0.045  0.804  0.079  1.0
  O  O16  1  0.250  0.604  0.927  1.0
  O  O17  1  0.750  0.396  0.073  1.0
  O  O18  1  0.750  0.104  0.573  1.0
  O  O19  1  0.250  0.896  0.427  1.0
  O  O20  1  0.250  0.561  0.182  1.0
  O  O21  1  0.750  0.439  0.818  1.0
  O  O22  1  0.750  0.061  0.318  1.0
  O  O23  1  0.250  0.939  0.682  1.0
[/CIF]
.
The structure described by RbClO4 crystallizes in the orthorhombic Pnma space group. Rb(1) is bonded in a 10-coordinate geometry to one O(2), three equivalent O(3), and six equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Rb(1) and one Cl(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.756
_cell_length_b   7.451
_cell_length_c   9.206
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   394.760
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.338  0.683  1.0
  Rb  Rb1  1  0.750  0.662  0.317  1.0
  Rb  Rb2  1  0.750  0.838  0.817  1.0
  Rb  Rb3  1  0.250  0.162  0.183  1.0
  Cl  Cl4  1  0.250  0.808  0.566  1.0
  Cl  Cl5  1  0.750  0.192  0.434  1.0
  Cl  Cl6  1  0.750  0.308  0.934  1.0
  Cl  Cl7  1  0.250  0.692  0.066  1.0
  O  O8  1  0.545  0.304  0.421  1.0
  O  O9  1  0.045  0.696  0.579  1.0
  O  O10  1  0.455  0.804  0.079  1.0
  O  O11  1  0.955  0.196  0.921  1.0
  O  O12  1  0.455  0.696  0.579  1.0
  O  O13  1  0.955  0.304  0.421  1.0
  O  O14  1  0.545  0.196  0.921  1.0
  O  O15  1  0.045  0.804  0.079  1.0
  O  O16  1  0.250  0.604  0.927  1.0
  O  O17  1  0.750  0.396  0.073  1.0
  O  O18  1  0.750  0.104  0.573  1.0
  O  O19  1  0.250  0.896  0.427  1.0
  O  O20  1  0.250  0.561  0.182  1.0
  O  O21  1  0.750  0.439  0.818  1.0
  O  O22  1  0.750  0.061  0.318  1.0
  O  O23  1  0.250  0.939  0.682  1.0
[/CIF]
.