The material described by CrSbTeO6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2nm space group. Cr(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form CrO6 octahedra that share corners with four equivalent Sb(1)O6 octahedra, corners with four equivalent Te(1)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with four equivalent Cr(1)O6 octahedra, corners with four equivalent Te(1)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, and  an edgeedge with one Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. Te(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form TeO6 octahedra that share corners with four equivalent Cr(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-54°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cr(1), one Sb(1), and one Te(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Cr(1), one Sb(1), and one Te(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Cr(1), one Sb(1), and one Te(1) atom. is represented by the CIF file [CIF]
data_CrSbTeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.806
_cell_length_b   4.806
_cell_length_c   9.672
_cell_angle_alpha   89.999
_cell_angle_beta   89.998
_cell_angle_gamma   89.999
_symmetry_Int_Tables_number   1
_cell_volume   223.384
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.500  0.500  0.832  1.0
  Cr  Cr1  1  1.000  0.000  0.332  1.0
  O  O2  1  0.802  0.802  0.823  1.0
  O  O3  1  0.198  0.198  0.823  1.0
  O  O4  1  0.698  0.302  0.323  1.0
  O  O5  1  0.302  0.698  0.323  1.0
  O  O6  1  0.818  0.818  0.501  1.0
  O  O7  1  0.182  0.182  0.501  1.0
  O  O8  1  0.682  0.318  0.001  1.0
  O  O9  1  0.318  0.682  0.001  1.0
  O  O10  1  0.800  0.800  0.175  1.0
  O  O11  1  0.200  0.200  0.175  1.0
  O  O12  1  0.700  0.300  0.675  1.0
  O  O13  1  0.300  0.700  0.675  1.0
  Sb  Sb14  1  0.500  0.500  0.167  1.0
  Sb  Sb15  1  0.000  0.000  0.667  1.0
  Te  Te16  1  0.500  0.500  0.501  1.0
  Te  Te17  1  0.000  1.000  0.001  1.0
[/CIF]
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The material described by CrSbTeO6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2nm space group. Cr(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form CrO6 octahedra that share corners with four equivalent Sb(1)O6 octahedra, corners with four equivalent Te(1)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-54°. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with four equivalent Cr(1)O6 octahedra, corners with four equivalent Te(1)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, and  an edgeedge with one Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. Te(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form TeO6 octahedra that share corners with four equivalent Cr(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, and  an edgeedge with one Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-54°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cr(1), one Sb(1), and one Te(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Cr(1), one Sb(1), and one Te(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Cr(1), one Sb(1), and one Te(1) atom. is represented by the CIF file [CIF]
data_CrSbTeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.806
_cell_length_b   4.806
_cell_length_c   9.672
_cell_angle_alpha   89.999
_cell_angle_beta   89.998
_cell_angle_gamma   89.999
_symmetry_Int_Tables_number   1
_cell_volume   223.384
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.500  0.500  0.832  1.0
  Cr  Cr1  1  1.000  0.000  0.332  1.0
  O  O2  1  0.802  0.802  0.823  1.0
  O  O3  1  0.198  0.198  0.823  1.0
  O  O4  1  0.698  0.302  0.323  1.0
  O  O5  1  0.302  0.698  0.323  1.0
  O  O6  1  0.818  0.818  0.501  1.0
  O  O7  1  0.182  0.182  0.501  1.0
  O  O8  1  0.682  0.318  0.001  1.0
  O  O9  1  0.318  0.682  0.001  1.0
  O  O10  1  0.800  0.800  0.175  1.0
  O  O11  1  0.200  0.200  0.175  1.0
  O  O12  1  0.700  0.300  0.675  1.0
  O  O13  1  0.300  0.700  0.675  1.0
  Sb  Sb14  1  0.500  0.500  0.167  1.0
  Sb  Sb15  1  0.000  0.000  0.667  1.0
  Te  Te16  1  0.500  0.500  0.501  1.0
  Te  Te17  1  0.000  1.000  0.001  1.0
[/CIF]
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