The structure described by Hf3P crystallizes in the tetragonal P4_2/n space group. There are three inequivalent Hf sites. In the first Hf site, Hf(1) is bonded in a distorted bent 150 degrees geometry to two equivalent P(1) atoms. In the second Hf site, Hf(2) is bonded in a distorted see-saw-like geometry to four equivalent P(1) atoms. In the third Hf site, Hf(3) is bonded in a 3-coordinate geometry to three equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to two equivalent Hf(1), three equivalent Hf(3), and four equivalent Hf(2) atoms. is represented by the CIF card [CIF]
data_Hf3P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.288
_cell_length_b   10.659
_cell_length_c   10.659
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   600.809
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf0  1  0.718  0.165  0.643  1.0
  Hf  Hf1  1  0.218  0.357  0.665  1.0
  Hf  Hf2  1  0.218  0.143  0.835  1.0
  Hf  Hf3  1  0.718  0.335  0.857  1.0
  Hf  Hf4  1  0.282  0.835  0.357  1.0
  Hf  Hf5  1  0.782  0.643  0.335  1.0
  Hf  Hf6  1  0.782  0.857  0.165  1.0
  Hf  Hf7  1  0.282  0.665  0.143  1.0
  Hf  Hf8  1  0.529  0.112  0.277  1.0
  Hf  Hf9  1  0.029  0.723  0.612  1.0
  Hf  Hf10  1  0.029  0.777  0.888  1.0
  Hf  Hf11  1  0.529  0.388  0.223  1.0
  Hf  Hf12  1  0.471  0.888  0.723  1.0
  Hf  Hf13  1  0.971  0.277  0.388  1.0
  Hf  Hf14  1  0.971  0.223  0.112  1.0
  Hf  Hf15  1  0.471  0.612  0.777  1.0
  Hf  Hf16  1  0.239  0.069  0.534  1.0
  Hf  Hf17  1  0.739  0.466  0.569  1.0
  Hf  Hf18  1  0.739  0.034  0.931  1.0
  Hf  Hf19  1  0.239  0.431  0.966  1.0
  Hf  Hf20  1  0.761  0.931  0.466  1.0
  Hf  Hf21  1  0.261  0.534  0.431  1.0
  Hf  Hf22  1  0.261  0.966  0.069  1.0
  Hf  Hf23  1  0.761  0.569  0.034  1.0
  P  P24  1  0.036  0.044  0.291  1.0
  P  P25  1  0.536  0.709  0.544  1.0
  P  P26  1  0.536  0.791  0.956  1.0
  P  P27  1  0.036  0.456  0.209  1.0
  P  P28  1  0.964  0.956  0.709  1.0
  P  P29  1  0.464  0.291  0.456  1.0
  P  P30  1  0.464  0.209  0.044  1.0
  P  P31  1  0.964  0.544  0.791  1.0
[/CIF]
.
The structure described by Hf3P crystallizes in the tetragonal P4_2/n space group. There are three inequivalent Hf sites. In the first Hf site, Hf(1) is bonded in a distorted bent 150 degrees geometry to two equivalent P(1) atoms. In the second Hf site, Hf(2) is bonded in a distorted see-saw-like geometry to four equivalent P(1) atoms. In the third Hf site, Hf(3) is bonded in a 3-coordinate geometry to three equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to two equivalent Hf(1), three equivalent Hf(3), and four equivalent Hf(2) atoms. is represented by the CIF card [CIF]
data_Hf3P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.288
_cell_length_b   10.659
_cell_length_c   10.659
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   600.809
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf0  1  0.718  0.165  0.643  1.0
  Hf  Hf1  1  0.218  0.357  0.665  1.0
  Hf  Hf2  1  0.218  0.143  0.835  1.0
  Hf  Hf3  1  0.718  0.335  0.857  1.0
  Hf  Hf4  1  0.282  0.835  0.357  1.0
  Hf  Hf5  1  0.782  0.643  0.335  1.0
  Hf  Hf6  1  0.782  0.857  0.165  1.0
  Hf  Hf7  1  0.282  0.665  0.143  1.0
  Hf  Hf8  1  0.529  0.112  0.277  1.0
  Hf  Hf9  1  0.029  0.723  0.612  1.0
  Hf  Hf10  1  0.029  0.777  0.888  1.0
  Hf  Hf11  1  0.529  0.388  0.223  1.0
  Hf  Hf12  1  0.471  0.888  0.723  1.0
  Hf  Hf13  1  0.971  0.277  0.388  1.0
  Hf  Hf14  1  0.971  0.223  0.112  1.0
  Hf  Hf15  1  0.471  0.612  0.777  1.0
  Hf  Hf16  1  0.239  0.069  0.534  1.0
  Hf  Hf17  1  0.739  0.466  0.569  1.0
  Hf  Hf18  1  0.739  0.034  0.931  1.0
  Hf  Hf19  1  0.239  0.431  0.966  1.0
  Hf  Hf20  1  0.761  0.931  0.466  1.0
  Hf  Hf21  1  0.261  0.534  0.431  1.0
  Hf  Hf22  1  0.261  0.966  0.069  1.0
  Hf  Hf23  1  0.761  0.569  0.034  1.0
  P  P24  1  0.036  0.044  0.291  1.0
  P  P25  1  0.536  0.709  0.544  1.0
  P  P26  1  0.536  0.791  0.956  1.0
  P  P27  1  0.036  0.456  0.209  1.0
  P  P28  1  0.964  0.956  0.709  1.0
  P  P29  1  0.464  0.291  0.456  1.0
  P  P30  1  0.464  0.209  0.044  1.0
  P  P31  1  0.964  0.544  0.791  1.0
[/CIF]
.