The crystal structure described by W2C9NHO10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two W2C9NHO10 clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded to one C(2), one C(3), one C(5), one C(6), one N(1), and one H(1) atom to form corner-sharing WHC4N octahedra. The corner-sharing octahedral tilt angles are 53°. In the second W site, W(2) is bonded to one C(1), one C(4), one C(7), one C(8), one C(9), and one H(1) atom to form corner-sharing WHC5 octahedra. The corner-sharing octahedral tilt angles are 53°. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one W(2) and one O(3) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one W(1) and one O(1) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one W(1) and one O(7) atom. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one W(2) and one O(2,5) atom. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one W(1) and one O(6) atom. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one W(1) and one O(4) atom. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one W(2) and one O(2,5) atom. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one W(2) and one O(8,9) atom. In the ninth C site, C(9) is bonded in a distorted linear geometry to one W(2) and one O(8,9) atom. N(1) is bonded in a linear geometry to one W(1) and one O(10) atom. H(1) is bonded in a bent 120 degrees geometry to one W(1) and one W(2) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2,5) is bonded in a single-bond geometry to one C(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(5) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one C(3) atom. In the seventh O site, O(8,9) is bonded in a single-bond geometry to one C(9) atom. In the eighth O site, O(10) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_HW2C9NO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.164
_cell_length_b   9.864
_cell_length_c   12.744
_cell_angle_alpha   80.954
_cell_angle_beta   88.664
_cell_angle_gamma   69.992
_symmetry_Int_Tables_number   1
_cell_volume   835.246
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.257  0.191  0.298  1.0
  H  H1  1  0.743  0.809  0.702  1.0
  W  W2  1  0.070  0.390  0.272  1.0
  W  W3  1  0.930  0.610  0.728  1.0
  W  W4  1  0.248  0.027  0.235  1.0
  W  W5  1  0.752  0.973  0.765  1.0
  C  C6  1  0.496  0.046  0.155  1.0
  C  C7  1  0.504  0.954  0.845  1.0
  C  C8  1  0.189  0.418  0.121  1.0
  C  C9  1  0.811  0.582  0.879  1.0
  C  C10  1  0.966  0.337  0.422  1.0
  C  C11  1  0.034  0.663  0.578  1.0
  C  C12  1  0.090  0.119  0.092  1.0
  C  C13  1  0.910  0.881  0.908  1.0
  C  C14  1  0.315  0.415  0.343  1.0
  C  C15  1  0.685  0.585  0.657  1.0
  C  C16  1  0.822  0.365  0.203  1.0
  C  C17  1  0.178  0.635  0.797  1.0
  C  C18  1  0.420  0.920  0.373  1.0
  C  C19  1  0.580  0.080  0.627  1.0
  C  C20  1  0.993  0.023  0.312  1.0
  C  C21  1  0.007  0.977  0.688  1.0
  C  C22  1  0.305  0.827  0.194  1.0
  C  C23  1  0.695  0.173  0.806  1.0
  N  N24  1  0.933  0.592  0.263  1.0
  N  N25  1  0.067  0.408  0.737  1.0
  O  O26  1  0.251  0.434  0.037  1.0
  O  O27  1  0.749  0.566  0.963  1.0
  O  O28  1  0.515  0.856  0.449  1.0
  O  O29  1  0.485  0.144  0.551  1.0
  O  O30  1  0.633  0.057  0.108  1.0
  O  O31  1  0.367  0.943  0.892  1.0
  O  O32  1  0.678  0.359  0.169  1.0
  O  O33  1  0.322  0.641  0.831  1.0
  O  O34  1  0.008  0.168  0.010  1.0
  O  O35  1  0.992  0.832  0.990  1.0
  O  O36  1  0.444  0.436  0.383  1.0
  O  O37  1  0.556  0.564  0.617  1.0
  O  O38  1  0.907  0.309  0.505  1.0
  O  O39  1  0.093  0.691  0.495  1.0
  O  O40  1  0.343  0.710  0.172  1.0
  O  O41  1  0.657  0.290  0.828  1.0
  O  O42  1  0.847  0.025  0.356  1.0
  O  O43  1  0.153  0.975  0.644  1.0
  O  O44  1  0.850  0.719  0.257  1.0
  O  O45  1  0.150  0.281  0.743  1.0
[/CIF]
.
The crystal structure described by W2C9NHO10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two W2C9NHO10 clusters. There are two inequivalent W sites. In the first W site, W(1) is bonded to one C(2), one C(3), one C(5), one C(6), one N(1), and one H(1) atom to form corner-sharing WHC4N octahedra. The corner-sharing octahedral tilt angles are 53°. In the second W site, W(2) is bonded to one C(1), one C(4), one C(7), one C(8), one C(9), and one H(1) atom to form corner-sharing WHC5 octahedra. The corner-sharing octahedral tilt angles are 53°. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one W(2) and one O(3) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one W(1) and one O(1) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one W(1) and one O(7) atom. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one W(2) and one O(2,5) atom. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one W(1) and one O(6) atom. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one W(1) and one O(4) atom. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one W(2) and one O(2,5) atom. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one W(2) and one O(8,9) atom. In the ninth C site, C(9) is bonded in a distorted linear geometry to one W(2) and one O(8,9) atom. N(1) is bonded in a linear geometry to one W(1) and one O(10) atom. H(1) is bonded in a bent 120 degrees geometry to one W(1) and one W(2) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2,5) is bonded in a single-bond geometry to one C(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(5) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one C(3) atom. In the seventh O site, O(8,9) is bonded in a single-bond geometry to one C(9) atom. In the eighth O site, O(10) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_HW2C9NO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.164
_cell_length_b   9.864
_cell_length_c   12.744
_cell_angle_alpha   80.954
_cell_angle_beta   88.664
_cell_angle_gamma   69.992
_symmetry_Int_Tables_number   1
_cell_volume   835.246
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.257  0.191  0.298  1.0
  H  H1  1  0.743  0.809  0.702  1.0
  W  W2  1  0.070  0.390  0.272  1.0
  W  W3  1  0.930  0.610  0.728  1.0
  W  W4  1  0.248  0.027  0.235  1.0
  W  W5  1  0.752  0.973  0.765  1.0
  C  C6  1  0.496  0.046  0.155  1.0
  C  C7  1  0.504  0.954  0.845  1.0
  C  C8  1  0.189  0.418  0.121  1.0
  C  C9  1  0.811  0.582  0.879  1.0
  C  C10  1  0.966  0.337  0.422  1.0
  C  C11  1  0.034  0.663  0.578  1.0
  C  C12  1  0.090  0.119  0.092  1.0
  C  C13  1  0.910  0.881  0.908  1.0
  C  C14  1  0.315  0.415  0.343  1.0
  C  C15  1  0.685  0.585  0.657  1.0
  C  C16  1  0.822  0.365  0.203  1.0
  C  C17  1  0.178  0.635  0.797  1.0
  C  C18  1  0.420  0.920  0.373  1.0
  C  C19  1  0.580  0.080  0.627  1.0
  C  C20  1  0.993  0.023  0.312  1.0
  C  C21  1  0.007  0.977  0.688  1.0
  C  C22  1  0.305  0.827  0.194  1.0
  C  C23  1  0.695  0.173  0.806  1.0
  N  N24  1  0.933  0.592  0.263  1.0
  N  N25  1  0.067  0.408  0.737  1.0
  O  O26  1  0.251  0.434  0.037  1.0
  O  O27  1  0.749  0.566  0.963  1.0
  O  O28  1  0.515  0.856  0.449  1.0
  O  O29  1  0.485  0.144  0.551  1.0
  O  O30  1  0.633  0.057  0.108  1.0
  O  O31  1  0.367  0.943  0.892  1.0
  O  O32  1  0.678  0.359  0.169  1.0
  O  O33  1  0.322  0.641  0.831  1.0
  O  O34  1  0.008  0.168  0.010  1.0
  O  O35  1  0.992  0.832  0.990  1.0
  O  O36  1  0.444  0.436  0.383  1.0
  O  O37  1  0.556  0.564  0.617  1.0
  O  O38  1  0.907  0.309  0.505  1.0
  O  O39  1  0.093  0.691  0.495  1.0
  O  O40  1  0.343  0.710  0.172  1.0
  O  O41  1  0.657  0.290  0.828  1.0
  O  O42  1  0.847  0.025  0.356  1.0
  O  O43  1  0.153  0.975  0.644  1.0
  O  O44  1  0.850  0.719  0.257  1.0
  O  O45  1  0.150  0.281  0.743  1.0
[/CIF]
.