The material described by CuHS(NO)4 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CuHS(NO)4 clusters. Cu(1) is bonded in a see-saw-like geometry to two equivalent N(2), one H(1), and one O(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one Cu(1) and one N(1) atom. H(1) is bonded in a single-bond geometry to one Cu(1) atom. S(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(2) is bonded in a bent 150 degrees geometry to one Cu(1) and one S(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_CuHS(NO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.338
_cell_length_b   9.193
_cell_length_c   10.419
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   798.616
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.250  0.629  0.047  1.0
  Cu  Cu1  1  0.750  0.371  0.953  1.0
  Cu  Cu2  1  0.750  0.129  0.453  1.0
  Cu  Cu3  1  0.250  0.871  0.547  1.0
  H  H4  1  0.250  0.689  0.181  1.0
  H  H5  1  0.750  0.311  0.819  1.0
  H  H6  1  0.750  0.189  0.319  1.0
  H  H7  1  0.250  0.811  0.681  1.0
  S  S8  1  0.250  0.048  0.280  1.0
  S  S9  1  0.750  0.952  0.720  1.0
  S  S10  1  0.750  0.548  0.220  1.0
  S  S11  1  0.250  0.452  0.780  1.0
  N  N12  1  0.447  0.311  0.489  1.0
  N  N13  1  0.553  0.689  0.511  1.0
  N  N14  1  0.553  0.811  0.011  1.0
  N  N15  1  0.947  0.689  0.511  1.0
  N  N16  1  0.447  0.189  0.989  1.0
  N  N17  1  0.053  0.311  0.489  1.0
  N  N18  1  0.053  0.189  0.989  1.0
  N  N19  1  0.947  0.811  0.011  1.0
  N  N20  1  0.551  0.265  0.983  1.0
  N  N21  1  0.449  0.735  0.017  1.0
  N  N22  1  0.449  0.765  0.517  1.0
  N  N23  1  0.051  0.735  0.017  1.0
  N  N24  1  0.551  0.235  0.483  1.0
  N  N25  1  0.949  0.265  0.983  1.0
  N  N26  1  0.949  0.235  0.483  1.0
  N  N27  1  0.051  0.765  0.517  1.0
  O  O28  1  0.104  0.982  0.227  1.0
  O  O29  1  0.896  0.018  0.773  1.0
  O  O30  1  0.896  0.482  0.273  1.0
  O  O31  1  0.604  0.018  0.773  1.0
  O  O32  1  0.104  0.518  0.727  1.0
  O  O33  1  0.396  0.982  0.227  1.0
  O  O34  1  0.396  0.518  0.727  1.0
  O  O35  1  0.604  0.482  0.273  1.0
  O  O36  1  0.250  0.019  0.428  1.0
  O  O37  1  0.750  0.981  0.572  1.0
  O  O38  1  0.750  0.519  0.072  1.0
  O  O39  1  0.250  0.481  0.928  1.0
  O  O40  1  0.250  0.208  0.271  1.0
  O  O41  1  0.750  0.792  0.729  1.0
  O  O42  1  0.750  0.708  0.229  1.0
  O  O43  1  0.250  0.292  0.771  1.0
[/CIF]
.
The material described by CuHS(NO)4 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CuHS(NO)4 clusters. Cu(1) is bonded in a see-saw-like geometry to two equivalent N(2), one H(1), and one O(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one Cu(1) and one N(1) atom. H(1) is bonded in a single-bond geometry to one Cu(1) atom. S(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(2) is bonded in a bent 150 degrees geometry to one Cu(1) and one S(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_CuHS(NO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.338
_cell_length_b   9.193
_cell_length_c   10.419
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   798.616
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.250  0.629  0.047  1.0
  Cu  Cu1  1  0.750  0.371  0.953  1.0
  Cu  Cu2  1  0.750  0.129  0.453  1.0
  Cu  Cu3  1  0.250  0.871  0.547  1.0
  H  H4  1  0.250  0.689  0.181  1.0
  H  H5  1  0.750  0.311  0.819  1.0
  H  H6  1  0.750  0.189  0.319  1.0
  H  H7  1  0.250  0.811  0.681  1.0
  S  S8  1  0.250  0.048  0.280  1.0
  S  S9  1  0.750  0.952  0.720  1.0
  S  S10  1  0.750  0.548  0.220  1.0
  S  S11  1  0.250  0.452  0.780  1.0
  N  N12  1  0.447  0.311  0.489  1.0
  N  N13  1  0.553  0.689  0.511  1.0
  N  N14  1  0.553  0.811  0.011  1.0
  N  N15  1  0.947  0.689  0.511  1.0
  N  N16  1  0.447  0.189  0.989  1.0
  N  N17  1  0.053  0.311  0.489  1.0
  N  N18  1  0.053  0.189  0.989  1.0
  N  N19  1  0.947  0.811  0.011  1.0
  N  N20  1  0.551  0.265  0.983  1.0
  N  N21  1  0.449  0.735  0.017  1.0
  N  N22  1  0.449  0.765  0.517  1.0
  N  N23  1  0.051  0.735  0.017  1.0
  N  N24  1  0.551  0.235  0.483  1.0
  N  N25  1  0.949  0.265  0.983  1.0
  N  N26  1  0.949  0.235  0.483  1.0
  N  N27  1  0.051  0.765  0.517  1.0
  O  O28  1  0.104  0.982  0.227  1.0
  O  O29  1  0.896  0.018  0.773  1.0
  O  O30  1  0.896  0.482  0.273  1.0
  O  O31  1  0.604  0.018  0.773  1.0
  O  O32  1  0.104  0.518  0.727  1.0
  O  O33  1  0.396  0.982  0.227  1.0
  O  O34  1  0.396  0.518  0.727  1.0
  O  O35  1  0.604  0.482  0.273  1.0
  O  O36  1  0.250  0.019  0.428  1.0
  O  O37  1  0.750  0.981  0.572  1.0
  O  O38  1  0.750  0.519  0.072  1.0
  O  O39  1  0.250  0.481  0.928  1.0
  O  O40  1  0.250  0.208  0.271  1.0
  O  O41  1  0.750  0.792  0.729  1.0
  O  O42  1  0.750  0.708  0.229  1.0
  O  O43  1  0.250  0.292  0.771  1.0
[/CIF]
.