The material structure described by LiMn2P4H11O18 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 2-coordinate geometry to one O(18) and one O(5) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(15), one O(17), one O(2), one O(3), one O(6), and one O(9) atom. In the second Mn site, Mn(2) is bonded in a 8-coordinate geometry to one O(10), one O(14), one O(16), one O(17), one O(2), one O(4), one O(7), and one O(9) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(18), one O(3), one O(5), and one O(8) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one O(14), one O(2), one O(7), and one O(9) atom. In the third P site, P(3) is bonded in a tetrahedral geometry to one O(10), one O(12), one O(17), and one O(6) atom. In the fourth P site, P(4) is bonded in a tetrahedral geometry to one O(1), one O(11), one O(13), and one O(16) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(18) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. In the fourth H site, H(4) is bonded in a linear geometry to one O(11) and one O(8) atom. In the fifth H site, H(5) is bonded in a linear geometry to one O(12) and one O(3) atom. In the sixth H site, H(6) is bonded in a distorted linear geometry to one O(15) and one O(6) atom. In the seventh H site, H(7) is bonded in a distorted linear geometry to one O(14) and one O(4) atom. In the eighth H site, H(8) is bonded in a distorted linear geometry to one O(16) and one O(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(15) atom. In the tenth H site, H(10) is bonded in a linear geometry to one O(13) and one O(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(15) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one P(4) and one H(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(2), and one P(2) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one P(1), and one H(5) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Mn(2), one H(2), one H(3), and one H(7) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one P(1), and one H(10) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mn(1), one P(3), and one H(6) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mn(2), one P(2), and one H(8) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one P(1) and one H(4) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(2), and one P(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(2), and one P(3) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one P(4) and one H(4) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Mn(1), one P(3), and one H(5) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one P(4) and one H(10) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Mn(2), one P(2), and one H(7) atom. In the fifteenth O site, O(15) is bonded in a distorted water-like geometry to one Mn(1), one H(11), one H(6), and one H(9) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one P(4), and one H(8) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(2), and one P(3) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Li(1), one P(1), and one H(1) atom. is represented by the CIF file [CIF]
data_LiMn2P4H11O18
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.440
_cell_length_b   6.172
_cell_length_c   11.976
_cell_angle_alpha   75.086
_cell_angle_beta   83.615
_cell_angle_gamma   66.382
_symmetry_Int_Tables_number   1
_cell_volume   356.049
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.470  0.989  0.539  1.0
  Mn  Mn1  1  0.006  0.296  0.906  1.0
  Mn  Mn2  1  0.993  0.703  0.101  1.0
  P  P3  1  0.141  0.634  0.638  1.0
  P  P4  1  0.499  0.210  0.096  1.0
  P  P5  1  0.496  0.787  0.911  1.0
  P  P6  1  0.837  0.385  0.369  1.0
  H  H7  1  0.987  0.503  0.499  1.0
  H  H8  1  0.007  0.929  0.295  1.0
  H  H9  1  0.253  0.680  0.305  1.0
  H  H10  1  0.472  0.491  0.514  1.0
  H  H11  1  0.361  0.581  0.817  1.0
  H  H12  1  0.634  0.078  0.805  1.0
  H  H13  1  0.367  0.923  0.207  1.0
  H  H14  1  0.635  0.419  0.186  1.0
  H  H15  1  0.749  0.319  0.699  1.0
  H  H16  1  0.979  0.017  0.485  1.0
  H  H17  1  0.983  0.063  0.707  1.0
  O  O18  1  0.066  0.388  0.437  1.0
  O  O19  1  0.240  0.317  0.030  1.0
  O  O20  1  0.125  0.561  0.771  1.0
  O  O21  1  0.133  0.820  0.248  1.0
  O  O22  1  0.169  0.885  0.596  1.0
  O  O23  1  0.467  0.038  0.824  1.0
  O  O24  1  0.463  0.406  0.168  1.0
  O  O25  1  0.407  0.433  0.600  1.0
  O  O26  1  0.765  0.146  0.031  1.0
  O  O27  1  0.228  0.853  0.974  1.0
  O  O28  1  0.561  0.557  0.400  1.0
  O  O29  1  0.534  0.595  0.838  1.0
  O  O30  1  0.854  0.107  0.414  1.0
  O  O31  1  0.534  0.961  0.187  1.0
  O  O32  1  0.863  0.174  0.755  1.0
  O  O33  1  0.890  0.426  0.238  1.0
  O  O34  1  0.753  0.676  0.981  1.0
  O  O35  1  0.896  0.647  0.578  1.0
[/CIF]
.
The material structure described by LiMn2P4H11O18 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 2-coordinate geometry to one O(18) and one O(5) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(15), one O(17), one O(2), one O(3), one O(6), and one O(9) atom. In the second Mn site, Mn(2) is bonded in a 8-coordinate geometry to one O(10), one O(14), one O(16), one O(17), one O(2), one O(4), one O(7), and one O(9) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(18), one O(3), one O(5), and one O(8) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one O(14), one O(2), one O(7), and one O(9) atom. In the third P site, P(3) is bonded in a tetrahedral geometry to one O(10), one O(12), one O(17), and one O(6) atom. In the fourth P site, P(4) is bonded in a tetrahedral geometry to one O(1), one O(11), one O(13), and one O(16) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(1) and one O(18) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. In the fourth H site, H(4) is bonded in a linear geometry to one O(11) and one O(8) atom. In the fifth H site, H(5) is bonded in a linear geometry to one O(12) and one O(3) atom. In the sixth H site, H(6) is bonded in a distorted linear geometry to one O(15) and one O(6) atom. In the seventh H site, H(7) is bonded in a distorted linear geometry to one O(14) and one O(4) atom. In the eighth H site, H(8) is bonded in a distorted linear geometry to one O(16) and one O(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(15) atom. In the tenth H site, H(10) is bonded in a linear geometry to one O(13) and one O(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one O(15) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one P(4) and one H(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(2), and one P(2) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one P(1), and one H(5) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Mn(2), one H(2), one H(3), and one H(7) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one P(1), and one H(10) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mn(1), one P(3), and one H(6) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mn(2), one P(2), and one H(8) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one P(1) and one H(4) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(2), and one P(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(2), and one P(3) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one P(4) and one H(4) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Mn(1), one P(3), and one H(5) atom. In the thirteenth O site, O(13) is bonded in a distorted water-like geometry to one P(4) and one H(10) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Mn(2), one P(2), and one H(7) atom. In the fifteenth O site, O(15) is bonded in a distorted water-like geometry to one Mn(1), one H(11), one H(6), and one H(9) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one P(4), and one H(8) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(2), and one P(3) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Li(1), one P(1), and one H(1) atom. is represented by the CIF file [CIF]
data_LiMn2P4H11O18
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.440
_cell_length_b   6.172
_cell_length_c   11.976
_cell_angle_alpha   75.086
_cell_angle_beta   83.615
_cell_angle_gamma   66.382
_symmetry_Int_Tables_number   1
_cell_volume   356.049
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.470  0.989  0.539  1.0
  Mn  Mn1  1  0.006  0.296  0.906  1.0
  Mn  Mn2  1  0.993  0.703  0.101  1.0
  P  P3  1  0.141  0.634  0.638  1.0
  P  P4  1  0.499  0.210  0.096  1.0
  P  P5  1  0.496  0.787  0.911  1.0
  P  P6  1  0.837  0.385  0.369  1.0
  H  H7  1  0.987  0.503  0.499  1.0
  H  H8  1  0.007  0.929  0.295  1.0
  H  H9  1  0.253  0.680  0.305  1.0
  H  H10  1  0.472  0.491  0.514  1.0
  H  H11  1  0.361  0.581  0.817  1.0
  H  H12  1  0.634  0.078  0.805  1.0
  H  H13  1  0.367  0.923  0.207  1.0
  H  H14  1  0.635  0.419  0.186  1.0
  H  H15  1  0.749  0.319  0.699  1.0
  H  H16  1  0.979  0.017  0.485  1.0
  H  H17  1  0.983  0.063  0.707  1.0
  O  O18  1  0.066  0.388  0.437  1.0
  O  O19  1  0.240  0.317  0.030  1.0
  O  O20  1  0.125  0.561  0.771  1.0
  O  O21  1  0.133  0.820  0.248  1.0
  O  O22  1  0.169  0.885  0.596  1.0
  O  O23  1  0.467  0.038  0.824  1.0
  O  O24  1  0.463  0.406  0.168  1.0
  O  O25  1  0.407  0.433  0.600  1.0
  O  O26  1  0.765  0.146  0.031  1.0
  O  O27  1  0.228  0.853  0.974  1.0
  O  O28  1  0.561  0.557  0.400  1.0
  O  O29  1  0.534  0.595  0.838  1.0
  O  O30  1  0.854  0.107  0.414  1.0
  O  O31  1  0.534  0.961  0.187  1.0
  O  O32  1  0.863  0.174  0.755  1.0
  O  O33  1  0.890  0.426  0.238  1.0
  O  O34  1  0.753  0.676  0.981  1.0
  O  O35  1  0.896  0.647  0.578  1.0
[/CIF]
.