The material structure described by W3ZnO7 is Hydrophilite-derived structured and crystallizes in the orthorhombic Pnma space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form a mixture of distorted edge and corner-sharing WO6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 27-28°. In the second W site, W(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form a mixture of edge and corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 24°. Zn(1) is bonded in a trigonal planar geometry to one O(3) and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted T-shaped geometry to two equivalent W(2) and one Zn(1) atom. In the second O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Zn(1) atom. In the third O site, O(1) is bonded in a distorted T-shaped geometry to one W(2) and two equivalent W(1) atoms. In the fourth O site, O(2) is bonded in a distorted T-shaped geometry to one W(2) and two equivalent W(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnW3O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.564
_cell_length_b   7.896
_cell_length_c   11.434
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   592.590
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.886  0.507  0.750  1.0
  Zn  Zn1  1  0.386  0.993  0.250  1.0
  Zn  Zn2  1  0.114  0.493  0.250  1.0
  Zn  Zn3  1  0.614  0.007  0.750  1.0
  W  W4  1  0.245  0.737  0.031  1.0
  W  W5  1  0.745  0.763  0.969  1.0
  W  W6  1  0.755  0.263  0.531  1.0
  W  W7  1  0.255  0.237  0.469  1.0
  W  W8  1  0.247  0.762  0.750  1.0
  W  W9  1  0.747  0.738  0.250  1.0
  W  W10  1  0.753  0.238  0.250  1.0
  W  W11  1  0.253  0.262  0.750  1.0
  W  W12  1  0.745  0.763  0.531  1.0
  W  W13  1  0.245  0.737  0.469  1.0
  W  W14  1  0.255  0.237  0.031  1.0
  W  W15  1  0.755  0.263  0.969  1.0
  O  O16  1  0.553  0.252  0.109  1.0
  O  O17  1  0.053  0.248  0.891  1.0
  O  O18  1  0.447  0.748  0.609  1.0
  O  O19  1  0.947  0.752  0.391  1.0
  O  O20  1  0.447  0.748  0.891  1.0
  O  O21  1  0.947  0.752  0.109  1.0
  O  O22  1  0.553  0.252  0.391  1.0
  O  O23  1  0.053  0.248  0.609  1.0
  O  O24  1  0.954  0.228  0.107  1.0
  O  O25  1  0.454  0.272  0.893  1.0
  O  O26  1  0.046  0.772  0.607  1.0
  O  O27  1  0.546  0.728  0.393  1.0
  O  O28  1  0.046  0.772  0.893  1.0
  O  O29  1  0.546  0.728  0.107  1.0
  O  O30  1  0.954  0.228  0.393  1.0
  O  O31  1  0.454  0.272  0.607  1.0
  O  O32  1  0.314  0.011  0.750  1.0
  O  O33  1  0.814  0.489  0.250  1.0
  O  O34  1  0.686  0.989  0.250  1.0
  O  O35  1  0.186  0.511  0.750  1.0
  O  O36  1  0.230  0.491  0.408  1.0
  O  O37  1  0.730  0.009  0.592  1.0
  O  O38  1  0.770  0.509  0.908  1.0
  O  O39  1  0.270  0.991  0.092  1.0
  O  O40  1  0.770  0.509  0.592  1.0
  O  O41  1  0.270  0.991  0.408  1.0
  O  O42  1  0.230  0.491  0.092  1.0
  O  O43  1  0.730  0.009  0.908  1.0
[/CIF]
.
The material structure described by W3ZnO7 is Hydrophilite-derived structured and crystallizes in the orthorhombic Pnma space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form a mixture of distorted edge and corner-sharing WO6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 27-28°. In the second W site, W(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form a mixture of edge and corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 24°. Zn(1) is bonded in a trigonal planar geometry to one O(3) and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted T-shaped geometry to two equivalent W(2) and one Zn(1) atom. In the second O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Zn(1) atom. In the third O site, O(1) is bonded in a distorted T-shaped geometry to one W(2) and two equivalent W(1) atoms. In the fourth O site, O(2) is bonded in a distorted T-shaped geometry to one W(2) and two equivalent W(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnW3O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.564
_cell_length_b   7.896
_cell_length_c   11.434
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   592.590
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.886  0.507  0.750  1.0
  Zn  Zn1  1  0.386  0.993  0.250  1.0
  Zn  Zn2  1  0.114  0.493  0.250  1.0
  Zn  Zn3  1  0.614  0.007  0.750  1.0
  W  W4  1  0.245  0.737  0.031  1.0
  W  W5  1  0.745  0.763  0.969  1.0
  W  W6  1  0.755  0.263  0.531  1.0
  W  W7  1  0.255  0.237  0.469  1.0
  W  W8  1  0.247  0.762  0.750  1.0
  W  W9  1  0.747  0.738  0.250  1.0
  W  W10  1  0.753  0.238  0.250  1.0
  W  W11  1  0.253  0.262  0.750  1.0
  W  W12  1  0.745  0.763  0.531  1.0
  W  W13  1  0.245  0.737  0.469  1.0
  W  W14  1  0.255  0.237  0.031  1.0
  W  W15  1  0.755  0.263  0.969  1.0
  O  O16  1  0.553  0.252  0.109  1.0
  O  O17  1  0.053  0.248  0.891  1.0
  O  O18  1  0.447  0.748  0.609  1.0
  O  O19  1  0.947  0.752  0.391  1.0
  O  O20  1  0.447  0.748  0.891  1.0
  O  O21  1  0.947  0.752  0.109  1.0
  O  O22  1  0.553  0.252  0.391  1.0
  O  O23  1  0.053  0.248  0.609  1.0
  O  O24  1  0.954  0.228  0.107  1.0
  O  O25  1  0.454  0.272  0.893  1.0
  O  O26  1  0.046  0.772  0.607  1.0
  O  O27  1  0.546  0.728  0.393  1.0
  O  O28  1  0.046  0.772  0.893  1.0
  O  O29  1  0.546  0.728  0.107  1.0
  O  O30  1  0.954  0.228  0.393  1.0
  O  O31  1  0.454  0.272  0.607  1.0
  O  O32  1  0.314  0.011  0.750  1.0
  O  O33  1  0.814  0.489  0.250  1.0
  O  O34  1  0.686  0.989  0.250  1.0
  O  O35  1  0.186  0.511  0.750  1.0
  O  O36  1  0.230  0.491  0.408  1.0
  O  O37  1  0.730  0.009  0.592  1.0
  O  O38  1  0.770  0.509  0.908  1.0
  O  O39  1  0.270  0.991  0.092  1.0
  O  O40  1  0.770  0.509  0.592  1.0
  O  O41  1  0.270  0.991  0.408  1.0
  O  O42  1  0.230  0.491  0.092  1.0
  O  O43  1  0.730  0.009  0.908  1.0
[/CIF]
.