The compound described by Ga(PbN)3 crystallizes in the hexagonal P6_3/m space group. Ga(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. Pb(1) is bonded in a 3-coordinate geometry to three equivalent N(1) atoms. N(1) is bonded to one Ga(1) and three equivalent Pb(1) atoms to form a mixture of distorted corner and edge-sharing NGaPb3 tetrahedra. is represented by the CIF file [CIF]
data_Ga(PbN)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.464
_cell_length_b   10.467
_cell_length_c   3.637
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.991
_symmetry_Int_Tables_number   1
_cell_volume   344.971
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.667  0.333  0.750  1.0
  Ga  Ga1  1  0.333  0.667  0.250  1.0
  Pb  Pb2  1  0.975  0.632  0.250  1.0
  Pb  Pb3  1  0.658  0.025  0.250  1.0
  Pb  Pb4  1  0.368  0.342  0.250  1.0
  Pb  Pb5  1  0.025  0.368  0.750  1.0
  Pb  Pb6  1  0.342  0.975  0.750  1.0
  Pb  Pb7  1  0.632  0.658  0.750  1.0
  N  N8  1  0.870  0.468  0.750  1.0
  N  N9  1  0.599  0.130  0.750  1.0
  N  N10  1  0.532  0.401  0.750  1.0
  N  N11  1  0.130  0.532  0.250  1.0
  N  N12  1  0.401  0.870  0.250  1.0
  N  N13  1  0.468  0.599  0.250  1.0
[/CIF]
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The compound described by Ga(PbN)3 crystallizes in the hexagonal P6_3/m space group. Ga(1) is bonded in a trigonal planar geometry to three equivalent N(1) atoms. Pb(1) is bonded in a 3-coordinate geometry to three equivalent N(1) atoms. N(1) is bonded to one Ga(1) and three equivalent Pb(1) atoms to form a mixture of distorted corner and edge-sharing NGaPb3 tetrahedra. is represented by the CIF file [CIF]
data_Ga(PbN)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.464
_cell_length_b   10.467
_cell_length_c   3.637
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.991
_symmetry_Int_Tables_number   1
_cell_volume   344.971
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.667  0.333  0.750  1.0
  Ga  Ga1  1  0.333  0.667  0.250  1.0
  Pb  Pb2  1  0.975  0.632  0.250  1.0
  Pb  Pb3  1  0.658  0.025  0.250  1.0
  Pb  Pb4  1  0.368  0.342  0.250  1.0
  Pb  Pb5  1  0.025  0.368  0.750  1.0
  Pb  Pb6  1  0.342  0.975  0.750  1.0
  Pb  Pb7  1  0.632  0.658  0.750  1.0
  N  N8  1  0.870  0.468  0.750  1.0
  N  N9  1  0.599  0.130  0.750  1.0
  N  N10  1  0.532  0.401  0.750  1.0
  N  N11  1  0.130  0.532  0.250  1.0
  N  N12  1  0.401  0.870  0.250  1.0
  N  N13  1  0.468  0.599  0.250  1.0
[/CIF]
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