The compound described by FVO2 crystallizes in the orthorhombic P2_12_12_1 space group. V(1) is bonded to two equivalent O(1), two equivalent O(2), and one F(1) atom to form distorted corner-sharing VO4F trigonal bipyramids. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to two equivalent V(1) atoms. F(1) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_VO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.063
_cell_length_b   5.113
_cell_length_c   8.425
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   218.146
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.130  0.622  0.131  1.0
  V  V1  1  0.370  0.378  0.631  1.0
  V  V2  1  0.630  0.878  0.869  1.0
  V  V3  1  0.870  0.122  0.369  1.0
  O  O4  1  0.080  0.897  0.255  1.0
  O  O5  1  0.957  0.660  0.965  1.0
  O  O6  1  0.543  0.340  0.465  1.0
  O  O7  1  0.420  0.103  0.755  1.0
  O  O8  1  0.580  0.603  0.745  1.0
  O  O9  1  0.457  0.840  0.035  1.0
  O  O10  1  0.043  0.160  0.535  1.0
  O  O11  1  0.920  0.397  0.245  1.0
  F  F12  1  0.121  0.625  0.615  1.0
  F  F13  1  0.379  0.375  0.115  1.0
  F  F14  1  0.621  0.875  0.385  1.0
  F  F15  1  0.879  0.125  0.885  1.0
[/CIF]
.
The compound described by FVO2 crystallizes in the orthorhombic P2_12_12_1 space group. V(1) is bonded to two equivalent O(1), two equivalent O(2), and one F(1) atom to form distorted corner-sharing VO4F trigonal bipyramids. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to two equivalent V(1) atoms. F(1) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_VO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.063
_cell_length_b   5.113
_cell_length_c   8.425
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   218.146
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.130  0.622  0.131  1.0
  V  V1  1  0.370  0.378  0.631  1.0
  V  V2  1  0.630  0.878  0.869  1.0
  V  V3  1  0.870  0.122  0.369  1.0
  O  O4  1  0.080  0.897  0.255  1.0
  O  O5  1  0.957  0.660  0.965  1.0
  O  O6  1  0.543  0.340  0.465  1.0
  O  O7  1  0.420  0.103  0.755  1.0
  O  O8  1  0.580  0.603  0.745  1.0
  O  O9  1  0.457  0.840  0.035  1.0
  O  O10  1  0.043  0.160  0.535  1.0
  O  O11  1  0.920  0.397  0.245  1.0
  F  F12  1  0.121  0.625  0.615  1.0
  F  F13  1  0.379  0.375  0.115  1.0
  F  F14  1  0.621  0.875  0.385  1.0
  F  F15  1  0.879  0.125  0.885  1.0
[/CIF]
.