The structure described by Cd2H3O3Cl crystallizes in the orthorhombic Pnma space group. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one O(1), four equivalent O(2), and one Cl(1) atom to form distorted CdClO5 octahedra that share edges with two equivalent Cd(1)ClO5 octahedra and edges with four equivalent Cd(2)Cl2O4 octahedra. In the second Cd site, Cd(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent Cl(1) atoms to form distorted CdCl2O4 octahedra that share edges with two equivalent Cd(2)Cl2O4 octahedra and edges with four equivalent Cd(1)ClO5 octahedra. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1), two equivalent Cd(2), and one H(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(2), two equivalent Cd(1), and one H(1) atom. Cl(1) is bonded in a 3-coordinate geometry to one Cd(1) and two equivalent Cd(2) atoms. is represented by the CIF card [CIF]
data_Cd2H3ClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.925
_cell_length_b   7.600
_cell_length_c   10.042
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   528.505
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.309  0.750  0.762  1.0
  Cd  Cd1  1  0.809  0.750  0.738  1.0
  Cd  Cd2  1  0.691  0.250  0.238  1.0
  Cd  Cd3  1  0.191  0.250  0.262  1.0
  Cd  Cd4  1  0.500  0.000  0.500  1.0
  Cd  Cd5  1  0.000  0.500  0.000  1.0
  Cd  Cd6  1  0.500  0.500  0.500  1.0
  Cd  Cd7  1  0.000  0.000  0.000  1.0
  H  H8  1  0.927  0.954  0.280  1.0
  H  H9  1  0.427  0.546  0.220  1.0
  H  H10  1  0.073  0.454  0.720  1.0
  H  H11  1  0.573  0.046  0.780  1.0
  H  H12  1  0.073  0.046  0.720  1.0
  H  H13  1  0.573  0.454  0.780  1.0
  H  H14  1  0.927  0.546  0.280  1.0
  H  H15  1  0.427  0.954  0.220  1.0
  H  H16  1  0.192  0.750  0.487  1.0
  H  H17  1  0.692  0.750  0.013  1.0
  H  H18  1  0.808  0.250  0.513  1.0
  H  H19  1  0.308  0.250  0.987  1.0
  Cl  Cl20  1  0.190  0.250  0.539  1.0
  Cl  Cl21  1  0.690  0.250  0.961  1.0
  Cl  Cl22  1  0.810  0.750  0.461  1.0
  Cl  Cl23  1  0.310  0.750  0.039  1.0
  O  O24  1  0.179  0.250  0.027  1.0
  O  O25  1  0.679  0.250  0.473  1.0
  O  O26  1  0.821  0.750  0.973  1.0
  O  O27  1  0.321  0.750  0.527  1.0
  O  O28  1  0.443  0.054  0.280  1.0
  O  O29  1  0.943  0.446  0.220  1.0
  O  O30  1  0.557  0.554  0.720  1.0
  O  O31  1  0.057  0.946  0.780  1.0
  O  O32  1  0.557  0.946  0.720  1.0
  O  O33  1  0.057  0.554  0.780  1.0
  O  O34  1  0.443  0.446  0.280  1.0
  O  O35  1  0.943  0.054  0.220  1.0
[/CIF]
.
The structure described by Cd2H3O3Cl crystallizes in the orthorhombic Pnma space group. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one O(1), four equivalent O(2), and one Cl(1) atom to form distorted CdClO5 octahedra that share edges with two equivalent Cd(1)ClO5 octahedra and edges with four equivalent Cd(2)Cl2O4 octahedra. In the second Cd site, Cd(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent Cl(1) atoms to form distorted CdCl2O4 octahedra that share edges with two equivalent Cd(2)Cl2O4 octahedra and edges with four equivalent Cd(1)ClO5 octahedra. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1), two equivalent Cd(2), and one H(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(2), two equivalent Cd(1), and one H(1) atom. Cl(1) is bonded in a 3-coordinate geometry to one Cd(1) and two equivalent Cd(2) atoms. is represented by the CIF card [CIF]
data_Cd2H3ClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.925
_cell_length_b   7.600
_cell_length_c   10.042
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   528.505
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.309  0.750  0.762  1.0
  Cd  Cd1  1  0.809  0.750  0.738  1.0
  Cd  Cd2  1  0.691  0.250  0.238  1.0
  Cd  Cd3  1  0.191  0.250  0.262  1.0
  Cd  Cd4  1  0.500  0.000  0.500  1.0
  Cd  Cd5  1  0.000  0.500  0.000  1.0
  Cd  Cd6  1  0.500  0.500  0.500  1.0
  Cd  Cd7  1  0.000  0.000  0.000  1.0
  H  H8  1  0.927  0.954  0.280  1.0
  H  H9  1  0.427  0.546  0.220  1.0
  H  H10  1  0.073  0.454  0.720  1.0
  H  H11  1  0.573  0.046  0.780  1.0
  H  H12  1  0.073  0.046  0.720  1.0
  H  H13  1  0.573  0.454  0.780  1.0
  H  H14  1  0.927  0.546  0.280  1.0
  H  H15  1  0.427  0.954  0.220  1.0
  H  H16  1  0.192  0.750  0.487  1.0
  H  H17  1  0.692  0.750  0.013  1.0
  H  H18  1  0.808  0.250  0.513  1.0
  H  H19  1  0.308  0.250  0.987  1.0
  Cl  Cl20  1  0.190  0.250  0.539  1.0
  Cl  Cl21  1  0.690  0.250  0.961  1.0
  Cl  Cl22  1  0.810  0.750  0.461  1.0
  Cl  Cl23  1  0.310  0.750  0.039  1.0
  O  O24  1  0.179  0.250  0.027  1.0
  O  O25  1  0.679  0.250  0.473  1.0
  O  O26  1  0.821  0.750  0.973  1.0
  O  O27  1  0.321  0.750  0.527  1.0
  O  O28  1  0.443  0.054  0.280  1.0
  O  O29  1  0.943  0.446  0.220  1.0
  O  O30  1  0.557  0.554  0.720  1.0
  O  O31  1  0.057  0.946  0.780  1.0
  O  O32  1  0.557  0.946  0.720  1.0
  O  O33  1  0.057  0.554  0.780  1.0
  O  O34  1  0.443  0.446  0.280  1.0
  O  O35  1  0.943  0.054  0.220  1.0
[/CIF]
.