The material structure described by (DyP2H5O9)2O2 crystallizes in the triclinic P1 space group. The structure consists of one hydrogen peroxide molecule inside a DyP2H5O9 framework. In the DyP2H5O9 framework, there are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(13), one O(17), one O(5), one O(6), one O(7), and one O(9) atom. In the second Dy site, Dy(2) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(14), one O(18), one O(5), one O(6), one O(8), and one O(9) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(13), one O(5), and one O(9) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(10), one O(14), one O(2), and one O(6) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(1), one O(11), one O(15), and one O(3) atom to form corner-sharing PO4 tetrahedra. In the fourth P site, P(4) is bonded to one O(12), one O(16), one O(2), and one O(4) atom to form corner-sharing PO4 tetrahedra. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(8) atom. In the fifth H site, H(5) is bonded in a linear geometry to one O(16) and one O(3) atom. In the sixth H site, H(6) is bonded in a linear geometry to one O(15) and one O(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(17) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(18) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(17) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(18) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(2) and one P(4) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(3) and one H(5) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(4) and one H(6) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Dy(1), one Dy(2), and one P(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Dy(1), one Dy(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Dy(1), one H(1), and one H(3) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Dy(2), one H(2), and one H(4) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Dy(1), one Dy(2), and one P(1) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Dy(1), one Dy(2), and one P(2) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one P(3) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Dy(2) and one P(4) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Dy(1) and one P(1) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Dy(2) and one P(2) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one P(3) and one H(6) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one P(4) and one H(5) atom. In the seventeenth O site, O(17) is bonded in a distorted water-like geometry to one Dy(1), one H(7), and one H(9) atom. In the eighteenth O site, O(18) is bonded in a distorted water-like geometry to one Dy(2), one H(10), and one H(8) atom. is represented by the CIF card [CIF]
data_DyP2(HO2)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.453
_cell_length_b   6.952
_cell_length_c   10.002
_cell_angle_alpha   98.497
_cell_angle_beta   98.659
_cell_angle_gamma   88.803
_symmetry_Int_Tables_number   1
_cell_volume   438.679
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.369  0.261  0.541  1.0
  Dy  Dy1  1  0.630  0.740  0.459  1.0
  P  P2  1  0.805  0.233  0.435  1.0
  P  P3  1  0.195  0.768  0.565  1.0
  P  P4  1  0.057  0.139  0.210  1.0
  P  P5  1  0.942  0.861  0.790  1.0
  H  H6  1  0.720  0.485  0.736  1.0
  H  H7  1  0.275  0.515  0.265  1.0
  H  H8  1  0.767  0.266  0.764  1.0
  H  H9  1  0.232  0.734  0.236  1.0
  H  H10  1  0.976  0.176  0.988  1.0
  H  H11  1  0.022  0.824  0.012  1.0
  H  H12  1  0.151  0.204  0.788  1.0
  H  H13  1  0.849  0.794  0.213  1.0
  H  H14  1  0.383  0.284  0.843  1.0
  H  H15  1  0.625  0.694  0.157  1.0
  O  O16  1  0.844  0.180  0.277  1.0
  O  O17  1  0.155  0.821  0.723  1.0
  O  O18  1  0.020  0.251  0.084  1.0
  O  O19  1  0.981  0.748  0.916  1.0
  O  O20  1  0.660  0.412  0.441  1.0
  O  O21  1  0.338  0.589  0.560  1.0
  O  O22  1  0.657  0.357  0.733  1.0
  O  O23  1  0.341  0.642  0.268  1.0
  O  O24  1  0.666  0.070  0.464  1.0
  O  O25  1  0.334  0.931  0.537  1.0
  O  O26  1  0.242  0.230  0.309  1.0
  O  O27  1  0.757  0.768  0.692  1.0
  O  O28  1  0.013  0.258  0.526  1.0
  O  O29  1  0.986  0.744  0.474  1.0
  O  O30  1  0.065  0.919  0.165  1.0
  O  O31  1  0.932  0.081  0.834  1.0
  O  O32  1  0.272  0.270  0.765  1.0
  O  O33  1  0.729  0.727  0.238  1.0
  O  O34  1  0.503  0.987  0.975  1.0
  O  O35  1  0.495  0.809  0.970  1.0
[/CIF]
.
The material structure described by (DyP2H5O9)2O2 crystallizes in the triclinic P1 space group. The structure consists of one hydrogen peroxide molecule inside a DyP2H5O9 framework. In the DyP2H5O9 framework, there are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(13), one O(17), one O(5), one O(6), one O(7), and one O(9) atom. In the second Dy site, Dy(2) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(14), one O(18), one O(5), one O(6), one O(8), and one O(9) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(13), one O(5), and one O(9) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(10), one O(14), one O(2), and one O(6) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(1), one O(11), one O(15), and one O(3) atom to form corner-sharing PO4 tetrahedra. In the fourth P site, P(4) is bonded to one O(12), one O(16), one O(2), and one O(4) atom to form corner-sharing PO4 tetrahedra. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(8) atom. In the fifth H site, H(5) is bonded in a linear geometry to one O(16) and one O(3) atom. In the sixth H site, H(6) is bonded in a linear geometry to one O(15) and one O(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(17) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(18) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(17) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(18) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(2) and one P(4) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(3) and one H(5) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(4) and one H(6) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Dy(1), one Dy(2), and one P(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Dy(1), one Dy(2), and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Dy(1), one H(1), and one H(3) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Dy(2), one H(2), and one H(4) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Dy(1), one Dy(2), and one P(1) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Dy(1), one Dy(2), and one P(2) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one P(3) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Dy(2) and one P(4) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Dy(1) and one P(1) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Dy(2) and one P(2) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one P(3) and one H(6) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one P(4) and one H(5) atom. In the seventeenth O site, O(17) is bonded in a distorted water-like geometry to one Dy(1), one H(7), and one H(9) atom. In the eighteenth O site, O(18) is bonded in a distorted water-like geometry to one Dy(2), one H(10), and one H(8) atom. is represented by the CIF card [CIF]
data_DyP2(HO2)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.453
_cell_length_b   6.952
_cell_length_c   10.002
_cell_angle_alpha   98.497
_cell_angle_beta   98.659
_cell_angle_gamma   88.803
_symmetry_Int_Tables_number   1
_cell_volume   438.679
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.369  0.261  0.541  1.0
  Dy  Dy1  1  0.630  0.740  0.459  1.0
  P  P2  1  0.805  0.233  0.435  1.0
  P  P3  1  0.195  0.768  0.565  1.0
  P  P4  1  0.057  0.139  0.210  1.0
  P  P5  1  0.942  0.861  0.790  1.0
  H  H6  1  0.720  0.485  0.736  1.0
  H  H7  1  0.275  0.515  0.265  1.0
  H  H8  1  0.767  0.266  0.764  1.0
  H  H9  1  0.232  0.734  0.236  1.0
  H  H10  1  0.976  0.176  0.988  1.0
  H  H11  1  0.022  0.824  0.012  1.0
  H  H12  1  0.151  0.204  0.788  1.0
  H  H13  1  0.849  0.794  0.213  1.0
  H  H14  1  0.383  0.284  0.843  1.0
  H  H15  1  0.625  0.694  0.157  1.0
  O  O16  1  0.844  0.180  0.277  1.0
  O  O17  1  0.155  0.821  0.723  1.0
  O  O18  1  0.020  0.251  0.084  1.0
  O  O19  1  0.981  0.748  0.916  1.0
  O  O20  1  0.660  0.412  0.441  1.0
  O  O21  1  0.338  0.589  0.560  1.0
  O  O22  1  0.657  0.357  0.733  1.0
  O  O23  1  0.341  0.642  0.268  1.0
  O  O24  1  0.666  0.070  0.464  1.0
  O  O25  1  0.334  0.931  0.537  1.0
  O  O26  1  0.242  0.230  0.309  1.0
  O  O27  1  0.757  0.768  0.692  1.0
  O  O28  1  0.013  0.258  0.526  1.0
  O  O29  1  0.986  0.744  0.474  1.0
  O  O30  1  0.065  0.919  0.165  1.0
  O  O31  1  0.932  0.081  0.834  1.0
  O  O32  1  0.272  0.270  0.765  1.0
  O  O33  1  0.729  0.727  0.238  1.0
  O  O34  1  0.503  0.987  0.975  1.0
  O  O35  1  0.495  0.809  0.970  1.0
[/CIF]
.