The material structure described by CsBiO2 crystallizes in the monoclinic C2/c space group. Cs(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Bi(1) is bonded in a distorted see-saw-like geometry to four equivalent O(1) atoms. O(1) is bonded in a 5-coordinate geometry to three equivalent Cs(1) and two equivalent Bi(1) atoms. is represented by the CIF file [CIF]
data_CsBiO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.990
_cell_length_b   6.242
_cell_length_c   6.242
_cell_angle_alpha   96.541
_cell_angle_beta   110.970
_cell_angle_gamma   110.970
_symmetry_Int_Tables_number   1
_cell_volume   195.494
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.750  0.359  0.641  1.0
  Cs  Cs1  1  0.250  0.641  0.359  1.0
  Bi  Bi2  1  0.250  0.088  0.912  1.0
  Bi  Bi3  1  0.750  0.912  0.088  1.0
  O  O4  1  0.205  0.122  0.230  1.0
  O  O5  1  0.295  0.770  0.878  1.0
  O  O6  1  0.705  0.230  0.122  1.0
  O  O7  1  0.795  0.878  0.770  1.0
[/CIF]
.
The material structure described by CsBiO2 crystallizes in the monoclinic C2/c space group. Cs(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Bi(1) is bonded in a distorted see-saw-like geometry to four equivalent O(1) atoms. O(1) is bonded in a 5-coordinate geometry to three equivalent Cs(1) and two equivalent Bi(1) atoms. is represented by the CIF file [CIF]
data_CsBiO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.990
_cell_length_b   6.242
_cell_length_c   6.242
_cell_angle_alpha   96.541
_cell_angle_beta   110.970
_cell_angle_gamma   110.970
_symmetry_Int_Tables_number   1
_cell_volume   195.494
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.750  0.359  0.641  1.0
  Cs  Cs1  1  0.250  0.641  0.359  1.0
  Bi  Bi2  1  0.250  0.088  0.912  1.0
  Bi  Bi3  1  0.750  0.912  0.088  1.0
  O  O4  1  0.205  0.122  0.230  1.0
  O  O5  1  0.295  0.770  0.878  1.0
  O  O6  1  0.705  0.230  0.122  1.0
  O  O7  1  0.795  0.878  0.770  1.0
[/CIF]
.