The structure described by LiSn2P3O10 crystallizes in the monoclinic C2/c space group. The structure consists of a LiSn2P3O10 framework. Li(1) is bonded in a bent 150 degrees geometry to two equivalent O(4) atoms. Sn(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(3) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to two equivalent O(1) and two equivalent O(5) atoms to form corner-sharing PO4 tetrahedra. There are five inequivalent O sites. In the first O site, O(5) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sn(1) and one P(2) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Sn(1) and one P(1) atom. In the fourth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Sn(1) and one P(1) atom. In the fifth O site, O(4) is bonded in a bent 150 degrees geometry to one Li(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiSn2P3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.963
_cell_length_b   7.963
_cell_length_c   9.848
_cell_angle_alpha   67.369
_cell_angle_beta   67.369
_cell_angle_gamma   79.803
_symmetry_Int_Tables_number   1
_cell_volume   531.751
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.224  0.776  0.250  1.0
  Li  Li1  1  0.776  0.224  0.750  1.0
  Sn  Sn2  1  0.388  0.257  0.563  1.0
  Sn  Sn3  1  0.612  0.743  0.437  1.0
  Sn  Sn4  1  0.257  0.388  0.063  1.0
  Sn  Sn5  1  0.743  0.612  0.937  1.0
  P  P6  1  0.589  0.132  0.128  1.0
  P  P7  1  0.868  0.411  0.372  1.0
  P  P8  1  0.892  0.108  0.250  1.0
  P  P9  1  0.132  0.589  0.628  1.0
  P  P10  1  0.108  0.892  0.750  1.0
  P  P11  1  0.411  0.868  0.872  1.0
  O  O12  1  0.909  0.856  0.849  1.0
  O  O13  1  0.748  0.567  0.299  1.0
  O  O14  1  0.560  0.930  0.227  1.0
  O  O15  1  0.813  0.372  0.546  1.0
  O  O16  1  0.567  0.748  0.799  1.0
  O  O17  1  0.252  0.433  0.701  1.0
  O  O18  1  0.628  0.187  0.954  1.0
  O  O19  1  0.144  0.091  0.651  1.0
  O  O20  1  0.440  0.070  0.773  1.0
  O  O21  1  0.815  0.224  0.363  1.0
  O  O22  1  0.224  0.815  0.863  1.0
  O  O23  1  0.856  0.909  0.349  1.0
  O  O24  1  0.070  0.440  0.273  1.0
  O  O25  1  0.776  0.185  0.137  1.0
  O  O26  1  0.930  0.560  0.727  1.0
  O  O27  1  0.372  0.813  0.046  1.0
  O  O28  1  0.187  0.628  0.454  1.0
  O  O29  1  0.091  0.144  0.151  1.0
  O  O30  1  0.185  0.776  0.637  1.0
  O  O31  1  0.433  0.252  0.201  1.0
[/CIF]
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The structure described by LiSn2P3O10 crystallizes in the monoclinic C2/c space group. The structure consists of a LiSn2P3O10 framework. Li(1) is bonded in a bent 150 degrees geometry to two equivalent O(4) atoms. Sn(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(3) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to two equivalent O(1) and two equivalent O(5) atoms to form corner-sharing PO4 tetrahedra. There are five inequivalent O sites. In the first O site, O(5) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sn(1) and one P(2) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Sn(1) and one P(1) atom. In the fourth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Sn(1) and one P(1) atom. In the fifth O site, O(4) is bonded in a bent 150 degrees geometry to one Li(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiSn2P3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.963
_cell_length_b   7.963
_cell_length_c   9.848
_cell_angle_alpha   67.369
_cell_angle_beta   67.369
_cell_angle_gamma   79.803
_symmetry_Int_Tables_number   1
_cell_volume   531.751
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.224  0.776  0.250  1.0
  Li  Li1  1  0.776  0.224  0.750  1.0
  Sn  Sn2  1  0.388  0.257  0.563  1.0
  Sn  Sn3  1  0.612  0.743  0.437  1.0
  Sn  Sn4  1  0.257  0.388  0.063  1.0
  Sn  Sn5  1  0.743  0.612  0.937  1.0
  P  P6  1  0.589  0.132  0.128  1.0
  P  P7  1  0.868  0.411  0.372  1.0
  P  P8  1  0.892  0.108  0.250  1.0
  P  P9  1  0.132  0.589  0.628  1.0
  P  P10  1  0.108  0.892  0.750  1.0
  P  P11  1  0.411  0.868  0.872  1.0
  O  O12  1  0.909  0.856  0.849  1.0
  O  O13  1  0.748  0.567  0.299  1.0
  O  O14  1  0.560  0.930  0.227  1.0
  O  O15  1  0.813  0.372  0.546  1.0
  O  O16  1  0.567  0.748  0.799  1.0
  O  O17  1  0.252  0.433  0.701  1.0
  O  O18  1  0.628  0.187  0.954  1.0
  O  O19  1  0.144  0.091  0.651  1.0
  O  O20  1  0.440  0.070  0.773  1.0
  O  O21  1  0.815  0.224  0.363  1.0
  O  O22  1  0.224  0.815  0.863  1.0
  O  O23  1  0.856  0.909  0.349  1.0
  O  O24  1  0.070  0.440  0.273  1.0
  O  O25  1  0.776  0.185  0.137  1.0
  O  O26  1  0.930  0.560  0.727  1.0
  O  O27  1  0.372  0.813  0.046  1.0
  O  O28  1  0.187  0.628  0.454  1.0
  O  O29  1  0.091  0.144  0.151  1.0
  O  O30  1  0.185  0.776  0.637  1.0
  O  O31  1  0.433  0.252  0.201  1.0
[/CIF]
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