The structure described by Gd11Ni4In9 crystallizes in the orthorhombic Cmmm space group. There are five inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 8-coordinate geometry to two equivalent Ni(1), two equivalent In(2), and four equivalent In(1) atoms. In the second Gd site, Gd(2) is bonded in a 8-coordinate geometry to four equivalent In(1) and four equivalent In(2) atoms. In the third Gd site, Gd(3) is bonded in a 10-coordinate geometry to four equivalent Ni(1), two equivalent In(3), and four equivalent In(1) atoms. In the fourth Gd site, Gd(4) is bonded in a 10-coordinate geometry to four equivalent Ni(1), two equivalent In(3), and four equivalent In(2) atoms. In the fifth Gd site, Gd(5) is bonded in a 8-coordinate geometry to eight equivalent In(2) atoms. Ni(1) is bonded in a 9-coordinate geometry to two equivalent Gd(1), two equivalent Gd(3), two equivalent Gd(4), one In(1), one In(2), and one In(3) atom. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 10-coordinate geometry to two equivalent Gd(2), two equivalent Gd(3), four equivalent Gd(1), one Ni(1), and one In(1) atom. In the second In site, In(2) is bonded in a 10-coordinate geometry to two equivalent Gd(1), two equivalent Gd(2), two equivalent Gd(4), two equivalent Gd(5), one Ni(1), and one In(2) atom. In the third In site, In(3) is bonded to four equivalent Gd(3), four equivalent Gd(4), and four equivalent Ni(1) atoms to form face-sharing InGd8Ni4 cuboctahedra. is represented by the CIF file [CIF]
data_Gd11In9Ni4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.669
_cell_length_b   13.108
_cell_length_c   13.108
_cell_angle_alpha   111.154
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   587.937
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.000  0.924  0.582  1.0
  Gd  Gd1  1  0.000  0.076  0.418  1.0
  Gd  Gd2  1  0.000  0.582  0.924  1.0
  Gd  Gd3  1  0.000  0.418  0.076  1.0
  Gd  Gd4  1  0.000  0.157  0.843  1.0
  Gd  Gd5  1  0.000  0.843  0.157  1.0
  Gd  Gd6  1  0.000  0.374  0.626  1.0
  Gd  Gd7  1  0.000  0.626  0.374  1.0
  Gd  Gd8  1  0.000  0.688  0.688  1.0
  Gd  Gd9  1  0.000  0.312  0.312  1.0
  Gd  Gd10  1  0.000  0.000  0.000  1.0
  In  In11  1  0.500  0.162  0.633  1.0
  In  In12  1  0.500  0.838  0.367  1.0
  In  In13  1  0.500  0.633  0.162  1.0
  In  In14  1  0.500  0.367  0.838  1.0
  In  In15  1  0.500  0.922  0.780  1.0
  In  In16  1  0.500  0.078  0.220  1.0
  In  In17  1  0.500  0.780  0.922  1.0
  In  In18  1  0.500  0.220  0.078  1.0
  In  In19  1  0.500  0.500  0.500  1.0
  Ni  Ni20  1  0.500  0.757  0.551  1.0
  Ni  Ni21  1  0.500  0.243  0.449  1.0
  Ni  Ni22  1  0.500  0.551  0.757  1.0
  Ni  Ni23  1  0.500  0.449  0.243  1.0
[/CIF]
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The structure described by Gd11Ni4In9 crystallizes in the orthorhombic Cmmm space group. There are five inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 8-coordinate geometry to two equivalent Ni(1), two equivalent In(2), and four equivalent In(1) atoms. In the second Gd site, Gd(2) is bonded in a 8-coordinate geometry to four equivalent In(1) and four equivalent In(2) atoms. In the third Gd site, Gd(3) is bonded in a 10-coordinate geometry to four equivalent Ni(1), two equivalent In(3), and four equivalent In(1) atoms. In the fourth Gd site, Gd(4) is bonded in a 10-coordinate geometry to four equivalent Ni(1), two equivalent In(3), and four equivalent In(2) atoms. In the fifth Gd site, Gd(5) is bonded in a 8-coordinate geometry to eight equivalent In(2) atoms. Ni(1) is bonded in a 9-coordinate geometry to two equivalent Gd(1), two equivalent Gd(3), two equivalent Gd(4), one In(1), one In(2), and one In(3) atom. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 10-coordinate geometry to two equivalent Gd(2), two equivalent Gd(3), four equivalent Gd(1), one Ni(1), and one In(1) atom. In the second In site, In(2) is bonded in a 10-coordinate geometry to two equivalent Gd(1), two equivalent Gd(2), two equivalent Gd(4), two equivalent Gd(5), one Ni(1), and one In(2) atom. In the third In site, In(3) is bonded to four equivalent Gd(3), four equivalent Gd(4), and four equivalent Ni(1) atoms to form face-sharing InGd8Ni4 cuboctahedra. is represented by the CIF file [CIF]
data_Gd11In9Ni4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.669
_cell_length_b   13.108
_cell_length_c   13.108
_cell_angle_alpha   111.154
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   587.937
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.000  0.924  0.582  1.0
  Gd  Gd1  1  0.000  0.076  0.418  1.0
  Gd  Gd2  1  0.000  0.582  0.924  1.0
  Gd  Gd3  1  0.000  0.418  0.076  1.0
  Gd  Gd4  1  0.000  0.157  0.843  1.0
  Gd  Gd5  1  0.000  0.843  0.157  1.0
  Gd  Gd6  1  0.000  0.374  0.626  1.0
  Gd  Gd7  1  0.000  0.626  0.374  1.0
  Gd  Gd8  1  0.000  0.688  0.688  1.0
  Gd  Gd9  1  0.000  0.312  0.312  1.0
  Gd  Gd10  1  0.000  0.000  0.000  1.0
  In  In11  1  0.500  0.162  0.633  1.0
  In  In12  1  0.500  0.838  0.367  1.0
  In  In13  1  0.500  0.633  0.162  1.0
  In  In14  1  0.500  0.367  0.838  1.0
  In  In15  1  0.500  0.922  0.780  1.0
  In  In16  1  0.500  0.078  0.220  1.0
  In  In17  1  0.500  0.780  0.922  1.0
  In  In18  1  0.500  0.220  0.078  1.0
  In  In19  1  0.500  0.500  0.500  1.0
  Ni  Ni20  1  0.500  0.757  0.551  1.0
  Ni  Ni21  1  0.500  0.243  0.449  1.0
  Ni  Ni22  1  0.500  0.551  0.757  1.0
  Ni  Ni23  1  0.500  0.449  0.243  1.0
[/CIF]
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