The structure described by Tl4GeS4 crystallizes in the monoclinic Cc space group. There are four inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 4-coordinate geometry to one S(3), one S(4), and two equivalent S(1) atoms. In the second Tl site, Tl(2) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(3) atom. In the third Tl site, Tl(3) is bonded in a 3-coordinate geometry to one S(2), one S(3), and one S(4) atom. In the fourth Tl site, Tl(4) is bonded in a 1-coordinate geometry to one S(2) and one S(3) atom. Ge(1) is bonded in a tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to one Tl(2), two equivalent Tl(1), and one Ge(1) atom. In the second S site, S(2) is bonded in a rectangular see-saw-like geometry to one Tl(2), one Tl(3), one Tl(4), and one Ge(1) atom. In the third S site, S(3) is bonded in a 5-coordinate geometry to one Tl(1), one Tl(2), one Tl(3), one Tl(4), and one Ge(1) atom. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Tl(1), one Tl(3), and one Ge(1) atom. is represented by the CIF card [CIF]
data_Tl4GeS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.588
_cell_length_b   8.588
_cell_length_c   7.687
_cell_angle_alpha   73.080
_cell_angle_beta   73.080
_cell_angle_gamma   83.426
_symmetry_Int_Tables_number   1
_cell_volume   518.657
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.207  0.209  0.915  1.0
  Tl  Tl1  1  0.209  0.207  0.415  1.0
  Tl  Tl2  1  0.027  0.591  0.940  1.0
  Tl  Tl3  1  0.591  0.027  0.440  1.0
  Tl  Tl4  1  0.742  0.008  0.913  1.0
  Tl  Tl5  1  0.008  0.742  0.413  1.0
  Tl  Tl6  1  0.634  0.410  0.995  1.0
  Tl  Tl7  1  0.410  0.634  0.495  1.0
  Ge  Ge8  1  0.798  0.377  0.462  1.0
  Ge  Ge9  1  0.377  0.798  0.962  1.0
  S  S10  1  0.207  0.914  0.790  1.0
  S  S11  1  0.914  0.207  0.290  1.0
  S  S12  1  0.624  0.756  0.778  1.0
  S  S13  1  0.756  0.624  0.278  1.0
  S  S14  1  0.561  0.279  0.652  1.0
  S  S15  1  0.279  0.561  0.152  1.0
  S  S16  1  0.952  0.393  0.642  1.0
  S  S17  1  0.393  0.952  0.142  1.0
[/CIF]
.
The structure described by Tl4GeS4 crystallizes in the monoclinic Cc space group. There are four inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 4-coordinate geometry to one S(3), one S(4), and two equivalent S(1) atoms. In the second Tl site, Tl(2) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(3) atom. In the third Tl site, Tl(3) is bonded in a 3-coordinate geometry to one S(2), one S(3), and one S(4) atom. In the fourth Tl site, Tl(4) is bonded in a 1-coordinate geometry to one S(2) and one S(3) atom. Ge(1) is bonded in a tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to one Tl(2), two equivalent Tl(1), and one Ge(1) atom. In the second S site, S(2) is bonded in a rectangular see-saw-like geometry to one Tl(2), one Tl(3), one Tl(4), and one Ge(1) atom. In the third S site, S(3) is bonded in a 5-coordinate geometry to one Tl(1), one Tl(2), one Tl(3), one Tl(4), and one Ge(1) atom. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Tl(1), one Tl(3), and one Ge(1) atom. is represented by the CIF card [CIF]
data_Tl4GeS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.588
_cell_length_b   8.588
_cell_length_c   7.687
_cell_angle_alpha   73.080
_cell_angle_beta   73.080
_cell_angle_gamma   83.426
_symmetry_Int_Tables_number   1
_cell_volume   518.657
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.207  0.209  0.915  1.0
  Tl  Tl1  1  0.209  0.207  0.415  1.0
  Tl  Tl2  1  0.027  0.591  0.940  1.0
  Tl  Tl3  1  0.591  0.027  0.440  1.0
  Tl  Tl4  1  0.742  0.008  0.913  1.0
  Tl  Tl5  1  0.008  0.742  0.413  1.0
  Tl  Tl6  1  0.634  0.410  0.995  1.0
  Tl  Tl7  1  0.410  0.634  0.495  1.0
  Ge  Ge8  1  0.798  0.377  0.462  1.0
  Ge  Ge9  1  0.377  0.798  0.962  1.0
  S  S10  1  0.207  0.914  0.790  1.0
  S  S11  1  0.914  0.207  0.290  1.0
  S  S12  1  0.624  0.756  0.778  1.0
  S  S13  1  0.756  0.624  0.278  1.0
  S  S14  1  0.561  0.279  0.652  1.0
  S  S15  1  0.279  0.561  0.152  1.0
  S  S16  1  0.952  0.393  0.642  1.0
  S  S17  1  0.393  0.952  0.142  1.0
[/CIF]
.