The crystal structure described by SrLaCl5 crystallizes in the monoclinic P2_1/m space group. Sr(1) is bonded in a 8-coordinate geometry to one Cl(5), two equivalent Cl(1), two equivalent Cl(4), and three equivalent Cl(2) atoms. La(1) is bonded in a 7-coordinate geometry to one Cl(1), one Cl(4), two equivalent Cl(5), and three equivalent Cl(3) atoms. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted T-shaped geometry to two equivalent Sr(1) and one La(1) atom. In the second Cl site, Cl(2) is bonded in a trigonal non-coplanar geometry to three equivalent Sr(1) atoms. In the third Cl site, Cl(3) is bonded in a trigonal non-coplanar geometry to three equivalent La(1) atoms. In the fourth Cl site, Cl(4) is bonded in a distorted T-shaped geometry to two equivalent Sr(1) and one La(1) atom. In the fifth Cl site, Cl(5) is bonded in a distorted water-like geometry to one Sr(1) and two equivalent La(1) atoms. is represented by the CIF card [CIF]
data_SrLaCl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.391
_cell_length_b   7.673
_cell_length_c   12.862
_cell_angle_alpha   87.601
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   432.981
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.250  0.944  0.851  1.0
  Sr  Sr1  1  0.750  0.056  0.149  1.0
  La  La2  1  0.750  0.568  0.658  1.0
  La  La3  1  0.250  0.432  0.342  1.0
  Cl  Cl4  1  0.750  0.931  0.671  1.0
  Cl  Cl5  1  0.250  0.853  0.075  1.0
  Cl  Cl6  1  0.250  0.677  0.520  1.0
  Cl  Cl7  1  0.750  0.647  0.867  1.0
  Cl  Cl8  1  0.750  0.645  0.280  1.0
  Cl  Cl9  1  0.250  0.355  0.720  1.0
  Cl  Cl10  1  0.250  0.353  0.133  1.0
  Cl  Cl11  1  0.750  0.323  0.480  1.0
  Cl  Cl12  1  0.750  0.147  0.925  1.0
  Cl  Cl13  1  0.250  0.069  0.329  1.0
[/CIF]
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The crystal structure described by SrLaCl5 crystallizes in the monoclinic P2_1/m space group. Sr(1) is bonded in a 8-coordinate geometry to one Cl(5), two equivalent Cl(1), two equivalent Cl(4), and three equivalent Cl(2) atoms. La(1) is bonded in a 7-coordinate geometry to one Cl(1), one Cl(4), two equivalent Cl(5), and three equivalent Cl(3) atoms. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted T-shaped geometry to two equivalent Sr(1) and one La(1) atom. In the second Cl site, Cl(2) is bonded in a trigonal non-coplanar geometry to three equivalent Sr(1) atoms. In the third Cl site, Cl(3) is bonded in a trigonal non-coplanar geometry to three equivalent La(1) atoms. In the fourth Cl site, Cl(4) is bonded in a distorted T-shaped geometry to two equivalent Sr(1) and one La(1) atom. In the fifth Cl site, Cl(5) is bonded in a distorted water-like geometry to one Sr(1) and two equivalent La(1) atoms. is represented by the CIF card [CIF]
data_SrLaCl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.391
_cell_length_b   7.673
_cell_length_c   12.862
_cell_angle_alpha   87.601
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   432.981
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.250  0.944  0.851  1.0
  Sr  Sr1  1  0.750  0.056  0.149  1.0
  La  La2  1  0.750  0.568  0.658  1.0
  La  La3  1  0.250  0.432  0.342  1.0
  Cl  Cl4  1  0.750  0.931  0.671  1.0
  Cl  Cl5  1  0.250  0.853  0.075  1.0
  Cl  Cl6  1  0.250  0.677  0.520  1.0
  Cl  Cl7  1  0.750  0.647  0.867  1.0
  Cl  Cl8  1  0.750  0.645  0.280  1.0
  Cl  Cl9  1  0.250  0.355  0.720  1.0
  Cl  Cl10  1  0.250  0.353  0.133  1.0
  Cl  Cl11  1  0.750  0.323  0.480  1.0
  Cl  Cl12  1  0.750  0.147  0.925  1.0
  Cl  Cl13  1  0.250  0.069  0.329  1.0
[/CIF]
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