The structure described by Cr2Pb4H2O10ClF crystallizes in the orthorhombic Pmn2_1 space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a tetrahedral geometry to one O(3), one O(6), and two equivalent O(1) atoms. In the second Cr site, Cr(2) is bonded in a tetrahedral geometry to one O(4), one O(7), and two equivalent O(2) atoms. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 7-coordinate geometry to one O(3), one O(4), one O(5), one O(6), one O(7), one Cl(1), and one F(1) atom. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to one O(3), two equivalent O(5), and one F(1) atom. In the third Pb site, Pb(3) is bonded in a 4-coordinate geometry to one O(4), two equivalent O(5), and one F(1) atom. H(1) is bonded in a single-bond geometry to one O(5) atom. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a distorted single-bond geometry to one Cr(1) and two equivalent Pb(1) atoms. In the second O site, O(7) is bonded in a distorted single-bond geometry to one Cr(2) and two equivalent Pb(1) atoms. In the third O site, O(1) is bonded in a single-bond geometry to one Cr(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one Cr(2) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to one Cr(1), one Pb(2), and two equivalent Pb(1) atoms. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to one Cr(2), one Pb(3), and two equivalent Pb(1) atoms. In the seventh O site, O(5) is bonded in a single-bond geometry to one Pb(1), one Pb(2), one Pb(3), and one H(1) atom. Cl(1) is bonded in a 2-coordinate geometry to two equivalent Pb(1) atoms. F(1) is bonded in a distorted L-shaped geometry to one Pb(2), one Pb(3), and two equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_Cr2H2Pb4ClO10F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.004
_cell_length_b   7.717
_cell_length_c   11.953
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   646.070
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.353  0.500  0.002  1.0
  Cr  Cr1  1  0.352  0.500  0.498  1.0
  Cr  Cr2  1  0.648  0.000  0.998  1.0
  Cr  Cr3  1  0.647  0.000  0.502  1.0
  H  H4  1  0.844  0.796  0.751  1.0
  H  H5  1  0.844  0.204  0.751  1.0
  H  H6  1  0.156  0.704  0.251  1.0
  H  H7  1  0.156  0.296  0.251  1.0
  Pb  Pb8  1  0.580  0.750  0.250  1.0
  Pb  Pb9  1  0.580  0.250  0.250  1.0
  Pb  Pb10  1  0.420  0.750  0.750  1.0
  Pb  Pb11  1  0.420  0.250  0.750  1.0
  Pb  Pb12  1  0.876  0.500  0.899  1.0
  Pb  Pb13  1  0.876  0.500  0.599  1.0
  Pb  Pb14  1  0.124  0.000  0.099  1.0
  Pb  Pb15  1  0.124  0.000  0.399  1.0
  Cl  Cl16  1  0.923  0.500  0.269  1.0
  Cl  Cl17  1  0.077  0.000  0.769  1.0
  O  O18  1  0.218  0.674  0.989  1.0
  O  O19  1  0.218  0.326  0.989  1.0
  O  O20  1  0.218  0.674  0.512  1.0
  O  O21  1  0.218  0.326  0.512  1.0
  O  O22  1  0.782  0.826  0.012  1.0
  O  O23  1  0.782  0.174  0.012  1.0
  O  O24  1  0.782  0.826  0.489  1.0
  O  O25  1  0.782  0.174  0.489  1.0
  O  O26  1  0.508  0.500  0.892  1.0
  O  O27  1  0.509  0.500  0.608  1.0
  O  O28  1  0.491  0.000  0.108  1.0
  O  O29  1  0.492  0.000  0.392  1.0
  O  O30  1  0.767  0.688  0.750  1.0
  O  O31  1  0.767  0.312  0.750  1.0
  O  O32  1  0.233  0.812  0.250  1.0
  O  O33  1  0.233  0.188  0.250  1.0
  O  O34  1  0.473  0.500  0.124  1.0
  O  O35  1  0.471  0.500  0.376  1.0
  O  O36  1  0.529  0.000  0.876  1.0
  O  O37  1  0.527  0.000  0.624  1.0
  F  F38  1  0.871  0.000  0.250  1.0
  F  F39  1  0.129  0.500  0.750  1.0
[/CIF]
.
The structure described by Cr2Pb4H2O10ClF crystallizes in the orthorhombic Pmn2_1 space group. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded in a tetrahedral geometry to one O(3), one O(6), and two equivalent O(1) atoms. In the second Cr site, Cr(2) is bonded in a tetrahedral geometry to one O(4), one O(7), and two equivalent O(2) atoms. There are three inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 7-coordinate geometry to one O(3), one O(4), one O(5), one O(6), one O(7), one Cl(1), and one F(1) atom. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to one O(3), two equivalent O(5), and one F(1) atom. In the third Pb site, Pb(3) is bonded in a 4-coordinate geometry to one O(4), two equivalent O(5), and one F(1) atom. H(1) is bonded in a single-bond geometry to one O(5) atom. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a distorted single-bond geometry to one Cr(1) and two equivalent Pb(1) atoms. In the second O site, O(7) is bonded in a distorted single-bond geometry to one Cr(2) and two equivalent Pb(1) atoms. In the third O site, O(1) is bonded in a single-bond geometry to one Cr(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one Cr(2) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to one Cr(1), one Pb(2), and two equivalent Pb(1) atoms. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to one Cr(2), one Pb(3), and two equivalent Pb(1) atoms. In the seventh O site, O(5) is bonded in a single-bond geometry to one Pb(1), one Pb(2), one Pb(3), and one H(1) atom. Cl(1) is bonded in a 2-coordinate geometry to two equivalent Pb(1) atoms. F(1) is bonded in a distorted L-shaped geometry to one Pb(2), one Pb(3), and two equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_Cr2H2Pb4ClO10F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.004
_cell_length_b   7.717
_cell_length_c   11.953
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   646.070
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.353  0.500  0.002  1.0
  Cr  Cr1  1  0.352  0.500  0.498  1.0
  Cr  Cr2  1  0.648  0.000  0.998  1.0
  Cr  Cr3  1  0.647  0.000  0.502  1.0
  H  H4  1  0.844  0.796  0.751  1.0
  H  H5  1  0.844  0.204  0.751  1.0
  H  H6  1  0.156  0.704  0.251  1.0
  H  H7  1  0.156  0.296  0.251  1.0
  Pb  Pb8  1  0.580  0.750  0.250  1.0
  Pb  Pb9  1  0.580  0.250  0.250  1.0
  Pb  Pb10  1  0.420  0.750  0.750  1.0
  Pb  Pb11  1  0.420  0.250  0.750  1.0
  Pb  Pb12  1  0.876  0.500  0.899  1.0
  Pb  Pb13  1  0.876  0.500  0.599  1.0
  Pb  Pb14  1  0.124  0.000  0.099  1.0
  Pb  Pb15  1  0.124  0.000  0.399  1.0
  Cl  Cl16  1  0.923  0.500  0.269  1.0
  Cl  Cl17  1  0.077  0.000  0.769  1.0
  O  O18  1  0.218  0.674  0.989  1.0
  O  O19  1  0.218  0.326  0.989  1.0
  O  O20  1  0.218  0.674  0.512  1.0
  O  O21  1  0.218  0.326  0.512  1.0
  O  O22  1  0.782  0.826  0.012  1.0
  O  O23  1  0.782  0.174  0.012  1.0
  O  O24  1  0.782  0.826  0.489  1.0
  O  O25  1  0.782  0.174  0.489  1.0
  O  O26  1  0.508  0.500  0.892  1.0
  O  O27  1  0.509  0.500  0.608  1.0
  O  O28  1  0.491  0.000  0.108  1.0
  O  O29  1  0.492  0.000  0.392  1.0
  O  O30  1  0.767  0.688  0.750  1.0
  O  O31  1  0.767  0.312  0.750  1.0
  O  O32  1  0.233  0.812  0.250  1.0
  O  O33  1  0.233  0.188  0.250  1.0
  O  O34  1  0.473  0.500  0.124  1.0
  O  O35  1  0.471  0.500  0.376  1.0
  O  O36  1  0.529  0.000  0.876  1.0
  O  O37  1  0.527  0.000  0.624  1.0
  F  F38  1  0.871  0.000  0.250  1.0
  F  F39  1  0.129  0.500  0.750  1.0
[/CIF]
.