The crystal structure described by GdY(WO4)3 crystallizes in the monoclinic C2 space group. Gd(1) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(5), one O(7), one O(8), and one O(9) atom. Y(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(12), one O(2), one O(4), one O(6), one O(7), and one O(8) atom. There are four inequivalent W sites. In the first W site, W(1) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(3), one O(4), and one O(6) atom. In the second W site, W(2) is bonded in a 5-coordinate geometry to one O(12), one O(2), one O(3), one O(4), and one O(5) atom. In the third W site, W(3) is bonded in a tetrahedral geometry to two equivalent O(7) and two equivalent O(9) atoms. In the fourth W site, W(4) is bonded in a tetrahedral geometry to two equivalent O(10) and two equivalent O(8) atoms. There are twelve inequivalent O sites. In the first O site, O(7) is bonded in a trigonal planar geometry to one Gd(1), one Y(1), and one W(3) atom. In the second O site, O(8) is bonded in a trigonal planar geometry to one Gd(1), one Y(1), and one W(4) atom. In the third O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one W(3) atom. In the fourth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one W(4) atom. In the fifth O site, O(11) is bonded in a distorted trigonal planar geometry to one Gd(1), one Y(1), and one W(1) atom. In the sixth O site, O(12) is bonded in a distorted trigonal planar geometry to one Gd(1), one Y(1), and one W(2) atom. In the seventh O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one W(1) atom. In the eighth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one W(2) atom. In the ninth O site, O(3) is bonded in a trigonal non-coplanar geometry to one Gd(1), one W(1), and one W(2) atom. In the tenth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Y(1), one W(1), and one W(2) atom. In the eleventh O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one W(2) atom. In the twelfth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_GdY(WO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.981
_cell_length_b   6.981
_cell_length_c   11.464
_cell_angle_alpha   79.153
_cell_angle_beta   79.153
_cell_angle_gamma   111.738
_symmetry_Int_Tables_number   1
_cell_volume   488.938
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.212  0.459  0.844  1.0
  Gd  Gd1  1  0.541  0.788  0.156  1.0
  Y  Y2  1  0.788  0.542  0.656  1.0
  Y  Y3  1  0.458  0.212  0.344  1.0
  W  W4  1  0.038  0.250  0.205  1.0
  W  W5  1  0.750  0.962  0.795  1.0
  W  W6  1  0.959  0.748  0.298  1.0
  W  W7  1  0.252  0.041  0.702  1.0
  W  W8  1  0.633  0.367  0.000  1.0
  W  W9  1  0.366  0.634  0.500  1.0
  O  O10  1  0.042  0.396  0.053  1.0
  O  O11  1  0.604  0.958  0.947  1.0
  O  O12  1  0.954  0.602  0.450  1.0
  O  O13  1  0.398  0.046  0.550  1.0
  O  O14  1  0.893  0.971  0.179  1.0
  O  O15  1  0.029  0.107  0.821  1.0
  O  O16  1  0.107  0.028  0.323  1.0
  O  O17  1  0.972  0.893  0.677  1.0
  O  O18  1  0.269  0.835  0.812  1.0
  O  O19  1  0.165  0.731  0.188  1.0
  O  O20  1  0.735  0.169  0.685  1.0
  O  O21  1  0.831  0.265  0.315  1.0
  O  O22  1  0.838  0.419  0.855  1.0
  O  O23  1  0.581  0.162  0.145  1.0
  O  O24  1  0.159  0.582  0.643  1.0
  O  O25  1  0.418  0.841  0.357  1.0
  O  O26  1  0.375  0.292  0.971  1.0
  O  O27  1  0.708  0.625  0.029  1.0
  O  O28  1  0.624  0.707  0.530  1.0
  O  O29  1  0.293  0.376  0.470  1.0
  O  O30  1  0.583  0.685  0.786  1.0
  O  O31  1  0.315  0.417  0.214  1.0
  O  O32  1  0.421  0.315  0.713  1.0
  O  O33  1  0.685  0.579  0.287  1.0
[/CIF]
.
The crystal structure described by GdY(WO4)3 crystallizes in the monoclinic C2 space group. Gd(1) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(5), one O(7), one O(8), and one O(9) atom. Y(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(12), one O(2), one O(4), one O(6), one O(7), and one O(8) atom. There are four inequivalent W sites. In the first W site, W(1) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(3), one O(4), and one O(6) atom. In the second W site, W(2) is bonded in a 5-coordinate geometry to one O(12), one O(2), one O(3), one O(4), and one O(5) atom. In the third W site, W(3) is bonded in a tetrahedral geometry to two equivalent O(7) and two equivalent O(9) atoms. In the fourth W site, W(4) is bonded in a tetrahedral geometry to two equivalent O(10) and two equivalent O(8) atoms. There are twelve inequivalent O sites. In the first O site, O(7) is bonded in a trigonal planar geometry to one Gd(1), one Y(1), and one W(3) atom. In the second O site, O(8) is bonded in a trigonal planar geometry to one Gd(1), one Y(1), and one W(4) atom. In the third O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one W(3) atom. In the fourth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one W(4) atom. In the fifth O site, O(11) is bonded in a distorted trigonal planar geometry to one Gd(1), one Y(1), and one W(1) atom. In the sixth O site, O(12) is bonded in a distorted trigonal planar geometry to one Gd(1), one Y(1), and one W(2) atom. In the seventh O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one W(1) atom. In the eighth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one W(2) atom. In the ninth O site, O(3) is bonded in a trigonal non-coplanar geometry to one Gd(1), one W(1), and one W(2) atom. In the tenth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Y(1), one W(1), and one W(2) atom. In the eleventh O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one W(2) atom. In the twelfth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_GdY(WO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.981
_cell_length_b   6.981
_cell_length_c   11.464
_cell_angle_alpha   79.153
_cell_angle_beta   79.153
_cell_angle_gamma   111.738
_symmetry_Int_Tables_number   1
_cell_volume   488.938
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.212  0.459  0.844  1.0
  Gd  Gd1  1  0.541  0.788  0.156  1.0
  Y  Y2  1  0.788  0.542  0.656  1.0
  Y  Y3  1  0.458  0.212  0.344  1.0
  W  W4  1  0.038  0.250  0.205  1.0
  W  W5  1  0.750  0.962  0.795  1.0
  W  W6  1  0.959  0.748  0.298  1.0
  W  W7  1  0.252  0.041  0.702  1.0
  W  W8  1  0.633  0.367  0.000  1.0
  W  W9  1  0.366  0.634  0.500  1.0
  O  O10  1  0.042  0.396  0.053  1.0
  O  O11  1  0.604  0.958  0.947  1.0
  O  O12  1  0.954  0.602  0.450  1.0
  O  O13  1  0.398  0.046  0.550  1.0
  O  O14  1  0.893  0.971  0.179  1.0
  O  O15  1  0.029  0.107  0.821  1.0
  O  O16  1  0.107  0.028  0.323  1.0
  O  O17  1  0.972  0.893  0.677  1.0
  O  O18  1  0.269  0.835  0.812  1.0
  O  O19  1  0.165  0.731  0.188  1.0
  O  O20  1  0.735  0.169  0.685  1.0
  O  O21  1  0.831  0.265  0.315  1.0
  O  O22  1  0.838  0.419  0.855  1.0
  O  O23  1  0.581  0.162  0.145  1.0
  O  O24  1  0.159  0.582  0.643  1.0
  O  O25  1  0.418  0.841  0.357  1.0
  O  O26  1  0.375  0.292  0.971  1.0
  O  O27  1  0.708  0.625  0.029  1.0
  O  O28  1  0.624  0.707  0.530  1.0
  O  O29  1  0.293  0.376  0.470  1.0
  O  O30  1  0.583  0.685  0.786  1.0
  O  O31  1  0.315  0.417  0.214  1.0
  O  O32  1  0.421  0.315  0.713  1.0
  O  O33  1  0.685  0.579  0.287  1.0
[/CIF]
.