The compound described by HgC4AsNSe3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two HgC4AsNSe3 clusters. Hg(1) is bonded in a linear geometry to one Se(2) and one Se(3) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a 4-coordinate geometry to one C(2), one C(3), one C(4), and one N(1) atom. In the second C site, C(2) is bonded in a 3-coordinate geometry to one C(1), one C(3), and one N(1) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1), one C(2), one C(4), and one N(1) atom. In the fourth C site, C(4) is bonded in a 3-coordinate geometry to one C(1), one C(3), and one Se(1) atom. As(1) is bonded in a distorted T-shaped geometry to one Se(1), one Se(2), and one Se(3) atom. N(1) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one C(3) atom. There are three inequivalent Se sites. In the first Se site, Se(3) is bonded in a water-like geometry to one Hg(1) and one As(1) atom. In the second Se site, Se(1) is bonded in an L-shaped geometry to one C(4) and one As(1) atom. In the third Se site, Se(2) is bonded in an L-shaped geometry to one Hg(1) and one As(1) atom. is represented by the CIF file [CIF]
data_HgAsC4Se3N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   18.639
_cell_length_b   7.114
_cell_length_c   10.733
_cell_angle_alpha   52.870
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1134.607
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.484  0.300  0.428  1.0
  Hg  Hg1  1  0.016  0.300  0.928  1.0
  Hg  Hg2  1  0.516  0.700  0.572  1.0
  Hg  Hg3  1  0.984  0.700  0.072  1.0
  As  As4  1  0.446  0.841  0.846  1.0
  As  As5  1  0.054  0.841  0.346  1.0
  As  As6  1  0.554  0.159  0.154  1.0
  As  As7  1  0.946  0.159  0.654  1.0
  C  C8  1  0.621  0.025  0.889  1.0
  C  C9  1  0.879  0.025  0.389  1.0
  C  C10  1  0.379  0.975  0.111  1.0
  C  C11  1  0.121  0.975  0.611  1.0
  C  C12  1  0.670  0.824  0.923  1.0
  C  C13  1  0.830  0.824  0.423  1.0
  C  C14  1  0.330  0.176  0.077  1.0
  C  C15  1  0.170  0.176  0.577  1.0
  C  C16  1  0.714  0.036  0.883  1.0
  C  C17  1  0.786  0.036  0.383  1.0
  C  C18  1  0.286  0.964  0.117  1.0
  C  C19  1  0.214  0.964  0.617  1.0
  C  C20  1  0.667  0.143  0.931  1.0
  C  C21  1  0.833  0.143  0.431  1.0
  C  C22  1  0.333  0.857  0.069  1.0
  C  C23  1  0.167  0.857  0.569  1.0
  Se  Se24  1  0.328  0.699  0.984  1.0
  Se  Se25  1  0.172  0.699  0.484  1.0
  Se  Se26  1  0.672  0.301  0.016  1.0
  Se  Se27  1  0.828  0.301  0.516  1.0
  Se  Se28  1  0.395  0.221  0.629  1.0
  Se  Se29  1  0.105  0.221  0.129  1.0
  Se  Se30  1  0.605  0.779  0.371  1.0
  Se  Se31  1  0.895  0.779  0.871  1.0
  Se  Se32  1  0.425  0.576  0.777  1.0
  Se  Se33  1  0.075  0.576  0.277  1.0
  Se  Se34  1  0.575  0.424  0.223  1.0
  Se  Se35  1  0.925  0.424  0.723  1.0
  N  N36  1  0.667  0.063  0.760  1.0
  N  N37  1  0.833  0.063  0.260  1.0
  N  N38  1  0.333  0.937  0.240  1.0
  N  N39  1  0.167  0.937  0.740  1.0
[/CIF]
.
The compound described by HgC4AsNSe3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two HgC4AsNSe3 clusters. Hg(1) is bonded in a linear geometry to one Se(2) and one Se(3) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a 4-coordinate geometry to one C(2), one C(3), one C(4), and one N(1) atom. In the second C site, C(2) is bonded in a 3-coordinate geometry to one C(1), one C(3), and one N(1) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1), one C(2), one C(4), and one N(1) atom. In the fourth C site, C(4) is bonded in a 3-coordinate geometry to one C(1), one C(3), and one Se(1) atom. As(1) is bonded in a distorted T-shaped geometry to one Se(1), one Se(2), and one Se(3) atom. N(1) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one C(3) atom. There are three inequivalent Se sites. In the first Se site, Se(3) is bonded in a water-like geometry to one Hg(1) and one As(1) atom. In the second Se site, Se(1) is bonded in an L-shaped geometry to one C(4) and one As(1) atom. In the third Se site, Se(2) is bonded in an L-shaped geometry to one Hg(1) and one As(1) atom. is represented by the CIF file [CIF]
data_HgAsC4Se3N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   18.639
_cell_length_b   7.114
_cell_length_c   10.733
_cell_angle_alpha   52.870
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1134.607
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.484  0.300  0.428  1.0
  Hg  Hg1  1  0.016  0.300  0.928  1.0
  Hg  Hg2  1  0.516  0.700  0.572  1.0
  Hg  Hg3  1  0.984  0.700  0.072  1.0
  As  As4  1  0.446  0.841  0.846  1.0
  As  As5  1  0.054  0.841  0.346  1.0
  As  As6  1  0.554  0.159  0.154  1.0
  As  As7  1  0.946  0.159  0.654  1.0
  C  C8  1  0.621  0.025  0.889  1.0
  C  C9  1  0.879  0.025  0.389  1.0
  C  C10  1  0.379  0.975  0.111  1.0
  C  C11  1  0.121  0.975  0.611  1.0
  C  C12  1  0.670  0.824  0.923  1.0
  C  C13  1  0.830  0.824  0.423  1.0
  C  C14  1  0.330  0.176  0.077  1.0
  C  C15  1  0.170  0.176  0.577  1.0
  C  C16  1  0.714  0.036  0.883  1.0
  C  C17  1  0.786  0.036  0.383  1.0
  C  C18  1  0.286  0.964  0.117  1.0
  C  C19  1  0.214  0.964  0.617  1.0
  C  C20  1  0.667  0.143  0.931  1.0
  C  C21  1  0.833  0.143  0.431  1.0
  C  C22  1  0.333  0.857  0.069  1.0
  C  C23  1  0.167  0.857  0.569  1.0
  Se  Se24  1  0.328  0.699  0.984  1.0
  Se  Se25  1  0.172  0.699  0.484  1.0
  Se  Se26  1  0.672  0.301  0.016  1.0
  Se  Se27  1  0.828  0.301  0.516  1.0
  Se  Se28  1  0.395  0.221  0.629  1.0
  Se  Se29  1  0.105  0.221  0.129  1.0
  Se  Se30  1  0.605  0.779  0.371  1.0
  Se  Se31  1  0.895  0.779  0.871  1.0
  Se  Se32  1  0.425  0.576  0.777  1.0
  Se  Se33  1  0.075  0.576  0.277  1.0
  Se  Se34  1  0.575  0.424  0.223  1.0
  Se  Se35  1  0.925  0.424  0.723  1.0
  N  N36  1  0.667  0.063  0.760  1.0
  N  N37  1  0.833  0.063  0.260  1.0
  N  N38  1  0.333  0.937  0.240  1.0
  N  N39  1  0.167  0.937  0.740  1.0
[/CIF]
.