The compound described by TiO2(SnO2)4 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two titanium, diaqua- molecules and eight SnO2 clusters. In each SnO2 cluster, Sn(1) is bonded in a linear geometry to one O(10) and one O(8) atom. There are two inequivalent O sites. In the first O site, O(8) is bonded in a single-bond geometry to one Sn(1) atom. In the second O site, O(10) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the CIF card [CIF]
data_Ti(Sn2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.797
_cell_length_b   5.761
_cell_length_c   13.554
_cell_angle_alpha   78.662
_cell_angle_beta   89.956
_cell_angle_gamma   89.933
_symmetry_Int_Tables_number   1
_cell_volume   367.288
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  1.000  0.802  0.899  1.0
  Ti  Ti1  1  0.000  0.198  0.101  1.0
  Sn  Sn2  1  0.500  0.801  0.399  1.0
  Sn  Sn3  1  0.500  0.199  0.601  1.0
  Sn  Sn4  1  0.500  0.000  0.000  1.0
  Sn  Sn5  1  0.502  0.603  0.801  1.0
  Sn  Sn6  1  0.498  0.397  0.199  1.0
  Sn  Sn7  1  0.000  0.398  0.703  1.0
  Sn  Sn8  1  0.000  0.000  0.500  1.0
  Sn  Sn9  1  1.000  0.602  0.297  1.0
  O  O10  1  0.810  0.934  0.823  1.0
  O  O11  1  0.810  0.332  0.025  1.0
  O  O12  1  0.810  0.142  0.404  1.0
  O  O13  1  0.810  0.744  0.201  1.0
  O  O14  1  0.807  0.539  0.617  1.0
  O  O15  1  0.705  0.138  0.917  1.0
  O  O16  1  0.706  0.741  0.716  1.0
  O  O17  1  0.690  0.339  0.521  1.0
  O  O18  1  0.694  0.538  0.117  1.0
  O  O19  1  0.690  0.941  0.321  1.0
  O  O20  1  0.295  0.862  0.083  1.0
  O  O21  1  0.306  0.462  0.883  1.0
  O  O22  1  0.310  0.059  0.679  1.0
  O  O23  1  0.294  0.259  0.284  1.0
  O  O24  1  0.310  0.661  0.479  1.0
  O  O25  1  0.190  0.066  0.177  1.0
  O  O26  1  0.190  0.256  0.799  1.0
  O  O27  1  0.190  0.668  0.975  1.0
  O  O28  1  0.190  0.858  0.596  1.0
  O  O29  1  0.193  0.461  0.383  1.0
[/CIF]
.
The compound described by TiO2(SnO2)4 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two titanium, diaqua- molecules and eight SnO2 clusters. In each SnO2 cluster, Sn(1) is bonded in a linear geometry to one O(10) and one O(8) atom. There are two inequivalent O sites. In the first O site, O(8) is bonded in a single-bond geometry to one Sn(1) atom. In the second O site, O(10) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the CIF card [CIF]
data_Ti(Sn2O5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.797
_cell_length_b   5.761
_cell_length_c   13.554
_cell_angle_alpha   78.662
_cell_angle_beta   89.956
_cell_angle_gamma   89.933
_symmetry_Int_Tables_number   1
_cell_volume   367.288
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  1.000  0.802  0.899  1.0
  Ti  Ti1  1  0.000  0.198  0.101  1.0
  Sn  Sn2  1  0.500  0.801  0.399  1.0
  Sn  Sn3  1  0.500  0.199  0.601  1.0
  Sn  Sn4  1  0.500  0.000  0.000  1.0
  Sn  Sn5  1  0.502  0.603  0.801  1.0
  Sn  Sn6  1  0.498  0.397  0.199  1.0
  Sn  Sn7  1  0.000  0.398  0.703  1.0
  Sn  Sn8  1  0.000  0.000  0.500  1.0
  Sn  Sn9  1  1.000  0.602  0.297  1.0
  O  O10  1  0.810  0.934  0.823  1.0
  O  O11  1  0.810  0.332  0.025  1.0
  O  O12  1  0.810  0.142  0.404  1.0
  O  O13  1  0.810  0.744  0.201  1.0
  O  O14  1  0.807  0.539  0.617  1.0
  O  O15  1  0.705  0.138  0.917  1.0
  O  O16  1  0.706  0.741  0.716  1.0
  O  O17  1  0.690  0.339  0.521  1.0
  O  O18  1  0.694  0.538  0.117  1.0
  O  O19  1  0.690  0.941  0.321  1.0
  O  O20  1  0.295  0.862  0.083  1.0
  O  O21  1  0.306  0.462  0.883  1.0
  O  O22  1  0.310  0.059  0.679  1.0
  O  O23  1  0.294  0.259  0.284  1.0
  O  O24  1  0.310  0.661  0.479  1.0
  O  O25  1  0.190  0.066  0.177  1.0
  O  O26  1  0.190  0.256  0.799  1.0
  O  O27  1  0.190  0.668  0.975  1.0
  O  O28  1  0.190  0.858  0.596  1.0
  O  O29  1  0.193  0.461  0.383  1.0
[/CIF]
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