The material structure described by CoN14CoN10 is alpha structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CoN10 cluster and one CoN14 cluster. In the CoN10 cluster, Co(2) is bonded in an octahedral geometry to two equivalent N(11), two equivalent N(12), and two equivalent N(7) atoms. There are five inequivalent N sites. In the first N site, N(7) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one N(8) atom. In the second N site, N(8) is bonded in a linear geometry to one N(7) and one N(9) atom. In the third N site, N(9) is bonded in a single-bond geometry to one N(8) atom. In the fourth N site, N(11) is bonded in a single-bond geometry to one Co(2) atom. In the fifth N site, N(12) is bonded in a single-bond geometry to one Co(2) atom. In the CoN14 cluster, Co(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(10), and two equivalent N(4) atoms. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Co(1) and one N(5) atom. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom. In the seventh N site, N(10) is bonded in a single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoN12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.088
_cell_length_b   7.985
_cell_length_c   9.994
_cell_angle_alpha   107.368
_cell_angle_beta   93.301
_cell_angle_gamma   117.174
_symmetry_Int_Tables_number   1
_cell_volume   467.533
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.500  0.000  0.500  1.0
  N  N2  1  0.696  0.850  0.920  1.0
  N  N3  1  0.304  0.150  0.080  1.0
  N  N4  1  0.563  0.776  0.987  1.0
  N  N5  1  0.437  0.224  0.013  1.0
  N  N6  1  0.425  0.699  0.042  1.0
  N  N7  1  0.575  0.301  0.958  1.0
  N  N8  1  0.053  0.939  0.810  1.0
  N  N9  1  0.947  0.061  0.190  1.0
  N  N10  1  0.910  0.801  0.706  1.0
  N  N11  1  0.090  0.199  0.294  1.0
  N  N12  1  0.785  0.673  0.602  1.0
  N  N13  1  0.215  0.327  0.398  1.0
  N  N14  1  0.217  0.877  0.391  1.0
  N  N15  1  0.783  0.123  0.609  1.0
  N  N16  1  0.082  0.697  0.339  1.0
  N  N17  1  0.918  0.303  0.661  1.0
  N  N18  1  0.940  0.532  0.285  1.0
  N  N19  1  0.060  0.468  0.715  1.0
  N  N20  1  0.992  0.761  0.011  1.0
  N  N21  1  0.008  0.239  0.989  1.0
  N  N22  1  0.599  0.154  0.380  1.0
  N  N23  1  0.401  0.846  0.620  1.0
  N  N24  1  0.552  0.797  0.382  1.0
  N  N25  1  0.448  0.203  0.618  1.0
[/CIF]
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The material structure described by CoN14CoN10 is alpha structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CoN10 cluster and one CoN14 cluster. In the CoN10 cluster, Co(2) is bonded in an octahedral geometry to two equivalent N(11), two equivalent N(12), and two equivalent N(7) atoms. There are five inequivalent N sites. In the first N site, N(7) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one N(8) atom. In the second N site, N(8) is bonded in a linear geometry to one N(7) and one N(9) atom. In the third N site, N(9) is bonded in a single-bond geometry to one N(8) atom. In the fourth N site, N(11) is bonded in a single-bond geometry to one Co(2) atom. In the fifth N site, N(12) is bonded in a single-bond geometry to one Co(2) atom. In the CoN14 cluster, Co(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(10), and two equivalent N(4) atoms. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Co(1) and one N(5) atom. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom. In the seventh N site, N(10) is bonded in a single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoN12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.088
_cell_length_b   7.985
_cell_length_c   9.994
_cell_angle_alpha   107.368
_cell_angle_beta   93.301
_cell_angle_gamma   117.174
_symmetry_Int_Tables_number   1
_cell_volume   467.533
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.500  0.000  0.500  1.0
  N  N2  1  0.696  0.850  0.920  1.0
  N  N3  1  0.304  0.150  0.080  1.0
  N  N4  1  0.563  0.776  0.987  1.0
  N  N5  1  0.437  0.224  0.013  1.0
  N  N6  1  0.425  0.699  0.042  1.0
  N  N7  1  0.575  0.301  0.958  1.0
  N  N8  1  0.053  0.939  0.810  1.0
  N  N9  1  0.947  0.061  0.190  1.0
  N  N10  1  0.910  0.801  0.706  1.0
  N  N11  1  0.090  0.199  0.294  1.0
  N  N12  1  0.785  0.673  0.602  1.0
  N  N13  1  0.215  0.327  0.398  1.0
  N  N14  1  0.217  0.877  0.391  1.0
  N  N15  1  0.783  0.123  0.609  1.0
  N  N16  1  0.082  0.697  0.339  1.0
  N  N17  1  0.918  0.303  0.661  1.0
  N  N18  1  0.940  0.532  0.285  1.0
  N  N19  1  0.060  0.468  0.715  1.0
  N  N20  1  0.992  0.761  0.011  1.0
  N  N21  1  0.008  0.239  0.989  1.0
  N  N22  1  0.599  0.154  0.380  1.0
  N  N23  1  0.401  0.846  0.620  1.0
  N  N24  1  0.552  0.797  0.382  1.0
  N  N25  1  0.448  0.203  0.618  1.0
[/CIF]
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