The crystal structure described by KAuC2(NS)2 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 4-coordinate geometry to two equivalent N(1), two equivalent N(2), one S(2), and two equivalent S(1) atoms. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted linear geometry to two equivalent S(2) atoms. In the second Au site, Au(2) is bonded in a distorted linear geometry to two equivalent S(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(2) and one S(2) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one C(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one C(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Au(2), and one C(2) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one K(1), one Au(1), and one C(1) atom. is represented by the CIF file [CIF]
data_KAuC2(SN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.347
_cell_length_b   7.347
_cell_length_c   18.072
_cell_angle_alpha   71.441
_cell_angle_beta   71.441
_cell_angle_gamma   49.094
_symmetry_Int_Tables_number   1
_cell_volume   690.631
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.190  0.147  0.948  1.0
  K  K1  1  0.810  0.853  0.052  1.0
  K  K2  1  0.147  0.190  0.448  1.0
  K  K3  1  0.853  0.810  0.552  1.0
  Au  Au4  1  0.824  0.176  0.250  1.0
  Au  Au5  1  0.674  0.326  0.750  1.0
  Au  Au6  1  0.326  0.674  0.250  1.0
  Au  Au7  1  0.176  0.824  0.750  1.0
  C  C8  1  0.717  0.828  0.365  1.0
  C  C9  1  0.828  0.717  0.865  1.0
  C  C10  1  0.283  0.172  0.635  1.0
  C  C11  1  0.449  0.573  0.588  1.0
  C  C12  1  0.573  0.449  0.088  1.0
  C  C13  1  0.172  0.283  0.135  1.0
  C  C14  1  0.551  0.427  0.412  1.0
  C  C15  1  0.427  0.551  0.912  1.0
  S  S16  1  0.703  0.310  0.618  1.0
  S  S17  1  0.310  0.703  0.118  1.0
  S  S18  1  0.994  0.381  0.219  1.0
  S  S19  1  0.297  0.690  0.382  1.0
  S  S20  1  0.690  0.297  0.882  1.0
  S  S21  1  0.381  0.994  0.719  1.0
  S  S22  1  0.619  0.006  0.281  1.0
  S  S23  1  0.006  0.619  0.781  1.0
  N  N24  1  0.727  0.244  0.436  1.0
  N  N25  1  0.294  0.226  0.073  1.0
  N  N26  1  0.706  0.774  0.927  1.0
  N  N27  1  0.774  0.706  0.427  1.0
  N  N28  1  0.756  0.273  0.064  1.0
  N  N29  1  0.273  0.756  0.564  1.0
  N  N30  1  0.226  0.294  0.573  1.0
  N  N31  1  0.244  0.727  0.936  1.0
[/CIF]
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The crystal structure described by KAuC2(NS)2 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 4-coordinate geometry to two equivalent N(1), two equivalent N(2), one S(2), and two equivalent S(1) atoms. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted linear geometry to two equivalent S(2) atoms. In the second Au site, Au(2) is bonded in a distorted linear geometry to two equivalent S(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(2) and one S(2) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one C(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one C(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to two equivalent K(1), one Au(2), and one C(2) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one K(1), one Au(1), and one C(1) atom. is represented by the CIF file [CIF]
data_KAuC2(SN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.347
_cell_length_b   7.347
_cell_length_c   18.072
_cell_angle_alpha   71.441
_cell_angle_beta   71.441
_cell_angle_gamma   49.094
_symmetry_Int_Tables_number   1
_cell_volume   690.631
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.190  0.147  0.948  1.0
  K  K1  1  0.810  0.853  0.052  1.0
  K  K2  1  0.147  0.190  0.448  1.0
  K  K3  1  0.853  0.810  0.552  1.0
  Au  Au4  1  0.824  0.176  0.250  1.0
  Au  Au5  1  0.674  0.326  0.750  1.0
  Au  Au6  1  0.326  0.674  0.250  1.0
  Au  Au7  1  0.176  0.824  0.750  1.0
  C  C8  1  0.717  0.828  0.365  1.0
  C  C9  1  0.828  0.717  0.865  1.0
  C  C10  1  0.283  0.172  0.635  1.0
  C  C11  1  0.449  0.573  0.588  1.0
  C  C12  1  0.573  0.449  0.088  1.0
  C  C13  1  0.172  0.283  0.135  1.0
  C  C14  1  0.551  0.427  0.412  1.0
  C  C15  1  0.427  0.551  0.912  1.0
  S  S16  1  0.703  0.310  0.618  1.0
  S  S17  1  0.310  0.703  0.118  1.0
  S  S18  1  0.994  0.381  0.219  1.0
  S  S19  1  0.297  0.690  0.382  1.0
  S  S20  1  0.690  0.297  0.882  1.0
  S  S21  1  0.381  0.994  0.719  1.0
  S  S22  1  0.619  0.006  0.281  1.0
  S  S23  1  0.006  0.619  0.781  1.0
  N  N24  1  0.727  0.244  0.436  1.0
  N  N25  1  0.294  0.226  0.073  1.0
  N  N26  1  0.706  0.774  0.927  1.0
  N  N27  1  0.774  0.706  0.427  1.0
  N  N28  1  0.756  0.273  0.064  1.0
  N  N29  1  0.273  0.756  0.564  1.0
  N  N30  1  0.226  0.294  0.573  1.0
  N  N31  1  0.244  0.727  0.936  1.0
[/CIF]
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