The material structure described by MoB2(PbO2)6 crystallizes in the orthorhombic Cmcm space group. Mo(1) is bonded in a tetrahedral geometry to two equivalent O(4) and two equivalent O(5) atoms. B(1) is bonded in a trigonal planar geometry to one O(2) and two equivalent O(1) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to one O(3), one O(4), and two equivalent O(1) atoms. In the second Pb site, Pb(2) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one B(1), one Pb(1), and one Pb(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one B(1) and two equivalent Pb(2) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Pb(1) and two equivalent Pb(2) atoms. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Mo(1) and one Pb(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_B2Mo(PbO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.774
_cell_length_b   9.774
_cell_length_c   11.834
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   142.197
_symmetry_Int_Tables_number   1
_cell_volume   693.015
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.747  0.253  0.500  1.0
  B  B1  1  0.747  0.253  0.000  1.0
  B  B2  1  0.253  0.747  0.500  1.0
  B  B3  1  0.253  0.747  0.000  1.0
  Mo  Mo4  1  0.269  0.269  0.250  1.0
  Mo  Mo5  1  0.731  0.731  0.750  1.0
  Pb  Pb6  1  0.090  0.506  0.250  1.0
  Pb  Pb7  1  0.494  0.910  0.750  1.0
  Pb  Pb8  1  0.910  0.494  0.750  1.0
  Pb  Pb9  1  0.506  0.090  0.250  1.0
  Pb  Pb10  1  0.866  0.655  0.407  1.0
  Pb  Pb11  1  0.345  0.134  0.593  1.0
  Pb  Pb12  1  0.866  0.655  0.093  1.0
  Pb  Pb13  1  0.345  0.134  0.907  1.0
  Pb  Pb14  1  0.134  0.345  0.593  1.0
  Pb  Pb15  1  0.655  0.866  0.407  1.0
  Pb  Pb16  1  0.134  0.345  0.907  1.0
  Pb  Pb17  1  0.655  0.866  0.093  1.0
  O  O18  1  0.159  0.725  0.404  1.0
  O  O19  1  0.275  0.841  0.596  1.0
  O  O20  1  0.159  0.725  0.096  1.0
  O  O21  1  0.275  0.841  0.904  1.0
  O  O22  1  0.841  0.275  0.596  1.0
  O  O23  1  0.725  0.159  0.404  1.0
  O  O24  1  0.841  0.275  0.904  1.0
  O  O25  1  0.725  0.159  0.096  1.0
  O  O26  1  0.671  0.329  0.500  1.0
  O  O27  1  0.671  0.329  0.000  1.0
  O  O28  1  0.329  0.671  0.500  1.0
  O  O29  1  0.329  0.671  0.000  1.0
  O  O30  1  0.779  0.480  0.250  1.0
  O  O31  1  0.520  0.221  0.750  1.0
  O  O32  1  0.221  0.520  0.750  1.0
  O  O33  1  0.480  0.779  0.250  1.0
  O  O34  1  0.177  0.023  0.250  1.0
  O  O35  1  0.977  0.823  0.750  1.0
  O  O36  1  0.823  0.977  0.750  1.0
  O  O37  1  0.023  0.177  0.250  1.0
  O  O38  1  0.430  0.430  0.372  1.0
  O  O39  1  0.570  0.570  0.628  1.0
  O  O40  1  0.430  0.430  0.128  1.0
  O  O41  1  0.570  0.570  0.872  1.0
[/CIF]
.
The material structure described by MoB2(PbO2)6 crystallizes in the orthorhombic Cmcm space group. Mo(1) is bonded in a tetrahedral geometry to two equivalent O(4) and two equivalent O(5) atoms. B(1) is bonded in a trigonal planar geometry to one O(2) and two equivalent O(1) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to one O(3), one O(4), and two equivalent O(1) atoms. In the second Pb site, Pb(2) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one B(1), one Pb(1), and one Pb(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one B(1) and two equivalent Pb(2) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Pb(1) and two equivalent Pb(2) atoms. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Mo(1) and one Pb(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_B2Mo(PbO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.774
_cell_length_b   9.774
_cell_length_c   11.834
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   142.197
_symmetry_Int_Tables_number   1
_cell_volume   693.015
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.747  0.253  0.500  1.0
  B  B1  1  0.747  0.253  0.000  1.0
  B  B2  1  0.253  0.747  0.500  1.0
  B  B3  1  0.253  0.747  0.000  1.0
  Mo  Mo4  1  0.269  0.269  0.250  1.0
  Mo  Mo5  1  0.731  0.731  0.750  1.0
  Pb  Pb6  1  0.090  0.506  0.250  1.0
  Pb  Pb7  1  0.494  0.910  0.750  1.0
  Pb  Pb8  1  0.910  0.494  0.750  1.0
  Pb  Pb9  1  0.506  0.090  0.250  1.0
  Pb  Pb10  1  0.866  0.655  0.407  1.0
  Pb  Pb11  1  0.345  0.134  0.593  1.0
  Pb  Pb12  1  0.866  0.655  0.093  1.0
  Pb  Pb13  1  0.345  0.134  0.907  1.0
  Pb  Pb14  1  0.134  0.345  0.593  1.0
  Pb  Pb15  1  0.655  0.866  0.407  1.0
  Pb  Pb16  1  0.134  0.345  0.907  1.0
  Pb  Pb17  1  0.655  0.866  0.093  1.0
  O  O18  1  0.159  0.725  0.404  1.0
  O  O19  1  0.275  0.841  0.596  1.0
  O  O20  1  0.159  0.725  0.096  1.0
  O  O21  1  0.275  0.841  0.904  1.0
  O  O22  1  0.841  0.275  0.596  1.0
  O  O23  1  0.725  0.159  0.404  1.0
  O  O24  1  0.841  0.275  0.904  1.0
  O  O25  1  0.725  0.159  0.096  1.0
  O  O26  1  0.671  0.329  0.500  1.0
  O  O27  1  0.671  0.329  0.000  1.0
  O  O28  1  0.329  0.671  0.500  1.0
  O  O29  1  0.329  0.671  0.000  1.0
  O  O30  1  0.779  0.480  0.250  1.0
  O  O31  1  0.520  0.221  0.750  1.0
  O  O32  1  0.221  0.520  0.750  1.0
  O  O33  1  0.480  0.779  0.250  1.0
  O  O34  1  0.177  0.023  0.250  1.0
  O  O35  1  0.977  0.823  0.750  1.0
  O  O36  1  0.823  0.977  0.750  1.0
  O  O37  1  0.023  0.177  0.250  1.0
  O  O38  1  0.430  0.430  0.372  1.0
  O  O39  1  0.570  0.570  0.628  1.0
  O  O40  1  0.430  0.430  0.128  1.0
  O  O41  1  0.570  0.570  0.872  1.0
[/CIF]
.