The material described by RhF6 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four rhodium hexafluoride molecules. Rh(1) is bonded in an octahedral geometry to three equivalent F(1,4) and three equivalent F(2,3) atoms. There are two inequivalent F sites. In the first F site, F(2,3) is bonded in a single-bond geometry to one Rh(1) atom. In the second F site, F(1,4) is bonded in a single-bond geometry to one Rh(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RhF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.865
_cell_length_b   8.424
_cell_length_c   9.183
_cell_angle_alpha   90.000
_cell_angle_beta   90.001
_cell_angle_gamma   89.999
_symmetry_Int_Tables_number   1
_cell_volume   376.322
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.918  0.750  0.629  1.0
  Rh  Rh1  1  0.082  0.250  0.371  1.0
  Rh  Rh2  1  0.418  0.250  0.871  1.0
  Rh  Rh3  1  0.582  0.750  0.129  1.0
  F  F4  1  0.222  0.750  0.511  1.0
  F  F5  1  0.778  0.250  0.489  1.0
  F  F6  1  0.722  0.250  0.989  1.0
  F  F7  1  0.278  0.750  0.011  1.0
  F  F8  1  0.612  0.750  0.747  1.0
  F  F9  1  0.388  0.250  0.253  1.0
  F  F10  1  0.112  0.250  0.753  1.0
  F  F11  1  0.888  0.750  0.247  1.0
  F  F12  1  0.759  0.596  0.515  1.0
  F  F13  1  0.241  0.404  0.485  1.0
  F  F14  1  0.259  0.404  0.985  1.0
  F  F15  1  0.241  0.096  0.485  1.0
  F  F16  1  0.741  0.596  0.015  1.0
  F  F17  1  0.759  0.904  0.515  1.0
  F  F18  1  0.741  0.904  0.015  1.0
  F  F19  1  0.259  0.096  0.985  1.0
  F  F20  1  0.074  0.596  0.744  1.0
  F  F21  1  0.926  0.404  0.256  1.0
  F  F22  1  0.574  0.404  0.756  1.0
  F  F23  1  0.926  0.096  0.256  1.0
  F  F24  1  0.426  0.596  0.244  1.0
  F  F25  1  0.074  0.904  0.744  1.0
  F  F26  1  0.426  0.904  0.244  1.0
  F  F27  1  0.574  0.096  0.756  1.0
[/CIF]
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The material described by RhF6 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four rhodium hexafluoride molecules. Rh(1) is bonded in an octahedral geometry to three equivalent F(1,4) and three equivalent F(2,3) atoms. There are two inequivalent F sites. In the first F site, F(2,3) is bonded in a single-bond geometry to one Rh(1) atom. In the second F site, F(1,4) is bonded in a single-bond geometry to one Rh(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RhF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.865
_cell_length_b   8.424
_cell_length_c   9.183
_cell_angle_alpha   90.000
_cell_angle_beta   90.001
_cell_angle_gamma   89.999
_symmetry_Int_Tables_number   1
_cell_volume   376.322
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.918  0.750  0.629  1.0
  Rh  Rh1  1  0.082  0.250  0.371  1.0
  Rh  Rh2  1  0.418  0.250  0.871  1.0
  Rh  Rh3  1  0.582  0.750  0.129  1.0
  F  F4  1  0.222  0.750  0.511  1.0
  F  F5  1  0.778  0.250  0.489  1.0
  F  F6  1  0.722  0.250  0.989  1.0
  F  F7  1  0.278  0.750  0.011  1.0
  F  F8  1  0.612  0.750  0.747  1.0
  F  F9  1  0.388  0.250  0.253  1.0
  F  F10  1  0.112  0.250  0.753  1.0
  F  F11  1  0.888  0.750  0.247  1.0
  F  F12  1  0.759  0.596  0.515  1.0
  F  F13  1  0.241  0.404  0.485  1.0
  F  F14  1  0.259  0.404  0.985  1.0
  F  F15  1  0.241  0.096  0.485  1.0
  F  F16  1  0.741  0.596  0.015  1.0
  F  F17  1  0.759  0.904  0.515  1.0
  F  F18  1  0.741  0.904  0.015  1.0
  F  F19  1  0.259  0.096  0.985  1.0
  F  F20  1  0.074  0.596  0.744  1.0
  F  F21  1  0.926  0.404  0.256  1.0
  F  F22  1  0.574  0.404  0.756  1.0
  F  F23  1  0.926  0.096  0.256  1.0
  F  F24  1  0.426  0.596  0.244  1.0
  F  F25  1  0.074  0.904  0.744  1.0
  F  F26  1  0.426  0.904  0.244  1.0
  F  F27  1  0.574  0.096  0.756  1.0
[/CIF]
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