The material structure described by CrOF4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight CrOF4 clusters. Cr(1) is bonded in a distorted trigonal bipyramidal geometry to one O(2), one F(2), one F(3), one F(4), and one F(8) atom. O(2) is bonded in a single-bond geometry to one Cr(1) atom. There are four inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Cr(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Cr(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one Cr(1) atom. In the fourth F site, F(8) is bonded in a single-bond geometry to one Cr(1) atom. is represented by the CIF card [CIF]
data_CrOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.888
_cell_length_b   5.548
_cell_length_c   8.063
_cell_angle_alpha   89.139
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   755.440
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.142  0.731  0.991  1.0
  Cr  Cr1  1  0.611  0.749  0.908  1.0
  Cr  Cr2  1  0.358  0.731  0.491  1.0
  Cr  Cr3  1  0.889  0.749  0.408  1.0
  Cr  Cr4  1  0.111  0.251  0.592  1.0
  Cr  Cr5  1  0.642  0.269  0.509  1.0
  Cr  Cr6  1  0.389  0.251  0.092  1.0
  Cr  Cr7  1  0.858  0.269  0.009  1.0
  O  O8  1  0.921  0.901  0.555  1.0
  O  O9  1  0.579  0.901  0.055  1.0
  O  O10  1  0.364  0.564  0.648  1.0
  O  O11  1  0.136  0.564  0.148  1.0
  O  O12  1  0.864  0.436  0.852  1.0
  O  O13  1  0.636  0.436  0.352  1.0
  O  O14  1  0.421  0.099  0.945  1.0
  O  O15  1  0.079  0.099  0.445  1.0
  F  F16  1  0.651  0.975  0.771  1.0
  F  F17  1  0.849  0.975  0.271  1.0
  F  F18  1  0.872  0.981  0.926  1.0
  F  F19  1  0.628  0.981  0.426  1.0
  F  F20  1  0.243  0.803  0.970  1.0
  F  F21  1  0.257  0.803  0.470  1.0
  F  F22  1  0.045  0.746  0.915  1.0
  F  F23  1  0.530  0.736  0.771  1.0
  F  F24  1  0.455  0.746  0.415  1.0
  F  F25  1  0.970  0.736  0.271  1.0
  F  F26  1  0.710  0.690  0.962  1.0
  F  F27  1  0.790  0.690  0.462  1.0
  F  F28  1  0.089  0.547  0.528  1.0
  F  F29  1  0.411  0.547  0.028  1.0
  F  F30  1  0.160  0.518  0.831  1.0
  F  F31  1  0.660  0.482  0.669  1.0
  F  F32  1  0.340  0.518  0.331  1.0
  F  F33  1  0.840  0.482  0.169  1.0
  F  F34  1  0.589  0.453  0.972  1.0
  F  F35  1  0.911  0.453  0.472  1.0
  F  F36  1  0.210  0.310  0.538  1.0
  F  F37  1  0.290  0.310  0.038  1.0
  F  F38  1  0.030  0.264  0.729  1.0
  F  F39  1  0.545  0.254  0.585  1.0
  F  F40  1  0.470  0.264  0.229  1.0
  F  F41  1  0.955  0.254  0.085  1.0
  F  F42  1  0.743  0.197  0.530  1.0
  F  F43  1  0.757  0.197  0.030  1.0
  F  F44  1  0.372  0.019  0.574  1.0
  F  F45  1  0.128  0.019  0.074  1.0
  F  F46  1  0.151  0.025  0.729  1.0
  F  F47  1  0.349  0.025  0.229  1.0
[/CIF]
.
The material structure described by CrOF4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight CrOF4 clusters. Cr(1) is bonded in a distorted trigonal bipyramidal geometry to one O(2), one F(2), one F(3), one F(4), and one F(8) atom. O(2) is bonded in a single-bond geometry to one Cr(1) atom. There are four inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Cr(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Cr(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one Cr(1) atom. In the fourth F site, F(8) is bonded in a single-bond geometry to one Cr(1) atom. is represented by the CIF card [CIF]
data_CrOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.888
_cell_length_b   5.548
_cell_length_c   8.063
_cell_angle_alpha   89.139
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   755.440
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.142  0.731  0.991  1.0
  Cr  Cr1  1  0.611  0.749  0.908  1.0
  Cr  Cr2  1  0.358  0.731  0.491  1.0
  Cr  Cr3  1  0.889  0.749  0.408  1.0
  Cr  Cr4  1  0.111  0.251  0.592  1.0
  Cr  Cr5  1  0.642  0.269  0.509  1.0
  Cr  Cr6  1  0.389  0.251  0.092  1.0
  Cr  Cr7  1  0.858  0.269  0.009  1.0
  O  O8  1  0.921  0.901  0.555  1.0
  O  O9  1  0.579  0.901  0.055  1.0
  O  O10  1  0.364  0.564  0.648  1.0
  O  O11  1  0.136  0.564  0.148  1.0
  O  O12  1  0.864  0.436  0.852  1.0
  O  O13  1  0.636  0.436  0.352  1.0
  O  O14  1  0.421  0.099  0.945  1.0
  O  O15  1  0.079  0.099  0.445  1.0
  F  F16  1  0.651  0.975  0.771  1.0
  F  F17  1  0.849  0.975  0.271  1.0
  F  F18  1  0.872  0.981  0.926  1.0
  F  F19  1  0.628  0.981  0.426  1.0
  F  F20  1  0.243  0.803  0.970  1.0
  F  F21  1  0.257  0.803  0.470  1.0
  F  F22  1  0.045  0.746  0.915  1.0
  F  F23  1  0.530  0.736  0.771  1.0
  F  F24  1  0.455  0.746  0.415  1.0
  F  F25  1  0.970  0.736  0.271  1.0
  F  F26  1  0.710  0.690  0.962  1.0
  F  F27  1  0.790  0.690  0.462  1.0
  F  F28  1  0.089  0.547  0.528  1.0
  F  F29  1  0.411  0.547  0.028  1.0
  F  F30  1  0.160  0.518  0.831  1.0
  F  F31  1  0.660  0.482  0.669  1.0
  F  F32  1  0.340  0.518  0.331  1.0
  F  F33  1  0.840  0.482  0.169  1.0
  F  F34  1  0.589  0.453  0.972  1.0
  F  F35  1  0.911  0.453  0.472  1.0
  F  F36  1  0.210  0.310  0.538  1.0
  F  F37  1  0.290  0.310  0.038  1.0
  F  F38  1  0.030  0.264  0.729  1.0
  F  F39  1  0.545  0.254  0.585  1.0
  F  F40  1  0.470  0.264  0.229  1.0
  F  F41  1  0.955  0.254  0.085  1.0
  F  F42  1  0.743  0.197  0.530  1.0
  F  F43  1  0.757  0.197  0.030  1.0
  F  F44  1  0.372  0.019  0.574  1.0
  F  F45  1  0.128  0.019  0.074  1.0
  F  F46  1  0.151  0.025  0.729  1.0
  F  F47  1  0.349  0.025  0.229  1.0
[/CIF]
.