The compound described by RhF5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two RhF5 clusters. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form corner-sharing RhF6 octahedra. The corner-sharing octahedral tilt angles are 48°. In the second Rh site, Rh(2) is bonded to one F(10), one F(5), one F(6), one F(7), one F(8), and one F(9) atom to form corner-sharing RhF6 octahedra. The corner-sharing octahedral tilt angles are 48°. There are ten inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Rh(2) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Rh(2) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Rh(1) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one Rh(2) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one Rh(1) atom. In the sixth F site, F(10) is bonded in a single-bond geometry to one Rh(2) atom. In the seventh F site, F(3) is bonded in a single-bond geometry to one Rh(1) atom. In the eighth F site, F(4) is bonded in a single-bond geometry to one Rh(1) atom. In the ninth F site, F(5) is bonded in a bent 120 degrees geometry to one Rh(1) and one Rh(2) atom. In the tenth F site, F(6) is bonded in a bent 120 degrees geometry to one Rh(1) and one Rh(2) atom. is represented by the CIF file [CIF]
data_RhF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.734
_cell_length_b   5.409
_cell_length_c   12.090
_cell_angle_alpha   80.098
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   627.065
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.245  0.996  0.496  1.0
  Rh  Rh1  1  0.745  0.004  0.004  1.0
  Rh  Rh2  1  0.755  0.004  0.504  1.0
  Rh  Rh3  1  0.255  0.996  0.996  1.0
  Rh  Rh4  1  0.498  0.696  0.703  1.0
  Rh  Rh5  1  0.998  0.304  0.797  1.0
  Rh  Rh6  1  0.502  0.304  0.297  1.0
  Rh  Rh7  1  0.002  0.696  0.203  1.0
  F  F8  1  0.168  0.094  0.357  1.0
  F  F9  1  0.668  0.906  0.143  1.0
  F  F10  1  0.832  0.906  0.643  1.0
  F  F11  1  0.332  0.094  0.857  1.0
  F  F12  1  0.092  0.812  0.544  1.0
  F  F13  1  0.592  0.188  0.956  1.0
  F  F14  1  0.908  0.188  0.456  1.0
  F  F15  1  0.408  0.812  0.044  1.0
  F  F16  1  0.330  0.726  0.454  1.0
  F  F17  1  0.830  0.274  0.046  1.0
  F  F18  1  0.670  0.274  0.546  1.0
  F  F19  1  0.170  0.726  0.954  1.0
  F  F20  1  0.180  0.272  0.547  1.0
  F  F21  1  0.680  0.728  0.953  1.0
  F  F22  1  0.820  0.728  0.453  1.0
  F  F23  1  0.320  0.272  0.047  1.0
  F  F24  1  0.327  0.890  0.650  1.0
  F  F25  1  0.827  0.110  0.850  1.0
  F  F26  1  0.673  0.110  0.350  1.0
  F  F27  1  0.173  0.890  0.150  1.0
  F  F28  1  0.415  0.195  0.449  1.0
  F  F29  1  0.915  0.805  0.051  1.0
  F  F30  1  0.585  0.805  0.551  1.0
  F  F31  1  0.085  0.195  0.949  1.0
  F  F32  1  0.653  0.518  0.753  1.0
  F  F33  1  0.153  0.482  0.747  1.0
  F  F34  1  0.347  0.482  0.247  1.0
  F  F35  1  0.847  0.518  0.253  1.0
  F  F36  1  0.426  0.432  0.647  1.0
  F  F37  1  0.926  0.568  0.853  1.0
  F  F38  1  0.574  0.568  0.353  1.0
  F  F39  1  0.074  0.432  0.147  1.0
  F  F40  1  0.415  0.601  0.839  1.0
  F  F41  1  0.915  0.399  0.661  1.0
  F  F42  1  0.585  0.399  0.161  1.0
  F  F43  1  0.085  0.601  0.339  1.0
  F  F44  1  0.566  0.984  0.741  1.0
  F  F45  1  0.066  0.016  0.759  1.0
  F  F46  1  0.434  0.016  0.259  1.0
  F  F47  1  0.934  0.984  0.241  1.0
[/CIF]
.
The compound described by RhF5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two RhF5 clusters. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form corner-sharing RhF6 octahedra. The corner-sharing octahedral tilt angles are 48°. In the second Rh site, Rh(2) is bonded to one F(10), one F(5), one F(6), one F(7), one F(8), and one F(9) atom to form corner-sharing RhF6 octahedra. The corner-sharing octahedral tilt angles are 48°. There are ten inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Rh(2) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Rh(2) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Rh(1) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one Rh(2) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one Rh(1) atom. In the sixth F site, F(10) is bonded in a single-bond geometry to one Rh(2) atom. In the seventh F site, F(3) is bonded in a single-bond geometry to one Rh(1) atom. In the eighth F site, F(4) is bonded in a single-bond geometry to one Rh(1) atom. In the ninth F site, F(5) is bonded in a bent 120 degrees geometry to one Rh(1) and one Rh(2) atom. In the tenth F site, F(6) is bonded in a bent 120 degrees geometry to one Rh(1) and one Rh(2) atom. is represented by the CIF file [CIF]
data_RhF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.734
_cell_length_b   5.409
_cell_length_c   12.090
_cell_angle_alpha   80.098
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   627.065
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.245  0.996  0.496  1.0
  Rh  Rh1  1  0.745  0.004  0.004  1.0
  Rh  Rh2  1  0.755  0.004  0.504  1.0
  Rh  Rh3  1  0.255  0.996  0.996  1.0
  Rh  Rh4  1  0.498  0.696  0.703  1.0
  Rh  Rh5  1  0.998  0.304  0.797  1.0
  Rh  Rh6  1  0.502  0.304  0.297  1.0
  Rh  Rh7  1  0.002  0.696  0.203  1.0
  F  F8  1  0.168  0.094  0.357  1.0
  F  F9  1  0.668  0.906  0.143  1.0
  F  F10  1  0.832  0.906  0.643  1.0
  F  F11  1  0.332  0.094  0.857  1.0
  F  F12  1  0.092  0.812  0.544  1.0
  F  F13  1  0.592  0.188  0.956  1.0
  F  F14  1  0.908  0.188  0.456  1.0
  F  F15  1  0.408  0.812  0.044  1.0
  F  F16  1  0.330  0.726  0.454  1.0
  F  F17  1  0.830  0.274  0.046  1.0
  F  F18  1  0.670  0.274  0.546  1.0
  F  F19  1  0.170  0.726  0.954  1.0
  F  F20  1  0.180  0.272  0.547  1.0
  F  F21  1  0.680  0.728  0.953  1.0
  F  F22  1  0.820  0.728  0.453  1.0
  F  F23  1  0.320  0.272  0.047  1.0
  F  F24  1  0.327  0.890  0.650  1.0
  F  F25  1  0.827  0.110  0.850  1.0
  F  F26  1  0.673  0.110  0.350  1.0
  F  F27  1  0.173  0.890  0.150  1.0
  F  F28  1  0.415  0.195  0.449  1.0
  F  F29  1  0.915  0.805  0.051  1.0
  F  F30  1  0.585  0.805  0.551  1.0
  F  F31  1  0.085  0.195  0.949  1.0
  F  F32  1  0.653  0.518  0.753  1.0
  F  F33  1  0.153  0.482  0.747  1.0
  F  F34  1  0.347  0.482  0.247  1.0
  F  F35  1  0.847  0.518  0.253  1.0
  F  F36  1  0.426  0.432  0.647  1.0
  F  F37  1  0.926  0.568  0.853  1.0
  F  F38  1  0.574  0.568  0.353  1.0
  F  F39  1  0.074  0.432  0.147  1.0
  F  F40  1  0.415  0.601  0.839  1.0
  F  F41  1  0.915  0.399  0.661  1.0
  F  F42  1  0.585  0.399  0.161  1.0
  F  F43  1  0.085  0.601  0.339  1.0
  F  F44  1  0.566  0.984  0.741  1.0
  F  F45  1  0.066  0.016  0.759  1.0
  F  F46  1  0.434  0.016  0.259  1.0
  F  F47  1  0.934  0.984  0.241  1.0
[/CIF]
.