The compound described by AgP(OF)2 crystallizes in the monoclinic C2/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), one O(4), and three equivalent O(3) atoms to form distorted AgO5 trigonal bipyramids that share  a cornercorner with one P(3)O2F2 tetrahedra, corners with four equivalent P(1)O2F2 tetrahedra,  a cornercorner with one Ag(2)O5 trigonal bipyramid, corners with two equivalent Ag(1)O5 trigonal bipyramids,  an edgeedge with one Ag(2)O5 trigonal bipyramid, and edges with two equivalent Ag(1)O5 trigonal bipyramids. In the second Ag site, Ag(2) is bonded to one O(4), two equivalent O(1), and two equivalent O(2) atoms to form distorted AgO5 trigonal bipyramids that share  a cornercorner with one P(1)O2F2 tetrahedra, corners with two equivalent P(2)O2F2 tetrahedra, corners with two equivalent P(3)O2F2 tetrahedra,  a cornercorner with one Ag(1)O5 trigonal bipyramid,  an edgeedge with one Ag(1)O5 trigonal bipyramid, and edges with two equivalent Ag(2)O5 trigonal bipyramids. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(3), one O(4), one F(2), and one F(3) atom to form PO2F2 tetrahedra that share  a cornercorner with one Ag(2)O5 trigonal bipyramid and corners with four equivalent Ag(1)O5 trigonal bipyramids. In the second P site, P(2) is bonded to two equivalent O(2) and two equivalent F(1) atoms to form PO2F2 tetrahedra that share corners with four equivalent Ag(2)O5 trigonal bipyramids. In the third P site, P(3) is bonded to two equivalent O(1) and two equivalent F(4) atoms to form PO2F2 tetrahedra that share corners with two equivalent Ag(1)O5 trigonal bipyramids and corners with four equivalent Ag(2)O5 trigonal bipyramids. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1), two equivalent Ag(2), and one P(3) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and one P(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Ag(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one P(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgP(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.771
_cell_length_b   13.771
_cell_length_c   6.341
_cell_angle_alpha   79.859
_cell_angle_beta   79.859
_cell_angle_gamma   130.775
_symmetry_Int_Tables_number   1
_cell_volume   825.228
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.976  0.851  0.566  1.0
  Ag  Ag1  1  0.149  0.024  0.934  1.0
  Ag  Ag2  1  0.024  0.149  0.434  1.0
  Ag  Ag3  1  0.851  0.976  0.066  1.0
  Ag  Ag4  1  0.025  0.647  0.379  1.0
  Ag  Ag5  1  0.353  0.975  0.121  1.0
  Ag  Ag6  1  0.975  0.353  0.621  1.0
  Ag  Ag7  1  0.647  0.025  0.879  1.0
  P  P8  1  0.830  0.694  0.200  1.0
  P  P9  1  0.306  0.170  0.300  1.0
  P  P10  1  0.170  0.306  0.800  1.0
  P  P11  1  0.694  0.830  0.700  1.0
  P  P12  1  0.314  0.686  0.250  1.0
  P  P13  1  0.686  0.314  0.750  1.0
  P  P14  1  0.811  0.189  0.250  1.0
  P  P15  1  0.189  0.811  0.750  1.0
  O  O16  1  0.145  0.827  0.556  1.0
  O  O17  1  0.173  0.855  0.944  1.0
  O  O18  1  0.855  0.173  0.444  1.0
  O  O19  1  0.827  0.145  0.056  1.0
  O  O20  1  0.160  0.594  0.372  1.0
  O  O21  1  0.406  0.840  0.128  1.0
  O  O22  1  0.840  0.406  0.628  1.0
  O  O23  1  0.594  0.160  0.872  1.0
  O  O24  1  0.908  0.832  0.010  1.0
  O  O25  1  0.168  0.092  0.490  1.0
  O  O26  1  0.092  0.168  0.990  1.0
  O  O27  1  0.832  0.908  0.510  1.0
  O  O28  1  0.873  0.688  0.400  1.0
  O  O29  1  0.312  0.127  0.100  1.0
  O  O30  1  0.127  0.312  0.600  1.0
  O  O31  1  0.688  0.873  0.900  1.0
  F  F32  1  0.340  0.630  0.076  1.0
  F  F33  1  0.370  0.660  0.424  1.0
  F  F34  1  0.660  0.370  0.924  1.0
  F  F35  1  0.630  0.340  0.576  1.0
  F  F36  1  0.827  0.601  0.083  1.0
  F  F37  1  0.399  0.173  0.417  1.0
  F  F38  1  0.173  0.399  0.917  1.0
  F  F39  1  0.601  0.827  0.583  1.0
  F  F40  1  0.672  0.609  0.294  1.0
  F  F41  1  0.391  0.328  0.206  1.0
  F  F42  1  0.328  0.391  0.706  1.0
  F  F43  1  0.609  0.672  0.794  1.0
  F  F44  1  0.885  0.344  0.138  1.0
  F  F45  1  0.656  0.115  0.362  1.0
  F  F46  1  0.115  0.656  0.862  1.0
  F  F47  1  0.344  0.885  0.638  1.0
[/CIF]
.
The compound described by AgP(OF)2 crystallizes in the monoclinic C2/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one O(1), one O(4), and three equivalent O(3) atoms to form distorted AgO5 trigonal bipyramids that share  a cornercorner with one P(3)O2F2 tetrahedra, corners with four equivalent P(1)O2F2 tetrahedra,  a cornercorner with one Ag(2)O5 trigonal bipyramid, corners with two equivalent Ag(1)O5 trigonal bipyramids,  an edgeedge with one Ag(2)O5 trigonal bipyramid, and edges with two equivalent Ag(1)O5 trigonal bipyramids. In the second Ag site, Ag(2) is bonded to one O(4), two equivalent O(1), and two equivalent O(2) atoms to form distorted AgO5 trigonal bipyramids that share  a cornercorner with one P(1)O2F2 tetrahedra, corners with two equivalent P(2)O2F2 tetrahedra, corners with two equivalent P(3)O2F2 tetrahedra,  a cornercorner with one Ag(1)O5 trigonal bipyramid,  an edgeedge with one Ag(1)O5 trigonal bipyramid, and edges with two equivalent Ag(2)O5 trigonal bipyramids. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(3), one O(4), one F(2), and one F(3) atom to form PO2F2 tetrahedra that share  a cornercorner with one Ag(2)O5 trigonal bipyramid and corners with four equivalent Ag(1)O5 trigonal bipyramids. In the second P site, P(2) is bonded to two equivalent O(2) and two equivalent F(1) atoms to form PO2F2 tetrahedra that share corners with four equivalent Ag(2)O5 trigonal bipyramids. In the third P site, P(3) is bonded to two equivalent O(1) and two equivalent F(4) atoms to form PO2F2 tetrahedra that share corners with two equivalent Ag(1)O5 trigonal bipyramids and corners with four equivalent Ag(2)O5 trigonal bipyramids. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1), two equivalent Ag(2), and one P(3) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Ag(2) and one P(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Ag(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one P(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgP(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.771
_cell_length_b   13.771
_cell_length_c   6.341
_cell_angle_alpha   79.859
_cell_angle_beta   79.859
_cell_angle_gamma   130.775
_symmetry_Int_Tables_number   1
_cell_volume   825.228
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.976  0.851  0.566  1.0
  Ag  Ag1  1  0.149  0.024  0.934  1.0
  Ag  Ag2  1  0.024  0.149  0.434  1.0
  Ag  Ag3  1  0.851  0.976  0.066  1.0
  Ag  Ag4  1  0.025  0.647  0.379  1.0
  Ag  Ag5  1  0.353  0.975  0.121  1.0
  Ag  Ag6  1  0.975  0.353  0.621  1.0
  Ag  Ag7  1  0.647  0.025  0.879  1.0
  P  P8  1  0.830  0.694  0.200  1.0
  P  P9  1  0.306  0.170  0.300  1.0
  P  P10  1  0.170  0.306  0.800  1.0
  P  P11  1  0.694  0.830  0.700  1.0
  P  P12  1  0.314  0.686  0.250  1.0
  P  P13  1  0.686  0.314  0.750  1.0
  P  P14  1  0.811  0.189  0.250  1.0
  P  P15  1  0.189  0.811  0.750  1.0
  O  O16  1  0.145  0.827  0.556  1.0
  O  O17  1  0.173  0.855  0.944  1.0
  O  O18  1  0.855  0.173  0.444  1.0
  O  O19  1  0.827  0.145  0.056  1.0
  O  O20  1  0.160  0.594  0.372  1.0
  O  O21  1  0.406  0.840  0.128  1.0
  O  O22  1  0.840  0.406  0.628  1.0
  O  O23  1  0.594  0.160  0.872  1.0
  O  O24  1  0.908  0.832  0.010  1.0
  O  O25  1  0.168  0.092  0.490  1.0
  O  O26  1  0.092  0.168  0.990  1.0
  O  O27  1  0.832  0.908  0.510  1.0
  O  O28  1  0.873  0.688  0.400  1.0
  O  O29  1  0.312  0.127  0.100  1.0
  O  O30  1  0.127  0.312  0.600  1.0
  O  O31  1  0.688  0.873  0.900  1.0
  F  F32  1  0.340  0.630  0.076  1.0
  F  F33  1  0.370  0.660  0.424  1.0
  F  F34  1  0.660  0.370  0.924  1.0
  F  F35  1  0.630  0.340  0.576  1.0
  F  F36  1  0.827  0.601  0.083  1.0
  F  F37  1  0.399  0.173  0.417  1.0
  F  F38  1  0.173  0.399  0.917  1.0
  F  F39  1  0.601  0.827  0.583  1.0
  F  F40  1  0.672  0.609  0.294  1.0
  F  F41  1  0.391  0.328  0.206  1.0
  F  F42  1  0.328  0.391  0.706  1.0
  F  F43  1  0.609  0.672  0.794  1.0
  F  F44  1  0.885  0.344  0.138  1.0
  F  F45  1  0.656  0.115  0.362  1.0
  F  F46  1  0.115  0.656  0.862  1.0
  F  F47  1  0.344  0.885  0.638  1.0
[/CIF]
.