The compound described by HPF4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tetrafluorophosphanium molecules. P(1) is bonded in a distorted trigonal bipyramidal geometry to one H(1), one F(1), one F(2), one F(3), and one F(4) atom. H(1) is bonded in a single-bond geometry to one P(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_PHF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.803
_cell_length_b   4.453
_cell_length_c   9.430
_cell_angle_alpha   62.811
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   291.495
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.284  0.683  0.327  1.0
  P  P1  1  0.784  0.317  0.173  1.0
  P  P2  1  0.716  0.317  0.673  1.0
  P  P3  1  0.216  0.683  0.827  1.0
  H  H4  1  0.388  0.843  0.389  1.0
  H  H5  1  0.888  0.157  0.111  1.0
  H  H6  1  0.612  0.157  0.611  1.0
  H  H7  1  0.112  0.843  0.889  1.0
  F  F8  1  0.348  0.998  0.766  1.0
  F  F9  1  0.848  0.002  0.734  1.0
  F  F10  1  0.652  0.002  0.234  1.0
  F  F11  1  0.152  0.998  0.266  1.0
  F  F12  1  0.080  0.373  0.886  1.0
  F  F13  1  0.580  0.627  0.614  1.0
  F  F14  1  0.920  0.627  0.114  1.0
  F  F15  1  0.420  0.373  0.386  1.0
  F  F16  1  0.200  0.731  0.654  1.0
  F  F17  1  0.700  0.269  0.846  1.0
  F  F18  1  0.800  0.269  0.346  1.0
  F  F19  1  0.300  0.731  0.154  1.0
  F  F20  1  0.359  0.438  0.926  1.0
  F  F21  1  0.859  0.562  0.574  1.0
  F  F22  1  0.641  0.562  0.074  1.0
  F  F23  1  0.141  0.438  0.426  1.0
[/CIF]
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The compound described by HPF4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tetrafluorophosphanium molecules. P(1) is bonded in a distorted trigonal bipyramidal geometry to one H(1), one F(1), one F(2), one F(3), and one F(4) atom. H(1) is bonded in a single-bond geometry to one P(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_PHF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.803
_cell_length_b   4.453
_cell_length_c   9.430
_cell_angle_alpha   62.811
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   291.495
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.284  0.683  0.327  1.0
  P  P1  1  0.784  0.317  0.173  1.0
  P  P2  1  0.716  0.317  0.673  1.0
  P  P3  1  0.216  0.683  0.827  1.0
  H  H4  1  0.388  0.843  0.389  1.0
  H  H5  1  0.888  0.157  0.111  1.0
  H  H6  1  0.612  0.157  0.611  1.0
  H  H7  1  0.112  0.843  0.889  1.0
  F  F8  1  0.348  0.998  0.766  1.0
  F  F9  1  0.848  0.002  0.734  1.0
  F  F10  1  0.652  0.002  0.234  1.0
  F  F11  1  0.152  0.998  0.266  1.0
  F  F12  1  0.080  0.373  0.886  1.0
  F  F13  1  0.580  0.627  0.614  1.0
  F  F14  1  0.920  0.627  0.114  1.0
  F  F15  1  0.420  0.373  0.386  1.0
  F  F16  1  0.200  0.731  0.654  1.0
  F  F17  1  0.700  0.269  0.846  1.0
  F  F18  1  0.800  0.269  0.346  1.0
  F  F19  1  0.300  0.731  0.154  1.0
  F  F20  1  0.359  0.438  0.926  1.0
  F  F21  1  0.859  0.562  0.574  1.0
  F  F22  1  0.641  0.562  0.074  1.0
  F  F23  1  0.141  0.438  0.426  1.0
[/CIF]
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