The crystal structure described by Sb3O4F crystallizes in the monoclinic P2/c space group. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a rectangular see-saw-like geometry to one O(2), two equivalent O(1), and one F(1) atom. In the second Sb site, Sb(2) is bonded in a rectangular see-saw-like geometry to four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Sb(1) and two equivalent Sb(2) atoms. F(1) is bonded in a water-like geometry to two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_Sb3O4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.367
_cell_length_b   5.670
_cell_length_c   9.470
_cell_angle_alpha   87.585
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   287.959
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.707  0.180  0.190  1.0
  Sb  Sb1  1  0.293  0.680  0.190  1.0
  Sb  Sb2  1  0.176  0.250  0.500  1.0
  Sb  Sb3  1  0.824  0.750  0.500  1.0
  Sb  Sb4  1  0.707  0.320  0.810  1.0
  Sb  Sb5  1  0.293  0.820  0.810  1.0
  O  O6  1  0.544  0.457  0.274  1.0
  O  O7  1  0.456  0.957  0.274  1.0
  O  O8  1  0.910  0.094  0.379  1.0
  O  O9  1  0.090  0.594  0.379  1.0
  O  O10  1  0.910  0.406  0.621  1.0
  O  O11  1  0.090  0.906  0.621  1.0
  O  O12  1  0.544  0.043  0.726  1.0
  O  O13  1  0.456  0.543  0.726  1.0
  F  F14  1  0.425  0.250  0.000  1.0
  F  F15  1  0.575  0.750  0.000  1.0
[/CIF]
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The crystal structure described by Sb3O4F crystallizes in the monoclinic P2/c space group. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a rectangular see-saw-like geometry to one O(2), two equivalent O(1), and one F(1) atom. In the second Sb site, Sb(2) is bonded in a rectangular see-saw-like geometry to four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Sb(1) and two equivalent Sb(2) atoms. F(1) is bonded in a water-like geometry to two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_Sb3O4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.367
_cell_length_b   5.670
_cell_length_c   9.470
_cell_angle_alpha   87.585
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   287.959
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.707  0.180  0.190  1.0
  Sb  Sb1  1  0.293  0.680  0.190  1.0
  Sb  Sb2  1  0.176  0.250  0.500  1.0
  Sb  Sb3  1  0.824  0.750  0.500  1.0
  Sb  Sb4  1  0.707  0.320  0.810  1.0
  Sb  Sb5  1  0.293  0.820  0.810  1.0
  O  O6  1  0.544  0.457  0.274  1.0
  O  O7  1  0.456  0.957  0.274  1.0
  O  O8  1  0.910  0.094  0.379  1.0
  O  O9  1  0.090  0.594  0.379  1.0
  O  O10  1  0.910  0.406  0.621  1.0
  O  O11  1  0.090  0.906  0.621  1.0
  O  O12  1  0.544  0.043  0.726  1.0
  O  O13  1  0.456  0.543  0.726  1.0
  F  F14  1  0.425  0.250  0.000  1.0
  F  F15  1  0.575  0.750  0.000  1.0
[/CIF]
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