The crystal structure described by CoVO4 crystallizes in the orthorhombic Pnma space group. V(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form VO4 tetrahedra that share corners with four equivalent Co(1)O6 octahedra and  an edgeedge with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-61°. Co(1) is bonded to one O(2), one O(3), and four equivalent O(1) atoms to form CoO6 octahedra that share corners with four equivalent Co(1)O6 octahedra, corners with four equivalent V(1)O4 tetrahedra, and  an edgeedge with one V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 45°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Co(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one Co(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(1) and one Co(1) atom. is represented by the CIF card [CIF]
data_VCoO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.627
_cell_length_b   5.562
_cell_length_c   10.447
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   268.817
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.414  0.250  0.413  1.0
  V  V1  1  0.086  0.250  0.913  1.0
  V  V2  1  0.914  0.750  0.087  1.0
  V  V3  1  0.586  0.750  0.587  1.0
  Co  Co4  1  0.982  0.250  0.239  1.0
  Co  Co5  1  0.518  0.250  0.739  1.0
  Co  Co6  1  0.482  0.750  0.261  1.0
  Co  Co7  1  0.018  0.750  0.761  1.0
  O  O8  1  0.247  0.011  0.322  1.0
  O  O9  1  0.253  0.011  0.822  1.0
  O  O10  1  0.162  0.250  0.074  1.0
  O  O11  1  0.778  0.250  0.393  1.0
  O  O12  1  0.722  0.250  0.893  1.0
  O  O13  1  0.338  0.250  0.574  1.0
  O  O14  1  0.247  0.489  0.322  1.0
  O  O15  1  0.253  0.489  0.822  1.0
  O  O16  1  0.753  0.511  0.678  1.0
  O  O17  1  0.747  0.511  0.178  1.0
  O  O18  1  0.838  0.750  0.926  1.0
  O  O19  1  0.662  0.750  0.426  1.0
  O  O20  1  0.278  0.750  0.107  1.0
  O  O21  1  0.222  0.750  0.607  1.0
  O  O22  1  0.747  0.989  0.178  1.0
  O  O23  1  0.753  0.989  0.678  1.0
[/CIF]
.
The crystal structure described by CoVO4 crystallizes in the orthorhombic Pnma space group. V(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form VO4 tetrahedra that share corners with four equivalent Co(1)O6 octahedra and  an edgeedge with one Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-61°. Co(1) is bonded to one O(2), one O(3), and four equivalent O(1) atoms to form CoO6 octahedra that share corners with four equivalent Co(1)O6 octahedra, corners with four equivalent V(1)O4 tetrahedra, and  an edgeedge with one V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 45°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Co(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one Co(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(1) and one Co(1) atom. is represented by the CIF card [CIF]
data_VCoO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.627
_cell_length_b   5.562
_cell_length_c   10.447
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   268.817
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.414  0.250  0.413  1.0
  V  V1  1  0.086  0.250  0.913  1.0
  V  V2  1  0.914  0.750  0.087  1.0
  V  V3  1  0.586  0.750  0.587  1.0
  Co  Co4  1  0.982  0.250  0.239  1.0
  Co  Co5  1  0.518  0.250  0.739  1.0
  Co  Co6  1  0.482  0.750  0.261  1.0
  Co  Co7  1  0.018  0.750  0.761  1.0
  O  O8  1  0.247  0.011  0.322  1.0
  O  O9  1  0.253  0.011  0.822  1.0
  O  O10  1  0.162  0.250  0.074  1.0
  O  O11  1  0.778  0.250  0.393  1.0
  O  O12  1  0.722  0.250  0.893  1.0
  O  O13  1  0.338  0.250  0.574  1.0
  O  O14  1  0.247  0.489  0.322  1.0
  O  O15  1  0.253  0.489  0.822  1.0
  O  O16  1  0.753  0.511  0.678  1.0
  O  O17  1  0.747  0.511  0.178  1.0
  O  O18  1  0.838  0.750  0.926  1.0
  O  O19  1  0.662  0.750  0.426  1.0
  O  O20  1  0.278  0.750  0.107  1.0
  O  O21  1  0.222  0.750  0.607  1.0
  O  O22  1  0.747  0.989  0.178  1.0
  O  O23  1  0.753  0.989  0.678  1.0
[/CIF]
.