The crystal structure described by Li7V(O2F)2 crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(5), one F(1), one F(2), and one F(4) atom. In the second Li site, Li(2) is bonded in a distorted L-shaped geometry to one O(1), one O(4), one O(7), and one O(8) atom. In the third Li site, Li(3) is bonded in a 2-coordinate geometry to one O(6), one F(1), and one F(4) atom. In the fourth Li site, Li(4) is bonded in a 3-coordinate geometry to one O(2), one O(5), and one F(2) atom. In the fifth Li site, Li(5) is bonded in a 4-coordinate geometry to one O(3), one O(6), one O(8), one F(1), and one F(2) atom. In the sixth Li site, Li(6) is bonded in a 3-coordinate geometry to one O(4), one O(5), and one F(3) atom. In the seventh Li site, Li(7) is bonded in a 2-coordinate geometry to one O(4), one O(7), and one O(8) atom. In the eighth Li site, Li(8) is bonded in a 4-coordinate geometry to one O(2), one O(4), one O(5), and one F(4) atom. In the ninth Li site, Li(9) is bonded in a 2-coordinate geometry to one O(3), one O(8), and one F(1) atom. In the tenth Li site, Li(10) is bonded in a 1-coordinate geometry to one O(4) and one F(3) atom. In the eleventh Li site, Li(11) is bonded in a 2-coordinate geometry to one O(3) and one O(8) atom. In the twelfth Li site, Li(12) is bonded in a 4-coordinate geometry to one O(5), one F(1), one F(2), and one F(4) atom. In the thirteenth Li site, Li(13) is bonded in a 2-coordinate geometry to one O(1), one O(4), one O(7), and one O(8) atom. In the fourteenth Li site, Li(14) is bonded in a 2-coordinate geometry to one O(1), one O(4), and one O(8) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 2-coordinate geometry to one O(2), one O(4), one O(5), and one F(3) atom. In the second V site, V(2) is bonded in a 2-coordinate geometry to one O(3), one O(6), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(13), one Li(14), and one Li(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(4), one Li(8), and one V(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(11), one Li(5), one Li(9), and one V(2) atom. In the fourth O site, O(4) is bonded in a 8-coordinate geometry to one Li(10), one Li(13), one Li(14), one Li(2), one Li(6), one Li(7), one Li(8), and one V(1) atom. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to one Li(1), one Li(12), one Li(4), one Li(6), one Li(8), and one V(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(3), one Li(5), and one V(2) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Li(13), one Li(2), and one Li(7) atom. In the eighth O site, O(8) is bonded in a 8-coordinate geometry to one Li(11), one Li(13), one Li(14), one Li(2), one Li(5), one Li(7), one Li(9), and one V(2) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a 5-coordinate geometry to one Li(1), one Li(12), one Li(3), one Li(5), and one Li(9) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to one Li(1), one Li(12), one Li(4), and one Li(5) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(10), one Li(6), and one V(1) atom. In the fourth F site, F(4) is bonded in a 4-coordinate geometry to one Li(1), one Li(12), one Li(3), and one Li(8) atom. is represented by the CIF file [CIF]
data_Li7V(O2F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.527
_cell_length_b   5.866
_cell_length_c   9.844
_cell_angle_alpha   105.566
_cell_angle_beta   89.622
_cell_angle_gamma   117.334
_symmetry_Int_Tables_number   1
_cell_volume   270.553
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.032  0.937  0.764  1.0
  Li  Li1  1  0.496  0.391  0.251  1.0
  Li  Li2  1  0.544  0.046  0.617  1.0
  Li  Li3  1  0.965  0.453  0.874  1.0
  Li  Li4  1  0.032  0.754  0.547  1.0
  Li  Li5  1  0.529  0.310  0.049  1.0
  Li  Li6  1  0.979  0.658  0.319  1.0
  Li  Li7  1  0.456  0.706  0.949  1.0
  Li  Li8  1  0.957  0.207  0.451  1.0
  Li  Li9  1  0.015  0.527  0.123  1.0
  Li  Li10  1  0.495  0.989  0.383  1.0
  Li  Li11  1  0.429  0.531  0.735  1.0
  Li  Li12  1  0.028  0.110  0.253  1.0
  Li  Li13  1  0.512  0.840  0.190  1.0
  V  V14  1  0.029  0.983  0.010  1.0
  V  V15  1  0.493  0.525  0.473  1.0
  O  O16  1  0.296  0.048  0.195  1.0
  O  O17  1  0.159  0.779  0.957  1.0
  O  O18  1  0.688  0.329  0.449  1.0
  O  O19  1  0.734  0.660  0.116  1.0
  O  O20  1  0.247  0.340  0.899  1.0
  O  O21  1  0.345  0.710  0.543  1.0
  O  O22  1  0.219  0.458  0.305  1.0
  O  O23  1  0.782  0.873  0.381  1.0
  F  F24  1  0.227  0.126  0.607  1.0
  F  F25  1  0.791  0.580  0.692  1.0
  F  F26  1  0.817  0.203  0.061  1.0
  F  F27  1  0.705  0.927  0.807  1.0
[/CIF]
.
The crystal structure described by Li7V(O2F)2 crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(5), one F(1), one F(2), and one F(4) atom. In the second Li site, Li(2) is bonded in a distorted L-shaped geometry to one O(1), one O(4), one O(7), and one O(8) atom. In the third Li site, Li(3) is bonded in a 2-coordinate geometry to one O(6), one F(1), and one F(4) atom. In the fourth Li site, Li(4) is bonded in a 3-coordinate geometry to one O(2), one O(5), and one F(2) atom. In the fifth Li site, Li(5) is bonded in a 4-coordinate geometry to one O(3), one O(6), one O(8), one F(1), and one F(2) atom. In the sixth Li site, Li(6) is bonded in a 3-coordinate geometry to one O(4), one O(5), and one F(3) atom. In the seventh Li site, Li(7) is bonded in a 2-coordinate geometry to one O(4), one O(7), and one O(8) atom. In the eighth Li site, Li(8) is bonded in a 4-coordinate geometry to one O(2), one O(4), one O(5), and one F(4) atom. In the ninth Li site, Li(9) is bonded in a 2-coordinate geometry to one O(3), one O(8), and one F(1) atom. In the tenth Li site, Li(10) is bonded in a 1-coordinate geometry to one O(4) and one F(3) atom. In the eleventh Li site, Li(11) is bonded in a 2-coordinate geometry to one O(3) and one O(8) atom. In the twelfth Li site, Li(12) is bonded in a 4-coordinate geometry to one O(5), one F(1), one F(2), and one F(4) atom. In the thirteenth Li site, Li(13) is bonded in a 2-coordinate geometry to one O(1), one O(4), one O(7), and one O(8) atom. In the fourteenth Li site, Li(14) is bonded in a 2-coordinate geometry to one O(1), one O(4), and one O(8) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 2-coordinate geometry to one O(2), one O(4), one O(5), and one F(3) atom. In the second V site, V(2) is bonded in a 2-coordinate geometry to one O(3), one O(6), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(13), one Li(14), and one Li(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(4), one Li(8), and one V(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(11), one Li(5), one Li(9), and one V(2) atom. In the fourth O site, O(4) is bonded in a 8-coordinate geometry to one Li(10), one Li(13), one Li(14), one Li(2), one Li(6), one Li(7), one Li(8), and one V(1) atom. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to one Li(1), one Li(12), one Li(4), one Li(6), one Li(8), and one V(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(3), one Li(5), and one V(2) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Li(13), one Li(2), and one Li(7) atom. In the eighth O site, O(8) is bonded in a 8-coordinate geometry to one Li(11), one Li(13), one Li(14), one Li(2), one Li(5), one Li(7), one Li(9), and one V(2) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a 5-coordinate geometry to one Li(1), one Li(12), one Li(3), one Li(5), and one Li(9) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to one Li(1), one Li(12), one Li(4), and one Li(5) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(10), one Li(6), and one V(1) atom. In the fourth F site, F(4) is bonded in a 4-coordinate geometry to one Li(1), one Li(12), one Li(3), and one Li(8) atom. is represented by the CIF file [CIF]
data_Li7V(O2F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.527
_cell_length_b   5.866
_cell_length_c   9.844
_cell_angle_alpha   105.566
_cell_angle_beta   89.622
_cell_angle_gamma   117.334
_symmetry_Int_Tables_number   1
_cell_volume   270.553
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.032  0.937  0.764  1.0
  Li  Li1  1  0.496  0.391  0.251  1.0
  Li  Li2  1  0.544  0.046  0.617  1.0
  Li  Li3  1  0.965  0.453  0.874  1.0
  Li  Li4  1  0.032  0.754  0.547  1.0
  Li  Li5  1  0.529  0.310  0.049  1.0
  Li  Li6  1  0.979  0.658  0.319  1.0
  Li  Li7  1  0.456  0.706  0.949  1.0
  Li  Li8  1  0.957  0.207  0.451  1.0
  Li  Li9  1  0.015  0.527  0.123  1.0
  Li  Li10  1  0.495  0.989  0.383  1.0
  Li  Li11  1  0.429  0.531  0.735  1.0
  Li  Li12  1  0.028  0.110  0.253  1.0
  Li  Li13  1  0.512  0.840  0.190  1.0
  V  V14  1  0.029  0.983  0.010  1.0
  V  V15  1  0.493  0.525  0.473  1.0
  O  O16  1  0.296  0.048  0.195  1.0
  O  O17  1  0.159  0.779  0.957  1.0
  O  O18  1  0.688  0.329  0.449  1.0
  O  O19  1  0.734  0.660  0.116  1.0
  O  O20  1  0.247  0.340  0.899  1.0
  O  O21  1  0.345  0.710  0.543  1.0
  O  O22  1  0.219  0.458  0.305  1.0
  O  O23  1  0.782  0.873  0.381  1.0
  F  F24  1  0.227  0.126  0.607  1.0
  F  F25  1  0.791  0.580  0.692  1.0
  F  F26  1  0.817  0.203  0.061  1.0
  F  F27  1  0.705  0.927  0.807  1.0
[/CIF]
.