The crystal structure described by IMn(CO)5 is Cyanogen Chloride-derived structured and crystallizes in the orthorhombic Cmcm space group. The structure is zero-dimensional and consists of four IMn(CO)5 clusters. Mn(1) is bonded in a distorted square pyramidal geometry to one C(1), four equivalent C(2), and one I(1) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. I(1) is bonded in a single-bond geometry to one Mn(1) atom. is represented by the CIF card [CIF]
data_MnC5IO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.766
_cell_length_b   6.766
_cell_length_c   11.008
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   111.239
_symmetry_Int_Tables_number   1
_cell_volume   469.629
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.145  0.855  0.250  1.0
  Mn  Mn1  1  0.855  0.145  0.750  1.0
  C  C2  1  0.310  0.690  0.250  1.0
  C  C3  1  0.690  0.310  0.750  1.0
  C  C4  1  0.309  0.042  0.369  1.0
  C  C5  1  0.042  0.309  0.631  1.0
  C  C6  1  0.309  0.042  0.131  1.0
  C  C7  1  0.042  0.309  0.869  1.0
  C  C8  1  0.691  0.958  0.631  1.0
  C  C9  1  0.958  0.691  0.369  1.0
  C  C10  1  0.691  0.958  0.869  1.0
  C  C11  1  0.958  0.691  0.131  1.0
  I  I12  1  0.898  0.102  0.250  1.0
  I  I13  1  0.102  0.898  0.750  1.0
  O  O14  1  0.413  0.587  0.250  1.0
  O  O15  1  0.587  0.413  0.750  1.0
  O  O16  1  0.411  0.160  0.440  1.0
  O  O17  1  0.160  0.411  0.560  1.0
  O  O18  1  0.411  0.160  0.060  1.0
  O  O19  1  0.160  0.411  0.940  1.0
  O  O20  1  0.589  0.840  0.560  1.0
  O  O21  1  0.840  0.589  0.440  1.0
  O  O22  1  0.589  0.840  0.940  1.0
  O  O23  1  0.840  0.589  0.060  1.0
[/CIF]
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The crystal structure described by IMn(CO)5 is Cyanogen Chloride-derived structured and crystallizes in the orthorhombic Cmcm space group. The structure is zero-dimensional and consists of four IMn(CO)5 clusters. Mn(1) is bonded in a distorted square pyramidal geometry to one C(1), four equivalent C(2), and one I(1) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. I(1) is bonded in a single-bond geometry to one Mn(1) atom. is represented by the CIF card [CIF]
data_MnC5IO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.766
_cell_length_b   6.766
_cell_length_c   11.008
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   111.239
_symmetry_Int_Tables_number   1
_cell_volume   469.629
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.145  0.855  0.250  1.0
  Mn  Mn1  1  0.855  0.145  0.750  1.0
  C  C2  1  0.310  0.690  0.250  1.0
  C  C3  1  0.690  0.310  0.750  1.0
  C  C4  1  0.309  0.042  0.369  1.0
  C  C5  1  0.042  0.309  0.631  1.0
  C  C6  1  0.309  0.042  0.131  1.0
  C  C7  1  0.042  0.309  0.869  1.0
  C  C8  1  0.691  0.958  0.631  1.0
  C  C9  1  0.958  0.691  0.369  1.0
  C  C10  1  0.691  0.958  0.869  1.0
  C  C11  1  0.958  0.691  0.131  1.0
  I  I12  1  0.898  0.102  0.250  1.0
  I  I13  1  0.102  0.898  0.750  1.0
  O  O14  1  0.413  0.587  0.250  1.0
  O  O15  1  0.587  0.413  0.750  1.0
  O  O16  1  0.411  0.160  0.440  1.0
  O  O17  1  0.160  0.411  0.560  1.0
  O  O18  1  0.411  0.160  0.060  1.0
  O  O19  1  0.160  0.411  0.940  1.0
  O  O20  1  0.589  0.840  0.560  1.0
  O  O21  1  0.840  0.589  0.440  1.0
  O  O22  1  0.589  0.840  0.940  1.0
  O  O23  1  0.840  0.589  0.060  1.0
[/CIF]
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