The compound described by CoN5Br3 is High Pressure (4-7GPa) Tellurium structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CoN5Br3 clusters. Co(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one N(3), and two equivalent N(4) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Co(1), two equivalent N(4), and one Br(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Co(1) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one Co(1) and two equivalent Br(2) atoms. In the fourth N site, N(4) is bonded in a distorted L-shaped geometry to one Co(1) and one N(1) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one N(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one N(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoBr3N5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.869
_cell_length_b   9.909
_cell_length_c   16.661
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1134.032
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.616  0.250  0.852  1.0
  Co  Co1  1  0.884  0.250  0.352  1.0
  Co  Co2  1  0.384  0.750  0.148  1.0
  Co  Co3  1  0.116  0.750  0.648  1.0
  Br  Br4  1  0.619  0.250  0.100  1.0
  Br  Br5  1  0.881  0.250  0.600  1.0
  Br  Br6  1  0.381  0.750  0.900  1.0
  Br  Br7  1  0.119  0.750  0.400  1.0
  Br  Br8  1  0.256  0.409  0.291  1.0
  Br  Br9  1  0.244  0.091  0.791  1.0
  Br  Br10  1  0.744  0.909  0.709  1.0
  Br  Br11  1  0.756  0.591  0.209  1.0
  Br  Br12  1  0.744  0.591  0.709  1.0
  Br  Br13  1  0.756  0.909  0.209  1.0
  Br  Br14  1  0.256  0.091  0.291  1.0
  Br  Br15  1  0.244  0.409  0.791  1.0
  N  N16  1  0.656  0.250  0.981  1.0
  N  N17  1  0.844  0.250  0.481  1.0
  N  N18  1  0.344  0.750  0.019  1.0
  N  N19  1  0.156  0.750  0.519  1.0
  N  N20  1  0.768  0.250  0.783  1.0
  N  N21  1  0.732  0.250  0.283  1.0
  N  N22  1  0.232  0.750  0.217  1.0
  N  N23  1  0.268  0.750  0.717  1.0
  N  N24  1  0.357  0.250  0.833  1.0
  N  N25  1  0.143  0.250  0.333  1.0
  N  N26  1  0.643  0.750  0.167  1.0
  N  N27  1  0.857  0.750  0.667  1.0
  N  N28  1  0.664  0.138  0.942  1.0
  N  N29  1  0.836  0.362  0.442  1.0
  N  N30  1  0.336  0.638  0.058  1.0
  N  N31  1  0.164  0.862  0.558  1.0
  N  N32  1  0.336  0.862  0.058  1.0
  N  N33  1  0.164  0.638  0.558  1.0
  N  N34  1  0.664  0.362  0.942  1.0
  N  N35  1  0.836  0.138  0.442  1.0
[/CIF]
.
The compound described by CoN5Br3 is High Pressure (4-7GPa) Tellurium structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four CoN5Br3 clusters. Co(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one N(3), and two equivalent N(4) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one Co(1), two equivalent N(4), and one Br(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Co(1) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one Co(1) and two equivalent Br(2) atoms. In the fourth N site, N(4) is bonded in a distorted L-shaped geometry to one Co(1) and one N(1) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one N(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one N(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoBr3N5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.869
_cell_length_b   9.909
_cell_length_c   16.661
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1134.032
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.616  0.250  0.852  1.0
  Co  Co1  1  0.884  0.250  0.352  1.0
  Co  Co2  1  0.384  0.750  0.148  1.0
  Co  Co3  1  0.116  0.750  0.648  1.0
  Br  Br4  1  0.619  0.250  0.100  1.0
  Br  Br5  1  0.881  0.250  0.600  1.0
  Br  Br6  1  0.381  0.750  0.900  1.0
  Br  Br7  1  0.119  0.750  0.400  1.0
  Br  Br8  1  0.256  0.409  0.291  1.0
  Br  Br9  1  0.244  0.091  0.791  1.0
  Br  Br10  1  0.744  0.909  0.709  1.0
  Br  Br11  1  0.756  0.591  0.209  1.0
  Br  Br12  1  0.744  0.591  0.709  1.0
  Br  Br13  1  0.756  0.909  0.209  1.0
  Br  Br14  1  0.256  0.091  0.291  1.0
  Br  Br15  1  0.244  0.409  0.791  1.0
  N  N16  1  0.656  0.250  0.981  1.0
  N  N17  1  0.844  0.250  0.481  1.0
  N  N18  1  0.344  0.750  0.019  1.0
  N  N19  1  0.156  0.750  0.519  1.0
  N  N20  1  0.768  0.250  0.783  1.0
  N  N21  1  0.732  0.250  0.283  1.0
  N  N22  1  0.232  0.750  0.217  1.0
  N  N23  1  0.268  0.750  0.717  1.0
  N  N24  1  0.357  0.250  0.833  1.0
  N  N25  1  0.143  0.250  0.333  1.0
  N  N26  1  0.643  0.750  0.167  1.0
  N  N27  1  0.857  0.750  0.667  1.0
  N  N28  1  0.664  0.138  0.942  1.0
  N  N29  1  0.836  0.362  0.442  1.0
  N  N30  1  0.336  0.638  0.058  1.0
  N  N31  1  0.164  0.862  0.558  1.0
  N  N32  1  0.336  0.862  0.058  1.0
  N  N33  1  0.164  0.638  0.558  1.0
  N  N34  1  0.664  0.362  0.942  1.0
  N  N35  1  0.836  0.138  0.442  1.0
[/CIF]
.