The material described by Ag3VO4 crystallizes in the monoclinic C2/c space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to one V(1), one Ag(2), and two equivalent Ag(1) atoms to form distorted corner-sharing OVAg3 tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to one V(1), one Ag(2), and two equivalent Ag(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VAg3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.004
_cell_length_b   5.600
_cell_length_c   9.569
_cell_angle_alpha   79.670
_cell_angle_beta   74.842
_cell_angle_gamma   63.462
_symmetry_Int_Tables_number   1
_cell_volume   230.910
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.455  0.750  0.250  1.0
  V  V1  1  0.545  0.250  0.750  1.0
  Ag  Ag2  1  0.307  0.383  0.095  1.0
  Ag  Ag3  1  0.215  0.883  0.595  1.0
  Ag  Ag4  1  0.693  0.617  0.905  1.0
  Ag  Ag5  1  0.785  0.117  0.405  1.0
  Ag  Ag6  1  0.000  0.000  0.000  1.0
  Ag  Ag7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.866  0.968  0.790  1.0
  O  O9  1  0.624  0.532  0.710  1.0
  O  O10  1  0.134  0.032  0.210  1.0
  O  O11  1  0.376  0.468  0.290  1.0
  O  O12  1  0.754  0.707  0.103  1.0
  O  O13  1  0.246  0.293  0.897  1.0
  O  O14  1  0.564  0.793  0.397  1.0
  O  O15  1  0.436  0.207  0.603  1.0
[/CIF]
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The material described by Ag3VO4 crystallizes in the monoclinic C2/c space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to one V(1), one Ag(2), and two equivalent Ag(1) atoms to form distorted corner-sharing OVAg3 tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to one V(1), one Ag(2), and two equivalent Ag(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VAg3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.004
_cell_length_b   5.600
_cell_length_c   9.569
_cell_angle_alpha   79.670
_cell_angle_beta   74.842
_cell_angle_gamma   63.462
_symmetry_Int_Tables_number   1
_cell_volume   230.910
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.455  0.750  0.250  1.0
  V  V1  1  0.545  0.250  0.750  1.0
  Ag  Ag2  1  0.307  0.383  0.095  1.0
  Ag  Ag3  1  0.215  0.883  0.595  1.0
  Ag  Ag4  1  0.693  0.617  0.905  1.0
  Ag  Ag5  1  0.785  0.117  0.405  1.0
  Ag  Ag6  1  0.000  0.000  0.000  1.0
  Ag  Ag7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.866  0.968  0.790  1.0
  O  O9  1  0.624  0.532  0.710  1.0
  O  O10  1  0.134  0.032  0.210  1.0
  O  O11  1  0.376  0.468  0.290  1.0
  O  O12  1  0.754  0.707  0.103  1.0
  O  O13  1  0.246  0.293  0.897  1.0
  O  O14  1  0.564  0.793  0.397  1.0
  O  O15  1  0.436  0.207  0.603  1.0
[/CIF]
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