The compound described by NH3Te(OF)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two NH3Te(OF)2 clusters. N(1) is bonded in a bent 120 degrees geometry to one H(1) and one H(2) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one N(1) and one F(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(1) and one O(2) atom. Te(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one F(1), and one F(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one H(3) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one H(3) and one Te(1) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(1) is bonded in a bent 150 degrees geometry to one H(1) and one Te(1) atom. is represented by the CIF file [CIF]
data_TeH3N(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.258
_cell_length_b   6.455
_cell_length_c   10.698
_cell_angle_alpha   90.000
_cell_angle_beta   97.553
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   428.363
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.261  0.555  0.362  1.0
  Te  Te1  1  0.761  0.945  0.862  1.0
  Te  Te2  1  0.739  0.445  0.638  1.0
  Te  Te3  1  0.239  0.055  0.138  1.0
  H  H4  1  0.942  0.112  0.389  1.0
  H  H5  1  0.442  0.388  0.889  1.0
  H  H6  1  0.058  0.888  0.611  1.0
  H  H7  1  0.558  0.612  0.111  1.0
  H  H8  1  0.654  0.051  0.318  1.0
  H  H9  1  0.154  0.449  0.818  1.0
  H  H10  1  0.346  0.949  0.682  1.0
  H  H11  1  0.846  0.551  0.182  1.0
  H  H12  1  0.813  0.535  0.417  1.0
  H  H13  1  0.313  0.965  0.917  1.0
  H  H14  1  0.187  0.465  0.583  1.0
  H  H15  1  0.687  0.035  0.083  1.0
  N  N16  1  0.802  0.018  0.374  1.0
  N  N17  1  0.302  0.482  0.874  1.0
  N  N18  1  0.198  0.982  0.626  1.0
  N  N19  1  0.698  0.518  0.126  1.0
  O  O20  1  0.971  0.646  0.327  1.0
  O  O21  1  0.471  0.854  0.827  1.0
  O  O22  1  0.029  0.354  0.673  1.0
  O  O23  1  0.529  0.146  0.173  1.0
  O  O24  1  0.706  0.443  0.455  1.0
  O  O25  1  0.206  0.057  0.955  1.0
  O  O26  1  0.294  0.557  0.545  1.0
  O  O27  1  0.794  0.943  0.045  1.0
  F  F28  1  0.147  0.251  0.380  1.0
  F  F29  1  0.647  0.249  0.880  1.0
  F  F30  1  0.853  0.749  0.620  1.0
  F  F31  1  0.353  0.751  0.120  1.0
  F  F32  1  0.363  0.848  0.382  1.0
  F  F33  1  0.863  0.652  0.882  1.0
  F  F34  1  0.637  0.152  0.618  1.0
  F  F35  1  0.137  0.348  0.118  1.0
[/CIF]
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The compound described by NH3Te(OF)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two NH3Te(OF)2 clusters. N(1) is bonded in a bent 120 degrees geometry to one H(1) and one H(2) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one N(1) and one F(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(1) and one O(2) atom. Te(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one F(1), and one F(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one H(3) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one H(3) and one Te(1) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(1) is bonded in a bent 150 degrees geometry to one H(1) and one Te(1) atom. is represented by the CIF file [CIF]
data_TeH3N(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.258
_cell_length_b   6.455
_cell_length_c   10.698
_cell_angle_alpha   90.000
_cell_angle_beta   97.553
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   428.363
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.261  0.555  0.362  1.0
  Te  Te1  1  0.761  0.945  0.862  1.0
  Te  Te2  1  0.739  0.445  0.638  1.0
  Te  Te3  1  0.239  0.055  0.138  1.0
  H  H4  1  0.942  0.112  0.389  1.0
  H  H5  1  0.442  0.388  0.889  1.0
  H  H6  1  0.058  0.888  0.611  1.0
  H  H7  1  0.558  0.612  0.111  1.0
  H  H8  1  0.654  0.051  0.318  1.0
  H  H9  1  0.154  0.449  0.818  1.0
  H  H10  1  0.346  0.949  0.682  1.0
  H  H11  1  0.846  0.551  0.182  1.0
  H  H12  1  0.813  0.535  0.417  1.0
  H  H13  1  0.313  0.965  0.917  1.0
  H  H14  1  0.187  0.465  0.583  1.0
  H  H15  1  0.687  0.035  0.083  1.0
  N  N16  1  0.802  0.018  0.374  1.0
  N  N17  1  0.302  0.482  0.874  1.0
  N  N18  1  0.198  0.982  0.626  1.0
  N  N19  1  0.698  0.518  0.126  1.0
  O  O20  1  0.971  0.646  0.327  1.0
  O  O21  1  0.471  0.854  0.827  1.0
  O  O22  1  0.029  0.354  0.673  1.0
  O  O23  1  0.529  0.146  0.173  1.0
  O  O24  1  0.706  0.443  0.455  1.0
  O  O25  1  0.206  0.057  0.955  1.0
  O  O26  1  0.294  0.557  0.545  1.0
  O  O27  1  0.794  0.943  0.045  1.0
  F  F28  1  0.147  0.251  0.380  1.0
  F  F29  1  0.647  0.249  0.880  1.0
  F  F30  1  0.853  0.749  0.620  1.0
  F  F31  1  0.353  0.751  0.120  1.0
  F  F32  1  0.363  0.848  0.382  1.0
  F  F33  1  0.863  0.652  0.882  1.0
  F  F34  1  0.637  0.152  0.618  1.0
  F  F35  1  0.137  0.348  0.118  1.0
[/CIF]
.