The compound described by Re(TeBr2)2 is Indium-like structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of two Re(TeBr2)2 clusters. Re(1) is bonded in a 6-coordinate geometry to one Te(1), three equivalent Te(2), one Br(2), and one Br(3) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one Re(1), one Br(1), one Br(2), one Br(3), and one Br(4) atom. In the second Te site, Te(2) is bonded in a 3-coordinate geometry to three equivalent Re(1) atoms. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Te(1) atom. In the second Br site, Br(2) is bonded in a 2-coordinate geometry to one Re(1) and one Te(1) atom. In the third Br site, Br(3) is bonded in a 2-coordinate geometry to one Re(1) and one Te(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re(TeBr2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.896
_cell_length_b   10.896
_cell_length_c   10.895
_cell_angle_alpha   115.949
_cell_angle_beta   115.941
_cell_angle_gamma   97.183
_symmetry_Int_Tables_number   1
_cell_volume   962.412
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.204  0.854  0.417  1.0
  Re  Re1  1  0.146  0.562  0.350  1.0
  Re  Re2  1  0.438  0.788  0.583  1.0
  Re  Re3  1  0.212  0.796  0.650  1.0
  Te  Te4  1  0.655  0.681  0.583  1.0
  Te  Te5  1  0.405  0.032  0.733  1.0
  Te  Te6  1  0.319  0.902  0.974  1.0
  Te  Te7  1  0.300  0.672  0.267  1.0
  Te  Te8  1  0.098  0.072  0.417  1.0
  Te  Te9  1  0.968  0.700  0.373  1.0
  Te  Te10  1  0.928  0.345  0.026  1.0
  Te  Te11  1  0.328  0.595  0.627  1.0
  Br  Br12  1  0.695  0.409  0.946  1.0
  Br  Br13  1  0.116  0.995  0.787  1.0
  Br  Br14  1  0.942  0.351  0.301  1.0
  Br  Br15  1  0.591  0.538  0.287  1.0
  Br  Br16  1  0.548  0.143  0.156  1.0
  Br  Br17  1  0.607  0.452  0.595  1.0
  Br  Br18  1  0.005  0.792  0.121  1.0
  Br  Br19  1  0.049  0.640  0.699  1.0
  Br  Br20  1  0.462  0.749  0.054  1.0
  Br  Br21  1  0.649  0.951  0.591  1.0
  Br  Br22  1  0.208  0.329  0.213  1.0
  Br  Br23  1  0.360  0.058  0.409  1.0
  Br  Br24  1  0.671  0.884  0.879  1.0
  Br  Br25  1  0.251  0.305  0.713  1.0
  Br  Br26  1  0.857  0.013  0.405  1.0
  Br  Br27  1  0.987  0.393  0.844  1.0
[/CIF]
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The compound described by Re(TeBr2)2 is Indium-like structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of two Re(TeBr2)2 clusters. Re(1) is bonded in a 6-coordinate geometry to one Te(1), three equivalent Te(2), one Br(2), and one Br(3) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 5-coordinate geometry to one Re(1), one Br(1), one Br(2), one Br(3), and one Br(4) atom. In the second Te site, Te(2) is bonded in a 3-coordinate geometry to three equivalent Re(1) atoms. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Te(1) atom. In the second Br site, Br(2) is bonded in a 2-coordinate geometry to one Re(1) and one Te(1) atom. In the third Br site, Br(3) is bonded in a 2-coordinate geometry to one Re(1) and one Te(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re(TeBr2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.896
_cell_length_b   10.896
_cell_length_c   10.895
_cell_angle_alpha   115.949
_cell_angle_beta   115.941
_cell_angle_gamma   97.183
_symmetry_Int_Tables_number   1
_cell_volume   962.412
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.204  0.854  0.417  1.0
  Re  Re1  1  0.146  0.562  0.350  1.0
  Re  Re2  1  0.438  0.788  0.583  1.0
  Re  Re3  1  0.212  0.796  0.650  1.0
  Te  Te4  1  0.655  0.681  0.583  1.0
  Te  Te5  1  0.405  0.032  0.733  1.0
  Te  Te6  1  0.319  0.902  0.974  1.0
  Te  Te7  1  0.300  0.672  0.267  1.0
  Te  Te8  1  0.098  0.072  0.417  1.0
  Te  Te9  1  0.968  0.700  0.373  1.0
  Te  Te10  1  0.928  0.345  0.026  1.0
  Te  Te11  1  0.328  0.595  0.627  1.0
  Br  Br12  1  0.695  0.409  0.946  1.0
  Br  Br13  1  0.116  0.995  0.787  1.0
  Br  Br14  1  0.942  0.351  0.301  1.0
  Br  Br15  1  0.591  0.538  0.287  1.0
  Br  Br16  1  0.548  0.143  0.156  1.0
  Br  Br17  1  0.607  0.452  0.595  1.0
  Br  Br18  1  0.005  0.792  0.121  1.0
  Br  Br19  1  0.049  0.640  0.699  1.0
  Br  Br20  1  0.462  0.749  0.054  1.0
  Br  Br21  1  0.649  0.951  0.591  1.0
  Br  Br22  1  0.208  0.329  0.213  1.0
  Br  Br23  1  0.360  0.058  0.409  1.0
  Br  Br24  1  0.671  0.884  0.879  1.0
  Br  Br25  1  0.251  0.305  0.713  1.0
  Br  Br26  1  0.857  0.013  0.405  1.0
  Br  Br27  1  0.987  0.393  0.844  1.0
[/CIF]
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