The crystal structure described by Na2LiMn(PO3)5 crystallizes in the monoclinic P2_1/m space group. Na(1) is bonded to one O(3), one O(5), one O(7), one O(9), and two equivalent O(2) atoms to form distorted NaO6 pentagonal pyramids that share  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Na(1)O6 pentagonal pyramids. Li(1) is bonded in a 3-coordinate geometry to one O(9) and two equivalent O(4) atoms. Mn(1) is bonded to two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra, and edges with two equivalent Na(1)O6 pentagonal pyramids. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Na(1)O6 pentagonal pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-56°. In the second P site, P(2) is bonded to one O(2), one O(4), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with three equivalent Na(1)O6 pentagonal pyramids,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. In the third P site, P(3) is bonded to one O(3), one O(9), and two equivalent O(8) atoms to form PO4 tetrahedra that share corners with four equivalent Na(1)O6 pentagonal pyramids and corners with two equivalent P(2)O4 tetrahedra. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a distorted bent 120 degrees geometry to two equivalent Na(1), one Li(1), and one P(3) atom. In the second O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent P(1) atoms. In the third O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one P(2) atom. In the fourth O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Na(1) and one P(3) atom. In the fifth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one P(1), and one P(2) atom. In the sixth O site, O(5) is bonded in a distorted trigonal planar geometry to one Na(1), one Mn(1), and one P(1) atom. In the seventh O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(1) atom. In the eighth O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Mn(1), and one P(2) atom. In the ninth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one P(2) and one P(3) atom. is represented by the CIF card [CIF]
data_Na2LiMn(PO3)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.955
_cell_length_b   5.233
_cell_length_c   9.134
_cell_angle_alpha   75.236
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   644.989
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.901  0.411  0.145  1.0
  Na  Na1  1  0.599  0.411  0.145  1.0
  Na  Na2  1  0.401  0.589  0.855  1.0
  Na  Na3  1  0.099  0.589  0.855  1.0
  Li  Li4  1  0.250  0.474  0.170  1.0
  Li  Li5  1  0.750  0.526  0.830  1.0
  Mn  Mn6  1  0.000  0.000  0.500  1.0
  Mn  Mn7  1  0.500  0.000  0.500  1.0
  P  P8  1  0.356  0.490  0.488  1.0
  P  P9  1  0.144  0.490  0.488  1.0
  P  P10  1  0.922  0.148  0.814  1.0
  P  P11  1  0.578  0.148  0.814  1.0
  P  P12  1  0.250  0.039  0.998  1.0
  P  P13  1  0.750  0.961  0.002  1.0
  P  P14  1  0.422  0.852  0.186  1.0
  P  P15  1  0.078  0.852  0.186  1.0
  P  P16  1  0.644  0.510  0.512  1.0
  P  P17  1  0.856  0.510  0.512  1.0
  O  O18  1  0.750  0.444  0.464  1.0
  O  O19  1  0.959  0.295  0.922  1.0
  O  O20  1  0.541  0.295  0.922  1.0
  O  O21  1  0.250  0.281  0.871  1.0
  O  O22  1  0.853  0.356  0.693  1.0
  O  O23  1  0.647  0.356  0.693  1.0
  O  O24  1  0.578  0.378  0.423  1.0
  O  O25  1  0.922  0.378  0.423  1.0
  O  O26  1  0.366  0.203  0.494  1.0
  O  O27  1  0.134  0.203  0.494  1.0
  O  O28  1  0.989  0.004  0.735  1.0
  O  O29  1  0.511  0.004  0.735  1.0
  O  O30  1  0.840  0.930  0.891  1.0
  O  O31  1  0.660  0.930  0.891  1.0
  O  O32  1  0.750  0.240  0.021  1.0
  O  O33  1  0.250  0.760  0.979  1.0
  O  O34  1  0.340  0.070  0.109  1.0
  O  O35  1  0.160  0.070  0.109  1.0
  O  O36  1  0.489  0.996  0.265  1.0
  O  O37  1  0.011  0.996  0.265  1.0
  O  O38  1  0.866  0.797  0.506  1.0
  O  O39  1  0.634  0.797  0.506  1.0
  O  O40  1  0.422  0.622  0.577  1.0
  O  O41  1  0.078  0.622  0.577  1.0
  O  O42  1  0.353  0.644  0.307  1.0
  O  O43  1  0.147  0.644  0.307  1.0
  O  O44  1  0.750  0.719  0.129  1.0
  O  O45  1  0.459  0.705  0.078  1.0
  O  O46  1  0.041  0.705  0.078  1.0
  O  O47  1  0.250  0.556  0.536  1.0
[/CIF]
.
The crystal structure described by Na2LiMn(PO3)5 crystallizes in the monoclinic P2_1/m space group. Na(1) is bonded to one O(3), one O(5), one O(7), one O(9), and two equivalent O(2) atoms to form distorted NaO6 pentagonal pyramids that share  a cornercorner with one P(1)O4 tetrahedra, corners with two equivalent P(3)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Na(1)O6 pentagonal pyramids. Li(1) is bonded in a 3-coordinate geometry to one O(9) and two equivalent O(4) atoms. Mn(1) is bonded to two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra, and edges with two equivalent Na(1)O6 pentagonal pyramids. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(4), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Na(1)O6 pentagonal pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 51-56°. In the second P site, P(2) is bonded to one O(2), one O(4), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with three equivalent Na(1)O6 pentagonal pyramids,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. In the third P site, P(3) is bonded to one O(3), one O(9), and two equivalent O(8) atoms to form PO4 tetrahedra that share corners with four equivalent Na(1)O6 pentagonal pyramids and corners with two equivalent P(2)O4 tetrahedra. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a distorted bent 120 degrees geometry to two equivalent Na(1), one Li(1), and one P(3) atom. In the second O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent P(1) atoms. In the third O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one P(2) atom. In the fourth O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Na(1) and one P(3) atom. In the fifth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one P(1), and one P(2) atom. In the sixth O site, O(5) is bonded in a distorted trigonal planar geometry to one Na(1), one Mn(1), and one P(1) atom. In the seventh O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(1) atom. In the eighth O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Mn(1), and one P(2) atom. In the ninth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one P(2) and one P(3) atom. is represented by the CIF card [CIF]
data_Na2LiMn(PO3)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.955
_cell_length_b   5.233
_cell_length_c   9.134
_cell_angle_alpha   75.236
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   644.989
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.901  0.411  0.145  1.0
  Na  Na1  1  0.599  0.411  0.145  1.0
  Na  Na2  1  0.401  0.589  0.855  1.0
  Na  Na3  1  0.099  0.589  0.855  1.0
  Li  Li4  1  0.250  0.474  0.170  1.0
  Li  Li5  1  0.750  0.526  0.830  1.0
  Mn  Mn6  1  0.000  0.000  0.500  1.0
  Mn  Mn7  1  0.500  0.000  0.500  1.0
  P  P8  1  0.356  0.490  0.488  1.0
  P  P9  1  0.144  0.490  0.488  1.0
  P  P10  1  0.922  0.148  0.814  1.0
  P  P11  1  0.578  0.148  0.814  1.0
  P  P12  1  0.250  0.039  0.998  1.0
  P  P13  1  0.750  0.961  0.002  1.0
  P  P14  1  0.422  0.852  0.186  1.0
  P  P15  1  0.078  0.852  0.186  1.0
  P  P16  1  0.644  0.510  0.512  1.0
  P  P17  1  0.856  0.510  0.512  1.0
  O  O18  1  0.750  0.444  0.464  1.0
  O  O19  1  0.959  0.295  0.922  1.0
  O  O20  1  0.541  0.295  0.922  1.0
  O  O21  1  0.250  0.281  0.871  1.0
  O  O22  1  0.853  0.356  0.693  1.0
  O  O23  1  0.647  0.356  0.693  1.0
  O  O24  1  0.578  0.378  0.423  1.0
  O  O25  1  0.922  0.378  0.423  1.0
  O  O26  1  0.366  0.203  0.494  1.0
  O  O27  1  0.134  0.203  0.494  1.0
  O  O28  1  0.989  0.004  0.735  1.0
  O  O29  1  0.511  0.004  0.735  1.0
  O  O30  1  0.840  0.930  0.891  1.0
  O  O31  1  0.660  0.930  0.891  1.0
  O  O32  1  0.750  0.240  0.021  1.0
  O  O33  1  0.250  0.760  0.979  1.0
  O  O34  1  0.340  0.070  0.109  1.0
  O  O35  1  0.160  0.070  0.109  1.0
  O  O36  1  0.489  0.996  0.265  1.0
  O  O37  1  0.011  0.996  0.265  1.0
  O  O38  1  0.866  0.797  0.506  1.0
  O  O39  1  0.634  0.797  0.506  1.0
  O  O40  1  0.422  0.622  0.577  1.0
  O  O41  1  0.078  0.622  0.577  1.0
  O  O42  1  0.353  0.644  0.307  1.0
  O  O43  1  0.147  0.644  0.307  1.0
  O  O44  1  0.750  0.719  0.129  1.0
  O  O45  1  0.459  0.705  0.078  1.0
  O  O46  1  0.041  0.705  0.078  1.0
  O  O47  1  0.250  0.556  0.536  1.0
[/CIF]
.