The compound described by (MnO4)2Zn(NH3)4 is Silicon tetrafluoride-derived structured and crystallizes in the cubic F-43m space group. The structure is zero-dimensional and consists of eight mangan(iv)-hydroxyd molecules and four Zn(NH3)4 clusters. In each Zn(NH3)4 cluster, Zn(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1) and three equivalent H(1) atoms. H(1) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_Mn2ZnH12(NO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.457
_cell_length_b   7.457
_cell_length_c   7.457
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   293.152
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.500  0.500  0.500  1.0
  Mn  Mn1  1  0.250  0.250  0.250  1.0
  Zn  Zn2  1  0.000  0.000  0.000  1.0
  H  H3  1  0.015  0.793  0.793  1.0
  H  H4  1  0.400  0.793  0.015  1.0
  H  H5  1  0.793  0.400  0.793  1.0
  H  H6  1  0.793  0.793  0.400  1.0
  H  H7  1  0.400  0.015  0.793  1.0
  H  H8  1  0.793  0.015  0.400  1.0
  H  H9  1  0.793  0.400  0.015  1.0
  H  H10  1  0.793  0.015  0.793  1.0
  H  H11  1  0.793  0.793  0.015  1.0
  H  H12  1  0.015  0.400  0.793  1.0
  H  H13  1  0.015  0.793  0.400  1.0
  H  H14  1  0.400  0.793  0.793  1.0
  N  N15  1  0.887  0.887  0.887  1.0
  N  N16  1  0.338  0.887  0.887  1.0
  N  N17  1  0.887  0.338  0.887  1.0
  N  N18  1  0.887  0.887  0.338  1.0
  O  O19  1  0.589  0.589  0.589  1.0
  O  O20  1  0.234  0.589  0.589  1.0
  O  O21  1  0.589  0.234  0.589  1.0
  O  O22  1  0.589  0.589  0.234  1.0
  O  O23  1  0.161  0.161  0.161  1.0
  O  O24  1  0.516  0.161  0.161  1.0
  O  O25  1  0.161  0.516  0.161  1.0
  O  O26  1  0.161  0.161  0.516  1.0
[/CIF]
.
The compound described by (MnO4)2Zn(NH3)4 is Silicon tetrafluoride-derived structured and crystallizes in the cubic F-43m space group. The structure is zero-dimensional and consists of eight mangan(iv)-hydroxyd molecules and four Zn(NH3)4 clusters. In each Zn(NH3)4 cluster, Zn(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1) and three equivalent H(1) atoms. H(1) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_Mn2ZnH12(NO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.457
_cell_length_b   7.457
_cell_length_c   7.457
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   293.152
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.500  0.500  0.500  1.0
  Mn  Mn1  1  0.250  0.250  0.250  1.0
  Zn  Zn2  1  0.000  0.000  0.000  1.0
  H  H3  1  0.015  0.793  0.793  1.0
  H  H4  1  0.400  0.793  0.015  1.0
  H  H5  1  0.793  0.400  0.793  1.0
  H  H6  1  0.793  0.793  0.400  1.0
  H  H7  1  0.400  0.015  0.793  1.0
  H  H8  1  0.793  0.015  0.400  1.0
  H  H9  1  0.793  0.400  0.015  1.0
  H  H10  1  0.793  0.015  0.793  1.0
  H  H11  1  0.793  0.793  0.015  1.0
  H  H12  1  0.015  0.400  0.793  1.0
  H  H13  1  0.015  0.793  0.400  1.0
  H  H14  1  0.400  0.793  0.793  1.0
  N  N15  1  0.887  0.887  0.887  1.0
  N  N16  1  0.338  0.887  0.887  1.0
  N  N17  1  0.887  0.338  0.887  1.0
  N  N18  1  0.887  0.887  0.338  1.0
  O  O19  1  0.589  0.589  0.589  1.0
  O  O20  1  0.234  0.589  0.589  1.0
  O  O21  1  0.589  0.234  0.589  1.0
  O  O22  1  0.589  0.589  0.234  1.0
  O  O23  1  0.161  0.161  0.161  1.0
  O  O24  1  0.516  0.161  0.161  1.0
  O  O25  1  0.161  0.516  0.161  1.0
  O  O26  1  0.161  0.161  0.516  1.0
[/CIF]
.