The structure described by Pb10As3P3(O12Cl)2 crystallizes in the hexagonal P-6 space group. There are four inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to three equivalent O(2) and three equivalent O(5) atoms. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(6) atoms. In the third Pb site, Pb(3) is bonded in a 5-coordinate geometry to one O(1), two equivalent O(3), two equivalent O(4), and two equivalent Cl(1) atoms. In the fourth Pb site, Pb(4) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(3), two equivalent O(4), and two equivalent Cl(1) atoms. As(1) is bonded in a tetrahedral geometry to one O(2), one O(6), and two equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(5), and two equivalent O(3) atoms. There are six inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one P(1) atom. In the second O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Pb(2) and one As(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one Pb(3), two equivalent Pb(2), and one P(1) atom. In the fourth O site, O(2) is bonded in a 4-coordinate geometry to one Pb(4), two equivalent Pb(1), and one As(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one Pb(3), one Pb(4), and one P(1) atom. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to one Pb(3), one Pb(4), and one As(1) atom. Cl(1) is bonded to three equivalent Pb(3) and three equivalent Pb(4) atoms to form face-sharing ClPb6 octahedra. is represented by the CIF file [CIF]
data_As3P3Pb10(ClO12)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.322
_cell_length_b   10.322
_cell_length_c   7.443
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   686.779
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.741  0.047  0.500  1.0
  As  As1  1  0.305  0.259  0.500  1.0
  As  As2  1  0.953  0.695  0.500  1.0
  P  P3  1  0.924  0.287  0.000  1.0
  P  P4  1  0.363  0.076  0.000  1.0
  P  P5  1  0.713  0.637  0.000  1.0
  Pb  Pb6  1  0.000  0.000  0.240  1.0
  Pb  Pb7  1  0.667  0.333  0.751  1.0
  Pb  Pb8  1  0.667  0.333  0.249  1.0
  Pb  Pb9  1  0.000  0.000  0.760  1.0
  Pb  Pb10  1  0.075  0.650  0.000  1.0
  Pb  Pb11  1  0.575  0.925  0.000  1.0
  Pb  Pb12  1  0.350  0.425  0.000  1.0
  Pb  Pb13  1  0.587  0.678  0.500  1.0
  Pb  Pb14  1  0.090  0.413  0.500  1.0
  Pb  Pb15  1  0.322  0.910  0.500  1.0
  Cl  Cl16  1  0.333  0.667  0.250  1.0
  Cl  Cl17  1  0.333  0.667  0.750  1.0
  O  O18  1  0.747  0.192  0.000  1.0
  O  O19  1  0.444  0.253  0.000  1.0
  O  O20  1  0.808  0.556  0.000  1.0
  O  O21  1  0.936  0.146  0.500  1.0
  O  O22  1  0.210  0.064  0.500  1.0
  O  O23  1  0.854  0.790  0.500  1.0
  O  O24  1  0.971  0.391  0.169  1.0
  O  O25  1  0.419  0.029  0.169  1.0
  O  O26  1  0.609  0.581  0.169  1.0
  O  O27  1  0.690  0.929  0.684  1.0
  O  O28  1  0.240  0.310  0.684  1.0
  O  O29  1  0.071  0.760  0.684  1.0
  O  O30  1  0.690  0.929  0.316  1.0
  O  O31  1  0.240  0.310  0.316  1.0
  O  O32  1  0.071  0.760  0.316  1.0
  O  O33  1  0.971  0.391  0.831  1.0
  O  O34  1  0.419  0.029  0.831  1.0
  O  O35  1  0.609  0.581  0.831  1.0
  O  O36  1  0.992  0.182  0.000  1.0
  O  O37  1  0.190  0.008  0.000  1.0
  O  O38  1  0.818  0.810  0.000  1.0
  O  O39  1  0.666  0.162  0.500  1.0
  O  O40  1  0.496  0.334  0.500  1.0
  O  O41  1  0.838  0.504  0.500  1.0
[/CIF]
.
The structure described by Pb10As3P3(O12Cl)2 crystallizes in the hexagonal P-6 space group. There are four inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 6-coordinate geometry to three equivalent O(2) and three equivalent O(5) atoms. In the second Pb site, Pb(2) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(6) atoms. In the third Pb site, Pb(3) is bonded in a 5-coordinate geometry to one O(1), two equivalent O(3), two equivalent O(4), and two equivalent Cl(1) atoms. In the fourth Pb site, Pb(4) is bonded in a 5-coordinate geometry to one O(2), two equivalent O(3), two equivalent O(4), and two equivalent Cl(1) atoms. As(1) is bonded in a tetrahedral geometry to one O(2), one O(6), and two equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(5), and two equivalent O(3) atoms. There are six inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one P(1) atom. In the second O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Pb(2) and one As(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one Pb(3), two equivalent Pb(2), and one P(1) atom. In the fourth O site, O(2) is bonded in a 4-coordinate geometry to one Pb(4), two equivalent Pb(1), and one As(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one Pb(3), one Pb(4), and one P(1) atom. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to one Pb(3), one Pb(4), and one As(1) atom. Cl(1) is bonded to three equivalent Pb(3) and three equivalent Pb(4) atoms to form face-sharing ClPb6 octahedra. is represented by the CIF file [CIF]
data_As3P3Pb10(ClO12)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.322
_cell_length_b   10.322
_cell_length_c   7.443
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   686.779
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.741  0.047  0.500  1.0
  As  As1  1  0.305  0.259  0.500  1.0
  As  As2  1  0.953  0.695  0.500  1.0
  P  P3  1  0.924  0.287  0.000  1.0
  P  P4  1  0.363  0.076  0.000  1.0
  P  P5  1  0.713  0.637  0.000  1.0
  Pb  Pb6  1  0.000  0.000  0.240  1.0
  Pb  Pb7  1  0.667  0.333  0.751  1.0
  Pb  Pb8  1  0.667  0.333  0.249  1.0
  Pb  Pb9  1  0.000  0.000  0.760  1.0
  Pb  Pb10  1  0.075  0.650  0.000  1.0
  Pb  Pb11  1  0.575  0.925  0.000  1.0
  Pb  Pb12  1  0.350  0.425  0.000  1.0
  Pb  Pb13  1  0.587  0.678  0.500  1.0
  Pb  Pb14  1  0.090  0.413  0.500  1.0
  Pb  Pb15  1  0.322  0.910  0.500  1.0
  Cl  Cl16  1  0.333  0.667  0.250  1.0
  Cl  Cl17  1  0.333  0.667  0.750  1.0
  O  O18  1  0.747  0.192  0.000  1.0
  O  O19  1  0.444  0.253  0.000  1.0
  O  O20  1  0.808  0.556  0.000  1.0
  O  O21  1  0.936  0.146  0.500  1.0
  O  O22  1  0.210  0.064  0.500  1.0
  O  O23  1  0.854  0.790  0.500  1.0
  O  O24  1  0.971  0.391  0.169  1.0
  O  O25  1  0.419  0.029  0.169  1.0
  O  O26  1  0.609  0.581  0.169  1.0
  O  O27  1  0.690  0.929  0.684  1.0
  O  O28  1  0.240  0.310  0.684  1.0
  O  O29  1  0.071  0.760  0.684  1.0
  O  O30  1  0.690  0.929  0.316  1.0
  O  O31  1  0.240  0.310  0.316  1.0
  O  O32  1  0.071  0.760  0.316  1.0
  O  O33  1  0.971  0.391  0.831  1.0
  O  O34  1  0.419  0.029  0.831  1.0
  O  O35  1  0.609  0.581  0.831  1.0
  O  O36  1  0.992  0.182  0.000  1.0
  O  O37  1  0.190  0.008  0.000  1.0
  O  O38  1  0.818  0.810  0.000  1.0
  O  O39  1  0.666  0.162  0.500  1.0
  O  O40  1  0.496  0.334  0.500  1.0
  O  O41  1  0.838  0.504  0.500  1.0
[/CIF]
.