The crystal structure described by (NdH12(O3Cl)2)2Cl2 is beta-prime cadmium gold structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two NdH12(O3Cl)2 clusters. In each NdH12(O3Cl)2 cluster, Nd(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Nd(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Nd(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Nd(1), one H(5), and one H(6) atom. Cl(1) is bonded in a distorted single-bond geometry to one Nd(1) atom. is represented by the CIF file [CIF]
data_NdH12(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.659
_cell_length_b   8.084
_cell_length_c   9.803
_cell_angle_alpha   93.424
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   526.748
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.645  0.750  0.750  1.0
  Nd  Nd1  1  0.355  0.250  0.250  1.0
  H  H2  1  0.972  0.482  0.683  1.0
  H  H3  1  0.028  0.518  0.317  1.0
  H  H4  1  0.972  0.018  0.817  1.0
  H  H5  1  0.028  0.982  0.183  1.0
  H  H6  1  0.050  0.642  0.615  1.0
  H  H7  1  0.950  0.358  0.385  1.0
  H  H8  1  0.050  0.858  0.885  1.0
  H  H9  1  0.950  0.142  0.115  1.0
  H  H10  1  0.752  0.008  0.541  1.0
  H  H11  1  0.248  0.992  0.459  1.0
  H  H12  1  0.752  0.492  0.959  1.0
  H  H13  1  0.248  0.508  0.041  1.0
  H  H14  1  0.830  0.842  0.468  1.0
  H  H15  1  0.170  0.158  0.532  1.0
  H  H16  1  0.830  0.658  0.032  1.0
  H  H17  1  0.170  0.342  0.968  1.0
  H  H18  1  0.412  0.090  0.761  1.0
  H  H19  1  0.588  0.910  0.239  1.0
  H  H20  1  0.412  0.410  0.739  1.0
  H  H21  1  0.588  0.590  0.261  1.0
  H  H22  1  0.590  0.111  0.866  1.0
  H  H23  1  0.410  0.889  0.134  1.0
  H  H24  1  0.590  0.389  0.634  1.0
  H  H25  1  0.410  0.611  0.366  1.0
  Cl  Cl26  1  0.326  0.745  0.949  1.0
  Cl  Cl27  1  0.674  0.255  0.051  1.0
  Cl  Cl28  1  0.326  0.755  0.551  1.0
  Cl  Cl29  1  0.674  0.245  0.449  1.0
  Cl  Cl30  1  0.861  0.750  0.250  1.0
  Cl  Cl31  1  0.139  0.250  0.750  1.0
  O  O32  1  0.926  0.586  0.646  1.0
  O  O33  1  0.074  0.414  0.354  1.0
  O  O34  1  0.926  0.914  0.854  1.0
  O  O35  1  0.074  0.086  0.146  1.0
  O  O36  1  0.796  0.894  0.558  1.0
  O  O37  1  0.204  0.106  0.442  1.0
  O  O38  1  0.796  0.606  0.942  1.0
  O  O39  1  0.204  0.394  0.058  1.0
  O  O40  1  0.546  0.045  0.783  1.0
  O  O41  1  0.454  0.955  0.217  1.0
  O  O42  1  0.546  0.455  0.717  1.0
  O  O43  1  0.454  0.545  0.283  1.0
[/CIF]
.
The crystal structure described by (NdH12(O3Cl)2)2Cl2 is beta-prime cadmium gold structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two NdH12(O3Cl)2 clusters. In each NdH12(O3Cl)2 cluster, Nd(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent Cl(1) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Nd(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Nd(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Nd(1), one H(5), and one H(6) atom. Cl(1) is bonded in a distorted single-bond geometry to one Nd(1) atom. is represented by the CIF file [CIF]
data_NdH12(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.659
_cell_length_b   8.084
_cell_length_c   9.803
_cell_angle_alpha   93.424
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   526.748
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.645  0.750  0.750  1.0
  Nd  Nd1  1  0.355  0.250  0.250  1.0
  H  H2  1  0.972  0.482  0.683  1.0
  H  H3  1  0.028  0.518  0.317  1.0
  H  H4  1  0.972  0.018  0.817  1.0
  H  H5  1  0.028  0.982  0.183  1.0
  H  H6  1  0.050  0.642  0.615  1.0
  H  H7  1  0.950  0.358  0.385  1.0
  H  H8  1  0.050  0.858  0.885  1.0
  H  H9  1  0.950  0.142  0.115  1.0
  H  H10  1  0.752  0.008  0.541  1.0
  H  H11  1  0.248  0.992  0.459  1.0
  H  H12  1  0.752  0.492  0.959  1.0
  H  H13  1  0.248  0.508  0.041  1.0
  H  H14  1  0.830  0.842  0.468  1.0
  H  H15  1  0.170  0.158  0.532  1.0
  H  H16  1  0.830  0.658  0.032  1.0
  H  H17  1  0.170  0.342  0.968  1.0
  H  H18  1  0.412  0.090  0.761  1.0
  H  H19  1  0.588  0.910  0.239  1.0
  H  H20  1  0.412  0.410  0.739  1.0
  H  H21  1  0.588  0.590  0.261  1.0
  H  H22  1  0.590  0.111  0.866  1.0
  H  H23  1  0.410  0.889  0.134  1.0
  H  H24  1  0.590  0.389  0.634  1.0
  H  H25  1  0.410  0.611  0.366  1.0
  Cl  Cl26  1  0.326  0.745  0.949  1.0
  Cl  Cl27  1  0.674  0.255  0.051  1.0
  Cl  Cl28  1  0.326  0.755  0.551  1.0
  Cl  Cl29  1  0.674  0.245  0.449  1.0
  Cl  Cl30  1  0.861  0.750  0.250  1.0
  Cl  Cl31  1  0.139  0.250  0.750  1.0
  O  O32  1  0.926  0.586  0.646  1.0
  O  O33  1  0.074  0.414  0.354  1.0
  O  O34  1  0.926  0.914  0.854  1.0
  O  O35  1  0.074  0.086  0.146  1.0
  O  O36  1  0.796  0.894  0.558  1.0
  O  O37  1  0.204  0.106  0.442  1.0
  O  O38  1  0.796  0.606  0.942  1.0
  O  O39  1  0.204  0.394  0.058  1.0
  O  O40  1  0.546  0.045  0.783  1.0
  O  O41  1  0.454  0.955  0.217  1.0
  O  O42  1  0.546  0.455  0.717  1.0
  O  O43  1  0.454  0.545  0.283  1.0
[/CIF]
.