The crystal structure described by Na2RuN5H5O12 crystallizes in the monoclinic C2/m space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 8-coordinate geometry to two equivalent O(3), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. In the second Na site, Na(2) is bonded in a 8-coordinate geometry to two equivalent H(3), two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms. Ru(1) is bonded in an octahedral geometry to one N(1), two equivalent N(2), two equivalent N(3), and one O(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Ru(1) and one O(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ru(1), one O(3), and one O(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ru(1), one O(5), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one H(3) atom. In the third H site, H(3) is bonded in a distorted L-shaped geometry to one Na(2) and one H(2) atom. There are seven inequivalent O sites. In the first O site, O(5) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(3) atom. In the second O site, O(6) is bonded in a distorted L-shaped geometry to one Na(1) and one N(3) atom. In the third O site, O(7) is bonded in a distorted trigonal planar geometry to one Na(1), one Na(2), and one O(4) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(7) atom. In the fifth O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Na(2), one Ru(1), and one H(1) atom. In the sixth O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the seventh O site, O(3) is bonded in a single-bond geometry to one Na(1) and one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na2H5RuN5O12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.019
_cell_length_b   10.019
_cell_length_c   7.802
_cell_angle_alpha   71.361
_cell_angle_beta   71.361
_cell_angle_gamma   95.329
_symmetry_Int_Tables_number   1
_cell_volume   686.362
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.000  0.000  1.0
  Na  Na1  1  0.000  0.500  0.000  1.0
  Na  Na2  1  0.130  0.870  0.500  1.0
  Na  Na3  1  0.870  0.130  0.500  1.0
  H  H4  1  0.078  0.078  0.705  1.0
  H  H5  1  0.922  0.922  0.295  1.0
  H  H6  1  0.188  0.786  0.192  1.0
  H  H7  1  0.786  0.188  0.192  1.0
  H  H8  1  0.812  0.214  0.808  1.0
  H  H9  1  0.214  0.812  0.808  1.0
  H  H10  1  0.772  0.246  0.234  1.0
  H  H11  1  0.246  0.772  0.234  1.0
  H  H12  1  0.228  0.754  0.766  1.0
  H  H13  1  0.754  0.228  0.766  1.0
  Ru  Ru14  1  0.270  0.270  0.421  1.0
  Ru  Ru15  1  0.730  0.730  0.579  1.0
  N  N16  1  0.420  0.420  0.311  1.0
  N  N17  1  0.580  0.580  0.689  1.0
  N  N18  1  0.361  0.160  0.625  1.0
  N  N19  1  0.160  0.361  0.625  1.0
  N  N20  1  0.639  0.840  0.375  1.0
  N  N21  1  0.840  0.639  0.375  1.0
  N  N22  1  0.362  0.171  0.225  1.0
  N  N23  1  0.171  0.362  0.225  1.0
  N  N24  1  0.638  0.829  0.775  1.0
  N  N25  1  0.829  0.638  0.775  1.0
  O  O26  1  0.103  0.103  0.565  1.0
  O  O27  1  0.897  0.897  0.435  1.0
  O  O28  1  0.484  0.484  0.742  1.0
  O  O29  1  0.516  0.516  0.258  1.0
  O  O30  1  0.304  0.069  0.789  1.0
  O  O31  1  0.069  0.304  0.789  1.0
  O  O32  1  0.696  0.931  0.211  1.0
  O  O33  1  0.931  0.696  0.211  1.0
  O  O34  1  0.514  0.207  0.548  1.0
  O  O35  1  0.207  0.514  0.548  1.0
  O  O36  1  0.486  0.793  0.452  1.0
  O  O37  1  0.793  0.486  0.452  1.0
  O  O38  1  0.283  0.073  0.213  1.0
  O  O39  1  0.073  0.283  0.213  1.0
  O  O40  1  0.717  0.927  0.787  1.0
  O  O41  1  0.927  0.717  0.787  1.0
  O  O42  1  0.492  0.214  0.119  1.0
  O  O43  1  0.214  0.492  0.119  1.0
  O  O44  1  0.508  0.786  0.881  1.0
  O  O45  1  0.786  0.508  0.881  1.0
  O  O46  1  0.141  0.581  0.665  1.0
  O  O47  1  0.581  0.141  0.665  1.0
  O  O48  1  0.859  0.419  0.335  1.0
  O  O49  1  0.419  0.859  0.335  1.0
[/CIF]
.
The crystal structure described by Na2RuN5H5O12 crystallizes in the monoclinic C2/m space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 8-coordinate geometry to two equivalent O(3), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. In the second Na site, Na(2) is bonded in a 8-coordinate geometry to two equivalent H(3), two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms. Ru(1) is bonded in an octahedral geometry to one N(1), two equivalent N(2), two equivalent N(3), and one O(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Ru(1) and one O(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ru(1), one O(3), and one O(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ru(1), one O(5), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one H(3) atom. In the third H site, H(3) is bonded in a distorted L-shaped geometry to one Na(2) and one H(2) atom. There are seven inequivalent O sites. In the first O site, O(5) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(3) atom. In the second O site, O(6) is bonded in a distorted L-shaped geometry to one Na(1) and one N(3) atom. In the third O site, O(7) is bonded in a distorted trigonal planar geometry to one Na(1), one Na(2), and one O(4) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(7) atom. In the fifth O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Na(2), one Ru(1), and one H(1) atom. In the sixth O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the seventh O site, O(3) is bonded in a single-bond geometry to one Na(1) and one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na2H5RuN5O12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.019
_cell_length_b   10.019
_cell_length_c   7.802
_cell_angle_alpha   71.361
_cell_angle_beta   71.361
_cell_angle_gamma   95.329
_symmetry_Int_Tables_number   1
_cell_volume   686.362
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.000  0.000  1.0
  Na  Na1  1  0.000  0.500  0.000  1.0
  Na  Na2  1  0.130  0.870  0.500  1.0
  Na  Na3  1  0.870  0.130  0.500  1.0
  H  H4  1  0.078  0.078  0.705  1.0
  H  H5  1  0.922  0.922  0.295  1.0
  H  H6  1  0.188  0.786  0.192  1.0
  H  H7  1  0.786  0.188  0.192  1.0
  H  H8  1  0.812  0.214  0.808  1.0
  H  H9  1  0.214  0.812  0.808  1.0
  H  H10  1  0.772  0.246  0.234  1.0
  H  H11  1  0.246  0.772  0.234  1.0
  H  H12  1  0.228  0.754  0.766  1.0
  H  H13  1  0.754  0.228  0.766  1.0
  Ru  Ru14  1  0.270  0.270  0.421  1.0
  Ru  Ru15  1  0.730  0.730  0.579  1.0
  N  N16  1  0.420  0.420  0.311  1.0
  N  N17  1  0.580  0.580  0.689  1.0
  N  N18  1  0.361  0.160  0.625  1.0
  N  N19  1  0.160  0.361  0.625  1.0
  N  N20  1  0.639  0.840  0.375  1.0
  N  N21  1  0.840  0.639  0.375  1.0
  N  N22  1  0.362  0.171  0.225  1.0
  N  N23  1  0.171  0.362  0.225  1.0
  N  N24  1  0.638  0.829  0.775  1.0
  N  N25  1  0.829  0.638  0.775  1.0
  O  O26  1  0.103  0.103  0.565  1.0
  O  O27  1  0.897  0.897  0.435  1.0
  O  O28  1  0.484  0.484  0.742  1.0
  O  O29  1  0.516  0.516  0.258  1.0
  O  O30  1  0.304  0.069  0.789  1.0
  O  O31  1  0.069  0.304  0.789  1.0
  O  O32  1  0.696  0.931  0.211  1.0
  O  O33  1  0.931  0.696  0.211  1.0
  O  O34  1  0.514  0.207  0.548  1.0
  O  O35  1  0.207  0.514  0.548  1.0
  O  O36  1  0.486  0.793  0.452  1.0
  O  O37  1  0.793  0.486  0.452  1.0
  O  O38  1  0.283  0.073  0.213  1.0
  O  O39  1  0.073  0.283  0.213  1.0
  O  O40  1  0.717  0.927  0.787  1.0
  O  O41  1  0.927  0.717  0.787  1.0
  O  O42  1  0.492  0.214  0.119  1.0
  O  O43  1  0.214  0.492  0.119  1.0
  O  O44  1  0.508  0.786  0.881  1.0
  O  O45  1  0.786  0.508  0.881  1.0
  O  O46  1  0.141  0.581  0.665  1.0
  O  O47  1  0.581  0.141  0.665  1.0
  O  O48  1  0.859  0.419  0.335  1.0
  O  O49  1  0.419  0.859  0.335  1.0
[/CIF]
.