The compound described by (Mo2Cl9)2(N2)3 is Indium-derived structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of six ammonia atoms and two Mo2Cl9 clusters. In each Mo2Cl9 cluster, Mo(1) is bonded to three equivalent Cl(1) and three equivalent Cl(2) atoms to form face-sharing MoCl6 octahedra. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom. In the second Cl site, Cl(1) is bonded in a 2-coordinate geometry to two equivalent Mo(1) atoms. is represented by the CIF file [CIF]
data_Mo2(NCl3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.257
_cell_length_b   7.257
_cell_length_c   17.128
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   781.229
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.333  0.667  0.669  1.0
  Mo  Mo1  1  0.667  0.333  0.331  1.0
  Mo  Mo2  1  0.667  0.333  0.169  1.0
  Mo  Mo3  1  0.333  0.667  0.831  1.0
  N  N4  1  0.000  0.000  0.250  1.0
  N  N5  1  0.000  0.000  0.750  1.0
  N  N6  1  0.333  0.667  0.429  1.0
  N  N7  1  0.667  0.333  0.571  1.0
  N  N8  1  0.667  0.333  0.929  1.0
  N  N9  1  0.333  0.667  0.071  1.0
  Cl  Cl10  1  0.504  0.496  0.250  1.0
  Cl  Cl11  1  0.504  0.007  0.250  1.0
  Cl  Cl12  1  0.993  0.496  0.250  1.0
  Cl  Cl13  1  0.496  0.504  0.750  1.0
  Cl  Cl14  1  0.496  0.993  0.750  1.0
  Cl  Cl15  1  0.007  0.504  0.750  1.0
  Cl  Cl16  1  0.820  0.180  0.403  1.0
  Cl  Cl17  1  0.820  0.640  0.403  1.0
  Cl  Cl18  1  0.360  0.180  0.403  1.0
  Cl  Cl19  1  0.180  0.820  0.597  1.0
  Cl  Cl20  1  0.180  0.360  0.597  1.0
  Cl  Cl21  1  0.640  0.820  0.597  1.0
  Cl  Cl22  1  0.180  0.820  0.903  1.0
  Cl  Cl23  1  0.180  0.360  0.903  1.0
  Cl  Cl24  1  0.640  0.820  0.903  1.0
  Cl  Cl25  1  0.820  0.180  0.097  1.0
  Cl  Cl26  1  0.820  0.640  0.097  1.0
  Cl  Cl27  1  0.360  0.180  0.097  1.0
[/CIF]
.
The compound described by (Mo2Cl9)2(N2)3 is Indium-derived structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of six ammonia atoms and two Mo2Cl9 clusters. In each Mo2Cl9 cluster, Mo(1) is bonded to three equivalent Cl(1) and three equivalent Cl(2) atoms to form face-sharing MoCl6 octahedra. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom. In the second Cl site, Cl(1) is bonded in a 2-coordinate geometry to two equivalent Mo(1) atoms. is represented by the CIF file [CIF]
data_Mo2(NCl3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.257
_cell_length_b   7.257
_cell_length_c   17.128
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   781.229
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.333  0.667  0.669  1.0
  Mo  Mo1  1  0.667  0.333  0.331  1.0
  Mo  Mo2  1  0.667  0.333  0.169  1.0
  Mo  Mo3  1  0.333  0.667  0.831  1.0
  N  N4  1  0.000  0.000  0.250  1.0
  N  N5  1  0.000  0.000  0.750  1.0
  N  N6  1  0.333  0.667  0.429  1.0
  N  N7  1  0.667  0.333  0.571  1.0
  N  N8  1  0.667  0.333  0.929  1.0
  N  N9  1  0.333  0.667  0.071  1.0
  Cl  Cl10  1  0.504  0.496  0.250  1.0
  Cl  Cl11  1  0.504  0.007  0.250  1.0
  Cl  Cl12  1  0.993  0.496  0.250  1.0
  Cl  Cl13  1  0.496  0.504  0.750  1.0
  Cl  Cl14  1  0.496  0.993  0.750  1.0
  Cl  Cl15  1  0.007  0.504  0.750  1.0
  Cl  Cl16  1  0.820  0.180  0.403  1.0
  Cl  Cl17  1  0.820  0.640  0.403  1.0
  Cl  Cl18  1  0.360  0.180  0.403  1.0
  Cl  Cl19  1  0.180  0.820  0.597  1.0
  Cl  Cl20  1  0.180  0.360  0.597  1.0
  Cl  Cl21  1  0.640  0.820  0.597  1.0
  Cl  Cl22  1  0.180  0.820  0.903  1.0
  Cl  Cl23  1  0.180  0.360  0.903  1.0
  Cl  Cl24  1  0.640  0.820  0.903  1.0
  Cl  Cl25  1  0.820  0.180  0.097  1.0
  Cl  Cl26  1  0.820  0.640  0.097  1.0
  Cl  Cl27  1  0.360  0.180  0.097  1.0
[/CIF]
.