The material described by PtN4HCl3NCl is Indium-derived structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of nine chloramine molecules and nine PtN4HCl3 clusters. In each PtN4HCl3 cluster, Pt(1) is bonded in a trigonal bipyramidal geometry to one N(2), one N(4), two equivalent N(1), and one Cl(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one Pt(1) and two equivalent Cl(3) atoms. In the third N site, N(4) is bonded in a single-bond geometry to one Pt(1) atom. H(1) is bonded in a bent 120 degrees geometry to two equivalent Cl(3) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(3) is bonded in a distorted single-bond geometry to one N(2) and one H(1) atom. is represented by the CIF file [CIF]
data_HPtN5Cl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.250
_cell_length_b   11.250
_cell_length_c   11.250
_cell_angle_alpha   115.025
_cell_angle_beta   115.025
_cell_angle_gamma   115.025
_symmetry_Int_Tables_number   1
_cell_volume   795.137
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.100  0.100  0.798  1.0
  H  H1  1  0.798  0.100  0.100  1.0
  H  H2  1  0.100  0.798  0.100  1.0
  Pt  Pt3  1  0.282  0.282  0.647  1.0
  Pt  Pt4  1  0.647  0.282  0.282  1.0
  Pt  Pt5  1  0.282  0.647  0.282  1.0
  N  N6  1  0.265  0.769  0.431  1.0
  N  N7  1  0.431  0.265  0.769  1.0
  N  N8  1  0.769  0.265  0.431  1.0
  N  N9  1  0.769  0.431  0.265  1.0
  N  N10  1  0.265  0.431  0.769  1.0
  N  N11  1  0.431  0.769  0.265  1.0
  N  N12  1  0.069  0.069  0.597  1.0
  N  N13  1  0.597  0.069  0.069  1.0
  N  N14  1  0.069  0.597  0.069  1.0
  N  N15  1  0.631  0.631  0.139  1.0
  N  N16  1  0.139  0.631  0.631  1.0
  N  N17  1  0.631  0.139  0.631  1.0
  N  N18  1  0.092  0.092  0.385  1.0
  N  N19  1  0.385  0.092  0.092  1.0
  N  N20  1  0.092  0.385  0.092  1.0
  Cl  Cl21  1  0.606  0.606  0.258  1.0
  Cl  Cl22  1  0.258  0.606  0.606  1.0
  Cl  Cl23  1  0.606  0.258  0.606  1.0
  Cl  Cl24  1  0.517  0.517  0.703  1.0
  Cl  Cl25  1  0.703  0.517  0.517  1.0
  Cl  Cl26  1  0.517  0.703  0.517  1.0
  Cl  Cl27  1  0.182  0.036  0.739  1.0
  Cl  Cl28  1  0.739  0.182  0.036  1.0
  Cl  Cl29  1  0.036  0.182  0.739  1.0
  Cl  Cl30  1  0.036  0.739  0.182  1.0
  Cl  Cl31  1  0.182  0.739  0.036  1.0
  Cl  Cl32  1  0.739  0.036  0.182  1.0
[/CIF]
.
The material described by PtN4HCl3NCl is Indium-derived structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of nine chloramine molecules and nine PtN4HCl3 clusters. In each PtN4HCl3 cluster, Pt(1) is bonded in a trigonal bipyramidal geometry to one N(2), one N(4), two equivalent N(1), and one Cl(2) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one Pt(1) and two equivalent Cl(3) atoms. In the third N site, N(4) is bonded in a single-bond geometry to one Pt(1) atom. H(1) is bonded in a bent 120 degrees geometry to two equivalent Cl(3) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(3) is bonded in a distorted single-bond geometry to one N(2) and one H(1) atom. is represented by the CIF file [CIF]
data_HPtN5Cl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.250
_cell_length_b   11.250
_cell_length_c   11.250
_cell_angle_alpha   115.025
_cell_angle_beta   115.025
_cell_angle_gamma   115.025
_symmetry_Int_Tables_number   1
_cell_volume   795.137
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.100  0.100  0.798  1.0
  H  H1  1  0.798  0.100  0.100  1.0
  H  H2  1  0.100  0.798  0.100  1.0
  Pt  Pt3  1  0.282  0.282  0.647  1.0
  Pt  Pt4  1  0.647  0.282  0.282  1.0
  Pt  Pt5  1  0.282  0.647  0.282  1.0
  N  N6  1  0.265  0.769  0.431  1.0
  N  N7  1  0.431  0.265  0.769  1.0
  N  N8  1  0.769  0.265  0.431  1.0
  N  N9  1  0.769  0.431  0.265  1.0
  N  N10  1  0.265  0.431  0.769  1.0
  N  N11  1  0.431  0.769  0.265  1.0
  N  N12  1  0.069  0.069  0.597  1.0
  N  N13  1  0.597  0.069  0.069  1.0
  N  N14  1  0.069  0.597  0.069  1.0
  N  N15  1  0.631  0.631  0.139  1.0
  N  N16  1  0.139  0.631  0.631  1.0
  N  N17  1  0.631  0.139  0.631  1.0
  N  N18  1  0.092  0.092  0.385  1.0
  N  N19  1  0.385  0.092  0.092  1.0
  N  N20  1  0.092  0.385  0.092  1.0
  Cl  Cl21  1  0.606  0.606  0.258  1.0
  Cl  Cl22  1  0.258  0.606  0.606  1.0
  Cl  Cl23  1  0.606  0.258  0.606  1.0
  Cl  Cl24  1  0.517  0.517  0.703  1.0
  Cl  Cl25  1  0.703  0.517  0.517  1.0
  Cl  Cl26  1  0.517  0.703  0.517  1.0
  Cl  Cl27  1  0.182  0.036  0.739  1.0
  Cl  Cl28  1  0.739  0.182  0.036  1.0
  Cl  Cl29  1  0.036  0.182  0.739  1.0
  Cl  Cl30  1  0.036  0.739  0.182  1.0
  Cl  Cl31  1  0.182  0.739  0.036  1.0
  Cl  Cl32  1  0.739  0.036  0.182  1.0
[/CIF]
.