The material described by RbMg6V crystallizes in the orthorhombic Amm2 space group. Rb(1) is bonded in a 14-coordinate geometry to two equivalent Rb(1); two equivalent Mg(3); two equivalent Mg(4); four Mg(1,1); and four equivalent Mg(2) atoms. There are five inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Rb(1), two equivalent Mg(1), two equivalent Mg(3), two equivalent Mg(4), and four equivalent Mg(2) atoms to form a mixture of corner and face-sharing MgRb2Mg10 cuboctahedra. In the second Mg site, Mg(1) is bonded to two equivalent Rb(1), two equivalent Mg(1), two equivalent Mg(3), two equivalent Mg(4), and four equivalent Mg(2) atoms to form a mixture of corner and face-sharing MgRb2Mg10 cuboctahedra. In the third Mg site, Mg(2) is bonded in a 2-coordinate geometry to two equivalent Rb(1); four Mg(1,1); and two equivalent V(1) atoms. In the fourth Mg site, Mg(3) is bonded in a 2-coordinate geometry to two equivalent Rb(1); four Mg(1,1); and two equivalent V(1) atoms. In the fifth Mg site, Mg(4) is bonded in a 2-coordinate geometry to two equivalent Rb(1); four Mg(1,1); and two equivalent V(1) atoms. V(1) is bonded in a body-centered cubic geometry to two equivalent Mg(3), two equivalent Mg(4), and four equivalent Mg(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbMg6V
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.015
_cell_length_b   8.015
_cell_length_c   3.290
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.096
_symmetry_Int_Tables_number   1
_cell_volume   211.328
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.622  0.622  0.500  1.0
  Mg  Mg1  1  0.634  0.125  0.500  1.0
  Mg  Mg2  1  0.125  0.634  0.500  1.0
  Mg  Mg3  1  0.926  0.333  0.000  1.0
  Mg  Mg4  1  0.333  0.926  0.000  1.0
  Mg  Mg5  1  0.323  0.323  0.000  1.0
  Mg  Mg6  1  0.918  0.918  0.000  1.0
  V  V7  1  0.119  0.119  0.500  1.0
[/CIF]
.
The material described by RbMg6V crystallizes in the orthorhombic Amm2 space group. Rb(1) is bonded in a 14-coordinate geometry to two equivalent Rb(1); two equivalent Mg(3); two equivalent Mg(4); four Mg(1,1); and four equivalent Mg(2) atoms. There are five inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Rb(1), two equivalent Mg(1), two equivalent Mg(3), two equivalent Mg(4), and four equivalent Mg(2) atoms to form a mixture of corner and face-sharing MgRb2Mg10 cuboctahedra. In the second Mg site, Mg(1) is bonded to two equivalent Rb(1), two equivalent Mg(1), two equivalent Mg(3), two equivalent Mg(4), and four equivalent Mg(2) atoms to form a mixture of corner and face-sharing MgRb2Mg10 cuboctahedra. In the third Mg site, Mg(2) is bonded in a 2-coordinate geometry to two equivalent Rb(1); four Mg(1,1); and two equivalent V(1) atoms. In the fourth Mg site, Mg(3) is bonded in a 2-coordinate geometry to two equivalent Rb(1); four Mg(1,1); and two equivalent V(1) atoms. In the fifth Mg site, Mg(4) is bonded in a 2-coordinate geometry to two equivalent Rb(1); four Mg(1,1); and two equivalent V(1) atoms. V(1) is bonded in a body-centered cubic geometry to two equivalent Mg(3), two equivalent Mg(4), and four equivalent Mg(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbMg6V
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.015
_cell_length_b   8.015
_cell_length_c   3.290
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.096
_symmetry_Int_Tables_number   1
_cell_volume   211.328
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.622  0.622  0.500  1.0
  Mg  Mg1  1  0.634  0.125  0.500  1.0
  Mg  Mg2  1  0.125  0.634  0.500  1.0
  Mg  Mg3  1  0.926  0.333  0.000  1.0
  Mg  Mg4  1  0.333  0.926  0.000  1.0
  Mg  Mg5  1  0.323  0.323  0.000  1.0
  Mg  Mg6  1  0.918  0.918  0.000  1.0
  V  V7  1  0.119  0.119  0.500  1.0
[/CIF]
.