The material structure described by SnI4(S)16 is Indium-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of eight tin(iv) iodide molecules and eight S clusters. In each S cluster, there are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(6) and one S(7) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(4) and one S(7) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one S(5) and one S(6) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(2) and one S(4) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one S(3) and one S(8) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the seventh S site, S(7) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the eighth S site, S(8) is bonded in a single-bond geometry to one S(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sn(S4I)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.599
_cell_length_b   13.990
_cell_length_c   13.093
_cell_angle_alpha   65.141
_cell_angle_beta   60.397
_cell_angle_gamma   54.462
_symmetry_Int_Tables_number   1
_cell_volume   1858.202
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.008  0.992  0.992  1.0
  Sn  Sn1  1  0.258  0.242  0.242  1.0
  S  S2  1  0.838  0.092  0.591  1.0
  S  S3  1  0.647  0.177  0.449  1.0
  S  S4  1  0.370  0.864  0.533  1.0
  S  S5  1  0.812  0.605  0.722  1.0
  S  S6  1  0.328  0.743  0.516  1.0
  S  S7  1  0.516  0.783  0.576  1.0
  S  S8  1  0.802  0.147  0.426  1.0
  S  S9  1  0.734  0.837  0.922  1.0
  S  S10  1  0.727  0.449  0.177  1.0
  S  S11  1  0.126  0.576  0.783  1.0
  S  S12  1  0.717  0.018  0.880  1.0
  S  S13  1  0.749  0.772  0.080  1.0
  S  S14  1  0.862  0.722  0.605  1.0
  S  S15  1  0.478  0.591  0.092  1.0
  S  S16  1  0.645  0.438  0.388  1.0
  S  S17  1  0.659  0.772  0.412  1.0
  S  S18  1  0.386  0.880  0.018  1.0
  S  S19  1  0.528  0.388  0.438  1.0
  S  S20  1  0.232  0.533  0.864  1.0
  S  S21  1  0.507  0.922  0.837  1.0
  S  S22  1  0.170  0.850  0.501  1.0
  S  S23  1  0.824  0.625  0.448  1.0
  S  S24  1  0.103  0.448  0.625  1.0
  S  S25  1  0.674  0.124  0.734  1.0
  S  S26  1  0.467  0.734  0.124  1.0
  S  S27  1  0.413  0.516  0.743  1.0
  S  S28  1  0.158  0.412  0.772  1.0
  S  S29  1  0.400  0.080  0.772  1.0
  S  S30  1  0.801  0.523  0.603  1.0
  S  S31  1  0.625  0.426  0.147  1.0
  S  S32  1  0.073  0.603  0.523  1.0
  S  S33  1  0.478  0.501  0.850  1.0
  I  I34  1  0.193  0.769  0.022  1.0
  I  I35  1  0.257  0.445  0.218  1.0
  I  I36  1  0.016  0.022  0.769  1.0
  I  I37  1  0.805  0.993  0.170  1.0
  I  I38  1  0.481  0.057  0.234  1.0
  I  I39  1  0.228  0.234  0.057  1.0
  I  I40  1  0.080  0.218  0.445  1.0
  I  I41  1  0.032  0.170  0.993  1.0
[/CIF]
.
The material structure described by SnI4(S)16 is Indium-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of eight tin(iv) iodide molecules and eight S clusters. In each S cluster, there are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(6) and one S(7) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(4) and one S(7) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one S(5) and one S(6) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(2) and one S(4) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one S(3) and one S(8) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the seventh S site, S(7) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the eighth S site, S(8) is bonded in a single-bond geometry to one S(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sn(S4I)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.599
_cell_length_b   13.990
_cell_length_c   13.093
_cell_angle_alpha   65.141
_cell_angle_beta   60.397
_cell_angle_gamma   54.462
_symmetry_Int_Tables_number   1
_cell_volume   1858.202
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.008  0.992  0.992  1.0
  Sn  Sn1  1  0.258  0.242  0.242  1.0
  S  S2  1  0.838  0.092  0.591  1.0
  S  S3  1  0.647  0.177  0.449  1.0
  S  S4  1  0.370  0.864  0.533  1.0
  S  S5  1  0.812  0.605  0.722  1.0
  S  S6  1  0.328  0.743  0.516  1.0
  S  S7  1  0.516  0.783  0.576  1.0
  S  S8  1  0.802  0.147  0.426  1.0
  S  S9  1  0.734  0.837  0.922  1.0
  S  S10  1  0.727  0.449  0.177  1.0
  S  S11  1  0.126  0.576  0.783  1.0
  S  S12  1  0.717  0.018  0.880  1.0
  S  S13  1  0.749  0.772  0.080  1.0
  S  S14  1  0.862  0.722  0.605  1.0
  S  S15  1  0.478  0.591  0.092  1.0
  S  S16  1  0.645  0.438  0.388  1.0
  S  S17  1  0.659  0.772  0.412  1.0
  S  S18  1  0.386  0.880  0.018  1.0
  S  S19  1  0.528  0.388  0.438  1.0
  S  S20  1  0.232  0.533  0.864  1.0
  S  S21  1  0.507  0.922  0.837  1.0
  S  S22  1  0.170  0.850  0.501  1.0
  S  S23  1  0.824  0.625  0.448  1.0
  S  S24  1  0.103  0.448  0.625  1.0
  S  S25  1  0.674  0.124  0.734  1.0
  S  S26  1  0.467  0.734  0.124  1.0
  S  S27  1  0.413  0.516  0.743  1.0
  S  S28  1  0.158  0.412  0.772  1.0
  S  S29  1  0.400  0.080  0.772  1.0
  S  S30  1  0.801  0.523  0.603  1.0
  S  S31  1  0.625  0.426  0.147  1.0
  S  S32  1  0.073  0.603  0.523  1.0
  S  S33  1  0.478  0.501  0.850  1.0
  I  I34  1  0.193  0.769  0.022  1.0
  I  I35  1  0.257  0.445  0.218  1.0
  I  I36  1  0.016  0.022  0.769  1.0
  I  I37  1  0.805  0.993  0.170  1.0
  I  I38  1  0.481  0.057  0.234  1.0
  I  I39  1  0.228  0.234  0.057  1.0
  I  I40  1  0.080  0.218  0.445  1.0
  I  I41  1  0.032  0.170  0.993  1.0
[/CIF]
.