The crystal structure described by (CN6)2Cl2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two CN6 clusters. In each CN6 cluster, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 150 degrees geometry to one C(1) and one N(4) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one C(1) and one N(5) atom. In the third N site, N(3) is bonded in a distorted bent 150 degrees geometry to one C(1) and one N(6) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth N site, N(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(3) atom. is represented by the CIF file [CIF]
data_CN6Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.703
_cell_length_b   6.541
_cell_length_c   6.526
_cell_angle_alpha   120.755
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   282.560
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.750  0.997  1.000  1.0
  C  C1  1  0.250  0.003  0.000  1.0
  N  N2  1  0.750  0.240  0.118  1.0
  N  N3  1  0.750  0.883  0.127  1.0
  N  N4  1  0.750  0.868  0.756  1.0
  N  N5  1  0.250  0.760  0.882  1.0
  N  N6  1  0.250  0.117  0.873  1.0
  N  N7  1  0.250  0.132  0.244  1.0
  N  N8  1  0.750  0.406  0.311  1.0
  N  N9  1  0.750  0.689  0.094  1.0
  N  N10  1  0.750  0.897  0.594  1.0
  N  N11  1  0.250  0.594  0.689  1.0
  N  N12  1  0.250  0.311  0.906  1.0
  N  N13  1  0.250  0.103  0.406  1.0
  Cl  Cl14  1  0.750  0.351  0.674  1.0
  Cl  Cl15  1  0.250  0.649  0.326  1.0
[/CIF]
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The crystal structure described by (CN6)2Cl2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two CN6 clusters. In each CN6 cluster, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 150 degrees geometry to one C(1) and one N(4) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one C(1) and one N(5) atom. In the third N site, N(3) is bonded in a distorted bent 150 degrees geometry to one C(1) and one N(6) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth N site, N(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(3) atom. is represented by the CIF file [CIF]
data_CN6Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.703
_cell_length_b   6.541
_cell_length_c   6.526
_cell_angle_alpha   120.755
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   282.560
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.750  0.997  1.000  1.0
  C  C1  1  0.250  0.003  0.000  1.0
  N  N2  1  0.750  0.240  0.118  1.0
  N  N3  1  0.750  0.883  0.127  1.0
  N  N4  1  0.750  0.868  0.756  1.0
  N  N5  1  0.250  0.760  0.882  1.0
  N  N6  1  0.250  0.117  0.873  1.0
  N  N7  1  0.250  0.132  0.244  1.0
  N  N8  1  0.750  0.406  0.311  1.0
  N  N9  1  0.750  0.689  0.094  1.0
  N  N10  1  0.750  0.897  0.594  1.0
  N  N11  1  0.250  0.594  0.689  1.0
  N  N12  1  0.250  0.311  0.906  1.0
  N  N13  1  0.250  0.103  0.406  1.0
  Cl  Cl14  1  0.750  0.351  0.674  1.0
  Cl  Cl15  1  0.250  0.649  0.326  1.0
[/CIF]
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