The material described by (HgCl2)2N2(ClHgSO3)2 is Indium-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four ammonia atoms, four mercuric chloride molecules, and four ClHgSO3 clusters. In each ClHgSO3 cluster, Hg(1) is bonded in a distorted linear geometry to one S(1) and one Cl(1) atom. S(1) is bonded in a distorted trigonal planar geometry to one Hg(1), one O(2), and two equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one Hg(1) atom. is represented by the CIF file [CIF]
data_Hg2SN(ClO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.420
_cell_length_b   7.356
_cell_length_c   12.198
_cell_angle_alpha   90.000
_cell_angle_beta   105.257
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   555.672
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.557  0.787  0.114  1.0
  Hg  Hg1  1  0.443  0.287  0.886  1.0
  Hg  Hg2  1  0.098  0.159  0.195  1.0
  Hg  Hg3  1  0.902  0.659  0.805  1.0
  S  S4  1  0.669  0.858  0.338  1.0
  S  S5  1  0.331  0.358  0.662  1.0
  N  N6  1  0.262  0.796  0.523  1.0
  N  N7  1  0.738  0.296  0.477  1.0
  Cl  Cl8  1  0.455  0.721  0.910  1.0
  Cl  Cl9  1  0.545  0.221  0.090  1.0
  Cl  Cl10  1  0.042  0.894  0.084  1.0
  Cl  Cl11  1  0.958  0.394  0.916  1.0
  Cl  Cl12  1  0.150  0.422  0.299  1.0
  Cl  Cl13  1  0.850  0.922  0.701  1.0
  O  O14  1  0.862  0.960  0.334  1.0
  O  O15  1  0.473  0.960  0.334  1.0
  O  O16  1  0.138  0.460  0.666  1.0
  O  O17  1  0.527  0.460  0.666  1.0
  O  O18  1  0.692  0.676  0.384  1.0
  O  O19  1  0.308  0.176  0.616  1.0
[/CIF]
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The material described by (HgCl2)2N2(ClHgSO3)2 is Indium-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four ammonia atoms, four mercuric chloride molecules, and four ClHgSO3 clusters. In each ClHgSO3 cluster, Hg(1) is bonded in a distorted linear geometry to one S(1) and one Cl(1) atom. S(1) is bonded in a distorted trigonal planar geometry to one Hg(1), one O(2), and two equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one S(1) atom. Cl(1) is bonded in a single-bond geometry to one Hg(1) atom. is represented by the CIF file [CIF]
data_Hg2SN(ClO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.420
_cell_length_b   7.356
_cell_length_c   12.198
_cell_angle_alpha   90.000
_cell_angle_beta   105.257
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   555.672
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.557  0.787  0.114  1.0
  Hg  Hg1  1  0.443  0.287  0.886  1.0
  Hg  Hg2  1  0.098  0.159  0.195  1.0
  Hg  Hg3  1  0.902  0.659  0.805  1.0
  S  S4  1  0.669  0.858  0.338  1.0
  S  S5  1  0.331  0.358  0.662  1.0
  N  N6  1  0.262  0.796  0.523  1.0
  N  N7  1  0.738  0.296  0.477  1.0
  Cl  Cl8  1  0.455  0.721  0.910  1.0
  Cl  Cl9  1  0.545  0.221  0.090  1.0
  Cl  Cl10  1  0.042  0.894  0.084  1.0
  Cl  Cl11  1  0.958  0.394  0.916  1.0
  Cl  Cl12  1  0.150  0.422  0.299  1.0
  Cl  Cl13  1  0.850  0.922  0.701  1.0
  O  O14  1  0.862  0.960  0.334  1.0
  O  O15  1  0.473  0.960  0.334  1.0
  O  O16  1  0.138  0.460  0.666  1.0
  O  O17  1  0.527  0.460  0.666  1.0
  O  O18  1  0.692  0.676  0.384  1.0
  O  O19  1  0.308  0.176  0.616  1.0
[/CIF]
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