The compound described by PtN2H8(OCl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two azane;dichloroplatinum(2+);dihydrate molecules. Pt(1) is bonded in an octahedral geometry to two equivalent N(1), one O(1), one O(2), one Cl(1), and one Cl(2) atom. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(3), one H(4), and one H(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Pt(1) and one H(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Pt(1) and one H(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H8PtN2(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.626
_cell_length_b   6.479
_cell_length_c   6.774
_cell_angle_alpha   89.841
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   334.712
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.250  0.178  0.588  1.0
  H  H1  1  0.750  0.822  0.412  1.0
  H  H2  1  0.250  0.825  0.200  1.0
  H  H3  1  0.750  0.175  0.800  1.0
  H  H4  1  0.935  0.111  0.347  1.0
  H  H5  1  0.435  0.889  0.653  1.0
  H  H6  1  0.065  0.889  0.653  1.0
  H  H7  1  0.565  0.111  0.347  1.0
  H  H8  1  0.928  0.342  0.237  1.0
  H  H9  1  0.428  0.658  0.763  1.0
  H  H10  1  0.072  0.658  0.763  1.0
  H  H11  1  0.572  0.342  0.237  1.0
  H  H12  1  0.929  0.131  0.099  1.0
  H  H13  1  0.429  0.869  0.901  1.0
  H  H14  1  0.071  0.869  0.901  1.0
  H  H15  1  0.571  0.131  0.099  1.0
  Pt  Pt16  1  0.250  0.206  0.227  1.0
  Pt  Pt17  1  0.750  0.794  0.773  1.0
  N  N18  1  0.979  0.196  0.227  1.0
  N  N19  1  0.479  0.804  0.773  1.0
  N  N20  1  0.021  0.804  0.773  1.0
  N  N21  1  0.521  0.196  0.227  1.0
  Cl  Cl22  1  0.250  0.355  0.909  1.0
  Cl  Cl23  1  0.750  0.645  0.091  1.0
  Cl  Cl24  1  0.250  0.527  0.391  1.0
  Cl  Cl25  1  0.750  0.473  0.609  1.0
  O  O26  1  0.250  0.063  0.494  1.0
  O  O27  1  0.750  0.937  0.506  1.0
  O  O28  1  0.250  0.928  0.092  1.0
  O  O29  1  0.750  0.072  0.908  1.0
[/CIF]
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The compound described by PtN2H8(OCl)2 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two azane;dichloroplatinum(2+);dihydrate molecules. Pt(1) is bonded in an octahedral geometry to two equivalent N(1), one O(1), one O(2), one Cl(1), and one Cl(2) atom. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(3), one H(4), and one H(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Pt(1) and one H(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Pt(1) and one H(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H8PtN2(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.626
_cell_length_b   6.479
_cell_length_c   6.774
_cell_angle_alpha   89.841
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   334.712
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.250  0.178  0.588  1.0
  H  H1  1  0.750  0.822  0.412  1.0
  H  H2  1  0.250  0.825  0.200  1.0
  H  H3  1  0.750  0.175  0.800  1.0
  H  H4  1  0.935  0.111  0.347  1.0
  H  H5  1  0.435  0.889  0.653  1.0
  H  H6  1  0.065  0.889  0.653  1.0
  H  H7  1  0.565  0.111  0.347  1.0
  H  H8  1  0.928  0.342  0.237  1.0
  H  H9  1  0.428  0.658  0.763  1.0
  H  H10  1  0.072  0.658  0.763  1.0
  H  H11  1  0.572  0.342  0.237  1.0
  H  H12  1  0.929  0.131  0.099  1.0
  H  H13  1  0.429  0.869  0.901  1.0
  H  H14  1  0.071  0.869  0.901  1.0
  H  H15  1  0.571  0.131  0.099  1.0
  Pt  Pt16  1  0.250  0.206  0.227  1.0
  Pt  Pt17  1  0.750  0.794  0.773  1.0
  N  N18  1  0.979  0.196  0.227  1.0
  N  N19  1  0.479  0.804  0.773  1.0
  N  N20  1  0.021  0.804  0.773  1.0
  N  N21  1  0.521  0.196  0.227  1.0
  Cl  Cl22  1  0.250  0.355  0.909  1.0
  Cl  Cl23  1  0.750  0.645  0.091  1.0
  Cl  Cl24  1  0.250  0.527  0.391  1.0
  Cl  Cl25  1  0.750  0.473  0.609  1.0
  O  O26  1  0.250  0.063  0.494  1.0
  O  O27  1  0.750  0.937  0.506  1.0
  O  O28  1  0.250  0.928  0.092  1.0
  O  O29  1  0.750  0.072  0.908  1.0
[/CIF]
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