The compound described by La11Ni4In9 crystallizes in the orthorhombic Cmmm space group. There are five inequivalent La sites. In the first La site, La(1) is bonded in a 10-coordinate geometry to four equivalent Ni(1), two equivalent In(3), and four equivalent In(2) atoms. In the second La site, La(2) is bonded in a distorted body-centered cubic geometry to eight equivalent In(2) atoms. In the third La site, La(3) is bonded in a 2-coordinate geometry to two equivalent Ni(1), two equivalent In(2), and four equivalent In(1) atoms. In the fourth La site, La(4) is bonded in a 8-coordinate geometry to four equivalent In(1) and four equivalent In(2) atoms. In the fifth La site, La(5) is bonded in a 10-coordinate geometry to four equivalent Ni(1), two equivalent In(3), and four equivalent In(1) atoms. Ni(1) is bonded in a 9-coordinate geometry to two equivalent La(1), two equivalent La(3), two equivalent La(5), one In(1), one In(2), and one In(3) atom. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 10-coordinate geometry to two equivalent La(4), two equivalent La(5), four equivalent La(3), one Ni(1), and one In(1) atom. In the second In site, In(2) is bonded in a 10-coordinate geometry to two equivalent La(1), two equivalent La(2), two equivalent La(3), two equivalent La(4), one Ni(1), and one In(2) atom. In the third In site, In(3) is bonded to four equivalent La(1), four equivalent La(5), and four equivalent Ni(1) atoms to form face-sharing InLa8Ni4 cuboctahedra. is represented by the CIF file [CIF]
data_La11In9Ni4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.560
_cell_length_b   13.560
_cell_length_c   3.851
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   112.421
_symmetry_Int_Tables_number   1
_cell_volume   654.453
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.314  0.314  0.000  1.0
  La  La1  1  0.686  0.686  0.000  1.0
  La  La2  1  0.000  0.000  0.000  1.0
  La  La3  1  0.078  0.417  0.000  1.0
  La  La4  1  0.922  0.583  0.000  1.0
  La  La5  1  0.417  0.078  0.000  1.0
  La  La6  1  0.583  0.922  0.000  1.0
  La  La7  1  0.839  0.161  0.000  1.0
  La  La8  1  0.161  0.839  0.000  1.0
  La  La9  1  0.625  0.375  0.000  1.0
  La  La10  1  0.375  0.625  0.000  1.0
  In  In11  1  0.835  0.366  0.500  1.0
  In  In12  1  0.165  0.634  0.500  1.0
  In  In13  1  0.366  0.835  0.500  1.0
  In  In14  1  0.634  0.165  0.500  1.0
  In  In15  1  0.084  0.221  0.500  1.0
  In  In16  1  0.916  0.779  0.500  1.0
  In  In17  1  0.221  0.084  0.500  1.0
  In  In18  1  0.779  0.916  0.500  1.0
  In  In19  1  0.500  0.500  0.500  1.0
  Ni  Ni20  1  0.242  0.447  0.500  1.0
  Ni  Ni21  1  0.758  0.553  0.500  1.0
  Ni  Ni22  1  0.447  0.242  0.500  1.0
  Ni  Ni23  1  0.553  0.758  0.500  1.0
[/CIF]
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The compound described by La11Ni4In9 crystallizes in the orthorhombic Cmmm space group. There are five inequivalent La sites. In the first La site, La(1) is bonded in a 10-coordinate geometry to four equivalent Ni(1), two equivalent In(3), and four equivalent In(2) atoms. In the second La site, La(2) is bonded in a distorted body-centered cubic geometry to eight equivalent In(2) atoms. In the third La site, La(3) is bonded in a 2-coordinate geometry to two equivalent Ni(1), two equivalent In(2), and four equivalent In(1) atoms. In the fourth La site, La(4) is bonded in a 8-coordinate geometry to four equivalent In(1) and four equivalent In(2) atoms. In the fifth La site, La(5) is bonded in a 10-coordinate geometry to four equivalent Ni(1), two equivalent In(3), and four equivalent In(1) atoms. Ni(1) is bonded in a 9-coordinate geometry to two equivalent La(1), two equivalent La(3), two equivalent La(5), one In(1), one In(2), and one In(3) atom. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 10-coordinate geometry to two equivalent La(4), two equivalent La(5), four equivalent La(3), one Ni(1), and one In(1) atom. In the second In site, In(2) is bonded in a 10-coordinate geometry to two equivalent La(1), two equivalent La(2), two equivalent La(3), two equivalent La(4), one Ni(1), and one In(2) atom. In the third In site, In(3) is bonded to four equivalent La(1), four equivalent La(5), and four equivalent Ni(1) atoms to form face-sharing InLa8Ni4 cuboctahedra. is represented by the CIF file [CIF]
data_La11In9Ni4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.560
_cell_length_b   13.560
_cell_length_c   3.851
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   112.421
_symmetry_Int_Tables_number   1
_cell_volume   654.453
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.314  0.314  0.000  1.0
  La  La1  1  0.686  0.686  0.000  1.0
  La  La2  1  0.000  0.000  0.000  1.0
  La  La3  1  0.078  0.417  0.000  1.0
  La  La4  1  0.922  0.583  0.000  1.0
  La  La5  1  0.417  0.078  0.000  1.0
  La  La6  1  0.583  0.922  0.000  1.0
  La  La7  1  0.839  0.161  0.000  1.0
  La  La8  1  0.161  0.839  0.000  1.0
  La  La9  1  0.625  0.375  0.000  1.0
  La  La10  1  0.375  0.625  0.000  1.0
  In  In11  1  0.835  0.366  0.500  1.0
  In  In12  1  0.165  0.634  0.500  1.0
  In  In13  1  0.366  0.835  0.500  1.0
  In  In14  1  0.634  0.165  0.500  1.0
  In  In15  1  0.084  0.221  0.500  1.0
  In  In16  1  0.916  0.779  0.500  1.0
  In  In17  1  0.221  0.084  0.500  1.0
  In  In18  1  0.779  0.916  0.500  1.0
  In  In19  1  0.500  0.500  0.500  1.0
  Ni  Ni20  1  0.242  0.447  0.500  1.0
  Ni  Ni21  1  0.758  0.553  0.500  1.0
  Ni  Ni22  1  0.447  0.242  0.500  1.0
  Ni  Ni23  1  0.553  0.758  0.500  1.0
[/CIF]
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