The crystal structure described by WSCl4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two WSCl4 clusters. W(1) is bonded in a distorted trigonal bipyramidal geometry to one S(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. S(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one W(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF file [CIF]
data_WSCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.709
_cell_length_b   7.947
_cell_length_c   8.072
_cell_angle_alpha   101.243
_cell_angle_beta   94.136
_cell_angle_gamma   93.263
_symmetry_Int_Tables_number   1
_cell_volume   419.872
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.142  0.213  0.760  1.0
  W  W1  1  0.858  0.787  0.240  1.0
  S  S2  1  0.320  0.271  0.992  1.0
  S  S3  1  0.680  0.729  0.008  1.0
  Cl  Cl4  1  0.830  0.142  0.839  1.0
  Cl  Cl5  1  0.833  0.079  0.329  1.0
  Cl  Cl6  1  0.361  0.254  0.564  1.0
  Cl  Cl7  1  0.019  0.469  0.727  1.0
  Cl  Cl8  1  0.981  0.531  0.273  1.0
  Cl  Cl9  1  0.639  0.746  0.436  1.0
  Cl  Cl10  1  0.167  0.921  0.671  1.0
  Cl  Cl11  1  0.170  0.858  0.161  1.0
[/CIF]
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The crystal structure described by WSCl4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two WSCl4 clusters. W(1) is bonded in a distorted trigonal bipyramidal geometry to one S(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. S(1) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one W(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF file [CIF]
data_WSCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.709
_cell_length_b   7.947
_cell_length_c   8.072
_cell_angle_alpha   101.243
_cell_angle_beta   94.136
_cell_angle_gamma   93.263
_symmetry_Int_Tables_number   1
_cell_volume   419.872
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.142  0.213  0.760  1.0
  W  W1  1  0.858  0.787  0.240  1.0
  S  S2  1  0.320  0.271  0.992  1.0
  S  S3  1  0.680  0.729  0.008  1.0
  Cl  Cl4  1  0.830  0.142  0.839  1.0
  Cl  Cl5  1  0.833  0.079  0.329  1.0
  Cl  Cl6  1  0.361  0.254  0.564  1.0
  Cl  Cl7  1  0.019  0.469  0.727  1.0
  Cl  Cl8  1  0.981  0.531  0.273  1.0
  Cl  Cl9  1  0.639  0.746  0.436  1.0
  Cl  Cl10  1  0.167  0.921  0.671  1.0
  Cl  Cl11  1  0.170  0.858  0.161  1.0
[/CIF]
.