The compound described by UMn(MoO4)4 crystallizes in the monoclinic P2/c space group. U(1) is bonded to one O(9), two equivalent O(1), two equivalent O(5), and two equivalent O(8) atoms to form UO7 pentagonal bipyramids that share corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Mo(2)O6 octahedra, corners with two equivalent Mn(1)O7 pentagonal bipyramids, and edges with two equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-30°. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(2), one O(3), one O(7), one O(8), and one O(9) atom to form distorted MoO6 octahedra that share  a cornercorner with one Mo(1)O6 octahedra, corners with two equivalent Mo(2)O6 octahedra,  a cornercorner with one U(1)O7 pentagonal bipyramid,  a cornercorner with one Mn(1)O7 pentagonal bipyramid,  an edgeedge with one Mo(2)O6 octahedra, and  an edgeedge with one U(1)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 6-43°. In the second Mo site, Mo(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form distorted MoO6 octahedra that share  a cornercorner with one Mo(2)O6 octahedra, corners with two equivalent Mo(1)O6 octahedra,  a cornercorner with one U(1)O7 pentagonal bipyramid,  a cornercorner with one Mn(1)O7 pentagonal bipyramid,  an edgeedge with one Mo(1)O6 octahedra, and  an edgeedge with one Mn(1)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 6-47°. Mn(1) is bonded to one O(4), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms to form MnO7 pentagonal bipyramids that share corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Mo(2)O6 octahedra, corners with two equivalent U(1)O7 pentagonal bipyramids, and edges with two equivalent Mo(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-30°. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a trigonal planar geometry to one U(1) and two equivalent Mo(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one U(1), one Mo(1), and one Mo(2) atom. In the third O site, O(2) is bonded in a linear geometry to one Mo(1) and one Mo(2) atom. In the fourth O site, O(3) is bonded in a linear geometry to one Mo(1) and one Mo(2) atom. In the fifth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Mo(2) and one Mn(1) atom. In the sixth O site, O(5) is bonded in a linear geometry to one U(1) and one Mn(1) atom. In the seventh O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(2) and one Mn(1) atom. In the eighth O site, O(7) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mn(1) atom. In the ninth O site, O(8) is bonded in a bent 150 degrees geometry to one U(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_UMn(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.626
_cell_length_b   7.989
_cell_length_c   14.086
_cell_angle_alpha   55.697
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   615.963
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.296  0.500  0.750  1.0
  U  U1  1  0.704  0.500  0.250  1.0
  Mn  Mn2  1  0.693  0.000  0.250  1.0
  Mn  Mn3  1  0.307  0.000  0.750  1.0
  Mo  Mo4  1  0.830  0.303  0.911  1.0
  Mo  Mo5  1  0.170  0.697  0.089  1.0
  Mo  Mo6  1  0.830  0.697  0.589  1.0
  Mo  Mo7  1  0.170  0.303  0.411  1.0
  Mo  Mo8  1  0.823  0.812  0.901  1.0
  Mo  Mo9  1  0.177  0.188  0.099  1.0
  Mo  Mo10  1  0.823  0.188  0.599  1.0
  Mo  Mo11  1  0.177  0.812  0.401  1.0
  O  O12  1  0.847  0.314  0.434  1.0
  O  O13  1  0.153  0.686  0.566  1.0
  O  O14  1  0.846  0.412  0.596  1.0
  O  O15  1  0.154  0.588  0.404  1.0
  O  O16  1  0.842  0.090  0.904  1.0
  O  O17  1  0.158  0.910  0.096  1.0
  O  O18  1  0.940  0.000  0.750  1.0
  O  O19  1  0.060  0.000  0.250  1.0
  O  O20  1  0.299  0.268  0.749  1.0
  O  O21  1  0.701  0.732  0.251  1.0
  O  O22  1  0.433  0.870  0.368  1.0
  O  O23  1  0.567  0.130  0.632  1.0
  O  O24  1  0.153  0.314  0.934  1.0
  O  O25  1  0.847  0.686  0.066  1.0
  O  O26  1  0.299  0.732  0.751  1.0
  O  O27  1  0.701  0.268  0.249  1.0
  O  O28  1  0.844  0.182  0.067  1.0
  O  O29  1  0.156  0.818  0.933  1.0
  O  O30  1  0.570  0.374  0.873  1.0
  O  O31  1  0.430  0.626  0.127  1.0
  O  O32  1  0.567  0.870  0.868  1.0
  O  O33  1  0.433  0.130  0.132  1.0
  O  O34  1  0.158  0.090  0.404  1.0
  O  O35  1  0.842  0.910  0.596  1.0
  O  O36  1  0.941  0.500  0.750  1.0
  O  O37  1  0.059  0.500  0.250  1.0
  O  O38  1  0.570  0.626  0.627  1.0
  O  O39  1  0.430  0.374  0.373  1.0
  O  O40  1  0.846  0.588  0.904  1.0
  O  O41  1  0.154  0.412  0.096  1.0
  O  O42  1  0.844  0.818  0.433  1.0
  O  O43  1  0.156  0.182  0.567  1.0
[/CIF]
.
The compound described by UMn(MoO4)4 crystallizes in the monoclinic P2/c space group. U(1) is bonded to one O(9), two equivalent O(1), two equivalent O(5), and two equivalent O(8) atoms to form UO7 pentagonal bipyramids that share corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Mo(2)O6 octahedra, corners with two equivalent Mn(1)O7 pentagonal bipyramids, and edges with two equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 25-30°. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(2), one O(3), one O(7), one O(8), and one O(9) atom to form distorted MoO6 octahedra that share  a cornercorner with one Mo(1)O6 octahedra, corners with two equivalent Mo(2)O6 octahedra,  a cornercorner with one U(1)O7 pentagonal bipyramid,  a cornercorner with one Mn(1)O7 pentagonal bipyramid,  an edgeedge with one Mo(2)O6 octahedra, and  an edgeedge with one U(1)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 6-43°. In the second Mo site, Mo(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form distorted MoO6 octahedra that share  a cornercorner with one Mo(2)O6 octahedra, corners with two equivalent Mo(1)O6 octahedra,  a cornercorner with one U(1)O7 pentagonal bipyramid,  a cornercorner with one Mn(1)O7 pentagonal bipyramid,  an edgeedge with one Mo(1)O6 octahedra, and  an edgeedge with one Mn(1)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 6-47°. Mn(1) is bonded to one O(4), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms to form MnO7 pentagonal bipyramids that share corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Mo(2)O6 octahedra, corners with two equivalent U(1)O7 pentagonal bipyramids, and edges with two equivalent Mo(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-30°. There are nine inequivalent O sites. In the first O site, O(9) is bonded in a trigonal planar geometry to one U(1) and two equivalent Mo(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one U(1), one Mo(1), and one Mo(2) atom. In the third O site, O(2) is bonded in a linear geometry to one Mo(1) and one Mo(2) atom. In the fourth O site, O(3) is bonded in a linear geometry to one Mo(1) and one Mo(2) atom. In the fifth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Mo(2) and one Mn(1) atom. In the sixth O site, O(5) is bonded in a linear geometry to one U(1) and one Mn(1) atom. In the seventh O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(2) and one Mn(1) atom. In the eighth O site, O(7) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Mn(1) atom. In the ninth O site, O(8) is bonded in a bent 150 degrees geometry to one U(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_UMn(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.626
_cell_length_b   7.989
_cell_length_c   14.086
_cell_angle_alpha   55.697
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   615.963
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.296  0.500  0.750  1.0
  U  U1  1  0.704  0.500  0.250  1.0
  Mn  Mn2  1  0.693  0.000  0.250  1.0
  Mn  Mn3  1  0.307  0.000  0.750  1.0
  Mo  Mo4  1  0.830  0.303  0.911  1.0
  Mo  Mo5  1  0.170  0.697  0.089  1.0
  Mo  Mo6  1  0.830  0.697  0.589  1.0
  Mo  Mo7  1  0.170  0.303  0.411  1.0
  Mo  Mo8  1  0.823  0.812  0.901  1.0
  Mo  Mo9  1  0.177  0.188  0.099  1.0
  Mo  Mo10  1  0.823  0.188  0.599  1.0
  Mo  Mo11  1  0.177  0.812  0.401  1.0
  O  O12  1  0.847  0.314  0.434  1.0
  O  O13  1  0.153  0.686  0.566  1.0
  O  O14  1  0.846  0.412  0.596  1.0
  O  O15  1  0.154  0.588  0.404  1.0
  O  O16  1  0.842  0.090  0.904  1.0
  O  O17  1  0.158  0.910  0.096  1.0
  O  O18  1  0.940  0.000  0.750  1.0
  O  O19  1  0.060  0.000  0.250  1.0
  O  O20  1  0.299  0.268  0.749  1.0
  O  O21  1  0.701  0.732  0.251  1.0
  O  O22  1  0.433  0.870  0.368  1.0
  O  O23  1  0.567  0.130  0.632  1.0
  O  O24  1  0.153  0.314  0.934  1.0
  O  O25  1  0.847  0.686  0.066  1.0
  O  O26  1  0.299  0.732  0.751  1.0
  O  O27  1  0.701  0.268  0.249  1.0
  O  O28  1  0.844  0.182  0.067  1.0
  O  O29  1  0.156  0.818  0.933  1.0
  O  O30  1  0.570  0.374  0.873  1.0
  O  O31  1  0.430  0.626  0.127  1.0
  O  O32  1  0.567  0.870  0.868  1.0
  O  O33  1  0.433  0.130  0.132  1.0
  O  O34  1  0.158  0.090  0.404  1.0
  O  O35  1  0.842  0.910  0.596  1.0
  O  O36  1  0.941  0.500  0.750  1.0
  O  O37  1  0.059  0.500  0.250  1.0
  O  O38  1  0.570  0.626  0.627  1.0
  O  O39  1  0.430  0.374  0.373  1.0
  O  O40  1  0.846  0.588  0.904  1.0
  O  O41  1  0.154  0.412  0.096  1.0
  O  O42  1  0.844  0.818  0.433  1.0
  O  O43  1  0.156  0.182  0.567  1.0
[/CIF]
.