The material structure described by LiCoSbO4 is Spinel-derived structured and crystallizes in the orthorhombic Imma space group. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with six equivalent Co(1)O6 octahedra and corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-60°. Co(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form CoO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Co(1)O6 octahedra, and edges with four equivalent Sb(1)O6 octahedra. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with four equivalent Co(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Co(1), and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded to one Li(1), two equivalent Co(1), and one Sb(1) atom to form a mixture of distorted corner and edge-sharing OLiCo2Sb trigonal pyramids. is represented by the CIF file [CIF]
data_LiCoSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.042
_cell_length_b   6.191
_cell_length_c   6.191
_cell_angle_alpha   60.137
_cell_angle_beta   60.794
_cell_angle_gamma   60.795
_symmetry_Int_Tables_number   1
_cell_volume   165.891
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  0.500  1.0
  Co  Co1  1  0.500  0.500  0.500  1.0
  Li  Li2  1  0.854  0.896  0.896  1.0
  Li  Li3  1  0.146  0.104  0.104  1.0
  O  O4  1  0.727  0.750  0.750  1.0
  O  O5  1  0.274  0.750  0.750  1.0
  O  O6  1  0.726  0.250  0.250  1.0
  O  O7  1  0.273  0.250  0.250  1.0
  O  O8  1  0.723  0.297  0.757  1.0
  O  O9  1  0.723  0.757  0.297  1.0
  O  O10  1  0.277  0.703  0.243  1.0
  O  O11  1  0.277  0.243  0.703  1.0
  Sb  Sb12  1  0.500  0.500  1.000  1.0
  Sb  Sb13  1  0.500  0.000  0.500  1.0
[/CIF]
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The material structure described by LiCoSbO4 is Spinel-derived structured and crystallizes in the orthorhombic Imma space group. Li(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form LiO4 tetrahedra that share corners with six equivalent Co(1)O6 octahedra and corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-60°. Co(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form CoO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Co(1)O6 octahedra, and edges with four equivalent Sb(1)O6 octahedra. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Li(1)O4 tetrahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with four equivalent Co(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Co(1), and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded to one Li(1), two equivalent Co(1), and one Sb(1) atom to form a mixture of distorted corner and edge-sharing OLiCo2Sb trigonal pyramids. is represented by the CIF file [CIF]
data_LiCoSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.042
_cell_length_b   6.191
_cell_length_c   6.191
_cell_angle_alpha   60.137
_cell_angle_beta   60.794
_cell_angle_gamma   60.795
_symmetry_Int_Tables_number   1
_cell_volume   165.891
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  0.500  1.0
  Co  Co1  1  0.500  0.500  0.500  1.0
  Li  Li2  1  0.854  0.896  0.896  1.0
  Li  Li3  1  0.146  0.104  0.104  1.0
  O  O4  1  0.727  0.750  0.750  1.0
  O  O5  1  0.274  0.750  0.750  1.0
  O  O6  1  0.726  0.250  0.250  1.0
  O  O7  1  0.273  0.250  0.250  1.0
  O  O8  1  0.723  0.297  0.757  1.0
  O  O9  1  0.723  0.757  0.297  1.0
  O  O10  1  0.277  0.703  0.243  1.0
  O  O11  1  0.277  0.243  0.703  1.0
  Sb  Sb12  1  0.500  0.500  1.000  1.0
  Sb  Sb13  1  0.500  0.000  0.500  1.0
[/CIF]
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