The compound described by MnWO4WO2(CrO2)3(MnO2)2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of three chromhydroxyd molecules, two manganese;dihydrate molecules, one tungsten;dihydrate molecule, and one MnWO4 cluster. In the MnWO4 cluster, W(1) is bonded in a 2-coordinate geometry to one O(10) and one O(2) atom. Mn(1) is bonded in a distorted linear geometry to one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted L-shaped geometry to one W(1) and one Mn(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Mn(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one Mn(1) atom. In the fourth O site, O(10) is bonded in a distorted single-bond geometry to one W(1) atom. is represented by the CIF card [CIF]
data_Mn3Cr3(WO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.951
_cell_length_b   5.962
_cell_length_c   9.225
_cell_angle_alpha   90.393
_cell_angle_beta   89.883
_cell_angle_gamma   119.940
_symmetry_Int_Tables_number   1
_cell_volume   283.576
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.174  0.165  0.787  1.0
  Mn  Mn1  1  0.340  0.831  0.286  1.0
  Mn  Mn2  1  0.837  0.330  0.292  1.0
  Cr  Cr3  1  0.170  0.664  0.790  1.0
  Cr  Cr4  1  0.665  0.167  0.787  1.0
  Cr  Cr5  1  0.831  0.832  0.287  1.0
  W  W6  1  0.334  0.339  0.510  1.0
  W  W7  1  0.674  0.663  0.008  1.0
  O  O8  1  0.175  0.653  0.402  1.0
  O  O9  1  0.477  0.475  0.656  1.0
  O  O10  1  0.329  0.329  0.891  1.0
  O  O11  1  0.007  0.002  0.693  1.0
  O  O12  1  0.005  0.005  0.195  1.0
  O  O13  1  0.651  0.163  0.409  1.0
  O  O14  1  0.047  0.468  0.661  1.0
  O  O15  1  0.472  0.044  0.661  1.0
  O  O16  1  0.821  0.832  0.904  1.0
  O  O17  1  0.185  0.165  0.406  1.0
  O  O18  1  0.513  0.958  0.163  1.0
  O  O19  1  0.951  0.535  0.149  1.0
  O  O20  1  0.662  0.661  0.388  1.0
  O  O21  1  0.349  0.832  0.902  1.0
  O  O22  1  0.505  0.541  0.155  1.0
  O  O23  1  0.826  0.347  0.904  1.0
[/CIF]
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The compound described by MnWO4WO2(CrO2)3(MnO2)2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of three chromhydroxyd molecules, two manganese;dihydrate molecules, one tungsten;dihydrate molecule, and one MnWO4 cluster. In the MnWO4 cluster, W(1) is bonded in a 2-coordinate geometry to one O(10) and one O(2) atom. Mn(1) is bonded in a distorted linear geometry to one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted L-shaped geometry to one W(1) and one Mn(1) atom. In the second O site, O(3) is bonded in a single-bond geometry to one Mn(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one Mn(1) atom. In the fourth O site, O(10) is bonded in a distorted single-bond geometry to one W(1) atom. is represented by the CIF card [CIF]
data_Mn3Cr3(WO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.951
_cell_length_b   5.962
_cell_length_c   9.225
_cell_angle_alpha   90.393
_cell_angle_beta   89.883
_cell_angle_gamma   119.940
_symmetry_Int_Tables_number   1
_cell_volume   283.576
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.174  0.165  0.787  1.0
  Mn  Mn1  1  0.340  0.831  0.286  1.0
  Mn  Mn2  1  0.837  0.330  0.292  1.0
  Cr  Cr3  1  0.170  0.664  0.790  1.0
  Cr  Cr4  1  0.665  0.167  0.787  1.0
  Cr  Cr5  1  0.831  0.832  0.287  1.0
  W  W6  1  0.334  0.339  0.510  1.0
  W  W7  1  0.674  0.663  0.008  1.0
  O  O8  1  0.175  0.653  0.402  1.0
  O  O9  1  0.477  0.475  0.656  1.0
  O  O10  1  0.329  0.329  0.891  1.0
  O  O11  1  0.007  0.002  0.693  1.0
  O  O12  1  0.005  0.005  0.195  1.0
  O  O13  1  0.651  0.163  0.409  1.0
  O  O14  1  0.047  0.468  0.661  1.0
  O  O15  1  0.472  0.044  0.661  1.0
  O  O16  1  0.821  0.832  0.904  1.0
  O  O17  1  0.185  0.165  0.406  1.0
  O  O18  1  0.513  0.958  0.163  1.0
  O  O19  1  0.951  0.535  0.149  1.0
  O  O20  1  0.662  0.661  0.388  1.0
  O  O21  1  0.349  0.832  0.902  1.0
  O  O22  1  0.505  0.541  0.155  1.0
  O  O23  1  0.826  0.347  0.904  1.0
[/CIF]
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