The material described by Pt(NBr2)2(BrN)2 is Indium-derived structured and crystallizes in the orthorhombic F222 space group. The structure is zero-dimensional and consists of four BrN clusters and four Pt(NBr2)2 clusters. In each BrN cluster, N(2) is bonded in an L-shaped geometry to two equivalent Br(2) atoms. Br(2) is bonded in an L-shaped geometry to two equivalent N(2) atoms. In each Pt(NBr2)2 cluster, Pt(1) is bonded in a distorted octahedral geometry to two N(1,1); two equivalent Br(1); and two equivalent Br(3) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second Br site, Br(3) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pt(Br3N2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.314
_cell_length_b   7.314
_cell_length_c   7.623
_cell_angle_alpha   66.080
_cell_angle_beta   66.080
_cell_angle_gamma   98.905
_symmetry_Int_Tables_number   1
_cell_volume   314.879
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.250  0.750  0.500  1.0
  Br  Br1  1  0.034  0.534  0.931  1.0
  Br  Br2  1  0.466  0.966  0.069  1.0
  Br  Br3  1  0.120  0.120  0.761  1.0
  Br  Br4  1  0.880  0.880  0.239  1.0
  Br  Br5  1  0.978  0.478  0.500  1.0
  Br  Br6  1  0.522  0.022  0.500  1.0
  N  N7  1  0.415  0.585  0.500  1.0
  N  N8  1  0.883  0.117  0.000  1.0
  N  N9  1  0.085  0.915  0.500  1.0
  N  N10  1  0.117  0.883  0.000  1.0
[/CIF]
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The material described by Pt(NBr2)2(BrN)2 is Indium-derived structured and crystallizes in the orthorhombic F222 space group. The structure is zero-dimensional and consists of four BrN clusters and four Pt(NBr2)2 clusters. In each BrN cluster, N(2) is bonded in an L-shaped geometry to two equivalent Br(2) atoms. Br(2) is bonded in an L-shaped geometry to two equivalent N(2) atoms. In each Pt(NBr2)2 cluster, Pt(1) is bonded in a distorted octahedral geometry to two N(1,1); two equivalent Br(1); and two equivalent Br(3) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. There are two inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second Br site, Br(3) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pt(Br3N2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.314
_cell_length_b   7.314
_cell_length_c   7.623
_cell_angle_alpha   66.080
_cell_angle_beta   66.080
_cell_angle_gamma   98.905
_symmetry_Int_Tables_number   1
_cell_volume   314.879
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.250  0.750  0.500  1.0
  Br  Br1  1  0.034  0.534  0.931  1.0
  Br  Br2  1  0.466  0.966  0.069  1.0
  Br  Br3  1  0.120  0.120  0.761  1.0
  Br  Br4  1  0.880  0.880  0.239  1.0
  Br  Br5  1  0.978  0.478  0.500  1.0
  Br  Br6  1  0.522  0.022  0.500  1.0
  N  N7  1  0.415  0.585  0.500  1.0
  N  N8  1  0.883  0.117  0.000  1.0
  N  N9  1  0.085  0.915  0.500  1.0
  N  N10  1  0.117  0.883  0.000  1.0
[/CIF]
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