The material structure described by RbBS3 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 10-coordinate geometry to three equivalent S(1), three equivalent S(3), and four equivalent S(2) atoms. B(1) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form corner-sharing BS4 tetrahedra. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one B(1) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one B(1) atom. In the third S site, S(3) is bonded in a distorted water-like geometry to three equivalent Rb(1) and two equivalent B(1) atoms. is represented by the CIF card [CIF]
data_RbBS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.833
_cell_length_b   7.126
_cell_length_c   11.917
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   104.684
_symmetry_Int_Tables_number   1
_cell_volume   479.128
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.702  0.259  0.080  1.0
  Rb  Rb1  1  0.798  0.741  0.580  1.0
  Rb  Rb2  1  0.298  0.741  0.920  1.0
  Rb  Rb3  1  0.202  0.259  0.420  1.0
  B  B4  1  0.691  0.711  0.232  1.0
  B  B5  1  0.809  0.289  0.732  1.0
  B  B6  1  0.309  0.289  0.768  1.0
  B  B7  1  0.191  0.711  0.268  1.0
  S  S8  1  0.173  0.935  0.177  1.0
  S  S9  1  0.327  0.065  0.677  1.0
  S  S10  1  0.827  0.065  0.823  1.0
  S  S11  1  0.673  0.935  0.323  1.0
  S  S12  1  0.354  0.812  0.403  1.0
  S  S13  1  0.146  0.188  0.903  1.0
  S  S14  1  0.646  0.188  0.597  1.0
  S  S15  1  0.854  0.812  0.097  1.0
  S  S16  1  0.381  0.559  0.196  1.0
  S  S17  1  0.119  0.441  0.696  1.0
  S  S18  1  0.619  0.441  0.804  1.0
  S  S19  1  0.881  0.559  0.304  1.0
[/CIF]
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The material structure described by RbBS3 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 10-coordinate geometry to three equivalent S(1), three equivalent S(3), and four equivalent S(2) atoms. B(1) is bonded to one S(1), one S(2), and two equivalent S(3) atoms to form corner-sharing BS4 tetrahedra. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one B(1) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one B(1) atom. In the third S site, S(3) is bonded in a distorted water-like geometry to three equivalent Rb(1) and two equivalent B(1) atoms. is represented by the CIF card [CIF]
data_RbBS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.833
_cell_length_b   7.126
_cell_length_c   11.917
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   104.684
_symmetry_Int_Tables_number   1
_cell_volume   479.128
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.702  0.259  0.080  1.0
  Rb  Rb1  1  0.798  0.741  0.580  1.0
  Rb  Rb2  1  0.298  0.741  0.920  1.0
  Rb  Rb3  1  0.202  0.259  0.420  1.0
  B  B4  1  0.691  0.711  0.232  1.0
  B  B5  1  0.809  0.289  0.732  1.0
  B  B6  1  0.309  0.289  0.768  1.0
  B  B7  1  0.191  0.711  0.268  1.0
  S  S8  1  0.173  0.935  0.177  1.0
  S  S9  1  0.327  0.065  0.677  1.0
  S  S10  1  0.827  0.065  0.823  1.0
  S  S11  1  0.673  0.935  0.323  1.0
  S  S12  1  0.354  0.812  0.403  1.0
  S  S13  1  0.146  0.188  0.903  1.0
  S  S14  1  0.646  0.188  0.597  1.0
  S  S15  1  0.854  0.812  0.097  1.0
  S  S16  1  0.381  0.559  0.196  1.0
  S  S17  1  0.119  0.441  0.696  1.0
  S  S18  1  0.619  0.441  0.804  1.0
  S  S19  1  0.881  0.559  0.304  1.0
[/CIF]
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