The material structure described by ZnBiSbO5 crystallizes in the monoclinic P2_1/c space group. Zn(1) is bonded to one O(1), one O(2), one O(3), one O(5), and two equivalent O(4) atoms to form ZnO6 octahedra that share corners with four equivalent Sb(1)O4 tetrahedra and  an edgeedge with one Zn(1)O6 octahedra. Bi(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and two equivalent O(4) atoms. Sb(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form SbO4 tetrahedra that share corners with four equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-58°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one Bi(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one Bi(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1), one Bi(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded to two equivalent Zn(1) and two equivalent Bi(1) atoms to form edge-sharing OZn2Bi2 tetrahedra. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Zn(1), one Bi(1), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnBiSbO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.434
_cell_length_b   8.047
_cell_length_c   12.168
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   106.881
_symmetry_Int_Tables_number   1
_cell_volume   509.139
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.617  0.170  0.919  1.0
  Zn  Zn1  1  0.383  0.830  0.081  1.0
  Zn  Zn2  1  0.883  0.330  0.419  1.0
  Zn  Zn3  1  0.117  0.670  0.581  1.0
  Bi  Bi4  1  0.108  0.166  0.097  1.0
  Bi  Bi5  1  0.892  0.834  0.903  1.0
  Bi  Bi6  1  0.608  0.666  0.403  1.0
  Bi  Bi7  1  0.392  0.334  0.597  1.0
  Sb  Sb8  1  0.788  0.965  0.644  1.0
  Sb  Sb9  1  0.212  0.035  0.356  1.0
  Sb  Sb10  1  0.712  0.535  0.144  1.0
  Sb  Sb11  1  0.288  0.465  0.856  1.0
  O  O12  1  0.551  0.323  0.068  1.0
  O  O13  1  0.016  0.319  0.941  1.0
  O  O14  1  0.468  0.655  0.182  1.0
  O  O15  1  0.758  0.514  0.522  1.0
  O  O16  1  0.796  0.488  0.292  1.0
  O  O17  1  0.296  0.988  0.208  1.0
  O  O18  1  0.516  0.819  0.559  1.0
  O  O19  1  0.484  0.181  0.441  1.0
  O  O20  1  0.242  0.486  0.478  1.0
  O  O21  1  0.949  0.177  0.568  1.0
  O  O22  1  0.204  0.512  0.708  1.0
  O  O23  1  0.449  0.677  0.932  1.0
  O  O24  1  0.051  0.823  0.432  1.0
  O  O25  1  0.704  0.012  0.792  1.0
  O  O26  1  0.742  0.986  0.022  1.0
  O  O27  1  0.258  0.014  0.978  1.0
  O  O28  1  0.532  0.345  0.818  1.0
  O  O29  1  0.984  0.681  0.059  1.0
  O  O30  1  0.032  0.845  0.682  1.0
  O  O31  1  0.968  0.155  0.318  1.0
[/CIF]
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The material structure described by ZnBiSbO5 crystallizes in the monoclinic P2_1/c space group. Zn(1) is bonded to one O(1), one O(2), one O(3), one O(5), and two equivalent O(4) atoms to form ZnO6 octahedra that share corners with four equivalent Sb(1)O4 tetrahedra and  an edgeedge with one Zn(1)O6 octahedra. Bi(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and two equivalent O(4) atoms. Sb(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form SbO4 tetrahedra that share corners with four equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-58°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one Bi(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one Bi(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1), one Bi(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded to two equivalent Zn(1) and two equivalent Bi(1) atoms to form edge-sharing OZn2Bi2 tetrahedra. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Zn(1), one Bi(1), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnBiSbO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.434
_cell_length_b   8.047
_cell_length_c   12.168
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   106.881
_symmetry_Int_Tables_number   1
_cell_volume   509.139
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.617  0.170  0.919  1.0
  Zn  Zn1  1  0.383  0.830  0.081  1.0
  Zn  Zn2  1  0.883  0.330  0.419  1.0
  Zn  Zn3  1  0.117  0.670  0.581  1.0
  Bi  Bi4  1  0.108  0.166  0.097  1.0
  Bi  Bi5  1  0.892  0.834  0.903  1.0
  Bi  Bi6  1  0.608  0.666  0.403  1.0
  Bi  Bi7  1  0.392  0.334  0.597  1.0
  Sb  Sb8  1  0.788  0.965  0.644  1.0
  Sb  Sb9  1  0.212  0.035  0.356  1.0
  Sb  Sb10  1  0.712  0.535  0.144  1.0
  Sb  Sb11  1  0.288  0.465  0.856  1.0
  O  O12  1  0.551  0.323  0.068  1.0
  O  O13  1  0.016  0.319  0.941  1.0
  O  O14  1  0.468  0.655  0.182  1.0
  O  O15  1  0.758  0.514  0.522  1.0
  O  O16  1  0.796  0.488  0.292  1.0
  O  O17  1  0.296  0.988  0.208  1.0
  O  O18  1  0.516  0.819  0.559  1.0
  O  O19  1  0.484  0.181  0.441  1.0
  O  O20  1  0.242  0.486  0.478  1.0
  O  O21  1  0.949  0.177  0.568  1.0
  O  O22  1  0.204  0.512  0.708  1.0
  O  O23  1  0.449  0.677  0.932  1.0
  O  O24  1  0.051  0.823  0.432  1.0
  O  O25  1  0.704  0.012  0.792  1.0
  O  O26  1  0.742  0.986  0.022  1.0
  O  O27  1  0.258  0.014  0.978  1.0
  O  O28  1  0.532  0.345  0.818  1.0
  O  O29  1  0.984  0.681  0.059  1.0
  O  O30  1  0.032  0.845  0.682  1.0
  O  O31  1  0.968  0.155  0.318  1.0
[/CIF]
.