The structure described by Th2SbNO is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal I-4m2 space group. Th(1) is bonded in a 4-coordinate geometry to four equivalent Sb(1), two equivalent N(1), and two equivalent O(1) atoms. Sb(1) is bonded in a body-centered cubic geometry to eight equivalent Th(1) atoms. N(1) is bonded to four equivalent Th(1) atoms to form NTh4 tetrahedra that share corners with four equivalent N(1)Th4 tetrahedra and edges with four equivalent O(1)Th4 tetrahedra. O(1) is bonded to four equivalent Th(1) atoms to form OTh4 tetrahedra that share corners with four equivalent O(1)Th4 tetrahedra and edges with four equivalent N(1)Th4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Th2SbNO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.058
_cell_length_b   7.058
_cell_length_c   7.058
_cell_angle_alpha   146.556
_cell_angle_beta   146.556
_cell_angle_gamma   48.022
_symmetry_Int_Tables_number   1
_cell_volume   106.350
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.655  0.655  0.000  1.0
  Th  Th1  1  0.345  0.345  0.000  1.0
  Sb  Sb2  1  0.000  0.000  0.000  1.0
  N  N3  1  0.750  0.250  0.500  1.0
  O  O4  1  0.250  0.750  0.500  1.0
[/CIF]
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The structure described by Th2SbNO is alpha bismuth trifluoride-derived structured and crystallizes in the tetragonal I-4m2 space group. Th(1) is bonded in a 4-coordinate geometry to four equivalent Sb(1), two equivalent N(1), and two equivalent O(1) atoms. Sb(1) is bonded in a body-centered cubic geometry to eight equivalent Th(1) atoms. N(1) is bonded to four equivalent Th(1) atoms to form NTh4 tetrahedra that share corners with four equivalent N(1)Th4 tetrahedra and edges with four equivalent O(1)Th4 tetrahedra. O(1) is bonded to four equivalent Th(1) atoms to form OTh4 tetrahedra that share corners with four equivalent O(1)Th4 tetrahedra and edges with four equivalent N(1)Th4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Th2SbNO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.058
_cell_length_b   7.058
_cell_length_c   7.058
_cell_angle_alpha   146.556
_cell_angle_beta   146.556
_cell_angle_gamma   48.022
_symmetry_Int_Tables_number   1
_cell_volume   106.350
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.655  0.655  0.000  1.0
  Th  Th1  1  0.345  0.345  0.000  1.0
  Sb  Sb2  1  0.000  0.000  0.000  1.0
  N  N3  1  0.750  0.250  0.500  1.0
  O  O4  1  0.250  0.750  0.500  1.0
[/CIF]
.