The crystal structure described by (H3Te3OCl13)2SO2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two sulfur dioxide molecules and four H3Te3OCl13 clusters. In each H3Te3OCl13 cluster, there are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one Cl(8) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) and one Cl(9) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one Cl(10), one Cl(14), one Cl(2), one Cl(3), one Cl(8), and one Cl(9) atom to form edge-sharing TeCl6 octahedra. In the second Te site, Te(3) is bonded to one Cl(13), one Cl(14), two equivalent Cl(1), and two equivalent Cl(8) atoms to form edge-sharing TeCl6 octahedra. O(2) is bonded in a trigonal non-coplanar geometry to one H(2) and two equivalent H(1) atoms. There are eight inequivalent Cl sites. In the first Cl site, Cl(8) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one Te(1), and one Te(3) atom. In the second Cl site, Cl(9) is bonded in a distorted trigonal non-coplanar geometry to one H(2) and two equivalent Te(1) atoms. In the third Cl site, Cl(10) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Cl site, Cl(13) is bonded in a single-bond geometry to one Te(3) atom. In the fifth Cl site, Cl(14) is bonded in a distorted T-shaped geometry to one Te(3) and two equivalent Te(1) atoms. In the sixth Cl site, Cl(1) is bonded in a single-bond geometry to one Te(3) atom. In the seventh Cl site, Cl(2) is bonded in a single-bond geometry to one Te(1) atom. In the eighth Cl site, Cl(3) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF card [CIF]
data_Te6H6S(Cl13O2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.862
_cell_length_b   8.862
_cell_length_c   17.828
_cell_angle_alpha   81.917
_cell_angle_beta   81.917
_cell_angle_gamma   82.357
_symmetry_Int_Tables_number   1
_cell_volume   1363.374
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.925  0.545  0.462  1.0
  Te  Te1  1  0.924  0.545  0.963  1.0
  Te  Te2  1  0.925  0.925  0.272  1.0
  Te  Te3  1  0.545  0.925  0.462  1.0
  Te  Te4  1  0.545  0.924  0.963  1.0
  Te  Te5  1  0.926  0.926  0.772  1.0
  H  H6  1  0.699  0.562  0.281  1.0
  H  H7  1  0.561  0.561  0.348  1.0
  H  H8  1  0.562  0.699  0.281  1.0
  H  H9  1  0.703  0.566  0.787  1.0
  H  H10  1  0.565  0.565  0.855  1.0
  H  H11  1  0.566  0.703  0.787  1.0
  S  S12  1  0.454  0.454  0.646  1.0
  Cl  Cl13  1  0.899  0.196  0.268  1.0
  Cl  Cl14  1  0.538  0.196  0.448  1.0
  Cl  Cl15  1  0.935  0.277  0.467  1.0
  Cl  Cl16  1  0.538  0.195  0.949  1.0
  Cl  Cl17  1  0.900  0.197  0.768  1.0
  Cl  Cl18  1  0.196  0.538  0.448  1.0
  Cl  Cl19  1  0.898  0.537  0.098  1.0
  Cl  Cl20  1  0.934  0.277  0.967  1.0
  Cl  Cl21  1  0.920  0.590  0.296  1.0
  Cl  Cl22  1  0.590  0.590  0.459  1.0
  Cl  Cl23  1  0.195  0.538  0.949  1.0
  Cl  Cl24  1  0.900  0.537  0.597  1.0
  Cl  Cl25  1  0.196  0.899  0.268  1.0
  Cl  Cl26  1  0.537  0.898  0.098  1.0
  Cl  Cl27  1  0.923  0.589  0.797  1.0
  Cl  Cl28  1  0.589  0.589  0.965  1.0
  Cl  Cl29  1  0.277  0.935  0.467  1.0
  Cl  Cl30  1  0.934  0.934  0.139  1.0
  Cl  Cl31  1  0.590  0.920  0.296  1.0
  Cl  Cl32  1  0.537  0.900  0.597  1.0
  Cl  Cl33  1  0.197  0.900  0.768  1.0
  Cl  Cl34  1  0.887  0.887  0.443  1.0
  Cl  Cl35  1  0.277  0.934  0.967  1.0
  Cl  Cl36  1  0.935  0.935  0.639  1.0
  Cl  Cl37  1  0.589  0.923  0.797  1.0
  Cl  Cl38  1  0.887  0.887  0.943  1.0
  O  O39  1  0.506  0.291  0.660  1.0
  O  O40  1  0.291  0.506  0.660  1.0
  O  O41  1  0.582  0.582  0.290  1.0
  O  O42  1  0.586  0.586  0.797  1.0
[/CIF]
.
The crystal structure described by (H3Te3OCl13)2SO2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two sulfur dioxide molecules and four H3Te3OCl13 clusters. In each H3Te3OCl13 cluster, there are two inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) and one Cl(8) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) and one Cl(9) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one Cl(10), one Cl(14), one Cl(2), one Cl(3), one Cl(8), and one Cl(9) atom to form edge-sharing TeCl6 octahedra. In the second Te site, Te(3) is bonded to one Cl(13), one Cl(14), two equivalent Cl(1), and two equivalent Cl(8) atoms to form edge-sharing TeCl6 octahedra. O(2) is bonded in a trigonal non-coplanar geometry to one H(2) and two equivalent H(1) atoms. There are eight inequivalent Cl sites. In the first Cl site, Cl(8) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one Te(1), and one Te(3) atom. In the second Cl site, Cl(9) is bonded in a distorted trigonal non-coplanar geometry to one H(2) and two equivalent Te(1) atoms. In the third Cl site, Cl(10) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Cl site, Cl(13) is bonded in a single-bond geometry to one Te(3) atom. In the fifth Cl site, Cl(14) is bonded in a distorted T-shaped geometry to one Te(3) and two equivalent Te(1) atoms. In the sixth Cl site, Cl(1) is bonded in a single-bond geometry to one Te(3) atom. In the seventh Cl site, Cl(2) is bonded in a single-bond geometry to one Te(1) atom. In the eighth Cl site, Cl(3) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF card [CIF]
data_Te6H6S(Cl13O2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.862
_cell_length_b   8.862
_cell_length_c   17.828
_cell_angle_alpha   81.917
_cell_angle_beta   81.917
_cell_angle_gamma   82.357
_symmetry_Int_Tables_number   1
_cell_volume   1363.374
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.925  0.545  0.462  1.0
  Te  Te1  1  0.924  0.545  0.963  1.0
  Te  Te2  1  0.925  0.925  0.272  1.0
  Te  Te3  1  0.545  0.925  0.462  1.0
  Te  Te4  1  0.545  0.924  0.963  1.0
  Te  Te5  1  0.926  0.926  0.772  1.0
  H  H6  1  0.699  0.562  0.281  1.0
  H  H7  1  0.561  0.561  0.348  1.0
  H  H8  1  0.562  0.699  0.281  1.0
  H  H9  1  0.703  0.566  0.787  1.0
  H  H10  1  0.565  0.565  0.855  1.0
  H  H11  1  0.566  0.703  0.787  1.0
  S  S12  1  0.454  0.454  0.646  1.0
  Cl  Cl13  1  0.899  0.196  0.268  1.0
  Cl  Cl14  1  0.538  0.196  0.448  1.0
  Cl  Cl15  1  0.935  0.277  0.467  1.0
  Cl  Cl16  1  0.538  0.195  0.949  1.0
  Cl  Cl17  1  0.900  0.197  0.768  1.0
  Cl  Cl18  1  0.196  0.538  0.448  1.0
  Cl  Cl19  1  0.898  0.537  0.098  1.0
  Cl  Cl20  1  0.934  0.277  0.967  1.0
  Cl  Cl21  1  0.920  0.590  0.296  1.0
  Cl  Cl22  1  0.590  0.590  0.459  1.0
  Cl  Cl23  1  0.195  0.538  0.949  1.0
  Cl  Cl24  1  0.900  0.537  0.597  1.0
  Cl  Cl25  1  0.196  0.899  0.268  1.0
  Cl  Cl26  1  0.537  0.898  0.098  1.0
  Cl  Cl27  1  0.923  0.589  0.797  1.0
  Cl  Cl28  1  0.589  0.589  0.965  1.0
  Cl  Cl29  1  0.277  0.935  0.467  1.0
  Cl  Cl30  1  0.934  0.934  0.139  1.0
  Cl  Cl31  1  0.590  0.920  0.296  1.0
  Cl  Cl32  1  0.537  0.900  0.597  1.0
  Cl  Cl33  1  0.197  0.900  0.768  1.0
  Cl  Cl34  1  0.887  0.887  0.443  1.0
  Cl  Cl35  1  0.277  0.934  0.967  1.0
  Cl  Cl36  1  0.935  0.935  0.639  1.0
  Cl  Cl37  1  0.589  0.923  0.797  1.0
  Cl  Cl38  1  0.887  0.887  0.943  1.0
  O  O39  1  0.506  0.291  0.660  1.0
  O  O40  1  0.291  0.506  0.660  1.0
  O  O41  1  0.582  0.582  0.290  1.0
  O  O42  1  0.586  0.586  0.797  1.0
[/CIF]
.