The structure described by GdMoO5 crystallizes in the monoclinic P2_1/c space group. Gd(1) is bonded in a 8-coordinate geometry to one O(4), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Mo(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Gd(1) and one Mo(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Gd(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_GdMoO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.651
_cell_length_b   5.402
_cell_length_c   6.978
_cell_angle_alpha   64.603
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   430.738
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.055  0.645  0.711  1.0
  Gd  Gd1  1  0.945  0.355  0.289  1.0
  Gd  Gd2  1  0.555  0.355  0.789  1.0
  Gd  Gd3  1  0.445  0.645  0.211  1.0
  Mo  Mo4  1  0.361  0.913  0.644  1.0
  Mo  Mo5  1  0.639  0.087  0.356  1.0
  Mo  Mo6  1  0.861  0.087  0.856  1.0
  Mo  Mo7  1  0.139  0.913  0.144  1.0
  O  O8  1  0.421  0.497  0.952  1.0
  O  O9  1  0.579  0.503  0.048  1.0
  O  O10  1  0.921  0.503  0.548  1.0
  O  O11  1  0.079  0.497  0.452  1.0
  O  O12  1  0.927  0.988  0.661  1.0
  O  O13  1  0.073  0.012  0.339  1.0
  O  O14  1  0.427  0.012  0.839  1.0
  O  O15  1  0.573  0.988  0.161  1.0
  O  O16  1  0.436  0.707  0.535  1.0
  O  O17  1  0.564  0.293  0.465  1.0
  O  O18  1  0.936  0.293  0.965  1.0
  O  O19  1  0.064  0.707  0.035  1.0
  O  O20  1  0.230  0.794  0.713  1.0
  O  O21  1  0.770  0.206  0.287  1.0
  O  O22  1  0.730  0.206  0.787  1.0
  O  O23  1  0.270  0.794  0.213  1.0
  O  O24  1  0.652  0.767  0.578  1.0
  O  O25  1  0.348  0.233  0.422  1.0
  O  O26  1  0.152  0.233  0.922  1.0
  O  O27  1  0.848  0.767  0.078  1.0
[/CIF]
.
The structure described by GdMoO5 crystallizes in the monoclinic P2_1/c space group. Gd(1) is bonded in a 8-coordinate geometry to one O(4), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Mo(1) is bonded in a distorted tetrahedral geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Gd(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Gd(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Gd(1) and one Mo(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Gd(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_GdMoO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.651
_cell_length_b   5.402
_cell_length_c   6.978
_cell_angle_alpha   64.603
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   430.738
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.055  0.645  0.711  1.0
  Gd  Gd1  1  0.945  0.355  0.289  1.0
  Gd  Gd2  1  0.555  0.355  0.789  1.0
  Gd  Gd3  1  0.445  0.645  0.211  1.0
  Mo  Mo4  1  0.361  0.913  0.644  1.0
  Mo  Mo5  1  0.639  0.087  0.356  1.0
  Mo  Mo6  1  0.861  0.087  0.856  1.0
  Mo  Mo7  1  0.139  0.913  0.144  1.0
  O  O8  1  0.421  0.497  0.952  1.0
  O  O9  1  0.579  0.503  0.048  1.0
  O  O10  1  0.921  0.503  0.548  1.0
  O  O11  1  0.079  0.497  0.452  1.0
  O  O12  1  0.927  0.988  0.661  1.0
  O  O13  1  0.073  0.012  0.339  1.0
  O  O14  1  0.427  0.012  0.839  1.0
  O  O15  1  0.573  0.988  0.161  1.0
  O  O16  1  0.436  0.707  0.535  1.0
  O  O17  1  0.564  0.293  0.465  1.0
  O  O18  1  0.936  0.293  0.965  1.0
  O  O19  1  0.064  0.707  0.035  1.0
  O  O20  1  0.230  0.794  0.713  1.0
  O  O21  1  0.770  0.206  0.287  1.0
  O  O22  1  0.730  0.206  0.787  1.0
  O  O23  1  0.270  0.794  0.213  1.0
  O  O24  1  0.652  0.767  0.578  1.0
  O  O25  1  0.348  0.233  0.422  1.0
  O  O26  1  0.152  0.233  0.922  1.0
  O  O27  1  0.848  0.767  0.078  1.0
[/CIF]
.