The compound described by Ag2TeO3 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(3) and three equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded to one O(2), two equivalent O(1), and two equivalent O(3) atoms to form distorted corner-sharing AgO5 square pyramids. Te(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Ag(2) and one Te(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Ag(2), three equivalent Ag(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Ag(1), two equivalent Ag(2), and one Te(1) atom. is represented by the CIF card [CIF]
data_Ag2TeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.773
_cell_length_b   4.975
_cell_length_c   7.284
_cell_angle_alpha   88.636
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   390.345
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.927  0.252  0.387  1.0
  Ag  Ag1  1  0.739  0.752  0.634  1.0
  Ag  Ag2  1  0.761  0.752  0.134  1.0
  Ag  Ag3  1  0.261  0.248  0.366  1.0
  Ag  Ag4  1  0.073  0.748  0.613  1.0
  Ag  Ag5  1  0.573  0.252  0.887  1.0
  Ag  Ag6  1  0.427  0.748  0.113  1.0
  Ag  Ag7  1  0.239  0.248  0.866  1.0
  Te  Te8  1  0.398  0.745  0.634  1.0
  Te  Te9  1  0.898  0.255  0.866  1.0
  Te  Te10  1  0.602  0.255  0.366  1.0
  Te  Te11  1  0.102  0.745  0.134  1.0
  O  O12  1  0.386  0.361  0.620  1.0
  O  O13  1  0.886  0.639  0.880  1.0
  O  O14  1  0.614  0.639  0.380  1.0
  O  O15  1  0.114  0.361  0.120  1.0
  O  O16  1  0.022  0.248  0.678  1.0
  O  O17  1  0.522  0.752  0.822  1.0
  O  O18  1  0.978  0.752  0.322  1.0
  O  O19  1  0.478  0.248  0.178  1.0
  O  O20  1  0.257  0.781  0.792  1.0
  O  O21  1  0.243  0.781  0.292  1.0
  O  O22  1  0.743  0.219  0.208  1.0
  O  O23  1  0.757  0.219  0.708  1.0
[/CIF]
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The compound described by Ag2TeO3 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(3) and three equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded to one O(2), two equivalent O(1), and two equivalent O(3) atoms to form distorted corner-sharing AgO5 square pyramids. Te(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Ag(2) and one Te(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Ag(2), three equivalent Ag(1), and one Te(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Ag(1), two equivalent Ag(2), and one Te(1) atom. is represented by the CIF card [CIF]
data_Ag2TeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.773
_cell_length_b   4.975
_cell_length_c   7.284
_cell_angle_alpha   88.636
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   390.345
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.927  0.252  0.387  1.0
  Ag  Ag1  1  0.739  0.752  0.634  1.0
  Ag  Ag2  1  0.761  0.752  0.134  1.0
  Ag  Ag3  1  0.261  0.248  0.366  1.0
  Ag  Ag4  1  0.073  0.748  0.613  1.0
  Ag  Ag5  1  0.573  0.252  0.887  1.0
  Ag  Ag6  1  0.427  0.748  0.113  1.0
  Ag  Ag7  1  0.239  0.248  0.866  1.0
  Te  Te8  1  0.398  0.745  0.634  1.0
  Te  Te9  1  0.898  0.255  0.866  1.0
  Te  Te10  1  0.602  0.255  0.366  1.0
  Te  Te11  1  0.102  0.745  0.134  1.0
  O  O12  1  0.386  0.361  0.620  1.0
  O  O13  1  0.886  0.639  0.880  1.0
  O  O14  1  0.614  0.639  0.380  1.0
  O  O15  1  0.114  0.361  0.120  1.0
  O  O16  1  0.022  0.248  0.678  1.0
  O  O17  1  0.522  0.752  0.822  1.0
  O  O18  1  0.978  0.752  0.322  1.0
  O  O19  1  0.478  0.248  0.178  1.0
  O  O20  1  0.257  0.781  0.792  1.0
  O  O21  1  0.243  0.781  0.292  1.0
  O  O22  1  0.743  0.219  0.208  1.0
  O  O23  1  0.757  0.219  0.708  1.0
[/CIF]
.