The structure described by GdY3V4O16 is Zircon-derived structured and crystallizes in the orthorhombic C222 space group. Gd(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(3) atoms. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent O(4) atoms. In the second Y site, Y(2) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are three inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second V site, V(2) is bonded in a tetrahedral geometry to four equivalent O(3) atoms. In the third V site, V(3) is bonded in a tetrahedral geometry to four equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Gd(1), one Y(2), and one V(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Y(1), one Y(2), and one V(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Gd(1), one Y(2), and one V(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Y(1), one Y(2), and one V(3) atom. is represented by the CIF card [CIF]
data_GdY3V4O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.034
_cell_length_b   6.034
_cell_length_c   10.239
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   116.073
_symmetry_Int_Tables_number   1
_cell_volume   334.893
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.000  0.000  0.500  1.0
  Y  Y1  1  0.500  0.500  0.000  1.0
  Y  Y2  1  0.500  0.000  0.250  1.0
  Y  Y3  1  0.000  0.500  0.750  1.0
  V  V4  1  0.000  0.500  0.249  1.0
  V  V5  1  0.500  0.000  0.751  1.0
  V  V6  1  0.500  0.500  0.500  1.0
  V  V7  1  0.000  0.000  0.000  1.0
  O  O8  1  0.917  0.234  0.342  1.0
  O  O9  1  0.418  0.733  0.843  1.0
  O  O10  1  0.234  0.420  0.593  1.0
  O  O11  1  0.733  0.918  0.092  1.0
  O  O12  1  0.420  0.234  0.407  1.0
  O  O13  1  0.918  0.733  0.908  1.0
  O  O14  1  0.733  0.418  0.157  1.0
  O  O15  1  0.234  0.917  0.658  1.0
  O  O16  1  0.580  0.766  0.407  1.0
  O  O17  1  0.082  0.267  0.908  1.0
  O  O18  1  0.267  0.582  0.157  1.0
  O  O19  1  0.766  0.083  0.658  1.0
  O  O20  1  0.083  0.766  0.342  1.0
  O  O21  1  0.582  0.267  0.843  1.0
  O  O22  1  0.766  0.580  0.593  1.0
  O  O23  1  0.267  0.082  0.092  1.0
[/CIF]
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The structure described by GdY3V4O16 is Zircon-derived structured and crystallizes in the orthorhombic C222 space group. Gd(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(3) atoms. There are two inequivalent Y sites. In the first Y site, Y(1) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent O(4) atoms. In the second Y site, Y(2) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. There are three inequivalent V sites. In the first V site, V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second V site, V(2) is bonded in a tetrahedral geometry to four equivalent O(3) atoms. In the third V site, V(3) is bonded in a tetrahedral geometry to four equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Gd(1), one Y(2), and one V(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Y(1), one Y(2), and one V(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Gd(1), one Y(2), and one V(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Y(1), one Y(2), and one V(3) atom. is represented by the CIF card [CIF]
data_GdY3V4O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.034
_cell_length_b   6.034
_cell_length_c   10.239
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   116.073
_symmetry_Int_Tables_number   1
_cell_volume   334.893
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.000  0.000  0.500  1.0
  Y  Y1  1  0.500  0.500  0.000  1.0
  Y  Y2  1  0.500  0.000  0.250  1.0
  Y  Y3  1  0.000  0.500  0.750  1.0
  V  V4  1  0.000  0.500  0.249  1.0
  V  V5  1  0.500  0.000  0.751  1.0
  V  V6  1  0.500  0.500  0.500  1.0
  V  V7  1  0.000  0.000  0.000  1.0
  O  O8  1  0.917  0.234  0.342  1.0
  O  O9  1  0.418  0.733  0.843  1.0
  O  O10  1  0.234  0.420  0.593  1.0
  O  O11  1  0.733  0.918  0.092  1.0
  O  O12  1  0.420  0.234  0.407  1.0
  O  O13  1  0.918  0.733  0.908  1.0
  O  O14  1  0.733  0.418  0.157  1.0
  O  O15  1  0.234  0.917  0.658  1.0
  O  O16  1  0.580  0.766  0.407  1.0
  O  O17  1  0.082  0.267  0.908  1.0
  O  O18  1  0.267  0.582  0.157  1.0
  O  O19  1  0.766  0.083  0.658  1.0
  O  O20  1  0.083  0.766  0.342  1.0
  O  O21  1  0.582  0.267  0.843  1.0
  O  O22  1  0.766  0.580  0.593  1.0
  O  O23  1  0.267  0.082  0.092  1.0
[/CIF]
.