The structure described by Eu3WO6 is (Cubic) Perovskite-like structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent Eu sites. In the first Eu site, Eu(1) is bonded to twelve equivalent O(1) atoms to form EuO12 cuboctahedra that share corners with twelve equivalent Eu(1)O12 cuboctahedra, faces with six equivalent Eu(1)O12 cuboctahedra, faces with four equivalent Eu(2)O6 octahedra, and faces with four equivalent W(1)O6 octahedra. In the second Eu site, Eu(2) is bonded to six equivalent O(1) atoms to form EuO6 octahedra that share corners with six equivalent W(1)O6 octahedra and faces with eight equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Eu(2)O6 octahedra and faces with eight equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to one Eu(2), four equivalent Eu(1), and one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Eu3WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.044
_cell_length_b   6.044
_cell_length_c   6.044
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   156.140
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.250  0.250  0.250  1.0
  Eu  Eu1  1  0.500  0.500  0.500  1.0
  Eu  Eu2  1  0.750  0.750  0.750  1.0
  W  W3  1  0.000  0.000  0.000  1.0
  O  O4  1  0.771  0.229  0.229  1.0
  O  O5  1  0.229  0.771  0.229  1.0
  O  O6  1  0.771  0.229  0.771  1.0
  O  O7  1  0.771  0.771  0.229  1.0
  O  O8  1  0.229  0.229  0.771  1.0
  O  O9  1  0.229  0.771  0.771  1.0
[/CIF]
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The structure described by Eu3WO6 is (Cubic) Perovskite-like structured and crystallizes in the cubic Fm-3m space group. There are two inequivalent Eu sites. In the first Eu site, Eu(1) is bonded to twelve equivalent O(1) atoms to form EuO12 cuboctahedra that share corners with twelve equivalent Eu(1)O12 cuboctahedra, faces with six equivalent Eu(1)O12 cuboctahedra, faces with four equivalent Eu(2)O6 octahedra, and faces with four equivalent W(1)O6 octahedra. In the second Eu site, Eu(2) is bonded to six equivalent O(1) atoms to form EuO6 octahedra that share corners with six equivalent W(1)O6 octahedra and faces with eight equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. W(1) is bonded to six equivalent O(1) atoms to form WO6 octahedra that share corners with six equivalent Eu(2)O6 octahedra and faces with eight equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a distorted linear geometry to one Eu(2), four equivalent Eu(1), and one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Eu3WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.044
_cell_length_b   6.044
_cell_length_c   6.044
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   156.140
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.250  0.250  0.250  1.0
  Eu  Eu1  1  0.500  0.500  0.500  1.0
  Eu  Eu2  1  0.750  0.750  0.750  1.0
  W  W3  1  0.000  0.000  0.000  1.0
  O  O4  1  0.771  0.229  0.229  1.0
  O  O5  1  0.229  0.771  0.229  1.0
  O  O6  1  0.771  0.229  0.771  1.0
  O  O7  1  0.771  0.771  0.229  1.0
  O  O8  1  0.229  0.229  0.771  1.0
  O  O9  1  0.229  0.771  0.771  1.0
[/CIF]
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