The compound described by Pu(NO3)6N2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms and two Pu(NO3)6 clusters. In each Pu(NO3)6 cluster, Pu(1) is bonded in a cuboctahedral geometry to two equivalent O(1), two equivalent O(3), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(9) atoms. There are three inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one Pu(1) and one N(3) atom. In the second O site, O(6) is bonded in a distorted single-bond geometry to one Pu(1) and one N(3) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Pu(1) and one N(4) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one N(4) atom. In the fifth O site, O(1) is bonded in a distorted single-bond geometry to one Pu(1) and one N(2) atom. In the sixth O site, O(9) is bonded in a distorted water-like geometry to one Pu(1) and one N(4) atom. In the seventh O site, O(2) is bonded in a single-bond geometry to one N(2) atom. In the eighth O site, O(3) is bonded in a distorted single-bond geometry to one Pu(1) and one N(2) atom. In the ninth O site, O(4) is bonded in a single-bond geometry to one N(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pu(N4O9)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.703
_cell_length_b   8.033
_cell_length_c   14.962
_cell_angle_alpha   58.893
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   689.818
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.500  0.000  0.500  1.0
  Pu  Pu1  1  0.000  0.000  0.000  1.0
  N  N2  1  0.735  0.368  0.161  1.0
  N  N3  1  0.765  0.368  0.661  1.0
  N  N4  1  0.265  0.632  0.839  1.0
  N  N5  1  0.235  0.632  0.339  1.0
  N  N6  1  0.239  0.222  0.319  1.0
  N  N7  1  0.261  0.222  0.819  1.0
  N  N8  1  0.761  0.778  0.681  1.0
  N  N9  1  0.739  0.778  0.181  1.0
  N  N10  1  0.749  0.336  0.447  1.0
  N  N11  1  0.751  0.336  0.947  1.0
  N  N12  1  0.251  0.664  0.553  1.0
  N  N13  1  0.249  0.664  0.053  1.0
  N  N14  1  0.775  0.895  0.386  1.0
  N  N15  1  0.725  0.895  0.886  1.0
  N  N16  1  0.225  0.105  0.614  1.0
  N  N17  1  0.275  0.105  0.114  1.0
  O  O18  1  0.221  0.038  0.384  1.0
  O  O19  1  0.279  0.038  0.884  1.0
  O  O20  1  0.779  0.962  0.616  1.0
  O  O21  1  0.721  0.962  0.116  1.0
  O  O22  1  0.119  0.318  0.251  1.0
  O  O23  1  0.381  0.318  0.751  1.0
  O  O24  1  0.881  0.682  0.749  1.0
  O  O25  1  0.619  0.682  0.249  1.0
  O  O26  1  0.397  0.296  0.335  1.0
  O  O27  1  0.103  0.296  0.835  1.0
  O  O28  1  0.603  0.704  0.665  1.0
  O  O29  1  0.897  0.704  0.165  1.0
  O  O30  1  0.863  0.465  0.436  1.0
  O  O31  1  0.637  0.465  0.936  1.0
  O  O32  1  0.137  0.535  0.564  1.0
  O  O33  1  0.363  0.535  0.064  1.0
  O  O34  1  0.585  0.299  0.499  1.0
  O  O35  1  0.915  0.299  0.999  1.0
  O  O36  1  0.415  0.701  0.501  1.0
  O  O37  1  0.085  0.701  0.001  1.0
  O  O38  1  0.782  0.227  0.409  1.0
  O  O39  1  0.718  0.227  0.909  1.0
  O  O40  1  0.218  0.773  0.591  1.0
  O  O41  1  0.282  0.773  0.091  1.0
  O  O42  1  0.793  0.830  0.484  1.0
  O  O43  1  0.707  0.830  0.984  1.0
  O  O44  1  0.207  0.170  0.516  1.0
  O  O45  1  0.293  0.170  0.016  1.0
  O  O46  1  0.893  0.860  0.336  1.0
  O  O47  1  0.607  0.860  0.836  1.0
  O  O48  1  0.107  0.140  0.664  1.0
  O  O49  1  0.393  0.140  0.164  1.0
  O  O50  1  0.619  0.004  0.345  1.0
  O  O51  1  0.881  0.004  0.845  1.0
  O  O52  1  0.381  0.996  0.655  1.0
  O  O53  1  0.119  0.996  0.155  1.0
[/CIF]
.
The compound described by Pu(NO3)6N2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ammonia atoms and two Pu(NO3)6 clusters. In each Pu(NO3)6 cluster, Pu(1) is bonded in a cuboctahedral geometry to two equivalent O(1), two equivalent O(3), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(9) atoms. There are three inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(6) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one O(7), one O(8), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one Pu(1) and one N(3) atom. In the second O site, O(6) is bonded in a distorted single-bond geometry to one Pu(1) and one N(3) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Pu(1) and one N(4) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one N(4) atom. In the fifth O site, O(1) is bonded in a distorted single-bond geometry to one Pu(1) and one N(2) atom. In the sixth O site, O(9) is bonded in a distorted water-like geometry to one Pu(1) and one N(4) atom. In the seventh O site, O(2) is bonded in a single-bond geometry to one N(2) atom. In the eighth O site, O(3) is bonded in a distorted single-bond geometry to one Pu(1) and one N(2) atom. In the ninth O site, O(4) is bonded in a single-bond geometry to one N(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pu(N4O9)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.703
_cell_length_b   8.033
_cell_length_c   14.962
_cell_angle_alpha   58.893
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   689.818
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.500  0.000  0.500  1.0
  Pu  Pu1  1  0.000  0.000  0.000  1.0
  N  N2  1  0.735  0.368  0.161  1.0
  N  N3  1  0.765  0.368  0.661  1.0
  N  N4  1  0.265  0.632  0.839  1.0
  N  N5  1  0.235  0.632  0.339  1.0
  N  N6  1  0.239  0.222  0.319  1.0
  N  N7  1  0.261  0.222  0.819  1.0
  N  N8  1  0.761  0.778  0.681  1.0
  N  N9  1  0.739  0.778  0.181  1.0
  N  N10  1  0.749  0.336  0.447  1.0
  N  N11  1  0.751  0.336  0.947  1.0
  N  N12  1  0.251  0.664  0.553  1.0
  N  N13  1  0.249  0.664  0.053  1.0
  N  N14  1  0.775  0.895  0.386  1.0
  N  N15  1  0.725  0.895  0.886  1.0
  N  N16  1  0.225  0.105  0.614  1.0
  N  N17  1  0.275  0.105  0.114  1.0
  O  O18  1  0.221  0.038  0.384  1.0
  O  O19  1  0.279  0.038  0.884  1.0
  O  O20  1  0.779  0.962  0.616  1.0
  O  O21  1  0.721  0.962  0.116  1.0
  O  O22  1  0.119  0.318  0.251  1.0
  O  O23  1  0.381  0.318  0.751  1.0
  O  O24  1  0.881  0.682  0.749  1.0
  O  O25  1  0.619  0.682  0.249  1.0
  O  O26  1  0.397  0.296  0.335  1.0
  O  O27  1  0.103  0.296  0.835  1.0
  O  O28  1  0.603  0.704  0.665  1.0
  O  O29  1  0.897  0.704  0.165  1.0
  O  O30  1  0.863  0.465  0.436  1.0
  O  O31  1  0.637  0.465  0.936  1.0
  O  O32  1  0.137  0.535  0.564  1.0
  O  O33  1  0.363  0.535  0.064  1.0
  O  O34  1  0.585  0.299  0.499  1.0
  O  O35  1  0.915  0.299  0.999  1.0
  O  O36  1  0.415  0.701  0.501  1.0
  O  O37  1  0.085  0.701  0.001  1.0
  O  O38  1  0.782  0.227  0.409  1.0
  O  O39  1  0.718  0.227  0.909  1.0
  O  O40  1  0.218  0.773  0.591  1.0
  O  O41  1  0.282  0.773  0.091  1.0
  O  O42  1  0.793  0.830  0.484  1.0
  O  O43  1  0.707  0.830  0.984  1.0
  O  O44  1  0.207  0.170  0.516  1.0
  O  O45  1  0.293  0.170  0.016  1.0
  O  O46  1  0.893  0.860  0.336  1.0
  O  O47  1  0.607  0.860  0.836  1.0
  O  O48  1  0.107  0.140  0.664  1.0
  O  O49  1  0.393  0.140  0.164  1.0
  O  O50  1  0.619  0.004  0.345  1.0
  O  O51  1  0.881  0.004  0.845  1.0
  O  O52  1  0.381  0.996  0.655  1.0
  O  O53  1  0.119  0.996  0.155  1.0
[/CIF]
.