The crystal structure described by Ce(MoCo5)2 crystallizes in the orthorhombic Immm space group. Ce(1) is bonded in a 20-coordinate geometry to two equivalent Mo(1), two equivalent Co(4), four equivalent Co(1), four equivalent Co(2), and eight equivalent Co(3) atoms. Mo(1) is bonded in a 14-coordinate geometry to one Ce(1), one Mo(1), two equivalent Co(1), two equivalent Co(2), four equivalent Co(3), and four equivalent Co(4) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent Ce(1), two equivalent Mo(1), two equivalent Co(2), two equivalent Co(4), and four equivalent Co(3) atoms to form a mixture of distorted edge, face, and corner-sharing CoCe2Co8Mo2 cuboctahedra. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to two equivalent Ce(1), two equivalent Mo(1), two equivalent Co(1), two equivalent Co(4), and four equivalent Co(3) atoms. In the third Co site, Co(3) is bonded to two equivalent Ce(1), two equivalent Mo(1), two equivalent Co(1), two equivalent Co(2), two equivalent Co(3), and two equivalent Co(4) atoms to form a mixture of distorted edge, face, and corner-sharing CoCe2Co8Mo2 cuboctahedra. In the fourth Co site, Co(4) is bonded in a 14-coordinate geometry to one Ce(1), four equivalent Mo(1), one Co(4), two equivalent Co(1), two equivalent Co(2), and four equivalent Co(3) atoms. is represented by the CIF file [CIF]
data_Ce(Co5Mo)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.665
_cell_length_b   6.430
_cell_length_c   6.430
_cell_angle_alpha   97.440
_cell_angle_beta   111.270
_cell_angle_gamma   68.730
_symmetry_Int_Tables_number   1
_cell_volume   167.460
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.710  0.790  0.210  1.0
  Co  Co2  1  0.290  0.210  0.790  1.0
  Co  Co3  1  0.500  0.780  0.780  1.0
  Co  Co4  1  0.500  0.220  0.220  1.0
  Co  Co5  1  0.500  0.000  0.500  1.0
  Co  Co6  1  0.000  0.000  0.500  1.0
  Co  Co7  1  0.500  0.500  0.000  1.0
  Co  Co8  1  0.000  0.500  0.000  1.0
  Co  Co9  1  0.640  0.360  0.640  1.0
  Co  Co10  1  0.360  0.640  0.360  1.0
  Mo  Mo11  1  0.000  0.359  0.359  1.0
  Mo  Mo12  1  0.000  0.641  0.641  1.0
[/CIF]
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The crystal structure described by Ce(MoCo5)2 crystallizes in the orthorhombic Immm space group. Ce(1) is bonded in a 20-coordinate geometry to two equivalent Mo(1), two equivalent Co(4), four equivalent Co(1), four equivalent Co(2), and eight equivalent Co(3) atoms. Mo(1) is bonded in a 14-coordinate geometry to one Ce(1), one Mo(1), two equivalent Co(1), two equivalent Co(2), four equivalent Co(3), and four equivalent Co(4) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent Ce(1), two equivalent Mo(1), two equivalent Co(2), two equivalent Co(4), and four equivalent Co(3) atoms to form a mixture of distorted edge, face, and corner-sharing CoCe2Co8Mo2 cuboctahedra. In the second Co site, Co(2) is bonded in a 12-coordinate geometry to two equivalent Ce(1), two equivalent Mo(1), two equivalent Co(1), two equivalent Co(4), and four equivalent Co(3) atoms. In the third Co site, Co(3) is bonded to two equivalent Ce(1), two equivalent Mo(1), two equivalent Co(1), two equivalent Co(2), two equivalent Co(3), and two equivalent Co(4) atoms to form a mixture of distorted edge, face, and corner-sharing CoCe2Co8Mo2 cuboctahedra. In the fourth Co site, Co(4) is bonded in a 14-coordinate geometry to one Ce(1), four equivalent Mo(1), one Co(4), two equivalent Co(1), two equivalent Co(2), and four equivalent Co(3) atoms. is represented by the CIF file [CIF]
data_Ce(Co5Mo)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.665
_cell_length_b   6.430
_cell_length_c   6.430
_cell_angle_alpha   97.440
_cell_angle_beta   111.270
_cell_angle_gamma   68.730
_symmetry_Int_Tables_number   1
_cell_volume   167.460
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.710  0.790  0.210  1.0
  Co  Co2  1  0.290  0.210  0.790  1.0
  Co  Co3  1  0.500  0.780  0.780  1.0
  Co  Co4  1  0.500  0.220  0.220  1.0
  Co  Co5  1  0.500  0.000  0.500  1.0
  Co  Co6  1  0.000  0.000  0.500  1.0
  Co  Co7  1  0.500  0.500  0.000  1.0
  Co  Co8  1  0.000  0.500  0.000  1.0
  Co  Co9  1  0.640  0.360  0.640  1.0
  Co  Co10  1  0.360  0.640  0.360  1.0
  Mo  Mo11  1  0.000  0.359  0.359  1.0
  Mo  Mo12  1  0.000  0.641  0.641  1.0
[/CIF]
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