The structure described by AuCl(PF3) is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four AuCl(PF3) clusters. Au(1) is bonded in a linear geometry to one P(1) and one Cl(1) atom. P(1) is bonded in a 3-coordinate geometry to one Au(1), one F(2), and two equivalent F(1) atoms. Cl(1) is bonded in a single-bond geometry to one Au(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PAuClF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.941
_cell_length_b   5.657
_cell_length_c   18.786
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   525.092
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.526  0.750  0.646  1.0
  P  P1  1  0.026  0.250  0.854  1.0
  P  P2  1  0.974  0.750  0.146  1.0
  P  P3  1  0.474  0.250  0.354  1.0
  Au  Au4  1  0.158  0.250  0.966  1.0
  Au  Au5  1  0.658  0.750  0.534  1.0
  Au  Au6  1  0.842  0.750  0.034  1.0
  Au  Au7  1  0.342  0.250  0.466  1.0
  Cl  Cl8  1  0.154  0.250  0.578  1.0
  Cl  Cl9  1  0.846  0.750  0.422  1.0
  Cl  Cl10  1  0.346  0.250  0.078  1.0
  Cl  Cl11  1  0.654  0.750  0.922  1.0
  F  F12  1  0.129  0.461  0.807  1.0
  F  F13  1  0.720  0.250  0.832  1.0
  F  F14  1  0.371  0.039  0.307  1.0
  F  F15  1  0.371  0.461  0.307  1.0
  F  F16  1  0.629  0.539  0.693  1.0
  F  F17  1  0.629  0.961  0.693  1.0
  F  F18  1  0.780  0.250  0.332  1.0
  F  F19  1  0.280  0.750  0.168  1.0
  F  F20  1  0.871  0.539  0.193  1.0
  F  F21  1  0.871  0.961  0.193  1.0
  F  F22  1  0.220  0.750  0.668  1.0
  F  F23  1  0.129  0.039  0.807  1.0
[/CIF]
.
The structure described by AuCl(PF3) is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four AuCl(PF3) clusters. Au(1) is bonded in a linear geometry to one P(1) and one Cl(1) atom. P(1) is bonded in a 3-coordinate geometry to one Au(1), one F(2), and two equivalent F(1) atoms. Cl(1) is bonded in a single-bond geometry to one Au(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PAuClF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.941
_cell_length_b   5.657
_cell_length_c   18.786
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   525.092
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.526  0.750  0.646  1.0
  P  P1  1  0.026  0.250  0.854  1.0
  P  P2  1  0.974  0.750  0.146  1.0
  P  P3  1  0.474  0.250  0.354  1.0
  Au  Au4  1  0.158  0.250  0.966  1.0
  Au  Au5  1  0.658  0.750  0.534  1.0
  Au  Au6  1  0.842  0.750  0.034  1.0
  Au  Au7  1  0.342  0.250  0.466  1.0
  Cl  Cl8  1  0.154  0.250  0.578  1.0
  Cl  Cl9  1  0.846  0.750  0.422  1.0
  Cl  Cl10  1  0.346  0.250  0.078  1.0
  Cl  Cl11  1  0.654  0.750  0.922  1.0
  F  F12  1  0.129  0.461  0.807  1.0
  F  F13  1  0.720  0.250  0.832  1.0
  F  F14  1  0.371  0.039  0.307  1.0
  F  F15  1  0.371  0.461  0.307  1.0
  F  F16  1  0.629  0.539  0.693  1.0
  F  F17  1  0.629  0.961  0.693  1.0
  F  F18  1  0.780  0.250  0.332  1.0
  F  F19  1  0.280  0.750  0.168  1.0
  F  F20  1  0.871  0.539  0.193  1.0
  F  F21  1  0.871  0.961  0.193  1.0
  F  F22  1  0.220  0.750  0.668  1.0
  F  F23  1  0.129  0.039  0.807  1.0
[/CIF]
.