The material described by TbOF is Fluorite-derived structured and crystallizes in the trigonal R-3m space group. Tb(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded to four equivalent Tb(1) atoms to form OTb4 tetrahedra that share corners with six equivalent O(1)Tb4 tetrahedra, corners with ten equivalent F(1)Tb4 tetrahedra, edges with three equivalent O(1)Tb4 tetrahedra, and edges with three equivalent F(1)Tb4 tetrahedra. F(1) is bonded to four equivalent Tb(1) atoms to form FTb4 tetrahedra that share corners with six equivalent F(1)Tb4 tetrahedra, corners with ten equivalent O(1)Tb4 tetrahedra, edges with three equivalent O(1)Tb4 tetrahedra, and edges with three equivalent F(1)Tb4 tetrahedra. is represented by the CIF card [CIF]
data_TbOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.697
_cell_length_b   6.697
_cell_length_c   6.697
_cell_angle_alpha   33.059
_cell_angle_beta   33.059
_cell_angle_gamma   33.059
_symmetry_Int_Tables_number   1
_cell_volume   79.561
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.742  0.742  0.742  1.0
  Tb  Tb1  1  0.258  0.258  0.258  1.0
  O  O2  1  0.621  0.621  0.621  1.0
  O  O3  1  0.379  0.379  0.379  1.0
  F  F4  1  0.130  0.130  0.130  1.0
  F  F5  1  0.870  0.870  0.870  1.0
[/CIF]
.
The material described by TbOF is Fluorite-derived structured and crystallizes in the trigonal R-3m space group. Tb(1) is bonded in a body-centered cubic geometry to four equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded to four equivalent Tb(1) atoms to form OTb4 tetrahedra that share corners with six equivalent O(1)Tb4 tetrahedra, corners with ten equivalent F(1)Tb4 tetrahedra, edges with three equivalent O(1)Tb4 tetrahedra, and edges with three equivalent F(1)Tb4 tetrahedra. F(1) is bonded to four equivalent Tb(1) atoms to form FTb4 tetrahedra that share corners with six equivalent F(1)Tb4 tetrahedra, corners with ten equivalent O(1)Tb4 tetrahedra, edges with three equivalent O(1)Tb4 tetrahedra, and edges with three equivalent F(1)Tb4 tetrahedra. is represented by the CIF card [CIF]
data_TbOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.697
_cell_length_b   6.697
_cell_length_c   6.697
_cell_angle_alpha   33.059
_cell_angle_beta   33.059
_cell_angle_gamma   33.059
_symmetry_Int_Tables_number   1
_cell_volume   79.561
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.742  0.742  0.742  1.0
  Tb  Tb1  1  0.258  0.258  0.258  1.0
  O  O2  1  0.621  0.621  0.621  1.0
  O  O3  1  0.379  0.379  0.379  1.0
  F  F4  1  0.130  0.130  0.130  1.0
  F  F5  1  0.870  0.870  0.870  1.0
[/CIF]
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