The material structure described by GaTeO3F crystallizes in the monoclinic P2_1/c space group. Ga(1) is bonded to one O(2), one O(3), two equivalent O(1), and two equivalent F(1) atoms to form edge-sharing GaO4F2 octahedra. Te(1) is bonded in a 3-coordinate geometry to one O(1), one O(3), and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Ga(1) and one Te(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ga(1) and two equivalent Te(1) atoms. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ga(1) and one Te(1) atom. F(1) is bonded in a water-like geometry to two equivalent Ga(1) atoms. is represented by the CIF file [CIF]
data_GaTeO3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.115
_cell_length_b   5.164
_cell_length_c   12.686
_cell_angle_alpha   74.380
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   322.713
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.258  0.107  0.430  1.0
  Ga  Ga1  1  0.758  0.893  0.070  1.0
  Ga  Ga2  1  0.242  0.107  0.930  1.0
  Ga  Ga3  1  0.742  0.893  0.570  1.0
  Te  Te4  1  0.193  0.325  0.170  1.0
  Te  Te5  1  0.693  0.675  0.330  1.0
  Te  Te6  1  0.307  0.325  0.670  1.0
  Te  Te7  1  0.807  0.675  0.830  1.0
  O  O8  1  0.064  0.122  0.069  1.0
  O  O9  1  0.117  0.457  0.839  1.0
  O  O10  1  0.923  0.928  0.700  1.0
  O  O11  1  0.383  0.457  0.339  1.0
  O  O12  1  0.883  0.543  0.161  1.0
  O  O13  1  0.617  0.543  0.661  1.0
  O  O14  1  0.423  0.072  0.800  1.0
  O  O15  1  0.936  0.878  0.931  1.0
  O  O16  1  0.436  0.122  0.569  1.0
  O  O17  1  0.077  0.072  0.300  1.0
  O  O18  1  0.577  0.928  0.200  1.0
  O  O19  1  0.564  0.878  0.431  1.0
  F  F20  1  0.562  0.237  0.988  1.0
  F  F21  1  0.062  0.763  0.512  1.0
  F  F22  1  0.938  0.237  0.488  1.0
  F  F23  1  0.438  0.763  0.012  1.0
[/CIF]
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The material structure described by GaTeO3F crystallizes in the monoclinic P2_1/c space group. Ga(1) is bonded to one O(2), one O(3), two equivalent O(1), and two equivalent F(1) atoms to form edge-sharing GaO4F2 octahedra. Te(1) is bonded in a 3-coordinate geometry to one O(1), one O(3), and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Ga(1) and one Te(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ga(1) and two equivalent Te(1) atoms. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ga(1) and one Te(1) atom. F(1) is bonded in a water-like geometry to two equivalent Ga(1) atoms. is represented by the CIF file [CIF]
data_GaTeO3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.115
_cell_length_b   5.164
_cell_length_c   12.686
_cell_angle_alpha   74.380
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   322.713
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.258  0.107  0.430  1.0
  Ga  Ga1  1  0.758  0.893  0.070  1.0
  Ga  Ga2  1  0.242  0.107  0.930  1.0
  Ga  Ga3  1  0.742  0.893  0.570  1.0
  Te  Te4  1  0.193  0.325  0.170  1.0
  Te  Te5  1  0.693  0.675  0.330  1.0
  Te  Te6  1  0.307  0.325  0.670  1.0
  Te  Te7  1  0.807  0.675  0.830  1.0
  O  O8  1  0.064  0.122  0.069  1.0
  O  O9  1  0.117  0.457  0.839  1.0
  O  O10  1  0.923  0.928  0.700  1.0
  O  O11  1  0.383  0.457  0.339  1.0
  O  O12  1  0.883  0.543  0.161  1.0
  O  O13  1  0.617  0.543  0.661  1.0
  O  O14  1  0.423  0.072  0.800  1.0
  O  O15  1  0.936  0.878  0.931  1.0
  O  O16  1  0.436  0.122  0.569  1.0
  O  O17  1  0.077  0.072  0.300  1.0
  O  O18  1  0.577  0.928  0.200  1.0
  O  O19  1  0.564  0.878  0.431  1.0
  F  F20  1  0.562  0.237  0.988  1.0
  F  F21  1  0.062  0.763  0.512  1.0
  F  F22  1  0.938  0.237  0.488  1.0
  F  F23  1  0.438  0.763  0.012  1.0
[/CIF]
.