The structure described by CF3Cl is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four chlorotrifluoromethane molecules. C(1) is bonded in a tetrahedral geometry to one Cl(1), one F(1), and two equivalent F(2) atoms. Cl(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CClF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.973
_cell_length_b   5.973
_cell_length_c   4.679
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   106.202
_symmetry_Int_Tables_number   1
_cell_volume   160.288
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.690  0.310  0.001  1.0
  C  C1  1  0.310  0.690  0.501  1.0
  Cl  Cl2  1  0.866  0.134  0.096  1.0
  Cl  Cl3  1  0.134  0.866  0.596  1.0
  F  F4  1  0.675  0.325  0.716  1.0
  F  F5  1  0.325  0.675  0.216  1.0
  F  F6  1  0.776  0.527  0.106  1.0
  F  F7  1  0.224  0.473  0.606  1.0
  F  F8  1  0.473  0.224  0.106  1.0
  F  F9  1  0.527  0.776  0.606  1.0
[/CIF]
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The structure described by CF3Cl is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four chlorotrifluoromethane molecules. C(1) is bonded in a tetrahedral geometry to one Cl(1), one F(1), and two equivalent F(2) atoms. Cl(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CClF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.973
_cell_length_b   5.973
_cell_length_c   4.679
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   106.202
_symmetry_Int_Tables_number   1
_cell_volume   160.288
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.690  0.310  0.001  1.0
  C  C1  1  0.310  0.690  0.501  1.0
  Cl  Cl2  1  0.866  0.134  0.096  1.0
  Cl  Cl3  1  0.134  0.866  0.596  1.0
  F  F4  1  0.675  0.325  0.716  1.0
  F  F5  1  0.325  0.675  0.216  1.0
  F  F6  1  0.776  0.527  0.106  1.0
  F  F7  1  0.224  0.473  0.606  1.0
  F  F8  1  0.473  0.224  0.106  1.0
  F  F9  1  0.527  0.776  0.606  1.0
[/CIF]
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