The material structure described by Tb(PO)2 crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of eight Tb(PO)2 clusters. Tb(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. P(1) is bonded in a distorted single-bond geometry to one O(1) atom. O(1) is bonded in a water-like geometry to one Tb(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Tb(PO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.301
_cell_length_b   10.301
_cell_length_c   10.301
_cell_angle_alpha   127.359
_cell_angle_beta   127.359
_cell_angle_gamma   77.666
_symmetry_Int_Tables_number   1
_cell_volume   669.487
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.875  0.125  0.750  1.0
  Tb  Tb1  1  0.375  0.125  0.250  1.0
  Tb  Tb2  1  0.875  0.625  0.750  1.0
  Tb  Tb3  1  0.875  0.125  0.250  1.0
  P  P4  1  0.647  0.297  0.350  1.0
  P  P5  1  0.948  0.297  0.650  1.0
  P  P6  1  0.047  0.198  0.150  1.0
  P  P7  1  0.802  0.953  0.850  1.0
  P  P8  1  0.103  0.953  0.150  1.0
  P  P9  1  0.047  0.897  0.850  1.0
  P  P10  1  0.703  0.052  0.350  1.0
  P  P11  1  0.703  0.353  0.650  1.0
  O  O12  1  0.449  0.260  0.189  1.0
  O  O13  1  0.071  0.260  0.811  1.0
  O  O14  1  0.010  0.321  0.311  1.0
  O  O15  1  0.679  0.990  0.689  1.0
  O  O16  1  0.301  0.990  0.311  1.0
  O  O17  1  0.010  0.699  0.689  1.0
  O  O18  1  0.740  0.929  0.189  1.0
  O  O19  1  0.740  0.551  0.811  1.0
[/CIF]
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The material structure described by Tb(PO)2 crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of eight Tb(PO)2 clusters. Tb(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. P(1) is bonded in a distorted single-bond geometry to one O(1) atom. O(1) is bonded in a water-like geometry to one Tb(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Tb(PO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.301
_cell_length_b   10.301
_cell_length_c   10.301
_cell_angle_alpha   127.359
_cell_angle_beta   127.359
_cell_angle_gamma   77.666
_symmetry_Int_Tables_number   1
_cell_volume   669.487
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.875  0.125  0.750  1.0
  Tb  Tb1  1  0.375  0.125  0.250  1.0
  Tb  Tb2  1  0.875  0.625  0.750  1.0
  Tb  Tb3  1  0.875  0.125  0.250  1.0
  P  P4  1  0.647  0.297  0.350  1.0
  P  P5  1  0.948  0.297  0.650  1.0
  P  P6  1  0.047  0.198  0.150  1.0
  P  P7  1  0.802  0.953  0.850  1.0
  P  P8  1  0.103  0.953  0.150  1.0
  P  P9  1  0.047  0.897  0.850  1.0
  P  P10  1  0.703  0.052  0.350  1.0
  P  P11  1  0.703  0.353  0.650  1.0
  O  O12  1  0.449  0.260  0.189  1.0
  O  O13  1  0.071  0.260  0.811  1.0
  O  O14  1  0.010  0.321  0.311  1.0
  O  O15  1  0.679  0.990  0.689  1.0
  O  O16  1  0.301  0.990  0.311  1.0
  O  O17  1  0.010  0.699  0.689  1.0
  O  O18  1  0.740  0.929  0.189  1.0
  O  O19  1  0.740  0.551  0.811  1.0
[/CIF]
.