The crystal structure described by WSb3 is alpha bismuth trifluoride structured and crystallizes in the tetragonal I4/mmm space group. W(1) is bonded in a distorted body-centered cubic geometry to four equivalent Sb(2) and eight equivalent Sb(1) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted body-centered cubic geometry to four equivalent W(1) and four equivalent Sb(2) atoms. In the second Sb site, Sb(2) is bonded to four equivalent W(1) and eight equivalent Sb(1) atoms to form a mixture of distorted face, corner, and edge-sharing SbSb8W4 cuboctahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb3W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.079
_cell_length_b   5.079
_cell_length_c   5.079
_cell_angle_alpha   122.354
_cell_angle_beta   122.354
_cell_angle_gamma   85.968
_symmetry_Int_Tables_number   1
_cell_volume   89.114
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.750  0.250  0.500  1.0
  Sb  Sb1  1  0.250  0.750  0.500  1.0
  Sb  Sb2  1  0.500  0.500  0.000  1.0
  W  W3  1  0.000  0.000  0.000  1.0
[/CIF]
.
The crystal structure described by WSb3 is alpha bismuth trifluoride structured and crystallizes in the tetragonal I4/mmm space group. W(1) is bonded in a distorted body-centered cubic geometry to four equivalent Sb(2) and eight equivalent Sb(1) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted body-centered cubic geometry to four equivalent W(1) and four equivalent Sb(2) atoms. In the second Sb site, Sb(2) is bonded to four equivalent W(1) and eight equivalent Sb(1) atoms to form a mixture of distorted face, corner, and edge-sharing SbSb8W4 cuboctahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb3W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.079
_cell_length_b   5.079
_cell_length_c   5.079
_cell_angle_alpha   122.354
_cell_angle_beta   122.354
_cell_angle_gamma   85.968
_symmetry_Int_Tables_number   1
_cell_volume   89.114
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.750  0.250  0.500  1.0
  Sb  Sb1  1  0.250  0.750  0.500  1.0
  Sb  Sb2  1  0.500  0.500  0.000  1.0
  W  W3  1  0.000  0.000  0.000  1.0
[/CIF]
.