The compound described by Mg(Ag2O3)2 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 5-coordinate geometry to one O(3), one O(4), one O(6), and two equivalent O(1) atoms. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one O(2), one O(3), one O(5), and one O(6) atom. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one O(3), one O(5), and two equivalent O(4) atoms. In the third Ag site, Ag(3) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(4), and one O(5) atom. In the fourth Ag site, Ag(4) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to two equivalent Mg(1), one Ag(3), and one Ag(4) atom. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(3), and one Ag(4) atom. In the third O site, O(3) is bonded in a distorted trigonal pyramidal geometry to one Mg(1), one Ag(1), one Ag(2), and one Ag(4) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Mg(1), one Ag(3), and two equivalent Ag(2) atoms. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Ag(3) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mg(1), one Ag(1), and one Ag(4) atom. is represented by the CIF file [CIF]
data_Mg(Ag2O3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.067
_cell_length_b   6.186
_cell_length_c   7.330
_cell_angle_alpha   80.219
_cell_angle_beta   69.477
_cell_angle_gamma   61.928
_symmetry_Int_Tables_number   1
_cell_volume   152.375
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.210  0.199  0.700  1.0
  Ag  Ag1  1  0.576  0.751  0.078  1.0
  Ag  Ag2  1  0.649  0.697  0.552  1.0
  Ag  Ag3  1  0.890  0.218  0.388  1.0
  Ag  Ag4  1  0.451  0.292  0.947  1.0
  O  O5  1  0.827  0.084  0.682  1.0
  O  O6  1  0.001  0.482  0.182  1.0
  O  O7  1  0.697  0.534  0.850  1.0
  O  O8  1  0.309  0.446  0.503  1.0
  O  O9  1  0.467  0.948  0.312  1.0
  O  O10  1  0.192  0.065  0.981  1.0
[/CIF]
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The compound described by Mg(Ag2O3)2 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a 5-coordinate geometry to one O(3), one O(4), one O(6), and two equivalent O(1) atoms. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one O(2), one O(3), one O(5), and one O(6) atom. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one O(3), one O(5), and two equivalent O(4) atoms. In the third Ag site, Ag(3) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(4), and one O(5) atom. In the fourth Ag site, Ag(4) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted see-saw-like geometry to two equivalent Mg(1), one Ag(3), and one Ag(4) atom. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(3), and one Ag(4) atom. In the third O site, O(3) is bonded in a distorted trigonal pyramidal geometry to one Mg(1), one Ag(1), one Ag(2), and one Ag(4) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Mg(1), one Ag(3), and two equivalent Ag(2) atoms. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one Ag(3) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mg(1), one Ag(1), and one Ag(4) atom. is represented by the CIF file [CIF]
data_Mg(Ag2O3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.067
_cell_length_b   6.186
_cell_length_c   7.330
_cell_angle_alpha   80.219
_cell_angle_beta   69.477
_cell_angle_gamma   61.928
_symmetry_Int_Tables_number   1
_cell_volume   152.375
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.210  0.199  0.700  1.0
  Ag  Ag1  1  0.576  0.751  0.078  1.0
  Ag  Ag2  1  0.649  0.697  0.552  1.0
  Ag  Ag3  1  0.890  0.218  0.388  1.0
  Ag  Ag4  1  0.451  0.292  0.947  1.0
  O  O5  1  0.827  0.084  0.682  1.0
  O  O6  1  0.001  0.482  0.182  1.0
  O  O7  1  0.697  0.534  0.850  1.0
  O  O8  1  0.309  0.446  0.503  1.0
  O  O9  1  0.467  0.948  0.312  1.0
  O  O10  1  0.192  0.065  0.981  1.0
[/CIF]
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