The structure described by RbP2(HO2)3 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 10-coordinate geometry to one H(3), one O(3), one O(5), one O(6), two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. In the second P site, P(2) is bonded in a trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(5) atom. In the second H site, H(2) is bonded in a linear geometry to one O(3) and one O(4) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one Rb(1), one O(1), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1), one P(1), and one H(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent Rb(1), one P(1), and one H(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Rb(1), one P(1), and one H(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to two equivalent Rb(1), one P(2), and one H(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(2), and one H(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Rb(1), one P(2), and one H(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbP2(HO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.325
_cell_length_b   7.539
_cell_length_c   7.855
_cell_angle_alpha   88.131
_cell_angle_beta   116.342
_cell_angle_gamma   117.201
_symmetry_Int_Tables_number   1
_cell_volume   337.731
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.469  0.807  0.773  1.0
  Rb  Rb1  1  0.531  0.193  0.227  1.0
  P  P2  1  0.035  0.073  0.639  1.0
  P  P3  1  0.965  0.927  0.361  1.0
  P  P4  1  0.161  0.522  0.128  1.0
  P  P5  1  0.839  0.478  0.872  1.0
  H  H6  1  0.986  0.825  0.822  1.0
  H  H7  1  0.014  0.175  0.178  1.0
  H  H8  1  0.414  0.298  0.774  1.0
  H  H9  1  0.586  0.702  0.226  1.0
  H  H10  1  0.150  0.716  0.327  1.0
  H  H11  1  0.850  0.284  0.673  1.0
  O  O12  1  0.818  0.076  0.610  1.0
  O  O13  1  0.182  0.924  0.390  1.0
  O  O14  1  0.120  0.953  0.792  1.0
  O  O15  1  0.880  0.047  0.208  1.0
  O  O16  1  0.249  0.293  0.696  1.0
  O  O17  1  0.751  0.707  0.304  1.0
  O  O18  1  0.368  0.696  0.115  1.0
  O  O19  1  0.632  0.304  0.885  1.0
  O  O20  1  0.162  0.319  0.135  1.0
  O  O21  1  0.838  0.681  0.865  1.0
  O  O22  1  0.141  0.576  0.310  1.0
  O  O23  1  0.859  0.424  0.690  1.0
[/CIF]
.
The structure described by RbP2(HO2)3 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 10-coordinate geometry to one H(3), one O(3), one O(5), one O(6), two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. In the second P site, P(2) is bonded in a trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(5) atom. In the second H site, H(2) is bonded in a linear geometry to one O(3) and one O(4) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one Rb(1), one O(1), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1), one P(1), and one H(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent Rb(1), one P(1), and one H(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Rb(1), one P(1), and one H(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to two equivalent Rb(1), one P(2), and one H(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(2), and one H(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Rb(1), one P(2), and one H(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbP2(HO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.325
_cell_length_b   7.539
_cell_length_c   7.855
_cell_angle_alpha   88.131
_cell_angle_beta   116.342
_cell_angle_gamma   117.201
_symmetry_Int_Tables_number   1
_cell_volume   337.731
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.469  0.807  0.773  1.0
  Rb  Rb1  1  0.531  0.193  0.227  1.0
  P  P2  1  0.035  0.073  0.639  1.0
  P  P3  1  0.965  0.927  0.361  1.0
  P  P4  1  0.161  0.522  0.128  1.0
  P  P5  1  0.839  0.478  0.872  1.0
  H  H6  1  0.986  0.825  0.822  1.0
  H  H7  1  0.014  0.175  0.178  1.0
  H  H8  1  0.414  0.298  0.774  1.0
  H  H9  1  0.586  0.702  0.226  1.0
  H  H10  1  0.150  0.716  0.327  1.0
  H  H11  1  0.850  0.284  0.673  1.0
  O  O12  1  0.818  0.076  0.610  1.0
  O  O13  1  0.182  0.924  0.390  1.0
  O  O14  1  0.120  0.953  0.792  1.0
  O  O15  1  0.880  0.047  0.208  1.0
  O  O16  1  0.249  0.293  0.696  1.0
  O  O17  1  0.751  0.707  0.304  1.0
  O  O18  1  0.368  0.696  0.115  1.0
  O  O19  1  0.632  0.304  0.885  1.0
  O  O20  1  0.162  0.319  0.135  1.0
  O  O21  1  0.838  0.681  0.865  1.0
  O  O22  1  0.141  0.576  0.310  1.0
  O  O23  1  0.859  0.424  0.690  1.0
[/CIF]
.