The compound described by C8Cl3F2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 2,4,5,7,9,10-hexachloro-1,3,6,8-tetrafluoropyrene molecules. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(3), one C(6), and one Cl(3) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(7), one C(8), and one Cl(2) atom. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(2), and one Cl(1) atom. In the seventh C site, C(7) is bonded in a single-bond geometry to one C(1), one C(5), and one F(2) atom. In the eighth C site, C(8) is bonded in a single-bond geometry to one C(3), one C(5), and one F(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(6) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(5) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(8) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(7) atom. is represented by the CIF card [CIF]
data_C8Cl3F2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.930
_cell_length_b   11.162
_cell_length_c   15.635
_cell_angle_alpha   65.997
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   786.009
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.989  0.816  0.032  1.0
  C  C1  1  0.011  0.184  0.968  1.0
  C  C2  1  0.489  0.184  0.468  1.0
  C  C3  1  0.511  0.816  0.532  1.0
  C  C4  1  0.327  0.859  0.132  1.0
  C  C5  1  0.673  0.141  0.868  1.0
  C  C6  1  0.827  0.141  0.368  1.0
  C  C7  1  0.173  0.859  0.632  1.0
  C  C8  1  0.272  0.997  0.088  1.0
  C  C9  1  0.728  0.003  0.912  1.0
  C  C10  1  0.772  0.003  0.412  1.0
  C  C11  1  0.228  0.997  0.588  1.0
  C  C12  1  0.570  0.955  0.486  1.0
  C  C13  1  0.430  0.045  0.514  1.0
  C  C14  1  0.070  0.045  0.014  1.0
  C  C15  1  0.930  0.955  0.986  1.0
  C  C16  1  0.852  0.776  0.431  1.0
  C  C17  1  0.148  0.224  0.569  1.0
  C  C18  1  0.352  0.224  0.069  1.0
  C  C19  1  0.648  0.776  0.931  1.0
  C  C20  1  0.189  0.771  0.106  1.0
  C  C21  1  0.811  0.229  0.894  1.0
  C  C22  1  0.689  0.229  0.394  1.0
  C  C23  1  0.311  0.771  0.606  1.0
  C  C24  1  0.843  0.731  0.002  1.0
  C  C25  1  0.157  0.269  0.998  1.0
  C  C26  1  0.343  0.269  0.498  1.0
  C  C27  1  0.657  0.731  0.502  1.0
  C  C28  1  0.906  0.909  0.388  1.0
  C  C29  1  0.094  0.091  0.612  1.0
  C  C30  1  0.406  0.091  0.112  1.0
  C  C31  1  0.594  0.909  0.888  1.0
  Cl  Cl32  1  0.761  0.393  0.335  1.0
  Cl  Cl33  1  0.239  0.607  0.665  1.0
  Cl  Cl34  1  0.261  0.607  0.165  1.0
  Cl  Cl35  1  0.739  0.393  0.835  1.0
  Cl  Cl36  1  0.525  0.333  0.100  1.0
  Cl  Cl37  1  0.475  0.667  0.900  1.0
  Cl  Cl38  1  0.025  0.667  0.400  1.0
  Cl  Cl39  1  0.975  0.333  0.600  1.0
  Cl  Cl40  1  0.569  0.796  0.219  1.0
  Cl  Cl41  1  0.431  0.204  0.781  1.0
  Cl  Cl42  1  0.069  0.204  0.281  1.0
  Cl  Cl43  1  0.931  0.796  0.719  1.0
  F  F44  1  0.098  0.944  0.320  1.0
  F  F45  1  0.902  0.056  0.680  1.0
  F  F46  1  0.598  0.056  0.180  1.0
  F  F47  1  0.402  0.944  0.820  1.0
  F  F48  1  0.882  0.601  0.041  1.0
  F  F49  1  0.118  0.399  0.959  1.0
  F  F50  1  0.382  0.399  0.459  1.0
  F  F51  1  0.618  0.601  0.541  1.0
[/CIF]
.
The compound described by C8Cl3F2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 2,4,5,7,9,10-hexachloro-1,3,6,8-tetrafluoropyrene molecules. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(3), one C(6), and one Cl(3) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(7), one C(8), and one Cl(2) atom. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(2), and one Cl(1) atom. In the seventh C site, C(7) is bonded in a single-bond geometry to one C(1), one C(5), and one F(2) atom. In the eighth C site, C(8) is bonded in a single-bond geometry to one C(3), one C(5), and one F(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(6) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(5) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(8) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(7) atom. is represented by the CIF card [CIF]
data_C8Cl3F2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.930
_cell_length_b   11.162
_cell_length_c   15.635
_cell_angle_alpha   65.997
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   786.009
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.989  0.816  0.032  1.0
  C  C1  1  0.011  0.184  0.968  1.0
  C  C2  1  0.489  0.184  0.468  1.0
  C  C3  1  0.511  0.816  0.532  1.0
  C  C4  1  0.327  0.859  0.132  1.0
  C  C5  1  0.673  0.141  0.868  1.0
  C  C6  1  0.827  0.141  0.368  1.0
  C  C7  1  0.173  0.859  0.632  1.0
  C  C8  1  0.272  0.997  0.088  1.0
  C  C9  1  0.728  0.003  0.912  1.0
  C  C10  1  0.772  0.003  0.412  1.0
  C  C11  1  0.228  0.997  0.588  1.0
  C  C12  1  0.570  0.955  0.486  1.0
  C  C13  1  0.430  0.045  0.514  1.0
  C  C14  1  0.070  0.045  0.014  1.0
  C  C15  1  0.930  0.955  0.986  1.0
  C  C16  1  0.852  0.776  0.431  1.0
  C  C17  1  0.148  0.224  0.569  1.0
  C  C18  1  0.352  0.224  0.069  1.0
  C  C19  1  0.648  0.776  0.931  1.0
  C  C20  1  0.189  0.771  0.106  1.0
  C  C21  1  0.811  0.229  0.894  1.0
  C  C22  1  0.689  0.229  0.394  1.0
  C  C23  1  0.311  0.771  0.606  1.0
  C  C24  1  0.843  0.731  0.002  1.0
  C  C25  1  0.157  0.269  0.998  1.0
  C  C26  1  0.343  0.269  0.498  1.0
  C  C27  1  0.657  0.731  0.502  1.0
  C  C28  1  0.906  0.909  0.388  1.0
  C  C29  1  0.094  0.091  0.612  1.0
  C  C30  1  0.406  0.091  0.112  1.0
  C  C31  1  0.594  0.909  0.888  1.0
  Cl  Cl32  1  0.761  0.393  0.335  1.0
  Cl  Cl33  1  0.239  0.607  0.665  1.0
  Cl  Cl34  1  0.261  0.607  0.165  1.0
  Cl  Cl35  1  0.739  0.393  0.835  1.0
  Cl  Cl36  1  0.525  0.333  0.100  1.0
  Cl  Cl37  1  0.475  0.667  0.900  1.0
  Cl  Cl38  1  0.025  0.667  0.400  1.0
  Cl  Cl39  1  0.975  0.333  0.600  1.0
  Cl  Cl40  1  0.569  0.796  0.219  1.0
  Cl  Cl41  1  0.431  0.204  0.781  1.0
  Cl  Cl42  1  0.069  0.204  0.281  1.0
  Cl  Cl43  1  0.931  0.796  0.719  1.0
  F  F44  1  0.098  0.944  0.320  1.0
  F  F45  1  0.902  0.056  0.680  1.0
  F  F46  1  0.598  0.056  0.180  1.0
  F  F47  1  0.402  0.944  0.820  1.0
  F  F48  1  0.882  0.601  0.041  1.0
  F  F49  1  0.118  0.399  0.959  1.0
  F  F50  1  0.382  0.399  0.459  1.0
  F  F51  1  0.618  0.601  0.541  1.0
[/CIF]
.