The structure described by Pr5Co2 crystallizes in the monoclinic C2/c space group. There are three inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a distorted bent 150 degrees geometry to three equivalent Co(1) atoms. In the second Pr site, Pr(3) is bonded to four equivalent Co(1) atoms to form distorted edge-sharing PrCo4 tetrahedra. In the third Pr site, Pr(2) is bonded in a 3-coordinate geometry to three equivalent Co(1) atoms. Co(1) is bonded in a 8-coordinate geometry to two equivalent Pr(3), three equivalent Pr(1), and three equivalent Pr(2) atoms. is represented by the CIF card [CIF]
data_Pr5Co2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.597
_cell_length_b   7.060
_cell_length_c   9.019
_cell_angle_alpha   94.649
_cell_angle_beta   111.452
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   389.515
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.989  0.910  0.189  1.0
  Pr  Pr1  1  0.800  0.590  0.811  1.0
  Pr  Pr2  1  0.011  0.090  0.811  1.0
  Pr  Pr3  1  0.200  0.410  0.189  1.0
  Pr  Pr4  1  0.645  0.826  0.425  1.0
  Pr  Pr5  1  0.221  0.674  0.575  1.0
  Pr  Pr6  1  0.355  0.174  0.575  1.0
  Pr  Pr7  1  0.779  0.326  0.425  1.0
  Pr  Pr8  1  0.434  0.750  0.000  1.0
  Pr  Pr9  1  0.566  0.250  0.000  1.0
  Co  Co10  1  0.825  0.574  0.221  1.0
  Co  Co11  1  0.604  0.926  0.779  1.0
  Co  Co12  1  0.175  0.426  0.779  1.0
  Co  Co13  1  0.396  0.074  0.221  1.0
[/CIF]
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The structure described by Pr5Co2 crystallizes in the monoclinic C2/c space group. There are three inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a distorted bent 150 degrees geometry to three equivalent Co(1) atoms. In the second Pr site, Pr(3) is bonded to four equivalent Co(1) atoms to form distorted edge-sharing PrCo4 tetrahedra. In the third Pr site, Pr(2) is bonded in a 3-coordinate geometry to three equivalent Co(1) atoms. Co(1) is bonded in a 8-coordinate geometry to two equivalent Pr(3), three equivalent Pr(1), and three equivalent Pr(2) atoms. is represented by the CIF card [CIF]
data_Pr5Co2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.597
_cell_length_b   7.060
_cell_length_c   9.019
_cell_angle_alpha   94.649
_cell_angle_beta   111.452
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   389.515
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.989  0.910  0.189  1.0
  Pr  Pr1  1  0.800  0.590  0.811  1.0
  Pr  Pr2  1  0.011  0.090  0.811  1.0
  Pr  Pr3  1  0.200  0.410  0.189  1.0
  Pr  Pr4  1  0.645  0.826  0.425  1.0
  Pr  Pr5  1  0.221  0.674  0.575  1.0
  Pr  Pr6  1  0.355  0.174  0.575  1.0
  Pr  Pr7  1  0.779  0.326  0.425  1.0
  Pr  Pr8  1  0.434  0.750  0.000  1.0
  Pr  Pr9  1  0.566  0.250  0.000  1.0
  Co  Co10  1  0.825  0.574  0.221  1.0
  Co  Co11  1  0.604  0.926  0.779  1.0
  Co  Co12  1  0.175  0.426  0.779  1.0
  Co  Co13  1  0.396  0.074  0.221  1.0
[/CIF]
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