The structure described by MgZn2Te2(MoO6)2 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(11), one O(12), one O(5), and one O(6) atom to form MgO4 tetrahedra that share corners with two equivalent Mo(1)O5 tetrahedra. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(11), one O(3), one O(6), one O(7), and one O(8) atom to form distorted MoO5 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra, corners with two equivalent Mg(1)O4 tetrahedra, and  an edgeedge with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-70°. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(12), one O(5), and one O(9) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form distorted ZnO6 octahedra that share corners with four equivalent Zn(2)O6 octahedra,  a cornercorner with one Mo(1)O5 tetrahedra, and  an edgeedge with one Mo(1)O5 tetrahedra. The corner-sharing octahedral tilt angles range from 54-67°. In the second Zn site, Zn(2) is bonded to one O(1), one O(10), one O(2), one O(4), one O(8), and one O(9) atom to form distorted ZnO6 octahedra that share corners with four equivalent Zn(1)O6 octahedra and  a cornercorner with one Mo(1)O5 tetrahedra. The corner-sharing octahedral tilt angles range from 54-67°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(10), one O(2), and one O(9) atom. In the second Te site, Te(2) is bonded in a distorted see-saw-like geometry to one O(3), one O(4), one O(7), and one O(8) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted tetrahedral geometry to one Mo(2), one Zn(1), one Zn(2), and one Te(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one Te(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mo(1), one Zn(1), and one Te(2) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one Te(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mg(1) and one Mo(1) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mo(1), one Zn(1), and one Te(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Mo(1), one Zn(1), one Zn(2), and one Te(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Mo(2), one Zn(2), and one Te(1) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Mo(2), one Zn(2), and one Te(1) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Mg(1) and one Mo(1) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(2) atom. is represented by the CIF card [CIF]
data_MgZn2Te2(MoO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.091
_cell_length_b   5.352
_cell_length_c   10.223
_cell_angle_alpha   91.209
_cell_angle_beta   87.955
_cell_angle_gamma   91.146
_symmetry_Int_Tables_number   1
_cell_volume   278.248
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.984  0.985  0.995  1.0
  Zn  Zn1  1  0.491  0.496  0.519  1.0
  Zn  Zn2  1  0.004  0.996  0.477  1.0
  Te  Te3  1  0.996  0.501  0.282  1.0
  Te  Te4  1  0.487  0.000  0.714  1.0
  Mo  Mo5  1  0.979  0.484  0.764  1.0
  Mo  Mo6  1  0.475  0.030  0.221  1.0
  O  O7  1  0.235  0.311  0.385  1.0
  O  O8  1  0.793  0.667  0.417  1.0
  O  O9  1  0.709  0.679  0.695  1.0
  O  O10  1  0.276  0.822  0.589  1.0
  O  O11  1  0.704  0.849  0.113  1.0
  O  O12  1  0.860  0.232  0.872  1.0
  O  O13  1  0.264  0.318  0.672  1.0
  O  O14  1  0.735  0.177  0.597  1.0
  O  O15  1  0.245  0.812  0.318  1.0
  O  O16  1  0.752  0.195  0.315  1.0
  O  O17  1  0.122  0.726  0.874  1.0
  O  O18  1  0.251  0.159  0.104  1.0
[/CIF]
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The structure described by MgZn2Te2(MoO6)2 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(11), one O(12), one O(5), and one O(6) atom to form MgO4 tetrahedra that share corners with two equivalent Mo(1)O5 tetrahedra. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(11), one O(3), one O(6), one O(7), and one O(8) atom to form distorted MoO5 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra, corners with two equivalent Mg(1)O4 tetrahedra, and  an edgeedge with one Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-70°. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(12), one O(5), and one O(9) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form distorted ZnO6 octahedra that share corners with four equivalent Zn(2)O6 octahedra,  a cornercorner with one Mo(1)O5 tetrahedra, and  an edgeedge with one Mo(1)O5 tetrahedra. The corner-sharing octahedral tilt angles range from 54-67°. In the second Zn site, Zn(2) is bonded to one O(1), one O(10), one O(2), one O(4), one O(8), and one O(9) atom to form distorted ZnO6 octahedra that share corners with four equivalent Zn(1)O6 octahedra and  a cornercorner with one Mo(1)O5 tetrahedra. The corner-sharing octahedral tilt angles range from 54-67°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(10), one O(2), and one O(9) atom. In the second Te site, Te(2) is bonded in a distorted see-saw-like geometry to one O(3), one O(4), one O(7), and one O(8) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted tetrahedral geometry to one Mo(2), one Zn(1), one Zn(2), and one Te(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one Te(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mo(1), one Zn(1), and one Te(2) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Zn(1), one Zn(2), and one Te(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mg(1) and one Mo(1) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Mo(1), one Zn(1), and one Te(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Mo(1), one Zn(1), one Zn(2), and one Te(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Mo(2), one Zn(2), and one Te(1) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Mo(2), one Zn(2), and one Te(1) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Mg(1) and one Mo(1) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(2) atom. is represented by the CIF card [CIF]
data_MgZn2Te2(MoO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.091
_cell_length_b   5.352
_cell_length_c   10.223
_cell_angle_alpha   91.209
_cell_angle_beta   87.955
_cell_angle_gamma   91.146
_symmetry_Int_Tables_number   1
_cell_volume   278.248
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.984  0.985  0.995  1.0
  Zn  Zn1  1  0.491  0.496  0.519  1.0
  Zn  Zn2  1  0.004  0.996  0.477  1.0
  Te  Te3  1  0.996  0.501  0.282  1.0
  Te  Te4  1  0.487  0.000  0.714  1.0
  Mo  Mo5  1  0.979  0.484  0.764  1.0
  Mo  Mo6  1  0.475  0.030  0.221  1.0
  O  O7  1  0.235  0.311  0.385  1.0
  O  O8  1  0.793  0.667  0.417  1.0
  O  O9  1  0.709  0.679  0.695  1.0
  O  O10  1  0.276  0.822  0.589  1.0
  O  O11  1  0.704  0.849  0.113  1.0
  O  O12  1  0.860  0.232  0.872  1.0
  O  O13  1  0.264  0.318  0.672  1.0
  O  O14  1  0.735  0.177  0.597  1.0
  O  O15  1  0.245  0.812  0.318  1.0
  O  O16  1  0.752  0.195  0.315  1.0
  O  O17  1  0.122  0.726  0.874  1.0
  O  O18  1  0.251  0.159  0.104  1.0
[/CIF]
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