The material described by SrRhN2 crystallizes in the monoclinic P2_1/c space group. Sr(1) is bonded in a 6-coordinate geometry to two equivalent N(2) and four equivalent N(1) atoms. Rh(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form a mixture of distorted edge and corner-sharing RhN4 trigonal pyramids. There are two inequivalent N sites. In the first N site, N(1) is bonded to four equivalent Sr(1) and two equivalent Rh(1) atoms to form a mixture of distorted edge and corner-sharing NSr4Rh2 octahedra. The corner-sharing octahedral tilt angles range from 23-46°. In the second N site, N(2) is bonded in a 3-coordinate geometry to two equivalent Sr(1) and two equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_SrRhN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.088
_cell_length_b   8.357
_cell_length_c   5.329
_cell_angle_alpha   90.000
_cell_angle_beta   110.664
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   253.708
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.334  0.897  0.654  1.0
  Sr  Sr1  1  0.666  0.397  0.846  1.0
  Sr  Sr2  1  0.666  0.103  0.346  1.0
  Sr  Sr3  1  0.334  0.603  0.154  1.0
  Rh  Rh4  1  0.107  0.358  0.570  1.0
  Rh  Rh5  1  0.893  0.858  0.930  1.0
  Rh  Rh6  1  0.893  0.642  0.430  1.0
  Rh  Rh7  1  0.107  0.142  0.070  1.0
  N  N8  1  0.242  0.915  0.092  1.0
  N  N9  1  0.758  0.415  0.408  1.0
  N  N10  1  0.758  0.085  0.908  1.0
  N  N11  1  0.242  0.585  0.592  1.0
  N  N12  1  0.233  0.322  0.959  1.0
  N  N13  1  0.767  0.822  0.541  1.0
  N  N14  1  0.767  0.678  0.041  1.0
  N  N15  1  0.233  0.178  0.459  1.0
[/CIF]
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The material described by SrRhN2 crystallizes in the monoclinic P2_1/c space group. Sr(1) is bonded in a 6-coordinate geometry to two equivalent N(2) and four equivalent N(1) atoms. Rh(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form a mixture of distorted edge and corner-sharing RhN4 trigonal pyramids. There are two inequivalent N sites. In the first N site, N(1) is bonded to four equivalent Sr(1) and two equivalent Rh(1) atoms to form a mixture of distorted edge and corner-sharing NSr4Rh2 octahedra. The corner-sharing octahedral tilt angles range from 23-46°. In the second N site, N(2) is bonded in a 3-coordinate geometry to two equivalent Sr(1) and two equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_SrRhN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.088
_cell_length_b   8.357
_cell_length_c   5.329
_cell_angle_alpha   90.000
_cell_angle_beta   110.664
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   253.708
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.334  0.897  0.654  1.0
  Sr  Sr1  1  0.666  0.397  0.846  1.0
  Sr  Sr2  1  0.666  0.103  0.346  1.0
  Sr  Sr3  1  0.334  0.603  0.154  1.0
  Rh  Rh4  1  0.107  0.358  0.570  1.0
  Rh  Rh5  1  0.893  0.858  0.930  1.0
  Rh  Rh6  1  0.893  0.642  0.430  1.0
  Rh  Rh7  1  0.107  0.142  0.070  1.0
  N  N8  1  0.242  0.915  0.092  1.0
  N  N9  1  0.758  0.415  0.408  1.0
  N  N10  1  0.758  0.085  0.908  1.0
  N  N11  1  0.242  0.585  0.592  1.0
  N  N12  1  0.233  0.322  0.959  1.0
  N  N13  1  0.767  0.822  0.541  1.0
  N  N14  1  0.767  0.678  0.041  1.0
  N  N15  1  0.233  0.178  0.459  1.0
[/CIF]
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