The crystal structure described by Na3Li3Mn2P2(CO7)2 crystallizes in the triclinic P1 space group. There are six inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(2), one O(24), one O(25), and one O(9) atom. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(4), one O(5), and one O(8) atom. In the third Na site, Na(3) is bonded in a 6-coordinate geometry to one O(13), one O(14), one O(2), one O(3), one O(6), and one O(7) atom. In the fourth Na site, Na(4) is bonded in a 6-coordinate geometry to one O(13), one O(14), one O(2), one O(3), one O(6), and one O(8) atom. In the fifth Na site, Na(5) is bonded in a 7-coordinate geometry to one O(15), one O(16), one O(19), one O(21), one O(23), one O(26), and one O(27) atom. In the sixth Na site, Na(6) is bonded in a 7-coordinate geometry to one O(17), one O(18), one O(19), one O(21), one O(24), one O(25), and one O(28) atom. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(23), one O(26), one O(7), and one O(8) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(12), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(15), one O(16), one O(22), one O(23), one O(26), and one O(27) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(17), one O(18), one O(20), one O(24), and one O(28) atom. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(19), one O(20), one O(27), one O(4), and one O(5) atom. In the sixth Li site, Li(6) is bonded in a 5-coordinate geometry to one O(21), one O(22), one O(28), one O(3), and one O(6) atom. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(3), one O(5), one O(7), and one O(8) atom. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(18), one O(4), one O(6), and one O(9) atom. In the third Mn site, Mn(3) is bonded to one O(11), one O(17), one O(19), one O(20), one O(23), and one O(25) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the fourth Mn site, Mn(4) is bonded to one O(13), one O(15), one O(21), one O(22), one O(24), and one O(26) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(27), one O(3), and one O(5) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(28), one O(4), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(1), one O(23), and one O(25) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(2), one O(24), and one O(26) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(15), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra and  a cornercorner with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-63°. In the second P site, P(2) is bonded to one O(10), one O(13), one O(17), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra and  a cornercorner with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-61°. In the third P site, P(3) is bonded to one O(12), one O(16), one O(19), and one O(20) atom to form PO4 tetrahedra that share corners with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-54°. In the fourth P site, P(4) is bonded to one O(14), one O(18), one O(21), and one O(22) atom to form PO4 tetrahedra that share corners with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one Li(1), one Li(2), and one C(3) atom. In the second O site, O(2) is bonded to one Na(1), one Na(3), one Na(4), and one C(4) atom to form distorted ONa3C trigonal pyramids that share  a cornercorner with one O(7)NaLiMnP trigonal pyramid and  an edgeedge with one O(13)Na2MnP tetrahedra. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Na(3), one Na(4), one Li(6), one Mn(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Na(2), one Li(5), one Mn(2), and one C(2) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Na(2), one Li(2), one Li(5), one Mn(1), and one C(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Na(3), one Na(4), one Li(6), one Mn(2), and one C(2) atom. In the seventh O site, O(7) is bonded to one Na(3), one Li(1), one Mn(1), and one P(1) atom to form distorted ONaLiMnP trigonal pyramids that share  a cornercorner with one O(13)Na2MnP tetrahedra,  a cornercorner with one O(11)NaLiMnP tetrahedra,  a cornercorner with one O(16)NaLiMnP tetrahedra,  a cornercorner with one O(23)NaLi2MnC trigonal bipyramid, and  a cornercorner with one O(2)Na3C trigonal pyramid. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Na(2), one Na(4), one Li(1), one Mn(1), and one P(1) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Na(1), one Li(2), one Mn(2), and one P(2) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one Mn(2), and one P(2) atom. In the eleventh O site, O(11) is bonded to one Na(2), one Li(2), one Mn(3), and one P(1) atom to form distorted ONaLiMnP tetrahedra that share  a cornercorner with one O(23)NaLi2MnC trigonal bipyramid,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(17)NaLiMnP trigonal pyramid, and  a cornercorner with one O(7)NaLiMnP trigonal pyramid. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Na(2), one Li(2), one Mn(2), and one P(3) atom. In the thirteenth O site, O(13) is bonded to one Na(3), one Na(4), one Mn(4), and one P(2) atom to form distorted ONa2MnP tetrahedra that share  a cornercorner with one O(22)Li2MnP trigonal pyramid,  a cornercorner with one O(17)NaLiMnP trigonal pyramid,  a cornercorner with one O(7)NaLiMnP trigonal pyramid, and  an edgeedge with one O(2)Na3C trigonal pyramid. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Na(3), one Na(4), one Mn(1), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Na(5), one Li(3), one Mn(4), and one P(1) atom. In the sixteenth O site, O(16) is bonded to one Na(5), one Li(3), one Mn(1), and one P(3) atom to form distorted ONaLiMnP tetrahedra that share corners with two equivalent O(23)NaLi2MnC trigonal bipyramids,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(22)Li2MnP trigonal pyramid,  a cornercorner with one O(7)NaLiMnP trigonal pyramid, and  an edgeedge with one O(27)NaLi2C tetrahedra. In the seventeenth O site, O(17) is bonded to one Na(6), one Li(4), one Mn(3), and one P(2) atom to form distorted ONaLiMnP trigonal pyramids that share  a cornercorner with one O(13)Na2MnP tetrahedra,  a cornercorner with one O(11)NaLiMnP tetrahedra, corners with two equivalent O(28)NaLi2C tetrahedra, corners with two equivalent O(18)NaLiMnP tetrahedra,  a cornercorner with one O(23)NaLi2MnC trigonal bipyramid, and  an edgeedge with one O(20)Li2MnP trigonal pyramid. In the eighteenth O site, O(18) is bonded to one Na(6), one Li(4), one Mn(2), and one P(4) atom to form distorted ONaLiMnP tetrahedra that share  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(22)Li2MnP trigonal pyramid, corners with two equivalent O(17)NaLiMnP trigonal pyramids, and  an edgeedge with one O(28)NaLi2C tetrahedra. In the nineteenth O site, O(19) is bonded in a 5-coordinate geometry to one Na(5), one Na(6), one Li(5), one Mn(3), and one P(3) atom. In the twentieth O site, O(20) is bonded to one Li(4), one Li(5), one Mn(3), and one P(3) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(27)NaLi2C tetrahedra,  a cornercorner with one O(28)NaLi2C tetrahedra,  a cornercorner with one O(11)NaLiMnP tetrahedra,  a cornercorner with one O(16)NaLiMnP tetrahedra,  a cornercorner with one O(18)NaLiMnP tetrahedra,  a cornercorner with one O(23)NaLi2MnC trigonal bipyramid, and  an edgeedge with one O(17)NaLiMnP trigonal pyramid. In the twenty-first O site, O(21) is bonded in a 5-coordinate geometry to one Na(5), one Na(6), one Li(6), one Mn(4), and one P(4) atom. In the twenty-second O site, O(22) is bonded to one Li(3), one Li(6), one Mn(4), and one P(4) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(13)Na2MnP tetrahedra,  a cornercorner with one O(27)NaLi2C tetrahedra,  a cornercorner with one O(28)NaLi2C tetrahedra,  a cornercorner with one O(16)NaLiMnP tetrahedra,  a cornercorner with one O(18)NaLiMnP tetrahedra, and  a cornercorner with one O(23)NaLi2MnC trigonal bipyramid. In the twenty-third O site, O(23) is bonded to one Na(5), one Li(1), one Li(3), one Mn(3), and one C(3) atom to form distorted ONaLi2MnC trigonal bipyramids that share  a cornercorner with one O(11)NaLiMnP tetrahedra, corners with two equivalent O(27)NaLi2C tetrahedra, corners with two equivalent O(16)NaLiMnP tetrahedra,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(22)Li2MnP trigonal pyramid,  a cornercorner with one O(17)NaLiMnP trigonal pyramid, and  a cornercorner with one O(7)NaLiMnP trigonal pyramid. In the twenty-fourth O site, O(24) is bonded in a 5-coordinate geometry to one Na(1), one Na(6), one Li(4), one Mn(4), and one C(4) atom. In the twenty-fifth O site, O(25) is bonded in a 4-coordinate geometry to one Na(1), one Na(6), one Mn(3), and one C(3) atom. In the twenty-sixth O site, O(26) is bonded in a 2-coordinate geometry to one Na(5), one Li(1), one Li(3), one Mn(4), and one C(4) atom. In the twenty-seventh O site, O(27) is bonded to one Na(5), one Li(3), one Li(5), and one C(1) atom to form distorted ONaLi2C tetrahedra that share corners with two equivalent O(23)NaLi2MnC trigonal bipyramids,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(22)Li2MnP trigonal pyramid, and  an edgeedge with one O(16)NaLiMnP tetrahedra. In the twenty-eighth O site, O(28) is bonded to one Na(6), one Li(4), one Li(6), and one C(2) atom to form distorted ONaLi2C tetrahedra that share  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(22)Li2MnP trigonal pyramid, corners with two equivalent O(17)NaLiMnP trigonal pyramids, and  an edgeedge with one O(18)NaLiMnP tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na3Li3Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.766
_cell_length_b   8.751
_cell_length_c   10.150
_cell_angle_alpha   91.064
_cell_angle_beta   90.304
_cell_angle_gamma   91.086
_symmetry_Int_Tables_number   1
_cell_volume   600.786
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.244  0.916  0.379  1.0
  Na  Na1  1  0.500  0.746  0.626  1.0
  Na  Na2  1  0.999  0.745  0.123  1.0
  Na  Na3  1  0.501  0.743  0.122  1.0
  Na  Na4  1  0.501  0.254  0.876  1.0
  Na  Na5  1  0.501  0.255  0.376  1.0
  Li  Li6  1  0.236  0.920  0.875  1.0
  Li  Li7  1  0.020  0.730  0.621  1.0
  Li  Li8  1  0.982  0.266  0.884  1.0
  Li  Li9  1  0.980  0.270  0.384  1.0
  Li  Li10  1  0.767  0.086  0.626  1.0
  Li  Li11  1  0.760  0.089  0.123  1.0
  Mn  Mn12  1  0.751  0.642  0.885  1.0
  Mn  Mn13  1  0.752  0.640  0.391  1.0
  Mn  Mn14  1  0.246  0.355  0.613  1.0
  Mn  Mn15  1  0.245  0.356  0.109  1.0
  P  P16  1  0.241  0.595  0.849  1.0
  P  P17  1  0.245  0.585  0.354  1.0
  P  P18  1  0.758  0.406  0.649  1.0
  P  P19  1  0.753  0.402  0.146  1.0
  C  C20  1  0.760  0.955  0.866  1.0
  C  C21  1  0.759  0.955  0.367  1.0
  C  C22  1  0.239  0.052  0.639  1.0
  C  C23  1  0.248  0.051  0.130  1.0
  O  O24  1  0.227  0.904  0.654  1.0
  O  O25  1  0.255  0.907  0.150  1.0
  O  O26  1  0.753  0.910  0.987  1.0
  O  O27  1  0.751  0.910  0.489  1.0
  O  O28  1  0.753  0.854  0.769  1.0
  O  O29  1  0.753  0.853  0.271  1.0
  O  O30  1  0.068  0.696  0.897  1.0
  O  O31  1  0.434  0.684  0.889  1.0
  O  O32  1  0.068  0.683  0.401  1.0
  O  O33  1  0.436  0.673  0.399  1.0
  O  O34  1  0.231  0.579  0.695  1.0
  O  O35  1  0.768  0.572  0.595  1.0
  O  O36  1  0.243  0.573  0.200  1.0
  O  O37  1  0.749  0.564  0.088  1.0
  O  O38  1  0.233  0.430  0.905  1.0
  O  O39  1  0.773  0.420  0.802  1.0
  O  O40  1  0.232  0.420  0.408  1.0
  O  O41  1  0.771  0.420  0.300  1.0
  O  O42  1  0.564  0.319  0.609  1.0
  O  O43  1  0.928  0.304  0.595  1.0
  O  O44  1  0.564  0.306  0.110  1.0
  O  O45  1  0.927  0.305  0.093  1.0
  O  O46  1  0.243  0.141  0.743  1.0
  O  O47  1  0.242  0.147  0.230  1.0
  O  O48  1  0.249  0.111  0.523  1.0
  O  O49  1  0.247  0.102  0.010  1.0
  O  O50  1  0.773  0.099  0.838  1.0
  O  O51  1  0.774  0.098  0.339  1.0
[/CIF]
.
The crystal structure described by Na3Li3Mn2P2(CO7)2 crystallizes in the triclinic P1 space group. There are six inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(2), one O(24), one O(25), and one O(9) atom. In the second Na site, Na(2) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(4), one O(5), and one O(8) atom. In the third Na site, Na(3) is bonded in a 6-coordinate geometry to one O(13), one O(14), one O(2), one O(3), one O(6), and one O(7) atom. In the fourth Na site, Na(4) is bonded in a 6-coordinate geometry to one O(13), one O(14), one O(2), one O(3), one O(6), and one O(8) atom. In the fifth Na site, Na(5) is bonded in a 7-coordinate geometry to one O(15), one O(16), one O(19), one O(21), one O(23), one O(26), and one O(27) atom. In the sixth Na site, Na(6) is bonded in a 7-coordinate geometry to one O(17), one O(18), one O(19), one O(21), one O(24), one O(25), and one O(28) atom. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(23), one O(26), one O(7), and one O(8) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(12), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(15), one O(16), one O(22), one O(23), one O(26), and one O(27) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one O(17), one O(18), one O(20), one O(24), and one O(28) atom. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(19), one O(20), one O(27), one O(4), and one O(5) atom. In the sixth Li site, Li(6) is bonded in a 5-coordinate geometry to one O(21), one O(22), one O(28), one O(3), and one O(6) atom. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(3), one O(5), one O(7), and one O(8) atom. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(18), one O(4), one O(6), and one O(9) atom. In the third Mn site, Mn(3) is bonded to one O(11), one O(17), one O(19), one O(20), one O(23), and one O(25) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. In the fourth Mn site, Mn(4) is bonded to one O(13), one O(15), one O(21), one O(22), one O(24), and one O(26) atom to form distorted MnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(4)O4 tetrahedra. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(27), one O(3), and one O(5) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(28), one O(4), and one O(6) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(1), one O(23), and one O(25) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(2), one O(24), and one O(26) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(15), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra and  a cornercorner with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-63°. In the second P site, P(2) is bonded to one O(10), one O(13), one O(17), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra and  a cornercorner with one Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-61°. In the third P site, P(3) is bonded to one O(12), one O(16), one O(19), and one O(20) atom to form PO4 tetrahedra that share corners with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-54°. In the fourth P site, P(4) is bonded to one O(14), one O(18), one O(21), and one O(22) atom to form PO4 tetrahedra that share corners with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one Li(1), one Li(2), and one C(3) atom. In the second O site, O(2) is bonded to one Na(1), one Na(3), one Na(4), and one C(4) atom to form distorted ONa3C trigonal pyramids that share  a cornercorner with one O(7)NaLiMnP trigonal pyramid and  an edgeedge with one O(13)Na2MnP tetrahedra. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Na(3), one Na(4), one Li(6), one Mn(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Na(2), one Li(5), one Mn(2), and one C(2) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one Na(2), one Li(2), one Li(5), one Mn(1), and one C(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one Na(3), one Na(4), one Li(6), one Mn(2), and one C(2) atom. In the seventh O site, O(7) is bonded to one Na(3), one Li(1), one Mn(1), and one P(1) atom to form distorted ONaLiMnP trigonal pyramids that share  a cornercorner with one O(13)Na2MnP tetrahedra,  a cornercorner with one O(11)NaLiMnP tetrahedra,  a cornercorner with one O(16)NaLiMnP tetrahedra,  a cornercorner with one O(23)NaLi2MnC trigonal bipyramid, and  a cornercorner with one O(2)Na3C trigonal pyramid. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one Na(2), one Na(4), one Li(1), one Mn(1), and one P(1) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Na(1), one Li(2), one Mn(2), and one P(2) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one Mn(2), and one P(2) atom. In the eleventh O site, O(11) is bonded to one Na(2), one Li(2), one Mn(3), and one P(1) atom to form distorted ONaLiMnP tetrahedra that share  a cornercorner with one O(23)NaLi2MnC trigonal bipyramid,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(17)NaLiMnP trigonal pyramid, and  a cornercorner with one O(7)NaLiMnP trigonal pyramid. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Na(2), one Li(2), one Mn(2), and one P(3) atom. In the thirteenth O site, O(13) is bonded to one Na(3), one Na(4), one Mn(4), and one P(2) atom to form distorted ONa2MnP tetrahedra that share  a cornercorner with one O(22)Li2MnP trigonal pyramid,  a cornercorner with one O(17)NaLiMnP trigonal pyramid,  a cornercorner with one O(7)NaLiMnP trigonal pyramid, and  an edgeedge with one O(2)Na3C trigonal pyramid. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Na(3), one Na(4), one Mn(1), and one P(4) atom. In the fifteenth O site, O(15) is bonded in a 4-coordinate geometry to one Na(5), one Li(3), one Mn(4), and one P(1) atom. In the sixteenth O site, O(16) is bonded to one Na(5), one Li(3), one Mn(1), and one P(3) atom to form distorted ONaLiMnP tetrahedra that share corners with two equivalent O(23)NaLi2MnC trigonal bipyramids,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(22)Li2MnP trigonal pyramid,  a cornercorner with one O(7)NaLiMnP trigonal pyramid, and  an edgeedge with one O(27)NaLi2C tetrahedra. In the seventeenth O site, O(17) is bonded to one Na(6), one Li(4), one Mn(3), and one P(2) atom to form distorted ONaLiMnP trigonal pyramids that share  a cornercorner with one O(13)Na2MnP tetrahedra,  a cornercorner with one O(11)NaLiMnP tetrahedra, corners with two equivalent O(28)NaLi2C tetrahedra, corners with two equivalent O(18)NaLiMnP tetrahedra,  a cornercorner with one O(23)NaLi2MnC trigonal bipyramid, and  an edgeedge with one O(20)Li2MnP trigonal pyramid. In the eighteenth O site, O(18) is bonded to one Na(6), one Li(4), one Mn(2), and one P(4) atom to form distorted ONaLiMnP tetrahedra that share  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(22)Li2MnP trigonal pyramid, corners with two equivalent O(17)NaLiMnP trigonal pyramids, and  an edgeedge with one O(28)NaLi2C tetrahedra. In the nineteenth O site, O(19) is bonded in a 5-coordinate geometry to one Na(5), one Na(6), one Li(5), one Mn(3), and one P(3) atom. In the twentieth O site, O(20) is bonded to one Li(4), one Li(5), one Mn(3), and one P(3) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(27)NaLi2C tetrahedra,  a cornercorner with one O(28)NaLi2C tetrahedra,  a cornercorner with one O(11)NaLiMnP tetrahedra,  a cornercorner with one O(16)NaLiMnP tetrahedra,  a cornercorner with one O(18)NaLiMnP tetrahedra,  a cornercorner with one O(23)NaLi2MnC trigonal bipyramid, and  an edgeedge with one O(17)NaLiMnP trigonal pyramid. In the twenty-first O site, O(21) is bonded in a 5-coordinate geometry to one Na(5), one Na(6), one Li(6), one Mn(4), and one P(4) atom. In the twenty-second O site, O(22) is bonded to one Li(3), one Li(6), one Mn(4), and one P(4) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(13)Na2MnP tetrahedra,  a cornercorner with one O(27)NaLi2C tetrahedra,  a cornercorner with one O(28)NaLi2C tetrahedra,  a cornercorner with one O(16)NaLiMnP tetrahedra,  a cornercorner with one O(18)NaLiMnP tetrahedra, and  a cornercorner with one O(23)NaLi2MnC trigonal bipyramid. In the twenty-third O site, O(23) is bonded to one Na(5), one Li(1), one Li(3), one Mn(3), and one C(3) atom to form distorted ONaLi2MnC trigonal bipyramids that share  a cornercorner with one O(11)NaLiMnP tetrahedra, corners with two equivalent O(27)NaLi2C tetrahedra, corners with two equivalent O(16)NaLiMnP tetrahedra,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(22)Li2MnP trigonal pyramid,  a cornercorner with one O(17)NaLiMnP trigonal pyramid, and  a cornercorner with one O(7)NaLiMnP trigonal pyramid. In the twenty-fourth O site, O(24) is bonded in a 5-coordinate geometry to one Na(1), one Na(6), one Li(4), one Mn(4), and one C(4) atom. In the twenty-fifth O site, O(25) is bonded in a 4-coordinate geometry to one Na(1), one Na(6), one Mn(3), and one C(3) atom. In the twenty-sixth O site, O(26) is bonded in a 2-coordinate geometry to one Na(5), one Li(1), one Li(3), one Mn(4), and one C(4) atom. In the twenty-seventh O site, O(27) is bonded to one Na(5), one Li(3), one Li(5), and one C(1) atom to form distorted ONaLi2C tetrahedra that share corners with two equivalent O(23)NaLi2MnC trigonal bipyramids,  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(22)Li2MnP trigonal pyramid, and  an edgeedge with one O(16)NaLiMnP tetrahedra. In the twenty-eighth O site, O(28) is bonded to one Na(6), one Li(4), one Li(6), and one C(2) atom to form distorted ONaLi2C tetrahedra that share  a cornercorner with one O(20)Li2MnP trigonal pyramid,  a cornercorner with one O(22)Li2MnP trigonal pyramid, corners with two equivalent O(17)NaLiMnP trigonal pyramids, and  an edgeedge with one O(18)NaLiMnP tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na3Li3Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.766
_cell_length_b   8.751
_cell_length_c   10.150
_cell_angle_alpha   91.064
_cell_angle_beta   90.304
_cell_angle_gamma   91.086
_symmetry_Int_Tables_number   1
_cell_volume   600.786
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.244  0.916  0.379  1.0
  Na  Na1  1  0.500  0.746  0.626  1.0
  Na  Na2  1  0.999  0.745  0.123  1.0
  Na  Na3  1  0.501  0.743  0.122  1.0
  Na  Na4  1  0.501  0.254  0.876  1.0
  Na  Na5  1  0.501  0.255  0.376  1.0
  Li  Li6  1  0.236  0.920  0.875  1.0
  Li  Li7  1  0.020  0.730  0.621  1.0
  Li  Li8  1  0.982  0.266  0.884  1.0
  Li  Li9  1  0.980  0.270  0.384  1.0
  Li  Li10  1  0.767  0.086  0.626  1.0
  Li  Li11  1  0.760  0.089  0.123  1.0
  Mn  Mn12  1  0.751  0.642  0.885  1.0
  Mn  Mn13  1  0.752  0.640  0.391  1.0
  Mn  Mn14  1  0.246  0.355  0.613  1.0
  Mn  Mn15  1  0.245  0.356  0.109  1.0
  P  P16  1  0.241  0.595  0.849  1.0
  P  P17  1  0.245  0.585  0.354  1.0
  P  P18  1  0.758  0.406  0.649  1.0
  P  P19  1  0.753  0.402  0.146  1.0
  C  C20  1  0.760  0.955  0.866  1.0
  C  C21  1  0.759  0.955  0.367  1.0
  C  C22  1  0.239  0.052  0.639  1.0
  C  C23  1  0.248  0.051  0.130  1.0
  O  O24  1  0.227  0.904  0.654  1.0
  O  O25  1  0.255  0.907  0.150  1.0
  O  O26  1  0.753  0.910  0.987  1.0
  O  O27  1  0.751  0.910  0.489  1.0
  O  O28  1  0.753  0.854  0.769  1.0
  O  O29  1  0.753  0.853  0.271  1.0
  O  O30  1  0.068  0.696  0.897  1.0
  O  O31  1  0.434  0.684  0.889  1.0
  O  O32  1  0.068  0.683  0.401  1.0
  O  O33  1  0.436  0.673  0.399  1.0
  O  O34  1  0.231  0.579  0.695  1.0
  O  O35  1  0.768  0.572  0.595  1.0
  O  O36  1  0.243  0.573  0.200  1.0
  O  O37  1  0.749  0.564  0.088  1.0
  O  O38  1  0.233  0.430  0.905  1.0
  O  O39  1  0.773  0.420  0.802  1.0
  O  O40  1  0.232  0.420  0.408  1.0
  O  O41  1  0.771  0.420  0.300  1.0
  O  O42  1  0.564  0.319  0.609  1.0
  O  O43  1  0.928  0.304  0.595  1.0
  O  O44  1  0.564  0.306  0.110  1.0
  O  O45  1  0.927  0.305  0.093  1.0
  O  O46  1  0.243  0.141  0.743  1.0
  O  O47  1  0.242  0.147  0.230  1.0
  O  O48  1  0.249  0.111  0.523  1.0
  O  O49  1  0.247  0.102  0.010  1.0
  O  O50  1  0.773  0.099  0.838  1.0
  O  O51  1  0.774  0.098  0.339  1.0
[/CIF]
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