The material described by PrIn2Cl5 crystallizes in the orthorhombic Pnma space group. Pr(1) is bonded to one Cl(1), one Cl(3), one Cl(4), and four equivalent Cl(2) atoms to form edge-sharing PrCl7 pentagonal bipyramids. In(1) is bonded in a 4-coordinate geometry to one Cl(3), one Cl(4), and two equivalent Cl(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pr(1) and four equivalent In(1) atoms. In the second Cl site, Cl(2) is bonded in a water-like geometry to two equivalent Pr(1) atoms. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Pr(1) and two equivalent In(1) atoms. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Pr(1) and two equivalent In(1) atoms. is represented by the CIF card [CIF]
data_PrIn2Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.124
_cell_length_b   8.867
_cell_length_c   12.762
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   919.320
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.923  0.750  0.507  1.0
  Pr  Pr1  1  0.577  0.750  0.007  1.0
  Pr  Pr2  1  0.077  0.250  0.493  1.0
  Pr  Pr3  1  0.423  0.250  0.993  1.0
  In  In4  1  0.943  0.008  0.829  1.0
  In  In5  1  0.057  0.992  0.171  1.0
  In  In6  1  0.557  0.492  0.329  1.0
  In  In7  1  0.057  0.508  0.171  1.0
  In  In8  1  0.943  0.492  0.829  1.0
  In  In9  1  0.443  0.508  0.671  1.0
  In  In10  1  0.557  0.008  0.329  1.0
  In  In11  1  0.443  0.992  0.671  1.0
  Cl  Cl12  1  0.576  0.750  0.505  1.0
  Cl  Cl13  1  0.170  0.955  0.427  1.0
  Cl  Cl14  1  0.830  0.045  0.573  1.0
  Cl  Cl15  1  0.330  0.545  0.927  1.0
  Cl  Cl16  1  0.170  0.545  0.427  1.0
  Cl  Cl17  1  0.343  0.250  0.208  1.0
  Cl  Cl18  1  0.330  0.955  0.927  1.0
  Cl  Cl19  1  0.830  0.455  0.573  1.0
  Cl  Cl20  1  0.390  0.750  0.189  1.0
  Cl  Cl21  1  0.670  0.045  0.073  1.0
  Cl  Cl22  1  0.157  0.250  0.708  1.0
  Cl  Cl23  1  0.610  0.250  0.811  1.0
  Cl  Cl24  1  0.424  0.250  0.495  1.0
  Cl  Cl25  1  0.110  0.750  0.689  1.0
  Cl  Cl26  1  0.670  0.455  0.073  1.0
  Cl  Cl27  1  0.076  0.250  0.995  1.0
  Cl  Cl28  1  0.924  0.750  0.005  1.0
  Cl  Cl29  1  0.843  0.750  0.292  1.0
  Cl  Cl30  1  0.657  0.750  0.792  1.0
  Cl  Cl31  1  0.890  0.250  0.311  1.0
[/CIF]
.
The material described by PrIn2Cl5 crystallizes in the orthorhombic Pnma space group. Pr(1) is bonded to one Cl(1), one Cl(3), one Cl(4), and four equivalent Cl(2) atoms to form edge-sharing PrCl7 pentagonal bipyramids. In(1) is bonded in a 4-coordinate geometry to one Cl(3), one Cl(4), and two equivalent Cl(1) atoms. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Pr(1) and four equivalent In(1) atoms. In the second Cl site, Cl(2) is bonded in a water-like geometry to two equivalent Pr(1) atoms. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Pr(1) and two equivalent In(1) atoms. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Pr(1) and two equivalent In(1) atoms. is represented by the CIF card [CIF]
data_PrIn2Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.124
_cell_length_b   8.867
_cell_length_c   12.762
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   919.320
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.923  0.750  0.507  1.0
  Pr  Pr1  1  0.577  0.750  0.007  1.0
  Pr  Pr2  1  0.077  0.250  0.493  1.0
  Pr  Pr3  1  0.423  0.250  0.993  1.0
  In  In4  1  0.943  0.008  0.829  1.0
  In  In5  1  0.057  0.992  0.171  1.0
  In  In6  1  0.557  0.492  0.329  1.0
  In  In7  1  0.057  0.508  0.171  1.0
  In  In8  1  0.943  0.492  0.829  1.0
  In  In9  1  0.443  0.508  0.671  1.0
  In  In10  1  0.557  0.008  0.329  1.0
  In  In11  1  0.443  0.992  0.671  1.0
  Cl  Cl12  1  0.576  0.750  0.505  1.0
  Cl  Cl13  1  0.170  0.955  0.427  1.0
  Cl  Cl14  1  0.830  0.045  0.573  1.0
  Cl  Cl15  1  0.330  0.545  0.927  1.0
  Cl  Cl16  1  0.170  0.545  0.427  1.0
  Cl  Cl17  1  0.343  0.250  0.208  1.0
  Cl  Cl18  1  0.330  0.955  0.927  1.0
  Cl  Cl19  1  0.830  0.455  0.573  1.0
  Cl  Cl20  1  0.390  0.750  0.189  1.0
  Cl  Cl21  1  0.670  0.045  0.073  1.0
  Cl  Cl22  1  0.157  0.250  0.708  1.0
  Cl  Cl23  1  0.610  0.250  0.811  1.0
  Cl  Cl24  1  0.424  0.250  0.495  1.0
  Cl  Cl25  1  0.110  0.750  0.689  1.0
  Cl  Cl26  1  0.670  0.455  0.073  1.0
  Cl  Cl27  1  0.076  0.250  0.995  1.0
  Cl  Cl28  1  0.924  0.750  0.005  1.0
  Cl  Cl29  1  0.843  0.750  0.292  1.0
  Cl  Cl30  1  0.657  0.750  0.792  1.0
  Cl  Cl31  1  0.890  0.250  0.311  1.0
[/CIF]
.