The material described by Na3Sr4La3Ti10O30 crystallizes in the triclinic P1 space group. There are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(16), one O(18), one O(4), one O(6), one O(8), one O(9), two equivalent O(19), and two equivalent O(3) atoms. In the second Na site, Na(2) is bonded in a 12-coordinate geometry to one O(15), one O(16), one O(17), one O(18), one O(22), one O(24), one O(8), one O(9), two equivalent O(25), and two equivalent O(7) atoms. In the third Na site, Na(3) is bonded to one O(14), one O(15), one O(17), one O(21), one O(22), one O(23), one O(24), one O(26), two equivalent O(13), and two equivalent O(28) atoms to form distorted NaO12 cuboctahedra that share corners with four equivalent Na(3)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra, faces with four equivalent La(3)O12 cuboctahedra, faces with two equivalent Ti(4)O6 octahedra, faces with two equivalent Ti(6)O6 octahedra, faces with two equivalent Ti(7)O6 octahedra, and faces with two equivalent Ti(9)O6 octahedra. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(1), one O(10), one O(11), one O(27), one O(30), one O(4), one O(5), one O(6), two equivalent O(12), and two equivalent O(2) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, faces with four equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent Ti(10)O6 octahedra, faces with two equivalent Ti(3)O6 octahedra, and faces with two equivalent Ti(8)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(1), one O(10), one O(11), one O(27), one O(30), one O(4), one O(5), one O(6), two equivalent O(12), and two equivalent O(2) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra, faces with four equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent Ti(10)O6 octahedra, faces with two equivalent Ti(3)O6 octahedra, and faces with two equivalent Ti(8)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(1), one O(14), one O(21), one O(23), one O(26), one O(27), one O(30), one O(5), two equivalent O(20), and two equivalent O(29) atoms to form distorted SrO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra,  a faceface with one Na(3)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra, faces with four equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Ti(10)O6 octahedra, faces with two equivalent Ti(7)O6 octahedra, faces with two equivalent Ti(8)O6 octahedra, and faces with two equivalent Ti(9)O6 octahedra. In the fourth Sr site, Sr(4) is bonded to one O(1), one O(14), one O(21), one O(23), one O(26), one O(27), one O(30), one O(5), two equivalent O(20), and two equivalent O(29) atoms to form SrO12 cuboctahedra that share corners with four equivalent Na(3)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra, faces with four equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ti(10)O6 octahedra, faces with two equivalent Ti(7)O6 octahedra, faces with two equivalent Ti(8)O6 octahedra, and faces with two equivalent Ti(9)O6 octahedra. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(16), one O(18), one O(4), one O(6), one O(8), one O(9), two equivalent O(19), and two equivalent O(3) atoms. In the second La site, La(2) is bonded in a 12-coordinate geometry to one O(15), one O(16), one O(17), one O(18), one O(22), one O(24), one O(8), one O(9), two equivalent O(25), and two equivalent O(7) atoms. In the third La site, La(3) is bonded to one O(14), one O(15), one O(17), one O(21), one O(22), one O(23), one O(24), one O(26), two equivalent O(13), and two equivalent O(28) atoms to form distorted LaO12 cuboctahedra that share corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, faces with four equivalent Na(3)O12 cuboctahedra, faces with two equivalent Ti(4)O6 octahedra, faces with two equivalent Ti(6)O6 octahedra, faces with two equivalent Ti(7)O6 octahedra, and faces with two equivalent Ti(9)O6 octahedra. There are ten inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(10), one O(11), one O(12), one O(3), one O(4), and one O(6) atom to form TiO6 octahedra that share  a cornercorner with one Ti(5)O6 octahedra,  a cornercorner with one Ti(8)O6 octahedra, corners with four equivalent Ti(3)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-16°. In the second Ti site, Ti(2) is bonded to one O(16), one O(18), one O(19), one O(7), one O(8), and one O(9) atom to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 3-20°. In the third Ti site, Ti(3) is bonded to one O(10), one O(11), one O(19), one O(2), one O(4), and one O(6) atom to form TiO6 octahedra that share  a cornercorner with one Ti(10)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra, corners with four equivalent Ti(1)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-20°. In the fourth Ti site, Ti(4) is bonded to one O(13), one O(15), one O(17), one O(22), one O(24), and one O(25) atom to form TiO6 octahedra that share  a cornercorner with one Ti(5)O6 octahedra,  a cornercorner with one Ti(7)O6 octahedra, corners with four equivalent Ti(6)O6 octahedra, faces with two equivalent Na(3)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 3-22°. In the fifth Ti site, Ti(5) is bonded to one O(16), one O(18), one O(25), one O(3), one O(8), and one O(9) atom to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 3-22°. In the sixth Ti site, Ti(6) is bonded to one O(15), one O(17), one O(22), one O(24), one O(28), and one O(7) atom to form TiO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Ti(9)O6 octahedra, corners with four equivalent Ti(4)O6 octahedra, faces with two equivalent Na(3)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 3-20°. In the seventh Ti site, Ti(7) is bonded to one O(13), one O(14), one O(21), one O(23), one O(26), and one O(29) atom to form TiO6 octahedra that share  a cornercorner with one Ti(10)O6 octahedra,  a cornercorner with one Ti(4)O6 octahedra, corners with four equivalent Ti(9)O6 octahedra, faces with two equivalent Na(3)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-16°. In the eighth Ti site, Ti(8) is bonded to one O(1), one O(12), one O(20), one O(27), one O(30), and one O(5) atom to form TiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(9)O6 octahedra, corners with four equivalent Ti(10)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Sr(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the ninth Ti site, Ti(9) is bonded to one O(14), one O(20), one O(21), one O(23), one O(26), and one O(28) atom to form TiO6 octahedra that share  a cornercorner with one Ti(6)O6 octahedra,  a cornercorner with one Ti(8)O6 octahedra, corners with four equivalent Ti(7)O6 octahedra, faces with two equivalent Na(3)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-18°. In the tenth Ti site, Ti(10) is bonded to one O(1), one O(2), one O(27), one O(29), one O(30), and one O(5) atom to form TiO6 octahedra that share  a cornercorner with one Ti(3)O6 octahedra,  a cornercorner with one Ti(7)O6 octahedra, corners with four equivalent Ti(8)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Sr(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-12°. There are thirty inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Ti(10), and one Ti(8) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Sr(2), one Ti(10), and one Ti(3) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to two equivalent Na(1), two equivalent La(1), one Ti(1), and one Ti(5) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Na(1), one Sr(1), one Sr(2), one La(1), one Ti(1), and one Ti(3) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Ti(10), and one Ti(8) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Na(1), one Sr(1), one Sr(2), one La(1), one Ti(1), and one Ti(3) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to two equivalent Na(2), two equivalent La(2), one Ti(2), and one Ti(6) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Na(1), one Na(2), one La(1), one La(2), one Ti(2), and one Ti(5) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one La(1), one La(2), one Ti(2), and one Ti(5) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Na(1), one Sr(1), one Sr(2), one La(1), one Ti(1), and one Ti(3) atom. In the eleventh O site, O(11) is bonded in a distorted octahedral geometry to one Na(1), one Sr(1), one Sr(2), one La(1), one Ti(1), and one Ti(3) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Sr(2), one Ti(1), and one Ti(8) atom. In the thirteenth O site, O(13) is bonded in a 2-coordinate geometry to two equivalent Na(3), two equivalent La(3), one Ti(4), and one Ti(7) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one Na(3), one Sr(3), one Sr(4), one La(3), one Ti(7), and one Ti(9) atom. In the fifteenth O site, O(15) is bonded in a distorted linear geometry to one Na(2), one Na(3), one La(2), one La(3), one Ti(4), and one Ti(6) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one La(1), one La(2), one Ti(2), and one Ti(5) atom. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one La(2), one La(3), one Ti(4), and one Ti(6) atom. In the eighteenth O site, O(18) is bonded in a distorted linear geometry to one Na(1), one Na(2), one La(1), one La(2), one Ti(2), and one Ti(5) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to two equivalent Na(1), two equivalent La(1), one Ti(2), and one Ti(3) atom. In the twentieth O site, O(20) is bonded in a 2-coordinate geometry to two equivalent Sr(3), two equivalent Sr(4), one Ti(8), and one Ti(9) atom. In the twenty-first O site, O(21) is bonded in a distorted linear geometry to one Na(3), one Sr(3), one Sr(4), one La(3), one Ti(7), and one Ti(9) atom. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one La(2), one La(3), one Ti(4), and one Ti(6) atom. In the twenty-third O site, O(23) is bonded in a 2-coordinate geometry to one Na(3), one Sr(3), one Sr(4), one La(3), one Ti(7), and one Ti(9) atom. In the twenty-fourth O site, O(24) is bonded in a distorted linear geometry to one Na(2), one Na(3), one La(2), one La(3), one Ti(4), and one Ti(6) atom. In the twenty-fifth O site, O(25) is bonded in a 4-coordinate geometry to two equivalent Na(2), two equivalent La(2), one Ti(4), and one Ti(5) atom. In the twenty-sixth O site, O(26) is bonded in a 2-coordinate geometry to one Na(3), one Sr(3), one Sr(4), one La(3), one Ti(7), and one Ti(9) atom. In the twenty-seventh O site, O(27) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Ti(10), and one Ti(8) atom. In the twenty-eighth O site, O(28) is bonded in a 4-coordinate geometry to two equivalent Na(3), two equivalent La(3), one Ti(6), and one Ti(9) atom. In the twenty-ninth O site, O(29) is bonded in a 2-coordinate geometry to two equivalent Sr(3), two equivalent Sr(4), one Ti(10), and one Ti(7) atom. In the thirtieth O site, O(30) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Ti(10), and one Ti(8) atom. is represented by the CIF card [CIF]
data_Na3Sr4La3Ti10O30
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.544
_cell_length_b   5.549
_cell_length_c   19.905
_cell_angle_alpha   97.938
_cell_angle_beta   97.927
_cell_angle_gamma   90.437
_symmetry_Int_Tables_number   1
_cell_volume   600.392
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.149  0.643  0.300  1.0
  Na  Na1  1  0.746  0.246  0.499  1.0
  Na  Na2  1  0.347  0.850  0.698  1.0
  Sr  Sr3  1  0.049  0.551  0.101  1.0
  Sr  Sr4  1  0.550  0.050  0.099  1.0
  Sr  Sr5  1  0.448  0.953  0.897  1.0
  Sr  Sr6  1  0.949  0.453  0.899  1.0
  La  La7  1  0.649  0.141  0.300  1.0
  La  La8  1  0.246  0.746  0.499  1.0
  La  La9  1  0.846  0.350  0.697  1.0
  Ti  Ti10  1  0.097  0.095  0.200  1.0
  Ti  Ti11  1  0.697  0.690  0.399  1.0
  Ti  Ti12  1  0.600  0.596  0.201  1.0
  Ti  Ti13  1  0.295  0.297  0.598  1.0
  Ti  Ti14  1  0.197  0.191  0.400  1.0
  Ti  Ti15  1  0.794  0.797  0.598  1.0
  Ti  Ti16  1  0.393  0.402  0.796  1.0
  Ti  Ti17  1  0.999  0.002  0.998  1.0
  Ti  Ti18  1  0.898  0.906  0.796  1.0
  Ti  Ti19  1  0.499  0.503  0.998  1.0
  O  O20  1  0.753  0.252  0.000  1.0
  O  O21  1  0.528  0.530  0.101  1.0
  O  O22  1  0.111  0.123  0.302  1.0
  O  O23  1  0.848  0.349  0.202  1.0
  O  O24  1  0.756  0.755  0.009  1.0
  O  O25  1  0.843  0.852  0.191  1.0
  O  O26  1  0.704  0.719  0.500  1.0
  O  O27  1  0.448  0.951  0.401  1.0
  O  O28  1  0.454  0.436  0.385  1.0
  O  O29  1  0.367  0.352  0.214  1.0
  O  O30  1  0.359  0.860  0.203  1.0
  O  O31  1  0.075  0.076  0.101  1.0
  O  O32  1  0.310  0.318  0.699  1.0
  O  O33  1  0.148  0.646  0.798  1.0
  O  O34  1  0.046  0.548  0.600  1.0
  O  O35  1  0.961  0.961  0.416  1.0
  O  O36  1  0.053  0.035  0.584  1.0
  O  O37  1  0.957  0.461  0.401  1.0
  O  O38  1  0.683  0.697  0.302  1.0
  O  O39  1  0.926  0.928  0.899  1.0
  O  O40  1  0.654  0.152  0.798  1.0
  O  O41  1  0.560  0.559  0.615  1.0
  O  O42  1  0.656  0.633  0.786  1.0
  O  O43  1  0.555  0.057  0.600  1.0
  O  O44  1  0.285  0.302  0.500  1.0
  O  O45  1  0.152  0.160  0.810  1.0
  O  O46  1  0.249  0.244  0.991  1.0
  O  O47  1  0.883  0.893  0.699  1.0
  O  O48  1  0.473  0.475  0.899  1.0
  O  O49  1  0.250  0.749  0.000  1.0
[/CIF]
.
The material described by Na3Sr4La3Ti10O30 crystallizes in the triclinic P1 space group. There are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(16), one O(18), one O(4), one O(6), one O(8), one O(9), two equivalent O(19), and two equivalent O(3) atoms. In the second Na site, Na(2) is bonded in a 12-coordinate geometry to one O(15), one O(16), one O(17), one O(18), one O(22), one O(24), one O(8), one O(9), two equivalent O(25), and two equivalent O(7) atoms. In the third Na site, Na(3) is bonded to one O(14), one O(15), one O(17), one O(21), one O(22), one O(23), one O(24), one O(26), two equivalent O(13), and two equivalent O(28) atoms to form distorted NaO12 cuboctahedra that share corners with four equivalent Na(3)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra, faces with four equivalent La(3)O12 cuboctahedra, faces with two equivalent Ti(4)O6 octahedra, faces with two equivalent Ti(6)O6 octahedra, faces with two equivalent Ti(7)O6 octahedra, and faces with two equivalent Ti(9)O6 octahedra. There are four inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(1), one O(10), one O(11), one O(27), one O(30), one O(4), one O(5), one O(6), two equivalent O(12), and two equivalent O(2) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, faces with four equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent Ti(10)O6 octahedra, faces with two equivalent Ti(3)O6 octahedra, and faces with two equivalent Ti(8)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(1), one O(10), one O(11), one O(27), one O(30), one O(4), one O(5), one O(6), two equivalent O(12), and two equivalent O(2) atoms to form SrO12 cuboctahedra that share corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra,  a faceface with one Sr(3)O12 cuboctahedra, faces with four equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Ti(1)O6 octahedra, faces with two equivalent Ti(10)O6 octahedra, faces with two equivalent Ti(3)O6 octahedra, and faces with two equivalent Ti(8)O6 octahedra. In the third Sr site, Sr(3) is bonded to one O(1), one O(14), one O(21), one O(23), one O(26), one O(27), one O(30), one O(5), two equivalent O(20), and two equivalent O(29) atoms to form distorted SrO12 cuboctahedra that share corners with four equivalent Sr(1)O12 cuboctahedra, corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra,  a faceface with one Na(3)O12 cuboctahedra,  a faceface with one Sr(2)O12 cuboctahedra, faces with four equivalent Sr(4)O12 cuboctahedra, faces with two equivalent Ti(10)O6 octahedra, faces with two equivalent Ti(7)O6 octahedra, faces with two equivalent Ti(8)O6 octahedra, and faces with two equivalent Ti(9)O6 octahedra. In the fourth Sr site, Sr(4) is bonded to one O(1), one O(14), one O(21), one O(23), one O(26), one O(27), one O(30), one O(5), two equivalent O(20), and two equivalent O(29) atoms to form SrO12 cuboctahedra that share corners with four equivalent Na(3)O12 cuboctahedra, corners with four equivalent Sr(2)O12 cuboctahedra, corners with four equivalent Sr(4)O12 cuboctahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra, faces with four equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Ti(10)O6 octahedra, faces with two equivalent Ti(7)O6 octahedra, faces with two equivalent Ti(8)O6 octahedra, and faces with two equivalent Ti(9)O6 octahedra. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 12-coordinate geometry to one O(10), one O(11), one O(16), one O(18), one O(4), one O(6), one O(8), one O(9), two equivalent O(19), and two equivalent O(3) atoms. In the second La site, La(2) is bonded in a 12-coordinate geometry to one O(15), one O(16), one O(17), one O(18), one O(22), one O(24), one O(8), one O(9), two equivalent O(25), and two equivalent O(7) atoms. In the third La site, La(3) is bonded to one O(14), one O(15), one O(17), one O(21), one O(22), one O(23), one O(24), one O(26), two equivalent O(13), and two equivalent O(28) atoms to form distorted LaO12 cuboctahedra that share corners with four equivalent Sr(3)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra,  a faceface with one Sr(4)O12 cuboctahedra, faces with four equivalent Na(3)O12 cuboctahedra, faces with two equivalent Ti(4)O6 octahedra, faces with two equivalent Ti(6)O6 octahedra, faces with two equivalent Ti(7)O6 octahedra, and faces with two equivalent Ti(9)O6 octahedra. There are ten inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(10), one O(11), one O(12), one O(3), one O(4), and one O(6) atom to form TiO6 octahedra that share  a cornercorner with one Ti(5)O6 octahedra,  a cornercorner with one Ti(8)O6 octahedra, corners with four equivalent Ti(3)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-16°. In the second Ti site, Ti(2) is bonded to one O(16), one O(18), one O(19), one O(7), one O(8), and one O(9) atom to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 3-20°. In the third Ti site, Ti(3) is bonded to one O(10), one O(11), one O(19), one O(2), one O(4), and one O(6) atom to form TiO6 octahedra that share  a cornercorner with one Ti(10)O6 octahedra,  a cornercorner with one Ti(2)O6 octahedra, corners with four equivalent Ti(1)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, and faces with two equivalent Sr(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-20°. In the fourth Ti site, Ti(4) is bonded to one O(13), one O(15), one O(17), one O(22), one O(24), and one O(25) atom to form TiO6 octahedra that share  a cornercorner with one Ti(5)O6 octahedra,  a cornercorner with one Ti(7)O6 octahedra, corners with four equivalent Ti(6)O6 octahedra, faces with two equivalent Na(3)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 3-22°. In the fifth Ti site, Ti(5) is bonded to one O(16), one O(18), one O(25), one O(3), one O(8), and one O(9) atom to form corner-sharing TiO6 octahedra. The corner-sharing octahedral tilt angles range from 3-22°. In the sixth Ti site, Ti(6) is bonded to one O(15), one O(17), one O(22), one O(24), one O(28), and one O(7) atom to form TiO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra,  a cornercorner with one Ti(9)O6 octahedra, corners with four equivalent Ti(4)O6 octahedra, faces with two equivalent Na(3)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 3-20°. In the seventh Ti site, Ti(7) is bonded to one O(13), one O(14), one O(21), one O(23), one O(26), and one O(29) atom to form TiO6 octahedra that share  a cornercorner with one Ti(10)O6 octahedra,  a cornercorner with one Ti(4)O6 octahedra, corners with four equivalent Ti(9)O6 octahedra, faces with two equivalent Na(3)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-16°. In the eighth Ti site, Ti(8) is bonded to one O(1), one O(12), one O(20), one O(27), one O(30), and one O(5) atom to form TiO6 octahedra that share  a cornercorner with one Ti(1)O6 octahedra,  a cornercorner with one Ti(9)O6 octahedra, corners with four equivalent Ti(10)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Sr(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-12°. In the ninth Ti site, Ti(9) is bonded to one O(14), one O(20), one O(21), one O(23), one O(26), and one O(28) atom to form TiO6 octahedra that share  a cornercorner with one Ti(6)O6 octahedra,  a cornercorner with one Ti(8)O6 octahedra, corners with four equivalent Ti(7)O6 octahedra, faces with two equivalent Na(3)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, faces with two equivalent Sr(4)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-18°. In the tenth Ti site, Ti(10) is bonded to one O(1), one O(2), one O(27), one O(29), one O(30), and one O(5) atom to form TiO6 octahedra that share  a cornercorner with one Ti(3)O6 octahedra,  a cornercorner with one Ti(7)O6 octahedra, corners with four equivalent Ti(8)O6 octahedra, faces with two equivalent Sr(1)O12 cuboctahedra, faces with two equivalent Sr(2)O12 cuboctahedra, faces with two equivalent Sr(3)O12 cuboctahedra, and faces with two equivalent Sr(4)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-12°. There are thirty inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Ti(10), and one Ti(8) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Sr(2), one Ti(10), and one Ti(3) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to two equivalent Na(1), two equivalent La(1), one Ti(1), and one Ti(5) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Na(1), one Sr(1), one Sr(2), one La(1), one Ti(1), and one Ti(3) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Ti(10), and one Ti(8) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Na(1), one Sr(1), one Sr(2), one La(1), one Ti(1), and one Ti(3) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to two equivalent Na(2), two equivalent La(2), one Ti(2), and one Ti(6) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Na(1), one Na(2), one La(1), one La(2), one Ti(2), and one Ti(5) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one La(1), one La(2), one Ti(2), and one Ti(5) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Na(1), one Sr(1), one Sr(2), one La(1), one Ti(1), and one Ti(3) atom. In the eleventh O site, O(11) is bonded in a distorted octahedral geometry to one Na(1), one Sr(1), one Sr(2), one La(1), one Ti(1), and one Ti(3) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to two equivalent Sr(1), two equivalent Sr(2), one Ti(1), and one Ti(8) atom. In the thirteenth O site, O(13) is bonded in a 2-coordinate geometry to two equivalent Na(3), two equivalent La(3), one Ti(4), and one Ti(7) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one Na(3), one Sr(3), one Sr(4), one La(3), one Ti(7), and one Ti(9) atom. In the fifteenth O site, O(15) is bonded in a distorted linear geometry to one Na(2), one Na(3), one La(2), one La(3), one Ti(4), and one Ti(6) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one Na(1), one Na(2), one La(1), one La(2), one Ti(2), and one Ti(5) atom. In the seventeenth O site, O(17) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one La(2), one La(3), one Ti(4), and one Ti(6) atom. In the eighteenth O site, O(18) is bonded in a distorted linear geometry to one Na(1), one Na(2), one La(1), one La(2), one Ti(2), and one Ti(5) atom. In the nineteenth O site, O(19) is bonded in a 4-coordinate geometry to two equivalent Na(1), two equivalent La(1), one Ti(2), and one Ti(3) atom. In the twentieth O site, O(20) is bonded in a 2-coordinate geometry to two equivalent Sr(3), two equivalent Sr(4), one Ti(8), and one Ti(9) atom. In the twenty-first O site, O(21) is bonded in a distorted linear geometry to one Na(3), one Sr(3), one Sr(4), one La(3), one Ti(7), and one Ti(9) atom. In the twenty-second O site, O(22) is bonded in a 4-coordinate geometry to one Na(2), one Na(3), one La(2), one La(3), one Ti(4), and one Ti(6) atom. In the twenty-third O site, O(23) is bonded in a 2-coordinate geometry to one Na(3), one Sr(3), one Sr(4), one La(3), one Ti(7), and one Ti(9) atom. In the twenty-fourth O site, O(24) is bonded in a distorted linear geometry to one Na(2), one Na(3), one La(2), one La(3), one Ti(4), and one Ti(6) atom. In the twenty-fifth O site, O(25) is bonded in a 4-coordinate geometry to two equivalent Na(2), two equivalent La(2), one Ti(4), and one Ti(5) atom. In the twenty-sixth O site, O(26) is bonded in a 2-coordinate geometry to one Na(3), one Sr(3), one Sr(4), one La(3), one Ti(7), and one Ti(9) atom. In the twenty-seventh O site, O(27) is bonded in a 2-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Ti(10), and one Ti(8) atom. In the twenty-eighth O site, O(28) is bonded in a 4-coordinate geometry to two equivalent Na(3), two equivalent La(3), one Ti(6), and one Ti(9) atom. In the twenty-ninth O site, O(29) is bonded in a 2-coordinate geometry to two equivalent Sr(3), two equivalent Sr(4), one Ti(10), and one Ti(7) atom. In the thirtieth O site, O(30) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), one Sr(3), one Sr(4), one Ti(10), and one Ti(8) atom. is represented by the CIF card [CIF]
data_Na3Sr4La3Ti10O30
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.544
_cell_length_b   5.549
_cell_length_c   19.905
_cell_angle_alpha   97.938
_cell_angle_beta   97.927
_cell_angle_gamma   90.437
_symmetry_Int_Tables_number   1
_cell_volume   600.392
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.149  0.643  0.300  1.0
  Na  Na1  1  0.746  0.246  0.499  1.0
  Na  Na2  1  0.347  0.850  0.698  1.0
  Sr  Sr3  1  0.049  0.551  0.101  1.0
  Sr  Sr4  1  0.550  0.050  0.099  1.0
  Sr  Sr5  1  0.448  0.953  0.897  1.0
  Sr  Sr6  1  0.949  0.453  0.899  1.0
  La  La7  1  0.649  0.141  0.300  1.0
  La  La8  1  0.246  0.746  0.499  1.0
  La  La9  1  0.846  0.350  0.697  1.0
  Ti  Ti10  1  0.097  0.095  0.200  1.0
  Ti  Ti11  1  0.697  0.690  0.399  1.0
  Ti  Ti12  1  0.600  0.596  0.201  1.0
  Ti  Ti13  1  0.295  0.297  0.598  1.0
  Ti  Ti14  1  0.197  0.191  0.400  1.0
  Ti  Ti15  1  0.794  0.797  0.598  1.0
  Ti  Ti16  1  0.393  0.402  0.796  1.0
  Ti  Ti17  1  0.999  0.002  0.998  1.0
  Ti  Ti18  1  0.898  0.906  0.796  1.0
  Ti  Ti19  1  0.499  0.503  0.998  1.0
  O  O20  1  0.753  0.252  0.000  1.0
  O  O21  1  0.528  0.530  0.101  1.0
  O  O22  1  0.111  0.123  0.302  1.0
  O  O23  1  0.848  0.349  0.202  1.0
  O  O24  1  0.756  0.755  0.009  1.0
  O  O25  1  0.843  0.852  0.191  1.0
  O  O26  1  0.704  0.719  0.500  1.0
  O  O27  1  0.448  0.951  0.401  1.0
  O  O28  1  0.454  0.436  0.385  1.0
  O  O29  1  0.367  0.352  0.214  1.0
  O  O30  1  0.359  0.860  0.203  1.0
  O  O31  1  0.075  0.076  0.101  1.0
  O  O32  1  0.310  0.318  0.699  1.0
  O  O33  1  0.148  0.646  0.798  1.0
  O  O34  1  0.046  0.548  0.600  1.0
  O  O35  1  0.961  0.961  0.416  1.0
  O  O36  1  0.053  0.035  0.584  1.0
  O  O37  1  0.957  0.461  0.401  1.0
  O  O38  1  0.683  0.697  0.302  1.0
  O  O39  1  0.926  0.928  0.899  1.0
  O  O40  1  0.654  0.152  0.798  1.0
  O  O41  1  0.560  0.559  0.615  1.0
  O  O42  1  0.656  0.633  0.786  1.0
  O  O43  1  0.555  0.057  0.600  1.0
  O  O44  1  0.285  0.302  0.500  1.0
  O  O45  1  0.152  0.160  0.810  1.0
  O  O46  1  0.249  0.244  0.991  1.0
  O  O47  1  0.883  0.893  0.699  1.0
  O  O48  1  0.473  0.475  0.899  1.0
  O  O49  1  0.250  0.749  0.000  1.0
[/CIF]
.