The material structure described by Au2P3 crystallizes in the monoclinic C2/m space group. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted linear geometry to two equivalent P(1) and two equivalent P(2) atoms. In the second Au site, Au(2) is bonded in a linear geometry to two equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 5-coordinate geometry to two equivalent Au(1), one P(1), and two equivalent P(2) atoms. In the second P site, P(2) is bonded to one Au(1), one Au(2), one P(1), and one P(2) atom to form corner-sharing PP2Au2 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_P3Au2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.726
_cell_length_b   5.893
_cell_length_c   7.795
_cell_angle_alpha   67.793
_cell_angle_beta   83.450
_cell_angle_gamma   72.434
_symmetry_Int_Tables_number   1
_cell_volume   191.606
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.534  0.681  0.000  1.0
  P  P1  1  0.466  0.319  0.000  1.0
  P  P2  1  0.179  0.451  0.756  1.0
  P  P3  1  0.821  0.793  0.756  1.0
  P  P4  1  0.179  0.207  0.244  1.0
  P  P5  1  0.821  0.549  0.244  1.0
  Au  Au6  1  0.000  0.890  0.219  1.0
  Au  Au7  1  0.000  0.110  0.781  1.0
  Au  Au8  1  0.500  0.500  0.500  1.0
  Au  Au9  1  0.500  0.000  0.500  1.0
[/CIF]
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The material structure described by Au2P3 crystallizes in the monoclinic C2/m space group. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted linear geometry to two equivalent P(1) and two equivalent P(2) atoms. In the second Au site, Au(2) is bonded in a linear geometry to two equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 5-coordinate geometry to two equivalent Au(1), one P(1), and two equivalent P(2) atoms. In the second P site, P(2) is bonded to one Au(1), one Au(2), one P(1), and one P(2) atom to form corner-sharing PP2Au2 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_P3Au2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.726
_cell_length_b   5.893
_cell_length_c   7.795
_cell_angle_alpha   67.793
_cell_angle_beta   83.450
_cell_angle_gamma   72.434
_symmetry_Int_Tables_number   1
_cell_volume   191.606
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.534  0.681  0.000  1.0
  P  P1  1  0.466  0.319  0.000  1.0
  P  P2  1  0.179  0.451  0.756  1.0
  P  P3  1  0.821  0.793  0.756  1.0
  P  P4  1  0.179  0.207  0.244  1.0
  P  P5  1  0.821  0.549  0.244  1.0
  Au  Au6  1  0.000  0.890  0.219  1.0
  Au  Au7  1  0.000  0.110  0.781  1.0
  Au  Au8  1  0.500  0.500  0.500  1.0
  Au  Au9  1  0.500  0.000  0.500  1.0
[/CIF]
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