The crystal structure described by (Co(CO)4)2Co(NH3)6 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one azane;cobalt molecule and two Co(CO)4 clusters. In each Co(CO)4 cluster, Co(1) is bonded in a tetrahedral geometry to one C(1), one C(2), one C(3), and one C(4) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(1) and one O(3) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Co(1) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co3H18C8(N3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.465
_cell_length_b   8.524
_cell_length_c   8.553
_cell_angle_alpha   70.179
_cell_angle_beta   69.967
_cell_angle_gamma   70.466
_symmetry_Int_Tables_number   1
_cell_volume   528.553
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.624  0.624  0.624  1.0
  Co  Co1  1  0.376  0.376  0.376  1.0
  Co  Co2  1  0.000  0.000  0.000  1.0
  H  H3  1  0.094  0.638  0.071  1.0
  H  H4  1  0.638  0.070  0.095  1.0
  H  H5  1  0.072  0.095  0.638  1.0
  H  H6  1  0.906  0.362  0.929  1.0
  H  H7  1  0.362  0.930  0.905  1.0
  H  H8  1  0.928  0.905  0.362  1.0
  H  H9  1  0.239  0.707  0.899  1.0
  H  H10  1  0.707  0.899  0.238  1.0
  H  H11  1  0.900  0.238  0.707  1.0
  H  H12  1  0.761  0.293  0.101  1.0
  H  H13  1  0.293  0.101  0.762  1.0
  H  H14  1  0.100  0.762  0.293  1.0
  H  H15  1  0.050  0.712  0.883  1.0
  H  H16  1  0.712  0.882  0.052  1.0
  H  H17  1  0.882  0.051  0.713  1.0
  H  H18  1  0.950  0.288  0.117  1.0
  H  H19  1  0.288  0.118  0.948  1.0
  H  H20  1  0.118  0.949  0.287  1.0
  C  C21  1  0.442  0.767  0.561  1.0
  C  C22  1  0.768  0.562  0.442  1.0
  C  C23  1  0.561  0.442  0.767  1.0
  C  C24  1  0.558  0.233  0.439  1.0
  C  C25  1  0.232  0.438  0.558  1.0
  C  C26  1  0.439  0.558  0.233  1.0
  C  C27  1  0.716  0.716  0.715  1.0
  C  C28  1  0.284  0.284  0.285  1.0
  N  N29  1  0.109  0.733  0.959  1.0
  N  N30  1  0.733  0.958  0.109  1.0
  N  N31  1  0.959  0.109  0.733  1.0
  N  N32  1  0.891  0.267  0.041  1.0
  N  N33  1  0.267  0.042  0.891  1.0
  N  N34  1  0.041  0.891  0.267  1.0
  O  O35  1  0.316  0.860  0.520  1.0
  O  O36  1  0.859  0.520  0.316  1.0
  O  O37  1  0.520  0.316  0.860  1.0
  O  O38  1  0.684  0.140  0.480  1.0
  O  O39  1  0.141  0.480  0.684  1.0
  O  O40  1  0.480  0.684  0.140  1.0
  O  O41  1  0.777  0.777  0.777  1.0
  O  O42  1  0.223  0.223  0.223  1.0
[/CIF]
.
The crystal structure described by (Co(CO)4)2Co(NH3)6 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one azane;cobalt molecule and two Co(CO)4 clusters. In each Co(CO)4 cluster, Co(1) is bonded in a tetrahedral geometry to one C(1), one C(2), one C(3), and one C(4) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Co(1) and one O(3) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Co(1) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co3H18C8(N3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.465
_cell_length_b   8.524
_cell_length_c   8.553
_cell_angle_alpha   70.179
_cell_angle_beta   69.967
_cell_angle_gamma   70.466
_symmetry_Int_Tables_number   1
_cell_volume   528.553
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.624  0.624  0.624  1.0
  Co  Co1  1  0.376  0.376  0.376  1.0
  Co  Co2  1  0.000  0.000  0.000  1.0
  H  H3  1  0.094  0.638  0.071  1.0
  H  H4  1  0.638  0.070  0.095  1.0
  H  H5  1  0.072  0.095  0.638  1.0
  H  H6  1  0.906  0.362  0.929  1.0
  H  H7  1  0.362  0.930  0.905  1.0
  H  H8  1  0.928  0.905  0.362  1.0
  H  H9  1  0.239  0.707  0.899  1.0
  H  H10  1  0.707  0.899  0.238  1.0
  H  H11  1  0.900  0.238  0.707  1.0
  H  H12  1  0.761  0.293  0.101  1.0
  H  H13  1  0.293  0.101  0.762  1.0
  H  H14  1  0.100  0.762  0.293  1.0
  H  H15  1  0.050  0.712  0.883  1.0
  H  H16  1  0.712  0.882  0.052  1.0
  H  H17  1  0.882  0.051  0.713  1.0
  H  H18  1  0.950  0.288  0.117  1.0
  H  H19  1  0.288  0.118  0.948  1.0
  H  H20  1  0.118  0.949  0.287  1.0
  C  C21  1  0.442  0.767  0.561  1.0
  C  C22  1  0.768  0.562  0.442  1.0
  C  C23  1  0.561  0.442  0.767  1.0
  C  C24  1  0.558  0.233  0.439  1.0
  C  C25  1  0.232  0.438  0.558  1.0
  C  C26  1  0.439  0.558  0.233  1.0
  C  C27  1  0.716  0.716  0.715  1.0
  C  C28  1  0.284  0.284  0.285  1.0
  N  N29  1  0.109  0.733  0.959  1.0
  N  N30  1  0.733  0.958  0.109  1.0
  N  N31  1  0.959  0.109  0.733  1.0
  N  N32  1  0.891  0.267  0.041  1.0
  N  N33  1  0.267  0.042  0.891  1.0
  N  N34  1  0.041  0.891  0.267  1.0
  O  O35  1  0.316  0.860  0.520  1.0
  O  O36  1  0.859  0.520  0.316  1.0
  O  O37  1  0.520  0.316  0.860  1.0
  O  O38  1  0.684  0.140  0.480  1.0
  O  O39  1  0.141  0.480  0.684  1.0
  O  O40  1  0.480  0.684  0.140  1.0
  O  O41  1  0.777  0.777  0.777  1.0
  O  O42  1  0.223  0.223  0.223  1.0
[/CIF]
.