The material described by Pb(NS)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Pb(NS)2 clusters. Pb(1) is bonded in a 3-coordinate geometry to one N(2) and two equivalent S(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pb(1) and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one N(1) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. is represented by the CIF file [CIF]
data_Pb(SN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   17.320
_cell_length_b   5.480
_cell_length_c   6.420
_cell_angle_alpha   86.237
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   608.034
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.942  0.856  0.755  1.0
  Pb  Pb1  1  0.442  0.644  0.245  1.0
  Pb  Pb2  1  0.058  0.144  0.245  1.0
  Pb  Pb3  1  0.558  0.356  0.755  1.0
  S  S4  1  0.455  0.772  0.654  1.0
  S  S5  1  0.955  0.728  0.346  1.0
  S  S6  1  0.545  0.228  0.346  1.0
  S  S7  1  0.045  0.272  0.654  1.0
  S  S8  1  0.320  0.481  0.627  1.0
  S  S9  1  0.820  0.019  0.373  1.0
  S  S10  1  0.680  0.519  0.373  1.0
  S  S11  1  0.180  0.981  0.627  1.0
  N  N12  1  0.378  0.625  0.769  1.0
  N  N13  1  0.878  0.875  0.231  1.0
  N  N14  1  0.622  0.375  0.231  1.0
  N  N15  1  0.122  0.125  0.769  1.0
  N  N16  1  0.336  0.465  0.396  1.0
  N  N17  1  0.836  0.035  0.604  1.0
  N  N18  1  0.664  0.535  0.604  1.0
  N  N19  1  0.164  0.965  0.396  1.0
[/CIF]
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The material described by Pb(NS)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Pb(NS)2 clusters. Pb(1) is bonded in a 3-coordinate geometry to one N(2) and two equivalent S(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Pb(1) and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one N(1) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. is represented by the CIF file [CIF]
data_Pb(SN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   17.320
_cell_length_b   5.480
_cell_length_c   6.420
_cell_angle_alpha   86.237
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   608.034
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pb  Pb0  1  0.942  0.856  0.755  1.0
  Pb  Pb1  1  0.442  0.644  0.245  1.0
  Pb  Pb2  1  0.058  0.144  0.245  1.0
  Pb  Pb3  1  0.558  0.356  0.755  1.0
  S  S4  1  0.455  0.772  0.654  1.0
  S  S5  1  0.955  0.728  0.346  1.0
  S  S6  1  0.545  0.228  0.346  1.0
  S  S7  1  0.045  0.272  0.654  1.0
  S  S8  1  0.320  0.481  0.627  1.0
  S  S9  1  0.820  0.019  0.373  1.0
  S  S10  1  0.680  0.519  0.373  1.0
  S  S11  1  0.180  0.981  0.627  1.0
  N  N12  1  0.378  0.625  0.769  1.0
  N  N13  1  0.878  0.875  0.231  1.0
  N  N14  1  0.622  0.375  0.231  1.0
  N  N15  1  0.122  0.125  0.769  1.0
  N  N16  1  0.336  0.465  0.396  1.0
  N  N17  1  0.836  0.035  0.604  1.0
  N  N18  1  0.664  0.535  0.604  1.0
  N  N19  1  0.164  0.965  0.396  1.0
[/CIF]
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