The material described by KPH2SO3 crystallizes in the monoclinic Cm space group. K(1) is bonded in a 9-coordinate geometry to four equivalent S(1), one O(1), and four equivalent O(2) atoms. P(1) is bonded in a distorted tetrahedral geometry to one S(1), one O(1), and two equivalent O(2) atoms. H(1) is bonded in a linear geometry to one O(1) and one O(2) atom. S(1) is bonded in a distorted single-bond geometry to four equivalent K(1) and one P(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one P(1), and two equivalent H(1) atoms. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent K(1), one P(1), and one H(1) atom. is represented by the CIF file [CIF]
data_KPH2SO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.582
_cell_length_b   4.582
_cell_length_c   6.017
_cell_angle_alpha   76.949
_cell_angle_beta   76.949
_cell_angle_gamma   88.149
_symmetry_Int_Tables_number   1
_cell_volume   119.868
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.847  0.847  0.388  1.0
  P  P1  1  0.345  0.345  0.889  1.0
  H  H2  1  0.830  0.207  0.811  1.0
  H  H3  1  0.207  0.830  0.811  1.0
  S  S4  1  0.385  0.385  0.202  1.0
  O  O5  1  0.107  0.107  0.896  1.0
  O  O6  1  0.651  0.262  0.730  1.0
  O  O7  1  0.262  0.651  0.730  1.0
[/CIF]
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The material described by KPH2SO3 crystallizes in the monoclinic Cm space group. K(1) is bonded in a 9-coordinate geometry to four equivalent S(1), one O(1), and four equivalent O(2) atoms. P(1) is bonded in a distorted tetrahedral geometry to one S(1), one O(1), and two equivalent O(2) atoms. H(1) is bonded in a linear geometry to one O(1) and one O(2) atom. S(1) is bonded in a distorted single-bond geometry to four equivalent K(1) and one P(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one P(1), and two equivalent H(1) atoms. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent K(1), one P(1), and one H(1) atom. is represented by the CIF file [CIF]
data_KPH2SO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.582
_cell_length_b   4.582
_cell_length_c   6.017
_cell_angle_alpha   76.949
_cell_angle_beta   76.949
_cell_angle_gamma   88.149
_symmetry_Int_Tables_number   1
_cell_volume   119.868
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.847  0.847  0.388  1.0
  P  P1  1  0.345  0.345  0.889  1.0
  H  H2  1  0.830  0.207  0.811  1.0
  H  H3  1  0.207  0.830  0.811  1.0
  S  S4  1  0.385  0.385  0.202  1.0
  O  O5  1  0.107  0.107  0.896  1.0
  O  O6  1  0.651  0.262  0.730  1.0
  O  O7  1  0.262  0.651  0.730  1.0
[/CIF]
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