The structure described by PNCl2 is Indium-like structured and crystallizes in the tetragonal P4_2/n space group. The structure is zero-dimensional and consists of two akos000271203 molecules. P(1) is bonded to two equivalent N(1), one Cl(1), and one Cl(2) atom to form corner-sharing PN2Cl2 tetrahedra. N(1) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PNCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.991
_cell_length_b   10.916
_cell_length_c   10.916
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   713.821
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.309  0.576  0.794  1.0
  P  P1  1  0.809  0.294  0.424  1.0
  P  P2  1  0.691  0.424  0.206  1.0
  P  P3  1  0.809  0.206  0.076  1.0
  P  P4  1  0.691  0.076  0.294  1.0
  P  P5  1  0.309  0.924  0.706  1.0
  P  P6  1  0.191  0.794  0.924  1.0
  P  P7  1  0.191  0.706  0.576  1.0
  N  N8  1  0.671  0.386  0.344  1.0
  N  N9  1  0.329  0.614  0.656  1.0
  N  N10  1  0.671  0.114  0.156  1.0
  N  N11  1  0.829  0.156  0.386  1.0
  N  N12  1  0.829  0.344  0.114  1.0
  N  N13  1  0.329  0.886  0.844  1.0
  N  N14  1  0.171  0.656  0.886  1.0
  N  N15  1  0.171  0.844  0.614  1.0
  Cl  Cl16  1  0.621  0.951  0.647  1.0
  Cl  Cl17  1  0.175  0.408  0.804  1.0
  Cl  Cl18  1  0.621  0.549  0.853  1.0
  Cl  Cl19  1  0.825  0.908  0.304  1.0
  Cl  Cl20  1  0.879  0.853  0.951  1.0
  Cl  Cl21  1  0.325  0.804  0.092  1.0
  Cl  Cl22  1  0.175  0.092  0.696  1.0
  Cl  Cl23  1  0.121  0.147  0.049  1.0
  Cl  Cl24  1  0.675  0.304  0.592  1.0
  Cl  Cl25  1  0.379  0.049  0.353  1.0
  Cl  Cl26  1  0.675  0.196  0.908  1.0
  Cl  Cl27  1  0.825  0.592  0.196  1.0
  Cl  Cl28  1  0.325  0.696  0.408  1.0
  Cl  Cl29  1  0.121  0.353  0.451  1.0
  Cl  Cl30  1  0.879  0.647  0.549  1.0
  Cl  Cl31  1  0.379  0.451  0.147  1.0
[/CIF]
.
The structure described by PNCl2 is Indium-like structured and crystallizes in the tetragonal P4_2/n space group. The structure is zero-dimensional and consists of two akos000271203 molecules. P(1) is bonded to two equivalent N(1), one Cl(1), and one Cl(2) atom to form corner-sharing PN2Cl2 tetrahedra. N(1) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PNCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.991
_cell_length_b   10.916
_cell_length_c   10.916
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   713.821
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.309  0.576  0.794  1.0
  P  P1  1  0.809  0.294  0.424  1.0
  P  P2  1  0.691  0.424  0.206  1.0
  P  P3  1  0.809  0.206  0.076  1.0
  P  P4  1  0.691  0.076  0.294  1.0
  P  P5  1  0.309  0.924  0.706  1.0
  P  P6  1  0.191  0.794  0.924  1.0
  P  P7  1  0.191  0.706  0.576  1.0
  N  N8  1  0.671  0.386  0.344  1.0
  N  N9  1  0.329  0.614  0.656  1.0
  N  N10  1  0.671  0.114  0.156  1.0
  N  N11  1  0.829  0.156  0.386  1.0
  N  N12  1  0.829  0.344  0.114  1.0
  N  N13  1  0.329  0.886  0.844  1.0
  N  N14  1  0.171  0.656  0.886  1.0
  N  N15  1  0.171  0.844  0.614  1.0
  Cl  Cl16  1  0.621  0.951  0.647  1.0
  Cl  Cl17  1  0.175  0.408  0.804  1.0
  Cl  Cl18  1  0.621  0.549  0.853  1.0
  Cl  Cl19  1  0.825  0.908  0.304  1.0
  Cl  Cl20  1  0.879  0.853  0.951  1.0
  Cl  Cl21  1  0.325  0.804  0.092  1.0
  Cl  Cl22  1  0.175  0.092  0.696  1.0
  Cl  Cl23  1  0.121  0.147  0.049  1.0
  Cl  Cl24  1  0.675  0.304  0.592  1.0
  Cl  Cl25  1  0.379  0.049  0.353  1.0
  Cl  Cl26  1  0.675  0.196  0.908  1.0
  Cl  Cl27  1  0.825  0.592  0.196  1.0
  Cl  Cl28  1  0.325  0.696  0.408  1.0
  Cl  Cl29  1  0.121  0.353  0.451  1.0
  Cl  Cl30  1  0.879  0.647  0.549  1.0
  Cl  Cl31  1  0.379  0.451  0.147  1.0
[/CIF]
.