The material described by SrLa3Mn4O10 crystallizes in the monoclinic C2 space group. Sr(1) is bonded in a 8-coordinate geometry to one O(10), one O(2), one O(3), one O(4), one O(7), one O(9), and two equivalent O(6) atoms. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(3), one O(4), one O(8), one O(9), and two equivalent O(5) atoms. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(5), one O(7), two equivalent O(1), two equivalent O(10), and two equivalent O(4) atoms. In the third La site, La(3) is bonded in a 8-coordinate geometry to one O(6), one O(8), two equivalent O(2), two equivalent O(3), and two equivalent O(9) atoms. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(5), and two equivalent O(8) atoms to form MnO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra, and corners with two equivalent Mn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 36°. In the second Mn site, Mn(2) is bonded to one O(1), one O(6), and two equivalent O(7) atoms to form MnO4 tetrahedra that share  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra, and corners with two equivalent Mn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 37-42°. In the third Mn site, Mn(3) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(9) atoms to form MnO6 octahedra that share corners with four equivalent Mn(5)O6 octahedra and corners with two equivalent Mn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 18-19°. In the fourth Mn site, Mn(4) is bonded to two equivalent O(1), two equivalent O(10), and two equivalent O(4) atoms to form MnO6 octahedra that share corners with four equivalent Mn(5)O6 octahedra and corners with two equivalent Mn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 8-13°. In the fifth Mn site, Mn(5) is bonded to one O(10), one O(3), one O(4), one O(5), one O(6), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra,  a cornercorner with one Mn(1)O4 tetrahedra, and  a cornercorner with one Mn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 8-19°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one La(1), two equivalent La(2), one Mn(2), and one Mn(4) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Sr(1), two equivalent La(3), one Mn(1), and one Mn(3) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to one Sr(1), one La(1), two equivalent La(3), one Mn(3), and one Mn(5) atom. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Sr(1), one La(1), two equivalent La(2), one Mn(4), and one Mn(5) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one La(2), two equivalent La(1), one Mn(1), and one Mn(5) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one La(3), one Mn(2), and one Mn(5) atom. In the seventh O site, O(7) is bonded to one Sr(1), one La(2), and two equivalent Mn(2) atoms to form corner-sharing OSrLaMn2 tetrahedra. In the eighth O site, O(8) is bonded to one La(1), one La(3), and two equivalent Mn(1) atoms to form corner-sharing OLa2Mn2 tetrahedra. In the ninth O site, O(9) is bonded in a 6-coordinate geometry to one Sr(1), one La(1), two equivalent La(3), one Mn(3), and one Mn(5) atom. In the tenth O site, O(10) is bonded in a 6-coordinate geometry to one Sr(1), one La(1), two equivalent La(2), one Mn(4), and one Mn(5) atom. is represented by the CIF file [CIF]
data_SrLa3Mn4O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.072
_cell_length_b   9.072
_cell_length_c   11.633
_cell_angle_alpha   71.298
_cell_angle_beta   71.298
_cell_angle_gamma   35.908
_symmetry_Int_Tables_number   1
_cell_volume   528.733
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.397  0.372  0.799  1.0
  Sr  Sr1  1  0.628  0.603  0.201  1.0
  La  La2  1  0.592  0.626  0.703  1.0
  La  La3  1  0.374  0.408  0.297  1.0
  La  La4  1  0.909  0.871  0.068  1.0
  La  La5  1  0.129  0.091  0.932  1.0
  La  La6  1  0.089  0.137  0.433  1.0
  La  La7  1  0.863  0.911  0.567  1.0
  Mn  Mn8  1  0.202  0.296  0.599  1.0
  Mn  Mn9  1  0.704  0.798  0.401  1.0
  Mn  Mn10  1  0.797  0.704  0.901  1.0
  Mn  Mn11  1  0.296  0.203  0.099  1.0
  Mn  Mn12  1  0.494  0.506  0.500  1.0
  Mn  Mn13  1  0.504  0.496  0.000  1.0
  Mn  Mn14  1  0.003  0.004  0.249  1.0
  Mn  Mn15  1  0.996  0.997  0.751  1.0
  O  O16  1  0.322  0.399  0.115  1.0
  O  O17  1  0.601  0.678  0.885  1.0
  O  O18  1  0.678  0.599  0.399  1.0
  O  O19  1  0.401  0.322  0.601  1.0
  O  O20  1  0.266  0.770  0.608  1.0
  O  O21  1  0.230  0.734  0.392  1.0
  O  O22  1  0.742  0.239  0.887  1.0
  O  O23  1  0.761  0.258  0.113  1.0
  O  O24  1  0.895  0.836  0.282  1.0
  O  O25  1  0.164  0.105  0.718  1.0
  O  O26  1  0.125  0.144  0.224  1.0
  O  O27  1  0.856  0.875  0.776  1.0
  O  O28  1  0.163  0.320  0.932  1.0
  O  O29  1  0.680  0.837  0.068  1.0
  O  O30  1  0.818  0.678  0.578  1.0
  O  O31  1  0.322  0.182  0.422  1.0
  O  O32  1  0.723  0.241  0.388  1.0
  O  O33  1  0.759  0.277  0.612  1.0
  O  O34  1  0.273  0.759  0.112  1.0
  O  O35  1  0.241  0.727  0.888  1.0
[/CIF]
.
The material described by SrLa3Mn4O10 crystallizes in the monoclinic C2 space group. Sr(1) is bonded in a 8-coordinate geometry to one O(10), one O(2), one O(3), one O(4), one O(7), one O(9), and two equivalent O(6) atoms. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(3), one O(4), one O(8), one O(9), and two equivalent O(5) atoms. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(5), one O(7), two equivalent O(1), two equivalent O(10), and two equivalent O(4) atoms. In the third La site, La(3) is bonded in a 8-coordinate geometry to one O(6), one O(8), two equivalent O(2), two equivalent O(3), and two equivalent O(9) atoms. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(5), and two equivalent O(8) atoms to form MnO4 tetrahedra that share  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra, and corners with two equivalent Mn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 36°. In the second Mn site, Mn(2) is bonded to one O(1), one O(6), and two equivalent O(7) atoms to form MnO4 tetrahedra that share  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra, and corners with two equivalent Mn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 37-42°. In the third Mn site, Mn(3) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(9) atoms to form MnO6 octahedra that share corners with four equivalent Mn(5)O6 octahedra and corners with two equivalent Mn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 18-19°. In the fourth Mn site, Mn(4) is bonded to two equivalent O(1), two equivalent O(10), and two equivalent O(4) atoms to form MnO6 octahedra that share corners with four equivalent Mn(5)O6 octahedra and corners with two equivalent Mn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 8-13°. In the fifth Mn site, Mn(5) is bonded to one O(10), one O(3), one O(4), one O(5), one O(6), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra,  a cornercorner with one Mn(1)O4 tetrahedra, and  a cornercorner with one Mn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 8-19°. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one La(1), two equivalent La(2), one Mn(2), and one Mn(4) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Sr(1), two equivalent La(3), one Mn(1), and one Mn(3) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to one Sr(1), one La(1), two equivalent La(3), one Mn(3), and one Mn(5) atom. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Sr(1), one La(1), two equivalent La(2), one Mn(4), and one Mn(5) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one La(2), two equivalent La(1), one Mn(1), and one Mn(5) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one La(3), one Mn(2), and one Mn(5) atom. In the seventh O site, O(7) is bonded to one Sr(1), one La(2), and two equivalent Mn(2) atoms to form corner-sharing OSrLaMn2 tetrahedra. In the eighth O site, O(8) is bonded to one La(1), one La(3), and two equivalent Mn(1) atoms to form corner-sharing OLa2Mn2 tetrahedra. In the ninth O site, O(9) is bonded in a 6-coordinate geometry to one Sr(1), one La(1), two equivalent La(3), one Mn(3), and one Mn(5) atom. In the tenth O site, O(10) is bonded in a 6-coordinate geometry to one Sr(1), one La(1), two equivalent La(2), one Mn(4), and one Mn(5) atom. is represented by the CIF file [CIF]
data_SrLa3Mn4O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.072
_cell_length_b   9.072
_cell_length_c   11.633
_cell_angle_alpha   71.298
_cell_angle_beta   71.298
_cell_angle_gamma   35.908
_symmetry_Int_Tables_number   1
_cell_volume   528.733
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.397  0.372  0.799  1.0
  Sr  Sr1  1  0.628  0.603  0.201  1.0
  La  La2  1  0.592  0.626  0.703  1.0
  La  La3  1  0.374  0.408  0.297  1.0
  La  La4  1  0.909  0.871  0.068  1.0
  La  La5  1  0.129  0.091  0.932  1.0
  La  La6  1  0.089  0.137  0.433  1.0
  La  La7  1  0.863  0.911  0.567  1.0
  Mn  Mn8  1  0.202  0.296  0.599  1.0
  Mn  Mn9  1  0.704  0.798  0.401  1.0
  Mn  Mn10  1  0.797  0.704  0.901  1.0
  Mn  Mn11  1  0.296  0.203  0.099  1.0
  Mn  Mn12  1  0.494  0.506  0.500  1.0
  Mn  Mn13  1  0.504  0.496  0.000  1.0
  Mn  Mn14  1  0.003  0.004  0.249  1.0
  Mn  Mn15  1  0.996  0.997  0.751  1.0
  O  O16  1  0.322  0.399  0.115  1.0
  O  O17  1  0.601  0.678  0.885  1.0
  O  O18  1  0.678  0.599  0.399  1.0
  O  O19  1  0.401  0.322  0.601  1.0
  O  O20  1  0.266  0.770  0.608  1.0
  O  O21  1  0.230  0.734  0.392  1.0
  O  O22  1  0.742  0.239  0.887  1.0
  O  O23  1  0.761  0.258  0.113  1.0
  O  O24  1  0.895  0.836  0.282  1.0
  O  O25  1  0.164  0.105  0.718  1.0
  O  O26  1  0.125  0.144  0.224  1.0
  O  O27  1  0.856  0.875  0.776  1.0
  O  O28  1  0.163  0.320  0.932  1.0
  O  O29  1  0.680  0.837  0.068  1.0
  O  O30  1  0.818  0.678  0.578  1.0
  O  O31  1  0.322  0.182  0.422  1.0
  O  O32  1  0.723  0.241  0.388  1.0
  O  O33  1  0.759  0.277  0.612  1.0
  O  O34  1  0.273  0.759  0.112  1.0
  O  O35  1  0.241  0.727  0.888  1.0
[/CIF]
.