The material structure described by Li3Co3SbO8 crystallizes in the triclinic P-1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(1), two equivalent O(6), and two equivalent O(7) atoms to form LiO6 octahedra that share corners with six equivalent Co(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. In the second Li site, Li(2) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with six equivalent Co(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Co(2)O6 octahedra, corners with three equivalent Co(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-11°. In the fourth Li site, Li(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with six equivalent Co(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-8°. In the fifth Li site, Li(5) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with six equivalent Co(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-11°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with three equivalent Li(1)O6 octahedra, corners with three equivalent Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. In the second Co site, Co(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with six equivalent Li(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. In the third Co site, Co(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with six equivalent Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-11°. In the fourth Co site, Co(4) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-11°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(4), two equivalent O(5), and two equivalent O(8) atoms to form SbO6 octahedra that share edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. In the second Sb site, Sb(2) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(7) atoms to form SbO6 octahedra that share edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(3), one Li(4), one Co(1), one Co(3), and one Co(4) atom to form OLi3Co3 octahedra that share corners with three equivalent O(1)Li3Co3 octahedra, corners with three equivalent O(2)Li3Co3 octahedra,  an edgeedge with one O(4)Li2Co2Sb square pyramid,  an edgeedge with one O(5)Li2Co2Sb square pyramid,  an edgeedge with one O(8)Li2Co2Sb square pyramid, edges with three equivalent O(3)Li2Co2Sb square pyramids, edges with three equivalent O(6)Li2Co2Sb square pyramids, and edges with three equivalent O(7)Li2Co2Sb square pyramids. The corner-sharing octahedral tilt angles range from 0-3°. In the second O site, O(2) is bonded to one Li(2), one Li(3), one Li(5), one Co(1), one Co(2), and one Co(4) atom to form OLi3Co3 octahedra that share corners with three equivalent O(1)Li3Co3 octahedra, corners with three equivalent O(2)Li3Co3 octahedra,  an edgeedge with one O(3)Li2Co2Sb square pyramid,  an edgeedge with one O(6)Li2Co2Sb square pyramid,  an edgeedge with one O(7)Li2Co2Sb square pyramid, edges with three equivalent O(4)Li2Co2Sb square pyramids, edges with three equivalent O(5)Li2Co2Sb square pyramids, and edges with three equivalent O(8)Li2Co2Sb square pyramids. The corner-sharing octahedral tilt angles range from 0-3°. In the third O site, O(3) is bonded to one Li(3), one Li(4), one Co(3), one Co(4), and one Sb(2) atom to form OLi2Co2Sb square pyramids that share  a cornercorner with one O(5)Li2Co2Sb square pyramid,  a cornercorner with one O(6)Li2Co2Sb square pyramid,  a cornercorner with one O(7)Li2Co2Sb square pyramid,  a cornercorner with one O(8)Li2Co2Sb square pyramid, corners with two equivalent O(4)Li2Co2Sb square pyramids, corners with three equivalent O(3)Li2Co2Sb square pyramids,  an edgeedge with one O(2)Li3Co3 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with two equivalent O(6)Li2Co2Sb square pyramids, and edges with two equivalent O(7)Li2Co2Sb square pyramids. In the fourth O site, O(4) is bonded to one Li(3), one Li(5), one Co(2), one Co(4), and one Sb(1) atom to form OLi2Co2Sb square pyramids that share  a cornercorner with one O(5)Li2Co2Sb square pyramid,  a cornercorner with one O(6)Li2Co2Sb square pyramid,  a cornercorner with one O(7)Li2Co2Sb square pyramid,  a cornercorner with one O(8)Li2Co2Sb square pyramid, corners with two equivalent O(3)Li2Co2Sb square pyramids, corners with three equivalent O(4)Li2Co2Sb square pyramids,  an edgeedge with one O(1)Li3Co3 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with two equivalent O(5)Li2Co2Sb square pyramids, and edges with two equivalent O(8)Li2Co2Sb square pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Li(5), one Co(1), one Co(4), and one Sb(1) atom to form OLi2Co2Sb square pyramids that share  a cornercorner with one O(3)Li2Co2Sb square pyramid,  a cornercorner with one O(4)Li2Co2Sb square pyramid,  a cornercorner with one O(7)Li2Co2Sb square pyramid,  a cornercorner with one O(8)Li2Co2Sb square pyramid, corners with two equivalent O(6)Li2Co2Sb square pyramids, corners with three equivalent O(5)Li2Co2Sb square pyramids,  an edgeedge with one O(1)Li3Co3 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with two equivalent O(4)Li2Co2Sb square pyramids, and edges with two equivalent O(8)Li2Co2Sb square pyramids. In the sixth O site, O(6) is bonded to one Li(1), one Li(4), one Co(1), one Co(4), and one Sb(2) atom to form OLi2Co2Sb square pyramids that share  a cornercorner with one O(3)Li2Co2Sb square pyramid,  a cornercorner with one O(4)Li2Co2Sb square pyramid,  a cornercorner with one O(7)Li2Co2Sb square pyramid,  a cornercorner with one O(8)Li2Co2Sb square pyramid, corners with two equivalent O(5)Li2Co2Sb square pyramids, corners with three equivalent O(6)Li2Co2Sb square pyramids,  an edgeedge with one O(2)Li3Co3 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with two equivalent O(3)Li2Co2Sb square pyramids, and edges with two equivalent O(7)Li2Co2Sb square pyramids. In the seventh O site, O(7) is bonded to one Li(1), one Li(3), one Co(1), one Co(3), and one Sb(2) atom to form OLi2Co2Sb square pyramids that share  a cornercorner with one O(3)Li2Co2Sb square pyramid,  a cornercorner with one O(4)Li2Co2Sb square pyramid,  a cornercorner with one O(5)Li2Co2Sb square pyramid,  a cornercorner with one O(6)Li2Co2Sb square pyramid, corners with two equivalent O(8)Li2Co2Sb square pyramids, corners with three equivalent O(7)Li2Co2Sb square pyramids,  an edgeedge with one O(2)Li3Co3 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with two equivalent O(3)Li2Co2Sb square pyramids, and edges with two equivalent O(6)Li2Co2Sb square pyramids. In the eighth O site, O(8) is bonded to one Li(2), one Li(3), one Co(1), one Co(2), and one Sb(1) atom to form OLi2Co2Sb square pyramids that share  a cornercorner with one O(3)Li2Co2Sb square pyramid,  a cornercorner with one O(4)Li2Co2Sb square pyramid,  a cornercorner with one O(5)Li2Co2Sb square pyramid,  a cornercorner with one O(6)Li2Co2Sb square pyramid, corners with two equivalent O(7)Li2Co2Sb square pyramids, corners with three equivalent O(8)Li2Co2Sb square pyramids,  an edgeedge with one O(1)Li3Co3 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with two equivalent O(4)Li2Co2Sb square pyramids, and edges with two equivalent O(5)Li2Co2Sb square pyramids. is represented by the CIF file [CIF]
data_Li3Co3SbO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.070
_cell_length_b   10.425
_cell_length_c   6.050
_cell_angle_alpha   72.916
_cell_angle_beta   120.018
_cell_angle_gamma   105.858
_symmetry_Int_Tables_number   1
_cell_volume   313.147
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  1.000  0.500  1.0
  Li  Li1  1  0.500  0.500  1.000  1.0
  Li  Li2  1  0.745  0.755  0.744  1.0
  Li  Li3  1  0.255  0.245  0.256  1.0
  Li  Li4  1  0.500  0.000  0.500  1.0
  Li  Li5  1  0.000  0.500  1.000  1.0
  Co  Co6  1  0.253  0.750  0.253  1.0
  Co  Co7  1  0.747  0.250  0.747  1.0
  Co  Co8  1  1.000  0.500  0.500  1.0
  Co  Co9  1  0.500  0.000  1.000  1.0
  Co  Co10  1  0.750  0.749  0.247  1.0
  Co  Co11  1  0.250  0.251  0.753  1.0
  Sb  Sb12  1  0.500  0.500  0.500  1.0
  Sb  Sb13  1  0.000  0.000  1.000  1.0
  O  O14  1  0.380  0.128  0.665  1.0
  O  O15  1  0.887  0.626  0.173  1.0
  O  O16  1  0.620  0.872  0.335  1.0
  O  O17  1  0.113  0.374  0.828  1.0
  O  O18  1  0.650  0.884  0.887  1.0
  O  O19  1  0.140  0.391  0.393  1.0
  O  O20  1  0.350  0.116  0.113  1.0
  O  O21  1  0.859  0.609  0.607  1.0
  O  O22  1  0.393  0.623  0.153  1.0
  O  O23  1  0.892  0.122  0.652  1.0
  O  O24  1  0.607  0.377  0.847  1.0
  O  O25  1  0.108  0.878  0.348  1.0
  O  O26  1  0.127  0.883  0.892  1.0
  O  O27  1  0.610  0.379  0.386  1.0
  O  O28  1  0.873  0.117  0.108  1.0
  O  O29  1  0.390  0.621  0.614  1.0
[/CIF]
.
The material structure described by Li3Co3SbO8 crystallizes in the triclinic P-1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(1), two equivalent O(6), and two equivalent O(7) atoms to form LiO6 octahedra that share corners with six equivalent Co(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. In the second Li site, Li(2) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with six equivalent Co(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Co(2)O6 octahedra, corners with three equivalent Co(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-11°. In the fourth Li site, Li(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form LiO6 octahedra that share corners with six equivalent Co(4)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-8°. In the fifth Li site, Li(5) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form LiO6 octahedra that share corners with six equivalent Co(4)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-11°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with three equivalent Li(1)O6 octahedra, corners with three equivalent Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-13°. In the second Co site, Co(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with six equivalent Li(3)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-9°. In the third Co site, Co(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with six equivalent Li(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-11°. In the fourth Co site, Co(4) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-11°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(4), two equivalent O(5), and two equivalent O(8) atoms to form SbO6 octahedra that share edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. In the second Sb site, Sb(2) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(7) atoms to form SbO6 octahedra that share edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(3), one Li(4), one Co(1), one Co(3), and one Co(4) atom to form OLi3Co3 octahedra that share corners with three equivalent O(1)Li3Co3 octahedra, corners with three equivalent O(2)Li3Co3 octahedra,  an edgeedge with one O(4)Li2Co2Sb square pyramid,  an edgeedge with one O(5)Li2Co2Sb square pyramid,  an edgeedge with one O(8)Li2Co2Sb square pyramid, edges with three equivalent O(3)Li2Co2Sb square pyramids, edges with three equivalent O(6)Li2Co2Sb square pyramids, and edges with three equivalent O(7)Li2Co2Sb square pyramids. The corner-sharing octahedral tilt angles range from 0-3°. In the second O site, O(2) is bonded to one Li(2), one Li(3), one Li(5), one Co(1), one Co(2), and one Co(4) atom to form OLi3Co3 octahedra that share corners with three equivalent O(1)Li3Co3 octahedra, corners with three equivalent O(2)Li3Co3 octahedra,  an edgeedge with one O(3)Li2Co2Sb square pyramid,  an edgeedge with one O(6)Li2Co2Sb square pyramid,  an edgeedge with one O(7)Li2Co2Sb square pyramid, edges with three equivalent O(4)Li2Co2Sb square pyramids, edges with three equivalent O(5)Li2Co2Sb square pyramids, and edges with three equivalent O(8)Li2Co2Sb square pyramids. The corner-sharing octahedral tilt angles range from 0-3°. In the third O site, O(3) is bonded to one Li(3), one Li(4), one Co(3), one Co(4), and one Sb(2) atom to form OLi2Co2Sb square pyramids that share  a cornercorner with one O(5)Li2Co2Sb square pyramid,  a cornercorner with one O(6)Li2Co2Sb square pyramid,  a cornercorner with one O(7)Li2Co2Sb square pyramid,  a cornercorner with one O(8)Li2Co2Sb square pyramid, corners with two equivalent O(4)Li2Co2Sb square pyramids, corners with three equivalent O(3)Li2Co2Sb square pyramids,  an edgeedge with one O(2)Li3Co3 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with two equivalent O(6)Li2Co2Sb square pyramids, and edges with two equivalent O(7)Li2Co2Sb square pyramids. In the fourth O site, O(4) is bonded to one Li(3), one Li(5), one Co(2), one Co(4), and one Sb(1) atom to form OLi2Co2Sb square pyramids that share  a cornercorner with one O(5)Li2Co2Sb square pyramid,  a cornercorner with one O(6)Li2Co2Sb square pyramid,  a cornercorner with one O(7)Li2Co2Sb square pyramid,  a cornercorner with one O(8)Li2Co2Sb square pyramid, corners with two equivalent O(3)Li2Co2Sb square pyramids, corners with three equivalent O(4)Li2Co2Sb square pyramids,  an edgeedge with one O(1)Li3Co3 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with two equivalent O(5)Li2Co2Sb square pyramids, and edges with two equivalent O(8)Li2Co2Sb square pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Li(5), one Co(1), one Co(4), and one Sb(1) atom to form OLi2Co2Sb square pyramids that share  a cornercorner with one O(3)Li2Co2Sb square pyramid,  a cornercorner with one O(4)Li2Co2Sb square pyramid,  a cornercorner with one O(7)Li2Co2Sb square pyramid,  a cornercorner with one O(8)Li2Co2Sb square pyramid, corners with two equivalent O(6)Li2Co2Sb square pyramids, corners with three equivalent O(5)Li2Co2Sb square pyramids,  an edgeedge with one O(1)Li3Co3 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with two equivalent O(4)Li2Co2Sb square pyramids, and edges with two equivalent O(8)Li2Co2Sb square pyramids. In the sixth O site, O(6) is bonded to one Li(1), one Li(4), one Co(1), one Co(4), and one Sb(2) atom to form OLi2Co2Sb square pyramids that share  a cornercorner with one O(3)Li2Co2Sb square pyramid,  a cornercorner with one O(4)Li2Co2Sb square pyramid,  a cornercorner with one O(7)Li2Co2Sb square pyramid,  a cornercorner with one O(8)Li2Co2Sb square pyramid, corners with two equivalent O(5)Li2Co2Sb square pyramids, corners with three equivalent O(6)Li2Co2Sb square pyramids,  an edgeedge with one O(2)Li3Co3 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with two equivalent O(3)Li2Co2Sb square pyramids, and edges with two equivalent O(7)Li2Co2Sb square pyramids. In the seventh O site, O(7) is bonded to one Li(1), one Li(3), one Co(1), one Co(3), and one Sb(2) atom to form OLi2Co2Sb square pyramids that share  a cornercorner with one O(3)Li2Co2Sb square pyramid,  a cornercorner with one O(4)Li2Co2Sb square pyramid,  a cornercorner with one O(5)Li2Co2Sb square pyramid,  a cornercorner with one O(6)Li2Co2Sb square pyramid, corners with two equivalent O(8)Li2Co2Sb square pyramids, corners with three equivalent O(7)Li2Co2Sb square pyramids,  an edgeedge with one O(2)Li3Co3 octahedra, edges with three equivalent O(1)Li3Co3 octahedra, edges with two equivalent O(3)Li2Co2Sb square pyramids, and edges with two equivalent O(6)Li2Co2Sb square pyramids. In the eighth O site, O(8) is bonded to one Li(2), one Li(3), one Co(1), one Co(2), and one Sb(1) atom to form OLi2Co2Sb square pyramids that share  a cornercorner with one O(3)Li2Co2Sb square pyramid,  a cornercorner with one O(4)Li2Co2Sb square pyramid,  a cornercorner with one O(5)Li2Co2Sb square pyramid,  a cornercorner with one O(6)Li2Co2Sb square pyramid, corners with two equivalent O(7)Li2Co2Sb square pyramids, corners with three equivalent O(8)Li2Co2Sb square pyramids,  an edgeedge with one O(1)Li3Co3 octahedra, edges with three equivalent O(2)Li3Co3 octahedra, edges with two equivalent O(4)Li2Co2Sb square pyramids, and edges with two equivalent O(5)Li2Co2Sb square pyramids. is represented by the CIF file [CIF]
data_Li3Co3SbO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.070
_cell_length_b   10.425
_cell_length_c   6.050
_cell_angle_alpha   72.916
_cell_angle_beta   120.018
_cell_angle_gamma   105.858
_symmetry_Int_Tables_number   1
_cell_volume   313.147
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  1.000  0.500  1.0
  Li  Li1  1  0.500  0.500  1.000  1.0
  Li  Li2  1  0.745  0.755  0.744  1.0
  Li  Li3  1  0.255  0.245  0.256  1.0
  Li  Li4  1  0.500  0.000  0.500  1.0
  Li  Li5  1  0.000  0.500  1.000  1.0
  Co  Co6  1  0.253  0.750  0.253  1.0
  Co  Co7  1  0.747  0.250  0.747  1.0
  Co  Co8  1  1.000  0.500  0.500  1.0
  Co  Co9  1  0.500  0.000  1.000  1.0
  Co  Co10  1  0.750  0.749  0.247  1.0
  Co  Co11  1  0.250  0.251  0.753  1.0
  Sb  Sb12  1  0.500  0.500  0.500  1.0
  Sb  Sb13  1  0.000  0.000  1.000  1.0
  O  O14  1  0.380  0.128  0.665  1.0
  O  O15  1  0.887  0.626  0.173  1.0
  O  O16  1  0.620  0.872  0.335  1.0
  O  O17  1  0.113  0.374  0.828  1.0
  O  O18  1  0.650  0.884  0.887  1.0
  O  O19  1  0.140  0.391  0.393  1.0
  O  O20  1  0.350  0.116  0.113  1.0
  O  O21  1  0.859  0.609  0.607  1.0
  O  O22  1  0.393  0.623  0.153  1.0
  O  O23  1  0.892  0.122  0.652  1.0
  O  O24  1  0.607  0.377  0.847  1.0
  O  O25  1  0.108  0.878  0.348  1.0
  O  O26  1  0.127  0.883  0.892  1.0
  O  O27  1  0.610  0.379  0.386  1.0
  O  O28  1  0.873  0.117  0.108  1.0
  O  O29  1  0.390  0.621  0.614  1.0
[/CIF]
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