The material structure described by Y4O(OH)9NO3 crystallizes in the monoclinic P2_1 space group. The structure consists of two nitric acid molecules inside a Y4H9O10 framework. In the Y4H9O10 framework, there are four inequivalent Y sites. In the first Y site, Y(1) is bonded to one O(1), one O(10), one O(2), two equivalent O(4), and two equivalent O(9) atoms to form distorted edge-sharing YO7 pentagonal bipyramids. In the second Y site, Y(2) is bonded in a 9-coordinate geometry to one O(7), one O(8), one O(9), two equivalent O(10), two equivalent O(5), and two equivalent O(6) atoms. In the third Y site, Y(3) is bonded to one O(1), one O(2), one O(6), two equivalent O(3), and two equivalent O(7) atoms to form distorted edge-sharing YO7 pentagonal bipyramids. In the fourth Y site, Y(4) is bonded in a 7-coordinate geometry to one O(3), one O(4), one O(5), two equivalent O(2), and two equivalent O(8) atoms. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(10) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Y(1), one Y(3), and one H(1) atom. In the second O site, O(2) is bonded to one Y(1), one Y(3), and two equivalent Y(4) atoms to form corner-sharing OY4 tetrahedra. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Y(4), two equivalent Y(3), and one H(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Y(4), two equivalent Y(1), and one H(3) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Y(4), two equivalent Y(2), and one H(4) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Y(3), two equivalent Y(2), and one H(5) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Y(2), two equivalent Y(3), and one H(6) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Y(2), two equivalent Y(4), and one H(7) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Y(2), two equivalent Y(1), and one H(8) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Y(1), two equivalent Y(2), and one H(9) atom. is represented by the CIF card [CIF]
data_Y4H9NO13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.666
_cell_length_b   3.660
_cell_length_c   9.474
_cell_angle_alpha   80.056
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   569.239
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.501  0.631  0.731  1.0
  Y  Y1  1  0.001  0.369  0.269  1.0
  Y  Y2  1  0.790  0.882  0.268  1.0
  Y  Y3  1  0.290  0.118  0.732  1.0
  Y  Y4  1  0.690  0.547  0.939  1.0
  Y  Y5  1  0.190  0.453  0.061  1.0
  Y  Y6  1  0.682  0.199  0.597  1.0
  Y  Y7  1  0.182  0.801  0.403  1.0
  H  H8  1  0.524  0.521  0.042  1.0
  H  H9  1  0.024  0.479  0.958  1.0
  H  H10  1  0.811  0.090  0.825  1.0
  H  H11  1  0.311  0.910  0.175  1.0
  H  H12  1  0.511  0.265  0.486  1.0
  H  H13  1  0.011  0.735  0.514  1.0
  H  H14  1  0.649  0.335  0.293  1.0
  H  H15  1  0.149  0.665  0.707  1.0
  H  H16  1  0.853  0.468  0.050  1.0
  H  H17  1  0.353  0.532  0.950  1.0
  H  H18  1  0.620  0.957  0.139  1.0
  H  H19  1  0.120  0.043  0.861  1.0
  H  H20  1  0.819  0.709  0.594  1.0
  H  H21  1  0.319  0.291  0.406  1.0
  H  H22  1  0.940  0.958  0.065  1.0
  H  H23  1  0.440  0.042  0.935  1.0
  H  H24  1  0.864  0.321  0.467  1.0
  H  H25  1  0.364  0.679  0.533  1.0
  N  N26  1  0.961  0.175  0.747  1.0
  N  N27  1  0.461  0.825  0.253  1.0
  O  O28  1  0.554  0.552  0.954  1.0
  O  O29  1  0.054  0.448  0.046  1.0
  O  O30  1  0.636  0.645  0.714  1.0
  O  O31  1  0.136  0.355  0.286  1.0
  O  O32  1  0.752  0.101  0.818  1.0
  O  O33  1  0.252  0.899  0.182  1.0
  O  O34  1  0.537  0.191  0.580  1.0
  O  O35  1  0.037  0.809  0.420  1.0
  O  O36  1  0.698  0.336  0.349  1.0
  O  O37  1  0.198  0.664  0.651  1.0
  O  O38  1  0.800  0.464  0.092  1.0
  O  O39  1  0.300  0.536  0.908  1.0
  O  O40  1  0.674  0.973  0.098  1.0
  O  O41  1  0.174  0.027  0.902  1.0
  O  O42  1  0.772  0.745  0.532  1.0
  O  O43  1  0.272  0.255  0.468  1.0
  O  O44  1  0.932  0.916  0.169  1.0
  O  O45  1  0.432  0.084  0.831  1.0
  O  O46  1  0.868  0.342  0.364  1.0
  O  O47  1  0.368  0.658  0.636  1.0
  O  O48  1  0.919  0.043  0.856  1.0
  O  O49  1  0.419  0.957  0.144  1.0
  O  O50  1  0.032  0.065  0.735  1.0
  O  O51  1  0.532  0.935  0.265  1.0
  O  O52  1  0.931  0.416  0.649  1.0
  O  O53  1  0.431  0.584  0.351  1.0
[/CIF]
.
The material structure described by Y4O(OH)9NO3 crystallizes in the monoclinic P2_1 space group. The structure consists of two nitric acid molecules inside a Y4H9O10 framework. In the Y4H9O10 framework, there are four inequivalent Y sites. In the first Y site, Y(1) is bonded to one O(1), one O(10), one O(2), two equivalent O(4), and two equivalent O(9) atoms to form distorted edge-sharing YO7 pentagonal bipyramids. In the second Y site, Y(2) is bonded in a 9-coordinate geometry to one O(7), one O(8), one O(9), two equivalent O(10), two equivalent O(5), and two equivalent O(6) atoms. In the third Y site, Y(3) is bonded to one O(1), one O(2), one O(6), two equivalent O(3), and two equivalent O(7) atoms to form distorted edge-sharing YO7 pentagonal bipyramids. In the fourth Y site, Y(4) is bonded in a 7-coordinate geometry to one O(3), one O(4), one O(5), two equivalent O(2), and two equivalent O(8) atoms. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(10) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Y(1), one Y(3), and one H(1) atom. In the second O site, O(2) is bonded to one Y(1), one Y(3), and two equivalent Y(4) atoms to form corner-sharing OY4 tetrahedra. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Y(4), two equivalent Y(3), and one H(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Y(4), two equivalent Y(1), and one H(3) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Y(4), two equivalent Y(2), and one H(4) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Y(3), two equivalent Y(2), and one H(5) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Y(2), two equivalent Y(3), and one H(6) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Y(2), two equivalent Y(4), and one H(7) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Y(2), two equivalent Y(1), and one H(8) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Y(1), two equivalent Y(2), and one H(9) atom. is represented by the CIF card [CIF]
data_Y4H9NO13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.666
_cell_length_b   3.660
_cell_length_c   9.474
_cell_angle_alpha   80.056
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   569.239
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.501  0.631  0.731  1.0
  Y  Y1  1  0.001  0.369  0.269  1.0
  Y  Y2  1  0.790  0.882  0.268  1.0
  Y  Y3  1  0.290  0.118  0.732  1.0
  Y  Y4  1  0.690  0.547  0.939  1.0
  Y  Y5  1  0.190  0.453  0.061  1.0
  Y  Y6  1  0.682  0.199  0.597  1.0
  Y  Y7  1  0.182  0.801  0.403  1.0
  H  H8  1  0.524  0.521  0.042  1.0
  H  H9  1  0.024  0.479  0.958  1.0
  H  H10  1  0.811  0.090  0.825  1.0
  H  H11  1  0.311  0.910  0.175  1.0
  H  H12  1  0.511  0.265  0.486  1.0
  H  H13  1  0.011  0.735  0.514  1.0
  H  H14  1  0.649  0.335  0.293  1.0
  H  H15  1  0.149  0.665  0.707  1.0
  H  H16  1  0.853  0.468  0.050  1.0
  H  H17  1  0.353  0.532  0.950  1.0
  H  H18  1  0.620  0.957  0.139  1.0
  H  H19  1  0.120  0.043  0.861  1.0
  H  H20  1  0.819  0.709  0.594  1.0
  H  H21  1  0.319  0.291  0.406  1.0
  H  H22  1  0.940  0.958  0.065  1.0
  H  H23  1  0.440  0.042  0.935  1.0
  H  H24  1  0.864  0.321  0.467  1.0
  H  H25  1  0.364  0.679  0.533  1.0
  N  N26  1  0.961  0.175  0.747  1.0
  N  N27  1  0.461  0.825  0.253  1.0
  O  O28  1  0.554  0.552  0.954  1.0
  O  O29  1  0.054  0.448  0.046  1.0
  O  O30  1  0.636  0.645  0.714  1.0
  O  O31  1  0.136  0.355  0.286  1.0
  O  O32  1  0.752  0.101  0.818  1.0
  O  O33  1  0.252  0.899  0.182  1.0
  O  O34  1  0.537  0.191  0.580  1.0
  O  O35  1  0.037  0.809  0.420  1.0
  O  O36  1  0.698  0.336  0.349  1.0
  O  O37  1  0.198  0.664  0.651  1.0
  O  O38  1  0.800  0.464  0.092  1.0
  O  O39  1  0.300  0.536  0.908  1.0
  O  O40  1  0.674  0.973  0.098  1.0
  O  O41  1  0.174  0.027  0.902  1.0
  O  O42  1  0.772  0.745  0.532  1.0
  O  O43  1  0.272  0.255  0.468  1.0
  O  O44  1  0.932  0.916  0.169  1.0
  O  O45  1  0.432  0.084  0.831  1.0
  O  O46  1  0.868  0.342  0.364  1.0
  O  O47  1  0.368  0.658  0.636  1.0
  O  O48  1  0.919  0.043  0.856  1.0
  O  O49  1  0.419  0.957  0.144  1.0
  O  O50  1  0.032  0.065  0.735  1.0
  O  O51  1  0.532  0.935  0.265  1.0
  O  O52  1  0.931  0.416  0.649  1.0
  O  O53  1  0.431  0.584  0.351  1.0
[/CIF]
.