The crystal structure described by RbNa2Mn3P4O14Cl crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent O(2), two equivalent O(3), four equivalent O(1), and two equivalent Cl(1) atoms. Na(1) is bonded in a 6-coordinate geometry to one O(5), one O(7), two equivalent O(3), and two equivalent O(6) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(3), one O(4), one O(5), one O(6), one O(7), and one Cl(1) atom. In the second Mn site, Mn(2) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent Cl(1) atoms to form distorted MnCl2O4 octahedra that share corners with two equivalent Mn(2)Cl2O4 octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedra are not tilted. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(4), one O(5), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)Cl2O4 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 56°. In the second P site, P(2) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)Cl2O4 octahedra and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Mn(1), and one P(2) atom. In the second O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Mn(1), and one P(1) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1), one Mn(2), and one P(2) atom. In the fourth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one Mn(1), and one P(1) atom. In the fifth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(1), and one P(2) atom. In the sixth O site, O(3) is bonded in a 1-coordinate geometry to one Rb(1), two equivalent Na(1), one Mn(1), and one P(2) atom. In the seventh O site, O(4) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one P(1) atom. Cl(1) is bonded to two equivalent Rb(1), two equivalent Mn(1), and two equivalent Mn(2) atoms to form distorted corner-sharing ClRb2Mn4 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_RbNa2Mn3P4ClO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.045
_cell_length_b   11.045
_cell_length_c   14.037
_cell_angle_alpha   61.506
_cell_angle_beta   61.506
_cell_angle_gamma   27.823
_symmetry_Int_Tables_number   1
_cell_volume   696.103
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.500  0.000  1.0
  Rb  Rb1  1  0.500  0.500  0.500  1.0
  Na  Na2  1  0.254  0.305  0.153  1.0
  Na  Na3  1  0.695  0.746  0.347  1.0
  Na  Na4  1  0.746  0.695  0.847  1.0
  Na  Na5  1  0.305  0.254  0.653  1.0
  Mn  Mn6  1  0.671  0.643  0.155  1.0
  Mn  Mn7  1  0.357  0.329  0.345  1.0
  Mn  Mn8  1  0.329  0.357  0.845  1.0
  Mn  Mn9  1  0.643  0.671  0.655  1.0
  Mn  Mn10  1  0.948  0.052  0.250  1.0
  Mn  Mn11  1  0.052  0.948  0.750  1.0
  P  P12  1  0.174  0.141  0.007  1.0
  P  P13  1  0.859  0.826  0.493  1.0
  P  P14  1  0.826  0.859  0.993  1.0
  P  P15  1  0.141  0.174  0.507  1.0
  P  P16  1  0.877  0.886  0.171  1.0
  P  P17  1  0.114  0.123  0.329  1.0
  P  P18  1  0.123  0.114  0.829  1.0
  P  P19  1  0.886  0.877  0.671  1.0
  Cl  Cl20  1  0.458  0.542  0.250  1.0
  Cl  Cl21  1  0.542  0.458  0.750  1.0
  O  O22  1  0.955  0.964  0.146  1.0
  O  O23  1  0.036  0.045  0.354  1.0
  O  O24  1  0.045  0.036  0.854  1.0
  O  O25  1  0.964  0.955  0.646  1.0
  O  O26  1  0.061  0.154  0.951  1.0
  O  O27  1  0.846  0.939  0.549  1.0
  O  O28  1  0.939  0.846  0.049  1.0
  O  O29  1  0.154  0.061  0.451  1.0
  O  O30  1  0.896  0.416  0.290  1.0
  O  O31  1  0.584  0.104  0.210  1.0
  O  O32  1  0.104  0.584  0.710  1.0
  O  O33  1  0.416  0.896  0.790  1.0
  O  O34  1  0.989  0.248  0.116  1.0
  O  O35  1  0.752  0.011  0.384  1.0
  O  O36  1  0.011  0.752  0.884  1.0
  O  O37  1  0.248  0.989  0.616  1.0
  O  O38  1  0.459  0.855  0.023  1.0
  O  O39  1  0.145  0.541  0.477  1.0
  O  O40  1  0.541  0.145  0.977  1.0
  O  O41  1  0.855  0.459  0.523  1.0
  O  O42  1  0.048  0.623  0.244  1.0
  O  O43  1  0.377  0.952  0.256  1.0
  O  O44  1  0.952  0.377  0.756  1.0
  O  O45  1  0.623  0.048  0.744  1.0
  O  O46  1  0.859  0.678  0.072  1.0
  O  O47  1  0.322  0.141  0.428  1.0
  O  O48  1  0.141  0.322  0.928  1.0
  O  O49  1  0.678  0.859  0.572  1.0
[/CIF]
.
The crystal structure described by RbNa2Mn3P4O14Cl crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent O(2), two equivalent O(3), four equivalent O(1), and two equivalent Cl(1) atoms. Na(1) is bonded in a 6-coordinate geometry to one O(5), one O(7), two equivalent O(3), and two equivalent O(6) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(3), one O(4), one O(5), one O(6), one O(7), and one Cl(1) atom. In the second Mn site, Mn(2) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent Cl(1) atoms to form distorted MnCl2O4 octahedra that share corners with two equivalent Mn(2)Cl2O4 octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedra are not tilted. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(4), one O(5), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)Cl2O4 octahedra and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 56°. In the second P site, P(2) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(2)Cl2O4 octahedra and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a 4-coordinate geometry to two equivalent Na(1), one Mn(1), and one P(2) atom. In the second O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Mn(1), and one P(1) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Rb(1), one Mn(2), and one P(2) atom. In the fourth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one Mn(1), and one P(1) atom. In the fifth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(1), and one P(2) atom. In the sixth O site, O(3) is bonded in a 1-coordinate geometry to one Rb(1), two equivalent Na(1), one Mn(1), and one P(2) atom. In the seventh O site, O(4) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one P(1) atom. Cl(1) is bonded to two equivalent Rb(1), two equivalent Mn(1), and two equivalent Mn(2) atoms to form distorted corner-sharing ClRb2Mn4 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_RbNa2Mn3P4ClO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.045
_cell_length_b   11.045
_cell_length_c   14.037
_cell_angle_alpha   61.506
_cell_angle_beta   61.506
_cell_angle_gamma   27.823
_symmetry_Int_Tables_number   1
_cell_volume   696.103
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.500  0.000  1.0
  Rb  Rb1  1  0.500  0.500  0.500  1.0
  Na  Na2  1  0.254  0.305  0.153  1.0
  Na  Na3  1  0.695  0.746  0.347  1.0
  Na  Na4  1  0.746  0.695  0.847  1.0
  Na  Na5  1  0.305  0.254  0.653  1.0
  Mn  Mn6  1  0.671  0.643  0.155  1.0
  Mn  Mn7  1  0.357  0.329  0.345  1.0
  Mn  Mn8  1  0.329  0.357  0.845  1.0
  Mn  Mn9  1  0.643  0.671  0.655  1.0
  Mn  Mn10  1  0.948  0.052  0.250  1.0
  Mn  Mn11  1  0.052  0.948  0.750  1.0
  P  P12  1  0.174  0.141  0.007  1.0
  P  P13  1  0.859  0.826  0.493  1.0
  P  P14  1  0.826  0.859  0.993  1.0
  P  P15  1  0.141  0.174  0.507  1.0
  P  P16  1  0.877  0.886  0.171  1.0
  P  P17  1  0.114  0.123  0.329  1.0
  P  P18  1  0.123  0.114  0.829  1.0
  P  P19  1  0.886  0.877  0.671  1.0
  Cl  Cl20  1  0.458  0.542  0.250  1.0
  Cl  Cl21  1  0.542  0.458  0.750  1.0
  O  O22  1  0.955  0.964  0.146  1.0
  O  O23  1  0.036  0.045  0.354  1.0
  O  O24  1  0.045  0.036  0.854  1.0
  O  O25  1  0.964  0.955  0.646  1.0
  O  O26  1  0.061  0.154  0.951  1.0
  O  O27  1  0.846  0.939  0.549  1.0
  O  O28  1  0.939  0.846  0.049  1.0
  O  O29  1  0.154  0.061  0.451  1.0
  O  O30  1  0.896  0.416  0.290  1.0
  O  O31  1  0.584  0.104  0.210  1.0
  O  O32  1  0.104  0.584  0.710  1.0
  O  O33  1  0.416  0.896  0.790  1.0
  O  O34  1  0.989  0.248  0.116  1.0
  O  O35  1  0.752  0.011  0.384  1.0
  O  O36  1  0.011  0.752  0.884  1.0
  O  O37  1  0.248  0.989  0.616  1.0
  O  O38  1  0.459  0.855  0.023  1.0
  O  O39  1  0.145  0.541  0.477  1.0
  O  O40  1  0.541  0.145  0.977  1.0
  O  O41  1  0.855  0.459  0.523  1.0
  O  O42  1  0.048  0.623  0.244  1.0
  O  O43  1  0.377  0.952  0.256  1.0
  O  O44  1  0.952  0.377  0.756  1.0
  O  O45  1  0.623  0.048  0.744  1.0
  O  O46  1  0.859  0.678  0.072  1.0
  O  O47  1  0.322  0.141  0.428  1.0
  O  O48  1  0.141  0.322  0.928  1.0
  O  O49  1  0.678  0.859  0.572  1.0
[/CIF]
.