The material described by ReC5O5I is Cyanogen Chloride-derived structured and crystallizes in the orthorhombic Cmcm space group. The structure is zero-dimensional and consists of four ReC5O5I clusters. Re(1) is bonded in a distorted square pyramidal geometry to one C(2), four equivalent C(1), and one I(1) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Re(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Re(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. I(1) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF card [CIF]
data_ReC5IO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.781
_cell_length_b   6.781
_cell_length_c   10.994
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   110.325
_symmetry_Int_Tables_number   1
_cell_volume   473.988
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.140  0.860  0.750  1.0
  Re  Re1  1  0.860  0.140  0.250  1.0
  C  C2  1  0.683  0.946  0.122  1.0
  C  C3  1  0.317  0.054  0.622  1.0
  C  C4  1  0.684  0.316  0.250  1.0
  C  C5  1  0.054  0.317  0.378  1.0
  C  C6  1  0.946  0.683  0.622  1.0
  C  C7  1  0.316  0.684  0.750  1.0
  C  C8  1  0.946  0.683  0.878  1.0
  C  C9  1  0.054  0.317  0.122  1.0
  C  C10  1  0.317  0.054  0.878  1.0
  C  C11  1  0.683  0.946  0.378  1.0
  I  I12  1  0.115  0.885  0.250  1.0
  I  I13  1  0.885  0.115  0.750  1.0
  O  O14  1  0.419  0.167  0.550  1.0
  O  O15  1  0.833  0.581  0.950  1.0
  O  O16  1  0.581  0.833  0.450  1.0
  O  O17  1  0.420  0.580  0.750  1.0
  O  O18  1  0.581  0.833  0.050  1.0
  O  O19  1  0.167  0.419  0.050  1.0
  O  O20  1  0.580  0.420  0.250  1.0
  O  O21  1  0.833  0.581  0.550  1.0
  O  O22  1  0.419  0.167  0.950  1.0
  O  O23  1  0.167  0.419  0.450  1.0
[/CIF]
.
The material described by ReC5O5I is Cyanogen Chloride-derived structured and crystallizes in the orthorhombic Cmcm space group. The structure is zero-dimensional and consists of four ReC5O5I clusters. Re(1) is bonded in a distorted square pyramidal geometry to one C(2), four equivalent C(1), and one I(1) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Re(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Re(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. I(1) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF card [CIF]
data_ReC5IO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.781
_cell_length_b   6.781
_cell_length_c   10.994
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   110.325
_symmetry_Int_Tables_number   1
_cell_volume   473.988
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.140  0.860  0.750  1.0
  Re  Re1  1  0.860  0.140  0.250  1.0
  C  C2  1  0.683  0.946  0.122  1.0
  C  C3  1  0.317  0.054  0.622  1.0
  C  C4  1  0.684  0.316  0.250  1.0
  C  C5  1  0.054  0.317  0.378  1.0
  C  C6  1  0.946  0.683  0.622  1.0
  C  C7  1  0.316  0.684  0.750  1.0
  C  C8  1  0.946  0.683  0.878  1.0
  C  C9  1  0.054  0.317  0.122  1.0
  C  C10  1  0.317  0.054  0.878  1.0
  C  C11  1  0.683  0.946  0.378  1.0
  I  I12  1  0.115  0.885  0.250  1.0
  I  I13  1  0.885  0.115  0.750  1.0
  O  O14  1  0.419  0.167  0.550  1.0
  O  O15  1  0.833  0.581  0.950  1.0
  O  O16  1  0.581  0.833  0.450  1.0
  O  O17  1  0.420  0.580  0.750  1.0
  O  O18  1  0.581  0.833  0.050  1.0
  O  O19  1  0.167  0.419  0.050  1.0
  O  O20  1  0.580  0.420  0.250  1.0
  O  O21  1  0.833  0.581  0.550  1.0
  O  O22  1  0.419  0.167  0.950  1.0
  O  O23  1  0.167  0.419  0.450  1.0
[/CIF]
.