The compound described by K3Hg11 crystallizes in the orthorhombic Immm space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 12-coordinate geometry to two equivalent Hg(3), two equivalent Hg(4), four equivalent Hg(2), and six equivalent Hg(1) atoms. In the second K site, K(2) is bonded to four equivalent Hg(1) and eight equivalent Hg(2) atoms to form KHg12 cuboctahedra that share edges with two equivalent Hg(4)K4Hg8 cuboctahedra and faces with two equivalent K(2)Hg12 cuboctahedra. There are four inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a 10-coordinate geometry to one K(2), three equivalent K(1), one Hg(4), two equivalent Hg(3), and three equivalent Hg(2) atoms. In the second Hg site, Hg(2) is bonded in a 9-coordinate geometry to two equivalent K(1), two equivalent K(2), one Hg(2), one Hg(3), and three equivalent Hg(1) atoms. In the third Hg site, Hg(3) is bonded in a 4-coordinate geometry to two equivalent K(1), two equivalent Hg(2), two equivalent Hg(4), and four equivalent Hg(1) atoms. In the fourth Hg site, Hg(4) is bonded to four equivalent K(1), four equivalent Hg(1), and four equivalent Hg(3) atoms to form distorted HgK4Hg8 cuboctahedra that share edges with two equivalent K(2)Hg12 cuboctahedra and faces with two equivalent Hg(4)K4Hg8 cuboctahedra. is represented by the CIF card [CIF]
data_K3Hg11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.094
_cell_length_b   9.635
_cell_length_c   9.635
_cell_angle_alpha   69.981
_cell_angle_beta   74.672
_cell_angle_gamma   74.672
_symmetry_Int_Tables_number   1
_cell_volume   420.546
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.693  0.307  0.307  1.0
  K  K1  1  0.307  0.693  0.693  1.0
  K  K2  1  0.000  0.000  0.000  1.0
  Hg  Hg3  1  0.863  0.422  0.853  1.0
  Hg  Hg4  1  0.665  0.970  0.700  1.0
  Hg  Hg5  1  0.335  0.030  0.300  1.0
  Hg  Hg6  1  0.335  0.300  0.030  1.0
  Hg  Hg7  1  0.665  0.700  0.970  1.0
  Hg  Hg8  1  0.500  0.700  0.300  1.0
  Hg  Hg9  1  0.500  0.300  0.700  1.0
  Hg  Hg10  1  0.000  0.500  0.500  1.0
  Hg  Hg11  1  0.137  0.578  0.147  1.0
  Hg  Hg12  1  0.137  0.147  0.578  1.0
  Hg  Hg13  1  0.863  0.853  0.422  1.0
[/CIF]
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The compound described by K3Hg11 crystallizes in the orthorhombic Immm space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 12-coordinate geometry to two equivalent Hg(3), two equivalent Hg(4), four equivalent Hg(2), and six equivalent Hg(1) atoms. In the second K site, K(2) is bonded to four equivalent Hg(1) and eight equivalent Hg(2) atoms to form KHg12 cuboctahedra that share edges with two equivalent Hg(4)K4Hg8 cuboctahedra and faces with two equivalent K(2)Hg12 cuboctahedra. There are four inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a 10-coordinate geometry to one K(2), three equivalent K(1), one Hg(4), two equivalent Hg(3), and three equivalent Hg(2) atoms. In the second Hg site, Hg(2) is bonded in a 9-coordinate geometry to two equivalent K(1), two equivalent K(2), one Hg(2), one Hg(3), and three equivalent Hg(1) atoms. In the third Hg site, Hg(3) is bonded in a 4-coordinate geometry to two equivalent K(1), two equivalent Hg(2), two equivalent Hg(4), and four equivalent Hg(1) atoms. In the fourth Hg site, Hg(4) is bonded to four equivalent K(1), four equivalent Hg(1), and four equivalent Hg(3) atoms to form distorted HgK4Hg8 cuboctahedra that share edges with two equivalent K(2)Hg12 cuboctahedra and faces with two equivalent Hg(4)K4Hg8 cuboctahedra. is represented by the CIF card [CIF]
data_K3Hg11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.094
_cell_length_b   9.635
_cell_length_c   9.635
_cell_angle_alpha   69.981
_cell_angle_beta   74.672
_cell_angle_gamma   74.672
_symmetry_Int_Tables_number   1
_cell_volume   420.546
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.693  0.307  0.307  1.0
  K  K1  1  0.307  0.693  0.693  1.0
  K  K2  1  0.000  0.000  0.000  1.0
  Hg  Hg3  1  0.863  0.422  0.853  1.0
  Hg  Hg4  1  0.665  0.970  0.700  1.0
  Hg  Hg5  1  0.335  0.030  0.300  1.0
  Hg  Hg6  1  0.335  0.300  0.030  1.0
  Hg  Hg7  1  0.665  0.700  0.970  1.0
  Hg  Hg8  1  0.500  0.700  0.300  1.0
  Hg  Hg9  1  0.500  0.300  0.700  1.0
  Hg  Hg10  1  0.000  0.500  0.500  1.0
  Hg  Hg11  1  0.137  0.578  0.147  1.0
  Hg  Hg12  1  0.137  0.147  0.578  1.0
  Hg  Hg13  1  0.863  0.853  0.422  1.0
[/CIF]
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