The crystal structure described by LiAgF4 crystallizes in the orthorhombic Pbcn space group. Li(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form LiF6 octahedra that share corners with six equivalent Ag(1)F6 octahedra,  an edgeedge with one Ag(1)F6 octahedra, and edges with two equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 51-64°. Ag(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form distorted AgF6 octahedra that share corners with four equivalent Ag(1)F6 octahedra, corners with six equivalent Li(1)F6 octahedra, and  an edgeedge with one Li(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 44-64°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Li(1) and two equivalent Ag(1) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to two equivalent Li(1) and one Ag(1) atom. is represented by the CIF file [CIF]
data_LiAgF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.702
_cell_length_b   5.424
_cell_length_c   11.096
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   283.000
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.250  0.066  1.0
  Li  Li1  1  0.000  0.750  0.934  1.0
  Li  Li2  1  0.500  0.250  0.566  1.0
  Li  Li3  1  0.500  0.750  0.434  1.0
  Ag  Ag4  1  0.000  0.250  0.335  1.0
  Ag  Ag5  1  0.000  0.750  0.665  1.0
  Ag  Ag6  1  0.500  0.250  0.835  1.0
  Ag  Ag7  1  0.500  0.750  0.165  1.0
  F  F8  1  0.227  0.379  0.204  1.0
  F  F9  1  0.227  0.879  0.796  1.0
  F  F10  1  0.246  0.907  0.048  1.0
  F  F11  1  0.246  0.407  0.952  1.0
  F  F12  1  0.254  0.407  0.452  1.0
  F  F13  1  0.254  0.907  0.548  1.0
  F  F14  1  0.273  0.879  0.296  1.0
  F  F15  1  0.273  0.379  0.704  1.0
  F  F16  1  0.727  0.621  0.296  1.0
  F  F17  1  0.727  0.121  0.704  1.0
  F  F18  1  0.746  0.093  0.452  1.0
  F  F19  1  0.746  0.593  0.548  1.0
  F  F20  1  0.754  0.593  0.048  1.0
  F  F21  1  0.754  0.093  0.952  1.0
  F  F22  1  0.773  0.121  0.204  1.0
  F  F23  1  0.773  0.621  0.796  1.0
[/CIF]
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The crystal structure described by LiAgF4 crystallizes in the orthorhombic Pbcn space group. Li(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form LiF6 octahedra that share corners with six equivalent Ag(1)F6 octahedra,  an edgeedge with one Ag(1)F6 octahedra, and edges with two equivalent Li(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 51-64°. Ag(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form distorted AgF6 octahedra that share corners with four equivalent Ag(1)F6 octahedra, corners with six equivalent Li(1)F6 octahedra, and  an edgeedge with one Li(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 44-64°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Li(1) and two equivalent Ag(1) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to two equivalent Li(1) and one Ag(1) atom. is represented by the CIF file [CIF]
data_LiAgF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.702
_cell_length_b   5.424
_cell_length_c   11.096
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   283.000
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.250  0.066  1.0
  Li  Li1  1  0.000  0.750  0.934  1.0
  Li  Li2  1  0.500  0.250  0.566  1.0
  Li  Li3  1  0.500  0.750  0.434  1.0
  Ag  Ag4  1  0.000  0.250  0.335  1.0
  Ag  Ag5  1  0.000  0.750  0.665  1.0
  Ag  Ag6  1  0.500  0.250  0.835  1.0
  Ag  Ag7  1  0.500  0.750  0.165  1.0
  F  F8  1  0.227  0.379  0.204  1.0
  F  F9  1  0.227  0.879  0.796  1.0
  F  F10  1  0.246  0.907  0.048  1.0
  F  F11  1  0.246  0.407  0.952  1.0
  F  F12  1  0.254  0.407  0.452  1.0
  F  F13  1  0.254  0.907  0.548  1.0
  F  F14  1  0.273  0.879  0.296  1.0
  F  F15  1  0.273  0.379  0.704  1.0
  F  F16  1  0.727  0.621  0.296  1.0
  F  F17  1  0.727  0.121  0.704  1.0
  F  F18  1  0.746  0.093  0.452  1.0
  F  F19  1  0.746  0.593  0.548  1.0
  F  F20  1  0.754  0.593  0.048  1.0
  F  F21  1  0.754  0.093  0.952  1.0
  F  F22  1  0.773  0.121  0.204  1.0
  F  F23  1  0.773  0.621  0.796  1.0
[/CIF]
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