The material described by Cs2MoF6Hg crystallizes in the cubic Fm-3m space group. The structure consists of four 7439-97-6 atoms inside a Cs2MoF6 framework. In the Cs2MoF6 framework, Cs(1) is bonded to twelve equivalent F(1) atoms to form distorted CsF12 cuboctahedra that share corners with twelve equivalent Cs(1)F12 cuboctahedra, faces with six equivalent Cs(1)F12 cuboctahedra, and faces with four equivalent Mo(1)F6 octahedra. Mo(1) is bonded to six equivalent F(1) atoms to form MoF6 octahedra that share faces with eight equivalent Cs(1)F12 cuboctahedra. F(1) is bonded in a single-bond geometry to four equivalent Cs(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_Cs2HgMoF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.077
_cell_length_b   7.077
_cell_length_c   7.077
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   250.601
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.250  0.250  0.250  1.0
  Cs  Cs1  1  0.750  0.750  0.750  1.0
  Hg  Hg2  1  0.500  0.500  0.500  1.0
  Mo  Mo3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.198  0.802  0.198  1.0
  F  F5  1  0.802  0.802  0.198  1.0
  F  F6  1  0.802  0.198  0.802  1.0
  F  F7  1  0.802  0.198  0.198  1.0
  F  F8  1  0.198  0.802  0.802  1.0
  F  F9  1  0.198  0.198  0.802  1.0
[/CIF]
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The material described by Cs2MoF6Hg crystallizes in the cubic Fm-3m space group. The structure consists of four 7439-97-6 atoms inside a Cs2MoF6 framework. In the Cs2MoF6 framework, Cs(1) is bonded to twelve equivalent F(1) atoms to form distorted CsF12 cuboctahedra that share corners with twelve equivalent Cs(1)F12 cuboctahedra, faces with six equivalent Cs(1)F12 cuboctahedra, and faces with four equivalent Mo(1)F6 octahedra. Mo(1) is bonded to six equivalent F(1) atoms to form MoF6 octahedra that share faces with eight equivalent Cs(1)F12 cuboctahedra. F(1) is bonded in a single-bond geometry to four equivalent Cs(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_Cs2HgMoF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.077
_cell_length_b   7.077
_cell_length_c   7.077
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   250.601
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.250  0.250  0.250  1.0
  Cs  Cs1  1  0.750  0.750  0.750  1.0
  Hg  Hg2  1  0.500  0.500  0.500  1.0
  Mo  Mo3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.198  0.802  0.198  1.0
  F  F5  1  0.802  0.802  0.198  1.0
  F  F6  1  0.802  0.198  0.802  1.0
  F  F7  1  0.802  0.198  0.198  1.0
  F  F8  1  0.198  0.802  0.802  1.0
  F  F9  1  0.198  0.198  0.802  1.0
[/CIF]
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