The structure described by La3MnGaS7 crystallizes in the hexagonal P6_3 space group. La(1) is bonded in a 8-coordinate geometry to one S(3), three equivalent S(2), and four equivalent S(1) atoms. Mn(1) is bonded to six equivalent S(1) atoms to form face-sharing MnS6 octahedra. Ga(1) is bonded in a tetrahedral geometry to one S(3) and three equivalent S(2) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 6-coordinate geometry to four equivalent La(1) and two equivalent Mn(1) atoms. In the second S site, S(2) is bonded in a rectangular see-saw-like geometry to three equivalent La(1) and one Ga(1) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to three equivalent La(1) and one Ga(1) atom. is represented by the CIF file [CIF]
data_La3MnGaS7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.265
_cell_length_b   10.265
_cell_length_c   6.075
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   554.338
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.139  0.374  0.001  1.0
  La  La1  1  0.765  0.139  0.501  1.0
  La  La2  1  0.374  0.235  0.501  1.0
  La  La3  1  0.626  0.765  0.001  1.0
  La  La4  1  0.235  0.861  0.001  1.0
  La  La5  1  0.861  0.626  0.501  1.0
  Mn  Mn6  1  0.000  0.000  0.227  1.0
  Mn  Mn7  1  0.000  0.000  0.727  1.0
  Ga  Ga8  1  0.667  0.333  0.081  1.0
  Ga  Ga9  1  0.333  0.667  0.581  1.0
  S  S10  1  0.235  0.146  0.965  1.0
  S  S11  1  0.088  0.235  0.465  1.0
  S  S12  1  0.146  0.912  0.465  1.0
  S  S13  1  0.854  0.088  0.965  1.0
  S  S14  1  0.912  0.765  0.965  1.0
  S  S15  1  0.765  0.854  0.465  1.0
  S  S16  1  0.517  0.099  0.231  1.0
  S  S17  1  0.418  0.517  0.731  1.0
  S  S18  1  0.099  0.582  0.731  1.0
  S  S19  1  0.901  0.418  0.231  1.0
  S  S20  1  0.582  0.483  0.231  1.0
  S  S21  1  0.483  0.901  0.731  1.0
  S  S22  1  0.333  0.667  0.210  1.0
  S  S23  1  0.667  0.333  0.710  1.0
[/CIF]
.
The structure described by La3MnGaS7 crystallizes in the hexagonal P6_3 space group. La(1) is bonded in a 8-coordinate geometry to one S(3), three equivalent S(2), and four equivalent S(1) atoms. Mn(1) is bonded to six equivalent S(1) atoms to form face-sharing MnS6 octahedra. Ga(1) is bonded in a tetrahedral geometry to one S(3) and three equivalent S(2) atoms. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 6-coordinate geometry to four equivalent La(1) and two equivalent Mn(1) atoms. In the second S site, S(2) is bonded in a rectangular see-saw-like geometry to three equivalent La(1) and one Ga(1) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to three equivalent La(1) and one Ga(1) atom. is represented by the CIF file [CIF]
data_La3MnGaS7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.265
_cell_length_b   10.265
_cell_length_c   6.075
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   554.338
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.139  0.374  0.001  1.0
  La  La1  1  0.765  0.139  0.501  1.0
  La  La2  1  0.374  0.235  0.501  1.0
  La  La3  1  0.626  0.765  0.001  1.0
  La  La4  1  0.235  0.861  0.001  1.0
  La  La5  1  0.861  0.626  0.501  1.0
  Mn  Mn6  1  0.000  0.000  0.227  1.0
  Mn  Mn7  1  0.000  0.000  0.727  1.0
  Ga  Ga8  1  0.667  0.333  0.081  1.0
  Ga  Ga9  1  0.333  0.667  0.581  1.0
  S  S10  1  0.235  0.146  0.965  1.0
  S  S11  1  0.088  0.235  0.465  1.0
  S  S12  1  0.146  0.912  0.465  1.0
  S  S13  1  0.854  0.088  0.965  1.0
  S  S14  1  0.912  0.765  0.965  1.0
  S  S15  1  0.765  0.854  0.465  1.0
  S  S16  1  0.517  0.099  0.231  1.0
  S  S17  1  0.418  0.517  0.731  1.0
  S  S18  1  0.099  0.582  0.731  1.0
  S  S19  1  0.901  0.418  0.231  1.0
  S  S20  1  0.582  0.483  0.231  1.0
  S  S21  1  0.483  0.901  0.731  1.0
  S  S22  1  0.333  0.667  0.210  1.0
  S  S23  1  0.667  0.333  0.710  1.0
[/CIF]
.