The crystal structure described by (Ce(SO4)2)2N2 crystallizes in the monoclinic P2_1/m space group. The structure consists of two ammonia atoms inside a Ce(SO4)2 framework. In the Ce(SO4)2 framework, Ce(1) is bonded in a 9-coordinate geometry to one O(3), one O(4), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(6) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(3), one O(4), and two equivalent O(2) atoms. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(1), one O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Ce(1) and one S(2) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(1) atom. In the third O site, O(3) is bonded in a linear geometry to one Ce(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Ce(1) and one S(2) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Ce(1) and one S(2) atom. is represented by the CIF file [CIF]
data_CeS2NO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.348
_cell_length_b   7.016
_cell_length_c   9.128
_cell_angle_alpha   80.345
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   337.688
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.250  0.196  0.228  1.0
  Ce  Ce1  1  0.750  0.804  0.772  1.0
  S  S2  1  0.250  0.725  0.065  1.0
  S  S3  1  0.750  0.275  0.935  1.0
  S  S4  1  0.250  0.812  0.576  1.0
  S  S5  1  0.750  0.188  0.424  1.0
  N  N6  1  0.250  0.317  0.693  1.0
  N  N7  1  0.750  0.683  0.307  1.0
  O  O8  1  0.250  0.924  0.702  1.0
  O  O9  1  0.750  0.076  0.298  1.0
  O  O10  1  0.978  0.277  0.030  1.0
  O  O11  1  0.022  0.723  0.970  1.0
  O  O12  1  0.478  0.723  0.970  1.0
  O  O13  1  0.522  0.277  0.030  1.0
  O  O14  1  0.250  0.904  0.131  1.0
  O  O15  1  0.750  0.096  0.869  1.0
  O  O16  1  0.250  0.552  0.181  1.0
  O  O17  1  0.750  0.448  0.819  1.0
  O  O18  1  0.250  0.938  0.428  1.0
  O  O19  1  0.750  0.062  0.572  1.0
  O  O20  1  0.481  0.692  0.592  1.0
  O  O21  1  0.519  0.308  0.408  1.0
  O  O22  1  0.981  0.308  0.408  1.0
  O  O23  1  0.019  0.692  0.592  1.0
[/CIF]
.
The crystal structure described by (Ce(SO4)2)2N2 crystallizes in the monoclinic P2_1/m space group. The structure consists of two ammonia atoms inside a Ce(SO4)2 framework. In the Ce(SO4)2 framework, Ce(1) is bonded in a 9-coordinate geometry to one O(3), one O(4), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(6) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(3), one O(4), and two equivalent O(2) atoms. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(1), one O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Ce(1) and one S(2) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(1) atom. In the third O site, O(3) is bonded in a linear geometry to one Ce(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Ce(1) and one S(2) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Ce(1) and one S(2) atom. is represented by the CIF file [CIF]
data_CeS2NO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.348
_cell_length_b   7.016
_cell_length_c   9.128
_cell_angle_alpha   80.345
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   337.688
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.250  0.196  0.228  1.0
  Ce  Ce1  1  0.750  0.804  0.772  1.0
  S  S2  1  0.250  0.725  0.065  1.0
  S  S3  1  0.750  0.275  0.935  1.0
  S  S4  1  0.250  0.812  0.576  1.0
  S  S5  1  0.750  0.188  0.424  1.0
  N  N6  1  0.250  0.317  0.693  1.0
  N  N7  1  0.750  0.683  0.307  1.0
  O  O8  1  0.250  0.924  0.702  1.0
  O  O9  1  0.750  0.076  0.298  1.0
  O  O10  1  0.978  0.277  0.030  1.0
  O  O11  1  0.022  0.723  0.970  1.0
  O  O12  1  0.478  0.723  0.970  1.0
  O  O13  1  0.522  0.277  0.030  1.0
  O  O14  1  0.250  0.904  0.131  1.0
  O  O15  1  0.750  0.096  0.869  1.0
  O  O16  1  0.250  0.552  0.181  1.0
  O  O17  1  0.750  0.448  0.819  1.0
  O  O18  1  0.250  0.938  0.428  1.0
  O  O19  1  0.750  0.062  0.572  1.0
  O  O20  1  0.481  0.692  0.592  1.0
  O  O21  1  0.519  0.308  0.408  1.0
  O  O22  1  0.981  0.308  0.408  1.0
  O  O23  1  0.019  0.692  0.592  1.0
[/CIF]
.