The structure described by AgFAsF6 crystallizes in the orthorhombic Pnma space group. Ag(1) is bonded to one F(3), two equivalent F(1), two equivalent F(2), and two equivalent F(5) atoms to form AgF7 pentagonal bipyramids that share corners with three equivalent As(1)F6 octahedra, corners with two equivalent Ag(1)F7 pentagonal bipyramids, and  an edgeedge with one As(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 32-40°. As(1) is bonded to one F(3), one F(4), two equivalent F(1), and two equivalent F(5) atoms to form AsF6 octahedra that share corners with three equivalent Ag(1)F7 pentagonal bipyramids and  an edgeedge with one Ag(1)F7 pentagonal bipyramid. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Ag(1) and one As(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Ag(1) atoms. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a distorted water-like geometry to one Ag(1) and one As(1) atom. is represented by the CIF file [CIF]
data_AgAsF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.980
_cell_length_b   7.703
_cell_length_c   9.774
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   525.504
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.250  0.635  0.742  1.0
  Ag  Ag1  1  0.750  0.365  0.258  1.0
  Ag  Ag2  1  0.250  0.135  0.758  1.0
  Ag  Ag3  1  0.750  0.865  0.242  1.0
  As  As4  1  0.250  0.800  0.060  1.0
  As  As5  1  0.750  0.200  0.940  1.0
  As  As6  1  0.250  0.300  0.440  1.0
  As  As7  1  0.750  0.700  0.560  1.0
  F  F8  1  0.927  0.125  0.828  1.0
  F  F9  1  0.427  0.875  0.172  1.0
  F  F10  1  0.573  0.625  0.672  1.0
  F  F11  1  0.073  0.375  0.328  1.0
  F  F12  1  0.073  0.875  0.172  1.0
  F  F13  1  0.573  0.125  0.828  1.0
  F  F14  1  0.427  0.375  0.328  1.0
  F  F15  1  0.927  0.625  0.672  1.0
  F  F16  1  0.750  0.612  0.193  1.0
  F  F17  1  0.250  0.388  0.807  1.0
  F  F18  1  0.750  0.112  0.307  1.0
  F  F19  1  0.250  0.888  0.693  1.0
  F  F20  1  0.750  0.493  0.482  1.0
  F  F21  1  0.250  0.507  0.518  1.0
  F  F22  1  0.750  0.993  0.018  1.0
  F  F23  1  0.250  0.007  0.982  1.0
  F  F24  1  0.750  0.900  0.635  1.0
  F  F25  1  0.250  0.100  0.365  1.0
  F  F26  1  0.750  0.400  0.865  1.0
  F  F27  1  0.250  0.600  0.135  1.0
  F  F28  1  0.925  0.767  0.442  1.0
  F  F29  1  0.425  0.233  0.558  1.0
  F  F30  1  0.575  0.267  0.058  1.0
  F  F31  1  0.075  0.733  0.942  1.0
  F  F32  1  0.075  0.233  0.558  1.0
  F  F33  1  0.575  0.767  0.442  1.0
  F  F34  1  0.425  0.733  0.942  1.0
  F  F35  1  0.925  0.267  0.058  1.0
[/CIF]
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The structure described by AgFAsF6 crystallizes in the orthorhombic Pnma space group. Ag(1) is bonded to one F(3), two equivalent F(1), two equivalent F(2), and two equivalent F(5) atoms to form AgF7 pentagonal bipyramids that share corners with three equivalent As(1)F6 octahedra, corners with two equivalent Ag(1)F7 pentagonal bipyramids, and  an edgeedge with one As(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 32-40°. As(1) is bonded to one F(3), one F(4), two equivalent F(1), and two equivalent F(5) atoms to form AsF6 octahedra that share corners with three equivalent Ag(1)F7 pentagonal bipyramids and  an edgeedge with one Ag(1)F7 pentagonal bipyramid. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Ag(1) and one As(1) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Ag(1) atoms. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a distorted water-like geometry to one Ag(1) and one As(1) atom. is represented by the CIF file [CIF]
data_AgAsF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.980
_cell_length_b   7.703
_cell_length_c   9.774
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   525.504
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.250  0.635  0.742  1.0
  Ag  Ag1  1  0.750  0.365  0.258  1.0
  Ag  Ag2  1  0.250  0.135  0.758  1.0
  Ag  Ag3  1  0.750  0.865  0.242  1.0
  As  As4  1  0.250  0.800  0.060  1.0
  As  As5  1  0.750  0.200  0.940  1.0
  As  As6  1  0.250  0.300  0.440  1.0
  As  As7  1  0.750  0.700  0.560  1.0
  F  F8  1  0.927  0.125  0.828  1.0
  F  F9  1  0.427  0.875  0.172  1.0
  F  F10  1  0.573  0.625  0.672  1.0
  F  F11  1  0.073  0.375  0.328  1.0
  F  F12  1  0.073  0.875  0.172  1.0
  F  F13  1  0.573  0.125  0.828  1.0
  F  F14  1  0.427  0.375  0.328  1.0
  F  F15  1  0.927  0.625  0.672  1.0
  F  F16  1  0.750  0.612  0.193  1.0
  F  F17  1  0.250  0.388  0.807  1.0
  F  F18  1  0.750  0.112  0.307  1.0
  F  F19  1  0.250  0.888  0.693  1.0
  F  F20  1  0.750  0.493  0.482  1.0
  F  F21  1  0.250  0.507  0.518  1.0
  F  F22  1  0.750  0.993  0.018  1.0
  F  F23  1  0.250  0.007  0.982  1.0
  F  F24  1  0.750  0.900  0.635  1.0
  F  F25  1  0.250  0.100  0.365  1.0
  F  F26  1  0.750  0.400  0.865  1.0
  F  F27  1  0.250  0.600  0.135  1.0
  F  F28  1  0.925  0.767  0.442  1.0
  F  F29  1  0.425  0.233  0.558  1.0
  F  F30  1  0.575  0.267  0.058  1.0
  F  F31  1  0.075  0.733  0.942  1.0
  F  F32  1  0.075  0.233  0.558  1.0
  F  F33  1  0.575  0.767  0.442  1.0
  F  F34  1  0.425  0.733  0.942  1.0
  F  F35  1  0.925  0.267  0.058  1.0
[/CIF]
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