The material structure described by U7V5Ag3O35 crystallizes in the monoclinic Pm space group. There are seven inequivalent U sites. In the first U site, U(1) is bonded to one O(12), one O(14), one O(27), two equivalent O(1), and two equivalent O(10) atoms to form distorted UO7 pentagonal bipyramids that share  a cornercorner with one U(6)O6 octahedra, corners with two equivalent V(4)O4 tetrahedra, and  an edgeedge with one V(1)O4 tetrahedra. The corner-sharing octahedra are not tilted. In the second U site, U(2) is bonded to one O(11), one O(2), one O(28), one O(3), one O(9), and two equivalent O(13) atoms to form distorted UO7 pentagonal bipyramids that share  a cornercorner with one U(7)O6 octahedra, corners with two equivalent V(3)O4 tetrahedra, and  an edgeedge with one V(2)O4 tetrahedra. The corner-sharing octahedra are not tilted. In the third U site, U(3) is bonded in a 7-coordinate geometry to one O(11), one O(2), one O(26), one O(3), one O(9), and two equivalent O(4) atoms. In the fourth U site, U(4) is bonded in a 7-coordinate geometry to one O(26), one O(5), one O(6), two equivalent O(1), and two equivalent O(10) atoms. In the fifth U site, U(5) is bonded to one O(21), one O(22), one O(23), one O(25), and two equivalent O(24) atoms to form UO6 octahedra that share corners with two equivalent V(1)O4 tetrahedra and corners with two equivalent V(2)O4 tetrahedra. In the sixth U site, U(6) is bonded to one O(16), one O(17), one O(27), one O(7), and two equivalent O(18) atoms to form UO6 octahedra that share  a cornercorner with one U(1)O7 pentagonal bipyramid, corners with two equivalent V(3)O4 tetrahedra, and corners with two equivalent V(5)O4 tetrahedra. In the seventh U site, U(7) is bonded to one O(28); one O(8); two equivalent O(15); and two equivalent O(19,20) atoms to form UO6 octahedra that share  a cornercorner with one U(2)O7 pentagonal bipyramid, corners with two equivalent V(4)O4 tetrahedra, and corners with two equivalent V(5)O4 tetrahedra. There are five inequivalent V sites. In the first V site, V(1) is bonded to one O(23), one O(25), and two equivalent O(1) atoms to form VO4 tetrahedra that share corners with two equivalent U(5)O6 octahedra and  an edgeedge with one U(1)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles are 34°. In the second V site, V(2) is bonded to one O(2), one O(3), and two equivalent O(24) atoms to form VO4 tetrahedra that share corners with two equivalent U(5)O6 octahedra and  an edgeedge with one U(2)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles are 36°. In the third V site, V(3) is bonded to one O(11), one O(9), and two equivalent O(18) atoms to form VO4 tetrahedra that share corners with two equivalent U(6)O6 octahedra and corners with two equivalent U(2)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 30°. In the fourth V site, V(4) is bonded to two equivalent O(10) and two equivalent O(19,20) atoms to form VO4 tetrahedra that share corners with two equivalent U(7)O6 octahedra and corners with two equivalent U(1)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 30°. In the fifth V site, V(5) is bonded to one O(16), one O(17), and two equivalent O(15) atoms to form VO4 tetrahedra that share corners with two equivalent U(6)O6 octahedra and corners with two equivalent U(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-34°. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(21), one O(5), one O(6), and one O(8) atom. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one O(22), one O(7), and two equivalent O(4) atoms. There are twenty-seven inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one U(1), one U(4), and one V(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one U(2), one U(3), and one V(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one U(2), one U(3), and one V(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one U(3) and one Ag(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one U(4) and two equivalent Ag(1) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one U(4) and two equivalent Ag(1) atoms. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one U(6) and one Ag(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one U(7) and two equivalent Ag(1) atoms. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one U(2), one U(3), and one V(3) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one U(1), one U(4), and one V(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one U(2), one U(3), and one V(3) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one U(1) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one U(2) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one U(1) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one U(7) and one V(5) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one U(6) and one V(5) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one U(6) and one V(5) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one U(6) and one V(3) atom. In the nineteenth O site, O(19,20) is bonded in a bent 150 degrees geometry to one U(7) and one V(4) atom. In the twentieth O site, O(21) is bonded in a trigonal planar geometry to one U(5) and two equivalent Ag(1) atoms. In the twenty-first O site, O(22) is bonded in a bent 120 degrees geometry to one U(5) and one Ag(2) atom. In the twenty-second O site, O(23) is bonded in a bent 150 degrees geometry to one U(5) and one V(1) atom. In the twenty-third O site, O(24) is bonded in a bent 150 degrees geometry to one U(5) and one V(2) atom. In the twenty-fourth O site, O(25) is bonded in a bent 150 degrees geometry to one U(5) and one V(1) atom. In the twenty-fifth O site, O(26) is bonded in a linear geometry to one U(3) and one U(4) atom. In the twenty-sixth O site, O(27) is bonded in a linear geometry to one U(1) and one U(6) atom. In the twenty-seventh O site, O(28) is bonded in a linear geometry to one U(2) and one U(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_U7V5Ag3O35
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.336
_cell_length_b   7.367
_cell_length_c   15.050
_cell_angle_alpha   89.996
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   813.390
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.500  0.000  0.276  1.0
  U  U1  1  0.000  0.499  0.725  1.0
  U  U2  1  0.000  0.000  0.856  1.0
  U  U3  1  0.000  0.000  0.142  1.0
  U  U4  1  0.500  0.499  0.999  1.0
  U  U5  1  0.500  0.000  0.562  1.0
  U  U6  1  0.000  0.500  0.438  1.0
  V  V7  1  0.500  1.000  0.056  1.0
  V  V8  1  0.000  0.500  0.943  1.0
  V  V9  1  0.000  0.000  0.633  1.0
  V  V10  1  0.000  1.000  0.367  1.0
  V  V11  1  0.500  0.500  0.500  1.0
  Ag  Ag12  1  0.233  0.500  0.208  1.0
  Ag  Ag13  1  0.500  0.770  0.792  1.0
  Ag  Ag14  1  0.767  0.500  0.208  1.0
  O  O15  1  0.322  1.000  0.134  1.0
  O  O16  1  0.000  0.677  0.867  1.0
  O  O17  1  0.678  1.000  0.134  1.0
  O  O18  1  0.000  0.322  0.867  1.0
  O  O19  1  0.752  0.996  0.850  1.0
  O  O20  1  0.000  0.251  0.151  1.0
  O  O21  1  0.248  0.996  0.850  1.0
  O  O22  1  0.000  0.749  0.151  1.0
  O  O23  1  0.500  0.992  0.685  1.0
  O  O24  1  0.000  0.500  0.312  1.0
  O  O25  1  0.000  0.820  0.707  1.0
  O  O26  1  0.818  0.000  0.293  1.0
  O  O27  1  0.000  0.181  0.707  1.0
  O  O28  1  0.182  0.000  0.293  1.0
  O  O29  1  0.500  0.753  0.274  1.0
  O  O30  1  0.754  0.503  0.725  1.0
  O  O31  1  0.500  0.247  0.274  1.0
  O  O32  1  0.246  0.503  0.725  1.0
  O  O33  1  0.701  0.500  0.436  1.0
  O  O34  1  0.500  0.303  0.563  1.0
  O  O35  1  0.299  0.500  0.436  1.0
  O  O36  1  0.500  0.697  0.563  1.0
  O  O37  1  0.801  1.000  0.569  1.0
  O  O38  1  0.000  0.199  0.430  1.0
  O  O39  1  0.199  1.000  0.569  1.0
  O  O40  1  0.000  0.801  0.430  1.0
  O  O41  1  0.500  0.499  0.125  1.0
  O  O42  1  0.500  0.508  0.876  1.0
  O  O43  1  0.500  0.802  0.995  1.0
  O  O44  1  0.802  0.500  0.006  1.0
  O  O45  1  0.500  0.198  0.995  1.0
  O  O46  1  0.198  0.500  0.006  1.0
  O  O47  1  0.000  0.000  0.002  1.0
  O  O48  1  0.500  0.001  0.433  1.0
  O  O49  1  0.000  0.500  0.566  1.0
[/CIF]
.
The material structure described by U7V5Ag3O35 crystallizes in the monoclinic Pm space group. There are seven inequivalent U sites. In the first U site, U(1) is bonded to one O(12), one O(14), one O(27), two equivalent O(1), and two equivalent O(10) atoms to form distorted UO7 pentagonal bipyramids that share  a cornercorner with one U(6)O6 octahedra, corners with two equivalent V(4)O4 tetrahedra, and  an edgeedge with one V(1)O4 tetrahedra. The corner-sharing octahedra are not tilted. In the second U site, U(2) is bonded to one O(11), one O(2), one O(28), one O(3), one O(9), and two equivalent O(13) atoms to form distorted UO7 pentagonal bipyramids that share  a cornercorner with one U(7)O6 octahedra, corners with two equivalent V(3)O4 tetrahedra, and  an edgeedge with one V(2)O4 tetrahedra. The corner-sharing octahedra are not tilted. In the third U site, U(3) is bonded in a 7-coordinate geometry to one O(11), one O(2), one O(26), one O(3), one O(9), and two equivalent O(4) atoms. In the fourth U site, U(4) is bonded in a 7-coordinate geometry to one O(26), one O(5), one O(6), two equivalent O(1), and two equivalent O(10) atoms. In the fifth U site, U(5) is bonded to one O(21), one O(22), one O(23), one O(25), and two equivalent O(24) atoms to form UO6 octahedra that share corners with two equivalent V(1)O4 tetrahedra and corners with two equivalent V(2)O4 tetrahedra. In the sixth U site, U(6) is bonded to one O(16), one O(17), one O(27), one O(7), and two equivalent O(18) atoms to form UO6 octahedra that share  a cornercorner with one U(1)O7 pentagonal bipyramid, corners with two equivalent V(3)O4 tetrahedra, and corners with two equivalent V(5)O4 tetrahedra. In the seventh U site, U(7) is bonded to one O(28); one O(8); two equivalent O(15); and two equivalent O(19,20) atoms to form UO6 octahedra that share  a cornercorner with one U(2)O7 pentagonal bipyramid, corners with two equivalent V(4)O4 tetrahedra, and corners with two equivalent V(5)O4 tetrahedra. There are five inequivalent V sites. In the first V site, V(1) is bonded to one O(23), one O(25), and two equivalent O(1) atoms to form VO4 tetrahedra that share corners with two equivalent U(5)O6 octahedra and  an edgeedge with one U(1)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles are 34°. In the second V site, V(2) is bonded to one O(2), one O(3), and two equivalent O(24) atoms to form VO4 tetrahedra that share corners with two equivalent U(5)O6 octahedra and  an edgeedge with one U(2)O7 pentagonal bipyramid. The corner-sharing octahedral tilt angles are 36°. In the third V site, V(3) is bonded to one O(11), one O(9), and two equivalent O(18) atoms to form VO4 tetrahedra that share corners with two equivalent U(6)O6 octahedra and corners with two equivalent U(2)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 30°. In the fourth V site, V(4) is bonded to two equivalent O(10) and two equivalent O(19,20) atoms to form VO4 tetrahedra that share corners with two equivalent U(7)O6 octahedra and corners with two equivalent U(1)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 30°. In the fifth V site, V(5) is bonded to one O(16), one O(17), and two equivalent O(15) atoms to form VO4 tetrahedra that share corners with two equivalent U(6)O6 octahedra and corners with two equivalent U(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-34°. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(21), one O(5), one O(6), and one O(8) atom. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one O(22), one O(7), and two equivalent O(4) atoms. There are twenty-seven inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one U(1), one U(4), and one V(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one U(2), one U(3), and one V(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one U(2), one U(3), and one V(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one U(3) and one Ag(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one U(4) and two equivalent Ag(1) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one U(4) and two equivalent Ag(1) atoms. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one U(6) and one Ag(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one U(7) and two equivalent Ag(1) atoms. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one U(2), one U(3), and one V(3) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one U(1), one U(4), and one V(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one U(2), one U(3), and one V(3) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one U(1) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one U(2) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one U(1) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one U(7) and one V(5) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one U(6) and one V(5) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one U(6) and one V(5) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one U(6) and one V(3) atom. In the nineteenth O site, O(19,20) is bonded in a bent 150 degrees geometry to one U(7) and one V(4) atom. In the twentieth O site, O(21) is bonded in a trigonal planar geometry to one U(5) and two equivalent Ag(1) atoms. In the twenty-first O site, O(22) is bonded in a bent 120 degrees geometry to one U(5) and one Ag(2) atom. In the twenty-second O site, O(23) is bonded in a bent 150 degrees geometry to one U(5) and one V(1) atom. In the twenty-third O site, O(24) is bonded in a bent 150 degrees geometry to one U(5) and one V(2) atom. In the twenty-fourth O site, O(25) is bonded in a bent 150 degrees geometry to one U(5) and one V(1) atom. In the twenty-fifth O site, O(26) is bonded in a linear geometry to one U(3) and one U(4) atom. In the twenty-sixth O site, O(27) is bonded in a linear geometry to one U(1) and one U(6) atom. In the twenty-seventh O site, O(28) is bonded in a linear geometry to one U(2) and one U(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_U7V5Ag3O35
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.336
_cell_length_b   7.367
_cell_length_c   15.050
_cell_angle_alpha   89.996
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   813.390
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.500  0.000  0.276  1.0
  U  U1  1  0.000  0.499  0.725  1.0
  U  U2  1  0.000  0.000  0.856  1.0
  U  U3  1  0.000  0.000  0.142  1.0
  U  U4  1  0.500  0.499  0.999  1.0
  U  U5  1  0.500  0.000  0.562  1.0
  U  U6  1  0.000  0.500  0.438  1.0
  V  V7  1  0.500  1.000  0.056  1.0
  V  V8  1  0.000  0.500  0.943  1.0
  V  V9  1  0.000  0.000  0.633  1.0
  V  V10  1  0.000  1.000  0.367  1.0
  V  V11  1  0.500  0.500  0.500  1.0
  Ag  Ag12  1  0.233  0.500  0.208  1.0
  Ag  Ag13  1  0.500  0.770  0.792  1.0
  Ag  Ag14  1  0.767  0.500  0.208  1.0
  O  O15  1  0.322  1.000  0.134  1.0
  O  O16  1  0.000  0.677  0.867  1.0
  O  O17  1  0.678  1.000  0.134  1.0
  O  O18  1  0.000  0.322  0.867  1.0
  O  O19  1  0.752  0.996  0.850  1.0
  O  O20  1  0.000  0.251  0.151  1.0
  O  O21  1  0.248  0.996  0.850  1.0
  O  O22  1  0.000  0.749  0.151  1.0
  O  O23  1  0.500  0.992  0.685  1.0
  O  O24  1  0.000  0.500  0.312  1.0
  O  O25  1  0.000  0.820  0.707  1.0
  O  O26  1  0.818  0.000  0.293  1.0
  O  O27  1  0.000  0.181  0.707  1.0
  O  O28  1  0.182  0.000  0.293  1.0
  O  O29  1  0.500  0.753  0.274  1.0
  O  O30  1  0.754  0.503  0.725  1.0
  O  O31  1  0.500  0.247  0.274  1.0
  O  O32  1  0.246  0.503  0.725  1.0
  O  O33  1  0.701  0.500  0.436  1.0
  O  O34  1  0.500  0.303  0.563  1.0
  O  O35  1  0.299  0.500  0.436  1.0
  O  O36  1  0.500  0.697  0.563  1.0
  O  O37  1  0.801  1.000  0.569  1.0
  O  O38  1  0.000  0.199  0.430  1.0
  O  O39  1  0.199  1.000  0.569  1.0
  O  O40  1  0.000  0.801  0.430  1.0
  O  O41  1  0.500  0.499  0.125  1.0
  O  O42  1  0.500  0.508  0.876  1.0
  O  O43  1  0.500  0.802  0.995  1.0
  O  O44  1  0.802  0.500  0.006  1.0
  O  O45  1  0.500  0.198  0.995  1.0
  O  O46  1  0.198  0.500  0.006  1.0
  O  O47  1  0.000  0.000  0.002  1.0
  O  O48  1  0.500  0.001  0.433  1.0
  O  O49  1  0.000  0.500  0.566  1.0
[/CIF]
.