The material described by Hg2Cl5C3H7NH3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two trimethylammonium molecules and two Hg2Cl5 clusters. In each Hg2Cl5 cluster, there are two inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a 3-coordinate geometry to one Cl(2), one Cl(3), and one Cl(5) atom. In the second Hg site, Hg(2) is bonded in a distorted trigonal planar geometry to one Cl(1), one Cl(4), and one Cl(5) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Hg(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Hg(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Hg(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Hg(2) atom. In the fifth Cl site, Cl(5) is bonded in a distorted bent 120 degrees geometry to one Hg(1) and one Hg(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Hg2H10C3NCl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.386
_cell_length_b   10.253
_cell_length_c   11.111
_cell_angle_alpha   94.245
_cell_angle_beta   104.626
_cell_angle_gamma   98.704
_symmetry_Int_Tables_number   1
_cell_volume   691.065
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.080  0.891  0.164  1.0
  Hg  Hg1  1  0.313  0.128  0.569  1.0
  Hg  Hg2  1  0.687  0.872  0.431  1.0
  Hg  Hg3  1  0.920  0.109  0.836  1.0
  H  H4  1  0.738  0.404  0.415  1.0
  H  H5  1  0.448  0.272  0.032  1.0
  H  H6  1  0.272  0.642  0.923  1.0
  H  H7  1  0.728  0.358  0.077  1.0
  H  H8  1  0.157  0.720  0.664  1.0
  H  H9  1  0.895  0.450  0.306  1.0
  H  H10  1  0.339  0.806  0.879  1.0
  H  H11  1  0.560  0.492  0.707  1.0
  H  H12  1  0.552  0.728  0.968  1.0
  H  H13  1  0.105  0.550  0.694  1.0
  H  H14  1  0.685  0.555  0.869  1.0
  H  H15  1  0.415  0.454  0.822  1.0
  H  H16  1  0.315  0.445  0.131  1.0
  H  H17  1  0.661  0.194  0.121  1.0
  H  H18  1  0.456  0.279  0.249  1.0
  H  H19  1  0.262  0.596  0.585  1.0
  H  H20  1  0.585  0.546  0.178  1.0
  H  H21  1  0.843  0.280  0.336  1.0
  H  H22  1  0.440  0.508  0.293  1.0
  H  H23  1  0.544  0.721  0.751  1.0
  C  C24  1  0.604  0.289  0.105  1.0
  C  C25  1  0.396  0.711  0.895  1.0
  C  C26  1  0.223  0.628  0.672  1.0
  C  C27  1  0.777  0.372  0.328  1.0
  C  C28  1  0.470  0.471  0.205  1.0
  C  C29  1  0.530  0.529  0.795  1.0
  N  N30  1  0.431  0.652  0.776  1.0
  N  N31  1  0.569  0.348  0.224  1.0
  Cl  Cl32  1  0.328  0.330  0.471  1.0
  Cl  Cl33  1  0.006  0.657  0.127  1.0
  Cl  Cl34  1  0.110  0.122  0.153  1.0
  Cl  Cl35  1  0.592  0.914  0.209  1.0
  Cl  Cl36  1  0.672  0.670  0.529  1.0
  Cl  Cl37  1  0.890  0.877  0.847  1.0
  Cl  Cl38  1  0.408  0.086  0.791  1.0
  Cl  Cl39  1  0.994  0.343  0.873  1.0
  Cl  Cl40  1  0.806  0.103  0.560  1.0
  Cl  Cl41  1  0.194  0.897  0.440  1.0
[/CIF]
.
The material described by Hg2Cl5C3H7NH3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two trimethylammonium molecules and two Hg2Cl5 clusters. In each Hg2Cl5 cluster, there are two inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a 3-coordinate geometry to one Cl(2), one Cl(3), and one Cl(5) atom. In the second Hg site, Hg(2) is bonded in a distorted trigonal planar geometry to one Cl(1), one Cl(4), and one Cl(5) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Hg(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Hg(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Hg(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Hg(2) atom. In the fifth Cl site, Cl(5) is bonded in a distorted bent 120 degrees geometry to one Hg(1) and one Hg(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Hg2H10C3NCl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.386
_cell_length_b   10.253
_cell_length_c   11.111
_cell_angle_alpha   94.245
_cell_angle_beta   104.626
_cell_angle_gamma   98.704
_symmetry_Int_Tables_number   1
_cell_volume   691.065
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.080  0.891  0.164  1.0
  Hg  Hg1  1  0.313  0.128  0.569  1.0
  Hg  Hg2  1  0.687  0.872  0.431  1.0
  Hg  Hg3  1  0.920  0.109  0.836  1.0
  H  H4  1  0.738  0.404  0.415  1.0
  H  H5  1  0.448  0.272  0.032  1.0
  H  H6  1  0.272  0.642  0.923  1.0
  H  H7  1  0.728  0.358  0.077  1.0
  H  H8  1  0.157  0.720  0.664  1.0
  H  H9  1  0.895  0.450  0.306  1.0
  H  H10  1  0.339  0.806  0.879  1.0
  H  H11  1  0.560  0.492  0.707  1.0
  H  H12  1  0.552  0.728  0.968  1.0
  H  H13  1  0.105  0.550  0.694  1.0
  H  H14  1  0.685  0.555  0.869  1.0
  H  H15  1  0.415  0.454  0.822  1.0
  H  H16  1  0.315  0.445  0.131  1.0
  H  H17  1  0.661  0.194  0.121  1.0
  H  H18  1  0.456  0.279  0.249  1.0
  H  H19  1  0.262  0.596  0.585  1.0
  H  H20  1  0.585  0.546  0.178  1.0
  H  H21  1  0.843  0.280  0.336  1.0
  H  H22  1  0.440  0.508  0.293  1.0
  H  H23  1  0.544  0.721  0.751  1.0
  C  C24  1  0.604  0.289  0.105  1.0
  C  C25  1  0.396  0.711  0.895  1.0
  C  C26  1  0.223  0.628  0.672  1.0
  C  C27  1  0.777  0.372  0.328  1.0
  C  C28  1  0.470  0.471  0.205  1.0
  C  C29  1  0.530  0.529  0.795  1.0
  N  N30  1  0.431  0.652  0.776  1.0
  N  N31  1  0.569  0.348  0.224  1.0
  Cl  Cl32  1  0.328  0.330  0.471  1.0
  Cl  Cl33  1  0.006  0.657  0.127  1.0
  Cl  Cl34  1  0.110  0.122  0.153  1.0
  Cl  Cl35  1  0.592  0.914  0.209  1.0
  Cl  Cl36  1  0.672  0.670  0.529  1.0
  Cl  Cl37  1  0.890  0.877  0.847  1.0
  Cl  Cl38  1  0.408  0.086  0.791  1.0
  Cl  Cl39  1  0.994  0.343  0.873  1.0
  Cl  Cl40  1  0.806  0.103  0.560  1.0
  Cl  Cl41  1  0.194  0.897  0.440  1.0
[/CIF]
.