The material structure described by UMoO5 crystallizes in the orthorhombic Pcca space group. U(1) is bonded to one O(4), two equivalent O(3), and four equivalent O(1) atoms to form a mixture of corner and edge-sharing UO7 pentagonal bipyramids. Mo(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent U(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to two equivalent Mo(1) atoms. In the third O site, O(3) is bonded in a linear geometry to two equivalent U(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one U(1) and two equivalent Mo(1) atoms. is represented by the CIF file [CIF]
data_UMoO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.146
_cell_length_b   7.452
_cell_length_c   13.012
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   402.017
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.000  0.250  0.521  1.0
  U  U1  1  0.000  0.750  0.479  1.0
  U  U2  1  0.000  0.250  0.021  1.0
  U  U3  1  0.000  0.750  0.979  1.0
  Mo  Mo4  1  0.903  0.000  0.750  1.0
  Mo  Mo5  1  0.097  0.000  0.250  1.0
  Mo  Mo6  1  0.903  0.500  0.250  1.0
  Mo  Mo7  1  0.097  0.500  0.750  1.0
  O  O8  1  0.989  0.457  0.402  1.0
  O  O9  1  0.989  0.043  0.902  1.0
  O  O10  1  0.989  0.957  0.598  1.0
  O  O11  1  0.518  0.000  0.250  1.0
  O  O12  1  0.500  0.250  0.526  1.0
  O  O13  1  0.482  0.500  0.250  1.0
  O  O14  1  0.011  0.543  0.598  1.0
  O  O15  1  0.989  0.543  0.098  1.0
  O  O16  1  0.000  0.750  0.296  1.0
  O  O17  1  0.011  0.957  0.098  1.0
  O  O18  1  0.011  0.043  0.402  1.0
  O  O19  1  0.500  0.750  0.474  1.0
  O  O20  1  0.000  0.250  0.204  1.0
  O  O21  1  0.482  0.000  0.750  1.0
  O  O22  1  0.000  0.250  0.704  1.0
  O  O23  1  0.500  0.250  0.026  1.0
  O  O24  1  0.500  0.750  0.974  1.0
  O  O25  1  0.011  0.457  0.902  1.0
  O  O26  1  0.518  0.500  0.750  1.0
  O  O27  1  0.000  0.750  0.796  1.0
[/CIF]
.
The material structure described by UMoO5 crystallizes in the orthorhombic Pcca space group. U(1) is bonded to one O(4), two equivalent O(3), and four equivalent O(1) atoms to form a mixture of corner and edge-sharing UO7 pentagonal bipyramids. Mo(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent U(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to two equivalent Mo(1) atoms. In the third O site, O(3) is bonded in a linear geometry to two equivalent U(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one U(1) and two equivalent Mo(1) atoms. is represented by the CIF file [CIF]
data_UMoO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.146
_cell_length_b   7.452
_cell_length_c   13.012
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   402.017
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.000  0.250  0.521  1.0
  U  U1  1  0.000  0.750  0.479  1.0
  U  U2  1  0.000  0.250  0.021  1.0
  U  U3  1  0.000  0.750  0.979  1.0
  Mo  Mo4  1  0.903  0.000  0.750  1.0
  Mo  Mo5  1  0.097  0.000  0.250  1.0
  Mo  Mo6  1  0.903  0.500  0.250  1.0
  Mo  Mo7  1  0.097  0.500  0.750  1.0
  O  O8  1  0.989  0.457  0.402  1.0
  O  O9  1  0.989  0.043  0.902  1.0
  O  O10  1  0.989  0.957  0.598  1.0
  O  O11  1  0.518  0.000  0.250  1.0
  O  O12  1  0.500  0.250  0.526  1.0
  O  O13  1  0.482  0.500  0.250  1.0
  O  O14  1  0.011  0.543  0.598  1.0
  O  O15  1  0.989  0.543  0.098  1.0
  O  O16  1  0.000  0.750  0.296  1.0
  O  O17  1  0.011  0.957  0.098  1.0
  O  O18  1  0.011  0.043  0.402  1.0
  O  O19  1  0.500  0.750  0.474  1.0
  O  O20  1  0.000  0.250  0.204  1.0
  O  O21  1  0.482  0.000  0.750  1.0
  O  O22  1  0.000  0.250  0.704  1.0
  O  O23  1  0.500  0.250  0.026  1.0
  O  O24  1  0.500  0.750  0.974  1.0
  O  O25  1  0.011  0.457  0.902  1.0
  O  O26  1  0.518  0.500  0.750  1.0
  O  O27  1  0.000  0.750  0.796  1.0
[/CIF]
.