The material described by P2SO3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four P2SO3 clusters. There are four inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one O(1), one O(2), and one O(3) atom to form distorted corner-sharing PSO3 tetrahedra. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(4), and one O(5) atom. In the third P site, P(3) is bonded in a distorted trigonal non-coplanar geometry to one O(2), one O(4), and one O(6) atom. In the fourth P site, P(4) is bonded to one S(2), one O(3), one O(5), and one O(6) atom to form distorted corner-sharing PSO3 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one P(4) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(4) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(2) and one P(4) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one P(3) and one P(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P2SO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.760
_cell_length_b   11.726
_cell_length_c   12.154
_cell_angle_alpha   89.682
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   963.402
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.014  0.822  0.096  1.0
  P  P1  1  0.860  0.849  0.477  1.0
  P  P2  1  0.360  0.151  0.023  1.0
  P  P3  1  0.469  0.288  0.619  1.0
  P  P4  1  0.140  0.151  0.523  1.0
  P  P5  1  0.531  0.712  0.381  1.0
  P  P6  1  0.031  0.288  0.119  1.0
  P  P7  1  0.247  0.371  0.925  1.0
  P  P8  1  0.640  0.849  0.977  1.0
  P  P9  1  0.253  0.371  0.425  1.0
  P  P10  1  0.486  0.822  0.596  1.0
  P  P11  1  0.514  0.178  0.404  1.0
  P  P12  1  0.753  0.629  0.075  1.0
  P  P13  1  0.969  0.712  0.881  1.0
  P  P14  1  0.747  0.629  0.575  1.0
  P  P15  1  0.986  0.178  0.904  1.0
  S  S16  1  0.306  0.895  0.692  1.0
  S  S17  1  0.658  0.500  0.151  1.0
  S  S18  1  0.806  0.105  0.808  1.0
  S  S19  1  0.842  0.500  0.651  1.0
  S  S20  1  0.342  0.500  0.849  1.0
  S  S21  1  0.194  0.895  0.192  1.0
  S  S22  1  0.694  0.105  0.308  1.0
  S  S23  1  0.158  0.500  0.349  1.0
  O  O24  1  0.678  0.896  0.561  1.0
  O  O25  1  0.398  0.780  0.479  1.0
  O  O26  1  0.585  0.705  0.644  1.0
  O  O27  1  0.224  0.200  0.125  1.0
  O  O28  1  0.915  0.705  0.144  1.0
  O  O29  1  0.410  0.275  0.958  1.0
  O  O30  1  0.868  0.608  0.960  1.0
  O  O31  1  0.132  0.392  0.040  1.0
  O  O32  1  0.898  0.220  0.021  1.0
  O  O33  1  0.368  0.392  0.540  1.0
  O  O34  1  0.602  0.220  0.521  1.0
  O  O35  1  0.276  0.200  0.625  1.0
  O  O36  1  0.590  0.725  0.042  1.0
  O  O37  1  0.322  0.104  0.439  1.0
  O  O38  1  0.910  0.725  0.542  1.0
  O  O39  1  0.724  0.800  0.375  1.0
  O  O40  1  0.415  0.295  0.356  1.0
  O  O41  1  0.090  0.275  0.458  1.0
  O  O42  1  0.822  0.896  0.061  1.0
  O  O43  1  0.776  0.800  0.875  1.0
  O  O44  1  0.178  0.104  0.939  1.0
  O  O45  1  0.085  0.295  0.856  1.0
  O  O46  1  0.632  0.608  0.460  1.0
  O  O47  1  0.102  0.780  0.979  1.0
[/CIF]
.
The material described by P2SO3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four P2SO3 clusters. There are four inequivalent P sites. In the first P site, P(1) is bonded to one S(1), one O(1), one O(2), and one O(3) atom to form distorted corner-sharing PSO3 tetrahedra. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(4), and one O(5) atom. In the third P site, P(3) is bonded in a distorted trigonal non-coplanar geometry to one O(2), one O(4), and one O(6) atom. In the fourth P site, P(4) is bonded to one S(2), one O(3), one O(5), and one O(6) atom to form distorted corner-sharing PSO3 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one P(1) atom. In the second S site, S(2) is bonded in a single-bond geometry to one P(4) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(4) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one P(2) and one P(4) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one P(3) and one P(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P2SO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.760
_cell_length_b   11.726
_cell_length_c   12.154
_cell_angle_alpha   89.682
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   963.402
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.014  0.822  0.096  1.0
  P  P1  1  0.860  0.849  0.477  1.0
  P  P2  1  0.360  0.151  0.023  1.0
  P  P3  1  0.469  0.288  0.619  1.0
  P  P4  1  0.140  0.151  0.523  1.0
  P  P5  1  0.531  0.712  0.381  1.0
  P  P6  1  0.031  0.288  0.119  1.0
  P  P7  1  0.247  0.371  0.925  1.0
  P  P8  1  0.640  0.849  0.977  1.0
  P  P9  1  0.253  0.371  0.425  1.0
  P  P10  1  0.486  0.822  0.596  1.0
  P  P11  1  0.514  0.178  0.404  1.0
  P  P12  1  0.753  0.629  0.075  1.0
  P  P13  1  0.969  0.712  0.881  1.0
  P  P14  1  0.747  0.629  0.575  1.0
  P  P15  1  0.986  0.178  0.904  1.0
  S  S16  1  0.306  0.895  0.692  1.0
  S  S17  1  0.658  0.500  0.151  1.0
  S  S18  1  0.806  0.105  0.808  1.0
  S  S19  1  0.842  0.500  0.651  1.0
  S  S20  1  0.342  0.500  0.849  1.0
  S  S21  1  0.194  0.895  0.192  1.0
  S  S22  1  0.694  0.105  0.308  1.0
  S  S23  1  0.158  0.500  0.349  1.0
  O  O24  1  0.678  0.896  0.561  1.0
  O  O25  1  0.398  0.780  0.479  1.0
  O  O26  1  0.585  0.705  0.644  1.0
  O  O27  1  0.224  0.200  0.125  1.0
  O  O28  1  0.915  0.705  0.144  1.0
  O  O29  1  0.410  0.275  0.958  1.0
  O  O30  1  0.868  0.608  0.960  1.0
  O  O31  1  0.132  0.392  0.040  1.0
  O  O32  1  0.898  0.220  0.021  1.0
  O  O33  1  0.368  0.392  0.540  1.0
  O  O34  1  0.602  0.220  0.521  1.0
  O  O35  1  0.276  0.200  0.625  1.0
  O  O36  1  0.590  0.725  0.042  1.0
  O  O37  1  0.322  0.104  0.439  1.0
  O  O38  1  0.910  0.725  0.542  1.0
  O  O39  1  0.724  0.800  0.375  1.0
  O  O40  1  0.415  0.295  0.356  1.0
  O  O41  1  0.090  0.275  0.458  1.0
  O  O42  1  0.822  0.896  0.061  1.0
  O  O43  1  0.776  0.800  0.875  1.0
  O  O44  1  0.178  0.104  0.939  1.0
  O  O45  1  0.085  0.295  0.856  1.0
  O  O46  1  0.632  0.608  0.460  1.0
  O  O47  1  0.102  0.780  0.979  1.0
[/CIF]
.