The structure described by Tl2S2O3 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and four TlS2O3 clusters. In each TlS2O3 cluster, Tl(2) is bonded in a distorted single-bond geometry to one O(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one S(2) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one S(1), one O(1), and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Tl(2) and one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF card [CIF]
data_Tl2S2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.317
_cell_length_b   8.835
_cell_length_c   10.799
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   602.663
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.250  0.653  0.605  1.0
  Tl  Tl1  1  0.750  0.347  0.395  1.0
  Tl  Tl2  1  0.750  0.847  0.105  1.0
  Tl  Tl3  1  0.250  0.153  0.895  1.0
  Tl  Tl4  1  0.250  0.482  0.184  1.0
  Tl  Tl5  1  0.750  0.518  0.816  1.0
  Tl  Tl6  1  0.750  0.018  0.684  1.0
  Tl  Tl7  1  0.250  0.982  0.316  1.0
  S  S8  1  0.250  0.532  0.887  1.0
  S  S9  1  0.750  0.468  0.113  1.0
  S  S10  1  0.750  0.968  0.387  1.0
  S  S11  1  0.250  0.032  0.613  1.0
  S  S12  1  0.250  0.757  0.935  1.0
  S  S13  1  0.750  0.243  0.065  1.0
  S  S14  1  0.750  0.743  0.435  1.0
  S  S15  1  0.250  0.257  0.565  1.0
  O  O16  1  0.250  0.768  0.073  1.0
  O  O17  1  0.750  0.232  0.927  1.0
  O  O18  1  0.750  0.732  0.573  1.0
  O  O19  1  0.250  0.268  0.427  1.0
  O  O20  1  0.056  0.826  0.883  1.0
  O  O21  1  0.944  0.174  0.117  1.0
  O  O22  1  0.944  0.674  0.383  1.0
  O  O23  1  0.556  0.174  0.117  1.0
  O  O24  1  0.056  0.326  0.617  1.0
  O  O25  1  0.444  0.826  0.883  1.0
  O  O26  1  0.444  0.326  0.617  1.0
  O  O27  1  0.556  0.674  0.383  1.0
[/CIF]
.
The structure described by Tl2S2O3 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and four TlS2O3 clusters. In each TlS2O3 cluster, Tl(2) is bonded in a distorted single-bond geometry to one O(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one S(2) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one S(1), one O(1), and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Tl(2) and one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF card [CIF]
data_Tl2S2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.317
_cell_length_b   8.835
_cell_length_c   10.799
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   602.663
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.250  0.653  0.605  1.0
  Tl  Tl1  1  0.750  0.347  0.395  1.0
  Tl  Tl2  1  0.750  0.847  0.105  1.0
  Tl  Tl3  1  0.250  0.153  0.895  1.0
  Tl  Tl4  1  0.250  0.482  0.184  1.0
  Tl  Tl5  1  0.750  0.518  0.816  1.0
  Tl  Tl6  1  0.750  0.018  0.684  1.0
  Tl  Tl7  1  0.250  0.982  0.316  1.0
  S  S8  1  0.250  0.532  0.887  1.0
  S  S9  1  0.750  0.468  0.113  1.0
  S  S10  1  0.750  0.968  0.387  1.0
  S  S11  1  0.250  0.032  0.613  1.0
  S  S12  1  0.250  0.757  0.935  1.0
  S  S13  1  0.750  0.243  0.065  1.0
  S  S14  1  0.750  0.743  0.435  1.0
  S  S15  1  0.250  0.257  0.565  1.0
  O  O16  1  0.250  0.768  0.073  1.0
  O  O17  1  0.750  0.232  0.927  1.0
  O  O18  1  0.750  0.732  0.573  1.0
  O  O19  1  0.250  0.268  0.427  1.0
  O  O20  1  0.056  0.826  0.883  1.0
  O  O21  1  0.944  0.174  0.117  1.0
  O  O22  1  0.944  0.674  0.383  1.0
  O  O23  1  0.556  0.174  0.117  1.0
  O  O24  1  0.056  0.326  0.617  1.0
  O  O25  1  0.444  0.826  0.883  1.0
  O  O26  1  0.444  0.326  0.617  1.0
  O  O27  1  0.556  0.674  0.383  1.0
[/CIF]
.