The material described by Mo3Ag3AsO13 crystallizes in the triclinic P-1 space group. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 3-coordinate geometry to one O(11), one O(12), and one O(2) atom. In the second Mo site, Mo(2) is bonded in a 3-coordinate geometry to one O(1), one O(12), one O(13), and one O(9) atom. In the third Mo site, Mo(3) is bonded in a 4-coordinate geometry to one O(10), one O(3), one O(6), one O(8), and one O(9) atom. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(10), one O(11), one O(4), and one O(9) atom. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one O(10), one O(13), and one O(4) atom. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one O(1), one O(3), and one O(7) atom. As(1) is bonded in a 4-coordinate geometry to one O(4), one O(5), one O(6), and one O(7) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Mo(2) and one Ag(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mo(3), one Ag(3), and one O(8) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one As(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one As(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mo(3) and one As(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Ag(3) and one As(1) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Mo(3) and one O(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Mo(2), one Mo(3), and one Ag(1) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Mo(3), one Ag(1), and one Ag(2) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Mo(1) and one Ag(1) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one Mo(1) and one Mo(2) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Mo(2) and one Ag(2) atom. is represented by the CIF card [CIF]
data_Ag3Mo3AsO13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.185
_cell_length_b   8.370
_cell_length_c   9.865
_cell_angle_alpha   113.871
_cell_angle_beta   99.028
_cell_angle_gamma   105.651
_symmetry_Int_Tables_number   1
_cell_volume   567.288
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.391  0.234  0.420  1.0
  Ag  Ag1  1  0.609  0.766  0.580  1.0
  Ag  Ag2  1  0.090  0.791  0.558  1.0
  Ag  Ag3  1  0.910  0.209  0.442  1.0
  Ag  Ag4  1  0.256  0.494  0.035  1.0
  Ag  Ag5  1  0.744  0.506  0.965  1.0
  Mo  Mo6  1  0.302  0.333  0.756  1.0
  Mo  Mo7  1  0.698  0.667  0.244  1.0
  Mo  Mo8  1  0.117  0.711  0.232  1.0
  Mo  Mo9  1  0.883  0.289  0.768  1.0
  Mo  Mo10  1  0.487  0.069  0.142  1.0
  Mo  Mo11  1  0.513  0.931  0.858  1.0
  As  As12  1  0.947  0.108  0.169  1.0
  As  As13  1  0.053  0.892  0.831  1.0
  O  O14  1  0.218  0.545  0.243  1.0
  O  O15  1  0.782  0.455  0.757  1.0
  O  O16  1  0.461  0.525  0.737  1.0
  O  O17  1  0.539  0.475  0.263  1.0
  O  O18  1  0.409  0.285  0.031  1.0
  O  O19  1  0.591  0.715  0.969  1.0
  O  O20  1  0.081  0.115  0.346  1.0
  O  O21  1  0.919  0.885  0.654  1.0
  O  O22  1  0.915  0.890  0.177  1.0
  O  O23  1  0.085  0.110  0.823  1.0
  O  O24  1  0.748  0.185  0.131  1.0
  O  O25  1  0.252  0.815  0.869  1.0
  O  O26  1  0.030  0.250  0.018  1.0
  O  O27  1  0.970  0.750  0.982  1.0
  O  O28  1  0.442  0.131  0.877  1.0
  O  O29  1  0.558  0.869  0.123  1.0
  O  O30  1  0.262  0.930  0.137  1.0
  O  O31  1  0.738  0.070  0.863  1.0
  O  O32  1  0.558  0.035  0.341  1.0
  O  O33  1  0.442  0.965  0.659  1.0
  O  O34  1  0.765  0.687  0.424  1.0
  O  O35  1  0.235  0.313  0.576  1.0
  O  O36  1  0.113  0.440  0.748  1.0
  O  O37  1  0.887  0.560  0.252  1.0
  O  O38  1  0.210  0.719  0.420  1.0
  O  O39  1  0.790  0.281  0.580  1.0
[/CIF]
.
The material described by Mo3Ag3AsO13 crystallizes in the triclinic P-1 space group. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 3-coordinate geometry to one O(11), one O(12), and one O(2) atom. In the second Mo site, Mo(2) is bonded in a 3-coordinate geometry to one O(1), one O(12), one O(13), and one O(9) atom. In the third Mo site, Mo(3) is bonded in a 4-coordinate geometry to one O(10), one O(3), one O(6), one O(8), and one O(9) atom. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(10), one O(11), one O(4), and one O(9) atom. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one O(10), one O(13), and one O(4) atom. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one O(1), one O(3), and one O(7) atom. As(1) is bonded in a 4-coordinate geometry to one O(4), one O(5), one O(6), and one O(7) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Mo(2) and one Ag(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mo(3), one Ag(3), and one O(8) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(2), and one As(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one As(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mo(3) and one As(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Ag(3) and one As(1) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Mo(3) and one O(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Mo(2), one Mo(3), and one Ag(1) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Mo(3), one Ag(1), and one Ag(2) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Mo(1) and one Ag(1) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one Mo(1) and one Mo(2) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Mo(2) and one Ag(2) atom. is represented by the CIF card [CIF]
data_Ag3Mo3AsO13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.185
_cell_length_b   8.370
_cell_length_c   9.865
_cell_angle_alpha   113.871
_cell_angle_beta   99.028
_cell_angle_gamma   105.651
_symmetry_Int_Tables_number   1
_cell_volume   567.288
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.391  0.234  0.420  1.0
  Ag  Ag1  1  0.609  0.766  0.580  1.0
  Ag  Ag2  1  0.090  0.791  0.558  1.0
  Ag  Ag3  1  0.910  0.209  0.442  1.0
  Ag  Ag4  1  0.256  0.494  0.035  1.0
  Ag  Ag5  1  0.744  0.506  0.965  1.0
  Mo  Mo6  1  0.302  0.333  0.756  1.0
  Mo  Mo7  1  0.698  0.667  0.244  1.0
  Mo  Mo8  1  0.117  0.711  0.232  1.0
  Mo  Mo9  1  0.883  0.289  0.768  1.0
  Mo  Mo10  1  0.487  0.069  0.142  1.0
  Mo  Mo11  1  0.513  0.931  0.858  1.0
  As  As12  1  0.947  0.108  0.169  1.0
  As  As13  1  0.053  0.892  0.831  1.0
  O  O14  1  0.218  0.545  0.243  1.0
  O  O15  1  0.782  0.455  0.757  1.0
  O  O16  1  0.461  0.525  0.737  1.0
  O  O17  1  0.539  0.475  0.263  1.0
  O  O18  1  0.409  0.285  0.031  1.0
  O  O19  1  0.591  0.715  0.969  1.0
  O  O20  1  0.081  0.115  0.346  1.0
  O  O21  1  0.919  0.885  0.654  1.0
  O  O22  1  0.915  0.890  0.177  1.0
  O  O23  1  0.085  0.110  0.823  1.0
  O  O24  1  0.748  0.185  0.131  1.0
  O  O25  1  0.252  0.815  0.869  1.0
  O  O26  1  0.030  0.250  0.018  1.0
  O  O27  1  0.970  0.750  0.982  1.0
  O  O28  1  0.442  0.131  0.877  1.0
  O  O29  1  0.558  0.869  0.123  1.0
  O  O30  1  0.262  0.930  0.137  1.0
  O  O31  1  0.738  0.070  0.863  1.0
  O  O32  1  0.558  0.035  0.341  1.0
  O  O33  1  0.442  0.965  0.659  1.0
  O  O34  1  0.765  0.687  0.424  1.0
  O  O35  1  0.235  0.313  0.576  1.0
  O  O36  1  0.113  0.440  0.748  1.0
  O  O37  1  0.887  0.560  0.252  1.0
  O  O38  1  0.210  0.719  0.420  1.0
  O  O39  1  0.790  0.281  0.580  1.0
[/CIF]
.