The compound described by LiRh3Sn5 crystallizes in the orthorhombic Pbcm space group. Li(1) is bonded in a 12-coordinate geometry to two equivalent Rh(1), two equivalent Rh(2), two equivalent Sn(1), two equivalent Sn(3), and four equivalent Sn(2) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 1-coordinate geometry to one Li(1), one Sn(3), three equivalent Sn(1), and three equivalent Sn(2) atoms. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to two equivalent Li(1), two equivalent Sn(1), two equivalent Sn(2), and two equivalent Sn(3) atoms. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 6-coordinate geometry to one Li(1), one Rh(2), three equivalent Rh(1), and one Sn(1) atom. In the second Sn site, Sn(2) is bonded in a 5-coordinate geometry to two equivalent Li(1), one Rh(2), and three equivalent Rh(1) atoms. In the third Sn site, Sn(3) is bonded in a 5-coordinate geometry to two equivalent Li(1), two equivalent Rh(1), and two equivalent Rh(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiSn5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.445
_cell_length_b   9.789
_cell_length_c   12.868
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   685.972
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.596  0.109  0.250  1.0
  Li  Li1  1  0.596  0.391  0.750  1.0
  Li  Li2  1  0.404  0.609  0.250  1.0
  Li  Li3  1  0.404  0.891  0.750  1.0
  Sn  Sn4  1  0.867  0.126  0.063  1.0
  Sn  Sn5  1  0.625  0.826  0.112  1.0
  Sn  Sn6  1  0.133  0.874  0.563  1.0
  Sn  Sn7  1  0.625  0.674  0.612  1.0
  Sn  Sn8  1  0.867  0.126  0.437  1.0
  Sn  Sn9  1  0.133  0.626  0.063  1.0
  Sn  Sn10  1  0.375  0.326  0.112  1.0
  Sn  Sn11  1  0.625  0.826  0.388  1.0
  Sn  Sn12  1  0.133  0.874  0.937  1.0
  Sn  Sn13  1  0.375  0.174  0.888  1.0
  Sn  Sn14  1  0.625  0.674  0.888  1.0
  Sn  Sn15  1  0.375  0.326  0.388  1.0
  Sn  Sn16  1  0.375  0.174  0.612  1.0
  Sn  Sn17  1  0.867  0.374  0.937  1.0
  Sn  Sn18  1  0.840  0.425  0.250  1.0
  Sn  Sn19  1  0.160  0.575  0.750  1.0
  Sn  Sn20  1  0.133  0.626  0.437  1.0
  Sn  Sn21  1  0.840  0.075  0.750  1.0
  Sn  Sn22  1  0.160  0.925  0.250  1.0
  Sn  Sn23  1  0.867  0.374  0.563  1.0
  Rh  Rh24  1  0.647  0.552  0.422  1.0
  Rh  Rh25  1  0.353  0.448  0.922  1.0
  Rh  Rh26  1  0.647  0.552  0.078  1.0
  Rh  Rh27  1  0.647  0.948  0.922  1.0
  Rh  Rh28  1  0.095  0.304  0.750  1.0
  Rh  Rh29  1  0.353  0.052  0.078  1.0
  Rh  Rh30  1  0.353  0.052  0.422  1.0
  Rh  Rh31  1  0.647  0.948  0.578  1.0
  Rh  Rh32  1  0.905  0.804  0.750  1.0
  Rh  Rh33  1  0.905  0.696  0.250  1.0
  Rh  Rh34  1  0.353  0.448  0.578  1.0
  Rh  Rh35  1  0.095  0.196  0.250  1.0
[/CIF]
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The compound described by LiRh3Sn5 crystallizes in the orthorhombic Pbcm space group. Li(1) is bonded in a 12-coordinate geometry to two equivalent Rh(1), two equivalent Rh(2), two equivalent Sn(1), two equivalent Sn(3), and four equivalent Sn(2) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 1-coordinate geometry to one Li(1), one Sn(3), three equivalent Sn(1), and three equivalent Sn(2) atoms. In the second Rh site, Rh(2) is bonded in a 8-coordinate geometry to two equivalent Li(1), two equivalent Sn(1), two equivalent Sn(2), and two equivalent Sn(3) atoms. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 6-coordinate geometry to one Li(1), one Rh(2), three equivalent Rh(1), and one Sn(1) atom. In the second Sn site, Sn(2) is bonded in a 5-coordinate geometry to two equivalent Li(1), one Rh(2), and three equivalent Rh(1) atoms. In the third Sn site, Sn(3) is bonded in a 5-coordinate geometry to two equivalent Li(1), two equivalent Rh(1), and two equivalent Rh(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiSn5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.445
_cell_length_b   9.789
_cell_length_c   12.868
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   685.972
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.596  0.109  0.250  1.0
  Li  Li1  1  0.596  0.391  0.750  1.0
  Li  Li2  1  0.404  0.609  0.250  1.0
  Li  Li3  1  0.404  0.891  0.750  1.0
  Sn  Sn4  1  0.867  0.126  0.063  1.0
  Sn  Sn5  1  0.625  0.826  0.112  1.0
  Sn  Sn6  1  0.133  0.874  0.563  1.0
  Sn  Sn7  1  0.625  0.674  0.612  1.0
  Sn  Sn8  1  0.867  0.126  0.437  1.0
  Sn  Sn9  1  0.133  0.626  0.063  1.0
  Sn  Sn10  1  0.375  0.326  0.112  1.0
  Sn  Sn11  1  0.625  0.826  0.388  1.0
  Sn  Sn12  1  0.133  0.874  0.937  1.0
  Sn  Sn13  1  0.375  0.174  0.888  1.0
  Sn  Sn14  1  0.625  0.674  0.888  1.0
  Sn  Sn15  1  0.375  0.326  0.388  1.0
  Sn  Sn16  1  0.375  0.174  0.612  1.0
  Sn  Sn17  1  0.867  0.374  0.937  1.0
  Sn  Sn18  1  0.840  0.425  0.250  1.0
  Sn  Sn19  1  0.160  0.575  0.750  1.0
  Sn  Sn20  1  0.133  0.626  0.437  1.0
  Sn  Sn21  1  0.840  0.075  0.750  1.0
  Sn  Sn22  1  0.160  0.925  0.250  1.0
  Sn  Sn23  1  0.867  0.374  0.563  1.0
  Rh  Rh24  1  0.647  0.552  0.422  1.0
  Rh  Rh25  1  0.353  0.448  0.922  1.0
  Rh  Rh26  1  0.647  0.552  0.078  1.0
  Rh  Rh27  1  0.647  0.948  0.922  1.0
  Rh  Rh28  1  0.095  0.304  0.750  1.0
  Rh  Rh29  1  0.353  0.052  0.078  1.0
  Rh  Rh30  1  0.353  0.052  0.422  1.0
  Rh  Rh31  1  0.647  0.948  0.578  1.0
  Rh  Rh32  1  0.905  0.804  0.750  1.0
  Rh  Rh33  1  0.905  0.696  0.250  1.0
  Rh  Rh34  1  0.353  0.448  0.578  1.0
  Rh  Rh35  1  0.095  0.196  0.250  1.0
[/CIF]
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