The material described by CdGe4C4NS10C4N crystallizes in the tetragonal I-4 space group. The structure consists of two tetramethylammonium molecules inside a CdGe4C4NS10 framework. In the CdGe4C4NS10 framework, Cd(1) is bonded to four equivalent S(2) atoms to form CdS4 tetrahedra that share corners with four equivalent Ge(1)S4 tetrahedra. Ge(1) is bonded to one S(2), one S(3), and two equivalent S(1) atoms to form GeS4 tetrahedra that share  a cornercorner with one Cd(1)S4 tetrahedra and corners with three equivalent Ge(1)S4 tetrahedra. C(1) is bonded in a 3-coordinate geometry to one C(1), one N(1), and one S(2) atom. N(1) is bonded in a 4-coordinate geometry to four equivalent C(1) atoms. There are three inequivalent S sites. In the first S site, S(3) is bonded in a water-like geometry to two equivalent Ge(1) atoms. In the second S site, S(1) is bonded in a water-like geometry to two equivalent Ge(1) atoms. In the third S site, S(2) is bonded in a 3-coordinate geometry to one Cd(1), one Ge(1), and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdGe4C8(S5N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.256
_cell_length_b   8.256
_cell_length_c   10.322
_cell_angle_alpha   113.573
_cell_angle_beta   113.573
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   580.156
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.250  0.750  0.500  1.0
  Ge  Ge1  1  0.407  0.441  0.146  1.0
  Ge  Ge2  1  0.739  0.704  0.146  1.0
  Ge  Ge3  1  0.296  0.593  0.854  1.0
  Ge  Ge4  1  0.559  0.261  0.854  1.0
  C  C5  1  0.850  0.961  0.841  1.0
  C  C6  1  0.992  0.880  0.841  1.0
  C  C7  1  0.120  0.150  0.159  1.0
  C  C8  1  0.039  0.008  0.159  1.0
  C  C9  1  0.592  0.149  0.468  1.0
  C  C10  1  0.876  0.320  0.468  1.0
  C  C11  1  0.680  0.408  0.532  1.0
  C  C12  1  0.851  0.124  0.532  1.0
  S  S13  1  0.445  0.181  0.990  1.0
  S  S14  1  0.545  0.809  0.990  1.0
  S  S15  1  0.191  0.555  0.010  1.0
  S  S16  1  0.819  0.455  0.010  1.0
  S  S17  1  0.252  0.356  0.272  1.0
  S  S18  1  0.020  0.916  0.272  1.0
  S  S19  1  0.084  0.748  0.728  1.0
  S  S20  1  0.644  0.980  0.728  1.0
  S  S21  1  0.658  0.658  0.316  1.0
  S  S22  1  0.342  0.342  0.684  1.0
  N  N23  1  0.000  0.000  0.000  1.0
  N  N24  1  0.750  0.250  0.500  1.0
[/CIF]
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The material described by CdGe4C4NS10C4N crystallizes in the tetragonal I-4 space group. The structure consists of two tetramethylammonium molecules inside a CdGe4C4NS10 framework. In the CdGe4C4NS10 framework, Cd(1) is bonded to four equivalent S(2) atoms to form CdS4 tetrahedra that share corners with four equivalent Ge(1)S4 tetrahedra. Ge(1) is bonded to one S(2), one S(3), and two equivalent S(1) atoms to form GeS4 tetrahedra that share  a cornercorner with one Cd(1)S4 tetrahedra and corners with three equivalent Ge(1)S4 tetrahedra. C(1) is bonded in a 3-coordinate geometry to one C(1), one N(1), and one S(2) atom. N(1) is bonded in a 4-coordinate geometry to four equivalent C(1) atoms. There are three inequivalent S sites. In the first S site, S(3) is bonded in a water-like geometry to two equivalent Ge(1) atoms. In the second S site, S(1) is bonded in a water-like geometry to two equivalent Ge(1) atoms. In the third S site, S(2) is bonded in a 3-coordinate geometry to one Cd(1), one Ge(1), and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdGe4C8(S5N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.256
_cell_length_b   8.256
_cell_length_c   10.322
_cell_angle_alpha   113.573
_cell_angle_beta   113.573
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   580.156
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.250  0.750  0.500  1.0
  Ge  Ge1  1  0.407  0.441  0.146  1.0
  Ge  Ge2  1  0.739  0.704  0.146  1.0
  Ge  Ge3  1  0.296  0.593  0.854  1.0
  Ge  Ge4  1  0.559  0.261  0.854  1.0
  C  C5  1  0.850  0.961  0.841  1.0
  C  C6  1  0.992  0.880  0.841  1.0
  C  C7  1  0.120  0.150  0.159  1.0
  C  C8  1  0.039  0.008  0.159  1.0
  C  C9  1  0.592  0.149  0.468  1.0
  C  C10  1  0.876  0.320  0.468  1.0
  C  C11  1  0.680  0.408  0.532  1.0
  C  C12  1  0.851  0.124  0.532  1.0
  S  S13  1  0.445  0.181  0.990  1.0
  S  S14  1  0.545  0.809  0.990  1.0
  S  S15  1  0.191  0.555  0.010  1.0
  S  S16  1  0.819  0.455  0.010  1.0
  S  S17  1  0.252  0.356  0.272  1.0
  S  S18  1  0.020  0.916  0.272  1.0
  S  S19  1  0.084  0.748  0.728  1.0
  S  S20  1  0.644  0.980  0.728  1.0
  S  S21  1  0.658  0.658  0.316  1.0
  S  S22  1  0.342  0.342  0.684  1.0
  N  N23  1  0.000  0.000  0.000  1.0
  N  N24  1  0.750  0.250  0.500  1.0
[/CIF]
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