The material structure described by Fe3Te2(CO)9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Fe3Te2(CO)9 clusters. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 3-coordinate geometry to one C(1), one C(2), one C(9), one Te(1), and one Te(2) atom. In the second Fe site, Fe(2) is bonded in a 3-coordinate geometry to one C(4), one C(5), one C(8), one Te(1), and one Te(2) atom. In the third Fe site, Fe(3) is bonded in a 3-coordinate geometry to one C(3), one C(6), one C(7), one Te(1), and one Te(2) atom. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Fe(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Fe(1) and one O(4) atom. In the third C site, C(3) is bonded in a linear geometry to one Fe(3) and one O(2,9) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Fe(2) and one O(5) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Fe(2) and one O(3) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Fe(3) and one O(8) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Fe(3) and one O(6) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Fe(2) and one O(7) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Fe(1) and one O(2,9) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to one Fe(1), one Fe(2), and one Fe(3) atom. In the second Te site, Te(2) is bonded in a distorted T-shaped geometry to one Fe(1), one Fe(2), and one Fe(3) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2,9) is bonded in a single-bond geometry to one C(9) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(6) atom. is represented by the CIF file [CIF]
data_Fe3Te2(CO)9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.972
_cell_length_b   9.392
_cell_length_c   13.162
_cell_angle_alpha   94.833
_cell_angle_beta   95.231
_cell_angle_gamma   110.476
_symmetry_Int_Tables_number   1
_cell_volume   797.802
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.127  0.891  0.246  1.0
  Fe  Fe1  1  0.873  0.109  0.754  1.0
  Fe  Fe2  1  0.429  0.275  0.162  1.0
  Fe  Fe3  1  0.571  0.725  0.838  1.0
  Fe  Fe4  1  0.286  0.190  0.344  1.0
  Fe  Fe5  1  0.714  0.810  0.656  1.0
  Te  Te6  1  0.055  0.111  0.171  1.0
  Te  Te7  1  0.497  0.936  0.751  1.0
  Te  Te8  1  0.503  0.064  0.249  1.0
  Te  Te9  1  0.945  0.889  0.829  1.0
  C  C10  1  0.788  0.230  0.677  1.0
  C  C11  1  0.092  0.783  0.124  1.0
  C  C12  1  0.504  0.358  0.390  1.0
  C  C13  1  0.699  0.387  0.188  1.0
  C  C14  1  0.212  0.770  0.323  1.0
  C  C15  1  0.575  0.793  0.967  1.0
  C  C16  1  0.273  0.079  0.447  1.0
  C  C17  1  0.896  0.731  0.616  1.0
  C  C18  1  0.104  0.269  0.384  1.0
  C  C19  1  0.647  0.564  0.854  1.0
  C  C20  1  0.867  0.811  0.275  1.0
  C  C21  1  0.133  0.189  0.725  1.0
  C  C22  1  0.496  0.642  0.610  1.0
  C  C23  1  0.727  0.921  0.553  1.0
  C  C24  1  0.425  0.207  0.033  1.0
  C  C25  1  0.908  0.217  0.876  1.0
  C  C26  1  0.301  0.613  0.812  1.0
  C  C27  1  0.353  0.436  0.146  1.0
  O  O28  1  0.262  0.689  0.372  1.0
  O  O29  1  0.738  0.311  0.628  1.0
  O  O30  1  0.699  0.753  0.293  1.0
  O  O31  1  0.578  0.837  0.053  1.0
  O  O32  1  0.938  0.287  0.956  1.0
  O  O33  1  0.125  0.541  0.797  1.0
  O  O34  1  0.062  0.713  0.044  1.0
  O  O35  1  0.987  0.320  0.414  1.0
  O  O36  1  0.311  0.543  0.134  1.0
  O  O37  1  0.422  0.163  0.947  1.0
  O  O38  1  0.730  0.984  0.480  1.0
  O  O39  1  0.301  0.247  0.707  1.0
  O  O40  1  0.356  0.533  0.575  1.0
  O  O41  1  0.689  0.457  0.866  1.0
  O  O42  1  0.270  0.016  0.520  1.0
  O  O43  1  0.875  0.459  0.203  1.0
  O  O44  1  0.013  0.680  0.586  1.0
  O  O45  1  0.644  0.467  0.425  1.0
[/CIF]
.
The material structure described by Fe3Te2(CO)9 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Fe3Te2(CO)9 clusters. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a 3-coordinate geometry to one C(1), one C(2), one C(9), one Te(1), and one Te(2) atom. In the second Fe site, Fe(2) is bonded in a 3-coordinate geometry to one C(4), one C(5), one C(8), one Te(1), and one Te(2) atom. In the third Fe site, Fe(3) is bonded in a 3-coordinate geometry to one C(3), one C(6), one C(7), one Te(1), and one Te(2) atom. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Fe(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Fe(1) and one O(4) atom. In the third C site, C(3) is bonded in a linear geometry to one Fe(3) and one O(2,9) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Fe(2) and one O(5) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Fe(2) and one O(3) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Fe(3) and one O(8) atom. In the seventh C site, C(7) is bonded in a linear geometry to one Fe(3) and one O(6) atom. In the eighth C site, C(8) is bonded in a linear geometry to one Fe(2) and one O(7) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Fe(1) and one O(2,9) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to one Fe(1), one Fe(2), and one Fe(3) atom. In the second Te site, Te(2) is bonded in a distorted T-shaped geometry to one Fe(1), one Fe(2), and one Fe(3) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2,9) is bonded in a single-bond geometry to one C(9) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(6) atom. is represented by the CIF file [CIF]
data_Fe3Te2(CO)9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.972
_cell_length_b   9.392
_cell_length_c   13.162
_cell_angle_alpha   94.833
_cell_angle_beta   95.231
_cell_angle_gamma   110.476
_symmetry_Int_Tables_number   1
_cell_volume   797.802
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.127  0.891  0.246  1.0
  Fe  Fe1  1  0.873  0.109  0.754  1.0
  Fe  Fe2  1  0.429  0.275  0.162  1.0
  Fe  Fe3  1  0.571  0.725  0.838  1.0
  Fe  Fe4  1  0.286  0.190  0.344  1.0
  Fe  Fe5  1  0.714  0.810  0.656  1.0
  Te  Te6  1  0.055  0.111  0.171  1.0
  Te  Te7  1  0.497  0.936  0.751  1.0
  Te  Te8  1  0.503  0.064  0.249  1.0
  Te  Te9  1  0.945  0.889  0.829  1.0
  C  C10  1  0.788  0.230  0.677  1.0
  C  C11  1  0.092  0.783  0.124  1.0
  C  C12  1  0.504  0.358  0.390  1.0
  C  C13  1  0.699  0.387  0.188  1.0
  C  C14  1  0.212  0.770  0.323  1.0
  C  C15  1  0.575  0.793  0.967  1.0
  C  C16  1  0.273  0.079  0.447  1.0
  C  C17  1  0.896  0.731  0.616  1.0
  C  C18  1  0.104  0.269  0.384  1.0
  C  C19  1  0.647  0.564  0.854  1.0
  C  C20  1  0.867  0.811  0.275  1.0
  C  C21  1  0.133  0.189  0.725  1.0
  C  C22  1  0.496  0.642  0.610  1.0
  C  C23  1  0.727  0.921  0.553  1.0
  C  C24  1  0.425  0.207  0.033  1.0
  C  C25  1  0.908  0.217  0.876  1.0
  C  C26  1  0.301  0.613  0.812  1.0
  C  C27  1  0.353  0.436  0.146  1.0
  O  O28  1  0.262  0.689  0.372  1.0
  O  O29  1  0.738  0.311  0.628  1.0
  O  O30  1  0.699  0.753  0.293  1.0
  O  O31  1  0.578  0.837  0.053  1.0
  O  O32  1  0.938  0.287  0.956  1.0
  O  O33  1  0.125  0.541  0.797  1.0
  O  O34  1  0.062  0.713  0.044  1.0
  O  O35  1  0.987  0.320  0.414  1.0
  O  O36  1  0.311  0.543  0.134  1.0
  O  O37  1  0.422  0.163  0.947  1.0
  O  O38  1  0.730  0.984  0.480  1.0
  O  O39  1  0.301  0.247  0.707  1.0
  O  O40  1  0.356  0.533  0.575  1.0
  O  O41  1  0.689  0.457  0.866  1.0
  O  O42  1  0.270  0.016  0.520  1.0
  O  O43  1  0.875  0.459  0.203  1.0
  O  O44  1  0.013  0.680  0.586  1.0
  O  O45  1  0.644  0.467  0.425  1.0
[/CIF]
.