The compound described by KICl4 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 7-coordinate geometry to one Cl(1), one Cl(3), two equivalent Cl(2), and three equivalent Cl(4) atoms. I(1) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in an L-shaped geometry to one K(1) and one I(1) atom. In the second Cl site, Cl(2) is bonded in a T-shaped geometry to two equivalent K(1) and one I(1) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to one K(1) and one I(1) atom. In the fourth Cl site, Cl(4) is bonded to three equivalent K(1) and one I(1) atom to form a mixture of edge and corner-sharing ClK3I trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_KICl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.595
_cell_length_b   4.687
_cell_length_c   13.300
_cell_angle_alpha   75.308
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   819.782
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.346  0.653  0.084  1.0
  K  K1  1  0.846  0.347  0.416  1.0
  K  K2  1  0.654  0.347  0.916  1.0
  K  K3  1  0.154  0.653  0.584  1.0
  I  I4  1  0.066  0.806  0.200  1.0
  I  I5  1  0.566  0.194  0.300  1.0
  I  I6  1  0.934  0.194  0.800  1.0
  I  I7  1  0.434  0.806  0.700  1.0
  Cl  Cl8  1  0.115  0.742  0.031  1.0
  Cl  Cl9  1  0.615  0.258  0.469  1.0
  Cl  Cl10  1  0.885  0.258  0.969  1.0
  Cl  Cl11  1  0.385  0.742  0.531  1.0
  Cl  Cl12  1  0.232  0.044  0.217  1.0
  Cl  Cl13  1  0.732  0.956  0.283  1.0
  Cl  Cl14  1  0.768  0.956  0.783  1.0
  Cl  Cl15  1  0.268  0.044  0.717  1.0
  Cl  Cl16  1  0.909  0.557  0.184  1.0
  Cl  Cl17  1  0.409  0.443  0.316  1.0
  Cl  Cl18  1  0.091  0.443  0.816  1.0
  Cl  Cl19  1  0.591  0.557  0.684  1.0
  Cl  Cl20  1  0.011  0.862  0.385  1.0
  Cl  Cl21  1  0.511  0.138  0.115  1.0
  Cl  Cl22  1  0.989  0.138  0.615  1.0
  Cl  Cl23  1  0.489  0.862  0.885  1.0
[/CIF]
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The compound described by KICl4 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 7-coordinate geometry to one Cl(1), one Cl(3), two equivalent Cl(2), and three equivalent Cl(4) atoms. I(1) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in an L-shaped geometry to one K(1) and one I(1) atom. In the second Cl site, Cl(2) is bonded in a T-shaped geometry to two equivalent K(1) and one I(1) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to one K(1) and one I(1) atom. In the fourth Cl site, Cl(4) is bonded to three equivalent K(1) and one I(1) atom to form a mixture of edge and corner-sharing ClK3I trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_KICl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.595
_cell_length_b   4.687
_cell_length_c   13.300
_cell_angle_alpha   75.308
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   819.782
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.346  0.653  0.084  1.0
  K  K1  1  0.846  0.347  0.416  1.0
  K  K2  1  0.654  0.347  0.916  1.0
  K  K3  1  0.154  0.653  0.584  1.0
  I  I4  1  0.066  0.806  0.200  1.0
  I  I5  1  0.566  0.194  0.300  1.0
  I  I6  1  0.934  0.194  0.800  1.0
  I  I7  1  0.434  0.806  0.700  1.0
  Cl  Cl8  1  0.115  0.742  0.031  1.0
  Cl  Cl9  1  0.615  0.258  0.469  1.0
  Cl  Cl10  1  0.885  0.258  0.969  1.0
  Cl  Cl11  1  0.385  0.742  0.531  1.0
  Cl  Cl12  1  0.232  0.044  0.217  1.0
  Cl  Cl13  1  0.732  0.956  0.283  1.0
  Cl  Cl14  1  0.768  0.956  0.783  1.0
  Cl  Cl15  1  0.268  0.044  0.717  1.0
  Cl  Cl16  1  0.909  0.557  0.184  1.0
  Cl  Cl17  1  0.409  0.443  0.316  1.0
  Cl  Cl18  1  0.091  0.443  0.816  1.0
  Cl  Cl19  1  0.591  0.557  0.684  1.0
  Cl  Cl20  1  0.011  0.862  0.385  1.0
  Cl  Cl21  1  0.511  0.138  0.115  1.0
  Cl  Cl22  1  0.989  0.138  0.615  1.0
  Cl  Cl23  1  0.489  0.862  0.885  1.0
[/CIF]
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