The compound described by MgO6(H2)2(H2O)4(SO)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, two sulfur monoxide molecules, four water molecules, and one MgO6 cluster. In the MgO6 cluster, Mg(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(2) is bonded in an L-shaped geometry to one Mg(1) and one O(3) atom. In the second O site, O(3) is bonded in a water-like geometry to one O(1) and one O(2) atom. In the third O site, O(1) is bonded in an L-shaped geometry to one Mg(1) and one O(3) atom. is represented by the CIF card [CIF]
data_MgH12(SO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.635
_cell_length_b   7.773
_cell_length_c   7.812
_cell_angle_alpha   100.964
_cell_angle_beta   98.981
_cell_angle_gamma   98.239
_symmetry_Int_Tables_number   1
_cell_volume   442.330
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.000  0.000  0.000  1.0
  H  H1  1  0.483  0.934  0.740  1.0
  H  H2  1  0.517  0.066  0.260  1.0
  H  H3  1  0.708  0.287  0.844  1.0
  H  H4  1  0.292  0.713  0.156  1.0
  H  H5  1  0.850  0.931  0.475  1.0
  H  H6  1  0.150  0.069  0.525  1.0
  H  H7  1  0.821  0.357  0.716  1.0
  H  H8  1  0.179  0.643  0.284  1.0
  H  H9  1  0.546  0.914  0.561  1.0
  H  H10  1  0.454  0.086  0.439  1.0
  H  H11  1  0.843  0.872  0.540  1.0
  H  H12  1  0.157  0.128  0.460  1.0
  S  S13  1  0.481  0.541  0.627  1.0
  S  S14  1  0.519  0.459  0.373  1.0
  O  O15  1  0.892  0.131  0.195  1.0
  O  O16  1  0.108  0.869  0.805  1.0
  O  O17  1  0.259  0.976  0.086  1.0
  O  O18  1  0.741  0.024  0.914  1.0
  O  O19  1  0.730  0.113  0.085  1.0
  O  O20  1  0.270  0.887  0.915  1.0
  O  O21  1  0.767  0.397  0.818  1.0
  O  O22  1  0.233  0.603  0.182  1.0
  O  O23  1  0.294  0.464  0.641  1.0
  O  O24  1  0.706  0.536  0.359  1.0
  O  O25  1  0.438  0.897  0.612  1.0
  O  O26  1  0.562  0.103  0.388  1.0
[/CIF]
.
The compound described by MgO6(H2)2(H2O)4(SO)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, two sulfur monoxide molecules, four water molecules, and one MgO6 cluster. In the MgO6 cluster, Mg(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(2) is bonded in an L-shaped geometry to one Mg(1) and one O(3) atom. In the second O site, O(3) is bonded in a water-like geometry to one O(1) and one O(2) atom. In the third O site, O(1) is bonded in an L-shaped geometry to one Mg(1) and one O(3) atom. is represented by the CIF card [CIF]
data_MgH12(SO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.635
_cell_length_b   7.773
_cell_length_c   7.812
_cell_angle_alpha   100.964
_cell_angle_beta   98.981
_cell_angle_gamma   98.239
_symmetry_Int_Tables_number   1
_cell_volume   442.330
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.000  0.000  0.000  1.0
  H  H1  1  0.483  0.934  0.740  1.0
  H  H2  1  0.517  0.066  0.260  1.0
  H  H3  1  0.708  0.287  0.844  1.0
  H  H4  1  0.292  0.713  0.156  1.0
  H  H5  1  0.850  0.931  0.475  1.0
  H  H6  1  0.150  0.069  0.525  1.0
  H  H7  1  0.821  0.357  0.716  1.0
  H  H8  1  0.179  0.643  0.284  1.0
  H  H9  1  0.546  0.914  0.561  1.0
  H  H10  1  0.454  0.086  0.439  1.0
  H  H11  1  0.843  0.872  0.540  1.0
  H  H12  1  0.157  0.128  0.460  1.0
  S  S13  1  0.481  0.541  0.627  1.0
  S  S14  1  0.519  0.459  0.373  1.0
  O  O15  1  0.892  0.131  0.195  1.0
  O  O16  1  0.108  0.869  0.805  1.0
  O  O17  1  0.259  0.976  0.086  1.0
  O  O18  1  0.741  0.024  0.914  1.0
  O  O19  1  0.730  0.113  0.085  1.0
  O  O20  1  0.270  0.887  0.915  1.0
  O  O21  1  0.767  0.397  0.818  1.0
  O  O22  1  0.233  0.603  0.182  1.0
  O  O23  1  0.294  0.464  0.641  1.0
  O  O24  1  0.706  0.536  0.359  1.0
  O  O25  1  0.438  0.897  0.612  1.0
  O  O26  1  0.562  0.103  0.388  1.0
[/CIF]
.