The compound described by As2OCl3F5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four As2OCl3F5 clusters. There are two inequivalent As sites. In the first As site, As(1) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing AsOF5 octahedra. In the second As site, As(2) is bonded to one O(1), one Cl(1), one Cl(2), and one Cl(3) atom to form corner-sharing AsCl3O tetrahedra. The corner-sharing octahedral tilt angles are 53°. O(1) is bonded in a bent 120 degrees geometry to one As(1) and one As(2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one As(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one As(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one As(2) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_As2Cl3OF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   19.375
_cell_length_b   6.214
_cell_length_c   8.037
_cell_angle_alpha   71.754
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   919.043
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.621  0.552  0.816  1.0
  As  As1  1  0.613  0.139  0.184  1.0
  As  As2  1  0.879  0.552  0.316  1.0
  As  As3  1  0.379  0.448  0.184  1.0
  As  As4  1  0.387  0.861  0.816  1.0
  As  As5  1  0.121  0.448  0.684  1.0
  As  As6  1  0.113  0.861  0.316  1.0
  As  As7  1  0.887  0.139  0.684  1.0
  Cl  Cl8  1  0.367  0.686  0.634  1.0
  Cl  Cl9  1  0.705  0.970  0.158  1.0
  Cl  Cl10  1  0.295  0.030  0.842  1.0
  Cl  Cl11  1  0.867  0.314  0.866  1.0
  Cl  Cl12  1  0.795  0.970  0.658  1.0
  Cl  Cl13  1  0.463  0.107  0.711  1.0
  Cl  Cl14  1  0.037  0.107  0.211  1.0
  Cl  Cl15  1  0.205  0.030  0.342  1.0
  Cl  Cl16  1  0.963  0.893  0.789  1.0
  Cl  Cl17  1  0.537  0.893  0.289  1.0
  Cl  Cl18  1  0.633  0.314  0.366  1.0
  Cl  Cl19  1  0.133  0.686  0.134  1.0
  O  O20  1  0.578  0.304  0.992  1.0
  O  O21  1  0.922  0.304  0.492  1.0
  O  O22  1  0.422  0.696  0.008  1.0
  O  O23  1  0.078  0.696  0.508  1.0
  F  F24  1  0.345  0.647  0.279  1.0
  F  F25  1  0.696  0.519  0.949  1.0
  F  F26  1  0.155  0.647  0.779  1.0
  F  F27  1  0.913  0.740  0.420  1.0
  F  F28  1  0.543  0.564  0.700  1.0
  F  F29  1  0.457  0.436  0.300  1.0
  F  F30  1  0.804  0.519  0.449  1.0
  F  F31  1  0.655  0.353  0.721  1.0
  F  F32  1  0.587  0.740  0.920  1.0
  F  F33  1  0.196  0.481  0.551  1.0
  F  F34  1  0.843  0.778  0.148  1.0
  F  F35  1  0.657  0.778  0.648  1.0
  F  F36  1  0.304  0.481  0.051  1.0
  F  F37  1  0.087  0.260  0.580  1.0
  F  F38  1  0.343  0.222  0.352  1.0
  F  F39  1  0.413  0.260  0.080  1.0
  F  F40  1  0.845  0.353  0.221  1.0
  F  F41  1  0.043  0.436  0.800  1.0
  F  F42  1  0.957  0.564  0.200  1.0
  F  F43  1  0.157  0.222  0.852  1.0
[/CIF]
.
The compound described by As2OCl3F5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four As2OCl3F5 clusters. There are two inequivalent As sites. In the first As site, As(1) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing AsOF5 octahedra. In the second As site, As(2) is bonded to one O(1), one Cl(1), one Cl(2), and one Cl(3) atom to form corner-sharing AsCl3O tetrahedra. The corner-sharing octahedral tilt angles are 53°. O(1) is bonded in a bent 120 degrees geometry to one As(1) and one As(2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one As(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one As(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one As(2) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_As2Cl3OF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   19.375
_cell_length_b   6.214
_cell_length_c   8.037
_cell_angle_alpha   71.754
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   919.043
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.621  0.552  0.816  1.0
  As  As1  1  0.613  0.139  0.184  1.0
  As  As2  1  0.879  0.552  0.316  1.0
  As  As3  1  0.379  0.448  0.184  1.0
  As  As4  1  0.387  0.861  0.816  1.0
  As  As5  1  0.121  0.448  0.684  1.0
  As  As6  1  0.113  0.861  0.316  1.0
  As  As7  1  0.887  0.139  0.684  1.0
  Cl  Cl8  1  0.367  0.686  0.634  1.0
  Cl  Cl9  1  0.705  0.970  0.158  1.0
  Cl  Cl10  1  0.295  0.030  0.842  1.0
  Cl  Cl11  1  0.867  0.314  0.866  1.0
  Cl  Cl12  1  0.795  0.970  0.658  1.0
  Cl  Cl13  1  0.463  0.107  0.711  1.0
  Cl  Cl14  1  0.037  0.107  0.211  1.0
  Cl  Cl15  1  0.205  0.030  0.342  1.0
  Cl  Cl16  1  0.963  0.893  0.789  1.0
  Cl  Cl17  1  0.537  0.893  0.289  1.0
  Cl  Cl18  1  0.633  0.314  0.366  1.0
  Cl  Cl19  1  0.133  0.686  0.134  1.0
  O  O20  1  0.578  0.304  0.992  1.0
  O  O21  1  0.922  0.304  0.492  1.0
  O  O22  1  0.422  0.696  0.008  1.0
  O  O23  1  0.078  0.696  0.508  1.0
  F  F24  1  0.345  0.647  0.279  1.0
  F  F25  1  0.696  0.519  0.949  1.0
  F  F26  1  0.155  0.647  0.779  1.0
  F  F27  1  0.913  0.740  0.420  1.0
  F  F28  1  0.543  0.564  0.700  1.0
  F  F29  1  0.457  0.436  0.300  1.0
  F  F30  1  0.804  0.519  0.449  1.0
  F  F31  1  0.655  0.353  0.721  1.0
  F  F32  1  0.587  0.740  0.920  1.0
  F  F33  1  0.196  0.481  0.551  1.0
  F  F34  1  0.843  0.778  0.148  1.0
  F  F35  1  0.657  0.778  0.648  1.0
  F  F36  1  0.304  0.481  0.051  1.0
  F  F37  1  0.087  0.260  0.580  1.0
  F  F38  1  0.343  0.222  0.352  1.0
  F  F39  1  0.413  0.260  0.080  1.0
  F  F40  1  0.845  0.353  0.221  1.0
  F  F41  1  0.043  0.436  0.800  1.0
  F  F42  1  0.957  0.564  0.200  1.0
  F  F43  1  0.157  0.222  0.852  1.0
[/CIF]
.