The crystal structure described by (V2O13I3)2N2 crystallizes in the orthorhombic Ima2 space group. The structure consists of four ammonia atoms inside a V2O13I3 framework. In the V2O13I3 framework, V(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 150 degrees geometry to one V(1) and one I(2) atom. In the second O site, O(5) is bonded in a single-bond geometry to one V(1) atom. In the third O site, O(6) is bonded in a distorted bent 120 degrees geometry to two equivalent V(1) atoms. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to one V(1) and one I(1) atom. In the fifth O site, O(8) is bonded in a 3-coordinate geometry to one V(1), one I(1), and one I(2) atom. In the sixth O site, O(1) is bonded in a 2-coordinate geometry to two equivalent I(1) atoms. In the seventh O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the eighth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent I(2) atoms. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(7), one O(8), and two equivalent O(1) atoms. In the second I site, I(2) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(8) atoms to form distorted corner-sharing IO6 octahedra. The corner-sharing octahedral tilt angles are 51°. is represented by the CIF card [CIF]
data_V2I3NO13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.657
_cell_length_b   9.657
_cell_length_c   9.657
_cell_angle_alpha   131.606
_cell_angle_beta   112.706
_cell_angle_gamma   87.134
_symmetry_Int_Tables_number   1
_cell_volume   592.753
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.851  0.654  0.762  1.0
  V  V1  1  0.149  0.912  0.803  1.0
  V  V2  1  0.609  0.412  0.762  1.0
  V  V3  1  0.391  0.154  0.803  1.0
  I  I4  1  0.250  0.557  0.788  1.0
  I  I5  1  0.750  0.538  0.307  1.0
  I  I6  1  0.731  0.038  0.788  1.0
  I  I7  1  0.269  0.057  0.307  1.0
  I  I8  1  0.972  0.775  0.247  1.0
  I  I9  1  0.028  0.275  0.803  1.0
  N  N10  1  0.332  0.548  0.380  1.0
  N  N11  1  0.668  0.048  0.216  1.0
  O  O12  1  0.344  0.768  0.073  1.0
  O  O13  1  0.656  0.729  0.424  1.0
  O  O14  1  0.805  0.229  0.073  1.0
  O  O15  1  0.195  0.268  0.424  1.0
  O  O16  1  0.000  0.828  0.828  1.0
  O  O17  1  0.500  0.328  0.828  1.0
  O  O18  1  0.908  0.989  0.397  1.0
  O  O19  1  0.092  0.489  0.081  1.0
  O  O20  1  0.977  0.798  0.069  1.0
  O  O21  1  0.023  0.093  0.821  1.0
  O  O22  1  0.772  0.593  0.069  1.0
  O  O23  1  0.228  0.298  0.821  1.0
  O  O24  1  0.714  0.764  0.778  1.0
  O  O25  1  0.286  0.064  0.050  1.0
  O  O26  1  0.514  0.564  0.778  1.0
  O  O27  1  0.486  0.264  0.050  1.0
  O  O28  1  0.764  0.454  0.719  1.0
  O  O29  1  0.236  0.954  0.690  1.0
  O  O30  1  0.214  0.678  0.693  1.0
  O  O31  1  0.786  0.479  0.464  1.0
  O  O32  1  0.515  0.979  0.693  1.0
  O  O33  1  0.485  0.178  0.464  1.0
  O  O34  1  0.049  0.489  0.737  1.0
  O  O35  1  0.951  0.689  0.441  1.0
  O  O36  1  0.748  0.189  0.737  1.0
  O  O37  1  0.252  0.989  0.441  1.0
[/CIF]
.
The crystal structure described by (V2O13I3)2N2 crystallizes in the orthorhombic Ima2 space group. The structure consists of four ammonia atoms inside a V2O13I3 framework. In the V2O13I3 framework, V(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 150 degrees geometry to one V(1) and one I(2) atom. In the second O site, O(5) is bonded in a single-bond geometry to one V(1) atom. In the third O site, O(6) is bonded in a distorted bent 120 degrees geometry to two equivalent V(1) atoms. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to one V(1) and one I(1) atom. In the fifth O site, O(8) is bonded in a 3-coordinate geometry to one V(1), one I(1), and one I(2) atom. In the sixth O site, O(1) is bonded in a 2-coordinate geometry to two equivalent I(1) atoms. In the seventh O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the eighth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent I(2) atoms. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(7), one O(8), and two equivalent O(1) atoms. In the second I site, I(2) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(8) atoms to form distorted corner-sharing IO6 octahedra. The corner-sharing octahedral tilt angles are 51°. is represented by the CIF card [CIF]
data_V2I3NO13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.657
_cell_length_b   9.657
_cell_length_c   9.657
_cell_angle_alpha   131.606
_cell_angle_beta   112.706
_cell_angle_gamma   87.134
_symmetry_Int_Tables_number   1
_cell_volume   592.753
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.851  0.654  0.762  1.0
  V  V1  1  0.149  0.912  0.803  1.0
  V  V2  1  0.609  0.412  0.762  1.0
  V  V3  1  0.391  0.154  0.803  1.0
  I  I4  1  0.250  0.557  0.788  1.0
  I  I5  1  0.750  0.538  0.307  1.0
  I  I6  1  0.731  0.038  0.788  1.0
  I  I7  1  0.269  0.057  0.307  1.0
  I  I8  1  0.972  0.775  0.247  1.0
  I  I9  1  0.028  0.275  0.803  1.0
  N  N10  1  0.332  0.548  0.380  1.0
  N  N11  1  0.668  0.048  0.216  1.0
  O  O12  1  0.344  0.768  0.073  1.0
  O  O13  1  0.656  0.729  0.424  1.0
  O  O14  1  0.805  0.229  0.073  1.0
  O  O15  1  0.195  0.268  0.424  1.0
  O  O16  1  0.000  0.828  0.828  1.0
  O  O17  1  0.500  0.328  0.828  1.0
  O  O18  1  0.908  0.989  0.397  1.0
  O  O19  1  0.092  0.489  0.081  1.0
  O  O20  1  0.977  0.798  0.069  1.0
  O  O21  1  0.023  0.093  0.821  1.0
  O  O22  1  0.772  0.593  0.069  1.0
  O  O23  1  0.228  0.298  0.821  1.0
  O  O24  1  0.714  0.764  0.778  1.0
  O  O25  1  0.286  0.064  0.050  1.0
  O  O26  1  0.514  0.564  0.778  1.0
  O  O27  1  0.486  0.264  0.050  1.0
  O  O28  1  0.764  0.454  0.719  1.0
  O  O29  1  0.236  0.954  0.690  1.0
  O  O30  1  0.214  0.678  0.693  1.0
  O  O31  1  0.786  0.479  0.464  1.0
  O  O32  1  0.515  0.979  0.693  1.0
  O  O33  1  0.485  0.178  0.464  1.0
  O  O34  1  0.049  0.489  0.737  1.0
  O  O35  1  0.951  0.689  0.441  1.0
  O  O36  1  0.748  0.189  0.737  1.0
  O  O37  1  0.252  0.989  0.441  1.0
[/CIF]
.