The material structure described by (Bi(CO2)3)2(O2)3 crystallizes in the monoclinic P2_1/c space group. The structure consists of four trioxidane molecules inside a Bi(CO2)3 framework. In the Bi(CO2)3 framework, there are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. Bi(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(6), and two equivalent O(4) atoms. There are six inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 120 degrees geometry to one C(3) and one Bi(1) atom. In the second O site, O(6) is bonded in a distorted single-bond geometry to one C(3) and one Bi(1) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one C(1) and one Bi(1) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one C(1) and one Bi(1) atom. In the fifth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one C(2) and one Bi(1) atom. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to one C(2) and two equivalent Bi(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Bi(CO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.473
_cell_length_b   9.598
_cell_length_c   10.112
_cell_angle_alpha   81.226
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   812.746
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.093  0.816  0.913  1.0
  Bi  Bi1  1  0.593  0.184  0.587  1.0
  Bi  Bi2  1  0.907  0.184  0.087  1.0
  Bi  Bi3  1  0.407  0.816  0.413  1.0
  C  C4  1  0.975  0.514  0.071  1.0
  C  C5  1  0.475  0.486  0.429  1.0
  C  C6  1  0.025  0.486  0.929  1.0
  C  C7  1  0.525  0.514  0.571  1.0
  C  C8  1  0.380  0.919  0.726  1.0
  C  C9  1  0.880  0.081  0.774  1.0
  C  C10  1  0.620  0.081  0.274  1.0
  C  C11  1  0.120  0.919  0.226  1.0
  C  C12  1  0.382  0.028  0.826  1.0
  C  C13  1  0.882  0.972  0.674  1.0
  C  C14  1  0.618  0.972  0.174  1.0
  C  C15  1  0.118  0.028  0.326  1.0
  O  O16  1  0.984  0.639  0.095  1.0
  O  O17  1  0.484  0.361  0.405  1.0
  O  O18  1  0.016  0.361  0.905  1.0
  O  O19  1  0.516  0.639  0.595  1.0
  O  O20  1  0.927  0.409  0.154  1.0
  O  O21  1  0.427  0.591  0.346  1.0
  O  O22  1  0.073  0.591  0.846  1.0
  O  O23  1  0.573  0.409  0.654  1.0
  O  O24  1  0.289  0.815  0.747  1.0
  O  O25  1  0.789  0.185  0.753  1.0
  O  O26  1  0.711  0.185  0.253  1.0
  O  O27  1  0.211  0.815  0.247  1.0
  O  O28  1  0.470  0.946  0.624  1.0
  O  O29  1  0.970  0.054  0.876  1.0
  O  O30  1  0.530  0.054  0.376  1.0
  O  O31  1  0.030  0.946  0.124  1.0
  O  O32  1  0.459  0.142  0.790  1.0
  O  O33  1  0.959  0.858  0.710  1.0
  O  O34  1  0.541  0.858  0.210  1.0
  O  O35  1  0.041  0.142  0.290  1.0
  O  O36  1  0.306  0.997  0.932  1.0
  O  O37  1  0.806  0.003  0.568  1.0
  O  O38  1  0.694  0.003  0.068  1.0
  O  O39  1  0.194  0.997  0.432  1.0
  O  O40  1  0.653  0.774  0.912  1.0
  O  O41  1  0.153  0.226  0.588  1.0
  O  O42  1  0.347  0.226  0.088  1.0
  O  O43  1  0.847  0.774  0.412  1.0
  O  O44  1  0.451  0.652  0.006  1.0
  O  O45  1  0.951  0.348  0.494  1.0
  O  O46  1  0.549  0.348  0.994  1.0
  O  O47  1  0.049  0.652  0.506  1.0
  O  O48  1  0.099  0.341  0.520  1.0
  O  O49  1  0.599  0.659  0.980  1.0
  O  O50  1  0.901  0.659  0.480  1.0
  O  O51  1  0.401  0.341  0.020  1.0
[/CIF]
.
The material structure described by (Bi(CO2)3)2(O2)3 crystallizes in the monoclinic P2_1/c space group. The structure consists of four trioxidane molecules inside a Bi(CO2)3 framework. In the Bi(CO2)3 framework, there are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. Bi(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(6), and two equivalent O(4) atoms. There are six inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 120 degrees geometry to one C(3) and one Bi(1) atom. In the second O site, O(6) is bonded in a distorted single-bond geometry to one C(3) and one Bi(1) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one C(1) and one Bi(1) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one C(1) and one Bi(1) atom. In the fifth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one C(2) and one Bi(1) atom. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to one C(2) and two equivalent Bi(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Bi(CO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.473
_cell_length_b   9.598
_cell_length_c   10.112
_cell_angle_alpha   81.226
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   812.746
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.093  0.816  0.913  1.0
  Bi  Bi1  1  0.593  0.184  0.587  1.0
  Bi  Bi2  1  0.907  0.184  0.087  1.0
  Bi  Bi3  1  0.407  0.816  0.413  1.0
  C  C4  1  0.975  0.514  0.071  1.0
  C  C5  1  0.475  0.486  0.429  1.0
  C  C6  1  0.025  0.486  0.929  1.0
  C  C7  1  0.525  0.514  0.571  1.0
  C  C8  1  0.380  0.919  0.726  1.0
  C  C9  1  0.880  0.081  0.774  1.0
  C  C10  1  0.620  0.081  0.274  1.0
  C  C11  1  0.120  0.919  0.226  1.0
  C  C12  1  0.382  0.028  0.826  1.0
  C  C13  1  0.882  0.972  0.674  1.0
  C  C14  1  0.618  0.972  0.174  1.0
  C  C15  1  0.118  0.028  0.326  1.0
  O  O16  1  0.984  0.639  0.095  1.0
  O  O17  1  0.484  0.361  0.405  1.0
  O  O18  1  0.016  0.361  0.905  1.0
  O  O19  1  0.516  0.639  0.595  1.0
  O  O20  1  0.927  0.409  0.154  1.0
  O  O21  1  0.427  0.591  0.346  1.0
  O  O22  1  0.073  0.591  0.846  1.0
  O  O23  1  0.573  0.409  0.654  1.0
  O  O24  1  0.289  0.815  0.747  1.0
  O  O25  1  0.789  0.185  0.753  1.0
  O  O26  1  0.711  0.185  0.253  1.0
  O  O27  1  0.211  0.815  0.247  1.0
  O  O28  1  0.470  0.946  0.624  1.0
  O  O29  1  0.970  0.054  0.876  1.0
  O  O30  1  0.530  0.054  0.376  1.0
  O  O31  1  0.030  0.946  0.124  1.0
  O  O32  1  0.459  0.142  0.790  1.0
  O  O33  1  0.959  0.858  0.710  1.0
  O  O34  1  0.541  0.858  0.210  1.0
  O  O35  1  0.041  0.142  0.290  1.0
  O  O36  1  0.306  0.997  0.932  1.0
  O  O37  1  0.806  0.003  0.568  1.0
  O  O38  1  0.694  0.003  0.068  1.0
  O  O39  1  0.194  0.997  0.432  1.0
  O  O40  1  0.653  0.774  0.912  1.0
  O  O41  1  0.153  0.226  0.588  1.0
  O  O42  1  0.347  0.226  0.088  1.0
  O  O43  1  0.847  0.774  0.412  1.0
  O  O44  1  0.451  0.652  0.006  1.0
  O  O45  1  0.951  0.348  0.494  1.0
  O  O46  1  0.549  0.348  0.994  1.0
  O  O47  1  0.049  0.652  0.506  1.0
  O  O48  1  0.099  0.341  0.520  1.0
  O  O49  1  0.599  0.659  0.980  1.0
  O  O50  1  0.901  0.659  0.480  1.0
  O  O51  1  0.401  0.341  0.020  1.0
[/CIF]
.