The compound described by ZrVGe crystallizes in the tetragonal I4/mmm space group. Zr(1) is bonded in a 5-coordinate geometry to four equivalent V(1) and five equivalent Ge(1) atoms. V(1) is bonded to four equivalent Zr(1), four equivalent V(1), and four equivalent Ge(1) atoms to form a mixture of distorted face and corner-sharing VZr4V4Ge4 cuboctahedra. Ge(1) is bonded in a 9-coordinate geometry to five equivalent Zr(1) and four equivalent V(1) atoms. is represented by the CIF file [CIF]
data_ZrVGe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.735
_cell_length_b   3.735
_cell_length_c   7.729
_cell_angle_alpha   103.982
_cell_angle_beta   103.982
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   101.335
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.676  0.676  0.352  1.0
  Zr  Zr1  1  0.324  0.324  0.648  1.0
  V  V2  1  0.000  0.500  0.000  1.0
  V  V3  1  0.500  0.000  0.000  1.0
  Ge  Ge4  1  0.127  0.127  0.253  1.0
  Ge  Ge5  1  0.873  0.873  0.747  1.0
[/CIF]
.
The compound described by ZrVGe crystallizes in the tetragonal I4/mmm space group. Zr(1) is bonded in a 5-coordinate geometry to four equivalent V(1) and five equivalent Ge(1) atoms. V(1) is bonded to four equivalent Zr(1), four equivalent V(1), and four equivalent Ge(1) atoms to form a mixture of distorted face and corner-sharing VZr4V4Ge4 cuboctahedra. Ge(1) is bonded in a 9-coordinate geometry to five equivalent Zr(1) and four equivalent V(1) atoms. is represented by the CIF file [CIF]
data_ZrVGe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.735
_cell_length_b   3.735
_cell_length_c   7.729
_cell_angle_alpha   103.982
_cell_angle_beta   103.982
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   101.335
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.676  0.676  0.352  1.0
  Zr  Zr1  1  0.324  0.324  0.648  1.0
  V  V2  1  0.000  0.500  0.000  1.0
  V  V3  1  0.500  0.000  0.000  1.0
  Ge  Ge4  1  0.127  0.127  0.253  1.0
  Ge  Ge5  1  0.873  0.873  0.747  1.0
[/CIF]
.