The compound described by Li5VP3O11 crystallizes in the triclinic P-1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(5), one O(7), one O(8), and one O(9) atom to form LiO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with three equivalent P(3)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Li(4)O5 trigonal bipyramid. In the second Li site, Li(2) is bonded to one O(1), one O(4), one O(5), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra, corners with two equivalent Li(1)O5 trigonal bipyramids, and corners with three equivalent Li(4)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 42°. In the third Li site, Li(3) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(4), one O(5), and one O(8) atom. In the fourth Li site, Li(4) is bonded to one O(1), one O(3), one O(4), one O(8), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one P(2)O4 tetrahedra, and  an edgeedge with one Li(1)O5 trigonal bipyramid. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(3), one O(6), one O(7), and two equivalent O(10) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(10), and two equivalent O(3) atoms to form distorted VO6 octahedra that share corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, edges with two equivalent P(2)O4 tetrahedra, and edges with two equivalent Li(4)O5 trigonal bipyramids. In the second V site, V(2) is bonded to two equivalent O(11), two equivalent O(6), and two equivalent O(7) atoms to form VO6 octahedra that share corners with two equivalent P(3)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra, and edges with two equivalent Li(1)O5 trigonal bipyramids. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 55-69°. In the second P site, P(2) is bonded to one O(1), one O(10), one O(4), and one O(9) atom to form PO4 tetrahedra that share corners with three equivalent Li(2)O4 tetrahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one Li(4)O5 trigonal bipyramid. In the third P site, P(3) is bonded to one O(11), one O(2), one O(5), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one Li(4)O5 trigonal bipyramid, and corners with three equivalent Li(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 63°. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Li(4), one V(1), and one P(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Li(5), one V(1), and one P(1) atom. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Li(4), and one P(2) atom to form distorted OLi3P trigonal pyramids that share  a cornercorner with one O(11)Li2VP tetrahedra,  a cornercorner with one O(10)Li2VP trigonal pyramid, corners with two equivalent O(8)Li3P trigonal pyramids, and  an edgeedge with one O(5)Li3P tetrahedra. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), and one P(3) atom to form distorted OLi3P tetrahedra that share corners with three equivalent O(11)Li2VP tetrahedra,  a cornercorner with one O(7)Li2VP trigonal pyramid, corners with three equivalent O(8)Li3P trigonal pyramids, and  an edgeedge with one O(4)Li3P trigonal pyramid. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(5), one V(2), and one P(1) atom. In the seventh O site, O(7) is bonded to one Li(1), one Li(5), one V(2), and one P(1) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(11)Li2VP tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(7)Li2VP trigonal pyramid,  a cornercorner with one O(8)Li3P trigonal pyramid, corners with two equivalent O(10)Li2VP trigonal pyramids, and  an edgeedge with one O(11)Li2VP tetrahedra. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(4), and one P(3) atom to form distorted OLi3P trigonal pyramids that share  a cornercorner with one O(11)Li2VP tetrahedra, corners with three equivalent O(5)Li3P tetrahedra,  a cornercorner with one O(7)Li2VP trigonal pyramid, corners with two equivalent O(4)Li3P trigonal pyramids, and  an edgeedge with one O(11)Li2VP tetrahedra. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(2), one Li(4), and one P(2) atom. In the tenth O site, O(10) is bonded to two equivalent Li(5), one V(1), and one P(2) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(10)Li2VP trigonal pyramid,  a cornercorner with one O(4)Li3P trigonal pyramid, corners with two equivalent O(7)Li2VP trigonal pyramids, and  an edgeedge with one O(10)Li2VP trigonal pyramid. In the eleventh O site, O(11) is bonded to one Li(1), one Li(3), one V(2), and one P(3) atom to form distorted OLi2VP tetrahedra that share  a cornercorner with one O(11)Li2VP tetrahedra, corners with three equivalent O(5)Li3P tetrahedra,  a cornercorner with one O(7)Li2VP trigonal pyramid,  a cornercorner with one O(4)Li3P trigonal pyramid,  a cornercorner with one O(8)Li3P trigonal pyramid,  an edgeedge with one O(7)Li2VP trigonal pyramid, and  an edgeedge with one O(8)Li3P trigonal pyramid. is represented by the CIF file [CIF]
data_Li5VP3O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.375
_cell_length_b   8.529
_cell_length_c   9.645
_cell_angle_alpha   84.751
_cell_angle_beta   88.351
_cell_angle_gamma   85.099
_symmetry_Int_Tables_number   1
_cell_volume   438.588
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.780  0.671  0.658  1.0
  Li  Li1  1  0.706  0.379  0.167  1.0
  Li  Li2  1  0.673  0.617  0.321  1.0
  Li  Li3  1  0.832  0.381  0.841  1.0
  Li  Li4  1  0.489  0.996  0.162  1.0
  Li  Li5  1  0.511  0.004  0.838  1.0
  Li  Li6  1  0.168  0.619  0.159  1.0
  Li  Li7  1  0.327  0.383  0.679  1.0
  Li  Li8  1  0.294  0.621  0.833  1.0
  Li  Li9  1  0.220  0.329  0.342  1.0
  V  V10  1  0.000  0.000  0.000  1.0
  V  V11  1  0.500  0.000  0.500  1.0
  P  P12  1  0.964  0.050  0.686  1.0
  P  P13  1  0.787  0.706  0.985  1.0
  P  P14  1  0.730  0.328  0.520  1.0
  P  P15  1  0.270  0.672  0.480  1.0
  P  P16  1  0.213  0.294  0.015  1.0
  P  P17  1  0.036  0.950  0.314  1.0
  O  O18  1  0.061  0.744  0.943  1.0
  O  O19  1  0.948  0.188  0.558  1.0
  O  O20  1  0.874  0.134  0.815  1.0
  O  O21  1  0.789  0.604  0.127  1.0
  O  O22  1  0.819  0.400  0.378  1.0
  O  O23  1  0.760  0.011  0.314  1.0
  O  O24  1  0.775  0.931  0.661  1.0
  O  O25  1  0.710  0.435  0.640  1.0
  O  O26  1  0.666  0.623  0.870  1.0
  O  O27  1  0.652  0.873  0.005  1.0
  O  O28  1  0.521  0.748  0.485  1.0
  O  O29  1  0.479  0.252  0.515  1.0
  O  O30  1  0.348  0.127  0.995  1.0
  O  O31  1  0.334  0.377  0.130  1.0
  O  O32  1  0.290  0.565  0.360  1.0
  O  O33  1  0.225  0.069  0.339  1.0
  O  O34  1  0.240  0.989  0.686  1.0
  O  O35  1  0.181  0.600  0.622  1.0
  O  O36  1  0.211  0.396  0.873  1.0
  O  O37  1  0.126  0.866  0.185  1.0
  O  O38  1  0.052  0.812  0.442  1.0
  O  O39  1  0.939  0.256  0.057  1.0
[/CIF]
.
The compound described by Li5VP3O11 crystallizes in the triclinic P-1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(5), one O(7), one O(8), and one O(9) atom to form LiO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra, corners with three equivalent P(3)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Li(4)O5 trigonal bipyramid. In the second Li site, Li(2) is bonded to one O(1), one O(4), one O(5), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra, corners with two equivalent Li(1)O5 trigonal bipyramids, and corners with three equivalent Li(4)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 42°. In the third Li site, Li(3) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(4), one O(5), and one O(8) atom. In the fourth Li site, Li(4) is bonded to one O(1), one O(3), one O(4), one O(8), and one O(9) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one P(2)O4 tetrahedra, and  an edgeedge with one Li(1)O5 trigonal bipyramid. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(3), one O(6), one O(7), and two equivalent O(10) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(1), two equivalent O(10), and two equivalent O(3) atoms to form distorted VO6 octahedra that share corners with two equivalent Li(2)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, edges with two equivalent P(2)O4 tetrahedra, and edges with two equivalent Li(4)O5 trigonal bipyramids. In the second V site, V(2) is bonded to two equivalent O(11), two equivalent O(6), and two equivalent O(7) atoms to form VO6 octahedra that share corners with two equivalent P(3)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra, and edges with two equivalent Li(1)O5 trigonal bipyramids. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 55-69°. In the second P site, P(2) is bonded to one O(1), one O(10), one O(4), and one O(9) atom to form PO4 tetrahedra that share corners with three equivalent Li(2)O4 tetrahedra,  a cornercorner with one Li(1)O5 trigonal bipyramid,  a cornercorner with one Li(4)O5 trigonal bipyramid,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one Li(4)O5 trigonal bipyramid. In the third P site, P(3) is bonded to one O(11), one O(2), one O(5), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one Li(4)O5 trigonal bipyramid, and corners with three equivalent Li(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 63°. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Li(4), one V(1), and one P(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Li(5), one V(1), and one P(1) atom. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Li(4), and one P(2) atom to form distorted OLi3P trigonal pyramids that share  a cornercorner with one O(11)Li2VP tetrahedra,  a cornercorner with one O(10)Li2VP trigonal pyramid, corners with two equivalent O(8)Li3P trigonal pyramids, and  an edgeedge with one O(5)Li3P tetrahedra. In the fifth O site, O(5) is bonded to one Li(1), one Li(2), one Li(3), and one P(3) atom to form distorted OLi3P tetrahedra that share corners with three equivalent O(11)Li2VP tetrahedra,  a cornercorner with one O(7)Li2VP trigonal pyramid, corners with three equivalent O(8)Li3P trigonal pyramids, and  an edgeedge with one O(4)Li3P trigonal pyramid. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(5), one V(2), and one P(1) atom. In the seventh O site, O(7) is bonded to one Li(1), one Li(5), one V(2), and one P(1) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(11)Li2VP tetrahedra,  a cornercorner with one O(5)Li3P tetrahedra,  a cornercorner with one O(7)Li2VP trigonal pyramid,  a cornercorner with one O(8)Li3P trigonal pyramid, corners with two equivalent O(10)Li2VP trigonal pyramids, and  an edgeedge with one O(11)Li2VP tetrahedra. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(4), and one P(3) atom to form distorted OLi3P trigonal pyramids that share  a cornercorner with one O(11)Li2VP tetrahedra, corners with three equivalent O(5)Li3P tetrahedra,  a cornercorner with one O(7)Li2VP trigonal pyramid, corners with two equivalent O(4)Li3P trigonal pyramids, and  an edgeedge with one O(11)Li2VP tetrahedra. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(2), one Li(4), and one P(2) atom. In the tenth O site, O(10) is bonded to two equivalent Li(5), one V(1), and one P(2) atom to form distorted OLi2VP trigonal pyramids that share  a cornercorner with one O(10)Li2VP trigonal pyramid,  a cornercorner with one O(4)Li3P trigonal pyramid, corners with two equivalent O(7)Li2VP trigonal pyramids, and  an edgeedge with one O(10)Li2VP trigonal pyramid. In the eleventh O site, O(11) is bonded to one Li(1), one Li(3), one V(2), and one P(3) atom to form distorted OLi2VP tetrahedra that share  a cornercorner with one O(11)Li2VP tetrahedra, corners with three equivalent O(5)Li3P tetrahedra,  a cornercorner with one O(7)Li2VP trigonal pyramid,  a cornercorner with one O(4)Li3P trigonal pyramid,  a cornercorner with one O(8)Li3P trigonal pyramid,  an edgeedge with one O(7)Li2VP trigonal pyramid, and  an edgeedge with one O(8)Li3P trigonal pyramid. is represented by the CIF file [CIF]
data_Li5VP3O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.375
_cell_length_b   8.529
_cell_length_c   9.645
_cell_angle_alpha   84.751
_cell_angle_beta   88.351
_cell_angle_gamma   85.099
_symmetry_Int_Tables_number   1
_cell_volume   438.588
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.780  0.671  0.658  1.0
  Li  Li1  1  0.706  0.379  0.167  1.0
  Li  Li2  1  0.673  0.617  0.321  1.0
  Li  Li3  1  0.832  0.381  0.841  1.0
  Li  Li4  1  0.489  0.996  0.162  1.0
  Li  Li5  1  0.511  0.004  0.838  1.0
  Li  Li6  1  0.168  0.619  0.159  1.0
  Li  Li7  1  0.327  0.383  0.679  1.0
  Li  Li8  1  0.294  0.621  0.833  1.0
  Li  Li9  1  0.220  0.329  0.342  1.0
  V  V10  1  0.000  0.000  0.000  1.0
  V  V11  1  0.500  0.000  0.500  1.0
  P  P12  1  0.964  0.050  0.686  1.0
  P  P13  1  0.787  0.706  0.985  1.0
  P  P14  1  0.730  0.328  0.520  1.0
  P  P15  1  0.270  0.672  0.480  1.0
  P  P16  1  0.213  0.294  0.015  1.0
  P  P17  1  0.036  0.950  0.314  1.0
  O  O18  1  0.061  0.744  0.943  1.0
  O  O19  1  0.948  0.188  0.558  1.0
  O  O20  1  0.874  0.134  0.815  1.0
  O  O21  1  0.789  0.604  0.127  1.0
  O  O22  1  0.819  0.400  0.378  1.0
  O  O23  1  0.760  0.011  0.314  1.0
  O  O24  1  0.775  0.931  0.661  1.0
  O  O25  1  0.710  0.435  0.640  1.0
  O  O26  1  0.666  0.623  0.870  1.0
  O  O27  1  0.652  0.873  0.005  1.0
  O  O28  1  0.521  0.748  0.485  1.0
  O  O29  1  0.479  0.252  0.515  1.0
  O  O30  1  0.348  0.127  0.995  1.0
  O  O31  1  0.334  0.377  0.130  1.0
  O  O32  1  0.290  0.565  0.360  1.0
  O  O33  1  0.225  0.069  0.339  1.0
  O  O34  1  0.240  0.989  0.686  1.0
  O  O35  1  0.181  0.600  0.622  1.0
  O  O36  1  0.211  0.396  0.873  1.0
  O  O37  1  0.126  0.866  0.185  1.0
  O  O38  1  0.052  0.812  0.442  1.0
  O  O39  1  0.939  0.256  0.057  1.0
[/CIF]
.