The compound described by Y6Co2In crystallizes in the orthorhombic Immm space group. There are three inequivalent Y sites. In the first Y site, Y(1) is bonded in a 4-coordinate geometry to one Co(1), one Co(2), one In(1), and one In(2) atom. In the second Y site, Y(2) is bonded in a 5-coordinate geometry to one Co(1), two equivalent Co(2), one In(1), and one In(2) atom. In the third Y site, Y(3) is bonded in a 4-coordinate geometry to one Co(2), two equivalent Co(1), and one In(1) atom. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 9-coordinate geometry to two equivalent Y(1), two equivalent Y(2), four equivalent Y(3), and one Co(1) atom. In the second Co site, Co(2) is bonded in a 9-coordinate geometry to two equivalent Y(1), two equivalent Y(3), four equivalent Y(2), and one Co(2) atom. There are two inequivalent In sites. In the first In site, In(1) is bonded in a cuboctahedral geometry to four equivalent Y(1), four equivalent Y(2), and four equivalent Y(3) atoms. In the second In site, In(2) is bonded in a body-centered cubic geometry to four equivalent Y(1) and four equivalent Y(2) atoms. is represented by the CIF file [CIF]
data_Y6InCo2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.455
_cell_length_b   8.455
_cell_length_c   8.455
_cell_angle_alpha   111.201
_cell_angle_beta   109.838
_cell_angle_gamma   107.398
_symmetry_Int_Tables_number   1
_cell_volume   464.820
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.441  0.228  0.213  1.0
  Y  Y1  1  0.559  0.772  0.787  1.0
  Y  Y2  1  0.016  0.228  0.787  1.0
  Y  Y3  1  0.984  0.772  0.213  1.0
  Y  Y4  1  0.185  0.290  0.475  1.0
  Y  Y5  1  0.815  0.710  0.525  1.0
  Y  Y6  1  0.185  0.710  0.896  1.0
  Y  Y7  1  0.815  0.290  0.104  1.0
  Y  Y8  1  0.318  0.617  0.299  1.0
  Y  Y9  1  0.682  0.383  0.701  1.0
  Y  Y10  1  0.318  0.018  0.701  1.0
  Y  Y11  1  0.682  0.982  0.299  1.0
  In  In12  1  0.500  0.500  0.000  1.0
  In  In13  1  1.000  1.000  1.000  1.0
  Co  Co14  1  0.385  1.000  0.385  1.0
  Co  Co15  1  0.615  0.000  0.615  1.0
  Co  Co16  1  0.108  0.608  0.500  1.0
  Co  Co17  1  0.892  0.392  0.500  1.0
[/CIF]
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The compound described by Y6Co2In crystallizes in the orthorhombic Immm space group. There are three inequivalent Y sites. In the first Y site, Y(1) is bonded in a 4-coordinate geometry to one Co(1), one Co(2), one In(1), and one In(2) atom. In the second Y site, Y(2) is bonded in a 5-coordinate geometry to one Co(1), two equivalent Co(2), one In(1), and one In(2) atom. In the third Y site, Y(3) is bonded in a 4-coordinate geometry to one Co(2), two equivalent Co(1), and one In(1) atom. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 9-coordinate geometry to two equivalent Y(1), two equivalent Y(2), four equivalent Y(3), and one Co(1) atom. In the second Co site, Co(2) is bonded in a 9-coordinate geometry to two equivalent Y(1), two equivalent Y(3), four equivalent Y(2), and one Co(2) atom. There are two inequivalent In sites. In the first In site, In(1) is bonded in a cuboctahedral geometry to four equivalent Y(1), four equivalent Y(2), and four equivalent Y(3) atoms. In the second In site, In(2) is bonded in a body-centered cubic geometry to four equivalent Y(1) and four equivalent Y(2) atoms. is represented by the CIF file [CIF]
data_Y6InCo2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.455
_cell_length_b   8.455
_cell_length_c   8.455
_cell_angle_alpha   111.201
_cell_angle_beta   109.838
_cell_angle_gamma   107.398
_symmetry_Int_Tables_number   1
_cell_volume   464.820
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.441  0.228  0.213  1.0
  Y  Y1  1  0.559  0.772  0.787  1.0
  Y  Y2  1  0.016  0.228  0.787  1.0
  Y  Y3  1  0.984  0.772  0.213  1.0
  Y  Y4  1  0.185  0.290  0.475  1.0
  Y  Y5  1  0.815  0.710  0.525  1.0
  Y  Y6  1  0.185  0.710  0.896  1.0
  Y  Y7  1  0.815  0.290  0.104  1.0
  Y  Y8  1  0.318  0.617  0.299  1.0
  Y  Y9  1  0.682  0.383  0.701  1.0
  Y  Y10  1  0.318  0.018  0.701  1.0
  Y  Y11  1  0.682  0.982  0.299  1.0
  In  In12  1  0.500  0.500  0.000  1.0
  In  In13  1  1.000  1.000  1.000  1.0
  Co  Co14  1  0.385  1.000  0.385  1.0
  Co  Co15  1  0.615  0.000  0.615  1.0
  Co  Co16  1  0.108  0.608  0.500  1.0
  Co  Co17  1  0.892  0.392  0.500  1.0
[/CIF]
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