The material structure described by Rb2Mo6H2OCl14 crystallizes in the monoclinic Cc space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 6-coordinate geometry to one Cl(6), one Cl(8), two equivalent Cl(1), and two equivalent Cl(11) atoms. In the second Rb site, Rb(2) is bonded in a 5-coordinate geometry to one O(1), two equivalent Cl(14), and two equivalent Cl(4) atoms. There are six inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a square pyramidal geometry to one Cl(10), one Cl(12), one Cl(2), one Cl(5), and one Cl(8) atom. In the second Mo site, Mo(2) is bonded in a distorted T-shaped geometry to one Cl(1), one Cl(12), and one Cl(9) atom. In the third Mo site, Mo(3) is bonded in a distorted T-shaped geometry to one Cl(11), one Cl(5), and one Cl(7) atom. In the fourth Mo site, Mo(4) is bonded in a distorted T-shaped geometry to one Cl(14), one Cl(2), and one Cl(3) atom. In the fifth Mo site, Mo(5) is bonded in a distorted T-shaped geometry to one Cl(10), one Cl(13), and one Cl(4) atom. In the sixth Mo site, Mo(6) is bonded in a square pyramidal geometry to one Cl(13), one Cl(3), one Cl(6), one Cl(7), and one Cl(9) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted water-like geometry to one Rb(2), one H(1), and one H(2) atom. There are fourteen inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Rb(1) and one Mo(2) atom. In the second Cl site, Cl(2) is bonded in a distorted L-shaped geometry to one Mo(1) and one Mo(4) atom. In the third Cl site, Cl(3) is bonded in a distorted L-shaped geometry to one Mo(4) and one Mo(6) atom. In the fourth Cl site, Cl(4) is bonded in a trigonal non-coplanar geometry to two equivalent Rb(2) and one Mo(5) atom. In the fifth Cl site, Cl(5) is bonded in a distorted L-shaped geometry to one Mo(1) and one Mo(3) atom. In the sixth Cl site, Cl(6) is bonded in a distorted bent 120 degrees geometry to one Rb(1) and one Mo(6) atom. In the seventh Cl site, Cl(7) is bonded in a distorted L-shaped geometry to one Mo(3) and one Mo(6) atom. In the eighth Cl site, Cl(8) is bonded in a distorted bent 120 degrees geometry to one Rb(1) and one Mo(1) atom. In the ninth Cl site, Cl(9) is bonded in a distorted L-shaped geometry to one Mo(2) and one Mo(6) atom. In the tenth Cl site, Cl(10) is bonded in a distorted L-shaped geometry to one Mo(1) and one Mo(5) atom. In the eleventh Cl site, Cl(11) is bonded in a distorted trigonal planar geometry to two equivalent Rb(1) and one Mo(3) atom. In the twelfth Cl site, Cl(12) is bonded in a distorted L-shaped geometry to one Mo(1) and one Mo(2) atom. In the thirteenth Cl site, Cl(13) is bonded in a distorted L-shaped geometry to one Mo(5) and one Mo(6) atom. In the fourteenth Cl site, Cl(14) is bonded in a trigonal non-coplanar geometry to two equivalent Rb(2) and one Mo(4) atom. is represented by the CIF file [CIF]
data_Rb2Mo6H2Cl14O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.311
_cell_length_b   13.311
_cell_length_c   10.237
_cell_angle_alpha   70.129
_cell_angle_beta   70.129
_cell_angle_gamma   77.001
_symmetry_Int_Tables_number   1
_cell_volume   1592.013
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.552  0.446  0.752  1.0
  Rb  Rb1  1  0.446  0.552  0.252  1.0
  Rb  Rb2  1  0.044  0.957  0.026  1.0
  Rb  Rb3  1  0.957  0.044  0.526  1.0
  Mo  Mo4  1  0.525  0.083  0.657  1.0
  Mo  Mo5  1  0.083  0.525  0.157  1.0
  Mo  Mo6  1  0.472  0.830  0.700  1.0
  Mo  Mo7  1  0.830  0.472  0.200  1.0
  Mo  Mo8  1  0.532  0.163  0.296  1.0
  Mo  Mo9  1  0.163  0.532  0.796  1.0
  Mo  Mo10  1  0.311  0.059  0.565  1.0
  Mo  Mo11  1  0.059  0.311  0.065  1.0
  Mo  Mo12  1  0.689  0.936  0.434  1.0
  Mo  Mo13  1  0.936  0.689  0.934  1.0
  Mo  Mo14  1  0.475  0.912  0.341  1.0
  Mo  Mo15  1  0.912  0.475  0.841  1.0
  H  H16  1  0.174  0.746  0.245  1.0
  H  H17  1  0.746  0.174  0.745  1.0
  H  H18  1  0.250  0.832  0.200  1.0
  H  H19  1  0.832  0.250  0.700  1.0
  Cl  Cl20  1  0.465  0.659  0.893  1.0
  Cl  Cl21  1  0.659  0.465  0.393  1.0
  Cl  Cl22  1  0.371  0.217  0.591  1.0
  Cl  Cl23  1  0.217  0.371  0.091  1.0
  Cl  Cl24  1  0.293  0.887  0.525  1.0
  Cl  Cl25  1  0.887  0.293  0.025  1.0
  Cl  Cl26  1  0.885  0.898  0.365  1.0
  Cl  Cl27  1  0.898  0.885  0.865  1.0
  Cl  Cl28  1  0.653  0.183  0.427  1.0
  Cl  Cl29  1  0.183  0.653  0.927  1.0
  Cl  Cl30  1  0.447  0.821  0.190  1.0
  Cl  Cl31  1  0.821  0.447  0.690  1.0
  Cl  Cl32  1  0.401  0.099  0.221  1.0
  Cl  Cl33  1  0.099  0.401  0.721  1.0
  Cl  Cl34  1  0.555  0.172  0.810  1.0
  Cl  Cl35  1  0.172  0.555  0.310  1.0
  Cl  Cl36  1  0.558  0.743  0.496  1.0
  Cl  Cl37  1  0.743  0.558  0.996  1.0
  Cl  Cl38  1  0.674  0.931  0.690  1.0
  Cl  Cl39  1  0.931  0.674  0.190  1.0
  Cl  Cl40  1  0.543  0.340  0.114  1.0
  Cl  Cl41  1  0.340  0.543  0.614  1.0
  Cl  Cl42  1  0.392  0.963  0.850  1.0
  Cl  Cl43  1  0.963  0.392  0.350  1.0
  Cl  Cl44  1  0.663  0.956  0.192  1.0
  Cl  Cl45  1  0.956  0.663  0.692  1.0
  Cl  Cl46  1  0.118  0.105  0.668  1.0
  Cl  Cl47  1  0.105  0.118  0.168  1.0
  O  O48  1  0.181  0.822  0.197  1.0
  O  O49  1  0.822  0.181  0.697  1.0
[/CIF]
.
The material structure described by Rb2Mo6H2OCl14 crystallizes in the monoclinic Cc space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 6-coordinate geometry to one Cl(6), one Cl(8), two equivalent Cl(1), and two equivalent Cl(11) atoms. In the second Rb site, Rb(2) is bonded in a 5-coordinate geometry to one O(1), two equivalent Cl(14), and two equivalent Cl(4) atoms. There are six inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a square pyramidal geometry to one Cl(10), one Cl(12), one Cl(2), one Cl(5), and one Cl(8) atom. In the second Mo site, Mo(2) is bonded in a distorted T-shaped geometry to one Cl(1), one Cl(12), and one Cl(9) atom. In the third Mo site, Mo(3) is bonded in a distorted T-shaped geometry to one Cl(11), one Cl(5), and one Cl(7) atom. In the fourth Mo site, Mo(4) is bonded in a distorted T-shaped geometry to one Cl(14), one Cl(2), and one Cl(3) atom. In the fifth Mo site, Mo(5) is bonded in a distorted T-shaped geometry to one Cl(10), one Cl(13), and one Cl(4) atom. In the sixth Mo site, Mo(6) is bonded in a square pyramidal geometry to one Cl(13), one Cl(3), one Cl(6), one Cl(7), and one Cl(9) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted water-like geometry to one Rb(2), one H(1), and one H(2) atom. There are fourteen inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Rb(1) and one Mo(2) atom. In the second Cl site, Cl(2) is bonded in a distorted L-shaped geometry to one Mo(1) and one Mo(4) atom. In the third Cl site, Cl(3) is bonded in a distorted L-shaped geometry to one Mo(4) and one Mo(6) atom. In the fourth Cl site, Cl(4) is bonded in a trigonal non-coplanar geometry to two equivalent Rb(2) and one Mo(5) atom. In the fifth Cl site, Cl(5) is bonded in a distorted L-shaped geometry to one Mo(1) and one Mo(3) atom. In the sixth Cl site, Cl(6) is bonded in a distorted bent 120 degrees geometry to one Rb(1) and one Mo(6) atom. In the seventh Cl site, Cl(7) is bonded in a distorted L-shaped geometry to one Mo(3) and one Mo(6) atom. In the eighth Cl site, Cl(8) is bonded in a distorted bent 120 degrees geometry to one Rb(1) and one Mo(1) atom. In the ninth Cl site, Cl(9) is bonded in a distorted L-shaped geometry to one Mo(2) and one Mo(6) atom. In the tenth Cl site, Cl(10) is bonded in a distorted L-shaped geometry to one Mo(1) and one Mo(5) atom. In the eleventh Cl site, Cl(11) is bonded in a distorted trigonal planar geometry to two equivalent Rb(1) and one Mo(3) atom. In the twelfth Cl site, Cl(12) is bonded in a distorted L-shaped geometry to one Mo(1) and one Mo(2) atom. In the thirteenth Cl site, Cl(13) is bonded in a distorted L-shaped geometry to one Mo(5) and one Mo(6) atom. In the fourteenth Cl site, Cl(14) is bonded in a trigonal non-coplanar geometry to two equivalent Rb(2) and one Mo(4) atom. is represented by the CIF file [CIF]
data_Rb2Mo6H2Cl14O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.311
_cell_length_b   13.311
_cell_length_c   10.237
_cell_angle_alpha   70.129
_cell_angle_beta   70.129
_cell_angle_gamma   77.001
_symmetry_Int_Tables_number   1
_cell_volume   1592.013
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.552  0.446  0.752  1.0
  Rb  Rb1  1  0.446  0.552  0.252  1.0
  Rb  Rb2  1  0.044  0.957  0.026  1.0
  Rb  Rb3  1  0.957  0.044  0.526  1.0
  Mo  Mo4  1  0.525  0.083  0.657  1.0
  Mo  Mo5  1  0.083  0.525  0.157  1.0
  Mo  Mo6  1  0.472  0.830  0.700  1.0
  Mo  Mo7  1  0.830  0.472  0.200  1.0
  Mo  Mo8  1  0.532  0.163  0.296  1.0
  Mo  Mo9  1  0.163  0.532  0.796  1.0
  Mo  Mo10  1  0.311  0.059  0.565  1.0
  Mo  Mo11  1  0.059  0.311  0.065  1.0
  Mo  Mo12  1  0.689  0.936  0.434  1.0
  Mo  Mo13  1  0.936  0.689  0.934  1.0
  Mo  Mo14  1  0.475  0.912  0.341  1.0
  Mo  Mo15  1  0.912  0.475  0.841  1.0
  H  H16  1  0.174  0.746  0.245  1.0
  H  H17  1  0.746  0.174  0.745  1.0
  H  H18  1  0.250  0.832  0.200  1.0
  H  H19  1  0.832  0.250  0.700  1.0
  Cl  Cl20  1  0.465  0.659  0.893  1.0
  Cl  Cl21  1  0.659  0.465  0.393  1.0
  Cl  Cl22  1  0.371  0.217  0.591  1.0
  Cl  Cl23  1  0.217  0.371  0.091  1.0
  Cl  Cl24  1  0.293  0.887  0.525  1.0
  Cl  Cl25  1  0.887  0.293  0.025  1.0
  Cl  Cl26  1  0.885  0.898  0.365  1.0
  Cl  Cl27  1  0.898  0.885  0.865  1.0
  Cl  Cl28  1  0.653  0.183  0.427  1.0
  Cl  Cl29  1  0.183  0.653  0.927  1.0
  Cl  Cl30  1  0.447  0.821  0.190  1.0
  Cl  Cl31  1  0.821  0.447  0.690  1.0
  Cl  Cl32  1  0.401  0.099  0.221  1.0
  Cl  Cl33  1  0.099  0.401  0.721  1.0
  Cl  Cl34  1  0.555  0.172  0.810  1.0
  Cl  Cl35  1  0.172  0.555  0.310  1.0
  Cl  Cl36  1  0.558  0.743  0.496  1.0
  Cl  Cl37  1  0.743  0.558  0.996  1.0
  Cl  Cl38  1  0.674  0.931  0.690  1.0
  Cl  Cl39  1  0.931  0.674  0.190  1.0
  Cl  Cl40  1  0.543  0.340  0.114  1.0
  Cl  Cl41  1  0.340  0.543  0.614  1.0
  Cl  Cl42  1  0.392  0.963  0.850  1.0
  Cl  Cl43  1  0.963  0.392  0.350  1.0
  Cl  Cl44  1  0.663  0.956  0.192  1.0
  Cl  Cl45  1  0.956  0.663  0.692  1.0
  Cl  Cl46  1  0.118  0.105  0.668  1.0
  Cl  Cl47  1  0.105  0.118  0.168  1.0
  O  O48  1  0.181  0.822  0.197  1.0
  O  O49  1  0.822  0.181  0.697  1.0
[/CIF]
.