The crystal structure described by S8O is Indium-like structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four cyclooctasulfur oxide (s8o) molecules. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(2) and one S(8) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(2) and one S(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(3) and one S(5) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one S(4) and one S(6) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one S(5) and one S(7) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one S(6) and one S(8) atom. In the eighth S site, S(8) is bonded in a single-bond geometry to one S(1), one S(7), and one O(1) atom. O(1) is bonded in a single-bond geometry to one S(8) atom. is represented by the CIF file [CIF]
data_S8O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.249
_cell_length_b   8.166
_cell_length_c   13.439
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   905.335
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.523  0.498  0.358  1.0
  S  S1  1  0.477  0.998  0.642  1.0
  S  S2  1  0.477  0.498  0.858  1.0
  S  S3  1  0.523  0.998  0.142  1.0
  S  S4  1  0.481  0.356  0.475  1.0
  S  S5  1  0.519  0.856  0.525  1.0
  S  S6  1  0.519  0.356  0.975  1.0
  S  S7  1  0.481  0.856  0.025  1.0
  S  S8  1  0.640  0.418  0.589  1.0
  S  S9  1  0.360  0.918  0.411  1.0
  S  S10  1  0.360  0.418  0.089  1.0
  S  S11  1  0.640  0.918  0.911  1.0
  S  S12  1  0.822  0.248  0.589  1.0
  S  S13  1  0.178  0.748  0.411  1.0
  S  S14  1  0.178  0.248  0.089  1.0
  S  S15  1  0.822  0.748  0.911  1.0
  S  S16  1  0.022  0.352  0.527  1.0
  S  S17  1  0.978  0.852  0.473  1.0
  S  S18  1  0.978  0.352  0.027  1.0
  S  S19  1  0.022  0.852  0.973  1.0
  S  S20  1  0.035  0.284  0.379  1.0
  S  S21  1  0.965  0.784  0.621  1.0
  S  S22  1  0.965  0.284  0.879  1.0
  S  S23  1  0.035  0.784  0.121  1.0
  S  S24  1  0.929  0.456  0.296  1.0
  S  S25  1  0.071  0.956  0.704  1.0
  S  S26  1  0.071  0.456  0.796  1.0
  S  S27  1  0.929  0.956  0.204  1.0
  S  S28  1  0.687  0.846  0.236  1.0
  S  S29  1  0.313  0.346  0.764  1.0
  S  S30  1  0.313  0.846  0.736  1.0
  S  S31  1  0.687  0.346  0.264  1.0
  O  O32  1  0.689  0.683  0.189  1.0
  O  O33  1  0.311  0.183  0.811  1.0
  O  O34  1  0.311  0.683  0.689  1.0
  O  O35  1  0.689  0.183  0.311  1.0
[/CIF]
.
The crystal structure described by S8O is Indium-like structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four cyclooctasulfur oxide (s8o) molecules. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(2) and one S(8) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(2) and one S(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(3) and one S(5) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one S(4) and one S(6) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one S(5) and one S(7) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one S(6) and one S(8) atom. In the eighth S site, S(8) is bonded in a single-bond geometry to one S(1), one S(7), and one O(1) atom. O(1) is bonded in a single-bond geometry to one S(8) atom. is represented by the CIF file [CIF]
data_S8O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.249
_cell_length_b   8.166
_cell_length_c   13.439
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   905.335
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.523  0.498  0.358  1.0
  S  S1  1  0.477  0.998  0.642  1.0
  S  S2  1  0.477  0.498  0.858  1.0
  S  S3  1  0.523  0.998  0.142  1.0
  S  S4  1  0.481  0.356  0.475  1.0
  S  S5  1  0.519  0.856  0.525  1.0
  S  S6  1  0.519  0.356  0.975  1.0
  S  S7  1  0.481  0.856  0.025  1.0
  S  S8  1  0.640  0.418  0.589  1.0
  S  S9  1  0.360  0.918  0.411  1.0
  S  S10  1  0.360  0.418  0.089  1.0
  S  S11  1  0.640  0.918  0.911  1.0
  S  S12  1  0.822  0.248  0.589  1.0
  S  S13  1  0.178  0.748  0.411  1.0
  S  S14  1  0.178  0.248  0.089  1.0
  S  S15  1  0.822  0.748  0.911  1.0
  S  S16  1  0.022  0.352  0.527  1.0
  S  S17  1  0.978  0.852  0.473  1.0
  S  S18  1  0.978  0.352  0.027  1.0
  S  S19  1  0.022  0.852  0.973  1.0
  S  S20  1  0.035  0.284  0.379  1.0
  S  S21  1  0.965  0.784  0.621  1.0
  S  S22  1  0.965  0.284  0.879  1.0
  S  S23  1  0.035  0.784  0.121  1.0
  S  S24  1  0.929  0.456  0.296  1.0
  S  S25  1  0.071  0.956  0.704  1.0
  S  S26  1  0.071  0.456  0.796  1.0
  S  S27  1  0.929  0.956  0.204  1.0
  S  S28  1  0.687  0.846  0.236  1.0
  S  S29  1  0.313  0.346  0.764  1.0
  S  S30  1  0.313  0.846  0.736  1.0
  S  S31  1  0.687  0.346  0.264  1.0
  O  O32  1  0.689  0.683  0.189  1.0
  O  O33  1  0.311  0.183  0.811  1.0
  O  O34  1  0.311  0.683  0.689  1.0
  O  O35  1  0.689  0.183  0.311  1.0
[/CIF]
.