The crystal structure described by (Ag(NH3)2)2(AgN3H7O4)2(NH3)2(H2)2(NH2O)2H2O2(ClO2)2Cl2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 1333-74-0 molecule, one ammonia molecule, one hydrochloric acid atom, one hydroxychloride hydrate molecule, one hydroxylamine molecule, one water molecule, one Ag(NH3)2 cluster, and one AgN3H7O4 cluster. In the Ag(NH3)2 cluster, Ag(2) is bonded in a distorted bent 120 degrees geometry to one N(6) and one N(7) atom. There are two inequivalent N sites. In the first N site, N(6) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one H(11), one H(12), and one H(17) atom. In the second N site, N(7) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one H(18), one H(19), and one H(20) atom. There are six inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one N(6) atom. In the second H site, H(12) is bonded in a single-bond geometry to one N(6) atom. In the third H site, H(17) is bonded in a single-bond geometry to one N(6) atom. In the fourth H site, H(18) is bonded in a single-bond geometry to one N(7) atom. In the fifth H site, H(19) is bonded in a single-bond geometry to one N(7) atom. In the sixth H site, H(20) is bonded in a single-bond geometry to one N(7) atom. In the AgN3H7O4 cluster, Ag(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one N(4) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one Ag(1), one H(1), one H(2), and one O(7) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Ag(1) and one H(3) atom. In the third N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one H(4), one H(7), and one H(8) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(4) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(16) is bonded in a linear geometry to one O(4) and one O(8) atom. There are four inequivalent O sites. In the first O site, O(7) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(8) atom. In the second O site, O(8) is bonded in a distorted single-bond geometry to one H(16) and one O(7) atom. In the third O site, O(4) is bonded in a single-bond geometry to one H(16) and one O(5) atom. In the fourth O site, O(5) is bonded in a distorted single-bond geometry to one O(4) atom. is represented by the CIF file [CIF]
data_Ag2H21N7(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.185
_cell_length_b   8.714
_cell_length_c   9.087
_cell_angle_alpha   116.980
_cell_angle_beta   93.021
_cell_angle_gamma   92.424
_symmetry_Int_Tables_number   1
_cell_volume   575.229
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.256  0.053  0.039  1.0
  Ag  Ag1  1  0.727  0.052  0.043  1.0
  H  H2  1  0.141  0.843  0.230  1.0
  H  H3  1  0.334  0.815  0.188  1.0
  H  H4  1  0.179  0.836  0.719  1.0
  H  H5  1  0.326  0.383  0.123  1.0
  H  H6  1  0.598  0.543  0.637  1.0
  H  H7  1  0.810  0.744  0.791  1.0
  H  H8  1  0.160  0.378  0.216  1.0
  H  H9  1  0.345  0.385  0.306  1.0
  H  H10  1  0.670  0.731  0.914  1.0
  H  H11  1  0.834  0.622  0.885  1.0
  H  H12  1  0.814  0.220  0.353  1.0
  H  H13  1  0.614  0.216  0.340  1.0
  H  H14  1  0.712  0.294  0.630  1.0
  H  H15  1  0.589  0.387  0.787  1.0
  H  H16  1  0.841  0.969  0.515  1.0
  H  H17  1  0.109  0.185  0.510  1.0
  H  H18  1  0.705  0.055  0.355  1.0
  H  H19  1  0.727  0.305  0.987  1.0
  H  H20  1  0.845  0.186  0.842  1.0
  H  H21  1  0.644  0.148  0.798  1.0
  H  H22  1  0.824  0.876  0.450  1.0
  N  N23  1  0.254  0.908  0.247  1.0
  N  N24  1  0.256  0.839  0.815  1.0
  N  N25  1  0.749  0.664  0.828  1.0
  N  N26  1  0.275  0.334  0.195  1.0
  N  N27  1  0.595  0.292  0.667  1.0
  N  N28  1  0.710  0.139  0.304  1.0
  N  N29  1  0.736  0.180  0.890  1.0
  Cl  Cl30  1  0.801  0.536  0.208  1.0
  Cl  Cl31  1  0.275  0.552  0.839  1.0
  O  O32  1  0.511  0.478  0.544  1.0
  O  O33  1  0.126  0.607  0.934  1.0
  O  O34  1  0.424  0.552  0.949  1.0
  O  O35  1  0.046  0.286  0.504  1.0
  O  O36  1  0.944  0.338  0.626  1.0
  O  O37  1  0.481  0.306  0.564  1.0
  O  O38  1  0.309  0.973  0.421  1.0
  O  O39  1  0.188  0.041  0.520  1.0
[/CIF]
.
The crystal structure described by (Ag(NH3)2)2(AgN3H7O4)2(NH3)2(H2)2(NH2O)2H2O2(ClO2)2Cl2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 1333-74-0 molecule, one ammonia molecule, one hydrochloric acid atom, one hydroxychloride hydrate molecule, one hydroxylamine molecule, one water molecule, one Ag(NH3)2 cluster, and one AgN3H7O4 cluster. In the Ag(NH3)2 cluster, Ag(2) is bonded in a distorted bent 120 degrees geometry to one N(6) and one N(7) atom. There are two inequivalent N sites. In the first N site, N(6) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one H(11), one H(12), and one H(17) atom. In the second N site, N(7) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one H(18), one H(19), and one H(20) atom. There are six inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one N(6) atom. In the second H site, H(12) is bonded in a single-bond geometry to one N(6) atom. In the third H site, H(17) is bonded in a single-bond geometry to one N(6) atom. In the fourth H site, H(18) is bonded in a single-bond geometry to one N(7) atom. In the fifth H site, H(19) is bonded in a single-bond geometry to one N(7) atom. In the sixth H site, H(20) is bonded in a single-bond geometry to one N(7) atom. In the AgN3H7O4 cluster, Ag(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one N(4) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one Ag(1), one H(1), one H(2), and one O(7) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Ag(1) and one H(3) atom. In the third N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one H(4), one H(7), and one H(8) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(4) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(16) is bonded in a linear geometry to one O(4) and one O(8) atom. There are four inequivalent O sites. In the first O site, O(7) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(8) atom. In the second O site, O(8) is bonded in a distorted single-bond geometry to one H(16) and one O(7) atom. In the third O site, O(4) is bonded in a single-bond geometry to one H(16) and one O(5) atom. In the fourth O site, O(5) is bonded in a distorted single-bond geometry to one O(4) atom. is represented by the CIF file [CIF]
data_Ag2H21N7(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.185
_cell_length_b   8.714
_cell_length_c   9.087
_cell_angle_alpha   116.980
_cell_angle_beta   93.021
_cell_angle_gamma   92.424
_symmetry_Int_Tables_number   1
_cell_volume   575.229
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.256  0.053  0.039  1.0
  Ag  Ag1  1  0.727  0.052  0.043  1.0
  H  H2  1  0.141  0.843  0.230  1.0
  H  H3  1  0.334  0.815  0.188  1.0
  H  H4  1  0.179  0.836  0.719  1.0
  H  H5  1  0.326  0.383  0.123  1.0
  H  H6  1  0.598  0.543  0.637  1.0
  H  H7  1  0.810  0.744  0.791  1.0
  H  H8  1  0.160  0.378  0.216  1.0
  H  H9  1  0.345  0.385  0.306  1.0
  H  H10  1  0.670  0.731  0.914  1.0
  H  H11  1  0.834  0.622  0.885  1.0
  H  H12  1  0.814  0.220  0.353  1.0
  H  H13  1  0.614  0.216  0.340  1.0
  H  H14  1  0.712  0.294  0.630  1.0
  H  H15  1  0.589  0.387  0.787  1.0
  H  H16  1  0.841  0.969  0.515  1.0
  H  H17  1  0.109  0.185  0.510  1.0
  H  H18  1  0.705  0.055  0.355  1.0
  H  H19  1  0.727  0.305  0.987  1.0
  H  H20  1  0.845  0.186  0.842  1.0
  H  H21  1  0.644  0.148  0.798  1.0
  H  H22  1  0.824  0.876  0.450  1.0
  N  N23  1  0.254  0.908  0.247  1.0
  N  N24  1  0.256  0.839  0.815  1.0
  N  N25  1  0.749  0.664  0.828  1.0
  N  N26  1  0.275  0.334  0.195  1.0
  N  N27  1  0.595  0.292  0.667  1.0
  N  N28  1  0.710  0.139  0.304  1.0
  N  N29  1  0.736  0.180  0.890  1.0
  Cl  Cl30  1  0.801  0.536  0.208  1.0
  Cl  Cl31  1  0.275  0.552  0.839  1.0
  O  O32  1  0.511  0.478  0.544  1.0
  O  O33  1  0.126  0.607  0.934  1.0
  O  O34  1  0.424  0.552  0.949  1.0
  O  O35  1  0.046  0.286  0.504  1.0
  O  O36  1  0.944  0.338  0.626  1.0
  O  O37  1  0.481  0.306  0.564  1.0
  O  O38  1  0.309  0.973  0.421  1.0
  O  O39  1  0.188  0.041  0.520  1.0
[/CIF]
.