The compound described by Mn6O7F5 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(5), one O(6), one O(7), one F(1), and one F(2) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(4)O3F3 octahedra, corners with two equivalent Mn(5)O4F2 octahedra, corners with four equivalent Mn(6)O4F2 octahedra,  an edgeedge with one Mn(2)O3F3 octahedra, and  an edgeedge with one Mn(3)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 43-59°. In the second Mn site, Mn(2) is bonded to one O(2), one O(4), one O(6), one F(2), one F(3), and one F(4) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(5)O4F2 octahedra, corners with two equivalent Mn(6)O4F2 octahedra, corners with four equivalent Mn(4)O3F3 octahedra,  an edgeedge with one Mn(3)O3F3 octahedra, and  an edgeedge with one Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-54°. In the third Mn site, Mn(3) is bonded to one O(1), one O(4), one O(5), one F(1), one F(3), and one F(5) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(4)O3F3 octahedra, corners with two equivalent Mn(6)O4F2 octahedra, corners with four equivalent Mn(5)O4F2 octahedra,  an edgeedge with one Mn(2)O3F3 octahedra, and  an edgeedge with one Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-62°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(2), one O(7), one F(2), one F(3), and one F(4) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(3)O3F3 octahedra, corners with two equivalent Mn(1)O4F2 octahedra, corners with four equivalent Mn(2)O3F3 octahedra,  an edgeedge with one Mn(5)O4F2 octahedra, and  an edgeedge with one Mn(6)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(3), one O(4), one O(5), one F(4), and one F(5) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(2)O3F3 octahedra, corners with two equivalent Mn(1)O4F2 octahedra, corners with four equivalent Mn(3)O3F3 octahedra,  an edgeedge with one Mn(4)O3F3 octahedra, and  an edgeedge with one Mn(6)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-62°. In the sixth Mn site, Mn(6) is bonded to one O(2), one O(3), one O(6), one O(7), one F(1), and one F(5) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(2)O3F3 octahedra, corners with two equivalent Mn(3)O3F3 octahedra, corners with four equivalent Mn(1)O4F2 octahedra,  an edgeedge with one Mn(4)O3F3 octahedra, and  an edgeedge with one Mn(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-56°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(5) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(6) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(5) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(5) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(6) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(6) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted T-shaped geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(4) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(4) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(6) atom. is represented by the CIF card [CIF]
data_Mn6O7F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.630
_cell_length_b   7.764
_cell_length_c   5.598
_cell_angle_alpha   92.926
_cell_angle_beta   89.036
_cell_angle_gamma   90.593
_symmetry_Int_Tables_number   1
_cell_volume   200.948
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.466  0.011  0.484  1.0
  Mn  Mn1  1  0.516  0.666  0.160  1.0
  Mn  Mn2  1  0.523  0.335  0.827  1.0
  Mn  Mn3  1  0.993  0.676  0.673  1.0
  Mn  Mn4  1  0.967  0.324  0.347  1.0
  Mn  Mn5  1  0.009  0.983  0.009  1.0
  O  O6  1  0.806  0.451  0.634  1.0
  O  O7  1  0.812  0.767  0.967  1.0
  O  O8  1  0.802  0.091  0.290  1.0
  O  O9  1  0.695  0.433  0.129  1.0
  O  O10  1  0.307  0.238  0.535  1.0
  O  O11  1  0.305  0.891  0.199  1.0
  O  O12  1  0.200  0.898  0.709  1.0
  F  F13  1  0.712  0.091  0.798  1.0
  F  F14  1  0.687  0.780  0.471  1.0
  F  F15  1  0.297  0.566  0.869  1.0
  F  F16  1  0.197  0.573  0.371  1.0
  F  F17  1  0.204  0.225  0.028  1.0
[/CIF]
.
The compound described by Mn6O7F5 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(3), one O(5), one O(6), one O(7), one F(1), and one F(2) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(4)O3F3 octahedra, corners with two equivalent Mn(5)O4F2 octahedra, corners with four equivalent Mn(6)O4F2 octahedra,  an edgeedge with one Mn(2)O3F3 octahedra, and  an edgeedge with one Mn(3)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 43-59°. In the second Mn site, Mn(2) is bonded to one O(2), one O(4), one O(6), one F(2), one F(3), and one F(4) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(5)O4F2 octahedra, corners with two equivalent Mn(6)O4F2 octahedra, corners with four equivalent Mn(4)O3F3 octahedra,  an edgeedge with one Mn(3)O3F3 octahedra, and  an edgeedge with one Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-54°. In the third Mn site, Mn(3) is bonded to one O(1), one O(4), one O(5), one F(1), one F(3), and one F(5) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(4)O3F3 octahedra, corners with two equivalent Mn(6)O4F2 octahedra, corners with four equivalent Mn(5)O4F2 octahedra,  an edgeedge with one Mn(2)O3F3 octahedra, and  an edgeedge with one Mn(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-62°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(2), one O(7), one F(2), one F(3), and one F(4) atom to form MnO3F3 octahedra that share corners with two equivalent Mn(3)O3F3 octahedra, corners with two equivalent Mn(1)O4F2 octahedra, corners with four equivalent Mn(2)O3F3 octahedra,  an edgeedge with one Mn(5)O4F2 octahedra, and  an edgeedge with one Mn(6)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 45-54°. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(3), one O(4), one O(5), one F(4), and one F(5) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(2)O3F3 octahedra, corners with two equivalent Mn(1)O4F2 octahedra, corners with four equivalent Mn(3)O3F3 octahedra,  an edgeedge with one Mn(4)O3F3 octahedra, and  an edgeedge with one Mn(6)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 47-62°. In the sixth Mn site, Mn(6) is bonded to one O(2), one O(3), one O(6), one O(7), one F(1), and one F(5) atom to form MnO4F2 octahedra that share corners with two equivalent Mn(2)O3F3 octahedra, corners with two equivalent Mn(3)O3F3 octahedra, corners with four equivalent Mn(1)O4F2 octahedra,  an edgeedge with one Mn(4)O3F3 octahedra, and  an edgeedge with one Mn(5)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-56°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(3), one Mn(4), and one Mn(5) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(6) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(5), and one Mn(6) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(5) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(1), one Mn(3), and one Mn(5) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(6) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(4), and one Mn(6) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted T-shaped geometry to one Mn(1), one Mn(3), and one Mn(6) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Mn(4) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Mn(4) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(4), and one Mn(5) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Mn(3), one Mn(5), and one Mn(6) atom. is represented by the CIF card [CIF]
data_Mn6O7F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.630
_cell_length_b   7.764
_cell_length_c   5.598
_cell_angle_alpha   92.926
_cell_angle_beta   89.036
_cell_angle_gamma   90.593
_symmetry_Int_Tables_number   1
_cell_volume   200.948
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.466  0.011  0.484  1.0
  Mn  Mn1  1  0.516  0.666  0.160  1.0
  Mn  Mn2  1  0.523  0.335  0.827  1.0
  Mn  Mn3  1  0.993  0.676  0.673  1.0
  Mn  Mn4  1  0.967  0.324  0.347  1.0
  Mn  Mn5  1  0.009  0.983  0.009  1.0
  O  O6  1  0.806  0.451  0.634  1.0
  O  O7  1  0.812  0.767  0.967  1.0
  O  O8  1  0.802  0.091  0.290  1.0
  O  O9  1  0.695  0.433  0.129  1.0
  O  O10  1  0.307  0.238  0.535  1.0
  O  O11  1  0.305  0.891  0.199  1.0
  O  O12  1  0.200  0.898  0.709  1.0
  F  F13  1  0.712  0.091  0.798  1.0
  F  F14  1  0.687  0.780  0.471  1.0
  F  F15  1  0.297  0.566  0.869  1.0
  F  F16  1  0.197  0.573  0.371  1.0
  F  F17  1  0.204  0.225  0.028  1.0
[/CIF]
.