The compound described by Ag2S(NO)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one N(1) and one N(2) atom. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to one N(1), one N(2), one O(1), and one O(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one S(1) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one Ag(2), and one S(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Ag(2) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one S(1) atom. is represented by the CIF file [CIF]
data_Ag2S(NO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.498
_cell_length_b   7.593
_cell_length_c   10.726
_cell_angle_alpha   86.452
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   446.947
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.311  0.016  0.675  1.0
  Ag  Ag1  1  0.811  0.984  0.825  1.0
  Ag  Ag2  1  0.689  0.984  0.325  1.0
  Ag  Ag3  1  0.189  0.016  0.175  1.0
  Ag  Ag4  1  0.110  0.311  0.945  1.0
  Ag  Ag5  1  0.610  0.689  0.555  1.0
  Ag  Ag6  1  0.890  0.689  0.055  1.0
  Ag  Ag7  1  0.390  0.311  0.445  1.0
  S  S8  1  0.939  0.319  0.644  1.0
  S  S9  1  0.439  0.681  0.856  1.0
  S  S10  1  0.061  0.681  0.356  1.0
  S  S11  1  0.561  0.319  0.144  1.0
  N  N12  1  0.211  0.270  0.616  1.0
  N  N13  1  0.711  0.730  0.884  1.0
  N  N14  1  0.789  0.730  0.384  1.0
  N  N15  1  0.289  0.270  0.116  1.0
  N  N16  1  0.914  0.242  0.784  1.0
  N  N17  1  0.414  0.758  0.716  1.0
  N  N18  1  0.086  0.758  0.216  1.0
  N  N19  1  0.586  0.242  0.284  1.0
  O  O20  1  0.763  0.233  0.561  1.0
  O  O21  1  0.263  0.767  0.939  1.0
  O  O22  1  0.237  0.767  0.439  1.0
  O  O23  1  0.737  0.233  0.061  1.0
  O  O24  1  0.410  0.486  0.863  1.0
  O  O25  1  0.910  0.514  0.637  1.0
  O  O26  1  0.590  0.514  0.137  1.0
  O  O27  1  0.090  0.486  0.363  1.0
[/CIF]
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The compound described by Ag2S(NO)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one N(1) and one N(2) atom. In the second Ag site, Ag(2) is bonded in a distorted square co-planar geometry to one N(1), one N(2), one O(1), and one O(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one S(1) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one Ag(2), and one S(1) atom. S(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Ag(2) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one S(1) atom. is represented by the CIF file [CIF]
data_Ag2S(NO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.498
_cell_length_b   7.593
_cell_length_c   10.726
_cell_angle_alpha   86.452
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   446.947
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.311  0.016  0.675  1.0
  Ag  Ag1  1  0.811  0.984  0.825  1.0
  Ag  Ag2  1  0.689  0.984  0.325  1.0
  Ag  Ag3  1  0.189  0.016  0.175  1.0
  Ag  Ag4  1  0.110  0.311  0.945  1.0
  Ag  Ag5  1  0.610  0.689  0.555  1.0
  Ag  Ag6  1  0.890  0.689  0.055  1.0
  Ag  Ag7  1  0.390  0.311  0.445  1.0
  S  S8  1  0.939  0.319  0.644  1.0
  S  S9  1  0.439  0.681  0.856  1.0
  S  S10  1  0.061  0.681  0.356  1.0
  S  S11  1  0.561  0.319  0.144  1.0
  N  N12  1  0.211  0.270  0.616  1.0
  N  N13  1  0.711  0.730  0.884  1.0
  N  N14  1  0.789  0.730  0.384  1.0
  N  N15  1  0.289  0.270  0.116  1.0
  N  N16  1  0.914  0.242  0.784  1.0
  N  N17  1  0.414  0.758  0.716  1.0
  N  N18  1  0.086  0.758  0.216  1.0
  N  N19  1  0.586  0.242  0.284  1.0
  O  O20  1  0.763  0.233  0.561  1.0
  O  O21  1  0.263  0.767  0.939  1.0
  O  O22  1  0.237  0.767  0.439  1.0
  O  O23  1  0.737  0.233  0.061  1.0
  O  O24  1  0.410  0.486  0.863  1.0
  O  O25  1  0.910  0.514  0.637  1.0
  O  O26  1  0.590  0.514  0.137  1.0
  O  O27  1  0.090  0.486  0.363  1.0
[/CIF]
.