The crystal structure described by YCo3F15 crystallizes in the monoclinic P2_1/m space group. Y(1) is bonded in a 6-coordinate geometry to one F(1), one F(3), two equivalent F(5), and two equivalent F(8) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in an octahedral geometry to two equivalent F(4), two equivalent F(5), and two equivalent F(7) atoms. In the second Co site, Co(2) is bonded in a 6-coordinate geometry to one F(4), one F(5), one F(8), one F(9), and two equivalent F(6) atoms. There are nine inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Y(1) and one F(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one F(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Y(1) atom. In the fourth F site, F(4) is bonded in a bent 120 degrees geometry to one Co(1) and one Co(2) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to one Y(1), one Co(1), and one Co(2) atom. In the sixth F site, F(6) is bonded in a water-like geometry to two equivalent Co(2) atoms. In the seventh F site, F(7) is bonded in a single-bond geometry to one Co(1) atom. In the eighth F site, F(8) is bonded in a linear geometry to one Y(1) and one Co(2) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Co(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_YCo3F15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.501
_cell_length_b   5.758
_cell_length_c   9.391
_cell_angle_alpha   72.782
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   594.005
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.250  0.785  0.743  1.0
  Y  Y1  1  0.750  0.215  0.257  1.0
  Co  Co2  1  0.500  0.000  0.000  1.0
  Co  Co3  1  0.511  0.680  0.347  1.0
  Co  Co4  1  0.489  0.320  0.653  1.0
  Co  Co5  1  0.000  0.000  0.000  1.0
  Co  Co6  1  0.989  0.680  0.347  1.0
  Co  Co7  1  0.011  0.320  0.653  1.0
  F  F8  1  0.250  0.536  0.045  1.0
  F  F9  1  0.250  0.409  0.200  1.0
  F  F10  1  0.250  0.038  0.547  1.0
  F  F11  1  0.750  0.464  0.955  1.0
  F  F12  1  0.750  0.962  0.453  1.0
  F  F13  1  0.750  0.591  0.800  1.0
  F  F14  1  0.568  0.255  0.858  1.0
  F  F15  1  0.614  0.011  0.172  1.0
  F  F16  1  0.588  0.580  0.547  1.0
  F  F17  1  0.432  0.745  0.142  1.0
  F  F18  1  0.412  0.420  0.453  1.0
  F  F19  1  0.386  0.989  0.828  1.0
  F  F20  1  0.909  0.799  0.952  1.0
  F  F21  1  0.880  0.490  0.277  1.0
  F  F22  1  0.937  0.077  0.621  1.0
  F  F23  1  0.091  0.201  0.048  1.0
  F  F24  1  0.063  0.923  0.379  1.0
  F  F25  1  0.120  0.510  0.723  1.0
  F  F26  1  0.409  0.201  0.048  1.0
  F  F27  1  0.437  0.923  0.379  1.0
  F  F28  1  0.380  0.510  0.723  1.0
  F  F29  1  0.591  0.799  0.952  1.0
  F  F30  1  0.620  0.490  0.277  1.0
  F  F31  1  0.563  0.077  0.621  1.0
  F  F32  1  0.932  0.255  0.858  1.0
  F  F33  1  0.886  0.011  0.172  1.0
  F  F34  1  0.912  0.580  0.547  1.0
  F  F35  1  0.068  0.745  0.142  1.0
  F  F36  1  0.088  0.420  0.453  1.0
  F  F37  1  0.114  0.989  0.828  1.0
[/CIF]
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The crystal structure described by YCo3F15 crystallizes in the monoclinic P2_1/m space group. Y(1) is bonded in a 6-coordinate geometry to one F(1), one F(3), two equivalent F(5), and two equivalent F(8) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in an octahedral geometry to two equivalent F(4), two equivalent F(5), and two equivalent F(7) atoms. In the second Co site, Co(2) is bonded in a 6-coordinate geometry to one F(4), one F(5), one F(8), one F(9), and two equivalent F(6) atoms. There are nine inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Y(1) and one F(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one F(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Y(1) atom. In the fourth F site, F(4) is bonded in a bent 120 degrees geometry to one Co(1) and one Co(2) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to one Y(1), one Co(1), and one Co(2) atom. In the sixth F site, F(6) is bonded in a water-like geometry to two equivalent Co(2) atoms. In the seventh F site, F(7) is bonded in a single-bond geometry to one Co(1) atom. In the eighth F site, F(8) is bonded in a linear geometry to one Y(1) and one Co(2) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Co(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_YCo3F15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.501
_cell_length_b   5.758
_cell_length_c   9.391
_cell_angle_alpha   72.782
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   594.005
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.250  0.785  0.743  1.0
  Y  Y1  1  0.750  0.215  0.257  1.0
  Co  Co2  1  0.500  0.000  0.000  1.0
  Co  Co3  1  0.511  0.680  0.347  1.0
  Co  Co4  1  0.489  0.320  0.653  1.0
  Co  Co5  1  0.000  0.000  0.000  1.0
  Co  Co6  1  0.989  0.680  0.347  1.0
  Co  Co7  1  0.011  0.320  0.653  1.0
  F  F8  1  0.250  0.536  0.045  1.0
  F  F9  1  0.250  0.409  0.200  1.0
  F  F10  1  0.250  0.038  0.547  1.0
  F  F11  1  0.750  0.464  0.955  1.0
  F  F12  1  0.750  0.962  0.453  1.0
  F  F13  1  0.750  0.591  0.800  1.0
  F  F14  1  0.568  0.255  0.858  1.0
  F  F15  1  0.614  0.011  0.172  1.0
  F  F16  1  0.588  0.580  0.547  1.0
  F  F17  1  0.432  0.745  0.142  1.0
  F  F18  1  0.412  0.420  0.453  1.0
  F  F19  1  0.386  0.989  0.828  1.0
  F  F20  1  0.909  0.799  0.952  1.0
  F  F21  1  0.880  0.490  0.277  1.0
  F  F22  1  0.937  0.077  0.621  1.0
  F  F23  1  0.091  0.201  0.048  1.0
  F  F24  1  0.063  0.923  0.379  1.0
  F  F25  1  0.120  0.510  0.723  1.0
  F  F26  1  0.409  0.201  0.048  1.0
  F  F27  1  0.437  0.923  0.379  1.0
  F  F28  1  0.380  0.510  0.723  1.0
  F  F29  1  0.591  0.799  0.952  1.0
  F  F30  1  0.620  0.490  0.277  1.0
  F  F31  1  0.563  0.077  0.621  1.0
  F  F32  1  0.932  0.255  0.858  1.0
  F  F33  1  0.886  0.011  0.172  1.0
  F  F34  1  0.912  0.580  0.547  1.0
  F  F35  1  0.068  0.745  0.142  1.0
  F  F36  1  0.088  0.420  0.453  1.0
  F  F37  1  0.114  0.989  0.828  1.0
[/CIF]
.