The structure described by H4S(NO)2 is gamma plutonium structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of eight sulfamide molecules. N(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one S(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. O(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H4S(NO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.810
_cell_length_b   8.993
_cell_length_c   5.127
_cell_angle_alpha   83.195
_cell_angle_beta   65.542
_cell_angle_gamma   31.264
_symmetry_Int_Tables_number   1
_cell_volume   185.259
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.671  0.727  0.117  1.0
  H  H1  1  0.484  0.117  0.727  1.0
  H  H2  1  0.133  0.766  0.579  1.0
  H  H3  1  0.523  0.579  0.766  1.0
  H  H4  1  0.429  0.874  0.033  1.0
  H  H5  1  0.664  0.033  0.874  1.0
  H  H6  1  0.217  0.586  0.821  1.0
  H  H7  1  0.376  0.821  0.586  1.0
  S  S8  1  0.240  0.260  0.260  1.0
  S  S9  1  0.990  0.010  0.010  1.0
  N  N10  1  0.435  0.925  0.194  1.0
  N  N11  1  0.447  0.194  0.925  1.0
  N  N12  1  0.056  0.803  0.815  1.0
  N  N13  1  0.325  0.815  0.803  1.0
  O  O14  1  0.930  0.506  0.325  1.0
  O  O15  1  0.239  0.325  0.506  1.0
  O  O16  1  0.925  0.011  0.320  1.0
  O  O17  1  0.744  0.320  0.011  1.0
[/CIF]
.
The structure described by H4S(NO)2 is gamma plutonium structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of eight sulfamide molecules. N(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one S(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. O(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H4S(NO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.810
_cell_length_b   8.993
_cell_length_c   5.127
_cell_angle_alpha   83.195
_cell_angle_beta   65.542
_cell_angle_gamma   31.264
_symmetry_Int_Tables_number   1
_cell_volume   185.259
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.671  0.727  0.117  1.0
  H  H1  1  0.484  0.117  0.727  1.0
  H  H2  1  0.133  0.766  0.579  1.0
  H  H3  1  0.523  0.579  0.766  1.0
  H  H4  1  0.429  0.874  0.033  1.0
  H  H5  1  0.664  0.033  0.874  1.0
  H  H6  1  0.217  0.586  0.821  1.0
  H  H7  1  0.376  0.821  0.586  1.0
  S  S8  1  0.240  0.260  0.260  1.0
  S  S9  1  0.990  0.010  0.010  1.0
  N  N10  1  0.435  0.925  0.194  1.0
  N  N11  1  0.447  0.194  0.925  1.0
  N  N12  1  0.056  0.803  0.815  1.0
  N  N13  1  0.325  0.815  0.803  1.0
  O  O14  1  0.930  0.506  0.325  1.0
  O  O15  1  0.239  0.325  0.506  1.0
  O  O16  1  0.925  0.011  0.320  1.0
  O  O17  1  0.744  0.320  0.011  1.0
[/CIF]
.