The material described by HgN6 is Indium-like structured and crystallizes in the orthorhombic Iba2 space group. The structure is zero-dimensional and consists of eight HgN6 clusters. Hg(1) is bonded in a linear geometry to one N(1) and one N(4) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Hg(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one Hg(1) and one N(5) atom. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_HgN6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.472
_cell_length_b   8.074
_cell_length_c   10.732
_cell_angle_alpha   112.096
_cell_angle_beta   107.551
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   491.305
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.408  0.066  0.809  1.0
  Hg  Hg1  1  0.599  0.934  0.191  1.0
  Hg  Hg2  1  0.908  0.743  0.809  1.0
  Hg  Hg3  1  0.099  0.257  0.191  1.0
  N  N4  1  0.739  0.172  0.915  1.0
  N  N5  1  0.824  0.828  0.085  1.0
  N  N6  1  0.239  0.744  0.915  1.0
  N  N7  1  0.324  0.256  0.085  1.0
  N  N8  1  0.804  0.268  0.867  1.0
  N  N9  1  0.938  0.732  0.133  1.0
  N  N10  1  0.304  0.598  0.867  1.0
  N  N11  1  0.438  0.402  0.133  1.0
  N  N12  1  0.881  0.360  0.827  1.0
  N  N13  1  0.054  0.640  0.173  1.0
  N  N14  1  0.381  0.467  0.827  1.0
  N  N15  1  0.554  0.533  0.173  1.0
  N  N16  1  0.078  0.964  0.704  1.0
  N  N17  1  0.374  0.036  0.296  1.0
  N  N18  1  0.578  0.740  0.704  1.0
  N  N19  1  0.874  0.260  0.296  1.0
  N  N20  1  0.994  0.957  0.583  1.0
  N  N21  1  0.411  0.043  0.417  1.0
  N  N22  1  0.494  0.627  0.583  1.0
  N  N23  1  0.911  0.373  0.417  1.0
  N  N24  1  0.900  0.943  0.469  1.0
  N  N25  1  0.431  0.057  0.531  1.0
  N  N26  1  0.400  0.526  0.469  1.0
  N  N27  1  0.931  0.474  0.531  1.0
[/CIF]
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The material described by HgN6 is Indium-like structured and crystallizes in the orthorhombic Iba2 space group. The structure is zero-dimensional and consists of eight HgN6 clusters. Hg(1) is bonded in a linear geometry to one N(1) and one N(4) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Hg(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one Hg(1) and one N(5) atom. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_HgN6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.472
_cell_length_b   8.074
_cell_length_c   10.732
_cell_angle_alpha   112.096
_cell_angle_beta   107.551
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   491.305
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.408  0.066  0.809  1.0
  Hg  Hg1  1  0.599  0.934  0.191  1.0
  Hg  Hg2  1  0.908  0.743  0.809  1.0
  Hg  Hg3  1  0.099  0.257  0.191  1.0
  N  N4  1  0.739  0.172  0.915  1.0
  N  N5  1  0.824  0.828  0.085  1.0
  N  N6  1  0.239  0.744  0.915  1.0
  N  N7  1  0.324  0.256  0.085  1.0
  N  N8  1  0.804  0.268  0.867  1.0
  N  N9  1  0.938  0.732  0.133  1.0
  N  N10  1  0.304  0.598  0.867  1.0
  N  N11  1  0.438  0.402  0.133  1.0
  N  N12  1  0.881  0.360  0.827  1.0
  N  N13  1  0.054  0.640  0.173  1.0
  N  N14  1  0.381  0.467  0.827  1.0
  N  N15  1  0.554  0.533  0.173  1.0
  N  N16  1  0.078  0.964  0.704  1.0
  N  N17  1  0.374  0.036  0.296  1.0
  N  N18  1  0.578  0.740  0.704  1.0
  N  N19  1  0.874  0.260  0.296  1.0
  N  N20  1  0.994  0.957  0.583  1.0
  N  N21  1  0.411  0.043  0.417  1.0
  N  N22  1  0.494  0.627  0.583  1.0
  N  N23  1  0.911  0.373  0.417  1.0
  N  N24  1  0.900  0.943  0.469  1.0
  N  N25  1  0.431  0.057  0.531  1.0
  N  N26  1  0.400  0.526  0.469  1.0
  N  N27  1  0.931  0.474  0.531  1.0
[/CIF]
.