The material structure described by CoO6(SnF3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CoO6 cluster and one SnF3 cluster. In the CoO6 cluster, Co(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Co(1) and one O(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Co(1) and one O(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Co(1) atom. In the SnF3 cluster, Sn(1) is bonded in a distorted rectangular see-saw-like geometry to one F(1), one F(3), and two equivalent F(2) atoms. There are three inequivalent F sites. In the first F site, F(2) is bonded in a water-like geometry to two equivalent Sn(1) atoms. In the second F site, F(3) is bonded in a single-bond geometry to one Sn(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoSn2(OF)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.332
_cell_length_b   6.285
_cell_length_c   7.958
_cell_angle_alpha   93.849
_cell_angle_beta   91.669
_cell_angle_gamma   92.079
_symmetry_Int_Tables_number   1
_cell_volume   265.744
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  Sn  Sn1  1  0.712  0.411  0.584  1.0
  Sn  Sn2  1  0.288  0.589  0.416  1.0
  O  O3  1  0.193  0.079  0.813  1.0
  O  O4  1  0.807  0.921  0.187  1.0
  O  O5  1  0.259  0.894  0.858  1.0
  O  O6  1  0.741  0.106  0.142  1.0
  O  O7  1  0.215  0.141  0.134  1.0
  O  O8  1  0.785  0.859  0.866  1.0
  F  F9  1  0.625  0.387  0.817  1.0
  F  F10  1  0.375  0.613  0.183  1.0
  F  F11  1  0.079  0.503  0.648  1.0
  F  F12  1  0.921  0.497  0.352  1.0
  F  F13  1  0.769  0.113  0.526  1.0
  F  F14  1  0.231  0.887  0.474  1.0
[/CIF]
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The material structure described by CoO6(SnF3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CoO6 cluster and one SnF3 cluster. In the CoO6 cluster, Co(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Co(1) and one O(2) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Co(1) and one O(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Co(1) atom. In the SnF3 cluster, Sn(1) is bonded in a distorted rectangular see-saw-like geometry to one F(1), one F(3), and two equivalent F(2) atoms. There are three inequivalent F sites. In the first F site, F(2) is bonded in a water-like geometry to two equivalent Sn(1) atoms. In the second F site, F(3) is bonded in a single-bond geometry to one Sn(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoSn2(OF)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.332
_cell_length_b   6.285
_cell_length_c   7.958
_cell_angle_alpha   93.849
_cell_angle_beta   91.669
_cell_angle_gamma   92.079
_symmetry_Int_Tables_number   1
_cell_volume   265.744
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  Sn  Sn1  1  0.712  0.411  0.584  1.0
  Sn  Sn2  1  0.288  0.589  0.416  1.0
  O  O3  1  0.193  0.079  0.813  1.0
  O  O4  1  0.807  0.921  0.187  1.0
  O  O5  1  0.259  0.894  0.858  1.0
  O  O6  1  0.741  0.106  0.142  1.0
  O  O7  1  0.215  0.141  0.134  1.0
  O  O8  1  0.785  0.859  0.866  1.0
  F  F9  1  0.625  0.387  0.817  1.0
  F  F10  1  0.375  0.613  0.183  1.0
  F  F11  1  0.079  0.503  0.648  1.0
  F  F12  1  0.921  0.497  0.352  1.0
  F  F13  1  0.769  0.113  0.526  1.0
  F  F14  1  0.231  0.887  0.474  1.0
[/CIF]
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