The crystal structure described by (CuOCl3)2O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules and two CuOCl3 clusters. In each CuOCl3 cluster, Cu(1) is bonded to one O(1), one Cl(1), one Cl(2), and two equivalent Cl(3) atoms to form distorted edge-sharing CuCl4O square pyramids. O(1) is bonded in a single-bond geometry to one Cu(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cu(1) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to two equivalent Cu(1) atoms. is represented by the CIF file [CIF]
data_CuCl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.034
_cell_length_b   5.769
_cell_length_c   8.960
_cell_angle_alpha   69.115
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   484.530
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.024  0.124  0.148  1.0
  Cu  Cu1  1  0.524  0.876  0.352  1.0
  Cu  Cu2  1  0.976  0.876  0.852  1.0
  Cu  Cu3  1  0.476  0.124  0.648  1.0
  Cl  Cl4  1  0.148  0.452  0.139  1.0
  Cl  Cl5  1  0.648  0.548  0.361  1.0
  Cl  Cl6  1  0.852  0.548  0.861  1.0
  Cl  Cl7  1  0.352  0.452  0.639  1.0
  Cl  Cl8  1  0.376  0.825  0.182  1.0
  Cl  Cl9  1  0.876  0.175  0.318  1.0
  Cl  Cl10  1  0.624  0.175  0.818  1.0
  Cl  Cl11  1  0.124  0.825  0.682  1.0
  Cl  Cl12  1  0.368  0.119  0.424  1.0
  Cl  Cl13  1  0.868  0.881  0.076  1.0
  Cl  Cl14  1  0.632  0.881  0.576  1.0
  Cl  Cl15  1  0.132  0.119  0.924  1.0
  O  O16  1  0.114  0.846  0.298  1.0
  O  O17  1  0.614  0.154  0.202  1.0
  O  O18  1  0.886  0.154  0.702  1.0
  O  O19  1  0.386  0.846  0.798  1.0
  O  O20  1  0.478  0.397  0.035  1.0
  O  O21  1  0.978  0.603  0.465  1.0
  O  O22  1  0.522  0.603  0.965  1.0
  O  O23  1  0.022  0.397  0.535  1.0
[/CIF]
.
The crystal structure described by (CuOCl3)2O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules and two CuOCl3 clusters. In each CuOCl3 cluster, Cu(1) is bonded to one O(1), one Cl(1), one Cl(2), and two equivalent Cl(3) atoms to form distorted edge-sharing CuCl4O square pyramids. O(1) is bonded in a single-bond geometry to one Cu(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cu(1) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to two equivalent Cu(1) atoms. is represented by the CIF file [CIF]
data_CuCl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.034
_cell_length_b   5.769
_cell_length_c   8.960
_cell_angle_alpha   69.115
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   484.530
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.024  0.124  0.148  1.0
  Cu  Cu1  1  0.524  0.876  0.352  1.0
  Cu  Cu2  1  0.976  0.876  0.852  1.0
  Cu  Cu3  1  0.476  0.124  0.648  1.0
  Cl  Cl4  1  0.148  0.452  0.139  1.0
  Cl  Cl5  1  0.648  0.548  0.361  1.0
  Cl  Cl6  1  0.852  0.548  0.861  1.0
  Cl  Cl7  1  0.352  0.452  0.639  1.0
  Cl  Cl8  1  0.376  0.825  0.182  1.0
  Cl  Cl9  1  0.876  0.175  0.318  1.0
  Cl  Cl10  1  0.624  0.175  0.818  1.0
  Cl  Cl11  1  0.124  0.825  0.682  1.0
  Cl  Cl12  1  0.368  0.119  0.424  1.0
  Cl  Cl13  1  0.868  0.881  0.076  1.0
  Cl  Cl14  1  0.632  0.881  0.576  1.0
  Cl  Cl15  1  0.132  0.119  0.924  1.0
  O  O16  1  0.114  0.846  0.298  1.0
  O  O17  1  0.614  0.154  0.202  1.0
  O  O18  1  0.886  0.154  0.702  1.0
  O  O19  1  0.386  0.846  0.798  1.0
  O  O20  1  0.478  0.397  0.035  1.0
  O  O21  1  0.978  0.603  0.465  1.0
  O  O22  1  0.522  0.603  0.965  1.0
  O  O23  1  0.022  0.397  0.535  1.0
[/CIF]
.