The structure described by LiMnPO4 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a square co-planar geometry to one O(2), one O(3), and two equivalent O(1) atoms. Mn(1) is bonded in a distorted pentagonal planar geometry to one O(1), one O(2), one O(3), and two equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom. In the second O site, O(4) is bonded in a distorted T-shaped geometry to two equivalent Mn(1) and one P(1) atom. In the third O site, O(1) is bonded to two equivalent Li(1), one Mn(1), and one P(1) atom to form distorted corner-sharing OLi2MnP trigonal pyramids. In the fourth O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom. is represented by the CIF card [CIF]
data_LiMnPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.155
_cell_length_b   5.156
_cell_length_c   16.162
_cell_angle_alpha   87.351
_cell_angle_beta   92.615
_cell_angle_gamma   108.643
_symmetry_Int_Tables_number   1
_cell_volume   406.430
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.282  0.771  0.749  1.0
  Li  Li1  1  0.229  0.718  0.249  1.0
  Li  Li2  1  0.771  0.282  0.751  1.0
  Li  Li3  1  0.718  0.229  0.251  1.0
  Mn  Mn4  1  0.920  0.627  0.584  1.0
  Mn  Mn5  1  0.080  0.373  0.416  1.0
  Mn  Mn6  1  0.626  0.919  0.916  1.0
  Mn  Mn7  1  0.374  0.080  0.084  1.0
  P  P8  1  0.258  0.289  0.631  1.0
  P  P9  1  0.289  0.258  0.869  1.0
  P  P10  1  0.711  0.742  0.131  1.0
  P  P11  1  0.742  0.711  0.369  1.0
  O  O12  1  0.110  0.427  0.689  1.0
  O  O13  1  0.573  0.890  0.189  1.0
  O  O14  1  0.427  0.110  0.811  1.0
  O  O15  1  0.890  0.573  0.311  1.0
  O  O16  1  0.973  0.159  0.855  1.0
  O  O17  1  0.841  0.027  0.355  1.0
  O  O18  1  0.159  0.974  0.645  1.0
  O  O19  1  0.027  0.841  0.145  1.0
  O  O20  1  0.404  0.571  0.853  1.0
  O  O21  1  0.429  0.596  0.353  1.0
  O  O22  1  0.571  0.404  0.647  1.0
  O  O23  1  0.596  0.429  0.147  1.0
  O  O24  1  0.173  0.369  0.542  1.0
  O  O25  1  0.631  0.827  0.042  1.0
  O  O26  1  0.369  0.173  0.958  1.0
  O  O27  1  0.827  0.631  0.458  1.0
[/CIF]
.
The structure described by LiMnPO4 crystallizes in the monoclinic C2/c space group. Li(1) is bonded in a square co-planar geometry to one O(2), one O(3), and two equivalent O(1) atoms. Mn(1) is bonded in a distorted pentagonal planar geometry to one O(1), one O(2), one O(3), and two equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom. In the second O site, O(4) is bonded in a distorted T-shaped geometry to two equivalent Mn(1) and one P(1) atom. In the third O site, O(1) is bonded to two equivalent Li(1), one Mn(1), and one P(1) atom to form distorted corner-sharing OLi2MnP trigonal pyramids. In the fourth O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Mn(1), and one P(1) atom. is represented by the CIF card [CIF]
data_LiMnPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.155
_cell_length_b   5.156
_cell_length_c   16.162
_cell_angle_alpha   87.351
_cell_angle_beta   92.615
_cell_angle_gamma   108.643
_symmetry_Int_Tables_number   1
_cell_volume   406.430
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.282  0.771  0.749  1.0
  Li  Li1  1  0.229  0.718  0.249  1.0
  Li  Li2  1  0.771  0.282  0.751  1.0
  Li  Li3  1  0.718  0.229  0.251  1.0
  Mn  Mn4  1  0.920  0.627  0.584  1.0
  Mn  Mn5  1  0.080  0.373  0.416  1.0
  Mn  Mn6  1  0.626  0.919  0.916  1.0
  Mn  Mn7  1  0.374  0.080  0.084  1.0
  P  P8  1  0.258  0.289  0.631  1.0
  P  P9  1  0.289  0.258  0.869  1.0
  P  P10  1  0.711  0.742  0.131  1.0
  P  P11  1  0.742  0.711  0.369  1.0
  O  O12  1  0.110  0.427  0.689  1.0
  O  O13  1  0.573  0.890  0.189  1.0
  O  O14  1  0.427  0.110  0.811  1.0
  O  O15  1  0.890  0.573  0.311  1.0
  O  O16  1  0.973  0.159  0.855  1.0
  O  O17  1  0.841  0.027  0.355  1.0
  O  O18  1  0.159  0.974  0.645  1.0
  O  O19  1  0.027  0.841  0.145  1.0
  O  O20  1  0.404  0.571  0.853  1.0
  O  O21  1  0.429  0.596  0.353  1.0
  O  O22  1  0.571  0.404  0.647  1.0
  O  O23  1  0.596  0.429  0.147  1.0
  O  O24  1  0.173  0.369  0.542  1.0
  O  O25  1  0.631  0.827  0.042  1.0
  O  O26  1  0.369  0.173  0.958  1.0
  O  O27  1  0.827  0.631  0.458  1.0
[/CIF]
.