The compound described by Cu(AgO)2 crystallizes in the orthorhombic Immm space group. Ag(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. Cu(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to four equivalent Ag(1) and two equivalent Cu(1) atoms to form a mixture of distorted corner and edge-sharing OCu2Ag4 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cu(AgO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.709
_cell_length_b   5.709
_cell_length_c   5.709
_cell_angle_alpha   150.113
_cell_angle_beta   133.329
_cell_angle_gamma   56.413
_symmetry_Int_Tables_number   1
_cell_volume   66.984
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.000  0.000  0.000  1.0
  Ag  Ag1  1  0.649  0.649  0.000  1.0
  Ag  Ag2  1  0.351  0.351  0.000  1.0
  O  O3  1  0.870  0.370  0.500  1.0
  O  O4  1  0.130  0.630  0.500  1.0
[/CIF]
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The compound described by Cu(AgO)2 crystallizes in the orthorhombic Immm space group. Ag(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. Cu(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to four equivalent Ag(1) and two equivalent Cu(1) atoms to form a mixture of distorted corner and edge-sharing OCu2Ag4 octahedra. The corner-sharing octahedral tilt angles range from 0-10°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cu(AgO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.709
_cell_length_b   5.709
_cell_length_c   5.709
_cell_angle_alpha   150.113
_cell_angle_beta   133.329
_cell_angle_gamma   56.413
_symmetry_Int_Tables_number   1
_cell_volume   66.984
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.000  0.000  0.000  1.0
  Ag  Ag1  1  0.649  0.649  0.000  1.0
  Ag  Ag2  1  0.351  0.351  0.000  1.0
  O  O3  1  0.870  0.370  0.500  1.0
  O  O4  1  0.130  0.630  0.500  1.0
[/CIF]
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