The material structure described by ZnGaAlS4 crystallizes in the tetragonal I-4 space group. Zn(1) is bonded to four equivalent S(1) atoms to form ZnS4 tetrahedra that share corners with four equivalent Ga(1)S4 tetrahedra and corners with four equivalent Al(1)S4 tetrahedra. Ga(1) is bonded to four equivalent S(1) atoms to form GaS4 tetrahedra that share corners with four equivalent Zn(1)S4 tetrahedra and corners with four equivalent Al(1)S4 tetrahedra. Al(1) is bonded to four equivalent S(1) atoms to form AlS4 tetrahedra that share corners with four equivalent Zn(1)S4 tetrahedra and corners with four equivalent Ga(1)S4 tetrahedra. S(1) is bonded in a trigonal non-coplanar geometry to one Zn(1), one Ga(1), and one Al(1) atom. is represented by the CIF file [CIF]
data_AlZnGaS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.374
_cell_length_b   5.374
_cell_length_c   6.458
_cell_angle_alpha   65.414
_cell_angle_beta   65.414
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   150.817
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.500  0.500  0.000  1.0
  Zn  Zn1  1  0.000  0.000  0.000  1.0
  Ga  Ga2  1  0.750  0.250  0.500  1.0
  S  S3  1  0.873  0.388  0.744  1.0
  S  S4  1  0.383  0.868  0.744  1.0
  S  S5  1  0.612  0.617  0.256  1.0
  S  S6  1  0.132  0.127  0.256  1.0
[/CIF]
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The material structure described by ZnGaAlS4 crystallizes in the tetragonal I-4 space group. Zn(1) is bonded to four equivalent S(1) atoms to form ZnS4 tetrahedra that share corners with four equivalent Ga(1)S4 tetrahedra and corners with four equivalent Al(1)S4 tetrahedra. Ga(1) is bonded to four equivalent S(1) atoms to form GaS4 tetrahedra that share corners with four equivalent Zn(1)S4 tetrahedra and corners with four equivalent Al(1)S4 tetrahedra. Al(1) is bonded to four equivalent S(1) atoms to form AlS4 tetrahedra that share corners with four equivalent Zn(1)S4 tetrahedra and corners with four equivalent Ga(1)S4 tetrahedra. S(1) is bonded in a trigonal non-coplanar geometry to one Zn(1), one Ga(1), and one Al(1) atom. is represented by the CIF file [CIF]
data_AlZnGaS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.374
_cell_length_b   5.374
_cell_length_c   6.458
_cell_angle_alpha   65.414
_cell_angle_beta   65.414
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   150.817
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.500  0.500  0.000  1.0
  Zn  Zn1  1  0.000  0.000  0.000  1.0
  Ga  Ga2  1  0.750  0.250  0.500  1.0
  S  S3  1  0.873  0.388  0.744  1.0
  S  S4  1  0.383  0.868  0.744  1.0
  S  S5  1  0.612  0.617  0.256  1.0
  S  S6  1  0.132  0.127  0.256  1.0
[/CIF]
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