The structure described by La(IO3)3 crystallizes in the orthorhombic Pmmn space group. La(1) is bonded in a 7-coordinate geometry to one O(2), two equivalent O(4), and four equivalent O(1) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one La(1), one I(1), and one I(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1) and two equivalent I(1) atoms. In the third O site, O(3) is bonded in a distorted water-like geometry to two equivalent I(1) atoms. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one La(1) and one I(1) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms. In the second I site, I(2) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. is represented by the CIF card [CIF]
data_La(IO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.140
_cell_length_b   8.207
_cell_length_c   6.696
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   392.367
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.500  0.000  0.608  1.0
  La  La1  1  0.000  0.500  0.392  1.0
  I  I2  1  0.000  0.794  0.855  1.0
  I  I3  1  0.000  0.206  0.855  1.0
  I  I4  1  0.500  0.706  0.145  1.0
  I  I5  1  0.500  0.294  0.145  1.0
  I  I6  1  0.500  0.500  0.611  1.0
  I  I7  1  0.000  0.000  0.389  1.0
  O  O8  1  0.826  0.855  0.522  1.0
  O  O9  1  0.826  0.145  0.522  1.0
  O  O10  1  0.174  0.855  0.522  1.0
  O  O11  1  0.174  0.145  0.522  1.0
  O  O12  1  0.674  0.645  0.478  1.0
  O  O13  1  0.674  0.355  0.478  1.0
  O  O14  1  0.326  0.645  0.478  1.0
  O  O15  1  0.326  0.355  0.478  1.0
  O  O16  1  0.500  0.000  0.264  1.0
  O  O17  1  0.000  0.500  0.736  1.0
  O  O18  1  0.174  0.000  0.898  1.0
  O  O19  1  0.826  0.000  0.898  1.0
  O  O20  1  0.326  0.500  0.102  1.0
  O  O21  1  0.674  0.500  0.102  1.0
  O  O22  1  0.500  0.765  0.876  1.0
  O  O23  1  0.500  0.235  0.876  1.0
  O  O24  1  0.000  0.735  0.124  1.0
  O  O25  1  0.000  0.265  0.124  1.0
[/CIF]
.
The structure described by La(IO3)3 crystallizes in the orthorhombic Pmmn space group. La(1) is bonded in a 7-coordinate geometry to one O(2), two equivalent O(4), and four equivalent O(1) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one La(1), one I(1), and one I(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1) and two equivalent I(1) atoms. In the third O site, O(3) is bonded in a distorted water-like geometry to two equivalent I(1) atoms. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one La(1) and one I(1) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms. In the second I site, I(2) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. is represented by the CIF card [CIF]
data_La(IO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.140
_cell_length_b   8.207
_cell_length_c   6.696
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   392.367
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.500  0.000  0.608  1.0
  La  La1  1  0.000  0.500  0.392  1.0
  I  I2  1  0.000  0.794  0.855  1.0
  I  I3  1  0.000  0.206  0.855  1.0
  I  I4  1  0.500  0.706  0.145  1.0
  I  I5  1  0.500  0.294  0.145  1.0
  I  I6  1  0.500  0.500  0.611  1.0
  I  I7  1  0.000  0.000  0.389  1.0
  O  O8  1  0.826  0.855  0.522  1.0
  O  O9  1  0.826  0.145  0.522  1.0
  O  O10  1  0.174  0.855  0.522  1.0
  O  O11  1  0.174  0.145  0.522  1.0
  O  O12  1  0.674  0.645  0.478  1.0
  O  O13  1  0.674  0.355  0.478  1.0
  O  O14  1  0.326  0.645  0.478  1.0
  O  O15  1  0.326  0.355  0.478  1.0
  O  O16  1  0.500  0.000  0.264  1.0
  O  O17  1  0.000  0.500  0.736  1.0
  O  O18  1  0.174  0.000  0.898  1.0
  O  O19  1  0.826  0.000  0.898  1.0
  O  O20  1  0.326  0.500  0.102  1.0
  O  O21  1  0.674  0.500  0.102  1.0
  O  O22  1  0.500  0.765  0.876  1.0
  O  O23  1  0.500  0.235  0.876  1.0
  O  O24  1  0.000  0.735  0.124  1.0
  O  O25  1  0.000  0.265  0.124  1.0
[/CIF]
.