The material described by DyCo5P3 crystallizes in the orthorhombic Pnma space group. Dy(1) is bonded in a 17-coordinate geometry to one Co(1), one Co(5), three equivalent Co(2), three equivalent Co(3), three equivalent Co(4), two equivalent P(1), two equivalent P(2), and two equivalent P(3) atoms. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded in a 5-coordinate geometry to one Dy(1), one P(3), two equivalent P(1), and two equivalent P(2) atoms. In the second Co site, Co(2) is bonded in a 4-coordinate geometry to three equivalent Dy(1), one P(2), and three equivalent P(3) atoms. In the third Co site, Co(3) is bonded to three equivalent Dy(1), one P(1), one P(2), and two equivalent P(3) atoms to form distorted CoDy3P4 tetrahedra that share  a cornercorner with one Co(5)DyP4 tetrahedra, corners with three equivalent Co(4)Dy3P4 tetrahedra, corners with four equivalent Co(3)Dy3P4 tetrahedra, edges with two equivalent Co(3)Dy3P4 tetrahedra, edges with three equivalent Co(5)DyP4 tetrahedra, and faces with three equivalent Co(4)Dy3P4 tetrahedra. In the fourth Co site, Co(4) is bonded to three equivalent Dy(1), one P(1), one P(3), and two equivalent P(2) atoms to form distorted CoDy3P4 tetrahedra that share corners with two equivalent Co(5)DyP4 tetrahedra, corners with three equivalent Co(3)Dy3P4 tetrahedra, corners with four equivalent Co(4)Dy3P4 tetrahedra, edges with two equivalent Co(4)Dy3P4 tetrahedra, faces with two equivalent Co(5)DyP4 tetrahedra, and faces with three equivalent Co(3)Dy3P4 tetrahedra. In the fifth Co site, Co(5) is bonded to one Dy(1), one P(2), and three equivalent P(1) atoms to form distorted CoDyP4 tetrahedra that share  a cornercorner with one Co(3)Dy3P4 tetrahedra, corners with two equivalent Co(4)Dy3P4 tetrahedra, corners with two equivalent Co(5)DyP4 tetrahedra, edges with two equivalent Co(5)DyP4 tetrahedra, edges with three equivalent Co(3)Dy3P4 tetrahedra, and faces with two equivalent Co(4)Dy3P4 tetrahedra. There are three inequivalent P sites. In the first P site, P(3) is bonded in a 9-coordinate geometry to two equivalent Dy(1), one Co(1), one Co(4), two equivalent Co(3), and three equivalent Co(2) atoms. In the second P site, P(1) is bonded in a 9-coordinate geometry to two equivalent Dy(1), one Co(3), one Co(4), two equivalent Co(1), and three equivalent Co(5) atoms. In the third P site, P(2) is bonded in a 9-coordinate geometry to two equivalent Dy(1), one Co(2), one Co(3), one Co(5), two equivalent Co(1), and two equivalent Co(4) atoms. is represented by the CIF card [CIF]
data_DyCo5P3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.639
_cell_length_b   10.188
_cell_length_c   11.646
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   431.756
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.250  0.582  0.701  1.0
  Dy  Dy1  1  0.250  0.918  0.201  1.0
  Dy  Dy2  1  0.750  0.418  0.299  1.0
  Dy  Dy3  1  0.750  0.082  0.799  1.0
  Co  Co4  1  0.250  0.711  0.989  1.0
  Co  Co5  1  0.250  0.789  0.489  1.0
  Co  Co6  1  0.750  0.289  0.011  1.0
  Co  Co7  1  0.750  0.211  0.511  1.0
  Co  Co8  1  0.250  0.405  0.487  1.0
  Co  Co9  1  0.250  0.095  0.987  1.0
  Co  Co10  1  0.750  0.595  0.513  1.0
  Co  Co11  1  0.750  0.905  0.013  1.0
  Co  Co12  1  0.250  0.222  0.175  1.0
  Co  Co13  1  0.250  0.278  0.675  1.0
  Co  Co14  1  0.750  0.778  0.825  1.0
  Co  Co15  1  0.750  0.722  0.325  1.0
  Co  Co16  1  0.250  0.883  0.698  1.0
  Co  Co17  1  0.250  0.617  0.198  1.0
  Co  Co18  1  0.750  0.117  0.302  1.0
  Co  Co19  1  0.750  0.383  0.802  1.0
  Co  Co20  1  0.250  0.467  0.933  1.0
  Co  Co21  1  0.250  0.033  0.433  1.0
  Co  Co22  1  0.750  0.533  0.067  1.0
  Co  Co23  1  0.750  0.967  0.567  1.0
  P  P24  1  0.250  0.420  0.114  1.0
  P  P25  1  0.250  0.080  0.614  1.0
  P  P26  1  0.750  0.580  0.886  1.0
  P  P27  1  0.750  0.920  0.386  1.0
  P  P28  1  0.250  0.271  0.867  1.0
  P  P29  1  0.250  0.229  0.367  1.0
  P  P30  1  0.750  0.729  0.133  1.0
  P  P31  1  0.750  0.771  0.633  1.0
  P  P32  1  0.250  0.602  0.393  1.0
  P  P33  1  0.250  0.898  0.893  1.0
  P  P34  1  0.750  0.398  0.607  1.0
  P  P35  1  0.750  0.102  0.107  1.0
[/CIF]
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The material described by DyCo5P3 crystallizes in the orthorhombic Pnma space group. Dy(1) is bonded in a 17-coordinate geometry to one Co(1), one Co(5), three equivalent Co(2), three equivalent Co(3), three equivalent Co(4), two equivalent P(1), two equivalent P(2), and two equivalent P(3) atoms. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded in a 5-coordinate geometry to one Dy(1), one P(3), two equivalent P(1), and two equivalent P(2) atoms. In the second Co site, Co(2) is bonded in a 4-coordinate geometry to three equivalent Dy(1), one P(2), and three equivalent P(3) atoms. In the third Co site, Co(3) is bonded to three equivalent Dy(1), one P(1), one P(2), and two equivalent P(3) atoms to form distorted CoDy3P4 tetrahedra that share  a cornercorner with one Co(5)DyP4 tetrahedra, corners with three equivalent Co(4)Dy3P4 tetrahedra, corners with four equivalent Co(3)Dy3P4 tetrahedra, edges with two equivalent Co(3)Dy3P4 tetrahedra, edges with three equivalent Co(5)DyP4 tetrahedra, and faces with three equivalent Co(4)Dy3P4 tetrahedra. In the fourth Co site, Co(4) is bonded to three equivalent Dy(1), one P(1), one P(3), and two equivalent P(2) atoms to form distorted CoDy3P4 tetrahedra that share corners with two equivalent Co(5)DyP4 tetrahedra, corners with three equivalent Co(3)Dy3P4 tetrahedra, corners with four equivalent Co(4)Dy3P4 tetrahedra, edges with two equivalent Co(4)Dy3P4 tetrahedra, faces with two equivalent Co(5)DyP4 tetrahedra, and faces with three equivalent Co(3)Dy3P4 tetrahedra. In the fifth Co site, Co(5) is bonded to one Dy(1), one P(2), and three equivalent P(1) atoms to form distorted CoDyP4 tetrahedra that share  a cornercorner with one Co(3)Dy3P4 tetrahedra, corners with two equivalent Co(4)Dy3P4 tetrahedra, corners with two equivalent Co(5)DyP4 tetrahedra, edges with two equivalent Co(5)DyP4 tetrahedra, edges with three equivalent Co(3)Dy3P4 tetrahedra, and faces with two equivalent Co(4)Dy3P4 tetrahedra. There are three inequivalent P sites. In the first P site, P(3) is bonded in a 9-coordinate geometry to two equivalent Dy(1), one Co(1), one Co(4), two equivalent Co(3), and three equivalent Co(2) atoms. In the second P site, P(1) is bonded in a 9-coordinate geometry to two equivalent Dy(1), one Co(3), one Co(4), two equivalent Co(1), and three equivalent Co(5) atoms. In the third P site, P(2) is bonded in a 9-coordinate geometry to two equivalent Dy(1), one Co(2), one Co(3), one Co(5), two equivalent Co(1), and two equivalent Co(4) atoms. is represented by the CIF card [CIF]
data_DyCo5P3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.639
_cell_length_b   10.188
_cell_length_c   11.646
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   431.756
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.250  0.582  0.701  1.0
  Dy  Dy1  1  0.250  0.918  0.201  1.0
  Dy  Dy2  1  0.750  0.418  0.299  1.0
  Dy  Dy3  1  0.750  0.082  0.799  1.0
  Co  Co4  1  0.250  0.711  0.989  1.0
  Co  Co5  1  0.250  0.789  0.489  1.0
  Co  Co6  1  0.750  0.289  0.011  1.0
  Co  Co7  1  0.750  0.211  0.511  1.0
  Co  Co8  1  0.250  0.405  0.487  1.0
  Co  Co9  1  0.250  0.095  0.987  1.0
  Co  Co10  1  0.750  0.595  0.513  1.0
  Co  Co11  1  0.750  0.905  0.013  1.0
  Co  Co12  1  0.250  0.222  0.175  1.0
  Co  Co13  1  0.250  0.278  0.675  1.0
  Co  Co14  1  0.750  0.778  0.825  1.0
  Co  Co15  1  0.750  0.722  0.325  1.0
  Co  Co16  1  0.250  0.883  0.698  1.0
  Co  Co17  1  0.250  0.617  0.198  1.0
  Co  Co18  1  0.750  0.117  0.302  1.0
  Co  Co19  1  0.750  0.383  0.802  1.0
  Co  Co20  1  0.250  0.467  0.933  1.0
  Co  Co21  1  0.250  0.033  0.433  1.0
  Co  Co22  1  0.750  0.533  0.067  1.0
  Co  Co23  1  0.750  0.967  0.567  1.0
  P  P24  1  0.250  0.420  0.114  1.0
  P  P25  1  0.250  0.080  0.614  1.0
  P  P26  1  0.750  0.580  0.886  1.0
  P  P27  1  0.750  0.920  0.386  1.0
  P  P28  1  0.250  0.271  0.867  1.0
  P  P29  1  0.250  0.229  0.367  1.0
  P  P30  1  0.750  0.729  0.133  1.0
  P  P31  1  0.750  0.771  0.633  1.0
  P  P32  1  0.250  0.602  0.393  1.0
  P  P33  1  0.250  0.898  0.893  1.0
  P  P34  1  0.750  0.398  0.607  1.0
  P  P35  1  0.750  0.102  0.107  1.0
[/CIF]
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