The structure described by Eu(WO4)2Tl crystallizes in the monoclinic C2/c space group. The structure consists of four 7440-28-0 atoms inside a Eu(WO4)2 framework. In the Eu(WO4)2 framework, Eu(1) is bonded in a 8-coordinate geometry to two equivalent O(3), two equivalent O(4), and four equivalent O(2) atoms. W(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form a mixture of distorted corner and edge-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 43°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Eu(1) and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Eu(1) and two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Eu(1) and one W(1) atom. is represented by the CIF file [CIF]
data_EuTl(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.726
_cell_length_b   7.726
_cell_length_c   7.558
_cell_angle_alpha   62.852
_cell_angle_beta   62.852
_cell_angle_gamma   89.473
_symmetry_Int_Tables_number   1
_cell_volume   345.765
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.775  0.225  0.750  1.0
  Eu  Eu1  1  0.225  0.775  0.250  1.0
  Tl  Tl2  1  0.203  0.797  0.750  1.0
  Tl  Tl3  1  0.797  0.203  0.250  1.0
  W  W4  1  0.698  0.689  0.776  1.0
  W  W5  1  0.302  0.311  0.224  1.0
  W  W6  1  0.311  0.302  0.724  1.0
  W  W7  1  0.689  0.698  0.276  1.0
  O  O8  1  0.620  0.756  0.557  1.0
  O  O9  1  0.380  0.244  0.443  1.0
  O  O10  1  0.244  0.380  0.943  1.0
  O  O11  1  0.756  0.620  0.057  1.0
  O  O12  1  0.381  0.070  0.869  1.0
  O  O13  1  0.619  0.930  0.131  1.0
  O  O14  1  0.930  0.619  0.631  1.0
  O  O15  1  0.070  0.381  0.369  1.0
  O  O16  1  0.584  0.372  0.971  1.0
  O  O17  1  0.416  0.628  0.029  1.0
  O  O18  1  0.628  0.416  0.529  1.0
  O  O19  1  0.372  0.584  0.471  1.0
  O  O20  1  0.788  0.949  0.690  1.0
  O  O21  1  0.212  0.051  0.310  1.0
  O  O22  1  0.051  0.212  0.810  1.0
  O  O23  1  0.949  0.788  0.190  1.0
[/CIF]
.
The structure described by Eu(WO4)2Tl crystallizes in the monoclinic C2/c space group. The structure consists of four 7440-28-0 atoms inside a Eu(WO4)2 framework. In the Eu(WO4)2 framework, Eu(1) is bonded in a 8-coordinate geometry to two equivalent O(3), two equivalent O(4), and four equivalent O(2) atoms. W(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form a mixture of distorted corner and edge-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 43°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Eu(1) and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Eu(1) and two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Eu(1) and one W(1) atom. is represented by the CIF file [CIF]
data_EuTl(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.726
_cell_length_b   7.726
_cell_length_c   7.558
_cell_angle_alpha   62.852
_cell_angle_beta   62.852
_cell_angle_gamma   89.473
_symmetry_Int_Tables_number   1
_cell_volume   345.765
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.775  0.225  0.750  1.0
  Eu  Eu1  1  0.225  0.775  0.250  1.0
  Tl  Tl2  1  0.203  0.797  0.750  1.0
  Tl  Tl3  1  0.797  0.203  0.250  1.0
  W  W4  1  0.698  0.689  0.776  1.0
  W  W5  1  0.302  0.311  0.224  1.0
  W  W6  1  0.311  0.302  0.724  1.0
  W  W7  1  0.689  0.698  0.276  1.0
  O  O8  1  0.620  0.756  0.557  1.0
  O  O9  1  0.380  0.244  0.443  1.0
  O  O10  1  0.244  0.380  0.943  1.0
  O  O11  1  0.756  0.620  0.057  1.0
  O  O12  1  0.381  0.070  0.869  1.0
  O  O13  1  0.619  0.930  0.131  1.0
  O  O14  1  0.930  0.619  0.631  1.0
  O  O15  1  0.070  0.381  0.369  1.0
  O  O16  1  0.584  0.372  0.971  1.0
  O  O17  1  0.416  0.628  0.029  1.0
  O  O18  1  0.628  0.416  0.529  1.0
  O  O19  1  0.372  0.584  0.471  1.0
  O  O20  1  0.788  0.949  0.690  1.0
  O  O21  1  0.212  0.051  0.310  1.0
  O  O22  1  0.051  0.212  0.810  1.0
  O  O23  1  0.949  0.788  0.190  1.0
[/CIF]
.