The structure described by Yb(HoS2)2 crystallizes in the tetragonal I-42d space group. Yb(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Ho(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. S(1) is bonded to two equivalent Yb(1) and four equivalent Ho(1) atoms to form a mixture of distorted corner, face, and edge-sharing SYb2Ho4 octahedra. The corner-sharing octahedral tilt angles range from 18-50°. is represented by the CIF card [CIF]
data_Yb(HoS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.180
_cell_length_b   7.180
_cell_length_c   7.180
_cell_angle_alpha   109.376
_cell_angle_beta   109.376
_cell_angle_gamma   109.661
_symmetry_Int_Tables_number   1
_cell_volume   284.888
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.250  0.750  0.500  1.0
  Yb  Yb1  1  1.000  1.000  1.000  1.0
  Ho  Ho2  1  0.497  0.875  0.122  1.0
  Ho  Ho3  1  0.753  0.375  0.878  1.0
  Ho  Ho4  1  0.125  0.247  0.622  1.0
  Ho  Ho5  1  0.625  0.503  0.378  1.0
  S  S6  1  0.012  0.620  0.750  1.0
  S  S7  1  0.870  0.762  0.250  1.0
  S  S8  1  0.380  0.130  0.392  1.0
  S  S9  1  0.738  0.988  0.608  1.0
  S  S10  1  0.870  0.262  0.250  1.0
  S  S11  1  0.380  0.130  0.892  1.0
  S  S12  1  0.238  0.488  0.108  1.0
  S  S13  1  0.512  0.620  0.750  1.0
[/CIF]
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The structure described by Yb(HoS2)2 crystallizes in the tetragonal I-42d space group. Yb(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Ho(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. S(1) is bonded to two equivalent Yb(1) and four equivalent Ho(1) atoms to form a mixture of distorted corner, face, and edge-sharing SYb2Ho4 octahedra. The corner-sharing octahedral tilt angles range from 18-50°. is represented by the CIF card [CIF]
data_Yb(HoS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.180
_cell_length_b   7.180
_cell_length_c   7.180
_cell_angle_alpha   109.376
_cell_angle_beta   109.376
_cell_angle_gamma   109.661
_symmetry_Int_Tables_number   1
_cell_volume   284.888
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.250  0.750  0.500  1.0
  Yb  Yb1  1  1.000  1.000  1.000  1.0
  Ho  Ho2  1  0.497  0.875  0.122  1.0
  Ho  Ho3  1  0.753  0.375  0.878  1.0
  Ho  Ho4  1  0.125  0.247  0.622  1.0
  Ho  Ho5  1  0.625  0.503  0.378  1.0
  S  S6  1  0.012  0.620  0.750  1.0
  S  S7  1  0.870  0.762  0.250  1.0
  S  S8  1  0.380  0.130  0.392  1.0
  S  S9  1  0.738  0.988  0.608  1.0
  S  S10  1  0.870  0.262  0.250  1.0
  S  S11  1  0.380  0.130  0.892  1.0
  S  S12  1  0.238  0.488  0.108  1.0
  S  S13  1  0.512  0.620  0.750  1.0
[/CIF]
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