The compound described by KSbO3 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 7-coordinate geometry to two equivalent O(2), two equivalent O(3), and three equivalent O(1) atoms. Sb(1) is bonded to one O(3), two equivalent O(1), and two equivalent O(2) atoms to form edge-sharing SbO5 square pyramids. There are three inequivalent O sites. In the first O site, O(1) is bonded to three equivalent K(1) and two equivalent Sb(1) atoms to form a mixture of distorted edge and corner-sharing OK3Sb2 trigonal bipyramids. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to two equivalent K(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent K(1), one Sb(1), and one O(3) atom. is represented by the CIF file [CIF]
data_KSbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.990
_cell_length_b   6.234
_cell_length_c   6.826
_cell_angle_alpha   72.286
_cell_angle_beta   69.064
_cell_angle_gamma   67.333
_symmetry_Int_Tables_number   1
_cell_volume   179.557
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.096  0.686  0.091  1.0
  K  K1  1  0.904  0.314  0.909  1.0
  Sb  Sb2  1  0.724  0.239  0.499  1.0
  Sb  Sb3  1  0.276  0.761  0.501  1.0
  O  O4  1  0.423  0.453  0.718  1.0
  O  O5  1  0.927  0.958  0.714  1.0
  O  O6  1  0.939  0.621  0.522  1.0
  O  O7  1  0.577  0.547  0.282  1.0
  O  O8  1  0.073  0.042  0.286  1.0
  O  O9  1  0.061  0.379  0.478  1.0
[/CIF]
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The compound described by KSbO3 crystallizes in the triclinic P-1 space group. K(1) is bonded in a 7-coordinate geometry to two equivalent O(2), two equivalent O(3), and three equivalent O(1) atoms. Sb(1) is bonded to one O(3), two equivalent O(1), and two equivalent O(2) atoms to form edge-sharing SbO5 square pyramids. There are three inequivalent O sites. In the first O site, O(1) is bonded to three equivalent K(1) and two equivalent Sb(1) atoms to form a mixture of distorted edge and corner-sharing OK3Sb2 trigonal bipyramids. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to two equivalent K(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent K(1), one Sb(1), and one O(3) atom. is represented by the CIF file [CIF]
data_KSbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.990
_cell_length_b   6.234
_cell_length_c   6.826
_cell_angle_alpha   72.286
_cell_angle_beta   69.064
_cell_angle_gamma   67.333
_symmetry_Int_Tables_number   1
_cell_volume   179.557
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.096  0.686  0.091  1.0
  K  K1  1  0.904  0.314  0.909  1.0
  Sb  Sb2  1  0.724  0.239  0.499  1.0
  Sb  Sb3  1  0.276  0.761  0.501  1.0
  O  O4  1  0.423  0.453  0.718  1.0
  O  O5  1  0.927  0.958  0.714  1.0
  O  O6  1  0.939  0.621  0.522  1.0
  O  O7  1  0.577  0.547  0.282  1.0
  O  O8  1  0.073  0.042  0.286  1.0
  O  O9  1  0.061  0.379  0.478  1.0
[/CIF]
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