The compound described by LiAg3F8 crystallizes in the triclinic P1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted see-saw-like geometry to one F(1), one F(11), one F(2), and one F(3) atom. In the second Li site, Li(2) is bonded in a distorted see-saw-like geometry to one F(14), one F(15), one F(16), and one F(6) atom. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to one F(1), one F(13), one F(14), one F(16), one F(5), and one F(8) atom. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one F(13), one F(15), one F(2), one F(5), one F(6), and one F(7) atom. In the third Ag site, Ag(3) is bonded in a distorted octahedral geometry to one F(10), one F(11), one F(13), one F(4), one F(6), and one F(7) atom. In the fourth Ag site, Ag(4) is bonded in a distorted octahedral geometry to one F(12), one F(14), one F(3), one F(5), one F(8), and one F(9) atom. In the fifth Ag site, Ag(5) is bonded in a 6-coordinate geometry to one F(10), one F(11), one F(12), one F(15), one F(2), and one F(4) atom. In the sixth Ag site, Ag(6) is bonded in a 6-coordinate geometry to one F(1), one F(12), one F(16), one F(3), one F(4), and one F(9) atom. There are sixteen inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one Ag(6) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Li(1), one Ag(2), and one Ag(5) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Li(1), one Ag(4), and one Ag(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Ag(3), one Ag(5), and one Ag(6) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Ag(1), one Ag(2), and one Ag(4) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Li(2), one Ag(2), and one Ag(3) atom. In the seventh F site, F(7) is bonded in a distorted bent 150 degrees geometry to one Ag(2) and one Ag(3) atom. In the eighth F site, F(8) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one Ag(4) atom. In the ninth F site, F(9) is bonded in a distorted bent 150 degrees geometry to one Ag(4) and one Ag(6) atom. In the tenth F site, F(10) is bonded in a distorted bent 150 degrees geometry to one Ag(3) and one Ag(5) atom. In the eleventh F site, F(11) is bonded in a trigonal planar geometry to one Li(1), one Ag(3), and one Ag(5) atom. In the twelfth F site, F(12) is bonded in a distorted trigonal planar geometry to one Ag(4), one Ag(5), and one Ag(6) atom. In the thirteenth F site, F(13) is bonded in a distorted trigonal planar geometry to one Ag(1), one Ag(2), and one Ag(3) atom. In the fourteenth F site, F(14) is bonded in a trigonal planar geometry to one Li(2), one Ag(1), and one Ag(4) atom. In the fifteenth F site, F(15) is bonded in a 3-coordinate geometry to one Li(2), one Ag(2), and one Ag(5) atom. In the sixteenth F site, F(16) is bonded in a 3-coordinate geometry to one Li(2), one Ag(1), and one Ag(6) atom. is represented by the CIF file [CIF]
data_LiAg3F8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.389
_cell_length_b   6.899
_cell_length_c   9.977
_cell_angle_alpha   89.206
_cell_angle_beta   105.765
_cell_angle_gamma   67.028
_symmetry_Int_Tables_number   1
_cell_volume   325.628
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.719  0.749  0.251  1.0
  Li  Li1  1  0.283  0.251  0.749  1.0
  Ag  Ag2  1  0.886  0.869  0.612  1.0
  Ag  Ag3  1  0.644  0.630  0.889  1.0
  Ag  Ag4  1  1.000  0.000  1.000  1.0
  Ag  Ag5  1  0.500  0.500  0.500  1.0
  Ag  Ag6  1  0.355  0.370  0.111  1.0
  Ag  Ag7  1  0.114  0.130  0.388  1.0
  F  F8  1  0.632  0.898  0.410  1.0
  F  F9  1  0.620  0.602  0.090  1.0
  F  F10  1  0.745  0.485  0.374  1.0
  F  F11  1  0.819  0.139  0.202  1.0
  F  F12  1  0.742  0.640  0.702  1.0
  F  F13  1  0.644  0.986  0.873  1.0
  F  F14  1  0.941  0.290  0.914  1.0
  F  F15  1  0.816  0.210  0.586  1.0
  F  F16  1  0.184  0.790  0.414  1.0
  F  F17  1  0.059  0.710  0.085  1.0
  F  F18  1  0.356  0.014  0.127  1.0
  F  F19  1  0.257  0.361  0.298  1.0
  F  F20  1  0.182  0.859  0.798  1.0
  F  F21  1  0.257  0.514  0.626  1.0
  F  F22  1  0.379  0.397  0.910  1.0
  F  F23  1  0.367  0.102  0.590  1.0
[/CIF]
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The compound described by LiAg3F8 crystallizes in the triclinic P1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted see-saw-like geometry to one F(1), one F(11), one F(2), and one F(3) atom. In the second Li site, Li(2) is bonded in a distorted see-saw-like geometry to one F(14), one F(15), one F(16), and one F(6) atom. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 6-coordinate geometry to one F(1), one F(13), one F(14), one F(16), one F(5), and one F(8) atom. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to one F(13), one F(15), one F(2), one F(5), one F(6), and one F(7) atom. In the third Ag site, Ag(3) is bonded in a distorted octahedral geometry to one F(10), one F(11), one F(13), one F(4), one F(6), and one F(7) atom. In the fourth Ag site, Ag(4) is bonded in a distorted octahedral geometry to one F(12), one F(14), one F(3), one F(5), one F(8), and one F(9) atom. In the fifth Ag site, Ag(5) is bonded in a 6-coordinate geometry to one F(10), one F(11), one F(12), one F(15), one F(2), and one F(4) atom. In the sixth Ag site, Ag(6) is bonded in a 6-coordinate geometry to one F(1), one F(12), one F(16), one F(3), one F(4), and one F(9) atom. There are sixteen inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one Ag(6) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Li(1), one Ag(2), and one Ag(5) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to one Li(1), one Ag(4), and one Ag(6) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Ag(3), one Ag(5), and one Ag(6) atom. In the fifth F site, F(5) is bonded in a distorted trigonal planar geometry to one Ag(1), one Ag(2), and one Ag(4) atom. In the sixth F site, F(6) is bonded in a trigonal planar geometry to one Li(2), one Ag(2), and one Ag(3) atom. In the seventh F site, F(7) is bonded in a distorted bent 150 degrees geometry to one Ag(2) and one Ag(3) atom. In the eighth F site, F(8) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one Ag(4) atom. In the ninth F site, F(9) is bonded in a distorted bent 150 degrees geometry to one Ag(4) and one Ag(6) atom. In the tenth F site, F(10) is bonded in a distorted bent 150 degrees geometry to one Ag(3) and one Ag(5) atom. In the eleventh F site, F(11) is bonded in a trigonal planar geometry to one Li(1), one Ag(3), and one Ag(5) atom. In the twelfth F site, F(12) is bonded in a distorted trigonal planar geometry to one Ag(4), one Ag(5), and one Ag(6) atom. In the thirteenth F site, F(13) is bonded in a distorted trigonal planar geometry to one Ag(1), one Ag(2), and one Ag(3) atom. In the fourteenth F site, F(14) is bonded in a trigonal planar geometry to one Li(2), one Ag(1), and one Ag(4) atom. In the fifteenth F site, F(15) is bonded in a 3-coordinate geometry to one Li(2), one Ag(2), and one Ag(5) atom. In the sixteenth F site, F(16) is bonded in a 3-coordinate geometry to one Li(2), one Ag(1), and one Ag(6) atom. is represented by the CIF file [CIF]
data_LiAg3F8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.389
_cell_length_b   6.899
_cell_length_c   9.977
_cell_angle_alpha   89.206
_cell_angle_beta   105.765
_cell_angle_gamma   67.028
_symmetry_Int_Tables_number   1
_cell_volume   325.628
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.719  0.749  0.251  1.0
  Li  Li1  1  0.283  0.251  0.749  1.0
  Ag  Ag2  1  0.886  0.869  0.612  1.0
  Ag  Ag3  1  0.644  0.630  0.889  1.0
  Ag  Ag4  1  1.000  0.000  1.000  1.0
  Ag  Ag5  1  0.500  0.500  0.500  1.0
  Ag  Ag6  1  0.355  0.370  0.111  1.0
  Ag  Ag7  1  0.114  0.130  0.388  1.0
  F  F8  1  0.632  0.898  0.410  1.0
  F  F9  1  0.620  0.602  0.090  1.0
  F  F10  1  0.745  0.485  0.374  1.0
  F  F11  1  0.819  0.139  0.202  1.0
  F  F12  1  0.742  0.640  0.702  1.0
  F  F13  1  0.644  0.986  0.873  1.0
  F  F14  1  0.941  0.290  0.914  1.0
  F  F15  1  0.816  0.210  0.586  1.0
  F  F16  1  0.184  0.790  0.414  1.0
  F  F17  1  0.059  0.710  0.085  1.0
  F  F18  1  0.356  0.014  0.127  1.0
  F  F19  1  0.257  0.361  0.298  1.0
  F  F20  1  0.182  0.859  0.798  1.0
  F  F21  1  0.257  0.514  0.626  1.0
  F  F22  1  0.379  0.397  0.910  1.0
  F  F23  1  0.367  0.102  0.590  1.0
[/CIF]
.