The structure described by RhSb2 crystallizes in the monoclinic P2_1/c space group. Rh(1) is bonded to three equivalent Sb(1) and three equivalent Sb(2) atoms to form a mixture of corner and edge-sharing RhSb6 octahedra. The corner-sharing octahedral tilt angles range from 51-57°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to three equivalent Rh(1) atoms. In the second Sb site, Sb(2) is bonded in a 3-coordinate geometry to three equivalent Rh(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.606
_cell_length_b   6.654
_cell_length_c   6.733
_cell_angle_alpha   116.128
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   265.707
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.638  0.655  0.824  1.0
  Sb  Sb1  1  0.138  0.345  0.676  1.0
  Sb  Sb2  1  0.362  0.345  0.176  1.0
  Sb  Sb3  1  0.862  0.655  0.324  1.0
  Sb  Sb4  1  0.364  0.849  0.627  1.0
  Sb  Sb5  1  0.864  0.151  0.873  1.0
  Sb  Sb6  1  0.636  0.151  0.373  1.0
  Sb  Sb7  1  0.136  0.849  0.127  1.0
  Rh  Rh8  1  0.000  0.728  0.713  1.0
  Rh  Rh9  1  0.500  0.272  0.787  1.0
  Rh  Rh10  1  1.000  0.272  0.287  1.0
  Rh  Rh11  1  0.500  0.728  0.213  1.0
[/CIF]
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The structure described by RhSb2 crystallizes in the monoclinic P2_1/c space group. Rh(1) is bonded to three equivalent Sb(1) and three equivalent Sb(2) atoms to form a mixture of corner and edge-sharing RhSb6 octahedra. The corner-sharing octahedral tilt angles range from 51-57°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to three equivalent Rh(1) atoms. In the second Sb site, Sb(2) is bonded in a 3-coordinate geometry to three equivalent Rh(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.606
_cell_length_b   6.654
_cell_length_c   6.733
_cell_angle_alpha   116.128
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   265.707
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.638  0.655  0.824  1.0
  Sb  Sb1  1  0.138  0.345  0.676  1.0
  Sb  Sb2  1  0.362  0.345  0.176  1.0
  Sb  Sb3  1  0.862  0.655  0.324  1.0
  Sb  Sb4  1  0.364  0.849  0.627  1.0
  Sb  Sb5  1  0.864  0.151  0.873  1.0
  Sb  Sb6  1  0.636  0.151  0.373  1.0
  Sb  Sb7  1  0.136  0.849  0.127  1.0
  Rh  Rh8  1  0.000  0.728  0.713  1.0
  Rh  Rh9  1  0.500  0.272  0.787  1.0
  Rh  Rh10  1  1.000  0.272  0.287  1.0
  Rh  Rh11  1  0.500  0.728  0.213  1.0
[/CIF]
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