The compound described by CrN4H13O(H2O)2Cl2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four hydrochloric acid atoms, four water molecules, and one CrN4H13O cluster. In the CrN4H13O cluster, Cr(1) is bonded to one N(1), one N(2), one N(3), one N(4), and two equivalent O(3) atoms to form edge-sharing CrN4O2 octahedra. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(5), one H(6), and one H(7) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(10), one H(8), and one H(9) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(15), one H(16), and one H(17) atom. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(12), one H(13), and one H(14) atom. There are thirteen inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(7) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one O(3) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one N(4) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one N(4) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one N(4) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one N(3) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one N(3) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one N(3) atom. O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cr(1) and one H(11) atom. is represented by the CIF file [CIF]
data_CrH17N4Cl2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.836
_cell_length_b   7.931
_cell_length_c   10.448
_cell_angle_alpha   92.583
_cell_angle_beta   106.140
_cell_angle_gamma   105.674
_symmetry_Int_Tables_number   1
_cell_volume   519.471
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.989  0.992  0.850  1.0
  Cr  Cr1  1  0.011  0.008  0.150  1.0
  H  H2  1  0.540  0.328  0.593  1.0
  H  H3  1  0.460  0.672  0.407  1.0
  H  H4  1  0.745  0.390  0.548  1.0
  H  H5  1  0.255  0.610  0.452  1.0
  H  H6  1  0.606  0.328  0.159  1.0
  H  H7  1  0.394  0.672  0.841  1.0
  H  H8  1  0.672  0.428  0.307  1.0
  H  H9  1  0.328  0.572  0.693  1.0
  H  H10  1  0.256  0.887  0.734  1.0
  H  H11  1  0.744  0.113  0.266  1.0
  H  H12  1  0.191  0.058  0.664  1.0
  H  H13  1  0.809  0.942  0.336  1.0
  H  H14  1  0.363  0.092  0.815  1.0
  H  H15  1  0.637  0.908  0.185  1.0
  H  H16  1  0.712  0.083  0.642  1.0
  H  H17  1  0.288  0.917  0.358  1.0
  H  H18  1  0.762  0.900  0.592  1.0
  H  H19  1  0.238  0.100  0.408  1.0
  H  H20  1  0.604  0.886  0.687  1.0
  H  H21  1  0.396  0.114  0.313  1.0
  H  H22  1  0.268  0.913  0.040  1.0
  H  H23  1  0.732  0.087  0.960  1.0
  H  H24  1  0.111  0.331  0.279  1.0
  H  H25  1  0.889  0.669  0.721  1.0
  H  H26  1  0.243  0.345  0.169  1.0
  H  H27  1  0.757  0.655  0.831  1.0
  H  H28  1  0.986  0.335  0.119  1.0
  H  H29  1  0.014  0.665  0.881  1.0
  H  H30  1  0.923  0.700  0.242  1.0
  H  H31  1  0.077  0.300  0.758  1.0
  H  H32  1  0.787  0.663  0.081  1.0
  H  H33  1  0.213  0.337  0.919  1.0
  H  H34  1  0.046  0.681  0.129  1.0
  H  H35  1  0.954  0.319  0.871  1.0
  N  N36  1  0.224  0.004  0.752  1.0
  N  N37  1  0.776  0.996  0.248  1.0
  N  N38  1  0.739  0.967  0.671  1.0
  N  N39  1  0.261  0.033  0.329  1.0
  N  N40  1  0.069  0.269  0.851  1.0
  N  N41  1  0.931  0.731  0.149  1.0
  N  N42  1  0.902  0.713  0.818  1.0
  N  N43  1  0.098  0.287  0.182  1.0
  Cl  Cl44  1  0.809  0.674  0.453  1.0
  Cl  Cl45  1  0.191  0.326  0.547  1.0
  Cl  Cl46  1  0.652  0.330  0.958  1.0
  Cl  Cl47  1  0.348  0.670  0.042  1.0
  O  O48  1  0.681  0.310  0.604  1.0
  O  O49  1  0.319  0.690  0.396  1.0
  O  O50  1  0.604  0.311  0.252  1.0
  O  O51  1  0.396  0.689  0.748  1.0
  O  O52  1  0.800  0.990  0.968  1.0
  O  O53  1  0.200  0.010  0.032  1.0
[/CIF]
.
The compound described by CrN4H13O(H2O)2Cl2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four hydrochloric acid atoms, four water molecules, and one CrN4H13O cluster. In the CrN4H13O cluster, Cr(1) is bonded to one N(1), one N(2), one N(3), one N(4), and two equivalent O(3) atoms to form edge-sharing CrN4O2 octahedra. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(5), one H(6), and one H(7) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(10), one H(8), and one H(9) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(15), one H(16), and one H(17) atom. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one Cr(1), one H(12), one H(13), and one H(14) atom. There are thirteen inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(7) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one O(3) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one N(4) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one N(4) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one N(4) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one N(3) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one N(3) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one N(3) atom. O(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cr(1) and one H(11) atom. is represented by the CIF file [CIF]
data_CrH17N4Cl2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.836
_cell_length_b   7.931
_cell_length_c   10.448
_cell_angle_alpha   92.583
_cell_angle_beta   106.140
_cell_angle_gamma   105.674
_symmetry_Int_Tables_number   1
_cell_volume   519.471
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.989  0.992  0.850  1.0
  Cr  Cr1  1  0.011  0.008  0.150  1.0
  H  H2  1  0.540  0.328  0.593  1.0
  H  H3  1  0.460  0.672  0.407  1.0
  H  H4  1  0.745  0.390  0.548  1.0
  H  H5  1  0.255  0.610  0.452  1.0
  H  H6  1  0.606  0.328  0.159  1.0
  H  H7  1  0.394  0.672  0.841  1.0
  H  H8  1  0.672  0.428  0.307  1.0
  H  H9  1  0.328  0.572  0.693  1.0
  H  H10  1  0.256  0.887  0.734  1.0
  H  H11  1  0.744  0.113  0.266  1.0
  H  H12  1  0.191  0.058  0.664  1.0
  H  H13  1  0.809  0.942  0.336  1.0
  H  H14  1  0.363  0.092  0.815  1.0
  H  H15  1  0.637  0.908  0.185  1.0
  H  H16  1  0.712  0.083  0.642  1.0
  H  H17  1  0.288  0.917  0.358  1.0
  H  H18  1  0.762  0.900  0.592  1.0
  H  H19  1  0.238  0.100  0.408  1.0
  H  H20  1  0.604  0.886  0.687  1.0
  H  H21  1  0.396  0.114  0.313  1.0
  H  H22  1  0.268  0.913  0.040  1.0
  H  H23  1  0.732  0.087  0.960  1.0
  H  H24  1  0.111  0.331  0.279  1.0
  H  H25  1  0.889  0.669  0.721  1.0
  H  H26  1  0.243  0.345  0.169  1.0
  H  H27  1  0.757  0.655  0.831  1.0
  H  H28  1  0.986  0.335  0.119  1.0
  H  H29  1  0.014  0.665  0.881  1.0
  H  H30  1  0.923  0.700  0.242  1.0
  H  H31  1  0.077  0.300  0.758  1.0
  H  H32  1  0.787  0.663  0.081  1.0
  H  H33  1  0.213  0.337  0.919  1.0
  H  H34  1  0.046  0.681  0.129  1.0
  H  H35  1  0.954  0.319  0.871  1.0
  N  N36  1  0.224  0.004  0.752  1.0
  N  N37  1  0.776  0.996  0.248  1.0
  N  N38  1  0.739  0.967  0.671  1.0
  N  N39  1  0.261  0.033  0.329  1.0
  N  N40  1  0.069  0.269  0.851  1.0
  N  N41  1  0.931  0.731  0.149  1.0
  N  N42  1  0.902  0.713  0.818  1.0
  N  N43  1  0.098  0.287  0.182  1.0
  Cl  Cl44  1  0.809  0.674  0.453  1.0
  Cl  Cl45  1  0.191  0.326  0.547  1.0
  Cl  Cl46  1  0.652  0.330  0.958  1.0
  Cl  Cl47  1  0.348  0.670  0.042  1.0
  O  O48  1  0.681  0.310  0.604  1.0
  O  O49  1  0.319  0.690  0.396  1.0
  O  O50  1  0.604  0.311  0.252  1.0
  O  O51  1  0.396  0.689  0.748  1.0
  O  O52  1  0.800  0.990  0.968  1.0
  O  O53  1  0.200  0.010  0.032  1.0
[/CIF]
.