The compound described by Cs2Pd(IBr2)2 crystallizes in the monoclinic C2/m space group. Cs(1) is bonded in a 11-coordinate geometry to three equivalent I(1) and eight equivalent Br(1) atoms. Pd(1) is bonded to two equivalent I(1) and four equivalent Br(1) atoms to form PdI2Br4 octahedra that share corners with two equivalent I(1)Cs3PdI square pyramids. I(1) is bonded to three equivalent Cs(1), one Pd(1), and one I(1) atom to form distorted ICs3PdI square pyramids that share  a cornercorner with one Pd(1)I2Br4 octahedra, corners with three equivalent I(1)Cs3PdI square pyramids, and edges with two equivalent I(1)Cs3PdI square pyramids. The corner-sharing octahedral tilt angles are 3°. Br(1) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one Pd(1) atom. is represented by the CIF card [CIF]
data_Cs2Pd(IBr2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.549
_cell_length_b   7.549
_cell_length_c   8.925
_cell_angle_alpha   55.656
_cell_angle_beta   55.656
_cell_angle_gamma   68.199
_symmetry_Int_Tables_number   1
_cell_volume   345.729
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.246  0.246  0.276  1.0
  Cs  Cs1  1  0.754  0.754  0.724  1.0
  Pd  Pd2  1  0.000  0.000  0.000  1.0
  I  I3  1  0.657  0.657  0.349  1.0
  I  I4  1  0.343  0.343  0.651  1.0
  Br  Br5  1  0.808  0.223  0.181  1.0
  Br  Br6  1  0.192  0.777  0.819  1.0
  Br  Br7  1  0.223  0.808  0.181  1.0
  Br  Br8  1  0.777  0.192  0.819  1.0
[/CIF]
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The compound described by Cs2Pd(IBr2)2 crystallizes in the monoclinic C2/m space group. Cs(1) is bonded in a 11-coordinate geometry to three equivalent I(1) and eight equivalent Br(1) atoms. Pd(1) is bonded to two equivalent I(1) and four equivalent Br(1) atoms to form PdI2Br4 octahedra that share corners with two equivalent I(1)Cs3PdI square pyramids. I(1) is bonded to three equivalent Cs(1), one Pd(1), and one I(1) atom to form distorted ICs3PdI square pyramids that share  a cornercorner with one Pd(1)I2Br4 octahedra, corners with three equivalent I(1)Cs3PdI square pyramids, and edges with two equivalent I(1)Cs3PdI square pyramids. The corner-sharing octahedral tilt angles are 3°. Br(1) is bonded in a 5-coordinate geometry to four equivalent Cs(1) and one Pd(1) atom. is represented by the CIF card [CIF]
data_Cs2Pd(IBr2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.549
_cell_length_b   7.549
_cell_length_c   8.925
_cell_angle_alpha   55.656
_cell_angle_beta   55.656
_cell_angle_gamma   68.199
_symmetry_Int_Tables_number   1
_cell_volume   345.729
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.246  0.246  0.276  1.0
  Cs  Cs1  1  0.754  0.754  0.724  1.0
  Pd  Pd2  1  0.000  0.000  0.000  1.0
  I  I3  1  0.657  0.657  0.349  1.0
  I  I4  1  0.343  0.343  0.651  1.0
  Br  Br5  1  0.808  0.223  0.181  1.0
  Br  Br6  1  0.192  0.777  0.819  1.0
  Br  Br7  1  0.223  0.808  0.181  1.0
  Br  Br8  1  0.777  0.192  0.819  1.0
[/CIF]
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