The crystal structure described by AsF3AsSF8NS2F3NSOFNF2NOF crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one arsenic trifluoride molecule, one difluoroamine molecule, one n-hydroxyhypofluorous amide molecule, one AsSF8 cluster, one NS2F3 cluster, and one NSOF cluster. In the AsSF8 cluster, As(2) is bonded in a distorted rectangular see-saw-like geometry to one F(11), one F(18), one F(5), and one F(6) atom. S(3) is bonded in a square pyramidal geometry to one F(15), one F(5), one F(7), one F(8), and one F(9) atom. There are eight inequivalent F sites. In the first F site, F(5) is bonded in a distorted bent 150 degrees geometry to one As(2) and one S(3) atom. In the second F site, F(6) is bonded in a single-bond geometry to one As(2) atom. In the third F site, F(7) is bonded in a single-bond geometry to one S(3) atom. In the fourth F site, F(8) is bonded in a single-bond geometry to one S(3) atom. In the fifth F site, F(9) is bonded in a single-bond geometry to one S(3) atom. In the sixth F site, F(11) is bonded in a single-bond geometry to one As(2) atom. In the seventh F site, F(15) is bonded in a single-bond geometry to one S(3) atom. In the eighth F site, F(18) is bonded in a single-bond geometry to one As(2) atom. In the NS2F3 cluster, N(3) is bonded in a single-bond geometry to one S(4) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a 2-coordinate geometry to one F(12), one F(13), and one F(14) atom. In the second S site, S(4) is bonded in a water-like geometry to one N(3) and one F(13) atom. There are three inequivalent F sites. In the first F site, F(12) is bonded in a single-bond geometry to one S(2) atom. In the second F site, F(13) is bonded in a bent 120 degrees geometry to one S(2) and one S(4) atom. In the third F site, F(14) is bonded in a single-bond geometry to one S(2) atom. In the NSOF cluster, N(2) is bonded in a single-bond geometry to one S(1) atom. S(1) is bonded in a distorted trigonal planar geometry to one N(2), one O(2), and one F(16) atom. O(2) is bonded in a single-bond geometry to one S(1) atom. F(16) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_AsS2N2OF9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.540
_cell_length_b   7.558
_cell_length_c   7.795
_cell_angle_alpha   91.251
_cell_angle_beta   109.637
_cell_angle_gamma   89.726
_symmetry_Int_Tables_number   1
_cell_volume   418.263
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.285  0.334  0.504  1.0
  As  As1  1  0.621  0.731  0.514  1.0
  S  S2  1  0.640  0.715  0.963  1.0
  S  S3  1  0.176  0.709  0.086  1.0
  S  S4  1  0.748  0.270  0.821  1.0
  S  S5  1  0.333  0.117  0.987  1.0
  N  N6  1  0.155  0.827  0.390  1.0
  N  N7  1  0.841  0.716  0.056  1.0
  N  N8  1  0.290  0.217  0.125  1.0
  N  N9  1  0.701  0.209  0.390  1.0
  O  O10  1  0.680  0.333  0.302  1.0
  O  O11  1  0.502  0.781  0.801  1.0
  F  F12  1  0.246  0.510  0.637  1.0
  F  F13  1  0.243  0.168  0.643  1.0
  F  F14  1  0.052  0.338  0.357  1.0
  F  F15  1  0.121  0.991  0.311  1.0
  F  F16  1  0.742  0.476  0.691  1.0
  F  F17  1  0.791  0.854  0.685  1.0
  F  F18  1  0.895  0.375  0.985  1.0
  F  F19  1  0.765  0.103  0.962  1.0
  F  F20  1  0.921  0.197  0.757  1.0
  F  F21  1  0.115  0.844  0.544  1.0
  F  F22  1  0.505  0.921  0.385  1.0
  F  F23  1  0.261  0.547  0.217  1.0
  F  F24  1  0.166  0.928  0.906  1.0
  F  F25  1  0.147  0.599  0.908  1.0
  F  F26  1  0.565  0.393  0.916  1.0
  F  F27  1  0.513  0.699  0.094  1.0
  F  F28  1  0.785  0.056  0.303  1.0
  F  F29  1  0.781  0.689  0.397  1.0
[/CIF]
.
The crystal structure described by AsF3AsSF8NS2F3NSOFNF2NOF crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one arsenic trifluoride molecule, one difluoroamine molecule, one n-hydroxyhypofluorous amide molecule, one AsSF8 cluster, one NS2F3 cluster, and one NSOF cluster. In the AsSF8 cluster, As(2) is bonded in a distorted rectangular see-saw-like geometry to one F(11), one F(18), one F(5), and one F(6) atom. S(3) is bonded in a square pyramidal geometry to one F(15), one F(5), one F(7), one F(8), and one F(9) atom. There are eight inequivalent F sites. In the first F site, F(5) is bonded in a distorted bent 150 degrees geometry to one As(2) and one S(3) atom. In the second F site, F(6) is bonded in a single-bond geometry to one As(2) atom. In the third F site, F(7) is bonded in a single-bond geometry to one S(3) atom. In the fourth F site, F(8) is bonded in a single-bond geometry to one S(3) atom. In the fifth F site, F(9) is bonded in a single-bond geometry to one S(3) atom. In the sixth F site, F(11) is bonded in a single-bond geometry to one As(2) atom. In the seventh F site, F(15) is bonded in a single-bond geometry to one S(3) atom. In the eighth F site, F(18) is bonded in a single-bond geometry to one As(2) atom. In the NS2F3 cluster, N(3) is bonded in a single-bond geometry to one S(4) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a 2-coordinate geometry to one F(12), one F(13), and one F(14) atom. In the second S site, S(4) is bonded in a water-like geometry to one N(3) and one F(13) atom. There are three inequivalent F sites. In the first F site, F(12) is bonded in a single-bond geometry to one S(2) atom. In the second F site, F(13) is bonded in a bent 120 degrees geometry to one S(2) and one S(4) atom. In the third F site, F(14) is bonded in a single-bond geometry to one S(2) atom. In the NSOF cluster, N(2) is bonded in a single-bond geometry to one S(1) atom. S(1) is bonded in a distorted trigonal planar geometry to one N(2), one O(2), and one F(16) atom. O(2) is bonded in a single-bond geometry to one S(1) atom. F(16) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_AsS2N2OF9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.540
_cell_length_b   7.558
_cell_length_c   7.795
_cell_angle_alpha   91.251
_cell_angle_beta   109.637
_cell_angle_gamma   89.726
_symmetry_Int_Tables_number   1
_cell_volume   418.263
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.285  0.334  0.504  1.0
  As  As1  1  0.621  0.731  0.514  1.0
  S  S2  1  0.640  0.715  0.963  1.0
  S  S3  1  0.176  0.709  0.086  1.0
  S  S4  1  0.748  0.270  0.821  1.0
  S  S5  1  0.333  0.117  0.987  1.0
  N  N6  1  0.155  0.827  0.390  1.0
  N  N7  1  0.841  0.716  0.056  1.0
  N  N8  1  0.290  0.217  0.125  1.0
  N  N9  1  0.701  0.209  0.390  1.0
  O  O10  1  0.680  0.333  0.302  1.0
  O  O11  1  0.502  0.781  0.801  1.0
  F  F12  1  0.246  0.510  0.637  1.0
  F  F13  1  0.243  0.168  0.643  1.0
  F  F14  1  0.052  0.338  0.357  1.0
  F  F15  1  0.121  0.991  0.311  1.0
  F  F16  1  0.742  0.476  0.691  1.0
  F  F17  1  0.791  0.854  0.685  1.0
  F  F18  1  0.895  0.375  0.985  1.0
  F  F19  1  0.765  0.103  0.962  1.0
  F  F20  1  0.921  0.197  0.757  1.0
  F  F21  1  0.115  0.844  0.544  1.0
  F  F22  1  0.505  0.921  0.385  1.0
  F  F23  1  0.261  0.547  0.217  1.0
  F  F24  1  0.166  0.928  0.906  1.0
  F  F25  1  0.147  0.599  0.908  1.0
  F  F26  1  0.565  0.393  0.916  1.0
  F  F27  1  0.513  0.699  0.094  1.0
  F  F28  1  0.785  0.056  0.303  1.0
  F  F29  1  0.781  0.689  0.397  1.0
[/CIF]
.