The crystal structure described by BaAgZnF7 crystallizes in the monoclinic P2_1/c space group. Ba(1) is bonded in a 12-coordinate geometry to one F(1), one F(2), two equivalent F(3), two equivalent F(4), two equivalent F(5), two equivalent F(6), and two equivalent F(7) atoms. Ag(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form AgF6 octahedra that share corners with three equivalent Zn(1)F6 octahedra and  an edgeedge with one Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 53-59°. Zn(1) is bonded to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom to form ZnF6 octahedra that share corners with three equivalent Ag(1)F6 octahedra and  an edgeedge with one Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 53-59°. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Ag(1), and one Zn(1) atom. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Ag(1), and one Zn(1) atom. In the third F site, F(3) is bonded to two equivalent Ba(1), one Ag(1), and one Zn(1) atom to form distorted corner-sharing FBa2ZnAg trigonal pyramids. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to two equivalent Ba(1) and one Ag(1) atom. In the fifth F site, F(5) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1), one Ag(1), and one Zn(1) atom. In the sixth F site, F(6) is bonded in a distorted water-like geometry to two equivalent Ba(1), one Ag(1), and one Zn(1) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to two equivalent Ba(1) and one Zn(1) atom. is represented by the CIF file [CIF]
data_BaZnAgF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.265
_cell_length_b   5.783
_cell_length_c   9.877
_cell_angle_alpha   87.052
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   585.500
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.322  0.734  0.498  1.0
  Ba  Ba1  1  0.822  0.266  0.002  1.0
  Ba  Ba2  1  0.678  0.266  0.502  1.0
  Ba  Ba3  1  0.178  0.734  0.998  1.0
  Zn  Zn4  1  0.397  0.303  0.807  1.0
  Zn  Zn5  1  0.897  0.697  0.693  1.0
  Zn  Zn6  1  0.103  0.303  0.307  1.0
  Zn  Zn7  1  0.603  0.697  0.193  1.0
  Ag  Ag8  1  0.610  0.803  0.813  1.0
  Ag  Ag9  1  0.390  0.197  0.187  1.0
  Ag  Ag10  1  0.890  0.803  0.313  1.0
  Ag  Ag11  1  0.110  0.197  0.687  1.0
  F  F12  1  0.445  0.869  0.119  1.0
  F  F13  1  0.062  0.627  0.375  1.0
  F  F14  1  0.716  0.507  0.750  1.0
  F  F15  1  0.284  0.493  0.250  1.0
  F  F16  1  0.462  0.102  0.380  1.0
  F  F17  1  0.802  0.738  0.509  1.0
  F  F18  1  0.786  0.984  0.749  1.0
  F  F19  1  0.962  0.898  0.120  1.0
  F  F20  1  0.438  0.627  0.875  1.0
  F  F21  1  0.216  0.493  0.750  1.0
  F  F22  1  0.055  0.869  0.619  1.0
  F  F23  1  0.555  0.131  0.881  1.0
  F  F24  1  0.286  0.016  0.751  1.0
  F  F25  1  0.959  0.609  0.874  1.0
  F  F26  1  0.538  0.898  0.620  1.0
  F  F27  1  0.038  0.102  0.880  1.0
  F  F28  1  0.214  0.016  0.251  1.0
  F  F29  1  0.945  0.131  0.381  1.0
  F  F30  1  0.459  0.391  0.626  1.0
  F  F31  1  0.938  0.373  0.625  1.0
  F  F32  1  0.041  0.391  0.126  1.0
  F  F33  1  0.714  0.984  0.249  1.0
  F  F34  1  0.541  0.609  0.374  1.0
  F  F35  1  0.302  0.262  0.991  1.0
  F  F36  1  0.198  0.262  0.491  1.0
  F  F37  1  0.698  0.738  0.009  1.0
  F  F38  1  0.562  0.373  0.125  1.0
  F  F39  1  0.784  0.507  0.250  1.0
[/CIF]
.
The crystal structure described by BaAgZnF7 crystallizes in the monoclinic P2_1/c space group. Ba(1) is bonded in a 12-coordinate geometry to one F(1), one F(2), two equivalent F(3), two equivalent F(4), two equivalent F(5), two equivalent F(6), and two equivalent F(7) atoms. Ag(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form AgF6 octahedra that share corners with three equivalent Zn(1)F6 octahedra and  an edgeedge with one Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 53-59°. Zn(1) is bonded to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom to form ZnF6 octahedra that share corners with three equivalent Ag(1)F6 octahedra and  an edgeedge with one Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 53-59°. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Ag(1), and one Zn(1) atom. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Ba(1), one Ag(1), and one Zn(1) atom. In the third F site, F(3) is bonded to two equivalent Ba(1), one Ag(1), and one Zn(1) atom to form distorted corner-sharing FBa2ZnAg trigonal pyramids. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to two equivalent Ba(1) and one Ag(1) atom. In the fifth F site, F(5) is bonded in a distorted bent 120 degrees geometry to two equivalent Ba(1), one Ag(1), and one Zn(1) atom. In the sixth F site, F(6) is bonded in a distorted water-like geometry to two equivalent Ba(1), one Ag(1), and one Zn(1) atom. In the seventh F site, F(7) is bonded in a distorted trigonal planar geometry to two equivalent Ba(1) and one Zn(1) atom. is represented by the CIF file [CIF]
data_BaZnAgF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.265
_cell_length_b   5.783
_cell_length_c   9.877
_cell_angle_alpha   87.052
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   585.500
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.322  0.734  0.498  1.0
  Ba  Ba1  1  0.822  0.266  0.002  1.0
  Ba  Ba2  1  0.678  0.266  0.502  1.0
  Ba  Ba3  1  0.178  0.734  0.998  1.0
  Zn  Zn4  1  0.397  0.303  0.807  1.0
  Zn  Zn5  1  0.897  0.697  0.693  1.0
  Zn  Zn6  1  0.103  0.303  0.307  1.0
  Zn  Zn7  1  0.603  0.697  0.193  1.0
  Ag  Ag8  1  0.610  0.803  0.813  1.0
  Ag  Ag9  1  0.390  0.197  0.187  1.0
  Ag  Ag10  1  0.890  0.803  0.313  1.0
  Ag  Ag11  1  0.110  0.197  0.687  1.0
  F  F12  1  0.445  0.869  0.119  1.0
  F  F13  1  0.062  0.627  0.375  1.0
  F  F14  1  0.716  0.507  0.750  1.0
  F  F15  1  0.284  0.493  0.250  1.0
  F  F16  1  0.462  0.102  0.380  1.0
  F  F17  1  0.802  0.738  0.509  1.0
  F  F18  1  0.786  0.984  0.749  1.0
  F  F19  1  0.962  0.898  0.120  1.0
  F  F20  1  0.438  0.627  0.875  1.0
  F  F21  1  0.216  0.493  0.750  1.0
  F  F22  1  0.055  0.869  0.619  1.0
  F  F23  1  0.555  0.131  0.881  1.0
  F  F24  1  0.286  0.016  0.751  1.0
  F  F25  1  0.959  0.609  0.874  1.0
  F  F26  1  0.538  0.898  0.620  1.0
  F  F27  1  0.038  0.102  0.880  1.0
  F  F28  1  0.214  0.016  0.251  1.0
  F  F29  1  0.945  0.131  0.381  1.0
  F  F30  1  0.459  0.391  0.626  1.0
  F  F31  1  0.938  0.373  0.625  1.0
  F  F32  1  0.041  0.391  0.126  1.0
  F  F33  1  0.714  0.984  0.249  1.0
  F  F34  1  0.541  0.609  0.374  1.0
  F  F35  1  0.302  0.262  0.991  1.0
  F  F36  1  0.198  0.262  0.491  1.0
  F  F37  1  0.698  0.738  0.009  1.0
  F  F38  1  0.562  0.373  0.125  1.0
  F  F39  1  0.784  0.507  0.250  1.0
[/CIF]
.