The structure described by Cs2WBiPO8 crystallizes in the orthorhombic Ibca space group. Cs(1) is bonded in a 8-coordinate geometry to one O(1), two equivalent O(2), two equivalent O(3), and three equivalent O(4) atoms. W(1) is bonded in a tetrahedral geometry to two equivalent O(3) and two equivalent O(4) atoms. Bi(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are four inequivalent O sites. In the first O site, O(4) is bonded in a 4-coordinate geometry to three equivalent Cs(1) and one W(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Cs(1), two equivalent Bi(1), and one P(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Cs(1), one Bi(1), and one P(1) atom. In the fourth O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Cs(1), one W(1), and one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs2BiPWO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.933
_cell_length_b   12.933
_cell_length_c   12.933
_cell_angle_alpha   147.824
_cell_angle_beta   121.689
_cell_angle_gamma   68.178
_symmetry_Int_Tables_number   1
_cell_volume   967.531
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.244  0.690  0.616  1.0
  Cs  Cs1  1  0.574  0.628  0.884  1.0
  Cs  Cs2  1  0.926  0.810  0.054  1.0
  Cs  Cs3  1  0.256  0.872  0.446  1.0
  Cs  Cs4  1  0.756  0.310  0.384  1.0
  Cs  Cs5  1  0.426  0.372  0.116  1.0
  Cs  Cs6  1  0.074  0.190  0.946  1.0
  Cs  Cs7  1  0.744  0.128  0.554  1.0
  Bi  Bi8  1  0.834  0.750  0.584  1.0
  Bi  Bi9  1  0.666  0.250  0.916  1.0
  Bi  Bi10  1  0.166  0.250  0.416  1.0
  Bi  Bi11  1  0.334  0.750  0.084  1.0
  P  P12  1  0.074  0.750  0.824  1.0
  P  P13  1  0.426  0.250  0.676  1.0
  P  P14  1  0.926  0.250  0.176  1.0
  P  P15  1  0.574  0.750  0.324  1.0
  W  W16  1  0.906  0.656  0.250  1.0
  W  W17  1  0.594  0.844  0.750  1.0
  W  W18  1  0.094  0.344  0.750  1.0
  W  W19  1  0.406  0.156  0.250  1.0
  O  O20  1  0.158  0.590  0.732  1.0
  O  O21  1  0.358  0.426  0.768  1.0
  O  O22  1  0.142  0.910  0.068  1.0
  O  O23  1  0.342  0.074  0.432  1.0
  O  O24  1  0.842  0.410  0.268  1.0
  O  O25  1  0.642  0.574  0.232  1.0
  O  O26  1  0.858  0.090  0.932  1.0
  O  O27  1  0.658  0.926  0.568  1.0
  O  O28  1  0.943  0.671  0.727  1.0
  O  O29  1  0.444  0.216  0.773  1.0
  O  O30  1  0.056  0.829  0.772  1.0
  O  O31  1  0.557  0.284  0.728  1.0
  O  O32  1  0.057  0.329  0.273  1.0
  O  O33  1  0.556  0.784  0.227  1.0
  O  O34  1  0.944  0.171  0.228  1.0
  O  O35  1  0.443  0.716  0.272  1.0
  O  O36  1  0.893  0.809  0.484  1.0
  O  O37  1  0.825  0.409  0.016  1.0
  O  O38  1  0.675  0.691  0.584  1.0
  O  O39  1  0.607  0.091  0.916  1.0
  O  O40  1  0.107  0.191  0.516  1.0
  O  O41  1  0.175  0.591  0.984  1.0
  O  O42  1  0.325  0.309  0.416  1.0
  O  O43  1  0.393  0.909  0.084  1.0
  O  O44  1  0.845  0.766  0.202  1.0
  O  O45  1  0.064  0.643  0.298  1.0
  O  O46  1  0.436  0.734  0.579  1.0
  O  O47  1  0.655  0.857  0.921  1.0
  O  O48  1  0.155  0.234  0.798  1.0
  O  O49  1  0.936  0.357  0.702  1.0
  O  O50  1  0.564  0.266  0.421  1.0
  O  O51  1  0.345  0.143  0.079  1.0
[/CIF]
.
The structure described by Cs2WBiPO8 crystallizes in the orthorhombic Ibca space group. Cs(1) is bonded in a 8-coordinate geometry to one O(1), two equivalent O(2), two equivalent O(3), and three equivalent O(4) atoms. W(1) is bonded in a tetrahedral geometry to two equivalent O(3) and two equivalent O(4) atoms. Bi(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are four inequivalent O sites. In the first O site, O(4) is bonded in a 4-coordinate geometry to three equivalent Cs(1) and one W(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Cs(1), two equivalent Bi(1), and one P(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Cs(1), one Bi(1), and one P(1) atom. In the fourth O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Cs(1), one W(1), and one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs2BiPWO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.933
_cell_length_b   12.933
_cell_length_c   12.933
_cell_angle_alpha   147.824
_cell_angle_beta   121.689
_cell_angle_gamma   68.178
_symmetry_Int_Tables_number   1
_cell_volume   967.531
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.244  0.690  0.616  1.0
  Cs  Cs1  1  0.574  0.628  0.884  1.0
  Cs  Cs2  1  0.926  0.810  0.054  1.0
  Cs  Cs3  1  0.256  0.872  0.446  1.0
  Cs  Cs4  1  0.756  0.310  0.384  1.0
  Cs  Cs5  1  0.426  0.372  0.116  1.0
  Cs  Cs6  1  0.074  0.190  0.946  1.0
  Cs  Cs7  1  0.744  0.128  0.554  1.0
  Bi  Bi8  1  0.834  0.750  0.584  1.0
  Bi  Bi9  1  0.666  0.250  0.916  1.0
  Bi  Bi10  1  0.166  0.250  0.416  1.0
  Bi  Bi11  1  0.334  0.750  0.084  1.0
  P  P12  1  0.074  0.750  0.824  1.0
  P  P13  1  0.426  0.250  0.676  1.0
  P  P14  1  0.926  0.250  0.176  1.0
  P  P15  1  0.574  0.750  0.324  1.0
  W  W16  1  0.906  0.656  0.250  1.0
  W  W17  1  0.594  0.844  0.750  1.0
  W  W18  1  0.094  0.344  0.750  1.0
  W  W19  1  0.406  0.156  0.250  1.0
  O  O20  1  0.158  0.590  0.732  1.0
  O  O21  1  0.358  0.426  0.768  1.0
  O  O22  1  0.142  0.910  0.068  1.0
  O  O23  1  0.342  0.074  0.432  1.0
  O  O24  1  0.842  0.410  0.268  1.0
  O  O25  1  0.642  0.574  0.232  1.0
  O  O26  1  0.858  0.090  0.932  1.0
  O  O27  1  0.658  0.926  0.568  1.0
  O  O28  1  0.943  0.671  0.727  1.0
  O  O29  1  0.444  0.216  0.773  1.0
  O  O30  1  0.056  0.829  0.772  1.0
  O  O31  1  0.557  0.284  0.728  1.0
  O  O32  1  0.057  0.329  0.273  1.0
  O  O33  1  0.556  0.784  0.227  1.0
  O  O34  1  0.944  0.171  0.228  1.0
  O  O35  1  0.443  0.716  0.272  1.0
  O  O36  1  0.893  0.809  0.484  1.0
  O  O37  1  0.825  0.409  0.016  1.0
  O  O38  1  0.675  0.691  0.584  1.0
  O  O39  1  0.607  0.091  0.916  1.0
  O  O40  1  0.107  0.191  0.516  1.0
  O  O41  1  0.175  0.591  0.984  1.0
  O  O42  1  0.325  0.309  0.416  1.0
  O  O43  1  0.393  0.909  0.084  1.0
  O  O44  1  0.845  0.766  0.202  1.0
  O  O45  1  0.064  0.643  0.298  1.0
  O  O46  1  0.436  0.734  0.579  1.0
  O  O47  1  0.655  0.857  0.921  1.0
  O  O48  1  0.155  0.234  0.798  1.0
  O  O49  1  0.936  0.357  0.702  1.0
  O  O50  1  0.564  0.266  0.421  1.0
  O  O51  1  0.345  0.143  0.079  1.0
[/CIF]
.