The crystal structure described by V2NO4F3NF is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two monofluoroamine molecules and two V2NO4F3 clusters. In each V2NO4F3 cluster, there are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), one O(4), one F(1), and one F(3) atom to form distorted edge-sharing VO3F2 trigonal bipyramids. In the second V site, V(2) is bonded to one O(2), one O(3), one F(2), and one F(3) atom to form edge-sharing VO2F2 tetrahedra. N(1) is bonded in a single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one V(2) atom. In the third O site, O(3) is bonded in a water-like geometry to one V(1) and one V(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one V(1) and one N(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(2) atom. In the third F site, F(3) is bonded in an L-shaped geometry to one V(1) and one V(2) atom. is represented by the CIF file [CIF]
data_VN(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.624
_cell_length_b   6.008
_cell_length_c   6.988
_cell_angle_alpha   79.715
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   480.166
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.149  0.063  0.477  1.0
  V  V1  1  0.851  0.063  0.977  1.0
  V  V2  1  0.308  0.289  0.694  1.0
  V  V3  1  0.692  0.289  0.194  1.0
  N  N4  1  0.998  0.593  0.098  1.0
  N  N5  1  0.002  0.593  0.598  1.0
  N  N6  1  0.444  0.837  0.075  1.0
  N  N7  1  0.556  0.837  0.575  1.0
  O  O8  1  0.018  0.157  0.457  1.0
  O  O9  1  0.982  0.157  0.957  1.0
  O  O10  1  0.264  0.440  0.848  1.0
  O  O11  1  0.736  0.440  0.348  1.0
  O  O12  1  0.234  0.037  0.724  1.0
  O  O13  1  0.766  0.037  0.224  1.0
  O  O14  1  0.089  0.692  0.586  1.0
  O  O15  1  0.911  0.692  0.086  1.0
  F  F16  1  0.219  0.950  0.282  1.0
  F  F17  1  0.781  0.950  0.782  1.0
  F  F18  1  0.460  0.274  0.692  1.0
  F  F19  1  0.540  0.274  0.192  1.0
  F  F20  1  0.242  0.376  0.446  1.0
  F  F21  1  0.758  0.376  0.946  1.0
  F  F22  1  0.442  0.822  0.538  1.0
  F  F23  1  0.558  0.822  0.038  1.0
[/CIF]
.
The crystal structure described by V2NO4F3NF is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two monofluoroamine molecules and two V2NO4F3 clusters. In each V2NO4F3 cluster, there are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), one O(4), one F(1), and one F(3) atom to form distorted edge-sharing VO3F2 trigonal bipyramids. In the second V site, V(2) is bonded to one O(2), one O(3), one F(2), and one F(3) atom to form edge-sharing VO2F2 tetrahedra. N(1) is bonded in a single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one V(2) atom. In the third O site, O(3) is bonded in a water-like geometry to one V(1) and one V(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one V(1) and one N(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(2) atom. In the third F site, F(3) is bonded in an L-shaped geometry to one V(1) and one V(2) atom. is represented by the CIF file [CIF]
data_VN(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.624
_cell_length_b   6.008
_cell_length_c   6.988
_cell_angle_alpha   79.715
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   480.166
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.149  0.063  0.477  1.0
  V  V1  1  0.851  0.063  0.977  1.0
  V  V2  1  0.308  0.289  0.694  1.0
  V  V3  1  0.692  0.289  0.194  1.0
  N  N4  1  0.998  0.593  0.098  1.0
  N  N5  1  0.002  0.593  0.598  1.0
  N  N6  1  0.444  0.837  0.075  1.0
  N  N7  1  0.556  0.837  0.575  1.0
  O  O8  1  0.018  0.157  0.457  1.0
  O  O9  1  0.982  0.157  0.957  1.0
  O  O10  1  0.264  0.440  0.848  1.0
  O  O11  1  0.736  0.440  0.348  1.0
  O  O12  1  0.234  0.037  0.724  1.0
  O  O13  1  0.766  0.037  0.224  1.0
  O  O14  1  0.089  0.692  0.586  1.0
  O  O15  1  0.911  0.692  0.086  1.0
  F  F16  1  0.219  0.950  0.282  1.0
  F  F17  1  0.781  0.950  0.782  1.0
  F  F18  1  0.460  0.274  0.692  1.0
  F  F19  1  0.540  0.274  0.192  1.0
  F  F20  1  0.242  0.376  0.446  1.0
  F  F21  1  0.758  0.376  0.946  1.0
  F  F22  1  0.442  0.822  0.538  1.0
  F  F23  1  0.558  0.822  0.038  1.0
[/CIF]
.