The crystal structure described by MgMn2Te2(MoO6)2 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a tetrahedral geometry to one O(10), one O(7), one O(8), and one O(9) atom. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(11), one O(3), one O(5), one O(8), and one O(9) atom. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(4), one O(6), and one O(7) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(2), one O(3), one O(4), and one O(5) atom. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(1), one O(12), one O(2), one O(3), one O(4), and one O(6) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(2), one O(3), and one O(5) atom. In the second Te site, Te(2) is bonded in a 4-coordinate geometry to one O(1), one O(12), one O(4), and one O(6) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Te(2) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Te(1) atom. In the third O site, O(3) is bonded to one Mo(1), one Mn(1), one Mn(2), and one Te(1) atom to form distorted corner-sharing OMn2TeMo tetrahedra. In the fourth O site, O(4) is bonded to one Mo(2), one Mn(1), one Mn(2), and one Te(2) atom to form distorted corner-sharing OMn2TeMo tetrahedra. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mn(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mo(2), one Mn(2), and one Te(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one Mo(2) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mg(1) and one Mo(1) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one Mo(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(2) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Mo(1), one Mn(1), and one Te(1) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Mo(2), one Mn(2), and one Te(2) atom. is represented by the CIF card [CIF]
data_MgMn2Te2(MoO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.192
_cell_length_b   5.372
_cell_length_c   10.229
_cell_angle_alpha   87.452
_cell_angle_beta   88.397
_cell_angle_gamma   89.554
_symmetry_Int_Tables_number   1
_cell_volume   284.876
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.513  0.478  0.005  1.0
  Mn  Mn1  1  0.002  0.994  0.483  1.0
  Mn  Mn2  1  0.496  0.511  0.523  1.0
  Te  Te3  1  0.022  0.504  0.280  1.0
  Te  Te4  1  0.502  0.998  0.725  1.0
  Mo  Mo5  1  0.543  0.972  0.233  1.0
  Mo  Mo6  1  0.022  0.526  0.779  1.0
  O  O7  1  0.688  0.171  0.587  1.0
  O  O8  1  0.203  0.335  0.417  1.0
  O  O9  1  0.774  0.690  0.386  1.0
  O  O10  1  0.269  0.805  0.624  1.0
  O  O11  1  0.790  0.189  0.304  1.0
  O  O12  1  0.240  0.294  0.692  1.0
  O  O13  1  0.243  0.648  0.898  1.0
  O  O14  1  0.644  0.735  0.118  1.0
  O  O15  1  0.383  0.220  0.130  1.0
  O  O16  1  0.783  0.351  0.885  1.0
  O  O17  1  0.259  0.813  0.329  1.0
  O  O18  1  0.760  0.705  0.680  1.0
[/CIF]
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The crystal structure described by MgMn2Te2(MoO6)2 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a tetrahedral geometry to one O(10), one O(7), one O(8), and one O(9) atom. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(11), one O(3), one O(5), one O(8), and one O(9) atom. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(4), one O(6), and one O(7) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(2), one O(3), one O(4), and one O(5) atom. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(1), one O(12), one O(2), one O(3), one O(4), and one O(6) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(2), one O(3), and one O(5) atom. In the second Te site, Te(2) is bonded in a 4-coordinate geometry to one O(1), one O(12), one O(4), and one O(6) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Te(2) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Te(1) atom. In the third O site, O(3) is bonded to one Mo(1), one Mn(1), one Mn(2), and one Te(1) atom to form distorted corner-sharing OMn2TeMo tetrahedra. In the fourth O site, O(4) is bonded to one Mo(2), one Mn(1), one Mn(2), and one Te(2) atom to form distorted corner-sharing OMn2TeMo tetrahedra. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mn(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mo(2), one Mn(2), and one Te(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one Mo(2) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mg(1) and one Mo(1) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one Mo(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(2) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Mo(1), one Mn(1), and one Te(1) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Mo(2), one Mn(2), and one Te(2) atom. is represented by the CIF card [CIF]
data_MgMn2Te2(MoO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.192
_cell_length_b   5.372
_cell_length_c   10.229
_cell_angle_alpha   87.452
_cell_angle_beta   88.397
_cell_angle_gamma   89.554
_symmetry_Int_Tables_number   1
_cell_volume   284.876
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.513  0.478  0.005  1.0
  Mn  Mn1  1  0.002  0.994  0.483  1.0
  Mn  Mn2  1  0.496  0.511  0.523  1.0
  Te  Te3  1  0.022  0.504  0.280  1.0
  Te  Te4  1  0.502  0.998  0.725  1.0
  Mo  Mo5  1  0.543  0.972  0.233  1.0
  Mo  Mo6  1  0.022  0.526  0.779  1.0
  O  O7  1  0.688  0.171  0.587  1.0
  O  O8  1  0.203  0.335  0.417  1.0
  O  O9  1  0.774  0.690  0.386  1.0
  O  O10  1  0.269  0.805  0.624  1.0
  O  O11  1  0.790  0.189  0.304  1.0
  O  O12  1  0.240  0.294  0.692  1.0
  O  O13  1  0.243  0.648  0.898  1.0
  O  O14  1  0.644  0.735  0.118  1.0
  O  O15  1  0.383  0.220  0.130  1.0
  O  O16  1  0.783  0.351  0.885  1.0
  O  O17  1  0.259  0.813  0.329  1.0
  O  O18  1  0.760  0.705  0.680  1.0
[/CIF]
.