The compound described by Na6ZnGe3Si2(PO6)4 crystallizes in the triclinic P1 space group. There are six inequivalent Na sites. In the first Na site, Na(1) is bonded in a distorted hexagonal planar geometry to one O(1), one O(11), one O(21), one O(23), one O(3), and one O(9) atom. In the second Na site, Na(2) is bonded in a distorted hexagonal planar geometry to one O(10), one O(12), one O(2), one O(22), one O(24), and one O(4) atom. In the third Na site, Na(3) is bonded in a 8-coordinate geometry to one O(1), one O(13), one O(14), one O(19), one O(2), one O(20), one O(21), and one O(22) atom. In the fourth Na site, Na(4) is bonded in a 7-coordinate geometry to one O(16), one O(17), one O(18), one O(23), one O(24), one O(3), and one O(4) atom. In the fifth Na site, Na(5) is bonded in a 7-coordinate geometry to one O(11), one O(12), one O(14), one O(23), one O(4), one O(5), and one O(8) atom. In the sixth Na site, Na(6) is bonded in a 8-coordinate geometry to one O(10), one O(16), one O(18), one O(2), one O(21), one O(6), one O(7), and one O(9) atom. Zn(1) is bonded to one O(12), one O(14), one O(17), one O(24), one O(4), and one O(6) atom to form distorted ZnO6 octahedra that share  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one O(1), one O(15), one O(20), one O(21), one O(7), and one O(9) atom to form GeO6 octahedra that share  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. In the second Ge site, Ge(2) is bonded to one O(10), one O(16), one O(19), one O(2), one O(22), and one O(8) atom to form GeO6 octahedra that share  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. In the third Ge site, Ge(3) is bonded to one O(11), one O(13), one O(18), one O(23), one O(3), and one O(5) atom to form GeO6 octahedra that share  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. There are two inequivalent Si sites. In the first Si site, Si(1) is bonded to one O(1), one O(10), one O(14), and one O(18) atom to form SiO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Ge(1)O6 octahedra,  a cornercorner with one Ge(2)O6 octahedra, and  a cornercorner with one Ge(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-41°. In the second Si site, Si(2) is bonded to one O(12), one O(16), one O(20), and one O(3) atom to form SiO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Ge(1)O6 octahedra,  a cornercorner with one Ge(2)O6 octahedra, and  a cornercorner with one Ge(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-40°. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(21), one O(22), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Ge(1)O6 octahedra,  a cornercorner with one Ge(2)O6 octahedra, and  a cornercorner with one Ge(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-38°. In the second P site, P(2) is bonded to one O(23), one O(24), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Ge(1)O6 octahedra,  a cornercorner with one Ge(2)O6 octahedra, and  a cornercorner with one Ge(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-42°. In the third P site, P(3) is bonded to one O(13), one O(17), one O(2), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Ge(1)O6 octahedra,  a cornercorner with one Ge(2)O6 octahedra, and  a cornercorner with one Ge(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-41°. In the fourth P site, P(4) is bonded to one O(11), one O(15), one O(19), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Ge(1)O6 octahedra,  a cornercorner with one Ge(2)O6 octahedra, and  a cornercorner with one Ge(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-41°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), one Na(3), one Ge(1), and one Si(1) atom to form distorted ONa2SiGe trigonal pyramids that share  a cornercorner with one O(11)Na2GeP trigonal pyramid,  a cornercorner with one O(10)Na2SiGe trigonal pyramid, and  a faceface with one O(21)Na3GeP trigonal bipyramid. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Na(2), one Na(3), one Na(6), one Ge(2), and one P(3) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(4), one Ge(3), and one Si(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Na(2), one Na(4), one Na(5), one Zn(1), and one P(4) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(5), one Ge(3), and one P(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(6), one Zn(1), and one P(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Na(6), one Ge(1), and one P(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Na(5), one Ge(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(6), one Ge(1), and one P(3) atom. In the tenth O site, O(10) is bonded to one Na(2), one Na(6), one Ge(2), and one Si(1) atom to form distorted ONa2SiGe trigonal pyramids that share  a cornercorner with one O(21)Na3GeP trigonal bipyramid and  a cornercorner with one O(1)Na2SiGe trigonal pyramid. In the eleventh O site, O(11) is bonded to one Na(1), one Na(5), one Ge(3), and one P(4) atom to form distorted ONa2GeP trigonal pyramids that share  a cornercorner with one O(21)Na3GeP trigonal bipyramid and  a cornercorner with one O(1)Na2SiGe trigonal pyramid. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Na(2), one Na(5), one Zn(1), and one Si(2) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Na(3), one Ge(3), and one P(3) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Na(3), one Na(5), one Zn(1), and one Si(1) atom. In the fifteenth O site, O(15) is bonded in a linear geometry to one Ge(1) and one P(4) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one Na(4), one Na(6), one Ge(2), and one Si(2) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Na(4), one Zn(1), and one P(3) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one Na(4), one Na(6), one Ge(3), and one Si(1) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Na(3), one Ge(2), and one P(4) atom. In the twentieth O site, O(20) is bonded in a distorted bent 150 degrees geometry to one Na(3), one Ge(1), and one Si(2) atom. In the twenty-first O site, O(21) is bonded to one Na(1), one Na(3), one Na(6), one Ge(1), and one P(1) atom to form distorted ONa3GeP trigonal bipyramids that share  a cornercorner with one O(11)Na2GeP trigonal pyramid,  a cornercorner with one O(10)Na2SiGe trigonal pyramid, and  a faceface with one O(1)Na2SiGe trigonal pyramid. In the twenty-second O site, O(22) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(3), one Ge(2), and one P(1) atom. In the twenty-third O site, O(23) is bonded in a 5-coordinate geometry to one Na(1), one Na(4), one Na(5), one Ge(3), and one P(2) atom. In the twenty-fourth O site, O(24) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(4), one Zn(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na6ZnSi2Ge3(PO6)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.710
_cell_length_b   8.720
_cell_length_c   8.732
_cell_angle_alpha   60.736
_cell_angle_beta   89.980
_cell_angle_gamma   119.601
_symmetry_Int_Tables_number   1
_cell_volume   476.805
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.148  0.794  0.559  1.0
  Ge  Ge1  1  0.351  0.202  0.941  1.0
  Ge  Ge2  1  0.848  0.202  0.442  1.0
  Na  Na3  1  0.001  0.506  0.998  1.0
  Na  Na4  1  0.512  0.517  0.486  1.0
  Na  Na5  1  0.387  0.642  0.765  1.0
  Na  Na6  1  0.621  0.385  0.235  1.0
  Na  Na7  1  0.271  0.639  0.229  1.0
  Na  Na8  1  0.744  0.332  0.780  1.0
  O  O9  1  0.259  0.851  0.722  1.0
  O  O10  1  0.574  0.524  0.756  1.0
  O  O11  1  0.728  0.177  0.271  1.0
  O  O12  1  0.397  0.441  0.261  1.0
  O  O13  1  0.029  0.310  0.558  1.0
  O  O14  1  0.881  0.107  0.908  1.0
  O  O15  1  0.994  0.682  0.440  1.0
  O  O16  1  0.140  0.917  0.086  1.0
  O  O17  1  0.913  0.681  0.728  1.0
  O  O18  1  0.441  0.175  0.769  1.0
  O  O19  1  0.062  0.290  0.262  1.0
  O  O20  1  0.557  0.835  0.242  1.0
  O  O21  1  0.780  0.917  0.588  1.0
  O  O22  1  0.466  0.828  0.925  1.0
  O  O23  1  0.176  0.051  0.415  1.0
  O  O24  1  0.512  0.167  0.073  1.0
  O  O25  1  0.722  0.684  0.938  1.0
  O  O26  1  0.650  0.169  0.570  1.0
  O  O27  1  0.273  0.298  0.062  1.0
  O  O28  1  0.361  0.857  0.440  1.0
  O  O29  1  0.075  0.494  0.732  1.0
  O  O30  1  0.236  0.312  0.756  1.0
  O  O31  1  0.960  0.526  0.255  1.0
  O  O32  1  0.783  0.687  0.249  1.0
  P  P33  1  0.051  0.297  0.742  1.0
  P  P34  1  0.967  0.710  0.256  1.0
  P  P35  1  0.752  0.708  0.753  1.0
  P  P36  1  0.230  0.269  0.253  1.0
  Si  Si37  1  0.452  0.002  0.748  1.0
  Si  Si38  1  0.539  0.001  0.256  1.0
  Zn  Zn39  1  0.657  0.811  0.051  1.0
[/CIF]
.
The compound described by Na6ZnGe3Si2(PO6)4 crystallizes in the triclinic P1 space group. There are six inequivalent Na sites. In the first Na site, Na(1) is bonded in a distorted hexagonal planar geometry to one O(1), one O(11), one O(21), one O(23), one O(3), and one O(9) atom. In the second Na site, Na(2) is bonded in a distorted hexagonal planar geometry to one O(10), one O(12), one O(2), one O(22), one O(24), and one O(4) atom. In the third Na site, Na(3) is bonded in a 8-coordinate geometry to one O(1), one O(13), one O(14), one O(19), one O(2), one O(20), one O(21), and one O(22) atom. In the fourth Na site, Na(4) is bonded in a 7-coordinate geometry to one O(16), one O(17), one O(18), one O(23), one O(24), one O(3), and one O(4) atom. In the fifth Na site, Na(5) is bonded in a 7-coordinate geometry to one O(11), one O(12), one O(14), one O(23), one O(4), one O(5), and one O(8) atom. In the sixth Na site, Na(6) is bonded in a 8-coordinate geometry to one O(10), one O(16), one O(18), one O(2), one O(21), one O(6), one O(7), and one O(9) atom. Zn(1) is bonded to one O(12), one O(14), one O(17), one O(24), one O(4), and one O(6) atom to form distorted ZnO6 octahedra that share  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded to one O(1), one O(15), one O(20), one O(21), one O(7), and one O(9) atom to form GeO6 octahedra that share  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. In the second Ge site, Ge(2) is bonded to one O(10), one O(16), one O(19), one O(2), one O(22), and one O(8) atom to form GeO6 octahedra that share  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. In the third Ge site, Ge(3) is bonded to one O(11), one O(13), one O(18), one O(23), one O(3), and one O(5) atom to form GeO6 octahedra that share  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. There are two inequivalent Si sites. In the first Si site, Si(1) is bonded to one O(1), one O(10), one O(14), and one O(18) atom to form SiO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Ge(1)O6 octahedra,  a cornercorner with one Ge(2)O6 octahedra, and  a cornercorner with one Ge(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 33-41°. In the second Si site, Si(2) is bonded to one O(12), one O(16), one O(20), and one O(3) atom to form SiO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Ge(1)O6 octahedra,  a cornercorner with one Ge(2)O6 octahedra, and  a cornercorner with one Ge(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-40°. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(21), one O(22), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Ge(1)O6 octahedra,  a cornercorner with one Ge(2)O6 octahedra, and  a cornercorner with one Ge(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 27-38°. In the second P site, P(2) is bonded to one O(23), one O(24), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Ge(1)O6 octahedra,  a cornercorner with one Ge(2)O6 octahedra, and  a cornercorner with one Ge(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-42°. In the third P site, P(3) is bonded to one O(13), one O(17), one O(2), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Ge(1)O6 octahedra,  a cornercorner with one Ge(2)O6 octahedra, and  a cornercorner with one Ge(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-41°. In the fourth P site, P(4) is bonded to one O(11), one O(15), one O(19), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one Ge(1)O6 octahedra,  a cornercorner with one Ge(2)O6 octahedra, and  a cornercorner with one Ge(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 16-41°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), one Na(3), one Ge(1), and one Si(1) atom to form distorted ONa2SiGe trigonal pyramids that share  a cornercorner with one O(11)Na2GeP trigonal pyramid,  a cornercorner with one O(10)Na2SiGe trigonal pyramid, and  a faceface with one O(21)Na3GeP trigonal bipyramid. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Na(2), one Na(3), one Na(6), one Ge(2), and one P(3) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(4), one Ge(3), and one Si(2) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Na(2), one Na(4), one Na(5), one Zn(1), and one P(4) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(5), one Ge(3), and one P(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(6), one Zn(1), and one P(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Na(6), one Ge(1), and one P(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Na(5), one Ge(2), and one P(2) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(6), one Ge(1), and one P(3) atom. In the tenth O site, O(10) is bonded to one Na(2), one Na(6), one Ge(2), and one Si(1) atom to form distorted ONa2SiGe trigonal pyramids that share  a cornercorner with one O(21)Na3GeP trigonal bipyramid and  a cornercorner with one O(1)Na2SiGe trigonal pyramid. In the eleventh O site, O(11) is bonded to one Na(1), one Na(5), one Ge(3), and one P(4) atom to form distorted ONa2GeP trigonal pyramids that share  a cornercorner with one O(21)Na3GeP trigonal bipyramid and  a cornercorner with one O(1)Na2SiGe trigonal pyramid. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Na(2), one Na(5), one Zn(1), and one Si(2) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Na(3), one Ge(3), and one P(3) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one Na(3), one Na(5), one Zn(1), and one Si(1) atom. In the fifteenth O site, O(15) is bonded in a linear geometry to one Ge(1) and one P(4) atom. In the sixteenth O site, O(16) is bonded in a 4-coordinate geometry to one Na(4), one Na(6), one Ge(2), and one Si(2) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Na(4), one Zn(1), and one P(3) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one Na(4), one Na(6), one Ge(3), and one Si(1) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Na(3), one Ge(2), and one P(4) atom. In the twentieth O site, O(20) is bonded in a distorted bent 150 degrees geometry to one Na(3), one Ge(1), and one Si(2) atom. In the twenty-first O site, O(21) is bonded to one Na(1), one Na(3), one Na(6), one Ge(1), and one P(1) atom to form distorted ONa3GeP trigonal bipyramids that share  a cornercorner with one O(11)Na2GeP trigonal pyramid,  a cornercorner with one O(10)Na2SiGe trigonal pyramid, and  a faceface with one O(1)Na2SiGe trigonal pyramid. In the twenty-second O site, O(22) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(3), one Ge(2), and one P(1) atom. In the twenty-third O site, O(23) is bonded in a 5-coordinate geometry to one Na(1), one Na(4), one Na(5), one Ge(3), and one P(2) atom. In the twenty-fourth O site, O(24) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(4), one Zn(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na6ZnSi2Ge3(PO6)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.710
_cell_length_b   8.720
_cell_length_c   8.732
_cell_angle_alpha   60.736
_cell_angle_beta   89.980
_cell_angle_gamma   119.601
_symmetry_Int_Tables_number   1
_cell_volume   476.805
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.148  0.794  0.559  1.0
  Ge  Ge1  1  0.351  0.202  0.941  1.0
  Ge  Ge2  1  0.848  0.202  0.442  1.0
  Na  Na3  1  0.001  0.506  0.998  1.0
  Na  Na4  1  0.512  0.517  0.486  1.0
  Na  Na5  1  0.387  0.642  0.765  1.0
  Na  Na6  1  0.621  0.385  0.235  1.0
  Na  Na7  1  0.271  0.639  0.229  1.0
  Na  Na8  1  0.744  0.332  0.780  1.0
  O  O9  1  0.259  0.851  0.722  1.0
  O  O10  1  0.574  0.524  0.756  1.0
  O  O11  1  0.728  0.177  0.271  1.0
  O  O12  1  0.397  0.441  0.261  1.0
  O  O13  1  0.029  0.310  0.558  1.0
  O  O14  1  0.881  0.107  0.908  1.0
  O  O15  1  0.994  0.682  0.440  1.0
  O  O16  1  0.140  0.917  0.086  1.0
  O  O17  1  0.913  0.681  0.728  1.0
  O  O18  1  0.441  0.175  0.769  1.0
  O  O19  1  0.062  0.290  0.262  1.0
  O  O20  1  0.557  0.835  0.242  1.0
  O  O21  1  0.780  0.917  0.588  1.0
  O  O22  1  0.466  0.828  0.925  1.0
  O  O23  1  0.176  0.051  0.415  1.0
  O  O24  1  0.512  0.167  0.073  1.0
  O  O25  1  0.722  0.684  0.938  1.0
  O  O26  1  0.650  0.169  0.570  1.0
  O  O27  1  0.273  0.298  0.062  1.0
  O  O28  1  0.361  0.857  0.440  1.0
  O  O29  1  0.075  0.494  0.732  1.0
  O  O30  1  0.236  0.312  0.756  1.0
  O  O31  1  0.960  0.526  0.255  1.0
  O  O32  1  0.783  0.687  0.249  1.0
  P  P33  1  0.051  0.297  0.742  1.0
  P  P34  1  0.967  0.710  0.256  1.0
  P  P35  1  0.752  0.708  0.753  1.0
  P  P36  1  0.230  0.269  0.253  1.0
  Si  Si37  1  0.452  0.002  0.748  1.0
  Si  Si38  1  0.539  0.001  0.256  1.0
  Zn  Zn39  1  0.657  0.811  0.051  1.0
[/CIF]
.