The structure described by MgCo5O8 is Spinel-like structured and crystallizes in the orthorhombic Imm2 space group. Mg(1) is bonded to two equivalent O(3) and two equivalent O(4) atoms to form MgO4 tetrahedra that share corners with six equivalent Co(1)O6 octahedra and corners with six equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-58°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share corners with three equivalent Mg(1)O4 tetrahedra, corners with three equivalent Co(2)O4 tetrahedra, edges with two equivalent Co(1)O6 octahedra, and edges with four equivalent Co(3)O6 octahedra. In the second Co site, Co(2) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form corner-sharing CoO4 tetrahedra. The corner-sharing octahedral tilt angles range from 57-58°. In the third Co site, Co(3) is bonded to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with three equivalent Mg(1)O4 tetrahedra, corners with three equivalent Co(2)O4 tetrahedra, edges with two equivalent Co(3)O6 octahedra, and edges with four equivalent Co(1)O6 octahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Co(1), one Co(2), and two equivalent Co(3) atoms to form distorted OCo4 trigonal pyramids that share  a cornercorner with one O(1)Co4 trigonal pyramid, corners with two equivalent O(2)Co4 trigonal pyramids, corners with four equivalent O(3)MgCo3 trigonal pyramids, corners with five equivalent O(4)MgCo3 trigonal pyramids,  an edgeedge with one O(1)Co4 trigonal pyramid, and edges with two equivalent O(2)Co4 trigonal pyramids. In the second O site, O(2) is bonded to one Co(2), one Co(3), and two equivalent Co(1) atoms to form distorted OCo4 trigonal pyramids that share  a cornercorner with one O(2)Co4 trigonal pyramid, corners with two equivalent O(1)Co4 trigonal pyramids, corners with four equivalent O(4)MgCo3 trigonal pyramids, corners with five equivalent O(3)MgCo3 trigonal pyramids,  an edgeedge with one O(2)Co4 trigonal pyramid, and edges with two equivalent O(1)Co4 trigonal pyramids. In the third O site, O(3) is bonded to one Mg(1), one Co(3), and two equivalent Co(1) atoms to form distorted OMgCo3 trigonal pyramids that share  a cornercorner with one O(3)MgCo3 trigonal pyramid, corners with two equivalent O(4)MgCo3 trigonal pyramids, corners with four equivalent O(1)Co4 trigonal pyramids, corners with five equivalent O(2)Co4 trigonal pyramids,  an edgeedge with one O(3)MgCo3 trigonal pyramid, and edges with two equivalent O(4)MgCo3 trigonal pyramids. In the fourth O site, O(4) is bonded to one Mg(1), one Co(1), and two equivalent Co(3) atoms to form distorted OMgCo3 trigonal pyramids that share  a cornercorner with one O(4)MgCo3 trigonal pyramid, corners with two equivalent O(3)MgCo3 trigonal pyramids, corners with four equivalent O(2)Co4 trigonal pyramids, corners with five equivalent O(1)Co4 trigonal pyramids,  an edgeedge with one O(4)MgCo3 trigonal pyramid, and edges with two equivalent O(3)MgCo3 trigonal pyramids. is represented by the CIF card [CIF]
data_MgCo5O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.970
_cell_length_b   5.958
_cell_length_c   5.956
_cell_angle_alpha   90.000
_cell_angle_beta   60.079
_cell_angle_gamma   60.060
_symmetry_Int_Tables_number   1
_cell_volume   150.130
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.747  0.126  0.876  1.0
  Co  Co1  1  0.497  0.500  0.501  1.0
  Co  Co2  1  0.497  0.003  0.501  1.0
  Co  Co3  1  0.248  0.876  0.126  1.0
  Co  Co4  1  0.001  0.499  0.502  1.0
  Co  Co5  1  0.001  0.499  0.997  1.0
  O  O6  1  0.981  0.742  0.260  1.0
  O  O7  1  0.980  0.277  0.260  1.0
  O  O8  1  0.518  0.741  0.725  1.0
  O  O9  1  0.518  0.741  0.258  1.0
  O  O10  1  0.479  0.260  0.741  1.0
  O  O11  1  0.479  0.260  0.280  1.0
  O  O12  1  0.020  0.722  0.740  1.0
  O  O13  1  0.020  0.258  0.740  1.0
[/CIF]
.
The structure described by MgCo5O8 is Spinel-like structured and crystallizes in the orthorhombic Imm2 space group. Mg(1) is bonded to two equivalent O(3) and two equivalent O(4) atoms to form MgO4 tetrahedra that share corners with six equivalent Co(1)O6 octahedra and corners with six equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-58°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share corners with three equivalent Mg(1)O4 tetrahedra, corners with three equivalent Co(2)O4 tetrahedra, edges with two equivalent Co(1)O6 octahedra, and edges with four equivalent Co(3)O6 octahedra. In the second Co site, Co(2) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form corner-sharing CoO4 tetrahedra. The corner-sharing octahedral tilt angles range from 57-58°. In the third Co site, Co(3) is bonded to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with three equivalent Mg(1)O4 tetrahedra, corners with three equivalent Co(2)O4 tetrahedra, edges with two equivalent Co(3)O6 octahedra, and edges with four equivalent Co(1)O6 octahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Co(1), one Co(2), and two equivalent Co(3) atoms to form distorted OCo4 trigonal pyramids that share  a cornercorner with one O(1)Co4 trigonal pyramid, corners with two equivalent O(2)Co4 trigonal pyramids, corners with four equivalent O(3)MgCo3 trigonal pyramids, corners with five equivalent O(4)MgCo3 trigonal pyramids,  an edgeedge with one O(1)Co4 trigonal pyramid, and edges with two equivalent O(2)Co4 trigonal pyramids. In the second O site, O(2) is bonded to one Co(2), one Co(3), and two equivalent Co(1) atoms to form distorted OCo4 trigonal pyramids that share  a cornercorner with one O(2)Co4 trigonal pyramid, corners with two equivalent O(1)Co4 trigonal pyramids, corners with four equivalent O(4)MgCo3 trigonal pyramids, corners with five equivalent O(3)MgCo3 trigonal pyramids,  an edgeedge with one O(2)Co4 trigonal pyramid, and edges with two equivalent O(1)Co4 trigonal pyramids. In the third O site, O(3) is bonded to one Mg(1), one Co(3), and two equivalent Co(1) atoms to form distorted OMgCo3 trigonal pyramids that share  a cornercorner with one O(3)MgCo3 trigonal pyramid, corners with two equivalent O(4)MgCo3 trigonal pyramids, corners with four equivalent O(1)Co4 trigonal pyramids, corners with five equivalent O(2)Co4 trigonal pyramids,  an edgeedge with one O(3)MgCo3 trigonal pyramid, and edges with two equivalent O(4)MgCo3 trigonal pyramids. In the fourth O site, O(4) is bonded to one Mg(1), one Co(1), and two equivalent Co(3) atoms to form distorted OMgCo3 trigonal pyramids that share  a cornercorner with one O(4)MgCo3 trigonal pyramid, corners with two equivalent O(3)MgCo3 trigonal pyramids, corners with four equivalent O(2)Co4 trigonal pyramids, corners with five equivalent O(1)Co4 trigonal pyramids,  an edgeedge with one O(4)MgCo3 trigonal pyramid, and edges with two equivalent O(3)MgCo3 trigonal pyramids. is represented by the CIF card [CIF]
data_MgCo5O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.970
_cell_length_b   5.958
_cell_length_c   5.956
_cell_angle_alpha   90.000
_cell_angle_beta   60.079
_cell_angle_gamma   60.060
_symmetry_Int_Tables_number   1
_cell_volume   150.130
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.747  0.126  0.876  1.0
  Co  Co1  1  0.497  0.500  0.501  1.0
  Co  Co2  1  0.497  0.003  0.501  1.0
  Co  Co3  1  0.248  0.876  0.126  1.0
  Co  Co4  1  0.001  0.499  0.502  1.0
  Co  Co5  1  0.001  0.499  0.997  1.0
  O  O6  1  0.981  0.742  0.260  1.0
  O  O7  1  0.980  0.277  0.260  1.0
  O  O8  1  0.518  0.741  0.725  1.0
  O  O9  1  0.518  0.741  0.258  1.0
  O  O10  1  0.479  0.260  0.741  1.0
  O  O11  1  0.479  0.260  0.280  1.0
  O  O12  1  0.020  0.722  0.740  1.0
  O  O13  1  0.020  0.258  0.740  1.0
[/CIF]
.