The crystal structure described by CeSO6 crystallizes in the orthorhombic P2_12_12_1 space group. Ce(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and three equivalent O(6) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ce(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ce(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Ce(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Ce(1) atoms. is represented by the CIF file [CIF]
data_CeSO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.324
_cell_length_b   8.751
_cell_length_c   11.896
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   450.175
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.404  0.118  0.926  1.0
  Ce  Ce1  1  0.904  0.382  0.074  1.0
  Ce  Ce2  1  0.096  0.882  0.426  1.0
  Ce  Ce3  1  0.596  0.618  0.574  1.0
  S  S4  1  0.600  0.048  0.222  1.0
  S  S5  1  0.100  0.452  0.778  1.0
  S  S6  1  0.900  0.952  0.722  1.0
  S  S7  1  0.400  0.548  0.278  1.0
  O  O8  1  0.764  0.196  0.210  1.0
  O  O9  1  0.264  0.304  0.790  1.0
  O  O10  1  0.736  0.804  0.710  1.0
  O  O11  1  0.236  0.696  0.290  1.0
  O  O12  1  0.437  0.011  0.114  1.0
  O  O13  1  0.937  0.489  0.886  1.0
  O  O14  1  0.063  0.989  0.614  1.0
  O  O15  1  0.563  0.511  0.386  1.0
  O  O16  1  0.130  0.936  0.814  1.0
  O  O17  1  0.630  0.564  0.186  1.0
  O  O18  1  0.370  0.064  0.314  1.0
  O  O19  1  0.870  0.436  0.686  1.0
  O  O20  1  0.683  0.076  0.749  1.0
  O  O21  1  0.183  0.424  0.251  1.0
  O  O22  1  0.817  0.924  0.249  1.0
  O  O23  1  0.317  0.576  0.751  1.0
  O  O24  1  0.559  0.822  0.976  1.0
  O  O25  1  0.059  0.678  0.024  1.0
  O  O26  1  0.941  0.178  0.476  1.0
  O  O27  1  0.441  0.322  0.524  1.0
  O  O28  1  0.905  0.169  0.972  1.0
  O  O29  1  0.405  0.331  0.028  1.0
  O  O30  1  0.595  0.831  0.472  1.0
  O  O31  1  0.095  0.669  0.528  1.0
[/CIF]
.
The crystal structure described by CeSO6 crystallizes in the orthorhombic P2_12_12_1 space group. Ce(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and three equivalent O(6) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ce(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ce(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Ce(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Ce(1) atoms. is represented by the CIF file [CIF]
data_CeSO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.324
_cell_length_b   8.751
_cell_length_c   11.896
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   450.175
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.404  0.118  0.926  1.0
  Ce  Ce1  1  0.904  0.382  0.074  1.0
  Ce  Ce2  1  0.096  0.882  0.426  1.0
  Ce  Ce3  1  0.596  0.618  0.574  1.0
  S  S4  1  0.600  0.048  0.222  1.0
  S  S5  1  0.100  0.452  0.778  1.0
  S  S6  1  0.900  0.952  0.722  1.0
  S  S7  1  0.400  0.548  0.278  1.0
  O  O8  1  0.764  0.196  0.210  1.0
  O  O9  1  0.264  0.304  0.790  1.0
  O  O10  1  0.736  0.804  0.710  1.0
  O  O11  1  0.236  0.696  0.290  1.0
  O  O12  1  0.437  0.011  0.114  1.0
  O  O13  1  0.937  0.489  0.886  1.0
  O  O14  1  0.063  0.989  0.614  1.0
  O  O15  1  0.563  0.511  0.386  1.0
  O  O16  1  0.130  0.936  0.814  1.0
  O  O17  1  0.630  0.564  0.186  1.0
  O  O18  1  0.370  0.064  0.314  1.0
  O  O19  1  0.870  0.436  0.686  1.0
  O  O20  1  0.683  0.076  0.749  1.0
  O  O21  1  0.183  0.424  0.251  1.0
  O  O22  1  0.817  0.924  0.249  1.0
  O  O23  1  0.317  0.576  0.751  1.0
  O  O24  1  0.559  0.822  0.976  1.0
  O  O25  1  0.059  0.678  0.024  1.0
  O  O26  1  0.941  0.178  0.476  1.0
  O  O27  1  0.441  0.322  0.524  1.0
  O  O28  1  0.905  0.169  0.972  1.0
  O  O29  1  0.405  0.331  0.028  1.0
  O  O30  1  0.595  0.831  0.472  1.0
  O  O31  1  0.095  0.669  0.528  1.0
[/CIF]
.