The compound described by SrNi5P3 crystallizes in the orthorhombic Cmcm space group. Sr(1) is bonded in a 15-coordinate geometry to four equivalent Ni(1), four equivalent Ni(2), three equivalent P(1), and four equivalent P(2) atoms. There are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 4-coordinate geometry to two equivalent Sr(1), two equivalent P(1), and two equivalent P(2) atoms. In the second Ni site, Ni(2) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one P(1), and three equivalent P(2) atoms. In the third Ni site, Ni(3) is bonded in a 4-coordinate geometry to four equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to three equivalent Sr(1), two equivalent Ni(2), and four equivalent Ni(1) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to two equivalent Sr(1), two equivalent Ni(1), two equivalent Ni(3), and three equivalent Ni(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_SrNi5P3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.589
_cell_length_b   6.107
_cell_length_c   11.521
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   107.088
_symmetry_Int_Tables_number   1
_cell_volume   241.380
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.838  0.676  0.250  1.0
  Sr  Sr1  1  0.162  0.324  0.750  1.0
  Ni  Ni2  1  0.550  0.100  0.355  1.0
  Ni  Ni3  1  0.550  0.100  0.145  1.0
  Ni  Ni4  1  0.198  0.395  0.068  1.0
  Ni  Ni5  1  0.802  0.605  0.932  1.0
  Ni  Ni6  1  0.802  0.605  0.568  1.0
  Ni  Ni7  1  0.198  0.395  0.432  1.0
  Ni  Ni8  1  0.000  0.000  0.500  1.0
  Ni  Ni9  1  0.000  0.000  0.000  1.0
  Ni  Ni10  1  0.450  0.900  0.855  1.0
  Ni  Ni11  1  0.450  0.900  0.645  1.0
  P  P12  1  0.115  0.231  0.250  1.0
  P  P13  1  0.885  0.769  0.750  1.0
  P  P14  1  0.619  0.238  0.963  1.0
  P  P15  1  0.381  0.762  0.037  1.0
  P  P16  1  0.381  0.762  0.463  1.0
  P  P17  1  0.619  0.238  0.537  1.0
[/CIF]
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The compound described by SrNi5P3 crystallizes in the orthorhombic Cmcm space group. Sr(1) is bonded in a 15-coordinate geometry to four equivalent Ni(1), four equivalent Ni(2), three equivalent P(1), and four equivalent P(2) atoms. There are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 4-coordinate geometry to two equivalent Sr(1), two equivalent P(1), and two equivalent P(2) atoms. In the second Ni site, Ni(2) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one P(1), and three equivalent P(2) atoms. In the third Ni site, Ni(3) is bonded in a 4-coordinate geometry to four equivalent P(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to three equivalent Sr(1), two equivalent Ni(2), and four equivalent Ni(1) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to two equivalent Sr(1), two equivalent Ni(1), two equivalent Ni(3), and three equivalent Ni(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_SrNi5P3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.589
_cell_length_b   6.107
_cell_length_c   11.521
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   107.088
_symmetry_Int_Tables_number   1
_cell_volume   241.380
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.838  0.676  0.250  1.0
  Sr  Sr1  1  0.162  0.324  0.750  1.0
  Ni  Ni2  1  0.550  0.100  0.355  1.0
  Ni  Ni3  1  0.550  0.100  0.145  1.0
  Ni  Ni4  1  0.198  0.395  0.068  1.0
  Ni  Ni5  1  0.802  0.605  0.932  1.0
  Ni  Ni6  1  0.802  0.605  0.568  1.0
  Ni  Ni7  1  0.198  0.395  0.432  1.0
  Ni  Ni8  1  0.000  0.000  0.500  1.0
  Ni  Ni9  1  0.000  0.000  0.000  1.0
  Ni  Ni10  1  0.450  0.900  0.855  1.0
  Ni  Ni11  1  0.450  0.900  0.645  1.0
  P  P12  1  0.115  0.231  0.250  1.0
  P  P13  1  0.885  0.769  0.750  1.0
  P  P14  1  0.619  0.238  0.963  1.0
  P  P15  1  0.381  0.762  0.037  1.0
  P  P16  1  0.381  0.762  0.463  1.0
  P  P17  1  0.619  0.238  0.537  1.0
[/CIF]
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