The structure described by Ba3RhF12 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 8-coordinate geometry to four equivalent F(1) and four equivalent F(3) atoms. In the second Ba site, Ba(2) is bonded in a 6-coordinate geometry to two equivalent F(1) and four equivalent F(2) atoms. Rh(1) is bonded in a body-centered cubic geometry to four equivalent F(1) and four equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Ba(1), one Ba(2), and one Rh(1) atom. In the second F site, F(2) is bonded in a water-like geometry to two equivalent Ba(2) atoms. In the third F site, F(3) is bonded in a 1-coordinate geometry to one Ba(1) and one Rh(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ba3RhF12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.677
_cell_length_b   8.059
_cell_length_c   8.506
_cell_angle_alpha   118.275
_cell_angle_beta   100.066
_cell_angle_gamma   68.349
_symmetry_Int_Tables_number   1
_cell_volume   374.657
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.500  0.000  0.000  1.0
  Ba  Ba1  1  0.000  0.500  0.500  1.0
  Ba  Ba2  1  0.000  0.000  0.500  1.0
  Rh  Rh3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.891  0.765  0.845  1.0
  F  F5  1  0.109  0.235  0.155  1.0
  F  F6  1  0.754  0.794  0.451  1.0
  F  F7  1  0.109  0.080  0.845  1.0
  F  F8  1  0.246  0.206  0.549  1.0
  F  F9  1  0.891  0.920  0.155  1.0
  F  F10  1  0.244  0.766  0.842  1.0
  F  F11  1  0.246  0.657  0.451  1.0
  F  F12  1  0.756  0.234  0.158  1.0
  F  F13  1  0.754  0.343  0.549  1.0
  F  F14  1  0.756  0.077  0.842  1.0
  F  F15  1  0.244  0.923  0.158  1.0
[/CIF]
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The structure described by Ba3RhF12 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a 8-coordinate geometry to four equivalent F(1) and four equivalent F(3) atoms. In the second Ba site, Ba(2) is bonded in a 6-coordinate geometry to two equivalent F(1) and four equivalent F(2) atoms. Rh(1) is bonded in a body-centered cubic geometry to four equivalent F(1) and four equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a 3-coordinate geometry to one Ba(1), one Ba(2), and one Rh(1) atom. In the second F site, F(2) is bonded in a water-like geometry to two equivalent Ba(2) atoms. In the third F site, F(3) is bonded in a 1-coordinate geometry to one Ba(1) and one Rh(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ba3RhF12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.677
_cell_length_b   8.059
_cell_length_c   8.506
_cell_angle_alpha   118.275
_cell_angle_beta   100.066
_cell_angle_gamma   68.349
_symmetry_Int_Tables_number   1
_cell_volume   374.657
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.500  0.000  0.000  1.0
  Ba  Ba1  1  0.000  0.500  0.500  1.0
  Ba  Ba2  1  0.000  0.000  0.500  1.0
  Rh  Rh3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.891  0.765  0.845  1.0
  F  F5  1  0.109  0.235  0.155  1.0
  F  F6  1  0.754  0.794  0.451  1.0
  F  F7  1  0.109  0.080  0.845  1.0
  F  F8  1  0.246  0.206  0.549  1.0
  F  F9  1  0.891  0.920  0.155  1.0
  F  F10  1  0.244  0.766  0.842  1.0
  F  F11  1  0.246  0.657  0.451  1.0
  F  F12  1  0.756  0.234  0.158  1.0
  F  F13  1  0.754  0.343  0.549  1.0
  F  F14  1  0.756  0.077  0.842  1.0
  F  F15  1  0.244  0.923  0.158  1.0
[/CIF]
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