The structure described by LiU2O8Cl3 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 3-coordinate geometry to one O(1), one O(4), one O(7), one O(8), and one Cl(1) atom. There are two inequivalent U sites. In the first U site, U(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), one O(5), one Cl(1), one Cl(3), and two equivalent Cl(2) atoms. In the second U site, U(2) is bonded in a 2-coordinate geometry to one O(3), one O(4), one O(6), two equivalent O(5), one Cl(1), and one Cl(3) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1) and one U(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one U(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one U(2) atom. In the fourth O site, O(4) is bonded in a linear geometry to one Li(1) and one U(2) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one U(1) and two equivalent U(2) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one U(2) and one Cl(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Li(1) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Li(1) and one O(8) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one U(1), one U(2), and one O(6) atom. In the second Cl site, Cl(2) is bonded in a water-like geometry to two equivalent U(1) atoms. In the third Cl site, Cl(3) is bonded in an L-shaped geometry to one U(1) and one U(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiU2Cl3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.852
_cell_length_b   8.694
_cell_length_c   8.713
_cell_angle_alpha   111.148
_cell_angle_beta   93.683
_cell_angle_gamma   95.144
_symmetry_Int_Tables_number   1
_cell_volume   549.553
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.638  0.192  0.776  1.0
  Li  Li1  1  0.362  0.808  0.224  1.0
  U  U2  1  0.187  0.193  0.205  1.0
  U  U3  1  0.813  0.807  0.795  1.0
  U  U4  1  0.630  0.516  0.338  1.0
  U  U5  1  0.370  0.484  0.662  1.0
  Cl  Cl6  1  0.446  0.296  0.022  1.0
  Cl  Cl7  1  0.554  0.704  0.978  1.0
  Cl  Cl8  1  0.888  0.970  0.141  1.0
  Cl  Cl9  1  0.112  0.030  0.859  1.0
  Cl  Cl10  1  0.090  0.246  0.520  1.0
  Cl  Cl11  1  0.910  0.754  0.480  1.0
  O  O12  1  0.308  0.026  0.213  1.0
  O  O13  1  0.692  0.974  0.787  1.0
  O  O14  1  0.070  0.354  0.186  1.0
  O  O15  1  0.930  0.646  0.814  1.0
  O  O16  1  0.747  0.352  0.348  1.0
  O  O17  1  0.253  0.648  0.652  1.0
  O  O18  1  0.506  0.677  0.315  1.0
  O  O19  1  0.494  0.323  0.685  1.0
  O  O20  1  0.386  0.384  0.385  1.0
  O  O21  1  0.614  0.616  0.615  1.0
  O  O22  1  0.718  0.461  0.070  1.0
  O  O23  1  0.282  0.539  0.930  1.0
  O  O24  1  0.872  0.321  0.833  1.0
  O  O25  1  0.128  0.679  0.167  1.0
  O  O26  1  0.567  0.021  0.476  1.0
  O  O27  1  0.433  0.979  0.524  1.0
[/CIF]
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The structure described by LiU2O8Cl3 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 3-coordinate geometry to one O(1), one O(4), one O(7), one O(8), and one Cl(1) atom. There are two inequivalent U sites. In the first U site, U(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), one O(5), one Cl(1), one Cl(3), and two equivalent Cl(2) atoms. In the second U site, U(2) is bonded in a 2-coordinate geometry to one O(3), one O(4), one O(6), two equivalent O(5), one Cl(1), and one Cl(3) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1) and one U(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one U(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one U(2) atom. In the fourth O site, O(4) is bonded in a linear geometry to one Li(1) and one U(2) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one U(1) and two equivalent U(2) atoms. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one U(2) and one Cl(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Li(1) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Li(1) and one O(8) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one U(1), one U(2), and one O(6) atom. In the second Cl site, Cl(2) is bonded in a water-like geometry to two equivalent U(1) atoms. In the third Cl site, Cl(3) is bonded in an L-shaped geometry to one U(1) and one U(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiU2Cl3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.852
_cell_length_b   8.694
_cell_length_c   8.713
_cell_angle_alpha   111.148
_cell_angle_beta   93.683
_cell_angle_gamma   95.144
_symmetry_Int_Tables_number   1
_cell_volume   549.553
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.638  0.192  0.776  1.0
  Li  Li1  1  0.362  0.808  0.224  1.0
  U  U2  1  0.187  0.193  0.205  1.0
  U  U3  1  0.813  0.807  0.795  1.0
  U  U4  1  0.630  0.516  0.338  1.0
  U  U5  1  0.370  0.484  0.662  1.0
  Cl  Cl6  1  0.446  0.296  0.022  1.0
  Cl  Cl7  1  0.554  0.704  0.978  1.0
  Cl  Cl8  1  0.888  0.970  0.141  1.0
  Cl  Cl9  1  0.112  0.030  0.859  1.0
  Cl  Cl10  1  0.090  0.246  0.520  1.0
  Cl  Cl11  1  0.910  0.754  0.480  1.0
  O  O12  1  0.308  0.026  0.213  1.0
  O  O13  1  0.692  0.974  0.787  1.0
  O  O14  1  0.070  0.354  0.186  1.0
  O  O15  1  0.930  0.646  0.814  1.0
  O  O16  1  0.747  0.352  0.348  1.0
  O  O17  1  0.253  0.648  0.652  1.0
  O  O18  1  0.506  0.677  0.315  1.0
  O  O19  1  0.494  0.323  0.685  1.0
  O  O20  1  0.386  0.384  0.385  1.0
  O  O21  1  0.614  0.616  0.615  1.0
  O  O22  1  0.718  0.461  0.070  1.0
  O  O23  1  0.282  0.539  0.930  1.0
  O  O24  1  0.872  0.321  0.833  1.0
  O  O25  1  0.128  0.679  0.167  1.0
  O  O26  1  0.567  0.021  0.476  1.0
  O  O27  1  0.433  0.979  0.524  1.0
[/CIF]
.