The structure described by Li(ReN2)3 is beta indium sulfide-derived structured and crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 6-coordinate geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. In the second Re site, Re(2) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Re(2), and two equivalent Re(1) atoms. In the second N site, N(2) is bonded to one Li(1), one Re(2), and two equivalent Re(1) atoms to form corner-sharing NLiRe3 trigonal pyramids. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Re(2) and two equivalent Re(1) atoms. is represented by the CIF card [CIF]
data_Li(ReN2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.842
_cell_length_b   5.004
_cell_length_c   8.758
_cell_angle_alpha   90.000
_cell_angle_beta   90.987
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   212.174
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.500  0.500  1.0
  Li  Li1  1  0.500  0.000  0.000  1.0
  Re  Re2  1  0.559  0.610  0.250  1.0
  Re  Re3  1  0.059  0.890  0.750  1.0
  Re  Re4  1  0.441  0.390  0.750  1.0
  Re  Re5  1  0.941  0.110  0.250  1.0
  Re  Re6  1  0.000  0.500  0.000  1.0
  Re  Re7  1  0.500  0.000  0.500  1.0
  N  N8  1  0.317  0.699  0.613  1.0
  N  N9  1  0.817  0.801  0.113  1.0
  N  N10  1  0.683  0.301  0.387  1.0
  N  N11  1  0.183  0.199  0.887  1.0
  N  N12  1  0.817  0.811  0.401  1.0
  N  N13  1  0.317  0.689  0.901  1.0
  N  N14  1  0.183  0.189  0.599  1.0
  N  N15  1  0.683  0.311  0.099  1.0
  N  N16  1  0.309  0.894  0.294  1.0
  N  N17  1  0.809  0.606  0.794  1.0
  N  N18  1  0.691  0.106  0.706  1.0
  N  N19  1  0.191  0.394  0.206  1.0
[/CIF]
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The structure described by Li(ReN2)3 is beta indium sulfide-derived structured and crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 6-coordinate geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. In the second Re site, Re(2) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Re(2), and two equivalent Re(1) atoms. In the second N site, N(2) is bonded to one Li(1), one Re(2), and two equivalent Re(1) atoms to form corner-sharing NLiRe3 trigonal pyramids. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Re(2) and two equivalent Re(1) atoms. is represented by the CIF card [CIF]
data_Li(ReN2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.842
_cell_length_b   5.004
_cell_length_c   8.758
_cell_angle_alpha   90.000
_cell_angle_beta   90.987
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   212.174
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.500  0.500  1.0
  Li  Li1  1  0.500  0.000  0.000  1.0
  Re  Re2  1  0.559  0.610  0.250  1.0
  Re  Re3  1  0.059  0.890  0.750  1.0
  Re  Re4  1  0.441  0.390  0.750  1.0
  Re  Re5  1  0.941  0.110  0.250  1.0
  Re  Re6  1  0.000  0.500  0.000  1.0
  Re  Re7  1  0.500  0.000  0.500  1.0
  N  N8  1  0.317  0.699  0.613  1.0
  N  N9  1  0.817  0.801  0.113  1.0
  N  N10  1  0.683  0.301  0.387  1.0
  N  N11  1  0.183  0.199  0.887  1.0
  N  N12  1  0.817  0.811  0.401  1.0
  N  N13  1  0.317  0.689  0.901  1.0
  N  N14  1  0.183  0.189  0.599  1.0
  N  N15  1  0.683  0.311  0.099  1.0
  N  N16  1  0.309  0.894  0.294  1.0
  N  N17  1  0.809  0.606  0.794  1.0
  N  N18  1  0.691  0.106  0.706  1.0
  N  N19  1  0.191  0.394  0.206  1.0
[/CIF]
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