The crystal structure described by VF5 is Indium-like structured and crystallizes in the orthorhombic Cmce space group. The structure is zero-dimensional and consists of four VF5 clusters. V(1) is bonded to one F(2), one F(4), two equivalent F(1), and two equivalent F(3) atoms to form distorted edge-sharing VF6 octahedra. There are four inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to two equivalent V(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_VF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.455
_cell_length_b   5.455
_cell_length_c   11.618
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   97.815
_symmetry_Int_Tables_number   1
_cell_volume   342.563
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.172  0.172  0.414  1.0
  V  V1  1  0.328  0.328  0.914  1.0
  V  V2  1  0.672  0.672  0.086  1.0
  V  V3  1  0.828  0.828  0.586  1.0
  F  F4  1  0.143  0.857  0.500  1.0
  F  F5  1  0.998  0.998  0.309  1.0
  F  F6  1  0.120  0.449  0.357  1.0
  F  F7  1  0.051  0.380  0.857  1.0
  F  F8  1  0.197  0.197  0.041  1.0
  F  F9  1  0.357  0.643  0.000  1.0
  F  F10  1  0.303  0.303  0.541  1.0
  F  F11  1  0.449  0.120  0.357  1.0
  F  F12  1  0.380  0.051  0.857  1.0
  F  F13  1  0.502  0.502  0.809  1.0
  F  F14  1  0.498  0.498  0.191  1.0
  F  F15  1  0.620  0.949  0.143  1.0
  F  F16  1  0.551  0.880  0.643  1.0
  F  F17  1  0.697  0.697  0.459  1.0
  F  F18  1  0.643  0.357  0.000  1.0
  F  F19  1  0.803  0.803  0.959  1.0
  F  F20  1  0.949  0.620  0.143  1.0
  F  F21  1  0.880  0.551  0.643  1.0
  F  F22  1  0.002  0.002  0.691  1.0
  F  F23  1  0.857  0.143  0.500  1.0
[/CIF]
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The crystal structure described by VF5 is Indium-like structured and crystallizes in the orthorhombic Cmce space group. The structure is zero-dimensional and consists of four VF5 clusters. V(1) is bonded to one F(2), one F(4), two equivalent F(1), and two equivalent F(3) atoms to form distorted edge-sharing VF6 octahedra. There are four inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to two equivalent V(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_VF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.455
_cell_length_b   5.455
_cell_length_c   11.618
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   97.815
_symmetry_Int_Tables_number   1
_cell_volume   342.563
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.172  0.172  0.414  1.0
  V  V1  1  0.328  0.328  0.914  1.0
  V  V2  1  0.672  0.672  0.086  1.0
  V  V3  1  0.828  0.828  0.586  1.0
  F  F4  1  0.143  0.857  0.500  1.0
  F  F5  1  0.998  0.998  0.309  1.0
  F  F6  1  0.120  0.449  0.357  1.0
  F  F7  1  0.051  0.380  0.857  1.0
  F  F8  1  0.197  0.197  0.041  1.0
  F  F9  1  0.357  0.643  0.000  1.0
  F  F10  1  0.303  0.303  0.541  1.0
  F  F11  1  0.449  0.120  0.357  1.0
  F  F12  1  0.380  0.051  0.857  1.0
  F  F13  1  0.502  0.502  0.809  1.0
  F  F14  1  0.498  0.498  0.191  1.0
  F  F15  1  0.620  0.949  0.143  1.0
  F  F16  1  0.551  0.880  0.643  1.0
  F  F17  1  0.697  0.697  0.459  1.0
  F  F18  1  0.643  0.357  0.000  1.0
  F  F19  1  0.803  0.803  0.959  1.0
  F  F20  1  0.949  0.620  0.143  1.0
  F  F21  1  0.880  0.551  0.643  1.0
  F  F22  1  0.002  0.002  0.691  1.0
  F  F23  1  0.857  0.143  0.500  1.0
[/CIF]
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