The compound described by (GaCl4)2N2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four ammonia atoms and four GaCl4 clusters. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. is represented by the CIF file [CIF]
data_GaNCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.244
_cell_length_b   9.604
_cell_length_c   11.308
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   786.685
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.250  0.189  0.566  1.0
  Ga  Ga1  1  0.250  0.311  0.066  1.0
  Ga  Ga2  1  0.750  0.811  0.434  1.0
  Ga  Ga3  1  0.750  0.689  0.934  1.0
  N  N4  1  0.250  0.824  0.184  1.0
  N  N5  1  0.250  0.676  0.684  1.0
  N  N6  1  0.750  0.176  0.816  1.0
  N  N7  1  0.750  0.324  0.316  1.0
  Cl  Cl8  1  0.005  0.325  0.576  1.0
  Cl  Cl9  1  0.495  0.175  0.076  1.0
  Cl  Cl10  1  0.505  0.675  0.424  1.0
  Cl  Cl11  1  0.995  0.825  0.924  1.0
  Cl  Cl12  1  0.995  0.675  0.424  1.0
  Cl  Cl13  1  0.505  0.825  0.924  1.0
  Cl  Cl14  1  0.495  0.325  0.576  1.0
  Cl  Cl15  1  0.005  0.175  0.076  1.0
  Cl  Cl16  1  0.250  0.050  0.721  1.0
  Cl  Cl17  1  0.250  0.450  0.221  1.0
  Cl  Cl18  1  0.750  0.950  0.279  1.0
  Cl  Cl19  1  0.750  0.550  0.779  1.0
  Cl  Cl20  1  0.250  0.075  0.398  1.0
  Cl  Cl21  1  0.250  0.425  0.898  1.0
  Cl  Cl22  1  0.750  0.925  0.602  1.0
  Cl  Cl23  1  0.750  0.575  0.102  1.0
[/CIF]
.
The compound described by (GaCl4)2N2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four ammonia atoms and four GaCl4 clusters. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. is represented by the CIF file [CIF]
data_GaNCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.244
_cell_length_b   9.604
_cell_length_c   11.308
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   786.685
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.250  0.189  0.566  1.0
  Ga  Ga1  1  0.250  0.311  0.066  1.0
  Ga  Ga2  1  0.750  0.811  0.434  1.0
  Ga  Ga3  1  0.750  0.689  0.934  1.0
  N  N4  1  0.250  0.824  0.184  1.0
  N  N5  1  0.250  0.676  0.684  1.0
  N  N6  1  0.750  0.176  0.816  1.0
  N  N7  1  0.750  0.324  0.316  1.0
  Cl  Cl8  1  0.005  0.325  0.576  1.0
  Cl  Cl9  1  0.495  0.175  0.076  1.0
  Cl  Cl10  1  0.505  0.675  0.424  1.0
  Cl  Cl11  1  0.995  0.825  0.924  1.0
  Cl  Cl12  1  0.995  0.675  0.424  1.0
  Cl  Cl13  1  0.505  0.825  0.924  1.0
  Cl  Cl14  1  0.495  0.325  0.576  1.0
  Cl  Cl15  1  0.005  0.175  0.076  1.0
  Cl  Cl16  1  0.250  0.050  0.721  1.0
  Cl  Cl17  1  0.250  0.450  0.221  1.0
  Cl  Cl18  1  0.750  0.950  0.279  1.0
  Cl  Cl19  1  0.750  0.550  0.779  1.0
  Cl  Cl20  1  0.250  0.075  0.398  1.0
  Cl  Cl21  1  0.250  0.425  0.898  1.0
  Cl  Cl22  1  0.750  0.925  0.602  1.0
  Cl  Cl23  1  0.750  0.575  0.102  1.0
[/CIF]
.