The material described by Co(CO)4 is alpha Po structured and crystallizes in the cubic P-43m space group. The structure is zero-dimensional and consists of one Co(CO)4 cluster. Co(1) is bonded in a tetrahedral geometry to four equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Co(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(CO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.765
_cell_length_b   5.765
_cell_length_c   5.765
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   191.628
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  0.500  1.0
  C  C1  1  0.319  0.681  0.681  1.0
  C  C2  1  0.319  0.319  0.319  1.0
  C  C3  1  0.681  0.319  0.681  1.0
  C  C4  1  0.681  0.681  0.319  1.0
  O  O5  1  0.203  0.203  0.203  1.0
  O  O6  1  0.203  0.797  0.797  1.0
  O  O7  1  0.797  0.203  0.797  1.0
  O  O8  1  0.797  0.797  0.203  1.0
[/CIF]
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The material described by Co(CO)4 is alpha Po structured and crystallizes in the cubic P-43m space group. The structure is zero-dimensional and consists of one Co(CO)4 cluster. Co(1) is bonded in a tetrahedral geometry to four equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Co(1) and one O(1) atom. O(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(CO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.765
_cell_length_b   5.765
_cell_length_c   5.765
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   191.628
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  0.500  1.0
  C  C1  1  0.319  0.681  0.681  1.0
  C  C2  1  0.319  0.319  0.319  1.0
  C  C3  1  0.681  0.319  0.681  1.0
  C  C4  1  0.681  0.681  0.319  1.0
  O  O5  1  0.203  0.203  0.203  1.0
  O  O6  1  0.203  0.797  0.797  1.0
  O  O7  1  0.797  0.203  0.797  1.0
  O  O8  1  0.797  0.797  0.203  1.0
[/CIF]
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