The material structure described by MoCdPO6 crystallizes in the monoclinic P2_1/c space group. Mo(1) is bonded to one O(2), one O(3), one O(5), one O(6), and two equivalent O(1) atoms to form distorted MoO6 octahedra that share corners with three equivalent Cd(1)O6 octahedra, corners with three equivalent P(1)O4 tetrahedra,  an edgeedge with one Mo(1)O6 octahedra, and  an edgeedge with one Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-58°. Cd(1) is bonded to one O(1), one O(3), one O(5), one O(6), and two equivalent O(4) atoms to form CdO6 octahedra that share corners with three equivalent Mo(1)O6 octahedra, corners with four equivalent P(1)O4 tetrahedra,  an edgeedge with one Mo(1)O6 octahedra, and  an edgeedge with one Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-58°. P(1) is bonded to one O(2), one O(3), one O(4), and one O(6) atom to form PO4 tetrahedra that share corners with three equivalent Mo(1)O6 octahedra and corners with four equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-62°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Mo(1) and one Cd(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mo(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mo(1), one Cd(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mo(1) and one Cd(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mo(1), one Cd(1), and one P(1) atom. is represented by the CIF card [CIF]
data_CdMoPO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.677
_cell_length_b   4.988
_cell_length_c   11.840
_cell_angle_alpha   70.998
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   484.490
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.828  0.671  0.424  1.0
  Cd  Cd1  1  0.328  0.329  0.076  1.0
  Cd  Cd2  1  0.672  0.671  0.924  1.0
  Cd  Cd3  1  0.172  0.329  0.576  1.0
  Mo  Mo4  1  0.910  0.989  0.114  1.0
  Mo  Mo5  1  0.090  0.011  0.886  1.0
  Mo  Mo6  1  0.410  0.011  0.386  1.0
  Mo  Mo7  1  0.590  0.989  0.614  1.0
  P  P8  1  0.558  0.681  0.209  1.0
  P  P9  1  0.442  0.319  0.791  1.0
  P  P10  1  0.058  0.319  0.291  1.0
  P  P11  1  0.942  0.681  0.709  1.0
  O  O12  1  0.390  0.128  0.535  1.0
  O  O13  1  0.020  0.590  0.189  1.0
  O  O14  1  0.536  0.059  0.777  1.0
  O  O15  1  0.464  0.941  0.223  1.0
  O  O16  1  0.981  0.657  0.586  1.0
  O  O17  1  0.036  0.941  0.723  1.0
  O  O18  1  0.610  0.872  0.465  1.0
  O  O19  1  0.481  0.343  0.914  1.0
  O  O20  1  0.480  0.590  0.689  1.0
  O  O21  1  0.980  0.410  0.811  1.0
  O  O22  1  0.520  0.410  0.311  1.0
  O  O23  1  0.110  0.128  0.035  1.0
  O  O24  1  0.713  0.278  0.562  1.0
  O  O25  1  0.232  0.261  0.276  1.0
  O  O26  1  0.519  0.657  0.086  1.0
  O  O27  1  0.268  0.261  0.776  1.0
  O  O28  1  0.768  0.739  0.724  1.0
  O  O29  1  0.287  0.722  0.438  1.0
  O  O30  1  0.732  0.739  0.224  1.0
  O  O31  1  0.964  0.059  0.277  1.0
  O  O32  1  0.890  0.872  0.965  1.0
  O  O33  1  0.019  0.343  0.414  1.0
  O  O34  1  0.213  0.722  0.938  1.0
  O  O35  1  0.787  0.278  0.062  1.0
[/CIF]
.
The material structure described by MoCdPO6 crystallizes in the monoclinic P2_1/c space group. Mo(1) is bonded to one O(2), one O(3), one O(5), one O(6), and two equivalent O(1) atoms to form distorted MoO6 octahedra that share corners with three equivalent Cd(1)O6 octahedra, corners with three equivalent P(1)O4 tetrahedra,  an edgeedge with one Mo(1)O6 octahedra, and  an edgeedge with one Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-58°. Cd(1) is bonded to one O(1), one O(3), one O(5), one O(6), and two equivalent O(4) atoms to form CdO6 octahedra that share corners with three equivalent Mo(1)O6 octahedra, corners with four equivalent P(1)O4 tetrahedra,  an edgeedge with one Mo(1)O6 octahedra, and  an edgeedge with one Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-58°. P(1) is bonded to one O(2), one O(3), one O(4), and one O(6) atom to form PO4 tetrahedra that share corners with three equivalent Mo(1)O6 octahedra and corners with four equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-62°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Mo(1) and one Cd(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mo(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Mo(1), one Cd(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mo(1) and one Cd(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mo(1), one Cd(1), and one P(1) atom. is represented by the CIF card [CIF]
data_CdMoPO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.677
_cell_length_b   4.988
_cell_length_c   11.840
_cell_angle_alpha   70.998
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   484.490
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.828  0.671  0.424  1.0
  Cd  Cd1  1  0.328  0.329  0.076  1.0
  Cd  Cd2  1  0.672  0.671  0.924  1.0
  Cd  Cd3  1  0.172  0.329  0.576  1.0
  Mo  Mo4  1  0.910  0.989  0.114  1.0
  Mo  Mo5  1  0.090  0.011  0.886  1.0
  Mo  Mo6  1  0.410  0.011  0.386  1.0
  Mo  Mo7  1  0.590  0.989  0.614  1.0
  P  P8  1  0.558  0.681  0.209  1.0
  P  P9  1  0.442  0.319  0.791  1.0
  P  P10  1  0.058  0.319  0.291  1.0
  P  P11  1  0.942  0.681  0.709  1.0
  O  O12  1  0.390  0.128  0.535  1.0
  O  O13  1  0.020  0.590  0.189  1.0
  O  O14  1  0.536  0.059  0.777  1.0
  O  O15  1  0.464  0.941  0.223  1.0
  O  O16  1  0.981  0.657  0.586  1.0
  O  O17  1  0.036  0.941  0.723  1.0
  O  O18  1  0.610  0.872  0.465  1.0
  O  O19  1  0.481  0.343  0.914  1.0
  O  O20  1  0.480  0.590  0.689  1.0
  O  O21  1  0.980  0.410  0.811  1.0
  O  O22  1  0.520  0.410  0.311  1.0
  O  O23  1  0.110  0.128  0.035  1.0
  O  O24  1  0.713  0.278  0.562  1.0
  O  O25  1  0.232  0.261  0.276  1.0
  O  O26  1  0.519  0.657  0.086  1.0
  O  O27  1  0.268  0.261  0.776  1.0
  O  O28  1  0.768  0.739  0.724  1.0
  O  O29  1  0.287  0.722  0.438  1.0
  O  O30  1  0.732  0.739  0.224  1.0
  O  O31  1  0.964  0.059  0.277  1.0
  O  O32  1  0.890  0.872  0.965  1.0
  O  O33  1  0.019  0.343  0.414  1.0
  O  O34  1  0.213  0.722  0.938  1.0
  O  O35  1  0.787  0.278  0.062  1.0
[/CIF]
.