The crystal structure described by Rb2U(N2O7)2 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), one O(7), two equivalent O(2), two equivalent O(5), and two equivalent O(6) atoms. U(1) is bonded in a distorted linear geometry to two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(7) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(3), one O(5), and one O(6) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Rb(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one U(1), and one N(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), one U(1), and one N(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one U(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Rb(1), one U(1), and one N(1) atom. is represented by the CIF card [CIF]
data_Rb2U(N2O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.116
_cell_length_b   6.634
_cell_length_c   13.145
_cell_angle_alpha   73.693
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   679.235
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.986  0.679  0.658  1.0
  Rb  Rb1  1  0.514  0.679  0.158  1.0
  Rb  Rb2  1  0.014  0.321  0.342  1.0
  Rb  Rb3  1  0.486  0.321  0.842  1.0
  U  U4  1  0.000  0.000  0.000  1.0
  U  U5  1  0.500  0.000  0.500  1.0
  N  N6  1  0.261  0.177  0.628  1.0
  N  N7  1  0.761  0.823  0.872  1.0
  N  N8  1  0.739  0.823  0.372  1.0
  N  N9  1  0.227  0.736  0.390  1.0
  N  N10  1  0.727  0.264  0.110  1.0
  N  N11  1  0.773  0.264  0.610  1.0
  N  N12  1  0.273  0.736  0.890  1.0
  N  N13  1  0.239  0.177  0.128  1.0
  O  O14  1  0.665  0.746  0.821  1.0
  O  O15  1  0.212  0.084  0.559  1.0
  O  O16  1  0.773  0.080  0.100  1.0
  O  O17  1  0.506  0.258  0.408  1.0
  O  O18  1  0.769  0.291  0.700  1.0
  O  O19  1  0.178  0.599  0.470  1.0
  O  O20  1  0.335  0.254  0.179  1.0
  O  O21  1  0.227  0.920  0.900  1.0
  O  O22  1  0.165  0.254  0.679  1.0
  O  O23  1  0.678  0.401  0.030  1.0
  O  O24  1  0.494  0.742  0.592  1.0
  O  O25  1  0.322  0.599  0.970  1.0
  O  O26  1  0.582  0.821  0.360  1.0
  O  O27  1  0.288  0.084  0.059  1.0
  O  O28  1  0.731  0.291  0.200  1.0
  O  O29  1  0.273  0.920  0.400  1.0
  O  O30  1  0.822  0.401  0.530  1.0
  O  O31  1  0.082  0.179  0.140  1.0
  O  O32  1  0.418  0.179  0.640  1.0
  O  O33  1  0.006  0.742  0.092  1.0
  O  O34  1  0.835  0.746  0.321  1.0
  O  O35  1  0.994  0.258  0.908  1.0
  O  O36  1  0.727  0.080  0.600  1.0
  O  O37  1  0.712  0.916  0.941  1.0
  O  O38  1  0.269  0.709  0.800  1.0
  O  O39  1  0.918  0.821  0.860  1.0
  O  O40  1  0.231  0.709  0.300  1.0
  O  O41  1  0.788  0.916  0.441  1.0
[/CIF]
.
The crystal structure described by Rb2U(N2O7)2 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), one O(7), two equivalent O(2), two equivalent O(5), and two equivalent O(6) atoms. U(1) is bonded in a distorted linear geometry to two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(7) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(3), one O(5), and one O(6) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Rb(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one U(1), and one N(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), one U(1), and one N(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one U(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Rb(1), one U(1), and one N(1) atom. is represented by the CIF card [CIF]
data_Rb2U(N2O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.116
_cell_length_b   6.634
_cell_length_c   13.145
_cell_angle_alpha   73.693
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   679.235
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.986  0.679  0.658  1.0
  Rb  Rb1  1  0.514  0.679  0.158  1.0
  Rb  Rb2  1  0.014  0.321  0.342  1.0
  Rb  Rb3  1  0.486  0.321  0.842  1.0
  U  U4  1  0.000  0.000  0.000  1.0
  U  U5  1  0.500  0.000  0.500  1.0
  N  N6  1  0.261  0.177  0.628  1.0
  N  N7  1  0.761  0.823  0.872  1.0
  N  N8  1  0.739  0.823  0.372  1.0
  N  N9  1  0.227  0.736  0.390  1.0
  N  N10  1  0.727  0.264  0.110  1.0
  N  N11  1  0.773  0.264  0.610  1.0
  N  N12  1  0.273  0.736  0.890  1.0
  N  N13  1  0.239  0.177  0.128  1.0
  O  O14  1  0.665  0.746  0.821  1.0
  O  O15  1  0.212  0.084  0.559  1.0
  O  O16  1  0.773  0.080  0.100  1.0
  O  O17  1  0.506  0.258  0.408  1.0
  O  O18  1  0.769  0.291  0.700  1.0
  O  O19  1  0.178  0.599  0.470  1.0
  O  O20  1  0.335  0.254  0.179  1.0
  O  O21  1  0.227  0.920  0.900  1.0
  O  O22  1  0.165  0.254  0.679  1.0
  O  O23  1  0.678  0.401  0.030  1.0
  O  O24  1  0.494  0.742  0.592  1.0
  O  O25  1  0.322  0.599  0.970  1.0
  O  O26  1  0.582  0.821  0.360  1.0
  O  O27  1  0.288  0.084  0.059  1.0
  O  O28  1  0.731  0.291  0.200  1.0
  O  O29  1  0.273  0.920  0.400  1.0
  O  O30  1  0.822  0.401  0.530  1.0
  O  O31  1  0.082  0.179  0.140  1.0
  O  O32  1  0.418  0.179  0.640  1.0
  O  O33  1  0.006  0.742  0.092  1.0
  O  O34  1  0.835  0.746  0.321  1.0
  O  O35  1  0.994  0.258  0.908  1.0
  O  O36  1  0.727  0.080  0.600  1.0
  O  O37  1  0.712  0.916  0.941  1.0
  O  O38  1  0.269  0.709  0.800  1.0
  O  O39  1  0.918  0.821  0.860  1.0
  O  O40  1  0.231  0.709  0.300  1.0
  O  O41  1  0.788  0.916  0.441  1.0
[/CIF]
.