The compound described by (Bi)5(GaCl4)3 is Iron carbide-derived structured and crystallizes in the trigonal R3c space group. The structure is zero-dimensional and consists of thirty 7440-69-9 atoms and eighteen GaCl4 clusters. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ga(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ga3Bi5Cl12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.222
_cell_length_b   12.222
_cell_length_c   12.222
_cell_angle_alpha   58.189
_cell_angle_beta   58.189
_cell_angle_gamma   58.189
_symmetry_Int_Tables_number   1
_cell_volume   1237.254
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.225  0.750  0.276  1.0
  Ga  Ga1  1  0.750  0.276  0.225  1.0
  Ga  Ga2  1  0.725  0.776  0.250  1.0
  Ga  Ga3  1  0.276  0.225  0.750  1.0
  Ga  Ga4  1  0.250  0.725  0.776  1.0
  Ga  Ga5  1  0.776  0.250  0.725  1.0
  Bi  Bi6  1  0.409  0.250  0.091  1.0
  Bi  Bi7  1  0.909  0.591  0.750  1.0
  Bi  Bi8  1  0.172  0.172  0.172  1.0
  Bi  Bi9  1  0.672  0.672  0.672  1.0
  Bi  Bi10  1  0.591  0.750  0.909  1.0
  Bi  Bi11  1  0.828  0.828  0.828  1.0
  Bi  Bi12  1  0.328  0.328  0.328  1.0
  Bi  Bi13  1  0.091  0.409  0.250  1.0
  Bi  Bi14  1  0.750  0.909  0.591  1.0
  Bi  Bi15  1  0.250  0.091  0.409  1.0
  Cl  Cl16  1  0.072  0.692  0.963  1.0
  Cl  Cl17  1  0.463  0.192  0.572  1.0
  Cl  Cl18  1  0.192  0.572  0.463  1.0
  Cl  Cl19  1  0.304  0.891  0.733  1.0
  Cl  Cl20  1  0.610  0.196  0.768  1.0
  Cl  Cl21  1  0.692  0.963  0.072  1.0
  Cl  Cl22  1  0.733  0.304  0.891  1.0
  Cl  Cl23  1  0.196  0.768  0.610  1.0
  Cl  Cl24  1  0.809  0.428  0.538  1.0
  Cl  Cl25  1  0.696  0.110  0.268  1.0
  Cl  Cl26  1  0.963  0.072  0.692  1.0
  Cl  Cl27  1  0.538  0.809  0.428  1.0
  Cl  Cl28  1  0.928  0.309  0.038  1.0
  Cl  Cl29  1  0.309  0.038  0.928  1.0
  Cl  Cl30  1  0.268  0.696  0.110  1.0
  Cl  Cl31  1  0.804  0.233  0.391  1.0
  Cl  Cl32  1  0.233  0.391  0.804  1.0
  Cl  Cl33  1  0.768  0.610  0.196  1.0
  Cl  Cl34  1  0.110  0.268  0.696  1.0
  Cl  Cl35  1  0.038  0.928  0.309  1.0
  Cl  Cl36  1  0.572  0.463  0.192  1.0
  Cl  Cl37  1  0.428  0.538  0.809  1.0
  Cl  Cl38  1  0.891  0.733  0.304  1.0
  Cl  Cl39  1  0.391  0.804  0.233  1.0
[/CIF]
.
The compound described by (Bi)5(GaCl4)3 is Iron carbide-derived structured and crystallizes in the trigonal R3c space group. The structure is zero-dimensional and consists of thirty 7440-69-9 atoms and eighteen GaCl4 clusters. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ga(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ga3Bi5Cl12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.222
_cell_length_b   12.222
_cell_length_c   12.222
_cell_angle_alpha   58.189
_cell_angle_beta   58.189
_cell_angle_gamma   58.189
_symmetry_Int_Tables_number   1
_cell_volume   1237.254
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.225  0.750  0.276  1.0
  Ga  Ga1  1  0.750  0.276  0.225  1.0
  Ga  Ga2  1  0.725  0.776  0.250  1.0
  Ga  Ga3  1  0.276  0.225  0.750  1.0
  Ga  Ga4  1  0.250  0.725  0.776  1.0
  Ga  Ga5  1  0.776  0.250  0.725  1.0
  Bi  Bi6  1  0.409  0.250  0.091  1.0
  Bi  Bi7  1  0.909  0.591  0.750  1.0
  Bi  Bi8  1  0.172  0.172  0.172  1.0
  Bi  Bi9  1  0.672  0.672  0.672  1.0
  Bi  Bi10  1  0.591  0.750  0.909  1.0
  Bi  Bi11  1  0.828  0.828  0.828  1.0
  Bi  Bi12  1  0.328  0.328  0.328  1.0
  Bi  Bi13  1  0.091  0.409  0.250  1.0
  Bi  Bi14  1  0.750  0.909  0.591  1.0
  Bi  Bi15  1  0.250  0.091  0.409  1.0
  Cl  Cl16  1  0.072  0.692  0.963  1.0
  Cl  Cl17  1  0.463  0.192  0.572  1.0
  Cl  Cl18  1  0.192  0.572  0.463  1.0
  Cl  Cl19  1  0.304  0.891  0.733  1.0
  Cl  Cl20  1  0.610  0.196  0.768  1.0
  Cl  Cl21  1  0.692  0.963  0.072  1.0
  Cl  Cl22  1  0.733  0.304  0.891  1.0
  Cl  Cl23  1  0.196  0.768  0.610  1.0
  Cl  Cl24  1  0.809  0.428  0.538  1.0
  Cl  Cl25  1  0.696  0.110  0.268  1.0
  Cl  Cl26  1  0.963  0.072  0.692  1.0
  Cl  Cl27  1  0.538  0.809  0.428  1.0
  Cl  Cl28  1  0.928  0.309  0.038  1.0
  Cl  Cl29  1  0.309  0.038  0.928  1.0
  Cl  Cl30  1  0.268  0.696  0.110  1.0
  Cl  Cl31  1  0.804  0.233  0.391  1.0
  Cl  Cl32  1  0.233  0.391  0.804  1.0
  Cl  Cl33  1  0.768  0.610  0.196  1.0
  Cl  Cl34  1  0.110  0.268  0.696  1.0
  Cl  Cl35  1  0.038  0.928  0.309  1.0
  Cl  Cl36  1  0.572  0.463  0.192  1.0
  Cl  Cl37  1  0.428  0.538  0.809  1.0
  Cl  Cl38  1  0.891  0.733  0.304  1.0
  Cl  Cl39  1  0.391  0.804  0.233  1.0
[/CIF]
.