The material structure described by LiMn(PO3)4 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(10), one O(5), and one O(6) atom. Mn(1) is bonded to one O(1), one O(10), one O(3), one O(6), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(3), one O(7), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 14-34°. In the second P site, P(2) is bonded to one O(10), one O(12), one O(2), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 19-36°. In the third P site, P(3) is bonded to one O(12), one O(5), one O(7), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 33°. In the fourth P site, P(4) is bonded to one O(1), one O(11), one O(2), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 37°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Mn(1), and one P(4) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one P(2) and one P(4) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one P(4) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Li(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the eighth O site, O(8) is bonded in a linear geometry to one Mn(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Li(1), one Mn(1), and one P(2) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one P(1) and one P(4) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. is represented by the CIF card [CIF]
data_LiMn(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.301
_cell_length_b   7.271
_cell_length_c   7.569
_cell_angle_alpha   70.723
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   483.196
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.662  0.374  0.417  1.0
  Li  Li1  1  0.162  0.626  0.583  1.0
  Mn  Mn2  1  0.502  0.754  0.246  1.0
  Mn  Mn3  1  0.002  0.246  0.754  1.0
  P  P4  1  0.794  0.095  0.124  1.0
  P  P5  1  0.706  0.604  0.631  1.0
  P  P6  1  0.206  0.396  0.369  1.0
  P  P7  1  0.911  0.952  0.519  1.0
  P  P8  1  0.294  0.905  0.876  1.0
  P  P9  1  0.585  0.442  0.019  1.0
  P  P10  1  0.085  0.558  0.981  1.0
  P  P11  1  0.411  0.048  0.481  1.0
  O  O12  1  0.598  0.555  0.158  1.0
  O  O13  1  0.128  0.401  0.181  1.0
  O  O14  1  0.913  0.100  0.986  1.0
  O  O15  1  0.413  0.900  0.014  1.0
  O  O16  1  0.951  0.664  0.989  1.0
  O  O17  1  0.044  0.839  0.519  1.0
  O  O18  1  0.312  0.557  0.347  1.0
  O  O19  1  0.873  0.095  0.313  1.0
  O  O20  1  0.186  0.064  0.838  1.0
  O  O21  1  0.544  0.161  0.481  1.0
  O  O22  1  0.373  0.905  0.687  1.0
  O  O23  1  0.451  0.336  0.011  1.0
  O  O24  1  0.400  0.918  0.363  1.0
  O  O25  1  0.092  0.399  0.513  1.0
  O  O26  1  0.900  0.082  0.637  1.0
  O  O27  1  0.592  0.601  0.487  1.0
  O  O28  1  0.228  0.691  0.936  1.0
  O  O29  1  0.270  0.183  0.432  1.0
  O  O30  1  0.098  0.445  0.842  1.0
  O  O31  1  0.686  0.936  0.162  1.0
  O  O32  1  0.770  0.817  0.568  1.0
  O  O33  1  0.728  0.309  0.064  1.0
  O  O34  1  0.812  0.443  0.653  1.0
  O  O35  1  0.628  0.599  0.819  1.0
[/CIF]
.
The material structure described by LiMn(PO3)4 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(10), one O(5), and one O(6) atom. Mn(1) is bonded to one O(1), one O(10), one O(3), one O(6), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. There are four inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(3), one O(7), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 14-34°. In the second P site, P(2) is bonded to one O(10), one O(12), one O(2), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 19-36°. In the third P site, P(3) is bonded to one O(12), one O(5), one O(7), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 33°. In the fourth P site, P(4) is bonded to one O(1), one O(11), one O(2), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 37°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one Mn(1), and one P(4) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one P(2) and one P(4) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one P(4) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Li(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one Mn(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the eighth O site, O(8) is bonded in a linear geometry to one Mn(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(3) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Li(1), one Mn(1), and one P(2) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one P(1) and one P(4) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. is represented by the CIF card [CIF]
data_LiMn(PO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.301
_cell_length_b   7.271
_cell_length_c   7.569
_cell_angle_alpha   70.723
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   483.196
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.662  0.374  0.417  1.0
  Li  Li1  1  0.162  0.626  0.583  1.0
  Mn  Mn2  1  0.502  0.754  0.246  1.0
  Mn  Mn3  1  0.002  0.246  0.754  1.0
  P  P4  1  0.794  0.095  0.124  1.0
  P  P5  1  0.706  0.604  0.631  1.0
  P  P6  1  0.206  0.396  0.369  1.0
  P  P7  1  0.911  0.952  0.519  1.0
  P  P8  1  0.294  0.905  0.876  1.0
  P  P9  1  0.585  0.442  0.019  1.0
  P  P10  1  0.085  0.558  0.981  1.0
  P  P11  1  0.411  0.048  0.481  1.0
  O  O12  1  0.598  0.555  0.158  1.0
  O  O13  1  0.128  0.401  0.181  1.0
  O  O14  1  0.913  0.100  0.986  1.0
  O  O15  1  0.413  0.900  0.014  1.0
  O  O16  1  0.951  0.664  0.989  1.0
  O  O17  1  0.044  0.839  0.519  1.0
  O  O18  1  0.312  0.557  0.347  1.0
  O  O19  1  0.873  0.095  0.313  1.0
  O  O20  1  0.186  0.064  0.838  1.0
  O  O21  1  0.544  0.161  0.481  1.0
  O  O22  1  0.373  0.905  0.687  1.0
  O  O23  1  0.451  0.336  0.011  1.0
  O  O24  1  0.400  0.918  0.363  1.0
  O  O25  1  0.092  0.399  0.513  1.0
  O  O26  1  0.900  0.082  0.637  1.0
  O  O27  1  0.592  0.601  0.487  1.0
  O  O28  1  0.228  0.691  0.936  1.0
  O  O29  1  0.270  0.183  0.432  1.0
  O  O30  1  0.098  0.445  0.842  1.0
  O  O31  1  0.686  0.936  0.162  1.0
  O  O32  1  0.770  0.817  0.568  1.0
  O  O33  1  0.728  0.309  0.064  1.0
  O  O34  1  0.812  0.443  0.653  1.0
  O  O35  1  0.628  0.599  0.819  1.0
[/CIF]
.