The structure described by KVSO9 crystallizes in the monoclinic P2_1 space group. K(1) is bonded in a 6-coordinate geometry to one O(3), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. V(1) is bonded in a 5-coordinate geometry to one O(5), one O(6), one O(7), one O(8), and one O(9) atom. S(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(5), and one O(7) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one O(2) and one O(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one O(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one K(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one K(1), one V(1), and one S(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one V(1) and one O(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one K(1), one V(1), and one S(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one K(1) and one V(1) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one K(1) and one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KVSO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.152
_cell_length_b   6.302
_cell_length_c   11.329
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   106.391
_symmetry_Int_Tables_number   1
_cell_volume   421.377
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.715  0.774  0.179  1.0
  K  K1  1  0.285  0.226  0.679  1.0
  V  V2  1  0.895  0.643  0.872  1.0
  V  V3  1  0.105  0.357  0.372  1.0
  S  S4  1  0.424  0.744  0.856  1.0
  S  S5  1  0.576  0.256  0.356  1.0
  O  O6  1  0.861  0.724  0.607  1.0
  O  O7  1  0.139  0.276  0.107  1.0
  O  O8  1  0.734  0.701  0.518  1.0
  O  O9  1  0.266  0.299  0.018  1.0
  O  O10  1  0.451  0.809  0.979  1.0
  O  O11  1  0.549  0.191  0.479  1.0
  O  O12  1  0.472  0.923  0.770  1.0
  O  O13  1  0.528  0.077  0.270  1.0
  O  O14  1  0.569  0.585  0.828  1.0
  O  O15  1  0.431  0.415  0.328  1.0
  O  O16  1  0.827  0.547  0.677  1.0
  O  O17  1  0.173  0.453  0.177  1.0
  O  O18  1  0.815  0.414  0.332  1.0
  O  O19  1  0.185  0.586  0.832  1.0
  O  O20  1  0.852  0.535  0.006  1.0
  O  O21  1  0.148  0.465  0.506  1.0
  O  O22  1  0.972  0.913  0.884  1.0
  O  O23  1  0.028  0.087  0.384  1.0
[/CIF]
.
The structure described by KVSO9 crystallizes in the monoclinic P2_1 space group. K(1) is bonded in a 6-coordinate geometry to one O(3), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. V(1) is bonded in a 5-coordinate geometry to one O(5), one O(6), one O(7), one O(8), and one O(9) atom. S(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(5), and one O(7) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one O(2) and one O(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one O(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one K(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one K(1), one V(1), and one S(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one V(1) and one O(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one K(1), one V(1), and one S(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one K(1) and one V(1) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one K(1) and one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KVSO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.152
_cell_length_b   6.302
_cell_length_c   11.329
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   106.391
_symmetry_Int_Tables_number   1
_cell_volume   421.377
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.715  0.774  0.179  1.0
  K  K1  1  0.285  0.226  0.679  1.0
  V  V2  1  0.895  0.643  0.872  1.0
  V  V3  1  0.105  0.357  0.372  1.0
  S  S4  1  0.424  0.744  0.856  1.0
  S  S5  1  0.576  0.256  0.356  1.0
  O  O6  1  0.861  0.724  0.607  1.0
  O  O7  1  0.139  0.276  0.107  1.0
  O  O8  1  0.734  0.701  0.518  1.0
  O  O9  1  0.266  0.299  0.018  1.0
  O  O10  1  0.451  0.809  0.979  1.0
  O  O11  1  0.549  0.191  0.479  1.0
  O  O12  1  0.472  0.923  0.770  1.0
  O  O13  1  0.528  0.077  0.270  1.0
  O  O14  1  0.569  0.585  0.828  1.0
  O  O15  1  0.431  0.415  0.328  1.0
  O  O16  1  0.827  0.547  0.677  1.0
  O  O17  1  0.173  0.453  0.177  1.0
  O  O18  1  0.815  0.414  0.332  1.0
  O  O19  1  0.185  0.586  0.832  1.0
  O  O20  1  0.852  0.535  0.006  1.0
  O  O21  1  0.148  0.465  0.506  1.0
  O  O22  1  0.972  0.913  0.884  1.0
  O  O23  1  0.028  0.087  0.384  1.0
[/CIF]
.