The material described by LiNH2 crystallizes in the orthorhombic Fddd space group. Li(1) is bonded in a 6-coordinate geometry to four equivalent N(1) and two equivalent H(1) atoms. N(1) is bonded in a distorted water-like geometry to four equivalent Li(1) and two equivalent H(1) atoms. H(1) is bonded in a single-bond geometry to one Li(1) and one N(1) atom. is represented by the CIF file [CIF]
data_LiH2N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.865
_cell_length_b   4.865
_cell_length_c   6.364
_cell_angle_alpha   112.276
_cell_angle_beta   112.276
_cell_angle_gamma   90.475
_symmetry_Int_Tables_number   1
_cell_volume   126.946
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.993  0.743  0.485  1.0
  Li  Li1  1  0.757  0.507  0.015  1.0
  Li  Li2  1  0.007  0.257  0.515  1.0
  Li  Li3  1  0.243  0.493  0.985  1.0
  H  H4  1  0.599  0.015  0.168  1.0
  H  H5  1  0.070  0.154  0.168  1.0
  H  H6  1  0.346  0.430  0.332  1.0
  H  H7  1  0.485  0.901  0.332  1.0
  H  H8  1  0.401  0.985  0.832  1.0
  H  H9  1  0.930  0.846  0.832  1.0
  H  H10  1  0.654  0.570  0.668  1.0
  H  H11  1  0.515  0.099  0.668  1.0
  N  N12  1  0.636  0.864  0.250  1.0
  N  N13  1  0.114  0.386  0.250  1.0
  N  N14  1  0.364  0.136  0.750  1.0
  N  N15  1  0.886  0.614  0.750  1.0
[/CIF]
.
The material described by LiNH2 crystallizes in the orthorhombic Fddd space group. Li(1) is bonded in a 6-coordinate geometry to four equivalent N(1) and two equivalent H(1) atoms. N(1) is bonded in a distorted water-like geometry to four equivalent Li(1) and two equivalent H(1) atoms. H(1) is bonded in a single-bond geometry to one Li(1) and one N(1) atom. is represented by the CIF file [CIF]
data_LiH2N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.865
_cell_length_b   4.865
_cell_length_c   6.364
_cell_angle_alpha   112.276
_cell_angle_beta   112.276
_cell_angle_gamma   90.475
_symmetry_Int_Tables_number   1
_cell_volume   126.946
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.993  0.743  0.485  1.0
  Li  Li1  1  0.757  0.507  0.015  1.0
  Li  Li2  1  0.007  0.257  0.515  1.0
  Li  Li3  1  0.243  0.493  0.985  1.0
  H  H4  1  0.599  0.015  0.168  1.0
  H  H5  1  0.070  0.154  0.168  1.0
  H  H6  1  0.346  0.430  0.332  1.0
  H  H7  1  0.485  0.901  0.332  1.0
  H  H8  1  0.401  0.985  0.832  1.0
  H  H9  1  0.930  0.846  0.832  1.0
  H  H10  1  0.654  0.570  0.668  1.0
  H  H11  1  0.515  0.099  0.668  1.0
  N  N12  1  0.636  0.864  0.250  1.0
  N  N13  1  0.114  0.386  0.250  1.0
  N  N14  1  0.364  0.136  0.750  1.0
  N  N15  1  0.886  0.614  0.750  1.0
[/CIF]
.