The structure described by U(HO)8 crystallizes in the monoclinic C2/c space group. U(1) is bonded to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms to form distorted edge-sharing UO8 hexagonal bipyramids. There are four inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(3) and one O(4) atom. In the second H site, H(2) is bonded in a distorted linear geometry to one O(3) and one O(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(1) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent U(1), one H(4), and one O(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one U(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one U(1), one H(1), and one H(2) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one H(1), one H(2), one H(3), and one H(4) atom. is represented by the CIF card [CIF]
data_U(HO)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.585
_cell_length_b   7.585
_cell_length_c   8.506
_cell_angle_alpha   60.103
_cell_angle_beta   60.103
_cell_angle_gamma   52.332
_symmetry_Int_Tables_number   1
_cell_volume   322.146
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.000  0.000  0.500  1.0
  U  U1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.772  0.706  0.818  1.0
  H  H3  1  0.294  0.228  0.682  1.0
  H  H4  1  0.228  0.294  0.182  1.0
  H  H5  1  0.706  0.772  0.318  1.0
  H  H6  1  0.770  0.706  0.630  1.0
  H  H7  1  0.294  0.230  0.870  1.0
  H  H8  1  0.230  0.294  0.370  1.0
  H  H9  1  0.706  0.770  0.130  1.0
  H  H10  1  0.676  0.513  0.574  1.0
  H  H11  1  0.487  0.324  0.926  1.0
  H  H12  1  0.324  0.487  0.426  1.0
  H  H13  1  0.513  0.676  0.074  1.0
  H  H14  1  0.474  0.760  0.605  1.0
  H  H15  1  0.240  0.526  0.895  1.0
  H  H16  1  0.526  0.240  0.395  1.0
  H  H17  1  0.760  0.474  0.105  1.0
  O  O18  1  0.054  0.817  0.807  1.0
  O  O19  1  0.183  0.946  0.693  1.0
  O  O20  1  0.946  0.183  0.193  1.0
  O  O21  1  0.817  0.054  0.307  1.0
  O  O22  1  0.734  0.244  0.582  1.0
  O  O23  1  0.756  0.266  0.918  1.0
  O  O24  1  0.266  0.756  0.418  1.0
  O  O25  1  0.244  0.734  0.082  1.0
  O  O26  1  0.831  0.750  0.678  1.0
  O  O27  1  0.250  0.169  0.822  1.0
  O  O28  1  0.169  0.250  0.322  1.0
  O  O29  1  0.750  0.831  0.178  1.0
  O  O30  1  0.642  0.670  0.549  1.0
  O  O31  1  0.330  0.358  0.951  1.0
  O  O32  1  0.358  0.330  0.451  1.0
  O  O33  1  0.670  0.642  0.049  1.0
[/CIF]
.
The structure described by U(HO)8 crystallizes in the monoclinic C2/c space group. U(1) is bonded to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms to form distorted edge-sharing UO8 hexagonal bipyramids. There are four inequivalent H sites. In the first H site, H(1) is bonded in a distorted linear geometry to one O(3) and one O(4) atom. In the second H site, H(2) is bonded in a distorted linear geometry to one O(3) and one O(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(1) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent U(1), one H(4), and one O(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one U(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one U(1), one H(1), and one H(2) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one H(1), one H(2), one H(3), and one H(4) atom. is represented by the CIF card [CIF]
data_U(HO)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.585
_cell_length_b   7.585
_cell_length_c   8.506
_cell_angle_alpha   60.103
_cell_angle_beta   60.103
_cell_angle_gamma   52.332
_symmetry_Int_Tables_number   1
_cell_volume   322.146
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.000  0.000  0.500  1.0
  U  U1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.772  0.706  0.818  1.0
  H  H3  1  0.294  0.228  0.682  1.0
  H  H4  1  0.228  0.294  0.182  1.0
  H  H5  1  0.706  0.772  0.318  1.0
  H  H6  1  0.770  0.706  0.630  1.0
  H  H7  1  0.294  0.230  0.870  1.0
  H  H8  1  0.230  0.294  0.370  1.0
  H  H9  1  0.706  0.770  0.130  1.0
  H  H10  1  0.676  0.513  0.574  1.0
  H  H11  1  0.487  0.324  0.926  1.0
  H  H12  1  0.324  0.487  0.426  1.0
  H  H13  1  0.513  0.676  0.074  1.0
  H  H14  1  0.474  0.760  0.605  1.0
  H  H15  1  0.240  0.526  0.895  1.0
  H  H16  1  0.526  0.240  0.395  1.0
  H  H17  1  0.760  0.474  0.105  1.0
  O  O18  1  0.054  0.817  0.807  1.0
  O  O19  1  0.183  0.946  0.693  1.0
  O  O20  1  0.946  0.183  0.193  1.0
  O  O21  1  0.817  0.054  0.307  1.0
  O  O22  1  0.734  0.244  0.582  1.0
  O  O23  1  0.756  0.266  0.918  1.0
  O  O24  1  0.266  0.756  0.418  1.0
  O  O25  1  0.244  0.734  0.082  1.0
  O  O26  1  0.831  0.750  0.678  1.0
  O  O27  1  0.250  0.169  0.822  1.0
  O  O28  1  0.169  0.250  0.322  1.0
  O  O29  1  0.750  0.831  0.178  1.0
  O  O30  1  0.642  0.670  0.549  1.0
  O  O31  1  0.330  0.358  0.951  1.0
  O  O32  1  0.358  0.330  0.451  1.0
  O  O33  1  0.670  0.642  0.049  1.0
[/CIF]
.