The material structure described by Os(SeCl6)2 is Indium-like structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of eight Os(SeCl6)2 clusters. Os(1) is bonded in an octahedral geometry to two equivalent Cl(3), two equivalent Cl(4), and two equivalent Cl(6) atoms. Se(1) is bonded in a 3-coordinate geometry to one Cl(1), one Cl(2), one Cl(4), one Cl(5), and one Cl(6) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Os(1) atom. In the fourth Cl site, Cl(4) is bonded in a distorted water-like geometry to one Os(1) and one Se(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Se(1) atom. In the sixth Cl site, Cl(6) is bonded in a water-like geometry to one Os(1) and one Se(1) atom. is represented by the CIF card [CIF]
data_Os(SeCl6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.789
_cell_length_b   12.613
_cell_length_c   8.950
_cell_angle_alpha   70.428
_cell_angle_beta   68.319
_cell_angle_gamma   41.252
_symmetry_Int_Tables_number   1
_cell_volume   880.820
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.835  0.835  0.665  1.0
  Os  Os1  1  0.585  0.585  0.415  1.0
  Se  Se2  1  0.028  0.476  0.015  1.0
  Se  Se3  1  0.235  0.769  0.222  1.0
  Se  Se4  1  0.769  0.235  0.774  1.0
  Se  Se5  1  0.476  0.028  0.481  1.0
  Cl  Cl6  1  0.358  0.795  0.990  1.0
  Cl  Cl7  1  0.995  0.021  0.215  1.0
  Cl  Cl8  1  0.693  0.624  0.156  1.0
  Cl  Cl9  1  0.260  0.393  0.892  1.0
  Cl  Cl10  1  0.575  0.942  0.774  1.0
  Cl  Cl11  1  0.722  0.094  0.626  1.0
  Cl  Cl12  1  0.648  0.209  0.016  1.0
  Cl  Cl13  1  0.324  0.840  0.379  1.0
  Cl  Cl14  1  0.393  0.260  0.455  1.0
  Cl  Cl15  1  0.481  0.035  0.229  1.0
  Cl  Cl16  1  0.871  0.793  0.926  1.0
  Cl  Cl17  1  0.542  0.476  0.308  1.0
  Cl  Cl18  1  0.122  0.234  0.041  1.0
  Cl  Cl19  1  0.209  0.648  0.128  1.0
  Cl  Cl20  1  0.094  0.722  0.557  1.0
  Cl  Cl21  1  0.793  0.871  0.410  1.0
  Cl  Cl22  1  0.035  0.481  0.255  1.0
  Cl  Cl23  1  0.942  0.575  0.708  1.0
  Cl  Cl24  1  0.476  0.542  0.675  1.0
  Cl  Cl25  1  0.840  0.324  0.457  1.0
  Cl  Cl26  1  0.624  0.693  0.528  1.0
  Cl  Cl27  1  0.795  0.358  0.857  1.0
  Cl  Cl28  1  0.021  0.995  0.769  1.0
  Cl  Cl29  1  0.234  0.122  0.602  1.0
[/CIF]
.
The material structure described by Os(SeCl6)2 is Indium-like structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of eight Os(SeCl6)2 clusters. Os(1) is bonded in an octahedral geometry to two equivalent Cl(3), two equivalent Cl(4), and two equivalent Cl(6) atoms. Se(1) is bonded in a 3-coordinate geometry to one Cl(1), one Cl(2), one Cl(4), one Cl(5), and one Cl(6) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Os(1) atom. In the fourth Cl site, Cl(4) is bonded in a distorted water-like geometry to one Os(1) and one Se(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Se(1) atom. In the sixth Cl site, Cl(6) is bonded in a water-like geometry to one Os(1) and one Se(1) atom. is represented by the CIF card [CIF]
data_Os(SeCl6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.789
_cell_length_b   12.613
_cell_length_c   8.950
_cell_angle_alpha   70.428
_cell_angle_beta   68.319
_cell_angle_gamma   41.252
_symmetry_Int_Tables_number   1
_cell_volume   880.820
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.835  0.835  0.665  1.0
  Os  Os1  1  0.585  0.585  0.415  1.0
  Se  Se2  1  0.028  0.476  0.015  1.0
  Se  Se3  1  0.235  0.769  0.222  1.0
  Se  Se4  1  0.769  0.235  0.774  1.0
  Se  Se5  1  0.476  0.028  0.481  1.0
  Cl  Cl6  1  0.358  0.795  0.990  1.0
  Cl  Cl7  1  0.995  0.021  0.215  1.0
  Cl  Cl8  1  0.693  0.624  0.156  1.0
  Cl  Cl9  1  0.260  0.393  0.892  1.0
  Cl  Cl10  1  0.575  0.942  0.774  1.0
  Cl  Cl11  1  0.722  0.094  0.626  1.0
  Cl  Cl12  1  0.648  0.209  0.016  1.0
  Cl  Cl13  1  0.324  0.840  0.379  1.0
  Cl  Cl14  1  0.393  0.260  0.455  1.0
  Cl  Cl15  1  0.481  0.035  0.229  1.0
  Cl  Cl16  1  0.871  0.793  0.926  1.0
  Cl  Cl17  1  0.542  0.476  0.308  1.0
  Cl  Cl18  1  0.122  0.234  0.041  1.0
  Cl  Cl19  1  0.209  0.648  0.128  1.0
  Cl  Cl20  1  0.094  0.722  0.557  1.0
  Cl  Cl21  1  0.793  0.871  0.410  1.0
  Cl  Cl22  1  0.035  0.481  0.255  1.0
  Cl  Cl23  1  0.942  0.575  0.708  1.0
  Cl  Cl24  1  0.476  0.542  0.675  1.0
  Cl  Cl25  1  0.840  0.324  0.457  1.0
  Cl  Cl26  1  0.624  0.693  0.528  1.0
  Cl  Cl27  1  0.795  0.358  0.857  1.0
  Cl  Cl28  1  0.021  0.995  0.769  1.0
  Cl  Cl29  1  0.234  0.122  0.602  1.0
[/CIF]
.