The crystal structure described by TbCo2In crystallizes in the orthorhombic Pmma space group. Tb(1) is bonded in a 13-coordinate geometry to three equivalent Co(1), four equivalent Co(2), and six equivalent In(1) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 9-coordinate geometry to three equivalent Tb(1), four equivalent Co(2), and two equivalent In(1) atoms. In the second Co site, Co(2) is bonded to four equivalent Tb(1), two equivalent Co(2), four equivalent Co(1), and two equivalent In(1) atoms to form a mixture of edge, face, and corner-sharing CoTb4In2Co6 cuboctahedra. In(1) is bonded in a 12-coordinate geometry to six equivalent Tb(1), two equivalent Co(1), two equivalent Co(2), and two equivalent In(1) atoms. is represented by the CIF card [CIF]
data_TbInCo2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.027
_cell_length_b   5.044
_cell_length_c   7.163
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   145.487
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.500  0.750  0.279  1.0
  Tb  Tb1  1  0.500  0.250  0.721  1.0
  In  In2  1  0.000  0.750  0.651  1.0
  In  In3  1  0.000  0.250  0.349  1.0
  Co  Co4  1  0.500  0.250  0.089  1.0
  Co  Co5  1  0.500  0.750  0.911  1.0
  Co  Co6  1  0.000  0.500  0.000  1.0
  Co  Co7  1  0.000  0.000  0.000  1.0
[/CIF]
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The crystal structure described by TbCo2In crystallizes in the orthorhombic Pmma space group. Tb(1) is bonded in a 13-coordinate geometry to three equivalent Co(1), four equivalent Co(2), and six equivalent In(1) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 9-coordinate geometry to three equivalent Tb(1), four equivalent Co(2), and two equivalent In(1) atoms. In the second Co site, Co(2) is bonded to four equivalent Tb(1), two equivalent Co(2), four equivalent Co(1), and two equivalent In(1) atoms to form a mixture of edge, face, and corner-sharing CoTb4In2Co6 cuboctahedra. In(1) is bonded in a 12-coordinate geometry to six equivalent Tb(1), two equivalent Co(1), two equivalent Co(2), and two equivalent In(1) atoms. is represented by the CIF card [CIF]
data_TbInCo2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.027
_cell_length_b   5.044
_cell_length_c   7.163
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   145.487
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.500  0.750  0.279  1.0
  Tb  Tb1  1  0.500  0.250  0.721  1.0
  In  In2  1  0.000  0.750  0.651  1.0
  In  In3  1  0.000  0.250  0.349  1.0
  Co  Co4  1  0.500  0.250  0.089  1.0
  Co  Co5  1  0.500  0.750  0.911  1.0
  Co  Co6  1  0.000  0.500  0.000  1.0
  Co  Co7  1  0.000  0.000  0.000  1.0
[/CIF]
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