The material structure described by (V(O3Cl)2)2Cl2 is Tungsten Carbide structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two V(O3Cl)2 clusters. In each V(O3Cl)2 cluster, V(1) is bonded in a distorted octahedral geometry to two equivalent O(2), two equivalent O(3), and two equivalent Cl(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cl(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one V(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one V(1) atom. Cl(2) is bonded in a distorted L-shaped geometry to one V(1) and one O(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.301
_cell_length_b   5.638
_cell_length_c   11.043
_cell_angle_alpha   90.000
_cell_angle_beta   92.581
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   329.718
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.500  0.500  1.0
  V  V1  1  0.000  0.000  0.000  1.0
  Cl  Cl2  1  0.500  0.500  0.000  1.0
  Cl  Cl3  1  0.500  0.000  0.500  1.0
  Cl  Cl4  1  0.289  0.556  0.673  1.0
  Cl  Cl5  1  0.711  0.056  0.827  1.0
  Cl  Cl6  1  0.711  0.444  0.327  1.0
  Cl  Cl7  1  0.289  0.944  0.173  1.0
  O  O8  1  0.767  0.468  0.814  1.0
  O  O9  1  0.233  0.968  0.686  1.0
  O  O10  1  0.233  0.532  0.186  1.0
  O  O11  1  0.767  0.032  0.314  1.0
  O  O12  1  0.235  0.346  0.412  1.0
  O  O13  1  0.765  0.846  0.088  1.0
  O  O14  1  0.765  0.654  0.588  1.0
  O  O15  1  0.235  0.154  0.912  1.0
  O  O16  1  0.918  0.215  0.566  1.0
  O  O17  1  0.082  0.715  0.934  1.0
  O  O18  1  0.082  0.785  0.434  1.0
  O  O19  1  0.918  0.285  0.066  1.0
[/CIF]
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The material structure described by (V(O3Cl)2)2Cl2 is Tungsten Carbide structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two V(O3Cl)2 clusters. In each V(O3Cl)2 cluster, V(1) is bonded in a distorted octahedral geometry to two equivalent O(2), two equivalent O(3), and two equivalent Cl(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cl(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one V(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one V(1) atom. Cl(2) is bonded in a distorted L-shaped geometry to one V(1) and one O(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.301
_cell_length_b   5.638
_cell_length_c   11.043
_cell_angle_alpha   90.000
_cell_angle_beta   92.581
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   329.718
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.500  0.500  1.0
  V  V1  1  0.000  0.000  0.000  1.0
  Cl  Cl2  1  0.500  0.500  0.000  1.0
  Cl  Cl3  1  0.500  0.000  0.500  1.0
  Cl  Cl4  1  0.289  0.556  0.673  1.0
  Cl  Cl5  1  0.711  0.056  0.827  1.0
  Cl  Cl6  1  0.711  0.444  0.327  1.0
  Cl  Cl7  1  0.289  0.944  0.173  1.0
  O  O8  1  0.767  0.468  0.814  1.0
  O  O9  1  0.233  0.968  0.686  1.0
  O  O10  1  0.233  0.532  0.186  1.0
  O  O11  1  0.767  0.032  0.314  1.0
  O  O12  1  0.235  0.346  0.412  1.0
  O  O13  1  0.765  0.846  0.088  1.0
  O  O14  1  0.765  0.654  0.588  1.0
  O  O15  1  0.235  0.154  0.912  1.0
  O  O16  1  0.918  0.215  0.566  1.0
  O  O17  1  0.082  0.715  0.934  1.0
  O  O18  1  0.082  0.785  0.434  1.0
  O  O19  1  0.918  0.285  0.066  1.0
[/CIF]
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