The structure described by (WTeO6)4(N2)2(O2)3 crystallizes in the orthorhombic Imm2 space group. The structure consists of four ammonia atoms and two trioxidane molecules inside a WTeO6 framework. In the WTeO6 framework, W(1) is bonded to one O(5), one O(8), two equivalent O(3), and two equivalent O(6) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-39°. Te(1) is bonded to one O(1), one O(4), two equivalent O(3), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-43°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Te(1) atoms. In the second O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the third O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent Te(1) atoms. In the fourth O site, O(5) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the fifth O site, O(6) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the sixth O site, O(8) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. is represented by the CIF card [CIF]
data_Te2W2N2O15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.343
_cell_length_b   7.343
_cell_length_c   7.343
_cell_angle_alpha   120.081
_cell_angle_beta   119.492
_cell_angle_gamma   90.371
_symmetry_Int_Tables_number   1
_cell_volume   280.870
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.785  0.536  0.751  1.0
  Te  Te1  1  0.785  0.035  0.249  1.0
  W  W2  1  0.284  0.534  0.750  1.0
  W  W3  1  0.784  0.534  0.250  1.0
  N  N4  1  0.713  0.006  0.707  1.0
  N  N5  1  0.299  0.006  0.293  1.0
  O  O6  1  0.856  0.856  0.000  1.0
  O  O7  1  0.232  0.232  0.000  1.0
  O  O8  1  0.846  0.846  0.372  1.0
  O  O9  1  0.474  0.474  0.628  1.0
  O  O10  1  0.474  0.846  0.000  1.0
  O  O11  1  0.846  0.474  1.000  1.0
  O  O12  1  0.717  0.217  0.500  1.0
  O  O13  1  0.088  0.588  0.500  1.0
  O  O14  1  0.716  0.221  0.124  1.0
  O  O15  1  0.097  0.592  0.876  1.0
  O  O16  1  0.097  0.221  0.505  1.0
  O  O17  1  0.716  0.592  0.495  1.0
  O  O18  1  0.168  0.018  0.850  1.0
  O  O19  1  0.168  0.318  0.150  1.0
  O  O20  1  0.479  0.479  0.000  1.0
[/CIF]
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The structure described by (WTeO6)4(N2)2(O2)3 crystallizes in the orthorhombic Imm2 space group. The structure consists of four ammonia atoms and two trioxidane molecules inside a WTeO6 framework. In the WTeO6 framework, W(1) is bonded to one O(5), one O(8), two equivalent O(3), and two equivalent O(6) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-39°. Te(1) is bonded to one O(1), one O(4), two equivalent O(3), and two equivalent O(6) atoms to form TeO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-43°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Te(1) atoms. In the second O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the third O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent Te(1) atoms. In the fourth O site, O(5) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the fifth O site, O(6) is bonded in a bent 150 degrees geometry to one W(1) and one Te(1) atom. In the sixth O site, O(8) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. is represented by the CIF card [CIF]
data_Te2W2N2O15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.343
_cell_length_b   7.343
_cell_length_c   7.343
_cell_angle_alpha   120.081
_cell_angle_beta   119.492
_cell_angle_gamma   90.371
_symmetry_Int_Tables_number   1
_cell_volume   280.870
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.785  0.536  0.751  1.0
  Te  Te1  1  0.785  0.035  0.249  1.0
  W  W2  1  0.284  0.534  0.750  1.0
  W  W3  1  0.784  0.534  0.250  1.0
  N  N4  1  0.713  0.006  0.707  1.0
  N  N5  1  0.299  0.006  0.293  1.0
  O  O6  1  0.856  0.856  0.000  1.0
  O  O7  1  0.232  0.232  0.000  1.0
  O  O8  1  0.846  0.846  0.372  1.0
  O  O9  1  0.474  0.474  0.628  1.0
  O  O10  1  0.474  0.846  0.000  1.0
  O  O11  1  0.846  0.474  1.000  1.0
  O  O12  1  0.717  0.217  0.500  1.0
  O  O13  1  0.088  0.588  0.500  1.0
  O  O14  1  0.716  0.221  0.124  1.0
  O  O15  1  0.097  0.592  0.876  1.0
  O  O16  1  0.097  0.221  0.505  1.0
  O  O17  1  0.716  0.592  0.495  1.0
  O  O18  1  0.168  0.018  0.850  1.0
  O  O19  1  0.168  0.318  0.150  1.0
  O  O20  1  0.479  0.479  0.000  1.0
[/CIF]
.