The structure described by Li3VCrP2(O4F)2 crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(5), one O(6), one O(8), and one F(1) atom to form distorted LiO4F trigonal bipyramids that share corners with two equivalent Cr(1)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, edges with two equivalent V(1)O4F2 octahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-52°. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(2), one O(6), one O(7), one F(1), and one F(2) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), one O(8), and one F(2) atom. V(1) is bonded to one O(1), one O(4), one O(5), one O(8), one F(1), and one F(2) atom to form VO4F2 octahedra that share corners with two equivalent Cr(1)O4F2 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and edges with two equivalent Li(1)O4F trigonal bipyramids. The corner-sharing octahedral tilt angles range from 57-59°. Cr(1) is bonded to one O(2), one O(3), one O(6), one O(7), one F(1), and one F(2) atom to form CrO4F2 octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent Li(1)O4F trigonal bipyramids. The corner-sharing octahedral tilt angles range from 57-59°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with two equivalent Cr(1)O4F2 octahedra, and  a cornercorner with one Li(1)O4F trigonal bipyramid. The corner-sharing octahedral tilt angles range from 35-49°. In the second P site, P(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with two equivalent Cr(1)O4F2 octahedra,  a cornercorner with one Li(1)O4F trigonal bipyramid, and  an edgeedge with one Li(1)O4F trigonal bipyramid. The corner-sharing octahedral tilt angles range from 35-50°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(3), one V(1), and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(2), one Cr(1), and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(3), one Cr(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a T-shaped geometry to one Li(3), one V(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a T-shaped geometry to one Li(1), one V(1), and one P(2) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Cr(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Li(2), one Cr(1), and one P(2) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(3), one V(1), and one P(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one V(1), and one Cr(1) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one V(1), and one Cr(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3VCrP2(O4F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.293
_cell_length_b   5.383
_cell_length_c   7.554
_cell_angle_alpha   73.581
_cell_angle_beta   70.800
_cell_angle_gamma   96.937
_symmetry_Int_Tables_number   1
_cell_volume   189.483
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.258  0.589  0.865  1.0
  Li  Li1  1  0.507  0.964  0.510  1.0
  Li  Li2  1  0.726  0.399  0.149  1.0
  V  V3  1  0.000  0.000  0.999  1.0
  Cr  Cr4  1  0.006  0.004  0.501  1.0
  P  P5  1  0.334  0.644  0.239  1.0
  P  P6  1  0.667  0.360  0.758  1.0
  O  O7  1  0.130  0.672  0.127  1.0
  O  O8  1  0.278  0.791  0.390  1.0
  O  O9  1  0.325  0.346  0.336  1.0
  O  O10  1  0.636  0.754  0.079  1.0
  O  O11  1  0.364  0.249  0.918  1.0
  O  O12  1  0.677  0.659  0.659  1.0
  O  O13  1  0.727  0.211  0.609  1.0
  O  O14  1  0.868  0.332  0.874  1.0
  F  F15  1  0.167  0.907  0.752  1.0
  F  F16  1  0.836  0.088  0.249  1.0
[/CIF]
.
The structure described by Li3VCrP2(O4F)2 crystallizes in the triclinic P1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(5), one O(6), one O(8), and one F(1) atom to form distorted LiO4F trigonal bipyramids that share corners with two equivalent Cr(1)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, edges with two equivalent V(1)O4F2 octahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-52°. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(2), one O(6), one O(7), one F(1), and one F(2) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), one O(8), and one F(2) atom. V(1) is bonded to one O(1), one O(4), one O(5), one O(8), one F(1), and one F(2) atom to form VO4F2 octahedra that share corners with two equivalent Cr(1)O4F2 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and edges with two equivalent Li(1)O4F trigonal bipyramids. The corner-sharing octahedral tilt angles range from 57-59°. Cr(1) is bonded to one O(2), one O(3), one O(6), one O(7), one F(1), and one F(2) atom to form CrO4F2 octahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent Li(1)O4F trigonal bipyramids. The corner-sharing octahedral tilt angles range from 57-59°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with two equivalent Cr(1)O4F2 octahedra, and  a cornercorner with one Li(1)O4F trigonal bipyramid. The corner-sharing octahedral tilt angles range from 35-49°. In the second P site, P(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O4F2 octahedra, corners with two equivalent Cr(1)O4F2 octahedra,  a cornercorner with one Li(1)O4F trigonal bipyramid, and  an edgeedge with one Li(1)O4F trigonal bipyramid. The corner-sharing octahedral tilt angles range from 35-50°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(3), one V(1), and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(2), one Cr(1), and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(3), one Cr(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a T-shaped geometry to one Li(3), one V(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a T-shaped geometry to one Li(1), one V(1), and one P(2) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one Li(2), one Cr(1), and one P(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Li(2), one Cr(1), and one P(2) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(3), one V(1), and one P(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one V(1), and one Cr(1) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one V(1), and one Cr(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3VCrP2(O4F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.293
_cell_length_b   5.383
_cell_length_c   7.554
_cell_angle_alpha   73.581
_cell_angle_beta   70.800
_cell_angle_gamma   96.937
_symmetry_Int_Tables_number   1
_cell_volume   189.483
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.258  0.589  0.865  1.0
  Li  Li1  1  0.507  0.964  0.510  1.0
  Li  Li2  1  0.726  0.399  0.149  1.0
  V  V3  1  0.000  0.000  0.999  1.0
  Cr  Cr4  1  0.006  0.004  0.501  1.0
  P  P5  1  0.334  0.644  0.239  1.0
  P  P6  1  0.667  0.360  0.758  1.0
  O  O7  1  0.130  0.672  0.127  1.0
  O  O8  1  0.278  0.791  0.390  1.0
  O  O9  1  0.325  0.346  0.336  1.0
  O  O10  1  0.636  0.754  0.079  1.0
  O  O11  1  0.364  0.249  0.918  1.0
  O  O12  1  0.677  0.659  0.659  1.0
  O  O13  1  0.727  0.211  0.609  1.0
  O  O14  1  0.868  0.332  0.874  1.0
  F  F15  1  0.167  0.907  0.752  1.0
  F  F16  1  0.836  0.088  0.249  1.0
[/CIF]
.