The structure described by CN2H5SnBr3 is alpha Rhenium trioxide-derived structured and crystallizes in the orthorhombic Amm2 space group. The structure consists of two iminomethanaminium molecules inside a SnBr3 framework. In the SnBr3 framework, Sn(1) is bonded to two equivalent Br(2) and four equivalent Br(1) atoms to form corner-sharing SnBr6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. There are two inequivalent Br sites. In the first Br site, Br(2) is bonded in a linear geometry to two equivalent Sn(1) atoms. In the second Br site, Br(1) is bonded in a linear geometry to two equivalent Sn(1) atoms. is represented by the CIF card [CIF]
data_SnH5CBr3N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.220
_cell_length_b   5.920
_cell_length_c   5.920
_cell_angle_alpha   92.676
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   217.725
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.500  0.367  0.633  1.0
  H  H1  1  0.798  0.729  0.271  1.0
  H  H2  1  0.202  0.729  0.271  1.0
  H  H3  1  0.679  0.914  0.086  1.0
  H  H4  1  0.321  0.914  0.086  1.0
  H  H5  1  0.000  0.047  0.953  1.0
  C  C6  1  0.000  0.919  0.081  1.0
  Br  Br7  1  0.500  0.869  0.649  1.0
  Br  Br8  1  0.500  0.351  0.131  1.0
  Br  Br9  1  0.000  0.391  0.609  1.0
  N  N10  1  0.814  0.848  0.152  1.0
  N  N11  1  0.186  0.848  0.152  1.0
[/CIF]
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The structure described by CN2H5SnBr3 is alpha Rhenium trioxide-derived structured and crystallizes in the orthorhombic Amm2 space group. The structure consists of two iminomethanaminium molecules inside a SnBr3 framework. In the SnBr3 framework, Sn(1) is bonded to two equivalent Br(2) and four equivalent Br(1) atoms to form corner-sharing SnBr6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. There are two inequivalent Br sites. In the first Br site, Br(2) is bonded in a linear geometry to two equivalent Sn(1) atoms. In the second Br site, Br(1) is bonded in a linear geometry to two equivalent Sn(1) atoms. is represented by the CIF card [CIF]
data_SnH5CBr3N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.220
_cell_length_b   5.920
_cell_length_c   5.920
_cell_angle_alpha   92.676
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   217.725
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.500  0.367  0.633  1.0
  H  H1  1  0.798  0.729  0.271  1.0
  H  H2  1  0.202  0.729  0.271  1.0
  H  H3  1  0.679  0.914  0.086  1.0
  H  H4  1  0.321  0.914  0.086  1.0
  H  H5  1  0.000  0.047  0.953  1.0
  C  C6  1  0.000  0.919  0.081  1.0
  Br  Br7  1  0.500  0.869  0.649  1.0
  Br  Br8  1  0.500  0.351  0.131  1.0
  Br  Br9  1  0.000  0.391  0.609  1.0
  N  N10  1  0.814  0.848  0.152  1.0
  N  N11  1  0.186  0.848  0.152  1.0
[/CIF]
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