The material structure described by O2BrF is Ammonia-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four O2BrF clusters. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Br(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one Br(1) atom. Br(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one F(1) atom. F(1) is bonded in a single-bond geometry to one Br(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BrO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.360
_cell_length_b   6.403
_cell_length_c   6.360
_cell_angle_alpha   48.380
_cell_angle_beta   47.809
_cell_angle_gamma   48.380
_symmetry_Int_Tables_number   1
_cell_volume   131.848
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Br  Br0  1  0.278  0.224  0.243  1.0
  Br  Br1  1  0.743  0.724  0.778  1.0
  O  O2  1  0.079  0.510  0.783  1.0
  O  O3  1  0.491  0.792  0.088  1.0
  O  O4  1  0.283  0.010  0.579  1.0
  O  O5  1  0.588  0.292  0.991  1.0
  F  F6  1  0.784  0.096  0.496  1.0
  F  F7  1  0.996  0.596  0.284  1.0
[/CIF]
.
The material structure described by O2BrF is Ammonia-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four O2BrF clusters. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Br(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one Br(1) atom. Br(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one F(1) atom. F(1) is bonded in a single-bond geometry to one Br(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BrO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.360
_cell_length_b   6.403
_cell_length_c   6.360
_cell_angle_alpha   48.380
_cell_angle_beta   47.809
_cell_angle_gamma   48.380
_symmetry_Int_Tables_number   1
_cell_volume   131.848
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Br  Br0  1  0.278  0.224  0.243  1.0
  Br  Br1  1  0.743  0.724  0.778  1.0
  O  O2  1  0.079  0.510  0.783  1.0
  O  O3  1  0.491  0.792  0.088  1.0
  O  O4  1  0.283  0.010  0.579  1.0
  O  O5  1  0.588  0.292  0.991  1.0
  F  F6  1  0.784  0.096  0.496  1.0
  F  F7  1  0.996  0.596  0.284  1.0
[/CIF]
.