The material described by Eu2Mo(WO6)2 crystallizes in the monoclinic C2/c space group. Eu(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(4), one O(6), two equivalent O(3), and two equivalent O(5) atoms. W(1) is bonded in a 5-coordinate geometry to one O(2), one O(3), one O(6), and two equivalent O(4) atoms. Mo(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(5) atoms. There are six inequivalent O sites. In the first O site, O(4) is bonded in a trigonal non-coplanar geometry to one Eu(1) and two equivalent W(1) atoms. In the second O site, O(5) is bonded in a distorted trigonal planar geometry to two equivalent Eu(1) and one Mo(1) atom. In the third O site, O(6) is bonded in a bent 150 degrees geometry to one Eu(1) and one W(1) atom. In the fourth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Eu(1) and one Mo(1) atom. In the fifth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Eu(1) and one W(1) atom. In the sixth O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Eu(1) and one W(1) atom. is represented by the CIF file [CIF]
data_Eu2Mo(WO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.094
_cell_length_b   7.094
_cell_length_c   11.629
_cell_angle_alpha   79.270
_cell_angle_beta   79.270
_cell_angle_gamma   111.810
_symmetry_Int_Tables_number   1
_cell_volume   512.570
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.193  0.444  0.095  1.0
  Eu  Eu1  1  0.556  0.807  0.405  1.0
  Eu  Eu2  1  0.807  0.556  0.905  1.0
  Eu  Eu3  1  0.444  0.193  0.595  1.0
  Mo  Mo4  1  0.620  0.380  0.250  1.0
  Mo  Mo5  1  0.380  0.620  0.750  1.0
  W  W6  1  0.007  0.299  0.454  1.0
  W  W7  1  0.701  0.993  0.046  1.0
  W  W8  1  0.993  0.701  0.546  1.0
  W  W9  1  0.299  0.007  0.954  1.0
  O  O10  1  0.515  0.100  0.279  1.0
  O  O11  1  0.900  0.485  0.221  1.0
  O  O12  1  0.485  0.900  0.721  1.0
  O  O13  1  0.100  0.515  0.779  1.0
  O  O14  1  0.896  0.827  0.439  1.0
  O  O15  1  0.173  0.104  0.061  1.0
  O  O16  1  0.104  0.173  0.561  1.0
  O  O17  1  0.827  0.896  0.939  1.0
  O  O18  1  0.725  0.127  0.462  1.0
  O  O19  1  0.873  0.275  0.038  1.0
  O  O20  1  0.275  0.873  0.538  1.0
  O  O21  1  0.127  0.725  0.962  1.0
  O  O22  1  0.401  0.827  0.075  1.0
  O  O23  1  0.173  0.599  0.425  1.0
  O  O24  1  0.599  0.173  0.925  1.0
  O  O25  1  0.827  0.401  0.575  1.0
  O  O26  1  0.555  0.476  0.113  1.0
  O  O27  1  0.524  0.445  0.387  1.0
  O  O28  1  0.445  0.524  0.887  1.0
  O  O29  1  0.476  0.555  0.613  1.0
  O  O30  1  0.140  0.293  0.305  1.0
  O  O31  1  0.707  0.860  0.195  1.0
  O  O32  1  0.860  0.707  0.695  1.0
  O  O33  1  0.293  0.140  0.805  1.0
[/CIF]
.
The material described by Eu2Mo(WO6)2 crystallizes in the monoclinic C2/c space group. Eu(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(4), one O(6), two equivalent O(3), and two equivalent O(5) atoms. W(1) is bonded in a 5-coordinate geometry to one O(2), one O(3), one O(6), and two equivalent O(4) atoms. Mo(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(5) atoms. There are six inequivalent O sites. In the first O site, O(4) is bonded in a trigonal non-coplanar geometry to one Eu(1) and two equivalent W(1) atoms. In the second O site, O(5) is bonded in a distorted trigonal planar geometry to two equivalent Eu(1) and one Mo(1) atom. In the third O site, O(6) is bonded in a bent 150 degrees geometry to one Eu(1) and one W(1) atom. In the fourth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Eu(1) and one Mo(1) atom. In the fifth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Eu(1) and one W(1) atom. In the sixth O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Eu(1) and one W(1) atom. is represented by the CIF file [CIF]
data_Eu2Mo(WO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.094
_cell_length_b   7.094
_cell_length_c   11.629
_cell_angle_alpha   79.270
_cell_angle_beta   79.270
_cell_angle_gamma   111.810
_symmetry_Int_Tables_number   1
_cell_volume   512.570
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Eu  Eu0  1  0.193  0.444  0.095  1.0
  Eu  Eu1  1  0.556  0.807  0.405  1.0
  Eu  Eu2  1  0.807  0.556  0.905  1.0
  Eu  Eu3  1  0.444  0.193  0.595  1.0
  Mo  Mo4  1  0.620  0.380  0.250  1.0
  Mo  Mo5  1  0.380  0.620  0.750  1.0
  W  W6  1  0.007  0.299  0.454  1.0
  W  W7  1  0.701  0.993  0.046  1.0
  W  W8  1  0.993  0.701  0.546  1.0
  W  W9  1  0.299  0.007  0.954  1.0
  O  O10  1  0.515  0.100  0.279  1.0
  O  O11  1  0.900  0.485  0.221  1.0
  O  O12  1  0.485  0.900  0.721  1.0
  O  O13  1  0.100  0.515  0.779  1.0
  O  O14  1  0.896  0.827  0.439  1.0
  O  O15  1  0.173  0.104  0.061  1.0
  O  O16  1  0.104  0.173  0.561  1.0
  O  O17  1  0.827  0.896  0.939  1.0
  O  O18  1  0.725  0.127  0.462  1.0
  O  O19  1  0.873  0.275  0.038  1.0
  O  O20  1  0.275  0.873  0.538  1.0
  O  O21  1  0.127  0.725  0.962  1.0
  O  O22  1  0.401  0.827  0.075  1.0
  O  O23  1  0.173  0.599  0.425  1.0
  O  O24  1  0.599  0.173  0.925  1.0
  O  O25  1  0.827  0.401  0.575  1.0
  O  O26  1  0.555  0.476  0.113  1.0
  O  O27  1  0.524  0.445  0.387  1.0
  O  O28  1  0.445  0.524  0.887  1.0
  O  O29  1  0.476  0.555  0.613  1.0
  O  O30  1  0.140  0.293  0.305  1.0
  O  O31  1  0.707  0.860  0.195  1.0
  O  O32  1  0.860  0.707  0.695  1.0
  O  O33  1  0.293  0.140  0.805  1.0
[/CIF]
.