The material described by WMoZn2O6 crystallizes in the trigonal R3 space group. W(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form WO6 octahedra that share corners with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles are 42°. Mo(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form MoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 42°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal planar geometry to three equivalent O(2) atoms. In the second Zn site, Zn(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent O(1) and three equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1), one Mo(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one W(1), one Mo(1), one Zn(1), and one Zn(2) atom. is represented by the CIF file [CIF]
data_Zn2MoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.690
_cell_length_b   5.690
_cell_length_c   5.690
_cell_angle_alpha   56.111
_cell_angle_beta   56.111
_cell_angle_gamma   56.111
_symmetry_Int_Tables_number   1
_cell_volume   118.541
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.266  0.266  0.266  1.0
  Zn  Zn1  1  0.775  0.775  0.775  1.0
  Mo  Mo2  1  0.498  0.498  0.498  1.0
  W  W3  1  0.999  0.999  0.999  1.0
  O  O4  1  0.098  0.753  0.378  1.0
  O  O5  1  0.901  0.217  0.621  1.0
  O  O6  1  0.753  0.378  0.098  1.0
  O  O7  1  0.378  0.098  0.753  1.0
  O  O8  1  0.621  0.901  0.217  1.0
  O  O9  1  0.217  0.621  0.901  1.0
[/CIF]
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The material described by WMoZn2O6 crystallizes in the trigonal R3 space group. W(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form WO6 octahedra that share corners with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles are 42°. Mo(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form MoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 42°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal planar geometry to three equivalent O(2) atoms. In the second Zn site, Zn(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent O(1) and three equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1), one Mo(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one W(1), one Mo(1), one Zn(1), and one Zn(2) atom. is represented by the CIF file [CIF]
data_Zn2MoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.690
_cell_length_b   5.690
_cell_length_c   5.690
_cell_angle_alpha   56.111
_cell_angle_beta   56.111
_cell_angle_gamma   56.111
_symmetry_Int_Tables_number   1
_cell_volume   118.541
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.266  0.266  0.266  1.0
  Zn  Zn1  1  0.775  0.775  0.775  1.0
  Mo  Mo2  1  0.498  0.498  0.498  1.0
  W  W3  1  0.999  0.999  0.999  1.0
  O  O4  1  0.098  0.753  0.378  1.0
  O  O5  1  0.901  0.217  0.621  1.0
  O  O6  1  0.753  0.378  0.098  1.0
  O  O7  1  0.378  0.098  0.753  1.0
  O  O8  1  0.621  0.901  0.217  1.0
  O  O9  1  0.217  0.621  0.901  1.0
[/CIF]
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