The structure described by CN3(CN3Br)2Bi2Br7 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of four bromoguanidine molecules, two diaziridinimine molecules, and two Bi2Br7 clusters. In each Bi2Br7 cluster, Bi(1) is bonded to one Br(1), one Br(2), one Br(3), one Br(5), and one Br(6) atom to form distorted face-sharing BiBr5 square pyramids. There are five inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to two equivalent Bi(1) atoms. In the second Br site, Br(2) is bonded in an L-shaped geometry to two equivalent Bi(1) atoms. In the third Br site, Br(3) is bonded in a single-bond geometry to one Bi(1) atom. In the fourth Br site, Br(5) is bonded in a single-bond geometry to one Bi(1) atom. In the fifth Br site, Br(6) is bonded in an L-shaped geometry to two equivalent Bi(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Bi2C3(BrN)9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   20.642
_cell_length_b   7.755
_cell_length_c   8.519
_cell_angle_alpha   73.995
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1310.748
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.345  0.845  0.209  1.0
  Bi  Bi1  1  0.845  0.155  0.791  1.0
  Bi  Bi2  1  0.655  0.155  0.791  1.0
  Bi  Bi3  1  0.155  0.845  0.209  1.0
  C  C4  1  0.587  0.691  0.376  1.0
  C  C5  1  0.087  0.309  0.624  1.0
  C  C6  1  0.413  0.309  0.624  1.0
  C  C7  1  0.913  0.691  0.376  1.0
  C  C8  1  0.250  0.384  0.888  1.0
  C  C9  1  0.750  0.616  0.112  1.0
  Br  Br10  1  0.250  0.535  0.337  1.0
  Br  Br11  1  0.750  0.465  0.663  1.0
  Br  Br12  1  0.250  0.008  0.407  1.0
  Br  Br13  1  0.750  0.992  0.593  1.0
  Br  Br14  1  0.422  0.135  0.134  1.0
  Br  Br15  1  0.922  0.865  0.866  1.0
  Br  Br16  1  0.578  0.865  0.866  1.0
  Br  Br17  1  0.078  0.135  0.134  1.0
  Br  Br18  1  0.413  0.677  0.597  1.0
  Br  Br19  1  0.913  0.323  0.403  1.0
  Br  Br20  1  0.587  0.323  0.403  1.0
  Br  Br21  1  0.087  0.677  0.597  1.0
  Br  Br22  1  0.418  0.655  0.058  1.0
  Br  Br23  1  0.918  0.345  0.942  1.0
  Br  Br24  1  0.582  0.345  0.942  1.0
  Br  Br25  1  0.082  0.655  0.058  1.0
  Br  Br26  1  0.250  0.933  0.954  1.0
  Br  Br27  1  0.750  0.067  0.046  1.0
  N  N28  1  0.579  0.565  0.285  1.0
  N  N29  1  0.079  0.435  0.715  1.0
  N  N30  1  0.421  0.435  0.715  1.0
  N  N31  1  0.921  0.565  0.285  1.0
  N  N32  1  0.600  0.635  0.536  1.0
  N  N33  1  0.100  0.365  0.464  1.0
  N  N34  1  0.400  0.365  0.464  1.0
  N  N35  1  0.900  0.635  0.536  1.0
  N  N36  1  0.582  0.862  0.288  1.0
  N  N37  1  0.082  0.138  0.712  1.0
  N  N38  1  0.418  0.138  0.712  1.0
  N  N39  1  0.918  0.862  0.288  1.0
  N  N40  1  0.250  0.517  0.720  1.0
  N  N41  1  0.750  0.483  0.280  1.0
  N  N42  1  0.250  0.355  0.727  1.0
  N  N43  1  0.750  0.645  0.273  1.0
  N  N44  1  0.250  0.341  0.035  1.0
  N  N45  1  0.750  0.659  0.965  1.0
[/CIF]
.
The structure described by CN3(CN3Br)2Bi2Br7 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of four bromoguanidine molecules, two diaziridinimine molecules, and two Bi2Br7 clusters. In each Bi2Br7 cluster, Bi(1) is bonded to one Br(1), one Br(2), one Br(3), one Br(5), and one Br(6) atom to form distorted face-sharing BiBr5 square pyramids. There are five inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to two equivalent Bi(1) atoms. In the second Br site, Br(2) is bonded in an L-shaped geometry to two equivalent Bi(1) atoms. In the third Br site, Br(3) is bonded in a single-bond geometry to one Bi(1) atom. In the fourth Br site, Br(5) is bonded in a single-bond geometry to one Bi(1) atom. In the fifth Br site, Br(6) is bonded in an L-shaped geometry to two equivalent Bi(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Bi2C3(BrN)9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   20.642
_cell_length_b   7.755
_cell_length_c   8.519
_cell_angle_alpha   73.995
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1310.748
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.345  0.845  0.209  1.0
  Bi  Bi1  1  0.845  0.155  0.791  1.0
  Bi  Bi2  1  0.655  0.155  0.791  1.0
  Bi  Bi3  1  0.155  0.845  0.209  1.0
  C  C4  1  0.587  0.691  0.376  1.0
  C  C5  1  0.087  0.309  0.624  1.0
  C  C6  1  0.413  0.309  0.624  1.0
  C  C7  1  0.913  0.691  0.376  1.0
  C  C8  1  0.250  0.384  0.888  1.0
  C  C9  1  0.750  0.616  0.112  1.0
  Br  Br10  1  0.250  0.535  0.337  1.0
  Br  Br11  1  0.750  0.465  0.663  1.0
  Br  Br12  1  0.250  0.008  0.407  1.0
  Br  Br13  1  0.750  0.992  0.593  1.0
  Br  Br14  1  0.422  0.135  0.134  1.0
  Br  Br15  1  0.922  0.865  0.866  1.0
  Br  Br16  1  0.578  0.865  0.866  1.0
  Br  Br17  1  0.078  0.135  0.134  1.0
  Br  Br18  1  0.413  0.677  0.597  1.0
  Br  Br19  1  0.913  0.323  0.403  1.0
  Br  Br20  1  0.587  0.323  0.403  1.0
  Br  Br21  1  0.087  0.677  0.597  1.0
  Br  Br22  1  0.418  0.655  0.058  1.0
  Br  Br23  1  0.918  0.345  0.942  1.0
  Br  Br24  1  0.582  0.345  0.942  1.0
  Br  Br25  1  0.082  0.655  0.058  1.0
  Br  Br26  1  0.250  0.933  0.954  1.0
  Br  Br27  1  0.750  0.067  0.046  1.0
  N  N28  1  0.579  0.565  0.285  1.0
  N  N29  1  0.079  0.435  0.715  1.0
  N  N30  1  0.421  0.435  0.715  1.0
  N  N31  1  0.921  0.565  0.285  1.0
  N  N32  1  0.600  0.635  0.536  1.0
  N  N33  1  0.100  0.365  0.464  1.0
  N  N34  1  0.400  0.365  0.464  1.0
  N  N35  1  0.900  0.635  0.536  1.0
  N  N36  1  0.582  0.862  0.288  1.0
  N  N37  1  0.082  0.138  0.712  1.0
  N  N38  1  0.418  0.138  0.712  1.0
  N  N39  1  0.918  0.862  0.288  1.0
  N  N40  1  0.250  0.517  0.720  1.0
  N  N41  1  0.750  0.483  0.280  1.0
  N  N42  1  0.250  0.355  0.727  1.0
  N  N43  1  0.750  0.645  0.273  1.0
  N  N44  1  0.250  0.341  0.035  1.0
  N  N45  1  0.750  0.659  0.965  1.0
[/CIF]
.