The crystal structure described by V2O3F is Hydrophilite-derived structured and crystallizes in the monoclinic C2 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(4), one O(5), one F(1), and one F(2) atom to form VO4F2 octahedra that share corners with three equivalent V(4)O5F octahedra, corners with five equivalent V(2)O5F octahedra,  an edgeedge with one V(1)O4F2 octahedra, and  an edgeedge with one V(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. In the second V site, V(2) is bonded to one O(1), one O(3), one O(4), two equivalent O(2), and one F(1) atom to form distorted VO5F octahedra that share corners with three equivalent V(3)O4F2 octahedra, corners with five equivalent V(1)O4F2 octahedra,  an edgeedge with one V(2)O5F octahedra, and  an edgeedge with one V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-52°. In the third V site, V(3) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with two equivalent V(4)O5F octahedra, corners with six equivalent V(2)O5F octahedra, and edges with two equivalent V(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. In the fourth V site, V(4) is bonded to one O(5), two equivalent O(1), two equivalent O(3), and one F(2) atom to form distorted VO5F octahedra that share corners with two equivalent V(3)O4F2 octahedra, corners with six equivalent V(1)O4F2 octahedra, and edges with two equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 48-52°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent V(2) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(4) and two equivalent V(1) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a distorted trigonal planar geometry to one V(4) and two equivalent V(1) atoms. In the second F site, F(1) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2O3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.467
_cell_length_b   5.467
_cell_length_c   6.942
_cell_angle_alpha   73.378
_cell_angle_beta   73.378
_cell_angle_gamma   75.173
_symmetry_Int_Tables_number   1
_cell_volume   187.043
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.673  0.663  0.835  1.0
  V  V1  1  0.301  0.371  0.666  1.0
  V  V2  1  0.629  0.699  0.334  1.0
  V  V3  1  0.337  0.327  0.165  1.0
  V  V4  1  0.007  0.993  0.500  1.0
  V  V5  1  0.044  0.956  0.000  1.0
  O  O6  1  0.235  0.228  0.963  1.0
  O  O7  1  0.572  0.563  0.631  1.0
  O  O8  1  0.893  0.904  0.298  1.0
  O  O9  1  0.096  0.107  0.702  1.0
  O  O10  1  0.772  0.765  0.037  1.0
  O  O11  1  0.437  0.428  0.369  1.0
  O  O12  1  0.032  0.643  0.666  1.0
  O  O13  1  0.357  0.968  0.334  1.0
  O  O14  1  0.312  0.688  0.000  1.0
  F  F15  1  0.629  0.034  0.668  1.0
  F  F16  1  0.966  0.371  0.332  1.0
  F  F17  1  0.708  0.292  0.000  1.0
[/CIF]
.
The crystal structure described by V2O3F is Hydrophilite-derived structured and crystallizes in the monoclinic C2 space group. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(4), one O(5), one F(1), and one F(2) atom to form VO4F2 octahedra that share corners with three equivalent V(4)O5F octahedra, corners with five equivalent V(2)O5F octahedra,  an edgeedge with one V(1)O4F2 octahedra, and  an edgeedge with one V(3)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. In the second V site, V(2) is bonded to one O(1), one O(3), one O(4), two equivalent O(2), and one F(1) atom to form distorted VO5F octahedra that share corners with three equivalent V(3)O4F2 octahedra, corners with five equivalent V(1)O4F2 octahedra,  an edgeedge with one V(2)O5F octahedra, and  an edgeedge with one V(4)O5F octahedra. The corner-sharing octahedral tilt angles range from 46-52°. In the third V site, V(3) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent F(1) atoms to form VO4F2 octahedra that share corners with two equivalent V(4)O5F octahedra, corners with six equivalent V(2)O5F octahedra, and edges with two equivalent V(1)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 48-52°. In the fourth V site, V(4) is bonded to one O(5), two equivalent O(1), two equivalent O(3), and one F(2) atom to form distorted VO5F octahedra that share corners with two equivalent V(3)O4F2 octahedra, corners with six equivalent V(1)O4F2 octahedra, and edges with two equivalent V(2)O5F octahedra. The corner-sharing octahedral tilt angles range from 48-52°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent V(2) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(4) and two equivalent V(1) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a distorted trigonal planar geometry to one V(4) and two equivalent V(1) atoms. In the second F site, F(1) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2O3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.467
_cell_length_b   5.467
_cell_length_c   6.942
_cell_angle_alpha   73.378
_cell_angle_beta   73.378
_cell_angle_gamma   75.173
_symmetry_Int_Tables_number   1
_cell_volume   187.043
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.673  0.663  0.835  1.0
  V  V1  1  0.301  0.371  0.666  1.0
  V  V2  1  0.629  0.699  0.334  1.0
  V  V3  1  0.337  0.327  0.165  1.0
  V  V4  1  0.007  0.993  0.500  1.0
  V  V5  1  0.044  0.956  0.000  1.0
  O  O6  1  0.235  0.228  0.963  1.0
  O  O7  1  0.572  0.563  0.631  1.0
  O  O8  1  0.893  0.904  0.298  1.0
  O  O9  1  0.096  0.107  0.702  1.0
  O  O10  1  0.772  0.765  0.037  1.0
  O  O11  1  0.437  0.428  0.369  1.0
  O  O12  1  0.032  0.643  0.666  1.0
  O  O13  1  0.357  0.968  0.334  1.0
  O  O14  1  0.312  0.688  0.000  1.0
  F  F15  1  0.629  0.034  0.668  1.0
  F  F16  1  0.966  0.371  0.332  1.0
  F  F17  1  0.708  0.292  0.000  1.0
[/CIF]
.