The compound described by V2Cu3Pb(O4Cl)2 crystallizes in the orthorhombic Ibam space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) and two equivalent Cl(1) atoms. In the second Cu site, Cu(2) is bonded in a 4-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent Cl(1) atoms. Pb(1) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent Cl(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one Cu(1), and one Cu(2) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one V(1), one Cu(2), and one Pb(1) atom. Cl(1) is bonded in a 5-coordinate geometry to one Cu(1), two equivalent Cu(2), and two equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_V2Cu3Pb(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.628
_cell_length_b   8.628
_cell_length_c   8.628
_cell_angle_alpha   116.265
_cell_angle_beta   113.953
_cell_angle_gamma   98.713
_symmetry_Int_Tables_number   1
_cell_volume   481.555
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.047  0.797  0.250  1.0
  V  V1  1  0.453  0.203  0.250  1.0
  V  V2  1  0.953  0.203  0.750  1.0
  V  V3  1  0.547  0.797  0.750  1.0
  Cu  Cu4  1  0.500  0.000  0.500  1.0
  Cu  Cu5  1  0.000  0.000  0.000  1.0
  Cu  Cu6  1  0.672  0.922  0.249  1.0
  Cu  Cu7  1  0.328  0.078  0.751  1.0
  Cu  Cu8  1  0.828  0.577  0.749  1.0
  Cu  Cu9  1  0.172  0.423  0.251  1.0
  Pb  Pb10  1  0.750  0.500  0.250  1.0
  Pb  Pb11  1  0.250  0.500  0.750  1.0
  Cl  Cl12  1  0.413  0.595  0.182  1.0
  Cl  Cl13  1  0.587  0.405  0.818  1.0
  Cl  Cl14  1  0.087  0.770  0.682  1.0
  Cl  Cl15  1  0.913  0.230  0.318  1.0
  O  O16  1  0.525  0.991  0.733  1.0
  O  O17  1  0.741  0.009  0.533  1.0
  O  O18  1  0.975  0.208  0.967  1.0
  O  O19  1  0.759  0.792  0.767  1.0
  O  O20  1  0.475  0.009  0.267  1.0
  O  O21  1  0.259  0.991  0.467  1.0
  O  O22  1  0.025  0.792  0.033  1.0
  O  O23  1  0.241  0.208  0.233  1.0
  O  O24  1  0.453  0.182  0.041  1.0
  O  O25  1  0.859  0.818  0.271  1.0
  O  O26  1  0.047  0.589  0.229  1.0
  O  O27  1  0.641  0.411  0.459  1.0
  O  O28  1  0.547  0.818  0.959  1.0
  O  O29  1  0.141  0.182  0.729  1.0
  O  O30  1  0.953  0.411  0.771  1.0
  O  O31  1  0.359  0.589  0.541  1.0
[/CIF]
.
The compound described by V2Cu3Pb(O4Cl)2 crystallizes in the orthorhombic Ibam space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) and two equivalent Cl(1) atoms. In the second Cu site, Cu(2) is bonded in a 4-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent Cl(1) atoms. Pb(1) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent Cl(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one Cu(1), and one Cu(2) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one V(1), one Cu(2), and one Pb(1) atom. Cl(1) is bonded in a 5-coordinate geometry to one Cu(1), two equivalent Cu(2), and two equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_V2Cu3Pb(ClO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.628
_cell_length_b   8.628
_cell_length_c   8.628
_cell_angle_alpha   116.265
_cell_angle_beta   113.953
_cell_angle_gamma   98.713
_symmetry_Int_Tables_number   1
_cell_volume   481.555
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.047  0.797  0.250  1.0
  V  V1  1  0.453  0.203  0.250  1.0
  V  V2  1  0.953  0.203  0.750  1.0
  V  V3  1  0.547  0.797  0.750  1.0
  Cu  Cu4  1  0.500  0.000  0.500  1.0
  Cu  Cu5  1  0.000  0.000  0.000  1.0
  Cu  Cu6  1  0.672  0.922  0.249  1.0
  Cu  Cu7  1  0.328  0.078  0.751  1.0
  Cu  Cu8  1  0.828  0.577  0.749  1.0
  Cu  Cu9  1  0.172  0.423  0.251  1.0
  Pb  Pb10  1  0.750  0.500  0.250  1.0
  Pb  Pb11  1  0.250  0.500  0.750  1.0
  Cl  Cl12  1  0.413  0.595  0.182  1.0
  Cl  Cl13  1  0.587  0.405  0.818  1.0
  Cl  Cl14  1  0.087  0.770  0.682  1.0
  Cl  Cl15  1  0.913  0.230  0.318  1.0
  O  O16  1  0.525  0.991  0.733  1.0
  O  O17  1  0.741  0.009  0.533  1.0
  O  O18  1  0.975  0.208  0.967  1.0
  O  O19  1  0.759  0.792  0.767  1.0
  O  O20  1  0.475  0.009  0.267  1.0
  O  O21  1  0.259  0.991  0.467  1.0
  O  O22  1  0.025  0.792  0.033  1.0
  O  O23  1  0.241  0.208  0.233  1.0
  O  O24  1  0.453  0.182  0.041  1.0
  O  O25  1  0.859  0.818  0.271  1.0
  O  O26  1  0.047  0.589  0.229  1.0
  O  O27  1  0.641  0.411  0.459  1.0
  O  O28  1  0.547  0.818  0.959  1.0
  O  O29  1  0.141  0.182  0.729  1.0
  O  O30  1  0.953  0.411  0.771  1.0
  O  O31  1  0.359  0.589  0.541  1.0
[/CIF]
.