The material described by NaTeF5 crystallizes in the orthorhombic Pnma space group. Na(1) is bonded to one F(3), two equivalent F(1), and four equivalent F(2) atoms to form distorted NaF7 pentagonal bipyramids that share corners with five equivalent Te(1)F5 square pyramids, edges with two equivalent Na(1)F7 pentagonal bipyramids, and  an edgeedge with one Te(1)F5 square pyramid. Te(1) is bonded to one F(3), two equivalent F(1), and two equivalent F(2) atoms to form distorted TeF5 square pyramids that share corners with five equivalent Na(1)F7 pentagonal bipyramids and  an edgeedge with one Na(1)F7 pentagonal bipyramid. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Na(1) and one Te(1) atom. In the second F site, F(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Na(1) and one Te(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Na(1) and one Te(1) atom. is represented by the CIF card [CIF]
data_NaTeF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.858
_cell_length_b   7.056
_cell_length_c   10.110
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   417.832
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.250  0.322  0.998  1.0
  Na  Na1  1  0.750  0.678  0.002  1.0
  Na  Na2  1  0.750  0.822  0.502  1.0
  Na  Na3  1  0.250  0.178  0.498  1.0
  Te  Te4  1  0.250  0.847  0.765  1.0
  Te  Te5  1  0.750  0.153  0.235  1.0
  Te  Te6  1  0.750  0.347  0.735  1.0
  Te  Te7  1  0.250  0.653  0.265  1.0
  F  F8  1  0.016  0.853  0.902  1.0
  F  F9  1  0.023  0.950  0.635  1.0
  F  F10  1  0.477  0.550  0.135  1.0
  F  F11  1  0.977  0.450  0.865  1.0
  F  F12  1  0.250  0.390  0.308  1.0
  F  F13  1  0.750  0.610  0.692  1.0
  F  F14  1  0.750  0.890  0.192  1.0
  F  F15  1  0.250  0.110  0.808  1.0
  F  F16  1  0.016  0.647  0.402  1.0
  F  F17  1  0.516  0.353  0.598  1.0
  F  F18  1  0.984  0.147  0.098  1.0
  F  F19  1  0.477  0.950  0.635  1.0
  F  F20  1  0.984  0.353  0.598  1.0
  F  F21  1  0.484  0.647  0.402  1.0
  F  F22  1  0.484  0.853  0.902  1.0
  F  F23  1  0.516  0.147  0.098  1.0
  F  F24  1  0.023  0.550  0.135  1.0
  F  F25  1  0.523  0.450  0.865  1.0
  F  F26  1  0.977  0.050  0.365  1.0
  F  F27  1  0.523  0.050  0.365  1.0
[/CIF]
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The material described by NaTeF5 crystallizes in the orthorhombic Pnma space group. Na(1) is bonded to one F(3), two equivalent F(1), and four equivalent F(2) atoms to form distorted NaF7 pentagonal bipyramids that share corners with five equivalent Te(1)F5 square pyramids, edges with two equivalent Na(1)F7 pentagonal bipyramids, and  an edgeedge with one Te(1)F5 square pyramid. Te(1) is bonded to one F(3), two equivalent F(1), and two equivalent F(2) atoms to form distorted TeF5 square pyramids that share corners with five equivalent Na(1)F7 pentagonal bipyramids and  an edgeedge with one Na(1)F7 pentagonal bipyramid. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Na(1) and one Te(1) atom. In the second F site, F(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Na(1) and one Te(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Na(1) and one Te(1) atom. is represented by the CIF card [CIF]
data_NaTeF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.858
_cell_length_b   7.056
_cell_length_c   10.110
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   417.832
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.250  0.322  0.998  1.0
  Na  Na1  1  0.750  0.678  0.002  1.0
  Na  Na2  1  0.750  0.822  0.502  1.0
  Na  Na3  1  0.250  0.178  0.498  1.0
  Te  Te4  1  0.250  0.847  0.765  1.0
  Te  Te5  1  0.750  0.153  0.235  1.0
  Te  Te6  1  0.750  0.347  0.735  1.0
  Te  Te7  1  0.250  0.653  0.265  1.0
  F  F8  1  0.016  0.853  0.902  1.0
  F  F9  1  0.023  0.950  0.635  1.0
  F  F10  1  0.477  0.550  0.135  1.0
  F  F11  1  0.977  0.450  0.865  1.0
  F  F12  1  0.250  0.390  0.308  1.0
  F  F13  1  0.750  0.610  0.692  1.0
  F  F14  1  0.750  0.890  0.192  1.0
  F  F15  1  0.250  0.110  0.808  1.0
  F  F16  1  0.016  0.647  0.402  1.0
  F  F17  1  0.516  0.353  0.598  1.0
  F  F18  1  0.984  0.147  0.098  1.0
  F  F19  1  0.477  0.950  0.635  1.0
  F  F20  1  0.984  0.353  0.598  1.0
  F  F21  1  0.484  0.647  0.402  1.0
  F  F22  1  0.484  0.853  0.902  1.0
  F  F23  1  0.516  0.147  0.098  1.0
  F  F24  1  0.023  0.550  0.135  1.0
  F  F25  1  0.523  0.450  0.865  1.0
  F  F26  1  0.977  0.050  0.365  1.0
  F  F27  1  0.523  0.050  0.365  1.0
[/CIF]
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