The material structure described by Mn2Pd(NO2)4 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Mn2Pd(NO2)4 cluster. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(4), one O(5), and one O(8) atom to form MnO4 tetrahedra that share  a cornercorner with one Pd(1)N4O2 octahedra. The corner-sharing octahedral tilt angles are 56°. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(6), and one O(7) atom to form MnO4 tetrahedra that share  a cornercorner with one Pd(1)N4O2 octahedra. The corner-sharing octahedral tilt angles are 56°. Pd(1) is bonded to one N(1), one N(2), one N(3), one N(4), one O(3), and one O(8) atom to form PdN4O2 octahedra that share  a cornercorner with one Mn(1)O4 tetrahedra and  a cornercorner with one Mn(2)O4 tetrahedra. There are four inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pd(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Pd(1) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Pd(1) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one Pd(1) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mn(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Mn(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(2) and one Pd(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mn(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mn(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Mn(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Mn(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(1) and one Pd(1) atom. is represented by the CIF file [CIF]
data_Mn2Pd(NO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.184
_cell_length_b   7.335
_cell_length_c   7.150
_cell_angle_alpha   74.864
_cell_angle_beta   68.025
_cell_angle_gamma   69.674
_symmetry_Int_Tables_number   1
_cell_volume   233.737
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.049  0.646  0.635  1.0
  Mn  Mn1  1  0.969  0.004  0.021  1.0
  Pd  Pd2  1  0.509  0.326  0.327  1.0
  N  N3  1  0.644  0.571  0.284  1.0
  N  N4  1  0.403  0.425  0.060  1.0
  N  N5  1  0.613  0.227  0.595  1.0
  N  N6  1  0.372  0.084  0.368  1.0
  O  O7  1  0.136  0.794  0.118  1.0
  O  O8  1  0.357  0.654  0.630  1.0
  O  O9  1  0.909  0.180  0.161  1.0
  O  O10  1  0.860  0.588  0.865  1.0
  O  O11  1  0.881  0.857  0.540  1.0
  O  O12  1  0.159  0.061  0.791  1.0
  O  O13  1  0.660  0.996  0.027  1.0
  O  O14  1  0.109  0.472  0.493  1.0
[/CIF]
.
The material structure described by Mn2Pd(NO2)4 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Mn2Pd(NO2)4 cluster. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(2), one O(4), one O(5), and one O(8) atom to form MnO4 tetrahedra that share  a cornercorner with one Pd(1)N4O2 octahedra. The corner-sharing octahedral tilt angles are 56°. In the second Mn site, Mn(2) is bonded to one O(1), one O(3), one O(6), and one O(7) atom to form MnO4 tetrahedra that share  a cornercorner with one Pd(1)N4O2 octahedra. The corner-sharing octahedral tilt angles are 56°. Pd(1) is bonded to one N(1), one N(2), one N(3), one N(4), one O(3), and one O(8) atom to form PdN4O2 octahedra that share  a cornercorner with one Mn(1)O4 tetrahedra and  a cornercorner with one Mn(2)O4 tetrahedra. There are four inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pd(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Pd(1) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Pd(1) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one Pd(1) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mn(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Mn(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(2) and one Pd(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mn(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mn(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Mn(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Mn(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(1) and one Pd(1) atom. is represented by the CIF file [CIF]
data_Mn2Pd(NO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.184
_cell_length_b   7.335
_cell_length_c   7.150
_cell_angle_alpha   74.864
_cell_angle_beta   68.025
_cell_angle_gamma   69.674
_symmetry_Int_Tables_number   1
_cell_volume   233.737
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.049  0.646  0.635  1.0
  Mn  Mn1  1  0.969  0.004  0.021  1.0
  Pd  Pd2  1  0.509  0.326  0.327  1.0
  N  N3  1  0.644  0.571  0.284  1.0
  N  N4  1  0.403  0.425  0.060  1.0
  N  N5  1  0.613  0.227  0.595  1.0
  N  N6  1  0.372  0.084  0.368  1.0
  O  O7  1  0.136  0.794  0.118  1.0
  O  O8  1  0.357  0.654  0.630  1.0
  O  O9  1  0.909  0.180  0.161  1.0
  O  O10  1  0.860  0.588  0.865  1.0
  O  O11  1  0.881  0.857  0.540  1.0
  O  O12  1  0.159  0.061  0.791  1.0
  O  O13  1  0.660  0.996  0.027  1.0
  O  O14  1  0.109  0.472  0.493  1.0
[/CIF]
.