The structure described by Rb5Au3O2 crystallizes in the orthorhombic Pbam space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 2-coordinate geometry to four equivalent Au(1) and two equivalent O(1) atoms. In the second Rb site, Rb(2) is bonded in a distorted linear geometry to four equivalent Au(1) and two equivalent O(1) atoms. In the third Rb site, Rb(3) is bonded in a 2-coordinate geometry to four equivalent Au(1) and two equivalent O(1) atoms. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a 10-coordinate geometry to two equivalent Rb(2), four equivalent Rb(1), and four equivalent Rb(3) atoms. In the second Au site, Au(2) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to one Rb(2), two equivalent Rb(1), two equivalent Rb(3), and one Au(2) atom to form corner-sharing ORb5Au octahedra. The corner-sharing octahedral tilt angles range from 0-15°. is represented by the CIF card [CIF]
data_Rb5Au3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.687
_cell_length_b   7.372
_cell_length_c   14.325
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   600.610
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.171  0.897  1.0
  Rb  Rb1  1  0.500  0.829  0.103  1.0
  Rb  Rb2  1  0.000  0.000  0.500  1.0
  Rb  Rb3  1  0.000  0.500  0.000  1.0
  Rb  Rb4  1  0.000  0.115  0.235  1.0
  Rb  Rb5  1  0.000  0.885  0.765  1.0
  Rb  Rb6  1  0.000  0.615  0.265  1.0
  Rb  Rb7  1  0.000  0.385  0.735  1.0
  Rb  Rb8  1  0.500  0.329  0.397  1.0
  Rb  Rb9  1  0.500  0.671  0.603  1.0
  Au  Au10  1  0.500  0.147  0.644  1.0
  Au  Au11  1  0.500  0.853  0.356  1.0
  Au  Au12  1  0.500  0.647  0.856  1.0
  Au  Au13  1  0.500  0.353  0.144  1.0
  Au  Au14  1  0.000  0.500  0.500  1.0
  Au  Au15  1  0.000  0.000  0.000  1.0
  O  O16  1  0.000  0.174  0.891  1.0
  O  O17  1  0.000  0.826  0.109  1.0
  O  O18  1  0.000  0.674  0.609  1.0
  O  O19  1  0.000  0.326  0.391  1.0
[/CIF]
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The structure described by Rb5Au3O2 crystallizes in the orthorhombic Pbam space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 2-coordinate geometry to four equivalent Au(1) and two equivalent O(1) atoms. In the second Rb site, Rb(2) is bonded in a distorted linear geometry to four equivalent Au(1) and two equivalent O(1) atoms. In the third Rb site, Rb(3) is bonded in a 2-coordinate geometry to four equivalent Au(1) and two equivalent O(1) atoms. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a 10-coordinate geometry to two equivalent Rb(2), four equivalent Rb(1), and four equivalent Rb(3) atoms. In the second Au site, Au(2) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to one Rb(2), two equivalent Rb(1), two equivalent Rb(3), and one Au(2) atom to form corner-sharing ORb5Au octahedra. The corner-sharing octahedral tilt angles range from 0-15°. is represented by the CIF card [CIF]
data_Rb5Au3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.687
_cell_length_b   7.372
_cell_length_c   14.325
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   600.610
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.171  0.897  1.0
  Rb  Rb1  1  0.500  0.829  0.103  1.0
  Rb  Rb2  1  0.000  0.000  0.500  1.0
  Rb  Rb3  1  0.000  0.500  0.000  1.0
  Rb  Rb4  1  0.000  0.115  0.235  1.0
  Rb  Rb5  1  0.000  0.885  0.765  1.0
  Rb  Rb6  1  0.000  0.615  0.265  1.0
  Rb  Rb7  1  0.000  0.385  0.735  1.0
  Rb  Rb8  1  0.500  0.329  0.397  1.0
  Rb  Rb9  1  0.500  0.671  0.603  1.0
  Au  Au10  1  0.500  0.147  0.644  1.0
  Au  Au11  1  0.500  0.853  0.356  1.0
  Au  Au12  1  0.500  0.647  0.856  1.0
  Au  Au13  1  0.500  0.353  0.144  1.0
  Au  Au14  1  0.000  0.500  0.500  1.0
  Au  Au15  1  0.000  0.000  0.000  1.0
  O  O16  1  0.000  0.174  0.891  1.0
  O  O17  1  0.000  0.826  0.109  1.0
  O  O18  1  0.000  0.674  0.609  1.0
  O  O19  1  0.000  0.326  0.391  1.0
[/CIF]
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