The structure described by HgGaCl4 is gamma plutonium structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two HgGaCl4 clusters. Hg(1) is bonded in a distorted single-bond geometry to one Cl(1) atom. Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to one Hg(1) and one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ga(1) atom. is represented by the CIF card [CIF]
data_GaHgCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.543
_cell_length_b   6.720
_cell_length_c   9.563
_cell_angle_alpha   82.256
_cell_angle_beta   73.757
_cell_angle_gamma   61.333
_symmetry_Int_Tables_number   1
_cell_volume   354.228
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.380  0.850  0.762  1.0
  Ga  Ga1  1  0.620  0.150  0.238  1.0
  Hg  Hg2  1  0.938  0.514  0.881  1.0
  Hg  Hg3  1  0.062  0.486  0.119  1.0
  Cl  Cl4  1  0.748  0.558  0.675  1.0
  Cl  Cl5  1  0.252  0.442  0.325  1.0
  Cl  Cl6  1  0.325  0.825  0.997  1.0
  Cl  Cl7  1  0.675  0.175  0.003  1.0
  Cl  Cl8  1  0.130  0.808  0.676  1.0
  Cl  Cl9  1  0.870  0.192  0.324  1.0
  Cl  Cl10  1  0.392  0.165  0.685  1.0
  Cl  Cl11  1  0.608  0.835  0.315  1.0
[/CIF]
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The structure described by HgGaCl4 is gamma plutonium structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two HgGaCl4 clusters. Hg(1) is bonded in a distorted single-bond geometry to one Cl(1) atom. Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to one Hg(1) and one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Ga(1) atom. is represented by the CIF card [CIF]
data_GaHgCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.543
_cell_length_b   6.720
_cell_length_c   9.563
_cell_angle_alpha   82.256
_cell_angle_beta   73.757
_cell_angle_gamma   61.333
_symmetry_Int_Tables_number   1
_cell_volume   354.228
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.380  0.850  0.762  1.0
  Ga  Ga1  1  0.620  0.150  0.238  1.0
  Hg  Hg2  1  0.938  0.514  0.881  1.0
  Hg  Hg3  1  0.062  0.486  0.119  1.0
  Cl  Cl4  1  0.748  0.558  0.675  1.0
  Cl  Cl5  1  0.252  0.442  0.325  1.0
  Cl  Cl6  1  0.325  0.825  0.997  1.0
  Cl  Cl7  1  0.675  0.175  0.003  1.0
  Cl  Cl8  1  0.130  0.808  0.676  1.0
  Cl  Cl9  1  0.870  0.192  0.324  1.0
  Cl  Cl10  1  0.392  0.165  0.685  1.0
  Cl  Cl11  1  0.608  0.835  0.315  1.0
[/CIF]
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