The crystal structure described by InInCl4 is Iron carbide-like structured and crystallizes in the orthorhombic Pnna space group. The structure is zero-dimensional and consists of four 7440-74-6 atoms and four InCl4 clusters. In each InCl4 cluster, In(1) is bonded in a tetrahedral geometry to two equivalent Cl(1) and two equivalent Cl(2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one In(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one In(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_InCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.710
_cell_length_b   9.943
_cell_length_c   9.921
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   760.553
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.750  0.814  0.000  1.0
  In  In1  1  0.250  0.186  0.000  1.0
  In  In2  1  0.750  0.686  0.500  1.0
  In  In3  1  0.250  0.314  0.500  1.0
  In  In4  1  0.312  0.750  0.750  1.0
  In  In5  1  0.688  0.250  0.250  1.0
  In  In6  1  0.188  0.750  0.250  1.0
  In  In7  1  0.812  0.250  0.750  1.0
  Cl  Cl8  1  0.999  0.681  0.953  1.0
  Cl  Cl9  1  0.001  0.319  0.047  1.0
  Cl  Cl10  1  0.501  0.681  0.047  1.0
  Cl  Cl11  1  0.501  0.819  0.453  1.0
  Cl  Cl12  1  0.499  0.319  0.953  1.0
  Cl  Cl13  1  0.499  0.181  0.547  1.0
  Cl  Cl14  1  0.999  0.819  0.547  1.0
  Cl  Cl15  1  0.001  0.181  0.453  1.0
  Cl  Cl16  1  0.660  0.948  0.813  1.0
  Cl  Cl17  1  0.340  0.052  0.187  1.0
  Cl  Cl18  1  0.840  0.948  0.187  1.0
  Cl  Cl19  1  0.840  0.552  0.313  1.0
  Cl  Cl20  1  0.160  0.052  0.813  1.0
  Cl  Cl21  1  0.160  0.448  0.687  1.0
  Cl  Cl22  1  0.660  0.552  0.687  1.0
  Cl  Cl23  1  0.340  0.448  0.313  1.0
[/CIF]
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The crystal structure described by InInCl4 is Iron carbide-like structured and crystallizes in the orthorhombic Pnna space group. The structure is zero-dimensional and consists of four 7440-74-6 atoms and four InCl4 clusters. In each InCl4 cluster, In(1) is bonded in a tetrahedral geometry to two equivalent Cl(1) and two equivalent Cl(2) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one In(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one In(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_InCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.710
_cell_length_b   9.943
_cell_length_c   9.921
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   760.553
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.750  0.814  0.000  1.0
  In  In1  1  0.250  0.186  0.000  1.0
  In  In2  1  0.750  0.686  0.500  1.0
  In  In3  1  0.250  0.314  0.500  1.0
  In  In4  1  0.312  0.750  0.750  1.0
  In  In5  1  0.688  0.250  0.250  1.0
  In  In6  1  0.188  0.750  0.250  1.0
  In  In7  1  0.812  0.250  0.750  1.0
  Cl  Cl8  1  0.999  0.681  0.953  1.0
  Cl  Cl9  1  0.001  0.319  0.047  1.0
  Cl  Cl10  1  0.501  0.681  0.047  1.0
  Cl  Cl11  1  0.501  0.819  0.453  1.0
  Cl  Cl12  1  0.499  0.319  0.953  1.0
  Cl  Cl13  1  0.499  0.181  0.547  1.0
  Cl  Cl14  1  0.999  0.819  0.547  1.0
  Cl  Cl15  1  0.001  0.181  0.453  1.0
  Cl  Cl16  1  0.660  0.948  0.813  1.0
  Cl  Cl17  1  0.340  0.052  0.187  1.0
  Cl  Cl18  1  0.840  0.948  0.187  1.0
  Cl  Cl19  1  0.840  0.552  0.313  1.0
  Cl  Cl20  1  0.160  0.052  0.813  1.0
  Cl  Cl21  1  0.160  0.448  0.687  1.0
  Cl  Cl22  1  0.660  0.552  0.687  1.0
  Cl  Cl23  1  0.340  0.448  0.313  1.0
[/CIF]
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