The material structure described by (RuN5Cl)2(AuCl4)2Cl2O is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two chlorine monoxide molecules, four AuCl4 clusters, and four RuN5Cl clusters. In two of the AuCl4 clusters, Au(1) is bonded in a square co-planar geometry to four equivalent Cl(2,3,5) atoms. Cl(2,3,5) is bonded in a single-bond geometry to one Au(1) atom. In two of the AuCl4 clusters, Au(2) is bonded in a square co-planar geometry to two equivalent Cl(4) and two equivalent Cl(6) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Au(2) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Au(2) atom. In each RuN5Cl cluster, Ru(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(3), one N(4), and one N(5) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second N site, N(2) is bonded in an L-shaped geometry to one Ru(1) and one Cl(1) atom. In the third N site, N(3) is bonded in an L-shaped geometry to one Ru(1) and one Cl(1) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one Ru(1) atom. In the fifth N site, N(5) is bonded in a single-bond geometry to one Ru(1) atom. Cl(1) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. is represented by the CIF card [CIF]
data_Ru2Au2N10Cl12O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.190
_cell_length_b   7.746
_cell_length_c   13.207
_cell_angle_alpha   101.881
_cell_angle_beta   90.000
_cell_angle_gamma   58.085
_symmetry_Int_Tables_number   1
_cell_volume   689.917
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.726  0.551  0.784  1.0
  Ru  Ru1  1  0.277  0.449  0.216  1.0
  Au  Au2  1  0.000  0.000  0.000  1.0
  Au  Au3  1  0.511  0.000  0.500  1.0
  N  N4  1  0.674  0.670  0.916  1.0
  N  N5  1  0.345  0.330  0.084  1.0
  N  N6  1  0.710  0.257  0.770  1.0
  N  N7  1  0.027  0.251  0.760  1.0
  N  N8  1  0.278  0.749  0.240  1.0
  N  N9  1  0.967  0.743  0.230  1.0
  N  N10  1  0.497  0.652  0.735  1.0
  N  N11  1  0.823  0.671  0.725  1.0
  N  N12  1  0.495  0.329  0.275  1.0
  N  N13  1  0.149  0.348  0.265  1.0
  Cl  Cl14  1  0.057  0.875  0.242  1.0
  Cl  Cl15  1  0.932  0.125  0.758  1.0
  Cl  Cl16  1  0.283  0.000  0.000  1.0
  Cl  Cl17  1  0.716  0.000  0.000  1.0
  Cl  Cl18  1  0.501  0.013  0.326  1.0
  Cl  Cl19  1  0.514  0.987  0.674  1.0
  Cl  Cl20  1  0.822  0.356  0.076  1.0
  Cl  Cl21  1  0.179  0.644  0.924  1.0
  Cl  Cl22  1  0.687  0.636  0.446  1.0
  Cl  Cl23  1  0.323  0.364  0.554  1.0
  Cl  Cl24  1  0.883  0.230  0.504  1.0
  Cl  Cl25  1  0.113  0.770  0.496  1.0
  O  O26  1  0.891  0.000  0.500  1.0
[/CIF]
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The material structure described by (RuN5Cl)2(AuCl4)2Cl2O is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two chlorine monoxide molecules, four AuCl4 clusters, and four RuN5Cl clusters. In two of the AuCl4 clusters, Au(1) is bonded in a square co-planar geometry to four equivalent Cl(2,3,5) atoms. Cl(2,3,5) is bonded in a single-bond geometry to one Au(1) atom. In two of the AuCl4 clusters, Au(2) is bonded in a square co-planar geometry to two equivalent Cl(4) and two equivalent Cl(6) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Au(2) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Au(2) atom. In each RuN5Cl cluster, Ru(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(3), one N(4), and one N(5) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second N site, N(2) is bonded in an L-shaped geometry to one Ru(1) and one Cl(1) atom. In the third N site, N(3) is bonded in an L-shaped geometry to one Ru(1) and one Cl(1) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one Ru(1) atom. In the fifth N site, N(5) is bonded in a single-bond geometry to one Ru(1) atom. Cl(1) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. is represented by the CIF card [CIF]
data_Ru2Au2N10Cl12O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.190
_cell_length_b   7.746
_cell_length_c   13.207
_cell_angle_alpha   101.881
_cell_angle_beta   90.000
_cell_angle_gamma   58.085
_symmetry_Int_Tables_number   1
_cell_volume   689.917
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ru  Ru0  1  0.726  0.551  0.784  1.0
  Ru  Ru1  1  0.277  0.449  0.216  1.0
  Au  Au2  1  0.000  0.000  0.000  1.0
  Au  Au3  1  0.511  0.000  0.500  1.0
  N  N4  1  0.674  0.670  0.916  1.0
  N  N5  1  0.345  0.330  0.084  1.0
  N  N6  1  0.710  0.257  0.770  1.0
  N  N7  1  0.027  0.251  0.760  1.0
  N  N8  1  0.278  0.749  0.240  1.0
  N  N9  1  0.967  0.743  0.230  1.0
  N  N10  1  0.497  0.652  0.735  1.0
  N  N11  1  0.823  0.671  0.725  1.0
  N  N12  1  0.495  0.329  0.275  1.0
  N  N13  1  0.149  0.348  0.265  1.0
  Cl  Cl14  1  0.057  0.875  0.242  1.0
  Cl  Cl15  1  0.932  0.125  0.758  1.0
  Cl  Cl16  1  0.283  0.000  0.000  1.0
  Cl  Cl17  1  0.716  0.000  0.000  1.0
  Cl  Cl18  1  0.501  0.013  0.326  1.0
  Cl  Cl19  1  0.514  0.987  0.674  1.0
  Cl  Cl20  1  0.822  0.356  0.076  1.0
  Cl  Cl21  1  0.179  0.644  0.924  1.0
  Cl  Cl22  1  0.687  0.636  0.446  1.0
  Cl  Cl23  1  0.323  0.364  0.554  1.0
  Cl  Cl24  1  0.883  0.230  0.504  1.0
  Cl  Cl25  1  0.113  0.770  0.496  1.0
  O  O26  1  0.891  0.000  0.500  1.0
[/CIF]
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