The structure described by (NH4)3TiF7 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 1333-74-0 molecule, one hydrofluoric acid atom, one molecular hydrogen;hydrofluoride molecule, one monofluoroamine molecule, one NH4F cluster, and one TiNH2F3 cluster. In the NH4F cluster, N(2) is bonded in a distorted T-shaped geometry to one H(5), one H(6), and one H(7) atom. There are four inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(2) and one F(2) atom. In the third H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one F(2) atom. F(2) is bonded in a 2-coordinate geometry to one H(6) and one H(9) atom. In the TiNH2F3 cluster, Ti(1) is bonded in a 2-coordinate geometry to one N(3), one F(1), and one F(5) atom. N(3) is bonded in a 3-coordinate geometry to one Ti(1), one H(8), and one F(5) atom. There are two inequivalent H sites. In the first H site, H(2) is bonded in a linear geometry to one F(3) and one F(5) atom. In the second H site, H(8) is bonded in a single-bond geometry to one N(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ti(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one H(2) atom. In the third F site, F(5) is bonded in a distorted water-like geometry to one Ti(1), one N(3), and one H(2) atom. is represented by the CIF file [CIF]
data_TiH12N3F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.186
_cell_length_b   7.236
_cell_length_c   7.464
_cell_angle_alpha   117.938
_cell_angle_beta   95.776
_cell_angle_gamma   107.370
_symmetry_Int_Tables_number   1
_cell_volume   313.618
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.511  0.039  0.116  1.0
  H  H1  1  0.055  0.996  0.743  1.0
  H  H2  1  0.598  0.833  0.846  1.0
  H  H3  1  0.043  0.041  0.071  1.0
  H  H4  1  0.266  0.471  0.831  1.0
  H  H5  1  0.136  0.882  0.560  1.0
  H  H6  1  0.037  0.671  0.496  1.0
  H  H7  1  0.291  0.769  0.536  1.0
  H  H8  1  0.805  0.240  0.335  1.0
  H  H9  1  0.735  0.703  0.217  1.0
  H  H10  1  0.953  0.088  0.053  1.0
  H  H11  1  0.135  0.204  0.233  1.0
  H  H12  1  0.997  0.886  0.786  1.0
  N  N13  1  0.211  0.600  0.811  1.0
  N  N14  1  0.163  0.737  0.587  1.0
  N  N15  1  0.716  0.154  0.250  1.0
  F  F16  1  0.341  0.855  0.285  1.0
  F  F17  1  0.820  0.596  0.337  1.0
  F  F18  1  0.589  0.802  0.733  1.0
  F  F19  1  0.228  0.195  0.365  1.0
  F  F20  1  0.608  0.870  0.040  1.0
  F  F21  1  0.357  0.249  0.885  1.0
  F  F22  1  0.013  0.500  0.844  1.0
[/CIF]
.
The structure described by (NH4)3TiF7 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 1333-74-0 molecule, one hydrofluoric acid atom, one molecular hydrogen;hydrofluoride molecule, one monofluoroamine molecule, one NH4F cluster, and one TiNH2F3 cluster. In the NH4F cluster, N(2) is bonded in a distorted T-shaped geometry to one H(5), one H(6), and one H(7) atom. There are four inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(2) and one F(2) atom. In the third H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one F(2) atom. F(2) is bonded in a 2-coordinate geometry to one H(6) and one H(9) atom. In the TiNH2F3 cluster, Ti(1) is bonded in a 2-coordinate geometry to one N(3), one F(1), and one F(5) atom. N(3) is bonded in a 3-coordinate geometry to one Ti(1), one H(8), and one F(5) atom. There are two inequivalent H sites. In the first H site, H(2) is bonded in a linear geometry to one F(3) and one F(5) atom. In the second H site, H(8) is bonded in a single-bond geometry to one N(3) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ti(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one H(2) atom. In the third F site, F(5) is bonded in a distorted water-like geometry to one Ti(1), one N(3), and one H(2) atom. is represented by the CIF file [CIF]
data_TiH12N3F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.186
_cell_length_b   7.236
_cell_length_c   7.464
_cell_angle_alpha   117.938
_cell_angle_beta   95.776
_cell_angle_gamma   107.370
_symmetry_Int_Tables_number   1
_cell_volume   313.618
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.511  0.039  0.116  1.0
  H  H1  1  0.055  0.996  0.743  1.0
  H  H2  1  0.598  0.833  0.846  1.0
  H  H3  1  0.043  0.041  0.071  1.0
  H  H4  1  0.266  0.471  0.831  1.0
  H  H5  1  0.136  0.882  0.560  1.0
  H  H6  1  0.037  0.671  0.496  1.0
  H  H7  1  0.291  0.769  0.536  1.0
  H  H8  1  0.805  0.240  0.335  1.0
  H  H9  1  0.735  0.703  0.217  1.0
  H  H10  1  0.953  0.088  0.053  1.0
  H  H11  1  0.135  0.204  0.233  1.0
  H  H12  1  0.997  0.886  0.786  1.0
  N  N13  1  0.211  0.600  0.811  1.0
  N  N14  1  0.163  0.737  0.587  1.0
  N  N15  1  0.716  0.154  0.250  1.0
  F  F16  1  0.341  0.855  0.285  1.0
  F  F17  1  0.820  0.596  0.337  1.0
  F  F18  1  0.589  0.802  0.733  1.0
  F  F19  1  0.228  0.195  0.365  1.0
  F  F20  1  0.608  0.870  0.040  1.0
  F  F21  1  0.357  0.249  0.885  1.0
  F  F22  1  0.013  0.500  0.844  1.0
[/CIF]
.