The compound described by Cu(NH3)4(N3O4)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two dinitramide molecules and one Cu(NH3)4 cluster. In the Cu(NH3)4 cluster, Cu(1) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent N(3) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one H(1), one H(5), and one H(6) atom. In the second N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one H(2), one H(3), and one H(4) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_CuH12(N5O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.696
_cell_length_b   7.495
_cell_length_c   7.635
_cell_angle_alpha   96.935
_cell_angle_beta   110.923
_cell_angle_gamma   115.237
_symmetry_Int_Tables_number   1
_cell_volume   306.396
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.000  0.500  0.000  1.0
  H  H1  1  0.954  0.203  0.742  1.0
  H  H2  1  0.729  0.228  0.115  1.0
  H  H3  1  0.978  0.709  0.762  1.0
  H  H4  1  0.843  0.116  0.014  1.0
  H  H5  1  0.165  0.429  0.750  1.0
  H  H6  1  0.046  0.797  0.258  1.0
  H  H7  1  0.022  0.291  0.238  1.0
  H  H8  1  0.271  0.772  0.885  1.0
  H  H9  1  0.835  0.571  0.250  1.0
  H  H10  1  0.235  0.329  0.929  1.0
  H  H11  1  0.157  0.884  0.986  1.0
  H  H12  1  0.765  0.671  0.071  1.0
  N  N13  1  0.099  0.349  0.835  1.0
  N  N14  1  0.405  0.186  0.597  1.0
  N  N15  1  0.901  0.651  0.165  1.0
  N  N16  1  0.885  0.255  0.100  1.0
  N  N17  1  0.336  0.129  0.395  1.0
  N  N18  1  0.664  0.871  0.605  1.0
  N  N19  1  0.595  0.814  0.403  1.0
  N  N20  1  0.115  0.745  0.900  1.0
  N  N21  1  0.500  0.744  0.662  1.0
  N  N22  1  0.500  0.256  0.338  1.0
  O  O23  1  0.413  0.205  0.150  1.0
  O  O24  1  0.716  0.397  0.450  1.0
  O  O25  1  0.447  0.632  0.287  1.0
  O  O26  1  0.553  0.368  0.713  1.0
  O  O27  1  0.284  0.603  0.550  1.0
  O  O28  1  0.711  0.962  0.353  1.0
  O  O29  1  0.587  0.795  0.850  1.0
  O  O30  1  0.289  0.038  0.647  1.0
[/CIF]
.
The compound described by Cu(NH3)4(N3O4)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two dinitramide molecules and one Cu(NH3)4 cluster. In the Cu(NH3)4 cluster, Cu(1) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent N(3) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one H(1), one H(5), and one H(6) atom. In the second N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Cu(1), one H(2), one H(3), and one H(4) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_CuH12(N5O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.696
_cell_length_b   7.495
_cell_length_c   7.635
_cell_angle_alpha   96.935
_cell_angle_beta   110.923
_cell_angle_gamma   115.237
_symmetry_Int_Tables_number   1
_cell_volume   306.396
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.000  0.500  0.000  1.0
  H  H1  1  0.954  0.203  0.742  1.0
  H  H2  1  0.729  0.228  0.115  1.0
  H  H3  1  0.978  0.709  0.762  1.0
  H  H4  1  0.843  0.116  0.014  1.0
  H  H5  1  0.165  0.429  0.750  1.0
  H  H6  1  0.046  0.797  0.258  1.0
  H  H7  1  0.022  0.291  0.238  1.0
  H  H8  1  0.271  0.772  0.885  1.0
  H  H9  1  0.835  0.571  0.250  1.0
  H  H10  1  0.235  0.329  0.929  1.0
  H  H11  1  0.157  0.884  0.986  1.0
  H  H12  1  0.765  0.671  0.071  1.0
  N  N13  1  0.099  0.349  0.835  1.0
  N  N14  1  0.405  0.186  0.597  1.0
  N  N15  1  0.901  0.651  0.165  1.0
  N  N16  1  0.885  0.255  0.100  1.0
  N  N17  1  0.336  0.129  0.395  1.0
  N  N18  1  0.664  0.871  0.605  1.0
  N  N19  1  0.595  0.814  0.403  1.0
  N  N20  1  0.115  0.745  0.900  1.0
  N  N21  1  0.500  0.744  0.662  1.0
  N  N22  1  0.500  0.256  0.338  1.0
  O  O23  1  0.413  0.205  0.150  1.0
  O  O24  1  0.716  0.397  0.450  1.0
  O  O25  1  0.447  0.632  0.287  1.0
  O  O26  1  0.553  0.368  0.713  1.0
  O  O27  1  0.284  0.603  0.550  1.0
  O  O28  1  0.711  0.962  0.353  1.0
  O  O29  1  0.587  0.795  0.850  1.0
  O  O30  1  0.289  0.038  0.647  1.0
[/CIF]
.