The compound described by AsF5 is Indium-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of two AsF5 clusters. As(1) is bonded in a trigonal bipyramidal geometry to two equivalent F(1) and three equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.624
_cell_length_b   5.624
_cell_length_c   6.234
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   170.767
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.667  0.333  0.750  1.0
  As  As1  1  0.333  0.667  0.250  1.0
  F  F2  1  0.333  0.667  0.527  1.0
  F  F3  1  0.667  0.333  0.027  1.0
  F  F4  1  0.160  0.321  0.250  1.0
  F  F5  1  0.840  0.160  0.750  1.0
  F  F6  1  0.321  0.160  0.750  1.0
  F  F7  1  0.679  0.840  0.250  1.0
  F  F8  1  0.160  0.840  0.250  1.0
  F  F9  1  0.840  0.679  0.750  1.0
  F  F10  1  0.333  0.667  0.973  1.0
  F  F11  1  0.667  0.333  0.473  1.0
[/CIF]
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The compound described by AsF5 is Indium-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of two AsF5 clusters. As(1) is bonded in a trigonal bipyramidal geometry to two equivalent F(1) and three equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.624
_cell_length_b   5.624
_cell_length_c   6.234
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   170.767
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.667  0.333  0.750  1.0
  As  As1  1  0.333  0.667  0.250  1.0
  F  F2  1  0.333  0.667  0.527  1.0
  F  F3  1  0.667  0.333  0.027  1.0
  F  F4  1  0.160  0.321  0.250  1.0
  F  F5  1  0.840  0.160  0.750  1.0
  F  F6  1  0.321  0.160  0.750  1.0
  F  F7  1  0.679  0.840  0.250  1.0
  F  F8  1  0.160  0.840  0.250  1.0
  F  F9  1  0.840  0.679  0.750  1.0
  F  F10  1  0.333  0.667  0.973  1.0
  F  F11  1  0.667  0.333  0.473  1.0
[/CIF]
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