The crystal structure described by Sm3La5VCr7O24 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent Sm sites. In the first Sm site, Sm(1) is bonded to one O(10), one O(11), one O(12), one O(13), one O(14), one O(4), one O(6), one O(7), one O(8), one O(9), and two equivalent O(5) atoms to form SmO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra, faces with two equivalent Sm(2)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra,  a faceface with one Cr(3)O6 octahedra,  a faceface with one Cr(5)O6 octahedra, faces with two equivalent Cr(1)O6 octahedra, and faces with two equivalent Cr(4)O6 octahedra. In the second Sm site, Sm(2) is bonded to one O(4), one O(6), two equivalent O(11), two equivalent O(12), two equivalent O(5), two equivalent O(7), and two equivalent O(8) atoms to form SmO12 cuboctahedra that share corners with four equivalent La(4)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with four equivalent Sm(1)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra,  a faceface with one Cr(3)O6 octahedra,  a faceface with one Cr(5)O6 octahedra, faces with two equivalent Cr(1)O6 octahedra, and faces with two equivalent Cr(4)O6 octahedra. There are four inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(13), one O(14), one O(3), one O(7), one O(8), one O(9), and two equivalent O(2) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(2)O12 cuboctahedra, corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra,  a faceface with one Cr(3)O6 octahedra,  a faceface with one Cr(5)O6 octahedra, faces with two equivalent Cr(1)O6 octahedra, and faces with two equivalent Cr(4)O6 octahedra. In the second La site, La(2) is bonded to one O(1), one O(3), two equivalent O(11), two equivalent O(12), two equivalent O(2), two equivalent O(7), and two equivalent O(8) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(3)O12 cuboctahedra, corners with eight equivalent Sm(1)O12 cuboctahedra, faces with two equivalent Sm(2)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra,  a faceface with one Cr(3)O6 octahedra,  a faceface with one Cr(5)O6 octahedra, faces with two equivalent Cr(1)O6 octahedra, and faces with two equivalent Cr(4)O6 octahedra. In the third La site, La(3) is bonded to one O(1), one O(3), two equivalent O(10), two equivalent O(13), two equivalent O(14), two equivalent O(2), and two equivalent O(9) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(2)O12 cuboctahedra, corners with eight equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra,  a faceface with one Cr(3)O6 octahedra,  a faceface with one Cr(5)O6 octahedra, faces with two equivalent Cr(1)O6 octahedra, and faces with two equivalent Cr(4)O6 octahedra. In the fourth La site, La(4) is bonded to one O(4), one O(6), two equivalent O(10), two equivalent O(13), two equivalent O(14), two equivalent O(5), and two equivalent O(9) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(2)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra, faces with four equivalent Sm(1)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra,  a faceface with one Cr(3)O6 octahedra,  a faceface with one Cr(5)O6 octahedra, faces with two equivalent Cr(1)O6 octahedra, and faces with two equivalent Cr(4)O6 octahedra. V(1) is bonded to one O(1), one O(4), two equivalent O(7), and two equivalent O(9) atoms to form VO6 octahedra that share corners with two equivalent Cr(3)O6 octahedra, corners with four equivalent Cr(1)O6 octahedra,  a faceface with one Sm(2)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are five inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(10), one O(2), one O(5), one O(7), one O(8), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Cr(4)O6 octahedra,  a faceface with one Sm(2)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second Cr site, Cr(2) is bonded to one O(3), one O(6), two equivalent O(10), and two equivalent O(8) atoms to form CrO6 octahedra that share corners with two equivalent Cr(5)O6 octahedra, corners with four equivalent Cr(1)O6 octahedra,  a faceface with one Sm(2)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Cr site, Cr(3) is bonded to one O(1), one O(4), two equivalent O(11), and two equivalent O(13) atoms to form CrO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent Cr(4)O6 octahedra,  a faceface with one Sm(2)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 1°. In the fourth Cr site, Cr(4) is bonded to one O(11), one O(12), one O(13), one O(14), one O(2), and one O(5) atom to form CrO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, corners with two equivalent Cr(5)O6 octahedra,  a faceface with one Sm(2)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fifth Cr site, Cr(5) is bonded to one O(3), one O(6), two equivalent O(12), and two equivalent O(14) atoms to form CrO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra, corners with four equivalent Cr(4)O6 octahedra,  a faceface with one Sm(2)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one La(2), one La(3), two equivalent La(1), one V(1), and one Cr(3) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one La(2), one La(3), two equivalent La(1), one Cr(1), and one Cr(4) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one La(2), one La(3), two equivalent La(1), one Cr(2), and one Cr(5) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sm(2), two equivalent Sm(1), one La(4), one V(1), and one Cr(3) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sm(2), two equivalent Sm(1), one La(4), one Cr(1), and one Cr(4) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sm(2), two equivalent Sm(1), one La(4), one Cr(2), and one Cr(5) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sm(1), one Sm(2), one La(1), one La(2), one V(1), and one Cr(1) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sm(1), one Sm(2), one La(1), one La(2), one Cr(1), and one Cr(2) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(4), one V(1), and one Cr(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(4), one Cr(1), and one Cr(2) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to one Sm(1), one Sm(2), one La(1), one La(2), one Cr(3), and one Cr(4) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one Sm(1), one Sm(2), one La(1), one La(2), one Cr(4), and one Cr(5) atom. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(4), one Cr(3), and one Cr(4) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(4), one Cr(4), and one Cr(5) atom. is represented by the CIF file [CIF]
data_La5Sm3VCr7O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.826
_cell_length_b   7.826
_cell_length_c   7.830
_cell_angle_alpha   89.881
_cell_angle_beta   89.881
_cell_angle_gamma   89.912
_symmetry_Int_Tables_number   1
_cell_volume   479.587
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.750  0.250  0.750  1.0
  La  La1  1  0.250  0.250  0.750  1.0
  La  La2  1  0.749  0.749  0.749  1.0
  La  La3  1  0.250  0.750  0.750  1.0
  La  La4  1  0.750  0.750  0.250  1.0
  Sm  Sm5  1  0.750  0.251  0.251  1.0
  Sm  Sm6  1  0.251  0.251  0.251  1.0
  Sm  Sm7  1  0.251  0.750  0.251  1.0
  V  V8  1  0.001  0.001  0.001  1.0
  Cr  Cr9  1  0.500  0.000  0.001  1.0
  Cr  Cr10  1  0.000  0.500  0.001  1.0
  Cr  Cr11  1  0.500  0.500  0.001  1.0
  Cr  Cr12  1  0.000  0.000  0.499  1.0
  Cr  Cr13  1  0.500  0.000  0.499  1.0
  Cr  Cr14  1  0.000  0.500  0.499  1.0
  Cr  Cr15  1  0.500  0.500  0.499  1.0
  O  O16  1  0.999  0.999  0.748  1.0
  O  O17  1  0.500  0.000  0.750  1.0
  O  O18  1  0.000  0.500  0.750  1.0
  O  O19  1  0.500  0.500  0.750  1.0
  O  O20  1  0.003  0.003  0.252  1.0
  O  O21  1  0.498  0.002  0.250  1.0
  O  O22  1  0.002  0.498  0.250  1.0
  O  O23  1  0.498  0.498  0.250  1.0
  O  O24  1  0.001  0.252  0.005  1.0
  O  O25  1  0.500  0.250  0.004  1.0
  O  O26  1  0.001  0.748  0.001  1.0
  O  O27  1  0.498  0.750  0.002  1.0
  O  O28  1  0.000  0.250  0.496  1.0
  O  O29  1  0.500  0.250  0.496  1.0
  O  O30  1  0.002  0.750  0.498  1.0
  O  O31  1  0.498  0.750  0.498  1.0
  O  O32  1  0.748  0.001  0.001  1.0
  O  O33  1  0.252  0.001  0.005  1.0
  O  O34  1  0.750  0.498  0.002  1.0
  O  O35  1  0.250  0.500  0.004  1.0
  O  O36  1  0.750  0.002  0.498  1.0
  O  O37  1  0.250  0.000  0.496  1.0
  O  O38  1  0.750  0.498  0.498  1.0
  O  O39  1  0.250  0.500  0.496  1.0
[/CIF]
.
The crystal structure described by Sm3La5VCr7O24 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent Sm sites. In the first Sm site, Sm(1) is bonded to one O(10), one O(11), one O(12), one O(13), one O(14), one O(4), one O(6), one O(7), one O(8), one O(9), and two equivalent O(5) atoms to form SmO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra, faces with two equivalent Sm(2)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra,  a faceface with one Cr(3)O6 octahedra,  a faceface with one Cr(5)O6 octahedra, faces with two equivalent Cr(1)O6 octahedra, and faces with two equivalent Cr(4)O6 octahedra. In the second Sm site, Sm(2) is bonded to one O(4), one O(6), two equivalent O(11), two equivalent O(12), two equivalent O(5), two equivalent O(7), and two equivalent O(8) atoms to form SmO12 cuboctahedra that share corners with four equivalent La(4)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with four equivalent Sm(1)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra,  a faceface with one Cr(3)O6 octahedra,  a faceface with one Cr(5)O6 octahedra, faces with two equivalent Cr(1)O6 octahedra, and faces with two equivalent Cr(4)O6 octahedra. There are four inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(13), one O(14), one O(3), one O(7), one O(8), one O(9), and two equivalent O(2) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(2)O12 cuboctahedra, corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra,  a faceface with one Cr(3)O6 octahedra,  a faceface with one Cr(5)O6 octahedra, faces with two equivalent Cr(1)O6 octahedra, and faces with two equivalent Cr(4)O6 octahedra. In the second La site, La(2) is bonded to one O(1), one O(3), two equivalent O(11), two equivalent O(12), two equivalent O(2), two equivalent O(7), and two equivalent O(8) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(3)O12 cuboctahedra, corners with eight equivalent Sm(1)O12 cuboctahedra, faces with two equivalent Sm(2)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra,  a faceface with one Cr(3)O6 octahedra,  a faceface with one Cr(5)O6 octahedra, faces with two equivalent Cr(1)O6 octahedra, and faces with two equivalent Cr(4)O6 octahedra. In the third La site, La(3) is bonded to one O(1), one O(3), two equivalent O(10), two equivalent O(13), two equivalent O(14), two equivalent O(2), and two equivalent O(9) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(2)O12 cuboctahedra, corners with eight equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra,  a faceface with one Cr(3)O6 octahedra,  a faceface with one Cr(5)O6 octahedra, faces with two equivalent Cr(1)O6 octahedra, and faces with two equivalent Cr(4)O6 octahedra. In the fourth La site, La(4) is bonded to one O(4), one O(6), two equivalent O(10), two equivalent O(13), two equivalent O(14), two equivalent O(5), and two equivalent O(9) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(2)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra, faces with four equivalent Sm(1)O12 cuboctahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one Cr(2)O6 octahedra,  a faceface with one Cr(3)O6 octahedra,  a faceface with one Cr(5)O6 octahedra, faces with two equivalent Cr(1)O6 octahedra, and faces with two equivalent Cr(4)O6 octahedra. V(1) is bonded to one O(1), one O(4), two equivalent O(7), and two equivalent O(9) atoms to form VO6 octahedra that share corners with two equivalent Cr(3)O6 octahedra, corners with four equivalent Cr(1)O6 octahedra,  a faceface with one Sm(2)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are five inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(10), one O(2), one O(5), one O(7), one O(8), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Cr(4)O6 octahedra,  a faceface with one Sm(2)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second Cr site, Cr(2) is bonded to one O(3), one O(6), two equivalent O(10), and two equivalent O(8) atoms to form CrO6 octahedra that share corners with two equivalent Cr(5)O6 octahedra, corners with four equivalent Cr(1)O6 octahedra,  a faceface with one Sm(2)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the third Cr site, Cr(3) is bonded to one O(1), one O(4), two equivalent O(11), and two equivalent O(13) atoms to form CrO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent Cr(4)O6 octahedra,  a faceface with one Sm(2)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 1°. In the fourth Cr site, Cr(4) is bonded to one O(11), one O(12), one O(13), one O(14), one O(2), and one O(5) atom to form CrO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, corners with two equivalent Cr(5)O6 octahedra,  a faceface with one Sm(2)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fifth Cr site, Cr(5) is bonded to one O(3), one O(6), two equivalent O(12), and two equivalent O(14) atoms to form CrO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra, corners with four equivalent Cr(4)O6 octahedra,  a faceface with one Sm(2)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(3)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one La(2), one La(3), two equivalent La(1), one V(1), and one Cr(3) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one La(2), one La(3), two equivalent La(1), one Cr(1), and one Cr(4) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one La(2), one La(3), two equivalent La(1), one Cr(2), and one Cr(5) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sm(2), two equivalent Sm(1), one La(4), one V(1), and one Cr(3) atom. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sm(2), two equivalent Sm(1), one La(4), one Cr(1), and one Cr(4) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sm(2), two equivalent Sm(1), one La(4), one Cr(2), and one Cr(5) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sm(1), one Sm(2), one La(1), one La(2), one V(1), and one Cr(1) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sm(1), one Sm(2), one La(1), one La(2), one Cr(1), and one Cr(2) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(4), one V(1), and one Cr(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(4), one Cr(1), and one Cr(2) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to one Sm(1), one Sm(2), one La(1), one La(2), one Cr(3), and one Cr(4) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one Sm(1), one Sm(2), one La(1), one La(2), one Cr(4), and one Cr(5) atom. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(4), one Cr(3), and one Cr(4) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(4), one Cr(4), and one Cr(5) atom. is represented by the CIF file [CIF]
data_La5Sm3VCr7O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.826
_cell_length_b   7.826
_cell_length_c   7.830
_cell_angle_alpha   89.881
_cell_angle_beta   89.881
_cell_angle_gamma   89.912
_symmetry_Int_Tables_number   1
_cell_volume   479.587
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.750  0.250  0.750  1.0
  La  La1  1  0.250  0.250  0.750  1.0
  La  La2  1  0.749  0.749  0.749  1.0
  La  La3  1  0.250  0.750  0.750  1.0
  La  La4  1  0.750  0.750  0.250  1.0
  Sm  Sm5  1  0.750  0.251  0.251  1.0
  Sm  Sm6  1  0.251  0.251  0.251  1.0
  Sm  Sm7  1  0.251  0.750  0.251  1.0
  V  V8  1  0.001  0.001  0.001  1.0
  Cr  Cr9  1  0.500  0.000  0.001  1.0
  Cr  Cr10  1  0.000  0.500  0.001  1.0
  Cr  Cr11  1  0.500  0.500  0.001  1.0
  Cr  Cr12  1  0.000  0.000  0.499  1.0
  Cr  Cr13  1  0.500  0.000  0.499  1.0
  Cr  Cr14  1  0.000  0.500  0.499  1.0
  Cr  Cr15  1  0.500  0.500  0.499  1.0
  O  O16  1  0.999  0.999  0.748  1.0
  O  O17  1  0.500  0.000  0.750  1.0
  O  O18  1  0.000  0.500  0.750  1.0
  O  O19  1  0.500  0.500  0.750  1.0
  O  O20  1  0.003  0.003  0.252  1.0
  O  O21  1  0.498  0.002  0.250  1.0
  O  O22  1  0.002  0.498  0.250  1.0
  O  O23  1  0.498  0.498  0.250  1.0
  O  O24  1  0.001  0.252  0.005  1.0
  O  O25  1  0.500  0.250  0.004  1.0
  O  O26  1  0.001  0.748  0.001  1.0
  O  O27  1  0.498  0.750  0.002  1.0
  O  O28  1  0.000  0.250  0.496  1.0
  O  O29  1  0.500  0.250  0.496  1.0
  O  O30  1  0.002  0.750  0.498  1.0
  O  O31  1  0.498  0.750  0.498  1.0
  O  O32  1  0.748  0.001  0.001  1.0
  O  O33  1  0.252  0.001  0.005  1.0
  O  O34  1  0.750  0.498  0.002  1.0
  O  O35  1  0.250  0.500  0.004  1.0
  O  O36  1  0.750  0.002  0.498  1.0
  O  O37  1  0.250  0.000  0.496  1.0
  O  O38  1  0.750  0.498  0.498  1.0
  O  O39  1  0.250  0.500  0.496  1.0
[/CIF]
.