The crystal structure described by TlGeF3 is Potassium chlorate structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two 7440-28-0 atoms and two GeF3 clusters. In each GeF3 cluster, Ge(1) is bonded in a distorted T-shaped geometry to one F(2) and two equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ge(1) atom. is represented by the CIF card [CIF]
data_TlGeF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.782
_cell_length_b   5.843
_cell_length_c   7.156
_cell_angle_alpha   90.000
_cell_angle_beta   105.435
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   192.735
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.839  0.250  0.193  1.0
  Tl  Tl1  1  0.161  0.750  0.807  1.0
  Ge  Ge2  1  0.565  0.250  0.642  1.0
  Ge  Ge3  1  0.435  0.750  0.358  1.0
  F  F4  1  0.680  0.027  0.831  1.0
  F  F5  1  0.320  0.527  0.169  1.0
  F  F6  1  0.807  0.750  0.329  1.0
  F  F7  1  0.193  0.250  0.671  1.0
  F  F8  1  0.320  0.973  0.169  1.0
  F  F9  1  0.680  0.473  0.831  1.0
[/CIF]
.
The crystal structure described by TlGeF3 is Potassium chlorate structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two 7440-28-0 atoms and two GeF3 clusters. In each GeF3 cluster, Ge(1) is bonded in a distorted T-shaped geometry to one F(2) and two equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ge(1) atom. is represented by the CIF card [CIF]
data_TlGeF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.782
_cell_length_b   5.843
_cell_length_c   7.156
_cell_angle_alpha   90.000
_cell_angle_beta   105.435
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   192.735
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.839  0.250  0.193  1.0
  Tl  Tl1  1  0.161  0.750  0.807  1.0
  Ge  Ge2  1  0.565  0.250  0.642  1.0
  Ge  Ge3  1  0.435  0.750  0.358  1.0
  F  F4  1  0.680  0.027  0.831  1.0
  F  F5  1  0.320  0.527  0.169  1.0
  F  F6  1  0.807  0.750  0.329  1.0
  F  F7  1  0.193  0.250  0.671  1.0
  F  F8  1  0.320  0.973  0.169  1.0
  F  F9  1  0.680  0.473  0.831  1.0
[/CIF]
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