The structure described by ClCH2CH2OH is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four chloromethyl methyl ether molecules. There are two inequivalent C sites. In the first C site, C(1) is bonded to one H(2), one H(4), one H(5), and one O(1) atom to form corner-sharing CH3O tetrahedra. In the second C site, C(2) is bonded to one H(1), one H(3), one O(1), and one Cl(1) atom to form distorted corner-sharing CH2ClO tetrahedra. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. O(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. Cl(1) is bonded in a single-bond geometry to one C(2) atom. is represented by the CIF card [CIF]
data_H5C2ClO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.372
_cell_length_b   6.461
_cell_length_c   8.759
_cell_angle_alpha   66.215
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   433.508
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.843  0.595  0.933  1.0
  H  H1  1  0.477  0.950  0.652  1.0
  H  H2  1  0.295  0.514  0.179  1.0
  H  H3  1  0.657  0.595  0.433  1.0
  H  H4  1  0.205  0.514  0.679  1.0
  H  H5  1  0.977  0.050  0.848  1.0
  H  H6  1  0.705  0.486  0.821  1.0
  H  H7  1  0.343  0.405  0.567  1.0
  H  H8  1  0.774  0.146  0.803  1.0
  H  H9  1  0.726  0.146  0.303  1.0
  H  H10  1  0.274  0.854  0.697  1.0
  H  H11  1  0.795  0.486  0.321  1.0
  H  H12  1  0.157  0.405  0.067  1.0
  H  H13  1  0.932  0.292  0.660  1.0
  H  H14  1  0.023  0.950  0.152  1.0
  H  H15  1  0.068  0.708  0.340  1.0
  H  H16  1  0.523  0.050  0.348  1.0
  H  H17  1  0.568  0.292  0.160  1.0
  H  H18  1  0.226  0.854  0.197  1.0
  H  H19  1  0.432  0.708  0.840  1.0
  C  C20  1  0.900  0.199  0.792  1.0
  C  C21  1  0.330  0.478  0.659  1.0
  C  C22  1  0.170  0.478  0.159  1.0
  C  C23  1  0.830  0.522  0.841  1.0
  C  C24  1  0.600  0.199  0.292  1.0
  C  C25  1  0.100  0.801  0.208  1.0
  C  C26  1  0.670  0.522  0.341  1.0
  C  C27  1  0.400  0.801  0.708  1.0
  Cl  Cl28  1  0.612  0.754  0.139  1.0
  Cl  Cl29  1  0.888  0.754  0.639  1.0
  Cl  Cl30  1  0.112  0.246  0.361  1.0
  Cl  Cl31  1  0.388  0.246  0.861  1.0
  O  O32  1  0.428  0.663  0.616  1.0
  O  O33  1  0.572  0.337  0.384  1.0
  O  O34  1  0.928  0.337  0.884  1.0
  O  O35  1  0.072  0.663  0.116  1.0
[/CIF]
.
The structure described by ClCH2CH2OH is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four chloromethyl methyl ether molecules. There are two inequivalent C sites. In the first C site, C(1) is bonded to one H(2), one H(4), one H(5), and one O(1) atom to form corner-sharing CH3O tetrahedra. In the second C site, C(2) is bonded to one H(1), one H(3), one O(1), and one Cl(1) atom to form distorted corner-sharing CH2ClO tetrahedra. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. O(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. Cl(1) is bonded in a single-bond geometry to one C(2) atom. is represented by the CIF card [CIF]
data_H5C2ClO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.372
_cell_length_b   6.461
_cell_length_c   8.759
_cell_angle_alpha   66.215
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   433.508
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.843  0.595  0.933  1.0
  H  H1  1  0.477  0.950  0.652  1.0
  H  H2  1  0.295  0.514  0.179  1.0
  H  H3  1  0.657  0.595  0.433  1.0
  H  H4  1  0.205  0.514  0.679  1.0
  H  H5  1  0.977  0.050  0.848  1.0
  H  H6  1  0.705  0.486  0.821  1.0
  H  H7  1  0.343  0.405  0.567  1.0
  H  H8  1  0.774  0.146  0.803  1.0
  H  H9  1  0.726  0.146  0.303  1.0
  H  H10  1  0.274  0.854  0.697  1.0
  H  H11  1  0.795  0.486  0.321  1.0
  H  H12  1  0.157  0.405  0.067  1.0
  H  H13  1  0.932  0.292  0.660  1.0
  H  H14  1  0.023  0.950  0.152  1.0
  H  H15  1  0.068  0.708  0.340  1.0
  H  H16  1  0.523  0.050  0.348  1.0
  H  H17  1  0.568  0.292  0.160  1.0
  H  H18  1  0.226  0.854  0.197  1.0
  H  H19  1  0.432  0.708  0.840  1.0
  C  C20  1  0.900  0.199  0.792  1.0
  C  C21  1  0.330  0.478  0.659  1.0
  C  C22  1  0.170  0.478  0.159  1.0
  C  C23  1  0.830  0.522  0.841  1.0
  C  C24  1  0.600  0.199  0.292  1.0
  C  C25  1  0.100  0.801  0.208  1.0
  C  C26  1  0.670  0.522  0.341  1.0
  C  C27  1  0.400  0.801  0.708  1.0
  Cl  Cl28  1  0.612  0.754  0.139  1.0
  Cl  Cl29  1  0.888  0.754  0.639  1.0
  Cl  Cl30  1  0.112  0.246  0.361  1.0
  Cl  Cl31  1  0.388  0.246  0.861  1.0
  O  O32  1  0.428  0.663  0.616  1.0
  O  O33  1  0.572  0.337  0.384  1.0
  O  O34  1  0.928  0.337  0.884  1.0
  O  O35  1  0.072  0.663  0.116  1.0
[/CIF]
.