The compound described by OsSeS3Cl4 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two OsSeS3Cl4 clusters. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in an octahedral geometry to one S(4), one S(5), one S(6), one Cl(1), one Cl(2), and one Cl(8) atom. In the second Os site, Os(2) is bonded in a 6-coordinate geometry to one Se(1), one S(3), one S(4), one S(6), one Cl(5), and one Cl(7) atom. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a 5-coordinate geometry to one Os(2), one Cl(4), one Cl(5), one Cl(6), and one Cl(7) atom. In the second Se site, Se(2) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(6) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Se(2) and one S(5) atom. In the second S site, S(2) is bonded in a water-like geometry to one Se(2) and one S(3) atom. In the third S site, S(3) is bonded in a 2-coordinate geometry to one Os(2) and one S(2) atom. In the fourth S site, S(4) is bonded in a distorted trigonal non-coplanar geometry to one Os(1), one Os(2), and one Cl(3) atom. In the fifth S site, S(5) is bonded in a 2-coordinate geometry to one Os(1) and one S(1) atom. In the sixth S site, S(6) is bonded in a 3-coordinate geometry to one Os(1), one Os(2), and one Se(2) atom. There are eight inequivalent Cl sites. In the first Cl site, Cl(7) is bonded in a 2-coordinate geometry to one Os(2) and one Se(1) atom. In the second Cl site, Cl(8) is bonded in a single-bond geometry to one Os(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Os(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Os(1) atom. In the fifth Cl site, Cl(3) is bonded in a single-bond geometry to one S(4) atom. In the sixth Cl site, Cl(4) is bonded in a single-bond geometry to one Se(1) atom. In the seventh Cl site, Cl(5) is bonded in a distorted single-bond geometry to one Os(2) and one Se(1) atom. In the eighth Cl site, Cl(6) is bonded in a single-bond geometry to one Se(1) atom. is represented by the CIF file [CIF]
data_OsSeS3Cl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.316
_cell_length_b   9.568
_cell_length_c   11.879
_cell_angle_alpha   74.184
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1018.786
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.802  0.048  0.775  1.0
  Os  Os1  1  0.302  0.952  0.225  1.0
  Os  Os2  1  0.671  0.311  0.709  1.0
  Os  Os3  1  0.171  0.689  0.291  1.0
  Se  Se4  1  0.797  0.504  0.786  1.0
  Se  Se5  1  0.297  0.496  0.214  1.0
  Se  Se6  1  0.393  0.013  0.867  1.0
  Se  Se7  1  0.893  0.987  0.133  1.0
  S  S8  1  0.979  0.151  0.219  1.0
  S  S9  1  0.479  0.849  0.781  1.0
  S  S10  1  0.321  0.166  0.695  1.0
  S  S11  1  0.821  0.834  0.305  1.0
  S  S12  1  0.506  0.224  0.604  1.0
  S  S13  1  0.006  0.776  0.396  1.0
  S  S14  1  0.862  0.240  0.620  1.0
  S  S15  1  0.362  0.760  0.380  1.0
  S  S16  1  0.641  0.953  0.676  1.0
  S  S17  1  0.141  0.047  0.324  1.0
  S  S18  1  0.640  0.137  0.877  1.0
  S  S19  1  0.140  0.863  0.123  1.0
  Cl  Cl20  1  0.484  0.078  0.306  1.0
  Cl  Cl21  1  0.984  0.922  0.694  1.0
  Cl  Cl22  1  0.002  0.123  0.878  1.0
  Cl  Cl23  1  0.502  0.877  0.122  1.0
  Cl  Cl24  1  0.810  0.205  0.459  1.0
  Cl  Cl25  1  0.310  0.795  0.541  1.0
  Cl  Cl26  1  0.813  0.420  0.978  1.0
  Cl  Cl27  1  0.313  0.580  0.022  1.0
  Cl  Cl28  1  0.498  0.450  0.786  1.0
  Cl  Cl29  1  0.998  0.550  0.214  1.0
  Cl  Cl30  1  0.026  0.512  0.741  1.0
  Cl  Cl31  1  0.526  0.488  0.259  1.0
  Cl  Cl32  1  0.696  0.542  0.558  1.0
  Cl  Cl33  1  0.196  0.458  0.442  1.0
  Cl  Cl34  1  0.802  0.830  0.934  1.0
  Cl  Cl35  1  0.302  0.170  0.066  1.0
[/CIF]
.
The compound described by OsSeS3Cl4 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two OsSeS3Cl4 clusters. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in an octahedral geometry to one S(4), one S(5), one S(6), one Cl(1), one Cl(2), and one Cl(8) atom. In the second Os site, Os(2) is bonded in a 6-coordinate geometry to one Se(1), one S(3), one S(4), one S(6), one Cl(5), and one Cl(7) atom. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a 5-coordinate geometry to one Os(2), one Cl(4), one Cl(5), one Cl(6), and one Cl(7) atom. In the second Se site, Se(2) is bonded in a 3-coordinate geometry to one S(1), one S(2), and one S(6) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Se(2) and one S(5) atom. In the second S site, S(2) is bonded in a water-like geometry to one Se(2) and one S(3) atom. In the third S site, S(3) is bonded in a 2-coordinate geometry to one Os(2) and one S(2) atom. In the fourth S site, S(4) is bonded in a distorted trigonal non-coplanar geometry to one Os(1), one Os(2), and one Cl(3) atom. In the fifth S site, S(5) is bonded in a 2-coordinate geometry to one Os(1) and one S(1) atom. In the sixth S site, S(6) is bonded in a 3-coordinate geometry to one Os(1), one Os(2), and one Se(2) atom. There are eight inequivalent Cl sites. In the first Cl site, Cl(7) is bonded in a 2-coordinate geometry to one Os(2) and one Se(1) atom. In the second Cl site, Cl(8) is bonded in a single-bond geometry to one Os(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Os(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Os(1) atom. In the fifth Cl site, Cl(3) is bonded in a single-bond geometry to one S(4) atom. In the sixth Cl site, Cl(4) is bonded in a single-bond geometry to one Se(1) atom. In the seventh Cl site, Cl(5) is bonded in a distorted single-bond geometry to one Os(2) and one Se(1) atom. In the eighth Cl site, Cl(6) is bonded in a single-bond geometry to one Se(1) atom. is represented by the CIF file [CIF]
data_OsSeS3Cl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.316
_cell_length_b   9.568
_cell_length_c   11.879
_cell_angle_alpha   74.184
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1018.786
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.802  0.048  0.775  1.0
  Os  Os1  1  0.302  0.952  0.225  1.0
  Os  Os2  1  0.671  0.311  0.709  1.0
  Os  Os3  1  0.171  0.689  0.291  1.0
  Se  Se4  1  0.797  0.504  0.786  1.0
  Se  Se5  1  0.297  0.496  0.214  1.0
  Se  Se6  1  0.393  0.013  0.867  1.0
  Se  Se7  1  0.893  0.987  0.133  1.0
  S  S8  1  0.979  0.151  0.219  1.0
  S  S9  1  0.479  0.849  0.781  1.0
  S  S10  1  0.321  0.166  0.695  1.0
  S  S11  1  0.821  0.834  0.305  1.0
  S  S12  1  0.506  0.224  0.604  1.0
  S  S13  1  0.006  0.776  0.396  1.0
  S  S14  1  0.862  0.240  0.620  1.0
  S  S15  1  0.362  0.760  0.380  1.0
  S  S16  1  0.641  0.953  0.676  1.0
  S  S17  1  0.141  0.047  0.324  1.0
  S  S18  1  0.640  0.137  0.877  1.0
  S  S19  1  0.140  0.863  0.123  1.0
  Cl  Cl20  1  0.484  0.078  0.306  1.0
  Cl  Cl21  1  0.984  0.922  0.694  1.0
  Cl  Cl22  1  0.002  0.123  0.878  1.0
  Cl  Cl23  1  0.502  0.877  0.122  1.0
  Cl  Cl24  1  0.810  0.205  0.459  1.0
  Cl  Cl25  1  0.310  0.795  0.541  1.0
  Cl  Cl26  1  0.813  0.420  0.978  1.0
  Cl  Cl27  1  0.313  0.580  0.022  1.0
  Cl  Cl28  1  0.498  0.450  0.786  1.0
  Cl  Cl29  1  0.998  0.550  0.214  1.0
  Cl  Cl30  1  0.026  0.512  0.741  1.0
  Cl  Cl31  1  0.526  0.488  0.259  1.0
  Cl  Cl32  1  0.696  0.542  0.558  1.0
  Cl  Cl33  1  0.196  0.458  0.442  1.0
  Cl  Cl34  1  0.802  0.830  0.934  1.0
  Cl  Cl35  1  0.302  0.170  0.066  1.0
[/CIF]
.