The material described by TbGaO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Tb(1) is bonded in a 8-coordinate geometry to two equivalent O(1) and six equivalent O(2) atoms. Ga(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 34-36°. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Tb(1) and two equivalent Ga(1) atoms to form distorted corner-sharing OTb2Ga2 trigonal pyramids. In the second O site, O(2) is bonded in a 5-coordinate geometry to three equivalent Tb(1) and two equivalent Ga(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_TbGaO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.321
_cell_length_b   5.604
_cell_length_c   7.660
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   228.397
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.019  0.066  0.750  1.0
  Tb  Tb1  1  0.481  0.566  0.750  1.0
  Tb  Tb2  1  0.519  0.434  0.250  1.0
  Tb  Tb3  1  0.981  0.934  0.250  1.0
  Ga  Ga4  1  0.000  0.500  0.500  1.0
  Ga  Ga5  1  0.500  0.000  0.500  1.0
  Ga  Ga6  1  0.500  0.000  0.000  1.0
  Ga  Ga7  1  0.000  0.500  0.000  1.0
  O  O8  1  0.109  0.537  0.250  1.0
  O  O9  1  0.196  0.802  0.556  1.0
  O  O10  1  0.196  0.802  0.944  1.0
  O  O11  1  0.304  0.302  0.944  1.0
  O  O12  1  0.304  0.302  0.556  1.0
  O  O13  1  0.391  0.037  0.250  1.0
  O  O14  1  0.609  0.963  0.750  1.0
  O  O15  1  0.696  0.698  0.056  1.0
  O  O16  1  0.696  0.698  0.444  1.0
  O  O17  1  0.804  0.198  0.444  1.0
  O  O18  1  0.804  0.198  0.056  1.0
  O  O19  1  0.891  0.463  0.750  1.0
[/CIF]
.
The material described by TbGaO3 is Orthorhombic Perovskite structured and crystallizes in the orthorhombic Pnma space group. Tb(1) is bonded in a 8-coordinate geometry to two equivalent O(1) and six equivalent O(2) atoms. Ga(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form corner-sharing GaO6 octahedra. The corner-sharing octahedral tilt angles range from 34-36°. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Tb(1) and two equivalent Ga(1) atoms to form distorted corner-sharing OTb2Ga2 trigonal pyramids. In the second O site, O(2) is bonded in a 5-coordinate geometry to three equivalent Tb(1) and two equivalent Ga(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_TbGaO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.321
_cell_length_b   5.604
_cell_length_c   7.660
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   228.397
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.019  0.066  0.750  1.0
  Tb  Tb1  1  0.481  0.566  0.750  1.0
  Tb  Tb2  1  0.519  0.434  0.250  1.0
  Tb  Tb3  1  0.981  0.934  0.250  1.0
  Ga  Ga4  1  0.000  0.500  0.500  1.0
  Ga  Ga5  1  0.500  0.000  0.500  1.0
  Ga  Ga6  1  0.500  0.000  0.000  1.0
  Ga  Ga7  1  0.000  0.500  0.000  1.0
  O  O8  1  0.109  0.537  0.250  1.0
  O  O9  1  0.196  0.802  0.556  1.0
  O  O10  1  0.196  0.802  0.944  1.0
  O  O11  1  0.304  0.302  0.944  1.0
  O  O12  1  0.304  0.302  0.556  1.0
  O  O13  1  0.391  0.037  0.250  1.0
  O  O14  1  0.609  0.963  0.750  1.0
  O  O15  1  0.696  0.698  0.056  1.0
  O  O16  1  0.696  0.698  0.444  1.0
  O  O17  1  0.804  0.198  0.444  1.0
  O  O18  1  0.804  0.198  0.056  1.0
  O  O19  1  0.891  0.463  0.750  1.0
[/CIF]
.