The material structure described by AgZnBiO5 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(5), and two equivalent O(2) atoms. Zn(1) is bonded to one O(1), one O(3), one O(5), and two equivalent O(4) atoms to form distorted ZnO5 square pyramids that share corners with three equivalent Bi(1)O6 octahedra, edges with two equivalent Bi(1)O6 octahedra, and  an edgeedge with one Zn(1)O5 square pyramid. The corner-sharing octahedral tilt angles range from 31-67°. Bi(1) is bonded to one O(1), one O(2), one O(3), one O(5), and two equivalent O(4) atoms to form distorted BiO6 octahedra that share corners with three equivalent Zn(1)O5 square pyramids,  an edgeedge with one Bi(1)O6 octahedra, and edges with two equivalent Zn(1)O5 square pyramids. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ag(1), one Zn(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent Ag(1) and one Bi(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Ag(1), one Zn(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to two equivalent Zn(1) and two equivalent Bi(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Zn(1), and one Bi(1) atom. is represented by the CIF card [CIF]
data_ZnAgBiO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.662
_cell_length_b   5.474
_cell_length_c   9.119
_cell_angle_alpha   64.136
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   478.943
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.081  0.595  0.834  1.0
  Zn  Zn1  1  0.919  0.405  0.166  1.0
  Zn  Zn2  1  0.581  0.405  0.666  1.0
  Zn  Zn3  1  0.419  0.595  0.334  1.0
  Ag  Ag4  1  0.382  0.286  0.021  1.0
  Ag  Ag5  1  0.618  0.714  0.979  1.0
  Ag  Ag6  1  0.882  0.714  0.479  1.0
  Ag  Ag7  1  0.118  0.286  0.521  1.0
  Bi  Bi8  1  0.887  0.016  0.858  1.0
  Bi  Bi9  1  0.113  0.984  0.142  1.0
  Bi  Bi10  1  0.613  0.016  0.358  1.0
  Bi  Bi11  1  0.387  0.984  0.642  1.0
  O  O12  1  0.936  0.808  0.724  1.0
  O  O13  1  0.969  0.366  0.647  1.0
  O  O14  1  0.809  0.081  0.310  1.0
  O  O15  1  0.454  0.754  0.513  1.0
  O  O16  1  0.704  0.693  0.572  1.0
  O  O17  1  0.796  0.693  0.072  1.0
  O  O18  1  0.531  0.366  0.147  1.0
  O  O19  1  0.469  0.634  0.853  1.0
  O  O20  1  0.546  0.246  0.487  1.0
  O  O21  1  0.436  0.192  0.776  1.0
  O  O22  1  0.296  0.307  0.428  1.0
  O  O23  1  0.064  0.192  0.276  1.0
  O  O24  1  0.564  0.808  0.224  1.0
  O  O25  1  0.204  0.307  0.928  1.0
  O  O26  1  0.954  0.246  0.987  1.0
  O  O27  1  0.046  0.754  0.013  1.0
  O  O28  1  0.191  0.919  0.690  1.0
  O  O29  1  0.031  0.634  0.353  1.0
  O  O30  1  0.309  0.919  0.190  1.0
  O  O31  1  0.691  0.081  0.810  1.0
[/CIF]
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The material structure described by AgZnBiO5 crystallizes in the monoclinic P2_1/c space group. Ag(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(5), and two equivalent O(2) atoms. Zn(1) is bonded to one O(1), one O(3), one O(5), and two equivalent O(4) atoms to form distorted ZnO5 square pyramids that share corners with three equivalent Bi(1)O6 octahedra, edges with two equivalent Bi(1)O6 octahedra, and  an edgeedge with one Zn(1)O5 square pyramid. The corner-sharing octahedral tilt angles range from 31-67°. Bi(1) is bonded to one O(1), one O(2), one O(3), one O(5), and two equivalent O(4) atoms to form distorted BiO6 octahedra that share corners with three equivalent Zn(1)O5 square pyramids,  an edgeedge with one Bi(1)O6 octahedra, and edges with two equivalent Zn(1)O5 square pyramids. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ag(1), one Zn(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent Ag(1) and one Bi(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Ag(1), one Zn(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to two equivalent Zn(1) and two equivalent Bi(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Zn(1), and one Bi(1) atom. is represented by the CIF card [CIF]
data_ZnAgBiO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.662
_cell_length_b   5.474
_cell_length_c   9.119
_cell_angle_alpha   64.136
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   478.943
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.081  0.595  0.834  1.0
  Zn  Zn1  1  0.919  0.405  0.166  1.0
  Zn  Zn2  1  0.581  0.405  0.666  1.0
  Zn  Zn3  1  0.419  0.595  0.334  1.0
  Ag  Ag4  1  0.382  0.286  0.021  1.0
  Ag  Ag5  1  0.618  0.714  0.979  1.0
  Ag  Ag6  1  0.882  0.714  0.479  1.0
  Ag  Ag7  1  0.118  0.286  0.521  1.0
  Bi  Bi8  1  0.887  0.016  0.858  1.0
  Bi  Bi9  1  0.113  0.984  0.142  1.0
  Bi  Bi10  1  0.613  0.016  0.358  1.0
  Bi  Bi11  1  0.387  0.984  0.642  1.0
  O  O12  1  0.936  0.808  0.724  1.0
  O  O13  1  0.969  0.366  0.647  1.0
  O  O14  1  0.809  0.081  0.310  1.0
  O  O15  1  0.454  0.754  0.513  1.0
  O  O16  1  0.704  0.693  0.572  1.0
  O  O17  1  0.796  0.693  0.072  1.0
  O  O18  1  0.531  0.366  0.147  1.0
  O  O19  1  0.469  0.634  0.853  1.0
  O  O20  1  0.546  0.246  0.487  1.0
  O  O21  1  0.436  0.192  0.776  1.0
  O  O22  1  0.296  0.307  0.428  1.0
  O  O23  1  0.064  0.192  0.276  1.0
  O  O24  1  0.564  0.808  0.224  1.0
  O  O25  1  0.204  0.307  0.928  1.0
  O  O26  1  0.954  0.246  0.987  1.0
  O  O27  1  0.046  0.754  0.013  1.0
  O  O28  1  0.191  0.919  0.690  1.0
  O  O29  1  0.031  0.634  0.353  1.0
  O  O30  1  0.309  0.919  0.190  1.0
  O  O31  1  0.691  0.081  0.810  1.0
[/CIF]
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