The structure described by WP4O12 crystallizes in the monoclinic C2/m space group. W(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form WO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with four equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(4), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 36°. In the second P site, P(2) is bonded to one O(3), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-44°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one W(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one P(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to two equivalent P(2) atoms. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one W(1) and one P(2) atom. is represented by the CIF file [CIF]
data_P4WO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.593
_cell_length_b   10.593
_cell_length_c   5.380
_cell_angle_alpha   81.469
_cell_angle_beta   81.469
_cell_angle_gamma   71.576
_symmetry_Int_Tables_number   1
_cell_volume   563.077
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.781  0.367  0.819  1.0
  P  P1  1  0.367  0.781  0.819  1.0
  P  P2  1  0.702  0.946  0.461  1.0
  P  P3  1  0.946  0.702  0.461  1.0
  P  P4  1  0.054  0.298  0.539  1.0
  P  P5  1  0.298  0.054  0.539  1.0
  P  P6  1  0.219  0.633  0.181  1.0
  P  P7  1  0.633  0.219  0.181  1.0
  W  W8  1  0.500  0.000  0.000  1.0
  W  W9  1  0.000  0.500  0.000  1.0
  O  O10  1  0.439  0.840  0.980  1.0
  O  O11  1  0.840  0.439  0.980  1.0
  O  O12  1  0.236  0.764  0.000  1.0
  O  O13  1  0.764  0.236  0.000  1.0
  O  O14  1  0.667  0.931  0.747  1.0
  O  O15  1  0.931  0.667  0.747  1.0
  O  O16  1  0.669  0.444  0.678  1.0
  O  O17  1  0.444  0.669  0.678  1.0
  O  O18  1  0.282  0.912  0.631  1.0
  O  O19  1  0.912  0.282  0.631  1.0
  O  O20  1  0.854  0.854  0.408  1.0
  O  O21  1  0.388  0.091  0.689  1.0
  O  O22  1  0.091  0.388  0.689  1.0
  O  O23  1  0.612  0.909  0.311  1.0
  O  O24  1  0.909  0.612  0.311  1.0
  O  O25  1  0.146  0.146  0.592  1.0
  O  O26  1  0.088  0.718  0.369  1.0
  O  O27  1  0.718  0.088  0.369  1.0
  O  O28  1  0.556  0.331  0.322  1.0
  O  O29  1  0.331  0.556  0.322  1.0
  O  O30  1  0.069  0.333  0.253  1.0
  O  O31  1  0.333  0.069  0.253  1.0
  O  O32  1  0.561  0.160  0.020  1.0
  O  O33  1  0.160  0.561  0.020  1.0
[/CIF]
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The structure described by WP4O12 crystallizes in the monoclinic C2/m space group. W(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form WO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra and corners with four equivalent P(2)O4 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(4), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 36°. In the second P site, P(2) is bonded to one O(3), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent W(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-44°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one W(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one P(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to two equivalent P(2) atoms. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one W(1) and one P(2) atom. is represented by the CIF file [CIF]
data_P4WO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.593
_cell_length_b   10.593
_cell_length_c   5.380
_cell_angle_alpha   81.469
_cell_angle_beta   81.469
_cell_angle_gamma   71.576
_symmetry_Int_Tables_number   1
_cell_volume   563.077
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.781  0.367  0.819  1.0
  P  P1  1  0.367  0.781  0.819  1.0
  P  P2  1  0.702  0.946  0.461  1.0
  P  P3  1  0.946  0.702  0.461  1.0
  P  P4  1  0.054  0.298  0.539  1.0
  P  P5  1  0.298  0.054  0.539  1.0
  P  P6  1  0.219  0.633  0.181  1.0
  P  P7  1  0.633  0.219  0.181  1.0
  W  W8  1  0.500  0.000  0.000  1.0
  W  W9  1  0.000  0.500  0.000  1.0
  O  O10  1  0.439  0.840  0.980  1.0
  O  O11  1  0.840  0.439  0.980  1.0
  O  O12  1  0.236  0.764  0.000  1.0
  O  O13  1  0.764  0.236  0.000  1.0
  O  O14  1  0.667  0.931  0.747  1.0
  O  O15  1  0.931  0.667  0.747  1.0
  O  O16  1  0.669  0.444  0.678  1.0
  O  O17  1  0.444  0.669  0.678  1.0
  O  O18  1  0.282  0.912  0.631  1.0
  O  O19  1  0.912  0.282  0.631  1.0
  O  O20  1  0.854  0.854  0.408  1.0
  O  O21  1  0.388  0.091  0.689  1.0
  O  O22  1  0.091  0.388  0.689  1.0
  O  O23  1  0.612  0.909  0.311  1.0
  O  O24  1  0.909  0.612  0.311  1.0
  O  O25  1  0.146  0.146  0.592  1.0
  O  O26  1  0.088  0.718  0.369  1.0
  O  O27  1  0.718  0.088  0.369  1.0
  O  O28  1  0.556  0.331  0.322  1.0
  O  O29  1  0.331  0.556  0.322  1.0
  O  O30  1  0.069  0.333  0.253  1.0
  O  O31  1  0.333  0.069  0.253  1.0
  O  O32  1  0.561  0.160  0.020  1.0
  O  O33  1  0.160  0.561  0.020  1.0
[/CIF]
.