The compound described by ZnS is Moissanite-4H structured and crystallizes in the hexagonal P6_3mc space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one S(1) and three equivalent S(2) atoms to form corner-sharing ZnS4 tetrahedra. In the second Zn site, Zn(2) is bonded to one S(2) and three equivalent S(1) atoms to form corner-sharing ZnS4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one Zn(1) and three equivalent Zn(2) atoms to form corner-sharing SZn4 tetrahedra. In the second S site, S(2) is bonded to one Zn(2) and three equivalent Zn(1) atoms to form corner-sharing SZn4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.809
_cell_length_b   3.809
_cell_length_c   12.453
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   156.459
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.667  0.333  0.750  1.0
  Zn  Zn1  1  0.333  0.667  0.250  1.0
  Zn  Zn2  1  0.000  0.000  0.500  1.0
  Zn  Zn3  1  0.000  0.000  0.000  1.0
  S  S4  1  0.667  0.333  0.938  1.0
  S  S5  1  0.333  0.667  0.438  1.0
  S  S6  1  0.000  0.000  0.687  1.0
  S  S7  1  0.000  0.000  0.187  1.0
[/CIF]
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The compound described by ZnS is Moissanite-4H structured and crystallizes in the hexagonal P6_3mc space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one S(1) and three equivalent S(2) atoms to form corner-sharing ZnS4 tetrahedra. In the second Zn site, Zn(2) is bonded to one S(2) and three equivalent S(1) atoms to form corner-sharing ZnS4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one Zn(1) and three equivalent Zn(2) atoms to form corner-sharing SZn4 tetrahedra. In the second S site, S(2) is bonded to one Zn(2) and three equivalent Zn(1) atoms to form corner-sharing SZn4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.809
_cell_length_b   3.809
_cell_length_c   12.453
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   156.459
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.667  0.333  0.750  1.0
  Zn  Zn1  1  0.333  0.667  0.250  1.0
  Zn  Zn2  1  0.000  0.000  0.500  1.0
  Zn  Zn3  1  0.000  0.000  0.000  1.0
  S  S4  1  0.667  0.333  0.938  1.0
  S  S5  1  0.333  0.667  0.438  1.0
  S  S6  1  0.000  0.000  0.687  1.0
  S  S7  1  0.000  0.000  0.187  1.0
[/CIF]
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