The crystal structure described by Li4V3Mn5O16 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra, and corners with three equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-64°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, and corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-65°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-52°. In the second V site, V(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. In the third V site, V(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and edges with two equivalent Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the second Mn site, Mn(2) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. In the third Mn site, Mn(3) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-56°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-55°. In the fifth Mn site, Mn(5) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Mn(1), and one Mn(4) atom. In the second O site, O(2) is bonded to one Li(4), one V(1), one V(2), and one Mn(1) atom to form distorted OLiMnV2 tetrahedra that share  a cornercorner with one O(8)LiMn2V tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra,  a cornercorner with one O(7)LiMn2V trigonal pyramid,  an edgeedge with one O(8)LiMn2V tetrahedra,  an edgeedge with one O(7)LiMn2V trigonal pyramid, and  an edgeedge with one O(3)LiMnV2 trigonal pyramid. In the third O site, O(3) is bonded to one Li(1), one V(1), one V(2), and one Mn(2) atom to form distorted OLiMnV2 trigonal pyramids that share  a cornercorner with one O(12)LiMn2V tetrahedra,  a cornercorner with one O(15)LiMn3 tetrahedra, corners with three equivalent O(4)LiMnV2 tetrahedra,  an edgeedge with one O(8)LiMn2V tetrahedra,  an edgeedge with one O(2)LiMnV2 tetrahedra, and  an edgeedge with one O(7)LiMn2V trigonal pyramid. In the fourth O site, O(4) is bonded to one Li(3), one V(1), one V(2), and one Mn(2) atom to form distorted OLiMnV2 tetrahedra that share corners with two equivalent O(8)LiMn2V tetrahedra, corners with two equivalent O(2)LiMnV2 tetrahedra, corners with two equivalent O(7)LiMn2V trigonal pyramids, and corners with three equivalent O(3)LiMnV2 trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), one V(3), one Mn(4), and one Mn(5) atom to form distorted OLiMn2V tetrahedra that share corners with two equivalent O(12)LiMn2V tetrahedra and corners with two equivalent O(15)LiMn3 tetrahedra. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Mn(1), and one Mn(5) atom. In the seventh O site, O(7) is bonded to one Li(4), one V(1), one Mn(1), and one Mn(2) atom to form distorted OLiMn2V trigonal pyramids that share  a cornercorner with one O(8)LiMn2V tetrahedra,  a cornercorner with one O(2)LiMnV2 tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra,  an edgeedge with one O(8)LiMn2V tetrahedra,  an edgeedge with one O(2)LiMnV2 tetrahedra, and  an edgeedge with one O(3)LiMnV2 trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(4), one V(2), one Mn(1), and one Mn(2) atom to form distorted OLiMn2V tetrahedra that share  a cornercorner with one O(2)LiMnV2 tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra,  a cornercorner with one O(7)LiMn2V trigonal pyramid,  an edgeedge with one O(2)LiMnV2 tetrahedra,  an edgeedge with one O(7)LiMn2V trigonal pyramid, and  an edgeedge with one O(3)LiMnV2 trigonal pyramid. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one V(2), and one Mn(3) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(1), one Mn(4), and one Mn(5) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(1), one V(3), one Mn(3), and one Mn(4) atom. In the twelfth O site, O(12) is bonded to one Li(1), one V(3), one Mn(3), and one Mn(5) atom to form distorted OLiMn2V tetrahedra that share  a cornercorner with one O(15)LiMn3 tetrahedra, corners with two equivalent O(5)LiMn2V tetrahedra,  a cornercorner with one O(3)LiMnV2 trigonal pyramid, and  an edgeedge with one O(15)LiMn3 tetrahedra. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(3), one Mn(4), and one Mn(5) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one Mn(2), and one Mn(3) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one Mn(3), one Mn(4), and one Mn(5) atom to form distorted OLiMn3 tetrahedra that share  a cornercorner with one O(12)LiMn2V tetrahedra, corners with two equivalent O(5)LiMn2V tetrahedra,  a cornercorner with one O(3)LiMnV2 trigonal pyramid, and  an edgeedge with one O(12)LiMn2V tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Mn(2), and one Mn(3) atom. is represented by the CIF card [CIF]
data_Li4Mn5V3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.798
_cell_length_b   5.964
_cell_length_c   9.656
_cell_angle_alpha   89.815
_cell_angle_beta   91.351
_cell_angle_gamma   118.357
_symmetry_Int_Tables_number   1
_cell_volume   293.768
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.671  0.336  0.896  1.0
  Li  Li1  1  0.986  0.972  0.994  1.0
  Li  Li2  1  0.997  0.021  0.495  1.0
  Li  Li3  1  0.339  0.667  0.397  1.0
  Mn  Mn4  1  0.673  0.351  0.487  1.0
  Mn  Mn5  1  0.830  0.154  0.212  1.0
  Mn  Mn6  1  0.326  0.646  0.987  1.0
  Mn  Mn7  1  0.669  0.844  0.714  1.0
  Mn  Mn8  1  0.171  0.357  0.714  1.0
  V  V9  1  0.828  0.645  0.215  1.0
  V  V10  1  0.334  0.147  0.213  1.0
  V  V11  1  0.186  0.862  0.713  1.0
  O  O12  1  0.857  0.707  0.608  1.0
  O  O13  1  0.511  0.467  0.339  1.0
  O  O14  1  0.663  0.317  0.106  1.0
  O  O15  1  0.994  0.985  0.310  1.0
  O  O16  1  0.011  0.032  0.809  1.0
  O  O17  1  0.325  0.180  0.604  1.0
  O  O18  1  0.964  0.498  0.342  1.0
  O  O19  1  0.513  0.028  0.331  1.0
  O  O20  1  0.160  0.815  0.104  1.0
  O  O21  1  0.847  0.197  0.598  1.0
  O  O22  1  0.482  0.978  0.827  1.0
  O  O23  1  0.044  0.535  0.837  1.0
  O  O24  1  0.330  0.670  0.609  1.0
  O  O25  1  0.661  0.788  0.098  1.0
  O  O26  1  0.471  0.514  0.844  1.0
  O  O27  1  0.156  0.288  0.105  1.0
[/CIF]
.
The crystal structure described by Li4V3Mn5O16 is Hausmannite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra, and corners with three equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-64°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(5)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, and corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-65°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-52°. In the second V site, V(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. In the third V site, V(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and edges with two equivalent Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the second Mn site, Mn(2) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Mn(3)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. In the third Mn site, Mn(3) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra, and  an edgeedge with one Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-56°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-55°. In the fifth Mn site, Mn(5) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Mn(3)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Mn(1), and one Mn(4) atom. In the second O site, O(2) is bonded to one Li(4), one V(1), one V(2), and one Mn(1) atom to form distorted OLiMnV2 tetrahedra that share  a cornercorner with one O(8)LiMn2V tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra,  a cornercorner with one O(7)LiMn2V trigonal pyramid,  an edgeedge with one O(8)LiMn2V tetrahedra,  an edgeedge with one O(7)LiMn2V trigonal pyramid, and  an edgeedge with one O(3)LiMnV2 trigonal pyramid. In the third O site, O(3) is bonded to one Li(1), one V(1), one V(2), and one Mn(2) atom to form distorted OLiMnV2 trigonal pyramids that share  a cornercorner with one O(12)LiMn2V tetrahedra,  a cornercorner with one O(15)LiMn3 tetrahedra, corners with three equivalent O(4)LiMnV2 tetrahedra,  an edgeedge with one O(8)LiMn2V tetrahedra,  an edgeedge with one O(2)LiMnV2 tetrahedra, and  an edgeedge with one O(7)LiMn2V trigonal pyramid. In the fourth O site, O(4) is bonded to one Li(3), one V(1), one V(2), and one Mn(2) atom to form distorted OLiMnV2 tetrahedra that share corners with two equivalent O(8)LiMn2V tetrahedra, corners with two equivalent O(2)LiMnV2 tetrahedra, corners with two equivalent O(7)LiMn2V trigonal pyramids, and corners with three equivalent O(3)LiMnV2 trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), one V(3), one Mn(4), and one Mn(5) atom to form distorted OLiMn2V tetrahedra that share corners with two equivalent O(12)LiMn2V tetrahedra and corners with two equivalent O(15)LiMn3 tetrahedra. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Mn(1), and one Mn(5) atom. In the seventh O site, O(7) is bonded to one Li(4), one V(1), one Mn(1), and one Mn(2) atom to form distorted OLiMn2V trigonal pyramids that share  a cornercorner with one O(8)LiMn2V tetrahedra,  a cornercorner with one O(2)LiMnV2 tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra,  an edgeedge with one O(8)LiMn2V tetrahedra,  an edgeedge with one O(2)LiMnV2 tetrahedra, and  an edgeedge with one O(3)LiMnV2 trigonal pyramid. In the eighth O site, O(8) is bonded to one Li(4), one V(2), one Mn(1), and one Mn(2) atom to form distorted OLiMn2V tetrahedra that share  a cornercorner with one O(2)LiMnV2 tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra,  a cornercorner with one O(7)LiMn2V trigonal pyramid,  an edgeedge with one O(2)LiMnV2 tetrahedra,  an edgeedge with one O(7)LiMn2V trigonal pyramid, and  an edgeedge with one O(3)LiMnV2 trigonal pyramid. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one V(2), and one Mn(3) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(1), one Mn(4), and one Mn(5) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(1), one V(3), one Mn(3), and one Mn(4) atom. In the twelfth O site, O(12) is bonded to one Li(1), one V(3), one Mn(3), and one Mn(5) atom to form distorted OLiMn2V tetrahedra that share  a cornercorner with one O(15)LiMn3 tetrahedra, corners with two equivalent O(5)LiMn2V tetrahedra,  a cornercorner with one O(3)LiMnV2 trigonal pyramid, and  an edgeedge with one O(15)LiMn3 tetrahedra. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(3), one Mn(4), and one Mn(5) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one Mn(2), and one Mn(3) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one Mn(3), one Mn(4), and one Mn(5) atom to form distorted OLiMn3 tetrahedra that share  a cornercorner with one O(12)LiMn2V tetrahedra, corners with two equivalent O(5)LiMn2V tetrahedra,  a cornercorner with one O(3)LiMnV2 trigonal pyramid, and  an edgeedge with one O(12)LiMn2V tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Mn(2), and one Mn(3) atom. is represented by the CIF card [CIF]
data_Li4Mn5V3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.798
_cell_length_b   5.964
_cell_length_c   9.656
_cell_angle_alpha   89.815
_cell_angle_beta   91.351
_cell_angle_gamma   118.357
_symmetry_Int_Tables_number   1
_cell_volume   293.768
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.671  0.336  0.896  1.0
  Li  Li1  1  0.986  0.972  0.994  1.0
  Li  Li2  1  0.997  0.021  0.495  1.0
  Li  Li3  1  0.339  0.667  0.397  1.0
  Mn  Mn4  1  0.673  0.351  0.487  1.0
  Mn  Mn5  1  0.830  0.154  0.212  1.0
  Mn  Mn6  1  0.326  0.646  0.987  1.0
  Mn  Mn7  1  0.669  0.844  0.714  1.0
  Mn  Mn8  1  0.171  0.357  0.714  1.0
  V  V9  1  0.828  0.645  0.215  1.0
  V  V10  1  0.334  0.147  0.213  1.0
  V  V11  1  0.186  0.862  0.713  1.0
  O  O12  1  0.857  0.707  0.608  1.0
  O  O13  1  0.511  0.467  0.339  1.0
  O  O14  1  0.663  0.317  0.106  1.0
  O  O15  1  0.994  0.985  0.310  1.0
  O  O16  1  0.011  0.032  0.809  1.0
  O  O17  1  0.325  0.180  0.604  1.0
  O  O18  1  0.964  0.498  0.342  1.0
  O  O19  1  0.513  0.028  0.331  1.0
  O  O20  1  0.160  0.815  0.104  1.0
  O  O21  1  0.847  0.197  0.598  1.0
  O  O22  1  0.482  0.978  0.827  1.0
  O  O23  1  0.044  0.535  0.837  1.0
  O  O24  1  0.330  0.670  0.609  1.0
  O  O25  1  0.661  0.788  0.098  1.0
  O  O26  1  0.471  0.514  0.844  1.0
  O  O27  1  0.156  0.288  0.105  1.0
[/CIF]
.