The material described by PO3NNO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four PO3N clusters. In each PO3N cluster, P(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. N(2) is bonded in a single-bond geometry to one O(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one N(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P(NO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.494
_cell_length_b   9.915
_cell_length_c   11.255
_cell_angle_alpha   65.888
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   559.607
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.940  0.917  0.172  1.0
  P  P1  1  0.060  0.083  0.828  1.0
  P  P2  1  0.440  0.583  0.828  1.0
  P  P3  1  0.560  0.417  0.172  1.0
  N  N4  1  0.918  0.648  0.561  1.0
  N  N5  1  0.082  0.352  0.439  1.0
  N  N6  1  0.418  0.852  0.439  1.0
  N  N7  1  0.582  0.148  0.561  1.0
  N  N8  1  0.201  0.725  0.126  1.0
  N  N9  1  0.799  0.275  0.874  1.0
  N  N10  1  0.701  0.775  0.874  1.0
  N  N11  1  0.299  0.225  0.126  1.0
  O  O12  1  0.666  0.702  0.798  1.0
  O  O13  1  0.334  0.298  0.202  1.0
  O  O14  1  0.166  0.798  0.202  1.0
  O  O15  1  0.834  0.202  0.798  1.0
  O  O16  1  0.944  0.985  0.265  1.0
  O  O17  1  0.056  0.015  0.735  1.0
  O  O18  1  0.444  0.515  0.735  1.0
  O  O19  1  0.556  0.485  0.265  1.0
  O  O20  1  0.778  0.922  0.067  1.0
  O  O21  1  0.222  0.078  0.933  1.0
  O  O22  1  0.278  0.578  0.933  1.0
  O  O23  1  0.722  0.422  0.067  1.0
  O  O24  1  0.786  0.679  0.473  1.0
  O  O25  1  0.214  0.321  0.527  1.0
  O  O26  1  0.286  0.821  0.527  1.0
  O  O27  1  0.714  0.179  0.473  1.0
[/CIF]
.
The material described by PO3NNO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four PO3N clusters. In each PO3N cluster, P(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. N(2) is bonded in a single-bond geometry to one O(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one N(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P(NO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.494
_cell_length_b   9.915
_cell_length_c   11.255
_cell_angle_alpha   65.888
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   559.607
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.940  0.917  0.172  1.0
  P  P1  1  0.060  0.083  0.828  1.0
  P  P2  1  0.440  0.583  0.828  1.0
  P  P3  1  0.560  0.417  0.172  1.0
  N  N4  1  0.918  0.648  0.561  1.0
  N  N5  1  0.082  0.352  0.439  1.0
  N  N6  1  0.418  0.852  0.439  1.0
  N  N7  1  0.582  0.148  0.561  1.0
  N  N8  1  0.201  0.725  0.126  1.0
  N  N9  1  0.799  0.275  0.874  1.0
  N  N10  1  0.701  0.775  0.874  1.0
  N  N11  1  0.299  0.225  0.126  1.0
  O  O12  1  0.666  0.702  0.798  1.0
  O  O13  1  0.334  0.298  0.202  1.0
  O  O14  1  0.166  0.798  0.202  1.0
  O  O15  1  0.834  0.202  0.798  1.0
  O  O16  1  0.944  0.985  0.265  1.0
  O  O17  1  0.056  0.015  0.735  1.0
  O  O18  1  0.444  0.515  0.735  1.0
  O  O19  1  0.556  0.485  0.265  1.0
  O  O20  1  0.778  0.922  0.067  1.0
  O  O21  1  0.222  0.078  0.933  1.0
  O  O22  1  0.278  0.578  0.933  1.0
  O  O23  1  0.722  0.422  0.067  1.0
  O  O24  1  0.786  0.679  0.473  1.0
  O  O25  1  0.214  0.321  0.527  1.0
  O  O26  1  0.286  0.821  0.527  1.0
  O  O27  1  0.714  0.179  0.473  1.0
[/CIF]
.