The compound described by LiRh3 is Uranium Silicide-like structured and crystallizes in the tetragonal I4/mmm space group. Li(1) is bonded to four equivalent Rh(2) and eight equivalent Rh(1) atoms to form a mixture of corner, face, and edge-sharing LiRh12 cuboctahedra. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded to four equivalent Li(1) atoms to form a mixture of distorted corner and edge-sharing RhLi4 cuboctahedra. In the second Rh site, Rh(2) is bonded in a distorted square co-planar geometry to four equivalent Li(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiRh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.677
_cell_length_b   4.677
_cell_length_c   4.677
_cell_angle_alpha   132.365
_cell_angle_beta   132.365
_cell_angle_gamma   69.653
_symmetry_Int_Tables_number   1
_cell_volume   54.779
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Rh  Rh1  1  0.750  0.250  0.500  1.0
  Rh  Rh2  1  0.250  0.750  0.500  1.0
  Rh  Rh3  1  0.500  0.500  0.000  1.0
[/CIF]
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The compound described by LiRh3 is Uranium Silicide-like structured and crystallizes in the tetragonal I4/mmm space group. Li(1) is bonded to four equivalent Rh(2) and eight equivalent Rh(1) atoms to form a mixture of corner, face, and edge-sharing LiRh12 cuboctahedra. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded to four equivalent Li(1) atoms to form a mixture of distorted corner and edge-sharing RhLi4 cuboctahedra. In the second Rh site, Rh(2) is bonded in a distorted square co-planar geometry to four equivalent Li(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiRh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.677
_cell_length_b   4.677
_cell_length_c   4.677
_cell_angle_alpha   132.365
_cell_angle_beta   132.365
_cell_angle_gamma   69.653
_symmetry_Int_Tables_number   1
_cell_volume   54.779
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.000  1.0
  Rh  Rh1  1  0.750  0.250  0.500  1.0
  Rh  Rh2  1  0.250  0.750  0.500  1.0
  Rh  Rh3  1  0.500  0.500  0.000  1.0
[/CIF]
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