The material structure described by Sn4SF6 crystallizes in the trigonal R3 space group. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 2-coordinate geometry to one S(1), one F(1), and one F(2) atom. In the second Sn site, Sn(2) is bonded in a 6-coordinate geometry to three equivalent F(1) and three equivalent F(2) atoms. S(1) is bonded in a trigonal non-coplanar geometry to three equivalent Sn(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Sn(1) and one Sn(2) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Sn(1) and one Sn(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sn4SF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.083
_cell_length_b   6.083
_cell_length_c   6.083
_cell_angle_alpha   93.409
_cell_angle_beta   93.409
_cell_angle_gamma   93.409
_symmetry_Int_Tables_number   1
_cell_volume   223.878
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.005  0.499  0.008  1.0
  Sn  Sn1  1  0.008  0.005  0.499  1.0
  Sn  Sn2  1  0.499  0.008  0.005  1.0
  Sn  Sn3  1  0.509  0.509  0.509  1.0
  S  S4  1  0.080  0.080  0.080  1.0
  F  F5  1  0.302  0.611  0.867  1.0
  F  F6  1  0.867  0.302  0.611  1.0
  F  F7  1  0.611  0.867  0.302  1.0
  F  F8  1  0.584  0.329  0.198  1.0
  F  F9  1  0.198  0.584  0.329  1.0
  F  F10  1  0.329  0.198  0.584  1.0
[/CIF]
.
The material structure described by Sn4SF6 crystallizes in the trigonal R3 space group. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 2-coordinate geometry to one S(1), one F(1), and one F(2) atom. In the second Sn site, Sn(2) is bonded in a 6-coordinate geometry to three equivalent F(1) and three equivalent F(2) atoms. S(1) is bonded in a trigonal non-coplanar geometry to three equivalent Sn(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Sn(1) and one Sn(2) atom. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Sn(1) and one Sn(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sn4SF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.083
_cell_length_b   6.083
_cell_length_c   6.083
_cell_angle_alpha   93.409
_cell_angle_beta   93.409
_cell_angle_gamma   93.409
_symmetry_Int_Tables_number   1
_cell_volume   223.878
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.005  0.499  0.008  1.0
  Sn  Sn1  1  0.008  0.005  0.499  1.0
  Sn  Sn2  1  0.499  0.008  0.005  1.0
  Sn  Sn3  1  0.509  0.509  0.509  1.0
  S  S4  1  0.080  0.080  0.080  1.0
  F  F5  1  0.302  0.611  0.867  1.0
  F  F6  1  0.867  0.302  0.611  1.0
  F  F7  1  0.611  0.867  0.302  1.0
  F  F8  1  0.584  0.329  0.198  1.0
  F  F9  1  0.198  0.584  0.329  1.0
  F  F10  1  0.329  0.198  0.584  1.0
[/CIF]
.