The material described by CF3CF4(SbF5)2COF is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two carbon tetrafluoride molecules, two formyl fluoride molecules, two trifluoromethane molecules, and two SbF5 clusters. In each SbF5 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form distorted corner-sharing SbF6 octahedra. In the second Sb site, Sb(2) is bonded to one F(10), one F(11), one F(6), one F(7), and one F(8) atom to form distorted corner-sharing SbF5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 35°. There are ten inequivalent F sites. In the first F site, F(11) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(6) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. In the eighth F site, F(7) is bonded in a single-bond geometry to one Sb(2) atom. In the ninth F site, F(8) is bonded in a single-bond geometry to one Sb(2) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF file [CIF]
data_Sb2C3OF18
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.907
_cell_length_b   10.670
_cell_length_c   10.395
_cell_angle_alpha   83.765
_cell_angle_beta   68.486
_cell_angle_gamma   63.586
_symmetry_Int_Tables_number   1
_cell_volume   821.409
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.374  0.809  0.081  1.0
  Sb  Sb1  1  0.626  0.191  0.919  1.0
  Sb  Sb2  1  0.982  0.675  0.183  1.0
  Sb  Sb3  1  0.018  0.325  0.817  1.0
  C  C4  1  0.415  0.814  0.591  1.0
  C  C5  1  0.585  0.186  0.409  1.0
  C  C6  1  0.280  0.769  0.702  1.0
  C  C7  1  0.720  0.231  0.298  1.0
  C  C8  1  0.050  0.702  0.520  1.0
  C  C9  1  0.950  0.298  0.480  1.0
  O  O10  1  0.299  0.652  0.718  1.0
  O  O11  1  0.701  0.348  0.282  1.0
  F  F12  1  0.231  0.954  0.995  1.0
  F  F13  1  0.769  0.046  0.005  1.0
  F  F14  1  0.458  0.657  0.190  1.0
  F  F15  1  0.542  0.343  0.810  1.0
  F  F16  1  0.410  0.679  0.949  1.0
  F  F17  1  0.590  0.321  0.051  1.0
  F  F18  1  0.273  0.933  0.239  1.0
  F  F19  1  0.727  0.067  0.761  1.0
  F  F20  1  0.591  0.824  0.993  1.0
  F  F21  1  0.409  0.176  0.007  1.0
  F  F22  1  0.111  0.783  0.186  1.0
  F  F23  1  0.889  0.217  0.814  1.0
  F  F24  1  0.774  0.839  0.266  1.0
  F  F25  1  0.226  0.161  0.734  1.0
  F  F26  1  0.847  0.572  0.253  1.0
  F  F27  1  0.153  0.428  0.747  1.0
  F  F28  1  0.960  0.682  0.444  1.0
  F  F29  1  0.040  0.318  0.556  1.0
  F  F30  1  0.009  0.680  0.996  1.0
  F  F31  1  0.991  0.320  0.004  1.0
  F  F32  1  0.188  0.515  0.186  1.0
  F  F33  1  0.812  0.485  0.814  1.0
  F  F34  1  0.521  0.713  0.487  1.0
  F  F35  1  0.479  0.287  0.513  1.0
  F  F36  1  0.521  0.831  0.649  1.0
  F  F37  1  0.479  0.169  0.351  1.0
  F  F38  1  0.332  0.936  0.538  1.0
  F  F39  1  0.668  0.064  0.462  1.0
  F  F40  1  0.134  0.883  0.779  1.0
  F  F41  1  0.866  0.117  0.221  1.0
  F  F42  1  0.955  0.705  0.653  1.0
  F  F43  1  0.045  0.295  0.347  1.0
  F  F44  1  0.213  0.596  0.485  1.0
  F  F45  1  0.787  0.404  0.515  1.0
  F  F46  1  0.059  0.824  0.489  1.0
  F  F47  1  0.941  0.176  0.511  1.0
[/CIF]
.
The material described by CF3CF4(SbF5)2COF is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two carbon tetrafluoride molecules, two formyl fluoride molecules, two trifluoromethane molecules, and two SbF5 clusters. In each SbF5 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form distorted corner-sharing SbF6 octahedra. In the second Sb site, Sb(2) is bonded to one F(10), one F(11), one F(6), one F(7), and one F(8) atom to form distorted corner-sharing SbF5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 35°. There are ten inequivalent F sites. In the first F site, F(11) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(6) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. In the eighth F site, F(7) is bonded in a single-bond geometry to one Sb(2) atom. In the ninth F site, F(8) is bonded in a single-bond geometry to one Sb(2) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF file [CIF]
data_Sb2C3OF18
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.907
_cell_length_b   10.670
_cell_length_c   10.395
_cell_angle_alpha   83.765
_cell_angle_beta   68.486
_cell_angle_gamma   63.586
_symmetry_Int_Tables_number   1
_cell_volume   821.409
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.374  0.809  0.081  1.0
  Sb  Sb1  1  0.626  0.191  0.919  1.0
  Sb  Sb2  1  0.982  0.675  0.183  1.0
  Sb  Sb3  1  0.018  0.325  0.817  1.0
  C  C4  1  0.415  0.814  0.591  1.0
  C  C5  1  0.585  0.186  0.409  1.0
  C  C6  1  0.280  0.769  0.702  1.0
  C  C7  1  0.720  0.231  0.298  1.0
  C  C8  1  0.050  0.702  0.520  1.0
  C  C9  1  0.950  0.298  0.480  1.0
  O  O10  1  0.299  0.652  0.718  1.0
  O  O11  1  0.701  0.348  0.282  1.0
  F  F12  1  0.231  0.954  0.995  1.0
  F  F13  1  0.769  0.046  0.005  1.0
  F  F14  1  0.458  0.657  0.190  1.0
  F  F15  1  0.542  0.343  0.810  1.0
  F  F16  1  0.410  0.679  0.949  1.0
  F  F17  1  0.590  0.321  0.051  1.0
  F  F18  1  0.273  0.933  0.239  1.0
  F  F19  1  0.727  0.067  0.761  1.0
  F  F20  1  0.591  0.824  0.993  1.0
  F  F21  1  0.409  0.176  0.007  1.0
  F  F22  1  0.111  0.783  0.186  1.0
  F  F23  1  0.889  0.217  0.814  1.0
  F  F24  1  0.774  0.839  0.266  1.0
  F  F25  1  0.226  0.161  0.734  1.0
  F  F26  1  0.847  0.572  0.253  1.0
  F  F27  1  0.153  0.428  0.747  1.0
  F  F28  1  0.960  0.682  0.444  1.0
  F  F29  1  0.040  0.318  0.556  1.0
  F  F30  1  0.009  0.680  0.996  1.0
  F  F31  1  0.991  0.320  0.004  1.0
  F  F32  1  0.188  0.515  0.186  1.0
  F  F33  1  0.812  0.485  0.814  1.0
  F  F34  1  0.521  0.713  0.487  1.0
  F  F35  1  0.479  0.287  0.513  1.0
  F  F36  1  0.521  0.831  0.649  1.0
  F  F37  1  0.479  0.169  0.351  1.0
  F  F38  1  0.332  0.936  0.538  1.0
  F  F39  1  0.668  0.064  0.462  1.0
  F  F40  1  0.134  0.883  0.779  1.0
  F  F41  1  0.866  0.117  0.221  1.0
  F  F42  1  0.955  0.705  0.653  1.0
  F  F43  1  0.045  0.295  0.347  1.0
  F  F44  1  0.213  0.596  0.485  1.0
  F  F45  1  0.787  0.404  0.515  1.0
  F  F46  1  0.059  0.824  0.489  1.0
  F  F47  1  0.941  0.176  0.511  1.0
[/CIF]
.