The compound described by YH5S3O13 crystallizes in the triclinic P-1 space group. Y(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(2), one O(3), one O(6), one O(7), and one O(9) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(4) and one O(5) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(11) and one O(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(12) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(12) atom. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one O(11) and one O(13) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(11), one O(5), and one O(7) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(10), one O(3), one O(6), and one O(8) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one O(13), one O(2), one O(4), and one O(9) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Y(1) and one S(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Y(1) and one S(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one H(1) and one S(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one H(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Y(1) and one S(2) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Y(1) and one S(1) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one H(2) and one S(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Y(1) and one S(3) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one S(2) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one H(2), one H(5), and one S(1) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Y(1), one H(3), and one H(4) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one H(5) and one S(3) atom. is represented by the CIF file [CIF]
data_YH5S3O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.869
_cell_length_b   8.119
_cell_length_c   9.743
_cell_angle_alpha   79.848
_cell_angle_beta   77.585
_cell_angle_gamma   77.580
_symmetry_Int_Tables_number   1
_cell_volume   513.372
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.134  0.677  0.693  1.0
  Y  Y1  1  0.866  0.323  0.307  1.0
  H  H2  1  0.072  0.776  0.181  1.0
  H  H3  1  0.422  0.135  0.618  1.0
  H  H4  1  0.593  0.211  0.136  1.0
  H  H5  1  0.199  0.920  0.864  1.0
  H  H6  1  0.508  0.863  0.104  1.0
  H  H7  1  0.492  0.137  0.896  1.0
  H  H8  1  0.801  0.080  0.136  1.0
  H  H9  1  0.407  0.789  0.864  1.0
  H  H10  1  0.578  0.865  0.382  1.0
  H  H11  1  0.928  0.224  0.819  1.0
  S  S12  1  0.199  0.889  0.319  1.0
  S  S13  1  0.306  0.335  0.459  1.0
  S  S14  1  0.205  0.292  0.955  1.0
  S  S15  1  0.795  0.708  0.045  1.0
  S  S16  1  0.694  0.665  0.541  1.0
  S  S17  1  0.801  0.111  0.681  1.0
  O  O18  1  0.054  0.038  0.274  1.0
  O  O19  1  0.104  0.352  0.089  1.0
  O  O20  1  0.185  0.323  0.357  1.0
  O  O21  1  0.106  0.171  0.910  1.0
  O  O22  1  0.176  0.739  0.246  1.0
  O  O23  1  0.202  0.459  0.556  1.0
  O  O24  1  0.162  0.835  0.471  1.0
  O  O25  1  0.326  0.153  0.549  1.0
  O  O26  1  0.253  0.429  0.841  1.0
  O  O27  1  0.509  0.365  0.390  1.0
  O  O28  1  0.413  0.911  0.268  1.0
  O  O29  1  0.275  0.812  0.834  1.0
  O  O30  1  0.417  0.185  0.986  1.0
  O  O31  1  0.583  0.815  0.014  1.0
  O  O32  1  0.725  0.188  0.166  1.0
  O  O33  1  0.587  0.089  0.732  1.0
  O  O34  1  0.491  0.635  0.610  1.0
  O  O35  1  0.747  0.571  0.159  1.0
  O  O36  1  0.674  0.847  0.451  1.0
  O  O37  1  0.838  0.165  0.529  1.0
  O  O38  1  0.798  0.541  0.444  1.0
  O  O39  1  0.824  0.261  0.754  1.0
  O  O40  1  0.894  0.829  0.090  1.0
  O  O41  1  0.815  0.677  0.643  1.0
  O  O42  1  0.896  0.648  0.911  1.0
  O  O43  1  0.946  0.962  0.726  1.0
[/CIF]
.
The compound described by YH5S3O13 crystallizes in the triclinic P-1 space group. Y(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(2), one O(3), one O(6), one O(7), and one O(9) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(4) and one O(5) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(11) and one O(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(12) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(12) atom. In the fifth H site, H(5) is bonded in a distorted single-bond geometry to one O(11) and one O(13) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(11), one O(5), and one O(7) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(10), one O(3), one O(6), and one O(8) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one O(13), one O(2), one O(4), and one O(9) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Y(1) and one S(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Y(1) and one S(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one H(1) and one S(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one H(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Y(1) and one S(2) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Y(1) and one S(1) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one H(2) and one S(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Y(1) and one S(3) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one S(2) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one H(2), one H(5), and one S(1) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Y(1), one H(3), and one H(4) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one H(5) and one S(3) atom. is represented by the CIF file [CIF]
data_YH5S3O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.869
_cell_length_b   8.119
_cell_length_c   9.743
_cell_angle_alpha   79.848
_cell_angle_beta   77.585
_cell_angle_gamma   77.580
_symmetry_Int_Tables_number   1
_cell_volume   513.372
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.134  0.677  0.693  1.0
  Y  Y1  1  0.866  0.323  0.307  1.0
  H  H2  1  0.072  0.776  0.181  1.0
  H  H3  1  0.422  0.135  0.618  1.0
  H  H4  1  0.593  0.211  0.136  1.0
  H  H5  1  0.199  0.920  0.864  1.0
  H  H6  1  0.508  0.863  0.104  1.0
  H  H7  1  0.492  0.137  0.896  1.0
  H  H8  1  0.801  0.080  0.136  1.0
  H  H9  1  0.407  0.789  0.864  1.0
  H  H10  1  0.578  0.865  0.382  1.0
  H  H11  1  0.928  0.224  0.819  1.0
  S  S12  1  0.199  0.889  0.319  1.0
  S  S13  1  0.306  0.335  0.459  1.0
  S  S14  1  0.205  0.292  0.955  1.0
  S  S15  1  0.795  0.708  0.045  1.0
  S  S16  1  0.694  0.665  0.541  1.0
  S  S17  1  0.801  0.111  0.681  1.0
  O  O18  1  0.054  0.038  0.274  1.0
  O  O19  1  0.104  0.352  0.089  1.0
  O  O20  1  0.185  0.323  0.357  1.0
  O  O21  1  0.106  0.171  0.910  1.0
  O  O22  1  0.176  0.739  0.246  1.0
  O  O23  1  0.202  0.459  0.556  1.0
  O  O24  1  0.162  0.835  0.471  1.0
  O  O25  1  0.326  0.153  0.549  1.0
  O  O26  1  0.253  0.429  0.841  1.0
  O  O27  1  0.509  0.365  0.390  1.0
  O  O28  1  0.413  0.911  0.268  1.0
  O  O29  1  0.275  0.812  0.834  1.0
  O  O30  1  0.417  0.185  0.986  1.0
  O  O31  1  0.583  0.815  0.014  1.0
  O  O32  1  0.725  0.188  0.166  1.0
  O  O33  1  0.587  0.089  0.732  1.0
  O  O34  1  0.491  0.635  0.610  1.0
  O  O35  1  0.747  0.571  0.159  1.0
  O  O36  1  0.674  0.847  0.451  1.0
  O  O37  1  0.838  0.165  0.529  1.0
  O  O38  1  0.798  0.541  0.444  1.0
  O  O39  1  0.824  0.261  0.754  1.0
  O  O40  1  0.894  0.829  0.090  1.0
  O  O41  1  0.815  0.677  0.643  1.0
  O  O42  1  0.896  0.648  0.911  1.0
  O  O43  1  0.946  0.962  0.726  1.0
[/CIF]
.