The material structure described by AgSbO3 crystallizes in the monoclinic C2 space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a trigonal planar geometry to one O(5), one O(6), and one O(7) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(1), one O(8), and one O(9) atom. In the third Ag site, Ag(3) is bonded in a trigonal planar geometry to one O(4), one O(6), and one O(7) atom. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(4), one O(5), one O(7), one O(8), and two equivalent O(2) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. In the second Sb site, Sb(2) is bonded to one O(1), one O(10), one O(4), one O(5), one O(6), and one O(9) atom to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. In the third Sb site, Sb(3) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(8) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. In the fourth Sb site, Sb(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. There are ten inequivalent O sites. In the first O site, O(7) is bonded to one Ag(1), one Ag(3), one Sb(1), and one Sb(4) atom to form distorted corner-sharing OAg2Sb2 tetrahedra. In the second O site, O(8) is bonded in a distorted trigonal planar geometry to one Ag(2), one Sb(1), and one Sb(3) atom. In the third O site, O(9) is bonded in a 4-coordinate geometry to two equivalent Ag(2) and two equivalent Sb(2) atoms. In the fourth O site, O(10) is bonded in a water-like geometry to two equivalent Sb(2) atoms. In the fifth O site, O(1) is bonded in a distorted trigonal planar geometry to one Ag(2), one Sb(2), and one Sb(4) atom. In the sixth O site, O(2) is bonded in a water-like geometry to two equivalent Sb(1) atoms. In the seventh O site, O(3) is bonded in a water-like geometry to one Sb(3) and one Sb(4) atom. In the eighth O site, O(4) is bonded in a 3-coordinate geometry to one Ag(3), one Sb(1), and one Sb(2) atom. In the ninth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Sb(1), and one Sb(2) atom. In the tenth O site, O(6) is bonded to one Ag(1), one Ag(3), one Sb(2), and one Sb(3) atom to form distorted corner-sharing OAg2Sb2 tetrahedra. is represented by the CIF card [CIF]
data_AgSbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.166
_cell_length_b   8.166
_cell_length_c   9.517
_cell_angle_alpha   55.483
_cell_angle_beta   55.483
_cell_angle_gamma   71.239
_symmetry_Int_Tables_number   1
_cell_volume   430.825
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.381  0.997  0.000  1.0
  Ag  Ag1  1  0.719  0.015  0.268  1.0
  Ag  Ag2  1  0.985  0.281  0.732  1.0
  Ag  Ag3  1  0.369  0.004  0.633  1.0
  Ag  Ag4  1  0.996  0.631  0.367  1.0
  Ag  Ag5  1  0.003  0.619  1.000  1.0
  Sb  Sb6  1  0.499  0.497  0.664  1.0
  Sb  Sb7  1  0.346  0.331  0.158  1.0
  Sb  Sb8  1  0.840  0.160  0.500  1.0
  Sb  Sb9  1  0.162  0.838  0.500  1.0
  Sb  Sb10  1  0.503  0.501  0.336  1.0
  Sb  Sb11  1  0.669  0.654  0.842  1.0
  O  O12  1  0.385  0.040  0.289  1.0
  O  O13  1  0.358  0.363  0.634  1.0
  O  O14  1  0.637  0.642  0.366  1.0
  O  O15  1  0.995  0.993  0.366  1.0
  O  O16  1  0.007  0.005  0.634  1.0
  O  O17  1  0.668  0.666  0.623  1.0
  O  O18  1  0.337  0.326  0.953  1.0
  O  O19  1  0.050  0.380  0.281  1.0
  O  O20  1  0.286  0.712  0.330  1.0
  O  O21  1  0.288  0.714  0.670  1.0
  O  O22  1  0.707  0.279  0.340  1.0
  O  O23  1  0.721  0.293  0.660  1.0
  O  O24  1  0.960  0.615  0.711  1.0
  O  O25  1  0.648  0.352  0.000  1.0
  O  O26  1  0.334  0.332  0.377  1.0
  O  O27  1  0.674  0.663  0.047  1.0
  O  O28  1  0.369  0.631  0.000  1.0
  O  O29  1  0.620  0.950  0.719  1.0
[/CIF]
.
The material structure described by AgSbO3 crystallizes in the monoclinic C2 space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a trigonal planar geometry to one O(5), one O(6), and one O(7) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(1), one O(8), and one O(9) atom. In the third Ag site, Ag(3) is bonded in a trigonal planar geometry to one O(4), one O(6), and one O(7) atom. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(4), one O(5), one O(7), one O(8), and two equivalent O(2) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. In the second Sb site, Sb(2) is bonded to one O(1), one O(10), one O(4), one O(5), one O(6), and one O(9) atom to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. In the third Sb site, Sb(3) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(8) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. In the fourth Sb site, Sb(4) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. There are ten inequivalent O sites. In the first O site, O(7) is bonded to one Ag(1), one Ag(3), one Sb(1), and one Sb(4) atom to form distorted corner-sharing OAg2Sb2 tetrahedra. In the second O site, O(8) is bonded in a distorted trigonal planar geometry to one Ag(2), one Sb(1), and one Sb(3) atom. In the third O site, O(9) is bonded in a 4-coordinate geometry to two equivalent Ag(2) and two equivalent Sb(2) atoms. In the fourth O site, O(10) is bonded in a water-like geometry to two equivalent Sb(2) atoms. In the fifth O site, O(1) is bonded in a distorted trigonal planar geometry to one Ag(2), one Sb(2), and one Sb(4) atom. In the sixth O site, O(2) is bonded in a water-like geometry to two equivalent Sb(1) atoms. In the seventh O site, O(3) is bonded in a water-like geometry to one Sb(3) and one Sb(4) atom. In the eighth O site, O(4) is bonded in a 3-coordinate geometry to one Ag(3), one Sb(1), and one Sb(2) atom. In the ninth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Sb(1), and one Sb(2) atom. In the tenth O site, O(6) is bonded to one Ag(1), one Ag(3), one Sb(2), and one Sb(3) atom to form distorted corner-sharing OAg2Sb2 tetrahedra. is represented by the CIF card [CIF]
data_AgSbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.166
_cell_length_b   8.166
_cell_length_c   9.517
_cell_angle_alpha   55.483
_cell_angle_beta   55.483
_cell_angle_gamma   71.239
_symmetry_Int_Tables_number   1
_cell_volume   430.825
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.381  0.997  0.000  1.0
  Ag  Ag1  1  0.719  0.015  0.268  1.0
  Ag  Ag2  1  0.985  0.281  0.732  1.0
  Ag  Ag3  1  0.369  0.004  0.633  1.0
  Ag  Ag4  1  0.996  0.631  0.367  1.0
  Ag  Ag5  1  0.003  0.619  1.000  1.0
  Sb  Sb6  1  0.499  0.497  0.664  1.0
  Sb  Sb7  1  0.346  0.331  0.158  1.0
  Sb  Sb8  1  0.840  0.160  0.500  1.0
  Sb  Sb9  1  0.162  0.838  0.500  1.0
  Sb  Sb10  1  0.503  0.501  0.336  1.0
  Sb  Sb11  1  0.669  0.654  0.842  1.0
  O  O12  1  0.385  0.040  0.289  1.0
  O  O13  1  0.358  0.363  0.634  1.0
  O  O14  1  0.637  0.642  0.366  1.0
  O  O15  1  0.995  0.993  0.366  1.0
  O  O16  1  0.007  0.005  0.634  1.0
  O  O17  1  0.668  0.666  0.623  1.0
  O  O18  1  0.337  0.326  0.953  1.0
  O  O19  1  0.050  0.380  0.281  1.0
  O  O20  1  0.286  0.712  0.330  1.0
  O  O21  1  0.288  0.714  0.670  1.0
  O  O22  1  0.707  0.279  0.340  1.0
  O  O23  1  0.721  0.293  0.660  1.0
  O  O24  1  0.960  0.615  0.711  1.0
  O  O25  1  0.648  0.352  0.000  1.0
  O  O26  1  0.334  0.332  0.377  1.0
  O  O27  1  0.674  0.663  0.047  1.0
  O  O28  1  0.369  0.631  0.000  1.0
  O  O29  1  0.620  0.950  0.719  1.0
[/CIF]
.