The structure described by Pt3(N3O2)2NO2(NO3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four nitric acid molecules, two nitrous acid molecules, and two Pt3(N3O2)2 clusters. In each Pt3(N3O2)2 cluster, there are three inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one O(1), and one O(2) atom. In the second Pt site, Pt(2) is bonded in a rectangular see-saw-like geometry to one N(3), one N(4), one O(1), and one O(3) atom. In the third Pt site, Pt(3) is bonded in a rectangular see-saw-like geometry to one N(5), one N(6), one O(2), and one O(3) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Pt(1) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Pt(2) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one Pt(2) atom. In the fifth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one Pt(3) and one O(4) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one Pt(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Pt(1) and one Pt(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one Pt(3) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Pt(2) and one Pt(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(5) atom. is represented by the CIF card [CIF]
data_PtN3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.010
_cell_length_b   10.047
_cell_length_c   10.852
_cell_angle_alpha   66.977
_cell_angle_beta   75.650
_cell_angle_gamma   79.215
_symmetry_Int_Tables_number   1
_cell_volume   871.468
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.283  0.699  0.238  1.0
  Pt  Pt1  1  0.717  0.301  0.762  1.0
  Pt  Pt2  1  0.974  0.899  0.411  1.0
  Pt  Pt3  1  0.026  0.101  0.589  1.0
  Pt  Pt4  1  0.156  0.063  0.046  1.0
  Pt  Pt5  1  0.844  0.937  0.954  1.0
  N  N6  1  0.374  0.599  0.376  1.0
  N  N7  1  0.626  0.401  0.624  1.0
  N  N8  1  0.339  0.598  0.122  1.0
  N  N9  1  0.661  0.402  0.878  1.0
  N  N10  1  0.784  0.975  0.412  1.0
  N  N11  1  0.216  0.025  0.588  1.0
  N  N12  1  0.952  0.747  0.585  1.0
  N  N13  1  0.048  0.253  0.415  1.0
  N  N14  1  0.093  0.296  0.987  1.0
  N  N15  1  0.907  0.704  0.013  1.0
  N  N16  1  0.292  0.064  0.902  1.0
  N  N17  1  0.708  0.936  0.098  1.0
  N  N18  1  0.798  0.643  0.342  1.0
  N  N19  1  0.202  0.357  0.658  1.0
  N  N20  1  0.714  0.370  0.214  1.0
  N  N21  1  0.286  0.630  0.786  1.0
  N  N22  1  0.603  0.810  0.761  1.0
  N  N23  1  0.397  0.190  0.239  1.0
  O  O24  1  0.177  0.820  0.362  1.0
  O  O25  1  0.823  0.180  0.638  1.0
  O  O26  1  0.158  0.843  0.115  1.0
  O  O27  1  0.842  0.157  0.885  1.0
  O  O28  1  0.031  0.059  0.211  1.0
  O  O29  1  0.969  0.941  0.789  1.0
  O  O30  1  0.919  0.623  0.121  1.0
  O  O31  1  0.081  0.377  0.879  1.0
  O  O32  1  0.683  0.727  0.327  1.0
  O  O33  1  0.317  0.273  0.673  1.0
  O  O34  1  0.844  0.548  0.437  1.0
  O  O35  1  0.156  0.452  0.563  1.0
  O  O36  1  0.803  0.333  0.121  1.0
  O  O37  1  0.197  0.667  0.879  1.0
  O  O38  1  0.646  0.497  0.185  1.0
  O  O39  1  0.354  0.503  0.815  1.0
  O  O40  1  0.693  0.282  0.335  1.0
  O  O41  1  0.307  0.718  0.665  1.0
  O  O42  1  0.689  0.706  0.731  1.0
  O  O43  1  0.311  0.294  0.269  1.0
  O  O44  1  0.604  0.937  0.676  1.0
  O  O45  1  0.396  0.063  0.324  1.0
  O  O46  1  0.520  0.781  0.878  1.0
  O  O47  1  0.480  0.219  0.122  1.0
[/CIF]
.
The structure described by Pt3(N3O2)2NO2(NO3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four nitric acid molecules, two nitrous acid molecules, and two Pt3(N3O2)2 clusters. In each Pt3(N3O2)2 cluster, there are three inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one O(1), and one O(2) atom. In the second Pt site, Pt(2) is bonded in a rectangular see-saw-like geometry to one N(3), one N(4), one O(1), and one O(3) atom. In the third Pt site, Pt(3) is bonded in a rectangular see-saw-like geometry to one N(5), one N(6), one O(2), and one O(3) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Pt(1) atom. In the third N site, N(3) is bonded in a single-bond geometry to one Pt(2) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one Pt(2) atom. In the fifth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one Pt(3) and one O(4) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one Pt(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Pt(1) and one Pt(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one Pt(3) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Pt(2) and one Pt(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(5) atom. is represented by the CIF card [CIF]
data_PtN3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.010
_cell_length_b   10.047
_cell_length_c   10.852
_cell_angle_alpha   66.977
_cell_angle_beta   75.650
_cell_angle_gamma   79.215
_symmetry_Int_Tables_number   1
_cell_volume   871.468
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.283  0.699  0.238  1.0
  Pt  Pt1  1  0.717  0.301  0.762  1.0
  Pt  Pt2  1  0.974  0.899  0.411  1.0
  Pt  Pt3  1  0.026  0.101  0.589  1.0
  Pt  Pt4  1  0.156  0.063  0.046  1.0
  Pt  Pt5  1  0.844  0.937  0.954  1.0
  N  N6  1  0.374  0.599  0.376  1.0
  N  N7  1  0.626  0.401  0.624  1.0
  N  N8  1  0.339  0.598  0.122  1.0
  N  N9  1  0.661  0.402  0.878  1.0
  N  N10  1  0.784  0.975  0.412  1.0
  N  N11  1  0.216  0.025  0.588  1.0
  N  N12  1  0.952  0.747  0.585  1.0
  N  N13  1  0.048  0.253  0.415  1.0
  N  N14  1  0.093  0.296  0.987  1.0
  N  N15  1  0.907  0.704  0.013  1.0
  N  N16  1  0.292  0.064  0.902  1.0
  N  N17  1  0.708  0.936  0.098  1.0
  N  N18  1  0.798  0.643  0.342  1.0
  N  N19  1  0.202  0.357  0.658  1.0
  N  N20  1  0.714  0.370  0.214  1.0
  N  N21  1  0.286  0.630  0.786  1.0
  N  N22  1  0.603  0.810  0.761  1.0
  N  N23  1  0.397  0.190  0.239  1.0
  O  O24  1  0.177  0.820  0.362  1.0
  O  O25  1  0.823  0.180  0.638  1.0
  O  O26  1  0.158  0.843  0.115  1.0
  O  O27  1  0.842  0.157  0.885  1.0
  O  O28  1  0.031  0.059  0.211  1.0
  O  O29  1  0.969  0.941  0.789  1.0
  O  O30  1  0.919  0.623  0.121  1.0
  O  O31  1  0.081  0.377  0.879  1.0
  O  O32  1  0.683  0.727  0.327  1.0
  O  O33  1  0.317  0.273  0.673  1.0
  O  O34  1  0.844  0.548  0.437  1.0
  O  O35  1  0.156  0.452  0.563  1.0
  O  O36  1  0.803  0.333  0.121  1.0
  O  O37  1  0.197  0.667  0.879  1.0
  O  O38  1  0.646  0.497  0.185  1.0
  O  O39  1  0.354  0.503  0.815  1.0
  O  O40  1  0.693  0.282  0.335  1.0
  O  O41  1  0.307  0.718  0.665  1.0
  O  O42  1  0.689  0.706  0.731  1.0
  O  O43  1  0.311  0.294  0.269  1.0
  O  O44  1  0.604  0.937  0.676  1.0
  O  O45  1  0.396  0.063  0.324  1.0
  O  O46  1  0.520  0.781  0.878  1.0
  O  O47  1  0.480  0.219  0.122  1.0
[/CIF]
.