The structure described by C2SbN(OF3)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four C2SbN(OF3)2 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one O(2), and one F(5) atom. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one O(1) atom. Sb(1) is bonded in an octahedral geometry to one O(2), one F(1), one F(2), one F(3), one F(4), and one F(6) atom. N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(1) and one Sb(1) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbC2N(OF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.597
_cell_length_b   9.020
_cell_length_c   15.591
_cell_angle_alpha   78.959
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   772.541
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.741  0.295  0.402  1.0
  Sb  Sb1  1  0.241  0.705  0.098  1.0
  Sb  Sb2  1  0.259  0.705  0.598  1.0
  Sb  Sb3  1  0.759  0.295  0.902  1.0
  C  C4  1  0.851  0.644  0.858  1.0
  C  C5  1  0.649  0.644  0.358  1.0
  C  C6  1  0.407  0.149  0.169  1.0
  C  C7  1  0.351  0.356  0.642  1.0
  C  C8  1  0.093  0.149  0.669  1.0
  C  C9  1  0.149  0.356  0.142  1.0
  C  C10  1  0.593  0.851  0.831  1.0
  C  C11  1  0.907  0.851  0.331  1.0
  N  N12  1  0.708  0.790  0.339  1.0
  N  N13  1  0.208  0.210  0.161  1.0
  N  N14  1  0.792  0.790  0.839  1.0
  N  N15  1  0.292  0.210  0.661  1.0
  O  O16  1  0.422  0.925  0.820  1.0
  O  O17  1  0.078  0.925  0.320  1.0
  O  O18  1  0.708  0.536  0.875  1.0
  O  O19  1  0.922  0.075  0.680  1.0
  O  O20  1  0.578  0.075  0.180  1.0
  O  O21  1  0.792  0.536  0.375  1.0
  O  O22  1  0.292  0.464  0.125  1.0
  O  O23  1  0.208  0.464  0.625  1.0
  F  F24  1  0.054  0.676  0.203  1.0
  F  F25  1  0.933  0.298  0.502  1.0
  F  F26  1  0.478  0.296  0.833  1.0
  F  F27  1  0.466  0.326  0.468  1.0
  F  F28  1  0.022  0.296  0.333  1.0
  F  F29  1  0.083  0.620  0.856  1.0
  F  F30  1  0.522  0.704  0.167  1.0
  F  F31  1  0.978  0.704  0.667  1.0
  F  F32  1  0.433  0.702  0.998  1.0
  F  F33  1  0.583  0.380  0.644  1.0
  F  F34  1  0.291  0.918  0.578  1.0
  F  F35  1  0.554  0.324  0.297  1.0
  F  F36  1  0.946  0.324  0.797  1.0
  F  F37  1  0.791  0.082  0.922  1.0
  F  F38  1  0.709  0.082  0.422  1.0
  F  F39  1  0.917  0.380  0.144  1.0
  F  F40  1  0.417  0.620  0.356  1.0
  F  F41  1  0.209  0.918  0.078  1.0
  F  F42  1  0.446  0.676  0.703  1.0
  F  F43  1  0.034  0.326  0.968  1.0
  F  F44  1  0.067  0.702  0.498  1.0
  F  F45  1  0.966  0.674  0.032  1.0
  F  F46  1  0.534  0.674  0.532  1.0
  F  F47  1  0.567  0.298  0.002  1.0
[/CIF]
.
The structure described by C2SbN(OF3)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four C2SbN(OF3)2 clusters. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one O(2), and one F(5) atom. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one O(1) atom. Sb(1) is bonded in an octahedral geometry to one O(2), one F(1), one F(2), one F(3), one F(4), and one F(6) atom. N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(1) and one Sb(1) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbC2N(OF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.597
_cell_length_b   9.020
_cell_length_c   15.591
_cell_angle_alpha   78.959
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   772.541
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.741  0.295  0.402  1.0
  Sb  Sb1  1  0.241  0.705  0.098  1.0
  Sb  Sb2  1  0.259  0.705  0.598  1.0
  Sb  Sb3  1  0.759  0.295  0.902  1.0
  C  C4  1  0.851  0.644  0.858  1.0
  C  C5  1  0.649  0.644  0.358  1.0
  C  C6  1  0.407  0.149  0.169  1.0
  C  C7  1  0.351  0.356  0.642  1.0
  C  C8  1  0.093  0.149  0.669  1.0
  C  C9  1  0.149  0.356  0.142  1.0
  C  C10  1  0.593  0.851  0.831  1.0
  C  C11  1  0.907  0.851  0.331  1.0
  N  N12  1  0.708  0.790  0.339  1.0
  N  N13  1  0.208  0.210  0.161  1.0
  N  N14  1  0.792  0.790  0.839  1.0
  N  N15  1  0.292  0.210  0.661  1.0
  O  O16  1  0.422  0.925  0.820  1.0
  O  O17  1  0.078  0.925  0.320  1.0
  O  O18  1  0.708  0.536  0.875  1.0
  O  O19  1  0.922  0.075  0.680  1.0
  O  O20  1  0.578  0.075  0.180  1.0
  O  O21  1  0.792  0.536  0.375  1.0
  O  O22  1  0.292  0.464  0.125  1.0
  O  O23  1  0.208  0.464  0.625  1.0
  F  F24  1  0.054  0.676  0.203  1.0
  F  F25  1  0.933  0.298  0.502  1.0
  F  F26  1  0.478  0.296  0.833  1.0
  F  F27  1  0.466  0.326  0.468  1.0
  F  F28  1  0.022  0.296  0.333  1.0
  F  F29  1  0.083  0.620  0.856  1.0
  F  F30  1  0.522  0.704  0.167  1.0
  F  F31  1  0.978  0.704  0.667  1.0
  F  F32  1  0.433  0.702  0.998  1.0
  F  F33  1  0.583  0.380  0.644  1.0
  F  F34  1  0.291  0.918  0.578  1.0
  F  F35  1  0.554  0.324  0.297  1.0
  F  F36  1  0.946  0.324  0.797  1.0
  F  F37  1  0.791  0.082  0.922  1.0
  F  F38  1  0.709  0.082  0.422  1.0
  F  F39  1  0.917  0.380  0.144  1.0
  F  F40  1  0.417  0.620  0.356  1.0
  F  F41  1  0.209  0.918  0.078  1.0
  F  F42  1  0.446  0.676  0.703  1.0
  F  F43  1  0.034  0.326  0.968  1.0
  F  F44  1  0.067  0.702  0.498  1.0
  F  F45  1  0.966  0.674  0.032  1.0
  F  F46  1  0.534  0.674  0.532  1.0
  F  F47  1  0.567  0.298  0.002  1.0
[/CIF]
.