The material structure described by K2MoSO3 crystallizes in the monoclinic C2/m space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to two equivalent S(1), two equivalent O(1), and four equivalent O(2) atoms. In the second K site, K(2) is bonded in a 9-coordinate geometry to three equivalent S(1), two equivalent O(1), and four equivalent O(2) atoms. Mo(1) is bonded in a distorted tetrahedral geometry to one S(1), one O(1), and two equivalent O(2) atoms. S(1) is bonded in a 6-coordinate geometry to two equivalent K(1), three equivalent K(2), and one Mo(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to two equivalent K(1), two equivalent K(2), and one Mo(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent K(1), two equivalent K(2), and one Mo(1) atom. is represented by the CIF card [CIF]
data_K2MoSO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.245
_cell_length_b   7.239
_cell_length_c   7.866
_cell_angle_alpha   107.765
_cell_angle_beta   90.000
_cell_angle_gamma   115.553
_symmetry_Int_Tables_number   1
_cell_volume   301.915
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.492  0.984  0.205  1.0
  K  K1  1  0.508  0.016  0.795  1.0
  K  K2  1  0.174  0.347  0.730  1.0
  K  K3  1  0.826  0.653  0.270  1.0
  Mo  Mo4  1  0.151  0.301  0.208  1.0
  Mo  Mo5  1  0.849  0.699  0.792  1.0
  S  S6  1  0.321  0.642  0.412  1.0
  S  S7  1  0.679  0.358  0.588  1.0
  O  O8  1  0.052  0.105  0.320  1.0
  O  O9  1  0.948  0.895  0.680  1.0
  O  O10  1  0.898  0.268  0.072  1.0
  O  O11  1  0.370  0.268  0.072  1.0
  O  O12  1  0.102  0.732  0.928  1.0
  O  O13  1  0.630  0.732  0.928  1.0
[/CIF]
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The material structure described by K2MoSO3 crystallizes in the monoclinic C2/m space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to two equivalent S(1), two equivalent O(1), and four equivalent O(2) atoms. In the second K site, K(2) is bonded in a 9-coordinate geometry to three equivalent S(1), two equivalent O(1), and four equivalent O(2) atoms. Mo(1) is bonded in a distorted tetrahedral geometry to one S(1), one O(1), and two equivalent O(2) atoms. S(1) is bonded in a 6-coordinate geometry to two equivalent K(1), three equivalent K(2), and one Mo(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to two equivalent K(1), two equivalent K(2), and one Mo(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent K(1), two equivalent K(2), and one Mo(1) atom. is represented by the CIF card [CIF]
data_K2MoSO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.245
_cell_length_b   7.239
_cell_length_c   7.866
_cell_angle_alpha   107.765
_cell_angle_beta   90.000
_cell_angle_gamma   115.553
_symmetry_Int_Tables_number   1
_cell_volume   301.915
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.492  0.984  0.205  1.0
  K  K1  1  0.508  0.016  0.795  1.0
  K  K2  1  0.174  0.347  0.730  1.0
  K  K3  1  0.826  0.653  0.270  1.0
  Mo  Mo4  1  0.151  0.301  0.208  1.0
  Mo  Mo5  1  0.849  0.699  0.792  1.0
  S  S6  1  0.321  0.642  0.412  1.0
  S  S7  1  0.679  0.358  0.588  1.0
  O  O8  1  0.052  0.105  0.320  1.0
  O  O9  1  0.948  0.895  0.680  1.0
  O  O10  1  0.898  0.268  0.072  1.0
  O  O11  1  0.370  0.268  0.072  1.0
  O  O12  1  0.102  0.732  0.928  1.0
  O  O13  1  0.630  0.732  0.928  1.0
[/CIF]
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