The material described by VO2 is trigonal omega-like structured and crystallizes in the tetragonal I4_1/a space group. V(1) is bonded to six equivalent O(1) atoms to form edge-sharing VO6 octahedra. O(1) is bonded in a distorted T-shaped geometry to three equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.890
_cell_length_b   5.891
_cell_length_c   5.887
_cell_angle_alpha   118.674
_cell_angle_beta   87.644
_cell_angle_gamma   61.379
_symmetry_Int_Tables_number   1
_cell_volume   147.273
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.000  1.0
  V  V1  1  0.500  0.500  0.500  1.0
  V  V2  1  0.000  1.000  0.500  1.0
  V  V3  1  0.500  1.000  0.500  1.0
  O  O4  1  0.267  0.530  0.261  1.0
  O  O5  1  0.262  0.971  0.269  1.0
  O  O6  1  0.268  0.970  0.703  1.0
  O  O7  1  0.703  0.529  0.268  1.0
  O  O8  1  0.297  0.471  0.733  1.0
  O  O9  1  0.732  0.030  0.297  1.0
  O  O10  1  0.738  0.029  0.731  1.0
  O  O11  1  0.733  0.470  0.739  1.0
[/CIF]
.
The material described by VO2 is trigonal omega-like structured and crystallizes in the tetragonal I4_1/a space group. V(1) is bonded to six equivalent O(1) atoms to form edge-sharing VO6 octahedra. O(1) is bonded in a distorted T-shaped geometry to three equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.890
_cell_length_b   5.891
_cell_length_c   5.887
_cell_angle_alpha   118.674
_cell_angle_beta   87.644
_cell_angle_gamma   61.379
_symmetry_Int_Tables_number   1
_cell_volume   147.273
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.000  1.0
  V  V1  1  0.500  0.500  0.500  1.0
  V  V2  1  0.000  1.000  0.500  1.0
  V  V3  1  0.500  1.000  0.500  1.0
  O  O4  1  0.267  0.530  0.261  1.0
  O  O5  1  0.262  0.971  0.269  1.0
  O  O6  1  0.268  0.970  0.703  1.0
  O  O7  1  0.703  0.529  0.268  1.0
  O  O8  1  0.297  0.471  0.733  1.0
  O  O9  1  0.732  0.030  0.297  1.0
  O  O10  1  0.738  0.029  0.731  1.0
  O  O11  1  0.733  0.470  0.739  1.0
[/CIF]
.