The crystal structure described by HoO17Br2BrO is Indium-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four hypobromous acid molecules and four HoO17Br2 clusters. In each HoO17Br2 cluster, Ho(1) is bonded in a 9-coordinate geometry to one O(7), two equivalent O(2), two equivalent O(3), two equivalent O(8), and two equivalent O(9) atoms. There are ten inequivalent O sites. In the first O site, O(6) is bonded in a water-like geometry to two equivalent O(2) atoms. In the second O site, O(7) is bonded in a single-bond geometry to one Ho(1) atom. In the third O site, O(8) is bonded in a water-like geometry to one Ho(1) and one O(1) atom. In the fourth O site, O(9) is bonded in a bent 150 degrees geometry to one Ho(1) and one O(4) atom. In the fifth O site, O(10) is bonded in a single-bond geometry to one Br(1) atom. In the sixth O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent O(8) atoms. In the seventh O site, O(2) is bonded in an L-shaped geometry to one Ho(1) and one O(6) atom. In the eighth O site, O(3) is bonded in a bent 120 degrees geometry to one Ho(1) and one Br(1) atom. In the ninth O site, O(4) is bonded in a single-bond geometry to one O(9) atom. In the tenth O site, O(5) is bonded in a single-bond geometry to one Br(1) atom. Br(1) is bonded in a trigonal non-coplanar geometry to one O(10), one O(3), and one O(5) atom. is represented by the CIF card [CIF]
data_Ho(BrO6)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.611
_cell_length_b   12.853
_cell_length_c   12.853
_cell_angle_alpha   128.533
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   854.391
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.515  0.349  0.651  1.0
  Ho  Ho1  1  0.015  0.651  0.349  1.0
  Br  Br2  1  0.331  0.180  0.324  1.0
  Br  Br3  1  0.831  0.324  0.180  1.0
  Br  Br4  1  0.831  0.820  0.676  1.0
  Br  Br5  1  0.331  0.676  0.820  1.0
  Br  Br6  1  0.338  0.101  0.899  1.0
  Br  Br7  1  0.838  0.899  0.101  1.0
  O  O8  1  0.889  0.264  0.736  1.0
  O  O9  1  0.389  0.736  0.264  1.0
  O  O10  1  0.790  0.296  0.506  1.0
  O  O11  1  0.290  0.506  0.296  1.0
  O  O12  1  0.290  0.704  0.494  1.0
  O  O13  1  0.790  0.494  0.704  1.0
  O  O14  1  0.354  0.189  0.466  1.0
  O  O15  1  0.854  0.466  0.189  1.0
  O  O16  1  0.854  0.811  0.534  1.0
  O  O17  1  0.354  0.534  0.811  1.0
  O  O18  1  0.291  0.068  0.651  1.0
  O  O19  1  0.791  0.651  0.068  1.0
  O  O20  1  0.791  0.932  0.349  1.0
  O  O21  1  0.291  0.349  0.932  1.0
  O  O22  1  0.236  0.329  0.384  1.0
  O  O23  1  0.736  0.384  0.329  1.0
  O  O24  1  0.736  0.671  0.616  1.0
  O  O25  1  0.236  0.616  0.671  1.0
  O  O26  1  0.890  0.411  0.589  1.0
  O  O27  1  0.970  0.554  0.446  1.0
  O  O28  1  0.470  0.446  0.554  1.0
  O  O29  1  0.390  0.589  0.411  1.0
  O  O30  1  0.794  0.182  0.620  1.0
  O  O31  1  0.912  0.618  0.115  1.0
  O  O32  1  0.412  0.115  0.618  1.0
  O  O33  1  0.294  0.620  0.182  1.0
  O  O34  1  0.912  0.885  0.383  1.0
  O  O35  1  0.794  0.380  0.818  1.0
  O  O36  1  0.294  0.818  0.380  1.0
  O  O37  1  0.412  0.383  0.885  1.0
  O  O38  1  0.149  0.071  0.232  1.0
  O  O39  1  0.649  0.232  0.071  1.0
  O  O40  1  0.149  0.768  0.929  1.0
  O  O41  1  0.649  0.929  0.768  1.0
  O  O42  1  0.078  0.100  0.900  1.0
  O  O43  1  0.578  0.900  0.100  1.0
[/CIF]
.
The crystal structure described by HoO17Br2BrO is Indium-derived structured and crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four hypobromous acid molecules and four HoO17Br2 clusters. In each HoO17Br2 cluster, Ho(1) is bonded in a 9-coordinate geometry to one O(7), two equivalent O(2), two equivalent O(3), two equivalent O(8), and two equivalent O(9) atoms. There are ten inequivalent O sites. In the first O site, O(6) is bonded in a water-like geometry to two equivalent O(2) atoms. In the second O site, O(7) is bonded in a single-bond geometry to one Ho(1) atom. In the third O site, O(8) is bonded in a water-like geometry to one Ho(1) and one O(1) atom. In the fourth O site, O(9) is bonded in a bent 150 degrees geometry to one Ho(1) and one O(4) atom. In the fifth O site, O(10) is bonded in a single-bond geometry to one Br(1) atom. In the sixth O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent O(8) atoms. In the seventh O site, O(2) is bonded in an L-shaped geometry to one Ho(1) and one O(6) atom. In the eighth O site, O(3) is bonded in a bent 120 degrees geometry to one Ho(1) and one Br(1) atom. In the ninth O site, O(4) is bonded in a single-bond geometry to one O(9) atom. In the tenth O site, O(5) is bonded in a single-bond geometry to one Br(1) atom. Br(1) is bonded in a trigonal non-coplanar geometry to one O(10), one O(3), and one O(5) atom. is represented by the CIF card [CIF]
data_Ho(BrO6)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.611
_cell_length_b   12.853
_cell_length_c   12.853
_cell_angle_alpha   128.533
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   854.391
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.515  0.349  0.651  1.0
  Ho  Ho1  1  0.015  0.651  0.349  1.0
  Br  Br2  1  0.331  0.180  0.324  1.0
  Br  Br3  1  0.831  0.324  0.180  1.0
  Br  Br4  1  0.831  0.820  0.676  1.0
  Br  Br5  1  0.331  0.676  0.820  1.0
  Br  Br6  1  0.338  0.101  0.899  1.0
  Br  Br7  1  0.838  0.899  0.101  1.0
  O  O8  1  0.889  0.264  0.736  1.0
  O  O9  1  0.389  0.736  0.264  1.0
  O  O10  1  0.790  0.296  0.506  1.0
  O  O11  1  0.290  0.506  0.296  1.0
  O  O12  1  0.290  0.704  0.494  1.0
  O  O13  1  0.790  0.494  0.704  1.0
  O  O14  1  0.354  0.189  0.466  1.0
  O  O15  1  0.854  0.466  0.189  1.0
  O  O16  1  0.854  0.811  0.534  1.0
  O  O17  1  0.354  0.534  0.811  1.0
  O  O18  1  0.291  0.068  0.651  1.0
  O  O19  1  0.791  0.651  0.068  1.0
  O  O20  1  0.791  0.932  0.349  1.0
  O  O21  1  0.291  0.349  0.932  1.0
  O  O22  1  0.236  0.329  0.384  1.0
  O  O23  1  0.736  0.384  0.329  1.0
  O  O24  1  0.736  0.671  0.616  1.0
  O  O25  1  0.236  0.616  0.671  1.0
  O  O26  1  0.890  0.411  0.589  1.0
  O  O27  1  0.970  0.554  0.446  1.0
  O  O28  1  0.470  0.446  0.554  1.0
  O  O29  1  0.390  0.589  0.411  1.0
  O  O30  1  0.794  0.182  0.620  1.0
  O  O31  1  0.912  0.618  0.115  1.0
  O  O32  1  0.412  0.115  0.618  1.0
  O  O33  1  0.294  0.620  0.182  1.0
  O  O34  1  0.912  0.885  0.383  1.0
  O  O35  1  0.794  0.380  0.818  1.0
  O  O36  1  0.294  0.818  0.380  1.0
  O  O37  1  0.412  0.383  0.885  1.0
  O  O38  1  0.149  0.071  0.232  1.0
  O  O39  1  0.649  0.232  0.071  1.0
  O  O40  1  0.149  0.768  0.929  1.0
  O  O41  1  0.649  0.929  0.768  1.0
  O  O42  1  0.078  0.100  0.900  1.0
  O  O43  1  0.578  0.900  0.100  1.0
[/CIF]
.