The structure described by RbCrO3Cl crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 11-coordinate geometry to two equivalent O(1), three equivalent O(2), three equivalent O(3), and three equivalent Cl(1) atoms. Cr(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one Cl(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Cr(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Cr(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to three equivalent Rb(1) and one Cr(1) atom. Cl(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one Cr(1) atom. is represented by the CIF card [CIF]
data_RbCrClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.765
_cell_length_b   8.256
_cell_length_c   8.286
_cell_angle_alpha   89.294
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   531.178
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.143  0.366  0.185  1.0
  Rb  Rb1  1  0.357  0.866  0.185  1.0
  Rb  Rb2  1  0.857  0.634  0.815  1.0
  Rb  Rb3  1  0.643  0.134  0.815  1.0
  Cr  Cr4  1  0.874  0.874  0.222  1.0
  Cr  Cr5  1  0.126  0.126  0.778  1.0
  Cr  Cr6  1  0.626  0.374  0.222  1.0
  Cr  Cr7  1  0.374  0.626  0.778  1.0
  Cl  Cl8  1  0.776  0.361  0.445  1.0
  Cl  Cl9  1  0.224  0.639  0.555  1.0
  Cl  Cl10  1  0.724  0.861  0.445  1.0
  Cl  Cl11  1  0.276  0.139  0.555  1.0
  O  O12  1  0.500  0.531  0.226  1.0
  O  O13  1  0.740  0.887  0.072  1.0
  O  O14  1  1.000  0.969  0.774  1.0
  O  O15  1  0.991  0.711  0.207  1.0
  O  O16  1  0.240  0.613  0.928  1.0
  O  O17  1  0.491  0.789  0.793  1.0
  O  O18  1  0.000  0.031  0.226  1.0
  O  O19  1  0.500  0.469  0.774  1.0
  O  O20  1  0.009  0.289  0.793  1.0
  O  O21  1  0.509  0.211  0.207  1.0
  O  O22  1  0.260  0.113  0.928  1.0
  O  O23  1  0.760  0.387  0.072  1.0
[/CIF]
.
The structure described by RbCrO3Cl crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 11-coordinate geometry to two equivalent O(1), three equivalent O(2), three equivalent O(3), and three equivalent Cl(1) atoms. Cr(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one Cl(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Cr(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Cr(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to three equivalent Rb(1) and one Cr(1) atom. Cl(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one Cr(1) atom. is represented by the CIF card [CIF]
data_RbCrClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.765
_cell_length_b   8.256
_cell_length_c   8.286
_cell_angle_alpha   89.294
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   531.178
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.143  0.366  0.185  1.0
  Rb  Rb1  1  0.357  0.866  0.185  1.0
  Rb  Rb2  1  0.857  0.634  0.815  1.0
  Rb  Rb3  1  0.643  0.134  0.815  1.0
  Cr  Cr4  1  0.874  0.874  0.222  1.0
  Cr  Cr5  1  0.126  0.126  0.778  1.0
  Cr  Cr6  1  0.626  0.374  0.222  1.0
  Cr  Cr7  1  0.374  0.626  0.778  1.0
  Cl  Cl8  1  0.776  0.361  0.445  1.0
  Cl  Cl9  1  0.224  0.639  0.555  1.0
  Cl  Cl10  1  0.724  0.861  0.445  1.0
  Cl  Cl11  1  0.276  0.139  0.555  1.0
  O  O12  1  0.500  0.531  0.226  1.0
  O  O13  1  0.740  0.887  0.072  1.0
  O  O14  1  1.000  0.969  0.774  1.0
  O  O15  1  0.991  0.711  0.207  1.0
  O  O16  1  0.240  0.613  0.928  1.0
  O  O17  1  0.491  0.789  0.793  1.0
  O  O18  1  0.000  0.031  0.226  1.0
  O  O19  1  0.500  0.469  0.774  1.0
  O  O20  1  0.009  0.289  0.793  1.0
  O  O21  1  0.509  0.211  0.207  1.0
  O  O22  1  0.260  0.113  0.928  1.0
  O  O23  1  0.760  0.387  0.072  1.0
[/CIF]
.