The material structure described by N2S3Cl is Indium-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight N2S3Cl clusters. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(1) and one Cl(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a distorted single-bond geometry to one N(2) and one Cl(1) atom. Cl(1) is bonded in a 2-coordinate geometry to one S(1) and one S(3) atom. is represented by the CIF file [CIF]
data_S3N2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.514
_cell_length_b   8.520
_cell_length_c   14.634
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1061.541
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.164  0.523  0.924  1.0
  S  S1  1  0.336  0.023  0.076  1.0
  S  S2  1  0.664  0.477  0.576  1.0
  S  S3  1  0.011  0.099  0.282  1.0
  S  S4  1  0.164  0.023  0.576  1.0
  S  S5  1  0.664  0.977  0.924  1.0
  S  S6  1  0.336  0.523  0.424  1.0
  S  S7  1  0.836  0.477  0.076  1.0
  S  S8  1  0.956  0.196  0.460  1.0
  S  S9  1  0.956  0.696  0.040  1.0
  S  S10  1  0.456  0.304  0.460  1.0
  S  S11  1  0.544  0.196  0.960  1.0
  S  S12  1  0.044  0.804  0.540  1.0
  S  S13  1  0.044  0.304  0.960  1.0
  S  S14  1  0.544  0.696  0.540  1.0
  S  S15  1  0.456  0.804  0.040  1.0
  S  S16  1  0.511  0.901  0.218  1.0
  S  S17  1  0.011  0.599  0.218  1.0
  S  S18  1  0.511  0.401  0.282  1.0
  S  S19  1  0.488  0.099  0.782  1.0
  S  S20  1  0.989  0.901  0.718  1.0
  S  S21  1  0.989  0.401  0.782  1.0
  S  S22  1  0.488  0.599  0.718  1.0
  S  S23  1  0.836  0.977  0.424  1.0
  N  N24  1  0.894  0.971  0.319  1.0
  N  N25  1  0.037  0.724  0.139  1.0
  N  N26  1  0.537  0.276  0.361  1.0
  N  N27  1  0.463  0.224  0.861  1.0
  N  N28  1  0.963  0.776  0.639  1.0
  N  N29  1  0.963  0.276  0.861  1.0
  N  N30  1  0.463  0.724  0.639  1.0
  N  N31  1  0.537  0.776  0.139  1.0
  N  N32  1  0.037  0.224  0.361  1.0
  N  N33  1  0.894  0.471  0.181  1.0
  N  N34  1  0.394  0.529  0.319  1.0
  N  N35  1  0.606  0.971  0.819  1.0
  N  N36  1  0.106  0.029  0.681  1.0
  N  N37  1  0.106  0.529  0.819  1.0
  N  N38  1  0.606  0.471  0.681  1.0
  N  N39  1  0.394  0.029  0.181  1.0
  Cl  Cl40  1  0.742  0.104  0.595  1.0
  Cl  Cl41  1  0.242  0.896  0.905  1.0
  Cl  Cl42  1  0.758  0.604  0.405  1.0
  Cl  Cl43  1  0.258  0.396  0.095  1.0
  Cl  Cl44  1  0.258  0.896  0.405  1.0
  Cl  Cl45  1  0.758  0.104  0.095  1.0
  Cl  Cl46  1  0.242  0.396  0.595  1.0
  Cl  Cl47  1  0.742  0.604  0.905  1.0
[/CIF]
.
The material structure described by N2S3Cl is Indium-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight N2S3Cl clusters. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(1) and one Cl(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a distorted single-bond geometry to one N(2) and one Cl(1) atom. Cl(1) is bonded in a 2-coordinate geometry to one S(1) and one S(3) atom. is represented by the CIF file [CIF]
data_S3N2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.514
_cell_length_b   8.520
_cell_length_c   14.634
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1061.541
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.164  0.523  0.924  1.0
  S  S1  1  0.336  0.023  0.076  1.0
  S  S2  1  0.664  0.477  0.576  1.0
  S  S3  1  0.011  0.099  0.282  1.0
  S  S4  1  0.164  0.023  0.576  1.0
  S  S5  1  0.664  0.977  0.924  1.0
  S  S6  1  0.336  0.523  0.424  1.0
  S  S7  1  0.836  0.477  0.076  1.0
  S  S8  1  0.956  0.196  0.460  1.0
  S  S9  1  0.956  0.696  0.040  1.0
  S  S10  1  0.456  0.304  0.460  1.0
  S  S11  1  0.544  0.196  0.960  1.0
  S  S12  1  0.044  0.804  0.540  1.0
  S  S13  1  0.044  0.304  0.960  1.0
  S  S14  1  0.544  0.696  0.540  1.0
  S  S15  1  0.456  0.804  0.040  1.0
  S  S16  1  0.511  0.901  0.218  1.0
  S  S17  1  0.011  0.599  0.218  1.0
  S  S18  1  0.511  0.401  0.282  1.0
  S  S19  1  0.488  0.099  0.782  1.0
  S  S20  1  0.989  0.901  0.718  1.0
  S  S21  1  0.989  0.401  0.782  1.0
  S  S22  1  0.488  0.599  0.718  1.0
  S  S23  1  0.836  0.977  0.424  1.0
  N  N24  1  0.894  0.971  0.319  1.0
  N  N25  1  0.037  0.724  0.139  1.0
  N  N26  1  0.537  0.276  0.361  1.0
  N  N27  1  0.463  0.224  0.861  1.0
  N  N28  1  0.963  0.776  0.639  1.0
  N  N29  1  0.963  0.276  0.861  1.0
  N  N30  1  0.463  0.724  0.639  1.0
  N  N31  1  0.537  0.776  0.139  1.0
  N  N32  1  0.037  0.224  0.361  1.0
  N  N33  1  0.894  0.471  0.181  1.0
  N  N34  1  0.394  0.529  0.319  1.0
  N  N35  1  0.606  0.971  0.819  1.0
  N  N36  1  0.106  0.029  0.681  1.0
  N  N37  1  0.106  0.529  0.819  1.0
  N  N38  1  0.606  0.471  0.681  1.0
  N  N39  1  0.394  0.029  0.181  1.0
  Cl  Cl40  1  0.742  0.104  0.595  1.0
  Cl  Cl41  1  0.242  0.896  0.905  1.0
  Cl  Cl42  1  0.758  0.604  0.405  1.0
  Cl  Cl43  1  0.258  0.396  0.095  1.0
  Cl  Cl44  1  0.258  0.896  0.405  1.0
  Cl  Cl45  1  0.758  0.104  0.095  1.0
  Cl  Cl46  1  0.242  0.396  0.595  1.0
  Cl  Cl47  1  0.742  0.604  0.905  1.0
[/CIF]
.