The material structure described by GaCl4NSe2Cl2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four GaCl4 clusters and four NSe2Cl2 clusters. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(5) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Ga(1) atom. In each NSe2Cl2 cluster, N(1) is bonded in a bent 150 degrees geometry to one Se(1) and one Se(2) atom. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a water-like geometry to one N(1) and one Cl(6) atom. In the second Se site, Se(2) is bonded in a water-like geometry to one N(1) and one Cl(4) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Se(2) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Se(1) atom. is represented by the CIF file [CIF]
data_GaSe2NCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.814
_cell_length_b   10.196
_cell_length_c   11.060
_cell_angle_alpha   65.525
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1212.575
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.194  0.827  0.487  1.0
  Ga  Ga1  1  0.806  0.173  0.513  1.0
  Ga  Ga2  1  0.694  0.173  0.013  1.0
  Ga  Ga3  1  0.306  0.827  0.987  1.0
  Se  Se4  1  0.546  0.726  0.454  1.0
  Se  Se5  1  0.454  0.274  0.546  1.0
  Se  Se6  1  0.954  0.726  0.954  1.0
  Se  Se7  1  0.682  0.788  0.879  1.0
  Se  Se8  1  0.318  0.212  0.121  1.0
  Se  Se9  1  0.046  0.274  0.046  1.0
  Se  Se10  1  0.818  0.788  0.379  1.0
  Se  Se11  1  0.182  0.212  0.621  1.0
  N  N12  1  0.672  0.785  0.372  1.0
  N  N13  1  0.828  0.785  0.872  1.0
  N  N14  1  0.172  0.215  0.128  1.0
  N  N15  1  0.328  0.215  0.628  1.0
  Cl  Cl16  1  0.414  0.836  0.822  1.0
  Cl  Cl17  1  0.403  0.858  0.143  1.0
  Cl  Cl18  1  0.176  0.003  0.913  1.0
  Cl  Cl19  1  0.824  0.997  0.087  1.0
  Cl  Cl20  1  0.914  0.164  0.678  1.0
  Cl  Cl21  1  0.097  0.858  0.643  1.0
  Cl  Cl22  1  0.368  0.365  0.922  1.0
  Cl  Cl23  1  0.288  0.622  0.567  1.0
  Cl  Cl24  1  0.920  0.576  0.160  1.0
  Cl  Cl25  1  0.586  0.164  0.178  1.0
  Cl  Cl26  1  0.676  0.997  0.587  1.0
  Cl  Cl27  1  0.212  0.622  0.067  1.0
  Cl  Cl28  1  0.868  0.635  0.578  1.0
  Cl  Cl29  1  0.324  0.003  0.413  1.0
  Cl  Cl30  1  0.632  0.635  0.078  1.0
  Cl  Cl31  1  0.597  0.142  0.857  1.0
  Cl  Cl32  1  0.086  0.836  0.322  1.0
  Cl  Cl33  1  0.132  0.365  0.422  1.0
  Cl  Cl34  1  0.080  0.424  0.840  1.0
  Cl  Cl35  1  0.712  0.378  0.433  1.0
  Cl  Cl36  1  0.580  0.576  0.660  1.0
  Cl  Cl37  1  0.788  0.378  0.933  1.0
  Cl  Cl38  1  0.420  0.424  0.340  1.0
  Cl  Cl39  1  0.903  0.142  0.357  1.0
[/CIF]
.
The material structure described by GaCl4NSe2Cl2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four GaCl4 clusters and four NSe2Cl2 clusters. In each GaCl4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(5) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ga(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Ga(1) atom. In each NSe2Cl2 cluster, N(1) is bonded in a bent 150 degrees geometry to one Se(1) and one Se(2) atom. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a water-like geometry to one N(1) and one Cl(6) atom. In the second Se site, Se(2) is bonded in a water-like geometry to one N(1) and one Cl(4) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Se(2) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Se(1) atom. is represented by the CIF file [CIF]
data_GaSe2NCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.814
_cell_length_b   10.196
_cell_length_c   11.060
_cell_angle_alpha   65.525
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1212.575
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.194  0.827  0.487  1.0
  Ga  Ga1  1  0.806  0.173  0.513  1.0
  Ga  Ga2  1  0.694  0.173  0.013  1.0
  Ga  Ga3  1  0.306  0.827  0.987  1.0
  Se  Se4  1  0.546  0.726  0.454  1.0
  Se  Se5  1  0.454  0.274  0.546  1.0
  Se  Se6  1  0.954  0.726  0.954  1.0
  Se  Se7  1  0.682  0.788  0.879  1.0
  Se  Se8  1  0.318  0.212  0.121  1.0
  Se  Se9  1  0.046  0.274  0.046  1.0
  Se  Se10  1  0.818  0.788  0.379  1.0
  Se  Se11  1  0.182  0.212  0.621  1.0
  N  N12  1  0.672  0.785  0.372  1.0
  N  N13  1  0.828  0.785  0.872  1.0
  N  N14  1  0.172  0.215  0.128  1.0
  N  N15  1  0.328  0.215  0.628  1.0
  Cl  Cl16  1  0.414  0.836  0.822  1.0
  Cl  Cl17  1  0.403  0.858  0.143  1.0
  Cl  Cl18  1  0.176  0.003  0.913  1.0
  Cl  Cl19  1  0.824  0.997  0.087  1.0
  Cl  Cl20  1  0.914  0.164  0.678  1.0
  Cl  Cl21  1  0.097  0.858  0.643  1.0
  Cl  Cl22  1  0.368  0.365  0.922  1.0
  Cl  Cl23  1  0.288  0.622  0.567  1.0
  Cl  Cl24  1  0.920  0.576  0.160  1.0
  Cl  Cl25  1  0.586  0.164  0.178  1.0
  Cl  Cl26  1  0.676  0.997  0.587  1.0
  Cl  Cl27  1  0.212  0.622  0.067  1.0
  Cl  Cl28  1  0.868  0.635  0.578  1.0
  Cl  Cl29  1  0.324  0.003  0.413  1.0
  Cl  Cl30  1  0.632  0.635  0.078  1.0
  Cl  Cl31  1  0.597  0.142  0.857  1.0
  Cl  Cl32  1  0.086  0.836  0.322  1.0
  Cl  Cl33  1  0.132  0.365  0.422  1.0
  Cl  Cl34  1  0.080  0.424  0.840  1.0
  Cl  Cl35  1  0.712  0.378  0.433  1.0
  Cl  Cl36  1  0.580  0.576  0.660  1.0
  Cl  Cl37  1  0.788  0.378  0.933  1.0
  Cl  Cl38  1  0.420  0.424  0.340  1.0
  Cl  Cl39  1  0.903  0.142  0.357  1.0
[/CIF]
.