The material structure described by (SbF6)3(AsF3)2S14I3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two arsenic trifluoride molecules, one S14I3 cluster, and three SbF6 clusters. In the S14I3 cluster, there are seven inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(4) and one S(6) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(4) and one S(5) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(6) and one S(7) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(1) and one S(2) atom. In the fifth S site, S(5) is bonded in a trigonal non-coplanar geometry to one S(2), one S(7), and one I(2) atom. In the sixth S site, S(6) is bonded in a distorted trigonal non-coplanar geometry to one S(1), one S(3), and one I(1) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one S(3) and one S(5) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one S(6) atom. In the second I site, I(2) is bonded in a linear geometry to two equivalent S(5) atoms. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(6), and one F(7) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_Sb3As2S14(IF8)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.472
_cell_length_b   9.546
_cell_length_c   13.465
_cell_angle_alpha   71.600
_cell_angle_beta   85.049
_cell_angle_gamma   85.321
_symmetry_Int_Tables_number   1
_cell_volume   1027.791
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.468  0.216  0.665  1.0
  Sb  Sb1  1  0.532  0.784  0.335  1.0
  Sb  Sb2  1  0.000  0.000  0.000  1.0
  As  As3  1  0.519  0.230  0.003  1.0
  As  As4  1  0.481  0.770  0.997  1.0
  S  S5  1  0.910  0.934  0.693  1.0
  S  S6  1  0.742  0.628  0.709  1.0
  S  S7  1  0.258  0.372  0.291  1.0
  S  S8  1  0.964  0.407  0.135  1.0
  S  S9  1  0.036  0.593  0.865  1.0
  S  S10  1  0.158  0.180  0.396  1.0
  S  S11  1  0.884  0.455  0.696  1.0
  S  S12  1  0.872  0.169  0.244  1.0
  S  S13  1  0.090  0.066  0.307  1.0
  S  S14  1  0.116  0.545  0.304  1.0
  S  S15  1  0.842  0.820  0.604  1.0
  S  S16  1  0.128  0.831  0.756  1.0
  S  S17  1  0.899  0.542  0.210  1.0
  S  S18  1  0.101  0.458  0.790  1.0
  I  I19  1  0.284  0.760  0.625  1.0
  I  I20  1  0.000  0.500  0.500  1.0
  I  I21  1  0.716  0.240  0.375  1.0
  F  F22  1  0.442  0.253  0.516  1.0
  F  F23  1  0.438  0.423  0.647  1.0
  F  F24  1  0.244  0.196  0.692  1.0
  F  F25  1  0.502  0.009  0.683  1.0
  F  F26  1  0.653  0.359  0.922  1.0
  F  F27  1  0.308  0.762  0.372  1.0
  F  F28  1  0.562  0.577  0.353  1.0
  F  F29  1  0.498  0.991  0.317  1.0
  F  F30  1  0.501  0.822  0.189  1.0
  F  F31  1  0.347  0.641  0.077  1.0
  F  F32  1  0.651  0.646  0.022  1.0
  F  F33  1  0.960  0.105  0.857  1.0
  F  F34  1  0.558  0.268  0.120  1.0
  F  F35  1  0.349  0.354  0.978  1.0
  F  F36  1  0.225  0.001  0.965  1.0
  F  F37  1  0.040  0.895  0.143  1.0
  F  F38  1  0.442  0.732  0.880  1.0
  F  F39  1  0.499  0.178  0.811  1.0
  F  F40  1  0.005  0.184  0.030  1.0
  F  F41  1  0.558  0.747  0.484  1.0
  F  F42  1  0.692  0.238  0.628  1.0
  F  F43  1  0.756  0.804  0.308  1.0
  F  F44  1  0.775  0.999  0.035  1.0
  F  F45  1  0.995  0.816  0.970  1.0
[/CIF]
.
The material structure described by (SbF6)3(AsF3)2S14I3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two arsenic trifluoride molecules, one S14I3 cluster, and three SbF6 clusters. In the S14I3 cluster, there are seven inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(4) and one S(6) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(4) and one S(5) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(6) and one S(7) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one S(1) and one S(2) atom. In the fifth S site, S(5) is bonded in a trigonal non-coplanar geometry to one S(2), one S(7), and one I(2) atom. In the sixth S site, S(6) is bonded in a distorted trigonal non-coplanar geometry to one S(1), one S(3), and one I(1) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one S(3) and one S(5) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one S(6) atom. In the second I site, I(2) is bonded in a linear geometry to two equivalent S(5) atoms. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(6), and one F(7) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_Sb3As2S14(IF8)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.472
_cell_length_b   9.546
_cell_length_c   13.465
_cell_angle_alpha   71.600
_cell_angle_beta   85.049
_cell_angle_gamma   85.321
_symmetry_Int_Tables_number   1
_cell_volume   1027.791
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.468  0.216  0.665  1.0
  Sb  Sb1  1  0.532  0.784  0.335  1.0
  Sb  Sb2  1  0.000  0.000  0.000  1.0
  As  As3  1  0.519  0.230  0.003  1.0
  As  As4  1  0.481  0.770  0.997  1.0
  S  S5  1  0.910  0.934  0.693  1.0
  S  S6  1  0.742  0.628  0.709  1.0
  S  S7  1  0.258  0.372  0.291  1.0
  S  S8  1  0.964  0.407  0.135  1.0
  S  S9  1  0.036  0.593  0.865  1.0
  S  S10  1  0.158  0.180  0.396  1.0
  S  S11  1  0.884  0.455  0.696  1.0
  S  S12  1  0.872  0.169  0.244  1.0
  S  S13  1  0.090  0.066  0.307  1.0
  S  S14  1  0.116  0.545  0.304  1.0
  S  S15  1  0.842  0.820  0.604  1.0
  S  S16  1  0.128  0.831  0.756  1.0
  S  S17  1  0.899  0.542  0.210  1.0
  S  S18  1  0.101  0.458  0.790  1.0
  I  I19  1  0.284  0.760  0.625  1.0
  I  I20  1  0.000  0.500  0.500  1.0
  I  I21  1  0.716  0.240  0.375  1.0
  F  F22  1  0.442  0.253  0.516  1.0
  F  F23  1  0.438  0.423  0.647  1.0
  F  F24  1  0.244  0.196  0.692  1.0
  F  F25  1  0.502  0.009  0.683  1.0
  F  F26  1  0.653  0.359  0.922  1.0
  F  F27  1  0.308  0.762  0.372  1.0
  F  F28  1  0.562  0.577  0.353  1.0
  F  F29  1  0.498  0.991  0.317  1.0
  F  F30  1  0.501  0.822  0.189  1.0
  F  F31  1  0.347  0.641  0.077  1.0
  F  F32  1  0.651  0.646  0.022  1.0
  F  F33  1  0.960  0.105  0.857  1.0
  F  F34  1  0.558  0.268  0.120  1.0
  F  F35  1  0.349  0.354  0.978  1.0
  F  F36  1  0.225  0.001  0.965  1.0
  F  F37  1  0.040  0.895  0.143  1.0
  F  F38  1  0.442  0.732  0.880  1.0
  F  F39  1  0.499  0.178  0.811  1.0
  F  F40  1  0.005  0.184  0.030  1.0
  F  F41  1  0.558  0.747  0.484  1.0
  F  F42  1  0.692  0.238  0.628  1.0
  F  F43  1  0.756  0.804  0.308  1.0
  F  F44  1  0.775  0.999  0.035  1.0
  F  F45  1  0.995  0.816  0.970  1.0
[/CIF]
.