The compound described by CsNO3 crystallizes in the triclinic P1 space group. There are nine inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 11-coordinate geometry to one O(10), one O(12), one O(16), one O(17), one O(19), one O(2), one O(20), one O(25), one O(26), one O(4), and one O(6) atom. In the second Cs site, Cs(2) is bonded in a 12-coordinate geometry to one O(11), one O(14), one O(15), one O(17), one O(21), one O(22), one O(24), one O(25), one O(27), one O(3), one O(8), and one O(9) atom. In the third Cs site, Cs(3) is bonded in a 11-coordinate geometry to one O(10), one O(13), one O(14), one O(15), one O(16), one O(24), one O(26), one O(4), one O(7), one O(8), and one O(9) atom. In the fourth Cs site, Cs(4) is bonded in a 12-coordinate geometry to one O(13), one O(15), one O(17), one O(18), one O(19), one O(2), one O(20), one O(24), one O(3), one O(6), one O(7), and one O(9) atom. In the fifth Cs site, Cs(5) is bonded in a 12-coordinate geometry to one O(1), one O(12), one O(13), one O(16), one O(18), one O(21), one O(23), one O(24), one O(27), one O(5), one O(6), and one O(7) atom. In the sixth Cs site, Cs(6) is bonded in a 12-coordinate geometry to one O(1), one O(10), one O(12), one O(14), one O(15), one O(18), one O(2), one O(21), one O(22), one O(26), one O(5), and one O(8) atom. In the seventh Cs site, Cs(7) is bonded in a 12-coordinate geometry to one O(1), one O(11), one O(12), one O(17), one O(19), one O(2), one O(23), one O(26), one O(27), one O(3), one O(5), and one O(9) atom. In the eighth Cs site, Cs(8) is bonded in a 12-coordinate geometry to one O(11), one O(13), one O(14), one O(18), one O(19), one O(20), one O(21), one O(22), one O(25), one O(4), one O(5), and one O(6) atom. In the ninth Cs site, Cs(9) is bonded in a 11-coordinate geometry to one O(1), one O(10), one O(11), one O(16), one O(22), one O(23), one O(25), one O(27), one O(3), one O(4), and one O(7) atom. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(12), one O(14), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(17), one O(19), and one O(24) atom. In the third N site, N(3,4) is bonded in a trigonal planar geometry to one O(2), one O(27), and one O(3) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one O(1), one O(13), and one O(18) atom. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one O(21), one O(22), and one O(6) atom. In the sixth N site, N(7) is bonded in a trigonal planar geometry to one O(23), one O(25), and one O(4) atom. In the seventh N site, N(8) is bonded in a trigonal planar geometry to one O(10), one O(20), and one O(26) atom. In the eighth N site, N(9) is bonded in a trigonal planar geometry to one O(16), one O(7), and one O(8) atom. There are twenty-seven inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cs(5), one Cs(6), one Cs(7), one Cs(9), and one N(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cs(1); one Cs(4); one Cs(6); one Cs(7); and one N(3,4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cs(2); one Cs(4); one Cs(7); one Cs(9); and one N(3,4) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cs(1), one Cs(3), one Cs(8), one Cs(9), and one N(7) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Cs(5), one Cs(6), one Cs(7), one Cs(8), and one N(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Cs(1), one Cs(4), one Cs(5), one Cs(8), and one N(6) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Cs(3), one Cs(4), one Cs(5), one Cs(9), and one N(9) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Cs(2), one Cs(3), one Cs(6), and one N(9) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Cs(2); one Cs(3); one Cs(4); one Cs(7); and one N(3,4) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one Cs(1), one Cs(3), one Cs(6), one Cs(9), and one N(8) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Cs(2); one Cs(7); one Cs(8); one Cs(9); and one N(3,4) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Cs(1), one Cs(5), one Cs(6), one Cs(7), and one N(1) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one Cs(3), one Cs(4), one Cs(5), one Cs(8), and one N(5) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Cs(2), one Cs(3), one Cs(6), one Cs(8), and one N(1) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Cs(2); one Cs(3); one Cs(4); one Cs(6); and one N(3,4) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one Cs(1), one Cs(3), one Cs(5), one Cs(9), and one N(9) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one Cs(1), one Cs(2), one Cs(4), one Cs(7), and one N(2) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one Cs(4), one Cs(5), one Cs(6), one Cs(8), and one N(5) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(4), one Cs(7), one Cs(8), and one N(2) atom. In the twentieth O site, O(20) is bonded in a single-bond geometry to one Cs(1), one Cs(4), one Cs(8), and one N(8) atom. In the twenty-first O site, O(21) is bonded in a single-bond geometry to one Cs(2), one Cs(5), one Cs(6), one Cs(8), and one N(6) atom. In the twenty-second O site, O(22) is bonded in a single-bond geometry to one Cs(2), one Cs(6), one Cs(8), one Cs(9), and one N(6) atom. In the twenty-third O site, O(23) is bonded in a single-bond geometry to one Cs(5), one Cs(7), one Cs(9), and one N(7) atom. In the twenty-fourth O site, O(24) is bonded in a single-bond geometry to one Cs(2), one Cs(3), one Cs(4), one Cs(5), and one N(2) atom. In the twenty-fifth O site, O(25) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(2), one Cs(8), one Cs(9), and one N(7) atom. In the twenty-sixth O site, O(26) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(3), one Cs(6), one Cs(7), and one N(8) atom. In the twenty-seventh O site, O(27) is bonded in a distorted single-bond geometry to one Cs(2); one Cs(5); one Cs(7); one Cs(9); and one N(3,4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsNO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.847
_cell_length_b   10.845
_cell_length_c   7.681
_cell_angle_alpha   89.993
_cell_angle_beta   89.992
_cell_angle_gamma   119.992
_symmetry_Int_Tables_number   1
_cell_volume   782.528
_cell_formula_units_Z   9
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.778  0.220  0.648  1.0
  Cs  Cs1  1  0.119  0.897  0.623  1.0
  Cs  Cs2  1  0.780  0.558  0.982  1.0
  Cs  Cs3  1  0.778  0.881  0.290  1.0
  Cs  Cs4  1  0.432  0.544  0.666  1.0
  Cs  Cs5  1  0.112  0.568  0.333  1.0
  Cs  Cs6  1  0.103  0.221  0.956  1.0
  Cs  Cs7  1  0.456  0.888  1.000  1.0
  Cs  Cs8  1  0.442  0.222  0.315  1.0
  N  N9  1  0.135  0.566  0.865  1.0
  N  N10  1  0.801  0.907  0.758  1.0
  N  N11  1  0.106  0.199  0.424  1.0
  N  N12  1  0.094  0.895  0.091  1.0
  N  N13  1  0.434  0.569  0.198  1.0
  N  N14  1  0.431  0.865  0.531  1.0
  N  N15  1  0.470  0.205  0.840  1.0
  N  N16  1  0.795  0.265  0.174  1.0
  N  N17  1  0.735  0.531  0.507  1.0
  O  O18  1  0.343  0.443  0.238  1.0
  O  O19  1  0.022  0.244  0.386  1.0
  O  O20  1  0.110  0.106  0.328  1.0
  O  O21  1  0.567  0.218  0.944  1.0
  O  O22  1  0.228  0.557  0.955  1.0
  O  O23  1  0.557  0.899  0.572  1.0
  O  O24  1  0.683  0.564  0.380  1.0
  O  O25  1  0.866  0.593  0.532  1.0
  O  O26  1  0.996  0.891  0.995  1.0
  O  O27  1  0.782  0.349  0.277  1.0
  O  O28  1  0.222  0.978  0.052  1.0
  O  O29  1  0.079  0.485  0.737  1.0
  O  O30  1  0.516  0.595  0.070  1.0
  O  O31  1  0.101  0.658  0.906  1.0
  O  O32  1  0.059  0.815  0.223  1.0
  O  O33  1  0.651  0.433  0.610  1.0
  O  O34  1  0.894  0.003  0.662  1.0
  O  O35  1  0.443  0.671  0.288  1.0
  O  O36  1  0.756  0.942  0.889  1.0
  O  O37  1  0.725  0.133  0.199  1.0
  O  O38  1  0.328  0.771  0.621  1.0
  O  O39  1  0.405  0.921  0.404  1.0
  O  O40  1  0.408  0.274  0.866  1.0
  O  O41  1  0.755  0.778  0.720  1.0
  O  O42  1  0.437  0.120  0.714  1.0
  O  O43  1  0.881  0.317  0.047  1.0
  O  O44  1  0.185  0.244  0.556  1.0
[/CIF]
.
The compound described by CsNO3 crystallizes in the triclinic P1 space group. There are nine inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 11-coordinate geometry to one O(10), one O(12), one O(16), one O(17), one O(19), one O(2), one O(20), one O(25), one O(26), one O(4), and one O(6) atom. In the second Cs site, Cs(2) is bonded in a 12-coordinate geometry to one O(11), one O(14), one O(15), one O(17), one O(21), one O(22), one O(24), one O(25), one O(27), one O(3), one O(8), and one O(9) atom. In the third Cs site, Cs(3) is bonded in a 11-coordinate geometry to one O(10), one O(13), one O(14), one O(15), one O(16), one O(24), one O(26), one O(4), one O(7), one O(8), and one O(9) atom. In the fourth Cs site, Cs(4) is bonded in a 12-coordinate geometry to one O(13), one O(15), one O(17), one O(18), one O(19), one O(2), one O(20), one O(24), one O(3), one O(6), one O(7), and one O(9) atom. In the fifth Cs site, Cs(5) is bonded in a 12-coordinate geometry to one O(1), one O(12), one O(13), one O(16), one O(18), one O(21), one O(23), one O(24), one O(27), one O(5), one O(6), and one O(7) atom. In the sixth Cs site, Cs(6) is bonded in a 12-coordinate geometry to one O(1), one O(10), one O(12), one O(14), one O(15), one O(18), one O(2), one O(21), one O(22), one O(26), one O(5), and one O(8) atom. In the seventh Cs site, Cs(7) is bonded in a 12-coordinate geometry to one O(1), one O(11), one O(12), one O(17), one O(19), one O(2), one O(23), one O(26), one O(27), one O(3), one O(5), and one O(9) atom. In the eighth Cs site, Cs(8) is bonded in a 12-coordinate geometry to one O(11), one O(13), one O(14), one O(18), one O(19), one O(20), one O(21), one O(22), one O(25), one O(4), one O(5), and one O(6) atom. In the ninth Cs site, Cs(9) is bonded in a 11-coordinate geometry to one O(1), one O(10), one O(11), one O(16), one O(22), one O(23), one O(25), one O(27), one O(3), one O(4), and one O(7) atom. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(12), one O(14), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(17), one O(19), and one O(24) atom. In the third N site, N(3,4) is bonded in a trigonal planar geometry to one O(2), one O(27), and one O(3) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one O(1), one O(13), and one O(18) atom. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one O(21), one O(22), and one O(6) atom. In the sixth N site, N(7) is bonded in a trigonal planar geometry to one O(23), one O(25), and one O(4) atom. In the seventh N site, N(8) is bonded in a trigonal planar geometry to one O(10), one O(20), and one O(26) atom. In the eighth N site, N(9) is bonded in a trigonal planar geometry to one O(16), one O(7), and one O(8) atom. There are twenty-seven inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cs(5), one Cs(6), one Cs(7), one Cs(9), and one N(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cs(1); one Cs(4); one Cs(6); one Cs(7); and one N(3,4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cs(2); one Cs(4); one Cs(7); one Cs(9); and one N(3,4) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cs(1), one Cs(3), one Cs(8), one Cs(9), and one N(7) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Cs(5), one Cs(6), one Cs(7), one Cs(8), and one N(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Cs(1), one Cs(4), one Cs(5), one Cs(8), and one N(6) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Cs(3), one Cs(4), one Cs(5), one Cs(9), and one N(9) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Cs(2), one Cs(3), one Cs(6), and one N(9) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Cs(2); one Cs(3); one Cs(4); one Cs(7); and one N(3,4) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one Cs(1), one Cs(3), one Cs(6), one Cs(9), and one N(8) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Cs(2); one Cs(7); one Cs(8); one Cs(9); and one N(3,4) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Cs(1), one Cs(5), one Cs(6), one Cs(7), and one N(1) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one Cs(3), one Cs(4), one Cs(5), one Cs(8), and one N(5) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Cs(2), one Cs(3), one Cs(6), one Cs(8), and one N(1) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Cs(2); one Cs(3); one Cs(4); one Cs(6); and one N(3,4) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one Cs(1), one Cs(3), one Cs(5), one Cs(9), and one N(9) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one Cs(1), one Cs(2), one Cs(4), one Cs(7), and one N(2) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one Cs(4), one Cs(5), one Cs(6), one Cs(8), and one N(5) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(4), one Cs(7), one Cs(8), and one N(2) atom. In the twentieth O site, O(20) is bonded in a single-bond geometry to one Cs(1), one Cs(4), one Cs(8), and one N(8) atom. In the twenty-first O site, O(21) is bonded in a single-bond geometry to one Cs(2), one Cs(5), one Cs(6), one Cs(8), and one N(6) atom. In the twenty-second O site, O(22) is bonded in a single-bond geometry to one Cs(2), one Cs(6), one Cs(8), one Cs(9), and one N(6) atom. In the twenty-third O site, O(23) is bonded in a single-bond geometry to one Cs(5), one Cs(7), one Cs(9), and one N(7) atom. In the twenty-fourth O site, O(24) is bonded in a single-bond geometry to one Cs(2), one Cs(3), one Cs(4), one Cs(5), and one N(2) atom. In the twenty-fifth O site, O(25) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(2), one Cs(8), one Cs(9), and one N(7) atom. In the twenty-sixth O site, O(26) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(3), one Cs(6), one Cs(7), and one N(8) atom. In the twenty-seventh O site, O(27) is bonded in a distorted single-bond geometry to one Cs(2); one Cs(5); one Cs(7); one Cs(9); and one N(3,4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsNO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.847
_cell_length_b   10.845
_cell_length_c   7.681
_cell_angle_alpha   89.993
_cell_angle_beta   89.992
_cell_angle_gamma   119.992
_symmetry_Int_Tables_number   1
_cell_volume   782.528
_cell_formula_units_Z   9
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.778  0.220  0.648  1.0
  Cs  Cs1  1  0.119  0.897  0.623  1.0
  Cs  Cs2  1  0.780  0.558  0.982  1.0
  Cs  Cs3  1  0.778  0.881  0.290  1.0
  Cs  Cs4  1  0.432  0.544  0.666  1.0
  Cs  Cs5  1  0.112  0.568  0.333  1.0
  Cs  Cs6  1  0.103  0.221  0.956  1.0
  Cs  Cs7  1  0.456  0.888  1.000  1.0
  Cs  Cs8  1  0.442  0.222  0.315  1.0
  N  N9  1  0.135  0.566  0.865  1.0
  N  N10  1  0.801  0.907  0.758  1.0
  N  N11  1  0.106  0.199  0.424  1.0
  N  N12  1  0.094  0.895  0.091  1.0
  N  N13  1  0.434  0.569  0.198  1.0
  N  N14  1  0.431  0.865  0.531  1.0
  N  N15  1  0.470  0.205  0.840  1.0
  N  N16  1  0.795  0.265  0.174  1.0
  N  N17  1  0.735  0.531  0.507  1.0
  O  O18  1  0.343  0.443  0.238  1.0
  O  O19  1  0.022  0.244  0.386  1.0
  O  O20  1  0.110  0.106  0.328  1.0
  O  O21  1  0.567  0.218  0.944  1.0
  O  O22  1  0.228  0.557  0.955  1.0
  O  O23  1  0.557  0.899  0.572  1.0
  O  O24  1  0.683  0.564  0.380  1.0
  O  O25  1  0.866  0.593  0.532  1.0
  O  O26  1  0.996  0.891  0.995  1.0
  O  O27  1  0.782  0.349  0.277  1.0
  O  O28  1  0.222  0.978  0.052  1.0
  O  O29  1  0.079  0.485  0.737  1.0
  O  O30  1  0.516  0.595  0.070  1.0
  O  O31  1  0.101  0.658  0.906  1.0
  O  O32  1  0.059  0.815  0.223  1.0
  O  O33  1  0.651  0.433  0.610  1.0
  O  O34  1  0.894  0.003  0.662  1.0
  O  O35  1  0.443  0.671  0.288  1.0
  O  O36  1  0.756  0.942  0.889  1.0
  O  O37  1  0.725  0.133  0.199  1.0
  O  O38  1  0.328  0.771  0.621  1.0
  O  O39  1  0.405  0.921  0.404  1.0
  O  O40  1  0.408  0.274  0.866  1.0
  O  O41  1  0.755  0.778  0.720  1.0
  O  O42  1  0.437  0.120  0.714  1.0
  O  O43  1  0.881  0.317  0.047  1.0
  O  O44  1  0.185  0.244  0.556  1.0
[/CIF]
.