The structure described by H2Te2O3F4 crystallizes in the orthorhombic Fdd2 space group. H(1) is bonded in a single-bond geometry to one O(2) and one F(2) atom. Te(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one F(1), and one F(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a distorted water-like geometry to one H(1) and one Te(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(2) is bonded in a 2-coordinate geometry to one H(1) and one Te(1) atom. is represented by the CIF card [CIF]
data_Te2H2O3F4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.023
_cell_length_b   10.763
_cell_length_c   6.372
_cell_angle_alpha   85.020
_cell_angle_beta   63.110
_cell_angle_gamma   31.871
_symmetry_Int_Tables_number   1
_cell_volume   301.140
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.690  0.413  0.091  1.0
  Te  Te1  1  0.805  0.091  0.413  1.0
  Te  Te2  1  0.837  0.560  0.445  1.0
  Te  Te3  1  0.159  0.445  0.560  1.0
  H  H4  1  0.440  0.761  0.802  1.0
  H  H5  1  0.996  0.802  0.761  1.0
  H  H6  1  0.489  0.810  0.254  1.0
  H  H7  1  0.448  0.254  0.810  1.0
  O  O8  1  0.796  0.704  0.704  1.0
  O  O9  1  0.546  0.454  0.454  1.0
  O  O10  1  0.638  0.598  0.730  1.0
  O  O11  1  0.034  0.730  0.598  1.0
  O  O12  1  0.652  0.612  0.216  1.0
  O  O13  1  0.520  0.216  0.612  1.0
  F  F14  1  0.579  0.347  0.825  1.0
  F  F15  1  0.249  0.825  0.347  1.0
  F  F16  1  0.903  0.671  0.001  1.0
  F  F17  1  0.425  0.001  0.671  1.0
  F  F18  1  0.196  0.163  0.366  1.0
  F  F19  1  0.275  0.366  0.163  1.0
  F  F20  1  0.087  0.054  0.975  1.0
  F  F21  1  0.884  0.975  0.054  1.0
[/CIF]
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The structure described by H2Te2O3F4 crystallizes in the orthorhombic Fdd2 space group. H(1) is bonded in a single-bond geometry to one O(2) and one F(2) atom. Te(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one F(1), and one F(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Te(1) atoms. In the second O site, O(2) is bonded in a distorted water-like geometry to one H(1) and one Te(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(2) is bonded in a 2-coordinate geometry to one H(1) and one Te(1) atom. is represented by the CIF card [CIF]
data_Te2H2O3F4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.023
_cell_length_b   10.763
_cell_length_c   6.372
_cell_angle_alpha   85.020
_cell_angle_beta   63.110
_cell_angle_gamma   31.871
_symmetry_Int_Tables_number   1
_cell_volume   301.140
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.690  0.413  0.091  1.0
  Te  Te1  1  0.805  0.091  0.413  1.0
  Te  Te2  1  0.837  0.560  0.445  1.0
  Te  Te3  1  0.159  0.445  0.560  1.0
  H  H4  1  0.440  0.761  0.802  1.0
  H  H5  1  0.996  0.802  0.761  1.0
  H  H6  1  0.489  0.810  0.254  1.0
  H  H7  1  0.448  0.254  0.810  1.0
  O  O8  1  0.796  0.704  0.704  1.0
  O  O9  1  0.546  0.454  0.454  1.0
  O  O10  1  0.638  0.598  0.730  1.0
  O  O11  1  0.034  0.730  0.598  1.0
  O  O12  1  0.652  0.612  0.216  1.0
  O  O13  1  0.520  0.216  0.612  1.0
  F  F14  1  0.579  0.347  0.825  1.0
  F  F15  1  0.249  0.825  0.347  1.0
  F  F16  1  0.903  0.671  0.001  1.0
  F  F17  1  0.425  0.001  0.671  1.0
  F  F18  1  0.196  0.163  0.366  1.0
  F  F19  1  0.275  0.366  0.163  1.0
  F  F20  1  0.087  0.054  0.975  1.0
  F  F21  1  0.884  0.975  0.054  1.0
[/CIF]
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