The material structure described by C4NGeCl3 is Indium-derived structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four trichlorogermane molecules and four C4N clusters. In each C4N cluster, there are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(3) and one N(1) atom. In the second C site, C(2) is bonded in a 1-coordinate geometry to one C(3) and one N(1) atom. In the third C site, C(3) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one C(4) atom. In the fourth C site, C(4) is bonded in a 2-coordinate geometry to one C(3) and one N(1) atom. N(1) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one C(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_GeC4NCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.123
_cell_length_b   8.500
_cell_length_c   12.085
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   834.483
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.276  0.724  0.275  1.0
  Ge  Ge1  1  0.724  0.224  0.725  1.0
  Ge  Ge2  1  0.776  0.224  0.225  1.0
  Ge  Ge3  1  0.224  0.724  0.775  1.0
  C  C4  1  0.399  0.196  0.477  1.0
  C  C5  1  0.601  0.696  0.523  1.0
  C  C6  1  0.899  0.696  0.023  1.0
  C  C7  1  0.101  0.196  0.977  1.0
  C  C8  1  0.179  0.187  0.444  1.0
  C  C9  1  0.821  0.687  0.556  1.0
  C  C10  1  0.679  0.687  0.056  1.0
  C  C11  1  0.321  0.187  0.944  1.0
  C  C12  1  0.270  0.098  0.532  1.0
  C  C13  1  0.730  0.598  0.468  1.0
  C  C14  1  0.770  0.598  0.968  1.0
  C  C15  1  0.230  0.098  0.032  1.0
  C  C16  1  0.247  0.259  0.581  1.0
  C  C17  1  0.753  0.759  0.419  1.0
  C  C18  1  0.747  0.759  0.919  1.0
  C  C19  1  0.253  0.259  0.081  1.0
  N  N20  1  0.221  0.329  0.971  1.0
  N  N21  1  0.779  0.829  0.029  1.0
  N  N22  1  0.721  0.829  0.529  1.0
  N  N23  1  0.279  0.329  0.471  1.0
  Cl  Cl24  1  0.438  0.519  0.265  1.0
  Cl  Cl25  1  0.562  0.019  0.735  1.0
  Cl  Cl26  1  0.938  0.019  0.235  1.0
  Cl  Cl27  1  0.062  0.519  0.765  1.0
  Cl  Cl28  1  0.430  0.937  0.264  1.0
  Cl  Cl29  1  0.570  0.437  0.736  1.0
  Cl  Cl30  1  0.930  0.437  0.236  1.0
  Cl  Cl31  1  0.070  0.937  0.764  1.0
  Cl  Cl32  1  0.162  0.728  0.440  1.0
  Cl  Cl33  1  0.838  0.228  0.560  1.0
  Cl  Cl34  1  0.662  0.228  0.060  1.0
  Cl  Cl35  1  0.338  0.728  0.940  1.0
[/CIF]
.
The material structure described by C4NGeCl3 is Indium-derived structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of four trichlorogermane molecules and four C4N clusters. In each C4N cluster, there are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(3) and one N(1) atom. In the second C site, C(2) is bonded in a 1-coordinate geometry to one C(3) and one N(1) atom. In the third C site, C(3) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one C(4) atom. In the fourth C site, C(4) is bonded in a 2-coordinate geometry to one C(3) and one N(1) atom. N(1) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one C(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_GeC4NCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.123
_cell_length_b   8.500
_cell_length_c   12.085
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   834.483
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.276  0.724  0.275  1.0
  Ge  Ge1  1  0.724  0.224  0.725  1.0
  Ge  Ge2  1  0.776  0.224  0.225  1.0
  Ge  Ge3  1  0.224  0.724  0.775  1.0
  C  C4  1  0.399  0.196  0.477  1.0
  C  C5  1  0.601  0.696  0.523  1.0
  C  C6  1  0.899  0.696  0.023  1.0
  C  C7  1  0.101  0.196  0.977  1.0
  C  C8  1  0.179  0.187  0.444  1.0
  C  C9  1  0.821  0.687  0.556  1.0
  C  C10  1  0.679  0.687  0.056  1.0
  C  C11  1  0.321  0.187  0.944  1.0
  C  C12  1  0.270  0.098  0.532  1.0
  C  C13  1  0.730  0.598  0.468  1.0
  C  C14  1  0.770  0.598  0.968  1.0
  C  C15  1  0.230  0.098  0.032  1.0
  C  C16  1  0.247  0.259  0.581  1.0
  C  C17  1  0.753  0.759  0.419  1.0
  C  C18  1  0.747  0.759  0.919  1.0
  C  C19  1  0.253  0.259  0.081  1.0
  N  N20  1  0.221  0.329  0.971  1.0
  N  N21  1  0.779  0.829  0.029  1.0
  N  N22  1  0.721  0.829  0.529  1.0
  N  N23  1  0.279  0.329  0.471  1.0
  Cl  Cl24  1  0.438  0.519  0.265  1.0
  Cl  Cl25  1  0.562  0.019  0.735  1.0
  Cl  Cl26  1  0.938  0.019  0.235  1.0
  Cl  Cl27  1  0.062  0.519  0.765  1.0
  Cl  Cl28  1  0.430  0.937  0.264  1.0
  Cl  Cl29  1  0.570  0.437  0.736  1.0
  Cl  Cl30  1  0.930  0.437  0.236  1.0
  Cl  Cl31  1  0.070  0.937  0.764  1.0
  Cl  Cl32  1  0.162  0.728  0.440  1.0
  Cl  Cl33  1  0.838  0.228  0.560  1.0
  Cl  Cl34  1  0.662  0.228  0.060  1.0
  Cl  Cl35  1  0.338  0.728  0.940  1.0
[/CIF]
.