The structure described by V2P2H2O11 crystallizes in the orthorhombic Pmmn space group. V(1) is bonded in a 6-coordinate geometry to one O(4), one O(5), two equivalent O(2), and two equivalent O(3) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. H(1) is bonded in a linear geometry to one O(1) and one O(5) atom. There are five inequivalent O sites. In the first O site, O(5) is bonded in a distorted water-like geometry to two equivalent V(1) and two equivalent H(1) atoms. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one P(1) and one H(1) atom. In the third O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the fourth O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent V(1) and one P(1) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2P2H2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.415
_cell_length_b   9.445
_cell_length_c   5.861
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   410.525
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.290  0.500  0.015  1.0
  V  V1  1  0.710  0.500  0.015  1.0
  V  V2  1  0.210  0.000  0.985  1.0
  V  V3  1  0.790  0.000  0.985  1.0
  P  P4  1  0.500  0.769  0.763  1.0
  P  P5  1  0.500  0.231  0.763  1.0
  P  P6  1  0.000  0.731  0.237  1.0
  P  P7  1  0.000  0.269  0.237  1.0
  H  H8  1  0.500  0.410  0.393  1.0
  H  H9  1  0.500  0.590  0.393  1.0
  H  H10  1  0.000  0.090  0.607  1.0
  H  H11  1  0.000  0.910  0.607  1.0
  O  O12  1  0.500  0.730  0.519  1.0
  O  O13  1  0.500  0.270  0.519  1.0
  O  O14  1  0.000  0.770  0.481  1.0
  O  O15  1  0.000  0.230  0.481  1.0
  O  O16  1  0.329  0.856  0.834  1.0
  O  O17  1  0.671  0.856  0.834  1.0
  O  O18  1  0.329  0.144  0.834  1.0
  O  O19  1  0.671  0.144  0.834  1.0
  O  O20  1  0.171  0.644  0.166  1.0
  O  O21  1  0.829  0.644  0.166  1.0
  O  O22  1  0.171  0.356  0.166  1.0
  O  O23  1  0.829  0.356  0.166  1.0
  O  O24  1  0.500  0.636  0.932  1.0
  O  O25  1  0.500  0.364  0.932  1.0
  O  O26  1  0.000  0.864  0.068  1.0
  O  O27  1  0.000  0.136  0.068  1.0
  O  O28  1  0.202  0.500  0.765  1.0
  O  O29  1  0.798  0.500  0.765  1.0
  O  O30  1  0.298  0.000  0.235  1.0
  O  O31  1  0.702  0.000  0.235  1.0
  O  O32  1  0.500  0.500  0.293  1.0
  O  O33  1  0.000  0.000  0.707  1.0
[/CIF]
.
The structure described by V2P2H2O11 crystallizes in the orthorhombic Pmmn space group. V(1) is bonded in a 6-coordinate geometry to one O(4), one O(5), two equivalent O(2), and two equivalent O(3) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. H(1) is bonded in a linear geometry to one O(1) and one O(5) atom. There are five inequivalent O sites. In the first O site, O(5) is bonded in a distorted water-like geometry to two equivalent V(1) and two equivalent H(1) atoms. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one P(1) and one H(1) atom. In the third O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the fourth O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent V(1) and one P(1) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2P2H2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.415
_cell_length_b   9.445
_cell_length_c   5.861
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   410.525
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.290  0.500  0.015  1.0
  V  V1  1  0.710  0.500  0.015  1.0
  V  V2  1  0.210  0.000  0.985  1.0
  V  V3  1  0.790  0.000  0.985  1.0
  P  P4  1  0.500  0.769  0.763  1.0
  P  P5  1  0.500  0.231  0.763  1.0
  P  P6  1  0.000  0.731  0.237  1.0
  P  P7  1  0.000  0.269  0.237  1.0
  H  H8  1  0.500  0.410  0.393  1.0
  H  H9  1  0.500  0.590  0.393  1.0
  H  H10  1  0.000  0.090  0.607  1.0
  H  H11  1  0.000  0.910  0.607  1.0
  O  O12  1  0.500  0.730  0.519  1.0
  O  O13  1  0.500  0.270  0.519  1.0
  O  O14  1  0.000  0.770  0.481  1.0
  O  O15  1  0.000  0.230  0.481  1.0
  O  O16  1  0.329  0.856  0.834  1.0
  O  O17  1  0.671  0.856  0.834  1.0
  O  O18  1  0.329  0.144  0.834  1.0
  O  O19  1  0.671  0.144  0.834  1.0
  O  O20  1  0.171  0.644  0.166  1.0
  O  O21  1  0.829  0.644  0.166  1.0
  O  O22  1  0.171  0.356  0.166  1.0
  O  O23  1  0.829  0.356  0.166  1.0
  O  O24  1  0.500  0.636  0.932  1.0
  O  O25  1  0.500  0.364  0.932  1.0
  O  O26  1  0.000  0.864  0.068  1.0
  O  O27  1  0.000  0.136  0.068  1.0
  O  O28  1  0.202  0.500  0.765  1.0
  O  O29  1  0.798  0.500  0.765  1.0
  O  O30  1  0.298  0.000  0.235  1.0
  O  O31  1  0.702  0.000  0.235  1.0
  O  O32  1  0.500  0.500  0.293  1.0
  O  O33  1  0.000  0.000  0.707  1.0
[/CIF]
.