The material described by MoPN(OCl3)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two MoPN(OCl3)2 clusters. Mo(1) is bonded to one N(1), one O(1), one Cl(1), one Cl(2), and two equivalent Cl(4) atoms to form distorted MoNCl4O octahedra that share  a cornercorner with one P(1)Cl3O tetrahedra and  an edgeedge with one Mo(1)NCl4O octahedra. P(1) is bonded to one O(1), one Cl(3), one Cl(5), and one Cl(6) atom to form PCl3O tetrahedra that share  a cornercorner with one Mo(1)NCl4O octahedra. The corner-sharing octahedral tilt angles are 31°. N(1) is bonded in a linear geometry to one Mo(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to two equivalent Mo(1) atoms. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one P(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_MoPN(Cl3O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.365
_cell_length_b   8.409
_cell_length_c   12.740
_cell_angle_alpha   70.384
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1146.871
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.384  0.922  0.122  1.0
  Mo  Mo1  1  0.884  0.078  0.378  1.0
  Mo  Mo2  1  0.616  0.078  0.878  1.0
  Mo  Mo3  1  0.116  0.922  0.622  1.0
  P  P4  1  0.241  0.333  0.025  1.0
  P  P5  1  0.259  0.333  0.525  1.0
  P  P6  1  0.759  0.667  0.975  1.0
  P  P7  1  0.741  0.667  0.475  1.0
  N  N8  1  0.070  0.707  0.665  1.0
  N  N9  1  0.430  0.707  0.165  1.0
  N  N10  1  0.570  0.293  0.835  1.0
  N  N11  1  0.930  0.293  0.335  1.0
  Cl  Cl12  1  0.902  0.044  0.204  1.0
  Cl  Cl13  1  0.682  0.140  0.381  1.0
  Cl  Cl14  1  0.693  0.444  0.067  1.0
  Cl  Cl15  1  0.807  0.444  0.567  1.0
  Cl  Cl16  1  0.905  0.036  0.584  1.0
  Cl  Cl17  1  0.595  0.036  0.084  1.0
  Cl  Cl18  1  0.098  0.956  0.796  1.0
  Cl  Cl19  1  0.111  0.289  0.935  1.0
  Cl  Cl20  1  0.307  0.556  0.933  1.0
  Cl  Cl21  1  0.389  0.289  0.435  1.0
  Cl  Cl22  1  0.889  0.711  0.065  1.0
  Cl  Cl23  1  0.818  0.140  0.881  1.0
  Cl  Cl24  1  0.598  0.044  0.704  1.0
  Cl  Cl25  1  0.095  0.964  0.416  1.0
  Cl  Cl26  1  0.193  0.556  0.433  1.0
  Cl  Cl27  1  0.669  0.632  0.343  1.0
  Cl  Cl28  1  0.331  0.368  0.657  1.0
  Cl  Cl29  1  0.831  0.632  0.843  1.0
  Cl  Cl30  1  0.169  0.368  0.157  1.0
  Cl  Cl31  1  0.611  0.711  0.565  1.0
  Cl  Cl32  1  0.402  0.956  0.296  1.0
  Cl  Cl33  1  0.318  0.860  0.619  1.0
  Cl  Cl34  1  0.405  0.964  0.916  1.0
  Cl  Cl35  1  0.182  0.860  0.119  1.0
  O  O36  1  0.165  0.200  0.557  1.0
  O  O37  1  0.335  0.200  0.057  1.0
  O  O38  1  0.665  0.800  0.943  1.0
  O  O39  1  0.457  0.563  0.187  1.0
  O  O40  1  0.957  0.437  0.313  1.0
  O  O41  1  0.043  0.563  0.687  1.0
  O  O42  1  0.543  0.437  0.813  1.0
  O  O43  1  0.835  0.800  0.443  1.0
[/CIF]
.
The material described by MoPN(OCl3)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two MoPN(OCl3)2 clusters. Mo(1) is bonded to one N(1), one O(1), one Cl(1), one Cl(2), and two equivalent Cl(4) atoms to form distorted MoNCl4O octahedra that share  a cornercorner with one P(1)Cl3O tetrahedra and  an edgeedge with one Mo(1)NCl4O octahedra. P(1) is bonded to one O(1), one Cl(3), one Cl(5), and one Cl(6) atom to form PCl3O tetrahedra that share  a cornercorner with one Mo(1)NCl4O octahedra. The corner-sharing octahedral tilt angles are 31°. N(1) is bonded in a linear geometry to one Mo(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to two equivalent Mo(1) atoms. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one P(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_MoPN(Cl3O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.365
_cell_length_b   8.409
_cell_length_c   12.740
_cell_angle_alpha   70.384
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1146.871
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.384  0.922  0.122  1.0
  Mo  Mo1  1  0.884  0.078  0.378  1.0
  Mo  Mo2  1  0.616  0.078  0.878  1.0
  Mo  Mo3  1  0.116  0.922  0.622  1.0
  P  P4  1  0.241  0.333  0.025  1.0
  P  P5  1  0.259  0.333  0.525  1.0
  P  P6  1  0.759  0.667  0.975  1.0
  P  P7  1  0.741  0.667  0.475  1.0
  N  N8  1  0.070  0.707  0.665  1.0
  N  N9  1  0.430  0.707  0.165  1.0
  N  N10  1  0.570  0.293  0.835  1.0
  N  N11  1  0.930  0.293  0.335  1.0
  Cl  Cl12  1  0.902  0.044  0.204  1.0
  Cl  Cl13  1  0.682  0.140  0.381  1.0
  Cl  Cl14  1  0.693  0.444  0.067  1.0
  Cl  Cl15  1  0.807  0.444  0.567  1.0
  Cl  Cl16  1  0.905  0.036  0.584  1.0
  Cl  Cl17  1  0.595  0.036  0.084  1.0
  Cl  Cl18  1  0.098  0.956  0.796  1.0
  Cl  Cl19  1  0.111  0.289  0.935  1.0
  Cl  Cl20  1  0.307  0.556  0.933  1.0
  Cl  Cl21  1  0.389  0.289  0.435  1.0
  Cl  Cl22  1  0.889  0.711  0.065  1.0
  Cl  Cl23  1  0.818  0.140  0.881  1.0
  Cl  Cl24  1  0.598  0.044  0.704  1.0
  Cl  Cl25  1  0.095  0.964  0.416  1.0
  Cl  Cl26  1  0.193  0.556  0.433  1.0
  Cl  Cl27  1  0.669  0.632  0.343  1.0
  Cl  Cl28  1  0.331  0.368  0.657  1.0
  Cl  Cl29  1  0.831  0.632  0.843  1.0
  Cl  Cl30  1  0.169  0.368  0.157  1.0
  Cl  Cl31  1  0.611  0.711  0.565  1.0
  Cl  Cl32  1  0.402  0.956  0.296  1.0
  Cl  Cl33  1  0.318  0.860  0.619  1.0
  Cl  Cl34  1  0.405  0.964  0.916  1.0
  Cl  Cl35  1  0.182  0.860  0.119  1.0
  O  O36  1  0.165  0.200  0.557  1.0
  O  O37  1  0.335  0.200  0.057  1.0
  O  O38  1  0.665  0.800  0.943  1.0
  O  O39  1  0.457  0.563  0.187  1.0
  O  O40  1  0.957  0.437  0.313  1.0
  O  O41  1  0.043  0.563  0.687  1.0
  O  O42  1  0.543  0.437  0.813  1.0
  O  O43  1  0.835  0.800  0.443  1.0
[/CIF]
.