The crystal structure described by LiVSiO4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent O(1) atoms to form LiO4 tetrahedra that share corners with four equivalent V(1)O4 tetrahedra and corners with four equivalent Si(1)O4 tetrahedra. V(1) is bonded to four equivalent O(1) atoms to form VO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Si(1)O4 tetrahedra. Si(1) is bonded to four equivalent O(1) atoms to form SiO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent V(1)O4 tetrahedra. O(1) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one Si(1) atom. is represented by the CIF card [CIF]
data_LiVSiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.855
_cell_length_b   4.855
_cell_length_c   5.167
_cell_angle_alpha   118.027
_cell_angle_beta   118.023
_cell_angle_gamma   89.990
_symmetry_Int_Tables_number   1
_cell_volume   91.026
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  1.000  1.0
  O  O1  1  0.311  0.419  0.254  1.0
  O  O2  1  0.166  0.689  0.746  1.0
  O  O3  1  0.943  0.834  0.254  1.0
  O  O4  1  0.581  0.057  0.746  1.0
  Si  Si5  1  0.250  0.750  0.500  1.0
  V  V6  1  1.000  0.000  1.000  1.0
[/CIF]
.
The crystal structure described by LiVSiO4 crystallizes in the tetragonal I-4 space group. Li(1) is bonded to four equivalent O(1) atoms to form LiO4 tetrahedra that share corners with four equivalent V(1)O4 tetrahedra and corners with four equivalent Si(1)O4 tetrahedra. V(1) is bonded to four equivalent O(1) atoms to form VO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent Si(1)O4 tetrahedra. Si(1) is bonded to four equivalent O(1) atoms to form SiO4 tetrahedra that share corners with four equivalent Li(1)O4 tetrahedra and corners with four equivalent V(1)O4 tetrahedra. O(1) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one Si(1) atom. is represented by the CIF card [CIF]
data_LiVSiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.855
_cell_length_b   4.855
_cell_length_c   5.167
_cell_angle_alpha   118.027
_cell_angle_beta   118.023
_cell_angle_gamma   89.990
_symmetry_Int_Tables_number   1
_cell_volume   91.026
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  1.000  1.0
  O  O1  1  0.311  0.419  0.254  1.0
  O  O2  1  0.166  0.689  0.746  1.0
  O  O3  1  0.943  0.834  0.254  1.0
  O  O4  1  0.581  0.057  0.746  1.0
  Si  Si5  1  0.250  0.750  0.500  1.0
  V  V6  1  1.000  0.000  1.000  1.0
[/CIF]
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