The compound described by Ga2S3 crystallizes in the orthorhombic Imm2 space group. Ga(1) is bonded to one S(2) and three equivalent S(1) atoms to form corner-sharing GaS4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to three equivalent Ga(1) atoms. In the second S site, S(2) is bonded in a water-like geometry to two equivalent Ga(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ga2S3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.446
_cell_length_b   6.446
_cell_length_c   6.446
_cell_angle_alpha   146.896
_cell_angle_beta   131.000
_cell_angle_gamma   60.413
_symmetry_Int_Tables_number   1
_cell_volume   109.376
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.834  0.841  0.993  1.0
  Ga  Ga1  1  0.152  0.159  0.993  1.0
  S  S2  1  0.093  0.334  0.758  1.0
  S  S3  1  0.424  0.666  0.758  1.0
  S  S4  1  0.748  0.000  0.748  1.0
[/CIF]
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The compound described by Ga2S3 crystallizes in the orthorhombic Imm2 space group. Ga(1) is bonded to one S(2) and three equivalent S(1) atoms to form corner-sharing GaS4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to three equivalent Ga(1) atoms. In the second S site, S(2) is bonded in a water-like geometry to two equivalent Ga(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ga2S3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.446
_cell_length_b   6.446
_cell_length_c   6.446
_cell_angle_alpha   146.896
_cell_angle_beta   131.000
_cell_angle_gamma   60.413
_symmetry_Int_Tables_number   1
_cell_volume   109.376
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.834  0.841  0.993  1.0
  Ga  Ga1  1  0.152  0.159  0.993  1.0
  S  S2  1  0.093  0.334  0.758  1.0
  S  S3  1  0.424  0.666  0.758  1.0
  S  S4  1  0.748  0.000  0.748  1.0
[/CIF]
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