The compound described by LiV(CO3)2 is Calcite-derived structured and crystallizes in the trigonal R32 space group. Li(1) is bonded to six equivalent O(1) atoms to form distorted LiO6 pentagonal pyramids that share corners with six equivalent V(1)O6 pentagonal pyramids. V(1) is bonded to six equivalent O(1) atoms to form distorted VO6 pentagonal pyramids that share corners with six equivalent Li(1)O6 pentagonal pyramids. C(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. O(1) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one C(1) atom. is represented by the CIF card [CIF]
data_LiV(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.059
_cell_length_b   6.059
_cell_length_c   6.059
_cell_angle_alpha   45.315
_cell_angle_beta   45.315
_cell_angle_gamma   45.315
_symmetry_Int_Tables_number   1
_cell_volume   102.389
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.500  1.0
  V  V1  1  0.000  0.000  0.000  1.0
  C  C2  1  0.255  0.255  0.255  1.0
  C  C3  1  0.745  0.745  0.745  1.0
  O  O4  1  0.455  0.008  0.774  1.0
  O  O5  1  0.992  0.545  0.226  1.0
  O  O6  1  0.545  0.226  0.992  1.0
  O  O7  1  0.774  0.455  0.008  1.0
  O  O8  1  0.226  0.992  0.545  1.0
  O  O9  1  0.008  0.774  0.455  1.0
[/CIF]
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The compound described by LiV(CO3)2 is Calcite-derived structured and crystallizes in the trigonal R32 space group. Li(1) is bonded to six equivalent O(1) atoms to form distorted LiO6 pentagonal pyramids that share corners with six equivalent V(1)O6 pentagonal pyramids. V(1) is bonded to six equivalent O(1) atoms to form distorted VO6 pentagonal pyramids that share corners with six equivalent Li(1)O6 pentagonal pyramids. C(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. O(1) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one C(1) atom. is represented by the CIF card [CIF]
data_LiV(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.059
_cell_length_b   6.059
_cell_length_c   6.059
_cell_angle_alpha   45.315
_cell_angle_beta   45.315
_cell_angle_gamma   45.315
_symmetry_Int_Tables_number   1
_cell_volume   102.389
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.500  1.0
  V  V1  1  0.000  0.000  0.000  1.0
  C  C2  1  0.255  0.255  0.255  1.0
  C  C3  1  0.745  0.745  0.745  1.0
  O  O4  1  0.455  0.008  0.774  1.0
  O  O5  1  0.992  0.545  0.226  1.0
  O  O6  1  0.545  0.226  0.992  1.0
  O  O7  1  0.774  0.455  0.008  1.0
  O  O8  1  0.226  0.992  0.545  1.0
  O  O9  1  0.008  0.774  0.455  1.0
[/CIF]
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