The material described by KV2AgO6 is Esseneite structured and crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. V(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form VO4 tetrahedra that share corners with three equivalent Ag(1)O6 octahedra and corners with two equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 32-57°. Ag(1) is bonded to two equivalent O(3) and four equivalent O(2) atoms to form AgO6 octahedra that share corners with six equivalent V(1)O4 tetrahedra and edges with two equivalent Ag(1)O6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent K(1) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one V(1), and two equivalent Ag(1) atoms. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(1), one V(1), and one Ag(1) atom. is represented by the CIF file [CIF]
data_KV2AgO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.450
_cell_length_b   7.450
_cell_length_c   5.905
_cell_angle_alpha   79.770
_cell_angle_beta   79.770
_cell_angle_gamma   85.514
_symmetry_Int_Tables_number   1
_cell_volume   317.011
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.804  0.196  0.750  1.0
  K  K1  1  0.196  0.804  0.250  1.0
  V  V2  1  0.298  0.124  0.731  1.0
  V  V3  1  0.702  0.876  0.269  1.0
  V  V4  1  0.876  0.702  0.769  1.0
  V  V5  1  0.124  0.298  0.231  1.0
  Ag  Ag6  1  0.407  0.593  0.750  1.0
  Ag  Ag7  1  0.593  0.407  0.250  1.0
  O  O8  1  0.830  0.864  0.510  1.0
  O  O9  1  0.170  0.136  0.490  1.0
  O  O10  1  0.136  0.170  0.990  1.0
  O  O11  1  0.864  0.830  0.010  1.0
  O  O12  1  0.459  0.281  0.659  1.0
  O  O13  1  0.541  0.719  0.341  1.0
  O  O14  1  0.719  0.541  0.841  1.0
  O  O15  1  0.281  0.459  0.159  1.0
  O  O16  1  0.390  0.913  0.799  1.0
  O  O17  1  0.610  0.087  0.201  1.0
  O  O18  1  0.087  0.610  0.701  1.0
  O  O19  1  0.913  0.390  0.299  1.0
[/CIF]
.
The material described by KV2AgO6 is Esseneite structured and crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent O(3), and four equivalent O(1) atoms. V(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form VO4 tetrahedra that share corners with three equivalent Ag(1)O6 octahedra and corners with two equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 32-57°. Ag(1) is bonded to two equivalent O(3) and four equivalent O(2) atoms to form AgO6 octahedra that share corners with six equivalent V(1)O4 tetrahedra and edges with two equivalent Ag(1)O6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent K(1) and two equivalent V(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one V(1), and two equivalent Ag(1) atoms. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(1), one V(1), and one Ag(1) atom. is represented by the CIF file [CIF]
data_KV2AgO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.450
_cell_length_b   7.450
_cell_length_c   5.905
_cell_angle_alpha   79.770
_cell_angle_beta   79.770
_cell_angle_gamma   85.514
_symmetry_Int_Tables_number   1
_cell_volume   317.011
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.804  0.196  0.750  1.0
  K  K1  1  0.196  0.804  0.250  1.0
  V  V2  1  0.298  0.124  0.731  1.0
  V  V3  1  0.702  0.876  0.269  1.0
  V  V4  1  0.876  0.702  0.769  1.0
  V  V5  1  0.124  0.298  0.231  1.0
  Ag  Ag6  1  0.407  0.593  0.750  1.0
  Ag  Ag7  1  0.593  0.407  0.250  1.0
  O  O8  1  0.830  0.864  0.510  1.0
  O  O9  1  0.170  0.136  0.490  1.0
  O  O10  1  0.136  0.170  0.990  1.0
  O  O11  1  0.864  0.830  0.010  1.0
  O  O12  1  0.459  0.281  0.659  1.0
  O  O13  1  0.541  0.719  0.341  1.0
  O  O14  1  0.719  0.541  0.841  1.0
  O  O15  1  0.281  0.459  0.159  1.0
  O  O16  1  0.390  0.913  0.799  1.0
  O  O17  1  0.610  0.087  0.201  1.0
  O  O18  1  0.087  0.610  0.701  1.0
  O  O19  1  0.913  0.390  0.299  1.0
[/CIF]
.