The crystal structure described by SAs is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four SAs clusters. There are four inequivalent As sites. In the first As site, As(1) is bonded in a distorted trigonal non-coplanar geometry to one S(2), one S(3), and one S(4) atom. In the second As site, As(2) is bonded in a distorted water-like geometry to one S(1) and one S(3) atom. In the third As site, As(3) is bonded in a distorted single-bond geometry to one S(2) atom. In the fourth As site, As(4) is bonded in a distorted water-like geometry to one S(1) and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one As(2) and one As(4) atom. In the second S site, S(2) is bonded in a water-like geometry to one As(1) and one As(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one As(1) and one As(2) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one As(1) and one As(4) atom. is represented by the CIF file [CIF]
data_AsS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.696
_cell_length_b   9.828
_cell_length_c   10.193
_cell_angle_alpha   90.000
_cell_angle_beta   97.685
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   863.314
_cell_formula_units_Z   16
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.544  0.866  0.316  1.0
  As  As1  1  0.340  0.362  0.368  1.0
  As  As2  1  0.840  0.138  0.368  1.0
  As  As3  1  0.834  0.655  0.851  1.0
  As  As4  1  0.322  0.544  0.085  1.0
  As  As5  1  0.822  0.956  0.085  1.0
  As  As6  1  0.160  0.862  0.632  1.0
  As  As7  1  0.456  0.134  0.684  1.0
  As  As8  1  0.666  0.155  0.149  1.0
  As  As9  1  0.660  0.638  0.632  1.0
  As  As10  1  0.044  0.634  0.316  1.0
  As  As11  1  0.178  0.044  0.915  1.0
  As  As12  1  0.166  0.345  0.149  1.0
  As  As13  1  0.956  0.366  0.684  1.0
  As  As14  1  0.334  0.845  0.851  1.0
  As  As15  1  0.678  0.456  0.915  1.0
  S  S16  1  0.506  0.478  0.254  1.0
  S  S17  1  0.955  0.447  0.197  1.0
  S  S18  1  0.785  0.475  0.533  1.0
  S  S19  1  0.715  0.975  0.467  1.0
  S  S20  1  0.545  0.947  0.803  1.0
  S  S21  1  0.455  0.053  0.197  1.0
  S  S22  1  0.808  0.284  0.833  1.0
  S  S23  1  0.494  0.522  0.746  1.0
  S  S24  1  0.006  0.022  0.254  1.0
  S  S25  1  0.308  0.216  0.833  1.0
  S  S26  1  0.215  0.525  0.467  1.0
  S  S27  1  0.285  0.025  0.533  1.0
  S  S28  1  0.994  0.978  0.746  1.0
  S  S29  1  0.045  0.553  0.803  1.0
  S  S30  1  0.192  0.716  0.167  1.0
  S  S31  1  0.692  0.784  0.167  1.0
[/CIF]
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The crystal structure described by SAs is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four SAs clusters. There are four inequivalent As sites. In the first As site, As(1) is bonded in a distorted trigonal non-coplanar geometry to one S(2), one S(3), and one S(4) atom. In the second As site, As(2) is bonded in a distorted water-like geometry to one S(1) and one S(3) atom. In the third As site, As(3) is bonded in a distorted single-bond geometry to one S(2) atom. In the fourth As site, As(4) is bonded in a distorted water-like geometry to one S(1) and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one As(2) and one As(4) atom. In the second S site, S(2) is bonded in a water-like geometry to one As(1) and one As(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one As(1) and one As(2) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one As(1) and one As(4) atom. is represented by the CIF file [CIF]
data_AsS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.696
_cell_length_b   9.828
_cell_length_c   10.193
_cell_angle_alpha   90.000
_cell_angle_beta   97.685
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   863.314
_cell_formula_units_Z   16
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.544  0.866  0.316  1.0
  As  As1  1  0.340  0.362  0.368  1.0
  As  As2  1  0.840  0.138  0.368  1.0
  As  As3  1  0.834  0.655  0.851  1.0
  As  As4  1  0.322  0.544  0.085  1.0
  As  As5  1  0.822  0.956  0.085  1.0
  As  As6  1  0.160  0.862  0.632  1.0
  As  As7  1  0.456  0.134  0.684  1.0
  As  As8  1  0.666  0.155  0.149  1.0
  As  As9  1  0.660  0.638  0.632  1.0
  As  As10  1  0.044  0.634  0.316  1.0
  As  As11  1  0.178  0.044  0.915  1.0
  As  As12  1  0.166  0.345  0.149  1.0
  As  As13  1  0.956  0.366  0.684  1.0
  As  As14  1  0.334  0.845  0.851  1.0
  As  As15  1  0.678  0.456  0.915  1.0
  S  S16  1  0.506  0.478  0.254  1.0
  S  S17  1  0.955  0.447  0.197  1.0
  S  S18  1  0.785  0.475  0.533  1.0
  S  S19  1  0.715  0.975  0.467  1.0
  S  S20  1  0.545  0.947  0.803  1.0
  S  S21  1  0.455  0.053  0.197  1.0
  S  S22  1  0.808  0.284  0.833  1.0
  S  S23  1  0.494  0.522  0.746  1.0
  S  S24  1  0.006  0.022  0.254  1.0
  S  S25  1  0.308  0.216  0.833  1.0
  S  S26  1  0.215  0.525  0.467  1.0
  S  S27  1  0.285  0.025  0.533  1.0
  S  S28  1  0.994  0.978  0.746  1.0
  S  S29  1  0.045  0.553  0.803  1.0
  S  S30  1  0.192  0.716  0.167  1.0
  S  S31  1  0.692  0.784  0.167  1.0
[/CIF]
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