The structure described by Li4Sb(TeO4)3 is Ilmenite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(4), one O(7), one O(8), and one O(9) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(2), one O(3), one O(5), and one O(6) atom. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(5), one O(6), one O(8), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a 3-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(4), and one O(7) atom. Sb(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form SbO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-42°. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent Te(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-43°. In the second Te site, Te(2) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent Te(3)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-41°. In the third Te site, Te(3) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles range from 39-43°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(4), one Te(1), and one Te(3) atom to form distorted OLi2Te2 tetrahedra that share  a cornercorner with one O(11)Li2SbTe tetrahedra,  a cornercorner with one O(3)Li2SbTe tetrahedra,  a cornercorner with one O(6)Li2Te2 tetrahedra,  a cornercorner with one O(9)Li2Te2 tetrahedra,  an edgeedge with one O(11)Li2SbTe tetrahedra, and  an edgeedge with one O(9)Li2Te2 tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Sb(1), and one Te(1) atom. In the third O site, O(3) is bonded to one Li(2), one Li(4), one Sb(1), and one Te(2) atom to form distorted OLi2SbTe tetrahedra that share  a cornercorner with one O(1)Li2Te2 tetrahedra, corners with two equivalent O(11)Li2SbTe tetrahedra,  a cornercorner with one O(5)Li2SbTe trigonal pyramid,  an edgeedge with one O(6)Li2Te2 tetrahedra, and  an edgeedge with one O(5)Li2SbTe trigonal pyramid. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one Li(4), one Te(1), and one Te(3) atom. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one Sb(1), and one Te(2) atom to form distorted OLi2SbTe trigonal pyramids that share  a cornercorner with one O(11)Li2SbTe tetrahedra,  a cornercorner with one O(3)Li2SbTe tetrahedra,  a cornercorner with one O(6)Li2Te2 tetrahedra,  a cornercorner with one O(9)Li2Te2 tetrahedra,  an edgeedge with one O(3)Li2SbTe tetrahedra, and  an edgeedge with one O(6)Li2Te2 tetrahedra. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Te(2), and one Te(3) atom to form distorted OLi2Te2 tetrahedra that share  a cornercorner with one O(1)Li2Te2 tetrahedra, corners with two equivalent O(9)Li2Te2 tetrahedra,  a cornercorner with one O(5)Li2SbTe trigonal pyramid,  an edgeedge with one O(3)Li2SbTe tetrahedra, and  an edgeedge with one O(5)Li2SbTe trigonal pyramid. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Li(1), one Li(4), one Te(2), and one Te(3) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(1), one Li(3), one Sb(1), and one Te(2) atom. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one Te(1), and one Te(3) atom to form distorted OLi2Te2 tetrahedra that share  a cornercorner with one O(1)Li2Te2 tetrahedra, corners with two equivalent O(6)Li2Te2 tetrahedra,  a cornercorner with one O(5)Li2SbTe trigonal pyramid,  an edgeedge with one O(11)Li2SbTe tetrahedra, and  an edgeedge with one O(1)Li2Te2 tetrahedra. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Sb(1), and one Te(2) atom. In the eleventh O site, O(11) is bonded to one Li(1), one Li(4), one Sb(1), and one Te(1) atom to form distorted OLi2SbTe tetrahedra that share  a cornercorner with one O(1)Li2Te2 tetrahedra, corners with two equivalent O(3)Li2SbTe tetrahedra,  a cornercorner with one O(5)Li2SbTe trigonal pyramid,  an edgeedge with one O(1)Li2Te2 tetrahedra, and  an edgeedge with one O(9)Li2Te2 tetrahedra. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Li(2), one Li(4), one Te(1), and one Te(3) atom. is represented by the CIF file [CIF]
data_Li4Sb(TeO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.302
_cell_length_b   5.609
_cell_length_c   7.728
_cell_angle_alpha   94.435
_cell_angle_beta   90.001
_cell_angle_gamma   90.024
_symmetry_Int_Tables_number   1
_cell_volume   229.119
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.993  0.420  0.287  1.0
  Li  Li1  1  0.505  0.922  0.793  1.0
  Li  Li2  1  0.004  0.453  0.779  1.0
  Li  Li3  1  0.498  0.951  0.269  1.0
  Sb  Sb4  1  0.000  0.996  0.002  1.0
  Te  Te5  1  1.000  0.996  0.502  1.0
  Te  Te6  1  0.500  0.492  0.004  1.0
  Te  Te7  1  0.499  0.494  0.504  1.0
  O  O8  1  0.296  0.177  0.423  1.0
  O  O9  1  0.138  0.010  0.743  1.0
  O  O10  1  0.321  0.831  0.054  1.0
  O  O11  1  0.169  0.700  0.425  1.0
  O  O12  1  0.808  0.701  0.923  1.0
  O  O13  1  0.374  0.516  0.755  1.0
  O  O14  1  0.626  0.513  0.248  1.0
  O  O15  1  0.171  0.317  0.059  1.0
  O  O16  1  0.846  0.316  0.557  1.0
  O  O17  1  0.697  0.186  0.927  1.0
  O  O18  1  0.865  0.023  0.256  1.0
  O  O19  1  0.687  0.843  0.562  1.0
[/CIF]
.
The structure described by Li4Sb(TeO4)3 is Ilmenite-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(4), one O(7), one O(8), and one O(9) atom. In the second Li site, Li(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(2), one O(3), one O(5), and one O(6) atom. In the third Li site, Li(3) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(5), one O(6), one O(8), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a 3-coordinate geometry to one O(1), one O(11), one O(12), one O(3), one O(4), and one O(7) atom. Sb(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form SbO6 octahedra that share corners with two equivalent Te(1)O6 octahedra and corners with four equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-42°. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent Te(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-43°. In the second Te site, Te(2) is bonded to one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent Te(3)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 39-41°. In the third Te site, Te(3) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles range from 39-43°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(4), one Te(1), and one Te(3) atom to form distorted OLi2Te2 tetrahedra that share  a cornercorner with one O(11)Li2SbTe tetrahedra,  a cornercorner with one O(3)Li2SbTe tetrahedra,  a cornercorner with one O(6)Li2Te2 tetrahedra,  a cornercorner with one O(9)Li2Te2 tetrahedra,  an edgeedge with one O(11)Li2SbTe tetrahedra, and  an edgeedge with one O(9)Li2Te2 tetrahedra. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Sb(1), and one Te(1) atom. In the third O site, O(3) is bonded to one Li(2), one Li(4), one Sb(1), and one Te(2) atom to form distorted OLi2SbTe tetrahedra that share  a cornercorner with one O(1)Li2Te2 tetrahedra, corners with two equivalent O(11)Li2SbTe tetrahedra,  a cornercorner with one O(5)Li2SbTe trigonal pyramid,  an edgeedge with one O(6)Li2Te2 tetrahedra, and  an edgeedge with one O(5)Li2SbTe trigonal pyramid. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Li(1), one Li(4), one Te(1), and one Te(3) atom. In the fifth O site, O(5) is bonded to one Li(2), one Li(3), one Sb(1), and one Te(2) atom to form distorted OLi2SbTe trigonal pyramids that share  a cornercorner with one O(11)Li2SbTe tetrahedra,  a cornercorner with one O(3)Li2SbTe tetrahedra,  a cornercorner with one O(6)Li2Te2 tetrahedra,  a cornercorner with one O(9)Li2Te2 tetrahedra,  an edgeedge with one O(3)Li2SbTe tetrahedra, and  an edgeedge with one O(6)Li2Te2 tetrahedra. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Te(2), and one Te(3) atom to form distorted OLi2Te2 tetrahedra that share  a cornercorner with one O(1)Li2Te2 tetrahedra, corners with two equivalent O(9)Li2Te2 tetrahedra,  a cornercorner with one O(5)Li2SbTe trigonal pyramid,  an edgeedge with one O(3)Li2SbTe tetrahedra, and  an edgeedge with one O(5)Li2SbTe trigonal pyramid. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Li(1), one Li(4), one Te(2), and one Te(3) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(1), one Li(3), one Sb(1), and one Te(2) atom. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one Te(1), and one Te(3) atom to form distorted OLi2Te2 tetrahedra that share  a cornercorner with one O(1)Li2Te2 tetrahedra, corners with two equivalent O(6)Li2Te2 tetrahedra,  a cornercorner with one O(5)Li2SbTe trigonal pyramid,  an edgeedge with one O(11)Li2SbTe tetrahedra, and  an edgeedge with one O(1)Li2Te2 tetrahedra. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Sb(1), and one Te(2) atom. In the eleventh O site, O(11) is bonded to one Li(1), one Li(4), one Sb(1), and one Te(1) atom to form distorted OLi2SbTe tetrahedra that share  a cornercorner with one O(1)Li2Te2 tetrahedra, corners with two equivalent O(3)Li2SbTe tetrahedra,  a cornercorner with one O(5)Li2SbTe trigonal pyramid,  an edgeedge with one O(1)Li2Te2 tetrahedra, and  an edgeedge with one O(9)Li2Te2 tetrahedra. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Li(2), one Li(4), one Te(1), and one Te(3) atom. is represented by the CIF file [CIF]
data_Li4Sb(TeO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.302
_cell_length_b   5.609
_cell_length_c   7.728
_cell_angle_alpha   94.435
_cell_angle_beta   90.001
_cell_angle_gamma   90.024
_symmetry_Int_Tables_number   1
_cell_volume   229.119
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.993  0.420  0.287  1.0
  Li  Li1  1  0.505  0.922  0.793  1.0
  Li  Li2  1  0.004  0.453  0.779  1.0
  Li  Li3  1  0.498  0.951  0.269  1.0
  Sb  Sb4  1  0.000  0.996  0.002  1.0
  Te  Te5  1  1.000  0.996  0.502  1.0
  Te  Te6  1  0.500  0.492  0.004  1.0
  Te  Te7  1  0.499  0.494  0.504  1.0
  O  O8  1  0.296  0.177  0.423  1.0
  O  O9  1  0.138  0.010  0.743  1.0
  O  O10  1  0.321  0.831  0.054  1.0
  O  O11  1  0.169  0.700  0.425  1.0
  O  O12  1  0.808  0.701  0.923  1.0
  O  O13  1  0.374  0.516  0.755  1.0
  O  O14  1  0.626  0.513  0.248  1.0
  O  O15  1  0.171  0.317  0.059  1.0
  O  O16  1  0.846  0.316  0.557  1.0
  O  O17  1  0.697  0.186  0.927  1.0
  O  O18  1  0.865  0.023  0.256  1.0
  O  O19  1  0.687  0.843  0.562  1.0
[/CIF]
.