The structure described by BiVO4 crystallizes in the monoclinic C2/c space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Bi(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Bi(1) atoms. is represented by the CIF file [CIF]
data_VBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.926
_cell_length_b   6.926
_cell_length_c   5.177
_cell_angle_alpha   68.050
_cell_angle_beta   68.050
_cell_angle_gamma   116.020
_symmetry_Int_Tables_number   1
_cell_volume   158.135
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.127  0.873  0.250  1.0
  V  V1  1  0.873  0.127  0.750  1.0
  Bi  Bi2  1  0.627  0.373  0.250  1.0
  Bi  Bi3  1  0.373  0.627  0.750  1.0
  O  O4  1  0.201  0.296  0.362  1.0
  O  O5  1  0.704  0.799  0.138  1.0
  O  O6  1  0.799  0.704  0.638  1.0
  O  O7  1  0.296  0.201  0.862  1.0
  O  O8  1  0.650  0.062  0.641  1.0
  O  O9  1  0.938  0.350  0.859  1.0
  O  O10  1  0.350  0.938  0.359  1.0
  O  O11  1  0.062  0.650  0.141  1.0
[/CIF]
.
The structure described by BiVO4 crystallizes in the monoclinic C2/c space group. V(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. Bi(1) is bonded in a 8-coordinate geometry to four equivalent O(1) and four equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Bi(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Bi(1) atoms. is represented by the CIF file [CIF]
data_VBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.926
_cell_length_b   6.926
_cell_length_c   5.177
_cell_angle_alpha   68.050
_cell_angle_beta   68.050
_cell_angle_gamma   116.020
_symmetry_Int_Tables_number   1
_cell_volume   158.135
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.127  0.873  0.250  1.0
  V  V1  1  0.873  0.127  0.750  1.0
  Bi  Bi2  1  0.627  0.373  0.250  1.0
  Bi  Bi3  1  0.373  0.627  0.750  1.0
  O  O4  1  0.201  0.296  0.362  1.0
  O  O5  1  0.704  0.799  0.138  1.0
  O  O6  1  0.799  0.704  0.638  1.0
  O  O7  1  0.296  0.201  0.862  1.0
  O  O8  1  0.650  0.062  0.641  1.0
  O  O9  1  0.938  0.350  0.859  1.0
  O  O10  1  0.350  0.938  0.359  1.0
  O  O11  1  0.062  0.650  0.141  1.0
[/CIF]
.