The crystal structure described by TiSi2 is Zirconium Disilicide structured and crystallizes in the orthorhombic Cmcm space group. Ti(1) is bonded in a 10-coordinate geometry to four equivalent Si(2) and six equivalent Si(1) atoms. There are two inequivalent Si sites. In the first Si site, Si(1) is bonded in a 8-coordinate geometry to six equivalent Ti(1) and two equivalent Si(1) atoms. In the second Si site, Si(2) is bonded in a 8-coordinate geometry to four equivalent Ti(1) and four equivalent Si(2) atoms. is represented by the CIF card [CIF]
data_TiSi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.530
_cell_length_b   3.565
_cell_length_c   6.986
_cell_angle_alpha   90.000
_cell_angle_beta   104.635
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   85.071
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.897  0.750  0.794  1.0
  Ti  Ti1  1  0.103  0.250  0.206  1.0
  Si  Si2  1  0.558  0.750  0.117  1.0
  Si  Si3  1  0.442  0.250  0.883  1.0
  Si  Si4  1  0.250  0.750  0.499  1.0
  Si  Si5  1  0.750  0.250  0.501  1.0
[/CIF]
.
The crystal structure described by TiSi2 is Zirconium Disilicide structured and crystallizes in the orthorhombic Cmcm space group. Ti(1) is bonded in a 10-coordinate geometry to four equivalent Si(2) and six equivalent Si(1) atoms. There are two inequivalent Si sites. In the first Si site, Si(1) is bonded in a 8-coordinate geometry to six equivalent Ti(1) and two equivalent Si(1) atoms. In the second Si site, Si(2) is bonded in a 8-coordinate geometry to four equivalent Ti(1) and four equivalent Si(2) atoms. is represented by the CIF card [CIF]
data_TiSi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.530
_cell_length_b   3.565
_cell_length_c   6.986
_cell_angle_alpha   90.000
_cell_angle_beta   104.635
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   85.071
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.897  0.750  0.794  1.0
  Ti  Ti1  1  0.103  0.250  0.206  1.0
  Si  Si2  1  0.558  0.750  0.117  1.0
  Si  Si3  1  0.442  0.250  0.883  1.0
  Si  Si4  1  0.250  0.750  0.499  1.0
  Si  Si5  1  0.750  0.250  0.501  1.0
[/CIF]
.