The material described by MnRhN2 crystallizes in the orthorhombic Pna2_1 space group. Mn(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form corner-sharing MnN4 tetrahedra. Rh(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a rectangular see-saw-like geometry to two equivalent Mn(1) and two equivalent Rh(1) atoms. In the second N site, N(2) is bonded to two equivalent Mn(1) and two equivalent Rh(1) atoms to form distorted corner-sharing NMn2Rh2 tetrahedra. is represented by the CIF card [CIF]
data_MnRhN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.096
_cell_length_b   5.990
_cell_length_c   5.477
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   167.202
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.567  0.888  0.966  1.0
  Mn  Mn1  1  0.433  0.112  0.466  1.0
  Mn  Mn2  1  0.933  0.388  0.466  1.0
  Mn  Mn3  1  0.067  0.612  0.966  1.0
  Rh  Rh4  1  0.621  0.341  0.040  1.0
  Rh  Rh5  1  0.379  0.659  0.540  1.0
  Rh  Rh6  1  0.879  0.841  0.540  1.0
  Rh  Rh7  1  0.121  0.159  0.040  1.0
  N  N8  1  0.574  0.873  0.304  1.0
  N  N9  1  0.426  0.127  0.804  1.0
  N  N10  1  0.926  0.373  0.804  1.0
  N  N11  1  0.074  0.627  0.304  1.0
  N  N12  1  0.583  0.383  0.413  1.0
  N  N13  1  0.417  0.617  0.913  1.0
  N  N14  1  0.917  0.883  0.913  1.0
  N  N15  1  0.083  0.117  0.413  1.0
[/CIF]
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The material described by MnRhN2 crystallizes in the orthorhombic Pna2_1 space group. Mn(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form corner-sharing MnN4 tetrahedra. Rh(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a rectangular see-saw-like geometry to two equivalent Mn(1) and two equivalent Rh(1) atoms. In the second N site, N(2) is bonded to two equivalent Mn(1) and two equivalent Rh(1) atoms to form distorted corner-sharing NMn2Rh2 tetrahedra. is represented by the CIF card [CIF]
data_MnRhN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.096
_cell_length_b   5.990
_cell_length_c   5.477
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   167.202
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.567  0.888  0.966  1.0
  Mn  Mn1  1  0.433  0.112  0.466  1.0
  Mn  Mn2  1  0.933  0.388  0.466  1.0
  Mn  Mn3  1  0.067  0.612  0.966  1.0
  Rh  Rh4  1  0.621  0.341  0.040  1.0
  Rh  Rh5  1  0.379  0.659  0.540  1.0
  Rh  Rh6  1  0.879  0.841  0.540  1.0
  Rh  Rh7  1  0.121  0.159  0.040  1.0
  N  N8  1  0.574  0.873  0.304  1.0
  N  N9  1  0.426  0.127  0.804  1.0
  N  N10  1  0.926  0.373  0.804  1.0
  N  N11  1  0.074  0.627  0.304  1.0
  N  N12  1  0.583  0.383  0.413  1.0
  N  N13  1  0.417  0.617  0.913  1.0
  N  N14  1  0.917  0.883  0.913  1.0
  N  N15  1  0.083  0.117  0.413  1.0
[/CIF]
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