The compound described by MnN9N(CH3)4 crystallizes in the monoclinic P2_1 space group. The structure consists of two tetramethylammonium molecules inside a MnN9 framework. In the MnN9 framework, Mn(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(4), one N(7), one N(8), and one N(9) atom. There are nine inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one N(5) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Mn(1) and one N(3) atom. In the third N site, N(3) is bonded in a linear geometry to one N(2) and one N(9) atom. In the fourth N site, N(4) is bonded in a bent 150 degrees geometry to one Mn(1) and one N(6) atom. In the fifth N site, N(5) is bonded in a linear geometry to one N(1) and one N(7) atom. In the sixth N site, N(6) is bonded in a linear geometry to one N(4) and one N(8) atom. In the seventh N site, N(7) is bonded in a bent 150 degrees geometry to one Mn(1) and one N(5) atom. In the eighth N site, N(8) is bonded in a bent 150 degrees geometry to one Mn(1) and one N(6) atom. In the ninth N site, N(9) is bonded in a distorted linear geometry to one Mn(1) and one N(3) atom. is represented by the CIF card [CIF]
data_MnH12(C2N5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.690
_cell_length_b   6.145
_cell_length_c   6.251
_cell_angle_alpha   89.778
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   487.474
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.753  0.001  0.997  1.0
  Mn  Mn1  1  0.253  0.999  0.003  1.0
  H  H2  1  0.412  0.327  0.656  1.0
  H  H3  1  0.422  0.789  0.595  1.0
  H  H4  1  0.922  0.211  0.405  1.0
  H  H5  1  0.481  0.477  0.125  1.0
  H  H6  1  0.081  0.326  0.808  1.0
  H  H7  1  0.563  0.827  0.563  1.0
  H  H8  1  0.667  0.519  0.468  1.0
  H  H9  1  0.106  0.722  0.638  1.0
  H  H10  1  0.414  0.249  0.377  1.0
  H  H11  1  0.839  0.519  0.541  1.0
  H  H12  1  0.513  0.648  0.767  1.0
  H  H13  1  0.912  0.673  0.344  1.0
  H  H14  1  0.167  0.481  0.532  1.0
  H  H15  1  0.942  0.258  0.782  1.0
  H  H16  1  0.914  0.751  0.623  1.0
  H  H17  1  0.442  0.742  0.218  1.0
  H  H18  1  0.981  0.523  0.875  1.0
  H  H19  1  0.339  0.481  0.459  1.0
  H  H20  1  0.101  0.669  0.353  1.0
  H  H21  1  0.063  0.173  0.437  1.0
  H  H22  1  0.013  0.352  0.233  1.0
  H  H23  1  0.581  0.674  0.192  1.0
  H  H24  1  0.601  0.331  0.647  1.0
  H  H25  1  0.606  0.278  0.362  1.0
  C  C26  1  0.002  0.387  0.771  1.0
  C  C27  1  0.102  0.597  0.514  1.0
  C  C28  1  0.410  0.384  0.490  1.0
  C  C29  1  0.602  0.403  0.486  1.0
  C  C30  1  0.502  0.613  0.229  1.0
  C  C31  1  1.000  0.287  0.394  1.0
  C  C32  1  0.500  0.713  0.606  1.0
  C  C33  1  0.910  0.616  0.510  1.0
  N  N34  1  0.230  0.322  0.052  1.0
  N  N35  1  0.910  0.921  0.019  1.0
  N  N36  1  0.004  0.935  0.026  1.0
  N  N37  1  0.271  0.942  0.324  1.0
  N  N38  1  0.253  0.503  0.001  1.0
  N  N39  1  0.752  0.003  0.498  1.0
  N  N40  1  0.777  0.317  0.053  1.0
  N  N41  1  0.734  0.948  0.318  1.0
  N  N42  1  0.097  0.930  0.041  1.0
  N  N43  1  0.753  0.497  0.999  1.0
  N  N44  1  0.504  0.065  0.974  1.0
  N  N45  1  0.410  0.079  0.981  1.0
  N  N46  1  0.503  0.528  0.453  1.0
  N  N47  1  0.597  0.070  0.959  1.0
  N  N48  1  0.730  0.678  0.948  1.0
  N  N49  1  0.277  0.683  0.947  1.0
  N  N50  1  0.771  0.058  0.676  1.0
  N  N51  1  0.234  0.052  0.682  1.0
  N  N52  1  0.252  0.997  0.502  1.0
  N  N53  1  0.003  0.472  0.547  1.0
[/CIF]
.
The compound described by MnN9N(CH3)4 crystallizes in the monoclinic P2_1 space group. The structure consists of two tetramethylammonium molecules inside a MnN9 framework. In the MnN9 framework, Mn(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(4), one N(7), one N(8), and one N(9) atom. There are nine inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one N(5) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Mn(1) and one N(3) atom. In the third N site, N(3) is bonded in a linear geometry to one N(2) and one N(9) atom. In the fourth N site, N(4) is bonded in a bent 150 degrees geometry to one Mn(1) and one N(6) atom. In the fifth N site, N(5) is bonded in a linear geometry to one N(1) and one N(7) atom. In the sixth N site, N(6) is bonded in a linear geometry to one N(4) and one N(8) atom. In the seventh N site, N(7) is bonded in a bent 150 degrees geometry to one Mn(1) and one N(5) atom. In the eighth N site, N(8) is bonded in a bent 150 degrees geometry to one Mn(1) and one N(6) atom. In the ninth N site, N(9) is bonded in a distorted linear geometry to one Mn(1) and one N(3) atom. is represented by the CIF card [CIF]
data_MnH12(C2N5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.690
_cell_length_b   6.145
_cell_length_c   6.251
_cell_angle_alpha   89.778
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   487.474
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.753  0.001  0.997  1.0
  Mn  Mn1  1  0.253  0.999  0.003  1.0
  H  H2  1  0.412  0.327  0.656  1.0
  H  H3  1  0.422  0.789  0.595  1.0
  H  H4  1  0.922  0.211  0.405  1.0
  H  H5  1  0.481  0.477  0.125  1.0
  H  H6  1  0.081  0.326  0.808  1.0
  H  H7  1  0.563  0.827  0.563  1.0
  H  H8  1  0.667  0.519  0.468  1.0
  H  H9  1  0.106  0.722  0.638  1.0
  H  H10  1  0.414  0.249  0.377  1.0
  H  H11  1  0.839  0.519  0.541  1.0
  H  H12  1  0.513  0.648  0.767  1.0
  H  H13  1  0.912  0.673  0.344  1.0
  H  H14  1  0.167  0.481  0.532  1.0
  H  H15  1  0.942  0.258  0.782  1.0
  H  H16  1  0.914  0.751  0.623  1.0
  H  H17  1  0.442  0.742  0.218  1.0
  H  H18  1  0.981  0.523  0.875  1.0
  H  H19  1  0.339  0.481  0.459  1.0
  H  H20  1  0.101  0.669  0.353  1.0
  H  H21  1  0.063  0.173  0.437  1.0
  H  H22  1  0.013  0.352  0.233  1.0
  H  H23  1  0.581  0.674  0.192  1.0
  H  H24  1  0.601  0.331  0.647  1.0
  H  H25  1  0.606  0.278  0.362  1.0
  C  C26  1  0.002  0.387  0.771  1.0
  C  C27  1  0.102  0.597  0.514  1.0
  C  C28  1  0.410  0.384  0.490  1.0
  C  C29  1  0.602  0.403  0.486  1.0
  C  C30  1  0.502  0.613  0.229  1.0
  C  C31  1  1.000  0.287  0.394  1.0
  C  C32  1  0.500  0.713  0.606  1.0
  C  C33  1  0.910  0.616  0.510  1.0
  N  N34  1  0.230  0.322  0.052  1.0
  N  N35  1  0.910  0.921  0.019  1.0
  N  N36  1  0.004  0.935  0.026  1.0
  N  N37  1  0.271  0.942  0.324  1.0
  N  N38  1  0.253  0.503  0.001  1.0
  N  N39  1  0.752  0.003  0.498  1.0
  N  N40  1  0.777  0.317  0.053  1.0
  N  N41  1  0.734  0.948  0.318  1.0
  N  N42  1  0.097  0.930  0.041  1.0
  N  N43  1  0.753  0.497  0.999  1.0
  N  N44  1  0.504  0.065  0.974  1.0
  N  N45  1  0.410  0.079  0.981  1.0
  N  N46  1  0.503  0.528  0.453  1.0
  N  N47  1  0.597  0.070  0.959  1.0
  N  N48  1  0.730  0.678  0.948  1.0
  N  N49  1  0.277  0.683  0.947  1.0
  N  N50  1  0.771  0.058  0.676  1.0
  N  N51  1  0.234  0.052  0.682  1.0
  N  N52  1  0.252  0.997  0.502  1.0
  N  N53  1  0.003  0.472  0.547  1.0
[/CIF]
.