The compound described by RbMnH4O2Cl3 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1), three equivalent Cl(2), and three equivalent Cl(3) atoms. Mn(1) is bonded to one O(1), one O(2), one Cl(2), one Cl(3), and two equivalent Cl(1) atoms to form edge-sharing MnCl4O2 octahedra. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one H(3), and one H(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1) and two equivalent Mn(1) atoms. In the second Cl site, Cl(2) is bonded in a 1-coordinate geometry to three equivalent Rb(1) and one Mn(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbMnH4Cl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.635
_cell_length_b   7.316
_cell_length_c   8.987
_cell_angle_alpha   91.263
_cell_angle_beta   107.604
_cell_angle_gamma   112.101
_symmetry_Int_Tables_number   1
_cell_volume   380.682
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.263  0.943  0.181  1.0
  Rb  Rb1  1  0.737  0.057  0.819  1.0
  Mn  Mn2  1  1.000  0.335  0.332  1.0
  Mn  Mn3  1  0.000  0.665  0.668  1.0
  H  H4  1  0.588  0.704  0.479  1.0
  H  H5  1  0.412  0.296  0.521  1.0
  H  H6  1  0.777  0.822  0.403  1.0
  H  H7  1  0.223  0.178  0.597  1.0
  H  H8  1  0.621  0.449  0.189  1.0
  H  H9  1  0.379  0.551  0.811  1.0
  H  H10  1  0.754  0.476  0.065  1.0
  H  H11  1  0.246  0.524  0.935  1.0
  Cl  Cl12  1  0.246  0.703  0.490  1.0
  Cl  Cl13  1  0.754  0.297  0.510  1.0
  Cl  Cl14  1  0.781  0.974  0.197  1.0
  Cl  Cl15  1  0.219  0.026  0.803  1.0
  Cl  Cl16  1  0.250  0.421  0.157  1.0
  Cl  Cl17  1  0.750  0.579  0.843  1.0
  O  O18  1  0.755  0.757  0.496  1.0
  O  O19  1  0.245  0.243  0.504  1.0
  O  O20  1  0.751  0.432  0.168  1.0
  O  O21  1  0.249  0.568  0.832  1.0
[/CIF]
.
The compound described by RbMnH4O2Cl3 crystallizes in the triclinic P-1 space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent Cl(1), three equivalent Cl(2), and three equivalent Cl(3) atoms. Mn(1) is bonded to one O(1), one O(2), one Cl(2), one Cl(3), and two equivalent Cl(1) atoms to form edge-sharing MnCl4O2 octahedra. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one H(3), and one H(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1) and two equivalent Mn(1) atoms. In the second Cl site, Cl(2) is bonded in a 1-coordinate geometry to three equivalent Rb(1) and one Mn(1) atom. In the third Cl site, Cl(3) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbMnH4Cl3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.635
_cell_length_b   7.316
_cell_length_c   8.987
_cell_angle_alpha   91.263
_cell_angle_beta   107.604
_cell_angle_gamma   112.101
_symmetry_Int_Tables_number   1
_cell_volume   380.682
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.263  0.943  0.181  1.0
  Rb  Rb1  1  0.737  0.057  0.819  1.0
  Mn  Mn2  1  1.000  0.335  0.332  1.0
  Mn  Mn3  1  0.000  0.665  0.668  1.0
  H  H4  1  0.588  0.704  0.479  1.0
  H  H5  1  0.412  0.296  0.521  1.0
  H  H6  1  0.777  0.822  0.403  1.0
  H  H7  1  0.223  0.178  0.597  1.0
  H  H8  1  0.621  0.449  0.189  1.0
  H  H9  1  0.379  0.551  0.811  1.0
  H  H10  1  0.754  0.476  0.065  1.0
  H  H11  1  0.246  0.524  0.935  1.0
  Cl  Cl12  1  0.246  0.703  0.490  1.0
  Cl  Cl13  1  0.754  0.297  0.510  1.0
  Cl  Cl14  1  0.781  0.974  0.197  1.0
  Cl  Cl15  1  0.219  0.026  0.803  1.0
  Cl  Cl16  1  0.250  0.421  0.157  1.0
  Cl  Cl17  1  0.750  0.579  0.843  1.0
  O  O18  1  0.755  0.757  0.496  1.0
  O  O19  1  0.245  0.243  0.504  1.0
  O  O20  1  0.751  0.432  0.168  1.0
  O  O21  1  0.249  0.568  0.832  1.0
[/CIF]
.