The compound described by Ag2O crystallizes in the orthorhombic Ibam space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. In the third Ag site, Ag(3) is bonded to four equivalent O(1) atoms to form distorted edge-sharing AgO4 tetrahedra. O(1) is bonded in a 5-coordinate geometry to one Ag(2), two equivalent Ag(1), and two equivalent Ag(3) atoms. is represented by the CIF file [CIF]
data_Ag2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.335
_cell_length_b   6.631
_cell_length_c   6.631
_cell_angle_alpha   94.254
_cell_angle_beta   61.463
_cell_angle_gamma   61.463
_symmetry_Int_Tables_number   1
_cell_volume   197.797
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.500  0.000  1.0
  Ag  Ag1  1  0.500  0.500  0.000  1.0
  Ag  Ag2  1  0.000  0.000  0.000  1.0
  Ag  Ag3  1  0.250  0.500  0.500  1.0
  Ag  Ag4  1  0.500  0.000  0.000  1.0
  Ag  Ag5  1  0.000  0.000  0.500  1.0
  Ag  Ag6  1  0.750  0.500  0.500  1.0
  Ag  Ag7  1  0.500  0.000  0.500  1.0
  O  O8  1  0.222  0.389  0.168  1.0
  O  O9  1  0.278  0.832  0.611  1.0
  O  O10  1  0.722  0.168  0.389  1.0
  O  O11  1  0.778  0.611  0.832  1.0
[/CIF]
.
The compound described by Ag2O crystallizes in the orthorhombic Ibam space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. In the third Ag site, Ag(3) is bonded to four equivalent O(1) atoms to form distorted edge-sharing AgO4 tetrahedra. O(1) is bonded in a 5-coordinate geometry to one Ag(2), two equivalent Ag(1), and two equivalent Ag(3) atoms. is represented by the CIF file [CIF]
data_Ag2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.335
_cell_length_b   6.631
_cell_length_c   6.631
_cell_angle_alpha   94.254
_cell_angle_beta   61.463
_cell_angle_gamma   61.463
_symmetry_Int_Tables_number   1
_cell_volume   197.797
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.500  0.000  1.0
  Ag  Ag1  1  0.500  0.500  0.000  1.0
  Ag  Ag2  1  0.000  0.000  0.000  1.0
  Ag  Ag3  1  0.250  0.500  0.500  1.0
  Ag  Ag4  1  0.500  0.000  0.000  1.0
  Ag  Ag5  1  0.000  0.000  0.500  1.0
  Ag  Ag6  1  0.750  0.500  0.500  1.0
  Ag  Ag7  1  0.500  0.000  0.500  1.0
  O  O8  1  0.222  0.389  0.168  1.0
  O  O9  1  0.278  0.832  0.611  1.0
  O  O10  1  0.722  0.168  0.389  1.0
  O  O11  1  0.778  0.611  0.832  1.0
[/CIF]
.