The compound described by PrSbO4 crystallizes in the monoclinic P2/c space group. Pr(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Sb(1) is bonded in a 4-coordinate geometry to one O(1), one O(4), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Pr(1), one Sb(1), and one O(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Pr(1) and one O(1) atom. In the third O site, O(3) is bonded to two equivalent Pr(1) and two equivalent Sb(1) atoms to form distorted edge-sharing OPr2Sb2 trigonal pyramids. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Pr(1) and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PrSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.749
_cell_length_b   6.034
_cell_length_c   14.012
_cell_angle_alpha   68.732
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   374.173
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.843  0.600  0.365  1.0
  Pr  Pr1  1  0.157  0.600  0.865  1.0
  Pr  Pr2  1  0.157  0.400  0.635  1.0
  Pr  Pr3  1  0.843  0.400  0.135  1.0
  Sb  Sb4  1  0.229  0.084  0.403  1.0
  Sb  Sb5  1  0.771  0.084  0.903  1.0
  Sb  Sb6  1  0.229  0.916  0.097  1.0
  Sb  Sb7  1  0.771  0.916  0.597  1.0
  O  O8  1  0.361  0.794  0.329  1.0
  O  O9  1  0.347  0.536  0.397  1.0
  O  O10  1  0.990  0.205  0.015  1.0
  O  O11  1  0.653  0.464  0.603  1.0
  O  O12  1  0.091  0.754  0.686  1.0
  O  O13  1  0.010  0.205  0.515  1.0
  O  O14  1  0.653  0.536  0.897  1.0
  O  O15  1  0.361  0.206  0.171  1.0
  O  O16  1  0.639  0.794  0.829  1.0
  O  O17  1  0.909  0.754  0.186  1.0
  O  O18  1  0.010  0.795  0.985  1.0
  O  O19  1  0.990  0.795  0.485  1.0
  O  O20  1  0.909  0.246  0.314  1.0
  O  O21  1  0.347  0.464  0.103  1.0
  O  O22  1  0.091  0.246  0.814  1.0
  O  O23  1  0.639  0.206  0.671  1.0
[/CIF]
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The compound described by PrSbO4 crystallizes in the monoclinic P2/c space group. Pr(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Sb(1) is bonded in a 4-coordinate geometry to one O(1), one O(4), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Pr(1), one Sb(1), and one O(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Pr(1) and one O(1) atom. In the third O site, O(3) is bonded to two equivalent Pr(1) and two equivalent Sb(1) atoms to form distorted edge-sharing OPr2Sb2 trigonal pyramids. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Pr(1) and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PrSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.749
_cell_length_b   6.034
_cell_length_c   14.012
_cell_angle_alpha   68.732
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   374.173
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.843  0.600  0.365  1.0
  Pr  Pr1  1  0.157  0.600  0.865  1.0
  Pr  Pr2  1  0.157  0.400  0.635  1.0
  Pr  Pr3  1  0.843  0.400  0.135  1.0
  Sb  Sb4  1  0.229  0.084  0.403  1.0
  Sb  Sb5  1  0.771  0.084  0.903  1.0
  Sb  Sb6  1  0.229  0.916  0.097  1.0
  Sb  Sb7  1  0.771  0.916  0.597  1.0
  O  O8  1  0.361  0.794  0.329  1.0
  O  O9  1  0.347  0.536  0.397  1.0
  O  O10  1  0.990  0.205  0.015  1.0
  O  O11  1  0.653  0.464  0.603  1.0
  O  O12  1  0.091  0.754  0.686  1.0
  O  O13  1  0.010  0.205  0.515  1.0
  O  O14  1  0.653  0.536  0.897  1.0
  O  O15  1  0.361  0.206  0.171  1.0
  O  O16  1  0.639  0.794  0.829  1.0
  O  O17  1  0.909  0.754  0.186  1.0
  O  O18  1  0.010  0.795  0.985  1.0
  O  O19  1  0.990  0.795  0.485  1.0
  O  O20  1  0.909  0.246  0.314  1.0
  O  O21  1  0.347  0.464  0.103  1.0
  O  O22  1  0.091  0.246  0.814  1.0
  O  O23  1  0.639  0.206  0.671  1.0
[/CIF]
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