The crystal structure described by GdCO4 crystallizes in the orthorhombic P2_12_12_1 space group. Gd(1) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(2), three equivalent O(3), and three equivalent O(4) atoms. C(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Gd(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Gd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Gd(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to three equivalent Gd(1) and one C(1) atom. is represented by the CIF file [CIF]
data_GdCO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.938
_cell_length_b   7.283
_cell_length_c   8.365
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   300.848
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.002  0.892  0.331  1.0
  Gd  Gd1  1  0.498  0.108  0.831  1.0
  Gd  Gd2  1  0.998  0.392  0.169  1.0
  Gd  Gd3  1  0.502  0.608  0.669  1.0
  C  C4  1  0.003  0.949  0.679  1.0
  C  C5  1  0.497  0.051  0.179  1.0
  C  C6  1  0.997  0.449  0.821  1.0
  C  C7  1  0.503  0.551  0.321  1.0
  O  O8  1  0.980  0.699  0.122  1.0
  O  O9  1  0.520  0.301  0.622  1.0
  O  O10  1  0.020  0.199  0.378  1.0
  O  O11  1  0.480  0.801  0.878  1.0
  O  O12  1  0.508  0.949  0.303  1.0
  O  O13  1  0.992  0.051  0.803  1.0
  O  O14  1  0.492  0.449  0.197  1.0
  O  O15  1  0.008  0.551  0.697  1.0
  O  O16  1  0.738  0.597  0.379  1.0
  O  O17  1  0.762  0.403  0.879  1.0
  O  O18  1  0.262  0.097  0.121  1.0
  O  O19  1  0.238  0.903  0.621  1.0
  O  O20  1  0.286  0.600  0.396  1.0
  O  O21  1  0.214  0.400  0.896  1.0
  O  O22  1  0.714  0.100  0.104  1.0
  O  O23  1  0.786  0.900  0.604  1.0
[/CIF]
.
The crystal structure described by GdCO4 crystallizes in the orthorhombic P2_12_12_1 space group. Gd(1) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(2), three equivalent O(3), and three equivalent O(4) atoms. C(1) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Gd(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Gd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Gd(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to three equivalent Gd(1) and one C(1) atom. is represented by the CIF file [CIF]
data_GdCO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.938
_cell_length_b   7.283
_cell_length_c   8.365
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   300.848
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.002  0.892  0.331  1.0
  Gd  Gd1  1  0.498  0.108  0.831  1.0
  Gd  Gd2  1  0.998  0.392  0.169  1.0
  Gd  Gd3  1  0.502  0.608  0.669  1.0
  C  C4  1  0.003  0.949  0.679  1.0
  C  C5  1  0.497  0.051  0.179  1.0
  C  C6  1  0.997  0.449  0.821  1.0
  C  C7  1  0.503  0.551  0.321  1.0
  O  O8  1  0.980  0.699  0.122  1.0
  O  O9  1  0.520  0.301  0.622  1.0
  O  O10  1  0.020  0.199  0.378  1.0
  O  O11  1  0.480  0.801  0.878  1.0
  O  O12  1  0.508  0.949  0.303  1.0
  O  O13  1  0.992  0.051  0.803  1.0
  O  O14  1  0.492  0.449  0.197  1.0
  O  O15  1  0.008  0.551  0.697  1.0
  O  O16  1  0.738  0.597  0.379  1.0
  O  O17  1  0.762  0.403  0.879  1.0
  O  O18  1  0.262  0.097  0.121  1.0
  O  O19  1  0.238  0.903  0.621  1.0
  O  O20  1  0.286  0.600  0.396  1.0
  O  O21  1  0.214  0.400  0.896  1.0
  O  O22  1  0.714  0.100  0.104  1.0
  O  O23  1  0.786  0.900  0.604  1.0
[/CIF]
.