The structure described by Zn2TiO4 crystallizes in the tetragonal P4_322 space group. Ti(1) is bonded in a distorted tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Zn site, Zn(2) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ti(1), one Zn(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Ti(1), one Zn(1), and one Zn(2) atom. is represented by the CIF file [CIF]
data_TiZn2O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.074
_cell_length_b   6.074
_cell_length_c   12.834
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   473.569
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.154  0.500  0.250  1.0
  Ti  Ti1  1  0.500  0.846  0.500  1.0
  Ti  Ti2  1  0.500  0.154  0.000  1.0
  Ti  Ti3  1  0.846  0.500  0.750  1.0
  Zn  Zn4  1  0.000  0.450  0.000  1.0
  Zn  Zn5  1  0.000  0.550  0.500  1.0
  Zn  Zn6  1  0.361  0.361  0.625  1.0
  Zn  Zn7  1  0.361  0.639  0.875  1.0
  Zn  Zn8  1  0.450  0.000  0.250  1.0
  Zn  Zn9  1  0.550  0.000  0.750  1.0
  Zn  Zn10  1  0.639  0.361  0.375  1.0
  Zn  Zn11  1  0.639  0.639  0.125  1.0
  O  O12  1  0.573  0.044  0.396  1.0
  O  O13  1  0.573  0.956  0.104  1.0
  O  O14  1  0.379  0.702  0.249  1.0
  O  O15  1  0.379  0.298  0.251  1.0
  O  O16  1  0.044  0.573  0.854  1.0
  O  O17  1  0.044  0.427  0.646  1.0
  O  O18  1  0.702  0.379  0.001  1.0
  O  O19  1  0.702  0.621  0.499  1.0
  O  O20  1  0.298  0.379  0.999  1.0
  O  O21  1  0.298  0.621  0.501  1.0
  O  O22  1  0.956  0.573  0.146  1.0
  O  O23  1  0.956  0.427  0.354  1.0
  O  O24  1  0.621  0.702  0.751  1.0
  O  O25  1  0.621  0.298  0.749  1.0
  O  O26  1  0.427  0.044  0.604  1.0
  O  O27  1  0.427  0.956  0.896  1.0
[/CIF]
.
The structure described by Zn2TiO4 crystallizes in the tetragonal P4_322 space group. Ti(1) is bonded in a distorted tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Zn site, Zn(2) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ti(1), one Zn(1), and one Zn(2) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Ti(1), one Zn(1), and one Zn(2) atom. is represented by the CIF file [CIF]
data_TiZn2O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.074
_cell_length_b   6.074
_cell_length_c   12.834
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   473.569
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.154  0.500  0.250  1.0
  Ti  Ti1  1  0.500  0.846  0.500  1.0
  Ti  Ti2  1  0.500  0.154  0.000  1.0
  Ti  Ti3  1  0.846  0.500  0.750  1.0
  Zn  Zn4  1  0.000  0.450  0.000  1.0
  Zn  Zn5  1  0.000  0.550  0.500  1.0
  Zn  Zn6  1  0.361  0.361  0.625  1.0
  Zn  Zn7  1  0.361  0.639  0.875  1.0
  Zn  Zn8  1  0.450  0.000  0.250  1.0
  Zn  Zn9  1  0.550  0.000  0.750  1.0
  Zn  Zn10  1  0.639  0.361  0.375  1.0
  Zn  Zn11  1  0.639  0.639  0.125  1.0
  O  O12  1  0.573  0.044  0.396  1.0
  O  O13  1  0.573  0.956  0.104  1.0
  O  O14  1  0.379  0.702  0.249  1.0
  O  O15  1  0.379  0.298  0.251  1.0
  O  O16  1  0.044  0.573  0.854  1.0
  O  O17  1  0.044  0.427  0.646  1.0
  O  O18  1  0.702  0.379  0.001  1.0
  O  O19  1  0.702  0.621  0.499  1.0
  O  O20  1  0.298  0.379  0.999  1.0
  O  O21  1  0.298  0.621  0.501  1.0
  O  O22  1  0.956  0.573  0.146  1.0
  O  O23  1  0.956  0.427  0.354  1.0
  O  O24  1  0.621  0.702  0.751  1.0
  O  O25  1  0.621  0.298  0.749  1.0
  O  O26  1  0.427  0.044  0.604  1.0
  O  O27  1  0.427  0.956  0.896  1.0
[/CIF]
.