The material described by Mn3Fe3(TeO8)2 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-51°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form distorted MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles are 50°. In the second Fe site, Fe(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the third Fe site, Fe(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form FeO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles are 48°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra, and  an edgeedge with one Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-51°. In the second Te site, Te(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Fe(3), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Fe(1), one Fe(2), and one Te(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Fe(1), and one Fe(2) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Mn(1), one Fe(1), and one Fe(2) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Mn(2), one Mn(3), and one Fe(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mn(3), one Fe(3), and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Mn(1), one Fe(1), and one Te(1) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Mn(1), one Fe(2), and one Te(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Fe(1), one Fe(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Te(1) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Mn(2), one Fe(3), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Mn(3), one Fe(3), and one Te(2) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one Mn(3), and one Fe(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Mn(1), one Fe(1), and one Te(2) atom. In the fifteenth O site, O(15) is bonded in a distorted T-shaped geometry to one Mn(2), one Mn(3), and one Te(2) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Mn(1), one Fe(2), and one Te(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn3Fe3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.990
_cell_length_b   6.014
_cell_length_c   9.243
_cell_angle_alpha   90.957
_cell_angle_beta   90.837
_cell_angle_gamma   119.618
_symmetry_Int_Tables_number   1
_cell_volume   289.324
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.345  0.175  0.211  1.0
  Mn  Mn1  1  0.174  0.343  0.712  1.0
  Mn  Mn2  1  0.169  0.835  0.704  1.0
  Fe  Fe3  1  0.839  0.173  0.206  1.0
  Fe  Fe4  1  0.838  0.665  0.210  1.0
  Fe  Fe5  1  0.665  0.838  0.710  1.0
  Te  Te6  1  0.666  0.337  0.487  1.0
  Te  Te7  1  0.336  0.666  0.987  1.0
  O  O8  1  0.824  0.175  0.601  1.0
  O  O9  1  0.951  0.476  0.354  1.0
  O  O10  1  0.656  0.326  0.107  1.0
  O  O11  1  0.017  0.011  0.298  1.0
  O  O12  1  0.015  0.012  0.797  1.0
  O  O13  1  0.819  0.653  0.599  1.0
  O  O14  1  0.509  0.044  0.343  1.0
  O  O15  1  0.509  0.468  0.342  1.0
  O  O16  1  0.654  0.823  0.098  1.0
  O  O17  1  0.352  0.189  0.598  1.0
  O  O18  1  0.470  0.510  0.843  1.0
  O  O19  1  0.475  0.949  0.851  1.0
  O  O20  1  0.319  0.656  0.610  1.0
  O  O21  1  0.182  0.351  0.101  1.0
  O  O22  1  0.041  0.499  0.847  1.0
  O  O23  1  0.176  0.826  0.099  1.0
[/CIF]
.
The material described by Mn3Fe3(TeO8)2 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-51°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form distorted MnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles are 51°. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles are 50°. In the second Fe site, Fe(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the third Fe site, Fe(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form FeO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles are 48°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra, and  an edgeedge with one Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-51°. In the second Te site, Te(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form TeO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(2), one Fe(3), and one Te(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Fe(1), one Fe(2), and one Te(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Fe(1), and one Fe(2) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Mn(1), one Fe(1), and one Fe(2) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Mn(2), one Mn(3), and one Fe(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mn(3), one Fe(3), and one Te(1) atom. In the seventh O site, O(7) is bonded in a distorted T-shaped geometry to one Mn(1), one Fe(1), and one Te(1) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Mn(1), one Fe(2), and one Te(1) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Fe(1), one Fe(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Mn(2), one Mn(3), and one Te(1) atom. In the eleventh O site, O(11) is bonded in a distorted T-shaped geometry to one Mn(2), one Fe(3), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Mn(3), one Fe(3), and one Te(2) atom. In the thirteenth O site, O(13) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one Mn(3), and one Fe(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Mn(1), one Fe(1), and one Te(2) atom. In the fifteenth O site, O(15) is bonded in a distorted T-shaped geometry to one Mn(2), one Mn(3), and one Te(2) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Mn(1), one Fe(2), and one Te(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn3Fe3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.990
_cell_length_b   6.014
_cell_length_c   9.243
_cell_angle_alpha   90.957
_cell_angle_beta   90.837
_cell_angle_gamma   119.618
_symmetry_Int_Tables_number   1
_cell_volume   289.324
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.345  0.175  0.211  1.0
  Mn  Mn1  1  0.174  0.343  0.712  1.0
  Mn  Mn2  1  0.169  0.835  0.704  1.0
  Fe  Fe3  1  0.839  0.173  0.206  1.0
  Fe  Fe4  1  0.838  0.665  0.210  1.0
  Fe  Fe5  1  0.665  0.838  0.710  1.0
  Te  Te6  1  0.666  0.337  0.487  1.0
  Te  Te7  1  0.336  0.666  0.987  1.0
  O  O8  1  0.824  0.175  0.601  1.0
  O  O9  1  0.951  0.476  0.354  1.0
  O  O10  1  0.656  0.326  0.107  1.0
  O  O11  1  0.017  0.011  0.298  1.0
  O  O12  1  0.015  0.012  0.797  1.0
  O  O13  1  0.819  0.653  0.599  1.0
  O  O14  1  0.509  0.044  0.343  1.0
  O  O15  1  0.509  0.468  0.342  1.0
  O  O16  1  0.654  0.823  0.098  1.0
  O  O17  1  0.352  0.189  0.598  1.0
  O  O18  1  0.470  0.510  0.843  1.0
  O  O19  1  0.475  0.949  0.851  1.0
  O  O20  1  0.319  0.656  0.610  1.0
  O  O21  1  0.182  0.351  0.101  1.0
  O  O22  1  0.041  0.499  0.847  1.0
  O  O23  1  0.176  0.826  0.099  1.0
[/CIF]
.