The crystal structure described by NaLi5Mn2P2(CO7)2 crystallizes in the monoclinic Pc space group. Na(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(12), one O(13), one O(4), and one O(5) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(4), one O(6), and one O(7) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(11), one O(12), one O(14), one O(8), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(14), one O(8), and one O(9) atom. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(14), one O(2), and one O(3) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(7), and one O(9) atom. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(12), one O(13), one O(6), and one O(8) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(14), one O(2), and one O(3) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(1), one O(12), and one O(13) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(4), one O(5), one O(6), and one O(8) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one O(10), one O(11), one O(7), and one O(9) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), one Li(1), one Li(2), and one C(2) atom to form a mixture of distorted corner and edge-sharing ONaLi2C tetrahedra. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Na(1), one Li(5), one Mn(1), and one C(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Na(1), one Li(2), one Li(5), one Mn(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Na(1), one Li(1), one Li(2), one Mn(1), and one P(1) atom. In the fifth O site, O(5) is bonded to one Na(1), one Li(1), one Mn(1), and one P(1) atom to form distorted ONaLiMnP trigonal pyramids that share  a cornercorner with one O(9)Li2MnP tetrahedra, corners with two equivalent O(1)NaLi2C tetrahedra, and corners with two equivalent O(6)NaLiMnP tetrahedra. In the sixth O site, O(6) is bonded to one Na(1), one Li(2), one Mn(2), and one P(1) atom to form distorted ONaLiMnP tetrahedra that share  a cornercorner with one O(10)Li2MnP trigonal pyramid, corners with two equivalent O(5)NaLiMnP trigonal pyramids, and  an edgeedge with one O(1)NaLi2C tetrahedra. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Li(2), one Mn(1), and one P(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(3), one Li(4), one Mn(2), and one P(1) atom. In the ninth O site, O(9) is bonded to one Li(3), one Li(4), one Mn(1), and one P(2) atom to form OLi2MnP tetrahedra that share  a cornercorner with one O(5)NaLiMnP trigonal pyramid, corners with two equivalent O(10)Li2MnP trigonal pyramids, and  an edgeedge with one O(14)Li3C tetrahedra. In the tenth O site, O(10) is bonded to one Li(4), one Li(5), one Mn(2), and one P(2) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(6)NaLiMnP tetrahedra, corners with two equivalent O(9)Li2MnP tetrahedra, and corners with two equivalent O(14)Li3C tetrahedra. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(3), one Li(5), one Mn(2), and one P(2) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one Li(1), one Li(3), one Li(4), one Mn(2), and one C(2) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Li(1), one Mn(2), and one C(2) atom. In the fourteenth O site, O(14) is bonded to one Li(3), one Li(4), one Li(5), and one C(1) atom to form a mixture of corner and edge-sharing OLi3C tetrahedra. is represented by the CIF card [CIF]
data_NaLi5Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.672
_cell_length_b   8.644
_cell_length_c   9.995
_cell_angle_alpha   87.645
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   575.983
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.249  0.247  0.628  1.0
  Na  Na1  1  0.751  0.247  0.128  1.0
  Li  Li2  1  0.507  0.085  0.872  1.0
  Li  Li3  1  0.493  0.085  0.372  1.0
  Li  Li4  1  0.723  0.271  0.616  1.0
  Li  Li5  1  0.277  0.271  0.116  1.0
  Li  Li6  1  0.777  0.734  0.885  1.0
  Li  Li7  1  0.224  0.736  0.884  1.0
  Li  Li8  1  0.776  0.736  0.384  1.0
  Li  Li9  1  0.223  0.734  0.385  1.0
  Li  Li10  1  0.988  0.911  0.628  1.0
  Li  Li11  1  0.012  0.911  0.128  1.0
  Mn  Mn12  1  0.003  0.355  0.887  1.0
  Mn  Mn13  1  0.997  0.355  0.387  1.0
  Mn  Mn14  1  0.498  0.650  0.611  1.0
  Mn  Mn15  1  0.502  0.650  0.111  1.0
  P  P16  1  0.505  0.410  0.852  1.0
  P  P17  1  0.495  0.410  0.352  1.0
  P  P18  1  0.994  0.595  0.642  1.0
  P  P19  1  0.006  0.595  0.142  1.0
  C  C20  1  0.998  0.038  0.865  1.0
  C  C21  1  0.002  0.038  0.365  1.0
  C  C22  1  0.510  0.958  0.640  1.0
  C  C23  1  0.490  0.958  0.140  1.0
  O  O24  1  0.535  0.101  0.672  1.0
  O  O25  1  0.465  0.101  0.172  1.0
  O  O26  1  0.996  0.079  0.989  1.0
  O  O27  1  0.004  0.079  0.489  1.0
  O  O28  1  0.001  0.144  0.769  1.0
  O  O29  1  0.999  0.144  0.269  1.0
  O  O30  1  0.320  0.310  0.898  1.0
  O  O31  1  0.689  0.315  0.904  1.0
  O  O32  1  0.311  0.315  0.404  1.0
  O  O33  1  0.680  0.310  0.398  1.0
  O  O34  1  0.514  0.423  0.696  1.0
  O  O35  1  0.979  0.427  0.594  1.0
  O  O36  1  0.486  0.423  0.196  1.0
  O  O37  1  0.021  0.427  0.094  1.0
  O  O38  1  0.498  0.577  0.903  1.0
  O  O39  1  0.999  0.584  0.799  1.0
  O  O40  1  0.502  0.577  0.403  1.0
  O  O41  1  0.001  0.584  0.299  1.0
  O  O42  1  0.815  0.698  0.593  1.0
  O  O43  1  0.181  0.683  0.588  1.0
  O  O44  1  0.819  0.683  0.088  1.0
  O  O45  1  0.185  0.698  0.093  1.0
  O  O46  1  0.494  0.852  0.735  1.0
  O  O47  1  0.506  0.852  0.235  1.0
  O  O48  1  0.499  0.921  0.515  1.0
  O  O49  1  0.501  0.921  0.015  1.0
  O  O50  1  0.999  0.894  0.835  1.0
  O  O51  1  0.001  0.894  0.335  1.0
[/CIF]
.
The crystal structure described by NaLi5Mn2P2(CO7)2 crystallizes in the monoclinic Pc space group. Na(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(1), one O(12), one O(13), one O(4), and one O(5) atom. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(4), one O(6), and one O(7) atom. In the third Li site, Li(3) is bonded in a 5-coordinate geometry to one O(11), one O(12), one O(14), one O(8), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(14), one O(8), and one O(9) atom. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(14), one O(2), and one O(3) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(7), and one O(9) atom. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(12), one O(13), one O(6), and one O(8) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(14), one O(2), and one O(3) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(1), one O(12), and one O(13) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one O(4), one O(5), one O(6), and one O(8) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one O(10), one O(11), one O(7), and one O(9) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), one Li(1), one Li(2), and one C(2) atom to form a mixture of distorted corner and edge-sharing ONaLi2C tetrahedra. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Na(1), one Li(5), one Mn(1), and one C(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Na(1), one Li(2), one Li(5), one Mn(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Na(1), one Li(1), one Li(2), one Mn(1), and one P(1) atom. In the fifth O site, O(5) is bonded to one Na(1), one Li(1), one Mn(1), and one P(1) atom to form distorted ONaLiMnP trigonal pyramids that share  a cornercorner with one O(9)Li2MnP tetrahedra, corners with two equivalent O(1)NaLi2C tetrahedra, and corners with two equivalent O(6)NaLiMnP tetrahedra. In the sixth O site, O(6) is bonded to one Na(1), one Li(2), one Mn(2), and one P(1) atom to form distorted ONaLiMnP tetrahedra that share  a cornercorner with one O(10)Li2MnP trigonal pyramid, corners with two equivalent O(5)NaLiMnP trigonal pyramids, and  an edgeedge with one O(1)NaLi2C tetrahedra. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Li(2), one Mn(1), and one P(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Li(3), one Li(4), one Mn(2), and one P(1) atom. In the ninth O site, O(9) is bonded to one Li(3), one Li(4), one Mn(1), and one P(2) atom to form OLi2MnP tetrahedra that share  a cornercorner with one O(5)NaLiMnP trigonal pyramid, corners with two equivalent O(10)Li2MnP trigonal pyramids, and  an edgeedge with one O(14)Li3C tetrahedra. In the tenth O site, O(10) is bonded to one Li(4), one Li(5), one Mn(2), and one P(2) atom to form distorted OLi2MnP trigonal pyramids that share  a cornercorner with one O(6)NaLiMnP tetrahedra, corners with two equivalent O(9)Li2MnP tetrahedra, and corners with two equivalent O(14)Li3C tetrahedra. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Li(3), one Li(5), one Mn(2), and one P(2) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one Li(1), one Li(3), one Li(4), one Mn(2), and one C(2) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Li(1), one Mn(2), and one C(2) atom. In the fourteenth O site, O(14) is bonded to one Li(3), one Li(4), one Li(5), and one C(1) atom to form a mixture of corner and edge-sharing OLi3C tetrahedra. is represented by the CIF card [CIF]
data_NaLi5Mn2P2(CO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.672
_cell_length_b   8.644
_cell_length_c   9.995
_cell_angle_alpha   87.645
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   575.983
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.249  0.247  0.628  1.0
  Na  Na1  1  0.751  0.247  0.128  1.0
  Li  Li2  1  0.507  0.085  0.872  1.0
  Li  Li3  1  0.493  0.085  0.372  1.0
  Li  Li4  1  0.723  0.271  0.616  1.0
  Li  Li5  1  0.277  0.271  0.116  1.0
  Li  Li6  1  0.777  0.734  0.885  1.0
  Li  Li7  1  0.224  0.736  0.884  1.0
  Li  Li8  1  0.776  0.736  0.384  1.0
  Li  Li9  1  0.223  0.734  0.385  1.0
  Li  Li10  1  0.988  0.911  0.628  1.0
  Li  Li11  1  0.012  0.911  0.128  1.0
  Mn  Mn12  1  0.003  0.355  0.887  1.0
  Mn  Mn13  1  0.997  0.355  0.387  1.0
  Mn  Mn14  1  0.498  0.650  0.611  1.0
  Mn  Mn15  1  0.502  0.650  0.111  1.0
  P  P16  1  0.505  0.410  0.852  1.0
  P  P17  1  0.495  0.410  0.352  1.0
  P  P18  1  0.994  0.595  0.642  1.0
  P  P19  1  0.006  0.595  0.142  1.0
  C  C20  1  0.998  0.038  0.865  1.0
  C  C21  1  0.002  0.038  0.365  1.0
  C  C22  1  0.510  0.958  0.640  1.0
  C  C23  1  0.490  0.958  0.140  1.0
  O  O24  1  0.535  0.101  0.672  1.0
  O  O25  1  0.465  0.101  0.172  1.0
  O  O26  1  0.996  0.079  0.989  1.0
  O  O27  1  0.004  0.079  0.489  1.0
  O  O28  1  0.001  0.144  0.769  1.0
  O  O29  1  0.999  0.144  0.269  1.0
  O  O30  1  0.320  0.310  0.898  1.0
  O  O31  1  0.689  0.315  0.904  1.0
  O  O32  1  0.311  0.315  0.404  1.0
  O  O33  1  0.680  0.310  0.398  1.0
  O  O34  1  0.514  0.423  0.696  1.0
  O  O35  1  0.979  0.427  0.594  1.0
  O  O36  1  0.486  0.423  0.196  1.0
  O  O37  1  0.021  0.427  0.094  1.0
  O  O38  1  0.498  0.577  0.903  1.0
  O  O39  1  0.999  0.584  0.799  1.0
  O  O40  1  0.502  0.577  0.403  1.0
  O  O41  1  0.001  0.584  0.299  1.0
  O  O42  1  0.815  0.698  0.593  1.0
  O  O43  1  0.181  0.683  0.588  1.0
  O  O44  1  0.819  0.683  0.088  1.0
  O  O45  1  0.185  0.698  0.093  1.0
  O  O46  1  0.494  0.852  0.735  1.0
  O  O47  1  0.506  0.852  0.235  1.0
  O  O48  1  0.499  0.921  0.515  1.0
  O  O49  1  0.501  0.921  0.015  1.0
  O  O50  1  0.999  0.894  0.835  1.0
  O  O51  1  0.001  0.894  0.335  1.0
[/CIF]
.