The structure described by Li6V3Sb3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form distorted LiO6 octahedra that share corners with two equivalent V(1)O6 octahedra; corners with two equivalent V(3)O6 octahedra; corners with two equivalent Sb(3)O6 octahedra; corners with three equivalent Li(6)O4 tetrahedra;  an edgeedge with one V(2)O6 octahedra; and edges with two equivalent Sb(1,2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. In the second Li site, Li(2) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra; corners with two equivalent V(1)O6 octahedra; corners with two equivalent V(3)O6 octahedra; corners with two equivalent Sb(1,2)O6 octahedra; corners with two equivalent Sb(3)O6 octahedra; and corners with three equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-70°. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the fifth Li site, Li(5) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form distorted LiO6 octahedra that share corners with two equivalent V(2)O6 octahedra; corners with four equivalent Sb(1,2)O6 octahedra; corners with three equivalent Li(2)O4 tetrahedra;  an edgeedge with one V(1)O6 octahedra;  an edgeedge with one V(3)O6 octahedra; and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. In the sixth Li site, Li(6) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra;  a cornercorner with one V(3)O6 octahedra;  a cornercorner with one Sb(3)O6 octahedra; corners with two equivalent V(2)O6 octahedra; corners with three equivalent Li(1)O6 octahedra; and corners with four equivalent Sb(1,2)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-68°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra,  a cornercorner with one Li(6)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra,  an edgeedge with one Li(5)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-57°. In the second V site, V(2) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Li(5)O6 octahedra;  a cornercorner with one Li(2)O4 tetrahedra; corners with two equivalent Li(6)O4 tetrahedra;  an edgeedge with one Li(1)O6 octahedra; and edges with four equivalent Sb(1,2)O6 octahedra. The corner-sharing octahedral tilt angles are 55°. In the third V site, V(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra,  a cornercorner with one Li(6)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra,  an edgeedge with one Li(5)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. There are two inequivalent Sb sites. In the first Sb site, Sb(1,2) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Li(5)O6 octahedra;  a cornercorner with one Li(2)O4 tetrahedra; corners with two equivalent Li(6)O4 tetrahedra;  an edgeedge with one Li(1)O6 octahedra; edges with two equivalent V(2)O6 octahedra; and edges with two equivalent Sb(1,2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. In the second Sb site, Sb(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with two equivalent Li(1)O6 octahedra,  a cornercorner with one Li(6)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra,  an edgeedge with one Li(5)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles are 56°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(4), one V(1), and one Sb(3) atom. In the second O site, O(2) is bonded to one Li(1); one Li(6); and two equivalent Sb(1,2) atoms to form distorted OLi2Sb2 tetrahedra that share  a cornercorner with one O(7)Li2VSb tetrahedra,  a cornercorner with one O(8)Li2VSb tetrahedra,  a cornercorner with one O(10)Li2V2 trigonal pyramid,  a cornercorner with one O(14)Li2VSb trigonal pyramid,  a cornercorner with one O(16)Li2VSb trigonal pyramid,  a cornercorner with one O(13)LiV2Sb trigonal pyramid,  an edgeedge with one O(7)Li2VSb tetrahedra, and  an edgeedge with one O(8)Li2VSb tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(2); one V(2); and two equivalent Sb(1,2) atoms. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Li(4); one V(2); and two equivalent Sb(1,2) atoms. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(1), one V(3), and one Sb(3) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(4), one V(3), and one Sb(3) atom. In the seventh O site, O(7) is bonded to one Li(1); one Li(6); one V(2); and one Sb(1,2) atom to form distorted OLi2VSb tetrahedra that share  a cornercorner with one O(2)Li2Sb2 tetrahedra,  a cornercorner with one O(8)Li2VSb tetrahedra,  a cornercorner with one O(10)Li2V2 trigonal pyramid,  a cornercorner with one O(16)Li2VSb trigonal pyramid,  a cornercorner with one O(13)LiV2Sb trigonal pyramid, corners with two equivalent O(14)Li2VSb trigonal pyramids,  an edgeedge with one O(2)Li2Sb2 tetrahedra, and  an edgeedge with one O(8)Li2VSb tetrahedra. In the eighth O site, O(8) is bonded to one Li(1); one Li(6); one V(2); and one Sb(1,2) atom to form distorted OLi2VSb tetrahedra that share  a cornercorner with one O(2)Li2Sb2 tetrahedra,  a cornercorner with one O(7)Li2VSb tetrahedra,  a cornercorner with one O(10)Li2V2 trigonal pyramid,  a cornercorner with one O(14)Li2VSb trigonal pyramid,  a cornercorner with one O(13)LiV2Sb trigonal pyramid, corners with two equivalent O(16)Li2VSb trigonal pyramids,  an edgeedge with one O(2)Li2Sb2 tetrahedra, and  an edgeedge with one O(7)Li2VSb tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(3); one Li(5); and two equivalent Sb(1,2) atoms. In the tenth O site, O(10) is bonded to one Li(1), one Li(4), one V(1), and one V(3) atom to form distorted OLi2V2 trigonal pyramids that share  a cornercorner with one O(2)Li2Sb2 tetrahedra,  a cornercorner with one O(11)Li2VSb tetrahedra,  a cornercorner with one O(12)Li2VSb tetrahedra,  a cornercorner with one O(7)Li2VSb tetrahedra,  a cornercorner with one O(8)Li2VSb tetrahedra, corners with two equivalent O(15)Li2V2 tetrahedra, and corners with two equivalent O(13)LiV2Sb trigonal pyramids. In the eleventh O site, O(11) is bonded to one Li(2), one Li(5), one V(1), and one Sb(3) atom to form distorted OLi2VSb tetrahedra that share  a cornercorner with one O(15)Li2V2 tetrahedra,  a cornercorner with one O(12)Li2VSb tetrahedra,  a cornercorner with one O(10)Li2V2 trigonal pyramid,  a cornercorner with one O(14)Li2VSb trigonal pyramid,  a cornercorner with one O(16)Li2VSb trigonal pyramid,  an edgeedge with one O(15)Li2V2 tetrahedra,  an edgeedge with one O(12)Li2VSb tetrahedra, and  an edgeedge with one O(13)LiV2Sb trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(2), one Li(5), one V(3), and one Sb(3) atom to form distorted OLi2VSb tetrahedra that share  a cornercorner with one O(15)Li2V2 tetrahedra,  a cornercorner with one O(11)Li2VSb tetrahedra,  a cornercorner with one O(10)Li2V2 trigonal pyramid,  a cornercorner with one O(14)Li2VSb trigonal pyramid,  a cornercorner with one O(16)Li2VSb trigonal pyramid,  an edgeedge with one O(15)Li2V2 tetrahedra,  an edgeedge with one O(11)Li2VSb tetrahedra, and  an edgeedge with one O(13)LiV2Sb trigonal pyramid. In the thirteenth O site, O(13) is bonded to one Li(6), one V(1), one V(3), and one Sb(3) atom to form distorted OLiV2Sb trigonal pyramids that share  a cornercorner with one O(2)Li2Sb2 tetrahedra,  a cornercorner with one O(7)Li2VSb tetrahedra,  a cornercorner with one O(8)Li2VSb tetrahedra, corners with two equivalent O(10)Li2V2 trigonal pyramids,  an edgeedge with one O(15)Li2V2 tetrahedra,  an edgeedge with one O(11)Li2VSb tetrahedra, and  an edgeedge with one O(12)Li2VSb tetrahedra. In the fourteenth O site, O(14) is bonded to one Li(3); one Li(5); one V(2); and one Sb(1,2) atom to form distorted OLi2VSb trigonal pyramids that share  a cornercorner with one O(2)Li2Sb2 tetrahedra,  a cornercorner with one O(15)Li2V2 tetrahedra,  a cornercorner with one O(11)Li2VSb tetrahedra,  a cornercorner with one O(12)Li2VSb tetrahedra,  a cornercorner with one O(8)Li2VSb tetrahedra, corners with two equivalent O(7)Li2VSb tetrahedra,  a cornercorner with one O(16)Li2VSb trigonal pyramid, and  an edgeedge with one O(16)Li2VSb trigonal pyramid. In the fifteenth O site, O(15) is bonded to one Li(2), one Li(5), one V(1), and one V(3) atom to form distorted OLi2V2 tetrahedra that share  a cornercorner with one O(11)Li2VSb tetrahedra,  a cornercorner with one O(12)Li2VSb tetrahedra,  a cornercorner with one O(14)Li2VSb trigonal pyramid,  a cornercorner with one O(16)Li2VSb trigonal pyramid, corners with two equivalent O(10)Li2V2 trigonal pyramids,  an edgeedge with one O(11)Li2VSb tetrahedra,  an edgeedge with one O(12)Li2VSb tetrahedra, and  an edgeedge with one O(13)LiV2Sb trigonal pyramid. In the sixteenth O site, O(16) is bonded to one Li(3); one Li(5); one V(2); and one Sb(1,2) atom to form distorted OLi2VSb trigonal pyramids that share  a cornercorner with one O(2)Li2Sb2 tetrahedra,  a cornercorner with one O(15)Li2V2 tetrahedra,  a cornercorner with one O(11)Li2VSb tetrahedra,  a cornercorner with one O(12)Li2VSb tetrahedra,  a cornercorner with one O(7)Li2VSb tetrahedra, corners with two equivalent O(8)Li2VSb tetrahedra,  a cornercorner with one O(14)Li2VSb trigonal pyramid, and  an edgeedge with one O(14)Li2VSb trigonal pyramid. is represented by the CIF file [CIF]
data_Li6V3Sb3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.059
_cell_length_b   6.120
_cell_length_c   10.074
_cell_angle_alpha   90.336
_cell_angle_beta   89.991
_cell_angle_gamma   119.641
_symmetry_Int_Tables_number   1
_cell_volume   324.637
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.664  0.328  0.507  1.0
  Li  Li1  1  0.668  0.337  0.879  1.0
  Li  Li2  1  0.988  0.976  0.997  1.0
  Li  Li3  1  0.995  0.990  0.503  1.0
  Li  Li4  1  0.337  0.675  0.003  1.0
  Li  Li5  1  0.329  0.659  0.388  1.0
  V  V6  1  0.177  0.839  0.718  1.0
  V  V7  1  0.833  0.665  0.217  1.0
  V  V8  1  0.669  0.831  0.713  1.0
  Sb  Sb9  1  0.336  0.169  0.215  1.0
  Sb  Sb10  1  0.833  0.169  0.215  1.0
  Sb  Sb11  1  0.169  0.340  0.715  1.0
  O  O12  1  0.305  0.151  0.609  1.0
  O  O13  1  0.514  0.027  0.328  1.0
  O  O14  1  0.662  0.325  0.101  1.0
  O  O15  1  0.005  0.009  0.323  1.0
  O  O16  1  0.002  0.005  0.818  1.0
  O  O17  1  0.845  0.152  0.610  1.0
  O  O18  1  0.509  0.482  0.322  1.0
  O  O19  1  0.973  0.482  0.322  1.0
  O  O20  1  0.152  0.303  0.102  1.0
  O  O21  1  0.849  0.704  0.619  1.0
  O  O22  1  0.030  0.521  0.822  1.0
  O  O23  1  0.490  0.521  0.822  1.0
  O  O24  1  0.333  0.667  0.605  1.0
  O  O25  1  0.159  0.852  0.110  1.0
  O  O26  1  0.481  0.966  0.812  1.0
  O  O27  1  0.693  0.852  0.110  1.0
[/CIF]
.
The structure described by Li6V3Sb3O16 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form distorted LiO6 octahedra that share corners with two equivalent V(1)O6 octahedra; corners with two equivalent V(3)O6 octahedra; corners with two equivalent Sb(3)O6 octahedra; corners with three equivalent Li(6)O4 tetrahedra;  an edgeedge with one V(2)O6 octahedra; and edges with two equivalent Sb(1,2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-57°. In the second Li site, Li(2) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra; corners with two equivalent V(1)O6 octahedra; corners with two equivalent V(3)O6 octahedra; corners with two equivalent Sb(1,2)O6 octahedra; corners with two equivalent Sb(3)O6 octahedra; and corners with three equivalent Li(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-70°. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(5), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the fifth Li site, Li(5) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form distorted LiO6 octahedra that share corners with two equivalent V(2)O6 octahedra; corners with four equivalent Sb(1,2)O6 octahedra; corners with three equivalent Li(2)O4 tetrahedra;  an edgeedge with one V(1)O6 octahedra;  an edgeedge with one V(3)O6 octahedra; and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. In the sixth Li site, Li(6) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra;  a cornercorner with one V(3)O6 octahedra;  a cornercorner with one Sb(3)O6 octahedra; corners with two equivalent V(2)O6 octahedra; corners with three equivalent Li(1)O6 octahedra; and corners with four equivalent Sb(1,2)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-68°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra,  a cornercorner with one Li(6)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra,  an edgeedge with one Li(5)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-57°. In the second V site, V(2) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Li(5)O6 octahedra;  a cornercorner with one Li(2)O4 tetrahedra; corners with two equivalent Li(6)O4 tetrahedra;  an edgeedge with one Li(1)O6 octahedra; and edges with four equivalent Sb(1,2)O6 octahedra. The corner-sharing octahedral tilt angles are 55°. In the third V site, V(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Li(1)O6 octahedra,  a cornercorner with one Li(6)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra,  an edgeedge with one Li(5)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-56°. There are two inequivalent Sb sites. In the first Sb site, Sb(1,2) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Li(5)O6 octahedra;  a cornercorner with one Li(2)O4 tetrahedra; corners with two equivalent Li(6)O4 tetrahedra;  an edgeedge with one Li(1)O6 octahedra; edges with two equivalent V(2)O6 octahedra; and edges with two equivalent Sb(1,2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. In the second Sb site, Sb(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form SbO6 octahedra that share corners with two equivalent Li(1)O6 octahedra,  a cornercorner with one Li(6)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra,  an edgeedge with one Li(5)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles are 56°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(4), one V(1), and one Sb(3) atom. In the second O site, O(2) is bonded to one Li(1); one Li(6); and two equivalent Sb(1,2) atoms to form distorted OLi2Sb2 tetrahedra that share  a cornercorner with one O(7)Li2VSb tetrahedra,  a cornercorner with one O(8)Li2VSb tetrahedra,  a cornercorner with one O(10)Li2V2 trigonal pyramid,  a cornercorner with one O(14)Li2VSb trigonal pyramid,  a cornercorner with one O(16)Li2VSb trigonal pyramid,  a cornercorner with one O(13)LiV2Sb trigonal pyramid,  an edgeedge with one O(7)Li2VSb tetrahedra, and  an edgeedge with one O(8)Li2VSb tetrahedra. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(2); one V(2); and two equivalent Sb(1,2) atoms. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Li(4); one V(2); and two equivalent Sb(1,2) atoms. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(1), one V(3), and one Sb(3) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Li(4), one V(3), and one Sb(3) atom. In the seventh O site, O(7) is bonded to one Li(1); one Li(6); one V(2); and one Sb(1,2) atom to form distorted OLi2VSb tetrahedra that share  a cornercorner with one O(2)Li2Sb2 tetrahedra,  a cornercorner with one O(8)Li2VSb tetrahedra,  a cornercorner with one O(10)Li2V2 trigonal pyramid,  a cornercorner with one O(16)Li2VSb trigonal pyramid,  a cornercorner with one O(13)LiV2Sb trigonal pyramid, corners with two equivalent O(14)Li2VSb trigonal pyramids,  an edgeedge with one O(2)Li2Sb2 tetrahedra, and  an edgeedge with one O(8)Li2VSb tetrahedra. In the eighth O site, O(8) is bonded to one Li(1); one Li(6); one V(2); and one Sb(1,2) atom to form distorted OLi2VSb tetrahedra that share  a cornercorner with one O(2)Li2Sb2 tetrahedra,  a cornercorner with one O(7)Li2VSb tetrahedra,  a cornercorner with one O(10)Li2V2 trigonal pyramid,  a cornercorner with one O(14)Li2VSb trigonal pyramid,  a cornercorner with one O(13)LiV2Sb trigonal pyramid, corners with two equivalent O(16)Li2VSb trigonal pyramids,  an edgeedge with one O(2)Li2Sb2 tetrahedra, and  an edgeedge with one O(7)Li2VSb tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(3); one Li(5); and two equivalent Sb(1,2) atoms. In the tenth O site, O(10) is bonded to one Li(1), one Li(4), one V(1), and one V(3) atom to form distorted OLi2V2 trigonal pyramids that share  a cornercorner with one O(2)Li2Sb2 tetrahedra,  a cornercorner with one O(11)Li2VSb tetrahedra,  a cornercorner with one O(12)Li2VSb tetrahedra,  a cornercorner with one O(7)Li2VSb tetrahedra,  a cornercorner with one O(8)Li2VSb tetrahedra, corners with two equivalent O(15)Li2V2 tetrahedra, and corners with two equivalent O(13)LiV2Sb trigonal pyramids. In the eleventh O site, O(11) is bonded to one Li(2), one Li(5), one V(1), and one Sb(3) atom to form distorted OLi2VSb tetrahedra that share  a cornercorner with one O(15)Li2V2 tetrahedra,  a cornercorner with one O(12)Li2VSb tetrahedra,  a cornercorner with one O(10)Li2V2 trigonal pyramid,  a cornercorner with one O(14)Li2VSb trigonal pyramid,  a cornercorner with one O(16)Li2VSb trigonal pyramid,  an edgeedge with one O(15)Li2V2 tetrahedra,  an edgeedge with one O(12)Li2VSb tetrahedra, and  an edgeedge with one O(13)LiV2Sb trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(2), one Li(5), one V(3), and one Sb(3) atom to form distorted OLi2VSb tetrahedra that share  a cornercorner with one O(15)Li2V2 tetrahedra,  a cornercorner with one O(11)Li2VSb tetrahedra,  a cornercorner with one O(10)Li2V2 trigonal pyramid,  a cornercorner with one O(14)Li2VSb trigonal pyramid,  a cornercorner with one O(16)Li2VSb trigonal pyramid,  an edgeedge with one O(15)Li2V2 tetrahedra,  an edgeedge with one O(11)Li2VSb tetrahedra, and  an edgeedge with one O(13)LiV2Sb trigonal pyramid. In the thirteenth O site, O(13) is bonded to one Li(6), one V(1), one V(3), and one Sb(3) atom to form distorted OLiV2Sb trigonal pyramids that share  a cornercorner with one O(2)Li2Sb2 tetrahedra,  a cornercorner with one O(7)Li2VSb tetrahedra,  a cornercorner with one O(8)Li2VSb tetrahedra, corners with two equivalent O(10)Li2V2 trigonal pyramids,  an edgeedge with one O(15)Li2V2 tetrahedra,  an edgeedge with one O(11)Li2VSb tetrahedra, and  an edgeedge with one O(12)Li2VSb tetrahedra. In the fourteenth O site, O(14) is bonded to one Li(3); one Li(5); one V(2); and one Sb(1,2) atom to form distorted OLi2VSb trigonal pyramids that share  a cornercorner with one O(2)Li2Sb2 tetrahedra,  a cornercorner with one O(15)Li2V2 tetrahedra,  a cornercorner with one O(11)Li2VSb tetrahedra,  a cornercorner with one O(12)Li2VSb tetrahedra,  a cornercorner with one O(8)Li2VSb tetrahedra, corners with two equivalent O(7)Li2VSb tetrahedra,  a cornercorner with one O(16)Li2VSb trigonal pyramid, and  an edgeedge with one O(16)Li2VSb trigonal pyramid. In the fifteenth O site, O(15) is bonded to one Li(2), one Li(5), one V(1), and one V(3) atom to form distorted OLi2V2 tetrahedra that share  a cornercorner with one O(11)Li2VSb tetrahedra,  a cornercorner with one O(12)Li2VSb tetrahedra,  a cornercorner with one O(14)Li2VSb trigonal pyramid,  a cornercorner with one O(16)Li2VSb trigonal pyramid, corners with two equivalent O(10)Li2V2 trigonal pyramids,  an edgeedge with one O(11)Li2VSb tetrahedra,  an edgeedge with one O(12)Li2VSb tetrahedra, and  an edgeedge with one O(13)LiV2Sb trigonal pyramid. In the sixteenth O site, O(16) is bonded to one Li(3); one Li(5); one V(2); and one Sb(1,2) atom to form distorted OLi2VSb trigonal pyramids that share  a cornercorner with one O(2)Li2Sb2 tetrahedra,  a cornercorner with one O(15)Li2V2 tetrahedra,  a cornercorner with one O(11)Li2VSb tetrahedra,  a cornercorner with one O(12)Li2VSb tetrahedra,  a cornercorner with one O(7)Li2VSb tetrahedra, corners with two equivalent O(8)Li2VSb tetrahedra,  a cornercorner with one O(14)Li2VSb trigonal pyramid, and  an edgeedge with one O(14)Li2VSb trigonal pyramid. is represented by the CIF file [CIF]
data_Li6V3Sb3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.059
_cell_length_b   6.120
_cell_length_c   10.074
_cell_angle_alpha   90.336
_cell_angle_beta   89.991
_cell_angle_gamma   119.641
_symmetry_Int_Tables_number   1
_cell_volume   324.637
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.664  0.328  0.507  1.0
  Li  Li1  1  0.668  0.337  0.879  1.0
  Li  Li2  1  0.988  0.976  0.997  1.0
  Li  Li3  1  0.995  0.990  0.503  1.0
  Li  Li4  1  0.337  0.675  0.003  1.0
  Li  Li5  1  0.329  0.659  0.388  1.0
  V  V6  1  0.177  0.839  0.718  1.0
  V  V7  1  0.833  0.665  0.217  1.0
  V  V8  1  0.669  0.831  0.713  1.0
  Sb  Sb9  1  0.336  0.169  0.215  1.0
  Sb  Sb10  1  0.833  0.169  0.215  1.0
  Sb  Sb11  1  0.169  0.340  0.715  1.0
  O  O12  1  0.305  0.151  0.609  1.0
  O  O13  1  0.514  0.027  0.328  1.0
  O  O14  1  0.662  0.325  0.101  1.0
  O  O15  1  0.005  0.009  0.323  1.0
  O  O16  1  0.002  0.005  0.818  1.0
  O  O17  1  0.845  0.152  0.610  1.0
  O  O18  1  0.509  0.482  0.322  1.0
  O  O19  1  0.973  0.482  0.322  1.0
  O  O20  1  0.152  0.303  0.102  1.0
  O  O21  1  0.849  0.704  0.619  1.0
  O  O22  1  0.030  0.521  0.822  1.0
  O  O23  1  0.490  0.521  0.822  1.0
  O  O24  1  0.333  0.667  0.605  1.0
  O  O25  1  0.159  0.852  0.110  1.0
  O  O26  1  0.481  0.966  0.812  1.0
  O  O27  1  0.693  0.852  0.110  1.0
[/CIF]
.