The structure described by CsAu(O3I)4 crystallizes in the monoclinic C2 space group. Cs(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(6), and four equivalent O(4) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Au(1), and one I(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cs(1), one I(1), and one I(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cs(1) and one I(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one I(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one I(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cs(1), one Au(1), and one I(2) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. In the second I site, I(2) is bonded in a 4-coordinate geometry to one O(2), one O(4), one O(5), and one O(6) atom. is represented by the CIF file [CIF]
data_CsAu(IO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.878
_cell_length_b   7.668
_cell_length_c   8.689
_cell_angle_alpha   107.525
_cell_angle_beta   90.000
_cell_angle_gamma   112.537
_symmetry_Int_Tables_number   1
_cell_volume   342.012
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.041  0.000  0.000  1.0
  Au  Au1  1  0.236  0.000  0.500  1.0
  I  I2  1  0.286  0.640  0.169  1.0
  I  I3  1  0.646  0.360  0.831  1.0
  I  I4  1  0.676  0.302  0.349  1.0
  I  I5  1  0.374  0.698  0.651  1.0
  O  O6  1  0.119  0.807  0.272  1.0
  O  O7  1  0.312  0.193  0.728  1.0
  O  O8  1  0.082  0.414  0.208  1.0
  O  O9  1  0.668  0.586  0.792  1.0
  O  O10  1  0.143  0.597  0.968  1.0
  O  O11  1  0.546  0.403  0.032  1.0
  O  O12  1  0.624  0.062  0.202  1.0
  O  O13  1  0.562  0.938  0.798  1.0
  O  O14  1  0.834  0.300  0.528  1.0
  O  O15  1  0.535  0.700  0.472  1.0
  O  O16  1  0.348  0.235  0.415  1.0
  O  O17  1  0.113  0.765  0.585  1.0
[/CIF]
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The structure described by CsAu(O3I)4 crystallizes in the monoclinic C2 space group. Cs(1) is bonded in a 12-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(6), and four equivalent O(4) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Au(1), and one I(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cs(1), one I(1), and one I(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cs(1) and one I(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one I(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one I(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cs(1), one Au(1), and one I(2) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. In the second I site, I(2) is bonded in a 4-coordinate geometry to one O(2), one O(4), one O(5), and one O(6) atom. is represented by the CIF file [CIF]
data_CsAu(IO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.878
_cell_length_b   7.668
_cell_length_c   8.689
_cell_angle_alpha   107.525
_cell_angle_beta   90.000
_cell_angle_gamma   112.537
_symmetry_Int_Tables_number   1
_cell_volume   342.012
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.041  0.000  0.000  1.0
  Au  Au1  1  0.236  0.000  0.500  1.0
  I  I2  1  0.286  0.640  0.169  1.0
  I  I3  1  0.646  0.360  0.831  1.0
  I  I4  1  0.676  0.302  0.349  1.0
  I  I5  1  0.374  0.698  0.651  1.0
  O  O6  1  0.119  0.807  0.272  1.0
  O  O7  1  0.312  0.193  0.728  1.0
  O  O8  1  0.082  0.414  0.208  1.0
  O  O9  1  0.668  0.586  0.792  1.0
  O  O10  1  0.143  0.597  0.968  1.0
  O  O11  1  0.546  0.403  0.032  1.0
  O  O12  1  0.624  0.062  0.202  1.0
  O  O13  1  0.562  0.938  0.798  1.0
  O  O14  1  0.834  0.300  0.528  1.0
  O  O15  1  0.535  0.700  0.472  1.0
  O  O16  1  0.348  0.235  0.415  1.0
  O  O17  1  0.113  0.765  0.585  1.0
[/CIF]
.