The crystal structure described by WSeS2Cl5 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four WSeS2Cl5 clusters. W(1) is bonded in a 8-coordinate geometry to one Se(1), two equivalent S(1), two equivalent S(2), one Cl(3), one Cl(4), and one Cl(5) atom. Se(1) is bonded in a 5-coordinate geometry to one W(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent W(1) and one S(2) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to two equivalent W(1) and one S(1) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(3) is bonded in a 2-coordinate geometry to one W(1) and one Se(1) atom. In the fourth Cl site, Cl(4) is bonded in a 2-coordinate geometry to one W(1) and one Se(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_WSeS2Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.195
_cell_length_b   10.195
_cell_length_c   14.460
_cell_angle_alpha   65.905
_cell_angle_beta   65.905
_cell_angle_gamma   57.141
_symmetry_Int_Tables_number   1
_cell_volume   1117.717
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.237  0.615  0.739  1.0
  W  W1  1  0.385  0.763  0.761  1.0
  W  W2  1  0.763  0.385  0.261  1.0
  W  W3  1  0.615  0.237  0.239  1.0
  Se  Se4  1  0.920  0.778  0.739  1.0
  Se  Se5  1  0.778  0.920  0.239  1.0
  Se  Se6  1  0.080  0.222  0.261  1.0
  Se  Se7  1  0.222  0.080  0.761  1.0
  S  S8  1  0.541  0.336  0.391  1.0
  S  S9  1  0.664  0.459  0.109  1.0
  S  S10  1  0.754  0.135  0.376  1.0
  S  S11  1  0.865  0.246  0.124  1.0
  S  S12  1  0.135  0.754  0.876  1.0
  S  S13  1  0.246  0.865  0.624  1.0
  S  S14  1  0.336  0.541  0.891  1.0
  S  S15  1  0.459  0.664  0.609  1.0
  Cl  Cl16  1  0.864  0.025  0.633  1.0
  Cl  Cl17  1  0.864  0.767  0.385  1.0
  Cl  Cl18  1  0.483  0.064  0.353  1.0
  Cl  Cl19  1  0.767  0.864  0.885  1.0
  Cl  Cl20  1  0.136  0.233  0.615  1.0
  Cl  Cl21  1  0.380  0.838  0.905  1.0
  Cl  Cl22  1  0.655  0.565  0.771  1.0
  Cl  Cl23  1  0.233  0.136  0.115  1.0
  Cl  Cl24  1  0.517  0.936  0.647  1.0
  Cl  Cl25  1  0.838  0.380  0.405  1.0
  Cl  Cl26  1  0.136  0.975  0.367  1.0
  Cl  Cl27  1  0.025  0.864  0.133  1.0
  Cl  Cl28  1  0.936  0.517  0.147  1.0
  Cl  Cl29  1  0.620  0.162  0.095  1.0
  Cl  Cl30  1  0.162  0.620  0.595  1.0
  Cl  Cl31  1  0.064  0.483  0.853  1.0
  Cl  Cl32  1  0.975  0.136  0.867  1.0
  Cl  Cl33  1  0.435  0.345  0.729  1.0
  Cl  Cl34  1  0.345  0.435  0.229  1.0
  Cl  Cl35  1  0.565  0.655  0.271  1.0
[/CIF]
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The crystal structure described by WSeS2Cl5 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four WSeS2Cl5 clusters. W(1) is bonded in a 8-coordinate geometry to one Se(1), two equivalent S(1), two equivalent S(2), one Cl(3), one Cl(4), and one Cl(5) atom. Se(1) is bonded in a 5-coordinate geometry to one W(1), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent W(1) and one S(2) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to two equivalent W(1) and one S(1) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(3) is bonded in a 2-coordinate geometry to one W(1) and one Se(1) atom. In the fourth Cl site, Cl(4) is bonded in a 2-coordinate geometry to one W(1) and one Se(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_WSeS2Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.195
_cell_length_b   10.195
_cell_length_c   14.460
_cell_angle_alpha   65.905
_cell_angle_beta   65.905
_cell_angle_gamma   57.141
_symmetry_Int_Tables_number   1
_cell_volume   1117.717
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.237  0.615  0.739  1.0
  W  W1  1  0.385  0.763  0.761  1.0
  W  W2  1  0.763  0.385  0.261  1.0
  W  W3  1  0.615  0.237  0.239  1.0
  Se  Se4  1  0.920  0.778  0.739  1.0
  Se  Se5  1  0.778  0.920  0.239  1.0
  Se  Se6  1  0.080  0.222  0.261  1.0
  Se  Se7  1  0.222  0.080  0.761  1.0
  S  S8  1  0.541  0.336  0.391  1.0
  S  S9  1  0.664  0.459  0.109  1.0
  S  S10  1  0.754  0.135  0.376  1.0
  S  S11  1  0.865  0.246  0.124  1.0
  S  S12  1  0.135  0.754  0.876  1.0
  S  S13  1  0.246  0.865  0.624  1.0
  S  S14  1  0.336  0.541  0.891  1.0
  S  S15  1  0.459  0.664  0.609  1.0
  Cl  Cl16  1  0.864  0.025  0.633  1.0
  Cl  Cl17  1  0.864  0.767  0.385  1.0
  Cl  Cl18  1  0.483  0.064  0.353  1.0
  Cl  Cl19  1  0.767  0.864  0.885  1.0
  Cl  Cl20  1  0.136  0.233  0.615  1.0
  Cl  Cl21  1  0.380  0.838  0.905  1.0
  Cl  Cl22  1  0.655  0.565  0.771  1.0
  Cl  Cl23  1  0.233  0.136  0.115  1.0
  Cl  Cl24  1  0.517  0.936  0.647  1.0
  Cl  Cl25  1  0.838  0.380  0.405  1.0
  Cl  Cl26  1  0.136  0.975  0.367  1.0
  Cl  Cl27  1  0.025  0.864  0.133  1.0
  Cl  Cl28  1  0.936  0.517  0.147  1.0
  Cl  Cl29  1  0.620  0.162  0.095  1.0
  Cl  Cl30  1  0.162  0.620  0.595  1.0
  Cl  Cl31  1  0.064  0.483  0.853  1.0
  Cl  Cl32  1  0.975  0.136  0.867  1.0
  Cl  Cl33  1  0.435  0.345  0.729  1.0
  Cl  Cl34  1  0.345  0.435  0.229  1.0
  Cl  Cl35  1  0.565  0.655  0.271  1.0
[/CIF]
.