The material structure described by V3Cu4CdTlO13 crystallizes in the monoclinic P2_1/m space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(6), one O(7), and two equivalent O(8) atoms to form VO4 tetrahedra that share corners with three equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-76°. In the second V site, V(2) is bonded to one O(3), one O(9), and two equivalent O(10) atoms to form VO4 tetrahedra that share  a cornercorner with one Cd(1)O6 octahedra,  a cornercorner with one Cu(2)O5 trigonal bipyramid, and corners with three equivalent Cu(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 51°. In the third V site, V(3) is bonded to one O(1), one O(2), and two equivalent O(4) atoms to form VO4 tetrahedra that share corners with two equivalent Cd(1)O6 octahedra,  a cornercorner with one Cu(3)O5 trigonal bipyramid, and corners with three equivalent Cu(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 36°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(4), one O(5), and one O(7) atom. In the second Cu site, Cu(2) is bonded to one O(2), one O(3), one O(5), and two equivalent O(4) atoms to form CuO5 trigonal bipyramids that share  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent V(3)O4 tetrahedra,  an edgeedge with one Cd(1)O6 octahedra, and  an edgeedge with one Cu(3)O5 trigonal bipyramid. In the third Cu site, Cu(3) is bonded to one O(1), one O(3), one O(5), and two equivalent O(10) atoms to form distorted CuO5 trigonal bipyramids that share  a cornercorner with one V(3)O4 tetrahedra, corners with three equivalent V(2)O4 tetrahedra, and  an edgeedge with one Cu(2)O5 trigonal bipyramid. Cd(1) is bonded to one O(7), one O(9), two equivalent O(4), and two equivalent O(8) atoms to form CdO6 octahedra that share  a cornercorner with one V(2)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, corners with three equivalent V(1)O4 tetrahedra, and  an edgeedge with one Cu(2)O5 trigonal bipyramid. Tl(1) is bonded in a 5-coordinate geometry to one O(9) and four equivalent O(8) atoms. There are ten inequivalent O sites. In the first O site, O(7) is bonded to one V(1), two equivalent Cu(1), and one Cd(1) atom to form distorted corner-sharing OVCdCu2 trigonal pyramids. In the second O site, O(8) is bonded in a 2-coordinate geometry to one V(1), one Cd(1), and two equivalent Tl(1) atoms. In the third O site, O(9) is bonded in a distorted bent 120 degrees geometry to one V(2), one Cd(1), and one Tl(1) atom. In the fourth O site, O(10) is bonded in a distorted trigonal planar geometry to one V(2), one Cu(1), and one Cu(3) atom. In the fifth O site, O(1) is bonded in a linear geometry to one V(3) and one Cu(3) atom. In the sixth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one V(3) and one Cu(2) atom. In the seventh O site, O(3) is bonded in a distorted trigonal planar geometry to one V(2), one Cu(2), and one Cu(3) atom. In the eighth O site, O(4) is bonded in a 4-coordinate geometry to one V(3), one Cu(1), one Cu(2), and one Cd(1) atom. In the ninth O site, O(5) is bonded to one Cu(2), one Cu(3), and two equivalent Cu(1) atoms to form distorted corner-sharing OCu4 trigonal pyramids. In the tenth O site, O(6) is bonded in a distorted single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_TlV3CdCu4O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.372
_cell_length_b   8.474
_cell_length_c   10.953
_cell_angle_alpha   82.798
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   586.750
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.250  0.510  0.102  1.0
  Tl  Tl1  1  0.750  0.490  0.898  1.0
  V  V2  1  0.250  0.139  0.992  1.0
  V  V3  1  0.750  0.861  0.008  1.0
  V  V4  1  0.250  0.463  0.701  1.0
  V  V5  1  0.750  0.537  0.299  1.0
  V  V6  1  0.250  0.175  0.379  1.0
  V  V7  1  0.750  0.825  0.621  1.0
  Cd  Cd8  1  0.250  0.803  0.862  1.0
  Cd  Cd9  1  0.750  0.197  0.138  1.0
  Cu  Cu10  1  0.501  0.890  0.281  1.0
  Cu  Cu11  1  0.499  0.110  0.719  1.0
  Cu  Cu12  1  0.001  0.110  0.719  1.0
  Cu  Cu13  1  0.999  0.890  0.281  1.0
  Cu  Cu14  1  0.250  0.855  0.559  1.0
  Cu  Cu15  1  0.750  0.145  0.441  1.0
  Cu  Cu16  1  0.250  0.599  0.392  1.0
  Cu  Cu17  1  0.750  0.401  0.608  1.0
  O  O18  1  0.250  0.375  0.380  1.0
  O  O19  1  0.750  0.625  0.620  1.0
  O  O20  1  0.250  0.086  0.531  1.0
  O  O21  1  0.750  0.914  0.469  1.0
  O  O22  1  0.250  0.620  0.578  1.0
  O  O23  1  0.750  0.380  0.422  1.0
  O  O24  1  0.510  0.883  0.693  1.0
  O  O25  1  0.490  0.117  0.307  1.0
  O  O26  1  0.010  0.117  0.307  1.0
  O  O27  1  0.990  0.883  0.693  1.0
  O  O28  1  0.250  0.841  0.378  1.0
  O  O29  1  0.750  0.159  0.622  1.0
  O  O30  1  0.250  0.976  0.097  1.0
  O  O31  1  0.750  0.024  0.903  1.0
  O  O32  1  0.250  0.078  0.828  1.0
  O  O33  1  0.750  0.922  0.172  1.0
  O  O34  1  0.466  0.254  0.018  1.0
  O  O35  1  0.534  0.746  0.982  1.0
  O  O36  1  0.966  0.746  0.982  1.0
  O  O37  1  0.034  0.254  0.018  1.0
  O  O38  1  0.250  0.545  0.835  1.0
  O  O39  1  0.750  0.455  0.165  1.0
  O  O40  1  0.977  0.660  0.298  1.0
  O  O41  1  0.023  0.340  0.702  1.0
  O  O42  1  0.477  0.340  0.702  1.0
  O  O43  1  0.523  0.660  0.298  1.0
[/CIF]
.
The material structure described by V3Cu4CdTlO13 crystallizes in the monoclinic P2_1/m space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(6), one O(7), and two equivalent O(8) atoms to form VO4 tetrahedra that share corners with three equivalent Cd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-76°. In the second V site, V(2) is bonded to one O(3), one O(9), and two equivalent O(10) atoms to form VO4 tetrahedra that share  a cornercorner with one Cd(1)O6 octahedra,  a cornercorner with one Cu(2)O5 trigonal bipyramid, and corners with three equivalent Cu(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 51°. In the third V site, V(3) is bonded to one O(1), one O(2), and two equivalent O(4) atoms to form VO4 tetrahedra that share corners with two equivalent Cd(1)O6 octahedra,  a cornercorner with one Cu(3)O5 trigonal bipyramid, and corners with three equivalent Cu(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 36°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(4), one O(5), and one O(7) atom. In the second Cu site, Cu(2) is bonded to one O(2), one O(3), one O(5), and two equivalent O(4) atoms to form CuO5 trigonal bipyramids that share  a cornercorner with one V(2)O4 tetrahedra, corners with three equivalent V(3)O4 tetrahedra,  an edgeedge with one Cd(1)O6 octahedra, and  an edgeedge with one Cu(3)O5 trigonal bipyramid. In the third Cu site, Cu(3) is bonded to one O(1), one O(3), one O(5), and two equivalent O(10) atoms to form distorted CuO5 trigonal bipyramids that share  a cornercorner with one V(3)O4 tetrahedra, corners with three equivalent V(2)O4 tetrahedra, and  an edgeedge with one Cu(2)O5 trigonal bipyramid. Cd(1) is bonded to one O(7), one O(9), two equivalent O(4), and two equivalent O(8) atoms to form CdO6 octahedra that share  a cornercorner with one V(2)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, corners with three equivalent V(1)O4 tetrahedra, and  an edgeedge with one Cu(2)O5 trigonal bipyramid. Tl(1) is bonded in a 5-coordinate geometry to one O(9) and four equivalent O(8) atoms. There are ten inequivalent O sites. In the first O site, O(7) is bonded to one V(1), two equivalent Cu(1), and one Cd(1) atom to form distorted corner-sharing OVCdCu2 trigonal pyramids. In the second O site, O(8) is bonded in a 2-coordinate geometry to one V(1), one Cd(1), and two equivalent Tl(1) atoms. In the third O site, O(9) is bonded in a distorted bent 120 degrees geometry to one V(2), one Cd(1), and one Tl(1) atom. In the fourth O site, O(10) is bonded in a distorted trigonal planar geometry to one V(2), one Cu(1), and one Cu(3) atom. In the fifth O site, O(1) is bonded in a linear geometry to one V(3) and one Cu(3) atom. In the sixth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one V(3) and one Cu(2) atom. In the seventh O site, O(3) is bonded in a distorted trigonal planar geometry to one V(2), one Cu(2), and one Cu(3) atom. In the eighth O site, O(4) is bonded in a 4-coordinate geometry to one V(3), one Cu(1), one Cu(2), and one Cd(1) atom. In the ninth O site, O(5) is bonded to one Cu(2), one Cu(3), and two equivalent Cu(1) atoms to form distorted corner-sharing OCu4 trigonal pyramids. In the tenth O site, O(6) is bonded in a distorted single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_TlV3CdCu4O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.372
_cell_length_b   8.474
_cell_length_c   10.953
_cell_angle_alpha   82.798
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   586.750
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.250  0.510  0.102  1.0
  Tl  Tl1  1  0.750  0.490  0.898  1.0
  V  V2  1  0.250  0.139  0.992  1.0
  V  V3  1  0.750  0.861  0.008  1.0
  V  V4  1  0.250  0.463  0.701  1.0
  V  V5  1  0.750  0.537  0.299  1.0
  V  V6  1  0.250  0.175  0.379  1.0
  V  V7  1  0.750  0.825  0.621  1.0
  Cd  Cd8  1  0.250  0.803  0.862  1.0
  Cd  Cd9  1  0.750  0.197  0.138  1.0
  Cu  Cu10  1  0.501  0.890  0.281  1.0
  Cu  Cu11  1  0.499  0.110  0.719  1.0
  Cu  Cu12  1  0.001  0.110  0.719  1.0
  Cu  Cu13  1  0.999  0.890  0.281  1.0
  Cu  Cu14  1  0.250  0.855  0.559  1.0
  Cu  Cu15  1  0.750  0.145  0.441  1.0
  Cu  Cu16  1  0.250  0.599  0.392  1.0
  Cu  Cu17  1  0.750  0.401  0.608  1.0
  O  O18  1  0.250  0.375  0.380  1.0
  O  O19  1  0.750  0.625  0.620  1.0
  O  O20  1  0.250  0.086  0.531  1.0
  O  O21  1  0.750  0.914  0.469  1.0
  O  O22  1  0.250  0.620  0.578  1.0
  O  O23  1  0.750  0.380  0.422  1.0
  O  O24  1  0.510  0.883  0.693  1.0
  O  O25  1  0.490  0.117  0.307  1.0
  O  O26  1  0.010  0.117  0.307  1.0
  O  O27  1  0.990  0.883  0.693  1.0
  O  O28  1  0.250  0.841  0.378  1.0
  O  O29  1  0.750  0.159  0.622  1.0
  O  O30  1  0.250  0.976  0.097  1.0
  O  O31  1  0.750  0.024  0.903  1.0
  O  O32  1  0.250  0.078  0.828  1.0
  O  O33  1  0.750  0.922  0.172  1.0
  O  O34  1  0.466  0.254  0.018  1.0
  O  O35  1  0.534  0.746  0.982  1.0
  O  O36  1  0.966  0.746  0.982  1.0
  O  O37  1  0.034  0.254  0.018  1.0
  O  O38  1  0.250  0.545  0.835  1.0
  O  O39  1  0.750  0.455  0.165  1.0
  O  O40  1  0.977  0.660  0.298  1.0
  O  O41  1  0.023  0.340  0.702  1.0
  O  O42  1  0.477  0.340  0.702  1.0
  O  O43  1  0.523  0.660  0.298  1.0
[/CIF]
.