The compound described by Zn(SnO2)4 is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. The structure consists of two 7440-66-6 atoms inside a SnO2 framework. In the SnO2 framework, there are four inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(2), one O(7), two equivalent O(4), and two equivalent O(5) atoms to form a mixture of corner and edge-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the second Sn site, Sn(2) is bonded to one O(4), one O(8), two equivalent O(3), and two equivalent O(6) atoms to form a mixture of corner and edge-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the third Sn site, Sn(3) is bonded to one O(1), one O(6), two equivalent O(2), and two equivalent O(8) atoms to form a mixture of corner and edge-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the fourth Sn site, Sn(4) is bonded to one O(3), one O(5), two equivalent O(1), and two equivalent O(7) atoms to form a mixture of corner and edge-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Sn(3) and two equivalent Sn(4) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one Sn(1) and two equivalent Sn(3) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one Sn(4) and two equivalent Sn(2) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Sn(2) and two equivalent Sn(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Sn(4) and two equivalent Sn(1) atoms. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Sn(3) and two equivalent Sn(2) atoms. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1) and two equivalent Sn(4) atoms. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Sn(2) and two equivalent Sn(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn(SnO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.810
_cell_length_b   7.810
_cell_length_c   10.489
_cell_angle_alpha   48.753
_cell_angle_beta   48.753
_cell_angle_gamma   23.814
_symmetry_Int_Tables_number   1
_cell_volume   190.892
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.527  0.527  0.957  1.0
  Sn  Sn1  1  0.369  0.369  0.443  1.0
  Sn  Sn2  1  0.856  0.856  0.784  1.0
  Sn  Sn3  1  0.173  0.173  0.152  1.0
  Sn  Sn4  1  0.661  0.661  0.492  1.0
  O  O5  1  0.156  0.156  0.368  1.0
  O  O6  1  0.554  0.554  0.244  1.0
  O  O7  1  0.476  0.476  0.691  1.0
  O  O8  1  0.873  0.873  0.569  1.0
  O  O9  1  0.850  0.850  0.332  1.0
  O  O10  1  0.236  0.236  0.896  1.0
  O  O11  1  0.179  0.179  0.604  1.0
  O  O12  1  0.794  0.794  0.040  1.0
[/CIF]
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The compound described by Zn(SnO2)4 is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. The structure consists of two 7440-66-6 atoms inside a SnO2 framework. In the SnO2 framework, there are four inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(2), one O(7), two equivalent O(4), and two equivalent O(5) atoms to form a mixture of corner and edge-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the second Sn site, Sn(2) is bonded to one O(4), one O(8), two equivalent O(3), and two equivalent O(6) atoms to form a mixture of corner and edge-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the third Sn site, Sn(3) is bonded to one O(1), one O(6), two equivalent O(2), and two equivalent O(8) atoms to form a mixture of corner and edge-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the fourth Sn site, Sn(4) is bonded to one O(3), one O(5), two equivalent O(1), and two equivalent O(7) atoms to form a mixture of corner and edge-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Sn(3) and two equivalent Sn(4) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one Sn(1) and two equivalent Sn(3) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to one Sn(4) and two equivalent Sn(2) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Sn(2) and two equivalent Sn(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Sn(4) and two equivalent Sn(1) atoms. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Sn(3) and two equivalent Sn(2) atoms. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1) and two equivalent Sn(4) atoms. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Sn(2) and two equivalent Sn(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn(SnO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.810
_cell_length_b   7.810
_cell_length_c   10.489
_cell_angle_alpha   48.753
_cell_angle_beta   48.753
_cell_angle_gamma   23.814
_symmetry_Int_Tables_number   1
_cell_volume   190.892
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.527  0.527  0.957  1.0
  Sn  Sn1  1  0.369  0.369  0.443  1.0
  Sn  Sn2  1  0.856  0.856  0.784  1.0
  Sn  Sn3  1  0.173  0.173  0.152  1.0
  Sn  Sn4  1  0.661  0.661  0.492  1.0
  O  O5  1  0.156  0.156  0.368  1.0
  O  O6  1  0.554  0.554  0.244  1.0
  O  O7  1  0.476  0.476  0.691  1.0
  O  O8  1  0.873  0.873  0.569  1.0
  O  O9  1  0.850  0.850  0.332  1.0
  O  O10  1  0.236  0.236  0.896  1.0
  O  O11  1  0.179  0.179  0.604  1.0
  O  O12  1  0.794  0.794  0.040  1.0
[/CIF]
.