The compound described by (FSO2)2N is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two imidodisulfurylfluoride molecules. N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one N(1), one O(1), one O(2), and one F(1) atom to form corner-sharing SNO2F tetrahedra. In the second S site, S(2) is bonded to one N(1), one O(3), one O(4), and one F(2) atom to form distorted corner-sharing SNO2F tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF card [CIF]
data_S2N(O2F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.503
_cell_length_b   7.121
_cell_length_c   8.245
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   98.607
_symmetry_Int_Tables_number   1
_cell_volume   319.415
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.810  0.106  0.978  1.0
  S  S1  1  0.190  0.894  0.478  1.0
  S  S2  1  0.724  0.356  0.245  1.0
  S  S3  1  0.276  0.644  0.745  1.0
  N  N4  1  0.665  0.267  0.058  1.0
  N  N5  1  0.335  0.733  0.558  1.0
  O  O6  1  0.065  0.191  0.989  1.0
  O  O7  1  0.935  0.809  0.489  1.0
  O  O8  1  0.698  0.043  0.829  1.0
  O  O9  1  0.302  0.957  0.329  1.0
  O  O10  1  0.510  0.431  0.293  1.0
  O  O11  1  0.490  0.569  0.793  1.0
  O  O12  1  0.854  0.246  0.349  1.0
  O  O13  1  0.146  0.754  0.849  1.0
  F  F14  1  0.772  0.931  0.098  1.0
  F  F15  1  0.228  0.069  0.598  1.0
  F  F16  1  0.918  0.529  0.182  1.0
  F  F17  1  0.082  0.471  0.682  1.0
[/CIF]
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The compound described by (FSO2)2N is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two imidodisulfurylfluoride molecules. N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one N(1), one O(1), one O(2), and one F(1) atom to form corner-sharing SNO2F tetrahedra. In the second S site, S(2) is bonded to one N(1), one O(3), one O(4), and one F(2) atom to form distorted corner-sharing SNO2F tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF card [CIF]
data_S2N(O2F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.503
_cell_length_b   7.121
_cell_length_c   8.245
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   98.607
_symmetry_Int_Tables_number   1
_cell_volume   319.415
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.810  0.106  0.978  1.0
  S  S1  1  0.190  0.894  0.478  1.0
  S  S2  1  0.724  0.356  0.245  1.0
  S  S3  1  0.276  0.644  0.745  1.0
  N  N4  1  0.665  0.267  0.058  1.0
  N  N5  1  0.335  0.733  0.558  1.0
  O  O6  1  0.065  0.191  0.989  1.0
  O  O7  1  0.935  0.809  0.489  1.0
  O  O8  1  0.698  0.043  0.829  1.0
  O  O9  1  0.302  0.957  0.329  1.0
  O  O10  1  0.510  0.431  0.293  1.0
  O  O11  1  0.490  0.569  0.793  1.0
  O  O12  1  0.854  0.246  0.349  1.0
  O  O13  1  0.146  0.754  0.849  1.0
  F  F14  1  0.772  0.931  0.098  1.0
  F  F15  1  0.228  0.069  0.598  1.0
  F  F16  1  0.918  0.529  0.182  1.0
  F  F17  1  0.082  0.471  0.682  1.0
[/CIF]
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