The compound described by Al8Cu4Ce crystallizes in the tetragonal I4/mmm space group. Ce(1) is bonded in a 20-coordinate geometry to eight equivalent Cu(1), four equivalent Al(1), and eight equivalent Al(2) atoms. Cu(1) is bonded to two equivalent Ce(1), two equivalent Cu(1), four equivalent Al(1), and four equivalent Al(2) atoms to form a mixture of distorted edge, face, and corner-sharing CuCe2Al8Cu2 cuboctahedra. There are two inequivalent Al sites. In the first Al site, Al(1) is bonded in a 10-coordinate geometry to one Ce(1), four equivalent Cu(1), one Al(1), and four equivalent Al(2) atoms. In the second Al site, Al(2) is bonded in a 12-coordinate geometry to two equivalent Ce(1), four equivalent Cu(1), two equivalent Al(2), and four equivalent Al(1) atoms. is represented by the CIF card [CIF]
data_Ce(Al2Cu)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.107
_cell_length_b   6.732
_cell_length_c   6.732
_cell_angle_alpha   81.299
_cell_angle_beta   67.648
_cell_angle_gamma   67.648
_symmetry_Int_Tables_number   1
_cell_volume   197.948
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.000  0.000  0.000  1.0
  Al  Al1  1  0.350  0.651  0.651  1.0
  Al  Al2  1  0.000  0.348  0.652  1.0
  Al  Al3  1  0.000  0.652  0.348  1.0
  Al  Al4  1  0.650  0.349  0.349  1.0
  Al  Al5  1  0.278  0.222  0.222  1.0
  Al  Al6  1  0.500  0.779  0.221  1.0
  Al  Al7  1  0.500  0.221  0.779  1.0
  Al  Al8  1  0.722  0.778  0.778  1.0
  Cu  Cu9  1  0.500  0.000  0.500  1.0
  Cu  Cu10  1  0.000  0.500  0.000  1.0
  Cu  Cu11  1  0.500  0.500  0.000  1.0
  Cu  Cu12  1  0.000  0.000  0.500  1.0
[/CIF]
.
The compound described by Al8Cu4Ce crystallizes in the tetragonal I4/mmm space group. Ce(1) is bonded in a 20-coordinate geometry to eight equivalent Cu(1), four equivalent Al(1), and eight equivalent Al(2) atoms. Cu(1) is bonded to two equivalent Ce(1), two equivalent Cu(1), four equivalent Al(1), and four equivalent Al(2) atoms to form a mixture of distorted edge, face, and corner-sharing CuCe2Al8Cu2 cuboctahedra. There are two inequivalent Al sites. In the first Al site, Al(1) is bonded in a 10-coordinate geometry to one Ce(1), four equivalent Cu(1), one Al(1), and four equivalent Al(2) atoms. In the second Al site, Al(2) is bonded in a 12-coordinate geometry to two equivalent Ce(1), four equivalent Cu(1), two equivalent Al(2), and four equivalent Al(1) atoms. is represented by the CIF card [CIF]
data_Ce(Al2Cu)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.107
_cell_length_b   6.732
_cell_length_c   6.732
_cell_angle_alpha   81.299
_cell_angle_beta   67.648
_cell_angle_gamma   67.648
_symmetry_Int_Tables_number   1
_cell_volume   197.948
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.000  0.000  0.000  1.0
  Al  Al1  1  0.350  0.651  0.651  1.0
  Al  Al2  1  0.000  0.348  0.652  1.0
  Al  Al3  1  0.000  0.652  0.348  1.0
  Al  Al4  1  0.650  0.349  0.349  1.0
  Al  Al5  1  0.278  0.222  0.222  1.0
  Al  Al6  1  0.500  0.779  0.221  1.0
  Al  Al7  1  0.500  0.221  0.779  1.0
  Al  Al8  1  0.722  0.778  0.778  1.0
  Cu  Cu9  1  0.500  0.000  0.500  1.0
  Cu  Cu10  1  0.000  0.500  0.000  1.0
  Cu  Cu11  1  0.500  0.500  0.000  1.0
  Cu  Cu12  1  0.000  0.000  0.500  1.0
[/CIF]
.