The crystal structure described by BiO2 crystallizes in the monoclinic C2/c space group. Bi(1) is bonded to six equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing BiO6 pentagonal pyramids. O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Bi(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.245
_cell_length_b   4.245
_cell_length_c   6.574
_cell_angle_alpha   72.019
_cell_angle_beta   70.469
_cell_angle_gamma   90.079
_symmetry_Int_Tables_number   1
_cell_volume   105.460
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.121  0.870  0.750  1.0
  Bi  Bi1  1  0.879  0.130  0.250  1.0
  O  O2  1  0.062  0.316  0.862  1.0
  O  O3  1  0.322  0.077  0.362  1.0
  O  O4  1  0.678  0.923  0.638  1.0
  O  O5  1  0.938  0.684  0.138  1.0
[/CIF]
.
The crystal structure described by BiO2 crystallizes in the monoclinic C2/c space group. Bi(1) is bonded to six equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing BiO6 pentagonal pyramids. O(1) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Bi(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.245
_cell_length_b   4.245
_cell_length_c   6.574
_cell_angle_alpha   72.019
_cell_angle_beta   70.469
_cell_angle_gamma   90.079
_symmetry_Int_Tables_number   1
_cell_volume   105.460
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.121  0.870  0.750  1.0
  Bi  Bi1  1  0.879  0.130  0.250  1.0
  O  O2  1  0.062  0.316  0.862  1.0
  O  O3  1  0.322  0.077  0.362  1.0
  O  O4  1  0.678  0.923  0.638  1.0
  O  O5  1  0.938  0.684  0.138  1.0
[/CIF]
.