The structure described by SbF5SO2F2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfuryl fluoride molecules and four SbF5 clusters. In each SbF5 cluster, Sb(1) is bonded in a distorted trigonal bipyramidal geometry to one F(1), one F(2), one F(3), one F(5), and one F(6) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbSO2F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.219
_cell_length_b   8.289
_cell_length_c   19.034
_cell_angle_alpha   90.000
_cell_angle_beta   90.527
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   823.396
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.899  0.596  0.863  1.0
  Sb  Sb1  1  0.101  0.096  0.637  1.0
  Sb  Sb2  1  0.101  0.404  0.137  1.0
  Sb  Sb3  1  0.899  0.904  0.363  1.0
  S  S4  1  0.486  0.636  0.622  1.0
  S  S5  1  0.514  0.136  0.878  1.0
  S  S6  1  0.514  0.364  0.378  1.0
  S  S7  1  0.486  0.864  0.122  1.0
  O  O8  1  0.451  0.668  0.550  1.0
  O  O9  1  0.549  0.168  0.950  1.0
  O  O10  1  0.549  0.332  0.450  1.0
  O  O11  1  0.451  0.832  0.050  1.0
  O  O12  1  0.388  0.502  0.659  1.0
  O  O13  1  0.612  0.002  0.841  1.0
  O  O14  1  0.612  0.498  0.341  1.0
  O  O15  1  0.388  0.998  0.159  1.0
  F  F16  1  0.099  0.493  0.794  1.0
  F  F17  1  0.901  0.993  0.706  1.0
  F  F18  1  0.901  0.507  0.206  1.0
  F  F19  1  0.099  0.007  0.294  1.0
  F  F20  1  0.618  0.621  0.925  1.0
  F  F21  1  0.382  0.121  0.575  1.0
  F  F22  1  0.382  0.379  0.075  1.0
  F  F23  1  0.618  0.879  0.425  1.0
  F  F24  1  0.039  0.448  0.928  1.0
  F  F25  1  0.961  0.948  0.572  1.0
  F  F26  1  0.961  0.552  0.072  1.0
  F  F27  1  0.039  0.052  0.428  1.0
  F  F28  1  0.599  0.295  0.836  1.0
  F  F29  1  0.401  0.795  0.664  1.0
  F  F30  1  0.401  0.705  0.164  1.0
  F  F31  1  0.599  0.205  0.336  1.0
  F  F32  1  0.676  0.657  0.789  1.0
  F  F33  1  0.324  0.157  0.711  1.0
  F  F34  1  0.324  0.343  0.211  1.0
  F  F35  1  0.676  0.843  0.289  1.0
  F  F36  1  0.088  0.784  0.880  1.0
  F  F37  1  0.912  0.284  0.620  1.0
  F  F38  1  0.912  0.216  0.120  1.0
  F  F39  1  0.088  0.716  0.380  1.0
  F  F40  1  0.779  0.654  0.641  1.0
  F  F41  1  0.221  0.154  0.859  1.0
  F  F42  1  0.221  0.346  0.359  1.0
  F  F43  1  0.779  0.846  0.141  1.0
[/CIF]
.
The structure described by SbF5SO2F2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four sulfuryl fluoride molecules and four SbF5 clusters. In each SbF5 cluster, Sb(1) is bonded in a distorted trigonal bipyramidal geometry to one F(1), one F(2), one F(3), one F(5), and one F(6) atom. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbSO2F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.219
_cell_length_b   8.289
_cell_length_c   19.034
_cell_angle_alpha   90.000
_cell_angle_beta   90.527
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   823.396
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.899  0.596  0.863  1.0
  Sb  Sb1  1  0.101  0.096  0.637  1.0
  Sb  Sb2  1  0.101  0.404  0.137  1.0
  Sb  Sb3  1  0.899  0.904  0.363  1.0
  S  S4  1  0.486  0.636  0.622  1.0
  S  S5  1  0.514  0.136  0.878  1.0
  S  S6  1  0.514  0.364  0.378  1.0
  S  S7  1  0.486  0.864  0.122  1.0
  O  O8  1  0.451  0.668  0.550  1.0
  O  O9  1  0.549  0.168  0.950  1.0
  O  O10  1  0.549  0.332  0.450  1.0
  O  O11  1  0.451  0.832  0.050  1.0
  O  O12  1  0.388  0.502  0.659  1.0
  O  O13  1  0.612  0.002  0.841  1.0
  O  O14  1  0.612  0.498  0.341  1.0
  O  O15  1  0.388  0.998  0.159  1.0
  F  F16  1  0.099  0.493  0.794  1.0
  F  F17  1  0.901  0.993  0.706  1.0
  F  F18  1  0.901  0.507  0.206  1.0
  F  F19  1  0.099  0.007  0.294  1.0
  F  F20  1  0.618  0.621  0.925  1.0
  F  F21  1  0.382  0.121  0.575  1.0
  F  F22  1  0.382  0.379  0.075  1.0
  F  F23  1  0.618  0.879  0.425  1.0
  F  F24  1  0.039  0.448  0.928  1.0
  F  F25  1  0.961  0.948  0.572  1.0
  F  F26  1  0.961  0.552  0.072  1.0
  F  F27  1  0.039  0.052  0.428  1.0
  F  F28  1  0.599  0.295  0.836  1.0
  F  F29  1  0.401  0.795  0.664  1.0
  F  F30  1  0.401  0.705  0.164  1.0
  F  F31  1  0.599  0.205  0.336  1.0
  F  F32  1  0.676  0.657  0.789  1.0
  F  F33  1  0.324  0.157  0.711  1.0
  F  F34  1  0.324  0.343  0.211  1.0
  F  F35  1  0.676  0.843  0.289  1.0
  F  F36  1  0.088  0.784  0.880  1.0
  F  F37  1  0.912  0.284  0.620  1.0
  F  F38  1  0.912  0.216  0.120  1.0
  F  F39  1  0.088  0.716  0.380  1.0
  F  F40  1  0.779  0.654  0.641  1.0
  F  F41  1  0.221  0.154  0.859  1.0
  F  F42  1  0.221  0.346  0.359  1.0
  F  F43  1  0.779  0.846  0.141  1.0
[/CIF]
.