The material structure described by Li9CrN5 crystallizes in the triclinic P-1 space group. There are nine inequivalent Li sites. In the first Li site, Li(1) is bonded to one N(1), one N(3), one N(4), and one N(5) atom to form distorted LiN4 tetrahedra that share  a cornercorner with one Li(3)N4 tetrahedra,  a cornercorner with one Li(4)N4 tetrahedra,  a cornercorner with one Li(5)N4 tetrahedra,  a cornercorner with one Li(8)N4 tetrahedra,  a cornercorner with one Li(9)N4 tetrahedra, corners with two equivalent Li(2)N4 tetrahedra, corners with two equivalent Li(7)N4 tetrahedra, corners with three equivalent Cr(1)N4 tetrahedra, corners with four equivalent Li(6)N4 tetrahedra,  an edgeedge with one Li(3)N4 tetrahedra,  an edgeedge with one Li(4)N4 tetrahedra,  an edgeedge with one Li(5)N4 tetrahedra,  an edgeedge with one Li(7)N4 tetrahedra,  an edgeedge with one Li(8)N4 tetrahedra, and  an edgeedge with one Li(9)N4 tetrahedra. In the second Li site, Li(2) is bonded to one N(1), one N(4), and two equivalent N(2) atoms to form distorted LiN4 tetrahedra that share  a cornercorner with one Li(6)N4 tetrahedra,  a cornercorner with one Li(7)N4 tetrahedra,  a cornercorner with one Li(8)N4 tetrahedra,  a cornercorner with one Cr(1)N4 tetrahedra, corners with two equivalent Li(1)N4 tetrahedra, corners with two equivalent Li(3)N4 tetrahedra, corners with two equivalent Li(4)N4 tetrahedra, corners with three equivalent Li(5)N4 tetrahedra, corners with three equivalent Li(9)N4 tetrahedra,  an edgeedge with one Li(2)N4 tetrahedra,  an edgeedge with one Li(3)N4 tetrahedra,  an edgeedge with one Li(5)N4 tetrahedra,  an edgeedge with one Li(7)N4 tetrahedra,  an edgeedge with one Li(8)N4 tetrahedra, and  an edgeedge with one Cr(1)N4 tetrahedra. In the third Li site, Li(3) is bonded to one N(2), one N(5), and two equivalent N(4) atoms to form distorted LiN4 tetrahedra that share  a cornercorner with one Li(1)N4 tetrahedra,  a cornercorner with one Li(4)N4 tetrahedra,  a cornercorner with one Li(5)N4 tetrahedra,  a cornercorner with one Li(6)N4 tetrahedra,  a cornercorner with one Li(9)N4 tetrahedra, corners with two equivalent Li(2)N4 tetrahedra, corners with two equivalent Cr(1)N4 tetrahedra, corners with three equivalent Li(8)N4 tetrahedra, corners with four equivalent Li(7)N4 tetrahedra,  an edgeedge with one Li(1)N4 tetrahedra,  an edgeedge with one Li(2)N4 tetrahedra,  an edgeedge with one Li(3)N4 tetrahedra,  an edgeedge with one Li(4)N4 tetrahedra,  an edgeedge with one Li(5)N4 tetrahedra, and  an edgeedge with one Cr(1)N4 tetrahedra. In the fourth Li site, Li(4) is bonded to one N(2), one N(3), and two equivalent N(5) atoms to form LiN4 tetrahedra that share  a cornercorner with one Li(1)N4 tetrahedra,  a cornercorner with one Li(3)N4 tetrahedra,  a cornercorner with one Li(5)N4 tetrahedra,  a cornercorner with one Li(7)N4 tetrahedra,  a cornercorner with one Li(9)N4 tetrahedra, corners with two equivalent Li(2)N4 tetrahedra, corners with two equivalent Li(6)N4 tetrahedra, corners with three equivalent Li(8)N4 tetrahedra, corners with four equivalent Cr(1)N4 tetrahedra,  an edgeedge with one Li(1)N4 tetrahedra,  an edgeedge with one Li(3)N4 tetrahedra,  an edgeedge with one Li(4)N4 tetrahedra,  an edgeedge with one Li(6)N4 tetrahedra,  an edgeedge with one Li(8)N4 tetrahedra, and  an edgeedge with one Li(9)N4 tetrahedra. In the fifth Li site, Li(5) is bonded to one N(2), one N(4), and two equivalent N(1) atoms to form distorted LiN4 tetrahedra that share  a cornercorner with one Li(1)N4 tetrahedra,  a cornercorner with one Li(3)N4 tetrahedra,  a cornercorner with one Li(4)N4 tetrahedra,  a cornercorner with one Li(9)N4 tetrahedra, corners with two equivalent Li(6)N4 tetrahedra, corners with two equivalent Li(7)N4 tetrahedra, corners with two equivalent Cr(1)N4 tetrahedra, corners with three equivalent Li(2)N4 tetrahedra, corners with three equivalent Li(8)N4 tetrahedra,  an edgeedge with one Li(1)N4 tetrahedra,  an edgeedge with one Li(2)N4 tetrahedra,  an edgeedge with one Li(3)N4 tetrahedra,  an edgeedge with one Li(5)N4 tetrahedra,  an edgeedge with one Li(7)N4 tetrahedra, and  an edgeedge with one Li(9)N4 tetrahedra. In the sixth Li site, Li(6) is bonded to one N(1), one N(5), and two equivalent N(3) atoms to form LiN4 tetrahedra that share  a cornercorner with one Li(2)N4 tetrahedra,  a cornercorner with one Li(3)N4 tetrahedra,  a cornercorner with one Li(7)N4 tetrahedra,  a cornercorner with one Li(8)N4 tetrahedra,  a cornercorner with one Cr(1)N4 tetrahedra, corners with two equivalent Li(4)N4 tetrahedra, corners with two equivalent Li(5)N4 tetrahedra, corners with three equivalent Li(9)N4 tetrahedra, corners with four equivalent Li(1)N4 tetrahedra,  an edgeedge with one Li(4)N4 tetrahedra,  an edgeedge with one Li(6)N4 tetrahedra,  an edgeedge with one Li(7)N4 tetrahedra,  an edgeedge with one Li(8)N4 tetrahedra,  an edgeedge with one Li(9)N4 tetrahedra, and  an edgeedge with one Cr(1)N4 tetrahedra. In the seventh Li site, Li(7) is bonded to one N(1), one N(3), and two equivalent N(4) atoms to form distorted LiN4 tetrahedra that share  a cornercorner with one Li(2)N4 tetrahedra,  a cornercorner with one Li(4)N4 tetrahedra,  a cornercorner with one Li(6)N4 tetrahedra,  a cornercorner with one Li(8)N4 tetrahedra,  a cornercorner with one Cr(1)N4 tetrahedra, corners with two equivalent Li(1)N4 tetrahedra, corners with two equivalent Li(5)N4 tetrahedra, corners with three equivalent Li(9)N4 tetrahedra, corners with four equivalent Li(3)N4 tetrahedra,  an edgeedge with one Li(1)N4 tetrahedra,  an edgeedge with one Li(2)N4 tetrahedra,  an edgeedge with one Li(5)N4 tetrahedra,  an edgeedge with one Li(6)N4 tetrahedra,  an edgeedge with one Li(7)N4 tetrahedra, and  an edgeedge with one Cr(1)N4 tetrahedra. In the eighth Li site, Li(8) is bonded to one N(1), one N(2), and two equivalent N(5) atoms to form distorted LiN4 tetrahedra that share  a cornercorner with one Li(1)N4 tetrahedra,  a cornercorner with one Li(2)N4 tetrahedra,  a cornercorner with one Li(6)N4 tetrahedra,  a cornercorner with one Li(7)N4 tetrahedra,  a cornercorner with one Cr(1)N4 tetrahedra, corners with two equivalent Li(9)N4 tetrahedra, corners with three equivalent Li(3)N4 tetrahedra, corners with three equivalent Li(4)N4 tetrahedra, corners with three equivalent Li(5)N4 tetrahedra,  an edgeedge with one Li(1)N4 tetrahedra,  an edgeedge with one Li(2)N4 tetrahedra,  an edgeedge with one Li(4)N4 tetrahedra,  an edgeedge with one Li(6)N4 tetrahedra,  an edgeedge with one Li(8)N4 tetrahedra, and  an edgeedge with one Cr(1)N4 tetrahedra. In the ninth Li site, Li(9) is bonded to one N(1), one N(2), and two equivalent N(3) atoms to form distorted LiN4 tetrahedra that share  a cornercorner with one Li(1)N4 tetrahedra,  a cornercorner with one Li(3)N4 tetrahedra,  a cornercorner with one Li(4)N4 tetrahedra,  a cornercorner with one Li(5)N4 tetrahedra,  a cornercorner with one Cr(1)N4 tetrahedra, corners with two equivalent Li(8)N4 tetrahedra, corners with three equivalent Li(2)N4 tetrahedra, corners with three equivalent Li(6)N4 tetrahedra, corners with three equivalent Li(7)N4 tetrahedra,  an edgeedge with one Li(1)N4 tetrahedra,  an edgeedge with one Li(4)N4 tetrahedra,  an edgeedge with one Li(5)N4 tetrahedra,  an edgeedge with one Li(6)N4 tetrahedra,  an edgeedge with one Li(9)N4 tetrahedra, and  an edgeedge with one Cr(1)N4 tetrahedra. Cr(1) is bonded to one N(2), one N(3), one N(4), and one N(5) atom to form CrN4 tetrahedra that share  a cornercorner with one Li(2)N4 tetrahedra,  a cornercorner with one Li(6)N4 tetrahedra,  a cornercorner with one Li(7)N4 tetrahedra,  a cornercorner with one Li(8)N4 tetrahedra,  a cornercorner with one Li(9)N4 tetrahedra, corners with two equivalent Li(3)N4 tetrahedra, corners with two equivalent Li(5)N4 tetrahedra, corners with three equivalent Li(1)N4 tetrahedra, corners with four equivalent Li(4)N4 tetrahedra,  an edgeedge with one Li(2)N4 tetrahedra,  an edgeedge with one Li(3)N4 tetrahedra,  an edgeedge with one Li(6)N4 tetrahedra,  an edgeedge with one Li(7)N4 tetrahedra,  an edgeedge with one Li(8)N4 tetrahedra, and  an edgeedge with one Li(9)N4 tetrahedra. There are five inequivalent N sites. In the first N site, N(1) is bonded in a body-centered cubic geometry to one Li(1), one Li(2), one Li(6), one Li(7), one Li(8), one Li(9), and two equivalent Li(5) atoms. In the second N site, N(2) is bonded in a distorted body-centered cubic geometry to one Li(3), one Li(4), one Li(5), one Li(8), one Li(9), two equivalent Li(2), and one Cr(1) atom. In the third N site, N(3) is bonded in a distorted body-centered cubic geometry to one Li(1), one Li(4), one Li(7), two equivalent Li(6), two equivalent Li(9), and one Cr(1) atom. In the fourth N site, N(4) is bonded in a 8-coordinate geometry to one Li(1), one Li(2), one Li(5), two equivalent Li(3), two equivalent Li(7), and one Cr(1) atom. In the fifth N site, N(5) is bonded in a distorted body-centered cubic geometry to one Li(1), one Li(3), one Li(6), two equivalent Li(4), two equivalent Li(8), and one Cr(1) atom. is represented by the CIF file [CIF]
data_Li9CrN5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.853
_cell_length_b   6.792
_cell_length_c   7.622
_cell_angle_alpha   76.913
_cell_angle_beta   75.101
_cell_angle_gamma   73.414
_symmetry_Int_Tables_number   1
_cell_volume   276.776
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.742  0.256  0.234  1.0
  Li  Li1  1  0.625  0.849  0.941  1.0
  Li  Li2  1  0.923  0.047  0.859  1.0
  Li  Li3  1  0.839  0.161  0.546  1.0
  Li  Li4  1  0.631  0.368  0.944  1.0
  Li  Li5  1  0.148  0.360  0.431  1.0
  Li  Li6  1  0.074  0.441  0.140  1.0
  Li  Li7  1  0.926  0.559  0.860  1.0
  Li  Li8  1  0.852  0.640  0.569  1.0
  Li  Li9  1  0.369  0.632  0.056  1.0
  Li  Li10  1  0.258  0.744  0.766  1.0
  Li  Li11  1  0.077  0.953  0.141  1.0
  Li  Li12  1  0.161  0.839  0.454  1.0
  Li  Li13  1  0.555  0.930  0.643  1.0
  Li  Li14  1  0.375  0.151  0.059  1.0
  Li  Li15  1  0.446  0.531  0.351  1.0
  Li  Li16  1  0.554  0.469  0.649  1.0
  Li  Li17  1  0.445  0.070  0.357  1.0
  Cr  Cr18  1  0.753  0.751  0.252  1.0
  Cr  Cr19  1  0.247  0.249  0.748  1.0
  N  N20  1  0.596  0.654  0.800  1.0
  N  N21  1  0.552  0.163  0.782  1.0
  N  N22  1  0.797  0.492  0.375  1.0
  N  N23  1  0.958  0.757  0.037  1.0
  N  N24  1  0.811  0.922  0.377  1.0
  N  N25  1  0.189  0.078  0.623  1.0
  N  N26  1  0.042  0.243  0.963  1.0
  N  N27  1  0.404  0.346  0.200  1.0
  N  N28  1  0.203  0.508  0.625  1.0
  N  N29  1  0.448  0.837  0.218  1.0
[/CIF]
.
The material structure described by Li9CrN5 crystallizes in the triclinic P-1 space group. There are nine inequivalent Li sites. In the first Li site, Li(1) is bonded to one N(1), one N(3), one N(4), and one N(5) atom to form distorted LiN4 tetrahedra that share  a cornercorner with one Li(3)N4 tetrahedra,  a cornercorner with one Li(4)N4 tetrahedra,  a cornercorner with one Li(5)N4 tetrahedra,  a cornercorner with one Li(8)N4 tetrahedra,  a cornercorner with one Li(9)N4 tetrahedra, corners with two equivalent Li(2)N4 tetrahedra, corners with two equivalent Li(7)N4 tetrahedra, corners with three equivalent Cr(1)N4 tetrahedra, corners with four equivalent Li(6)N4 tetrahedra,  an edgeedge with one Li(3)N4 tetrahedra,  an edgeedge with one Li(4)N4 tetrahedra,  an edgeedge with one Li(5)N4 tetrahedra,  an edgeedge with one Li(7)N4 tetrahedra,  an edgeedge with one Li(8)N4 tetrahedra, and  an edgeedge with one Li(9)N4 tetrahedra. In the second Li site, Li(2) is bonded to one N(1), one N(4), and two equivalent N(2) atoms to form distorted LiN4 tetrahedra that share  a cornercorner with one Li(6)N4 tetrahedra,  a cornercorner with one Li(7)N4 tetrahedra,  a cornercorner with one Li(8)N4 tetrahedra,  a cornercorner with one Cr(1)N4 tetrahedra, corners with two equivalent Li(1)N4 tetrahedra, corners with two equivalent Li(3)N4 tetrahedra, corners with two equivalent Li(4)N4 tetrahedra, corners with three equivalent Li(5)N4 tetrahedra, corners with three equivalent Li(9)N4 tetrahedra,  an edgeedge with one Li(2)N4 tetrahedra,  an edgeedge with one Li(3)N4 tetrahedra,  an edgeedge with one Li(5)N4 tetrahedra,  an edgeedge with one Li(7)N4 tetrahedra,  an edgeedge with one Li(8)N4 tetrahedra, and  an edgeedge with one Cr(1)N4 tetrahedra. In the third Li site, Li(3) is bonded to one N(2), one N(5), and two equivalent N(4) atoms to form distorted LiN4 tetrahedra that share  a cornercorner with one Li(1)N4 tetrahedra,  a cornercorner with one Li(4)N4 tetrahedra,  a cornercorner with one Li(5)N4 tetrahedra,  a cornercorner with one Li(6)N4 tetrahedra,  a cornercorner with one Li(9)N4 tetrahedra, corners with two equivalent Li(2)N4 tetrahedra, corners with two equivalent Cr(1)N4 tetrahedra, corners with three equivalent Li(8)N4 tetrahedra, corners with four equivalent Li(7)N4 tetrahedra,  an edgeedge with one Li(1)N4 tetrahedra,  an edgeedge with one Li(2)N4 tetrahedra,  an edgeedge with one Li(3)N4 tetrahedra,  an edgeedge with one Li(4)N4 tetrahedra,  an edgeedge with one Li(5)N4 tetrahedra, and  an edgeedge with one Cr(1)N4 tetrahedra. In the fourth Li site, Li(4) is bonded to one N(2), one N(3), and two equivalent N(5) atoms to form LiN4 tetrahedra that share  a cornercorner with one Li(1)N4 tetrahedra,  a cornercorner with one Li(3)N4 tetrahedra,  a cornercorner with one Li(5)N4 tetrahedra,  a cornercorner with one Li(7)N4 tetrahedra,  a cornercorner with one Li(9)N4 tetrahedra, corners with two equivalent Li(2)N4 tetrahedra, corners with two equivalent Li(6)N4 tetrahedra, corners with three equivalent Li(8)N4 tetrahedra, corners with four equivalent Cr(1)N4 tetrahedra,  an edgeedge with one Li(1)N4 tetrahedra,  an edgeedge with one Li(3)N4 tetrahedra,  an edgeedge with one Li(4)N4 tetrahedra,  an edgeedge with one Li(6)N4 tetrahedra,  an edgeedge with one Li(8)N4 tetrahedra, and  an edgeedge with one Li(9)N4 tetrahedra. In the fifth Li site, Li(5) is bonded to one N(2), one N(4), and two equivalent N(1) atoms to form distorted LiN4 tetrahedra that share  a cornercorner with one Li(1)N4 tetrahedra,  a cornercorner with one Li(3)N4 tetrahedra,  a cornercorner with one Li(4)N4 tetrahedra,  a cornercorner with one Li(9)N4 tetrahedra, corners with two equivalent Li(6)N4 tetrahedra, corners with two equivalent Li(7)N4 tetrahedra, corners with two equivalent Cr(1)N4 tetrahedra, corners with three equivalent Li(2)N4 tetrahedra, corners with three equivalent Li(8)N4 tetrahedra,  an edgeedge with one Li(1)N4 tetrahedra,  an edgeedge with one Li(2)N4 tetrahedra,  an edgeedge with one Li(3)N4 tetrahedra,  an edgeedge with one Li(5)N4 tetrahedra,  an edgeedge with one Li(7)N4 tetrahedra, and  an edgeedge with one Li(9)N4 tetrahedra. In the sixth Li site, Li(6) is bonded to one N(1), one N(5), and two equivalent N(3) atoms to form LiN4 tetrahedra that share  a cornercorner with one Li(2)N4 tetrahedra,  a cornercorner with one Li(3)N4 tetrahedra,  a cornercorner with one Li(7)N4 tetrahedra,  a cornercorner with one Li(8)N4 tetrahedra,  a cornercorner with one Cr(1)N4 tetrahedra, corners with two equivalent Li(4)N4 tetrahedra, corners with two equivalent Li(5)N4 tetrahedra, corners with three equivalent Li(9)N4 tetrahedra, corners with four equivalent Li(1)N4 tetrahedra,  an edgeedge with one Li(4)N4 tetrahedra,  an edgeedge with one Li(6)N4 tetrahedra,  an edgeedge with one Li(7)N4 tetrahedra,  an edgeedge with one Li(8)N4 tetrahedra,  an edgeedge with one Li(9)N4 tetrahedra, and  an edgeedge with one Cr(1)N4 tetrahedra. In the seventh Li site, Li(7) is bonded to one N(1), one N(3), and two equivalent N(4) atoms to form distorted LiN4 tetrahedra that share  a cornercorner with one Li(2)N4 tetrahedra,  a cornercorner with one Li(4)N4 tetrahedra,  a cornercorner with one Li(6)N4 tetrahedra,  a cornercorner with one Li(8)N4 tetrahedra,  a cornercorner with one Cr(1)N4 tetrahedra, corners with two equivalent Li(1)N4 tetrahedra, corners with two equivalent Li(5)N4 tetrahedra, corners with three equivalent Li(9)N4 tetrahedra, corners with four equivalent Li(3)N4 tetrahedra,  an edgeedge with one Li(1)N4 tetrahedra,  an edgeedge with one Li(2)N4 tetrahedra,  an edgeedge with one Li(5)N4 tetrahedra,  an edgeedge with one Li(6)N4 tetrahedra,  an edgeedge with one Li(7)N4 tetrahedra, and  an edgeedge with one Cr(1)N4 tetrahedra. In the eighth Li site, Li(8) is bonded to one N(1), one N(2), and two equivalent N(5) atoms to form distorted LiN4 tetrahedra that share  a cornercorner with one Li(1)N4 tetrahedra,  a cornercorner with one Li(2)N4 tetrahedra,  a cornercorner with one Li(6)N4 tetrahedra,  a cornercorner with one Li(7)N4 tetrahedra,  a cornercorner with one Cr(1)N4 tetrahedra, corners with two equivalent Li(9)N4 tetrahedra, corners with three equivalent Li(3)N4 tetrahedra, corners with three equivalent Li(4)N4 tetrahedra, corners with three equivalent Li(5)N4 tetrahedra,  an edgeedge with one Li(1)N4 tetrahedra,  an edgeedge with one Li(2)N4 tetrahedra,  an edgeedge with one Li(4)N4 tetrahedra,  an edgeedge with one Li(6)N4 tetrahedra,  an edgeedge with one Li(8)N4 tetrahedra, and  an edgeedge with one Cr(1)N4 tetrahedra. In the ninth Li site, Li(9) is bonded to one N(1), one N(2), and two equivalent N(3) atoms to form distorted LiN4 tetrahedra that share  a cornercorner with one Li(1)N4 tetrahedra,  a cornercorner with one Li(3)N4 tetrahedra,  a cornercorner with one Li(4)N4 tetrahedra,  a cornercorner with one Li(5)N4 tetrahedra,  a cornercorner with one Cr(1)N4 tetrahedra, corners with two equivalent Li(8)N4 tetrahedra, corners with three equivalent Li(2)N4 tetrahedra, corners with three equivalent Li(6)N4 tetrahedra, corners with three equivalent Li(7)N4 tetrahedra,  an edgeedge with one Li(1)N4 tetrahedra,  an edgeedge with one Li(4)N4 tetrahedra,  an edgeedge with one Li(5)N4 tetrahedra,  an edgeedge with one Li(6)N4 tetrahedra,  an edgeedge with one Li(9)N4 tetrahedra, and  an edgeedge with one Cr(1)N4 tetrahedra. Cr(1) is bonded to one N(2), one N(3), one N(4), and one N(5) atom to form CrN4 tetrahedra that share  a cornercorner with one Li(2)N4 tetrahedra,  a cornercorner with one Li(6)N4 tetrahedra,  a cornercorner with one Li(7)N4 tetrahedra,  a cornercorner with one Li(8)N4 tetrahedra,  a cornercorner with one Li(9)N4 tetrahedra, corners with two equivalent Li(3)N4 tetrahedra, corners with two equivalent Li(5)N4 tetrahedra, corners with three equivalent Li(1)N4 tetrahedra, corners with four equivalent Li(4)N4 tetrahedra,  an edgeedge with one Li(2)N4 tetrahedra,  an edgeedge with one Li(3)N4 tetrahedra,  an edgeedge with one Li(6)N4 tetrahedra,  an edgeedge with one Li(7)N4 tetrahedra,  an edgeedge with one Li(8)N4 tetrahedra, and  an edgeedge with one Li(9)N4 tetrahedra. There are five inequivalent N sites. In the first N site, N(1) is bonded in a body-centered cubic geometry to one Li(1), one Li(2), one Li(6), one Li(7), one Li(8), one Li(9), and two equivalent Li(5) atoms. In the second N site, N(2) is bonded in a distorted body-centered cubic geometry to one Li(3), one Li(4), one Li(5), one Li(8), one Li(9), two equivalent Li(2), and one Cr(1) atom. In the third N site, N(3) is bonded in a distorted body-centered cubic geometry to one Li(1), one Li(4), one Li(7), two equivalent Li(6), two equivalent Li(9), and one Cr(1) atom. In the fourth N site, N(4) is bonded in a 8-coordinate geometry to one Li(1), one Li(2), one Li(5), two equivalent Li(3), two equivalent Li(7), and one Cr(1) atom. In the fifth N site, N(5) is bonded in a distorted body-centered cubic geometry to one Li(1), one Li(3), one Li(6), two equivalent Li(4), two equivalent Li(8), and one Cr(1) atom. is represented by the CIF file [CIF]
data_Li9CrN5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.853
_cell_length_b   6.792
_cell_length_c   7.622
_cell_angle_alpha   76.913
_cell_angle_beta   75.101
_cell_angle_gamma   73.414
_symmetry_Int_Tables_number   1
_cell_volume   276.776
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.742  0.256  0.234  1.0
  Li  Li1  1  0.625  0.849  0.941  1.0
  Li  Li2  1  0.923  0.047  0.859  1.0
  Li  Li3  1  0.839  0.161  0.546  1.0
  Li  Li4  1  0.631  0.368  0.944  1.0
  Li  Li5  1  0.148  0.360  0.431  1.0
  Li  Li6  1  0.074  0.441  0.140  1.0
  Li  Li7  1  0.926  0.559  0.860  1.0
  Li  Li8  1  0.852  0.640  0.569  1.0
  Li  Li9  1  0.369  0.632  0.056  1.0
  Li  Li10  1  0.258  0.744  0.766  1.0
  Li  Li11  1  0.077  0.953  0.141  1.0
  Li  Li12  1  0.161  0.839  0.454  1.0
  Li  Li13  1  0.555  0.930  0.643  1.0
  Li  Li14  1  0.375  0.151  0.059  1.0
  Li  Li15  1  0.446  0.531  0.351  1.0
  Li  Li16  1  0.554  0.469  0.649  1.0
  Li  Li17  1  0.445  0.070  0.357  1.0
  Cr  Cr18  1  0.753  0.751  0.252  1.0
  Cr  Cr19  1  0.247  0.249  0.748  1.0
  N  N20  1  0.596  0.654  0.800  1.0
  N  N21  1  0.552  0.163  0.782  1.0
  N  N22  1  0.797  0.492  0.375  1.0
  N  N23  1  0.958  0.757  0.037  1.0
  N  N24  1  0.811  0.922  0.377  1.0
  N  N25  1  0.189  0.078  0.623  1.0
  N  N26  1  0.042  0.243  0.963  1.0
  N  N27  1  0.404  0.346  0.200  1.0
  N  N28  1  0.203  0.508  0.625  1.0
  N  N29  1  0.448  0.837  0.218  1.0
[/CIF]
.