The structure described by (Re(CO)5)2Pt(CO)2 is Cyanogen Chloride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Pt(CO)2 cluster and two Re(CO)5 clusters. In the Pt(CO)2 cluster, Pt(1) is bonded in a distorted linear geometry to two equivalent C(3) atoms. C(3) is bonded in a distorted linear geometry to one Pt(1) and one O(3) atom. O(3) is bonded in a single-bond geometry to one C(3) atom. In each Re(CO)5 cluster, Re(1) is bonded in a distorted square pyramidal geometry to one C(1), one C(2), one C(4), one C(5), and one C(6) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Re(1) and one O(4) atom. In the second C site, C(2) is bonded in a linear geometry to one Re(1) and one O(1,5) atom. In the third C site, C(4) is bonded in a linear geometry to one Re(1) and one O(6) atom. In the fourth C site, C(5) is bonded in a linear geometry to one Re(1) and one O(1,5) atom. In the fifth C site, C(6) is bonded in a linear geometry to one Re(1) and one O(2) atom. There are four inequivalent O sites. In the first O site, O(1,5) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(6) atom. In the third O site, O(4) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(4) atom. is represented by the CIF card [CIF]
data_Re2Pt(CO)12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.540
_cell_length_b   7.272
_cell_length_c   10.173
_cell_angle_alpha   71.539
_cell_angle_beta   85.406
_cell_angle_gamma   88.060
_symmetry_Int_Tables_number   1
_cell_volume   457.369
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.787  0.886  0.269  1.0
  Re  Re1  1  0.213  0.114  0.731  1.0
  Pt  Pt2  1  0.000  0.000  0.000  1.0
  C  C3  1  0.318  0.332  0.789  1.0
  C  C4  1  0.910  0.114  0.301  1.0
  C  C5  1  0.090  0.886  0.699  1.0
  C  C6  1  0.682  0.668  0.211  1.0
  C  C7  1  0.893  0.256  0.964  1.0
  C  C8  1  0.445  0.945  0.819  1.0
  C  C9  1  0.961  0.268  0.663  1.0
  C  C10  1  0.039  0.732  0.337  1.0
  C  C11  1  0.555  0.055  0.181  1.0
  C  C12  1  0.361  0.199  0.549  1.0
  C  C13  1  0.107  0.744  0.036  1.0
  C  C14  1  0.639  0.801  0.451  1.0
  O  O15  1  0.019  0.755  0.678  1.0
  O  O16  1  0.454  0.252  0.442  1.0
  O  O17  1  0.171  0.587  0.060  1.0
  O  O18  1  0.379  0.458  0.821  1.0
  O  O19  1  0.186  0.645  0.378  1.0
  O  O20  1  0.981  0.245  0.322  1.0
  O  O21  1  0.829  0.413  0.940  1.0
  O  O22  1  0.621  0.542  0.179  1.0
  O  O23  1  0.581  0.849  0.868  1.0
  O  O24  1  0.419  0.151  0.132  1.0
  O  O25  1  0.546  0.748  0.558  1.0
  O  O26  1  0.814  0.355  0.622  1.0
[/CIF]
.
The structure described by (Re(CO)5)2Pt(CO)2 is Cyanogen Chloride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Pt(CO)2 cluster and two Re(CO)5 clusters. In the Pt(CO)2 cluster, Pt(1) is bonded in a distorted linear geometry to two equivalent C(3) atoms. C(3) is bonded in a distorted linear geometry to one Pt(1) and one O(3) atom. O(3) is bonded in a single-bond geometry to one C(3) atom. In each Re(CO)5 cluster, Re(1) is bonded in a distorted square pyramidal geometry to one C(1), one C(2), one C(4), one C(5), and one C(6) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Re(1) and one O(4) atom. In the second C site, C(2) is bonded in a linear geometry to one Re(1) and one O(1,5) atom. In the third C site, C(4) is bonded in a linear geometry to one Re(1) and one O(6) atom. In the fourth C site, C(5) is bonded in a linear geometry to one Re(1) and one O(1,5) atom. In the fifth C site, C(6) is bonded in a linear geometry to one Re(1) and one O(2) atom. There are four inequivalent O sites. In the first O site, O(1,5) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(6) atom. In the third O site, O(4) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(4) atom. is represented by the CIF card [CIF]
data_Re2Pt(CO)12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.540
_cell_length_b   7.272
_cell_length_c   10.173
_cell_angle_alpha   71.539
_cell_angle_beta   85.406
_cell_angle_gamma   88.060
_symmetry_Int_Tables_number   1
_cell_volume   457.369
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.787  0.886  0.269  1.0
  Re  Re1  1  0.213  0.114  0.731  1.0
  Pt  Pt2  1  0.000  0.000  0.000  1.0
  C  C3  1  0.318  0.332  0.789  1.0
  C  C4  1  0.910  0.114  0.301  1.0
  C  C5  1  0.090  0.886  0.699  1.0
  C  C6  1  0.682  0.668  0.211  1.0
  C  C7  1  0.893  0.256  0.964  1.0
  C  C8  1  0.445  0.945  0.819  1.0
  C  C9  1  0.961  0.268  0.663  1.0
  C  C10  1  0.039  0.732  0.337  1.0
  C  C11  1  0.555  0.055  0.181  1.0
  C  C12  1  0.361  0.199  0.549  1.0
  C  C13  1  0.107  0.744  0.036  1.0
  C  C14  1  0.639  0.801  0.451  1.0
  O  O15  1  0.019  0.755  0.678  1.0
  O  O16  1  0.454  0.252  0.442  1.0
  O  O17  1  0.171  0.587  0.060  1.0
  O  O18  1  0.379  0.458  0.821  1.0
  O  O19  1  0.186  0.645  0.378  1.0
  O  O20  1  0.981  0.245  0.322  1.0
  O  O21  1  0.829  0.413  0.940  1.0
  O  O22  1  0.621  0.542  0.179  1.0
  O  O23  1  0.581  0.849  0.868  1.0
  O  O24  1  0.419  0.151  0.132  1.0
  O  O25  1  0.546  0.748  0.558  1.0
  O  O26  1  0.814  0.355  0.622  1.0
[/CIF]
.