The structure described by Li3Bi is Sodium arsenide structured and crystallizes in the hexagonal P6_3/mmc space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 11-coordinate geometry to three equivalent Li(2), four equivalent Li(1), and four equivalent Bi(1) atoms. In the second Li site, Li(2) is bonded in a trigonal planar geometry to six equivalent Li(1) and three equivalent Bi(1) atoms. Bi(1) is bonded in a 11-coordinate geometry to three equivalent Li(2) and eight equivalent Li(1) atoms. is represented by the CIF file [CIF]
data_Li3Bi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.806
_cell_length_b   4.806
_cell_length_c   8.535
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   170.768
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.333  0.667  0.912  1.0
  Li  Li1  1  0.667  0.333  0.412  1.0
  Li  Li2  1  0.000  0.000  0.250  1.0
  Li  Li3  1  0.000  0.000  0.750  1.0
  Li  Li4  1  0.333  0.667  0.588  1.0
  Li  Li5  1  0.667  0.333  0.088  1.0
  Bi  Bi6  1  0.667  0.333  0.750  1.0
  Bi  Bi7  1  0.333  0.667  0.250  1.0
[/CIF]
.
The structure described by Li3Bi is Sodium arsenide structured and crystallizes in the hexagonal P6_3/mmc space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a 11-coordinate geometry to three equivalent Li(2), four equivalent Li(1), and four equivalent Bi(1) atoms. In the second Li site, Li(2) is bonded in a trigonal planar geometry to six equivalent Li(1) and three equivalent Bi(1) atoms. Bi(1) is bonded in a 11-coordinate geometry to three equivalent Li(2) and eight equivalent Li(1) atoms. is represented by the CIF file [CIF]
data_Li3Bi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.806
_cell_length_b   4.806
_cell_length_c   8.535
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   170.768
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.333  0.667  0.912  1.0
  Li  Li1  1  0.667  0.333  0.412  1.0
  Li  Li2  1  0.000  0.000  0.250  1.0
  Li  Li3  1  0.000  0.000  0.750  1.0
  Li  Li4  1  0.333  0.667  0.588  1.0
  Li  Li5  1  0.667  0.333  0.088  1.0
  Bi  Bi6  1  0.667  0.333  0.750  1.0
  Bi  Bi7  1  0.333  0.667  0.250  1.0
[/CIF]
.