The structure described by Li3Mn5F15 crystallizes in the tetragonal P4bm space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a square co-planar geometry to four equivalent F(3) atoms. In the second Li site, Li(2) is bonded in a distorted T-shaped geometry to one F(5) and two equivalent F(2) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 0-42°. In the second Mn site, Mn(2) is bonded to one F(2), one F(5), two equivalent F(3), and two equivalent F(4) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 3-54°. There are five inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Mn(1) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Li(2), one Mn(1), and one Mn(2) atom. In the third F site, F(3) is bonded in a T-shaped geometry to one Li(1) and two equivalent Mn(2) atoms. In the fourth F site, F(4) is bonded in a linear geometry to two equivalent Mn(2) atoms. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Li(2) and two equivalent Mn(2) atoms. is represented by the CIF card [CIF]
data_Li3Mn5F15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.063
_cell_length_b   13.063
_cell_length_c   3.943
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   672.796
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.673  1.0
  Li  Li1  1  0.662  0.162  0.630  1.0
  Li  Li2  1  0.162  0.338  0.630  1.0
  Li  Li3  1  0.500  0.500  0.673  1.0
  Li  Li4  1  0.838  0.662  0.630  1.0
  Li  Li5  1  0.338  0.838  0.630  1.0
  Mn  Mn6  1  0.500  0.000  0.583  1.0
  Mn  Mn7  1  0.213  0.080  0.598  1.0
  Mn  Mn8  1  0.920  0.213  0.598  1.0
  Mn  Mn9  1  0.420  0.287  0.598  1.0
  Mn  Mn10  1  0.713  0.420  0.598  1.0
  Mn  Mn11  1  0.000  0.500  0.583  1.0
  Mn  Mn12  1  0.287  0.580  0.598  1.0
  Mn  Mn13  1  0.580  0.713  0.598  1.0
  Mn  Mn14  1  0.080  0.787  0.598  1.0
  Mn  Mn15  1  0.787  0.920  0.598  1.0
  F  F16  1  0.500  0.000  0.085  1.0
  F  F17  1  0.659  0.015  0.594  1.0
  F  F18  1  0.868  0.063  0.613  1.0
  F  F19  1  0.216  0.082  0.099  1.0
  F  F20  1  0.063  0.132  0.613  1.0
  F  F21  1  0.515  0.159  0.594  1.0
  F  F22  1  0.918  0.216  0.099  1.0
  F  F23  1  0.264  0.236  0.600  1.0
  F  F24  1  0.764  0.264  0.600  1.0
  F  F25  1  0.418  0.284  0.099  1.0
  F  F26  1  0.015  0.341  0.594  1.0
  F  F27  1  0.563  0.368  0.613  1.0
  F  F28  1  0.716  0.418  0.099  1.0
  F  F29  1  0.368  0.437  0.613  1.0
  F  F30  1  0.159  0.485  0.594  1.0
  F  F31  1  0.000  0.500  0.085  1.0
  F  F32  1  0.841  0.515  0.594  1.0
  F  F33  1  0.632  0.563  0.613  1.0
  F  F34  1  0.284  0.582  0.099  1.0
  F  F35  1  0.437  0.632  0.613  1.0
  F  F36  1  0.985  0.659  0.594  1.0
  F  F37  1  0.582  0.716  0.099  1.0
  F  F38  1  0.236  0.736  0.600  1.0
  F  F39  1  0.736  0.764  0.600  1.0
  F  F40  1  0.082  0.784  0.099  1.0
  F  F41  1  0.485  0.841  0.594  1.0
  F  F42  1  0.937  0.868  0.613  1.0
  F  F43  1  0.784  0.918  0.099  1.0
  F  F44  1  0.132  0.937  0.613  1.0
  F  F45  1  0.341  0.985  0.594  1.0
[/CIF]
.
The structure described by Li3Mn5F15 crystallizes in the tetragonal P4bm space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a square co-planar geometry to four equivalent F(3) atoms. In the second Li site, Li(2) is bonded in a distorted T-shaped geometry to one F(5) and two equivalent F(2) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 0-42°. In the second Mn site, Mn(2) is bonded to one F(2), one F(5), two equivalent F(3), and two equivalent F(4) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 3-54°. There are five inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Mn(1) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Li(2), one Mn(1), and one Mn(2) atom. In the third F site, F(3) is bonded in a T-shaped geometry to one Li(1) and two equivalent Mn(2) atoms. In the fourth F site, F(4) is bonded in a linear geometry to two equivalent Mn(2) atoms. In the fifth F site, F(5) is bonded in a trigonal planar geometry to one Li(2) and two equivalent Mn(2) atoms. is represented by the CIF card [CIF]
data_Li3Mn5F15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.063
_cell_length_b   13.063
_cell_length_c   3.943
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   672.796
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.000  0.000  0.673  1.0
  Li  Li1  1  0.662  0.162  0.630  1.0
  Li  Li2  1  0.162  0.338  0.630  1.0
  Li  Li3  1  0.500  0.500  0.673  1.0
  Li  Li4  1  0.838  0.662  0.630  1.0
  Li  Li5  1  0.338  0.838  0.630  1.0
  Mn  Mn6  1  0.500  0.000  0.583  1.0
  Mn  Mn7  1  0.213  0.080  0.598  1.0
  Mn  Mn8  1  0.920  0.213  0.598  1.0
  Mn  Mn9  1  0.420  0.287  0.598  1.0
  Mn  Mn10  1  0.713  0.420  0.598  1.0
  Mn  Mn11  1  0.000  0.500  0.583  1.0
  Mn  Mn12  1  0.287  0.580  0.598  1.0
  Mn  Mn13  1  0.580  0.713  0.598  1.0
  Mn  Mn14  1  0.080  0.787  0.598  1.0
  Mn  Mn15  1  0.787  0.920  0.598  1.0
  F  F16  1  0.500  0.000  0.085  1.0
  F  F17  1  0.659  0.015  0.594  1.0
  F  F18  1  0.868  0.063  0.613  1.0
  F  F19  1  0.216  0.082  0.099  1.0
  F  F20  1  0.063  0.132  0.613  1.0
  F  F21  1  0.515  0.159  0.594  1.0
  F  F22  1  0.918  0.216  0.099  1.0
  F  F23  1  0.264  0.236  0.600  1.0
  F  F24  1  0.764  0.264  0.600  1.0
  F  F25  1  0.418  0.284  0.099  1.0
  F  F26  1  0.015  0.341  0.594  1.0
  F  F27  1  0.563  0.368  0.613  1.0
  F  F28  1  0.716  0.418  0.099  1.0
  F  F29  1  0.368  0.437  0.613  1.0
  F  F30  1  0.159  0.485  0.594  1.0
  F  F31  1  0.000  0.500  0.085  1.0
  F  F32  1  0.841  0.515  0.594  1.0
  F  F33  1  0.632  0.563  0.613  1.0
  F  F34  1  0.284  0.582  0.099  1.0
  F  F35  1  0.437  0.632  0.613  1.0
  F  F36  1  0.985  0.659  0.594  1.0
  F  F37  1  0.582  0.716  0.099  1.0
  F  F38  1  0.236  0.736  0.600  1.0
  F  F39  1  0.736  0.764  0.600  1.0
  F  F40  1  0.082  0.784  0.099  1.0
  F  F41  1  0.485  0.841  0.594  1.0
  F  F42  1  0.937  0.868  0.613  1.0
  F  F43  1  0.784  0.918  0.099  1.0
  F  F44  1  0.132  0.937  0.613  1.0
  F  F45  1  0.341  0.985  0.594  1.0
[/CIF]
.