The compound described by (FeSO7Cl)2(O2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of six 7782-44-7 molecules and four FeSO7Cl clusters. In each FeSO7Cl cluster, Fe(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form FeO4 tetrahedra that share  a cornercorner with one S(1)O4 tetrahedra. S(1) is bonded to one O(5), one O(7), one O(8), and one O(9) atom to form SO4 tetrahedra that share  a cornercorner with one Fe(1)O4 tetrahedra. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(8) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(2) is bonded in a water-like geometry to one Fe(1) and one Cl(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one Fe(1) atom. In the sixth O site, O(4) is bonded in a single-bond geometry to one Fe(1) atom. In the seventh O site, O(5) is bonded in a bent 120 degrees geometry to one Fe(1) and one S(1) atom. Cl(1) is bonded in a single-bond geometry to one O(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_FeSClO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.022
_cell_length_b   11.197
_cell_length_c   14.124
_cell_angle_alpha   77.902
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1085.772
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.169  0.678  0.083  1.0
  Fe  Fe1  1  0.669  0.322  0.417  1.0
  Fe  Fe2  1  0.831  0.322  0.917  1.0
  Fe  Fe3  1  0.331  0.678  0.583  1.0
  S  S4  1  0.841  0.740  0.213  1.0
  S  S5  1  0.341  0.260  0.287  1.0
  S  S6  1  0.159  0.260  0.787  1.0
  S  S7  1  0.659  0.740  0.713  1.0
  Cl  Cl8  1  0.152  0.824  0.886  1.0
  Cl  Cl9  1  0.652  0.176  0.614  1.0
  Cl  Cl10  1  0.848  0.176  0.114  1.0
  Cl  Cl11  1  0.348  0.824  0.386  1.0
  O  O12  1  0.230  0.016  0.078  1.0
  O  O13  1  0.730  0.984  0.422  1.0
  O  O14  1  0.770  0.984  0.922  1.0
  O  O15  1  0.270  0.016  0.578  1.0
  O  O16  1  0.290  0.787  0.981  1.0
  O  O17  1  0.790  0.213  0.519  1.0
  O  O18  1  0.710  0.213  0.019  1.0
  O  O19  1  0.210  0.787  0.481  1.0
  O  O20  1  0.149  0.545  0.055  1.0
  O  O21  1  0.649  0.455  0.445  1.0
  O  O22  1  0.851  0.455  0.945  1.0
  O  O23  1  0.351  0.545  0.555  1.0
  O  O24  1  0.316  0.689  0.169  1.0
  O  O25  1  0.816  0.311  0.331  1.0
  O  O26  1  0.684  0.311  0.831  1.0
  O  O27  1  0.184  0.689  0.669  1.0
  O  O28  1  0.937  0.742  0.113  1.0
  O  O29  1  0.437  0.258  0.387  1.0
  O  O30  1  0.063  0.258  0.887  1.0
  O  O31  1  0.563  0.742  0.613  1.0
  O  O32  1  0.573  0.525  0.008  1.0
  O  O33  1  0.073  0.475  0.492  1.0
  O  O34  1  0.427  0.475  0.992  1.0
  O  O35  1  0.927  0.525  0.508  1.0
  O  O36  1  0.698  0.641  0.230  1.0
  O  O37  1  0.198  0.359  0.270  1.0
  O  O38  1  0.302  0.359  0.770  1.0
  O  O39  1  0.802  0.641  0.730  1.0
  O  O40  1  0.753  0.860  0.205  1.0
  O  O41  1  0.253  0.140  0.295  1.0
  O  O42  1  0.247  0.140  0.795  1.0
  O  O43  1  0.747  0.860  0.705  1.0
  O  O44  1  0.986  0.713  0.290  1.0
  O  O45  1  0.486  0.287  0.210  1.0
  O  O46  1  0.014  0.287  0.710  1.0
  O  O47  1  0.514  0.713  0.790  1.0
  O  O48  1  0.621  0.994  0.876  1.0
  O  O49  1  0.121  0.006  0.624  1.0
  O  O50  1  0.379  0.006  0.124  1.0
  O  O51  1  0.879  0.994  0.376  1.0
[/CIF]
.
The compound described by (FeSO7Cl)2(O2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of six 7782-44-7 molecules and four FeSO7Cl clusters. In each FeSO7Cl cluster, Fe(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form FeO4 tetrahedra that share  a cornercorner with one S(1)O4 tetrahedra. S(1) is bonded to one O(5), one O(7), one O(8), and one O(9) atom to form SO4 tetrahedra that share  a cornercorner with one Fe(1)O4 tetrahedra. There are seven inequivalent O sites. In the first O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(8) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(2) is bonded in a water-like geometry to one Fe(1) and one Cl(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one Fe(1) atom. In the sixth O site, O(4) is bonded in a single-bond geometry to one Fe(1) atom. In the seventh O site, O(5) is bonded in a bent 120 degrees geometry to one Fe(1) and one S(1) atom. Cl(1) is bonded in a single-bond geometry to one O(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_FeSClO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.022
_cell_length_b   11.197
_cell_length_c   14.124
_cell_angle_alpha   77.902
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1085.772
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.169  0.678  0.083  1.0
  Fe  Fe1  1  0.669  0.322  0.417  1.0
  Fe  Fe2  1  0.831  0.322  0.917  1.0
  Fe  Fe3  1  0.331  0.678  0.583  1.0
  S  S4  1  0.841  0.740  0.213  1.0
  S  S5  1  0.341  0.260  0.287  1.0
  S  S6  1  0.159  0.260  0.787  1.0
  S  S7  1  0.659  0.740  0.713  1.0
  Cl  Cl8  1  0.152  0.824  0.886  1.0
  Cl  Cl9  1  0.652  0.176  0.614  1.0
  Cl  Cl10  1  0.848  0.176  0.114  1.0
  Cl  Cl11  1  0.348  0.824  0.386  1.0
  O  O12  1  0.230  0.016  0.078  1.0
  O  O13  1  0.730  0.984  0.422  1.0
  O  O14  1  0.770  0.984  0.922  1.0
  O  O15  1  0.270  0.016  0.578  1.0
  O  O16  1  0.290  0.787  0.981  1.0
  O  O17  1  0.790  0.213  0.519  1.0
  O  O18  1  0.710  0.213  0.019  1.0
  O  O19  1  0.210  0.787  0.481  1.0
  O  O20  1  0.149  0.545  0.055  1.0
  O  O21  1  0.649  0.455  0.445  1.0
  O  O22  1  0.851  0.455  0.945  1.0
  O  O23  1  0.351  0.545  0.555  1.0
  O  O24  1  0.316  0.689  0.169  1.0
  O  O25  1  0.816  0.311  0.331  1.0
  O  O26  1  0.684  0.311  0.831  1.0
  O  O27  1  0.184  0.689  0.669  1.0
  O  O28  1  0.937  0.742  0.113  1.0
  O  O29  1  0.437  0.258  0.387  1.0
  O  O30  1  0.063  0.258  0.887  1.0
  O  O31  1  0.563  0.742  0.613  1.0
  O  O32  1  0.573  0.525  0.008  1.0
  O  O33  1  0.073  0.475  0.492  1.0
  O  O34  1  0.427  0.475  0.992  1.0
  O  O35  1  0.927  0.525  0.508  1.0
  O  O36  1  0.698  0.641  0.230  1.0
  O  O37  1  0.198  0.359  0.270  1.0
  O  O38  1  0.302  0.359  0.770  1.0
  O  O39  1  0.802  0.641  0.730  1.0
  O  O40  1  0.753  0.860  0.205  1.0
  O  O41  1  0.253  0.140  0.295  1.0
  O  O42  1  0.247  0.140  0.795  1.0
  O  O43  1  0.747  0.860  0.705  1.0
  O  O44  1  0.986  0.713  0.290  1.0
  O  O45  1  0.486  0.287  0.210  1.0
  O  O46  1  0.014  0.287  0.710  1.0
  O  O47  1  0.514  0.713  0.790  1.0
  O  O48  1  0.621  0.994  0.876  1.0
  O  O49  1  0.121  0.006  0.624  1.0
  O  O50  1  0.379  0.006  0.124  1.0
  O  O51  1  0.879  0.994  0.376  1.0
[/CIF]
.