The material described by S is alpha structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four octathiocane molecules. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(4) and one S(9) atom. In the second S site, S(4) is bonded in a water-like geometry to one S(1) and one S(12) atom. In the third S site, S(9) is bonded in a water-like geometry to one S(1) and one S(17) atom. In the fourth S site, S(12) is bonded in a water-like geometry to one S(20) and one S(4) atom. In the fifth S site, S(17) is bonded in a water-like geometry to one S(25) and one S(9) atom. In the sixth S site, S(20) is bonded in a water-like geometry to one S(12) and one S(28) atom. In the seventh S site, S(25) is bonded in a water-like geometry to one S(17) and one S(28) atom. In the eighth S site, S(28) is bonded in a water-like geometry to one S(20) and one S(25) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_S
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.722
_cell_length_b   14.147
_cell_length_c   9.620
_cell_angle_alpha   73.797
_cell_angle_beta   67.340
_cell_angle_gamma   38.863
_symmetry_Int_Tables_number   1
_cell_volume   1159.351
_cell_formula_units_Z   32
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.868  0.044  0.747  1.0
  S  S1  1  0.851  0.738  0.042  1.0
  S  S2  1  0.746  0.843  0.867  1.0
  S  S3  1  0.040  0.872  0.850  1.0
  S  S4  1  0.129  0.959  0.263  1.0
  S  S5  1  0.157  0.254  0.962  1.0
  S  S6  1  0.261  0.148  0.131  1.0
  S  S7  1  0.955  0.134  0.153  1.0
  S  S8  1  0.769  0.239  0.795  1.0
  S  S9  1  0.692  0.798  0.240  1.0
  S  S10  1  0.793  0.696  0.763  1.0
  S  S11  1  0.247  0.763  0.697  1.0
  S  S12  1  0.230  0.756  0.204  1.0
  S  S13  1  0.302  0.209  0.753  1.0
  S  S14  1  0.209  0.302  0.236  1.0
  S  S15  1  0.752  0.233  0.306  1.0
  S  S16  1  0.863  0.295  0.617  1.0
  S  S17  1  0.731  0.617  0.294  1.0
  S  S18  1  0.623  0.721  0.861  1.0
  S  S19  1  0.294  0.857  0.726  1.0
  S  S20  1  0.146  0.699  0.379  1.0
  S  S21  1  0.276  0.375  0.705  1.0
  S  S22  1  0.378  0.272  0.145  1.0
  S  S23  1  0.706  0.137  0.274  1.0
  S  S24  1  0.029  0.229  0.671  1.0
  S  S25  1  0.574  0.673  0.227  1.0
  S  S26  1  0.670  0.576  0.026  1.0
  S  S27  1  0.231  0.021  0.574  1.0
  S  S28  1  0.971  0.771  0.328  1.0
  S  S29  1  0.423  0.330  0.768  1.0
  S  S30  1  0.326  0.426  0.980  1.0
  S  S31  1  0.772  0.975  0.427  1.0
[/CIF]
.
The material described by S is alpha structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four octathiocane molecules. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(4) and one S(9) atom. In the second S site, S(4) is bonded in a water-like geometry to one S(1) and one S(12) atom. In the third S site, S(9) is bonded in a water-like geometry to one S(1) and one S(17) atom. In the fourth S site, S(12) is bonded in a water-like geometry to one S(20) and one S(4) atom. In the fifth S site, S(17) is bonded in a water-like geometry to one S(25) and one S(9) atom. In the sixth S site, S(20) is bonded in a water-like geometry to one S(12) and one S(28) atom. In the seventh S site, S(25) is bonded in a water-like geometry to one S(17) and one S(28) atom. In the eighth S site, S(28) is bonded in a water-like geometry to one S(20) and one S(25) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_S
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.722
_cell_length_b   14.147
_cell_length_c   9.620
_cell_angle_alpha   73.797
_cell_angle_beta   67.340
_cell_angle_gamma   38.863
_symmetry_Int_Tables_number   1
_cell_volume   1159.351
_cell_formula_units_Z   32
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.868  0.044  0.747  1.0
  S  S1  1  0.851  0.738  0.042  1.0
  S  S2  1  0.746  0.843  0.867  1.0
  S  S3  1  0.040  0.872  0.850  1.0
  S  S4  1  0.129  0.959  0.263  1.0
  S  S5  1  0.157  0.254  0.962  1.0
  S  S6  1  0.261  0.148  0.131  1.0
  S  S7  1  0.955  0.134  0.153  1.0
  S  S8  1  0.769  0.239  0.795  1.0
  S  S9  1  0.692  0.798  0.240  1.0
  S  S10  1  0.793  0.696  0.763  1.0
  S  S11  1  0.247  0.763  0.697  1.0
  S  S12  1  0.230  0.756  0.204  1.0
  S  S13  1  0.302  0.209  0.753  1.0
  S  S14  1  0.209  0.302  0.236  1.0
  S  S15  1  0.752  0.233  0.306  1.0
  S  S16  1  0.863  0.295  0.617  1.0
  S  S17  1  0.731  0.617  0.294  1.0
  S  S18  1  0.623  0.721  0.861  1.0
  S  S19  1  0.294  0.857  0.726  1.0
  S  S20  1  0.146  0.699  0.379  1.0
  S  S21  1  0.276  0.375  0.705  1.0
  S  S22  1  0.378  0.272  0.145  1.0
  S  S23  1  0.706  0.137  0.274  1.0
  S  S24  1  0.029  0.229  0.671  1.0
  S  S25  1  0.574  0.673  0.227  1.0
  S  S26  1  0.670  0.576  0.026  1.0
  S  S27  1  0.231  0.021  0.574  1.0
  S  S28  1  0.971  0.771  0.328  1.0
  S  S29  1  0.423  0.330  0.768  1.0
  S  S30  1  0.326  0.426  0.980  1.0
  S  S31  1  0.772  0.975  0.427  1.0
[/CIF]
.