The crystal structure described by YbAg(WO4)2 crystallizes in the monoclinic C2/m space group. Yb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted octahedral geometry to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms. In the second W site, W(2) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. Ag(1) is bonded in a distorted bent 150 degrees geometry to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Yb(1), one W(1), one W(2), and one Ag(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Yb(1) and one W(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Yb(1), one W(1), and one Ag(1) atom. In the fourth O site, O(4) is bonded to one W(1), two equivalent W(2), and one Ag(1) atom to form distorted edge-sharing OAgW3 tetrahedra. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Yb(1), one W(1), and one Ag(1) atom. is represented by the CIF card [CIF]
data_YbAg(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.488
_cell_length_b   7.488
_cell_length_c   7.256
_cell_angle_alpha   65.129
_cell_angle_beta   65.129
_cell_angle_gamma   94.730
_symmetry_Int_Tables_number   1
_cell_volume   317.829
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.705  0.295  0.000  1.0
  Yb  Yb1  1  0.295  0.705  0.000  1.0
  Ag  Ag2  1  0.710  0.710  0.510  1.0
  Ag  Ag3  1  0.290  0.290  0.490  1.0
  W  W4  1  0.223  0.223  0.007  1.0
  W  W5  1  0.777  0.777  0.993  1.0
  W  W6  1  0.830  0.170  0.500  1.0
  W  W7  1  0.170  0.830  0.500  1.0
  O  O8  1  0.348  0.102  0.233  1.0
  O  O9  1  0.652  0.898  0.767  1.0
  O  O10  1  0.898  0.652  0.767  1.0
  O  O11  1  0.102  0.348  0.233  1.0
  O  O12  1  0.674  0.213  0.364  1.0
  O  O13  1  0.326  0.787  0.636  1.0
  O  O14  1  0.787  0.326  0.636  1.0
  O  O15  1  0.213  0.674  0.364  1.0
  O  O16  1  0.694  0.946  0.110  1.0
  O  O17  1  0.306  0.054  0.890  1.0
  O  O18  1  0.054  0.306  0.890  1.0
  O  O19  1  0.946  0.694  0.110  1.0
  O  O20  1  0.977  0.977  0.340  1.0
  O  O21  1  0.023  0.023  0.660  1.0
  O  O22  1  0.545  0.545  0.168  1.0
  O  O23  1  0.455  0.455  0.832  1.0
[/CIF]
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The crystal structure described by YbAg(WO4)2 crystallizes in the monoclinic C2/m space group. Yb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a distorted octahedral geometry to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms. In the second W site, W(2) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms. Ag(1) is bonded in a distorted bent 150 degrees geometry to one O(4), one O(5), two equivalent O(1), and two equivalent O(3) atoms. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Yb(1), one W(1), one W(2), and one Ag(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Yb(1) and one W(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Yb(1), one W(1), and one Ag(1) atom. In the fourth O site, O(4) is bonded to one W(1), two equivalent W(2), and one Ag(1) atom to form distorted edge-sharing OAgW3 tetrahedra. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Yb(1), one W(1), and one Ag(1) atom. is represented by the CIF card [CIF]
data_YbAg(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.488
_cell_length_b   7.488
_cell_length_c   7.256
_cell_angle_alpha   65.129
_cell_angle_beta   65.129
_cell_angle_gamma   94.730
_symmetry_Int_Tables_number   1
_cell_volume   317.829
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.705  0.295  0.000  1.0
  Yb  Yb1  1  0.295  0.705  0.000  1.0
  Ag  Ag2  1  0.710  0.710  0.510  1.0
  Ag  Ag3  1  0.290  0.290  0.490  1.0
  W  W4  1  0.223  0.223  0.007  1.0
  W  W5  1  0.777  0.777  0.993  1.0
  W  W6  1  0.830  0.170  0.500  1.0
  W  W7  1  0.170  0.830  0.500  1.0
  O  O8  1  0.348  0.102  0.233  1.0
  O  O9  1  0.652  0.898  0.767  1.0
  O  O10  1  0.898  0.652  0.767  1.0
  O  O11  1  0.102  0.348  0.233  1.0
  O  O12  1  0.674  0.213  0.364  1.0
  O  O13  1  0.326  0.787  0.636  1.0
  O  O14  1  0.787  0.326  0.636  1.0
  O  O15  1  0.213  0.674  0.364  1.0
  O  O16  1  0.694  0.946  0.110  1.0
  O  O17  1  0.306  0.054  0.890  1.0
  O  O18  1  0.054  0.306  0.890  1.0
  O  O19  1  0.946  0.694  0.110  1.0
  O  O20  1  0.977  0.977  0.340  1.0
  O  O21  1  0.023  0.023  0.660  1.0
  O  O22  1  0.545  0.545  0.168  1.0
  O  O23  1  0.455  0.455  0.832  1.0
[/CIF]
.