The compound described by Tb2Rh3Si5 crystallizes in the monoclinic C2/c space group. Tb(1) is bonded in a 17-coordinate geometry to two equivalent Rh(1), five equivalent Rh(2), two equivalent Si(2), two equivalent Si(3), two equivalent Si(4), and four equivalent Si(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 6-coordinate geometry to four equivalent Tb(1), one Si(3), one Si(4), and four equivalent Si(1) atoms. In the second Rh site, Rh(2) is bonded in a 5-coordinate geometry to five equivalent Tb(1), one Si(1), one Si(3), one Si(4), and two equivalent Si(2) atoms. There are four inequivalent Si sites. In the first Si site, Si(1) is bonded in a 9-coordinate geometry to four equivalent Tb(1), one Rh(2), two equivalent Rh(1), one Si(3), and one Si(4) atom. In the second Si site, Si(2) is bonded in a 4-coordinate geometry to four equivalent Tb(1) and four equivalent Rh(2) atoms. In the third Si site, Si(3) is bonded in a 9-coordinate geometry to four equivalent Tb(1), one Rh(1), two equivalent Rh(2), and two equivalent Si(1) atoms. In the fourth Si site, Si(4) is bonded in a 3-coordinate geometry to four equivalent Tb(1), one Rh(1), two equivalent Rh(2), and two equivalent Si(1) atoms. is represented by the CIF card [CIF]
data_Tb2Si5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.668
_cell_length_b   8.088
_cell_length_c   8.088
_cell_angle_alpha   93.500
_cell_angle_beta   108.899
_cell_angle_gamma   108.899
_symmetry_Int_Tables_number   1
_cell_volume   326.132
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.239  0.866  0.599  1.0
  Tb  Tb1  1  0.261  0.401  0.134  1.0
  Tb  Tb2  1  0.761  0.134  0.401  1.0
  Tb  Tb3  1  0.739  0.599  0.866  1.0
  Si  Si4  1  0.161  0.057  0.266  1.0
  Si  Si5  1  0.339  0.734  0.943  1.0
  Si  Si6  1  0.839  0.943  0.734  1.0
  Si  Si7  1  0.661  0.266  0.057  1.0
  Si  Si8  1  0.250  0.512  0.488  1.0
  Si  Si9  1  0.750  0.488  0.512  1.0
  Si  Si10  1  0.250  0.776  0.224  1.0
  Si  Si11  1  0.750  0.789  0.211  1.0
  Si  Si12  1  0.250  0.211  0.789  1.0
  Si  Si13  1  0.750  0.224  0.776  1.0
  Rh  Rh14  1  0.750  0.998  0.002  1.0
  Rh  Rh15  1  0.126  0.461  0.740  1.0
  Rh  Rh16  1  0.626  0.740  0.461  1.0
  Rh  Rh17  1  0.874  0.539  0.260  1.0
  Rh  Rh18  1  0.250  0.002  0.998  1.0
  Rh  Rh19  1  0.374  0.260  0.539  1.0
[/CIF]
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The compound described by Tb2Rh3Si5 crystallizes in the monoclinic C2/c space group. Tb(1) is bonded in a 17-coordinate geometry to two equivalent Rh(1), five equivalent Rh(2), two equivalent Si(2), two equivalent Si(3), two equivalent Si(4), and four equivalent Si(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 6-coordinate geometry to four equivalent Tb(1), one Si(3), one Si(4), and four equivalent Si(1) atoms. In the second Rh site, Rh(2) is bonded in a 5-coordinate geometry to five equivalent Tb(1), one Si(1), one Si(3), one Si(4), and two equivalent Si(2) atoms. There are four inequivalent Si sites. In the first Si site, Si(1) is bonded in a 9-coordinate geometry to four equivalent Tb(1), one Rh(2), two equivalent Rh(1), one Si(3), and one Si(4) atom. In the second Si site, Si(2) is bonded in a 4-coordinate geometry to four equivalent Tb(1) and four equivalent Rh(2) atoms. In the third Si site, Si(3) is bonded in a 9-coordinate geometry to four equivalent Tb(1), one Rh(1), two equivalent Rh(2), and two equivalent Si(1) atoms. In the fourth Si site, Si(4) is bonded in a 3-coordinate geometry to four equivalent Tb(1), one Rh(1), two equivalent Rh(2), and two equivalent Si(1) atoms. is represented by the CIF card [CIF]
data_Tb2Si5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.668
_cell_length_b   8.088
_cell_length_c   8.088
_cell_angle_alpha   93.500
_cell_angle_beta   108.899
_cell_angle_gamma   108.899
_symmetry_Int_Tables_number   1
_cell_volume   326.132
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.239  0.866  0.599  1.0
  Tb  Tb1  1  0.261  0.401  0.134  1.0
  Tb  Tb2  1  0.761  0.134  0.401  1.0
  Tb  Tb3  1  0.739  0.599  0.866  1.0
  Si  Si4  1  0.161  0.057  0.266  1.0
  Si  Si5  1  0.339  0.734  0.943  1.0
  Si  Si6  1  0.839  0.943  0.734  1.0
  Si  Si7  1  0.661  0.266  0.057  1.0
  Si  Si8  1  0.250  0.512  0.488  1.0
  Si  Si9  1  0.750  0.488  0.512  1.0
  Si  Si10  1  0.250  0.776  0.224  1.0
  Si  Si11  1  0.750  0.789  0.211  1.0
  Si  Si12  1  0.250  0.211  0.789  1.0
  Si  Si13  1  0.750  0.224  0.776  1.0
  Rh  Rh14  1  0.750  0.998  0.002  1.0
  Rh  Rh15  1  0.126  0.461  0.740  1.0
  Rh  Rh16  1  0.626  0.740  0.461  1.0
  Rh  Rh17  1  0.874  0.539  0.260  1.0
  Rh  Rh18  1  0.250  0.002  0.998  1.0
  Rh  Rh19  1  0.374  0.260  0.539  1.0
[/CIF]
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