The structure described by Rb2CoPb(NO2)6 crystallizes in the orthorhombic Fmmm space group. Rb(1) is bonded to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms to form RbO12 cuboctahedra that share edges with six equivalent Rb(1)O12 cuboctahedra and faces with four equivalent Pb(1)O12 cuboctahedra. Co(1) is bonded in an octahedral geometry to two N(1,1); two equivalent N(2); and two N(3,3) atoms. Pb(1) is bonded to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms to form distorted PbO12 cuboctahedra that share faces with eight equivalent Rb(1)O12 cuboctahedra. There are nine inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(1) atoms. In the second N site, N(1) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(3) atoms. In the third N site, N(1) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(3) atoms. In the fourth N site, N(2) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(1) atoms. In the fifth N site, N(3) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(2) atoms. In the sixth N site, N(3) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(2) atoms. In the seventh N site, N(2) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(1) atoms. In the eighth N site, N(1) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(3) atoms. In the ninth N site, N(3) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Rb(1), one Pb(1), and one N(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent Rb(1), one Pb(1), and one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent Rb(1), one Pb(1), and one N(1) atom. is represented by the CIF file [CIF]
data_Rb2CoPb(NO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.570
_cell_length_b   7.697
_cell_length_c   7.547
_cell_angle_alpha   59.539
_cell_angle_beta   61.220
_cell_angle_gamma   59.248
_symmetry_Int_Tables_number   1
_cell_volume   310.738
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.750  0.750  1.0
  Rb  Rb1  1  0.250  0.250  0.250  1.0
  Co  Co2  1  0.000  1.000  0.000  1.0
  Pb  Pb3  1  0.500  0.500  0.500  1.0
  N  N4  1  0.195  0.805  0.805  1.0
  N  N5  1  0.804  0.804  0.196  1.0
  N  N6  1  0.813  0.187  0.813  1.0
  N  N7  1  0.187  0.813  0.187  1.0
  N  N8  1  0.196  0.196  0.804  1.0
  N  N9  1  0.805  0.195  0.195  1.0
  O  O10  1  0.153  0.358  0.642  1.0
  O  O11  1  0.846  0.641  0.359  1.0
  O  O12  1  0.348  0.652  0.150  1.0
  O  O13  1  0.641  0.847  0.154  1.0
  O  O14  1  0.359  0.153  0.847  1.0
  O  O15  1  0.353  0.843  0.646  1.0
  O  O16  1  0.150  0.850  0.348  1.0
  O  O17  1  0.652  0.348  0.850  1.0
  O  O18  1  0.157  0.646  0.843  1.0
  O  O19  1  0.646  0.157  0.354  1.0
  O  O20  1  0.850  0.150  0.652  1.0
  O  O21  1  0.843  0.354  0.157  1.0
[/CIF]
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The structure described by Rb2CoPb(NO2)6 crystallizes in the orthorhombic Fmmm space group. Rb(1) is bonded to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms to form RbO12 cuboctahedra that share edges with six equivalent Rb(1)O12 cuboctahedra and faces with four equivalent Pb(1)O12 cuboctahedra. Co(1) is bonded in an octahedral geometry to two N(1,1); two equivalent N(2); and two N(3,3) atoms. Pb(1) is bonded to four equivalent O(1), four equivalent O(2), and four equivalent O(3) atoms to form distorted PbO12 cuboctahedra that share faces with eight equivalent Rb(1)O12 cuboctahedra. There are nine inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(1) atoms. In the second N site, N(1) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(3) atoms. In the third N site, N(1) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(3) atoms. In the fourth N site, N(2) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(1) atoms. In the fifth N site, N(3) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(2) atoms. In the sixth N site, N(3) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(2) atoms. In the seventh N site, N(2) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(1) atoms. In the eighth N site, N(1) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(3) atoms. In the ninth N site, N(3) is bonded in a trigonal planar geometry to one Co(1) and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to two equivalent Rb(1), one Pb(1), and one N(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent Rb(1), one Pb(1), and one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent Rb(1), one Pb(1), and one N(1) atom. is represented by the CIF file [CIF]
data_Rb2CoPb(NO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.570
_cell_length_b   7.697
_cell_length_c   7.547
_cell_angle_alpha   59.539
_cell_angle_beta   61.220
_cell_angle_gamma   59.248
_symmetry_Int_Tables_number   1
_cell_volume   310.738
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.750  0.750  0.750  1.0
  Rb  Rb1  1  0.250  0.250  0.250  1.0
  Co  Co2  1  0.000  1.000  0.000  1.0
  Pb  Pb3  1  0.500  0.500  0.500  1.0
  N  N4  1  0.195  0.805  0.805  1.0
  N  N5  1  0.804  0.804  0.196  1.0
  N  N6  1  0.813  0.187  0.813  1.0
  N  N7  1  0.187  0.813  0.187  1.0
  N  N8  1  0.196  0.196  0.804  1.0
  N  N9  1  0.805  0.195  0.195  1.0
  O  O10  1  0.153  0.358  0.642  1.0
  O  O11  1  0.846  0.641  0.359  1.0
  O  O12  1  0.348  0.652  0.150  1.0
  O  O13  1  0.641  0.847  0.154  1.0
  O  O14  1  0.359  0.153  0.847  1.0
  O  O15  1  0.353  0.843  0.646  1.0
  O  O16  1  0.150  0.850  0.348  1.0
  O  O17  1  0.652  0.348  0.850  1.0
  O  O18  1  0.157  0.646  0.843  1.0
  O  O19  1  0.646  0.157  0.354  1.0
  O  O20  1  0.850  0.150  0.652  1.0
  O  O21  1  0.843  0.354  0.157  1.0
[/CIF]
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