The compound described by (Li3P3H4O11)4O2 crystallizes in the triclinic P1 space group. The structure consists of one water atom inside a Li3P3H4O11 framework. In the Li3P3H4O11 framework, there are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(13), one O(16), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. In the second Li site, Li(2) is bonded to one O(12), one O(14), one O(15), and one O(4) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the third Li site, Li(3) is bonded to one O(20), one O(22), one O(3), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. In the fourth Li site, Li(4) is bonded to one O(19), one O(21), one O(4), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the fifth Li site, Li(5) is bonded in a distorted trigonal planar geometry to one O(16), one O(5), and one O(8) atom. In the sixth Li site, Li(6) is bonded in a trigonal planar geometry to one O(15), one O(6), and one O(7) atom. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(13), one O(2), one O(4), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(10), one O(14), and one O(3) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the third P site, P(3) is bonded to one O(1), one O(17), one O(19), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. In the fourth P site, P(4) is bonded to one O(18), one O(2), one O(20), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the fifth P site, P(5) is bonded to one O(16), one O(17), one O(22), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. In the sixth P site, P(6) is bonded to one O(10), one O(15), one O(18), and one O(21) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(11) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(12) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(12) atom. There are twenty-two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one Li(3), and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(2), one Li(4), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Li(5), one H(1), and one H(5) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(6), one H(2), and one H(6) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one Li(6), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Li(4), one Li(5), and one P(4) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one P(1) and one P(5) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one P(2) and one P(6) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Li(1), one H(3), and one H(7) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Li(2), one H(4), and one H(8) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Li(1) and one P(1) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Li(2) and one P(2) atom. In the fifteenth O site, O(15) is bonded in a trigonal planar geometry to one Li(2), one Li(6), and one P(6) atom. In the sixteenth O site, O(16) is bonded in a trigonal planar geometry to one Li(1), one Li(5), and one P(5) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one P(3) and one P(5) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one P(4) and one P(6) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Li(4) and one P(3) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Li(3) and one P(4) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Li(4) and one P(6) atom. In the twenty-second O site, O(22) is bonded in a bent 150 degrees geometry to one Li(3) and one P(5) atom. is represented by the CIF card [CIF]
data_Li6P6H8O23
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.237
_cell_length_b   8.182
_cell_length_c   9.902
_cell_angle_alpha   115.527
_cell_angle_beta   115.649
_cell_angle_gamma   70.620
_symmetry_Int_Tables_number   1
_cell_volume   534.083
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.223  0.597  0.677  1.0
  Li  Li1  1  0.778  0.401  0.325  1.0
  Li  Li2  1  0.142  0.019  0.848  1.0
  Li  Li3  1  0.863  0.978  0.151  1.0
  Li  Li4  1  0.092  0.584  0.940  1.0
  Li  Li5  1  0.903  0.414  0.059  1.0
  P  P6  1  0.177  0.218  0.417  1.0
  P  P7  1  0.823  0.783  0.581  1.0
  P  P8  1  0.714  0.105  0.836  1.0
  P  P9  1  0.285  0.897  0.164  1.0
  P  P10  1  0.311  0.259  0.761  1.0
  P  P11  1  0.689  0.740  0.238  1.0
  H  H12  1  0.815  0.526  0.714  1.0
  H  H13  1  0.175  0.470  0.278  1.0
  H  H14  1  0.487  0.700  0.701  1.0
  H  H15  1  0.483  0.333  0.299  1.0
  H  H16  1  0.841  0.382  0.792  1.0
  H  H17  1  0.155  0.617  0.207  1.0
  H  H18  1  0.536  0.729  0.881  1.0
  H  H19  1  0.478  0.260  0.124  1.0
  O  O20  1  0.683  0.937  0.667  1.0
  O  O21  1  0.318  0.062  0.334  1.0
  O  O22  1  0.017  0.809  0.683  1.0
  O  O23  1  0.983  0.191  0.315  1.0
  O  O24  1  0.858  0.506  0.816  1.0
  O  O25  1  0.139  0.490  0.177  1.0
  O  O26  1  0.861  0.201  0.863  1.0
  O  O27  1  0.137  0.801  0.133  1.0
  O  O28  1  0.230  0.159  0.570  1.0
  O  O29  1  0.767  0.843  0.429  1.0
  O  O30  1  0.449  0.685  0.774  1.0
  O  O31  1  0.556  0.308  0.235  1.0
  O  O32  1  0.224  0.403  0.466  1.0
  O  O33  1  0.775  0.598  0.532  1.0
  O  O34  1  0.767  0.537  0.200  1.0
  O  O35  1  0.232  0.463  0.801  1.0
  O  O36  1  0.524  0.245  0.792  1.0
  O  O37  1  0.475  0.756  0.205  1.0
  O  O38  1  0.734  0.040  0.962  1.0
  O  O39  1  0.266  0.967  0.041  1.0
  O  O40  1  0.717  0.842  0.159  1.0
  O  O41  1  0.285  0.154  0.838  1.0
  O  O42  1  0.346  0.719  0.484  1.0
[/CIF]
.
The compound described by (Li3P3H4O11)4O2 crystallizes in the triclinic P1 space group. The structure consists of one water atom inside a Li3P3H4O11 framework. In the Li3P3H4O11 framework, there are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(13), one O(16), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. In the second Li site, Li(2) is bonded to one O(12), one O(14), one O(15), and one O(4) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the third Li site, Li(3) is bonded to one O(20), one O(22), one O(3), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. In the fourth Li site, Li(4) is bonded to one O(19), one O(21), one O(4), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the fifth Li site, Li(5) is bonded in a distorted trigonal planar geometry to one O(16), one O(5), and one O(8) atom. In the sixth Li site, Li(6) is bonded in a trigonal planar geometry to one O(15), one O(6), and one O(7) atom. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(13), one O(2), one O(4), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(10), one O(14), and one O(3) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the third P site, P(3) is bonded to one O(1), one O(17), one O(19), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. In the fourth P site, P(4) is bonded to one O(18), one O(2), one O(20), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. In the fifth P site, P(5) is bonded to one O(16), one O(17), one O(22), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. In the sixth P site, P(6) is bonded to one O(10), one O(15), one O(18), and one O(21) atom to form PO4 tetrahedra that share  a cornercorner with one Li(2)O4 tetrahedra,  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(11) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(12) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(12) atom. There are twenty-two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(4) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Li(1), one Li(3), and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(2), one Li(4), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Li(5), one H(1), and one H(5) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(6), one H(2), and one H(6) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Li(3), one Li(6), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Li(4), one Li(5), and one P(4) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one P(1) and one P(5) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one P(2) and one P(6) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Li(1), one H(3), and one H(7) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Li(2), one H(4), and one H(8) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Li(1) and one P(1) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Li(2) and one P(2) atom. In the fifteenth O site, O(15) is bonded in a trigonal planar geometry to one Li(2), one Li(6), and one P(6) atom. In the sixteenth O site, O(16) is bonded in a trigonal planar geometry to one Li(1), one Li(5), and one P(5) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one P(3) and one P(5) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one P(4) and one P(6) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Li(4) and one P(3) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Li(3) and one P(4) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Li(4) and one P(6) atom. In the twenty-second O site, O(22) is bonded in a bent 150 degrees geometry to one Li(3) and one P(5) atom. is represented by the CIF card [CIF]
data_Li6P6H8O23
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.237
_cell_length_b   8.182
_cell_length_c   9.902
_cell_angle_alpha   115.527
_cell_angle_beta   115.649
_cell_angle_gamma   70.620
_symmetry_Int_Tables_number   1
_cell_volume   534.083
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.223  0.597  0.677  1.0
  Li  Li1  1  0.778  0.401  0.325  1.0
  Li  Li2  1  0.142  0.019  0.848  1.0
  Li  Li3  1  0.863  0.978  0.151  1.0
  Li  Li4  1  0.092  0.584  0.940  1.0
  Li  Li5  1  0.903  0.414  0.059  1.0
  P  P6  1  0.177  0.218  0.417  1.0
  P  P7  1  0.823  0.783  0.581  1.0
  P  P8  1  0.714  0.105  0.836  1.0
  P  P9  1  0.285  0.897  0.164  1.0
  P  P10  1  0.311  0.259  0.761  1.0
  P  P11  1  0.689  0.740  0.238  1.0
  H  H12  1  0.815  0.526  0.714  1.0
  H  H13  1  0.175  0.470  0.278  1.0
  H  H14  1  0.487  0.700  0.701  1.0
  H  H15  1  0.483  0.333  0.299  1.0
  H  H16  1  0.841  0.382  0.792  1.0
  H  H17  1  0.155  0.617  0.207  1.0
  H  H18  1  0.536  0.729  0.881  1.0
  H  H19  1  0.478  0.260  0.124  1.0
  O  O20  1  0.683  0.937  0.667  1.0
  O  O21  1  0.318  0.062  0.334  1.0
  O  O22  1  0.017  0.809  0.683  1.0
  O  O23  1  0.983  0.191  0.315  1.0
  O  O24  1  0.858  0.506  0.816  1.0
  O  O25  1  0.139  0.490  0.177  1.0
  O  O26  1  0.861  0.201  0.863  1.0
  O  O27  1  0.137  0.801  0.133  1.0
  O  O28  1  0.230  0.159  0.570  1.0
  O  O29  1  0.767  0.843  0.429  1.0
  O  O30  1  0.449  0.685  0.774  1.0
  O  O31  1  0.556  0.308  0.235  1.0
  O  O32  1  0.224  0.403  0.466  1.0
  O  O33  1  0.775  0.598  0.532  1.0
  O  O34  1  0.767  0.537  0.200  1.0
  O  O35  1  0.232  0.463  0.801  1.0
  O  O36  1  0.524  0.245  0.792  1.0
  O  O37  1  0.475  0.756  0.205  1.0
  O  O38  1  0.734  0.040  0.962  1.0
  O  O39  1  0.266  0.967  0.041  1.0
  O  O40  1  0.717  0.842  0.159  1.0
  O  O41  1  0.285  0.154  0.838  1.0
  O  O42  1  0.346  0.719  0.484  1.0
[/CIF]
.