The material structure described by CsWSbO6 crystallizes in the orthorhombic Ima2 space group. Cs(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted CsO6 octahedra that share corners with six equivalent W(1)O6 octahedra and corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 67-74°. W(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-74°. Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent W(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-70°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Cs(1) and two equivalent W(1) atoms. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one W(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Cs(1), one W(1), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsSbWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.410
_cell_length_b   7.410
_cell_length_c   7.410
_cell_angle_alpha   120.727
_cell_angle_beta   119.694
_cell_angle_gamma   89.638
_symmetry_Int_Tables_number   1
_cell_volume   286.703
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.617  0.882  0.235  1.0
  Cs  Cs1  1  0.353  0.118  0.735  1.0
  Sb  Sb2  1  0.999  0.500  0.499  1.0
  Sb  Sb3  1  0.999  0.000  0.999  1.0
  W  W4  1  0.998  0.500  0.998  1.0
  W  W5  1  0.498  0.500  0.498  1.0
  O  O6  1  0.074  0.823  0.751  1.0
  O  O7  1  0.691  0.442  0.749  1.0
  O  O8  1  0.680  0.811  0.746  1.0
  O  O9  1  0.064  0.436  0.754  1.0
  O  O10  1  0.064  0.810  0.128  1.0
  O  O11  1  0.680  0.434  0.369  1.0
  O  O12  1  0.928  0.177  0.251  1.0
  O  O13  1  0.307  0.558  0.249  1.0
  O  O14  1  0.318  0.190  0.254  1.0
  O  O15  1  0.935  0.566  0.246  1.0
  O  O16  1  0.935  0.189  0.869  1.0
  O  O17  1  0.318  0.564  0.628  1.0
[/CIF]
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The material structure described by CsWSbO6 crystallizes in the orthorhombic Ima2 space group. Cs(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted CsO6 octahedra that share corners with six equivalent W(1)O6 octahedra and corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 67-74°. W(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-74°. Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with four equivalent W(1)O6 octahedra, and corners with six equivalent Cs(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-70°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Cs(1) and two equivalent W(1) atoms. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one W(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Cs(1), one W(1), and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsSbWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.410
_cell_length_b   7.410
_cell_length_c   7.410
_cell_angle_alpha   120.727
_cell_angle_beta   119.694
_cell_angle_gamma   89.638
_symmetry_Int_Tables_number   1
_cell_volume   286.703
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.617  0.882  0.235  1.0
  Cs  Cs1  1  0.353  0.118  0.735  1.0
  Sb  Sb2  1  0.999  0.500  0.499  1.0
  Sb  Sb3  1  0.999  0.000  0.999  1.0
  W  W4  1  0.998  0.500  0.998  1.0
  W  W5  1  0.498  0.500  0.498  1.0
  O  O6  1  0.074  0.823  0.751  1.0
  O  O7  1  0.691  0.442  0.749  1.0
  O  O8  1  0.680  0.811  0.746  1.0
  O  O9  1  0.064  0.436  0.754  1.0
  O  O10  1  0.064  0.810  0.128  1.0
  O  O11  1  0.680  0.434  0.369  1.0
  O  O12  1  0.928  0.177  0.251  1.0
  O  O13  1  0.307  0.558  0.249  1.0
  O  O14  1  0.318  0.190  0.254  1.0
  O  O15  1  0.935  0.566  0.246  1.0
  O  O16  1  0.935  0.189  0.869  1.0
  O  O17  1  0.318  0.564  0.628  1.0
[/CIF]
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