The crystal structure described by WNTeCl4F5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one WNTeCl4F5 cluster. W(1) is bonded in a 6-coordinate geometry to one N(1), one Cl(1), one Cl(2), one Cl(3), and two equivalent Cl(4) atoms. N(1) is bonded in a linear geometry to one W(1) and one Te(1) atom. Te(1) is bonded in an octahedral geometry to one N(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one W(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to two equivalent W(1) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeWNCl4F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.391
_cell_length_b   6.414
_cell_length_c   14.299
_cell_angle_alpha   83.874
_cell_angle_beta   86.541
_cell_angle_gamma   80.897
_symmetry_Int_Tables_number   1
_cell_volume   574.903
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.257  0.204  0.628  1.0
  Te  Te1  1  0.743  0.796  0.372  1.0
  W  W2  1  0.035  0.977  0.857  1.0
  W  W3  1  0.965  0.023  0.143  1.0
  N  N4  1  0.151  0.102  0.755  1.0
  N  N5  1  0.849  0.898  0.245  1.0
  Cl  Cl6  1  0.707  0.192  0.859  1.0
  Cl  Cl7  1  0.326  0.730  0.902  1.0
  Cl  Cl8  1  0.888  0.719  0.796  1.0
  Cl  Cl9  1  0.136  0.195  0.971  1.0
  Cl  Cl10  1  0.293  0.808  0.141  1.0
  Cl  Cl11  1  0.674  0.270  0.098  1.0
  Cl  Cl12  1  0.864  0.805  0.029  1.0
  Cl  Cl13  1  0.112  0.281  0.204  1.0
  F  F14  1  0.993  0.371  0.605  1.0
  F  F15  1  0.524  0.041  0.648  1.0
  F  F16  1  0.644  0.701  0.492  1.0
  F  F17  1  0.356  0.299  0.508  1.0
  F  F18  1  0.349  0.433  0.676  1.0
  F  F19  1  0.476  0.959  0.352  1.0
  F  F20  1  0.168  0.977  0.577  1.0
  F  F21  1  0.651  0.567  0.324  1.0
  F  F22  1  0.007  0.629  0.395  1.0
  F  F23  1  0.832  0.023  0.423  1.0
[/CIF]
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The crystal structure described by WNTeCl4F5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one WNTeCl4F5 cluster. W(1) is bonded in a 6-coordinate geometry to one N(1), one Cl(1), one Cl(2), one Cl(3), and two equivalent Cl(4) atoms. N(1) is bonded in a linear geometry to one W(1) and one Te(1) atom. Te(1) is bonded in an octahedral geometry to one N(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one W(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to two equivalent W(1) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeWNCl4F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.391
_cell_length_b   6.414
_cell_length_c   14.299
_cell_angle_alpha   83.874
_cell_angle_beta   86.541
_cell_angle_gamma   80.897
_symmetry_Int_Tables_number   1
_cell_volume   574.903
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.257  0.204  0.628  1.0
  Te  Te1  1  0.743  0.796  0.372  1.0
  W  W2  1  0.035  0.977  0.857  1.0
  W  W3  1  0.965  0.023  0.143  1.0
  N  N4  1  0.151  0.102  0.755  1.0
  N  N5  1  0.849  0.898  0.245  1.0
  Cl  Cl6  1  0.707  0.192  0.859  1.0
  Cl  Cl7  1  0.326  0.730  0.902  1.0
  Cl  Cl8  1  0.888  0.719  0.796  1.0
  Cl  Cl9  1  0.136  0.195  0.971  1.0
  Cl  Cl10  1  0.293  0.808  0.141  1.0
  Cl  Cl11  1  0.674  0.270  0.098  1.0
  Cl  Cl12  1  0.864  0.805  0.029  1.0
  Cl  Cl13  1  0.112  0.281  0.204  1.0
  F  F14  1  0.993  0.371  0.605  1.0
  F  F15  1  0.524  0.041  0.648  1.0
  F  F16  1  0.644  0.701  0.492  1.0
  F  F17  1  0.356  0.299  0.508  1.0
  F  F18  1  0.349  0.433  0.676  1.0
  F  F19  1  0.476  0.959  0.352  1.0
  F  F20  1  0.168  0.977  0.577  1.0
  F  F21  1  0.651  0.567  0.324  1.0
  F  F22  1  0.007  0.629  0.395  1.0
  F  F23  1  0.832  0.023  0.423  1.0
[/CIF]
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