The material structure described by SbRe2O6 crystallizes in the monoclinic C2/c space group. Re(1) is bonded to one O(1), two equivalent O(2), and three equivalent O(3) atoms to form a mixture of edge and corner-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 34-43°. Sb(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Re(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Re(1) atoms. In the third O site, O(3) is bonded in a 3-coordinate geometry to three equivalent Re(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re2SbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.418
_cell_length_b   8.418
_cell_length_c   5.505
_cell_angle_alpha   88.377
_cell_angle_beta   88.377
_cell_angle_gamma   34.262
_symmetry_Int_Tables_number   1
_cell_volume   219.492
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.414  0.948  0.609  1.0
  Re  Re1  1  0.052  0.586  0.891  1.0
  Re  Re2  1  0.586  0.052  0.391  1.0
  Re  Re3  1  0.948  0.414  0.109  1.0
  Sb  Sb4  1  0.304  0.696  0.250  1.0
  Sb  Sb5  1  0.696  0.304  0.750  1.0
  O  O6  1  0.481  0.657  0.573  1.0
  O  O7  1  0.343  0.519  0.927  1.0
  O  O8  1  0.519  0.343  0.427  1.0
  O  O9  1  0.657  0.481  0.073  1.0
  O  O10  1  0.111  0.169  0.386  1.0
  O  O11  1  0.831  0.889  0.114  1.0
  O  O12  1  0.739  0.692  0.828  1.0
  O  O13  1  0.308  0.261  0.672  1.0
  O  O14  1  0.261  0.308  0.172  1.0
  O  O15  1  0.692  0.739  0.328  1.0
  O  O16  1  0.169  0.111  0.886  1.0
  O  O17  1  0.889  0.831  0.614  1.0
[/CIF]
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The material structure described by SbRe2O6 crystallizes in the monoclinic C2/c space group. Re(1) is bonded to one O(1), two equivalent O(2), and three equivalent O(3) atoms to form a mixture of edge and corner-sharing ReO6 octahedra. The corner-sharing octahedral tilt angles range from 34-43°. Sb(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Re(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Re(1) atoms. In the third O site, O(3) is bonded in a 3-coordinate geometry to three equivalent Re(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Re2SbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.418
_cell_length_b   8.418
_cell_length_c   5.505
_cell_angle_alpha   88.377
_cell_angle_beta   88.377
_cell_angle_gamma   34.262
_symmetry_Int_Tables_number   1
_cell_volume   219.492
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.414  0.948  0.609  1.0
  Re  Re1  1  0.052  0.586  0.891  1.0
  Re  Re2  1  0.586  0.052  0.391  1.0
  Re  Re3  1  0.948  0.414  0.109  1.0
  Sb  Sb4  1  0.304  0.696  0.250  1.0
  Sb  Sb5  1  0.696  0.304  0.750  1.0
  O  O6  1  0.481  0.657  0.573  1.0
  O  O7  1  0.343  0.519  0.927  1.0
  O  O8  1  0.519  0.343  0.427  1.0
  O  O9  1  0.657  0.481  0.073  1.0
  O  O10  1  0.111  0.169  0.386  1.0
  O  O11  1  0.831  0.889  0.114  1.0
  O  O12  1  0.739  0.692  0.828  1.0
  O  O13  1  0.308  0.261  0.672  1.0
  O  O14  1  0.261  0.308  0.172  1.0
  O  O15  1  0.692  0.739  0.328  1.0
  O  O16  1  0.169  0.111  0.886  1.0
  O  O17  1  0.889  0.831  0.614  1.0
[/CIF]
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