The compound described by Pd(AuF4)2 crystallizes in the monoclinic P2_1/c space group. Pd(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Pd(1) and one Au(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Pd(1) and one Au(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Pd(1) and one Au(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Au(1) atom. is represented by the CIF file [CIF]
data_Pd(AuF4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.972
_cell_length_b   5.115
_cell_length_c   7.578
_cell_angle_alpha   47.232
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   312.184
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.500  0.500  0.500  1.0
  Pd  Pd1  1  0.000  0.500  0.000  1.0
  Au  Au2  1  0.687  0.245  0.020  1.0
  Au  Au3  1  0.187  0.755  0.480  1.0
  Au  Au4  1  0.813  0.245  0.520  1.0
  Au  Au5  1  0.313  0.755  0.980  1.0
  F  F6  1  0.471  0.942  0.818  1.0
  F  F7  1  0.971  0.058  0.682  1.0
  F  F8  1  0.529  0.058  0.182  1.0
  F  F9  1  0.029  0.942  0.318  1.0
  F  F10  1  0.896  0.565  0.207  1.0
  F  F11  1  0.396  0.435  0.293  1.0
  F  F12  1  0.846  0.425  0.859  1.0
  F  F13  1  0.346  0.575  0.641  1.0
  F  F14  1  0.154  0.575  0.141  1.0
  F  F15  1  0.654  0.425  0.359  1.0
  F  F16  1  0.271  0.052  0.177  1.0
  F  F17  1  0.771  0.948  0.323  1.0
  F  F18  1  0.729  0.948  0.823  1.0
  F  F19  1  0.229  0.052  0.677  1.0
  F  F20  1  0.604  0.565  0.707  1.0
  F  F21  1  0.104  0.435  0.793  1.0
[/CIF]
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The compound described by Pd(AuF4)2 crystallizes in the monoclinic P2_1/c space group. Pd(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Pd(1) and one Au(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Pd(1) and one Au(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Pd(1) and one Au(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Au(1) atom. is represented by the CIF file [CIF]
data_Pd(AuF4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.972
_cell_length_b   5.115
_cell_length_c   7.578
_cell_angle_alpha   47.232
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   312.184
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.500  0.500  0.500  1.0
  Pd  Pd1  1  0.000  0.500  0.000  1.0
  Au  Au2  1  0.687  0.245  0.020  1.0
  Au  Au3  1  0.187  0.755  0.480  1.0
  Au  Au4  1  0.813  0.245  0.520  1.0
  Au  Au5  1  0.313  0.755  0.980  1.0
  F  F6  1  0.471  0.942  0.818  1.0
  F  F7  1  0.971  0.058  0.682  1.0
  F  F8  1  0.529  0.058  0.182  1.0
  F  F9  1  0.029  0.942  0.318  1.0
  F  F10  1  0.896  0.565  0.207  1.0
  F  F11  1  0.396  0.435  0.293  1.0
  F  F12  1  0.846  0.425  0.859  1.0
  F  F13  1  0.346  0.575  0.641  1.0
  F  F14  1  0.154  0.575  0.141  1.0
  F  F15  1  0.654  0.425  0.359  1.0
  F  F16  1  0.271  0.052  0.177  1.0
  F  F17  1  0.771  0.948  0.323  1.0
  F  F18  1  0.729  0.948  0.823  1.0
  F  F19  1  0.229  0.052  0.677  1.0
  F  F20  1  0.604  0.565  0.707  1.0
  F  F21  1  0.104  0.435  0.793  1.0
[/CIF]
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