The crystal structure described by Ti5RhSb2 crystallizes in the tetragonal I4/mcm space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 6-coordinate geometry to two equivalent Rh(1) and four equivalent Sb(1) atoms. In the second Ti site, Ti(2) is bonded in a 6-coordinate geometry to two equivalent Ti(2) and four equivalent Sb(1) atoms. Rh(1) is bonded in a 8-coordinate geometry to eight equivalent Ti(1) atoms. Sb(1) is bonded in a 10-coordinate geometry to two equivalent Ti(2) and eight equivalent Ti(1) atoms. is represented by the CIF card [CIF]
data_Ti5Sb2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.869
_cell_length_b   7.869
_cell_length_c   7.869
_cell_angle_alpha   96.356
_cell_angle_beta   96.356
_cell_angle_gamma   141.133
_symmetry_Int_Tables_number   1
_cell_volume   288.362
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.073  0.789  0.863  1.0
  Ti  Ti1  1  0.789  0.927  0.716  1.0
  Ti  Ti2  1  0.211  0.073  0.284  1.0
  Ti  Ti3  1  0.927  0.211  0.137  1.0
  Ti  Ti4  1  0.289  0.573  0.863  1.0
  Ti  Ti5  1  0.711  0.427  0.137  1.0
  Ti  Ti6  1  0.427  0.289  0.716  1.0
  Ti  Ti7  1  0.573  0.711  0.284  1.0
  Ti  Ti8  1  0.750  0.250  0.500  1.0
  Ti  Ti9  1  0.250  0.750  0.500  1.0
  Sb  Sb10  1  0.163  0.337  0.500  1.0
  Sb  Sb11  1  0.337  0.837  0.173  1.0
  Sb  Sb12  1  0.663  0.163  0.827  1.0
  Sb  Sb13  1  0.837  0.663  0.500  1.0
  Rh  Rh14  1  0.750  0.750  0.000  1.0
  Rh  Rh15  1  0.250  0.250  0.000  1.0
[/CIF]
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The crystal structure described by Ti5RhSb2 crystallizes in the tetragonal I4/mcm space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 6-coordinate geometry to two equivalent Rh(1) and four equivalent Sb(1) atoms. In the second Ti site, Ti(2) is bonded in a 6-coordinate geometry to two equivalent Ti(2) and four equivalent Sb(1) atoms. Rh(1) is bonded in a 8-coordinate geometry to eight equivalent Ti(1) atoms. Sb(1) is bonded in a 10-coordinate geometry to two equivalent Ti(2) and eight equivalent Ti(1) atoms. is represented by the CIF card [CIF]
data_Ti5Sb2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.869
_cell_length_b   7.869
_cell_length_c   7.869
_cell_angle_alpha   96.356
_cell_angle_beta   96.356
_cell_angle_gamma   141.133
_symmetry_Int_Tables_number   1
_cell_volume   288.362
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.073  0.789  0.863  1.0
  Ti  Ti1  1  0.789  0.927  0.716  1.0
  Ti  Ti2  1  0.211  0.073  0.284  1.0
  Ti  Ti3  1  0.927  0.211  0.137  1.0
  Ti  Ti4  1  0.289  0.573  0.863  1.0
  Ti  Ti5  1  0.711  0.427  0.137  1.0
  Ti  Ti6  1  0.427  0.289  0.716  1.0
  Ti  Ti7  1  0.573  0.711  0.284  1.0
  Ti  Ti8  1  0.750  0.250  0.500  1.0
  Ti  Ti9  1  0.250  0.750  0.500  1.0
  Sb  Sb10  1  0.163  0.337  0.500  1.0
  Sb  Sb11  1  0.337  0.837  0.173  1.0
  Sb  Sb12  1  0.663  0.163  0.827  1.0
  Sb  Sb13  1  0.837  0.663  0.500  1.0
  Rh  Rh14  1  0.750  0.750  0.000  1.0
  Rh  Rh15  1  0.250  0.250  0.000  1.0
[/CIF]
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