The material structure described by VTiO4 is Hydrophilite-derived structured and crystallizes in the monoclinic P2_1/c space group. Ti(1) is bonded to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms to form distorted TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent V(1)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-53°. V(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent Ti(1)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and edges with two equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-53°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Ti(1) and one V(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ti(1) and two equivalent V(1) atoms. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Ti(1) and two equivalent V(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Ti(1) and one V(1) atom. is represented by the CIF file [CIF]
data_TiVO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.711
_cell_length_b   7.447
_cell_length_c   7.701
_cell_angle_alpha   99.768
_cell_angle_beta   90.001
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   266.216
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.527  0.416  0.315  1.0
  Ti  Ti1  1  0.027  0.084  0.185  1.0
  Ti  Ti2  1  0.473  0.584  0.685  1.0
  Ti  Ti3  1  0.973  0.916  0.815  1.0
  V  V4  1  0.507  0.288  0.920  1.0
  V  V5  1  0.007  0.212  0.580  1.0
  V  V6  1  0.493  0.712  0.080  1.0
  V  V7  1  0.993  0.788  0.420  1.0
  O  O8  1  0.286  0.260  0.144  1.0
  O  O9  1  0.786  0.240  0.356  1.0
  O  O10  1  0.714  0.740  0.856  1.0
  O  O11  1  0.214  0.760  0.644  1.0
  O  O12  1  0.247  0.156  0.777  1.0
  O  O13  1  0.747  0.344  0.723  1.0
  O  O14  1  0.753  0.844  0.223  1.0
  O  O15  1  0.253  0.656  0.277  1.0
  O  O16  1  0.185  0.023  0.395  1.0
  O  O17  1  0.685  0.477  0.105  1.0
  O  O18  1  0.815  0.977  0.605  1.0
  O  O19  1  0.315  0.523  0.895  1.0
  O  O20  1  0.218  0.893  0.020  1.0
  O  O21  1  0.718  0.607  0.480  1.0
  O  O22  1  0.782  0.107  0.980  1.0
  O  O23  1  0.282  0.393  0.520  1.0
[/CIF]
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The material structure described by VTiO4 is Hydrophilite-derived structured and crystallizes in the monoclinic P2_1/c space group. Ti(1) is bonded to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms to form distorted TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent V(1)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-53°. V(1) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms to form VO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent Ti(1)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and edges with two equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-53°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Ti(1) and one V(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ti(1) and two equivalent V(1) atoms. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Ti(1) and two equivalent V(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Ti(1) and one V(1) atom. is represented by the CIF file [CIF]
data_TiVO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.711
_cell_length_b   7.447
_cell_length_c   7.701
_cell_angle_alpha   99.768
_cell_angle_beta   90.001
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   266.216
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.527  0.416  0.315  1.0
  Ti  Ti1  1  0.027  0.084  0.185  1.0
  Ti  Ti2  1  0.473  0.584  0.685  1.0
  Ti  Ti3  1  0.973  0.916  0.815  1.0
  V  V4  1  0.507  0.288  0.920  1.0
  V  V5  1  0.007  0.212  0.580  1.0
  V  V6  1  0.493  0.712  0.080  1.0
  V  V7  1  0.993  0.788  0.420  1.0
  O  O8  1  0.286  0.260  0.144  1.0
  O  O9  1  0.786  0.240  0.356  1.0
  O  O10  1  0.714  0.740  0.856  1.0
  O  O11  1  0.214  0.760  0.644  1.0
  O  O12  1  0.247  0.156  0.777  1.0
  O  O13  1  0.747  0.344  0.723  1.0
  O  O14  1  0.753  0.844  0.223  1.0
  O  O15  1  0.253  0.656  0.277  1.0
  O  O16  1  0.185  0.023  0.395  1.0
  O  O17  1  0.685  0.477  0.105  1.0
  O  O18  1  0.815  0.977  0.605  1.0
  O  O19  1  0.315  0.523  0.895  1.0
  O  O20  1  0.218  0.893  0.020  1.0
  O  O21  1  0.718  0.607  0.480  1.0
  O  O22  1  0.782  0.107  0.980  1.0
  O  O23  1  0.282  0.393  0.520  1.0
[/CIF]
.