The crystal structure described by SOCl2 is Ammonia-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four thionyl chloride molecules. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one Cl(1), and one Cl(2) atom. O(1) is bonded in a single-bond geometry to one S(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_SCl2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.850
_cell_length_b   7.681
_cell_length_c   8.974
_cell_angle_alpha   100.452
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   396.516
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.937  0.758  0.165  1.0
  S  S1  1  0.437  0.742  0.835  1.0
  S  S2  1  0.063  0.242  0.835  1.0
  S  S3  1  0.563  0.258  0.165  1.0
  Cl  Cl4  1  0.795  0.735  0.373  1.0
  Cl  Cl5  1  0.295  0.765  0.627  1.0
  Cl  Cl6  1  0.205  0.265  0.627  1.0
  Cl  Cl7  1  0.705  0.235  0.373  1.0
  Cl  Cl8  1  0.222  0.910  0.249  1.0
  Cl  Cl9  1  0.722  0.590  0.751  1.0
  Cl  Cl10  1  0.778  0.090  0.751  1.0
  Cl  Cl11  1  0.278  0.410  0.249  1.0
  O  O12  1  0.789  0.870  0.096  1.0
  O  O13  1  0.289  0.630  0.904  1.0
  O  O14  1  0.211  0.130  0.904  1.0
  O  O15  1  0.711  0.370  0.096  1.0
[/CIF]
.
The crystal structure described by SOCl2 is Ammonia-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four thionyl chloride molecules. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one Cl(1), and one Cl(2) atom. O(1) is bonded in a single-bond geometry to one S(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_SCl2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.850
_cell_length_b   7.681
_cell_length_c   8.974
_cell_angle_alpha   100.452
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   396.516
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.937  0.758  0.165  1.0
  S  S1  1  0.437  0.742  0.835  1.0
  S  S2  1  0.063  0.242  0.835  1.0
  S  S3  1  0.563  0.258  0.165  1.0
  Cl  Cl4  1  0.795  0.735  0.373  1.0
  Cl  Cl5  1  0.295  0.765  0.627  1.0
  Cl  Cl6  1  0.205  0.265  0.627  1.0
  Cl  Cl7  1  0.705  0.235  0.373  1.0
  Cl  Cl8  1  0.222  0.910  0.249  1.0
  Cl  Cl9  1  0.722  0.590  0.751  1.0
  Cl  Cl10  1  0.778  0.090  0.751  1.0
  Cl  Cl11  1  0.278  0.410  0.249  1.0
  O  O12  1  0.789  0.870  0.096  1.0
  O  O13  1  0.289  0.630  0.904  1.0
  O  O14  1  0.211  0.130  0.904  1.0
  O  O15  1  0.711  0.370  0.096  1.0
[/CIF]
.