The compound described by Sn3SbF9 crystallizes in the orthorhombic Pbcm space group. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 4-coordinate geometry to two equivalent F(2) and two equivalent F(4) atoms. In the second Sn site, Sn(2) is bonded in a distorted rectangular see-saw-like geometry to one F(2), one F(3), one F(4), and one F(5) atom. Sb(1) is bonded in a distorted square pyramidal geometry to one F(1), two equivalent F(3), and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(4) is bonded in a bent 120 degrees geometry to one Sn(1) and one Sn(2) atom. In the second F site, F(5) is bonded in a distorted linear geometry to one Sn(2) and one Sb(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(2) is bonded in a bent 150 degrees geometry to one Sn(1) and one Sn(2) atom. In the fifth F site, F(3) is bonded in a bent 150 degrees geometry to one Sn(2) and one Sb(1) atom. is represented by the CIF card [CIF]
data_Sn3SbF9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.627
_cell_length_b   9.159
_cell_length_c   20.839
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   883.137
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.044  0.750  0.500  1.0
  Sn  Sn1  1  0.956  0.250  0.000  1.0
  Sn  Sn2  1  0.956  0.250  0.500  1.0
  Sn  Sn3  1  0.044  0.750  0.000  1.0
  Sn  Sn4  1  0.521  0.517  0.621  1.0
  Sn  Sn5  1  0.479  0.483  0.121  1.0
  Sn  Sn6  1  0.521  0.983  0.379  1.0
  Sn  Sn7  1  0.479  0.017  0.879  1.0
  Sn  Sn8  1  0.479  0.483  0.379  1.0
  Sn  Sn9  1  0.521  0.517  0.879  1.0
  Sn  Sn10  1  0.479  0.017  0.621  1.0
  Sn  Sn11  1  0.521  0.983  0.121  1.0
  Sb  Sb12  1  0.068  0.248  0.750  1.0
  Sb  Sb13  1  0.932  0.752  0.250  1.0
  Sb  Sb14  1  0.068  0.252  0.250  1.0
  Sb  Sb15  1  0.932  0.748  0.750  1.0
  F  F16  1  0.178  0.921  0.750  1.0
  F  F17  1  0.822  0.079  0.250  1.0
  F  F18  1  0.178  0.579  0.250  1.0
  F  F19  1  0.822  0.421  0.750  1.0
  F  F20  1  0.383  0.821  0.561  1.0
  F  F21  1  0.617  0.179  0.061  1.0
  F  F22  1  0.383  0.679  0.439  1.0
  F  F23  1  0.617  0.321  0.939  1.0
  F  F24  1  0.617  0.179  0.439  1.0
  F  F25  1  0.383  0.821  0.939  1.0
  F  F26  1  0.617  0.321  0.561  1.0
  F  F27  1  0.383  0.679  0.061  1.0
  F  F28  1  0.227  0.370  0.661  1.0
  F  F29  1  0.773  0.630  0.161  1.0
  F  F30  1  0.227  0.130  0.339  1.0
  F  F31  1  0.773  0.870  0.839  1.0
  F  F32  1  0.773  0.630  0.339  1.0
  F  F33  1  0.227  0.370  0.839  1.0
  F  F34  1  0.773  0.870  0.661  1.0
  F  F35  1  0.227  0.130  0.161  1.0
  F  F36  1  0.191  0.541  0.552  1.0
  F  F37  1  0.809  0.459  0.052  1.0
  F  F38  1  0.191  0.959  0.448  1.0
  F  F39  1  0.809  0.041  0.948  1.0
  F  F40  1  0.809  0.459  0.448  1.0
  F  F41  1  0.191  0.541  0.948  1.0
  F  F42  1  0.809  0.041  0.552  1.0
  F  F43  1  0.191  0.959  0.052  1.0
  F  F44  1  0.220  0.673  0.685  1.0
  F  F45  1  0.780  0.327  0.185  1.0
  F  F46  1  0.220  0.827  0.315  1.0
  F  F47  1  0.780  0.173  0.815  1.0
  F  F48  1  0.780  0.327  0.315  1.0
  F  F49  1  0.220  0.673  0.815  1.0
  F  F50  1  0.780  0.173  0.685  1.0
  F  F51  1  0.220  0.827  0.185  1.0
[/CIF]
.
The compound described by Sn3SbF9 crystallizes in the orthorhombic Pbcm space group. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 4-coordinate geometry to two equivalent F(2) and two equivalent F(4) atoms. In the second Sn site, Sn(2) is bonded in a distorted rectangular see-saw-like geometry to one F(2), one F(3), one F(4), and one F(5) atom. Sb(1) is bonded in a distorted square pyramidal geometry to one F(1), two equivalent F(3), and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(4) is bonded in a bent 120 degrees geometry to one Sn(1) and one Sn(2) atom. In the second F site, F(5) is bonded in a distorted linear geometry to one Sn(2) and one Sb(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(2) is bonded in a bent 150 degrees geometry to one Sn(1) and one Sn(2) atom. In the fifth F site, F(3) is bonded in a bent 150 degrees geometry to one Sn(2) and one Sb(1) atom. is represented by the CIF card [CIF]
data_Sn3SbF9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.627
_cell_length_b   9.159
_cell_length_c   20.839
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   883.137
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.044  0.750  0.500  1.0
  Sn  Sn1  1  0.956  0.250  0.000  1.0
  Sn  Sn2  1  0.956  0.250  0.500  1.0
  Sn  Sn3  1  0.044  0.750  0.000  1.0
  Sn  Sn4  1  0.521  0.517  0.621  1.0
  Sn  Sn5  1  0.479  0.483  0.121  1.0
  Sn  Sn6  1  0.521  0.983  0.379  1.0
  Sn  Sn7  1  0.479  0.017  0.879  1.0
  Sn  Sn8  1  0.479  0.483  0.379  1.0
  Sn  Sn9  1  0.521  0.517  0.879  1.0
  Sn  Sn10  1  0.479  0.017  0.621  1.0
  Sn  Sn11  1  0.521  0.983  0.121  1.0
  Sb  Sb12  1  0.068  0.248  0.750  1.0
  Sb  Sb13  1  0.932  0.752  0.250  1.0
  Sb  Sb14  1  0.068  0.252  0.250  1.0
  Sb  Sb15  1  0.932  0.748  0.750  1.0
  F  F16  1  0.178  0.921  0.750  1.0
  F  F17  1  0.822  0.079  0.250  1.0
  F  F18  1  0.178  0.579  0.250  1.0
  F  F19  1  0.822  0.421  0.750  1.0
  F  F20  1  0.383  0.821  0.561  1.0
  F  F21  1  0.617  0.179  0.061  1.0
  F  F22  1  0.383  0.679  0.439  1.0
  F  F23  1  0.617  0.321  0.939  1.0
  F  F24  1  0.617  0.179  0.439  1.0
  F  F25  1  0.383  0.821  0.939  1.0
  F  F26  1  0.617  0.321  0.561  1.0
  F  F27  1  0.383  0.679  0.061  1.0
  F  F28  1  0.227  0.370  0.661  1.0
  F  F29  1  0.773  0.630  0.161  1.0
  F  F30  1  0.227  0.130  0.339  1.0
  F  F31  1  0.773  0.870  0.839  1.0
  F  F32  1  0.773  0.630  0.339  1.0
  F  F33  1  0.227  0.370  0.839  1.0
  F  F34  1  0.773  0.870  0.661  1.0
  F  F35  1  0.227  0.130  0.161  1.0
  F  F36  1  0.191  0.541  0.552  1.0
  F  F37  1  0.809  0.459  0.052  1.0
  F  F38  1  0.191  0.959  0.448  1.0
  F  F39  1  0.809  0.041  0.948  1.0
  F  F40  1  0.809  0.459  0.448  1.0
  F  F41  1  0.191  0.541  0.948  1.0
  F  F42  1  0.809  0.041  0.552  1.0
  F  F43  1  0.191  0.959  0.052  1.0
  F  F44  1  0.220  0.673  0.685  1.0
  F  F45  1  0.780  0.327  0.185  1.0
  F  F46  1  0.220  0.827  0.315  1.0
  F  F47  1  0.780  0.173  0.815  1.0
  F  F48  1  0.780  0.327  0.315  1.0
  F  F49  1  0.220  0.673  0.815  1.0
  F  F50  1  0.780  0.173  0.685  1.0
  F  F51  1  0.220  0.827  0.185  1.0
[/CIF]
.