The compound described by F3CP is Indium-like structured and crystallizes in the tetragonal P4_2/nmc space group. The structure is zero-dimensional and consists of eight trifluoromethylphosphane molecules. C(1) is bonded in a distorted bent 120 degrees geometry to one P(1) and one F(1) atom. P(1) is bonded in a 3-coordinate geometry to one C(1) and two equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PCF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.381
_cell_length_b   11.381
_cell_length_c   6.347
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   822.091
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.500  0.709  0.425  1.0
  P  P1  1  0.209  0.000  0.925  1.0
  P  P2  1  0.791  0.000  0.925  1.0
  P  P3  1  0.500  0.291  0.425  1.0
  P  P4  1  0.000  0.209  0.075  1.0
  P  P5  1  0.000  0.791  0.075  1.0
  P  P6  1  0.709  0.500  0.575  1.0
  P  P7  1  0.291  0.500  0.575  1.0
  C  C8  1  0.500  0.757  0.696  1.0
  C  C9  1  0.257  0.000  0.196  1.0
  C  C10  1  0.743  0.000  0.196  1.0
  C  C11  1  0.500  0.243  0.696  1.0
  C  C12  1  0.000  0.257  0.804  1.0
  C  C13  1  0.000  0.743  0.804  1.0
  C  C14  1  0.757  0.500  0.304  1.0
  C  C15  1  0.243  0.500  0.304  1.0
  F  F16  1  0.500  0.683  0.858  1.0
  F  F17  1  0.183  0.000  0.358  1.0
  F  F18  1  0.817  0.000  0.358  1.0
  F  F19  1  0.500  0.317  0.858  1.0
  F  F20  1  0.000  0.183  0.642  1.0
  F  F21  1  0.000  0.817  0.642  1.0
  F  F22  1  0.683  0.500  0.142  1.0
  F  F23  1  0.317  0.500  0.142  1.0
  F  F24  1  0.605  0.789  0.334  1.0
  F  F25  1  0.289  0.895  0.834  1.0
  F  F26  1  0.711  0.105  0.834  1.0
  F  F27  1  0.395  0.211  0.334  1.0
  F  F28  1  0.895  0.289  0.166  1.0
  F  F29  1  0.105  0.711  0.166  1.0
  F  F30  1  0.789  0.605  0.666  1.0
  F  F31  1  0.211  0.395  0.666  1.0
  F  F32  1  0.895  0.711  0.166  1.0
  F  F33  1  0.211  0.605  0.666  1.0
  F  F34  1  0.789  0.395  0.666  1.0
  F  F35  1  0.105  0.289  0.166  1.0
  F  F36  1  0.605  0.211  0.334  1.0
  F  F37  1  0.395  0.789  0.334  1.0
  F  F38  1  0.711  0.895  0.834  1.0
  F  F39  1  0.289  0.105  0.834  1.0
[/CIF]
.
The compound described by F3CP is Indium-like structured and crystallizes in the tetragonal P4_2/nmc space group. The structure is zero-dimensional and consists of eight trifluoromethylphosphane molecules. C(1) is bonded in a distorted bent 120 degrees geometry to one P(1) and one F(1) atom. P(1) is bonded in a 3-coordinate geometry to one C(1) and two equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PCF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.381
_cell_length_b   11.381
_cell_length_c   6.347
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   822.091
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.500  0.709  0.425  1.0
  P  P1  1  0.209  0.000  0.925  1.0
  P  P2  1  0.791  0.000  0.925  1.0
  P  P3  1  0.500  0.291  0.425  1.0
  P  P4  1  0.000  0.209  0.075  1.0
  P  P5  1  0.000  0.791  0.075  1.0
  P  P6  1  0.709  0.500  0.575  1.0
  P  P7  1  0.291  0.500  0.575  1.0
  C  C8  1  0.500  0.757  0.696  1.0
  C  C9  1  0.257  0.000  0.196  1.0
  C  C10  1  0.743  0.000  0.196  1.0
  C  C11  1  0.500  0.243  0.696  1.0
  C  C12  1  0.000  0.257  0.804  1.0
  C  C13  1  0.000  0.743  0.804  1.0
  C  C14  1  0.757  0.500  0.304  1.0
  C  C15  1  0.243  0.500  0.304  1.0
  F  F16  1  0.500  0.683  0.858  1.0
  F  F17  1  0.183  0.000  0.358  1.0
  F  F18  1  0.817  0.000  0.358  1.0
  F  F19  1  0.500  0.317  0.858  1.0
  F  F20  1  0.000  0.183  0.642  1.0
  F  F21  1  0.000  0.817  0.642  1.0
  F  F22  1  0.683  0.500  0.142  1.0
  F  F23  1  0.317  0.500  0.142  1.0
  F  F24  1  0.605  0.789  0.334  1.0
  F  F25  1  0.289  0.895  0.834  1.0
  F  F26  1  0.711  0.105  0.834  1.0
  F  F27  1  0.395  0.211  0.334  1.0
  F  F28  1  0.895  0.289  0.166  1.0
  F  F29  1  0.105  0.711  0.166  1.0
  F  F30  1  0.789  0.605  0.666  1.0
  F  F31  1  0.211  0.395  0.666  1.0
  F  F32  1  0.895  0.711  0.166  1.0
  F  F33  1  0.211  0.605  0.666  1.0
  F  F34  1  0.789  0.395  0.666  1.0
  F  F35  1  0.105  0.289  0.166  1.0
  F  F36  1  0.605  0.211  0.334  1.0
  F  F37  1  0.395  0.789  0.334  1.0
  F  F38  1  0.711  0.895  0.834  1.0
  F  F39  1  0.289  0.105  0.834  1.0
[/CIF]
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