The structure described by Li3V2P4(HO8)2 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(21), one O(24), one O(5), one O(8), and one O(9) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(23), one O(27), and one O(3) atom. In the third Li site, Li(3) is bonded to one O(1), one O(11), one O(17), one O(19), and one O(4) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles are 76°. In the fourth Li site, Li(4) is bonded to one O(14), one O(16), one O(22), one O(29), and one O(32) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one V(4)O6 octahedra, and  an edgeedge with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 76°. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(10), one O(20), one O(23), one O(30), and one O(6) atom. In the sixth Li site, Li(6) is bonded in a 5-coordinate geometry to one O(13), one O(24), one O(25), one O(28), and one O(9) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one Li(3)O5 trigonal bipyramid. In the second V site, V(2) is bonded to one O(13), one O(16), one O(17), one O(21), one O(28), and one O(5) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid, and  a cornercorner with one Li(4)O5 trigonal bipyramid. In the third V site, V(3) is bonded to one O(12), one O(15), one O(18), one O(20), one O(27), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and  a cornercorner with one P(8)O4 tetrahedra. In the fourth V site, V(4) is bonded to one O(22), one O(25), one O(26), one O(29), one O(30), and one O(31) atom to form VO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and  an edgeedge with one Li(4)O5 trigonal bipyramid. There are eight inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(16), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 23-51°. In the second P site, P(2) is bonded to one O(15), one O(29), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 25-45°. In the third P site, P(3) is bonded to one O(14), one O(20), one O(22), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  an edgeedge with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 21-52°. In the fourth P site, P(4) is bonded to one O(1), one O(2), one O(21), and one O(30) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 18-51°. In the fifth P site, P(5) is bonded to one O(11), one O(12), one O(19), and one O(25) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 21-53°. In the sixth P site, P(6) is bonded to one O(13), one O(3), one O(31), and one O(32) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 23-51°. In the seventh P site, P(7) is bonded to one O(17), one O(23), one O(26), and one O(27) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 26-51°. In the eighth P site, P(8) is bonded to one O(18), one O(24), one O(28), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 24-44°. There are four inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(23) and one O(9) atom. In the second H site, H(2) is bonded in a linear geometry to one O(10) and one O(24) atom. In the third H site, H(3) is bonded in a linear geometry to one O(14) and one O(19) atom. In the fourth H site, H(4) is bonded in a linear geometry to one O(1) and one O(32) atom. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(3), one P(4), and one H(4) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one P(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Li(2), one V(1), and one P(6) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Li(3), one V(1), and one P(8) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Li(1), one V(2), and one P(2) atom. In the sixth O site, O(6) is bonded in a T-shaped geometry to one Li(5), one V(3), and one P(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one P(3) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Li(1), one Li(6), one P(2), and one H(1) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Li(2), one Li(5), one P(1), and one H(2) atom. In the eleventh O site, O(11) is bonded in a T-shaped geometry to one Li(3), one V(1), and one P(5) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to one Li(2), one V(3), and one P(5) atom. In the thirteenth O site, O(13) is bonded in a distorted T-shaped geometry to one Li(6), one V(2), and one P(6) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Li(4), one P(3), and one H(3) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one V(3) and one P(2) atom. In the sixteenth O site, O(16) is bonded in a trigonal planar geometry to one Li(4), one V(2), and one P(1) atom. In the seventeenth O site, O(17) is bonded in a trigonal planar geometry to one Li(3), one V(2), and one P(7) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one V(3) and one P(8) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Li(3), one P(5), and one H(3) atom. In the twentieth O site, O(20) is bonded in a distorted T-shaped geometry to one Li(5), one V(3), and one P(3) atom. In the twenty-first O site, O(21) is bonded in a distorted T-shaped geometry to one Li(1), one V(2), and one P(4) atom. In the twenty-second O site, O(22) is bonded in a T-shaped geometry to one Li(4), one V(4), and one P(3) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Li(2), one Li(5), one P(7), and one H(1) atom. In the twenty-fourth O site, O(24) is bonded in a 4-coordinate geometry to one Li(1), one Li(6), one P(8), and one H(2) atom. In the twenty-fifth O site, O(25) is bonded in a distorted trigonal planar geometry to one Li(6), one V(4), and one P(5) atom. In the twenty-sixth O site, O(26) is bonded in a bent 150 degrees geometry to one V(4) and one P(7) atom. In the twenty-seventh O site, O(27) is bonded in a distorted T-shaped geometry to one Li(2), one V(3), and one P(7) atom. In the twenty-eighth O site, O(28) is bonded in a distorted T-shaped geometry to one Li(6), one V(2), and one P(8) atom. In the twenty-ninth O site, O(29) is bonded in a distorted T-shaped geometry to one Li(4), one V(4), and one P(2) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal planar geometry to one Li(5), one V(4), and one P(4) atom. In the thirty-first O site, O(31) is bonded in a bent 150 degrees geometry to one V(4) and one P(6) atom. In the thirty-second O site, O(32) is bonded in a trigonal planar geometry to one Li(4), one P(6), and one H(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3V2P4(HO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.458
_cell_length_b   9.398
_cell_length_c   7.904
_cell_angle_alpha   78.644
_cell_angle_beta   78.661
_cell_angle_gamma   117.718
_symmetry_Int_Tables_number   1
_cell_volume   575.133
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.459  0.095  0.341  1.0
  Li  Li1  1  0.045  0.412  0.655  1.0
  Li  Li2  1  0.337  0.207  0.849  1.0
  Li  Li3  1  0.657  0.788  0.155  1.0
  Li  Li4  1  0.959  0.596  0.344  1.0
  Li  Li5  1  0.550  0.914  0.657  1.0
  V  V6  1  0.247  0.250  0.489  1.0
  V  V7  1  0.500  0.999  0.002  1.0
  V  V8  1  0.996  0.496  0.004  1.0
  V  V9  1  0.752  0.751  0.503  1.0
  P  P10  1  0.258  0.605  0.268  1.0
  P  P11  1  0.756  0.108  0.268  1.0
  P  P12  1  0.643  0.493  0.227  1.0
  P  P13  1  0.145  0.993  0.231  1.0
  P  P14  1  0.354  0.509  0.765  1.0
  P  P15  1  0.858  0.009  0.761  1.0
  P  P16  1  0.739  0.395  0.739  1.0
  P  P17  1  0.238  0.891  0.739  1.0
  H  H18  1  0.757  0.267  0.515  1.0
  H  H19  1  0.254  0.766  0.512  1.0
  H  H20  1  0.486  0.494  0.988  1.0
  H  H21  1  0.983  0.995  0.987  1.0
  O  O22  1  0.127  0.065  0.052  1.0
  O  O23  1  0.164  0.114  0.355  1.0
  O  O24  1  0.018  0.190  0.649  1.0
  O  O25  1  0.232  0.055  0.689  1.0
  O  O26  1  0.630  0.090  0.163  1.0
  O  O27  1  0.133  0.587  0.159  1.0
  O  O28  1  0.270  0.444  0.319  1.0
  O  O29  1  0.486  0.312  0.355  1.0
  O  O30  1  0.687  0.128  0.448  1.0
  O  O31  1  0.182  0.626  0.447  1.0
  O  O32  1  0.331  0.382  0.654  1.0
  O  O33  1  0.187  0.511  0.814  1.0
  O  O34  1  0.695  0.015  0.809  1.0
  O  O35  1  0.615  0.561  0.054  1.0
  O  O36  1  0.929  0.273  0.143  1.0
  O  O37  1  0.436  0.761  0.150  1.0
  O  O38  1  0.562  0.236  0.850  1.0
  O  O39  1  0.067  0.727  0.856  1.0
  O  O40  1  0.378  0.431  0.940  1.0
  O  O41  1  0.807  0.483  0.187  1.0
  O  O42  1  0.312  0.994  0.193  1.0
  O  O43  1  0.665  0.617  0.338  1.0
  O  O44  1  0.819  0.375  0.556  1.0
  O  O45  1  0.313  0.875  0.552  1.0
  O  O46  1  0.506  0.688  0.649  1.0
  O  O47  1  0.732  0.555  0.684  1.0
  O  O48  1  0.866  0.409  0.842  1.0
  O  O49  1  0.369  0.914  0.836  1.0
  O  O50  1  0.768  0.948  0.306  1.0
  O  O51  1  0.992  0.816  0.350  1.0
  O  O52  1  0.845  0.892  0.650  1.0
  O  O53  1  0.873  0.941  0.950  1.0
[/CIF]
.
The structure described by Li3V2P4(HO8)2 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one O(21), one O(24), one O(5), one O(8), and one O(9) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(23), one O(27), and one O(3) atom. In the third Li site, Li(3) is bonded to one O(1), one O(11), one O(17), one O(19), and one O(4) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles are 76°. In the fourth Li site, Li(4) is bonded to one O(14), one O(16), one O(22), one O(29), and one O(32) atom to form distorted LiO5 trigonal bipyramids that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one V(4)O6 octahedra, and  an edgeedge with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 76°. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(10), one O(20), one O(23), one O(30), and one O(6) atom. In the sixth Li site, Li(6) is bonded in a 5-coordinate geometry to one O(13), one O(24), one O(25), one O(28), and one O(9) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one Li(3)O5 trigonal bipyramid. In the second V site, V(2) is bonded to one O(13), one O(16), one O(17), one O(21), one O(28), and one O(5) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  a cornercorner with one Li(3)O5 trigonal bipyramid, and  a cornercorner with one Li(4)O5 trigonal bipyramid. In the third V site, V(3) is bonded to one O(12), one O(15), one O(18), one O(20), one O(27), and one O(6) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and  a cornercorner with one P(8)O4 tetrahedra. In the fourth V site, V(4) is bonded to one O(22), one O(25), one O(26), one O(29), one O(30), and one O(31) atom to form VO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and  an edgeedge with one Li(4)O5 trigonal bipyramid. There are eight inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(16), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 23-51°. In the second P site, P(2) is bonded to one O(15), one O(29), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 25-45°. In the third P site, P(3) is bonded to one O(14), one O(20), one O(22), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  an edgeedge with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 21-52°. In the fourth P site, P(4) is bonded to one O(1), one O(2), one O(21), and one O(30) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 18-51°. In the fifth P site, P(5) is bonded to one O(11), one O(12), one O(19), and one O(25) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  an edgeedge with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 21-53°. In the sixth P site, P(6) is bonded to one O(13), one O(3), one O(31), and one O(32) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 23-51°. In the seventh P site, P(7) is bonded to one O(17), one O(23), one O(26), and one O(27) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(4)O6 octahedra, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 26-51°. In the eighth P site, P(8) is bonded to one O(18), one O(24), one O(28), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, and  a cornercorner with one Li(3)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 24-44°. There are four inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(23) and one O(9) atom. In the second H site, H(2) is bonded in a linear geometry to one O(10) and one O(24) atom. In the third H site, H(3) is bonded in a linear geometry to one O(14) and one O(19) atom. In the fourth H site, H(4) is bonded in a linear geometry to one O(1) and one O(32) atom. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(3), one P(4), and one H(4) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one P(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Li(2), one V(1), and one P(6) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Li(3), one V(1), and one P(8) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Li(1), one V(2), and one P(2) atom. In the sixth O site, O(6) is bonded in a T-shaped geometry to one Li(5), one V(3), and one P(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one P(3) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Li(1), one Li(6), one P(2), and one H(1) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Li(2), one Li(5), one P(1), and one H(2) atom. In the eleventh O site, O(11) is bonded in a T-shaped geometry to one Li(3), one V(1), and one P(5) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to one Li(2), one V(3), and one P(5) atom. In the thirteenth O site, O(13) is bonded in a distorted T-shaped geometry to one Li(6), one V(2), and one P(6) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Li(4), one P(3), and one H(3) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one V(3) and one P(2) atom. In the sixteenth O site, O(16) is bonded in a trigonal planar geometry to one Li(4), one V(2), and one P(1) atom. In the seventeenth O site, O(17) is bonded in a trigonal planar geometry to one Li(3), one V(2), and one P(7) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one V(3) and one P(8) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Li(3), one P(5), and one H(3) atom. In the twentieth O site, O(20) is bonded in a distorted T-shaped geometry to one Li(5), one V(3), and one P(3) atom. In the twenty-first O site, O(21) is bonded in a distorted T-shaped geometry to one Li(1), one V(2), and one P(4) atom. In the twenty-second O site, O(22) is bonded in a T-shaped geometry to one Li(4), one V(4), and one P(3) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Li(2), one Li(5), one P(7), and one H(1) atom. In the twenty-fourth O site, O(24) is bonded in a 4-coordinate geometry to one Li(1), one Li(6), one P(8), and one H(2) atom. In the twenty-fifth O site, O(25) is bonded in a distorted trigonal planar geometry to one Li(6), one V(4), and one P(5) atom. In the twenty-sixth O site, O(26) is bonded in a bent 150 degrees geometry to one V(4) and one P(7) atom. In the twenty-seventh O site, O(27) is bonded in a distorted T-shaped geometry to one Li(2), one V(3), and one P(7) atom. In the twenty-eighth O site, O(28) is bonded in a distorted T-shaped geometry to one Li(6), one V(2), and one P(8) atom. In the twenty-ninth O site, O(29) is bonded in a distorted T-shaped geometry to one Li(4), one V(4), and one P(2) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal planar geometry to one Li(5), one V(4), and one P(4) atom. In the thirty-first O site, O(31) is bonded in a bent 150 degrees geometry to one V(4) and one P(6) atom. In the thirty-second O site, O(32) is bonded in a trigonal planar geometry to one Li(4), one P(6), and one H(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li3V2P4(HO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.458
_cell_length_b   9.398
_cell_length_c   7.904
_cell_angle_alpha   78.644
_cell_angle_beta   78.661
_cell_angle_gamma   117.718
_symmetry_Int_Tables_number   1
_cell_volume   575.133
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.459  0.095  0.341  1.0
  Li  Li1  1  0.045  0.412  0.655  1.0
  Li  Li2  1  0.337  0.207  0.849  1.0
  Li  Li3  1  0.657  0.788  0.155  1.0
  Li  Li4  1  0.959  0.596  0.344  1.0
  Li  Li5  1  0.550  0.914  0.657  1.0
  V  V6  1  0.247  0.250  0.489  1.0
  V  V7  1  0.500  0.999  0.002  1.0
  V  V8  1  0.996  0.496  0.004  1.0
  V  V9  1  0.752  0.751  0.503  1.0
  P  P10  1  0.258  0.605  0.268  1.0
  P  P11  1  0.756  0.108  0.268  1.0
  P  P12  1  0.643  0.493  0.227  1.0
  P  P13  1  0.145  0.993  0.231  1.0
  P  P14  1  0.354  0.509  0.765  1.0
  P  P15  1  0.858  0.009  0.761  1.0
  P  P16  1  0.739  0.395  0.739  1.0
  P  P17  1  0.238  0.891  0.739  1.0
  H  H18  1  0.757  0.267  0.515  1.0
  H  H19  1  0.254  0.766  0.512  1.0
  H  H20  1  0.486  0.494  0.988  1.0
  H  H21  1  0.983  0.995  0.987  1.0
  O  O22  1  0.127  0.065  0.052  1.0
  O  O23  1  0.164  0.114  0.355  1.0
  O  O24  1  0.018  0.190  0.649  1.0
  O  O25  1  0.232  0.055  0.689  1.0
  O  O26  1  0.630  0.090  0.163  1.0
  O  O27  1  0.133  0.587  0.159  1.0
  O  O28  1  0.270  0.444  0.319  1.0
  O  O29  1  0.486  0.312  0.355  1.0
  O  O30  1  0.687  0.128  0.448  1.0
  O  O31  1  0.182  0.626  0.447  1.0
  O  O32  1  0.331  0.382  0.654  1.0
  O  O33  1  0.187  0.511  0.814  1.0
  O  O34  1  0.695  0.015  0.809  1.0
  O  O35  1  0.615  0.561  0.054  1.0
  O  O36  1  0.929  0.273  0.143  1.0
  O  O37  1  0.436  0.761  0.150  1.0
  O  O38  1  0.562  0.236  0.850  1.0
  O  O39  1  0.067  0.727  0.856  1.0
  O  O40  1  0.378  0.431  0.940  1.0
  O  O41  1  0.807  0.483  0.187  1.0
  O  O42  1  0.312  0.994  0.193  1.0
  O  O43  1  0.665  0.617  0.338  1.0
  O  O44  1  0.819  0.375  0.556  1.0
  O  O45  1  0.313  0.875  0.552  1.0
  O  O46  1  0.506  0.688  0.649  1.0
  O  O47  1  0.732  0.555  0.684  1.0
  O  O48  1  0.866  0.409  0.842  1.0
  O  O49  1  0.369  0.914  0.836  1.0
  O  O50  1  0.768  0.948  0.306  1.0
  O  O51  1  0.992  0.816  0.350  1.0
  O  O52  1  0.845  0.892  0.650  1.0
  O  O53  1  0.873  0.941  0.950  1.0
[/CIF]
.