The compound described by YMo(WO4)2 crystallizes in the triclinic P1 space group. Y(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(8) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form distorted edge-sharing WO6 octahedra. In the second W site, W(2) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form distorted edge-sharing WO6 octahedra. Mo(1) is bonded in a 4-coordinate geometry to one O(2), one O(3), one O(5), and one O(7) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Y(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a trigonal pyramidal geometry to one Y(1), one W(1), one W(2), and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one W(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one W(2) and one Mo(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Y(1) and one W(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one W(1), one W(2), and one Mo(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Y(1), one W(1), and one W(2) atom. is represented by the CIF file [CIF]
data_YMo(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.195
_cell_length_b   5.980
_cell_length_c   6.415
_cell_angle_alpha   117.075
_cell_angle_beta   109.729
_cell_angle_gamma   88.184
_symmetry_Int_Tables_number   1
_cell_volume   165.271
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.484  0.336  0.889  1.0
  Mo  Mo1  1  0.032  0.788  0.907  1.0
  W  W2  1  0.294  0.599  0.406  1.0
  W  W3  1  0.781  0.938  0.393  1.0
  O  O4  1  0.304  0.288  0.154  1.0
  O  O5  1  0.263  0.542  0.677  1.0
  O  O6  1  0.391  0.752  0.190  1.0
  O  O7  1  0.173  0.972  0.587  1.0
  O  O8  1  0.803  0.014  0.154  1.0
  O  O9  1  0.722  0.238  0.626  1.0
  O  O10  1  0.679  0.779  0.605  1.0
  O  O11  1  0.873  0.574  0.215  1.0
[/CIF]
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The compound described by YMo(WO4)2 crystallizes in the triclinic P1 space group. Y(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(8) atom. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form distorted edge-sharing WO6 octahedra. In the second W site, W(2) is bonded to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form distorted edge-sharing WO6 octahedra. Mo(1) is bonded in a 4-coordinate geometry to one O(2), one O(3), one O(5), and one O(7) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Y(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one Mo(1) atom. In the third O site, O(3) is bonded in a trigonal pyramidal geometry to one Y(1), one W(1), one W(2), and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one W(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one W(2) and one Mo(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Y(1) and one W(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one W(1), one W(2), and one Mo(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Y(1), one W(1), and one W(2) atom. is represented by the CIF file [CIF]
data_YMo(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.195
_cell_length_b   5.980
_cell_length_c   6.415
_cell_angle_alpha   117.075
_cell_angle_beta   109.729
_cell_angle_gamma   88.184
_symmetry_Int_Tables_number   1
_cell_volume   165.271
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.484  0.336  0.889  1.0
  Mo  Mo1  1  0.032  0.788  0.907  1.0
  W  W2  1  0.294  0.599  0.406  1.0
  W  W3  1  0.781  0.938  0.393  1.0
  O  O4  1  0.304  0.288  0.154  1.0
  O  O5  1  0.263  0.542  0.677  1.0
  O  O6  1  0.391  0.752  0.190  1.0
  O  O7  1  0.173  0.972  0.587  1.0
  O  O8  1  0.803  0.014  0.154  1.0
  O  O9  1  0.722  0.238  0.626  1.0
  O  O10  1  0.679  0.779  0.605  1.0
  O  O11  1  0.873  0.574  0.215  1.0
[/CIF]
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