The material described by Li10Cr3Mn3(NiO8)2 crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(13), one O(15), one O(2), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Ni(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-64°. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(1), one O(12), one O(16), one O(6), one O(8), and one O(9) atom. In the third Li site, Li(3) is bonded to one O(12), one O(13), one O(2), one O(3), one O(5), and one O(8) atom to form distorted LiO6 octahedra that share corners with three equivalent Ni(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  a faceface with one Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-9°. In the fourth Li site, Li(4) is bonded to one O(1), one O(11), one O(14), one O(4), one O(6), and one O(7) atom to form distorted LiO6 octahedra that share corners with three equivalent Ni(1)O6 octahedra, corners with three equivalent Li(10)O4 tetrahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  a faceface with one Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the fifth Li site, Li(5) is bonded in a 3-coordinate geometry to one O(10), one O(11), one O(13), one O(15), one O(2), and one O(4) atom. In the sixth Li site, Li(6) is bonded in a 4-coordinate geometry to one O(10), one O(11), one O(15), one O(2), one O(5), and one O(7) atom. In the seventh Li site, Li(7) is bonded in a 3-coordinate geometry to one O(1), one O(12), one O(14), one O(16), one O(3), and one O(9) atom. In the eighth Li site, Li(8) is bonded in a 3-coordinate geometry to one O(14), one O(16), one O(3), one O(6), one O(8), and one O(9) atom. In the ninth Li site, Li(9) is bonded in a 4-coordinate geometry to one O(10), one O(13), one O(15), one O(4), one O(5), and one O(7) atom. In the tenth Li site, Li(10) is bonded to one O(1), one O(14), one O(16), and one O(6) atom to form LiO4 tetrahedra that share  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Ni(2)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(3)O6 octahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-64°. There are three inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(1), one O(15), one O(4), one O(6), one O(7), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent Ni(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  an edgeedge with one Ni(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(10)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-52°. In the second Cr site, Cr(2) is bonded to one O(10), one O(16), one O(2), one O(3), one O(5), and one O(8) atom to form CrO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra,  a cornercorner with one Li(10)O4 tetrahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-53°. In the third Cr site, Cr(3) is bonded to one O(1), one O(11), one O(14), one O(15), one O(4), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent Ni(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  an edgeedge with one Ni(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(10)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-51°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(12), one O(13), one O(16), one O(2), and one O(3) atom to form distorted MnO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra,  a cornercorner with one Li(10)O4 tetrahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the second Mn site, Mn(2) is bonded to one O(11), one O(14), one O(15), one O(6), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Ni(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  an edgeedge with one Ni(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and  an edgeedge with one Li(10)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(16), one O(5), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra,  a cornercorner with one Li(10)O4 tetrahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-53°. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(11), one O(13), one O(2), one O(4), one O(5), and one O(7) atom to form distorted NiO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  a faceface with one Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-55°. In the second Ni site, Ni(2) is bonded to one O(1), one O(12), one O(14), one O(3), one O(6), and one O(8) atom to form distorted NiO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(10)O4 tetrahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  a faceface with one Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-52°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a 7-coordinate geometry to one Li(10), one Li(2), one Li(4), one Li(7), one Cr(1), one Cr(3), and one Ni(2) atom. In the second O site, O(2) is bonded in a 7-coordinate geometry to one Li(1), one Li(3), one Li(5), one Li(6), one Cr(2), one Mn(1), and one Ni(1) atom. In the third O site, O(3) is bonded to one Li(3), one Li(7), one Li(8), one Cr(2), one Mn(1), and one Ni(2) atom to form OLi3MnCrNi octahedra that share edges with two equivalent O(12)Li3Mn2Ni octahedra, edges with two equivalent O(8)Li3MnCrNi octahedra,  an edgeedge with one O(10)Li3Mn2Cr pentagonal pyramid, and  an edgeedge with one O(9)Li3MnCr2 pentagonal pyramid. In the fourth O site, O(4) is bonded to one Li(4), one Li(5), one Li(9), one Cr(1), one Cr(3), and one Ni(1) atom to form OLi3Cr2Ni octahedra that share edges with two equivalent O(11)Li3MnCrNi octahedra, edges with two equivalent O(7)Li3MnCrNi octahedra,  an edgeedge with one O(10)Li3Mn2Cr pentagonal pyramid, and  an edgeedge with one O(9)Li3MnCr2 pentagonal pyramid. In the fifth O site, O(5) is bonded in a 7-coordinate geometry to one Li(1), one Li(3), one Li(6), one Li(9), one Cr(2), one Mn(3), and one Ni(1) atom. In the sixth O site, O(6) is bonded in a 7-coordinate geometry to one Li(10), one Li(2), one Li(4), one Li(8), one Cr(1), one Mn(2), and one Ni(2) atom. In the seventh O site, O(7) is bonded to one Li(4), one Li(6), one Li(9), one Cr(1), one Mn(2), and one Ni(1) atom to form OLi3MnCrNi octahedra that share edges with two equivalent O(4)Li3Cr2Ni octahedra, edges with two equivalent O(11)Li3MnCrNi octahedra,  an edgeedge with one O(10)Li3Mn2Cr pentagonal pyramid, and  an edgeedge with one O(9)Li3MnCr2 pentagonal pyramid. In the eighth O site, O(8) is bonded to one Li(2), one Li(3), one Li(8), one Cr(2), one Mn(3), and one Ni(2) atom to form OLi3MnCrNi octahedra that share edges with two equivalent O(12)Li3Mn2Ni octahedra, edges with two equivalent O(3)Li3MnCrNi octahedra,  an edgeedge with one O(10)Li3Mn2Cr pentagonal pyramid, and  an edgeedge with one O(9)Li3MnCr2 pentagonal pyramid. In the ninth O site, O(9) is bonded to one Li(2), one Li(7), one Li(8), one Cr(1), one Cr(3), and one Mn(2) atom to form distorted OLi3MnCr2 pentagonal pyramids that share  an edgeedge with one O(4)Li3Cr2Ni octahedra,  an edgeedge with one O(12)Li3Mn2Ni octahedra,  an edgeedge with one O(11)Li3MnCrNi octahedra,  an edgeedge with one O(3)Li3MnCrNi octahedra,  an edgeedge with one O(7)Li3MnCrNi octahedra, and  an edgeedge with one O(8)Li3MnCrNi octahedra. In the tenth O site, O(10) is bonded to one Li(5), one Li(6), one Li(9), one Cr(2), one Mn(1), and one Mn(3) atom to form distorted OLi3Mn2Cr pentagonal pyramids that share  an edgeedge with one O(4)Li3Cr2Ni octahedra,  an edgeedge with one O(12)Li3Mn2Ni octahedra,  an edgeedge with one O(11)Li3MnCrNi octahedra,  an edgeedge with one O(3)Li3MnCrNi octahedra,  an edgeedge with one O(7)Li3MnCrNi octahedra, and  an edgeedge with one O(8)Li3MnCrNi octahedra. In the eleventh O site, O(11) is bonded to one Li(4), one Li(5), one Li(6), one Cr(3), one Mn(2), and one Ni(1) atom to form OLi3MnCrNi octahedra that share edges with two equivalent O(4)Li3Cr2Ni octahedra, edges with two equivalent O(7)Li3MnCrNi octahedra,  an edgeedge with one O(10)Li3Mn2Cr pentagonal pyramid, and  an edgeedge with one O(9)Li3MnCr2 pentagonal pyramid. In the twelfth O site, O(12) is bonded to one Li(2), one Li(3), one Li(7), one Mn(1), one Mn(3), and one Ni(2) atom to form OLi3Mn2Ni octahedra that share edges with two equivalent O(3)Li3MnCrNi octahedra, edges with two equivalent O(8)Li3MnCrNi octahedra,  an edgeedge with one O(10)Li3Mn2Cr pentagonal pyramid, and  an edgeedge with one O(9)Li3MnCr2 pentagonal pyramid. In the thirteenth O site, O(13) is bonded in a 7-coordinate geometry to one Li(1), one Li(3), one Li(5), one Li(9), one Mn(1), one Mn(3), and one Ni(1) atom. In the fourteenth O site, O(14) is bonded in a 7-coordinate geometry to one Li(10), one Li(4), one Li(7), one Li(8), one Cr(3), one Mn(2), and one Ni(2) atom. In the fifteenth O site, O(15) is bonded in a 7-coordinate geometry to one Li(1), one Li(5), one Li(6), one Li(9), one Cr(1), one Cr(3), and one Mn(2) atom. In the sixteenth O site, O(16) is bonded in a 7-coordinate geometry to one Li(10), one Li(2), one Li(7), one Li(8), one Cr(2), one Mn(1), and one Mn(3) atom. is represented by the CIF file [CIF]
data_Li10Mn3Cr3(NiO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.917
_cell_length_b   5.987
_cell_length_c   9.806
_cell_angle_alpha   90.879
_cell_angle_beta   90.905
_cell_angle_gamma   119.085
_symmetry_Int_Tables_number   1
_cell_volume   303.448
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.016  0.994  0.482  1.0
  Li  Li1  1  0.197  0.398  0.063  1.0
  Li  Li2  1  0.355  0.677  0.283  1.0
  Li  Li3  1  0.687  0.336  0.783  1.0
  Li  Li4  1  0.817  0.186  0.563  1.0
  Li  Li5  1  0.400  0.182  0.565  1.0
  Li  Li6  1  0.216  0.813  0.054  1.0
  Li  Li7  1  0.618  0.797  0.058  1.0
  Li  Li8  1  0.803  0.598  0.555  1.0
  Li  Li9  1  0.018  0.011  0.983  1.0
  Mn  Mn10  1  0.849  0.176  0.286  1.0
  Mn  Mn11  1  0.679  0.831  0.784  1.0
  Mn  Mn12  1  0.846  0.666  0.285  1.0
  Cr  Cr13  1  0.185  0.337  0.787  1.0
  Cr  Cr14  1  0.352  0.172  0.286  1.0
  Cr  Cr15  1  0.184  0.831  0.785  1.0
  Ni  Ni16  1  0.343  0.654  0.530  1.0
  Ni  Ni17  1  0.679  0.336  0.030  1.0
  O  O18  1  0.341  0.161  0.904  1.0
  O  O19  1  0.169  0.319  0.403  1.0
  O  O20  1  0.532  0.025  0.167  1.0
  O  O21  1  0.031  0.508  0.666  1.0
  O  O22  1  0.181  0.841  0.395  1.0
  O  O23  1  0.853  0.164  0.896  1.0
  O  O24  1  0.506  0.505  0.672  1.0
  O  O25  1  0.521  0.493  0.171  1.0
  O  O26  1  0.329  0.657  0.909  1.0
  O  O27  1  0.674  0.304  0.409  1.0
  O  O28  1  0.505  0.970  0.670  1.0
  O  O29  1  0.999  0.522  0.162  1.0
  O  O30  1  0.685  0.801  0.411  1.0
  O  O31  1  0.853  0.688  0.899  1.0
  O  O32  1  0.043  0.014  0.669  1.0
  O  O33  1  0.021  0.036  0.170  1.0
[/CIF]
.
The material described by Li10Cr3Mn3(NiO8)2 crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(13), one O(15), one O(2), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Cr(1)O6 octahedra,  a cornercorner with one Cr(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra, corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Ni(1)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-64°. In the second Li site, Li(2) is bonded in a 4-coordinate geometry to one O(1), one O(12), one O(16), one O(6), one O(8), and one O(9) atom. In the third Li site, Li(3) is bonded to one O(12), one O(13), one O(2), one O(3), one O(5), and one O(8) atom to form distorted LiO6 octahedra that share corners with three equivalent Ni(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  a faceface with one Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-9°. In the fourth Li site, Li(4) is bonded to one O(1), one O(11), one O(14), one O(4), one O(6), and one O(7) atom to form distorted LiO6 octahedra that share corners with three equivalent Ni(1)O6 octahedra, corners with three equivalent Li(10)O4 tetrahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  a faceface with one Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-10°. In the fifth Li site, Li(5) is bonded in a 3-coordinate geometry to one O(10), one O(11), one O(13), one O(15), one O(2), and one O(4) atom. In the sixth Li site, Li(6) is bonded in a 4-coordinate geometry to one O(10), one O(11), one O(15), one O(2), one O(5), and one O(7) atom. In the seventh Li site, Li(7) is bonded in a 3-coordinate geometry to one O(1), one O(12), one O(14), one O(16), one O(3), and one O(9) atom. In the eighth Li site, Li(8) is bonded in a 3-coordinate geometry to one O(14), one O(16), one O(3), one O(6), one O(8), and one O(9) atom. In the ninth Li site, Li(9) is bonded in a 4-coordinate geometry to one O(10), one O(13), one O(15), one O(4), one O(5), and one O(7) atom. In the tenth Li site, Li(10) is bonded to one O(1), one O(14), one O(16), and one O(6) atom to form LiO4 tetrahedra that share  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Ni(2)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(3)O6 octahedra, and  an edgeedge with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-64°. There are three inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(1), one O(15), one O(4), one O(6), one O(7), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent Ni(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  an edgeedge with one Ni(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(10)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-52°. In the second Cr site, Cr(2) is bonded to one O(10), one O(16), one O(2), one O(3), one O(5), and one O(8) atom to form CrO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra,  a cornercorner with one Li(10)O4 tetrahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-53°. In the third Cr site, Cr(3) is bonded to one O(1), one O(11), one O(14), one O(15), one O(4), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent Ni(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  an edgeedge with one Ni(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and  an edgeedge with one Li(10)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-51°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(10), one O(12), one O(13), one O(16), one O(2), and one O(3) atom to form distorted MnO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra,  a cornercorner with one Li(10)O4 tetrahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and  an edgeedge with one Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the second Mn site, Mn(2) is bonded to one O(11), one O(14), one O(15), one O(6), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with two equivalent Ni(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  an edgeedge with one Ni(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and  an edgeedge with one Li(10)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(16), one O(5), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Ni(1)O6 octahedra,  a cornercorner with one Li(10)O4 tetrahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 42-53°. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(11), one O(13), one O(2), one O(4), one O(5), and one O(7) atom to form distorted NiO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with three equivalent Li(4)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra,  an edgeedge with one Cr(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  a faceface with one Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-55°. In the second Ni site, Ni(2) is bonded to one O(1), one O(12), one O(14), one O(3), one O(6), and one O(8) atom to form distorted NiO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(10)O4 tetrahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  a faceface with one Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-52°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a 7-coordinate geometry to one Li(10), one Li(2), one Li(4), one Li(7), one Cr(1), one Cr(3), and one Ni(2) atom. In the second O site, O(2) is bonded in a 7-coordinate geometry to one Li(1), one Li(3), one Li(5), one Li(6), one Cr(2), one Mn(1), and one Ni(1) atom. In the third O site, O(3) is bonded to one Li(3), one Li(7), one Li(8), one Cr(2), one Mn(1), and one Ni(2) atom to form OLi3MnCrNi octahedra that share edges with two equivalent O(12)Li3Mn2Ni octahedra, edges with two equivalent O(8)Li3MnCrNi octahedra,  an edgeedge with one O(10)Li3Mn2Cr pentagonal pyramid, and  an edgeedge with one O(9)Li3MnCr2 pentagonal pyramid. In the fourth O site, O(4) is bonded to one Li(4), one Li(5), one Li(9), one Cr(1), one Cr(3), and one Ni(1) atom to form OLi3Cr2Ni octahedra that share edges with two equivalent O(11)Li3MnCrNi octahedra, edges with two equivalent O(7)Li3MnCrNi octahedra,  an edgeedge with one O(10)Li3Mn2Cr pentagonal pyramid, and  an edgeedge with one O(9)Li3MnCr2 pentagonal pyramid. In the fifth O site, O(5) is bonded in a 7-coordinate geometry to one Li(1), one Li(3), one Li(6), one Li(9), one Cr(2), one Mn(3), and one Ni(1) atom. In the sixth O site, O(6) is bonded in a 7-coordinate geometry to one Li(10), one Li(2), one Li(4), one Li(8), one Cr(1), one Mn(2), and one Ni(2) atom. In the seventh O site, O(7) is bonded to one Li(4), one Li(6), one Li(9), one Cr(1), one Mn(2), and one Ni(1) atom to form OLi3MnCrNi octahedra that share edges with two equivalent O(4)Li3Cr2Ni octahedra, edges with two equivalent O(11)Li3MnCrNi octahedra,  an edgeedge with one O(10)Li3Mn2Cr pentagonal pyramid, and  an edgeedge with one O(9)Li3MnCr2 pentagonal pyramid. In the eighth O site, O(8) is bonded to one Li(2), one Li(3), one Li(8), one Cr(2), one Mn(3), and one Ni(2) atom to form OLi3MnCrNi octahedra that share edges with two equivalent O(12)Li3Mn2Ni octahedra, edges with two equivalent O(3)Li3MnCrNi octahedra,  an edgeedge with one O(10)Li3Mn2Cr pentagonal pyramid, and  an edgeedge with one O(9)Li3MnCr2 pentagonal pyramid. In the ninth O site, O(9) is bonded to one Li(2), one Li(7), one Li(8), one Cr(1), one Cr(3), and one Mn(2) atom to form distorted OLi3MnCr2 pentagonal pyramids that share  an edgeedge with one O(4)Li3Cr2Ni octahedra,  an edgeedge with one O(12)Li3Mn2Ni octahedra,  an edgeedge with one O(11)Li3MnCrNi octahedra,  an edgeedge with one O(3)Li3MnCrNi octahedra,  an edgeedge with one O(7)Li3MnCrNi octahedra, and  an edgeedge with one O(8)Li3MnCrNi octahedra. In the tenth O site, O(10) is bonded to one Li(5), one Li(6), one Li(9), one Cr(2), one Mn(1), and one Mn(3) atom to form distorted OLi3Mn2Cr pentagonal pyramids that share  an edgeedge with one O(4)Li3Cr2Ni octahedra,  an edgeedge with one O(12)Li3Mn2Ni octahedra,  an edgeedge with one O(11)Li3MnCrNi octahedra,  an edgeedge with one O(3)Li3MnCrNi octahedra,  an edgeedge with one O(7)Li3MnCrNi octahedra, and  an edgeedge with one O(8)Li3MnCrNi octahedra. In the eleventh O site, O(11) is bonded to one Li(4), one Li(5), one Li(6), one Cr(3), one Mn(2), and one Ni(1) atom to form OLi3MnCrNi octahedra that share edges with two equivalent O(4)Li3Cr2Ni octahedra, edges with two equivalent O(7)Li3MnCrNi octahedra,  an edgeedge with one O(10)Li3Mn2Cr pentagonal pyramid, and  an edgeedge with one O(9)Li3MnCr2 pentagonal pyramid. In the twelfth O site, O(12) is bonded to one Li(2), one Li(3), one Li(7), one Mn(1), one Mn(3), and one Ni(2) atom to form OLi3Mn2Ni octahedra that share edges with two equivalent O(3)Li3MnCrNi octahedra, edges with two equivalent O(8)Li3MnCrNi octahedra,  an edgeedge with one O(10)Li3Mn2Cr pentagonal pyramid, and  an edgeedge with one O(9)Li3MnCr2 pentagonal pyramid. In the thirteenth O site, O(13) is bonded in a 7-coordinate geometry to one Li(1), one Li(3), one Li(5), one Li(9), one Mn(1), one Mn(3), and one Ni(1) atom. In the fourteenth O site, O(14) is bonded in a 7-coordinate geometry to one Li(10), one Li(4), one Li(7), one Li(8), one Cr(3), one Mn(2), and one Ni(2) atom. In the fifteenth O site, O(15) is bonded in a 7-coordinate geometry to one Li(1), one Li(5), one Li(6), one Li(9), one Cr(1), one Cr(3), and one Mn(2) atom. In the sixteenth O site, O(16) is bonded in a 7-coordinate geometry to one Li(10), one Li(2), one Li(7), one Li(8), one Cr(2), one Mn(1), and one Mn(3) atom. is represented by the CIF file [CIF]
data_Li10Mn3Cr3(NiO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.917
_cell_length_b   5.987
_cell_length_c   9.806
_cell_angle_alpha   90.879
_cell_angle_beta   90.905
_cell_angle_gamma   119.085
_symmetry_Int_Tables_number   1
_cell_volume   303.448
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.016  0.994  0.482  1.0
  Li  Li1  1  0.197  0.398  0.063  1.0
  Li  Li2  1  0.355  0.677  0.283  1.0
  Li  Li3  1  0.687  0.336  0.783  1.0
  Li  Li4  1  0.817  0.186  0.563  1.0
  Li  Li5  1  0.400  0.182  0.565  1.0
  Li  Li6  1  0.216  0.813  0.054  1.0
  Li  Li7  1  0.618  0.797  0.058  1.0
  Li  Li8  1  0.803  0.598  0.555  1.0
  Li  Li9  1  0.018  0.011  0.983  1.0
  Mn  Mn10  1  0.849  0.176  0.286  1.0
  Mn  Mn11  1  0.679  0.831  0.784  1.0
  Mn  Mn12  1  0.846  0.666  0.285  1.0
  Cr  Cr13  1  0.185  0.337  0.787  1.0
  Cr  Cr14  1  0.352  0.172  0.286  1.0
  Cr  Cr15  1  0.184  0.831  0.785  1.0
  Ni  Ni16  1  0.343  0.654  0.530  1.0
  Ni  Ni17  1  0.679  0.336  0.030  1.0
  O  O18  1  0.341  0.161  0.904  1.0
  O  O19  1  0.169  0.319  0.403  1.0
  O  O20  1  0.532  0.025  0.167  1.0
  O  O21  1  0.031  0.508  0.666  1.0
  O  O22  1  0.181  0.841  0.395  1.0
  O  O23  1  0.853  0.164  0.896  1.0
  O  O24  1  0.506  0.505  0.672  1.0
  O  O25  1  0.521  0.493  0.171  1.0
  O  O26  1  0.329  0.657  0.909  1.0
  O  O27  1  0.674  0.304  0.409  1.0
  O  O28  1  0.505  0.970  0.670  1.0
  O  O29  1  0.999  0.522  0.162  1.0
  O  O30  1  0.685  0.801  0.411  1.0
  O  O31  1  0.853  0.688  0.899  1.0
  O  O32  1  0.043  0.014  0.669  1.0
  O  O33  1  0.021  0.036  0.170  1.0
[/CIF]
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