The crystal structure described by K2Cd(AuS)4 crystallizes in the orthorhombic Ibam space group. K(1) is bonded in a 8-coordinate geometry to two equivalent Au(1) and six equivalent S(1) atoms. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a 4-coordinate geometry to two equivalent K(1) and two equivalent S(1) atoms. In the second Au site, Au(2) is bonded in a 4-coordinate geometry to two equivalent Cd(1) and two equivalent S(1) atoms. Cd(1) is bonded in a 4-coordinate geometry to four equivalent Au(2) and four equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to three equivalent K(1), one Au(1), one Au(2), and one Cd(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2Cd(AuS)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.875
_cell_length_b   9.875
_cell_length_c   9.875
_cell_angle_alpha   137.682
_cell_angle_beta   113.564
_cell_angle_gamma   81.998
_symmetry_Int_Tables_number   1
_cell_volume   574.917
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.152  0.161  0.313  1.0
  K  K1  1  0.348  0.661  0.010  1.0
  K  K2  1  0.652  0.339  0.990  1.0
  K  K3  1  0.848  0.839  0.687  1.0
  Cd  Cd4  1  0.750  0.750  0.000  1.0
  Cd  Cd5  1  0.250  0.250  0.000  1.0
  Au  Au6  1  0.137  0.637  0.500  1.0
  Au  Au7  1  0.863  0.363  0.500  1.0
  Au  Au8  1  0.500  0.000  0.000  1.0
  Au  Au9  1  0.637  0.137  0.500  1.0
  Au  Au10  1  0.363  0.863  0.500  1.0
  Au  Au11  1  0.000  0.500  0.000  1.0
  Au  Au12  1  0.000  0.000  0.500  1.0
  Au  Au13  1  0.500  0.500  0.500  1.0
  S  S14  1  0.019  0.350  0.108  1.0
  S  S15  1  0.742  0.850  0.331  1.0
  S  S16  1  0.758  0.089  0.108  1.0
  S  S17  1  0.981  0.650  0.892  1.0
  S  S18  1  0.258  0.150  0.669  1.0
  S  S19  1  0.519  0.411  0.669  1.0
  S  S20  1  0.481  0.589  0.331  1.0
  S  S21  1  0.242  0.911  0.892  1.0
[/CIF]
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The crystal structure described by K2Cd(AuS)4 crystallizes in the orthorhombic Ibam space group. K(1) is bonded in a 8-coordinate geometry to two equivalent Au(1) and six equivalent S(1) atoms. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a 4-coordinate geometry to two equivalent K(1) and two equivalent S(1) atoms. In the second Au site, Au(2) is bonded in a 4-coordinate geometry to two equivalent Cd(1) and two equivalent S(1) atoms. Cd(1) is bonded in a 4-coordinate geometry to four equivalent Au(2) and four equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to three equivalent K(1), one Au(1), one Au(2), and one Cd(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2Cd(AuS)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.875
_cell_length_b   9.875
_cell_length_c   9.875
_cell_angle_alpha   137.682
_cell_angle_beta   113.564
_cell_angle_gamma   81.998
_symmetry_Int_Tables_number   1
_cell_volume   574.917
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.152  0.161  0.313  1.0
  K  K1  1  0.348  0.661  0.010  1.0
  K  K2  1  0.652  0.339  0.990  1.0
  K  K3  1  0.848  0.839  0.687  1.0
  Cd  Cd4  1  0.750  0.750  0.000  1.0
  Cd  Cd5  1  0.250  0.250  0.000  1.0
  Au  Au6  1  0.137  0.637  0.500  1.0
  Au  Au7  1  0.863  0.363  0.500  1.0
  Au  Au8  1  0.500  0.000  0.000  1.0
  Au  Au9  1  0.637  0.137  0.500  1.0
  Au  Au10  1  0.363  0.863  0.500  1.0
  Au  Au11  1  0.000  0.500  0.000  1.0
  Au  Au12  1  0.000  0.000  0.500  1.0
  Au  Au13  1  0.500  0.500  0.500  1.0
  S  S14  1  0.019  0.350  0.108  1.0
  S  S15  1  0.742  0.850  0.331  1.0
  S  S16  1  0.758  0.089  0.108  1.0
  S  S17  1  0.981  0.650  0.892  1.0
  S  S18  1  0.258  0.150  0.669  1.0
  S  S19  1  0.519  0.411  0.669  1.0
  S  S20  1  0.481  0.589  0.331  1.0
  S  S21  1  0.242  0.911  0.892  1.0
[/CIF]
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