The structure described by WO3 is High-temperature superconductor-like structured and crystallizes in the tetragonal P-42_1m space group. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a linear geometry to two equivalent W(1) atoms. In the second O site, O(1) is bonded in a linear geometry to two equivalent W(1) atoms. is represented by the CIF card [CIF]
data_WO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.589
_cell_length_b   7.589
_cell_length_c   3.886
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   223.811
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.733  0.233  0.055  1.0
  W  W1  1  0.267  0.767  0.055  1.0
  W  W2  1  0.767  0.733  0.945  1.0
  W  W3  1  0.233  0.267  0.945  1.0
  O  O4  1  0.745  0.245  0.511  1.0
  O  O5  1  0.245  0.255  0.489  1.0
  O  O6  1  0.255  0.755  0.511  1.0
  O  O7  1  0.755  0.745  0.489  1.0
  O  O8  1  0.251  0.005  0.005  1.0
  O  O9  1  0.249  0.505  0.995  1.0
  O  O10  1  0.995  0.251  0.995  1.0
  O  O11  1  0.749  0.995  0.005  1.0
  O  O12  1  0.005  0.749  0.995  1.0
  O  O13  1  0.495  0.249  0.005  1.0
  O  O14  1  0.505  0.751  0.005  1.0
  O  O15  1  0.751  0.495  0.995  1.0
[/CIF]
.
The structure described by WO3 is High-temperature superconductor-like structured and crystallizes in the tetragonal P-42_1m space group. W(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form distorted corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a linear geometry to two equivalent W(1) atoms. In the second O site, O(1) is bonded in a linear geometry to two equivalent W(1) atoms. is represented by the CIF card [CIF]
data_WO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.589
_cell_length_b   7.589
_cell_length_c   3.886
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   223.811
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.733  0.233  0.055  1.0
  W  W1  1  0.267  0.767  0.055  1.0
  W  W2  1  0.767  0.733  0.945  1.0
  W  W3  1  0.233  0.267  0.945  1.0
  O  O4  1  0.745  0.245  0.511  1.0
  O  O5  1  0.245  0.255  0.489  1.0
  O  O6  1  0.255  0.755  0.511  1.0
  O  O7  1  0.755  0.745  0.489  1.0
  O  O8  1  0.251  0.005  0.005  1.0
  O  O9  1  0.249  0.505  0.995  1.0
  O  O10  1  0.995  0.251  0.995  1.0
  O  O11  1  0.749  0.995  0.005  1.0
  O  O12  1  0.005  0.749  0.995  1.0
  O  O13  1  0.495  0.249  0.005  1.0
  O  O14  1  0.505  0.751  0.005  1.0
  O  O15  1  0.751  0.495  0.995  1.0
[/CIF]
.