The crystal structure described by (Mg(HCl)2)2Ca(ClO)2(H2)8(H2O2)2(O2)3 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 1333-74-0 molecules, one chlorkalk molecule, two trioxidane molecules, four water molecules, and one Mg(HCl)2 cluster. In the Mg(HCl)2 cluster, Mg(1) is bonded in a 5-coordinate geometry to one H(3), one H(9), one Cl(2), and two equivalent Cl(3) atoms. There are two inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one Mg(1) atom. In the second H site, H(9) is bonded in a single-bond geometry to one Mg(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Mg(1) atom. In the second Cl site, Cl(3) is bonded in an L-shaped geometry to two equivalent Mg(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CaMg2H24(ClO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.278
_cell_length_b   8.955
_cell_length_c   13.061
_cell_angle_alpha   106.755
_cell_angle_beta   90.488
_cell_angle_gamma   107.101
_symmetry_Int_Tables_number   1
_cell_volume   881.485
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.000  0.000  0.000  1.0
  Mg  Mg1  1  0.811  0.374  0.488  1.0
  Mg  Mg2  1  0.189  0.626  0.512  1.0
  H  H3  1  0.900  0.691  0.975  1.0
  H  H4  1  0.433  0.629  0.025  1.0
  H  H5  1  0.642  0.378  0.598  1.0
  H  H6  1  0.100  0.309  0.025  1.0
  H  H7  1  0.567  0.371  0.975  1.0
  H  H8  1  0.358  0.622  0.402  1.0
  H  H9  1  0.190  0.893  0.434  1.0
  H  H10  1  0.803  0.500  0.097  1.0
  H  H11  1  0.029  0.293  0.982  1.0
  H  H12  1  0.810  0.107  0.566  1.0
  H  H13  1  0.197  0.500  0.903  1.0
  H  H14  1  0.971  0.707  0.018  1.0
  H  H15  1  0.414  0.636  0.792  1.0
  H  H16  1  0.836  0.879  0.422  1.0
  H  H17  1  0.235  0.503  0.635  1.0
  H  H18  1  0.586  0.364  0.208  1.0
  H  H19  1  0.164  0.121  0.578  1.0
  H  H20  1  0.765  0.497  0.365  1.0
  H  H21  1  0.532  0.372  0.922  1.0
  H  H22  1  0.271  0.878  0.416  1.0
  H  H23  1  0.848  0.919  0.378  1.0
  H  H24  1  0.468  0.628  0.078  1.0
  H  H25  1  0.729  0.122  0.584  1.0
  H  H26  1  0.152  0.081  0.622  1.0
  Cl  Cl27  1  0.656  0.942  0.988  1.0
  Cl  Cl28  1  0.468  0.762  0.567  1.0
  Cl  Cl29  1  0.931  0.668  0.564  1.0
  Cl  Cl30  1  0.344  0.058  0.012  1.0
  Cl  Cl31  1  0.532  0.238  0.433  1.0
  Cl  Cl32  1  0.069  0.332  0.436  1.0
  O  O33  1  0.700  0.371  0.185  1.0
  O  O34  1  0.742  0.527  0.160  1.0
  O  O35  1  0.760  0.842  0.897  1.0
  O  O36  1  0.300  0.629  0.815  1.0
  O  O37  1  0.258  0.473  0.840  1.0
  O  O38  1  0.240  0.158  0.103  1.0
  O  O39  1  0.841  0.993  0.758  1.0
  O  O40  1  0.790  0.234  0.803  1.0
  O  O41  1  0.899  0.152  0.794  1.0
  O  O42  1  0.159  0.007  0.242  1.0
  O  O43  1  0.210  0.766  0.197  1.0
  O  O44  1  0.101  0.848  0.206  1.0
[/CIF]
.
The crystal structure described by (Mg(HCl)2)2Ca(ClO)2(H2)8(H2O2)2(O2)3 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 1333-74-0 molecules, one chlorkalk molecule, two trioxidane molecules, four water molecules, and one Mg(HCl)2 cluster. In the Mg(HCl)2 cluster, Mg(1) is bonded in a 5-coordinate geometry to one H(3), one H(9), one Cl(2), and two equivalent Cl(3) atoms. There are two inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one Mg(1) atom. In the second H site, H(9) is bonded in a single-bond geometry to one Mg(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Mg(1) atom. In the second Cl site, Cl(3) is bonded in an L-shaped geometry to two equivalent Mg(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CaMg2H24(ClO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.278
_cell_length_b   8.955
_cell_length_c   13.061
_cell_angle_alpha   106.755
_cell_angle_beta   90.488
_cell_angle_gamma   107.101
_symmetry_Int_Tables_number   1
_cell_volume   881.485
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.000  0.000  0.000  1.0
  Mg  Mg1  1  0.811  0.374  0.488  1.0
  Mg  Mg2  1  0.189  0.626  0.512  1.0
  H  H3  1  0.900  0.691  0.975  1.0
  H  H4  1  0.433  0.629  0.025  1.0
  H  H5  1  0.642  0.378  0.598  1.0
  H  H6  1  0.100  0.309  0.025  1.0
  H  H7  1  0.567  0.371  0.975  1.0
  H  H8  1  0.358  0.622  0.402  1.0
  H  H9  1  0.190  0.893  0.434  1.0
  H  H10  1  0.803  0.500  0.097  1.0
  H  H11  1  0.029  0.293  0.982  1.0
  H  H12  1  0.810  0.107  0.566  1.0
  H  H13  1  0.197  0.500  0.903  1.0
  H  H14  1  0.971  0.707  0.018  1.0
  H  H15  1  0.414  0.636  0.792  1.0
  H  H16  1  0.836  0.879  0.422  1.0
  H  H17  1  0.235  0.503  0.635  1.0
  H  H18  1  0.586  0.364  0.208  1.0
  H  H19  1  0.164  0.121  0.578  1.0
  H  H20  1  0.765  0.497  0.365  1.0
  H  H21  1  0.532  0.372  0.922  1.0
  H  H22  1  0.271  0.878  0.416  1.0
  H  H23  1  0.848  0.919  0.378  1.0
  H  H24  1  0.468  0.628  0.078  1.0
  H  H25  1  0.729  0.122  0.584  1.0
  H  H26  1  0.152  0.081  0.622  1.0
  Cl  Cl27  1  0.656  0.942  0.988  1.0
  Cl  Cl28  1  0.468  0.762  0.567  1.0
  Cl  Cl29  1  0.931  0.668  0.564  1.0
  Cl  Cl30  1  0.344  0.058  0.012  1.0
  Cl  Cl31  1  0.532  0.238  0.433  1.0
  Cl  Cl32  1  0.069  0.332  0.436  1.0
  O  O33  1  0.700  0.371  0.185  1.0
  O  O34  1  0.742  0.527  0.160  1.0
  O  O35  1  0.760  0.842  0.897  1.0
  O  O36  1  0.300  0.629  0.815  1.0
  O  O37  1  0.258  0.473  0.840  1.0
  O  O38  1  0.240  0.158  0.103  1.0
  O  O39  1  0.841  0.993  0.758  1.0
  O  O40  1  0.790  0.234  0.803  1.0
  O  O41  1  0.899  0.152  0.794  1.0
  O  O42  1  0.159  0.007  0.242  1.0
  O  O43  1  0.210  0.766  0.197  1.0
  O  O44  1  0.101  0.848  0.206  1.0
[/CIF]
.