The compound described by CsAgGaF6 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 7-coordinate geometry to one F(4), two equivalent F(1), and four equivalent F(3) atoms. Ag(1) is bonded to two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms to form AgF6 octahedra that share corners with two equivalent Ag(1)F6 octahedra and corners with four equivalent Ga(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 48-61°. Ga(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form GaF6 octahedra that share corners with two equivalent Ga(1)F6 octahedra and corners with four equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 21-61°. There are four inequivalent F sites. In the first F site, F(4) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Ag(1) atoms. In the second F site, F(1) is bonded in a 2-coordinate geometry to one Cs(1), one Ag(1), and one Ga(1) atom. In the third F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Ga(1) atoms. In the fourth F site, F(3) is bonded in a 4-coordinate geometry to two equivalent Cs(1), one Ag(1), and one Ga(1) atom. is represented by the CIF card [CIF]
data_CsGaAgF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.569
_cell_length_b   7.703
_cell_length_c   10.634
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   619.981
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.020  0.250  0.633  1.0
  Cs  Cs1  1  0.980  0.750  0.367  1.0
  Cs  Cs2  1  0.480  0.750  0.133  1.0
  Cs  Cs3  1  0.520  0.250  0.867  1.0
  Ga  Ga4  1  0.000  0.000  0.000  1.0
  Ga  Ga5  1  0.500  0.000  0.500  1.0
  Ga  Ga6  1  0.000  0.500  0.000  1.0
  Ga  Ga7  1  0.500  0.500  0.500  1.0
  Ag  Ag8  1  0.215  0.250  0.253  1.0
  Ag  Ag9  1  0.785  0.750  0.747  1.0
  Ag  Ag10  1  0.285  0.750  0.753  1.0
  Ag  Ag11  1  0.715  0.250  0.247  1.0
  F  F12  1  0.291  0.035  0.403  1.0
  F  F13  1  0.709  0.965  0.597  1.0
  F  F14  1  0.209  0.965  0.903  1.0
  F  F15  1  0.709  0.535  0.597  1.0
  F  F16  1  0.791  0.035  0.097  1.0
  F  F17  1  0.291  0.465  0.403  1.0
  F  F18  1  0.791  0.465  0.097  1.0
  F  F19  1  0.209  0.535  0.903  1.0
  F  F20  1  0.545  0.250  0.510  1.0
  F  F21  1  0.455  0.750  0.490  1.0
  F  F22  1  0.955  0.750  0.010  1.0
  F  F23  1  0.045  0.250  0.990  1.0
  F  F24  1  0.141  0.509  0.150  1.0
  F  F25  1  0.859  0.491  0.850  1.0
  F  F26  1  0.359  0.491  0.650  1.0
  F  F27  1  0.859  0.009  0.850  1.0
  F  F28  1  0.641  0.509  0.350  1.0
  F  F29  1  0.141  0.991  0.150  1.0
  F  F30  1  0.641  0.991  0.350  1.0
  F  F31  1  0.359  0.009  0.650  1.0
  F  F32  1  0.463  0.250  0.170  1.0
  F  F33  1  0.537  0.750  0.830  1.0
  F  F34  1  0.037  0.750  0.670  1.0
  F  F35  1  0.963  0.250  0.330  1.0
[/CIF]
.
The compound described by CsAgGaF6 crystallizes in the orthorhombic Pnma space group. Cs(1) is bonded in a 7-coordinate geometry to one F(4), two equivalent F(1), and four equivalent F(3) atoms. Ag(1) is bonded to two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms to form AgF6 octahedra that share corners with two equivalent Ag(1)F6 octahedra and corners with four equivalent Ga(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 48-61°. Ga(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form GaF6 octahedra that share corners with two equivalent Ga(1)F6 octahedra and corners with four equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 21-61°. There are four inequivalent F sites. In the first F site, F(4) is bonded in a 2-coordinate geometry to one Cs(1) and two equivalent Ag(1) atoms. In the second F site, F(1) is bonded in a 2-coordinate geometry to one Cs(1), one Ag(1), and one Ga(1) atom. In the third F site, F(2) is bonded in a bent 150 degrees geometry to two equivalent Ga(1) atoms. In the fourth F site, F(3) is bonded in a 4-coordinate geometry to two equivalent Cs(1), one Ag(1), and one Ga(1) atom. is represented by the CIF card [CIF]
data_CsGaAgF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.569
_cell_length_b   7.703
_cell_length_c   10.634
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   619.981
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.020  0.250  0.633  1.0
  Cs  Cs1  1  0.980  0.750  0.367  1.0
  Cs  Cs2  1  0.480  0.750  0.133  1.0
  Cs  Cs3  1  0.520  0.250  0.867  1.0
  Ga  Ga4  1  0.000  0.000  0.000  1.0
  Ga  Ga5  1  0.500  0.000  0.500  1.0
  Ga  Ga6  1  0.000  0.500  0.000  1.0
  Ga  Ga7  1  0.500  0.500  0.500  1.0
  Ag  Ag8  1  0.215  0.250  0.253  1.0
  Ag  Ag9  1  0.785  0.750  0.747  1.0
  Ag  Ag10  1  0.285  0.750  0.753  1.0
  Ag  Ag11  1  0.715  0.250  0.247  1.0
  F  F12  1  0.291  0.035  0.403  1.0
  F  F13  1  0.709  0.965  0.597  1.0
  F  F14  1  0.209  0.965  0.903  1.0
  F  F15  1  0.709  0.535  0.597  1.0
  F  F16  1  0.791  0.035  0.097  1.0
  F  F17  1  0.291  0.465  0.403  1.0
  F  F18  1  0.791  0.465  0.097  1.0
  F  F19  1  0.209  0.535  0.903  1.0
  F  F20  1  0.545  0.250  0.510  1.0
  F  F21  1  0.455  0.750  0.490  1.0
  F  F22  1  0.955  0.750  0.010  1.0
  F  F23  1  0.045  0.250  0.990  1.0
  F  F24  1  0.141  0.509  0.150  1.0
  F  F25  1  0.859  0.491  0.850  1.0
  F  F26  1  0.359  0.491  0.650  1.0
  F  F27  1  0.859  0.009  0.850  1.0
  F  F28  1  0.641  0.509  0.350  1.0
  F  F29  1  0.141  0.991  0.150  1.0
  F  F30  1  0.641  0.991  0.350  1.0
  F  F31  1  0.359  0.009  0.650  1.0
  F  F32  1  0.463  0.250  0.170  1.0
  F  F33  1  0.537  0.750  0.830  1.0
  F  F34  1  0.037  0.750  0.670  1.0
  F  F35  1  0.963  0.250  0.330  1.0
[/CIF]
.