The crystal structure described by ClF3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ClF3 clusters. Cl(1) is bonded in a T-shaped geometry to one F(3), one F(5), and one F(6) atom. There are three inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Cl(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one Cl(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Cl(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ClF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.255
_cell_length_b   7.720
_cell_length_c   15.057
_cell_angle_alpha   96.114
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   491.743
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cl  Cl0  1  0.928  0.785  0.580  1.0
  Cl  Cl1  1  0.994  0.384  0.132  1.0
  Cl  Cl2  1  0.506  0.384  0.632  1.0
  Cl  Cl3  1  0.494  0.616  0.368  1.0
  Cl  Cl4  1  0.072  0.215  0.420  1.0
  Cl  Cl5  1  0.428  0.215  0.920  1.0
  Cl  Cl6  1  0.006  0.616  0.868  1.0
  Cl  Cl7  1  0.572  0.785  0.080  1.0
  F  F8  1  0.698  0.594  0.950  1.0
  F  F9  1  0.287  0.647  0.791  1.0
  F  F10  1  0.726  0.122  0.975  1.0
  F  F11  1  0.213  0.647  0.291  1.0
  F  F12  1  0.405  0.182  0.630  1.0
  F  F13  1  0.989  0.090  0.330  1.0
  F  F14  1  0.011  0.910  0.670  1.0
  F  F15  1  0.226  0.878  0.525  1.0
  F  F16  1  0.802  0.594  0.450  1.0
  F  F17  1  0.274  0.878  0.025  1.0
  F  F18  1  0.595  0.818  0.370  1.0
  F  F19  1  0.622  0.691  0.643  1.0
  F  F20  1  0.095  0.182  0.130  1.0
  F  F21  1  0.713  0.353  0.209  1.0
  F  F22  1  0.122  0.309  0.857  1.0
  F  F23  1  0.511  0.090  0.830  1.0
  F  F24  1  0.378  0.309  0.357  1.0
  F  F25  1  0.774  0.122  0.475  1.0
  F  F26  1  0.878  0.691  0.143  1.0
  F  F27  1  0.198  0.406  0.550  1.0
  F  F28  1  0.302  0.406  0.050  1.0
  F  F29  1  0.489  0.910  0.170  1.0
  F  F30  1  0.787  0.353  0.709  1.0
  F  F31  1  0.905  0.818  0.870  1.0
[/CIF]
.
The crystal structure described by ClF3 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ClF3 clusters. Cl(1) is bonded in a T-shaped geometry to one F(3), one F(5), and one F(6) atom. There are three inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one Cl(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one Cl(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Cl(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ClF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.255
_cell_length_b   7.720
_cell_length_c   15.057
_cell_angle_alpha   96.114
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   491.743
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cl  Cl0  1  0.928  0.785  0.580  1.0
  Cl  Cl1  1  0.994  0.384  0.132  1.0
  Cl  Cl2  1  0.506  0.384  0.632  1.0
  Cl  Cl3  1  0.494  0.616  0.368  1.0
  Cl  Cl4  1  0.072  0.215  0.420  1.0
  Cl  Cl5  1  0.428  0.215  0.920  1.0
  Cl  Cl6  1  0.006  0.616  0.868  1.0
  Cl  Cl7  1  0.572  0.785  0.080  1.0
  F  F8  1  0.698  0.594  0.950  1.0
  F  F9  1  0.287  0.647  0.791  1.0
  F  F10  1  0.726  0.122  0.975  1.0
  F  F11  1  0.213  0.647  0.291  1.0
  F  F12  1  0.405  0.182  0.630  1.0
  F  F13  1  0.989  0.090  0.330  1.0
  F  F14  1  0.011  0.910  0.670  1.0
  F  F15  1  0.226  0.878  0.525  1.0
  F  F16  1  0.802  0.594  0.450  1.0
  F  F17  1  0.274  0.878  0.025  1.0
  F  F18  1  0.595  0.818  0.370  1.0
  F  F19  1  0.622  0.691  0.643  1.0
  F  F20  1  0.095  0.182  0.130  1.0
  F  F21  1  0.713  0.353  0.209  1.0
  F  F22  1  0.122  0.309  0.857  1.0
  F  F23  1  0.511  0.090  0.830  1.0
  F  F24  1  0.378  0.309  0.357  1.0
  F  F25  1  0.774  0.122  0.475  1.0
  F  F26  1  0.878  0.691  0.143  1.0
  F  F27  1  0.198  0.406  0.550  1.0
  F  F28  1  0.302  0.406  0.050  1.0
  F  F29  1  0.489  0.910  0.170  1.0
  F  F30  1  0.787  0.353  0.709  1.0
  F  F31  1  0.905  0.818  0.870  1.0
[/CIF]
.