The compound described by RbAuCdS2 crystallizes in the orthorhombic Pcca space group. Rb(1) is bonded to two equivalent Au(1) and six equivalent S(1) atoms to form a mixture of distorted corner and edge-sharing RbAu2S6 hexagonal bipyramids. Au(1) is bonded in a 2-coordinate geometry to two equivalent Rb(1) and two equivalent S(1) atoms. Cd(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to three equivalent Rb(1), one Au(1), and two equivalent Cd(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbCdAuS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.919
_cell_length_b   6.970
_cell_length_c   13.960
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   575.954
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.723  0.750  0.000  1.0
  Rb  Rb1  1  0.723  0.250  0.500  1.0
  Rb  Rb2  1  0.277  0.750  0.500  1.0
  Rb  Rb3  1  0.277  0.250  0.000  1.0
  Cd  Cd4  1  0.000  0.562  0.750  1.0
  Cd  Cd5  1  0.000  0.062  0.750  1.0
  Cd  Cd6  1  0.000  0.938  0.250  1.0
  Cd  Cd7  1  0.000  0.438  0.250  1.0
  Au  Au8  1  0.500  0.316  0.750  1.0
  Au  Au9  1  0.500  0.684  0.250  1.0
  Au  Au10  1  0.500  0.816  0.750  1.0
  Au  Au11  1  0.500  0.184  0.250  1.0
  S  S12  1  0.795  0.315  0.861  1.0
  S  S13  1  0.795  0.685  0.361  1.0
  S  S14  1  0.205  0.315  0.639  1.0
  S  S15  1  0.795  0.815  0.639  1.0
  S  S16  1  0.205  0.185  0.361  1.0
  S  S17  1  0.205  0.685  0.139  1.0
  S  S18  1  0.795  0.185  0.139  1.0
  S  S19  1  0.205  0.815  0.861  1.0
[/CIF]
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The compound described by RbAuCdS2 crystallizes in the orthorhombic Pcca space group. Rb(1) is bonded to two equivalent Au(1) and six equivalent S(1) atoms to form a mixture of distorted corner and edge-sharing RbAu2S6 hexagonal bipyramids. Au(1) is bonded in a 2-coordinate geometry to two equivalent Rb(1) and two equivalent S(1) atoms. Cd(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to three equivalent Rb(1), one Au(1), and two equivalent Cd(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbCdAuS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.919
_cell_length_b   6.970
_cell_length_c   13.960
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   575.954
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.723  0.750  0.000  1.0
  Rb  Rb1  1  0.723  0.250  0.500  1.0
  Rb  Rb2  1  0.277  0.750  0.500  1.0
  Rb  Rb3  1  0.277  0.250  0.000  1.0
  Cd  Cd4  1  0.000  0.562  0.750  1.0
  Cd  Cd5  1  0.000  0.062  0.750  1.0
  Cd  Cd6  1  0.000  0.938  0.250  1.0
  Cd  Cd7  1  0.000  0.438  0.250  1.0
  Au  Au8  1  0.500  0.316  0.750  1.0
  Au  Au9  1  0.500  0.684  0.250  1.0
  Au  Au10  1  0.500  0.816  0.750  1.0
  Au  Au11  1  0.500  0.184  0.250  1.0
  S  S12  1  0.795  0.315  0.861  1.0
  S  S13  1  0.795  0.685  0.361  1.0
  S  S14  1  0.205  0.315  0.639  1.0
  S  S15  1  0.795  0.815  0.639  1.0
  S  S16  1  0.205  0.185  0.361  1.0
  S  S17  1  0.205  0.685  0.139  1.0
  S  S18  1  0.795  0.185  0.139  1.0
  S  S19  1  0.205  0.815  0.861  1.0
[/CIF]
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