The crystal structure described by Li6V2OF11 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one V(2), one F(10), one F(3), one F(7), and one F(8) atom. In the second Li site, Li(2) is bonded in a distorted bent 150 degrees geometry to one V(1), one F(1), and one F(9) atom. In the third Li site, Li(3) is bonded in a 2-coordinate geometry to one O(1), one F(10), and one F(9) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one F(1), one F(3), one F(5), and one F(8) atom. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(1), one F(2), one F(4), one F(6), and one F(9) atom. In the sixth Li site, Li(6) is bonded in a 2-coordinate geometry to one F(11), one F(6), and one F(8) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one Li(2), one O(1), one F(11), one F(6), and one F(9) atom. In the second V site, V(2) is bonded in a distorted linear geometry to one Li(1), one F(2), and one F(3) atom. O(1) is bonded in a 4-coordinate geometry to one Li(3), one Li(5), one V(1), and one F(4) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a 2-coordinate geometry to one Li(2) and one Li(4) atom. In the second F site, F(2) is bonded in an L-shaped geometry to one Li(5) and one V(2) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(1), one Li(4), and one V(2) atom. In the fourth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one Li(5) and one O(1) atom. In the fifth F site, F(5) is bonded in a 1-coordinate geometry to one Li(4) atom. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Li(5), one Li(6), and one V(1) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Li(1) atom. In the eighth F site, F(8) is bonded in a distorted single-bond geometry to one Li(1), one Li(4), and one Li(6) atom. In the ninth F site, F(9) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Li(5), and one V(1) atom. In the tenth F site, F(10) is bonded in a distorted L-shaped geometry to one Li(1) and one Li(3) atom. In the eleventh F site, F(11) is bonded in an L-shaped geometry to one Li(6) and one V(1) atom. is represented by the CIF file [CIF]
data_Li6V2OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.145
_cell_length_b   5.522
_cell_length_c   8.779
_cell_angle_alpha   106.276
_cell_angle_beta   89.670
_cell_angle_gamma   117.551
_symmetry_Int_Tables_number   1
_cell_volume   209.971
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.201  0.286  0.058  1.0
  Li  Li1  1  0.053  0.716  0.692  1.0
  Li  Li2  1  0.981  0.273  0.333  1.0
  Li  Li3  1  0.754  0.680  0.933  1.0
  Li  Li4  1  0.295  0.742  0.412  1.0
  Li  Li5  1  0.457  0.320  0.815  1.0
  V  V6  1  0.737  0.329  0.566  1.0
  V  V7  1  0.513  0.685  0.172  1.0
  O  O8  1  0.770  0.494  0.382  1.0
  F  F9  1  0.778  0.846  0.707  1.0
  F  F10  1  0.287  0.807  0.218  1.0
  F  F11  1  0.698  0.511  0.133  1.0
  F  F12  1  0.722  0.799  0.473  1.0
  F  F13  1  0.233  0.807  0.976  1.0
  F  F14  1  0.301  0.195  0.532  1.0
  F  F15  1  0.772  0.170  0.036  1.0
  F  F16  1  0.329  0.501  0.874  1.0
  F  F17  1  0.165  0.492  0.615  1.0
  F  F18  1  0.225  0.203  0.276  1.0
  F  F19  1  0.721  0.207  0.763  1.0
[/CIF]
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The crystal structure described by Li6V2OF11 crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded in a 5-coordinate geometry to one V(2), one F(10), one F(3), one F(7), and one F(8) atom. In the second Li site, Li(2) is bonded in a distorted bent 150 degrees geometry to one V(1), one F(1), and one F(9) atom. In the third Li site, Li(3) is bonded in a 2-coordinate geometry to one O(1), one F(10), and one F(9) atom. In the fourth Li site, Li(4) is bonded in a 4-coordinate geometry to one F(1), one F(3), one F(5), and one F(8) atom. In the fifth Li site, Li(5) is bonded in a 5-coordinate geometry to one O(1), one F(2), one F(4), one F(6), and one F(9) atom. In the sixth Li site, Li(6) is bonded in a 2-coordinate geometry to one F(11), one F(6), and one F(8) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one Li(2), one O(1), one F(11), one F(6), and one F(9) atom. In the second V site, V(2) is bonded in a distorted linear geometry to one Li(1), one F(2), and one F(3) atom. O(1) is bonded in a 4-coordinate geometry to one Li(3), one Li(5), one V(1), and one F(4) atom. There are eleven inequivalent F sites. In the first F site, F(1) is bonded in a 2-coordinate geometry to one Li(2) and one Li(4) atom. In the second F site, F(2) is bonded in an L-shaped geometry to one Li(5) and one V(2) atom. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Li(1), one Li(4), and one V(2) atom. In the fourth F site, F(4) is bonded in a distorted bent 120 degrees geometry to one Li(5) and one O(1) atom. In the fifth F site, F(5) is bonded in a 1-coordinate geometry to one Li(4) atom. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Li(5), one Li(6), and one V(1) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Li(1) atom. In the eighth F site, F(8) is bonded in a distorted single-bond geometry to one Li(1), one Li(4), and one Li(6) atom. In the ninth F site, F(9) is bonded in a 4-coordinate geometry to one Li(2), one Li(3), one Li(5), and one V(1) atom. In the tenth F site, F(10) is bonded in a distorted L-shaped geometry to one Li(1) and one Li(3) atom. In the eleventh F site, F(11) is bonded in an L-shaped geometry to one Li(6) and one V(1) atom. is represented by the CIF file [CIF]
data_Li6V2OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.145
_cell_length_b   5.522
_cell_length_c   8.779
_cell_angle_alpha   106.276
_cell_angle_beta   89.670
_cell_angle_gamma   117.551
_symmetry_Int_Tables_number   1
_cell_volume   209.971
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.201  0.286  0.058  1.0
  Li  Li1  1  0.053  0.716  0.692  1.0
  Li  Li2  1  0.981  0.273  0.333  1.0
  Li  Li3  1  0.754  0.680  0.933  1.0
  Li  Li4  1  0.295  0.742  0.412  1.0
  Li  Li5  1  0.457  0.320  0.815  1.0
  V  V6  1  0.737  0.329  0.566  1.0
  V  V7  1  0.513  0.685  0.172  1.0
  O  O8  1  0.770  0.494  0.382  1.0
  F  F9  1  0.778  0.846  0.707  1.0
  F  F10  1  0.287  0.807  0.218  1.0
  F  F11  1  0.698  0.511  0.133  1.0
  F  F12  1  0.722  0.799  0.473  1.0
  F  F13  1  0.233  0.807  0.976  1.0
  F  F14  1  0.301  0.195  0.532  1.0
  F  F15  1  0.772  0.170  0.036  1.0
  F  F16  1  0.329  0.501  0.874  1.0
  F  F17  1  0.165  0.492  0.615  1.0
  F  F18  1  0.225  0.203  0.276  1.0
  F  F19  1  0.721  0.207  0.763  1.0
[/CIF]
.