The material described by Ag13Ga5 is zeta silver zinc-like structured and crystallizes in the triclinic P1 space group. There are thirteen inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 2-coordinate geometry to two equivalent Ag(12), two equivalent Ag(13), two equivalent Ag(8), two equivalent Ag(9), one Ga(3), and one Ga(4) atom. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent Ag(7), one Ga(2), one Ga(5), and two equivalent Ga(1) atoms. In the third Ag site, Ag(3) is bonded in a 2-coordinate geometry to two equivalent Ag(13), two equivalent Ag(7), two equivalent Ag(9), one Ga(2), and one Ga(5) atom. In the fourth Ag site, Ag(4) is bonded in a 4-coordinate geometry to two equivalent Ag(12), two equivalent Ag(8), one Ga(3), one Ga(4), and two equivalent Ga(1) atoms. In the fifth Ag site, Ag(5) is bonded in a 2-coordinate geometry to two equivalent Ag(13), two equivalent Ag(8), two equivalent Ag(9), one Ga(2), and one Ga(4) atom. In the sixth Ag site, Ag(6) is bonded in a 4-coordinate geometry to two equivalent Ag(12), two equivalent Ag(7), one Ga(3), one Ga(5), and two equivalent Ga(1) atoms. In the seventh Ag site, Ag(7) is bonded in a 12-coordinate geometry to two equivalent Ag(2), two equivalent Ag(3), two equivalent Ag(6), two equivalent Ag(7), one Ga(1), one Ga(5), and two equivalent Ga(2) atoms. In the eighth Ag site, Ag(8) is bonded in a 12-coordinate geometry to one Ag(13), two equivalent Ag(1), two equivalent Ag(4), two equivalent Ag(5), two equivalent Ag(8), one Ga(4), and two equivalent Ga(3) atoms. In the ninth Ag site, Ag(9) is bonded in a 12-coordinate geometry to one Ag(13), two equivalent Ag(1), two equivalent Ag(3), two equivalent Ag(5), two equivalent Ag(9), one Ga(4), and two equivalent Ga(2) atoms. In the tenth Ag site, Ag(10) is bonded in a 4-coordinate geometry to one Ga(1), one Ga(5), and two equivalent Ga(3) atoms. In the eleventh Ag site, Ag(11) is bonded in a 3-coordinate geometry to one Ag(13), one Ga(5), and two equivalent Ga(2) atoms. In the twelfth Ag site, Ag(12) is bonded in a 12-coordinate geometry to two equivalent Ag(1), two equivalent Ag(12), two equivalent Ag(4), two equivalent Ag(6), one Ga(1), one Ga(4), and two equivalent Ga(3) atoms. In the thirteenth Ag site, Ag(13) is bonded in a 11-coordinate geometry to one Ag(11), one Ag(8), one Ag(9), two equivalent Ag(1), two equivalent Ag(13), two equivalent Ag(3), and two equivalent Ag(5) atoms. There are five inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 11-coordinate geometry to one Ag(10), one Ag(12), one Ag(7), two equivalent Ag(2), two equivalent Ag(4), two equivalent Ag(6), and two equivalent Ga(1) atoms. In the second Ga site, Ga(2) is bonded in a 11-coordinate geometry to one Ag(2), one Ag(3), one Ag(5), two equivalent Ag(11), two equivalent Ag(7), two equivalent Ag(9), and two equivalent Ga(2) atoms. In the third Ga site, Ga(3) is bonded in a 11-coordinate geometry to one Ag(1), one Ag(4), one Ag(6), two equivalent Ag(10), two equivalent Ag(12), two equivalent Ag(8), and two equivalent Ga(3) atoms. In the fourth Ga site, Ga(4) is bonded in a 6-coordinate geometry to one Ag(1), one Ag(12), one Ag(4), one Ag(5), one Ag(8), and one Ag(9) atom. In the fifth Ga site, Ga(5) is bonded in a 6-coordinate geometry to one Ag(10), one Ag(11), one Ag(2), one Ag(3), one Ag(6), and one Ag(7) atom. is represented by the CIF card [CIF]
data_Ga5Ag13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.889
_cell_length_b   7.757
_cell_length_c   13.366
_cell_angle_alpha   90.004
_cell_angle_beta   89.940
_cell_angle_gamma   90.068
_symmetry_Int_Tables_number   1
_cell_volume   299.516
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.248  0.001  0.667  1.0
  Ga  Ga1  1  0.750  0.999  0.332  1.0
  Ga  Ga2  1  0.753  0.500  0.835  1.0
  Ga  Ga3  1  0.006  0.001  0.001  1.0
  Ga  Ga4  1  0.005  0.499  0.498  1.0
  Ag  Ag5  1  0.745  0.671  0.011  1.0
  Ag  Ag6  1  0.749  0.165  0.516  1.0
  Ag  Ag7  1  0.744  0.649  0.329  1.0
  Ag  Ag8  1  0.747  0.143  0.824  1.0
  Ag  Ag9  1  0.744  0.185  0.159  1.0
  Ag  Ag10  1  0.746  0.689  0.660  1.0
  Ag  Ag11  1  0.250  0.836  0.487  1.0
  Ag  Ag12  1  0.254  0.332  0.982  1.0
  Ag  Ag13  1  0.254  0.857  0.175  1.0
  Ag  Ag14  1  0.251  0.356  0.675  1.0
  Ag  Ag15  1  0.255  0.306  0.343  1.0
  Ag  Ag16  1  0.252  0.811  0.838  1.0
  Ag  Ag17  1  0.246  0.500  0.167  1.0
[/CIF]
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The material described by Ag13Ga5 is zeta silver zinc-like structured and crystallizes in the triclinic P1 space group. There are thirteen inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 2-coordinate geometry to two equivalent Ag(12), two equivalent Ag(13), two equivalent Ag(8), two equivalent Ag(9), one Ga(3), and one Ga(4) atom. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent Ag(7), one Ga(2), one Ga(5), and two equivalent Ga(1) atoms. In the third Ag site, Ag(3) is bonded in a 2-coordinate geometry to two equivalent Ag(13), two equivalent Ag(7), two equivalent Ag(9), one Ga(2), and one Ga(5) atom. In the fourth Ag site, Ag(4) is bonded in a 4-coordinate geometry to two equivalent Ag(12), two equivalent Ag(8), one Ga(3), one Ga(4), and two equivalent Ga(1) atoms. In the fifth Ag site, Ag(5) is bonded in a 2-coordinate geometry to two equivalent Ag(13), two equivalent Ag(8), two equivalent Ag(9), one Ga(2), and one Ga(4) atom. In the sixth Ag site, Ag(6) is bonded in a 4-coordinate geometry to two equivalent Ag(12), two equivalent Ag(7), one Ga(3), one Ga(5), and two equivalent Ga(1) atoms. In the seventh Ag site, Ag(7) is bonded in a 12-coordinate geometry to two equivalent Ag(2), two equivalent Ag(3), two equivalent Ag(6), two equivalent Ag(7), one Ga(1), one Ga(5), and two equivalent Ga(2) atoms. In the eighth Ag site, Ag(8) is bonded in a 12-coordinate geometry to one Ag(13), two equivalent Ag(1), two equivalent Ag(4), two equivalent Ag(5), two equivalent Ag(8), one Ga(4), and two equivalent Ga(3) atoms. In the ninth Ag site, Ag(9) is bonded in a 12-coordinate geometry to one Ag(13), two equivalent Ag(1), two equivalent Ag(3), two equivalent Ag(5), two equivalent Ag(9), one Ga(4), and two equivalent Ga(2) atoms. In the tenth Ag site, Ag(10) is bonded in a 4-coordinate geometry to one Ga(1), one Ga(5), and two equivalent Ga(3) atoms. In the eleventh Ag site, Ag(11) is bonded in a 3-coordinate geometry to one Ag(13), one Ga(5), and two equivalent Ga(2) atoms. In the twelfth Ag site, Ag(12) is bonded in a 12-coordinate geometry to two equivalent Ag(1), two equivalent Ag(12), two equivalent Ag(4), two equivalent Ag(6), one Ga(1), one Ga(4), and two equivalent Ga(3) atoms. In the thirteenth Ag site, Ag(13) is bonded in a 11-coordinate geometry to one Ag(11), one Ag(8), one Ag(9), two equivalent Ag(1), two equivalent Ag(13), two equivalent Ag(3), and two equivalent Ag(5) atoms. There are five inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 11-coordinate geometry to one Ag(10), one Ag(12), one Ag(7), two equivalent Ag(2), two equivalent Ag(4), two equivalent Ag(6), and two equivalent Ga(1) atoms. In the second Ga site, Ga(2) is bonded in a 11-coordinate geometry to one Ag(2), one Ag(3), one Ag(5), two equivalent Ag(11), two equivalent Ag(7), two equivalent Ag(9), and two equivalent Ga(2) atoms. In the third Ga site, Ga(3) is bonded in a 11-coordinate geometry to one Ag(1), one Ag(4), one Ag(6), two equivalent Ag(10), two equivalent Ag(12), two equivalent Ag(8), and two equivalent Ga(3) atoms. In the fourth Ga site, Ga(4) is bonded in a 6-coordinate geometry to one Ag(1), one Ag(12), one Ag(4), one Ag(5), one Ag(8), and one Ag(9) atom. In the fifth Ga site, Ga(5) is bonded in a 6-coordinate geometry to one Ag(10), one Ag(11), one Ag(2), one Ag(3), one Ag(6), and one Ag(7) atom. is represented by the CIF card [CIF]
data_Ga5Ag13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.889
_cell_length_b   7.757
_cell_length_c   13.366
_cell_angle_alpha   90.004
_cell_angle_beta   89.940
_cell_angle_gamma   90.068
_symmetry_Int_Tables_number   1
_cell_volume   299.516
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.248  0.001  0.667  1.0
  Ga  Ga1  1  0.750  0.999  0.332  1.0
  Ga  Ga2  1  0.753  0.500  0.835  1.0
  Ga  Ga3  1  0.006  0.001  0.001  1.0
  Ga  Ga4  1  0.005  0.499  0.498  1.0
  Ag  Ag5  1  0.745  0.671  0.011  1.0
  Ag  Ag6  1  0.749  0.165  0.516  1.0
  Ag  Ag7  1  0.744  0.649  0.329  1.0
  Ag  Ag8  1  0.747  0.143  0.824  1.0
  Ag  Ag9  1  0.744  0.185  0.159  1.0
  Ag  Ag10  1  0.746  0.689  0.660  1.0
  Ag  Ag11  1  0.250  0.836  0.487  1.0
  Ag  Ag12  1  0.254  0.332  0.982  1.0
  Ag  Ag13  1  0.254  0.857  0.175  1.0
  Ag  Ag14  1  0.251  0.356  0.675  1.0
  Ag  Ag15  1  0.255  0.306  0.343  1.0
  Ag  Ag16  1  0.252  0.811  0.838  1.0
  Ag  Ag17  1  0.246  0.500  0.167  1.0
[/CIF]
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