The compound described by Li4Co3Ni3(SbO8)2 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra, and corners with three equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-62°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-66°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with three equivalent Sb(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, and  an edgeedge with one Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 61-64°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Ni(1)O6 octahedra, and corners with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-63°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 51°. In the second Co site, Co(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 51°. In the third Co site, Co(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 50°. There are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form NiO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 54-55°. In the second Ni site, Ni(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form NiO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 51-54°. In the third Ni site, Ni(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form NiO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 51-53°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form SbO6 octahedra that share corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra, corners with three equivalent Li(3)O4 trigonal pyramids,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. In the second Sb site, Sb(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Ni(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 trigonal pyramids,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, and  an edgeedge with one Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-55°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one Co(3), one Ni(2), and one Sb(1) atom. In the second O site, O(2) is bonded to one Li(4), one Co(1), one Co(2), and one Sb(1) atom to form distorted OLiCo2Sb trigonal pyramids that share  a cornercorner with one O(13)LiCoNi2 tetrahedra, corners with two equivalent O(4)LiCo2Ni tetrahedra, and  an edgeedge with one O(3)LiCo2Ni tetrahedra. In the third O site, O(3) is bonded to one Li(1), one Co(1), one Co(2), and one Ni(1) atom to form distorted OLiCo2Ni tetrahedra that share  a cornercorner with one O(15)LiNi2Sb tetrahedra, corners with three equivalent O(4)LiCo2Ni tetrahedra, and  an edgeedge with one O(2)LiCo2Sb trigonal pyramid. In the fourth O site, O(4) is bonded to one Li(3), one Co(1), one Co(2), and one Ni(1) atom to form OLiCo2Ni tetrahedra that share corners with three equivalent O(3)LiCo2Ni tetrahedra and corners with two equivalent O(2)LiCo2Sb trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Co(3), one Ni(2), and one Ni(3) atom to form OLiCoNi2 tetrahedra that share corners with two equivalent O(15)LiNi2Sb tetrahedra and corners with three equivalent O(13)LiCoNi2 tetrahedra. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one Co(3), one Ni(3), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Co(1), one Ni(1), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Co(2), one Ni(1), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(1), one Co(2), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ni(2), one Ni(3), and one Sb(1) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Co(3), one Ni(2), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Co(3), one Ni(3), and one Sb(2) atom. In the thirteenth O site, O(13) is bonded to one Li(4), one Co(3), one Ni(2), and one Ni(3) atom to form OLiCoNi2 tetrahedra that share corners with three equivalent O(5)LiCoNi2 tetrahedra,  a cornercorner with one O(2)LiCo2Sb trigonal pyramid, and  an edgeedge with one O(15)LiNi2Sb tetrahedra. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(1), one Ni(1), and one Sb(2) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one Ni(2), one Ni(3), and one Sb(2) atom to form distorted OLiNi2Sb tetrahedra that share  a cornercorner with one O(3)LiCo2Ni tetrahedra, corners with two equivalent O(5)LiCoNi2 tetrahedra, and  an edgeedge with one O(13)LiCoNi2 tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(2), one Ni(1), and one Sb(2) atom. is represented by the CIF card [CIF]
data_Li4Co3Ni3(SbO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.815
_cell_length_b   5.770
_cell_length_c   9.502
_cell_angle_alpha   89.997
_cell_angle_beta   91.571
_cell_angle_gamma   119.694
_symmetry_Int_Tables_number   1
_cell_volume   276.765
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.325  0.663  0.901  1.0
  Li  Li1  1  0.005  0.002  0.992  1.0
  Li  Li2  1  0.008  0.004  0.492  1.0
  Li  Li3  1  0.666  0.333  0.400  1.0
  Co  Co4  1  0.170  0.830  0.215  1.0
  Co  Co5  1  0.170  0.340  0.215  1.0
  Co  Co6  1  0.342  0.171  0.715  1.0
  Ni  Ni7  1  0.663  0.832  0.213  1.0
  Ni  Ni8  1  0.831  0.663  0.714  1.0
  Ni  Ni9  1  0.832  0.169  0.714  1.0
  Sb  Sb10  1  0.338  0.669  0.486  1.0
  Sb  Sb11  1  0.658  0.329  0.990  1.0
  O  O12  1  0.175  0.843  0.595  1.0
  O  O13  1  0.033  0.516  0.334  1.0
  O  O14  1  0.332  0.666  0.117  1.0
  O  O15  1  0.002  0.001  0.303  1.0
  O  O16  1  0.012  0.006  0.802  1.0
  O  O17  1  0.174  0.332  0.595  1.0
  O  O18  1  0.478  0.969  0.342  1.0
  O  O19  1  0.477  0.508  0.342  1.0
  O  O20  1  0.324  0.162  0.103  1.0
  O  O21  1  0.687  0.843  0.594  1.0
  O  O22  1  0.498  0.472  0.844  1.0
  O  O23  1  0.499  0.026  0.844  1.0
  O  O24  1  0.657  0.329  0.618  1.0
  O  O25  1  0.842  0.677  0.094  1.0
  O  O26  1  0.959  0.480  0.841  1.0
  O  O27  1  0.843  0.166  0.093  1.0
[/CIF]
.
The compound described by Li4Co3Ni3(SbO8)2 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra, and corners with three equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-62°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 60-66°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(4), and one O(6) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra, corners with three equivalent Sb(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, and  an edgeedge with one Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 61-64°. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  a cornercorner with one Ni(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Ni(1)O6 octahedra, and corners with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 57-63°. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 51°. In the second Co site, Co(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 51°. In the third Co site, Co(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 50°. There are three inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form NiO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  a cornercorner with one Li(3)O4 trigonal pyramid,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 54-55°. In the second Ni site, Ni(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form NiO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Ni(3)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 51-54°. In the third Ni site, Ni(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form NiO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, edges with two equivalent Ni(2)O6 octahedra, and  an edgeedge with one Li(3)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 51-53°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form SbO6 octahedra that share corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Ni(2)O6 octahedra, corners with two equivalent Ni(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra, corners with three equivalent Li(3)O4 trigonal pyramids,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. In the second Sb site, Sb(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form SbO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Ni(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 trigonal pyramids,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, and  an edgeedge with one Ni(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-55°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one Co(3), one Ni(2), and one Sb(1) atom. In the second O site, O(2) is bonded to one Li(4), one Co(1), one Co(2), and one Sb(1) atom to form distorted OLiCo2Sb trigonal pyramids that share  a cornercorner with one O(13)LiCoNi2 tetrahedra, corners with two equivalent O(4)LiCo2Ni tetrahedra, and  an edgeedge with one O(3)LiCo2Ni tetrahedra. In the third O site, O(3) is bonded to one Li(1), one Co(1), one Co(2), and one Ni(1) atom to form distorted OLiCo2Ni tetrahedra that share  a cornercorner with one O(15)LiNi2Sb tetrahedra, corners with three equivalent O(4)LiCo2Ni tetrahedra, and  an edgeedge with one O(2)LiCo2Sb trigonal pyramid. In the fourth O site, O(4) is bonded to one Li(3), one Co(1), one Co(2), and one Ni(1) atom to form OLiCo2Ni tetrahedra that share corners with three equivalent O(3)LiCo2Ni tetrahedra and corners with two equivalent O(2)LiCo2Sb trigonal pyramids. In the fifth O site, O(5) is bonded to one Li(2), one Co(3), one Ni(2), and one Ni(3) atom to form OLiCoNi2 tetrahedra that share corners with two equivalent O(15)LiNi2Sb tetrahedra and corners with three equivalent O(13)LiCoNi2 tetrahedra. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one Co(3), one Ni(3), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Co(1), one Ni(1), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Co(2), one Ni(1), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(1), one Co(2), and one Sb(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ni(2), one Ni(3), and one Sb(1) atom. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Co(3), one Ni(2), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Co(3), one Ni(3), and one Sb(2) atom. In the thirteenth O site, O(13) is bonded to one Li(4), one Co(3), one Ni(2), and one Ni(3) atom to form OLiCoNi2 tetrahedra that share corners with three equivalent O(5)LiCoNi2 tetrahedra,  a cornercorner with one O(2)LiCo2Sb trigonal pyramid, and  an edgeedge with one O(15)LiNi2Sb tetrahedra. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(1), one Ni(1), and one Sb(2) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one Ni(2), one Ni(3), and one Sb(2) atom to form distorted OLiNi2Sb tetrahedra that share  a cornercorner with one O(3)LiCo2Ni tetrahedra, corners with two equivalent O(5)LiCoNi2 tetrahedra, and  an edgeedge with one O(13)LiCoNi2 tetrahedra. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one Co(2), one Ni(1), and one Sb(2) atom. is represented by the CIF card [CIF]
data_Li4Co3Ni3(SbO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.815
_cell_length_b   5.770
_cell_length_c   9.502
_cell_angle_alpha   89.997
_cell_angle_beta   91.571
_cell_angle_gamma   119.694
_symmetry_Int_Tables_number   1
_cell_volume   276.765
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.325  0.663  0.901  1.0
  Li  Li1  1  0.005  0.002  0.992  1.0
  Li  Li2  1  0.008  0.004  0.492  1.0
  Li  Li3  1  0.666  0.333  0.400  1.0
  Co  Co4  1  0.170  0.830  0.215  1.0
  Co  Co5  1  0.170  0.340  0.215  1.0
  Co  Co6  1  0.342  0.171  0.715  1.0
  Ni  Ni7  1  0.663  0.832  0.213  1.0
  Ni  Ni8  1  0.831  0.663  0.714  1.0
  Ni  Ni9  1  0.832  0.169  0.714  1.0
  Sb  Sb10  1  0.338  0.669  0.486  1.0
  Sb  Sb11  1  0.658  0.329  0.990  1.0
  O  O12  1  0.175  0.843  0.595  1.0
  O  O13  1  0.033  0.516  0.334  1.0
  O  O14  1  0.332  0.666  0.117  1.0
  O  O15  1  0.002  0.001  0.303  1.0
  O  O16  1  0.012  0.006  0.802  1.0
  O  O17  1  0.174  0.332  0.595  1.0
  O  O18  1  0.478  0.969  0.342  1.0
  O  O19  1  0.477  0.508  0.342  1.0
  O  O20  1  0.324  0.162  0.103  1.0
  O  O21  1  0.687  0.843  0.594  1.0
  O  O22  1  0.498  0.472  0.844  1.0
  O  O23  1  0.499  0.026  0.844  1.0
  O  O24  1  0.657  0.329  0.618  1.0
  O  O25  1  0.842  0.677  0.094  1.0
  O  O26  1  0.959  0.480  0.841  1.0
  O  O27  1  0.843  0.166  0.093  1.0
[/CIF]
.