The structure described by SAs is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tetraarsenic tetrasulfide molecules. There are four inequivalent As sites. In the first As site, As(1) is bonded in a distorted L-shaped geometry to one S(1) and one S(2) atom. In the second As site, As(2) is bonded in a distorted L-shaped geometry to one S(1) and one S(3) atom. In the third As site, As(3) is bonded in a distorted L-shaped geometry to one S(2) and one S(4) atom. In the fourth As site, As(4) is bonded in a distorted L-shaped geometry to one S(3) and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one As(1) and one As(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one As(1) and one As(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one As(2) and one As(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one As(3) and one As(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.780
_cell_length_b   9.548
_cell_length_c   14.077
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   106.911
_symmetry_Int_Tables_number   1
_cell_volume   871.856
_cell_formula_units_Z   16
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.769  0.123  0.984  1.0
  As  As1  1  0.731  0.377  0.484  1.0
  As  As2  1  0.231  0.877  0.016  1.0
  As  As3  1  0.269  0.623  0.516  1.0
  As  As4  1  0.866  0.421  0.139  1.0
  As  As5  1  0.634  0.079  0.639  1.0
  As  As6  1  0.134  0.579  0.861  1.0
  As  As7  1  0.366  0.921  0.361  1.0
  As  As8  1  0.179  0.316  0.126  1.0
  As  As9  1  0.321  0.184  0.626  1.0
  As  As10  1  0.821  0.684  0.874  1.0
  As  As11  1  0.679  0.816  0.374  1.0
  As  As12  1  0.720  0.043  0.161  1.0
  As  As13  1  0.780  0.457  0.661  1.0
  As  As14  1  0.280  0.957  0.839  1.0
  As  As15  1  0.220  0.543  0.339  1.0
  S  S16  1  0.713  0.343  0.999  1.0
  S  S17  1  0.787  0.157  0.499  1.0
  S  S18  1  0.287  0.657  0.001  1.0
  S  S19  1  0.213  0.843  0.501  1.0
  S  S20  1  0.113  0.214  0.982  1.0
  S  S21  1  0.387  0.286  0.482  1.0
  S  S22  1  0.887  0.786  0.018  1.0
  S  S23  1  0.613  0.714  0.518  1.0
  S  S24  1  0.654  0.240  0.223  1.0
  S  S25  1  0.846  0.260  0.723  1.0
  S  S26  1  0.346  0.760  0.777  1.0
  S  S27  1  0.154  0.740  0.277  1.0
  S  S28  1  0.051  0.107  0.206  1.0
  S  S29  1  0.449  0.393  0.706  1.0
  S  S30  1  0.949  0.893  0.794  1.0
  S  S31  1  0.551  0.607  0.294  1.0
[/CIF]
.
The structure described by SAs is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tetraarsenic tetrasulfide molecules. There are four inequivalent As sites. In the first As site, As(1) is bonded in a distorted L-shaped geometry to one S(1) and one S(2) atom. In the second As site, As(2) is bonded in a distorted L-shaped geometry to one S(1) and one S(3) atom. In the third As site, As(3) is bonded in a distorted L-shaped geometry to one S(2) and one S(4) atom. In the fourth As site, As(4) is bonded in a distorted L-shaped geometry to one S(3) and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one As(1) and one As(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one As(1) and one As(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one As(2) and one As(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one As(3) and one As(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AsS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.780
_cell_length_b   9.548
_cell_length_c   14.077
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   106.911
_symmetry_Int_Tables_number   1
_cell_volume   871.856
_cell_formula_units_Z   16
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.769  0.123  0.984  1.0
  As  As1  1  0.731  0.377  0.484  1.0
  As  As2  1  0.231  0.877  0.016  1.0
  As  As3  1  0.269  0.623  0.516  1.0
  As  As4  1  0.866  0.421  0.139  1.0
  As  As5  1  0.634  0.079  0.639  1.0
  As  As6  1  0.134  0.579  0.861  1.0
  As  As7  1  0.366  0.921  0.361  1.0
  As  As8  1  0.179  0.316  0.126  1.0
  As  As9  1  0.321  0.184  0.626  1.0
  As  As10  1  0.821  0.684  0.874  1.0
  As  As11  1  0.679  0.816  0.374  1.0
  As  As12  1  0.720  0.043  0.161  1.0
  As  As13  1  0.780  0.457  0.661  1.0
  As  As14  1  0.280  0.957  0.839  1.0
  As  As15  1  0.220  0.543  0.339  1.0
  S  S16  1  0.713  0.343  0.999  1.0
  S  S17  1  0.787  0.157  0.499  1.0
  S  S18  1  0.287  0.657  0.001  1.0
  S  S19  1  0.213  0.843  0.501  1.0
  S  S20  1  0.113  0.214  0.982  1.0
  S  S21  1  0.387  0.286  0.482  1.0
  S  S22  1  0.887  0.786  0.018  1.0
  S  S23  1  0.613  0.714  0.518  1.0
  S  S24  1  0.654  0.240  0.223  1.0
  S  S25  1  0.846  0.260  0.723  1.0
  S  S26  1  0.346  0.760  0.777  1.0
  S  S27  1  0.154  0.740  0.277  1.0
  S  S28  1  0.051  0.107  0.206  1.0
  S  S29  1  0.449  0.393  0.706  1.0
  S  S30  1  0.949  0.893  0.794  1.0
  S  S31  1  0.551  0.607  0.294  1.0
[/CIF]
.