The material structure described by K2PtN3(O2Cl)3 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent Cl(2), and four equivalent Cl(1) atoms. In the second K site, K(2) is bonded in a 10-coordinate geometry to one O(3), one O(4), two equivalent O(2), four equivalent O(1), and two equivalent Cl(1) atoms. Pt(1) is bonded in an octahedral geometry to one N(1), two equivalent N(2), one Cl(2), and two equivalent Cl(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Pt(1), one O(3), and one O(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Pt(1), one O(1), and one O(2) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(2) and one N(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(2) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one K(2) and one N(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to one K(2), two equivalent K(1), and one Pt(1) atom to form a mixture of distorted edge and corner-sharing ClK3Pt trigonal pyramids. In the second Cl site, Cl(2) is bonded in a 2-coordinate geometry to two equivalent K(1) and one Pt(1) atom. is represented by the CIF file [CIF]
data_K2PtN3(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.769
_cell_length_b   6.768
_cell_length_c   11.085
_cell_angle_alpha   79.001
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   572.123
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.790  0.469  1.0
  K  K1  1  0.250  0.383  0.114  1.0
  K  K2  1  0.750  0.210  0.531  1.0
  K  K3  1  0.750  0.617  0.886  1.0
  Pt  Pt4  1  0.250  0.120  0.752  1.0
  Pt  Pt5  1  0.750  0.880  0.248  1.0
  N  N6  1  0.750  0.052  0.067  1.0
  N  N7  1  0.442  0.315  0.793  1.0
  N  N8  1  0.558  0.685  0.207  1.0
  N  N9  1  0.250  0.948  0.933  1.0
  N  N10  1  0.942  0.685  0.207  1.0
  N  N11  1  0.058  0.315  0.793  1.0
  Cl  Cl12  1  0.469  0.903  0.699  1.0
  Cl  Cl13  1  0.250  0.295  0.543  1.0
  Cl  Cl14  1  0.531  0.097  0.301  1.0
  Cl  Cl15  1  0.969  0.097  0.301  1.0
  Cl  Cl16  1  0.750  0.705  0.457  1.0
  Cl  Cl17  1  0.031  0.903  0.699  1.0
  O  O18  1  0.936  0.625  0.109  1.0
  O  O19  1  0.943  0.366  0.716  1.0
  O  O20  1  0.064  0.375  0.891  1.0
  O  O21  1  0.250  0.764  0.941  1.0
  O  O22  1  0.750  0.236  0.059  1.0
  O  O23  1  0.250  0.032  0.023  1.0
  O  O24  1  0.057  0.634  0.284  1.0
  O  O25  1  0.436  0.375  0.891  1.0
  O  O26  1  0.557  0.366  0.716  1.0
  O  O27  1  0.443  0.634  0.284  1.0
  O  O28  1  0.564  0.625  0.109  1.0
  O  O29  1  0.750  0.968  0.977  1.0
[/CIF]
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The material structure described by K2PtN3(O2Cl)3 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to two equivalent O(2), two equivalent Cl(2), and four equivalent Cl(1) atoms. In the second K site, K(2) is bonded in a 10-coordinate geometry to one O(3), one O(4), two equivalent O(2), four equivalent O(1), and two equivalent Cl(1) atoms. Pt(1) is bonded in an octahedral geometry to one N(1), two equivalent N(2), one Cl(2), and two equivalent Cl(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Pt(1), one O(3), and one O(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Pt(1), one O(1), and one O(2) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(2) and one N(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one K(2) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one K(2) and one N(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to one K(2), two equivalent K(1), and one Pt(1) atom to form a mixture of distorted edge and corner-sharing ClK3Pt trigonal pyramids. In the second Cl site, Cl(2) is bonded in a 2-coordinate geometry to two equivalent K(1) and one Pt(1) atom. is represented by the CIF file [CIF]
data_K2PtN3(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.769
_cell_length_b   6.768
_cell_length_c   11.085
_cell_angle_alpha   79.001
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   572.123
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.790  0.469  1.0
  K  K1  1  0.250  0.383  0.114  1.0
  K  K2  1  0.750  0.210  0.531  1.0
  K  K3  1  0.750  0.617  0.886  1.0
  Pt  Pt4  1  0.250  0.120  0.752  1.0
  Pt  Pt5  1  0.750  0.880  0.248  1.0
  N  N6  1  0.750  0.052  0.067  1.0
  N  N7  1  0.442  0.315  0.793  1.0
  N  N8  1  0.558  0.685  0.207  1.0
  N  N9  1  0.250  0.948  0.933  1.0
  N  N10  1  0.942  0.685  0.207  1.0
  N  N11  1  0.058  0.315  0.793  1.0
  Cl  Cl12  1  0.469  0.903  0.699  1.0
  Cl  Cl13  1  0.250  0.295  0.543  1.0
  Cl  Cl14  1  0.531  0.097  0.301  1.0
  Cl  Cl15  1  0.969  0.097  0.301  1.0
  Cl  Cl16  1  0.750  0.705  0.457  1.0
  Cl  Cl17  1  0.031  0.903  0.699  1.0
  O  O18  1  0.936  0.625  0.109  1.0
  O  O19  1  0.943  0.366  0.716  1.0
  O  O20  1  0.064  0.375  0.891  1.0
  O  O21  1  0.250  0.764  0.941  1.0
  O  O22  1  0.750  0.236  0.059  1.0
  O  O23  1  0.250  0.032  0.023  1.0
  O  O24  1  0.057  0.634  0.284  1.0
  O  O25  1  0.436  0.375  0.891  1.0
  O  O26  1  0.557  0.366  0.716  1.0
  O  O27  1  0.443  0.634  0.284  1.0
  O  O28  1  0.564  0.625  0.109  1.0
  O  O29  1  0.750  0.968  0.977  1.0
[/CIF]
.