The material structure described by KInI4 crystallizes in the orthorhombic Iba2 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 4-coordinate geometry to two equivalent I(2) and two equivalent I(4) atoms. In the second K site, K(2) is bonded in a distorted T-shaped geometry to one I(1), one I(3), and one I(5) atom. There are two inequivalent In sites. In the first In site, In(1) is bonded in a tetrahedral geometry to one I(1), one I(4), one I(5), and one I(6) atom. In the second In site, In(2) is bonded in a tetrahedral geometry to two equivalent I(2) and two equivalent I(3) atoms. There are six inequivalent I sites. In the first I site, I(1) is bonded in a water-like geometry to one K(2) and one In(1) atom. In the second I site, I(2) is bonded in a distorted single-bond geometry to one K(1) and one In(2) atom. In the third I site, I(3) is bonded in a water-like geometry to one K(2) and one In(2) atom. In the fourth I site, I(4) is bonded in a single-bond geometry to one K(1) and one In(1) atom. In the fifth I site, I(5) is bonded in a water-like geometry to one K(2) and one In(1) atom. In the sixth I site, I(6) is bonded in a single-bond geometry to one In(1) atom. is represented by the CIF card [CIF]
data_KInI4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.477
_cell_length_b   14.477
_cell_length_c   14.477
_cell_angle_alpha   120.482
_cell_angle_beta   117.047
_cell_angle_gamma   92.178
_symmetry_Int_Tables_number   1
_cell_volume   2181.675
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.993  0.993  0.000  1.0
  K  K1  1  0.973  0.672  0.302  1.0
  K  K2  1  0.370  0.671  0.698  1.0
  K  K3  1  0.493  0.493  0.000  1.0
  K  K4  1  0.473  0.171  0.301  1.0
  K  K5  1  0.870  0.172  0.699  1.0
  In  In6  1  0.252  0.249  0.502  1.0
  In  In7  1  0.754  0.754  0.000  1.0
  In  In8  1  0.248  0.749  0.997  1.0
  In  In9  1  0.752  0.250  0.003  1.0
  In  In10  1  0.254  0.254  0.000  1.0
  In  In11  1  0.748  0.750  0.498  1.0
  I  I12  1  0.291  0.303  0.359  1.0
  I  I13  1  0.938  0.715  0.002  1.0
  I  I14  1  0.713  0.936  0.998  1.0
  I  I15  1  0.572  0.557  0.783  1.0
  I  I16  1  0.062  0.065  0.346  1.0
  I  I17  1  0.214  0.440  0.651  1.0
  I  I18  1  0.434  0.217  0.642  1.0
  I  I19  1  0.714  0.063  0.774  1.0
  I  I20  1  0.444  0.803  0.012  1.0
  I  I21  1  0.074  0.717  0.783  1.0
  I  I22  1  0.791  0.432  0.988  1.0
  I  I23  1  0.774  0.789  0.217  1.0
  I  I24  1  0.213  0.215  0.777  1.0
  I  I25  1  0.562  0.216  0.997  1.0
  I  I26  1  0.289  0.940  0.226  1.0
  I  I27  1  0.934  0.292  0.217  1.0
  I  I28  1  0.219  0.565  0.003  1.0
  I  I29  1  0.789  0.563  0.349  1.0
  I  I30  1  0.574  0.792  0.358  1.0
  I  I31  1  0.944  0.932  0.641  1.0
  I  I32  1  0.438  0.436  0.223  1.0
  I  I33  1  0.072  0.289  0.015  1.0
  I  I34  1  0.274  0.057  0.985  1.0
  I  I35  1  0.719  0.716  0.654  1.0
[/CIF]
.
The material structure described by KInI4 crystallizes in the orthorhombic Iba2 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 4-coordinate geometry to two equivalent I(2) and two equivalent I(4) atoms. In the second K site, K(2) is bonded in a distorted T-shaped geometry to one I(1), one I(3), and one I(5) atom. There are two inequivalent In sites. In the first In site, In(1) is bonded in a tetrahedral geometry to one I(1), one I(4), one I(5), and one I(6) atom. In the second In site, In(2) is bonded in a tetrahedral geometry to two equivalent I(2) and two equivalent I(3) atoms. There are six inequivalent I sites. In the first I site, I(1) is bonded in a water-like geometry to one K(2) and one In(1) atom. In the second I site, I(2) is bonded in a distorted single-bond geometry to one K(1) and one In(2) atom. In the third I site, I(3) is bonded in a water-like geometry to one K(2) and one In(2) atom. In the fourth I site, I(4) is bonded in a single-bond geometry to one K(1) and one In(1) atom. In the fifth I site, I(5) is bonded in a water-like geometry to one K(2) and one In(1) atom. In the sixth I site, I(6) is bonded in a single-bond geometry to one In(1) atom. is represented by the CIF card [CIF]
data_KInI4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.477
_cell_length_b   14.477
_cell_length_c   14.477
_cell_angle_alpha   120.482
_cell_angle_beta   117.047
_cell_angle_gamma   92.178
_symmetry_Int_Tables_number   1
_cell_volume   2181.675
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.993  0.993  0.000  1.0
  K  K1  1  0.973  0.672  0.302  1.0
  K  K2  1  0.370  0.671  0.698  1.0
  K  K3  1  0.493  0.493  0.000  1.0
  K  K4  1  0.473  0.171  0.301  1.0
  K  K5  1  0.870  0.172  0.699  1.0
  In  In6  1  0.252  0.249  0.502  1.0
  In  In7  1  0.754  0.754  0.000  1.0
  In  In8  1  0.248  0.749  0.997  1.0
  In  In9  1  0.752  0.250  0.003  1.0
  In  In10  1  0.254  0.254  0.000  1.0
  In  In11  1  0.748  0.750  0.498  1.0
  I  I12  1  0.291  0.303  0.359  1.0
  I  I13  1  0.938  0.715  0.002  1.0
  I  I14  1  0.713  0.936  0.998  1.0
  I  I15  1  0.572  0.557  0.783  1.0
  I  I16  1  0.062  0.065  0.346  1.0
  I  I17  1  0.214  0.440  0.651  1.0
  I  I18  1  0.434  0.217  0.642  1.0
  I  I19  1  0.714  0.063  0.774  1.0
  I  I20  1  0.444  0.803  0.012  1.0
  I  I21  1  0.074  0.717  0.783  1.0
  I  I22  1  0.791  0.432  0.988  1.0
  I  I23  1  0.774  0.789  0.217  1.0
  I  I24  1  0.213  0.215  0.777  1.0
  I  I25  1  0.562  0.216  0.997  1.0
  I  I26  1  0.289  0.940  0.226  1.0
  I  I27  1  0.934  0.292  0.217  1.0
  I  I28  1  0.219  0.565  0.003  1.0
  I  I29  1  0.789  0.563  0.349  1.0
  I  I30  1  0.574  0.792  0.358  1.0
  I  I31  1  0.944  0.932  0.641  1.0
  I  I32  1  0.438  0.436  0.223  1.0
  I  I33  1  0.072  0.289  0.015  1.0
  I  I34  1  0.274  0.057  0.985  1.0
  I  I35  1  0.719  0.716  0.654  1.0
[/CIF]
.