The structure described by InSO5 crystallizes in the orthorhombic Pnma space group. In(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form InO6 octahedra that share corners with two equivalent In(1)O6 octahedra and corners with four equivalent S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 42°. S(1) is bonded to one O(3), one O(4), and two equivalent O(1) atoms to form SO4 tetrahedra that share corners with four equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-39°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one In(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent In(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one In(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one In(1) and one S(1) atom. is represented by the CIF card [CIF]
data_InSO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.696
_cell_length_b   7.926
_cell_length_c   7.706
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   408.988
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.750  0.639  0.260  1.0
  In  In1  1  0.250  0.361  0.740  1.0
  In  In2  1  0.250  0.861  0.760  1.0
  In  In3  1  0.750  0.139  0.240  1.0
  S  S4  1  0.750  0.877  0.872  1.0
  S  S5  1  0.250  0.123  0.128  1.0
  S  S6  1  0.250  0.623  0.372  1.0
  S  S7  1  0.750  0.377  0.628  1.0
  O  O8  1  0.927  0.872  0.753  1.0
  O  O9  1  0.073  0.128  0.247  1.0
  O  O10  1  0.073  0.628  0.253  1.0
  O  O11  1  0.427  0.128  0.247  1.0
  O  O12  1  0.927  0.372  0.747  1.0
  O  O13  1  0.573  0.872  0.753  1.0
  O  O14  1  0.573  0.372  0.747  1.0
  O  O15  1  0.427  0.628  0.253  1.0
  O  O16  1  0.750  0.892  0.349  1.0
  O  O17  1  0.250  0.108  0.651  1.0
  O  O18  1  0.250  0.608  0.849  1.0
  O  O19  1  0.750  0.392  0.151  1.0
  O  O20  1  0.750  0.727  0.985  1.0
  O  O21  1  0.250  0.273  0.015  1.0
  O  O22  1  0.250  0.773  0.485  1.0
  O  O23  1  0.750  0.227  0.515  1.0
  O  O24  1  0.750  0.538  0.529  1.0
  O  O25  1  0.250  0.462  0.471  1.0
  O  O26  1  0.250  0.962  0.029  1.0
  O  O27  1  0.750  0.038  0.971  1.0
[/CIF]
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The structure described by InSO5 crystallizes in the orthorhombic Pnma space group. In(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form InO6 octahedra that share corners with two equivalent In(1)O6 octahedra and corners with four equivalent S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 42°. S(1) is bonded to one O(3), one O(4), and two equivalent O(1) atoms to form SO4 tetrahedra that share corners with four equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-39°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one In(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent In(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one In(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one In(1) and one S(1) atom. is represented by the CIF card [CIF]
data_InSO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.696
_cell_length_b   7.926
_cell_length_c   7.706
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   408.988
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.750  0.639  0.260  1.0
  In  In1  1  0.250  0.361  0.740  1.0
  In  In2  1  0.250  0.861  0.760  1.0
  In  In3  1  0.750  0.139  0.240  1.0
  S  S4  1  0.750  0.877  0.872  1.0
  S  S5  1  0.250  0.123  0.128  1.0
  S  S6  1  0.250  0.623  0.372  1.0
  S  S7  1  0.750  0.377  0.628  1.0
  O  O8  1  0.927  0.872  0.753  1.0
  O  O9  1  0.073  0.128  0.247  1.0
  O  O10  1  0.073  0.628  0.253  1.0
  O  O11  1  0.427  0.128  0.247  1.0
  O  O12  1  0.927  0.372  0.747  1.0
  O  O13  1  0.573  0.872  0.753  1.0
  O  O14  1  0.573  0.372  0.747  1.0
  O  O15  1  0.427  0.628  0.253  1.0
  O  O16  1  0.750  0.892  0.349  1.0
  O  O17  1  0.250  0.108  0.651  1.0
  O  O18  1  0.250  0.608  0.849  1.0
  O  O19  1  0.750  0.392  0.151  1.0
  O  O20  1  0.750  0.727  0.985  1.0
  O  O21  1  0.250  0.273  0.015  1.0
  O  O22  1  0.250  0.773  0.485  1.0
  O  O23  1  0.750  0.227  0.515  1.0
  O  O24  1  0.750  0.538  0.529  1.0
  O  O25  1  0.250  0.462  0.471  1.0
  O  O26  1  0.250  0.962  0.029  1.0
  O  O27  1  0.750  0.038  0.971  1.0
[/CIF]
.