The structure described by LiPr2Zn2(PO)2 crystallizes in the trigonal R-3m space group. Li(1) is bonded to six equivalent Zn(1) and six equivalent P(1) atoms to form face-sharing LiZn6P6 cuboctahedra. Pr(1) is bonded in a 4-coordinate geometry to three equivalent P(1) and four equivalent O(1) atoms. Zn(1) is bonded in a 7-coordinate geometry to three equivalent Li(1) and four equivalent P(1) atoms. P(1) is bonded in a 10-coordinate geometry to three equivalent Li(1), three equivalent Pr(1), and four equivalent Zn(1) atoms. O(1) is bonded to four equivalent Pr(1) atoms to form a mixture of corner and edge-sharing OPr4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiPr2Zn2(PO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.437
_cell_length_b   10.437
_cell_length_c   10.437
_cell_angle_alpha   23.007
_cell_angle_beta   23.007
_cell_angle_gamma   23.007
_symmetry_Int_Tables_number   1
_cell_volume   152.442
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.500  1.0
  Pr  Pr1  1  0.618  0.618  0.618  1.0
  Pr  Pr2  1  0.382  0.382  0.382  1.0
  Zn  Zn3  1  0.203  0.203  0.203  1.0
  Zn  Zn4  1  0.797  0.797  0.797  1.0
  P  P5  1  0.117  0.117  0.117  1.0
  P  P6  1  0.883  0.883  0.883  1.0
  O  O7  1  0.696  0.696  0.696  1.0
  O  O8  1  0.304  0.304  0.304  1.0
[/CIF]
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The structure described by LiPr2Zn2(PO)2 crystallizes in the trigonal R-3m space group. Li(1) is bonded to six equivalent Zn(1) and six equivalent P(1) atoms to form face-sharing LiZn6P6 cuboctahedra. Pr(1) is bonded in a 4-coordinate geometry to three equivalent P(1) and four equivalent O(1) atoms. Zn(1) is bonded in a 7-coordinate geometry to three equivalent Li(1) and four equivalent P(1) atoms. P(1) is bonded in a 10-coordinate geometry to three equivalent Li(1), three equivalent Pr(1), and four equivalent Zn(1) atoms. O(1) is bonded to four equivalent Pr(1) atoms to form a mixture of corner and edge-sharing OPr4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiPr2Zn2(PO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.437
_cell_length_b   10.437
_cell_length_c   10.437
_cell_angle_alpha   23.007
_cell_angle_beta   23.007
_cell_angle_gamma   23.007
_symmetry_Int_Tables_number   1
_cell_volume   152.442
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.500  1.0
  Pr  Pr1  1  0.618  0.618  0.618  1.0
  Pr  Pr2  1  0.382  0.382  0.382  1.0
  Zn  Zn3  1  0.203  0.203  0.203  1.0
  Zn  Zn4  1  0.797  0.797  0.797  1.0
  P  P5  1  0.117  0.117  0.117  1.0
  P  P6  1  0.883  0.883  0.883  1.0
  O  O7  1  0.696  0.696  0.696  1.0
  O  O8  1  0.304  0.304  0.304  1.0
[/CIF]
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