The material described by NCl3 is Ammonia-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of twelve nitrogen trichloride molecules. N(1) is bonded in a trigonal non-coplanar geometry to three equivalent Cl(1,2) atoms. Cl(1,2) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.602
_cell_length_b   9.399
_cell_length_c   16.632
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1188.412
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  N  N0  1  0.895  0.250  0.051  1.0
  N  N1  1  0.395  0.250  0.449  1.0
  N  N2  1  0.105  0.750  0.949  1.0
  N  N3  1  0.605  0.750  0.551  1.0
  N  N4  1  0.807  0.250  0.350  1.0
  N  N5  1  0.307  0.250  0.150  1.0
  N  N6  1  0.193  0.750  0.650  1.0
  N  N7  1  0.693  0.750  0.850  1.0
  N  N8  1  0.041  0.250  0.696  1.0
  N  N9  1  0.541  0.250  0.804  1.0
  N  N10  1  0.959  0.750  0.304  1.0
  N  N11  1  0.459  0.750  0.196  1.0
  Cl  Cl12  1  0.770  0.098  0.078  1.0
  Cl  Cl13  1  0.270  0.402  0.422  1.0
  Cl  Cl14  1  0.230  0.598  0.922  1.0
  Cl  Cl15  1  0.730  0.902  0.578  1.0
  Cl  Cl16  1  0.230  0.902  0.922  1.0
  Cl  Cl17  1  0.730  0.598  0.578  1.0
  Cl  Cl18  1  0.770  0.402  0.078  1.0
  Cl  Cl19  1  0.270  0.098  0.422  1.0
  Cl  Cl20  1  0.919  0.250  0.945  1.0
  Cl  Cl21  1  0.419  0.250  0.555  1.0
  Cl  Cl22  1  0.081  0.750  0.055  1.0
  Cl  Cl23  1  0.581  0.750  0.445  1.0
  Cl  Cl24  1  0.779  0.099  0.412  1.0
  Cl  Cl25  1  0.279  0.401  0.088  1.0
  Cl  Cl26  1  0.221  0.599  0.588  1.0
  Cl  Cl27  1  0.721  0.901  0.912  1.0
  Cl  Cl28  1  0.221  0.901  0.588  1.0
  Cl  Cl29  1  0.721  0.599  0.912  1.0
  Cl  Cl30  1  0.779  0.401  0.412  1.0
  Cl  Cl31  1  0.279  0.099  0.088  1.0
  Cl  Cl32  1  0.636  0.250  0.278  1.0
  Cl  Cl33  1  0.136  0.250  0.222  1.0
  Cl  Cl34  1  0.364  0.750  0.722  1.0
  Cl  Cl35  1  0.864  0.750  0.778  1.0
  Cl  Cl36  1  0.977  0.098  0.751  1.0
  Cl  Cl37  1  0.477  0.402  0.749  1.0
  Cl  Cl38  1  0.023  0.598  0.249  1.0
  Cl  Cl39  1  0.523  0.902  0.251  1.0
  Cl  Cl40  1  0.023  0.902  0.249  1.0
  Cl  Cl41  1  0.523  0.598  0.251  1.0
  Cl  Cl42  1  0.977  0.402  0.751  1.0
  Cl  Cl43  1  0.477  0.098  0.749  1.0
  Cl  Cl44  1  0.918  0.250  0.605  1.0
  Cl  Cl45  1  0.418  0.250  0.895  1.0
  Cl  Cl46  1  0.082  0.750  0.395  1.0
  Cl  Cl47  1  0.582  0.750  0.105  1.0
[/CIF]
.
The material described by NCl3 is Ammonia-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of twelve nitrogen trichloride molecules. N(1) is bonded in a trigonal non-coplanar geometry to three equivalent Cl(1,2) atoms. Cl(1,2) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NCl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.602
_cell_length_b   9.399
_cell_length_c   16.632
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1188.412
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  N  N0  1  0.895  0.250  0.051  1.0
  N  N1  1  0.395  0.250  0.449  1.0
  N  N2  1  0.105  0.750  0.949  1.0
  N  N3  1  0.605  0.750  0.551  1.0
  N  N4  1  0.807  0.250  0.350  1.0
  N  N5  1  0.307  0.250  0.150  1.0
  N  N6  1  0.193  0.750  0.650  1.0
  N  N7  1  0.693  0.750  0.850  1.0
  N  N8  1  0.041  0.250  0.696  1.0
  N  N9  1  0.541  0.250  0.804  1.0
  N  N10  1  0.959  0.750  0.304  1.0
  N  N11  1  0.459  0.750  0.196  1.0
  Cl  Cl12  1  0.770  0.098  0.078  1.0
  Cl  Cl13  1  0.270  0.402  0.422  1.0
  Cl  Cl14  1  0.230  0.598  0.922  1.0
  Cl  Cl15  1  0.730  0.902  0.578  1.0
  Cl  Cl16  1  0.230  0.902  0.922  1.0
  Cl  Cl17  1  0.730  0.598  0.578  1.0
  Cl  Cl18  1  0.770  0.402  0.078  1.0
  Cl  Cl19  1  0.270  0.098  0.422  1.0
  Cl  Cl20  1  0.919  0.250  0.945  1.0
  Cl  Cl21  1  0.419  0.250  0.555  1.0
  Cl  Cl22  1  0.081  0.750  0.055  1.0
  Cl  Cl23  1  0.581  0.750  0.445  1.0
  Cl  Cl24  1  0.779  0.099  0.412  1.0
  Cl  Cl25  1  0.279  0.401  0.088  1.0
  Cl  Cl26  1  0.221  0.599  0.588  1.0
  Cl  Cl27  1  0.721  0.901  0.912  1.0
  Cl  Cl28  1  0.221  0.901  0.588  1.0
  Cl  Cl29  1  0.721  0.599  0.912  1.0
  Cl  Cl30  1  0.779  0.401  0.412  1.0
  Cl  Cl31  1  0.279  0.099  0.088  1.0
  Cl  Cl32  1  0.636  0.250  0.278  1.0
  Cl  Cl33  1  0.136  0.250  0.222  1.0
  Cl  Cl34  1  0.364  0.750  0.722  1.0
  Cl  Cl35  1  0.864  0.750  0.778  1.0
  Cl  Cl36  1  0.977  0.098  0.751  1.0
  Cl  Cl37  1  0.477  0.402  0.749  1.0
  Cl  Cl38  1  0.023  0.598  0.249  1.0
  Cl  Cl39  1  0.523  0.902  0.251  1.0
  Cl  Cl40  1  0.023  0.902  0.249  1.0
  Cl  Cl41  1  0.523  0.598  0.251  1.0
  Cl  Cl42  1  0.977  0.402  0.751  1.0
  Cl  Cl43  1  0.477  0.098  0.749  1.0
  Cl  Cl44  1  0.918  0.250  0.605  1.0
  Cl  Cl45  1  0.418  0.250  0.895  1.0
  Cl  Cl46  1  0.082  0.750  0.395  1.0
  Cl  Cl47  1  0.582  0.750  0.105  1.0
[/CIF]
.