The structure described by CrPb6(OCl)6O2 crystallizes in the trigonal R-3 space group. The structure consists of three hydrogen peroxide molecules inside a CrPb6(OCl)6 framework. In the CrPb6(OCl)6 framework, Cr(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. Pb(1) is bonded in a 2-coordinate geometry to two equivalent O(1) and two equivalent Cl(1) atoms. O(1) is bonded in a 3-coordinate geometry to one Cr(1) and two equivalent Pb(1) atoms. Cl(1) is bonded in a 2-coordinate geometry to two equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_CrPb6(Cl3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.317
_cell_length_b   8.317
_cell_length_c   8.317
_cell_angle_alpha   108.502
_cell_angle_beta   108.502
_cell_angle_gamma   108.502
_symmetry_Int_Tables_number   1
_cell_volume   458.152
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.500  0.500  0.500  1.0
  Pb  Pb1  1  0.893  0.779  0.541  1.0
  Pb  Pb2  1  0.541  0.893  0.779  1.0
  Pb  Pb3  1  0.779  0.541  0.893  1.0
  Pb  Pb4  1  0.107  0.221  0.459  1.0
  Pb  Pb5  1  0.459  0.107  0.221  1.0
  Pb  Pb6  1  0.221  0.459  0.107  1.0
  Cl  Cl7  1  0.207  0.720  0.836  1.0
  Cl  Cl8  1  0.836  0.207  0.720  1.0
  Cl  Cl9  1  0.720  0.836  0.207  1.0
  Cl  Cl10  1  0.793  0.280  0.164  1.0
  Cl  Cl11  1  0.164  0.793  0.280  1.0
  Cl  Cl12  1  0.280  0.164  0.793  1.0
  O  O13  1  0.473  0.403  0.254  1.0
  O  O14  1  0.254  0.473  0.403  1.0
  O  O15  1  0.403  0.254  0.473  1.0
  O  O16  1  0.527  0.597  0.746  1.0
  O  O17  1  0.746  0.527  0.597  1.0
  O  O18  1  0.597  0.746  0.527  1.0
  O  O19  1  0.927  0.927  0.927  1.0
  O  O20  1  0.073  0.073  0.073  1.0
[/CIF]
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The structure described by CrPb6(OCl)6O2 crystallizes in the trigonal R-3 space group. The structure consists of three hydrogen peroxide molecules inside a CrPb6(OCl)6 framework. In the CrPb6(OCl)6 framework, Cr(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. Pb(1) is bonded in a 2-coordinate geometry to two equivalent O(1) and two equivalent Cl(1) atoms. O(1) is bonded in a 3-coordinate geometry to one Cr(1) and two equivalent Pb(1) atoms. Cl(1) is bonded in a 2-coordinate geometry to two equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_CrPb6(Cl3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.317
_cell_length_b   8.317
_cell_length_c   8.317
_cell_angle_alpha   108.502
_cell_angle_beta   108.502
_cell_angle_gamma   108.502
_symmetry_Int_Tables_number   1
_cell_volume   458.152
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.500  0.500  0.500  1.0
  Pb  Pb1  1  0.893  0.779  0.541  1.0
  Pb  Pb2  1  0.541  0.893  0.779  1.0
  Pb  Pb3  1  0.779  0.541  0.893  1.0
  Pb  Pb4  1  0.107  0.221  0.459  1.0
  Pb  Pb5  1  0.459  0.107  0.221  1.0
  Pb  Pb6  1  0.221  0.459  0.107  1.0
  Cl  Cl7  1  0.207  0.720  0.836  1.0
  Cl  Cl8  1  0.836  0.207  0.720  1.0
  Cl  Cl9  1  0.720  0.836  0.207  1.0
  Cl  Cl10  1  0.793  0.280  0.164  1.0
  Cl  Cl11  1  0.164  0.793  0.280  1.0
  Cl  Cl12  1  0.280  0.164  0.793  1.0
  O  O13  1  0.473  0.403  0.254  1.0
  O  O14  1  0.254  0.473  0.403  1.0
  O  O15  1  0.403  0.254  0.473  1.0
  O  O16  1  0.527  0.597  0.746  1.0
  O  O17  1  0.746  0.527  0.597  1.0
  O  O18  1  0.597  0.746  0.527  1.0
  O  O19  1  0.927  0.927  0.927  1.0
  O  O20  1  0.073  0.073  0.073  1.0
[/CIF]
.