The structure described by TmPdP crystallizes in the orthorhombic Pnma space group. Tm(1) is bonded in a 11-coordinate geometry to six equivalent Pd(1) and five equivalent P(1) atoms. Pd(1) is bonded to six equivalent Tm(1), two equivalent Pd(1), and four equivalent P(1) atoms to form a mixture of distorted face, corner, and edge-sharing PdTm6P4Pd2 cuboctahedra. P(1) is bonded in a 9-coordinate geometry to five equivalent Tm(1) and four equivalent Pd(1) atoms. is represented by the CIF card [CIF]
data_TmPPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.949
_cell_length_b   6.844
_cell_length_c   7.673
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   207.411
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.250  0.533  0.188  1.0
  Tm  Tm1  1  0.750  0.467  0.812  1.0
  Tm  Tm2  1  0.750  0.967  0.688  1.0
  Tm  Tm3  1  0.250  0.033  0.312  1.0
  P  P4  1  0.250  0.746  0.877  1.0
  P  P5  1  0.750  0.254  0.123  1.0
  P  P6  1  0.750  0.754  0.377  1.0
  P  P7  1  0.250  0.246  0.623  1.0
  Pd  Pd8  1  0.250  0.648  0.561  1.0
  Pd  Pd9  1  0.750  0.352  0.439  1.0
  Pd  Pd10  1  0.750  0.852  0.061  1.0
  Pd  Pd11  1  0.250  0.148  0.939  1.0
[/CIF]
.
The structure described by TmPdP crystallizes in the orthorhombic Pnma space group. Tm(1) is bonded in a 11-coordinate geometry to six equivalent Pd(1) and five equivalent P(1) atoms. Pd(1) is bonded to six equivalent Tm(1), two equivalent Pd(1), and four equivalent P(1) atoms to form a mixture of distorted face, corner, and edge-sharing PdTm6P4Pd2 cuboctahedra. P(1) is bonded in a 9-coordinate geometry to five equivalent Tm(1) and four equivalent Pd(1) atoms. is represented by the CIF card [CIF]
data_TmPPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.949
_cell_length_b   6.844
_cell_length_c   7.673
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   207.411
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.250  0.533  0.188  1.0
  Tm  Tm1  1  0.750  0.467  0.812  1.0
  Tm  Tm2  1  0.750  0.967  0.688  1.0
  Tm  Tm3  1  0.250  0.033  0.312  1.0
  P  P4  1  0.250  0.746  0.877  1.0
  P  P5  1  0.750  0.254  0.123  1.0
  P  P6  1  0.750  0.754  0.377  1.0
  P  P7  1  0.250  0.246  0.623  1.0
  Pd  Pd8  1  0.250  0.648  0.561  1.0
  Pd  Pd9  1  0.750  0.352  0.439  1.0
  Pd  Pd10  1  0.750  0.852  0.061  1.0
  Pd  Pd11  1  0.250  0.148  0.939  1.0
[/CIF]
.