The crystal structure described by Li7Mn(OF)3 crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded in a 2-coordinate geometry to one F(1), one F(2), and one F(6) atom. In the second Li site, Li(2) is bonded in a distorted L-shaped geometry to one O(1) and one F(5) atom. In the third Li site, Li(3) is bonded in a distorted L-shaped geometry to one O(5), one F(1), and one F(6) atom. In the fourth Li site, Li(4) is bonded in a 3-coordinate geometry to one O(2), one F(2), and one F(3) atom. In the fifth Li site, Li(5) is bonded in a 2-coordinate geometry to one O(5), one O(6), one F(1), and one F(2) atom. In the sixth Li site, Li(6) is bonded in a 3-coordinate geometry to one O(1), one O(4), one F(3), and one F(4) atom. In the seventh Li site, Li(7) is bonded in a distorted linear geometry to one O(6) and one F(5) atom. In the eighth Li site, Li(8) is bonded in a 3-coordinate geometry to one O(2), one F(3), and one F(6) atom. In the ninth Li site, Li(9) is bonded in a 3-coordinate geometry to one O(3), one O(6), and one F(1) atom. In the tenth Li site, Li(10) is bonded in a 2-coordinate geometry to one O(4) and one F(4) atom. In the eleventh Li site, Li(11) is bonded in a 2-coordinate geometry to one O(1), one O(3), and one O(6) atom. In the twelfth Li site, Li(12) is bonded in a 2-coordinate geometry to one F(2), one F(3), and one F(6) atom. In the thirteenth Li site, Li(13) is bonded in a 2-coordinate geometry to one O(1), one O(6), and one F(5) atom. In the fourteenth Li site, Li(14) is bonded in a 2-coordinate geometry to one O(1), one O(4), and one O(6) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 1-coordinate geometry to one O(1), one O(2), and one F(4) atom. In the second Mn site, Mn(2) is bonded in a distorted linear geometry to one O(3), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Li(11), one Li(13), one Li(14), one Li(2), one Li(6), and one Mn(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(4), one Li(8), and one Mn(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(11), one Li(9), and one Mn(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(10), one Li(14), and one Li(6) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(3), one Li(5), and one Mn(2) atom. In the sixth O site, O(6) is bonded in a 7-coordinate geometry to one Li(11), one Li(13), one Li(14), one Li(5), one Li(7), one Li(9), and one Mn(2) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to one Li(1), one Li(3), one Li(5), and one Li(9) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to one Li(1), one Li(12), one Li(4), and one Li(5) atom. In the third F site, F(3) is bonded in a 4-coordinate geometry to one Li(12), one Li(4), one Li(6), and one Li(8) atom. In the fourth F site, F(4) is bonded in a 3-coordinate geometry to one Li(10), one Li(6), and one Mn(1) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to one Li(13), one Li(2), and one Li(7) atom. In the sixth F site, F(6) is bonded in a 4-coordinate geometry to one Li(1), one Li(12), one Li(3), and one Li(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li7Mn(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.477
_cell_length_b   6.071
_cell_length_c   10.137
_cell_angle_alpha   105.911
_cell_angle_beta   91.310
_cell_angle_gamma   111.428
_symmetry_Int_Tables_number   1
_cell_volume   298.923
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.002  0.900  0.775  1.0
  Li  Li1  1  0.488  0.381  0.254  1.0
  Li  Li2  1  0.509  0.048  0.603  1.0
  Li  Li3  1  1.000  0.467  0.880  1.0
  Li  Li4  1  0.044  0.774  0.555  1.0
  Li  Li5  1  0.520  0.318  0.049  1.0
  Li  Li6  1  0.928  0.626  0.334  1.0
  Li  Li7  1  0.475  0.743  0.944  1.0
  Li  Li8  1  0.954  0.190  0.461  1.0
  Li  Li9  1  0.982  0.509  0.110  1.0
  Li  Li10  1  0.502  0.988  0.382  1.0
  Li  Li11  1  0.485  0.606  0.723  1.0
  Li  Li12  1  0.043  0.103  0.259  1.0
  Li  Li13  1  0.563  0.872  0.185  1.0
  Mn  Mn14  1  0.028  0.942  0.045  1.0
  Mn  Mn15  1  0.537  0.548  0.483  1.0
  O  O16  1  0.325  0.073  0.192  1.0
  O  O17  1  0.143  0.751  0.957  1.0
  O  O18  1  0.662  0.305  0.441  1.0
  O  O19  1  0.705  0.643  0.125  1.0
  O  O20  1  0.345  0.724  0.535  1.0
  O  O21  1  0.803  0.873  0.375  1.0
  F  F22  1  0.174  0.074  0.617  1.0
  F  F23  1  0.821  0.581  0.704  1.0
  F  F24  1  0.319  0.413  0.882  1.0
  F  F25  1  0.823  0.212  0.051  1.0
  F  F26  1  0.155  0.421  0.293  1.0
  F  F27  1  0.666  0.917  0.787  1.0
[/CIF]
.
The crystal structure described by Li7Mn(OF)3 crystallizes in the triclinic P1 space group. There are fourteen inequivalent Li sites. In the first Li site, Li(1) is bonded in a 2-coordinate geometry to one F(1), one F(2), and one F(6) atom. In the second Li site, Li(2) is bonded in a distorted L-shaped geometry to one O(1) and one F(5) atom. In the third Li site, Li(3) is bonded in a distorted L-shaped geometry to one O(5), one F(1), and one F(6) atom. In the fourth Li site, Li(4) is bonded in a 3-coordinate geometry to one O(2), one F(2), and one F(3) atom. In the fifth Li site, Li(5) is bonded in a 2-coordinate geometry to one O(5), one O(6), one F(1), and one F(2) atom. In the sixth Li site, Li(6) is bonded in a 3-coordinate geometry to one O(1), one O(4), one F(3), and one F(4) atom. In the seventh Li site, Li(7) is bonded in a distorted linear geometry to one O(6) and one F(5) atom. In the eighth Li site, Li(8) is bonded in a 3-coordinate geometry to one O(2), one F(3), and one F(6) atom. In the ninth Li site, Li(9) is bonded in a 3-coordinate geometry to one O(3), one O(6), and one F(1) atom. In the tenth Li site, Li(10) is bonded in a 2-coordinate geometry to one O(4) and one F(4) atom. In the eleventh Li site, Li(11) is bonded in a 2-coordinate geometry to one O(1), one O(3), and one O(6) atom. In the twelfth Li site, Li(12) is bonded in a 2-coordinate geometry to one F(2), one F(3), and one F(6) atom. In the thirteenth Li site, Li(13) is bonded in a 2-coordinate geometry to one O(1), one O(6), and one F(5) atom. In the fourteenth Li site, Li(14) is bonded in a 2-coordinate geometry to one O(1), one O(4), and one O(6) atom. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 1-coordinate geometry to one O(1), one O(2), and one F(4) atom. In the second Mn site, Mn(2) is bonded in a distorted linear geometry to one O(3), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Li(11), one Li(13), one Li(14), one Li(2), one Li(6), and one Mn(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(4), one Li(8), and one Mn(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(11), one Li(9), and one Mn(2) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(10), one Li(14), and one Li(6) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(3), one Li(5), and one Mn(2) atom. In the sixth O site, O(6) is bonded in a 7-coordinate geometry to one Li(11), one Li(13), one Li(14), one Li(5), one Li(7), one Li(9), and one Mn(2) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a 4-coordinate geometry to one Li(1), one Li(3), one Li(5), and one Li(9) atom. In the second F site, F(2) is bonded in a 4-coordinate geometry to one Li(1), one Li(12), one Li(4), and one Li(5) atom. In the third F site, F(3) is bonded in a 4-coordinate geometry to one Li(12), one Li(4), one Li(6), and one Li(8) atom. In the fourth F site, F(4) is bonded in a 3-coordinate geometry to one Li(10), one Li(6), and one Mn(1) atom. In the fifth F site, F(5) is bonded in a 3-coordinate geometry to one Li(13), one Li(2), and one Li(7) atom. In the sixth F site, F(6) is bonded in a 4-coordinate geometry to one Li(1), one Li(12), one Li(3), and one Li(8) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li7Mn(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.477
_cell_length_b   6.071
_cell_length_c   10.137
_cell_angle_alpha   105.911
_cell_angle_beta   91.310
_cell_angle_gamma   111.428
_symmetry_Int_Tables_number   1
_cell_volume   298.923
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.002  0.900  0.775  1.0
  Li  Li1  1  0.488  0.381  0.254  1.0
  Li  Li2  1  0.509  0.048  0.603  1.0
  Li  Li3  1  1.000  0.467  0.880  1.0
  Li  Li4  1  0.044  0.774  0.555  1.0
  Li  Li5  1  0.520  0.318  0.049  1.0
  Li  Li6  1  0.928  0.626  0.334  1.0
  Li  Li7  1  0.475  0.743  0.944  1.0
  Li  Li8  1  0.954  0.190  0.461  1.0
  Li  Li9  1  0.982  0.509  0.110  1.0
  Li  Li10  1  0.502  0.988  0.382  1.0
  Li  Li11  1  0.485  0.606  0.723  1.0
  Li  Li12  1  0.043  0.103  0.259  1.0
  Li  Li13  1  0.563  0.872  0.185  1.0
  Mn  Mn14  1  0.028  0.942  0.045  1.0
  Mn  Mn15  1  0.537  0.548  0.483  1.0
  O  O16  1  0.325  0.073  0.192  1.0
  O  O17  1  0.143  0.751  0.957  1.0
  O  O18  1  0.662  0.305  0.441  1.0
  O  O19  1  0.705  0.643  0.125  1.0
  O  O20  1  0.345  0.724  0.535  1.0
  O  O21  1  0.803  0.873  0.375  1.0
  F  F22  1  0.174  0.074  0.617  1.0
  F  F23  1  0.821  0.581  0.704  1.0
  F  F24  1  0.319  0.413  0.882  1.0
  F  F25  1  0.823  0.212  0.051  1.0
  F  F26  1  0.155  0.421  0.293  1.0
  F  F27  1  0.666  0.917  0.787  1.0
[/CIF]
.