The structure described by V6O11F is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(4), one O(6), two equivalent O(1), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent V(3)O5F octahedra, corners with three equivalent V(6)O5F octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one V(5)O5F octahedra, and  an edgeedge with one V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. In the second V site, V(2) is bonded to one O(3), one O(4), one O(5), one O(7), and two equivalent O(1) atoms to form VO6 octahedra that share corners with two equivalent V(4)O6 octahedra, corners with three equivalent V(5)O5F octahedra, corners with three equivalent V(1)O6 octahedra,  an edgeedge with one V(3)O5F octahedra, and  an edgeedge with one V(6)O5F octahedra. The corner-sharing octahedral tilt angles range from 44-54°. In the third V site, V(3) is bonded to one O(4), one O(6), one O(7), two equivalent O(2), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(1)O6 octahedra, corners with three equivalent V(5)O5F octahedra, corners with three equivalent V(4)O6 octahedra,  an edgeedge with one V(6)O5F octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. In the fourth V site, V(4) is bonded to one O(3), one O(7), two equivalent O(2), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with three equivalent V(3)O5F octahedra, corners with three equivalent V(6)O5F octahedra,  an edgeedge with one V(5)O5F octahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-52°. In the fifth V site, V(5) is bonded to one O(5), two equivalent O(1), two equivalent O(2), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(6)O5F octahedra, corners with three equivalent V(3)O5F octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-54°. In the sixth V site, V(6) is bonded to one O(3), one O(5), one O(6), two equivalent O(8), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(5)O5F octahedra, corners with three equivalent V(1)O6 octahedra, corners with three equivalent V(4)O6 octahedra,  an edgeedge with one V(3)O5F octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one V(2), one V(5), and one V(6) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(6) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(6) atom. F(1) is bonded in a distorted trigonal planar geometry to one V(3), one V(5), and one V(6) atom. is represented by the CIF card [CIF]
data_V6O11F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.479
_cell_length_b   5.479
_cell_length_c   7.231
_cell_angle_alpha   71.742
_cell_angle_beta   71.742
_cell_angle_gamma   71.543
_symmetry_Int_Tables_number   1
_cell_volume   189.959
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.327  0.327  0.170  1.0
  V  V1  1  0.661  0.661  0.332  1.0
  V  V2  1  0.349  0.349  0.670  1.0
  V  V3  1  0.669  0.669  0.842  1.0
  V  V4  1  0.996  0.996  0.489  1.0
  V  V5  1  0.998  0.998  0.014  1.0
  O  O6  1  0.975  0.373  0.326  1.0
  O  O7  1  0.624  0.034  0.672  1.0
  O  O8  1  0.763  0.763  0.032  1.0
  O  O9  1  0.441  0.441  0.365  1.0
  O  O10  1  0.893  0.893  0.297  1.0
  O  O11  1  0.231  0.231  0.967  1.0
  O  O12  1  0.573  0.573  0.632  1.0
  O  O13  1  0.700  0.294  0.998  1.0
  O  O14  1  0.373  0.975  0.326  1.0
  O  O15  1  0.034  0.624  0.672  1.0
  O  O16  1  0.294  0.700  0.998  1.0
  F  F17  1  0.101  0.101  0.700  1.0
[/CIF]
.
The structure described by V6O11F is Hydrophilite-derived structured and crystallizes in the monoclinic Cm space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(4), one O(6), two equivalent O(1), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent V(3)O5F octahedra, corners with three equivalent V(6)O5F octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one V(5)O5F octahedra, and  an edgeedge with one V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. In the second V site, V(2) is bonded to one O(3), one O(4), one O(5), one O(7), and two equivalent O(1) atoms to form VO6 octahedra that share corners with two equivalent V(4)O6 octahedra, corners with three equivalent V(5)O5F octahedra, corners with three equivalent V(1)O6 octahedra,  an edgeedge with one V(3)O5F octahedra, and  an edgeedge with one V(6)O5F octahedra. The corner-sharing octahedral tilt angles range from 44-54°. In the third V site, V(3) is bonded to one O(4), one O(6), one O(7), two equivalent O(2), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(1)O6 octahedra, corners with three equivalent V(5)O5F octahedra, corners with three equivalent V(4)O6 octahedra,  an edgeedge with one V(6)O5F octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. In the fourth V site, V(4) is bonded to one O(3), one O(7), two equivalent O(2), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with three equivalent V(3)O5F octahedra, corners with three equivalent V(6)O5F octahedra,  an edgeedge with one V(5)O5F octahedra, and  an edgeedge with one V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-52°. In the fifth V site, V(5) is bonded to one O(5), two equivalent O(1), two equivalent O(2), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(6)O5F octahedra, corners with three equivalent V(3)O5F octahedra, corners with three equivalent V(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and  an edgeedge with one V(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-54°. In the sixth V site, V(6) is bonded to one O(3), one O(5), one O(6), two equivalent O(8), and one F(1) atom to form VO5F octahedra that share corners with two equivalent V(5)O5F octahedra, corners with three equivalent V(1)O6 octahedra, corners with three equivalent V(4)O6 octahedra,  an edgeedge with one V(3)O5F octahedra, and  an edgeedge with one V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-53°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(5) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(3), one V(4), and one V(5) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(2), one V(4), and one V(6) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one V(2), and one V(3) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one V(2), one V(5), and one V(6) atom. In the sixth O site, O(6) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(6) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(6) atom. F(1) is bonded in a distorted trigonal planar geometry to one V(3), one V(5), and one V(6) atom. is represented by the CIF card [CIF]
data_V6O11F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.479
_cell_length_b   5.479
_cell_length_c   7.231
_cell_angle_alpha   71.742
_cell_angle_beta   71.742
_cell_angle_gamma   71.543
_symmetry_Int_Tables_number   1
_cell_volume   189.959
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.327  0.327  0.170  1.0
  V  V1  1  0.661  0.661  0.332  1.0
  V  V2  1  0.349  0.349  0.670  1.0
  V  V3  1  0.669  0.669  0.842  1.0
  V  V4  1  0.996  0.996  0.489  1.0
  V  V5  1  0.998  0.998  0.014  1.0
  O  O6  1  0.975  0.373  0.326  1.0
  O  O7  1  0.624  0.034  0.672  1.0
  O  O8  1  0.763  0.763  0.032  1.0
  O  O9  1  0.441  0.441  0.365  1.0
  O  O10  1  0.893  0.893  0.297  1.0
  O  O11  1  0.231  0.231  0.967  1.0
  O  O12  1  0.573  0.573  0.632  1.0
  O  O13  1  0.700  0.294  0.998  1.0
  O  O14  1  0.373  0.975  0.326  1.0
  O  O15  1  0.034  0.624  0.672  1.0
  O  O16  1  0.294  0.700  0.998  1.0
  F  F17  1  0.101  0.101  0.700  1.0
[/CIF]
.