The material described by Cr(SbO3)2 is Hydrophilite-derived structured and crystallizes in the monoclinic C2/m space group. Cr(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form CrO6 octahedra that share corners with twelve equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to one Cr(1) and two equivalent Sb(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one Cr(1) and two equivalent Sb(1) atoms. is represented by the CIF file [CIF]
data_Cr(SbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.317
_cell_length_b   5.317
_cell_length_c   4.703
_cell_angle_alpha   88.315
_cell_angle_beta   88.315
_cell_angle_gamma   121.093
_symmetry_Int_Tables_number   1
_cell_volume   113.638
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.000  0.000  0.000  1.0
  Sb  Sb1  1  0.667  0.333  0.500  1.0
  Sb  Sb2  1  0.333  0.667  0.500  1.0
  O  O3  1  0.011  0.368  0.268  1.0
  O  O4  1  0.989  0.632  0.732  1.0
  O  O5  1  0.655  0.655  0.266  1.0
  O  O6  1  0.345  0.345  0.734  1.0
  O  O7  1  0.632  0.989  0.732  1.0
  O  O8  1  0.368  0.011  0.268  1.0
[/CIF]
.
The material described by Cr(SbO3)2 is Hydrophilite-derived structured and crystallizes in the monoclinic C2/m space group. Cr(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form CrO6 octahedra that share corners with twelve equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Cr(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to one Cr(1) and two equivalent Sb(1) atoms. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to one Cr(1) and two equivalent Sb(1) atoms. is represented by the CIF file [CIF]
data_Cr(SbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.317
_cell_length_b   5.317
_cell_length_c   4.703
_cell_angle_alpha   88.315
_cell_angle_beta   88.315
_cell_angle_gamma   121.093
_symmetry_Int_Tables_number   1
_cell_volume   113.638
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.000  0.000  0.000  1.0
  Sb  Sb1  1  0.667  0.333  0.500  1.0
  Sb  Sb2  1  0.333  0.667  0.500  1.0
  O  O3  1  0.011  0.368  0.268  1.0
  O  O4  1  0.989  0.632  0.732  1.0
  O  O5  1  0.655  0.655  0.266  1.0
  O  O6  1  0.345  0.345  0.734  1.0
  O  O7  1  0.632  0.989  0.732  1.0
  O  O8  1  0.368  0.011  0.268  1.0
[/CIF]
.