The material structure described by CeVO2 crystallizes in the tetragonal I4_1/amd space group. Ce(1) is bonded to six equivalent O(1) atoms to form edge-sharing CeO6 octahedra. V(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Ce(1) and two equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing OCe3V2 trigonal bipyramids. is represented by the CIF file [CIF]
data_CeVO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.565
_cell_length_b   7.565
_cell_length_c   7.565
_cell_angle_alpha   130.841
_cell_angle_beta   130.841
_cell_angle_gamma   72.065
_symmetry_Int_Tables_number   1
_cell_volume   242.292
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.875  0.625  0.250  1.0
  Ce  Ce1  1  0.375  0.625  0.750  1.0
  Ce  Ce2  1  0.375  0.625  0.250  1.0
  Ce  Ce3  1  0.375  0.125  0.750  1.0
  V  V4  1  0.375  0.125  0.250  1.0
  V  V5  1  0.875  0.125  0.750  1.0
  V  V6  1  0.875  0.125  0.250  1.0
  V  V7  1  0.875  0.625  0.750  1.0
  O  O8  1  0.177  0.397  0.220  1.0
  O  O9  1  0.177  0.957  0.780  1.0
  O  O10  1  0.147  0.427  0.720  1.0
  O  O11  1  0.573  0.853  0.280  1.0
  O  O12  1  0.707  0.427  0.280  1.0
  O  O13  1  0.573  0.293  0.720  1.0
  O  O14  1  0.603  0.823  0.780  1.0
  O  O15  1  0.043  0.823  0.220  1.0
[/CIF]
.
The material structure described by CeVO2 crystallizes in the tetragonal I4_1/amd space group. Ce(1) is bonded to six equivalent O(1) atoms to form edge-sharing CeO6 octahedra. V(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent Ce(1) and two equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing OCe3V2 trigonal bipyramids. is represented by the CIF file [CIF]
data_CeVO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.565
_cell_length_b   7.565
_cell_length_c   7.565
_cell_angle_alpha   130.841
_cell_angle_beta   130.841
_cell_angle_gamma   72.065
_symmetry_Int_Tables_number   1
_cell_volume   242.292
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.875  0.625  0.250  1.0
  Ce  Ce1  1  0.375  0.625  0.750  1.0
  Ce  Ce2  1  0.375  0.625  0.250  1.0
  Ce  Ce3  1  0.375  0.125  0.750  1.0
  V  V4  1  0.375  0.125  0.250  1.0
  V  V5  1  0.875  0.125  0.750  1.0
  V  V6  1  0.875  0.125  0.250  1.0
  V  V7  1  0.875  0.625  0.750  1.0
  O  O8  1  0.177  0.397  0.220  1.0
  O  O9  1  0.177  0.957  0.780  1.0
  O  O10  1  0.147  0.427  0.720  1.0
  O  O11  1  0.573  0.853  0.280  1.0
  O  O12  1  0.707  0.427  0.280  1.0
  O  O13  1  0.573  0.293  0.720  1.0
  O  O14  1  0.603  0.823  0.780  1.0
  O  O15  1  0.043  0.823  0.220  1.0
[/CIF]
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