The crystal structure described by Li5SbS crystallizes in the monoclinic P2_1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted bent 150 degrees geometry to one Sb(2), one S(1), and one S(2) atom. In the second Li site, Li(2) is bonded in a distorted trigonal planar geometry to one Li(4), one Li(7), one Sb(1), one Sb(2), and one S(1) atom. In the third Li site, Li(3) is bonded in a distorted trigonal planar geometry to one Li(4), one Li(7), one Sb(1), one Sb(2), and one S(2) atom. In the fourth Li site, Li(4) is bonded in a 10-coordinate geometry to one Li(2), one Li(3), one Li(6), one Li(9), two equivalent Li(7), one Sb(2), two equivalent Sb(1), and one S(1) atom. In the fifth Li site, Li(5) is bonded in a 2-coordinate geometry to one Li(7), one Sb(1), one Sb(2), one S(1), and one S(2) atom. In the sixth Li site, Li(6) is bonded in a 2-coordinate geometry to one Li(4), one Sb(1), one Sb(2), one S(1), and one S(2) atom. In the seventh Li site, Li(7) is bonded in a 10-coordinate geometry to one Li(2), one Li(3), one Li(5), one Li(8), two equivalent Li(4), one Sb(2), two equivalent Sb(1), and one S(1) atom. In the eighth Li site, Li(8) is bonded in a 3-coordinate geometry to one Li(7), one Sb(1), one Sb(2), and one S(2) atom. In the ninth Li site, Li(9) is bonded in a 3-coordinate geometry to one Li(4), one Sb(1), one Sb(2), and one S(2) atom. In the tenth Li site, Li(10) is bonded in a distorted trigonal planar geometry to one Sb(2), one S(1), and one S(2) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 10-coordinate geometry to one Li(2), one Li(3), one Li(5), one Li(6), one Li(8), one Li(9), two equivalent Li(4), and two equivalent Li(7) atoms. In the second Sb site, Sb(2) is bonded in a 10-coordinate geometry to one Li(1), one Li(10), one Li(2), one Li(3), one Li(4), one Li(5), one Li(6), one Li(7), one Li(8), and one Li(9) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a pentagonal bipyramidal geometry to one Li(1), one Li(10), one Li(2), one Li(4), one Li(5), one Li(6), and one Li(7) atom. In the second S site, S(2) is bonded in a 7-coordinate geometry to one Li(1), one Li(10), one Li(3), one Li(5), one Li(6), one Li(8), and one Li(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li5SbS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.025
_cell_length_b   7.905
_cell_length_c   8.508
_cell_angle_alpha   87.873
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   539.323
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.741  0.401  0.426  1.0
  Li  Li1  1  0.252  0.998  0.977  1.0
  Li  Li2  1  0.250  0.481  0.267  1.0
  Li  Li3  1  0.904  0.339  0.017  1.0
  Li  Li4  1  0.925  0.845  0.734  1.0
  Li  Li5  1  0.568  0.846  0.733  1.0
  Li  Li6  1  0.589  0.338  0.014  1.0
  Li  Li7  1  0.918  0.745  0.288  1.0
  Li  Li8  1  0.572  0.750  0.284  1.0
  Li  Li9  1  0.246  0.987  0.533  1.0
  Li  Li10  1  0.089  0.662  0.986  1.0
  Li  Li11  1  0.746  0.013  0.467  1.0
  Li  Li12  1  0.072  0.250  0.716  1.0
  Li  Li13  1  0.418  0.255  0.712  1.0
  Li  Li14  1  0.404  0.661  0.983  1.0
  Li  Li15  1  0.750  0.519  0.733  1.0
  Li  Li16  1  0.068  0.154  0.267  1.0
  Li  Li17  1  0.425  0.155  0.266  1.0
  Li  Li18  1  0.241  0.599  0.574  1.0
  Li  Li19  1  0.752  0.002  0.023  1.0
  Sb  Sb20  1  0.247  0.335  0.989  1.0
  Sb  Sb21  1  0.245  0.824  0.263  1.0
  Sb  Sb22  1  0.747  0.665  0.011  1.0
  Sb  Sb23  1  0.745  0.176  0.737  1.0
  S  S24  1  0.747  0.183  0.235  1.0
  S  S25  1  0.743  0.709  0.514  1.0
  S  S26  1  0.243  0.291  0.486  1.0
  S  S27  1  0.247  0.817  0.765  1.0
[/CIF]
.
The crystal structure described by Li5SbS crystallizes in the monoclinic P2_1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded in a distorted bent 150 degrees geometry to one Sb(2), one S(1), and one S(2) atom. In the second Li site, Li(2) is bonded in a distorted trigonal planar geometry to one Li(4), one Li(7), one Sb(1), one Sb(2), and one S(1) atom. In the third Li site, Li(3) is bonded in a distorted trigonal planar geometry to one Li(4), one Li(7), one Sb(1), one Sb(2), and one S(2) atom. In the fourth Li site, Li(4) is bonded in a 10-coordinate geometry to one Li(2), one Li(3), one Li(6), one Li(9), two equivalent Li(7), one Sb(2), two equivalent Sb(1), and one S(1) atom. In the fifth Li site, Li(5) is bonded in a 2-coordinate geometry to one Li(7), one Sb(1), one Sb(2), one S(1), and one S(2) atom. In the sixth Li site, Li(6) is bonded in a 2-coordinate geometry to one Li(4), one Sb(1), one Sb(2), one S(1), and one S(2) atom. In the seventh Li site, Li(7) is bonded in a 10-coordinate geometry to one Li(2), one Li(3), one Li(5), one Li(8), two equivalent Li(4), one Sb(2), two equivalent Sb(1), and one S(1) atom. In the eighth Li site, Li(8) is bonded in a 3-coordinate geometry to one Li(7), one Sb(1), one Sb(2), and one S(2) atom. In the ninth Li site, Li(9) is bonded in a 3-coordinate geometry to one Li(4), one Sb(1), one Sb(2), and one S(2) atom. In the tenth Li site, Li(10) is bonded in a distorted trigonal planar geometry to one Sb(2), one S(1), and one S(2) atom. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 10-coordinate geometry to one Li(2), one Li(3), one Li(5), one Li(6), one Li(8), one Li(9), two equivalent Li(4), and two equivalent Li(7) atoms. In the second Sb site, Sb(2) is bonded in a 10-coordinate geometry to one Li(1), one Li(10), one Li(2), one Li(3), one Li(4), one Li(5), one Li(6), one Li(7), one Li(8), and one Li(9) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a pentagonal bipyramidal geometry to one Li(1), one Li(10), one Li(2), one Li(4), one Li(5), one Li(6), and one Li(7) atom. In the second S site, S(2) is bonded in a 7-coordinate geometry to one Li(1), one Li(10), one Li(3), one Li(5), one Li(6), one Li(8), and one Li(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li5SbS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.025
_cell_length_b   7.905
_cell_length_c   8.508
_cell_angle_alpha   87.873
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   539.323
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.741  0.401  0.426  1.0
  Li  Li1  1  0.252  0.998  0.977  1.0
  Li  Li2  1  0.250  0.481  0.267  1.0
  Li  Li3  1  0.904  0.339  0.017  1.0
  Li  Li4  1  0.925  0.845  0.734  1.0
  Li  Li5  1  0.568  0.846  0.733  1.0
  Li  Li6  1  0.589  0.338  0.014  1.0
  Li  Li7  1  0.918  0.745  0.288  1.0
  Li  Li8  1  0.572  0.750  0.284  1.0
  Li  Li9  1  0.246  0.987  0.533  1.0
  Li  Li10  1  0.089  0.662  0.986  1.0
  Li  Li11  1  0.746  0.013  0.467  1.0
  Li  Li12  1  0.072  0.250  0.716  1.0
  Li  Li13  1  0.418  0.255  0.712  1.0
  Li  Li14  1  0.404  0.661  0.983  1.0
  Li  Li15  1  0.750  0.519  0.733  1.0
  Li  Li16  1  0.068  0.154  0.267  1.0
  Li  Li17  1  0.425  0.155  0.266  1.0
  Li  Li18  1  0.241  0.599  0.574  1.0
  Li  Li19  1  0.752  0.002  0.023  1.0
  Sb  Sb20  1  0.247  0.335  0.989  1.0
  Sb  Sb21  1  0.245  0.824  0.263  1.0
  Sb  Sb22  1  0.747  0.665  0.011  1.0
  Sb  Sb23  1  0.745  0.176  0.737  1.0
  S  S24  1  0.747  0.183  0.235  1.0
  S  S25  1  0.743  0.709  0.514  1.0
  S  S26  1  0.243  0.291  0.486  1.0
  S  S27  1  0.247  0.817  0.765  1.0
[/CIF]
.