The material described by InH12(N2Cl)2InH6(NCl2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one InH12(N2Cl)2 cluster and one InH6(NCl2)2 cluster. In the InH12(N2Cl)2 cluster, In(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent Cl(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one In(1), one H(1), one H(4), and one H(5) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one In(1), one H(2), one H(7), and one H(9) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one N(2) atom. Cl(2) is bonded in a single-bond geometry to one In(1) atom. In the InH6(NCl2)2 cluster, In(2) is bonded in an octahedral geometry to two equivalent N(3), two equivalent Cl(1), and two equivalent Cl(3) atoms. N(3) is bonded in a distorted trigonal non-coplanar geometry to one In(2), one H(3), one H(6), and one H(8) atom. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(8) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one In(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one In(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_InH9(NCl)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.998
_cell_length_b   6.952
_cell_length_c   10.006
_cell_angle_alpha   86.240
_cell_angle_beta   86.701
_cell_angle_gamma   85.397
_symmetry_Int_Tables_number   1
_cell_volume   414.398
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.000  0.500  0.000  1.0
  In  In1  1  0.500  0.000  0.500  1.0
  H  H2  1  0.096  0.122  0.108  1.0
  H  H3  1  0.086  0.531  0.721  1.0
  H  H4  1  0.095  0.850  0.453  1.0
  H  H5  1  0.309  0.174  0.001  1.0
  H  H6  1  0.293  0.254  0.154  1.0
  H  H7  1  0.262  0.824  0.316  1.0
  H  H8  1  0.272  0.363  0.782  1.0
  H  H9  1  0.293  0.671  0.448  1.0
  H  H10  1  0.311  0.597  0.790  1.0
  H  H11  1  0.689  0.403  0.210  1.0
  H  H12  1  0.707  0.329  0.552  1.0
  H  H13  1  0.728  0.637  0.218  1.0
  H  H14  1  0.738  0.176  0.684  1.0
  H  H15  1  0.707  0.746  0.846  1.0
  H  H16  1  0.691  0.826  0.999  1.0
  H  H17  1  0.905  0.150  0.547  1.0
  H  H18  1  0.914  0.469  0.279  1.0
  H  H19  1  0.904  0.878  0.892  1.0
  N  N20  1  0.200  0.227  0.075  1.0
  N  N21  1  0.193  0.497  0.797  1.0
  N  N22  1  0.257  0.814  0.420  1.0
  N  N23  1  0.743  0.186  0.580  1.0
  N  N24  1  0.807  0.503  0.203  1.0
  N  N25  1  0.800  0.773  0.925  1.0
  Cl  Cl26  1  0.262  0.309  0.417  1.0
  Cl  Cl27  1  0.284  0.711  0.088  1.0
  Cl  Cl28  1  0.271  0.997  0.727  1.0
  Cl  Cl29  1  0.729  0.003  0.273  1.0
  Cl  Cl30  1  0.716  0.289  0.912  1.0
  Cl  Cl31  1  0.738  0.691  0.583  1.0
[/CIF]
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The material described by InH12(N2Cl)2InH6(NCl2)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one InH12(N2Cl)2 cluster and one InH6(NCl2)2 cluster. In the InH12(N2Cl)2 cluster, In(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent Cl(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one In(1), one H(1), one H(4), and one H(5) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one In(1), one H(2), one H(7), and one H(9) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one N(2) atom. Cl(2) is bonded in a single-bond geometry to one In(1) atom. In the InH6(NCl2)2 cluster, In(2) is bonded in an octahedral geometry to two equivalent N(3), two equivalent Cl(1), and two equivalent Cl(3) atoms. N(3) is bonded in a distorted trigonal non-coplanar geometry to one In(2), one H(3), one H(6), and one H(8) atom. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(8) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one In(2) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one In(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_InH9(NCl)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.998
_cell_length_b   6.952
_cell_length_c   10.006
_cell_angle_alpha   86.240
_cell_angle_beta   86.701
_cell_angle_gamma   85.397
_symmetry_Int_Tables_number   1
_cell_volume   414.398
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.000  0.500  0.000  1.0
  In  In1  1  0.500  0.000  0.500  1.0
  H  H2  1  0.096  0.122  0.108  1.0
  H  H3  1  0.086  0.531  0.721  1.0
  H  H4  1  0.095  0.850  0.453  1.0
  H  H5  1  0.309  0.174  0.001  1.0
  H  H6  1  0.293  0.254  0.154  1.0
  H  H7  1  0.262  0.824  0.316  1.0
  H  H8  1  0.272  0.363  0.782  1.0
  H  H9  1  0.293  0.671  0.448  1.0
  H  H10  1  0.311  0.597  0.790  1.0
  H  H11  1  0.689  0.403  0.210  1.0
  H  H12  1  0.707  0.329  0.552  1.0
  H  H13  1  0.728  0.637  0.218  1.0
  H  H14  1  0.738  0.176  0.684  1.0
  H  H15  1  0.707  0.746  0.846  1.0
  H  H16  1  0.691  0.826  0.999  1.0
  H  H17  1  0.905  0.150  0.547  1.0
  H  H18  1  0.914  0.469  0.279  1.0
  H  H19  1  0.904  0.878  0.892  1.0
  N  N20  1  0.200  0.227  0.075  1.0
  N  N21  1  0.193  0.497  0.797  1.0
  N  N22  1  0.257  0.814  0.420  1.0
  N  N23  1  0.743  0.186  0.580  1.0
  N  N24  1  0.807  0.503  0.203  1.0
  N  N25  1  0.800  0.773  0.925  1.0
  Cl  Cl26  1  0.262  0.309  0.417  1.0
  Cl  Cl27  1  0.284  0.711  0.088  1.0
  Cl  Cl28  1  0.271  0.997  0.727  1.0
  Cl  Cl29  1  0.729  0.003  0.273  1.0
  Cl  Cl30  1  0.716  0.289  0.912  1.0
  Cl  Cl31  1  0.738  0.691  0.583  1.0
[/CIF]
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