The crystal structure described by TbWO5 crystallizes in the monoclinic P2_1/c space group. Tb(1) is bonded in a 8-coordinate geometry to one O(4), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. W(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to two equivalent Tb(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Tb(1) and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Tb(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one Tb(1) and one W(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Tb(1) and one W(1) atom. is represented by the CIF card [CIF]
data_TbWO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.894
_cell_length_b   5.299
_cell_length_c   7.031
_cell_angle_alpha   63.163
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   428.602
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.556  0.638  0.217  1.0
  Tb  Tb1  1  0.444  0.362  0.783  1.0
  Tb  Tb2  1  0.056  0.362  0.283  1.0
  Tb  Tb3  1  0.944  0.638  0.717  1.0
  W  W4  1  0.861  0.884  0.156  1.0
  W  W5  1  0.139  0.116  0.844  1.0
  W  W6  1  0.361  0.116  0.344  1.0
  W  W7  1  0.639  0.884  0.656  1.0
  O  O8  1  0.911  0.526  0.432  1.0
  O  O9  1  0.089  0.474  0.568  1.0
  O  O10  1  0.411  0.474  0.068  1.0
  O  O11  1  0.589  0.526  0.932  1.0
  O  O12  1  0.430  0.993  0.158  1.0
  O  O13  1  0.570  0.007  0.842  1.0
  O  O14  1  0.930  0.007  0.342  1.0
  O  O15  1  0.070  0.993  0.658  1.0
  O  O16  1  0.932  0.690  0.030  1.0
  O  O17  1  0.068  0.310  0.970  1.0
  O  O18  1  0.432  0.310  0.470  1.0
  O  O19  1  0.568  0.690  0.530  1.0
  O  O20  1  0.726  0.793  0.205  1.0
  O  O21  1  0.274  0.207  0.795  1.0
  O  O22  1  0.226  0.207  0.295  1.0
  O  O23  1  0.774  0.793  0.705  1.0
  O  O24  1  0.143  0.772  0.074  1.0
  O  O25  1  0.857  0.228  0.926  1.0
  O  O26  1  0.643  0.228  0.426  1.0
  O  O27  1  0.357  0.772  0.574  1.0
[/CIF]
.
The crystal structure described by TbWO5 crystallizes in the monoclinic P2_1/c space group. Tb(1) is bonded in a 8-coordinate geometry to one O(4), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. W(1) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to two equivalent Tb(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Tb(1) and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Tb(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one Tb(1) and one W(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Tb(1) and one W(1) atom. is represented by the CIF card [CIF]
data_TbWO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.894
_cell_length_b   5.299
_cell_length_c   7.031
_cell_angle_alpha   63.163
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   428.602
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.556  0.638  0.217  1.0
  Tb  Tb1  1  0.444  0.362  0.783  1.0
  Tb  Tb2  1  0.056  0.362  0.283  1.0
  Tb  Tb3  1  0.944  0.638  0.717  1.0
  W  W4  1  0.861  0.884  0.156  1.0
  W  W5  1  0.139  0.116  0.844  1.0
  W  W6  1  0.361  0.116  0.344  1.0
  W  W7  1  0.639  0.884  0.656  1.0
  O  O8  1  0.911  0.526  0.432  1.0
  O  O9  1  0.089  0.474  0.568  1.0
  O  O10  1  0.411  0.474  0.068  1.0
  O  O11  1  0.589  0.526  0.932  1.0
  O  O12  1  0.430  0.993  0.158  1.0
  O  O13  1  0.570  0.007  0.842  1.0
  O  O14  1  0.930  0.007  0.342  1.0
  O  O15  1  0.070  0.993  0.658  1.0
  O  O16  1  0.932  0.690  0.030  1.0
  O  O17  1  0.068  0.310  0.970  1.0
  O  O18  1  0.432  0.310  0.470  1.0
  O  O19  1  0.568  0.690  0.530  1.0
  O  O20  1  0.726  0.793  0.205  1.0
  O  O21  1  0.274  0.207  0.795  1.0
  O  O22  1  0.226  0.207  0.295  1.0
  O  O23  1  0.774  0.793  0.705  1.0
  O  O24  1  0.143  0.772  0.074  1.0
  O  O25  1  0.857  0.228  0.926  1.0
  O  O26  1  0.643  0.228  0.426  1.0
  O  O27  1  0.357  0.772  0.574  1.0
[/CIF]
.