The crystal structure described by Rb4V5CdO15Cl crystallizes in the tetragonal P4 space group. Rb(1) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(3), two equivalent O(5), three equivalent O(1), and one Cl(1) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form VO4 tetrahedra that share  a cornercorner with one Cd(1)ClO4 square pyramid,  a cornercorner with one V(1)O4 tetrahedra, and  a cornercorner with one V(2)O5 trigonal bipyramid. In the second V site, V(2) is bonded to one O(4) and four equivalent O(5) atoms to form distorted corner-sharing VO5 trigonal bipyramids. Cd(1) is bonded to four equivalent O(3) and one Cl(1) atom to form distorted CdClO4 square pyramids that share corners with four equivalent V(1)O4 tetrahedra. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Rb(1) and two equivalent V(1) atoms. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Rb(1), one V(1), and one Cd(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one V(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to two equivalent Rb(1), one V(1), and one V(2) atom. Cl(1) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one Cd(1) atom. is represented by the CIF file [CIF]
data_Rb4V5CdClO15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.287
_cell_length_b   9.287
_cell_length_c   5.786
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   499.034
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.676  0.835  0.938  1.0
  Rb  Rb1  1  0.165  0.676  0.938  1.0
  Rb  Rb2  1  0.324  0.165  0.938  1.0
  Rb  Rb3  1  0.835  0.324  0.938  1.0
  V  V4  1  0.618  0.143  0.461  1.0
  V  V5  1  0.143  0.382  0.461  1.0
  V  V6  1  0.382  0.857  0.461  1.0
  V  V7  1  0.500  0.500  0.489  1.0
  V  V8  1  0.857  0.618  0.461  1.0
  Cd  Cd9  1  0.000  0.000  0.490  1.0
  Cl  Cl10  1  0.000  0.000  0.044  1.0
  O  O11  1  0.143  0.385  0.173  1.0
  O  O12  1  0.000  0.500  0.572  1.0
  O  O13  1  0.787  0.112  0.562  1.0
  O  O14  1  0.112  0.213  0.562  1.0
  O  O15  1  0.615  0.143  0.173  1.0
  O  O16  1  0.500  0.500  0.208  1.0
  O  O17  1  0.213  0.888  0.562  1.0
  O  O18  1  0.446  0.690  0.576  1.0
  O  O19  1  0.690  0.554  0.576  1.0
  O  O20  1  0.310  0.446  0.576  1.0
  O  O21  1  0.500  0.000  0.572  1.0
  O  O22  1  0.385  0.857  0.173  1.0
  O  O23  1  0.888  0.787  0.562  1.0
  O  O24  1  0.857  0.615  0.173  1.0
  O  O25  1  0.554  0.310  0.576  1.0
[/CIF]
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The crystal structure described by Rb4V5CdO15Cl crystallizes in the tetragonal P4 space group. Rb(1) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(3), two equivalent O(5), three equivalent O(1), and one Cl(1) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form VO4 tetrahedra that share  a cornercorner with one Cd(1)ClO4 square pyramid,  a cornercorner with one V(1)O4 tetrahedra, and  a cornercorner with one V(2)O5 trigonal bipyramid. In the second V site, V(2) is bonded to one O(4) and four equivalent O(5) atoms to form distorted corner-sharing VO5 trigonal bipyramids. Cd(1) is bonded to four equivalent O(3) and one Cl(1) atom to form distorted CdClO4 square pyramids that share corners with four equivalent V(1)O4 tetrahedra. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Rb(1) and two equivalent V(1) atoms. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Rb(1), one V(1), and one Cd(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one V(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to two equivalent Rb(1), one V(1), and one V(2) atom. Cl(1) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one Cd(1) atom. is represented by the CIF file [CIF]
data_Rb4V5CdClO15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.287
_cell_length_b   9.287
_cell_length_c   5.786
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   499.034
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.676  0.835  0.938  1.0
  Rb  Rb1  1  0.165  0.676  0.938  1.0
  Rb  Rb2  1  0.324  0.165  0.938  1.0
  Rb  Rb3  1  0.835  0.324  0.938  1.0
  V  V4  1  0.618  0.143  0.461  1.0
  V  V5  1  0.143  0.382  0.461  1.0
  V  V6  1  0.382  0.857  0.461  1.0
  V  V7  1  0.500  0.500  0.489  1.0
  V  V8  1  0.857  0.618  0.461  1.0
  Cd  Cd9  1  0.000  0.000  0.490  1.0
  Cl  Cl10  1  0.000  0.000  0.044  1.0
  O  O11  1  0.143  0.385  0.173  1.0
  O  O12  1  0.000  0.500  0.572  1.0
  O  O13  1  0.787  0.112  0.562  1.0
  O  O14  1  0.112  0.213  0.562  1.0
  O  O15  1  0.615  0.143  0.173  1.0
  O  O16  1  0.500  0.500  0.208  1.0
  O  O17  1  0.213  0.888  0.562  1.0
  O  O18  1  0.446  0.690  0.576  1.0
  O  O19  1  0.690  0.554  0.576  1.0
  O  O20  1  0.310  0.446  0.576  1.0
  O  O21  1  0.500  0.000  0.572  1.0
  O  O22  1  0.385  0.857  0.173  1.0
  O  O23  1  0.888  0.787  0.562  1.0
  O  O24  1  0.857  0.615  0.173  1.0
  O  O25  1  0.554  0.310  0.576  1.0
[/CIF]
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