The compound described by PtS6N2 is Indium-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is zero-dimensional and consists of four ammonia atoms and two PtS6 clusters. In each PtS6 cluster, Pt(1) is bonded in a square co-planar geometry to four equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to two equivalent S(2) atoms. In the second S site, S(2) is bonded in an L-shaped geometry to one Pt(1) and one S(1) atom. is represented by the CIF card [CIF]
data_Pt(S3N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.559
_cell_length_b   9.559
_cell_length_c   5.375
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   135.991
_symmetry_Int_Tables_number   1
_cell_volume   341.264
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.000  0.000  0.000  1.0
  S  S1  1  0.823  0.177  0.000  1.0
  S  S2  1  0.306  0.108  0.000  1.0
  S  S3  1  0.892  0.694  0.000  1.0
  S  S4  1  0.177  0.823  0.000  1.0
  S  S5  1  0.694  0.892  0.000  1.0
  S  S6  1  0.108  0.306  0.000  1.0
  N  N7  1  0.666  0.334  0.500  1.0
  N  N8  1  0.334  0.666  0.500  1.0
[/CIF]
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The compound described by PtS6N2 is Indium-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is zero-dimensional and consists of four ammonia atoms and two PtS6 clusters. In each PtS6 cluster, Pt(1) is bonded in a square co-planar geometry to four equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to two equivalent S(2) atoms. In the second S site, S(2) is bonded in an L-shaped geometry to one Pt(1) and one S(1) atom. is represented by the CIF card [CIF]
data_Pt(S3N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.559
_cell_length_b   9.559
_cell_length_c   5.375
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   135.991
_symmetry_Int_Tables_number   1
_cell_volume   341.264
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.000  0.000  0.000  1.0
  S  S1  1  0.823  0.177  0.000  1.0
  S  S2  1  0.306  0.108  0.000  1.0
  S  S3  1  0.892  0.694  0.000  1.0
  S  S4  1  0.177  0.823  0.000  1.0
  S  S5  1  0.694  0.892  0.000  1.0
  S  S6  1  0.108  0.306  0.000  1.0
  N  N7  1  0.666  0.334  0.500  1.0
  N  N8  1  0.334  0.666  0.500  1.0
[/CIF]
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