The material structure described by TbAgC2H2SO9 crystallizes in the monoclinic C2/m space group. Tb(1) is bonded in a 8-coordinate geometry to one O(1), one O(4), one O(6), one O(7), two equivalent O(3), and two equivalent O(5) atoms. Ag(1) is bonded in a 4-coordinate geometry to one O(6), one O(7), and two equivalent O(5) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to two equivalent O(5) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) and one O(2) atom. S(1) is bonded in a tetrahedral geometry to one O(2), one O(4), and two equivalent O(3) atoms. There are seven inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Tb(1) and one S(1) atom. In the second O site, O(4) is bonded in a bent 150 degrees geometry to one Tb(1) and one S(1) atom. In the third O site, O(5) is bonded in a distorted trigonal planar geometry to one Tb(1), one Ag(1), and one C(2) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one Tb(1), one Ag(1), and one C(1) atom. In the fifth O site, O(7) is bonded in a distorted single-bond geometry to one Tb(1), one Ag(1), and one C(1) atom. In the sixth O site, O(1) is bonded in a distorted water-like geometry to one Tb(1), one H(1), and one H(2) atom. In the seventh O site, O(2) is bonded in a distorted linear geometry to one H(2) and one S(1) atom. is represented by the CIF card [CIF]
data_TbAgH2C2SO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.738
_cell_length_b   7.738
_cell_length_c   9.089
_cell_angle_alpha   66.102
_cell_angle_beta   66.102
_cell_angle_gamma   53.409
_symmetry_Int_Tables_number   1
_cell_volume   389.442
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.757  0.757  0.268  1.0
  Tb  Tb1  1  0.243  0.243  0.732  1.0
  Ag  Ag2  1  0.914  0.914  0.668  1.0
  Ag  Ag3  1  0.086  0.086  0.332  1.0
  H  H4  1  0.699  0.699  0.988  1.0
  H  H5  1  0.301  0.301  0.012  1.0
  H  H6  1  0.585  0.585  0.147  1.0
  H  H7  1  0.415  0.415  0.853  1.0
  C  C8  1  0.983  0.983  0.930  1.0
  C  C9  1  0.017  0.017  0.070  1.0
  C  C10  1  0.390  0.610  0.500  1.0
  C  C11  1  0.610  0.390  0.500  1.0
  S  S12  1  0.666  0.666  0.716  1.0
  S  S13  1  0.334  0.334  0.284  1.0
  O  O14  1  0.664  0.664  0.109  1.0
  O  O15  1  0.336  0.336  0.891  1.0
  O  O16  1  0.552  0.552  0.753  1.0
  O  O17  1  0.448  0.448  0.247  1.0
  O  O18  1  0.520  0.865  0.791  1.0
  O  O19  1  0.135  0.480  0.209  1.0
  O  O20  1  0.480  0.135  0.209  1.0
  O  O21  1  0.865  0.520  0.791  1.0
  O  O22  1  0.739  0.739  0.535  1.0
  O  O23  1  0.261  0.261  0.465  1.0
  O  O24  1  0.398  0.783  0.418  1.0
  O  O25  1  0.217  0.602  0.582  1.0
  O  O26  1  0.602  0.217  0.582  1.0
  O  O27  1  0.783  0.398  0.418  1.0
  O  O28  1  0.056  0.056  0.782  1.0
  O  O29  1  0.944  0.944  0.218  1.0
  O  O30  1  0.882  0.882  0.972  1.0
  O  O31  1  0.118  0.118  0.028  1.0
[/CIF]
.
The material structure described by TbAgC2H2SO9 crystallizes in the monoclinic C2/m space group. Tb(1) is bonded in a 8-coordinate geometry to one O(1), one O(4), one O(6), one O(7), two equivalent O(3), and two equivalent O(5) atoms. Ag(1) is bonded in a 4-coordinate geometry to one O(6), one O(7), and two equivalent O(5) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to two equivalent O(5) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) and one O(2) atom. S(1) is bonded in a tetrahedral geometry to one O(2), one O(4), and two equivalent O(3) atoms. There are seven inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Tb(1) and one S(1) atom. In the second O site, O(4) is bonded in a bent 150 degrees geometry to one Tb(1) and one S(1) atom. In the third O site, O(5) is bonded in a distorted trigonal planar geometry to one Tb(1), one Ag(1), and one C(2) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one Tb(1), one Ag(1), and one C(1) atom. In the fifth O site, O(7) is bonded in a distorted single-bond geometry to one Tb(1), one Ag(1), and one C(1) atom. In the sixth O site, O(1) is bonded in a distorted water-like geometry to one Tb(1), one H(1), and one H(2) atom. In the seventh O site, O(2) is bonded in a distorted linear geometry to one H(2) and one S(1) atom. is represented by the CIF card [CIF]
data_TbAgH2C2SO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.738
_cell_length_b   7.738
_cell_length_c   9.089
_cell_angle_alpha   66.102
_cell_angle_beta   66.102
_cell_angle_gamma   53.409
_symmetry_Int_Tables_number   1
_cell_volume   389.442
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.757  0.757  0.268  1.0
  Tb  Tb1  1  0.243  0.243  0.732  1.0
  Ag  Ag2  1  0.914  0.914  0.668  1.0
  Ag  Ag3  1  0.086  0.086  0.332  1.0
  H  H4  1  0.699  0.699  0.988  1.0
  H  H5  1  0.301  0.301  0.012  1.0
  H  H6  1  0.585  0.585  0.147  1.0
  H  H7  1  0.415  0.415  0.853  1.0
  C  C8  1  0.983  0.983  0.930  1.0
  C  C9  1  0.017  0.017  0.070  1.0
  C  C10  1  0.390  0.610  0.500  1.0
  C  C11  1  0.610  0.390  0.500  1.0
  S  S12  1  0.666  0.666  0.716  1.0
  S  S13  1  0.334  0.334  0.284  1.0
  O  O14  1  0.664  0.664  0.109  1.0
  O  O15  1  0.336  0.336  0.891  1.0
  O  O16  1  0.552  0.552  0.753  1.0
  O  O17  1  0.448  0.448  0.247  1.0
  O  O18  1  0.520  0.865  0.791  1.0
  O  O19  1  0.135  0.480  0.209  1.0
  O  O20  1  0.480  0.135  0.209  1.0
  O  O21  1  0.865  0.520  0.791  1.0
  O  O22  1  0.739  0.739  0.535  1.0
  O  O23  1  0.261  0.261  0.465  1.0
  O  O24  1  0.398  0.783  0.418  1.0
  O  O25  1  0.217  0.602  0.582  1.0
  O  O26  1  0.602  0.217  0.582  1.0
  O  O27  1  0.783  0.398  0.418  1.0
  O  O28  1  0.056  0.056  0.782  1.0
  O  O29  1  0.944  0.944  0.218  1.0
  O  O30  1  0.882  0.882  0.972  1.0
  O  O31  1  0.118  0.118  0.028  1.0
[/CIF]
.