The structure described by Rb2Pd(NO3)4 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 10-coordinate geometry to one O(2), one O(4), one O(6), two equivalent O(1), two equivalent O(3), and three equivalent O(5) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(6) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Rb(1), one Pd(1), and one N(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Rb(1) and one N(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one N(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Rb(1), one Pd(1), and one N(2) atom. is represented by the CIF file [CIF]
data_Rb2Pd(NO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.172
_cell_length_b   8.037
_cell_length_c   9.975
_cell_angle_alpha   79.683
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   644.555
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.571  0.341  0.322  1.0
  Rb  Rb1  1  0.429  0.659  0.678  1.0
  Rb  Rb2  1  0.071  0.659  0.178  1.0
  Rb  Rb3  1  0.929  0.341  0.822  1.0
  Pd  Pd4  1  0.000  0.000  0.500  1.0
  Pd  Pd5  1  0.500  0.000  0.000  1.0
  N  N6  1  0.454  0.834  0.284  1.0
  N  N7  1  0.546  0.166  0.716  1.0
  N  N8  1  0.155  0.324  0.518  1.0
  N  N9  1  0.345  0.324  0.018  1.0
  N  N10  1  0.655  0.676  0.982  1.0
  N  N11  1  0.845  0.676  0.482  1.0
  N  N12  1  0.046  0.834  0.784  1.0
  N  N13  1  0.954  0.166  0.216  1.0
  O  O14  1  0.178  0.447  0.576  1.0
  O  O15  1  0.678  0.553  0.924  1.0
  O  O16  1  0.106  0.842  0.659  1.0
  O  O17  1  0.784  0.692  0.593  1.0
  O  O18  1  0.716  0.692  0.093  1.0
  O  O19  1  0.894  0.158  0.341  1.0
  O  O20  1  0.822  0.553  0.424  1.0
  O  O21  1  0.941  0.936  0.807  1.0
  O  O22  1  0.284  0.308  0.907  1.0
  O  O23  1  0.605  0.282  0.629  1.0
  O  O24  1  0.443  0.205  0.084  1.0
  O  O25  1  0.441  0.064  0.693  1.0
  O  O26  1  0.943  0.795  0.416  1.0
  O  O27  1  0.606  0.158  0.841  1.0
  O  O28  1  0.557  0.795  0.916  1.0
  O  O29  1  0.057  0.205  0.584  1.0
  O  O30  1  0.105  0.718  0.871  1.0
  O  O31  1  0.395  0.718  0.371  1.0
  O  O32  1  0.895  0.282  0.129  1.0
  O  O33  1  0.059  0.064  0.193  1.0
  O  O34  1  0.559  0.936  0.307  1.0
  O  O35  1  0.216  0.308  0.407  1.0
  O  O36  1  0.322  0.447  0.076  1.0
  O  O37  1  0.394  0.842  0.159  1.0
[/CIF]
.
The structure described by Rb2Pd(NO3)4 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 10-coordinate geometry to one O(2), one O(4), one O(6), two equivalent O(1), two equivalent O(3), and three equivalent O(5) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(6) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Rb(1), one Pd(1), and one N(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one N(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Rb(1) and one N(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one N(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Rb(1), one Pd(1), and one N(2) atom. is represented by the CIF file [CIF]
data_Rb2Pd(NO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.172
_cell_length_b   8.037
_cell_length_c   9.975
_cell_angle_alpha   79.683
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   644.555
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.571  0.341  0.322  1.0
  Rb  Rb1  1  0.429  0.659  0.678  1.0
  Rb  Rb2  1  0.071  0.659  0.178  1.0
  Rb  Rb3  1  0.929  0.341  0.822  1.0
  Pd  Pd4  1  0.000  0.000  0.500  1.0
  Pd  Pd5  1  0.500  0.000  0.000  1.0
  N  N6  1  0.454  0.834  0.284  1.0
  N  N7  1  0.546  0.166  0.716  1.0
  N  N8  1  0.155  0.324  0.518  1.0
  N  N9  1  0.345  0.324  0.018  1.0
  N  N10  1  0.655  0.676  0.982  1.0
  N  N11  1  0.845  0.676  0.482  1.0
  N  N12  1  0.046  0.834  0.784  1.0
  N  N13  1  0.954  0.166  0.216  1.0
  O  O14  1  0.178  0.447  0.576  1.0
  O  O15  1  0.678  0.553  0.924  1.0
  O  O16  1  0.106  0.842  0.659  1.0
  O  O17  1  0.784  0.692  0.593  1.0
  O  O18  1  0.716  0.692  0.093  1.0
  O  O19  1  0.894  0.158  0.341  1.0
  O  O20  1  0.822  0.553  0.424  1.0
  O  O21  1  0.941  0.936  0.807  1.0
  O  O22  1  0.284  0.308  0.907  1.0
  O  O23  1  0.605  0.282  0.629  1.0
  O  O24  1  0.443  0.205  0.084  1.0
  O  O25  1  0.441  0.064  0.693  1.0
  O  O26  1  0.943  0.795  0.416  1.0
  O  O27  1  0.606  0.158  0.841  1.0
  O  O28  1  0.557  0.795  0.916  1.0
  O  O29  1  0.057  0.205  0.584  1.0
  O  O30  1  0.105  0.718  0.871  1.0
  O  O31  1  0.395  0.718  0.371  1.0
  O  O32  1  0.895  0.282  0.129  1.0
  O  O33  1  0.059  0.064  0.193  1.0
  O  O34  1  0.559  0.936  0.307  1.0
  O  O35  1  0.216  0.308  0.407  1.0
  O  O36  1  0.322  0.447  0.076  1.0
  O  O37  1  0.394  0.842  0.159  1.0
[/CIF]
.