The material described by SnO4Cl3 is alpha structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two SnO4Cl3 clusters. Sn(1) is bonded in a 6-coordinate geometry to one O(2), two equivalent O(1), one Cl(1), one Cl(2), and one Cl(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to two equivalent Sn(1) and one O(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Sn(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one O(1) and one O(4) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the CIF file [CIF]
data_SnCl3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.653
_cell_length_b   10.085
_cell_length_c   15.767
_cell_angle_alpha   54.464
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   860.909
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.538  0.836  0.495  1.0
  Sn  Sn1  1  0.962  0.836  0.995  1.0
  Sn  Sn2  1  0.462  0.164  0.505  1.0
  Sn  Sn3  1  0.038  0.164  0.005  1.0
  Cl  Cl4  1  0.384  0.942  0.334  1.0
  Cl  Cl5  1  0.116  0.942  0.834  1.0
  Cl  Cl6  1  0.616  0.058  0.666  1.0
  Cl  Cl7  1  0.884  0.058  0.166  1.0
  Cl  Cl8  1  0.858  0.729  0.484  1.0
  Cl  Cl9  1  0.642  0.729  0.984  1.0
  Cl  Cl10  1  0.142  0.271  0.516  1.0
  Cl  Cl11  1  0.358  0.271  0.016  1.0
  Cl  Cl12  1  0.386  0.563  0.606  1.0
  Cl  Cl13  1  0.114  0.563  0.106  1.0
  Cl  Cl14  1  0.614  0.437  0.394  1.0
  Cl  Cl15  1  0.886  0.437  0.894  1.0
  O  O16  1  0.671  0.055  0.459  1.0
  O  O17  1  0.829  0.055  0.959  1.0
  O  O18  1  0.329  0.945  0.541  1.0
  O  O19  1  0.171  0.945  0.041  1.0
  O  O20  1  0.670  0.685  0.644  1.0
  O  O21  1  0.830  0.685  0.144  1.0
  O  O22  1  0.330  0.315  0.356  1.0
  O  O23  1  0.170  0.315  0.856  1.0
  O  O24  1  0.803  0.171  0.337  1.0
  O  O25  1  0.697  0.171  0.837  1.0
  O  O26  1  0.197  0.829  0.663  1.0
  O  O27  1  0.303  0.829  0.163  1.0
  O  O28  1  0.707  0.277  0.262  1.0
  O  O29  1  0.793  0.277  0.762  1.0
  O  O30  1  0.293  0.723  0.738  1.0
  O  O31  1  0.207  0.723  0.238  1.0
[/CIF]
.
The material described by SnO4Cl3 is alpha structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two SnO4Cl3 clusters. Sn(1) is bonded in a 6-coordinate geometry to one O(2), two equivalent O(1), one Cl(1), one Cl(2), and one Cl(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to two equivalent Sn(1) and one O(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Sn(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one O(1) and one O(4) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the CIF file [CIF]
data_SnCl3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.653
_cell_length_b   10.085
_cell_length_c   15.767
_cell_angle_alpha   54.464
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   860.909
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.538  0.836  0.495  1.0
  Sn  Sn1  1  0.962  0.836  0.995  1.0
  Sn  Sn2  1  0.462  0.164  0.505  1.0
  Sn  Sn3  1  0.038  0.164  0.005  1.0
  Cl  Cl4  1  0.384  0.942  0.334  1.0
  Cl  Cl5  1  0.116  0.942  0.834  1.0
  Cl  Cl6  1  0.616  0.058  0.666  1.0
  Cl  Cl7  1  0.884  0.058  0.166  1.0
  Cl  Cl8  1  0.858  0.729  0.484  1.0
  Cl  Cl9  1  0.642  0.729  0.984  1.0
  Cl  Cl10  1  0.142  0.271  0.516  1.0
  Cl  Cl11  1  0.358  0.271  0.016  1.0
  Cl  Cl12  1  0.386  0.563  0.606  1.0
  Cl  Cl13  1  0.114  0.563  0.106  1.0
  Cl  Cl14  1  0.614  0.437  0.394  1.0
  Cl  Cl15  1  0.886  0.437  0.894  1.0
  O  O16  1  0.671  0.055  0.459  1.0
  O  O17  1  0.829  0.055  0.959  1.0
  O  O18  1  0.329  0.945  0.541  1.0
  O  O19  1  0.171  0.945  0.041  1.0
  O  O20  1  0.670  0.685  0.644  1.0
  O  O21  1  0.830  0.685  0.144  1.0
  O  O22  1  0.330  0.315  0.356  1.0
  O  O23  1  0.170  0.315  0.856  1.0
  O  O24  1  0.803  0.171  0.337  1.0
  O  O25  1  0.697  0.171  0.837  1.0
  O  O26  1  0.197  0.829  0.663  1.0
  O  O27  1  0.303  0.829  0.163  1.0
  O  O28  1  0.707  0.277  0.262  1.0
  O  O29  1  0.793  0.277  0.762  1.0
  O  O30  1  0.293  0.723  0.738  1.0
  O  O31  1  0.207  0.723  0.238  1.0
[/CIF]
.