The compound described by Tc2C6NO8C2N is beta-prime cadmium gold structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of two aziridine molecules and two Tc2C6NO8 clusters. In each Tc2C6NO8 cluster, Tc(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one O(2) atom. In the second C site, C(2) is bonded in a water-like geometry to one C(1) and one C(2) atom. In the third C site, C(4) is bonded in a distorted single-bond geometry to one O(4) atom. N(1) is bonded in a water-like geometry to two equivalent C(1) atoms. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Tc(1) atom. In the second O site, O(4) is bonded in a bent 150 degrees geometry to one Tc(1) and one C(4) atom. In the third O site, O(1) is bonded in a single-bond geometry to one Tc(1) atom. In the fourth O site, O(2) is bonded in a bent 150 degrees geometry to one Tc(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TcC4NO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.521
_cell_length_b   10.070
_cell_length_c   11.903
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   661.722
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  0.592  0.269  0.757  1.0
  Tc  Tc1  1  0.592  0.731  0.243  1.0
  Tc  Tc2  1  0.408  0.231  0.257  1.0
  Tc  Tc3  1  0.408  0.769  0.743  1.0
  C  C4  1  0.863  0.538  0.083  1.0
  C  C5  1  0.863  0.462  0.917  1.0
  C  C6  1  0.137  0.962  0.583  1.0
  C  C7  1  0.137  0.038  0.417  1.0
  C  C8  1  0.116  0.499  0.947  1.0
  C  C9  1  0.116  0.501  0.053  1.0
  C  C10  1  0.884  0.001  0.447  1.0
  C  C11  1  0.884  0.999  0.553  1.0
  C  C12  1  0.094  0.428  0.539  1.0
  C  C13  1  0.094  0.572  0.461  1.0
  C  C14  1  0.906  0.072  0.039  1.0
  C  C15  1  0.906  0.928  0.961  1.0
  C  C16  1  0.178  0.441  0.419  1.0
  C  C17  1  0.178  0.559  0.581  1.0
  C  C18  1  0.822  0.059  0.919  1.0
  C  C19  1  0.822  0.941  0.081  1.0
  N  N20  1  0.707  0.500  0.000  1.0
  N  N21  1  0.293  0.000  0.500  1.0
  N  N22  1  0.873  0.500  0.500  1.0
  N  N23  1  0.127  0.000  0.000  1.0
  O  O24  1  0.297  0.286  0.797  1.0
  O  O25  1  0.297  0.714  0.203  1.0
  O  O26  1  0.703  0.214  0.297  1.0
  O  O27  1  0.703  0.786  0.703  1.0
  O  O28  1  0.805  0.403  0.826  1.0
  O  O29  1  0.805  0.597  0.174  1.0
  O  O30  1  0.195  0.097  0.326  1.0
  O  O31  1  0.195  0.903  0.674  1.0
  O  O32  1  0.662  0.255  0.618  1.0
  O  O33  1  0.662  0.745  0.382  1.0
  O  O34  1  0.338  0.245  0.118  1.0
  O  O35  1  0.338  0.755  0.882  1.0
  O  O36  1  0.791  0.118  0.828  1.0
  O  O37  1  0.791  0.882  0.172  1.0
  O  O38  1  0.209  0.382  0.328  1.0
  O  O39  1  0.209  0.618  0.672  1.0
[/CIF]
.
The compound described by Tc2C6NO8C2N is beta-prime cadmium gold structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of two aziridine molecules and two Tc2C6NO8 clusters. In each Tc2C6NO8 cluster, Tc(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one O(2) atom. In the second C site, C(2) is bonded in a water-like geometry to one C(1) and one C(2) atom. In the third C site, C(4) is bonded in a distorted single-bond geometry to one O(4) atom. N(1) is bonded in a water-like geometry to two equivalent C(1) atoms. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Tc(1) atom. In the second O site, O(4) is bonded in a bent 150 degrees geometry to one Tc(1) and one C(4) atom. In the third O site, O(1) is bonded in a single-bond geometry to one Tc(1) atom. In the fourth O site, O(2) is bonded in a bent 150 degrees geometry to one Tc(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TcC4NO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.521
_cell_length_b   10.070
_cell_length_c   11.903
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   661.722
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  0.592  0.269  0.757  1.0
  Tc  Tc1  1  0.592  0.731  0.243  1.0
  Tc  Tc2  1  0.408  0.231  0.257  1.0
  Tc  Tc3  1  0.408  0.769  0.743  1.0
  C  C4  1  0.863  0.538  0.083  1.0
  C  C5  1  0.863  0.462  0.917  1.0
  C  C6  1  0.137  0.962  0.583  1.0
  C  C7  1  0.137  0.038  0.417  1.0
  C  C8  1  0.116  0.499  0.947  1.0
  C  C9  1  0.116  0.501  0.053  1.0
  C  C10  1  0.884  0.001  0.447  1.0
  C  C11  1  0.884  0.999  0.553  1.0
  C  C12  1  0.094  0.428  0.539  1.0
  C  C13  1  0.094  0.572  0.461  1.0
  C  C14  1  0.906  0.072  0.039  1.0
  C  C15  1  0.906  0.928  0.961  1.0
  C  C16  1  0.178  0.441  0.419  1.0
  C  C17  1  0.178  0.559  0.581  1.0
  C  C18  1  0.822  0.059  0.919  1.0
  C  C19  1  0.822  0.941  0.081  1.0
  N  N20  1  0.707  0.500  0.000  1.0
  N  N21  1  0.293  0.000  0.500  1.0
  N  N22  1  0.873  0.500  0.500  1.0
  N  N23  1  0.127  0.000  0.000  1.0
  O  O24  1  0.297  0.286  0.797  1.0
  O  O25  1  0.297  0.714  0.203  1.0
  O  O26  1  0.703  0.214  0.297  1.0
  O  O27  1  0.703  0.786  0.703  1.0
  O  O28  1  0.805  0.403  0.826  1.0
  O  O29  1  0.805  0.597  0.174  1.0
  O  O30  1  0.195  0.097  0.326  1.0
  O  O31  1  0.195  0.903  0.674  1.0
  O  O32  1  0.662  0.255  0.618  1.0
  O  O33  1  0.662  0.745  0.382  1.0
  O  O34  1  0.338  0.245  0.118  1.0
  O  O35  1  0.338  0.755  0.882  1.0
  O  O36  1  0.791  0.118  0.828  1.0
  O  O37  1  0.791  0.882  0.172  1.0
  O  O38  1  0.209  0.382  0.328  1.0
  O  O39  1  0.209  0.618  0.672  1.0
[/CIF]
.