The compound described by Re(SeCl6)2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Re(SeCl6)2 cluster. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in an octahedral geometry to one Cl(14), one Cl(17), one Cl(20), one Cl(24), one Cl(6), and one Cl(8) atom. In the second Re site, Re(2) is bonded in an octahedral geometry to one Cl(10), one Cl(2), one Cl(21), one Cl(3), one Cl(4), and one Cl(7) atom. There are four inequivalent Se sites. In the first Se site, Se(1) is bonded in a 3-coordinate geometry to one Cl(12), one Cl(13), one Cl(23), and one Cl(8) atom. In the second Se site, Se(2) is bonded in a 5-coordinate geometry to one Cl(14), one Cl(18), one Cl(24), one Cl(5), and one Cl(9) atom. In the third Se site, Se(3) is bonded in a 3-coordinate geometry to one Cl(1), one Cl(11), one Cl(21), and one Cl(22) atom. In the fourth Se site, Se(4) is bonded in a 6-coordinate geometry to one Cl(10), one Cl(15), one Cl(16), one Cl(17), one Cl(19), and one Cl(4) atom. There are twenty-four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Se(3) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Re(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(2) atom. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to one Re(2) and one Se(4) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Se(2) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Re(1) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one Re(2) atom. In the eighth Cl site, Cl(8) is bonded in a distorted water-like geometry to one Re(1) and one Se(1) atom. In the ninth Cl site, Cl(9) is bonded in a single-bond geometry to one Se(2) atom. In the tenth Cl site, Cl(10) is bonded in a distorted single-bond geometry to one Re(2) and one Se(4) atom. In the eleventh Cl site, Cl(11) is bonded in a single-bond geometry to one Se(3) atom. In the twelfth Cl site, Cl(12) is bonded in a single-bond geometry to one Se(1) atom. In the thirteenth Cl site, Cl(13) is bonded in a single-bond geometry to one Se(1) atom. In the fourteenth Cl site, Cl(14) is bonded in a water-like geometry to one Re(1) and one Se(2) atom. In the fifteenth Cl site, Cl(15) is bonded in a single-bond geometry to one Se(4) atom. In the sixteenth Cl site, Cl(16) is bonded in a single-bond geometry to one Se(4) atom. In the seventeenth Cl site, Cl(17) is bonded in a distorted single-bond geometry to one Re(1) and one Se(4) atom. In the eighteenth Cl site, Cl(18) is bonded in a single-bond geometry to one Se(2) atom. In the nineteenth Cl site, Cl(19) is bonded in a single-bond geometry to one Se(4) atom. In the twentieth Cl site, Cl(20) is bonded in a single-bond geometry to one Re(1) atom. In the twenty-first Cl site, Cl(21) is bonded in a distorted water-like geometry to one Re(2) and one Se(3) atom. In the twenty-second Cl site, Cl(22) is bonded in a single-bond geometry to one Se(3) atom. In the twenty-third Cl site, Cl(23) is bonded in a single-bond geometry to one Se(1) atom. In the twenty-fourth Cl site, Cl(24) is bonded in a distorted water-like geometry to one Re(1) and one Se(2) atom. is represented by the CIF file [CIF]
data_Re(SeCl6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.724
_cell_length_b   12.503
_cell_length_c   8.863
_cell_angle_alpha   70.781
_cell_angle_beta   68.096
_cell_angle_gamma   41.123
_symmetry_Int_Tables_number   1
_cell_volume   857.653
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.917  0.923  0.575  1.0
  Re  Re1  1  0.674  0.665  0.327  1.0
  Se  Se2  1  0.729  0.274  0.217  1.0
  Se  Se3  1  0.268  0.735  0.779  1.0
  Se  Se4  1  0.035  0.473  0.513  1.0
  Se  Se5  1  0.474  0.033  0.978  1.0
  Cl  Cl6  1  0.124  0.230  0.536  1.0
  Cl  Cl7  1  0.929  0.564  0.219  1.0
  Cl  Cl8  1  0.407  0.784  0.442  1.0
  Cl  Cl9  1  0.626  0.718  0.067  1.0
  Cl  Cl10  1  0.301  0.856  0.876  1.0
  Cl  Cl11  1  0.036  0.963  0.314  1.0
  Cl  Cl12  1  0.786  0.401  0.367  1.0
  Cl  Cl13  1  0.662  0.180  0.544  1.0
  Cl  Cl14  1  0.513  0.482  0.790  1.0
  Cl  Cl15  1  0.563  0.933  0.292  1.0
  Cl  Cl16  1  0.278  0.379  0.397  1.0
  Cl  Cl17  1  0.852  0.297  0.975  1.0
  Cl  Cl18  1  0.705  0.147  0.135  1.0
  Cl  Cl19  1  0.967  0.027  0.693  1.0
  Cl  Cl20  1  0.469  0.029  0.735  1.0
  Cl  Cl21  1  0.231  0.125  0.108  1.0
  Cl  Cl22  1  0.800  0.891  0.843  1.0
  Cl  Cl23  1  0.150  0.706  0.017  1.0
  Cl  Cl24  1  0.378  0.274  0.948  1.0
  Cl  Cl25  1  0.884  0.810  0.460  1.0
  Cl  Cl26  1  0.710  0.634  0.595  1.0
  Cl  Cl27  1  0.030  0.461  0.772  1.0
  Cl  Cl28  1  0.474  0.519  0.222  1.0
  Cl  Cl29  1  0.184  0.659  0.613  1.0
[/CIF]
.
The compound described by Re(SeCl6)2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Re(SeCl6)2 cluster. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in an octahedral geometry to one Cl(14), one Cl(17), one Cl(20), one Cl(24), one Cl(6), and one Cl(8) atom. In the second Re site, Re(2) is bonded in an octahedral geometry to one Cl(10), one Cl(2), one Cl(21), one Cl(3), one Cl(4), and one Cl(7) atom. There are four inequivalent Se sites. In the first Se site, Se(1) is bonded in a 3-coordinate geometry to one Cl(12), one Cl(13), one Cl(23), and one Cl(8) atom. In the second Se site, Se(2) is bonded in a 5-coordinate geometry to one Cl(14), one Cl(18), one Cl(24), one Cl(5), and one Cl(9) atom. In the third Se site, Se(3) is bonded in a 3-coordinate geometry to one Cl(1), one Cl(11), one Cl(21), and one Cl(22) atom. In the fourth Se site, Se(4) is bonded in a 6-coordinate geometry to one Cl(10), one Cl(15), one Cl(16), one Cl(17), one Cl(19), and one Cl(4) atom. There are twenty-four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Se(3) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Re(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(2) atom. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to one Re(2) and one Se(4) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Se(2) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Re(1) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one Re(2) atom. In the eighth Cl site, Cl(8) is bonded in a distorted water-like geometry to one Re(1) and one Se(1) atom. In the ninth Cl site, Cl(9) is bonded in a single-bond geometry to one Se(2) atom. In the tenth Cl site, Cl(10) is bonded in a distorted single-bond geometry to one Re(2) and one Se(4) atom. In the eleventh Cl site, Cl(11) is bonded in a single-bond geometry to one Se(3) atom. In the twelfth Cl site, Cl(12) is bonded in a single-bond geometry to one Se(1) atom. In the thirteenth Cl site, Cl(13) is bonded in a single-bond geometry to one Se(1) atom. In the fourteenth Cl site, Cl(14) is bonded in a water-like geometry to one Re(1) and one Se(2) atom. In the fifteenth Cl site, Cl(15) is bonded in a single-bond geometry to one Se(4) atom. In the sixteenth Cl site, Cl(16) is bonded in a single-bond geometry to one Se(4) atom. In the seventeenth Cl site, Cl(17) is bonded in a distorted single-bond geometry to one Re(1) and one Se(4) atom. In the eighteenth Cl site, Cl(18) is bonded in a single-bond geometry to one Se(2) atom. In the nineteenth Cl site, Cl(19) is bonded in a single-bond geometry to one Se(4) atom. In the twentieth Cl site, Cl(20) is bonded in a single-bond geometry to one Re(1) atom. In the twenty-first Cl site, Cl(21) is bonded in a distorted water-like geometry to one Re(2) and one Se(3) atom. In the twenty-second Cl site, Cl(22) is bonded in a single-bond geometry to one Se(3) atom. In the twenty-third Cl site, Cl(23) is bonded in a single-bond geometry to one Se(1) atom. In the twenty-fourth Cl site, Cl(24) is bonded in a distorted water-like geometry to one Re(1) and one Se(2) atom. is represented by the CIF file [CIF]
data_Re(SeCl6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.724
_cell_length_b   12.503
_cell_length_c   8.863
_cell_angle_alpha   70.781
_cell_angle_beta   68.096
_cell_angle_gamma   41.123
_symmetry_Int_Tables_number   1
_cell_volume   857.653
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.917  0.923  0.575  1.0
  Re  Re1  1  0.674  0.665  0.327  1.0
  Se  Se2  1  0.729  0.274  0.217  1.0
  Se  Se3  1  0.268  0.735  0.779  1.0
  Se  Se4  1  0.035  0.473  0.513  1.0
  Se  Se5  1  0.474  0.033  0.978  1.0
  Cl  Cl6  1  0.124  0.230  0.536  1.0
  Cl  Cl7  1  0.929  0.564  0.219  1.0
  Cl  Cl8  1  0.407  0.784  0.442  1.0
  Cl  Cl9  1  0.626  0.718  0.067  1.0
  Cl  Cl10  1  0.301  0.856  0.876  1.0
  Cl  Cl11  1  0.036  0.963  0.314  1.0
  Cl  Cl12  1  0.786  0.401  0.367  1.0
  Cl  Cl13  1  0.662  0.180  0.544  1.0
  Cl  Cl14  1  0.513  0.482  0.790  1.0
  Cl  Cl15  1  0.563  0.933  0.292  1.0
  Cl  Cl16  1  0.278  0.379  0.397  1.0
  Cl  Cl17  1  0.852  0.297  0.975  1.0
  Cl  Cl18  1  0.705  0.147  0.135  1.0
  Cl  Cl19  1  0.967  0.027  0.693  1.0
  Cl  Cl20  1  0.469  0.029  0.735  1.0
  Cl  Cl21  1  0.231  0.125  0.108  1.0
  Cl  Cl22  1  0.800  0.891  0.843  1.0
  Cl  Cl23  1  0.150  0.706  0.017  1.0
  Cl  Cl24  1  0.378  0.274  0.948  1.0
  Cl  Cl25  1  0.884  0.810  0.460  1.0
  Cl  Cl26  1  0.710  0.634  0.595  1.0
  Cl  Cl27  1  0.030  0.461  0.772  1.0
  Cl  Cl28  1  0.474  0.519  0.222  1.0
  Cl  Cl29  1  0.184  0.659  0.613  1.0
[/CIF]
.