The compound described by C3NH10Br is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two trimethylazanium;hydrobromide molecules. There are two inequivalent C sites. In the first C site, C(1) is bonded to one N(1) and three equivalent H(2,3) atoms to form corner-sharing CH3N tetrahedra. In the second C site, C(2) is bonded to one N(1), one H(4), one H(5), and one H(6) atom to form corner-sharing CH3N tetrahedra. N(1) is bonded in a tetrahedral geometry to one C(1), two equivalent C(2), and one H(1) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) and one Br(1) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. Br(1) is bonded in a single-bond geometry to one H(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H10C3BrN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.653
_cell_length_b   7.270
_cell_length_c   8.608
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   107.283
_symmetry_Int_Tables_number   1
_cell_volume   337.807
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.706  0.924  0.750  1.0
  H  H1  1  0.294  0.076  0.250  1.0
  H  H2  1  0.833  0.666  0.646  1.0
  H  H3  1  0.167  0.334  0.146  1.0
  H  H4  1  0.167  0.334  0.354  1.0
  H  H5  1  0.833  0.666  0.854  1.0
  H  H6  1  0.587  0.497  0.750  1.0
  H  H7  1  0.413  0.503  0.250  1.0
  H  H8  1  0.286  0.616  0.609  1.0
  H  H9  1  0.714  0.384  0.109  1.0
  H  H10  1  0.714  0.384  0.391  1.0
  H  H11  1  0.286  0.616  0.891  1.0
  H  H12  1  0.317  0.870  0.608  1.0
  H  H13  1  0.683  0.130  0.108  1.0
  H  H14  1  0.683  0.130  0.392  1.0
  H  H15  1  0.317  0.870  0.892  1.0
  H  H16  1  0.537  0.781  0.505  1.0
  H  H17  1  0.463  0.219  0.005  1.0
  H  H18  1  0.463  0.219  0.495  1.0
  H  H19  1  0.537  0.781  0.995  1.0
  C  C20  1  0.717  0.643  0.750  1.0
  C  C21  1  0.283  0.357  0.250  1.0
  C  C22  1  0.417  0.762  0.608  1.0
  C  C23  1  0.583  0.238  0.108  1.0
  C  C24  1  0.583  0.238  0.392  1.0
  C  C25  1  0.417  0.762  0.892  1.0
  Br  Br26  1  0.982  0.819  0.250  1.0
  Br  Br27  1  0.018  0.181  0.750  1.0
  N  N28  1  0.573  0.784  0.750  1.0
  N  N29  1  0.427  0.216  0.250  1.0
[/CIF]
.
The compound described by C3NH10Br is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two trimethylazanium;hydrobromide molecules. There are two inequivalent C sites. In the first C site, C(1) is bonded to one N(1) and three equivalent H(2,3) atoms to form corner-sharing CH3N tetrahedra. In the second C site, C(2) is bonded to one N(1), one H(4), one H(5), and one H(6) atom to form corner-sharing CH3N tetrahedra. N(1) is bonded in a tetrahedral geometry to one C(1), two equivalent C(2), and one H(1) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) and one Br(1) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. Br(1) is bonded in a single-bond geometry to one H(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H10C3BrN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.653
_cell_length_b   7.270
_cell_length_c   8.608
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   107.283
_symmetry_Int_Tables_number   1
_cell_volume   337.807
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.706  0.924  0.750  1.0
  H  H1  1  0.294  0.076  0.250  1.0
  H  H2  1  0.833  0.666  0.646  1.0
  H  H3  1  0.167  0.334  0.146  1.0
  H  H4  1  0.167  0.334  0.354  1.0
  H  H5  1  0.833  0.666  0.854  1.0
  H  H6  1  0.587  0.497  0.750  1.0
  H  H7  1  0.413  0.503  0.250  1.0
  H  H8  1  0.286  0.616  0.609  1.0
  H  H9  1  0.714  0.384  0.109  1.0
  H  H10  1  0.714  0.384  0.391  1.0
  H  H11  1  0.286  0.616  0.891  1.0
  H  H12  1  0.317  0.870  0.608  1.0
  H  H13  1  0.683  0.130  0.108  1.0
  H  H14  1  0.683  0.130  0.392  1.0
  H  H15  1  0.317  0.870  0.892  1.0
  H  H16  1  0.537  0.781  0.505  1.0
  H  H17  1  0.463  0.219  0.005  1.0
  H  H18  1  0.463  0.219  0.495  1.0
  H  H19  1  0.537  0.781  0.995  1.0
  C  C20  1  0.717  0.643  0.750  1.0
  C  C21  1  0.283  0.357  0.250  1.0
  C  C22  1  0.417  0.762  0.608  1.0
  C  C23  1  0.583  0.238  0.108  1.0
  C  C24  1  0.583  0.238  0.392  1.0
  C  C25  1  0.417  0.762  0.892  1.0
  Br  Br26  1  0.982  0.819  0.250  1.0
  Br  Br27  1  0.018  0.181  0.750  1.0
  N  N28  1  0.573  0.784  0.750  1.0
  N  N29  1  0.427  0.216  0.250  1.0
[/CIF]
.