The structure described by NaSbO6 crystallizes in the tetragonal P4_2/n space group. Na(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form NaO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-68°. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with six equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-68°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Na(1), one Sb(1), and one O(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Na(1), one Sb(1), and one O(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Na(1) and one Sb(1) atom. is represented by the CIF file [CIF]
data_NaSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.703
_cell_length_b   8.703
_cell_length_c   6.882
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   521.236
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.250  0.750  0.750  1.0
  Na  Na1  1  0.750  0.250  0.750  1.0
  Na  Na2  1  0.750  0.750  0.250  1.0
  Na  Na3  1  0.250  0.250  0.250  1.0
  Sb  Sb4  1  0.250  0.250  0.750  1.0
  Sb  Sb5  1  0.750  0.750  0.750  1.0
  Sb  Sb6  1  0.250  0.750  0.250  1.0
  Sb  Sb7  1  0.750  0.250  0.250  1.0
  O  O8  1  0.001  0.254  0.909  1.0
  O  O9  1  0.999  0.746  0.909  1.0
  O  O10  1  0.246  0.501  0.409  1.0
  O  O11  1  0.754  0.499  0.409  1.0
  O  O12  1  0.499  0.246  0.591  1.0
  O  O13  1  0.501  0.754  0.591  1.0
  O  O14  1  0.254  0.999  0.091  1.0
  O  O15  1  0.746  0.001  0.091  1.0
  O  O16  1  0.288  0.004  0.902  1.0
  O  O17  1  0.712  0.996  0.902  1.0
  O  O18  1  0.496  0.788  0.402  1.0
  O  O19  1  0.504  0.212  0.402  1.0
  O  O20  1  0.212  0.496  0.598  1.0
  O  O21  1  0.788  0.504  0.598  1.0
  O  O22  1  0.004  0.712  0.098  1.0
  O  O23  1  0.996  0.288  0.098  1.0
  O  O24  1  0.165  0.151  0.541  1.0
  O  O25  1  0.835  0.849  0.541  1.0
  O  O26  1  0.349  0.665  0.041  1.0
  O  O27  1  0.651  0.335  0.041  1.0
  O  O28  1  0.335  0.349  0.959  1.0
  O  O29  1  0.665  0.651  0.959  1.0
  O  O30  1  0.151  0.835  0.459  1.0
  O  O31  1  0.849  0.165  0.459  1.0
[/CIF]
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The structure described by NaSbO6 crystallizes in the tetragonal P4_2/n space group. Na(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form NaO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-68°. Sb(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SbO6 octahedra that share corners with six equivalent Na(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-68°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Na(1), one Sb(1), and one O(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Na(1), one Sb(1), and one O(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Na(1) and one Sb(1) atom. is represented by the CIF file [CIF]
data_NaSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.703
_cell_length_b   8.703
_cell_length_c   6.882
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   521.236
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.250  0.750  0.750  1.0
  Na  Na1  1  0.750  0.250  0.750  1.0
  Na  Na2  1  0.750  0.750  0.250  1.0
  Na  Na3  1  0.250  0.250  0.250  1.0
  Sb  Sb4  1  0.250  0.250  0.750  1.0
  Sb  Sb5  1  0.750  0.750  0.750  1.0
  Sb  Sb6  1  0.250  0.750  0.250  1.0
  Sb  Sb7  1  0.750  0.250  0.250  1.0
  O  O8  1  0.001  0.254  0.909  1.0
  O  O9  1  0.999  0.746  0.909  1.0
  O  O10  1  0.246  0.501  0.409  1.0
  O  O11  1  0.754  0.499  0.409  1.0
  O  O12  1  0.499  0.246  0.591  1.0
  O  O13  1  0.501  0.754  0.591  1.0
  O  O14  1  0.254  0.999  0.091  1.0
  O  O15  1  0.746  0.001  0.091  1.0
  O  O16  1  0.288  0.004  0.902  1.0
  O  O17  1  0.712  0.996  0.902  1.0
  O  O18  1  0.496  0.788  0.402  1.0
  O  O19  1  0.504  0.212  0.402  1.0
  O  O20  1  0.212  0.496  0.598  1.0
  O  O21  1  0.788  0.504  0.598  1.0
  O  O22  1  0.004  0.712  0.098  1.0
  O  O23  1  0.996  0.288  0.098  1.0
  O  O24  1  0.165  0.151  0.541  1.0
  O  O25  1  0.835  0.849  0.541  1.0
  O  O26  1  0.349  0.665  0.041  1.0
  O  O27  1  0.651  0.335  0.041  1.0
  O  O28  1  0.335  0.349  0.959  1.0
  O  O29  1  0.665  0.651  0.959  1.0
  O  O30  1  0.151  0.835  0.459  1.0
  O  O31  1  0.849  0.165  0.459  1.0
[/CIF]
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