The crystal structure described by CuCNH2S2 crystallizes in the orthorhombic P2_12_12_1 space group. Cu(1) is bonded to two equivalent S(1) and two equivalent S(2) atoms to form corner-sharing CuS4 tetrahedra. C(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one S(2) atom. N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to two equivalent Cu(1) and one C(1) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to two equivalent Cu(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CuH2CS2N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.961
_cell_length_b   6.813
_cell_length_c   9.611
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   390.375
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.094  0.740  0.630  1.0
  Cu  Cu1  1  0.406  0.260  0.130  1.0
  Cu  Cu2  1  0.594  0.760  0.370  1.0
  Cu  Cu3  1  0.906  0.240  0.870  1.0
  H  H4  1  0.343  0.871  0.840  1.0
  H  H5  1  0.157  0.129  0.340  1.0
  H  H6  1  0.843  0.629  0.160  1.0
  H  H7  1  0.657  0.371  0.660  1.0
  H  H8  1  0.599  0.946  0.911  1.0
  H  H9  1  0.901  0.054  0.411  1.0
  H  H10  1  0.099  0.554  0.089  1.0
  H  H11  1  0.401  0.446  0.589  1.0
  C  C12  1  0.587  0.938  0.698  1.0
  C  C13  1  0.913  0.062  0.198  1.0
  C  C14  1  0.087  0.562  0.302  1.0
  C  C15  1  0.413  0.438  0.802  1.0
  S  S16  1  0.414  0.892  0.558  1.0
  S  S17  1  0.086  0.108  0.058  1.0
  S  S18  1  0.914  0.608  0.442  1.0
  S  S19  1  0.586  0.392  0.942  1.0
  S  S20  1  0.139  0.522  0.821  1.0
  S  S21  1  0.361  0.478  0.321  1.0
  S  S22  1  0.639  0.978  0.179  1.0
  S  S23  1  0.861  0.022  0.679  1.0
  N  N24  1  0.503  0.918  0.825  1.0
  N  N25  1  0.997  0.082  0.325  1.0
  N  N26  1  0.003  0.582  0.175  1.0
  N  N27  1  0.497  0.418  0.675  1.0
[/CIF]
.
The crystal structure described by CuCNH2S2 crystallizes in the orthorhombic P2_12_12_1 space group. Cu(1) is bonded to two equivalent S(1) and two equivalent S(2) atoms to form corner-sharing CuS4 tetrahedra. C(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one S(2) atom. N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to two equivalent Cu(1) and one C(1) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to two equivalent Cu(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CuH2CS2N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.961
_cell_length_b   6.813
_cell_length_c   9.611
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   390.375
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.094  0.740  0.630  1.0
  Cu  Cu1  1  0.406  0.260  0.130  1.0
  Cu  Cu2  1  0.594  0.760  0.370  1.0
  Cu  Cu3  1  0.906  0.240  0.870  1.0
  H  H4  1  0.343  0.871  0.840  1.0
  H  H5  1  0.157  0.129  0.340  1.0
  H  H6  1  0.843  0.629  0.160  1.0
  H  H7  1  0.657  0.371  0.660  1.0
  H  H8  1  0.599  0.946  0.911  1.0
  H  H9  1  0.901  0.054  0.411  1.0
  H  H10  1  0.099  0.554  0.089  1.0
  H  H11  1  0.401  0.446  0.589  1.0
  C  C12  1  0.587  0.938  0.698  1.0
  C  C13  1  0.913  0.062  0.198  1.0
  C  C14  1  0.087  0.562  0.302  1.0
  C  C15  1  0.413  0.438  0.802  1.0
  S  S16  1  0.414  0.892  0.558  1.0
  S  S17  1  0.086  0.108  0.058  1.0
  S  S18  1  0.914  0.608  0.442  1.0
  S  S19  1  0.586  0.392  0.942  1.0
  S  S20  1  0.139  0.522  0.821  1.0
  S  S21  1  0.361  0.478  0.321  1.0
  S  S22  1  0.639  0.978  0.179  1.0
  S  S23  1  0.861  0.022  0.679  1.0
  N  N24  1  0.503  0.918  0.825  1.0
  N  N25  1  0.997  0.082  0.325  1.0
  N  N26  1  0.003  0.582  0.175  1.0
  N  N27  1  0.497  0.418  0.675  1.0
[/CIF]
.