The crystal structure described by Ag3CS(NO2)3 crystallizes in the triclinic P-1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 2-coordinate geometry to one N(2), one S(1), and one O(5) atom. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to two equivalent S(1), two equivalent O(4), and two equivalent O(6) atoms. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to one N(2), one S(1), one O(1), one O(2), and one O(3) atom. In the fourth Ag site, Ag(4) is bonded in a 6-coordinate geometry to two equivalent S(1), two equivalent O(4), and two equivalent O(5) atoms. C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(5), and one O(6) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(3), and one C(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(4) atom. S(1) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), one Ag(4), and one C(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ag(3) and one N(3) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one N(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Ag(3) and one N(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(2), one Ag(4), and one N(3) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Ag(1), one Ag(4), and one N(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Ag(2) and one N(1) atom. is represented by the CIF file [CIF]
data_Ag3CS(NO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.599
_cell_length_b   7.993
_cell_length_c   8.132
_cell_angle_alpha   105.378
_cell_angle_beta   93.444
_cell_angle_gamma   90.539
_symmetry_Int_Tables_number   1
_cell_volume   412.703
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.449  0.273  0.143  1.0
  Ag  Ag1  1  0.551  0.727  0.857  1.0
  Ag  Ag2  1  0.000  0.000  0.500  1.0
  Ag  Ag3  1  0.027  0.645  0.824  1.0
  Ag  Ag4  1  0.973  0.355  0.176  1.0
  Ag  Ag5  1  0.500  0.000  0.500  1.0
  C  C6  1  0.270  0.611  0.436  1.0
  C  C7  1  0.730  0.389  0.564  1.0
  S  S8  1  0.723  0.216  0.399  1.0
  S  S9  1  0.277  0.784  0.601  1.0
  N  N10  1  0.684  0.676  0.212  1.0
  N  N11  1  0.316  0.324  0.788  1.0
  N  N12  1  0.741  0.514  0.681  1.0
  N  N13  1  0.830  0.064  0.868  1.0
  N  N14  1  0.259  0.486  0.319  1.0
  N  N15  1  0.170  0.936  0.132  1.0
  O  O16  1  0.759  0.050  0.005  1.0
  O  O17  1  0.278  0.461  0.905  1.0
  O  O18  1  0.933  0.196  0.864  1.0
  O  O19  1  0.722  0.539  0.095  1.0
  O  O20  1  0.203  0.061  0.269  1.0
  O  O21  1  0.241  0.950  0.995  1.0
  O  O22  1  0.576  0.791  0.170  1.0
  O  O23  1  0.067  0.804  0.136  1.0
  O  O24  1  0.750  0.695  0.364  1.0
  O  O25  1  0.250  0.305  0.636  1.0
  O  O26  1  0.797  0.939  0.731  1.0
  O  O27  1  0.424  0.209  0.830  1.0
[/CIF]
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The crystal structure described by Ag3CS(NO2)3 crystallizes in the triclinic P-1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 2-coordinate geometry to one N(2), one S(1), and one O(5) atom. In the second Ag site, Ag(2) is bonded in a 6-coordinate geometry to two equivalent S(1), two equivalent O(4), and two equivalent O(6) atoms. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to one N(2), one S(1), one O(1), one O(2), and one O(3) atom. In the fourth Ag site, Ag(4) is bonded in a 6-coordinate geometry to two equivalent S(1), two equivalent O(4), and two equivalent O(5) atoms. C(1) is bonded in a distorted linear geometry to one N(2) and one S(1) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(5), and one O(6) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(3), and one C(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(4) atom. S(1) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), one Ag(4), and one C(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Ag(3) and one N(3) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one N(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Ag(3) and one N(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(2), one Ag(4), and one N(3) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Ag(1), one Ag(4), and one N(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Ag(2) and one N(1) atom. is represented by the CIF file [CIF]
data_Ag3CS(NO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.599
_cell_length_b   7.993
_cell_length_c   8.132
_cell_angle_alpha   105.378
_cell_angle_beta   93.444
_cell_angle_gamma   90.539
_symmetry_Int_Tables_number   1
_cell_volume   412.703
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.449  0.273  0.143  1.0
  Ag  Ag1  1  0.551  0.727  0.857  1.0
  Ag  Ag2  1  0.000  0.000  0.500  1.0
  Ag  Ag3  1  0.027  0.645  0.824  1.0
  Ag  Ag4  1  0.973  0.355  0.176  1.0
  Ag  Ag5  1  0.500  0.000  0.500  1.0
  C  C6  1  0.270  0.611  0.436  1.0
  C  C7  1  0.730  0.389  0.564  1.0
  S  S8  1  0.723  0.216  0.399  1.0
  S  S9  1  0.277  0.784  0.601  1.0
  N  N10  1  0.684  0.676  0.212  1.0
  N  N11  1  0.316  0.324  0.788  1.0
  N  N12  1  0.741  0.514  0.681  1.0
  N  N13  1  0.830  0.064  0.868  1.0
  N  N14  1  0.259  0.486  0.319  1.0
  N  N15  1  0.170  0.936  0.132  1.0
  O  O16  1  0.759  0.050  0.005  1.0
  O  O17  1  0.278  0.461  0.905  1.0
  O  O18  1  0.933  0.196  0.864  1.0
  O  O19  1  0.722  0.539  0.095  1.0
  O  O20  1  0.203  0.061  0.269  1.0
  O  O21  1  0.241  0.950  0.995  1.0
  O  O22  1  0.576  0.791  0.170  1.0
  O  O23  1  0.067  0.804  0.136  1.0
  O  O24  1  0.750  0.695  0.364  1.0
  O  O25  1  0.250  0.305  0.636  1.0
  O  O26  1  0.797  0.939  0.731  1.0
  O  O27  1  0.424  0.209  0.830  1.0
[/CIF]
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