The material structure described by Mn2Pt(CO)12 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Mn2Pt(CO)12 cluster. Mn(1) is bonded to one Pt(1), one C(1), one C(2), one C(3), one C(5), and one C(6) atom to form corner-sharing MnPtC5 square pyramids. Pt(1) is bonded in a distorted square co-planar geometry to two equivalent Mn(1) and two equivalent C(4) atoms. There are six inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(2,5,6) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(1) atom. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(2,5,6) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one Pt(1) and one O(4) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Mn(1) and one O(2,5,6) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Mn(1) and one O(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2,5,6) is bonded in a single-bond geometry to one C(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2Pt(CO)12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.690
_cell_length_b   7.557
_cell_length_c   10.200
_cell_angle_alpha   69.885
_cell_angle_beta   83.846
_cell_angle_gamma   86.105
_symmetry_Int_Tables_number   1
_cell_volume   481.128
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.207  0.113  0.731  1.0
  Mn  Mn1  1  0.793  0.887  0.269  1.0
  Pt  Pt2  1  0.000  0.000  0.000  1.0
  C  C3  1  0.975  0.253  0.670  1.0
  C  C4  1  0.345  0.190  0.559  1.0
  C  C5  1  0.421  0.961  0.814  1.0
  C  C6  1  0.894  0.250  0.967  1.0
  C  C7  1  0.579  0.039  0.186  1.0
  C  C8  1  0.655  0.810  0.441  1.0
  C  C9  1  0.902  0.092  0.293  1.0
  C  C10  1  0.025  0.747  0.330  1.0
  C  C11  1  0.106  0.750  0.033  1.0
  C  C12  1  0.705  0.694  0.217  1.0
  C  C13  1  0.295  0.306  0.783  1.0
  C  C14  1  0.098  0.908  0.707  1.0
  O  O15  1  0.565  0.763  0.550  1.0
  O  O16  1  0.435  0.237  0.450  1.0
  O  O17  1  0.970  0.216  0.313  1.0
  O  O18  1  0.354  0.426  0.813  1.0
  O  O19  1  0.170  0.597  0.054  1.0
  O  O20  1  0.559  0.870  0.862  1.0
  O  O21  1  0.441  0.130  0.138  1.0
  O  O22  1  0.831  0.338  0.627  1.0
  O  O23  1  0.030  0.784  0.687  1.0
  O  O24  1  0.169  0.662  0.373  1.0
  O  O25  1  0.646  0.574  0.187  1.0
  O  O26  1  0.830  0.403  0.946  1.0
[/CIF]
.
The material structure described by Mn2Pt(CO)12 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Mn2Pt(CO)12 cluster. Mn(1) is bonded to one Pt(1), one C(1), one C(2), one C(3), one C(5), and one C(6) atom to form corner-sharing MnPtC5 square pyramids. Pt(1) is bonded in a distorted square co-planar geometry to two equivalent Mn(1) and two equivalent C(4) atoms. There are six inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Mn(1) and one O(2,5,6) atom. In the second C site, C(2) is bonded in a linear geometry to one Mn(1) and one O(1) atom. In the third C site, C(3) is bonded in a linear geometry to one Mn(1) and one O(2,5,6) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one Pt(1) and one O(4) atom. In the fifth C site, C(5) is bonded in a linear geometry to one Mn(1) and one O(2,5,6) atom. In the sixth C site, C(6) is bonded in a linear geometry to one Mn(1) and one O(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(2,5,6) is bonded in a single-bond geometry to one C(5) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn2Pt(CO)12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.690
_cell_length_b   7.557
_cell_length_c   10.200
_cell_angle_alpha   69.885
_cell_angle_beta   83.846
_cell_angle_gamma   86.105
_symmetry_Int_Tables_number   1
_cell_volume   481.128
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.207  0.113  0.731  1.0
  Mn  Mn1  1  0.793  0.887  0.269  1.0
  Pt  Pt2  1  0.000  0.000  0.000  1.0
  C  C3  1  0.975  0.253  0.670  1.0
  C  C4  1  0.345  0.190  0.559  1.0
  C  C5  1  0.421  0.961  0.814  1.0
  C  C6  1  0.894  0.250  0.967  1.0
  C  C7  1  0.579  0.039  0.186  1.0
  C  C8  1  0.655  0.810  0.441  1.0
  C  C9  1  0.902  0.092  0.293  1.0
  C  C10  1  0.025  0.747  0.330  1.0
  C  C11  1  0.106  0.750  0.033  1.0
  C  C12  1  0.705  0.694  0.217  1.0
  C  C13  1  0.295  0.306  0.783  1.0
  C  C14  1  0.098  0.908  0.707  1.0
  O  O15  1  0.565  0.763  0.550  1.0
  O  O16  1  0.435  0.237  0.450  1.0
  O  O17  1  0.970  0.216  0.313  1.0
  O  O18  1  0.354  0.426  0.813  1.0
  O  O19  1  0.170  0.597  0.054  1.0
  O  O20  1  0.559  0.870  0.862  1.0
  O  O21  1  0.441  0.130  0.138  1.0
  O  O22  1  0.831  0.338  0.627  1.0
  O  O23  1  0.030  0.784  0.687  1.0
  O  O24  1  0.169  0.662  0.373  1.0
  O  O25  1  0.646  0.574  0.187  1.0
  O  O26  1  0.830  0.403  0.946  1.0
[/CIF]
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