The material structure described by WBr5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one WBr5 cluster. W(1) is bonded to one Br(2), one Br(3), one Br(4), one Br(5), and two equivalent Br(1) atoms to form edge-sharing WBr6 octahedra. There are five inequivalent Br sites. In the first Br site, Br(1) is bonded in a water-like geometry to two equivalent W(1) atoms. In the second Br site, Br(2) is bonded in a single-bond geometry to one W(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one W(1) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_WBr5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.637
_cell_length_b   7.165
_cell_length_c   9.704
_cell_angle_alpha   109.042
_cell_angle_beta   90.700
_cell_angle_gamma   116.203
_symmetry_Int_Tables_number   1
_cell_volume   384.674
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.899  0.289  0.786  1.0
  W  W1  1  0.101  0.711  0.214  1.0
  Br  Br2  1  0.245  0.689  0.956  1.0
  Br  Br3  1  0.755  0.311  0.044  1.0
  Br  Br4  1  0.568  0.927  0.660  1.0
  Br  Br5  1  0.432  0.073  0.340  1.0
  Br  Br6  1  0.062  0.309  0.566  1.0
  Br  Br7  1  0.938  0.691  0.434  1.0
  Br  Br8  1  0.123  0.132  0.856  1.0
  Br  Br9  1  0.877  0.868  0.144  1.0
  Br  Br10  1  0.702  0.497  0.761  1.0
  Br  Br11  1  0.298  0.503  0.239  1.0
[/CIF]
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The material structure described by WBr5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one WBr5 cluster. W(1) is bonded to one Br(2), one Br(3), one Br(4), one Br(5), and two equivalent Br(1) atoms to form edge-sharing WBr6 octahedra. There are five inequivalent Br sites. In the first Br site, Br(1) is bonded in a water-like geometry to two equivalent W(1) atoms. In the second Br site, Br(2) is bonded in a single-bond geometry to one W(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth Br site, Br(4) is bonded in a single-bond geometry to one W(1) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_WBr5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.637
_cell_length_b   7.165
_cell_length_c   9.704
_cell_angle_alpha   109.042
_cell_angle_beta   90.700
_cell_angle_gamma   116.203
_symmetry_Int_Tables_number   1
_cell_volume   384.674
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.899  0.289  0.786  1.0
  W  W1  1  0.101  0.711  0.214  1.0
  Br  Br2  1  0.245  0.689  0.956  1.0
  Br  Br3  1  0.755  0.311  0.044  1.0
  Br  Br4  1  0.568  0.927  0.660  1.0
  Br  Br5  1  0.432  0.073  0.340  1.0
  Br  Br6  1  0.062  0.309  0.566  1.0
  Br  Br7  1  0.938  0.691  0.434  1.0
  Br  Br8  1  0.123  0.132  0.856  1.0
  Br  Br9  1  0.877  0.868  0.144  1.0
  Br  Br10  1  0.702  0.497  0.761  1.0
  Br  Br11  1  0.298  0.503  0.239  1.0
[/CIF]
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