The compound described by C2PN3S2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one C2PN3S2 cluster. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(6) and one S(3) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(1) and one S(4) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one N(5) and one S(1) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one N(4) and one S(2) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(2), one N(3), one N(4), and one N(6) atom to form corner-sharing PN4 tetrahedra. In the second P site, P(2) is bonded to one N(1), one N(2), one N(3), and one N(5) atom to form corner-sharing PN4 tetrahedra. There are six inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one C(2) and one P(2) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the fourth N site, N(4) is bonded in a bent 150 degrees geometry to one C(4) and one P(1) atom. In the fifth N site, N(5) is bonded in a bent 150 degrees geometry to one C(3) and one P(2) atom. In the sixth N site, N(6) is bonded in a bent 150 degrees geometry to one C(1) and one P(1) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one C(3) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(4) atom. In the third S site, S(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth S site, S(4) is bonded in a single-bond geometry to one C(2) atom. is represented by the CIF file [CIF]
data_PC2S2N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.149
_cell_length_b   8.215
_cell_length_c   10.055
_cell_angle_alpha   99.508
_cell_angle_beta   103.977
_cell_angle_gamma   95.270
_symmetry_Int_Tables_number   1
_cell_volume   638.101
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.062  0.261  0.428  1.0
  P  P1  1  0.065  0.464  0.703  1.0
  P  P2  1  0.935  0.536  0.297  1.0
  P  P3  1  0.938  0.739  0.572  1.0
  C  C4  1  0.797  0.018  0.275  1.0
  C  C5  1  0.203  0.982  0.725  1.0
  C  C6  1  0.578  0.438  0.192  1.0
  C  C7  1  0.062  0.717  0.128  1.0
  C  C8  1  0.402  0.223  0.472  1.0
  C  C9  1  0.938  0.283  0.872  1.0
  C  C10  1  0.422  0.562  0.808  1.0
  C  C11  1  0.598  0.777  0.528  1.0
  S  S12  1  0.851  0.144  0.931  1.0
  S  S13  1  0.149  0.856  0.069  1.0
  S  S14  1  0.399  0.750  0.477  1.0
  S  S15  1  0.601  0.250  0.523  1.0
  S  S16  1  0.372  0.079  0.828  1.0
  S  S17  1  0.379  0.403  0.147  1.0
  S  S18  1  0.628  0.921  0.172  1.0
  S  S19  1  0.621  0.597  0.853  1.0
  N  N20  1  0.732  0.461  0.225  1.0
  N  N21  1  0.041  0.389  0.327  1.0
  N  N22  1  0.955  0.692  0.418  1.0
  N  N23  1  0.248  0.193  0.429  1.0
  N  N24  1  0.991  0.603  0.166  1.0
  N  N25  1  0.045  0.308  0.582  1.0
  N  N26  1  0.930  0.086  0.356  1.0
  N  N27  1  0.070  0.914  0.644  1.0
  N  N28  1  0.752  0.807  0.571  1.0
  N  N29  1  0.959  0.611  0.673  1.0
  N  N30  1  0.268  0.539  0.775  1.0
  N  N31  1  0.009  0.397  0.834  1.0
[/CIF]
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The compound described by C2PN3S2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one C2PN3S2 cluster. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(6) and one S(3) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(1) and one S(4) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one N(5) and one S(1) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one N(4) and one S(2) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(2), one N(3), one N(4), and one N(6) atom to form corner-sharing PN4 tetrahedra. In the second P site, P(2) is bonded to one N(1), one N(2), one N(3), and one N(5) atom to form corner-sharing PN4 tetrahedra. There are six inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one C(2) and one P(2) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. In the fourth N site, N(4) is bonded in a bent 150 degrees geometry to one C(4) and one P(1) atom. In the fifth N site, N(5) is bonded in a bent 150 degrees geometry to one C(3) and one P(2) atom. In the sixth N site, N(6) is bonded in a bent 150 degrees geometry to one C(1) and one P(1) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one C(3) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(4) atom. In the third S site, S(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth S site, S(4) is bonded in a single-bond geometry to one C(2) atom. is represented by the CIF file [CIF]
data_PC2S2N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.149
_cell_length_b   8.215
_cell_length_c   10.055
_cell_angle_alpha   99.508
_cell_angle_beta   103.977
_cell_angle_gamma   95.270
_symmetry_Int_Tables_number   1
_cell_volume   638.101
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.062  0.261  0.428  1.0
  P  P1  1  0.065  0.464  0.703  1.0
  P  P2  1  0.935  0.536  0.297  1.0
  P  P3  1  0.938  0.739  0.572  1.0
  C  C4  1  0.797  0.018  0.275  1.0
  C  C5  1  0.203  0.982  0.725  1.0
  C  C6  1  0.578  0.438  0.192  1.0
  C  C7  1  0.062  0.717  0.128  1.0
  C  C8  1  0.402  0.223  0.472  1.0
  C  C9  1  0.938  0.283  0.872  1.0
  C  C10  1  0.422  0.562  0.808  1.0
  C  C11  1  0.598  0.777  0.528  1.0
  S  S12  1  0.851  0.144  0.931  1.0
  S  S13  1  0.149  0.856  0.069  1.0
  S  S14  1  0.399  0.750  0.477  1.0
  S  S15  1  0.601  0.250  0.523  1.0
  S  S16  1  0.372  0.079  0.828  1.0
  S  S17  1  0.379  0.403  0.147  1.0
  S  S18  1  0.628  0.921  0.172  1.0
  S  S19  1  0.621  0.597  0.853  1.0
  N  N20  1  0.732  0.461  0.225  1.0
  N  N21  1  0.041  0.389  0.327  1.0
  N  N22  1  0.955  0.692  0.418  1.0
  N  N23  1  0.248  0.193  0.429  1.0
  N  N24  1  0.991  0.603  0.166  1.0
  N  N25  1  0.045  0.308  0.582  1.0
  N  N26  1  0.930  0.086  0.356  1.0
  N  N27  1  0.070  0.914  0.644  1.0
  N  N28  1  0.752  0.807  0.571  1.0
  N  N29  1  0.959  0.611  0.673  1.0
  N  N30  1  0.268  0.539  0.775  1.0
  N  N31  1  0.009  0.397  0.834  1.0
[/CIF]
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