The compound described by LaAgAs2 crystallizes in the orthorhombic Pbcm space group. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 6-coordinate geometry to one Ag(1), two equivalent Ag(2), one As(3), two equivalent As(2), and four equivalent As(1) atoms. In the second La site, La(2) is bonded in a 12-coordinate geometry to two equivalent Ag(1), two equivalent Ag(2), two equivalent As(2), two equivalent As(3), and four equivalent As(1) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 8-coordinate geometry to one La(1), two equivalent La(2), one As(3), and four equivalent As(1) atoms. In the second Ag site, Ag(2) is bonded in a 10-coordinate geometry to two equivalent La(1), two equivalent La(2), two equivalent Ag(2), two equivalent As(2), and two equivalent As(3) atoms. There are three inequivalent As sites. In the first As site, As(1) is bonded in a 8-coordinate geometry to two equivalent La(1), two equivalent La(2), two equivalent Ag(1), and two equivalent As(1) atoms. In the second As site, As(2) is bonded to two equivalent La(1), two equivalent La(2), and two equivalent Ag(2) atoms to form distorted corner-sharing AsLa4Ag2 pentagonal pyramids. In the third As site, As(3) is bonded in a 6-coordinate geometry to one La(1), two equivalent La(2), one Ag(1), and two equivalent Ag(2) atoms. is represented by the CIF card [CIF]
data_LaAgAs2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.156
_cell_length_b   5.955
_cell_length_c   21.433
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   785.700
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.978  0.750  0.367  1.0
  La  La1  1  0.022  0.250  0.633  1.0
  La  La2  1  0.978  0.250  0.133  1.0
  La  La3  1  0.022  0.750  0.867  1.0
  La  La4  1  0.506  0.250  0.372  1.0
  La  La5  1  0.494  0.750  0.628  1.0
  La  La6  1  0.506  0.750  0.128  1.0
  La  La7  1  0.494  0.250  0.872  1.0
  Ag  Ag8  1  0.430  0.750  0.437  1.0
  Ag  Ag9  1  0.570  0.250  0.563  1.0
  Ag  Ag10  1  0.430  0.250  0.063  1.0
  Ag  Ag11  1  0.570  0.750  0.937  1.0
  Ag  Ag12  1  0.237  0.500  0.250  1.0
  Ag  Ag13  1  0.763  0.000  0.750  1.0
  Ag  Ag14  1  0.763  0.500  0.750  1.0
  Ag  Ag15  1  0.237  0.000  0.250  1.0
  As  As16  1  0.792  0.962  0.493  1.0
  As  As17  1  0.208  0.462  0.507  1.0
  As  As18  1  0.792  0.038  0.007  1.0
  As  As19  1  0.208  0.538  0.993  1.0
  As  As20  1  0.208  0.038  0.507  1.0
  As  As21  1  0.792  0.538  0.493  1.0
  As  As22  1  0.208  0.962  0.993  1.0
  As  As23  1  0.792  0.462  0.007  1.0
  As  As24  1  0.016  0.250  0.335  1.0
  As  As25  1  0.984  0.750  0.665  1.0
  As  As26  1  0.016  0.750  0.165  1.0
  As  As27  1  0.984  0.250  0.835  1.0
  As  As28  1  0.518  0.750  0.319  1.0
  As  As29  1  0.482  0.250  0.681  1.0
  As  As30  1  0.518  0.250  0.181  1.0
  As  As31  1  0.482  0.750  0.819  1.0
[/CIF]
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The compound described by LaAgAs2 crystallizes in the orthorhombic Pbcm space group. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 6-coordinate geometry to one Ag(1), two equivalent Ag(2), one As(3), two equivalent As(2), and four equivalent As(1) atoms. In the second La site, La(2) is bonded in a 12-coordinate geometry to two equivalent Ag(1), two equivalent Ag(2), two equivalent As(2), two equivalent As(3), and four equivalent As(1) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 8-coordinate geometry to one La(1), two equivalent La(2), one As(3), and four equivalent As(1) atoms. In the second Ag site, Ag(2) is bonded in a 10-coordinate geometry to two equivalent La(1), two equivalent La(2), two equivalent Ag(2), two equivalent As(2), and two equivalent As(3) atoms. There are three inequivalent As sites. In the first As site, As(1) is bonded in a 8-coordinate geometry to two equivalent La(1), two equivalent La(2), two equivalent Ag(1), and two equivalent As(1) atoms. In the second As site, As(2) is bonded to two equivalent La(1), two equivalent La(2), and two equivalent Ag(2) atoms to form distorted corner-sharing AsLa4Ag2 pentagonal pyramids. In the third As site, As(3) is bonded in a 6-coordinate geometry to one La(1), two equivalent La(2), one Ag(1), and two equivalent Ag(2) atoms. is represented by the CIF card [CIF]
data_LaAgAs2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.156
_cell_length_b   5.955
_cell_length_c   21.433
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   785.700
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.978  0.750  0.367  1.0
  La  La1  1  0.022  0.250  0.633  1.0
  La  La2  1  0.978  0.250  0.133  1.0
  La  La3  1  0.022  0.750  0.867  1.0
  La  La4  1  0.506  0.250  0.372  1.0
  La  La5  1  0.494  0.750  0.628  1.0
  La  La6  1  0.506  0.750  0.128  1.0
  La  La7  1  0.494  0.250  0.872  1.0
  Ag  Ag8  1  0.430  0.750  0.437  1.0
  Ag  Ag9  1  0.570  0.250  0.563  1.0
  Ag  Ag10  1  0.430  0.250  0.063  1.0
  Ag  Ag11  1  0.570  0.750  0.937  1.0
  Ag  Ag12  1  0.237  0.500  0.250  1.0
  Ag  Ag13  1  0.763  0.000  0.750  1.0
  Ag  Ag14  1  0.763  0.500  0.750  1.0
  Ag  Ag15  1  0.237  0.000  0.250  1.0
  As  As16  1  0.792  0.962  0.493  1.0
  As  As17  1  0.208  0.462  0.507  1.0
  As  As18  1  0.792  0.038  0.007  1.0
  As  As19  1  0.208  0.538  0.993  1.0
  As  As20  1  0.208  0.038  0.507  1.0
  As  As21  1  0.792  0.538  0.493  1.0
  As  As22  1  0.208  0.962  0.993  1.0
  As  As23  1  0.792  0.462  0.007  1.0
  As  As24  1  0.016  0.250  0.335  1.0
  As  As25  1  0.984  0.750  0.665  1.0
  As  As26  1  0.016  0.750  0.165  1.0
  As  As27  1  0.984  0.250  0.835  1.0
  As  As28  1  0.518  0.750  0.319  1.0
  As  As29  1  0.482  0.250  0.681  1.0
  As  As30  1  0.518  0.250  0.181  1.0
  As  As31  1  0.482  0.750  0.819  1.0
[/CIF]
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