The material structure described by HoZn(SbO3)2 crystallizes in the triclinic P1 space group. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 6-coordinate geometry to one O(12), one O(2), one O(3), one O(4), one O(5), and one O(7) atom. In the second Ho site, Ho(2) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(6), one O(8), and one O(9) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a rectangular see-saw-like geometry to one O(12), one O(4), one O(5), and one O(7) atom. In the second Zn site, Zn(2) is bonded to one O(1), one O(10), one O(11), and one O(6) atom to form distorted ZnO4 trigonal pyramids that share  an edgeedge with one Sb(2)O6 octahedra. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one O(12), one O(2), and one O(9) atom. In the second Sb site, Sb(2) is bonded to one O(1), one O(11), one O(12), one O(3), one O(5), and one O(8) atom to form SbO6 octahedra that share  an edgeedge with one Zn(2)O4 trigonal pyramid. In the third Sb site, Sb(3) is bonded in a 3-coordinate geometry to one O(3), one O(7), and one O(8) atom. In the fourth Sb site, Sb(4) is bonded in a 5-coordinate geometry to one O(10), one O(2), one O(4), one O(6), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Ho(2), one Zn(2), and one Sb(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ho(1), one Sb(1), and one Sb(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Ho(1), one Sb(2), and one Sb(3) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Ho(1), one Zn(1), and one Sb(4) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Ho(1), one Zn(1), and one Sb(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Ho(2), one Zn(2), and one Sb(4) atom. In the seventh O site, O(7) is bonded in a trigonal non-coplanar geometry to one Ho(1), one Zn(1), and one Sb(3) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Ho(2), one Sb(2), and one Sb(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Ho(2), one Sb(1), and one Sb(4) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Ho(2), one Zn(2), and one Sb(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Ho(2), one Zn(2), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal pyramidal geometry to one Ho(1), one Zn(1), one Sb(1), and one Sb(2) atom. is represented by the CIF file [CIF]
data_HoZn(SbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.559
_cell_length_b   6.336
_cell_length_c   8.595
_cell_angle_alpha   96.505
_cell_angle_beta   89.685
_cell_angle_gamma   94.189
_symmetry_Int_Tables_number   1
_cell_volume   299.952
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.964  0.928  0.251  1.0
  Ho  Ho1  1  0.446  0.588  0.742  1.0
  Zn  Zn2  1  0.470  0.656  0.258  1.0
  Zn  Zn3  1  0.977  0.830  0.783  1.0
  Sb  Sb4  1  0.020  0.418  0.008  1.0
  Sb  Sb5  1  0.980  0.500  0.477  1.0
  Sb  Sb6  1  0.485  0.092  0.518  1.0
  Sb  Sb7  1  0.516  0.014  0.005  1.0
  O  O8  1  0.817  0.492  0.682  1.0
  O  O9  1  0.942  0.131  0.068  1.0
  O  O10  1  0.808  0.210  0.402  1.0
  O  O11  1  0.669  0.762  0.091  1.0
  O  O12  1  0.744  0.697  0.407  1.0
  O  O13  1  0.657  0.916  0.793  1.0
  O  O14  1  0.351  0.973  0.313  1.0
  O  O15  1  0.285  0.355  0.533  1.0
  O  O16  1  0.320  0.351  0.899  1.0
  O  O17  1  0.231  0.790  0.929  1.0
  O  O18  1  0.182  0.757  0.588  1.0
  O  O19  1  0.135  0.541  0.253  1.0
[/CIF]
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The material structure described by HoZn(SbO3)2 crystallizes in the triclinic P1 space group. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 6-coordinate geometry to one O(12), one O(2), one O(3), one O(4), one O(5), and one O(7) atom. In the second Ho site, Ho(2) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(11), one O(6), one O(8), and one O(9) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a rectangular see-saw-like geometry to one O(12), one O(4), one O(5), and one O(7) atom. In the second Zn site, Zn(2) is bonded to one O(1), one O(10), one O(11), and one O(6) atom to form distorted ZnO4 trigonal pyramids that share  an edgeedge with one Sb(2)O6 octahedra. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 3-coordinate geometry to one O(12), one O(2), and one O(9) atom. In the second Sb site, Sb(2) is bonded to one O(1), one O(11), one O(12), one O(3), one O(5), and one O(8) atom to form SbO6 octahedra that share  an edgeedge with one Zn(2)O4 trigonal pyramid. In the third Sb site, Sb(3) is bonded in a 3-coordinate geometry to one O(3), one O(7), and one O(8) atom. In the fourth Sb site, Sb(4) is bonded in a 5-coordinate geometry to one O(10), one O(2), one O(4), one O(6), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Ho(2), one Zn(2), and one Sb(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ho(1), one Sb(1), and one Sb(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Ho(1), one Sb(2), and one Sb(3) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Ho(1), one Zn(1), and one Sb(4) atom. In the fifth O site, O(5) is bonded in a distorted T-shaped geometry to one Ho(1), one Zn(1), and one Sb(2) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Ho(2), one Zn(2), and one Sb(4) atom. In the seventh O site, O(7) is bonded in a trigonal non-coplanar geometry to one Ho(1), one Zn(1), and one Sb(3) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Ho(2), one Sb(2), and one Sb(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Ho(2), one Sb(1), and one Sb(4) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Ho(2), one Zn(2), and one Sb(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Ho(2), one Zn(2), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal pyramidal geometry to one Ho(1), one Zn(1), one Sb(1), and one Sb(2) atom. is represented by the CIF file [CIF]
data_HoZn(SbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.559
_cell_length_b   6.336
_cell_length_c   8.595
_cell_angle_alpha   96.505
_cell_angle_beta   89.685
_cell_angle_gamma   94.189
_symmetry_Int_Tables_number   1
_cell_volume   299.952
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.964  0.928  0.251  1.0
  Ho  Ho1  1  0.446  0.588  0.742  1.0
  Zn  Zn2  1  0.470  0.656  0.258  1.0
  Zn  Zn3  1  0.977  0.830  0.783  1.0
  Sb  Sb4  1  0.020  0.418  0.008  1.0
  Sb  Sb5  1  0.980  0.500  0.477  1.0
  Sb  Sb6  1  0.485  0.092  0.518  1.0
  Sb  Sb7  1  0.516  0.014  0.005  1.0
  O  O8  1  0.817  0.492  0.682  1.0
  O  O9  1  0.942  0.131  0.068  1.0
  O  O10  1  0.808  0.210  0.402  1.0
  O  O11  1  0.669  0.762  0.091  1.0
  O  O12  1  0.744  0.697  0.407  1.0
  O  O13  1  0.657  0.916  0.793  1.0
  O  O14  1  0.351  0.973  0.313  1.0
  O  O15  1  0.285  0.355  0.533  1.0
  O  O16  1  0.320  0.351  0.899  1.0
  O  O17  1  0.231  0.790  0.929  1.0
  O  O18  1  0.182  0.757  0.588  1.0
  O  O19  1  0.135  0.541  0.253  1.0
[/CIF]
.