The compound described by LiVBO4 crystallizes in the orthorhombic Ccc2 space group. Li(1) is bonded in a distorted see-saw-like geometry to one O(2), one O(3), and two equivalent O(4) atoms. V(1) is bonded to one O(2), one O(3), one O(4), and two equivalent O(1) atoms to form distorted corner-sharing VO5 trigonal bipyramids. B(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent V(1) and one B(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one B(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one B(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Li(1) and one V(1) atom. is represented by the CIF file [CIF]
data_LiVBO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.574
_cell_length_b   8.400
_cell_length_c   5.200
_cell_angle_alpha   89.989
_cell_angle_beta   90.016
_cell_angle_gamma   124.716
_symmetry_Int_Tables_number   1
_cell_volume   343.732
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.231  0.506  0.772  1.0
  Li  Li1  1  0.275  0.506  0.272  1.0
  Li  Li2  1  0.725  0.494  0.272  1.0
  Li  Li3  1  0.769  0.494  0.772  1.0
  V  V4  1  0.129  0.804  0.466  1.0
  V  V5  1  0.325  0.196  0.966  1.0
  V  V6  1  0.675  0.804  0.966  1.0
  V  V7  1  0.871  0.196  0.466  1.0
  B  B8  1  0.193  0.771  0.018  1.0
  B  B9  1  0.577  0.771  0.518  1.0
  B  B10  1  0.423  0.229  0.518  1.0
  B  B11  1  0.807  0.229  0.018  1.0
  O  O12  1  0.191  0.929  0.106  1.0
  O  O13  1  0.195  0.721  0.771  1.0
  O  O14  1  0.189  0.668  0.229  1.0
  O  O15  1  0.081  0.315  0.504  1.0
  O  O16  1  0.235  0.316  0.004  1.0
  O  O17  1  0.262  0.071  0.605  1.0
  O  O18  1  0.479  0.667  0.729  1.0
  O  O19  1  0.526  0.721  0.271  1.0
  O  O20  1  0.474  0.279  0.271  1.0
  O  O21  1  0.521  0.333  0.729  1.0
  O  O22  1  0.738  0.929  0.606  1.0
  O  O23  1  0.766  0.684  0.004  1.0
  O  O24  1  0.919  0.685  0.504  1.0
  O  O25  1  0.812  0.333  0.229  1.0
  O  O26  1  0.805  0.279  0.771  1.0
  O  O27  1  0.809  0.071  0.106  1.0
[/CIF]
.
The compound described by LiVBO4 crystallizes in the orthorhombic Ccc2 space group. Li(1) is bonded in a distorted see-saw-like geometry to one O(2), one O(3), and two equivalent O(4) atoms. V(1) is bonded to one O(2), one O(3), one O(4), and two equivalent O(1) atoms to form distorted corner-sharing VO5 trigonal bipyramids. B(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent V(1) and one B(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Li(1), one V(1), and one B(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one V(1), and one B(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Li(1) and one V(1) atom. is represented by the CIF file [CIF]
data_LiVBO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.574
_cell_length_b   8.400
_cell_length_c   5.200
_cell_angle_alpha   89.989
_cell_angle_beta   90.016
_cell_angle_gamma   124.716
_symmetry_Int_Tables_number   1
_cell_volume   343.732
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.231  0.506  0.772  1.0
  Li  Li1  1  0.275  0.506  0.272  1.0
  Li  Li2  1  0.725  0.494  0.272  1.0
  Li  Li3  1  0.769  0.494  0.772  1.0
  V  V4  1  0.129  0.804  0.466  1.0
  V  V5  1  0.325  0.196  0.966  1.0
  V  V6  1  0.675  0.804  0.966  1.0
  V  V7  1  0.871  0.196  0.466  1.0
  B  B8  1  0.193  0.771  0.018  1.0
  B  B9  1  0.577  0.771  0.518  1.0
  B  B10  1  0.423  0.229  0.518  1.0
  B  B11  1  0.807  0.229  0.018  1.0
  O  O12  1  0.191  0.929  0.106  1.0
  O  O13  1  0.195  0.721  0.771  1.0
  O  O14  1  0.189  0.668  0.229  1.0
  O  O15  1  0.081  0.315  0.504  1.0
  O  O16  1  0.235  0.316  0.004  1.0
  O  O17  1  0.262  0.071  0.605  1.0
  O  O18  1  0.479  0.667  0.729  1.0
  O  O19  1  0.526  0.721  0.271  1.0
  O  O20  1  0.474  0.279  0.271  1.0
  O  O21  1  0.521  0.333  0.729  1.0
  O  O22  1  0.738  0.929  0.606  1.0
  O  O23  1  0.766  0.684  0.004  1.0
  O  O24  1  0.919  0.685  0.504  1.0
  O  O25  1  0.812  0.333  0.229  1.0
  O  O26  1  0.805  0.279  0.771  1.0
  O  O27  1  0.809  0.071  0.106  1.0
[/CIF]
.