The structure described by LiCoCO4 crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded to one O(2), one O(4), and two equivalent O(1) atoms to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, and  an edgeedge with one Co(1)O4 tetrahedra. Co(1) is bonded to one O(2), one O(3), and two equivalent O(4) atoms to form CoO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, and  an edgeedge with one Li(1)O4 tetrahedra. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Co(1), and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent Co(1) atoms. is represented by the CIF card [CIF]
data_LiCoCO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.266
_cell_length_b   6.586
_cell_length_c   10.612
_cell_angle_alpha   81.746
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   364.220
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.655  0.883  0.794  1.0
  Li  Li1  1  0.845  0.883  0.294  1.0
  Li  Li2  1  0.155  0.117  0.706  1.0
  Li  Li3  1  0.345  0.117  0.206  1.0
  Co  Co4  1  0.852  0.490  0.846  1.0
  Co  Co5  1  0.352  0.510  0.654  1.0
  Co  Co6  1  0.648  0.490  0.346  1.0
  Co  Co7  1  0.148  0.510  0.154  1.0
  C  C8  1  0.182  0.795  0.926  1.0
  C  C9  1  0.318  0.795  0.426  1.0
  C  C10  1  0.682  0.205  0.574  1.0
  C  C11  1  0.818  0.205  0.074  1.0
  O  O12  1  0.296  0.920  0.844  1.0
  O  O13  1  0.204  0.920  0.344  1.0
  O  O14  1  0.942  0.744  0.911  1.0
  O  O15  1  0.558  0.744  0.411  1.0
  O  O16  1  0.203  0.711  0.530  1.0
  O  O17  1  0.631  0.613  0.730  1.0
  O  O18  1  0.297  0.711  0.030  1.0
  O  O19  1  0.869  0.613  0.230  1.0
  O  O20  1  0.131  0.387  0.770  1.0
  O  O21  1  0.703  0.289  0.970  1.0
  O  O22  1  0.369  0.387  0.270  1.0
  O  O23  1  0.797  0.289  0.470  1.0
  O  O24  1  0.442  0.256  0.589  1.0
  O  O25  1  0.058  0.256  0.089  1.0
  O  O26  1  0.796  0.080  0.656  1.0
  O  O27  1  0.704  0.080  0.156  1.0
[/CIF]
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The structure described by LiCoCO4 crystallizes in the monoclinic P2_1/c space group. Li(1) is bonded to one O(2), one O(4), and two equivalent O(1) atoms to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, and  an edgeedge with one Co(1)O4 tetrahedra. Co(1) is bonded to one O(2), one O(3), and two equivalent O(4) atoms to form CoO4 tetrahedra that share  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Co(1)O4 tetrahedra, and  an edgeedge with one Li(1)O4 tetrahedra. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent Li(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Co(1), and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent Co(1) atoms. is represented by the CIF card [CIF]
data_LiCoCO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.266
_cell_length_b   6.586
_cell_length_c   10.612
_cell_angle_alpha   81.746
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   364.220
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.655  0.883  0.794  1.0
  Li  Li1  1  0.845  0.883  0.294  1.0
  Li  Li2  1  0.155  0.117  0.706  1.0
  Li  Li3  1  0.345  0.117  0.206  1.0
  Co  Co4  1  0.852  0.490  0.846  1.0
  Co  Co5  1  0.352  0.510  0.654  1.0
  Co  Co6  1  0.648  0.490  0.346  1.0
  Co  Co7  1  0.148  0.510  0.154  1.0
  C  C8  1  0.182  0.795  0.926  1.0
  C  C9  1  0.318  0.795  0.426  1.0
  C  C10  1  0.682  0.205  0.574  1.0
  C  C11  1  0.818  0.205  0.074  1.0
  O  O12  1  0.296  0.920  0.844  1.0
  O  O13  1  0.204  0.920  0.344  1.0
  O  O14  1  0.942  0.744  0.911  1.0
  O  O15  1  0.558  0.744  0.411  1.0
  O  O16  1  0.203  0.711  0.530  1.0
  O  O17  1  0.631  0.613  0.730  1.0
  O  O18  1  0.297  0.711  0.030  1.0
  O  O19  1  0.869  0.613  0.230  1.0
  O  O20  1  0.131  0.387  0.770  1.0
  O  O21  1  0.703  0.289  0.970  1.0
  O  O22  1  0.369  0.387  0.270  1.0
  O  O23  1  0.797  0.289  0.470  1.0
  O  O24  1  0.442  0.256  0.589  1.0
  O  O25  1  0.058  0.256  0.089  1.0
  O  O26  1  0.796  0.080  0.656  1.0
  O  O27  1  0.704  0.080  0.156  1.0
[/CIF]
.