The material structure described by Li4Ti3Co3(SbO8)2 is Spinel-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one O(8), and two equivalent O(11) atoms to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra, and corners with four equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-65°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(4), one O(5), and two equivalent O(12) atoms. In the third Li site, Li(3) is bonded to one O(3), one O(6), and two equivalent O(9) atoms to form distorted LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with three equivalent Sb(1)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-67°. In the fourth Li site, Li(4) is bonded to one O(1), one O(7), and two equivalent O(10) atoms to form LiO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent Sb(1)O6 octahedra, and corners with four equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(4), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form TiO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with four equivalent Co(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 50°. In the second Ti site, Ti(2) is bonded to one O(1), one O(10), one O(12), one O(2), one O(3), and one O(5) atom to form TiO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(2), one O(3), two equivalent O(10), and two equivalent O(12) atoms to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, and edges with four equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the second Co site, Co(2) is bonded to one O(11), one O(4), one O(6), one O(7), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-55°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(6), two equivalent O(10), and two equivalent O(9) atoms to form SbO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent Co(2)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the second Sb site, Sb(2) is bonded to one O(5), one O(8), two equivalent O(11), and two equivalent O(12) atoms to form SbO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Ti(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ti(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(4), two equivalent Ti(2), and one Sb(1) atom to form distorted OLiTi2Sb tetrahedra that share corners with two equivalent O(3)LiTi2Co tetrahedra, corners with two equivalent O(10)LiTiCoSb tetrahedra, and edges with two equivalent O(10)LiTiCoSb tetrahedra. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Ti(2), and one Co(1) atom. In the third O site, O(3) is bonded to one Li(3), two equivalent Ti(2), and one Co(1) atom to form OLiTi2Co tetrahedra that share corners with two equivalent O(1)LiTi2Sb tetrahedra and corners with four equivalent O(10)LiTiCoSb tetrahedra. In the fourth O site, O(4) is bonded to one Li(2), one Ti(1), and two equivalent Co(2) atoms to form corner-sharing OLiTiCo2 tetrahedra. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(2), two equivalent Ti(2), and one Sb(2) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), two equivalent Co(2), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(4), one Ti(1), and two equivalent Co(2) atoms. In the eighth O site, O(8) is bonded to one Li(1), two equivalent Co(2), and one Sb(2) atom to form distorted corner-sharing OLiCo2Sb tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(1), one Co(2), and one Sb(1) atom. In the tenth O site, O(10) is bonded to one Li(4), one Ti(2), one Co(1), and one Sb(1) atom to form distorted OLiTiCoSb tetrahedra that share  a cornercorner with one O(1)LiTi2Sb tetrahedra,  a cornercorner with one O(10)LiTiCoSb tetrahedra, corners with two equivalent O(3)LiTi2Co tetrahedra,  an edgeedge with one O(1)LiTi2Sb tetrahedra, and  an edgeedge with one O(10)LiTiCoSb tetrahedra. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Ti(1), one Co(2), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(2), one Co(1), and one Sb(2) atom. is represented by the CIF card [CIF]
data_Li4Ti3Co3(SbO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.969
_cell_length_b   6.028
_cell_length_c   9.756
_cell_angle_alpha   90.911
_cell_angle_beta   90.010
_cell_angle_gamma   119.668
_symmetry_Int_Tables_number   1
_cell_volume   304.953
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.173  0.345  0.790  1.0
  Co  Co1  1  0.345  0.172  0.289  1.0
  Co  Co2  1  0.827  0.172  0.289  1.0
  Li  Li3  1  0.339  0.678  0.102  1.0
  Li  Li4  1  0.008  0.015  0.020  1.0
  Li  Li5  1  0.997  0.995  0.505  1.0
  Li  Li6  1  0.668  0.335  0.593  1.0
  O  O7  1  0.478  0.957  0.661  1.0
  O  O8  1  0.350  0.700  0.894  1.0
  O  O9  1  0.993  0.986  0.697  1.0
  O  O10  1  0.991  0.982  0.205  1.0
  O  O11  1  0.829  0.658  0.894  1.0
  O  O12  1  0.160  0.320  0.417  1.0
  O  O13  1  0.682  0.364  0.397  1.0
  O  O14  1  0.519  0.038  0.148  1.0
  O  O15  1  0.160  0.816  0.405  1.0
  O  O16  1  0.656  0.816  0.405  1.0
  O  O17  1  0.041  0.536  0.658  1.0
  O  O18  1  0.495  0.536  0.658  1.0
  O  O19  1  0.530  0.496  0.145  1.0
  O  O20  1  0.966  0.496  0.145  1.0
  O  O21  1  0.331  0.157  0.900  1.0
  O  O22  1  0.826  0.157  0.900  1.0
  Sb  Sb23  1  0.327  0.655  0.507  1.0
  Sb  Sb24  1  0.660  0.319  0.015  1.0
  Ti  Ti25  1  0.825  0.651  0.281  1.0
  Ti  Ti26  1  0.165  0.824  0.785  1.0
  Ti  Ti27  1  0.659  0.824  0.785  1.0
[/CIF]
.
The material structure described by Li4Ti3Co3(SbO8)2 is Spinel-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one O(8), and two equivalent O(11) atoms to form LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra, and corners with four equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-65°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(4), one O(5), and two equivalent O(12) atoms. In the third Li site, Li(3) is bonded to one O(3), one O(6), and two equivalent O(9) atoms to form distorted LiO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Ti(2)O6 octahedra, corners with three equivalent Sb(1)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-67°. In the fourth Li site, Li(4) is bonded to one O(1), one O(7), and two equivalent O(10) atoms to form LiO4 tetrahedra that share  a cornercorner with one Ti(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent Sb(1)O6 octahedra, and corners with four equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-63°. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(4), one O(7), two equivalent O(11), and two equivalent O(9) atoms to form TiO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with four equivalent Co(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 50°. In the second Ti site, Ti(2) is bonded to one O(1), one O(10), one O(12), one O(2), one O(3), and one O(5) atom to form TiO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Ti(2)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(2), one O(3), two equivalent O(10), and two equivalent O(12) atoms to form CoO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sb(1)O6 octahedra, and edges with four equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the second Co site, Co(2) is bonded to one O(11), one O(4), one O(6), one O(7), one O(8), and one O(9) atom to form CoO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-55°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(6), two equivalent O(10), and two equivalent O(9) atoms to form SbO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent Co(2)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the second Sb site, Sb(2) is bonded to one O(5), one O(8), two equivalent O(11), and two equivalent O(12) atoms to form SbO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Ti(2)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Ti(1)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(4), two equivalent Ti(2), and one Sb(1) atom to form distorted OLiTi2Sb tetrahedra that share corners with two equivalent O(3)LiTi2Co tetrahedra, corners with two equivalent O(10)LiTiCoSb tetrahedra, and edges with two equivalent O(10)LiTiCoSb tetrahedra. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), two equivalent Ti(2), and one Co(1) atom. In the third O site, O(3) is bonded to one Li(3), two equivalent Ti(2), and one Co(1) atom to form OLiTi2Co tetrahedra that share corners with two equivalent O(1)LiTi2Sb tetrahedra and corners with four equivalent O(10)LiTiCoSb tetrahedra. In the fourth O site, O(4) is bonded to one Li(2), one Ti(1), and two equivalent Co(2) atoms to form corner-sharing OLiTiCo2 tetrahedra. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(2), two equivalent Ti(2), and one Sb(2) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), two equivalent Co(2), and one Sb(1) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(4), one Ti(1), and two equivalent Co(2) atoms. In the eighth O site, O(8) is bonded to one Li(1), two equivalent Co(2), and one Sb(2) atom to form distorted corner-sharing OLiCo2Sb tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(3), one Ti(1), one Co(2), and one Sb(1) atom. In the tenth O site, O(10) is bonded to one Li(4), one Ti(2), one Co(1), and one Sb(1) atom to form distorted OLiTiCoSb tetrahedra that share  a cornercorner with one O(1)LiTi2Sb tetrahedra,  a cornercorner with one O(10)LiTiCoSb tetrahedra, corners with two equivalent O(3)LiTi2Co tetrahedra,  an edgeedge with one O(1)LiTi2Sb tetrahedra, and  an edgeedge with one O(10)LiTiCoSb tetrahedra. In the eleventh O site, O(11) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one Ti(1), one Co(2), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Li(2), one Ti(2), one Co(1), and one Sb(2) atom. is represented by the CIF card [CIF]
data_Li4Ti3Co3(SbO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.969
_cell_length_b   6.028
_cell_length_c   9.756
_cell_angle_alpha   90.911
_cell_angle_beta   90.010
_cell_angle_gamma   119.668
_symmetry_Int_Tables_number   1
_cell_volume   304.953
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.173  0.345  0.790  1.0
  Co  Co1  1  0.345  0.172  0.289  1.0
  Co  Co2  1  0.827  0.172  0.289  1.0
  Li  Li3  1  0.339  0.678  0.102  1.0
  Li  Li4  1  0.008  0.015  0.020  1.0
  Li  Li5  1  0.997  0.995  0.505  1.0
  Li  Li6  1  0.668  0.335  0.593  1.0
  O  O7  1  0.478  0.957  0.661  1.0
  O  O8  1  0.350  0.700  0.894  1.0
  O  O9  1  0.993  0.986  0.697  1.0
  O  O10  1  0.991  0.982  0.205  1.0
  O  O11  1  0.829  0.658  0.894  1.0
  O  O12  1  0.160  0.320  0.417  1.0
  O  O13  1  0.682  0.364  0.397  1.0
  O  O14  1  0.519  0.038  0.148  1.0
  O  O15  1  0.160  0.816  0.405  1.0
  O  O16  1  0.656  0.816  0.405  1.0
  O  O17  1  0.041  0.536  0.658  1.0
  O  O18  1  0.495  0.536  0.658  1.0
  O  O19  1  0.530  0.496  0.145  1.0
  O  O20  1  0.966  0.496  0.145  1.0
  O  O21  1  0.331  0.157  0.900  1.0
  O  O22  1  0.826  0.157  0.900  1.0
  Sb  Sb23  1  0.327  0.655  0.507  1.0
  Sb  Sb24  1  0.660  0.319  0.015  1.0
  Ti  Ti25  1  0.825  0.651  0.281  1.0
  Ti  Ti26  1  0.165  0.824  0.785  1.0
  Ti  Ti27  1  0.659  0.824  0.785  1.0
[/CIF]
.