The structure described by Mo2P3O11 crystallizes in the monoclinic C2/c space group. Mo(1) is bonded to one O(1), one O(3), one O(4), one O(5), and two equivalent O(2) atoms to form MoO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra, and  an edgeedge with one Mo(1)O6 octahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with four equivalent Mo(1)O6 octahedra and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-53°. In the second P site, P(2) is bonded to two equivalent O(1) and two equivalent O(4) atoms to form PO4 tetrahedra that share corners with four equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-33°. There are six inequivalent O sites. In the first O site, O(6) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. In the second O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one P(2) atom. In the third O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Mo(1) and one P(1) atom. In the fourth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one P(1) atom. In the fifth O site, O(4) is bonded in a bent 150 degrees geometry to one Mo(1) and one P(2) atom. In the sixth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mo2P3O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.381
_cell_length_b   7.381
_cell_length_c   9.035
_cell_angle_alpha   70.592
_cell_angle_beta   70.591
_cell_angle_gamma   72.395
_symmetry_Int_Tables_number   1
_cell_volume   427.492
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.365  0.886  0.710  1.0
  Mo  Mo1  1  0.636  0.114  0.790  1.0
  Mo  Mo2  1  0.114  0.635  0.290  1.0
  Mo  Mo3  1  0.886  0.364  0.210  1.0
  P  P4  1  0.545  0.671  0.037  1.0
  P  P5  1  0.329  0.455  0.963  1.0
  P  P6  1  0.672  0.545  0.537  1.0
  P  P7  1  0.455  0.328  0.463  1.0
  P  P8  1  0.039  0.961  0.500  1.0
  P  P9  1  0.961  0.039  1.000  1.0
  O  O10  1  0.052  0.772  0.459  1.0
  O  O11  1  0.534  0.841  0.880  1.0
  O  O12  1  0.159  0.466  0.120  1.0
  O  O13  1  0.622  0.280  0.322  1.0
  O  O14  1  0.280  0.621  0.821  1.0
  O  O15  1  0.841  0.534  0.380  1.0
  O  O16  1  0.136  0.019  0.854  1.0
  O  O17  1  0.019  0.136  0.354  1.0
  O  O18  1  0.615  0.745  0.565  1.0
  O  O19  1  0.379  0.720  0.178  1.0
  O  O20  1  0.720  0.378  0.678  1.0
  O  O21  1  0.255  0.385  0.435  1.0
  O  O22  1  0.228  0.948  0.541  1.0
  O  O23  1  0.948  0.228  0.041  1.0
  O  O24  1  0.772  0.052  0.959  1.0
  O  O25  1  0.488  0.512  0.500  1.0
  O  O26  1  0.746  0.614  0.065  1.0
  O  O27  1  0.981  0.864  0.146  1.0
  O  O28  1  0.466  0.159  0.620  1.0
  O  O29  1  0.386  0.254  0.935  1.0
  O  O30  1  0.864  0.981  0.646  1.0
  O  O31  1  0.512  0.488  1.000  1.0
[/CIF]
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The structure described by Mo2P3O11 crystallizes in the monoclinic C2/c space group. Mo(1) is bonded to one O(1), one O(3), one O(4), one O(5), and two equivalent O(2) atoms to form MoO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with four equivalent P(1)O4 tetrahedra, and  an edgeedge with one Mo(1)O6 octahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form PO4 tetrahedra that share corners with four equivalent Mo(1)O6 octahedra and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-53°. In the second P site, P(2) is bonded to two equivalent O(1) and two equivalent O(4) atoms to form PO4 tetrahedra that share corners with four equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-33°. There are six inequivalent O sites. In the first O site, O(6) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. In the second O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one P(2) atom. In the third O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Mo(1) and one P(1) atom. In the fourth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one P(1) atom. In the fifth O site, O(4) is bonded in a bent 150 degrees geometry to one Mo(1) and one P(2) atom. In the sixth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mo2P3O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.381
_cell_length_b   7.381
_cell_length_c   9.035
_cell_angle_alpha   70.592
_cell_angle_beta   70.591
_cell_angle_gamma   72.395
_symmetry_Int_Tables_number   1
_cell_volume   427.492
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.365  0.886  0.710  1.0
  Mo  Mo1  1  0.636  0.114  0.790  1.0
  Mo  Mo2  1  0.114  0.635  0.290  1.0
  Mo  Mo3  1  0.886  0.364  0.210  1.0
  P  P4  1  0.545  0.671  0.037  1.0
  P  P5  1  0.329  0.455  0.963  1.0
  P  P6  1  0.672  0.545  0.537  1.0
  P  P7  1  0.455  0.328  0.463  1.0
  P  P8  1  0.039  0.961  0.500  1.0
  P  P9  1  0.961  0.039  1.000  1.0
  O  O10  1  0.052  0.772  0.459  1.0
  O  O11  1  0.534  0.841  0.880  1.0
  O  O12  1  0.159  0.466  0.120  1.0
  O  O13  1  0.622  0.280  0.322  1.0
  O  O14  1  0.280  0.621  0.821  1.0
  O  O15  1  0.841  0.534  0.380  1.0
  O  O16  1  0.136  0.019  0.854  1.0
  O  O17  1  0.019  0.136  0.354  1.0
  O  O18  1  0.615  0.745  0.565  1.0
  O  O19  1  0.379  0.720  0.178  1.0
  O  O20  1  0.720  0.378  0.678  1.0
  O  O21  1  0.255  0.385  0.435  1.0
  O  O22  1  0.228  0.948  0.541  1.0
  O  O23  1  0.948  0.228  0.041  1.0
  O  O24  1  0.772  0.052  0.959  1.0
  O  O25  1  0.488  0.512  0.500  1.0
  O  O26  1  0.746  0.614  0.065  1.0
  O  O27  1  0.981  0.864  0.146  1.0
  O  O28  1  0.466  0.159  0.620  1.0
  O  O29  1  0.386  0.254  0.935  1.0
  O  O30  1  0.864  0.981  0.646  1.0
  O  O31  1  0.512  0.488  1.000  1.0
[/CIF]
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