The crystal structure described by CN(Te)2AsF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two cyanogen molecules, two tellurium tetramer molecules, and four AsF6 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_Te2AsCNF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.603
_cell_length_b   6.958
_cell_length_c   13.515
_cell_angle_alpha   64.652
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   900.970
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.093  0.735  0.397  1.0
  Te  Te1  1  0.654  0.653  0.946  1.0
  Te  Te2  1  0.846  0.653  0.446  1.0
  Te  Te3  1  0.346  0.347  0.054  1.0
  Te  Te4  1  0.907  0.265  0.603  1.0
  Te  Te5  1  0.407  0.735  0.897  1.0
  Te  Te6  1  0.154  0.347  0.554  1.0
  Te  Te7  1  0.593  0.265  0.103  1.0
  As  As8  1  0.055  0.681  0.788  1.0
  As  As9  1  0.445  0.681  0.288  1.0
  As  As10  1  0.945  0.319  0.212  1.0
  As  As11  1  0.555  0.319  0.712  1.0
  C  C12  1  0.936  0.997  0.007  1.0
  C  C13  1  0.064  0.003  0.993  1.0
  C  C14  1  0.564  0.997  0.507  1.0
  C  C15  1  0.436  0.003  0.493  1.0
  N  N16  1  0.674  0.991  0.519  1.0
  N  N17  1  0.326  0.009  0.481  1.0
  N  N18  1  0.174  0.009  0.981  1.0
  N  N19  1  0.826  0.991  0.019  1.0
  F  F20  1  0.818  0.438  0.250  1.0
  F  F21  1  0.534  0.445  0.333  1.0
  F  F22  1  0.466  0.555  0.667  1.0
  F  F23  1  0.490  0.225  0.845  1.0
  F  F24  1  0.876  0.402  0.079  1.0
  F  F25  1  0.932  0.808  0.827  1.0
  F  F26  1  0.510  0.775  0.155  1.0
  F  F27  1  0.682  0.438  0.750  1.0
  F  F28  1  0.624  0.402  0.579  1.0
  F  F29  1  0.568  0.808  0.327  1.0
  F  F30  1  0.356  0.924  0.244  1.0
  F  F31  1  0.856  0.076  0.256  1.0
  F  F32  1  0.376  0.598  0.421  1.0
  F  F33  1  0.644  0.076  0.756  1.0
  F  F34  1  0.010  0.225  0.345  1.0
  F  F35  1  0.966  0.445  0.833  1.0
  F  F36  1  0.124  0.598  0.921  1.0
  F  F37  1  0.432  0.192  0.673  1.0
  F  F38  1  0.068  0.192  0.173  1.0
  F  F39  1  0.990  0.775  0.655  1.0
  F  F40  1  0.182  0.562  0.750  1.0
  F  F41  1  0.318  0.562  0.250  1.0
  F  F42  1  0.034  0.555  0.167  1.0
  F  F43  1  0.144  0.924  0.744  1.0
[/CIF]
.
The crystal structure described by CN(Te)2AsF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two cyanogen molecules, two tellurium tetramer molecules, and four AsF6 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_Te2AsCNF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.603
_cell_length_b   6.958
_cell_length_c   13.515
_cell_angle_alpha   64.652
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   900.970
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.093  0.735  0.397  1.0
  Te  Te1  1  0.654  0.653  0.946  1.0
  Te  Te2  1  0.846  0.653  0.446  1.0
  Te  Te3  1  0.346  0.347  0.054  1.0
  Te  Te4  1  0.907  0.265  0.603  1.0
  Te  Te5  1  0.407  0.735  0.897  1.0
  Te  Te6  1  0.154  0.347  0.554  1.0
  Te  Te7  1  0.593  0.265  0.103  1.0
  As  As8  1  0.055  0.681  0.788  1.0
  As  As9  1  0.445  0.681  0.288  1.0
  As  As10  1  0.945  0.319  0.212  1.0
  As  As11  1  0.555  0.319  0.712  1.0
  C  C12  1  0.936  0.997  0.007  1.0
  C  C13  1  0.064  0.003  0.993  1.0
  C  C14  1  0.564  0.997  0.507  1.0
  C  C15  1  0.436  0.003  0.493  1.0
  N  N16  1  0.674  0.991  0.519  1.0
  N  N17  1  0.326  0.009  0.481  1.0
  N  N18  1  0.174  0.009  0.981  1.0
  N  N19  1  0.826  0.991  0.019  1.0
  F  F20  1  0.818  0.438  0.250  1.0
  F  F21  1  0.534  0.445  0.333  1.0
  F  F22  1  0.466  0.555  0.667  1.0
  F  F23  1  0.490  0.225  0.845  1.0
  F  F24  1  0.876  0.402  0.079  1.0
  F  F25  1  0.932  0.808  0.827  1.0
  F  F26  1  0.510  0.775  0.155  1.0
  F  F27  1  0.682  0.438  0.750  1.0
  F  F28  1  0.624  0.402  0.579  1.0
  F  F29  1  0.568  0.808  0.327  1.0
  F  F30  1  0.356  0.924  0.244  1.0
  F  F31  1  0.856  0.076  0.256  1.0
  F  F32  1  0.376  0.598  0.421  1.0
  F  F33  1  0.644  0.076  0.756  1.0
  F  F34  1  0.010  0.225  0.345  1.0
  F  F35  1  0.966  0.445  0.833  1.0
  F  F36  1  0.124  0.598  0.921  1.0
  F  F37  1  0.432  0.192  0.673  1.0
  F  F38  1  0.068  0.192  0.173  1.0
  F  F39  1  0.990  0.775  0.655  1.0
  F  F40  1  0.182  0.562  0.750  1.0
  F  F41  1  0.318  0.562  0.250  1.0
  F  F42  1  0.034  0.555  0.167  1.0
  F  F43  1  0.144  0.924  0.744  1.0
[/CIF]
.