The crystal structure described by CN2S is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four aminothiocyanate molecules. C(1) is bonded in a distorted single-bond geometry to one N(2) and one S(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one S(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted water-like geometry to one C(1) and one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CSN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.812
_cell_length_b   6.652
_cell_length_c   12.203
_cell_angle_alpha   90.000
_cell_angle_beta   93.017
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   309.024
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.877  0.361  0.603  1.0
  C  C1  1  0.123  0.861  0.897  1.0
  C  C2  1  0.123  0.639  0.397  1.0
  C  C3  1  0.877  0.139  0.103  1.0
  S  S4  1  0.971  0.593  0.686  1.0
  S  S5  1  0.029  0.093  0.814  1.0
  S  S6  1  0.029  0.407  0.314  1.0
  S  S7  1  0.971  0.907  0.186  1.0
  N  N8  1  0.678  0.739  0.674  1.0
  N  N9  1  0.322  0.239  0.826  1.0
  N  N10  1  0.322  0.261  0.326  1.0
  N  N11  1  0.678  0.761  0.174  1.0
  N  N12  1  0.825  0.215  0.551  1.0
  N  N13  1  0.175  0.715  0.949  1.0
  N  N14  1  0.175  0.785  0.449  1.0
  N  N15  1  0.825  0.285  0.051  1.0
[/CIF]
.
The crystal structure described by CN2S is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four aminothiocyanate molecules. C(1) is bonded in a distorted single-bond geometry to one N(2) and one S(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one S(1) atom. In the second N site, N(2) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted water-like geometry to one C(1) and one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CSN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.812
_cell_length_b   6.652
_cell_length_c   12.203
_cell_angle_alpha   90.000
_cell_angle_beta   93.017
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   309.024
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.877  0.361  0.603  1.0
  C  C1  1  0.123  0.861  0.897  1.0
  C  C2  1  0.123  0.639  0.397  1.0
  C  C3  1  0.877  0.139  0.103  1.0
  S  S4  1  0.971  0.593  0.686  1.0
  S  S5  1  0.029  0.093  0.814  1.0
  S  S6  1  0.029  0.407  0.314  1.0
  S  S7  1  0.971  0.907  0.186  1.0
  N  N8  1  0.678  0.739  0.674  1.0
  N  N9  1  0.322  0.239  0.826  1.0
  N  N10  1  0.322  0.261  0.326  1.0
  N  N11  1  0.678  0.761  0.174  1.0
  N  N12  1  0.825  0.215  0.551  1.0
  N  N13  1  0.175  0.715  0.949  1.0
  N  N14  1  0.175  0.785  0.449  1.0
  N  N15  1  0.825  0.285  0.051  1.0
[/CIF]
.