The compound described by Mo8NiP3 crystallizes in the triclinic P1 space group. There are thirty-two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 14-coordinate geometry to one Mo(13), one Mo(19), one Mo(27), one Mo(30), one Mo(4), two equivalent Mo(10), two equivalent Mo(7), one Ni(4), two equivalent Ni(1), one P(1), and one P(7) atom. In the second Mo site, Mo(2) is bonded in a 14-coordinate geometry to one Mo(14), one Mo(20), one Mo(25), one Mo(28), one Mo(31), one Mo(5), two equivalent Mo(11), two equivalent Mo(8), two equivalent Ni(2), one P(2), and one P(8) atom. In the third Mo site, Mo(3) is bonded in a 14-coordinate geometry to one Mo(15), one Mo(21), one Mo(26), one Mo(29), one Mo(32), one Mo(6), two equivalent Mo(12), two equivalent Mo(9), two equivalent Ni(3), one P(3), and one P(9) atom. In the fourth Mo site, Mo(4) is bonded in a 14-coordinate geometry to one Mo(1), one Mo(16), one Mo(22), one Mo(27), one Mo(30), two equivalent Mo(10), two equivalent Mo(7), one Ni(1), two equivalent Ni(4), one P(10), and one P(4) atom. In the fifth Mo site, Mo(5) is bonded in a 14-coordinate geometry to one Mo(17), one Mo(2), one Mo(23), one Mo(28), one Mo(31), two equivalent Mo(11), two equivalent Mo(25), two equivalent Mo(8), one Ni(2), one P(11), and one P(5) atom. In the sixth Mo site, Mo(6) is bonded in a 14-coordinate geometry to one Mo(18), one Mo(24), one Mo(29), one Mo(3), one Mo(32), two equivalent Mo(12), two equivalent Mo(26), two equivalent Mo(9), one Ni(3), one P(12), and one P(6) atom. In the seventh Mo site, Mo(7) is bonded in a 3-coordinate geometry to one Mo(10), two equivalent Mo(1), two equivalent Mo(4), one P(4), and one P(7) atom. In the eighth Mo site, Mo(8) is bonded in a 14-coordinate geometry to one Mo(11), one Mo(17), one Mo(20), one Mo(25), one Mo(30), two equivalent Mo(2), two equivalent Mo(28), two equivalent Mo(5), one Ni(2), one P(5), and one P(8) atom. In the ninth Mo site, Mo(9) is bonded in a 3-coordinate geometry to one Mo(12), two equivalent Mo(3), two equivalent Mo(6), one P(6), and one P(9) atom. In the tenth Mo site, Mo(10) is bonded in a 3-coordinate geometry to one Mo(7), two equivalent Mo(1), two equivalent Mo(4), one P(1), and one P(10) atom. In the eleventh Mo site, Mo(11) is bonded in a 14-coordinate geometry to one Mo(14), one Mo(23), one Mo(25), one Mo(29), one Mo(8), two equivalent Mo(2), two equivalent Mo(31), two equivalent Mo(5), one Ni(2), one P(11), and one P(2) atom. In the twelfth Mo site, Mo(12) is bonded in a 14-coordinate geometry to one Mo(15), one Mo(24), one Mo(26), one Mo(27), one Mo(9), two equivalent Mo(3), two equivalent Mo(32), two equivalent Mo(6), one Ni(3), one P(12), and one P(3) atom. In the thirteenth Mo site, Mo(13) is bonded in a 5-coordinate geometry to one Mo(1), one Ni(1), one P(10), one P(8), and two equivalent P(1) atoms. In the fourteenth Mo site, Mo(14) is bonded in a 5-coordinate geometry to one Mo(11), one Mo(2), one Ni(2), one P(11), one P(9), and two equivalent P(2) atoms. In the fifteenth Mo site, Mo(15) is bonded in a 5-coordinate geometry to one Mo(12), one Mo(3), one Ni(3), one P(12), one P(7), and two equivalent P(3) atoms. In the sixteenth Mo site, Mo(16) is bonded in a 5-coordinate geometry to one Mo(4), one Ni(4), one P(12), one P(7), and two equivalent P(4) atoms. In the seventeenth Mo site, Mo(17) is bonded in a 4-coordinate geometry to one Mo(5), one Mo(8), one P(10), one P(8), and two equivalent P(5) atoms. In the eighteenth Mo site, Mo(18) is bonded in a 4-coordinate geometry to one Mo(6), one P(11), one P(9), and two equivalent P(6) atoms. In the nineteenth Mo site, Mo(19) is bonded in a 5-coordinate geometry to one Mo(1), one Ni(1), one P(3), one P(4), and two equivalent P(7) atoms. In the twentieth Mo site, Mo(20) is bonded in a 5-coordinate geometry to one Mo(2), one Mo(8), one Ni(2), one P(1), one P(5), and two equivalent P(8) atoms. In the twenty-first Mo site, Mo(21) is bonded in a 5-coordinate geometry to one Mo(3), one Ni(3), one P(2), one P(6), and two equivalent P(9) atoms. In the twenty-second Mo site, Mo(22) is bonded in a 5-coordinate geometry to one Mo(4), one Ni(4), one P(1), one P(5), and two equivalent P(10) atoms. In the twenty-third Mo site, Mo(23) is bonded in a 4-coordinate geometry to one Mo(11), one Mo(5), one P(2), one P(6), and two equivalent P(11) atoms. In the twenty-fourth Mo site, Mo(24) is bonded in a 4-coordinate geometry to one Mo(12), one Mo(6), one P(3), one P(4), and two equivalent P(12) atoms. In the twenty-fifth Mo site, Mo(25) is bonded in a 4-coordinate geometry to one Mo(11), one Mo(2), one Mo(8), two equivalent Mo(5), two equivalent Ni(2), one P(11), and one P(5) atom. In the twenty-sixth Mo site, Mo(26) is bonded in a 4-coordinate geometry to one Mo(12), one Mo(3), two equivalent Mo(6), two equivalent Ni(3), one P(12), one P(3), and one P(6) atom. In the twenty-seventh Mo site, Mo(27) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(12), one Mo(4), one P(4), and one P(7) atom. In the twenty-eighth Mo site, Mo(28) is bonded in a 2-coordinate geometry to one Mo(2), one Mo(5), two equivalent Mo(8), one P(5), and one P(8) atom. In the twenty-ninth Mo site, Mo(29) is bonded in a 2-coordinate geometry to one Mo(11), one Mo(3), one Mo(6), one P(6), and one P(9) atom. In the thirtieth Mo site, Mo(30) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(4), one Mo(8), one P(1), and one P(10) atom. In the thirty-first Mo site, Mo(31) is bonded in a 2-coordinate geometry to one Mo(2), one Mo(5), two equivalent Mo(11), one P(11), and one P(2) atom. In the thirty-second Mo site, Mo(32) is bonded in a 2-coordinate geometry to one Mo(3), one Mo(6), two equivalent Mo(12), one P(12), and one P(3) atom. There are four inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 2-coordinate geometry to one Mo(13), one Mo(19), one Mo(4), two equivalent Mo(1), one P(1), and one P(7) atom. In the second Ni site, Ni(2) is bonded in a 2-coordinate geometry to one Mo(11), one Mo(14), one Mo(20), one Mo(5), one Mo(8), two equivalent Mo(2), two equivalent Mo(25), one P(2), and one P(8) atom. In the third Ni site, Ni(3) is bonded in a 2-coordinate geometry to one Mo(12), one Mo(15), one Mo(21), one Mo(6), two equivalent Mo(26), two equivalent Mo(3), one P(3), and one P(9) atom. In the fourth Ni site, Ni(4) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(16), one Mo(22), two equivalent Mo(4), one P(10), and one P(4) atom. There are twelve inequivalent P sites. In the first P site, P(1) is bonded in a 8-coordinate geometry to one Mo(1), one Mo(10), one Mo(20), one Mo(22), one Mo(30), two equivalent Mo(13), and one Ni(1) atom. In the second P site, P(2) is bonded in a 1-coordinate geometry to one Mo(11), one Mo(2), one Mo(21), one Mo(23), one Mo(31), two equivalent Mo(14), and one Ni(2) atom. In the third P site, P(3) is bonded in a 9-coordinate geometry to one Mo(12), one Mo(19), one Mo(24), one Mo(26), one Mo(3), one Mo(32), two equivalent Mo(15), and one Ni(3) atom. In the fourth P site, P(4) is bonded in a 8-coordinate geometry to one Mo(19), one Mo(24), one Mo(27), one Mo(4), one Mo(7), two equivalent Mo(16), and one Ni(4) atom. In the fifth P site, P(5) is bonded in a 8-coordinate geometry to one Mo(20), one Mo(22), one Mo(25), one Mo(28), one Mo(5), one Mo(8), and two equivalent Mo(17) atoms. In the sixth P site, P(6) is bonded in a 8-coordinate geometry to one Mo(21), one Mo(23), one Mo(26), one Mo(29), one Mo(6), one Mo(9), and two equivalent Mo(18) atoms. In the seventh P site, P(7) is bonded in a 8-coordinate geometry to one Mo(1), one Mo(15), one Mo(16), one Mo(27), one Mo(7), two equivalent Mo(19), and one Ni(1) atom. In the eighth P site, P(8) is bonded in a 8-coordinate geometry to one Mo(13), one Mo(17), one Mo(2), one Mo(28), one Mo(8), two equivalent Mo(20), and one Ni(2) atom. In the ninth P site, P(9) is bonded in a 8-coordinate geometry to one Mo(14), one Mo(18), one Mo(29), one Mo(3), one Mo(9), two equivalent Mo(21), and one Ni(3) atom. In the tenth P site, P(10) is bonded in a 8-coordinate geometry to one Mo(10), one Mo(13), one Mo(17), one Mo(30), one Mo(4), two equivalent Mo(22), and one Ni(4) atom. In the eleventh P site, P(11) is bonded in a 8-coordinate geometry to one Mo(11), one Mo(14), one Mo(18), one Mo(25), one Mo(31), one Mo(5), and two equivalent Mo(23) atoms. In the twelfth P site, P(12) is bonded in a 8-coordinate geometry to one Mo(12), one Mo(15), one Mo(16), one Mo(26), one Mo(32), one Mo(6), and two equivalent Mo(24) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_NiMo8P3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.804
_cell_length_b   7.351
_cell_length_c   20.865
_cell_angle_alpha   87.328
_cell_angle_beta   83.826
_cell_angle_gamma   71.066
_symmetry_Int_Tables_number   1
_cell_volume   692.854
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.442  0.903  0.163  1.0
  Ni  Ni1  1  0.787  0.894  0.495  1.0
  Ni  Ni2  1  0.122  0.893  0.828  1.0
  Ni  Ni3  1  0.844  0.094  0.170  1.0
  Mo  Mo4  1  0.049  0.688  0.165  1.0
  Mo  Mo5  1  0.387  0.683  0.498  1.0
  Mo  Mo6  1  0.720  0.684  0.831  1.0
  Mo  Mo7  1  0.237  0.311  0.169  1.0
  Mo  Mo8  1  0.583  0.308  0.502  1.0
  Mo  Mo9  1  0.913  0.309  0.836  1.0
  Mo  Mo10  1  0.721  0.495  0.106  1.0
  Mo  Mo11  1  0.049  0.497  0.438  1.0
  Mo  Mo12  1  0.385  0.496  0.772  1.0
  Mo  Mo13  1  0.654  0.505  0.228  1.0
  Mo  Mo14  1  0.984  0.505  0.562  1.0
  Mo  Mo15  1  0.314  0.506  0.895  1.0
  Mo  Mo16  1  0.681  0.860  0.281  1.0
  Mo  Mo17  1  0.009  0.859  0.616  1.0
  Mo  Mo18  1  0.340  0.859  0.950  1.0
  Mo  Mo19  1  0.154  0.137  0.053  1.0
  Mo  Mo20  1  0.483  0.143  0.382  1.0
  Mo  Mo21  1  0.816  0.141  0.718  1.0
  Mo  Mo22  1  0.804  0.849  0.049  1.0
  Mo  Mo23  1  0.138  0.853  0.380  1.0
  Mo  Mo24  1  0.472  0.852  0.714  1.0
  Mo  Mo25  1  0.035  0.151  0.284  1.0
  Mo  Mo26  1  0.357  0.154  0.622  1.0
  Mo  Mo27  1  0.690  0.155  0.957  1.0
  Mo  Mo28  1  0.189  0.086  0.504  1.0
  Mo  Mo29  1  0.522  0.086  0.839  1.0
  Mo  Mo30  1  0.253  0.490  0.031  1.0
  Mo  Mo31  1  0.581  0.495  0.366  1.0
  Mo  Mo32  1  0.918  0.495  0.699  1.0
  Mo  Mo33  1  0.109  0.509  0.301  1.0
  Mo  Mo34  1  0.441  0.513  0.633  1.0
  Mo  Mo35  1  0.770  0.515  0.967  1.0
  P  P36  1  0.228  0.802  0.258  1.0
  P  P37  1  0.556  0.809  0.589  1.0
  P  P38  1  0.886  0.812  0.923  1.0
  P  P39  1  0.620  0.197  0.077  1.0
  P  P40  1  0.946  0.202  0.405  1.0
  P  P41  1  0.277  0.202  0.740  1.0
  P  P42  1  0.335  0.782  0.069  1.0
  P  P43  1  0.666  0.788  0.402  1.0
  P  P44  1  0.000  0.786  0.736  1.0
  P  P45  1  0.520  0.215  0.264  1.0
  P  P46  1  0.840  0.216  0.600  1.0
  P  P47  1  0.172  0.217  0.935  1.0
[/CIF]
.
The compound described by Mo8NiP3 crystallizes in the triclinic P1 space group. There are thirty-two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 14-coordinate geometry to one Mo(13), one Mo(19), one Mo(27), one Mo(30), one Mo(4), two equivalent Mo(10), two equivalent Mo(7), one Ni(4), two equivalent Ni(1), one P(1), and one P(7) atom. In the second Mo site, Mo(2) is bonded in a 14-coordinate geometry to one Mo(14), one Mo(20), one Mo(25), one Mo(28), one Mo(31), one Mo(5), two equivalent Mo(11), two equivalent Mo(8), two equivalent Ni(2), one P(2), and one P(8) atom. In the third Mo site, Mo(3) is bonded in a 14-coordinate geometry to one Mo(15), one Mo(21), one Mo(26), one Mo(29), one Mo(32), one Mo(6), two equivalent Mo(12), two equivalent Mo(9), two equivalent Ni(3), one P(3), and one P(9) atom. In the fourth Mo site, Mo(4) is bonded in a 14-coordinate geometry to one Mo(1), one Mo(16), one Mo(22), one Mo(27), one Mo(30), two equivalent Mo(10), two equivalent Mo(7), one Ni(1), two equivalent Ni(4), one P(10), and one P(4) atom. In the fifth Mo site, Mo(5) is bonded in a 14-coordinate geometry to one Mo(17), one Mo(2), one Mo(23), one Mo(28), one Mo(31), two equivalent Mo(11), two equivalent Mo(25), two equivalent Mo(8), one Ni(2), one P(11), and one P(5) atom. In the sixth Mo site, Mo(6) is bonded in a 14-coordinate geometry to one Mo(18), one Mo(24), one Mo(29), one Mo(3), one Mo(32), two equivalent Mo(12), two equivalent Mo(26), two equivalent Mo(9), one Ni(3), one P(12), and one P(6) atom. In the seventh Mo site, Mo(7) is bonded in a 3-coordinate geometry to one Mo(10), two equivalent Mo(1), two equivalent Mo(4), one P(4), and one P(7) atom. In the eighth Mo site, Mo(8) is bonded in a 14-coordinate geometry to one Mo(11), one Mo(17), one Mo(20), one Mo(25), one Mo(30), two equivalent Mo(2), two equivalent Mo(28), two equivalent Mo(5), one Ni(2), one P(5), and one P(8) atom. In the ninth Mo site, Mo(9) is bonded in a 3-coordinate geometry to one Mo(12), two equivalent Mo(3), two equivalent Mo(6), one P(6), and one P(9) atom. In the tenth Mo site, Mo(10) is bonded in a 3-coordinate geometry to one Mo(7), two equivalent Mo(1), two equivalent Mo(4), one P(1), and one P(10) atom. In the eleventh Mo site, Mo(11) is bonded in a 14-coordinate geometry to one Mo(14), one Mo(23), one Mo(25), one Mo(29), one Mo(8), two equivalent Mo(2), two equivalent Mo(31), two equivalent Mo(5), one Ni(2), one P(11), and one P(2) atom. In the twelfth Mo site, Mo(12) is bonded in a 14-coordinate geometry to one Mo(15), one Mo(24), one Mo(26), one Mo(27), one Mo(9), two equivalent Mo(3), two equivalent Mo(32), two equivalent Mo(6), one Ni(3), one P(12), and one P(3) atom. In the thirteenth Mo site, Mo(13) is bonded in a 5-coordinate geometry to one Mo(1), one Ni(1), one P(10), one P(8), and two equivalent P(1) atoms. In the fourteenth Mo site, Mo(14) is bonded in a 5-coordinate geometry to one Mo(11), one Mo(2), one Ni(2), one P(11), one P(9), and two equivalent P(2) atoms. In the fifteenth Mo site, Mo(15) is bonded in a 5-coordinate geometry to one Mo(12), one Mo(3), one Ni(3), one P(12), one P(7), and two equivalent P(3) atoms. In the sixteenth Mo site, Mo(16) is bonded in a 5-coordinate geometry to one Mo(4), one Ni(4), one P(12), one P(7), and two equivalent P(4) atoms. In the seventeenth Mo site, Mo(17) is bonded in a 4-coordinate geometry to one Mo(5), one Mo(8), one P(10), one P(8), and two equivalent P(5) atoms. In the eighteenth Mo site, Mo(18) is bonded in a 4-coordinate geometry to one Mo(6), one P(11), one P(9), and two equivalent P(6) atoms. In the nineteenth Mo site, Mo(19) is bonded in a 5-coordinate geometry to one Mo(1), one Ni(1), one P(3), one P(4), and two equivalent P(7) atoms. In the twentieth Mo site, Mo(20) is bonded in a 5-coordinate geometry to one Mo(2), one Mo(8), one Ni(2), one P(1), one P(5), and two equivalent P(8) atoms. In the twenty-first Mo site, Mo(21) is bonded in a 5-coordinate geometry to one Mo(3), one Ni(3), one P(2), one P(6), and two equivalent P(9) atoms. In the twenty-second Mo site, Mo(22) is bonded in a 5-coordinate geometry to one Mo(4), one Ni(4), one P(1), one P(5), and two equivalent P(10) atoms. In the twenty-third Mo site, Mo(23) is bonded in a 4-coordinate geometry to one Mo(11), one Mo(5), one P(2), one P(6), and two equivalent P(11) atoms. In the twenty-fourth Mo site, Mo(24) is bonded in a 4-coordinate geometry to one Mo(12), one Mo(6), one P(3), one P(4), and two equivalent P(12) atoms. In the twenty-fifth Mo site, Mo(25) is bonded in a 4-coordinate geometry to one Mo(11), one Mo(2), one Mo(8), two equivalent Mo(5), two equivalent Ni(2), one P(11), and one P(5) atom. In the twenty-sixth Mo site, Mo(26) is bonded in a 4-coordinate geometry to one Mo(12), one Mo(3), two equivalent Mo(6), two equivalent Ni(3), one P(12), one P(3), and one P(6) atom. In the twenty-seventh Mo site, Mo(27) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(12), one Mo(4), one P(4), and one P(7) atom. In the twenty-eighth Mo site, Mo(28) is bonded in a 2-coordinate geometry to one Mo(2), one Mo(5), two equivalent Mo(8), one P(5), and one P(8) atom. In the twenty-ninth Mo site, Mo(29) is bonded in a 2-coordinate geometry to one Mo(11), one Mo(3), one Mo(6), one P(6), and one P(9) atom. In the thirtieth Mo site, Mo(30) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(4), one Mo(8), one P(1), and one P(10) atom. In the thirty-first Mo site, Mo(31) is bonded in a 2-coordinate geometry to one Mo(2), one Mo(5), two equivalent Mo(11), one P(11), and one P(2) atom. In the thirty-second Mo site, Mo(32) is bonded in a 2-coordinate geometry to one Mo(3), one Mo(6), two equivalent Mo(12), one P(12), and one P(3) atom. There are four inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 2-coordinate geometry to one Mo(13), one Mo(19), one Mo(4), two equivalent Mo(1), one P(1), and one P(7) atom. In the second Ni site, Ni(2) is bonded in a 2-coordinate geometry to one Mo(11), one Mo(14), one Mo(20), one Mo(5), one Mo(8), two equivalent Mo(2), two equivalent Mo(25), one P(2), and one P(8) atom. In the third Ni site, Ni(3) is bonded in a 2-coordinate geometry to one Mo(12), one Mo(15), one Mo(21), one Mo(6), two equivalent Mo(26), two equivalent Mo(3), one P(3), and one P(9) atom. In the fourth Ni site, Ni(4) is bonded in a 2-coordinate geometry to one Mo(1), one Mo(16), one Mo(22), two equivalent Mo(4), one P(10), and one P(4) atom. There are twelve inequivalent P sites. In the first P site, P(1) is bonded in a 8-coordinate geometry to one Mo(1), one Mo(10), one Mo(20), one Mo(22), one Mo(30), two equivalent Mo(13), and one Ni(1) atom. In the second P site, P(2) is bonded in a 1-coordinate geometry to one Mo(11), one Mo(2), one Mo(21), one Mo(23), one Mo(31), two equivalent Mo(14), and one Ni(2) atom. In the third P site, P(3) is bonded in a 9-coordinate geometry to one Mo(12), one Mo(19), one Mo(24), one Mo(26), one Mo(3), one Mo(32), two equivalent Mo(15), and one Ni(3) atom. In the fourth P site, P(4) is bonded in a 8-coordinate geometry to one Mo(19), one Mo(24), one Mo(27), one Mo(4), one Mo(7), two equivalent Mo(16), and one Ni(4) atom. In the fifth P site, P(5) is bonded in a 8-coordinate geometry to one Mo(20), one Mo(22), one Mo(25), one Mo(28), one Mo(5), one Mo(8), and two equivalent Mo(17) atoms. In the sixth P site, P(6) is bonded in a 8-coordinate geometry to one Mo(21), one Mo(23), one Mo(26), one Mo(29), one Mo(6), one Mo(9), and two equivalent Mo(18) atoms. In the seventh P site, P(7) is bonded in a 8-coordinate geometry to one Mo(1), one Mo(15), one Mo(16), one Mo(27), one Mo(7), two equivalent Mo(19), and one Ni(1) atom. In the eighth P site, P(8) is bonded in a 8-coordinate geometry to one Mo(13), one Mo(17), one Mo(2), one Mo(28), one Mo(8), two equivalent Mo(20), and one Ni(2) atom. In the ninth P site, P(9) is bonded in a 8-coordinate geometry to one Mo(14), one Mo(18), one Mo(29), one Mo(3), one Mo(9), two equivalent Mo(21), and one Ni(3) atom. In the tenth P site, P(10) is bonded in a 8-coordinate geometry to one Mo(10), one Mo(13), one Mo(17), one Mo(30), one Mo(4), two equivalent Mo(22), and one Ni(4) atom. In the eleventh P site, P(11) is bonded in a 8-coordinate geometry to one Mo(11), one Mo(14), one Mo(18), one Mo(25), one Mo(31), one Mo(5), and two equivalent Mo(23) atoms. In the twelfth P site, P(12) is bonded in a 8-coordinate geometry to one Mo(12), one Mo(15), one Mo(16), one Mo(26), one Mo(32), one Mo(6), and two equivalent Mo(24) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_NiMo8P3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.804
_cell_length_b   7.351
_cell_length_c   20.865
_cell_angle_alpha   87.328
_cell_angle_beta   83.826
_cell_angle_gamma   71.066
_symmetry_Int_Tables_number   1
_cell_volume   692.854
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.442  0.903  0.163  1.0
  Ni  Ni1  1  0.787  0.894  0.495  1.0
  Ni  Ni2  1  0.122  0.893  0.828  1.0
  Ni  Ni3  1  0.844  0.094  0.170  1.0
  Mo  Mo4  1  0.049  0.688  0.165  1.0
  Mo  Mo5  1  0.387  0.683  0.498  1.0
  Mo  Mo6  1  0.720  0.684  0.831  1.0
  Mo  Mo7  1  0.237  0.311  0.169  1.0
  Mo  Mo8  1  0.583  0.308  0.502  1.0
  Mo  Mo9  1  0.913  0.309  0.836  1.0
  Mo  Mo10  1  0.721  0.495  0.106  1.0
  Mo  Mo11  1  0.049  0.497  0.438  1.0
  Mo  Mo12  1  0.385  0.496  0.772  1.0
  Mo  Mo13  1  0.654  0.505  0.228  1.0
  Mo  Mo14  1  0.984  0.505  0.562  1.0
  Mo  Mo15  1  0.314  0.506  0.895  1.0
  Mo  Mo16  1  0.681  0.860  0.281  1.0
  Mo  Mo17  1  0.009  0.859  0.616  1.0
  Mo  Mo18  1  0.340  0.859  0.950  1.0
  Mo  Mo19  1  0.154  0.137  0.053  1.0
  Mo  Mo20  1  0.483  0.143  0.382  1.0
  Mo  Mo21  1  0.816  0.141  0.718  1.0
  Mo  Mo22  1  0.804  0.849  0.049  1.0
  Mo  Mo23  1  0.138  0.853  0.380  1.0
  Mo  Mo24  1  0.472  0.852  0.714  1.0
  Mo  Mo25  1  0.035  0.151  0.284  1.0
  Mo  Mo26  1  0.357  0.154  0.622  1.0
  Mo  Mo27  1  0.690  0.155  0.957  1.0
  Mo  Mo28  1  0.189  0.086  0.504  1.0
  Mo  Mo29  1  0.522  0.086  0.839  1.0
  Mo  Mo30  1  0.253  0.490  0.031  1.0
  Mo  Mo31  1  0.581  0.495  0.366  1.0
  Mo  Mo32  1  0.918  0.495  0.699  1.0
  Mo  Mo33  1  0.109  0.509  0.301  1.0
  Mo  Mo34  1  0.441  0.513  0.633  1.0
  Mo  Mo35  1  0.770  0.515  0.967  1.0
  P  P36  1  0.228  0.802  0.258  1.0
  P  P37  1  0.556  0.809  0.589  1.0
  P  P38  1  0.886  0.812  0.923  1.0
  P  P39  1  0.620  0.197  0.077  1.0
  P  P40  1  0.946  0.202  0.405  1.0
  P  P41  1  0.277  0.202  0.740  1.0
  P  P42  1  0.335  0.782  0.069  1.0
  P  P43  1  0.666  0.788  0.402  1.0
  P  P44  1  0.000  0.786  0.736  1.0
  P  P45  1  0.520  0.215  0.264  1.0
  P  P46  1  0.840  0.216  0.600  1.0
  P  P47  1  0.172  0.217  0.935  1.0
[/CIF]
.