The structure described by La5Rh4 crystallizes in the orthorhombic Pnma space group. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 6-coordinate geometry to one Rh(3), two equivalent Rh(2), and three equivalent Rh(1) atoms. In the second La site, La(2) is bonded in a 7-coordinate geometry to one Rh(2), two equivalent Rh(3), and four equivalent Rh(1) atoms. In the third La site, La(3) is bonded in a 6-coordinate geometry to two equivalent Rh(1), two equivalent Rh(2), and two equivalent Rh(3) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(3) is bonded in a 9-coordinate geometry to two equivalent La(1), two equivalent La(3), four equivalent La(2), and one Rh(2) atom. In the second Rh site, Rh(1) is bonded in a 8-coordinate geometry to one La(3), three equivalent La(1), and four equivalent La(2) atoms. In the third Rh site, Rh(2) is bonded in a 9-coordinate geometry to two equivalent La(2), two equivalent La(3), four equivalent La(1), and one Rh(3) atom. is represented by the CIF file [CIF]
data_La5Rh4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.646
_cell_length_b   7.724
_cell_length_c   15.427
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   911.158
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.339  0.835  0.878  1.0
  La  La1  1  0.839  0.665  0.622  1.0
  La  La2  1  0.661  0.165  0.378  1.0
  La  La3  1  0.161  0.335  0.122  1.0
  La  La4  1  0.661  0.165  0.122  1.0
  La  La5  1  0.161  0.335  0.378  1.0
  La  La6  1  0.339  0.835  0.622  1.0
  La  La7  1  0.839  0.665  0.878  1.0
  La  La8  1  0.496  0.318  0.909  1.0
  La  La9  1  0.996  0.182  0.591  1.0
  La  La10  1  0.504  0.682  0.409  1.0
  La  La11  1  0.004  0.818  0.091  1.0
  La  La12  1  0.504  0.682  0.091  1.0
  La  La13  1  0.004  0.818  0.409  1.0
  La  La14  1  0.496  0.318  0.591  1.0
  La  La15  1  0.996  0.182  0.909  1.0
  La  La16  1  0.186  0.476  0.750  1.0
  La  La17  1  0.686  0.024  0.750  1.0
  La  La18  1  0.814  0.524  0.250  1.0
  La  La19  1  0.314  0.976  0.250  1.0
  Rh  Rh20  1  0.313  0.029  0.041  1.0
  Rh  Rh21  1  0.813  0.471  0.459  1.0
  Rh  Rh22  1  0.687  0.971  0.541  1.0
  Rh  Rh23  1  0.187  0.529  0.959  1.0
  Rh  Rh24  1  0.687  0.971  0.959  1.0
  Rh  Rh25  1  0.187  0.529  0.541  1.0
  Rh  Rh26  1  0.313  0.029  0.459  1.0
  Rh  Rh27  1  0.813  0.471  0.041  1.0
  Rh  Rh28  1  0.530  0.610  0.750  1.0
  Rh  Rh29  1  0.030  0.890  0.750  1.0
  Rh  Rh30  1  0.470  0.390  0.250  1.0
  Rh  Rh31  1  0.970  0.110  0.250  1.0
  Rh  Rh32  1  0.301  0.139  0.750  1.0
  Rh  Rh33  1  0.801  0.361  0.750  1.0
  Rh  Rh34  1  0.699  0.861  0.250  1.0
  Rh  Rh35  1  0.199  0.639  0.250  1.0
[/CIF]
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The structure described by La5Rh4 crystallizes in the orthorhombic Pnma space group. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 6-coordinate geometry to one Rh(3), two equivalent Rh(2), and three equivalent Rh(1) atoms. In the second La site, La(2) is bonded in a 7-coordinate geometry to one Rh(2), two equivalent Rh(3), and four equivalent Rh(1) atoms. In the third La site, La(3) is bonded in a 6-coordinate geometry to two equivalent Rh(1), two equivalent Rh(2), and two equivalent Rh(3) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(3) is bonded in a 9-coordinate geometry to two equivalent La(1), two equivalent La(3), four equivalent La(2), and one Rh(2) atom. In the second Rh site, Rh(1) is bonded in a 8-coordinate geometry to one La(3), three equivalent La(1), and four equivalent La(2) atoms. In the third Rh site, Rh(2) is bonded in a 9-coordinate geometry to two equivalent La(2), two equivalent La(3), four equivalent La(1), and one Rh(3) atom. is represented by the CIF file [CIF]
data_La5Rh4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.646
_cell_length_b   7.724
_cell_length_c   15.427
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   911.158
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.339  0.835  0.878  1.0
  La  La1  1  0.839  0.665  0.622  1.0
  La  La2  1  0.661  0.165  0.378  1.0
  La  La3  1  0.161  0.335  0.122  1.0
  La  La4  1  0.661  0.165  0.122  1.0
  La  La5  1  0.161  0.335  0.378  1.0
  La  La6  1  0.339  0.835  0.622  1.0
  La  La7  1  0.839  0.665  0.878  1.0
  La  La8  1  0.496  0.318  0.909  1.0
  La  La9  1  0.996  0.182  0.591  1.0
  La  La10  1  0.504  0.682  0.409  1.0
  La  La11  1  0.004  0.818  0.091  1.0
  La  La12  1  0.504  0.682  0.091  1.0
  La  La13  1  0.004  0.818  0.409  1.0
  La  La14  1  0.496  0.318  0.591  1.0
  La  La15  1  0.996  0.182  0.909  1.0
  La  La16  1  0.186  0.476  0.750  1.0
  La  La17  1  0.686  0.024  0.750  1.0
  La  La18  1  0.814  0.524  0.250  1.0
  La  La19  1  0.314  0.976  0.250  1.0
  Rh  Rh20  1  0.313  0.029  0.041  1.0
  Rh  Rh21  1  0.813  0.471  0.459  1.0
  Rh  Rh22  1  0.687  0.971  0.541  1.0
  Rh  Rh23  1  0.187  0.529  0.959  1.0
  Rh  Rh24  1  0.687  0.971  0.959  1.0
  Rh  Rh25  1  0.187  0.529  0.541  1.0
  Rh  Rh26  1  0.313  0.029  0.459  1.0
  Rh  Rh27  1  0.813  0.471  0.041  1.0
  Rh  Rh28  1  0.530  0.610  0.750  1.0
  Rh  Rh29  1  0.030  0.890  0.750  1.0
  Rh  Rh30  1  0.470  0.390  0.250  1.0
  Rh  Rh31  1  0.970  0.110  0.250  1.0
  Rh  Rh32  1  0.301  0.139  0.750  1.0
  Rh  Rh33  1  0.801  0.361  0.750  1.0
  Rh  Rh34  1  0.699  0.861  0.250  1.0
  Rh  Rh35  1  0.199  0.639  0.250  1.0
[/CIF]
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