The crystal structure described by LiWAgZn2O6 crystallizes in the triclinic P1 space group. Li(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(6) atom. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with four equivalent Zn(1)O4 trigonal pyramids and corners with four equivalent Zn(2)O4 trigonal pyramids. Ag(1) is bonded in a linear geometry to one O(1) and one O(2) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form distorted ZnO4 trigonal pyramids that share corners with four equivalent W(1)O6 octahedra and  an edgeedge with one Zn(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 14-67°. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(4), and one O(6) atom to form distorted ZnO4 trigonal pyramids that share corners with four equivalent W(1)O6 octahedra and  an edgeedge with one Zn(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 14-69°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one W(1), one Ag(1), and one Zn(2) atom to form corner-sharing OLiZnAgW trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), one W(1), one Ag(1), and one Zn(1) atom to form corner-sharing OLiZnAgW trigonal pyramids. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one W(1), one Zn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a linear geometry to one W(1) and one Zn(2) atom. In the fifth O site, O(5) is bonded in a linear geometry to one W(1) and one Zn(1) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one W(1), one Zn(1), and one Zn(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiZn2AgWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.935
_cell_length_b   6.835
_cell_length_c   7.196
_cell_angle_alpha   89.132
_cell_angle_beta   128.705
_cell_angle_gamma   127.533
_symmetry_Int_Tables_number   1
_cell_volume   145.707
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.531  0.498  0.500  1.0
  Zn  Zn1  1  0.992  0.530  0.193  1.0
  Zn  Zn2  1  0.991  0.413  0.803  1.0
  Ag  Ag3  1  0.003  0.003  0.502  1.0
  W  W4  1  0.992  0.975  0.999  1.0
  O  O5  1  0.340  0.125  0.412  1.0
  O  O6  1  0.652  0.840  0.587  1.0
  O  O7  1  0.018  0.280  0.053  1.0
  O  O8  1  0.443  0.670  0.850  1.0
  O  O9  1  0.539  0.284  0.145  1.0
  O  O10  1  0.971  0.678  0.946  1.0
[/CIF]
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The crystal structure described by LiWAgZn2O6 crystallizes in the triclinic P1 space group. Li(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(6) atom. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with four equivalent Zn(1)O4 trigonal pyramids and corners with four equivalent Zn(2)O4 trigonal pyramids. Ag(1) is bonded in a linear geometry to one O(1) and one O(2) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form distorted ZnO4 trigonal pyramids that share corners with four equivalent W(1)O6 octahedra and  an edgeedge with one Zn(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 14-67°. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(4), and one O(6) atom to form distorted ZnO4 trigonal pyramids that share corners with four equivalent W(1)O6 octahedra and  an edgeedge with one Zn(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 14-69°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one W(1), one Ag(1), and one Zn(2) atom to form corner-sharing OLiZnAgW trigonal pyramids. In the second O site, O(2) is bonded to one Li(1), one W(1), one Ag(1), and one Zn(1) atom to form corner-sharing OLiZnAgW trigonal pyramids. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one W(1), one Zn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a linear geometry to one W(1) and one Zn(2) atom. In the fifth O site, O(5) is bonded in a linear geometry to one W(1) and one Zn(1) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(1), one W(1), one Zn(1), and one Zn(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiZn2AgWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.935
_cell_length_b   6.835
_cell_length_c   7.196
_cell_angle_alpha   89.132
_cell_angle_beta   128.705
_cell_angle_gamma   127.533
_symmetry_Int_Tables_number   1
_cell_volume   145.707
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.531  0.498  0.500  1.0
  Zn  Zn1  1  0.992  0.530  0.193  1.0
  Zn  Zn2  1  0.991  0.413  0.803  1.0
  Ag  Ag3  1  0.003  0.003  0.502  1.0
  W  W4  1  0.992  0.975  0.999  1.0
  O  O5  1  0.340  0.125  0.412  1.0
  O  O6  1  0.652  0.840  0.587  1.0
  O  O7  1  0.018  0.280  0.053  1.0
  O  O8  1  0.443  0.670  0.850  1.0
  O  O9  1  0.539  0.284  0.145  1.0
  O  O10  1  0.971  0.678  0.946  1.0
[/CIF]
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