The compound described by Te7(OF5)6 is Copper structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of three Te7(OF5)6 clusters. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing TeOF5 octahedra. The corner-sharing octahedral tilt angles are 43°. In the second Te site, Te(2) is bonded to six equivalent O(1) atoms to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles are 43°. O(1) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(2) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF file [CIF]
data_Te7(OF5)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.771
_cell_length_b   10.771
_cell_length_c   10.771
_cell_angle_alpha   50.121
_cell_angle_beta   50.121
_cell_angle_gamma   50.121
_symmetry_Int_Tables_number   1
_cell_volume   677.331
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.768  0.392  0.081  1.0
  Te  Te1  1  0.608  0.919  0.232  1.0
  Te  Te2  1  0.392  0.081  0.768  1.0
  Te  Te3  1  0.919  0.232  0.608  1.0
  Te  Te4  1  0.000  0.000  0.000  1.0
  Te  Te5  1  0.232  0.608  0.919  1.0
  Te  Te6  1  0.081  0.768  0.392  1.0
  O  O7  1  0.076  0.757  0.050  1.0
  O  O8  1  0.243  0.950  0.924  1.0
  O  O9  1  0.050  0.076  0.757  1.0
  O  O10  1  0.950  0.924  0.243  1.0
  O  O11  1  0.757  0.050  0.076  1.0
  O  O12  1  0.924  0.243  0.950  1.0
  F  F13  1  0.053  0.367  0.459  1.0
  F  F14  1  0.909  0.521  0.911  1.0
  F  F15  1  0.459  0.053  0.367  1.0
  F  F16  1  0.802  0.379  0.459  1.0
  F  F17  1  0.947  0.633  0.541  1.0
  F  F18  1  0.911  0.909  0.521  1.0
  F  F19  1  0.633  0.541  0.947  1.0
  F  F20  1  0.379  0.459  0.802  1.0
  F  F21  1  0.267  0.253  0.622  1.0
  F  F22  1  0.521  0.911  0.909  1.0
  F  F23  1  0.091  0.479  0.089  1.0
  F  F24  1  0.541  0.947  0.633  1.0
  F  F25  1  0.198  0.621  0.541  1.0
  F  F26  1  0.621  0.541  0.198  1.0
  F  F27  1  0.541  0.198  0.621  1.0
  F  F28  1  0.253  0.622  0.267  1.0
  F  F29  1  0.733  0.747  0.378  1.0
  F  F30  1  0.378  0.733  0.747  1.0
  F  F31  1  0.215  0.901  0.250  1.0
  F  F32  1  0.901  0.250  0.215  1.0
  F  F33  1  0.750  0.785  0.099  1.0
  F  F34  1  0.479  0.089  0.091  1.0
  F  F35  1  0.099  0.750  0.785  1.0
  F  F36  1  0.459  0.802  0.379  1.0
  F  F37  1  0.785  0.099  0.750  1.0
  F  F38  1  0.089  0.091  0.479  1.0
  F  F39  1  0.367  0.459  0.053  1.0
  F  F40  1  0.747  0.378  0.733  1.0
  F  F41  1  0.250  0.215  0.901  1.0
  F  F42  1  0.622  0.267  0.253  1.0
[/CIF]
.
The compound described by Te7(OF5)6 is Copper structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of three Te7(OF5)6 clusters. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one F(1), one F(2), one F(3), one F(4), and one F(5) atom to form corner-sharing TeOF5 octahedra. The corner-sharing octahedral tilt angles are 43°. In the second Te site, Te(2) is bonded to six equivalent O(1) atoms to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles are 43°. O(1) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(2) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF file [CIF]
data_Te7(OF5)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.771
_cell_length_b   10.771
_cell_length_c   10.771
_cell_angle_alpha   50.121
_cell_angle_beta   50.121
_cell_angle_gamma   50.121
_symmetry_Int_Tables_number   1
_cell_volume   677.331
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.768  0.392  0.081  1.0
  Te  Te1  1  0.608  0.919  0.232  1.0
  Te  Te2  1  0.392  0.081  0.768  1.0
  Te  Te3  1  0.919  0.232  0.608  1.0
  Te  Te4  1  0.000  0.000  0.000  1.0
  Te  Te5  1  0.232  0.608  0.919  1.0
  Te  Te6  1  0.081  0.768  0.392  1.0
  O  O7  1  0.076  0.757  0.050  1.0
  O  O8  1  0.243  0.950  0.924  1.0
  O  O9  1  0.050  0.076  0.757  1.0
  O  O10  1  0.950  0.924  0.243  1.0
  O  O11  1  0.757  0.050  0.076  1.0
  O  O12  1  0.924  0.243  0.950  1.0
  F  F13  1  0.053  0.367  0.459  1.0
  F  F14  1  0.909  0.521  0.911  1.0
  F  F15  1  0.459  0.053  0.367  1.0
  F  F16  1  0.802  0.379  0.459  1.0
  F  F17  1  0.947  0.633  0.541  1.0
  F  F18  1  0.911  0.909  0.521  1.0
  F  F19  1  0.633  0.541  0.947  1.0
  F  F20  1  0.379  0.459  0.802  1.0
  F  F21  1  0.267  0.253  0.622  1.0
  F  F22  1  0.521  0.911  0.909  1.0
  F  F23  1  0.091  0.479  0.089  1.0
  F  F24  1  0.541  0.947  0.633  1.0
  F  F25  1  0.198  0.621  0.541  1.0
  F  F26  1  0.621  0.541  0.198  1.0
  F  F27  1  0.541  0.198  0.621  1.0
  F  F28  1  0.253  0.622  0.267  1.0
  F  F29  1  0.733  0.747  0.378  1.0
  F  F30  1  0.378  0.733  0.747  1.0
  F  F31  1  0.215  0.901  0.250  1.0
  F  F32  1  0.901  0.250  0.215  1.0
  F  F33  1  0.750  0.785  0.099  1.0
  F  F34  1  0.479  0.089  0.091  1.0
  F  F35  1  0.099  0.750  0.785  1.0
  F  F36  1  0.459  0.802  0.379  1.0
  F  F37  1  0.785  0.099  0.750  1.0
  F  F38  1  0.089  0.091  0.479  1.0
  F  F39  1  0.367  0.459  0.053  1.0
  F  F40  1  0.747  0.378  0.733  1.0
  F  F41  1  0.250  0.215  0.901  1.0
  F  F42  1  0.622  0.267  0.253  1.0
[/CIF]
.