The structure described by Bi3FeMo2O12 crystallizes in the monoclinic C2/c space group. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(6) atom. Fe(1) is bonded in a tetrahedral geometry to two equivalent O(3) and two equivalent O(5) atoms. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 8-coordinate geometry to one O(2), one O(5), two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms. In the second Bi site, Bi(2) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. There are six inequivalent O sites. In the first O site, O(6) is bonded in a distorted single-bond geometry to one Mo(1) and two equivalent Bi(1) atoms. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Mo(1) and two equivalent Bi(1) atoms. In the third O site, O(2) is bonded in a 3-coordinate geometry to one Mo(1), one Bi(1), and one Bi(2) atom. In the fourth O site, O(3) is bonded in a trigonal planar geometry to one Fe(1) and two equivalent Bi(1) atoms. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one Mo(1) and one Bi(2) atom. In the sixth O site, O(5) is bonded in a distorted trigonal planar geometry to one Fe(1), one Bi(1), and one Bi(2) atom. is represented by the CIF card [CIF]
data_FeBi3(MoO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.413
_cell_length_b   10.413
_cell_length_c   5.348
_cell_angle_alpha   75.589
_cell_angle_beta   75.589
_cell_angle_gamma   69.252
_symmetry_Int_Tables_number   1
_cell_volume   516.877
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.882  0.118  0.250  1.0
  Fe  Fe1  1  0.118  0.882  0.750  1.0
  Bi  Bi2  1  0.040  0.264  0.590  1.0
  Bi  Bi3  1  0.344  0.656  0.250  1.0
  Bi  Bi4  1  0.656  0.344  0.750  1.0
  Bi  Bi5  1  0.960  0.736  0.410  1.0
  Bi  Bi6  1  0.264  0.040  0.090  1.0
  Bi  Bi7  1  0.736  0.960  0.910  1.0
  Mo  Mo8  1  0.460  0.204  0.424  1.0
  Mo  Mo9  1  0.204  0.460  0.924  1.0
  Mo  Mo10  1  0.540  0.796  0.576  1.0
  Mo  Mo11  1  0.796  0.540  0.076  1.0
  O  O12  1  0.071  0.496  0.737  1.0
  O  O13  1  0.594  0.175  0.623  1.0
  O  O14  1  0.871  0.954  0.508  1.0
  O  O15  1  0.362  0.457  0.697  1.0
  O  O16  1  0.153  0.747  0.529  1.0
  O  O17  1  0.825  0.406  0.877  1.0
  O  O18  1  0.747  0.153  0.029  1.0
  O  O19  1  0.638  0.543  0.303  1.0
  O  O20  1  0.929  0.504  0.263  1.0
  O  O21  1  0.789  0.705  0.858  1.0
  O  O22  1  0.175  0.594  0.123  1.0
  O  O23  1  0.504  0.929  0.763  1.0
  O  O24  1  0.847  0.253  0.471  1.0
  O  O25  1  0.129  0.046  0.492  1.0
  O  O26  1  0.211  0.295  0.142  1.0
  O  O27  1  0.543  0.638  0.803  1.0
  O  O28  1  0.295  0.211  0.642  1.0
  O  O29  1  0.406  0.825  0.377  1.0
  O  O30  1  0.253  0.847  0.971  1.0
  O  O31  1  0.457  0.362  0.197  1.0
  O  O32  1  0.496  0.071  0.237  1.0
  O  O33  1  0.046  0.129  0.992  1.0
  O  O34  1  0.954  0.871  0.008  1.0
  O  O35  1  0.705  0.789  0.358  1.0
[/CIF]
.
The structure described by Bi3FeMo2O12 crystallizes in the monoclinic C2/c space group. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(6) atom. Fe(1) is bonded in a tetrahedral geometry to two equivalent O(3) and two equivalent O(5) atoms. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 8-coordinate geometry to one O(2), one O(5), two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms. In the second Bi site, Bi(2) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. There are six inequivalent O sites. In the first O site, O(6) is bonded in a distorted single-bond geometry to one Mo(1) and two equivalent Bi(1) atoms. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Mo(1) and two equivalent Bi(1) atoms. In the third O site, O(2) is bonded in a 3-coordinate geometry to one Mo(1), one Bi(1), and one Bi(2) atom. In the fourth O site, O(3) is bonded in a trigonal planar geometry to one Fe(1) and two equivalent Bi(1) atoms. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one Mo(1) and one Bi(2) atom. In the sixth O site, O(5) is bonded in a distorted trigonal planar geometry to one Fe(1), one Bi(1), and one Bi(2) atom. is represented by the CIF card [CIF]
data_FeBi3(MoO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.413
_cell_length_b   10.413
_cell_length_c   5.348
_cell_angle_alpha   75.589
_cell_angle_beta   75.589
_cell_angle_gamma   69.252
_symmetry_Int_Tables_number   1
_cell_volume   516.877
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.882  0.118  0.250  1.0
  Fe  Fe1  1  0.118  0.882  0.750  1.0
  Bi  Bi2  1  0.040  0.264  0.590  1.0
  Bi  Bi3  1  0.344  0.656  0.250  1.0
  Bi  Bi4  1  0.656  0.344  0.750  1.0
  Bi  Bi5  1  0.960  0.736  0.410  1.0
  Bi  Bi6  1  0.264  0.040  0.090  1.0
  Bi  Bi7  1  0.736  0.960  0.910  1.0
  Mo  Mo8  1  0.460  0.204  0.424  1.0
  Mo  Mo9  1  0.204  0.460  0.924  1.0
  Mo  Mo10  1  0.540  0.796  0.576  1.0
  Mo  Mo11  1  0.796  0.540  0.076  1.0
  O  O12  1  0.071  0.496  0.737  1.0
  O  O13  1  0.594  0.175  0.623  1.0
  O  O14  1  0.871  0.954  0.508  1.0
  O  O15  1  0.362  0.457  0.697  1.0
  O  O16  1  0.153  0.747  0.529  1.0
  O  O17  1  0.825  0.406  0.877  1.0
  O  O18  1  0.747  0.153  0.029  1.0
  O  O19  1  0.638  0.543  0.303  1.0
  O  O20  1  0.929  0.504  0.263  1.0
  O  O21  1  0.789  0.705  0.858  1.0
  O  O22  1  0.175  0.594  0.123  1.0
  O  O23  1  0.504  0.929  0.763  1.0
  O  O24  1  0.847  0.253  0.471  1.0
  O  O25  1  0.129  0.046  0.492  1.0
  O  O26  1  0.211  0.295  0.142  1.0
  O  O27  1  0.543  0.638  0.803  1.0
  O  O28  1  0.295  0.211  0.642  1.0
  O  O29  1  0.406  0.825  0.377  1.0
  O  O30  1  0.253  0.847  0.971  1.0
  O  O31  1  0.457  0.362  0.197  1.0
  O  O32  1  0.496  0.071  0.237  1.0
  O  O33  1  0.046  0.129  0.992  1.0
  O  O34  1  0.954  0.871  0.008  1.0
  O  O35  1  0.705  0.789  0.358  1.0
[/CIF]
.