The compound described by C2TeS2(N2I)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four C2TeS2(N2I)2 clusters. C(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one S(1) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a 2-coordinate geometry to one C(1) and one N(1) atom. In the second N site, N(1) is bonded in a 2-coordinate geometry to one C(1) and one N(2) atom. Te(1) is bonded in a rectangular see-saw-like geometry to two equivalent S(1) and two equivalent I(1) atoms. S(1) is bonded in a water-like geometry to one C(1) and one Te(1) atom. I(1) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF card [CIF]
data_TeC2S2(IN2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.262
_cell_length_b   8.897
_cell_length_c   11.423
_cell_angle_alpha   112.437
_cell_angle_beta   90.000
_cell_angle_gamma   117.664
_symmetry_Int_Tables_number   1
_cell_volume   671.109
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.098  0.000  0.750  1.0
  Te  Te1  1  0.902  0.000  0.250  1.0
  C  C2  1  0.240  0.735  0.467  1.0
  C  C3  1  0.505  0.265  0.033  1.0
  C  C4  1  0.760  0.265  0.533  1.0
  C  C5  1  0.495  0.735  0.967  1.0
  S  S6  1  0.265  0.763  0.614  1.0
  S  S7  1  0.502  0.237  0.886  1.0
  S  S8  1  0.735  0.237  0.386  1.0
  S  S9  1  0.498  0.763  0.114  1.0
  I  I10  1  0.764  0.744  0.559  1.0
  I  I11  1  0.020  0.256  0.941  1.0
  I  I12  1  0.236  0.256  0.441  1.0
  I  I13  1  0.980  0.744  0.059  1.0
  N  N14  1  0.228  0.636  0.336  1.0
  N  N15  1  0.592  0.364  0.164  1.0
  N  N16  1  0.772  0.364  0.664  1.0
  N  N17  1  0.408  0.636  0.836  1.0
  N  N18  1  0.217  0.790  0.372  1.0
  N  N19  1  0.427  0.210  0.128  1.0
  N  N20  1  0.783  0.210  0.628  1.0
  N  N21  1  0.573  0.790  0.872  1.0
[/CIF]
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The compound described by C2TeS2(N2I)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four C2TeS2(N2I)2 clusters. C(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one S(1) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a 2-coordinate geometry to one C(1) and one N(1) atom. In the second N site, N(1) is bonded in a 2-coordinate geometry to one C(1) and one N(2) atom. Te(1) is bonded in a rectangular see-saw-like geometry to two equivalent S(1) and two equivalent I(1) atoms. S(1) is bonded in a water-like geometry to one C(1) and one Te(1) atom. I(1) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF card [CIF]
data_TeC2S2(IN2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.262
_cell_length_b   8.897
_cell_length_c   11.423
_cell_angle_alpha   112.437
_cell_angle_beta   90.000
_cell_angle_gamma   117.664
_symmetry_Int_Tables_number   1
_cell_volume   671.109
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.098  0.000  0.750  1.0
  Te  Te1  1  0.902  0.000  0.250  1.0
  C  C2  1  0.240  0.735  0.467  1.0
  C  C3  1  0.505  0.265  0.033  1.0
  C  C4  1  0.760  0.265  0.533  1.0
  C  C5  1  0.495  0.735  0.967  1.0
  S  S6  1  0.265  0.763  0.614  1.0
  S  S7  1  0.502  0.237  0.886  1.0
  S  S8  1  0.735  0.237  0.386  1.0
  S  S9  1  0.498  0.763  0.114  1.0
  I  I10  1  0.764  0.744  0.559  1.0
  I  I11  1  0.020  0.256  0.941  1.0
  I  I12  1  0.236  0.256  0.441  1.0
  I  I13  1  0.980  0.744  0.059  1.0
  N  N14  1  0.228  0.636  0.336  1.0
  N  N15  1  0.592  0.364  0.164  1.0
  N  N16  1  0.772  0.364  0.664  1.0
  N  N17  1  0.408  0.636  0.836  1.0
  N  N18  1  0.217  0.790  0.372  1.0
  N  N19  1  0.427  0.210  0.128  1.0
  N  N20  1  0.783  0.210  0.628  1.0
  N  N21  1  0.573  0.790  0.872  1.0
[/CIF]
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