The structure described by PtN4(NO3)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen nitric acid molecules and eight PtN4 clusters. In four of the PtN4 clusters, Pt(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2,3) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2,3) is bonded in a single-bond geometry to one Pt(1) atom. In four of the PtN4 clusters, Pt(2) is bonded in a square co-planar geometry to two equivalent N(2,3) and two equivalent N(4) atoms. There are two inequivalent N sites. In the first N site, N(2,3) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(4) is bonded in a single-bond geometry to one Pt(2) atom. is represented by the CIF file [CIF]
data_Pt(NO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.467
_cell_length_b   9.467
_cell_length_c   11.764
_cell_angle_alpha   70.985
_cell_angle_beta   70.985
_cell_angle_gamma   73.140
_symmetry_Int_Tables_number   1
_cell_volume   922.256
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.000  0.500  0.000  1.0
  Pt  Pt1  1  0.500  0.000  0.500  1.0
  Pt  Pt2  1  0.500  0.000  0.000  1.0
  Pt  Pt3  1  0.000  0.500  0.500  1.0
  N  N4  1  0.813  0.651  0.005  1.0
  N  N5  1  0.349  0.187  0.495  1.0
  N  N6  1  0.187  0.349  0.995  1.0
  N  N7  1  0.651  0.813  0.505  1.0
  N  N8  1  0.890  0.349  0.071  1.0
  N  N9  1  0.651  0.110  0.429  1.0
  N  N10  1  0.110  0.651  0.929  1.0
  N  N11  1  0.349  0.890  0.571  1.0
  N  N12  1  0.365  0.874  0.083  1.0
  N  N13  1  0.126  0.635  0.417  1.0
  N  N14  1  0.635  0.126  0.917  1.0
  N  N15  1  0.874  0.365  0.583  1.0
  N  N16  1  0.525  0.001  0.157  1.0
  N  N17  1  0.999  0.475  0.343  1.0
  N  N18  1  0.475  0.999  0.843  1.0
  N  N19  1  0.001  0.525  0.657  1.0
  N  N20  1  0.127  0.073  0.340  1.0
  N  N21  1  0.927  0.873  0.160  1.0
  N  N22  1  0.873  0.927  0.660  1.0
  N  N23  1  0.073  0.127  0.840  1.0
  N  N24  1  0.456  0.432  0.153  1.0
  N  N25  1  0.568  0.544  0.347  1.0
  N  N26  1  0.544  0.568  0.847  1.0
  N  N27  1  0.432  0.456  0.653  1.0
  O  O28  1  0.071  0.128  0.249  1.0
  O  O29  1  0.872  0.929  0.251  1.0
  O  O30  1  0.929  0.872  0.751  1.0
  O  O31  1  0.128  0.071  0.749  1.0
  O  O32  1  0.230  0.954  0.345  1.0
  O  O33  1  0.046  0.770  0.155  1.0
  O  O34  1  0.770  0.046  0.655  1.0
  O  O35  1  0.954  0.230  0.845  1.0
  O  O36  1  0.084  0.136  0.428  1.0
  O  O37  1  0.864  0.916  0.072  1.0
  O  O38  1  0.916  0.864  0.572  1.0
  O  O39  1  0.136  0.084  0.928  1.0
  O  O40  1  0.314  0.453  0.179  1.0
  O  O41  1  0.547  0.686  0.321  1.0
  O  O42  1  0.686  0.547  0.821  1.0
  O  O43  1  0.453  0.314  0.679  1.0
  O  O44  1  0.521  0.543  0.109  1.0
  O  O45  1  0.457  0.479  0.391  1.0
  O  O46  1  0.479  0.457  0.891  1.0
  O  O47  1  0.543  0.521  0.609  1.0
  O  O48  1  0.535  0.298  0.170  1.0
  O  O49  1  0.702  0.465  0.330  1.0
  O  O50  1  0.465  0.702  0.830  1.0
  O  O51  1  0.298  0.535  0.670  1.0
[/CIF]
.
The structure described by PtN4(NO3)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen nitric acid molecules and eight PtN4 clusters. In four of the PtN4 clusters, Pt(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2,3) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(2,3) is bonded in a single-bond geometry to one Pt(1) atom. In four of the PtN4 clusters, Pt(2) is bonded in a square co-planar geometry to two equivalent N(2,3) and two equivalent N(4) atoms. There are two inequivalent N sites. In the first N site, N(2,3) is bonded in a single-bond geometry to one Pt(1) atom. In the second N site, N(4) is bonded in a single-bond geometry to one Pt(2) atom. is represented by the CIF file [CIF]
data_Pt(NO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.467
_cell_length_b   9.467
_cell_length_c   11.764
_cell_angle_alpha   70.985
_cell_angle_beta   70.985
_cell_angle_gamma   73.140
_symmetry_Int_Tables_number   1
_cell_volume   922.256
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.000  0.500  0.000  1.0
  Pt  Pt1  1  0.500  0.000  0.500  1.0
  Pt  Pt2  1  0.500  0.000  0.000  1.0
  Pt  Pt3  1  0.000  0.500  0.500  1.0
  N  N4  1  0.813  0.651  0.005  1.0
  N  N5  1  0.349  0.187  0.495  1.0
  N  N6  1  0.187  0.349  0.995  1.0
  N  N7  1  0.651  0.813  0.505  1.0
  N  N8  1  0.890  0.349  0.071  1.0
  N  N9  1  0.651  0.110  0.429  1.0
  N  N10  1  0.110  0.651  0.929  1.0
  N  N11  1  0.349  0.890  0.571  1.0
  N  N12  1  0.365  0.874  0.083  1.0
  N  N13  1  0.126  0.635  0.417  1.0
  N  N14  1  0.635  0.126  0.917  1.0
  N  N15  1  0.874  0.365  0.583  1.0
  N  N16  1  0.525  0.001  0.157  1.0
  N  N17  1  0.999  0.475  0.343  1.0
  N  N18  1  0.475  0.999  0.843  1.0
  N  N19  1  0.001  0.525  0.657  1.0
  N  N20  1  0.127  0.073  0.340  1.0
  N  N21  1  0.927  0.873  0.160  1.0
  N  N22  1  0.873  0.927  0.660  1.0
  N  N23  1  0.073  0.127  0.840  1.0
  N  N24  1  0.456  0.432  0.153  1.0
  N  N25  1  0.568  0.544  0.347  1.0
  N  N26  1  0.544  0.568  0.847  1.0
  N  N27  1  0.432  0.456  0.653  1.0
  O  O28  1  0.071  0.128  0.249  1.0
  O  O29  1  0.872  0.929  0.251  1.0
  O  O30  1  0.929  0.872  0.751  1.0
  O  O31  1  0.128  0.071  0.749  1.0
  O  O32  1  0.230  0.954  0.345  1.0
  O  O33  1  0.046  0.770  0.155  1.0
  O  O34  1  0.770  0.046  0.655  1.0
  O  O35  1  0.954  0.230  0.845  1.0
  O  O36  1  0.084  0.136  0.428  1.0
  O  O37  1  0.864  0.916  0.072  1.0
  O  O38  1  0.916  0.864  0.572  1.0
  O  O39  1  0.136  0.084  0.928  1.0
  O  O40  1  0.314  0.453  0.179  1.0
  O  O41  1  0.547  0.686  0.321  1.0
  O  O42  1  0.686  0.547  0.821  1.0
  O  O43  1  0.453  0.314  0.679  1.0
  O  O44  1  0.521  0.543  0.109  1.0
  O  O45  1  0.457  0.479  0.391  1.0
  O  O46  1  0.479  0.457  0.891  1.0
  O  O47  1  0.543  0.521  0.609  1.0
  O  O48  1  0.535  0.298  0.170  1.0
  O  O49  1  0.702  0.465  0.330  1.0
  O  O50  1  0.465  0.702  0.830  1.0
  O  O51  1  0.298  0.535  0.670  1.0
[/CIF]
.