The material structure described by Rb(WO3)3 crystallizes in the orthorhombic Cccm space group. Rb(1) is bonded to four O(3,3,3); four equivalent O(4); and four equivalent O(5) atoms to form RbO12 cuboctahedra that share edges with four equivalent W(1)O6 octahedra, edges with four equivalent W(2)O6 octahedra, edges with four equivalent W(3)O6 octahedra, and faces with two equivalent Rb(1)O12 cuboctahedra. There are three inequivalent W sites. In the first W site, W(1) is bonded to two O(1,1); two equivalent O(4); and two equivalent O(5) atoms to form WO6 octahedra that share corners with two equivalent W(2)O6 octahedra, corners with four equivalent W(3)O6 octahedra, and edges with four equivalent Rb(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-31°. In the second W site, W(2) is bonded to two equivalent O(2); two O(3,3); and two equivalent O(5) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with two equivalent W(2)O6 octahedra, corners with two equivalent W(3)O6 octahedra, and edges with four equivalent Rb(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-31°. In the third W site, W(3) is bonded to two O(1,1); two equivalent O(3); and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(2)O6 octahedra, corners with four equivalent W(1)O6 octahedra, and edges with four equivalent Rb(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-31°. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one W(1) and one W(3) atom. In the second O site, O(2) is bonded in a linear geometry to two equivalent W(2) atoms. In the third O site, O(1) is bonded in a linear geometry to one W(1) and one W(3) atom. In the fourth O site, O(1) is bonded in a linear geometry to one W(1) and one W(3) atom. In the fifth O site, O(1) is bonded in a linear geometry to one W(1) and one W(3) atom. In the sixth O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent Rb(1), one W(2), and one W(3) atom. In the seventh O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent Rb(1), one W(1), and one W(3) atom. In the eighth O site, O(5) is bonded in a bent 150 degrees geometry to two equivalent Rb(1), one W(1), and one W(2) atom. In the ninth O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent Rb(1), one W(2), and one W(3) atom. In the tenth O site, O(1) is bonded in a linear geometry to one W(1) and one W(3) atom. In the eleventh O site, O(1) is bonded in a linear geometry to one W(1) and one W(3) atom. In the twelfth O site, O(1) is bonded in a linear geometry to one W(1) and one W(3) atom. In the thirteenth O site, O(2) is bonded in a linear geometry to two equivalent W(2) atoms. In the fourteenth O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent Rb(1), one W(2), and one W(3) atom. In the fifteenth O site, O(5) is bonded in a bent 150 degrees geometry to two equivalent Rb(1), one W(1), and one W(2) atom. is represented by the CIF card [CIF]
data_Rb(WO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.897
_cell_length_b   7.523
_cell_length_c   7.547
_cell_angle_alpha   119.892
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   191.832
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.500  1.000  0.500  1.0
  O  O1  1  0.500  0.000  0.000  1.0
  O  O2  1  0.500  0.500  0.500  1.0
  O  O3  1  1.000  0.713  0.792  1.0
  O  O4  1  1.000  0.289  0.579  1.0
  O  O5  1  1.000  0.079  0.792  1.0
  O  O6  1  1.000  0.287  0.208  1.0
  O  O7  1  1.000  0.711  0.421  1.0
  O  O8  1  0.000  0.921  0.208  1.0
  Rb  Rb9  1  0.500  0.500  0.000  1.0
  W  W10  1  1.000  0.500  0.500  1.0
  W  W11  1  0.000  0.000  0.000  1.0
  W  W12  1  1.000  1.000  0.500  1.0
[/CIF]
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The material structure described by Rb(WO3)3 crystallizes in the orthorhombic Cccm space group. Rb(1) is bonded to four O(3,3,3); four equivalent O(4); and four equivalent O(5) atoms to form RbO12 cuboctahedra that share edges with four equivalent W(1)O6 octahedra, edges with four equivalent W(2)O6 octahedra, edges with four equivalent W(3)O6 octahedra, and faces with two equivalent Rb(1)O12 cuboctahedra. There are three inequivalent W sites. In the first W site, W(1) is bonded to two O(1,1); two equivalent O(4); and two equivalent O(5) atoms to form WO6 octahedra that share corners with two equivalent W(2)O6 octahedra, corners with four equivalent W(3)O6 octahedra, and edges with four equivalent Rb(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-31°. In the second W site, W(2) is bonded to two equivalent O(2); two O(3,3); and two equivalent O(5) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra, corners with two equivalent W(2)O6 octahedra, corners with two equivalent W(3)O6 octahedra, and edges with four equivalent Rb(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-31°. In the third W site, W(3) is bonded to two O(1,1); two equivalent O(3); and two equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(2)O6 octahedra, corners with four equivalent W(1)O6 octahedra, and edges with four equivalent Rb(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-31°. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one W(1) and one W(3) atom. In the second O site, O(2) is bonded in a linear geometry to two equivalent W(2) atoms. In the third O site, O(1) is bonded in a linear geometry to one W(1) and one W(3) atom. In the fourth O site, O(1) is bonded in a linear geometry to one W(1) and one W(3) atom. In the fifth O site, O(1) is bonded in a linear geometry to one W(1) and one W(3) atom. In the sixth O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent Rb(1), one W(2), and one W(3) atom. In the seventh O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent Rb(1), one W(1), and one W(3) atom. In the eighth O site, O(5) is bonded in a bent 150 degrees geometry to two equivalent Rb(1), one W(1), and one W(2) atom. In the ninth O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent Rb(1), one W(2), and one W(3) atom. In the tenth O site, O(1) is bonded in a linear geometry to one W(1) and one W(3) atom. In the eleventh O site, O(1) is bonded in a linear geometry to one W(1) and one W(3) atom. In the twelfth O site, O(1) is bonded in a linear geometry to one W(1) and one W(3) atom. In the thirteenth O site, O(2) is bonded in a linear geometry to two equivalent W(2) atoms. In the fourteenth O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent Rb(1), one W(2), and one W(3) atom. In the fifteenth O site, O(5) is bonded in a bent 150 degrees geometry to two equivalent Rb(1), one W(1), and one W(2) atom. is represented by the CIF card [CIF]
data_Rb(WO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.897
_cell_length_b   7.523
_cell_length_c   7.547
_cell_angle_alpha   119.892
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   191.832
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.500  1.000  0.500  1.0
  O  O1  1  0.500  0.000  0.000  1.0
  O  O2  1  0.500  0.500  0.500  1.0
  O  O3  1  1.000  0.713  0.792  1.0
  O  O4  1  1.000  0.289  0.579  1.0
  O  O5  1  1.000  0.079  0.792  1.0
  O  O6  1  1.000  0.287  0.208  1.0
  O  O7  1  1.000  0.711  0.421  1.0
  O  O8  1  0.000  0.921  0.208  1.0
  Rb  Rb9  1  0.500  0.500  0.000  1.0
  W  W10  1  1.000  0.500  0.500  1.0
  W  W11  1  0.000  0.000  0.000  1.0
  W  W12  1  1.000  1.000  0.500  1.0
[/CIF]
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