The structure described by CsReN2 crystallizes in the orthorhombic Pbcm space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 10-coordinate geometry to two equivalent N(1), two equivalent N(3), and six equivalent N(2) atoms. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent N(3), and four equivalent N(2) atoms. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded to two equivalent N(2) and two equivalent N(3) atoms to form corner-sharing ReN4 tetrahedra. In the second Re site, Re(2) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form corner-sharing ReN4 tetrahedra. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted linear geometry to two equivalent Cs(1), two equivalent Cs(2), and two equivalent Re(2) atoms. In the second N site, N(2) is bonded in a linear geometry to two equivalent Cs(2), three equivalent Cs(1), one Re(1), and one Re(2) atom. In the third N site, N(3) is bonded in a linear geometry to two equivalent Cs(1), two equivalent Cs(2), and two equivalent Re(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsReN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.203
_cell_length_b   8.577
_cell_length_c   12.359
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   657.546
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.750  0.126  0.500  1.0
  Cs  Cs1  1  0.250  0.874  0.000  1.0
  Cs  Cs2  1  0.250  0.874  0.500  1.0
  Cs  Cs3  1  0.750  0.126  0.000  1.0
  Cs  Cs4  1  0.816  0.377  0.750  1.0
  Cs  Cs5  1  0.316  0.623  0.750  1.0
  Cs  Cs6  1  0.184  0.623  0.250  1.0
  Cs  Cs7  1  0.684  0.377  0.250  1.0
  Re  Re8  1  0.250  0.375  0.500  1.0
  Re  Re9  1  0.750  0.625  0.000  1.0
  Re  Re10  1  0.750  0.625  0.500  1.0
  Re  Re11  1  0.250  0.375  0.000  1.0
  Re  Re12  1  0.290  0.124  0.750  1.0
  Re  Re13  1  0.790  0.876  0.750  1.0
  Re  Re14  1  0.710  0.876  0.250  1.0
  Re  Re15  1  0.210  0.124  0.250  1.0
  N  N16  1  0.555  0.016  0.750  1.0
  N  N17  1  0.055  0.984  0.750  1.0
  N  N18  1  0.445  0.984  0.250  1.0
  N  N19  1  0.945  0.016  0.250  1.0
  N  N20  1  0.267  0.248  0.875  1.0
  N  N21  1  0.767  0.752  0.625  1.0
  N  N22  1  0.733  0.752  0.375  1.0
  N  N23  1  0.233  0.248  0.125  1.0
  N  N24  1  0.733  0.752  0.125  1.0
  N  N25  1  0.233  0.248  0.375  1.0
  N  N26  1  0.267  0.248  0.625  1.0
  N  N27  1  0.767  0.752  0.875  1.0
  N  N28  1  0.000  0.500  0.000  1.0
  N  N29  1  0.500  0.500  0.500  1.0
  N  N30  1  0.000  0.500  0.500  1.0
  N  N31  1  0.500  0.500  0.000  1.0
[/CIF]
.
The structure described by CsReN2 crystallizes in the orthorhombic Pbcm space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 10-coordinate geometry to two equivalent N(1), two equivalent N(3), and six equivalent N(2) atoms. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent N(3), and four equivalent N(2) atoms. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded to two equivalent N(2) and two equivalent N(3) atoms to form corner-sharing ReN4 tetrahedra. In the second Re site, Re(2) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form corner-sharing ReN4 tetrahedra. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted linear geometry to two equivalent Cs(1), two equivalent Cs(2), and two equivalent Re(2) atoms. In the second N site, N(2) is bonded in a linear geometry to two equivalent Cs(2), three equivalent Cs(1), one Re(1), and one Re(2) atom. In the third N site, N(3) is bonded in a linear geometry to two equivalent Cs(1), two equivalent Cs(2), and two equivalent Re(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsReN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.203
_cell_length_b   8.577
_cell_length_c   12.359
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   657.546
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.750  0.126  0.500  1.0
  Cs  Cs1  1  0.250  0.874  0.000  1.0
  Cs  Cs2  1  0.250  0.874  0.500  1.0
  Cs  Cs3  1  0.750  0.126  0.000  1.0
  Cs  Cs4  1  0.816  0.377  0.750  1.0
  Cs  Cs5  1  0.316  0.623  0.750  1.0
  Cs  Cs6  1  0.184  0.623  0.250  1.0
  Cs  Cs7  1  0.684  0.377  0.250  1.0
  Re  Re8  1  0.250  0.375  0.500  1.0
  Re  Re9  1  0.750  0.625  0.000  1.0
  Re  Re10  1  0.750  0.625  0.500  1.0
  Re  Re11  1  0.250  0.375  0.000  1.0
  Re  Re12  1  0.290  0.124  0.750  1.0
  Re  Re13  1  0.790  0.876  0.750  1.0
  Re  Re14  1  0.710  0.876  0.250  1.0
  Re  Re15  1  0.210  0.124  0.250  1.0
  N  N16  1  0.555  0.016  0.750  1.0
  N  N17  1  0.055  0.984  0.750  1.0
  N  N18  1  0.445  0.984  0.250  1.0
  N  N19  1  0.945  0.016  0.250  1.0
  N  N20  1  0.267  0.248  0.875  1.0
  N  N21  1  0.767  0.752  0.625  1.0
  N  N22  1  0.733  0.752  0.375  1.0
  N  N23  1  0.233  0.248  0.125  1.0
  N  N24  1  0.733  0.752  0.125  1.0
  N  N25  1  0.233  0.248  0.375  1.0
  N  N26  1  0.267  0.248  0.625  1.0
  N  N27  1  0.767  0.752  0.875  1.0
  N  N28  1  0.000  0.500  0.000  1.0
  N  N29  1  0.500  0.500  0.500  1.0
  N  N30  1  0.000  0.500  0.500  1.0
  N  N31  1  0.500  0.500  0.000  1.0
[/CIF]
.