The crystal structure described by Cd(AuF6)2 crystallizes in the monoclinic C2/c space group. Au(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form AuF6 octahedra that share corners with three equivalent Cd(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. Cd(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(5) atoms to form CdF6 octahedra that share corners with six equivalent Au(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Au(1) and one Cd(1) atom. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Au(1) and one Cd(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Au(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Au(1) atom. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one Au(1) and one Cd(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Au(1) atom. is represented by the CIF card [CIF]
data_Cd(AuF6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.136
_cell_length_b   7.136
_cell_length_c   10.001
_cell_angle_alpha   67.557
_cell_angle_beta   67.557
_cell_angle_gamma   75.101
_symmetry_Int_Tables_number   1
_cell_volume   431.356
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.182  0.818  0.750  1.0
  Cd  Cd1  1  0.818  0.182  0.250  1.0
  Au  Au2  1  0.246  0.255  0.367  1.0
  Au  Au3  1  0.255  0.246  0.867  1.0
  Au  Au4  1  0.754  0.745  0.633  1.0
  Au  Au5  1  0.745  0.754  0.133  1.0
  F  F6  1  0.857  0.872  0.229  1.0
  F  F7  1  0.143  0.128  0.771  1.0
  F  F8  1  0.303  0.978  0.500  1.0
  F  F9  1  0.984  0.279  0.512  1.0
  F  F10  1  0.279  0.984  0.012  1.0
  F  F11  1  0.371  0.357  0.458  1.0
  F  F12  1  0.357  0.371  0.958  1.0
  F  F13  1  0.872  0.857  0.729  1.0
  F  F14  1  0.777  0.484  0.282  1.0
  F  F15  1  0.022  0.697  0.000  1.0
  F  F16  1  0.697  0.022  0.500  1.0
  F  F17  1  0.978  0.303  1.000  1.0
  F  F18  1  0.522  0.195  0.736  1.0
  F  F19  1  0.629  0.643  0.542  1.0
  F  F20  1  0.223  0.516  0.718  1.0
  F  F21  1  0.643  0.629  0.042  1.0
  F  F22  1  0.484  0.777  0.782  1.0
  F  F23  1  0.805  0.478  0.764  1.0
  F  F24  1  0.516  0.223  0.218  1.0
  F  F25  1  0.478  0.805  0.264  1.0
  F  F26  1  0.195  0.522  0.236  1.0
  F  F27  1  0.721  0.016  0.988  1.0
  F  F28  1  0.128  0.143  0.271  1.0
  F  F29  1  0.016  0.721  0.488  1.0
[/CIF]
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The crystal structure described by Cd(AuF6)2 crystallizes in the monoclinic C2/c space group. Au(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom to form AuF6 octahedra that share corners with three equivalent Cd(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. Cd(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(5) atoms to form CdF6 octahedra that share corners with six equivalent Au(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 45-53°. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Au(1) and one Cd(1) atom. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Au(1) and one Cd(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Au(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Au(1) atom. In the fifth F site, F(5) is bonded in a bent 120 degrees geometry to one Au(1) and one Cd(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Au(1) atom. is represented by the CIF card [CIF]
data_Cd(AuF6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.136
_cell_length_b   7.136
_cell_length_c   10.001
_cell_angle_alpha   67.557
_cell_angle_beta   67.557
_cell_angle_gamma   75.101
_symmetry_Int_Tables_number   1
_cell_volume   431.356
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.182  0.818  0.750  1.0
  Cd  Cd1  1  0.818  0.182  0.250  1.0
  Au  Au2  1  0.246  0.255  0.367  1.0
  Au  Au3  1  0.255  0.246  0.867  1.0
  Au  Au4  1  0.754  0.745  0.633  1.0
  Au  Au5  1  0.745  0.754  0.133  1.0
  F  F6  1  0.857  0.872  0.229  1.0
  F  F7  1  0.143  0.128  0.771  1.0
  F  F8  1  0.303  0.978  0.500  1.0
  F  F9  1  0.984  0.279  0.512  1.0
  F  F10  1  0.279  0.984  0.012  1.0
  F  F11  1  0.371  0.357  0.458  1.0
  F  F12  1  0.357  0.371  0.958  1.0
  F  F13  1  0.872  0.857  0.729  1.0
  F  F14  1  0.777  0.484  0.282  1.0
  F  F15  1  0.022  0.697  0.000  1.0
  F  F16  1  0.697  0.022  0.500  1.0
  F  F17  1  0.978  0.303  1.000  1.0
  F  F18  1  0.522  0.195  0.736  1.0
  F  F19  1  0.629  0.643  0.542  1.0
  F  F20  1  0.223  0.516  0.718  1.0
  F  F21  1  0.643  0.629  0.042  1.0
  F  F22  1  0.484  0.777  0.782  1.0
  F  F23  1  0.805  0.478  0.764  1.0
  F  F24  1  0.516  0.223  0.218  1.0
  F  F25  1  0.478  0.805  0.264  1.0
  F  F26  1  0.195  0.522  0.236  1.0
  F  F27  1  0.721  0.016  0.988  1.0
  F  F28  1  0.128  0.143  0.271  1.0
  F  F29  1  0.016  0.721  0.488  1.0
[/CIF]
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