The compound described by (RuN3H6)2(NH4)2(N3H12Cl)2(ClO4)4Cl2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ammonium molecules, two hydrochloric acid atoms, four hypochlorous acid;trihydrate molecules, two triazanium;hydrochloride molecules, and two RuN3H6 clusters. In each RuN3H6 cluster, Ru(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ru(1), one H(3), and one H(5) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1) and two equivalent H(4) atoms. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H22RuN7(ClO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.555
_cell_length_b   7.555
_cell_length_c   10.765
_cell_angle_alpha   69.008
_cell_angle_beta   69.008
_cell_angle_gamma   57.482
_symmetry_Int_Tables_number   1
_cell_volume   472.965
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.461  0.643  0.450  1.0
  H  H1  1  0.643  0.461  0.450  1.0
  H  H2  1  0.338  0.542  0.526  1.0
  H  H3  1  0.542  0.338  0.526  1.0
  H  H4  1  0.414  0.808  0.751  1.0
  H  H5  1  0.016  0.786  0.842  1.0
  H  H6  1  0.808  0.414  0.751  1.0
  H  H7  1  0.889  0.468  0.852  1.0
  H  H8  1  0.468  0.889  0.852  1.0
  H  H9  1  0.786  0.016  0.842  1.0
  H  H10  1  0.215  0.502  0.071  1.0
  H  H11  1  0.192  0.701  0.120  1.0
  H  H12  1  0.973  0.691  0.121  1.0
  H  H13  1  0.121  0.520  0.242  1.0
  H  H14  1  0.210  0.210  0.075  1.0
  H  H15  1  0.502  0.215  0.071  1.0
  H  H16  1  0.701  0.192  0.120  1.0
  H  H17  1  0.975  0.208  0.130  1.0
  H  H18  1  0.208  0.975  0.130  1.0
  H  H19  1  0.691  0.973  0.121  1.0
  H  H20  1  0.520  0.121  0.242  1.0
  H  H21  1  0.118  0.118  0.249  1.0
  Ru  Ru22  1  0.062  0.062  0.892  1.0
  N  N23  1  0.353  0.871  0.836  1.0
  N  N24  1  0.918  0.918  0.885  1.0
  N  N25  1  0.871  0.353  0.836  1.0
  N  N26  1  0.498  0.498  0.530  1.0
  N  N27  1  0.125  0.603  0.142  1.0
  N  N28  1  0.603  0.125  0.142  1.0
  N  N29  1  0.127  0.127  0.150  1.0
  Cl  Cl30  1  0.835  0.835  0.532  1.0
  Cl  Cl31  1  0.612  0.612  0.182  1.0
  Cl  Cl32  1  0.346  0.346  0.912  1.0
  Cl  Cl33  1  0.174  0.174  0.446  1.0
  O  O34  1  0.885  0.885  0.382  1.0
  O  O35  1  0.306  0.977  0.390  1.0
  O  O36  1  0.297  0.297  0.391  1.0
  O  O37  1  0.977  0.306  0.390  1.0
  O  O38  1  0.715  0.715  0.582  1.0
  O  O39  1  0.036  0.707  0.582  1.0
  O  O40  1  0.707  0.036  0.582  1.0
  O  O41  1  0.125  0.125  0.591  1.0
[/CIF]
.
The compound described by (RuN3H6)2(NH4)2(N3H12Cl)2(ClO4)4Cl2 is Indium-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ammonium molecules, two hydrochloric acid atoms, four hypochlorous acid;trihydrate molecules, two triazanium;hydrochloride molecules, and two RuN3H6 clusters. In each RuN3H6 cluster, Ru(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ru(1), one H(3), and one H(5) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1) and two equivalent H(4) atoms. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H22RuN7(ClO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.555
_cell_length_b   7.555
_cell_length_c   10.765
_cell_angle_alpha   69.008
_cell_angle_beta   69.008
_cell_angle_gamma   57.482
_symmetry_Int_Tables_number   1
_cell_volume   472.965
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.461  0.643  0.450  1.0
  H  H1  1  0.643  0.461  0.450  1.0
  H  H2  1  0.338  0.542  0.526  1.0
  H  H3  1  0.542  0.338  0.526  1.0
  H  H4  1  0.414  0.808  0.751  1.0
  H  H5  1  0.016  0.786  0.842  1.0
  H  H6  1  0.808  0.414  0.751  1.0
  H  H7  1  0.889  0.468  0.852  1.0
  H  H8  1  0.468  0.889  0.852  1.0
  H  H9  1  0.786  0.016  0.842  1.0
  H  H10  1  0.215  0.502  0.071  1.0
  H  H11  1  0.192  0.701  0.120  1.0
  H  H12  1  0.973  0.691  0.121  1.0
  H  H13  1  0.121  0.520  0.242  1.0
  H  H14  1  0.210  0.210  0.075  1.0
  H  H15  1  0.502  0.215  0.071  1.0
  H  H16  1  0.701  0.192  0.120  1.0
  H  H17  1  0.975  0.208  0.130  1.0
  H  H18  1  0.208  0.975  0.130  1.0
  H  H19  1  0.691  0.973  0.121  1.0
  H  H20  1  0.520  0.121  0.242  1.0
  H  H21  1  0.118  0.118  0.249  1.0
  Ru  Ru22  1  0.062  0.062  0.892  1.0
  N  N23  1  0.353  0.871  0.836  1.0
  N  N24  1  0.918  0.918  0.885  1.0
  N  N25  1  0.871  0.353  0.836  1.0
  N  N26  1  0.498  0.498  0.530  1.0
  N  N27  1  0.125  0.603  0.142  1.0
  N  N28  1  0.603  0.125  0.142  1.0
  N  N29  1  0.127  0.127  0.150  1.0
  Cl  Cl30  1  0.835  0.835  0.532  1.0
  Cl  Cl31  1  0.612  0.612  0.182  1.0
  Cl  Cl32  1  0.346  0.346  0.912  1.0
  Cl  Cl33  1  0.174  0.174  0.446  1.0
  O  O34  1  0.885  0.885  0.382  1.0
  O  O35  1  0.306  0.977  0.390  1.0
  O  O36  1  0.297  0.297  0.391  1.0
  O  O37  1  0.977  0.306  0.390  1.0
  O  O38  1  0.715  0.715  0.582  1.0
  O  O39  1  0.036  0.707  0.582  1.0
  O  O40  1  0.707  0.036  0.582  1.0
  O  O41  1  0.125  0.125  0.591  1.0
[/CIF]
.