The structure described by NaPO crystallizes in the orthorhombic Imma space group. Na(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. P(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to two equivalent Na(1) and four equivalent P(1) atoms to form a mixture of corner and edge-sharing ONa2P4 octahedra. The corner-sharing octahedra are not tilted. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaPO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.768
_cell_length_b   5.768
_cell_length_c   5.768
_cell_angle_alpha   148.865
_cell_angle_beta   115.973
_cell_angle_gamma   72.908
_symmetry_Int_Tables_number   1
_cell_volume   87.827
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.000  0.500  1.0
  Na  Na1  1  0.000  0.500  0.500  1.0
  P  P2  1  0.000  0.000  0.500  1.0
  P  P3  1  0.500  0.000  0.000  1.0
  O  O4  1  0.250  0.507  0.257  1.0
  O  O5  1  0.750  0.493  0.743  1.0
[/CIF]
.
The structure described by NaPO crystallizes in the orthorhombic Imma space group. Na(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. P(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. O(1) is bonded to two equivalent Na(1) and four equivalent P(1) atoms to form a mixture of corner and edge-sharing ONa2P4 octahedra. The corner-sharing octahedra are not tilted. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaPO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.768
_cell_length_b   5.768
_cell_length_c   5.768
_cell_angle_alpha   148.865
_cell_angle_beta   115.973
_cell_angle_gamma   72.908
_symmetry_Int_Tables_number   1
_cell_volume   87.827
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.500  0.000  0.500  1.0
  Na  Na1  1  0.000  0.500  0.500  1.0
  P  P2  1  0.000  0.000  0.500  1.0
  P  P3  1  0.500  0.000  0.000  1.0
  O  O4  1  0.250  0.507  0.257  1.0
  O  O5  1  0.750  0.493  0.743  1.0
[/CIF]
.