The compound described by CuC5NH9O5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CuC5NH9O5 cluster. Cu(1) is bonded in a square pyramidal geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one H(1), one O(1), and one O(2) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one H(2), one O(3), and one O(4) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(1), one H(3), and one O(5) atom. In the fourth C site, C(4) is bonded to one N(1), one H(4), one H(5), and one H(6) atom to form corner-sharing CH3N tetrahedra. In the fifth C site, C(5) is bonded to one N(1); one H(9); and two equivalent H(7,8) atoms to form corner-sharing CH3N tetrahedra. N(1) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(5) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7,8) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CuH9C5NO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.736
_cell_length_b   7.830
_cell_length_c   10.353
_cell_angle_alpha   100.571
_cell_angle_beta   100.159
_cell_angle_gamma   109.774
_symmetry_Int_Tables_number   1
_cell_volume   488.079
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.875  0.432  0.874  1.0
  Cu  Cu1  1  0.125  0.568  0.126  1.0
  H  H2  1  0.415  0.823  0.882  1.0
  H  H3  1  0.585  0.177  0.118  1.0
  H  H4  1  0.220  0.137  0.937  1.0
  H  H5  1  0.780  0.863  0.063  1.0
  H  H6  1  0.387  0.362  0.714  1.0
  H  H7  1  0.613  0.638  0.286  1.0
  H  H8  1  0.561  0.196  0.422  1.0
  H  H9  1  0.439  0.804  0.578  1.0
  H  H10  1  0.284  0.044  0.337  1.0
  H  H11  1  0.716  0.956  0.663  1.0
  H  H12  1  0.388  0.278  0.319  1.0
  H  H13  1  0.612  0.722  0.681  1.0
  H  H14  1  0.080  0.315  0.584  1.0
  H  H15  1  0.920  0.685  0.416  1.0
  H  H16  1  0.094  0.353  0.420  1.0
  H  H17  1  0.906  0.647  0.580  1.0
  H  H18  1  0.986  0.119  0.438  1.0
  H  H19  1  0.014  0.881  0.562  1.0
  C  C20  1  0.289  0.723  0.917  1.0
  C  C21  1  0.711  0.277  0.083  1.0
  C  C22  1  0.153  0.248  0.954  1.0
  C  C23  1  0.847  0.752  0.046  1.0
  C  C24  1  0.462  0.316  0.635  1.0
  C  C25  1  0.538  0.684  0.365  1.0
  C  C26  1  0.395  0.190  0.390  1.0
  C  C27  1  0.605  0.810  0.610  1.0
  C  C28  1  0.110  0.262  0.487  1.0
  C  C29  1  0.890  0.738  0.513  1.0
  N  N30  1  0.328  0.257  0.509  1.0
  N  N31  1  0.672  0.743  0.491  1.0
  O  O32  1  0.121  0.611  0.824  1.0
  O  O33  1  0.879  0.389  0.176  1.0
  O  O34  1  0.334  0.737  0.044  1.0
  O  O35  1  0.666  0.263  0.956  1.0
  O  O36  1  0.015  0.245  0.852  1.0
  O  O37  1  0.985  0.755  0.148  1.0
  O  O38  1  0.227  0.359  0.072  1.0
  O  O39  1  0.773  0.641  0.928  1.0
  O  O40  1  0.653  0.321  0.662  1.0
  O  O41  1  0.347  0.679  0.338  1.0
[/CIF]
.
The compound described by CuC5NH9O5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CuC5NH9O5 cluster. Cu(1) is bonded in a square pyramidal geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one H(1), one O(1), and one O(2) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one H(2), one O(3), and one O(4) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(1), one H(3), and one O(5) atom. In the fourth C site, C(4) is bonded to one N(1), one H(4), one H(5), and one H(6) atom to form corner-sharing CH3N tetrahedra. In the fifth C site, C(5) is bonded to one N(1); one H(9); and two equivalent H(7,8) atoms to form corner-sharing CH3N tetrahedra. N(1) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(5) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7,8) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CuH9C5NO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.736
_cell_length_b   7.830
_cell_length_c   10.353
_cell_angle_alpha   100.571
_cell_angle_beta   100.159
_cell_angle_gamma   109.774
_symmetry_Int_Tables_number   1
_cell_volume   488.079
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.875  0.432  0.874  1.0
  Cu  Cu1  1  0.125  0.568  0.126  1.0
  H  H2  1  0.415  0.823  0.882  1.0
  H  H3  1  0.585  0.177  0.118  1.0
  H  H4  1  0.220  0.137  0.937  1.0
  H  H5  1  0.780  0.863  0.063  1.0
  H  H6  1  0.387  0.362  0.714  1.0
  H  H7  1  0.613  0.638  0.286  1.0
  H  H8  1  0.561  0.196  0.422  1.0
  H  H9  1  0.439  0.804  0.578  1.0
  H  H10  1  0.284  0.044  0.337  1.0
  H  H11  1  0.716  0.956  0.663  1.0
  H  H12  1  0.388  0.278  0.319  1.0
  H  H13  1  0.612  0.722  0.681  1.0
  H  H14  1  0.080  0.315  0.584  1.0
  H  H15  1  0.920  0.685  0.416  1.0
  H  H16  1  0.094  0.353  0.420  1.0
  H  H17  1  0.906  0.647  0.580  1.0
  H  H18  1  0.986  0.119  0.438  1.0
  H  H19  1  0.014  0.881  0.562  1.0
  C  C20  1  0.289  0.723  0.917  1.0
  C  C21  1  0.711  0.277  0.083  1.0
  C  C22  1  0.153  0.248  0.954  1.0
  C  C23  1  0.847  0.752  0.046  1.0
  C  C24  1  0.462  0.316  0.635  1.0
  C  C25  1  0.538  0.684  0.365  1.0
  C  C26  1  0.395  0.190  0.390  1.0
  C  C27  1  0.605  0.810  0.610  1.0
  C  C28  1  0.110  0.262  0.487  1.0
  C  C29  1  0.890  0.738  0.513  1.0
  N  N30  1  0.328  0.257  0.509  1.0
  N  N31  1  0.672  0.743  0.491  1.0
  O  O32  1  0.121  0.611  0.824  1.0
  O  O33  1  0.879  0.389  0.176  1.0
  O  O34  1  0.334  0.737  0.044  1.0
  O  O35  1  0.666  0.263  0.956  1.0
  O  O36  1  0.015  0.245  0.852  1.0
  O  O37  1  0.985  0.755  0.148  1.0
  O  O38  1  0.227  0.359  0.072  1.0
  O  O39  1  0.773  0.641  0.928  1.0
  O  O40  1  0.653  0.321  0.662  1.0
  O  O41  1  0.347  0.679  0.338  1.0
[/CIF]
.