The material described by Al5Re24 is alpha-derived structured and crystallizes in the cubic I-43m space group. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 13-coordinate geometry to five equivalent Re(2), six equivalent Re(1), and two equivalent Al(2) atoms. In the second Re site, Re(2) is bonded in a 12-coordinate geometry to three equivalent Re(2), five equivalent Re(1), one Al(1), and three equivalent Al(2) atoms. There are two inequivalent Al sites. In the first Al site, Al(1) is bonded in a 16-coordinate geometry to twelve equivalent Re(2) and four equivalent Al(2) atoms. In the second Al site, Al(2) is bonded in a 16-coordinate geometry to six equivalent Re(1), nine equivalent Re(2), and one Al(1) atom. is represented by the CIF card [CIF]
data_Al5Re24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.338
_cell_length_b   8.338
_cell_length_c   8.338
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   446.172
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.000  0.000  0.000  1.0
  Al  Al1  1  0.641  0.000  0.000  1.0
  Al  Al2  1  0.000  0.641  0.000  1.0
  Al  Al3  1  0.000  0.000  0.641  1.0
  Al  Al4  1  0.359  0.359  0.359  1.0
  Re  Re5  1  0.399  0.680  0.000  1.0
  Re  Re6  1  0.718  0.320  0.320  1.0
  Re  Re7  1  0.399  0.000  0.680  1.0
  Re  Re8  1  0.680  0.399  0.000  1.0
  Re  Re9  1  0.000  0.399  0.680  1.0
  Re  Re10  1  0.320  0.718  0.320  1.0
  Re  Re11  1  0.320  0.320  0.718  1.0
  Re  Re12  1  0.000  0.680  0.399  1.0
  Re  Re13  1  0.680  0.000  0.399  1.0
  Re  Re14  1  0.601  0.601  0.282  1.0
  Re  Re15  1  0.282  0.601  0.601  1.0
  Re  Re16  1  0.601  0.282  0.601  1.0
  Re  Re17  1  0.375  0.192  0.000  1.0
  Re  Re18  1  0.183  0.808  0.808  1.0
  Re  Re19  1  0.375  0.000  0.192  1.0
  Re  Re20  1  0.192  0.375  0.000  1.0
  Re  Re21  1  0.000  0.375  0.192  1.0
  Re  Re22  1  0.808  0.183  0.808  1.0
  Re  Re23  1  0.808  0.808  0.183  1.0
  Re  Re24  1  0.000  0.192  0.375  1.0
  Re  Re25  1  0.192  0.000  0.375  1.0
  Re  Re26  1  0.625  0.625  0.817  1.0
  Re  Re27  1  0.817  0.625  0.625  1.0
  Re  Re28  1  0.625  0.817  0.625  1.0
[/CIF]
.
The material described by Al5Re24 is alpha-derived structured and crystallizes in the cubic I-43m space group. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 13-coordinate geometry to five equivalent Re(2), six equivalent Re(1), and two equivalent Al(2) atoms. In the second Re site, Re(2) is bonded in a 12-coordinate geometry to three equivalent Re(2), five equivalent Re(1), one Al(1), and three equivalent Al(2) atoms. There are two inequivalent Al sites. In the first Al site, Al(1) is bonded in a 16-coordinate geometry to twelve equivalent Re(2) and four equivalent Al(2) atoms. In the second Al site, Al(2) is bonded in a 16-coordinate geometry to six equivalent Re(1), nine equivalent Re(2), and one Al(1) atom. is represented by the CIF card [CIF]
data_Al5Re24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.338
_cell_length_b   8.338
_cell_length_c   8.338
_cell_angle_alpha   109.471
_cell_angle_beta   109.471
_cell_angle_gamma   109.471
_symmetry_Int_Tables_number   1
_cell_volume   446.172
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.000  0.000  0.000  1.0
  Al  Al1  1  0.641  0.000  0.000  1.0
  Al  Al2  1  0.000  0.641  0.000  1.0
  Al  Al3  1  0.000  0.000  0.641  1.0
  Al  Al4  1  0.359  0.359  0.359  1.0
  Re  Re5  1  0.399  0.680  0.000  1.0
  Re  Re6  1  0.718  0.320  0.320  1.0
  Re  Re7  1  0.399  0.000  0.680  1.0
  Re  Re8  1  0.680  0.399  0.000  1.0
  Re  Re9  1  0.000  0.399  0.680  1.0
  Re  Re10  1  0.320  0.718  0.320  1.0
  Re  Re11  1  0.320  0.320  0.718  1.0
  Re  Re12  1  0.000  0.680  0.399  1.0
  Re  Re13  1  0.680  0.000  0.399  1.0
  Re  Re14  1  0.601  0.601  0.282  1.0
  Re  Re15  1  0.282  0.601  0.601  1.0
  Re  Re16  1  0.601  0.282  0.601  1.0
  Re  Re17  1  0.375  0.192  0.000  1.0
  Re  Re18  1  0.183  0.808  0.808  1.0
  Re  Re19  1  0.375  0.000  0.192  1.0
  Re  Re20  1  0.192  0.375  0.000  1.0
  Re  Re21  1  0.000  0.375  0.192  1.0
  Re  Re22  1  0.808  0.183  0.808  1.0
  Re  Re23  1  0.808  0.808  0.183  1.0
  Re  Re24  1  0.000  0.192  0.375  1.0
  Re  Re25  1  0.192  0.000  0.375  1.0
  Re  Re26  1  0.625  0.625  0.817  1.0
  Re  Re27  1  0.817  0.625  0.625  1.0
  Re  Re28  1  0.625  0.817  0.625  1.0
[/CIF]
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