The material described by Ce2Pd4In5 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 6-coordinate geometry to one Pd(1), one Pd(2), one Pd(3), and three equivalent Pd(4) atoms. In the second Ce site, Ce(2) is bonded in a 14-coordinate geometry to two equivalent Pd(1), two equivalent Pd(3), one In(1), one In(4), two equivalent In(2), three equivalent In(3), and three equivalent In(5) atoms. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to one Ce(1), two equivalent Ce(2), one In(2), two equivalent In(1), and three equivalent In(5) atoms. In the second Pd site, Pd(2) is bonded in a body-centered cubic geometry to one Ce(1), one In(4), three equivalent In(1), and three equivalent In(2) atoms. In the third Pd site, Pd(3) is bonded in a 9-coordinate geometry to one Ce(1), two equivalent Ce(2), one In(2), two equivalent In(4), and three equivalent In(3) atoms. In the fourth Pd site, Pd(4) is bonded in a distorted body-centered cubic geometry to three equivalent Ce(1), one In(1), one In(2), and three equivalent In(4) atoms. There are five inequivalent In sites. In the first In site, In(1) is bonded in a 6-coordinate geometry to one Ce(2), one Pd(4), two equivalent Pd(1), and three equivalent Pd(2) atoms. In the second In site, In(2) is bonded in a 6-coordinate geometry to two equivalent Ce(2), one Pd(1), one Pd(3), one Pd(4), and three equivalent Pd(2) atoms. In the third In site, In(3) is bonded in a 3-coordinate geometry to three equivalent Ce(2) and three equivalent Pd(3) atoms. In the fourth In site, In(4) is bonded in a 6-coordinate geometry to one Ce(2), one Pd(2), two equivalent Pd(3), and three equivalent Pd(4) atoms. In the fifth In site, In(5) is bonded in a 3-coordinate geometry to three equivalent Ce(2) and three equivalent Pd(1) atoms. is represented by the CIF card [CIF]
data_Ce2In5Pd4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.667
_cell_length_b   9.723
_cell_length_c   10.641
_cell_angle_alpha   77.302
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   471.062
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.250  0.326  0.703  1.0
  Ce  Ce1  1  0.750  0.674  0.297  1.0
  Ce  Ce2  1  0.250  0.224  0.111  1.0
  Ce  Ce3  1  0.750  0.776  0.889  1.0
  In  In4  1  0.750  0.083  0.653  1.0
  In  In5  1  0.250  0.833  0.650  1.0
  In  In6  1  0.750  0.423  0.921  1.0
  In  In7  1  0.750  0.167  0.350  1.0
  In  In8  1  0.750  0.594  0.640  1.0
  In  In9  1  0.250  0.882  0.075  1.0
  In  In10  1  0.250  0.577  0.079  1.0
  In  In11  1  0.250  0.917  0.347  1.0
  In  In12  1  0.750  0.118  0.925  1.0
  In  In13  1  0.250  0.406  0.360  1.0
  Pd  Pd14  1  0.250  0.017  0.815  1.0
  Pd  Pd15  1  0.250  0.123  0.504  1.0
  Pd  Pd16  1  0.750  0.426  0.184  1.0
  Pd  Pd17  1  0.750  0.877  0.496  1.0
  Pd  Pd18  1  0.750  0.983  0.185  1.0
  Pd  Pd19  1  0.750  0.371  0.513  1.0
  Pd  Pd20  1  0.250  0.574  0.816  1.0
  Pd  Pd21  1  0.250  0.629  0.487  1.0
[/CIF]
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The material described by Ce2Pd4In5 crystallizes in the monoclinic P2_1/m space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 6-coordinate geometry to one Pd(1), one Pd(2), one Pd(3), and three equivalent Pd(4) atoms. In the second Ce site, Ce(2) is bonded in a 14-coordinate geometry to two equivalent Pd(1), two equivalent Pd(3), one In(1), one In(4), two equivalent In(2), three equivalent In(3), and three equivalent In(5) atoms. There are four inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to one Ce(1), two equivalent Ce(2), one In(2), two equivalent In(1), and three equivalent In(5) atoms. In the second Pd site, Pd(2) is bonded in a body-centered cubic geometry to one Ce(1), one In(4), three equivalent In(1), and three equivalent In(2) atoms. In the third Pd site, Pd(3) is bonded in a 9-coordinate geometry to one Ce(1), two equivalent Ce(2), one In(2), two equivalent In(4), and three equivalent In(3) atoms. In the fourth Pd site, Pd(4) is bonded in a distorted body-centered cubic geometry to three equivalent Ce(1), one In(1), one In(2), and three equivalent In(4) atoms. There are five inequivalent In sites. In the first In site, In(1) is bonded in a 6-coordinate geometry to one Ce(2), one Pd(4), two equivalent Pd(1), and three equivalent Pd(2) atoms. In the second In site, In(2) is bonded in a 6-coordinate geometry to two equivalent Ce(2), one Pd(1), one Pd(3), one Pd(4), and three equivalent Pd(2) atoms. In the third In site, In(3) is bonded in a 3-coordinate geometry to three equivalent Ce(2) and three equivalent Pd(3) atoms. In the fourth In site, In(4) is bonded in a 6-coordinate geometry to one Ce(2), one Pd(2), two equivalent Pd(3), and three equivalent Pd(4) atoms. In the fifth In site, In(5) is bonded in a 3-coordinate geometry to three equivalent Ce(2) and three equivalent Pd(1) atoms. is represented by the CIF card [CIF]
data_Ce2In5Pd4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.667
_cell_length_b   9.723
_cell_length_c   10.641
_cell_angle_alpha   77.302
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   471.062
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.250  0.326  0.703  1.0
  Ce  Ce1  1  0.750  0.674  0.297  1.0
  Ce  Ce2  1  0.250  0.224  0.111  1.0
  Ce  Ce3  1  0.750  0.776  0.889  1.0
  In  In4  1  0.750  0.083  0.653  1.0
  In  In5  1  0.250  0.833  0.650  1.0
  In  In6  1  0.750  0.423  0.921  1.0
  In  In7  1  0.750  0.167  0.350  1.0
  In  In8  1  0.750  0.594  0.640  1.0
  In  In9  1  0.250  0.882  0.075  1.0
  In  In10  1  0.250  0.577  0.079  1.0
  In  In11  1  0.250  0.917  0.347  1.0
  In  In12  1  0.750  0.118  0.925  1.0
  In  In13  1  0.250  0.406  0.360  1.0
  Pd  Pd14  1  0.250  0.017  0.815  1.0
  Pd  Pd15  1  0.250  0.123  0.504  1.0
  Pd  Pd16  1  0.750  0.426  0.184  1.0
  Pd  Pd17  1  0.750  0.877  0.496  1.0
  Pd  Pd18  1  0.750  0.983  0.185  1.0
  Pd  Pd19  1  0.750  0.371  0.513  1.0
  Pd  Pd20  1  0.250  0.574  0.816  1.0
  Pd  Pd21  1  0.250  0.629  0.487  1.0
[/CIF]
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