The compound described by Rb3P3(HO3)4 crystallizes in the triclinic P-1 space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 5-coordinate geometry to one O(11), one O(4), one O(6), one O(7), and one O(9) atom. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to one H(1), one O(1), one O(11), one O(2), one O(8), one O(9), and two equivalent O(5) atoms. In the third Rb site, Rb(3) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(4), one O(6), one O(9), and two equivalent O(8) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(2), one O(5), one O(6), and one O(7) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(3), one O(7), one O(8), and one O(9) atom to form corner-sharing PO4 tetrahedra. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Rb(2) and one O(10) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(10) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(11) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(11) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Rb(2), one P(1), and one P(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(3), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Rb(2) and one P(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Rb(1), one Rb(3), and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(2), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(3), and one P(3) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(3), and one P(3) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Rb(3), one H(1), and one H(2) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one Rb(1), one Rb(2), one H(3), and one H(4) atom. In the twelfth O site, O(12) is bonded in a distorted L-shaped geometry to one Rb(3) and one O(12) atom. is represented by the CIF card [CIF]
data_Rb3P3(HO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.709
_cell_length_b   9.722
_cell_length_c   9.782
_cell_angle_alpha   119.448
_cell_angle_beta   111.730
_cell_angle_gamma   86.261
_symmetry_Int_Tables_number   1
_cell_volume   662.915
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.406  0.667  0.186  1.0
  Rb  Rb1  1  0.594  0.333  0.814  1.0
  Rb  Rb2  1  0.144  0.068  0.274  1.0
  Rb  Rb3  1  0.856  0.932  0.726  1.0
  Rb  Rb4  1  0.257  0.681  0.696  1.0
  Rb  Rb5  1  0.743  0.319  0.304  1.0
  P  P6  1  0.914  0.695  0.299  1.0
  P  P7  1  0.086  0.305  0.701  1.0
  P  P8  1  0.748  0.778  0.027  1.0
  P  P9  1  0.252  0.222  0.973  1.0
  P  P10  1  0.954  0.606  0.832  1.0
  P  P11  1  0.046  0.394  0.168  1.0
  H  H12  1  0.622  0.964  0.886  1.0
  H  H13  1  0.378  0.036  0.114  1.0
  H  H14  1  0.507  0.914  0.117  1.0
  H  H15  1  0.493  0.086  0.883  1.0
  H  H16  1  0.402  0.943  0.590  1.0
  H  H17  1  0.598  0.057  0.410  1.0
  H  H18  1  0.213  0.882  0.482  1.0
  H  H19  1  0.787  0.118  0.518  1.0
  O  O20  1  0.030  0.803  0.480  1.0
  O  O21  1  0.970  0.197  0.520  1.0
  O  O22  1  0.880  0.804  0.208  1.0
  O  O23  1  0.120  0.196  0.792  1.0
  O  O24  1  0.021  0.572  0.197  1.0
  O  O25  1  0.979  0.428  0.803  1.0
  O  O26  1  0.753  0.608  0.257  1.0
  O  O27  1  0.247  0.392  0.743  1.0
  O  O28  1  0.789  0.921  0.019  1.0
  O  O29  1  0.211  0.079  0.981  1.0
  O  O30  1  0.571  0.734  0.998  1.0
  O  O31  1  0.429  0.266  0.002  1.0
  O  O32  1  0.795  0.619  0.889  1.0
  O  O33  1  0.205  0.381  0.111  1.0
  O  O34  1  0.888  0.599  0.663  1.0
  O  O35  1  0.112  0.401  0.337  1.0
  O  O36  1  0.103  0.726  0.975  1.0
  O  O37  1  0.897  0.274  0.025  1.0
  O  O38  1  0.471  0.011  0.193  1.0
  O  O39  1  0.529  0.989  0.807  1.0
  O  O40  1  0.316  0.913  0.477  1.0
  O  O41  1  0.684  0.087  0.523  1.0
  O  O42  1  0.456  0.449  0.494  1.0
  O  O43  1  0.544  0.551  0.506  1.0
[/CIF]
.
The compound described by Rb3P3(HO3)4 crystallizes in the triclinic P-1 space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 5-coordinate geometry to one O(11), one O(4), one O(6), one O(7), and one O(9) atom. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to one H(1), one O(1), one O(11), one O(2), one O(8), one O(9), and two equivalent O(5) atoms. In the third Rb site, Rb(3) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(4), one O(6), one O(9), and two equivalent O(8) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(2), one O(5), one O(6), and one O(7) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(3), one O(7), one O(8), and one O(9) atom to form corner-sharing PO4 tetrahedra. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Rb(2) and one O(10) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(10) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(11) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(11) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Rb(2), one P(1), and one P(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(3), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Rb(2) and one P(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Rb(1), one Rb(3), and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(2), and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(3), and one P(3) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(3), and one P(3) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Rb(3), one H(1), and one H(2) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one Rb(1), one Rb(2), one H(3), and one H(4) atom. In the twelfth O site, O(12) is bonded in a distorted L-shaped geometry to one Rb(3) and one O(12) atom. is represented by the CIF card [CIF]
data_Rb3P3(HO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.709
_cell_length_b   9.722
_cell_length_c   9.782
_cell_angle_alpha   119.448
_cell_angle_beta   111.730
_cell_angle_gamma   86.261
_symmetry_Int_Tables_number   1
_cell_volume   662.915
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.406  0.667  0.186  1.0
  Rb  Rb1  1  0.594  0.333  0.814  1.0
  Rb  Rb2  1  0.144  0.068  0.274  1.0
  Rb  Rb3  1  0.856  0.932  0.726  1.0
  Rb  Rb4  1  0.257  0.681  0.696  1.0
  Rb  Rb5  1  0.743  0.319  0.304  1.0
  P  P6  1  0.914  0.695  0.299  1.0
  P  P7  1  0.086  0.305  0.701  1.0
  P  P8  1  0.748  0.778  0.027  1.0
  P  P9  1  0.252  0.222  0.973  1.0
  P  P10  1  0.954  0.606  0.832  1.0
  P  P11  1  0.046  0.394  0.168  1.0
  H  H12  1  0.622  0.964  0.886  1.0
  H  H13  1  0.378  0.036  0.114  1.0
  H  H14  1  0.507  0.914  0.117  1.0
  H  H15  1  0.493  0.086  0.883  1.0
  H  H16  1  0.402  0.943  0.590  1.0
  H  H17  1  0.598  0.057  0.410  1.0
  H  H18  1  0.213  0.882  0.482  1.0
  H  H19  1  0.787  0.118  0.518  1.0
  O  O20  1  0.030  0.803  0.480  1.0
  O  O21  1  0.970  0.197  0.520  1.0
  O  O22  1  0.880  0.804  0.208  1.0
  O  O23  1  0.120  0.196  0.792  1.0
  O  O24  1  0.021  0.572  0.197  1.0
  O  O25  1  0.979  0.428  0.803  1.0
  O  O26  1  0.753  0.608  0.257  1.0
  O  O27  1  0.247  0.392  0.743  1.0
  O  O28  1  0.789  0.921  0.019  1.0
  O  O29  1  0.211  0.079  0.981  1.0
  O  O30  1  0.571  0.734  0.998  1.0
  O  O31  1  0.429  0.266  0.002  1.0
  O  O32  1  0.795  0.619  0.889  1.0
  O  O33  1  0.205  0.381  0.111  1.0
  O  O34  1  0.888  0.599  0.663  1.0
  O  O35  1  0.112  0.401  0.337  1.0
  O  O36  1  0.103  0.726  0.975  1.0
  O  O37  1  0.897  0.274  0.025  1.0
  O  O38  1  0.471  0.011  0.193  1.0
  O  O39  1  0.529  0.989  0.807  1.0
  O  O40  1  0.316  0.913  0.477  1.0
  O  O41  1  0.684  0.087  0.523  1.0
  O  O42  1  0.456  0.449  0.494  1.0
  O  O43  1  0.544  0.551  0.506  1.0
[/CIF]
.