The compound described by Ni(N3O2)2 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two Ni(N3O2)2 clusters. Ni(1) is bonded in an octahedral geometry to two equivalent N(1) and four equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ni(1), one O(1), and one O(2) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ni(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_Ni(N3O2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.677
_cell_length_b   6.028
_cell_length_c   6.028
_cell_angle_alpha   64.748
_cell_angle_beta   69.667
_cell_angle_gamma   69.667
_symmetry_Int_Tables_number   1
_cell_volume   170.072
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.000  0.000  0.000  1.0
  N  N1  1  0.006  0.209  0.209  1.0
  N  N2  1  0.994  0.791  0.791  1.0
  N  N3  1  0.758  0.260  0.857  1.0
  N  N4  1  0.758  0.857  0.260  1.0
  N  N5  1  0.242  0.740  0.143  1.0
  N  N6  1  0.242  0.143  0.740  1.0
  O  O7  1  0.794  0.307  0.307  1.0
  O  O8  1  0.206  0.693  0.693  1.0
  O  O9  1  0.221  0.206  0.206  1.0
  O  O10  1  0.779  0.794  0.794  1.0
[/CIF]
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The compound described by Ni(N3O2)2 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two Ni(N3O2)2 clusters. Ni(1) is bonded in an octahedral geometry to two equivalent N(1) and four equivalent N(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ni(1), one O(1), and one O(2) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Ni(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_Ni(N3O2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.677
_cell_length_b   6.028
_cell_length_c   6.028
_cell_angle_alpha   64.748
_cell_angle_beta   69.667
_cell_angle_gamma   69.667
_symmetry_Int_Tables_number   1
_cell_volume   170.072
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.000  0.000  0.000  1.0
  N  N1  1  0.006  0.209  0.209  1.0
  N  N2  1  0.994  0.791  0.791  1.0
  N  N3  1  0.758  0.260  0.857  1.0
  N  N4  1  0.758  0.857  0.260  1.0
  N  N5  1  0.242  0.740  0.143  1.0
  N  N6  1  0.242  0.143  0.740  1.0
  O  O7  1  0.794  0.307  0.307  1.0
  O  O8  1  0.206  0.693  0.693  1.0
  O  O9  1  0.221  0.206  0.206  1.0
  O  O10  1  0.779  0.794  0.794  1.0
[/CIF]
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