The structure described by NiO4NiCl4NiO4ClO2ClO2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 7782-44-7 molecule, one hydroxy hypochlorite molecule, one NiCl4 cluster, one NiO4 cluster, and one NiO4Cl cluster. In the NiCl4 cluster, Ni(1) is bonded in a tetrahedral geometry to one Cl(3), one Cl(4), one Cl(5), and one Cl(6) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Ni(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Ni(1) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Ni(1) atom. In the fourth Cl site, Cl(6) is bonded in a single-bond geometry to one Ni(1) atom. In the NiO4 cluster, Ni(2) is bonded in a trigonal planar geometry to one O(3), one O(5), and one O(6) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ni(2) and one O(4) atom. In the second O site, O(4) is bonded in a single-bond geometry to one O(3) atom. In the third O site, O(5) is bonded in a single-bond geometry to one Ni(2) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one Ni(2) atom. In the NiO4Cl cluster, Ni(3) is bonded in a T-shaped geometry to one O(10), one O(2), and one O(9) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one O(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ni(3) and one O(1) atom. In the third O site, O(9) is bonded in a single-bond geometry to one Ni(3) atom. In the fourth O site, O(10) is bonded in a bent 120 degrees geometry to one Ni(3) and one Cl(2) atom. Cl(2) is bonded in a single-bond geometry to one O(10) atom. is represented by the CIF card [CIF]
data_Ni(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.583
_cell_length_b   6.659
_cell_length_c   12.270
_cell_angle_alpha   88.548
_cell_angle_beta   82.255
_cell_angle_gamma   86.391
_symmetry_Int_Tables_number   1
_cell_volume   531.811
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.583  0.595  0.506  1.0
  Ni  Ni1  1  0.998  0.002  0.294  1.0
  Ni  Ni2  1  0.975  0.008  0.802  1.0
  Cl  Cl3  1  0.998  0.497  0.960  1.0
  Cl  Cl4  1  0.534  0.001  0.918  1.0
  Cl  Cl5  1  0.914  0.524  0.499  1.0
  Cl  Cl6  1  0.516  0.917  0.500  1.0
  Cl  Cl7  1  0.490  0.464  0.363  1.0
  Cl  Cl8  1  0.465  0.468  0.664  1.0
  O  O9  1  0.082  0.040  0.024  1.0
  O  O10  1  0.954  0.978  0.969  1.0
  O  O11  1  0.967  0.056  0.451  1.0
  O  O12  1  0.056  0.939  0.513  1.0
  O  O13  1  0.792  0.005  0.238  1.0
  O  O14  1  0.227  0.964  0.231  1.0
  O  O15  1  0.090  0.433  0.222  1.0
  O  O16  1  0.942  0.556  0.238  1.0
  O  O17  1  0.239  0.029  0.762  1.0
  O  O18  1  0.699  0.006  0.807  1.0
  O  O19  1  0.030  0.567  0.734  1.0
  O  O20  1  0.950  0.451  0.805  1.0
[/CIF]
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The structure described by NiO4NiCl4NiO4ClO2ClO2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 7782-44-7 molecule, one hydroxy hypochlorite molecule, one NiCl4 cluster, one NiO4 cluster, and one NiO4Cl cluster. In the NiCl4 cluster, Ni(1) is bonded in a tetrahedral geometry to one Cl(3), one Cl(4), one Cl(5), and one Cl(6) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Ni(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Ni(1) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Ni(1) atom. In the fourth Cl site, Cl(6) is bonded in a single-bond geometry to one Ni(1) atom. In the NiO4 cluster, Ni(2) is bonded in a trigonal planar geometry to one O(3), one O(5), and one O(6) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ni(2) and one O(4) atom. In the second O site, O(4) is bonded in a single-bond geometry to one O(3) atom. In the third O site, O(5) is bonded in a single-bond geometry to one Ni(2) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one Ni(2) atom. In the NiO4Cl cluster, Ni(3) is bonded in a T-shaped geometry to one O(10), one O(2), and one O(9) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one O(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ni(3) and one O(1) atom. In the third O site, O(9) is bonded in a single-bond geometry to one Ni(3) atom. In the fourth O site, O(10) is bonded in a bent 120 degrees geometry to one Ni(3) and one Cl(2) atom. Cl(2) is bonded in a single-bond geometry to one O(10) atom. is represented by the CIF card [CIF]
data_Ni(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.583
_cell_length_b   6.659
_cell_length_c   12.270
_cell_angle_alpha   88.548
_cell_angle_beta   82.255
_cell_angle_gamma   86.391
_symmetry_Int_Tables_number   1
_cell_volume   531.811
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.583  0.595  0.506  1.0
  Ni  Ni1  1  0.998  0.002  0.294  1.0
  Ni  Ni2  1  0.975  0.008  0.802  1.0
  Cl  Cl3  1  0.998  0.497  0.960  1.0
  Cl  Cl4  1  0.534  0.001  0.918  1.0
  Cl  Cl5  1  0.914  0.524  0.499  1.0
  Cl  Cl6  1  0.516  0.917  0.500  1.0
  Cl  Cl7  1  0.490  0.464  0.363  1.0
  Cl  Cl8  1  0.465  0.468  0.664  1.0
  O  O9  1  0.082  0.040  0.024  1.0
  O  O10  1  0.954  0.978  0.969  1.0
  O  O11  1  0.967  0.056  0.451  1.0
  O  O12  1  0.056  0.939  0.513  1.0
  O  O13  1  0.792  0.005  0.238  1.0
  O  O14  1  0.227  0.964  0.231  1.0
  O  O15  1  0.090  0.433  0.222  1.0
  O  O16  1  0.942  0.556  0.238  1.0
  O  O17  1  0.239  0.029  0.762  1.0
  O  O18  1  0.699  0.006  0.807  1.0
  O  O19  1  0.030  0.567  0.734  1.0
  O  O20  1  0.950  0.451  0.805  1.0
[/CIF]
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