The compound described by Ba2BiSbO6 crystallizes in the trigonal R-3 space group. Ba(1) is bonded in a 12-coordinate geometry to twelve equivalent O(1) atoms. Bi(1) is bonded to six equivalent O(1) atoms to form BiO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 15°. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles are 15°. O(1) is bonded in a 6-coordinate geometry to four equivalent Ba(1), one Bi(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_Ba2BiSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.103
_cell_length_b   6.103
_cell_length_c   6.103
_cell_angle_alpha   60.478
_cell_angle_beta   60.478
_cell_angle_gamma   60.478
_symmetry_Int_Tables_number   1
_cell_volume   162.475
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.251  0.251  0.251  1.0
  Ba  Ba1  1  0.749  0.749  0.749  1.0
  Bi  Bi2  1  0.000  0.000  0.000  1.0
  Sb  Sb3  1  0.500  0.500  0.500  1.0
  O  O4  1  0.729  0.221  0.315  1.0
  O  O5  1  0.221  0.315  0.729  1.0
  O  O6  1  0.315  0.729  0.221  1.0
  O  O7  1  0.271  0.779  0.685  1.0
  O  O8  1  0.685  0.271  0.779  1.0
  O  O9  1  0.779  0.685  0.271  1.0
[/CIF]
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The compound described by Ba2BiSbO6 crystallizes in the trigonal R-3 space group. Ba(1) is bonded in a 12-coordinate geometry to twelve equivalent O(1) atoms. Bi(1) is bonded to six equivalent O(1) atoms to form BiO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 15°. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles are 15°. O(1) is bonded in a 6-coordinate geometry to four equivalent Ba(1), one Bi(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_Ba2BiSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.103
_cell_length_b   6.103
_cell_length_c   6.103
_cell_angle_alpha   60.478
_cell_angle_beta   60.478
_cell_angle_gamma   60.478
_symmetry_Int_Tables_number   1
_cell_volume   162.475
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.251  0.251  0.251  1.0
  Ba  Ba1  1  0.749  0.749  0.749  1.0
  Bi  Bi2  1  0.000  0.000  0.000  1.0
  Sb  Sb3  1  0.500  0.500  0.500  1.0
  O  O4  1  0.729  0.221  0.315  1.0
  O  O5  1  0.221  0.315  0.729  1.0
  O  O6  1  0.315  0.729  0.221  1.0
  O  O7  1  0.271  0.779  0.685  1.0
  O  O8  1  0.685  0.271  0.779  1.0
  O  O9  1  0.779  0.685  0.271  1.0
[/CIF]
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