The material described by Li5Co3(SbO5)2 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 1-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. In the second Li site, Li(2) is bonded in a 2-coordinate geometry to one Co(1), one O(1), one O(2), and one O(5) atom. In the third Li site, Li(3) is bonded in a 8-coordinate geometry to two equivalent Sb(1), two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 12-coordinate geometry to two equivalent Li(2), two equivalent Co(2), two equivalent O(1), two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. In the second Co site, Co(2) is bonded in a 3-coordinate geometry to one Co(1), one O(1), one O(4), and two equivalent O(2) atoms. Sb(1) is bonded in a 2-coordinate geometry to one Li(3), one O(1), one O(2), one O(3), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Li(1), one Li(2), one Li(3), one Co(1), one Co(2), and one Sb(1) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to one Li(1), one Li(2), one Co(1), two equivalent Co(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Li(3), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to one Li(1), one Co(1), and one Co(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Li(3), one Co(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_Li5Co3(SbO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.256
_cell_length_b   5.287
_cell_length_c   8.088
_cell_angle_alpha   106.780
_cell_angle_beta   103.288
_cell_angle_gamma   101.529
_symmetry_Int_Tables_number   1
_cell_volume   200.696
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.838  0.507  0.393  1.0
  Li  Li1  1  0.616  0.493  0.803  1.0
  Li  Li2  1  0.000  0.000  0.500  1.0
  Li  Li3  1  0.384  0.507  0.197  1.0
  Li  Li4  1  0.162  0.493  0.607  1.0
  Co  Co5  1  0.000  0.500  0.000  1.0
  Co  Co6  1  0.821  0.996  0.909  1.0
  Co  Co7  1  0.179  0.004  0.091  1.0
  Sb  Sb8  1  0.413  0.004  0.700  1.0
  Sb  Sb9  1  0.587  0.996  0.300  1.0
  O  O10  1  0.233  0.243  0.825  1.0
  O  O11  1  0.407  0.754  0.932  1.0
  O  O12  1  0.592  0.782  0.546  1.0
  O  O13  1  0.969  0.247  0.246  1.0
  O  O14  1  0.786  0.237  0.657  1.0
  O  O15  1  0.214  0.763  0.343  1.0
  O  O16  1  0.031  0.753  0.754  1.0
  O  O17  1  0.408  0.218  0.454  1.0
  O  O18  1  0.593  0.246  0.068  1.0
  O  O19  1  0.767  0.757  0.175  1.0
[/CIF]
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The material described by Li5Co3(SbO5)2 crystallizes in the triclinic P-1 space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded in a 1-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. In the second Li site, Li(2) is bonded in a 2-coordinate geometry to one Co(1), one O(1), one O(2), and one O(5) atom. In the third Li site, Li(3) is bonded in a 8-coordinate geometry to two equivalent Sb(1), two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 12-coordinate geometry to two equivalent Li(2), two equivalent Co(2), two equivalent O(1), two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms. In the second Co site, Co(2) is bonded in a 3-coordinate geometry to one Co(1), one O(1), one O(4), and two equivalent O(2) atoms. Sb(1) is bonded in a 2-coordinate geometry to one Li(3), one O(1), one O(2), one O(3), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Li(1), one Li(2), one Li(3), one Co(1), one Co(2), and one Sb(1) atom. In the second O site, O(2) is bonded in a 6-coordinate geometry to one Li(1), one Li(2), one Co(1), two equivalent Co(2), and one Sb(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Li(3), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to one Li(1), one Co(1), and one Co(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Li(1), one Li(2), one Li(3), one Co(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_Li5Co3(SbO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.256
_cell_length_b   5.287
_cell_length_c   8.088
_cell_angle_alpha   106.780
_cell_angle_beta   103.288
_cell_angle_gamma   101.529
_symmetry_Int_Tables_number   1
_cell_volume   200.696
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.838  0.507  0.393  1.0
  Li  Li1  1  0.616  0.493  0.803  1.0
  Li  Li2  1  0.000  0.000  0.500  1.0
  Li  Li3  1  0.384  0.507  0.197  1.0
  Li  Li4  1  0.162  0.493  0.607  1.0
  Co  Co5  1  0.000  0.500  0.000  1.0
  Co  Co6  1  0.821  0.996  0.909  1.0
  Co  Co7  1  0.179  0.004  0.091  1.0
  Sb  Sb8  1  0.413  0.004  0.700  1.0
  Sb  Sb9  1  0.587  0.996  0.300  1.0
  O  O10  1  0.233  0.243  0.825  1.0
  O  O11  1  0.407  0.754  0.932  1.0
  O  O12  1  0.592  0.782  0.546  1.0
  O  O13  1  0.969  0.247  0.246  1.0
  O  O14  1  0.786  0.237  0.657  1.0
  O  O15  1  0.214  0.763  0.343  1.0
  O  O16  1  0.031  0.753  0.754  1.0
  O  O17  1  0.408  0.218  0.454  1.0
  O  O18  1  0.593  0.246  0.068  1.0
  O  O19  1  0.767  0.757  0.175  1.0
[/CIF]
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