The structure described by V5CdTl4O15Cl crystallizes in the tetragonal P4 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form VO4 tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra and  a cornercorner with one V(2)O5 trigonal bipyramid. In the second V site, V(2) is bonded to one O(5) and four equivalent O(4) atoms to form distorted corner-sharing VO5 trigonal bipyramids. Cd(1) is bonded in a 5-coordinate geometry to four equivalent O(3) and one Cl(1) atom. Tl(1) is bonded in a distorted L-shaped geometry to one O(1) and one O(3) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) and one Tl(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the third O site, O(3) is bonded in a 3-coordinate geometry to one V(1), one Cd(1), and one Tl(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one V(2) atom. Cl(1) is bonded in a distorted single-bond geometry to one Cd(1) atom. is represented by the CIF card [CIF]
data_Tl4V5CdClO15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.274
_cell_length_b   9.274
_cell_length_c   5.714
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   491.527
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.834  0.313  0.920  1.0
  Tl  Tl1  1  0.166  0.687  0.920  1.0
  Tl  Tl2  1  0.687  0.834  0.920  1.0
  Tl  Tl3  1  0.313  0.166  0.920  1.0
  V  V4  1  0.857  0.619  0.447  1.0
  V  V5  1  0.381  0.857  0.447  1.0
  V  V6  1  0.619  0.143  0.447  1.0
  V  V7  1  0.500  0.500  0.472  1.0
  V  V8  1  0.143  0.381  0.447  1.0
  Cd  Cd9  1  0.000  0.000  0.489  1.0
  Cl  Cl10  1  0.000  0.000  0.034  1.0
  O  O11  1  0.145  0.376  0.155  1.0
  O  O12  1  0.000  0.500  0.551  1.0
  O  O13  1  0.376  0.855  0.155  1.0
  O  O14  1  0.855  0.624  0.155  1.0
  O  O15  1  0.116  0.211  0.561  1.0
  O  O16  1  0.789  0.116  0.561  1.0
  O  O17  1  0.448  0.691  0.560  1.0
  O  O18  1  0.884  0.789  0.561  1.0
  O  O19  1  0.552  0.309  0.560  1.0
  O  O20  1  0.309  0.448  0.560  1.0
  O  O21  1  0.624  0.145  0.155  1.0
  O  O22  1  0.500  0.000  0.551  1.0
  O  O23  1  0.691  0.552  0.560  1.0
  O  O24  1  0.211  0.884  0.561  1.0
  O  O25  1  0.500  0.500  0.189  1.0
[/CIF]
.
The structure described by V5CdTl4O15Cl crystallizes in the tetragonal P4 space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form VO4 tetrahedra that share  a cornercorner with one V(1)O4 tetrahedra and  a cornercorner with one V(2)O5 trigonal bipyramid. In the second V site, V(2) is bonded to one O(5) and four equivalent O(4) atoms to form distorted corner-sharing VO5 trigonal bipyramids. Cd(1) is bonded in a 5-coordinate geometry to four equivalent O(3) and one Cl(1) atom. Tl(1) is bonded in a distorted L-shaped geometry to one O(1) and one O(3) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) and one Tl(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the third O site, O(3) is bonded in a 3-coordinate geometry to one V(1), one Cd(1), and one Tl(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one V(2) atom. Cl(1) is bonded in a distorted single-bond geometry to one Cd(1) atom. is represented by the CIF card [CIF]
data_Tl4V5CdClO15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.274
_cell_length_b   9.274
_cell_length_c   5.714
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   491.527
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.834  0.313  0.920  1.0
  Tl  Tl1  1  0.166  0.687  0.920  1.0
  Tl  Tl2  1  0.687  0.834  0.920  1.0
  Tl  Tl3  1  0.313  0.166  0.920  1.0
  V  V4  1  0.857  0.619  0.447  1.0
  V  V5  1  0.381  0.857  0.447  1.0
  V  V6  1  0.619  0.143  0.447  1.0
  V  V7  1  0.500  0.500  0.472  1.0
  V  V8  1  0.143  0.381  0.447  1.0
  Cd  Cd9  1  0.000  0.000  0.489  1.0
  Cl  Cl10  1  0.000  0.000  0.034  1.0
  O  O11  1  0.145  0.376  0.155  1.0
  O  O12  1  0.000  0.500  0.551  1.0
  O  O13  1  0.376  0.855  0.155  1.0
  O  O14  1  0.855  0.624  0.155  1.0
  O  O15  1  0.116  0.211  0.561  1.0
  O  O16  1  0.789  0.116  0.561  1.0
  O  O17  1  0.448  0.691  0.560  1.0
  O  O18  1  0.884  0.789  0.561  1.0
  O  O19  1  0.552  0.309  0.560  1.0
  O  O20  1  0.309  0.448  0.560  1.0
  O  O21  1  0.624  0.145  0.155  1.0
  O  O22  1  0.500  0.000  0.551  1.0
  O  O23  1  0.691  0.552  0.560  1.0
  O  O24  1  0.211  0.884  0.561  1.0
  O  O25  1  0.500  0.500  0.189  1.0
[/CIF]
.