The crystal structure described by (Rb3P3O11)2O2 crystallizes in the triclinic P-1 space group. The structure consists of one hydrogen peroxide molecule inside a Rb3P3O11 framework. In the Rb3P3O11 framework, there are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(3), one O(7), one O(8), and two equivalent O(1) atoms. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(12), one O(2), one O(7), one O(8), and two equivalent O(3) atoms. In the third Rb site, Rb(3) is bonded in a 7-coordinate geometry to one O(11), one O(7), one O(9), two equivalent O(12), and two equivalent O(2) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(2), one O(5), and one O(8) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(10), one O(12), and one O(9) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(3), one O(5), one O(7), and one O(9) atom to form corner-sharing PO4 tetrahedra. There are eleven inequivalent O sites. In the first O site, O(11) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(2), one Rb(3), and one O(6) atom. In the second O site, O(12) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(3), and one P(2) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one P(2) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(3), and one P(1) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(2), and one P(3) atom. In the sixth O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one O(11) atom. In the eighth O site, O(7) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(3), and one P(3) atom. In the ninth O site, O(8) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one P(1) atom. In the tenth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Rb(3), one P(2), and one P(3) atom. In the eleventh O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.807
_cell_length_b   9.701
_cell_length_c   9.593
_cell_angle_alpha   60.658
_cell_angle_beta   69.393
_cell_angle_gamma   66.968
_symmetry_Int_Tables_number   1
_cell_volume   644.257
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.135  0.810  0.425  1.0
  Rb  Rb1  1  0.865  0.190  0.575  1.0
  Rb  Rb2  1  0.754  0.023  0.197  1.0
  Rb  Rb3  1  0.246  0.977  0.803  1.0
  Rb  Rb4  1  0.588  0.508  0.146  1.0
  Rb  Rb5  1  0.412  0.492  0.854  1.0
  P  P6  1  0.080  0.604  0.202  1.0
  P  P7  1  0.920  0.396  0.798  1.0
  P  P8  1  0.250  0.248  0.277  1.0
  P  P9  1  0.750  0.752  0.723  1.0
  P  P10  1  0.043  0.231  0.103  1.0
  P  P11  1  0.957  0.769  0.897  1.0
  O  O12  1  0.209  0.098  0.421  1.0
  O  O13  1  0.791  0.902  0.579  1.0
  O  O14  1  0.244  0.647  0.109  1.0
  O  O15  1  0.756  0.353  0.891  1.0
  O  O16  1  0.100  0.066  0.095  1.0
  O  O17  1  0.900  0.934  0.905  1.0
  O  O18  1  0.474  0.941  0.056  1.0
  O  O19  1  0.526  0.059  0.944  1.0
  O  O20  1  0.021  0.378  0.924  1.0
  O  O21  1  0.979  0.622  0.076  1.0
  O  O22  1  0.362  0.362  0.575  1.0
  O  O23  1  0.638  0.638  0.425  1.0
  O  O24  1  0.890  0.260  0.231  1.0
  O  O25  1  0.110  0.740  0.769  1.0
  O  O26  1  0.040  0.314  0.689  1.0
  O  O27  1  0.960  0.686  0.311  1.0
  O  O28  1  0.203  0.268  0.115  1.0
  O  O29  1  0.797  0.732  0.885  1.0
  O  O30  1  0.112  0.406  0.310  1.0
  O  O31  1  0.888  0.594  0.690  1.0
  O  O32  1  0.458  0.251  0.531  1.0
  O  O33  1  0.542  0.749  0.469  1.0
  O  O34  1  0.425  0.268  0.218  1.0
  O  O35  1  0.575  0.732  0.782  1.0
[/CIF]
.
The crystal structure described by (Rb3P3O11)2O2 crystallizes in the triclinic P-1 space group. The structure consists of one hydrogen peroxide molecule inside a Rb3P3O11 framework. In the Rb3P3O11 framework, there are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(3), one O(7), one O(8), and two equivalent O(1) atoms. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(12), one O(2), one O(7), one O(8), and two equivalent O(3) atoms. In the third Rb site, Rb(3) is bonded in a 7-coordinate geometry to one O(11), one O(7), one O(9), two equivalent O(12), and two equivalent O(2) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(2), one O(5), and one O(8) atom to form corner-sharing PO4 tetrahedra. In the second P site, P(2) is bonded to one O(1), one O(10), one O(12), and one O(9) atom to form corner-sharing PO4 tetrahedra. In the third P site, P(3) is bonded to one O(3), one O(5), one O(7), and one O(9) atom to form corner-sharing PO4 tetrahedra. There are eleven inequivalent O sites. In the first O site, O(11) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(2), one Rb(3), and one O(6) atom. In the second O site, O(12) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(3), and one P(2) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one P(2) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(3), and one P(1) atom. In the fifth O site, O(3) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(2), and one P(3) atom. In the sixth O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one O(11) atom. In the eighth O site, O(7) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(3), and one P(3) atom. In the ninth O site, O(8) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), and one P(1) atom. In the tenth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Rb(3), one P(2), and one P(3) atom. In the eleventh O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one P(1), and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.807
_cell_length_b   9.701
_cell_length_c   9.593
_cell_angle_alpha   60.658
_cell_angle_beta   69.393
_cell_angle_gamma   66.968
_symmetry_Int_Tables_number   1
_cell_volume   644.257
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.135  0.810  0.425  1.0
  Rb  Rb1  1  0.865  0.190  0.575  1.0
  Rb  Rb2  1  0.754  0.023  0.197  1.0
  Rb  Rb3  1  0.246  0.977  0.803  1.0
  Rb  Rb4  1  0.588  0.508  0.146  1.0
  Rb  Rb5  1  0.412  0.492  0.854  1.0
  P  P6  1  0.080  0.604  0.202  1.0
  P  P7  1  0.920  0.396  0.798  1.0
  P  P8  1  0.250  0.248  0.277  1.0
  P  P9  1  0.750  0.752  0.723  1.0
  P  P10  1  0.043  0.231  0.103  1.0
  P  P11  1  0.957  0.769  0.897  1.0
  O  O12  1  0.209  0.098  0.421  1.0
  O  O13  1  0.791  0.902  0.579  1.0
  O  O14  1  0.244  0.647  0.109  1.0
  O  O15  1  0.756  0.353  0.891  1.0
  O  O16  1  0.100  0.066  0.095  1.0
  O  O17  1  0.900  0.934  0.905  1.0
  O  O18  1  0.474  0.941  0.056  1.0
  O  O19  1  0.526  0.059  0.944  1.0
  O  O20  1  0.021  0.378  0.924  1.0
  O  O21  1  0.979  0.622  0.076  1.0
  O  O22  1  0.362  0.362  0.575  1.0
  O  O23  1  0.638  0.638  0.425  1.0
  O  O24  1  0.890  0.260  0.231  1.0
  O  O25  1  0.110  0.740  0.769  1.0
  O  O26  1  0.040  0.314  0.689  1.0
  O  O27  1  0.960  0.686  0.311  1.0
  O  O28  1  0.203  0.268  0.115  1.0
  O  O29  1  0.797  0.732  0.885  1.0
  O  O30  1  0.112  0.406  0.310  1.0
  O  O31  1  0.888  0.594  0.690  1.0
  O  O32  1  0.458  0.251  0.531  1.0
  O  O33  1  0.542  0.749  0.469  1.0
  O  O34  1  0.425  0.268  0.218  1.0
  O  O35  1  0.575  0.732  0.782  1.0
[/CIF]
.