The material structure described by Ge2C2(SeF2)3 is diamond structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Ge2C2(SeF2)3 clusters. Ge(1) is bonded to one C(1) and three equivalent Se(1) atoms to form corner-sharing GeCSe3 tetrahedra. C(1) is bonded in a distorted trigonal non-coplanar geometry to one Ge(1) and three equivalent F(1) atoms. Se(1) is bonded in a water-like geometry to two equivalent Ge(1) atoms. F(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF file [CIF]
data_Ge2C2(SeF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.627
_cell_length_b   11.627
_cell_length_c   11.627
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   1111.436
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.827  0.827  0.827  1.0
  Ge  Ge1  1  0.731  0.423  0.423  1.0
  Ge  Ge2  1  0.423  0.731  0.423  1.0
  Ge  Ge3  1  0.423  0.423  0.731  1.0
  Ge  Ge4  1  0.827  0.519  0.827  1.0
  Ge  Ge5  1  0.827  0.827  0.519  1.0
  Ge  Ge6  1  0.519  0.827  0.827  1.0
  Ge  Ge7  1  0.423  0.423  0.423  1.0
  C  C8  1  0.899  0.899  0.899  1.0
  C  C9  1  0.947  0.351  0.351  1.0
  C  C10  1  0.351  0.947  0.351  1.0
  C  C11  1  0.351  0.351  0.947  1.0
  C  C12  1  0.899  0.303  0.899  1.0
  C  C13  1  0.899  0.899  0.303  1.0
  C  C14  1  0.303  0.899  0.899  1.0
  C  C15  1  0.351  0.351  0.351  1.0
  Se  Se16  1  0.923  0.577  0.923  1.0
  Se  Se17  1  0.673  0.327  0.327  1.0
  Se  Se18  1  0.327  0.673  0.673  1.0
  Se  Se19  1  0.673  0.327  0.673  1.0
  Se  Se20  1  0.327  0.327  0.673  1.0
  Se  Se21  1  0.673  0.673  0.327  1.0
  Se  Se22  1  0.923  0.923  0.577  1.0
  Se  Se23  1  0.577  0.923  0.923  1.0
  Se  Se24  1  0.923  0.577  0.577  1.0
  Se  Se25  1  0.577  0.577  0.923  1.0
  Se  Se26  1  0.327  0.673  0.327  1.0
  Se  Se27  1  0.577  0.923  0.577  1.0
  F  F28  1  0.790  0.980  0.980  1.0
  F  F29  1  1.000  0.270  0.460  1.0
  F  F30  1  0.270  1.000  0.270  1.0
  F  F31  1  0.270  0.270  1.000  1.0
  F  F32  1  1.000  0.460  0.270  1.0
  F  F33  1  0.270  0.460  1.000  1.0
  F  F34  1  0.270  1.000  0.460  1.0
  F  F35  1  0.980  0.790  0.980  1.0
  F  F36  1  0.980  0.980  0.790  1.0
  F  F37  1  0.790  0.250  0.980  1.0
  F  F38  1  0.790  0.980  0.250  1.0
  F  F39  1  0.980  0.250  0.980  1.0
  F  F40  1  0.250  0.790  0.980  1.0
  F  F41  1  0.250  0.980  0.790  1.0
  F  F42  1  0.980  0.980  0.250  1.0
  F  F43  1  0.460  1.000  0.270  1.0
  F  F44  1  0.460  0.270  1.000  1.0
  F  F45  1  1.000  0.270  0.270  1.0
  F  F46  1  0.460  0.270  0.270  1.0
  F  F47  1  0.270  0.460  0.270  1.0
  F  F48  1  0.270  0.270  0.460  1.0
  F  F49  1  0.980  0.790  0.250  1.0
  F  F50  1  0.980  0.250  0.790  1.0
  F  F51  1  0.250  0.980  0.980  1.0
[/CIF]
.
The material structure described by Ge2C2(SeF2)3 is diamond structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of eight Ge2C2(SeF2)3 clusters. Ge(1) is bonded to one C(1) and three equivalent Se(1) atoms to form corner-sharing GeCSe3 tetrahedra. C(1) is bonded in a distorted trigonal non-coplanar geometry to one Ge(1) and three equivalent F(1) atoms. Se(1) is bonded in a water-like geometry to two equivalent Ge(1) atoms. F(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF file [CIF]
data_Ge2C2(SeF2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.627
_cell_length_b   11.627
_cell_length_c   11.627
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   1111.436
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.827  0.827  0.827  1.0
  Ge  Ge1  1  0.731  0.423  0.423  1.0
  Ge  Ge2  1  0.423  0.731  0.423  1.0
  Ge  Ge3  1  0.423  0.423  0.731  1.0
  Ge  Ge4  1  0.827  0.519  0.827  1.0
  Ge  Ge5  1  0.827  0.827  0.519  1.0
  Ge  Ge6  1  0.519  0.827  0.827  1.0
  Ge  Ge7  1  0.423  0.423  0.423  1.0
  C  C8  1  0.899  0.899  0.899  1.0
  C  C9  1  0.947  0.351  0.351  1.0
  C  C10  1  0.351  0.947  0.351  1.0
  C  C11  1  0.351  0.351  0.947  1.0
  C  C12  1  0.899  0.303  0.899  1.0
  C  C13  1  0.899  0.899  0.303  1.0
  C  C14  1  0.303  0.899  0.899  1.0
  C  C15  1  0.351  0.351  0.351  1.0
  Se  Se16  1  0.923  0.577  0.923  1.0
  Se  Se17  1  0.673  0.327  0.327  1.0
  Se  Se18  1  0.327  0.673  0.673  1.0
  Se  Se19  1  0.673  0.327  0.673  1.0
  Se  Se20  1  0.327  0.327  0.673  1.0
  Se  Se21  1  0.673  0.673  0.327  1.0
  Se  Se22  1  0.923  0.923  0.577  1.0
  Se  Se23  1  0.577  0.923  0.923  1.0
  Se  Se24  1  0.923  0.577  0.577  1.0
  Se  Se25  1  0.577  0.577  0.923  1.0
  Se  Se26  1  0.327  0.673  0.327  1.0
  Se  Se27  1  0.577  0.923  0.577  1.0
  F  F28  1  0.790  0.980  0.980  1.0
  F  F29  1  1.000  0.270  0.460  1.0
  F  F30  1  0.270  1.000  0.270  1.0
  F  F31  1  0.270  0.270  1.000  1.0
  F  F32  1  1.000  0.460  0.270  1.0
  F  F33  1  0.270  0.460  1.000  1.0
  F  F34  1  0.270  1.000  0.460  1.0
  F  F35  1  0.980  0.790  0.980  1.0
  F  F36  1  0.980  0.980  0.790  1.0
  F  F37  1  0.790  0.250  0.980  1.0
  F  F38  1  0.790  0.980  0.250  1.0
  F  F39  1  0.980  0.250  0.980  1.0
  F  F40  1  0.250  0.790  0.980  1.0
  F  F41  1  0.250  0.980  0.790  1.0
  F  F42  1  0.980  0.980  0.250  1.0
  F  F43  1  0.460  1.000  0.270  1.0
  F  F44  1  0.460  0.270  1.000  1.0
  F  F45  1  1.000  0.270  0.270  1.0
  F  F46  1  0.460  0.270  0.270  1.0
  F  F47  1  0.270  0.460  0.270  1.0
  F  F48  1  0.270  0.270  0.460  1.0
  F  F49  1  0.980  0.790  0.250  1.0
  F  F50  1  0.980  0.250  0.790  1.0
  F  F51  1  0.250  0.980  0.980  1.0
[/CIF]
.