The structure described by Ba4La6Mn5In5O30 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Ba sites. In the first Ba site, Ba(1) is bonded to one O(1), one O(4), two equivalent O(3), two equivalent O(6), two equivalent O(8), and four equivalent O(2) atoms to form BaO12 cuboctahedra that share corners with six equivalent Ba(1)O12 cuboctahedra, faces with three equivalent Ba(2)O12 cuboctahedra, faces with three equivalent Ba(3)O12 cuboctahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra, faces with three equivalent Mn(1)O6 octahedra, and faces with three equivalent Mn(4)O6 octahedra. In the second Ba site, Ba(2) is bonded to one O(20), one O(8), two equivalent O(1), two equivalent O(17), two equivalent O(2), and four equivalent O(3) atoms to form distorted BaO12 cuboctahedra that share corners with three equivalent Ba(3)O12 cuboctahedra, corners with six equivalent Ba(2)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra,  a faceface with one Mn(4)O6 octahedra,  a faceface with one In(4)O6 octahedra, faces with three equivalent Mn(1)O6 octahedra, and faces with three equivalent Mn(2)O6 octahedra. In the third Ba site, Ba(3) is bonded to one O(12), one O(8), two equivalent O(2), two equivalent O(4), two equivalent O(5), and four equivalent O(6) atoms to form BaO12 cuboctahedra that share corners with three equivalent Ba(2)O12 cuboctahedra, corners with six equivalent Ba(3)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one In(1)O6 octahedra, faces with three equivalent Mn(3)O6 octahedra, and faces with three equivalent Mn(4)O6 octahedra. In the fourth Ba site, Ba(4) is bonded in a 12-coordinate geometry to one O(12), one O(16), two equivalent O(5), two equivalent O(7), two equivalent O(9), and four equivalent O(10) atoms. There are six inequivalent La sites. In the first La site, La(1) is bonded in a 11-coordinate geometry to one O(4), two equivalent O(10), two equivalent O(12), two equivalent O(6), and four equivalent O(5) atoms. In the second La site, La(2) is bonded in a 5-coordinate geometry to one O(7), two equivalent O(14), and two equivalent O(9) atoms. In the third La site, La(3) is bonded in a 5-coordinate geometry to one O(11), two equivalent O(13), and two equivalent O(18) atoms. In the fourth La site, La(4) is bonded in a 5-coordinate geometry to one O(19), two equivalent O(14), and two equivalent O(9) atoms. In the fifth La site, La(5) is bonded in a 8-coordinate geometry to one O(1), one O(15), two equivalent O(17), two equivalent O(20), and two equivalent O(3) atoms. In the sixth La site, La(6) is bonded in a 5-coordinate geometry to one O(20), two equivalent O(13), and two equivalent O(18) atoms. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(8), two equivalent O(2), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with three equivalent Mn(2)O6 octahedra, corners with three equivalent Mn(4)O6 octahedra,  a faceface with one Ba(3)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 3-14°. In the second Mn site, Mn(2) is bonded to one O(1), one O(20), two equivalent O(17), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with three equivalent In(4)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 7-20°. In the third Mn site, Mn(3) is bonded to one O(12), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with three equivalent Mn(4)O6 octahedra, corners with three equivalent In(1)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 4-15°. In the fourth Mn site, Mn(4) is bonded to one O(4), one O(8), two equivalent O(2), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with three equivalent Mn(3)O6 octahedra,  a faceface with one Ba(2)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 3-13°. In the fifth Mn site, Mn(5) is bonded to one O(16), one O(7), two equivalent O(10), and two equivalent O(9) atoms to form MnO6 octahedra that share corners with three equivalent In(1)O6 octahedra and corners with three equivalent In(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-29°. There are five inequivalent In sites. In the first In site, In(1) is bonded to one O(12), one O(7), two equivalent O(10), and two equivalent O(5) atoms to form InO6 octahedra that share corners with three equivalent Mn(3)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra, and  a faceface with one Ba(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 12-29°. In the second In site, In(2) is bonded to one O(11), one O(19), two equivalent O(13), and two equivalent O(14) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 35-43°. In the third In site, In(3) is bonded to one O(11), one O(16), two equivalent O(14), and two equivalent O(9) atoms to form InO6 octahedra that share corners with three equivalent Mn(5)O6 octahedra and corners with three equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-36°. In the fourth In site, In(4) is bonded to one O(15), one O(20), two equivalent O(17), and two equivalent O(18) atoms to form InO6 octahedra that share corners with three equivalent Mn(2)O6 octahedra, corners with three equivalent In(5)O6 octahedra, and  a faceface with one Ba(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 16-41°. In the fifth In site, In(5) is bonded to one O(15), one O(19), two equivalent O(13), and two equivalent O(18) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 29-43°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded to one Ba(1), two equivalent Ba(2), one La(5), one Mn(1), and one Mn(2) atom to form distorted OBa3LaMn2 octahedra that share  a cornercorner with one O(8)Ba4Mn2 octahedra, corners with two equivalent O(1)Ba3LaMn2 octahedra, corners with two equivalent O(6)Ba3LaMn2 octahedra, and edges with two equivalent O(8)Ba4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the second O site, O(2) is bonded in a distorted linear geometry to one Ba(2), one Ba(3), two equivalent Ba(1), one Mn(1), and one Mn(4) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to one Ba(1), two equivalent Ba(2), one La(5), one Mn(1), and one Mn(2) atom. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Ba(1), two equivalent Ba(3), one La(1), one Mn(3), and one Mn(4) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Ba(3), one Ba(4), two equivalent La(1), one Mn(3), and one In(1) atom. In the sixth O site, O(6) is bonded to one Ba(1), two equivalent Ba(3), one La(1), one Mn(3), and one Mn(4) atom to form distorted OBa3LaMn2 octahedra that share  a cornercorner with one O(1)Ba3LaMn2 octahedra, corners with two equivalent O(8)Ba4Mn2 octahedra, corners with four equivalent O(6)Ba3LaMn2 octahedra,  a faceface with one O(8)Ba4Mn2 octahedra, and faces with two equivalent O(6)Ba3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 4-62°. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to two equivalent Ba(4), one La(2), one Mn(5), and one In(1) atom. In the eighth O site, O(8) is bonded to one Ba(2), one Ba(3), two equivalent Ba(1), one Mn(1), and one Mn(4) atom to form distorted OBa4Mn2 octahedra that share  a cornercorner with one O(1)Ba3LaMn2 octahedra, corners with two equivalent O(8)Ba4Mn2 octahedra, corners with four equivalent O(6)Ba3LaMn2 octahedra, edges with two equivalent O(1)Ba3LaMn2 octahedra, and faces with two equivalent O(6)Ba3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Ba(4), one La(2), one La(4), one Mn(5), and one In(3) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to two equivalent Ba(4), one La(1), one Mn(5), and one In(1) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one La(3), one In(2), and one In(3) atom. In the twelfth O site, O(12) is bonded in a 6-coordinate geometry to one Ba(3), one Ba(4), two equivalent La(1), one Mn(3), and one In(1) atom. In the thirteenth O site, O(13) is bonded to one La(3), one La(6), one In(2), and one In(5) atom to form a mixture of distorted corner and edge-sharing OLa2In2 tetrahedra. In the fourteenth O site, O(14) is bonded to one La(2), one La(4), one In(2), and one In(3) atom to form a mixture of distorted corner and edge-sharing OLa2In2 tetrahedra. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one La(5), one In(4), and one In(5) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Ba(4), one Mn(5), and one In(3) atom. In the seventeenth O site, O(17) is bonded in a 2-coordinate geometry to one Ba(2), one La(5), one Mn(2), and one In(4) atom. In the eighteenth O site, O(18) is bonded to one La(3), one La(6), one In(4), and one In(5) atom to form a mixture of distorted corner and edge-sharing OLa2In2 tetrahedra. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one La(4), one In(2), and one In(5) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Ba(2), one La(6), two equivalent La(5), one Mn(2), and one In(4) atom. is represented by the CIF card [CIF]
data_Ba4La6Mn5In5O30
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.778
_cell_length_b   5.778
_cell_length_c   23.850
_cell_angle_alpha   82.542
_cell_angle_beta   82.542
_cell_angle_gamma   59.571
_symmetry_Int_Tables_number   1
_cell_volume   678.836
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.448  0.448  0.153  1.0
  Ba  Ba1  1  0.148  0.148  0.057  1.0
  Ba  Ba2  1  0.753  0.753  0.247  1.0
  Ba  Ba3  1  0.351  0.351  0.444  1.0
  La  La4  1  0.047  0.047  0.338  1.0
  La  La5  1  0.641  0.641  0.544  1.0
  La  La6  1  0.245  0.245  0.757  1.0
  La  La7  1  0.958  0.958  0.636  1.0
  La  La8  1  0.840  0.840  0.967  1.0
  La  La9  1  0.556  0.556  0.858  1.0
  Mn  Mn10  1  0.797  0.797  0.105  1.0
  Mn  Mn11  1  0.506  0.506  0.006  1.0
  Mn  Mn12  1  0.406  0.406  0.298  1.0
  Mn  Mn13  1  0.097  0.097  0.199  1.0
  Mn  Mn14  1  0.003  0.003  0.494  1.0
  In  In15  1  0.701  0.701  0.397  1.0
  In  In16  1  0.602  0.602  0.700  1.0
  In  In17  1  0.297  0.297  0.597  1.0
  In  In18  1  0.193  0.193  0.906  1.0
  In  In19  1  0.902  0.902  0.802  1.0
  O  O20  1  0.637  0.637  0.058  1.0
  O  O21  1  0.453  0.955  0.152  1.0
  O  O22  1  0.651  0.131  0.047  1.0
  O  O23  1  0.247  0.247  0.261  1.0
  O  O24  1  0.080  0.583  0.347  1.0
  O  O25  1  0.243  0.764  0.250  1.0
  O  O26  1  0.955  0.453  0.152  1.0
  O  O27  1  0.131  0.651  0.047  1.0
  O  O28  1  0.823  0.823  0.466  1.0
  O  O29  1  0.948  0.948  0.149  1.0
  O  O30  1  0.689  0.175  0.552  1.0
  O  O31  1  0.847  0.303  0.439  1.0
  O  O32  1  0.583  0.080  0.347  1.0
  O  O33  1  0.764  0.243  0.250  1.0
  O  O34  1  0.400  0.400  0.670  1.0
  O  O35  1  0.561  0.561  0.338  1.0
  O  O36  1  0.305  0.791  0.769  1.0
  O  O37  1  0.412  0.895  0.631  1.0
  O  O38  1  0.175  0.689  0.552  1.0
  O  O39  1  0.303  0.847  0.439  1.0
  O  O40  1  0.993  0.993  0.881  1.0
  O  O41  1  0.159  0.159  0.531  1.0
  O  O42  1  0.842  0.398  0.961  1.0
  O  O43  1  0.011  0.505  0.840  1.0
  O  O44  1  0.791  0.305  0.769  1.0
  O  O45  1  0.895  0.412  0.631  1.0
  O  O46  1  0.808  0.808  0.723  1.0
  O  O47  1  0.398  0.842  0.961  1.0
  O  O48  1  0.505  0.011  0.840  1.0
  O  O49  1  0.381  0.381  0.945  1.0
[/CIF]
.
The structure described by Ba4La6Mn5In5O30 is Orthorhombic Perovskite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Ba sites. In the first Ba site, Ba(1) is bonded to one O(1), one O(4), two equivalent O(3), two equivalent O(6), two equivalent O(8), and four equivalent O(2) atoms to form BaO12 cuboctahedra that share corners with six equivalent Ba(1)O12 cuboctahedra, faces with three equivalent Ba(2)O12 cuboctahedra, faces with three equivalent Ba(3)O12 cuboctahedra,  a faceface with one Mn(2)O6 octahedra,  a faceface with one Mn(3)O6 octahedra, faces with three equivalent Mn(1)O6 octahedra, and faces with three equivalent Mn(4)O6 octahedra. In the second Ba site, Ba(2) is bonded to one O(20), one O(8), two equivalent O(1), two equivalent O(17), two equivalent O(2), and four equivalent O(3) atoms to form distorted BaO12 cuboctahedra that share corners with three equivalent Ba(3)O12 cuboctahedra, corners with six equivalent Ba(2)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra,  a faceface with one Mn(4)O6 octahedra,  a faceface with one In(4)O6 octahedra, faces with three equivalent Mn(1)O6 octahedra, and faces with three equivalent Mn(2)O6 octahedra. In the third Ba site, Ba(3) is bonded to one O(12), one O(8), two equivalent O(2), two equivalent O(4), two equivalent O(5), and four equivalent O(6) atoms to form BaO12 cuboctahedra that share corners with three equivalent Ba(2)O12 cuboctahedra, corners with six equivalent Ba(3)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra,  a faceface with one Mn(1)O6 octahedra,  a faceface with one In(1)O6 octahedra, faces with three equivalent Mn(3)O6 octahedra, and faces with three equivalent Mn(4)O6 octahedra. In the fourth Ba site, Ba(4) is bonded in a 12-coordinate geometry to one O(12), one O(16), two equivalent O(5), two equivalent O(7), two equivalent O(9), and four equivalent O(10) atoms. There are six inequivalent La sites. In the first La site, La(1) is bonded in a 11-coordinate geometry to one O(4), two equivalent O(10), two equivalent O(12), two equivalent O(6), and four equivalent O(5) atoms. In the second La site, La(2) is bonded in a 5-coordinate geometry to one O(7), two equivalent O(14), and two equivalent O(9) atoms. In the third La site, La(3) is bonded in a 5-coordinate geometry to one O(11), two equivalent O(13), and two equivalent O(18) atoms. In the fourth La site, La(4) is bonded in a 5-coordinate geometry to one O(19), two equivalent O(14), and two equivalent O(9) atoms. In the fifth La site, La(5) is bonded in a 8-coordinate geometry to one O(1), one O(15), two equivalent O(17), two equivalent O(20), and two equivalent O(3) atoms. In the sixth La site, La(6) is bonded in a 5-coordinate geometry to one O(20), two equivalent O(13), and two equivalent O(18) atoms. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(8), two equivalent O(2), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with three equivalent Mn(2)O6 octahedra, corners with three equivalent Mn(4)O6 octahedra,  a faceface with one Ba(3)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 3-14°. In the second Mn site, Mn(2) is bonded to one O(1), one O(20), two equivalent O(17), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with three equivalent In(4)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 7-20°. In the third Mn site, Mn(3) is bonded to one O(12), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with three equivalent Mn(4)O6 octahedra, corners with three equivalent In(1)O6 octahedra,  a faceface with one Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 4-15°. In the fourth Mn site, Mn(4) is bonded to one O(4), one O(8), two equivalent O(2), and two equivalent O(6) atoms to form MnO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with three equivalent Mn(3)O6 octahedra,  a faceface with one Ba(2)O12 cuboctahedra, faces with three equivalent Ba(1)O12 cuboctahedra, and faces with three equivalent Ba(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 3-13°. In the fifth Mn site, Mn(5) is bonded to one O(16), one O(7), two equivalent O(10), and two equivalent O(9) atoms to form MnO6 octahedra that share corners with three equivalent In(1)O6 octahedra and corners with three equivalent In(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-29°. There are five inequivalent In sites. In the first In site, In(1) is bonded to one O(12), one O(7), two equivalent O(10), and two equivalent O(5) atoms to form InO6 octahedra that share corners with three equivalent Mn(3)O6 octahedra, corners with three equivalent Mn(5)O6 octahedra, and  a faceface with one Ba(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 12-29°. In the second In site, In(2) is bonded to one O(11), one O(19), two equivalent O(13), and two equivalent O(14) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 35-43°. In the third In site, In(3) is bonded to one O(11), one O(16), two equivalent O(14), and two equivalent O(9) atoms to form InO6 octahedra that share corners with three equivalent Mn(5)O6 octahedra and corners with three equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-36°. In the fourth In site, In(4) is bonded to one O(15), one O(20), two equivalent O(17), and two equivalent O(18) atoms to form InO6 octahedra that share corners with three equivalent Mn(2)O6 octahedra, corners with three equivalent In(5)O6 octahedra, and  a faceface with one Ba(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 16-41°. In the fifth In site, In(5) is bonded to one O(15), one O(19), two equivalent O(13), and two equivalent O(18) atoms to form corner-sharing InO6 octahedra. The corner-sharing octahedral tilt angles range from 29-43°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded to one Ba(1), two equivalent Ba(2), one La(5), one Mn(1), and one Mn(2) atom to form distorted OBa3LaMn2 octahedra that share  a cornercorner with one O(8)Ba4Mn2 octahedra, corners with two equivalent O(1)Ba3LaMn2 octahedra, corners with two equivalent O(6)Ba3LaMn2 octahedra, and edges with two equivalent O(8)Ba4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-62°. In the second O site, O(2) is bonded in a distorted linear geometry to one Ba(2), one Ba(3), two equivalent Ba(1), one Mn(1), and one Mn(4) atom. In the third O site, O(3) is bonded in a 6-coordinate geometry to one Ba(1), two equivalent Ba(2), one La(5), one Mn(1), and one Mn(2) atom. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Ba(1), two equivalent Ba(3), one La(1), one Mn(3), and one Mn(4) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Ba(3), one Ba(4), two equivalent La(1), one Mn(3), and one In(1) atom. In the sixth O site, O(6) is bonded to one Ba(1), two equivalent Ba(3), one La(1), one Mn(3), and one Mn(4) atom to form distorted OBa3LaMn2 octahedra that share  a cornercorner with one O(1)Ba3LaMn2 octahedra, corners with two equivalent O(8)Ba4Mn2 octahedra, corners with four equivalent O(6)Ba3LaMn2 octahedra,  a faceface with one O(8)Ba4Mn2 octahedra, and faces with two equivalent O(6)Ba3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 4-62°. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to two equivalent Ba(4), one La(2), one Mn(5), and one In(1) atom. In the eighth O site, O(8) is bonded to one Ba(2), one Ba(3), two equivalent Ba(1), one Mn(1), and one Mn(4) atom to form distorted OBa4Mn2 octahedra that share  a cornercorner with one O(1)Ba3LaMn2 octahedra, corners with two equivalent O(8)Ba4Mn2 octahedra, corners with four equivalent O(6)Ba3LaMn2 octahedra, edges with two equivalent O(1)Ba3LaMn2 octahedra, and faces with two equivalent O(6)Ba3LaMn2 octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Ba(4), one La(2), one La(4), one Mn(5), and one In(3) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to two equivalent Ba(4), one La(1), one Mn(5), and one In(1) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one La(3), one In(2), and one In(3) atom. In the twelfth O site, O(12) is bonded in a 6-coordinate geometry to one Ba(3), one Ba(4), two equivalent La(1), one Mn(3), and one In(1) atom. In the thirteenth O site, O(13) is bonded to one La(3), one La(6), one In(2), and one In(5) atom to form a mixture of distorted corner and edge-sharing OLa2In2 tetrahedra. In the fourteenth O site, O(14) is bonded to one La(2), one La(4), one In(2), and one In(3) atom to form a mixture of distorted corner and edge-sharing OLa2In2 tetrahedra. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one La(5), one In(4), and one In(5) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Ba(4), one Mn(5), and one In(3) atom. In the seventeenth O site, O(17) is bonded in a 2-coordinate geometry to one Ba(2), one La(5), one Mn(2), and one In(4) atom. In the eighteenth O site, O(18) is bonded to one La(3), one La(6), one In(4), and one In(5) atom to form a mixture of distorted corner and edge-sharing OLa2In2 tetrahedra. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one La(4), one In(2), and one In(5) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Ba(2), one La(6), two equivalent La(5), one Mn(2), and one In(4) atom. is represented by the CIF card [CIF]
data_Ba4La6Mn5In5O30
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.778
_cell_length_b   5.778
_cell_length_c   23.850
_cell_angle_alpha   82.542
_cell_angle_beta   82.542
_cell_angle_gamma   59.571
_symmetry_Int_Tables_number   1
_cell_volume   678.836
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.448  0.448  0.153  1.0
  Ba  Ba1  1  0.148  0.148  0.057  1.0
  Ba  Ba2  1  0.753  0.753  0.247  1.0
  Ba  Ba3  1  0.351  0.351  0.444  1.0
  La  La4  1  0.047  0.047  0.338  1.0
  La  La5  1  0.641  0.641  0.544  1.0
  La  La6  1  0.245  0.245  0.757  1.0
  La  La7  1  0.958  0.958  0.636  1.0
  La  La8  1  0.840  0.840  0.967  1.0
  La  La9  1  0.556  0.556  0.858  1.0
  Mn  Mn10  1  0.797  0.797  0.105  1.0
  Mn  Mn11  1  0.506  0.506  0.006  1.0
  Mn  Mn12  1  0.406  0.406  0.298  1.0
  Mn  Mn13  1  0.097  0.097  0.199  1.0
  Mn  Mn14  1  0.003  0.003  0.494  1.0
  In  In15  1  0.701  0.701  0.397  1.0
  In  In16  1  0.602  0.602  0.700  1.0
  In  In17  1  0.297  0.297  0.597  1.0
  In  In18  1  0.193  0.193  0.906  1.0
  In  In19  1  0.902  0.902  0.802  1.0
  O  O20  1  0.637  0.637  0.058  1.0
  O  O21  1  0.453  0.955  0.152  1.0
  O  O22  1  0.651  0.131  0.047  1.0
  O  O23  1  0.247  0.247  0.261  1.0
  O  O24  1  0.080  0.583  0.347  1.0
  O  O25  1  0.243  0.764  0.250  1.0
  O  O26  1  0.955  0.453  0.152  1.0
  O  O27  1  0.131  0.651  0.047  1.0
  O  O28  1  0.823  0.823  0.466  1.0
  O  O29  1  0.948  0.948  0.149  1.0
  O  O30  1  0.689  0.175  0.552  1.0
  O  O31  1  0.847  0.303  0.439  1.0
  O  O32  1  0.583  0.080  0.347  1.0
  O  O33  1  0.764  0.243  0.250  1.0
  O  O34  1  0.400  0.400  0.670  1.0
  O  O35  1  0.561  0.561  0.338  1.0
  O  O36  1  0.305  0.791  0.769  1.0
  O  O37  1  0.412  0.895  0.631  1.0
  O  O38  1  0.175  0.689  0.552  1.0
  O  O39  1  0.303  0.847  0.439  1.0
  O  O40  1  0.993  0.993  0.881  1.0
  O  O41  1  0.159  0.159  0.531  1.0
  O  O42  1  0.842  0.398  0.961  1.0
  O  O43  1  0.011  0.505  0.840  1.0
  O  O44  1  0.791  0.305  0.769  1.0
  O  O45  1  0.895  0.412  0.631  1.0
  O  O46  1  0.808  0.808  0.723  1.0
  O  O47  1  0.398  0.842  0.961  1.0
  O  O48  1  0.505  0.011  0.840  1.0
  O  O49  1  0.381  0.381  0.945  1.0
[/CIF]
.