The structure described by Dy3VH3O8 crystallizes in the monoclinic P2_1 space group. There are three inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 8-coordinate geometry to one H(3), one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. In the second Dy site, Dy(2) is bonded in a 8-coordinate geometry to one H(3), one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. In the third Dy site, Dy(3) is bonded in a 9-coordinate geometry to one H(3), one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. V(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(7) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(6) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one Dy(1), one Dy(2), one Dy(3), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Dy(1), one Dy(2), one Dy(3), and one V(1) atom to form a mixture of corner and edge-sharing ODy3V tetrahedra. In the second O site, O(2) is bonded to one Dy(1), one Dy(2), one Dy(3), and one V(1) atom to form a mixture of corner and edge-sharing ODy3V tetrahedra. In the third O site, O(3) is bonded to one Dy(1), one Dy(2), one Dy(3), and one V(1) atom to form a mixture of corner and edge-sharing ODy3V tetrahedra. In the fourth O site, O(4) is bonded to one Dy(1), one Dy(2), one Dy(3), and one V(1) atom to form a mixture of corner and edge-sharing ODy3V tetrahedra. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Dy(1), one Dy(2), one Dy(3), and one H(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Dy(1), one Dy(2), one Dy(3), and one H(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Dy(3), one V(1), and one H(3) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Dy(1), one Dy(2), one Dy(3), and one H(3) atom. is represented by the CIF card [CIF]
data_Dy3VH3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.600
_cell_length_b   6.030
_cell_length_c   10.470
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   105.946
_symmetry_Int_Tables_number   1
_cell_volume   339.958
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.677  0.306  0.531  1.0
  Dy  Dy1  1  0.323  0.694  0.031  1.0
  Dy  Dy2  1  0.322  0.701  0.461  1.0
  Dy  Dy3  1  0.678  0.299  0.961  1.0
  Dy  Dy4  1  0.776  0.780  0.748  1.0
  Dy  Dy5  1  0.224  0.220  0.248  1.0
  V  V6  1  0.190  0.457  0.746  1.0
  V  V7  1  0.810  0.543  0.246  1.0
  H  H8  1  0.845  0.908  0.463  1.0
  H  H9  1  0.155  0.092  0.963  1.0
  H  H10  1  0.158  0.099  0.536  1.0
  H  H11  1  0.842  0.901  0.036  1.0
  H  H12  1  0.768  0.165  0.743  1.0
  H  H13  1  0.232  0.835  0.243  1.0
  O  O14  1  0.002  0.592  0.621  1.0
  O  O15  1  0.998  0.408  0.121  1.0
  O  O16  1  0.995  0.411  0.372  1.0
  O  O17  1  0.005  0.589  0.872  1.0
  O  O18  1  0.462  0.540  0.626  1.0
  O  O19  1  0.538  0.460  0.126  1.0
  O  O20  1  0.537  0.466  0.366  1.0
  O  O21  1  0.463  0.534  0.866  1.0
  O  O22  1  0.728  0.941  0.524  1.0
  O  O23  1  0.272  0.059  0.024  1.0
  O  O24  1  0.268  0.065  0.471  1.0
  O  O25  1  0.732  0.935  0.971  1.0
  O  O26  1  0.059  0.161  0.745  1.0
  O  O27  1  0.941  0.839  0.245  1.0
  O  O28  1  0.584  0.119  0.747  1.0
  O  O29  1  0.416  0.881  0.247  1.0
[/CIF]
.
The structure described by Dy3VH3O8 crystallizes in the monoclinic P2_1 space group. There are three inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 8-coordinate geometry to one H(3), one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. In the second Dy site, Dy(2) is bonded in a 8-coordinate geometry to one H(3), one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. In the third Dy site, Dy(3) is bonded in a 9-coordinate geometry to one H(3), one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. V(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(4), and one O(7) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(6) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one Dy(1), one Dy(2), one Dy(3), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded to one Dy(1), one Dy(2), one Dy(3), and one V(1) atom to form a mixture of corner and edge-sharing ODy3V tetrahedra. In the second O site, O(2) is bonded to one Dy(1), one Dy(2), one Dy(3), and one V(1) atom to form a mixture of corner and edge-sharing ODy3V tetrahedra. In the third O site, O(3) is bonded to one Dy(1), one Dy(2), one Dy(3), and one V(1) atom to form a mixture of corner and edge-sharing ODy3V tetrahedra. In the fourth O site, O(4) is bonded to one Dy(1), one Dy(2), one Dy(3), and one V(1) atom to form a mixture of corner and edge-sharing ODy3V tetrahedra. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Dy(1), one Dy(2), one Dy(3), and one H(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Dy(1), one Dy(2), one Dy(3), and one H(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Dy(3), one V(1), and one H(3) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Dy(1), one Dy(2), one Dy(3), and one H(3) atom. is represented by the CIF card [CIF]
data_Dy3VH3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.600
_cell_length_b   6.030
_cell_length_c   10.470
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   105.946
_symmetry_Int_Tables_number   1
_cell_volume   339.958
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.677  0.306  0.531  1.0
  Dy  Dy1  1  0.323  0.694  0.031  1.0
  Dy  Dy2  1  0.322  0.701  0.461  1.0
  Dy  Dy3  1  0.678  0.299  0.961  1.0
  Dy  Dy4  1  0.776  0.780  0.748  1.0
  Dy  Dy5  1  0.224  0.220  0.248  1.0
  V  V6  1  0.190  0.457  0.746  1.0
  V  V7  1  0.810  0.543  0.246  1.0
  H  H8  1  0.845  0.908  0.463  1.0
  H  H9  1  0.155  0.092  0.963  1.0
  H  H10  1  0.158  0.099  0.536  1.0
  H  H11  1  0.842  0.901  0.036  1.0
  H  H12  1  0.768  0.165  0.743  1.0
  H  H13  1  0.232  0.835  0.243  1.0
  O  O14  1  0.002  0.592  0.621  1.0
  O  O15  1  0.998  0.408  0.121  1.0
  O  O16  1  0.995  0.411  0.372  1.0
  O  O17  1  0.005  0.589  0.872  1.0
  O  O18  1  0.462  0.540  0.626  1.0
  O  O19  1  0.538  0.460  0.126  1.0
  O  O20  1  0.537  0.466  0.366  1.0
  O  O21  1  0.463  0.534  0.866  1.0
  O  O22  1  0.728  0.941  0.524  1.0
  O  O23  1  0.272  0.059  0.024  1.0
  O  O24  1  0.268  0.065  0.471  1.0
  O  O25  1  0.732  0.935  0.971  1.0
  O  O26  1  0.059  0.161  0.745  1.0
  O  O27  1  0.941  0.839  0.245  1.0
  O  O28  1  0.584  0.119  0.747  1.0
  O  O29  1  0.416  0.881  0.247  1.0
[/CIF]
.