The material structure described by CdH8(NO5)2 is gamma plutonium structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two cadmium;nitric acid;tetrahydrate molecules. Cd(1) is bonded in a 8-coordinate geometry to one O(1), one O(15), one O(16), one O(17), one O(18), one O(2), one O(5), and one O(6) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(10), one O(2), and one O(6) atom. There are eight inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one O(15) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(16) atom. In the third H site, H(7) is bonded in a single-bond geometry to one O(15) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one O(16) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one O(17) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one O(18) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one O(17) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one O(18) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one N(2) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1) and one N(1) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one Cd(1) and one N(2) atom. In the fifth O site, O(9) is bonded in a single-bond geometry to one N(1) atom. In the sixth O site, O(10) is bonded in a single-bond geometry to one N(2) atom. In the seventh O site, O(15) is bonded in a distorted water-like geometry to one Cd(1), one H(3), and one H(7) atom. In the eighth O site, O(16) is bonded in a distorted water-like geometry to one Cd(1), one H(4), and one H(8) atom. In the ninth O site, O(17) is bonded in a water-like geometry to one Cd(1), one H(13), and one H(9) atom. In the tenth O site, O(18) is bonded in a water-like geometry to one Cd(1), one H(10), and one H(14) atom. is represented by the CIF file [CIF]
data_CdH8(NO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.909
_cell_length_b   6.322
_cell_length_c   13.290
_cell_angle_alpha   84.008
_cell_angle_beta   77.165
_cell_angle_gamma   62.220
_symmetry_Int_Tables_number   1
_cell_volume   428.284
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.246  0.512  0.499  1.0
  Cd  Cd1  1  0.999  0.008  0.001  1.0
  H  H2  1  0.990  0.383  0.114  1.0
  H  H3  1  0.623  0.377  0.886  1.0
  H  H4  1  0.756  0.876  0.615  1.0
  H  H5  1  0.357  0.886  0.386  1.0
  H  H6  1  0.058  0.437  0.996  1.0
  H  H7  1  0.504  0.439  0.004  1.0
  H  H8  1  0.757  0.943  0.497  1.0
  H  H9  1  0.300  0.944  0.504  1.0
  H  H10  1  0.631  0.187  0.331  1.0
  H  H11  1  0.181  0.187  0.668  1.0
  H  H12  1  0.107  0.681  0.831  1.0
  H  H13  1  0.219  0.681  0.170  1.0
  H  H14  1  0.769  0.266  0.396  1.0
  H  H15  1  0.967  0.265  0.600  1.0
  H  H16  1  0.823  0.763  0.896  1.0
  H  H17  1  0.419  0.763  0.102  1.0
  N  N18  1  0.019  0.493  0.320  1.0
  N  N19  1  0.492  0.493  0.678  1.0
  N  N20  1  0.420  0.992  0.821  1.0
  N  N21  1  0.591  0.991  0.179  1.0
  O  O22  1  0.007  0.375  0.403  1.0
  O  O23  1  0.622  0.375  0.595  1.0
  O  O24  1  0.462  0.877  0.905  1.0
  O  O25  1  0.661  0.872  0.097  1.0
  O  O26  1  0.151  0.609  0.309  1.0
  O  O27  1  0.245  0.613  0.688  1.0
  O  O28  1  0.184  0.114  0.809  1.0
  O  O29  1  0.711  0.109  0.189  1.0
  O  O30  1  0.901  0.496  0.252  1.0
  O  O31  1  0.607  0.491  0.747  1.0
  O  O32  1  0.607  0.987  0.753  1.0
  O  O33  1  0.408  0.992  0.248  1.0
  O  O34  1  0.081  0.307  0.047  1.0
  O  O35  1  0.617  0.306  0.955  1.0
  O  O36  1  0.819  0.808  0.545  1.0
  O  O37  1  0.372  0.812  0.454  1.0
  O  O38  1  0.636  0.209  0.403  1.0
  O  O39  1  0.157  0.210  0.596  1.0
  O  O40  1  0.006  0.705  0.903  1.0
  O  O41  1  0.293  0.704  0.097  1.0
[/CIF]
.
The material structure described by CdH8(NO5)2 is gamma plutonium structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two cadmium;nitric acid;tetrahydrate molecules. Cd(1) is bonded in a 8-coordinate geometry to one O(1), one O(15), one O(16), one O(17), one O(18), one O(2), one O(5), and one O(6) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(5), and one O(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(10), one O(2), and one O(6) atom. There are eight inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one O(15) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(16) atom. In the third H site, H(7) is bonded in a single-bond geometry to one O(15) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one O(16) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one O(17) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one O(18) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one O(17) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one O(18) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one N(2) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1) and one N(1) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one Cd(1) and one N(2) atom. In the fifth O site, O(9) is bonded in a single-bond geometry to one N(1) atom. In the sixth O site, O(10) is bonded in a single-bond geometry to one N(2) atom. In the seventh O site, O(15) is bonded in a distorted water-like geometry to one Cd(1), one H(3), and one H(7) atom. In the eighth O site, O(16) is bonded in a distorted water-like geometry to one Cd(1), one H(4), and one H(8) atom. In the ninth O site, O(17) is bonded in a water-like geometry to one Cd(1), one H(13), and one H(9) atom. In the tenth O site, O(18) is bonded in a water-like geometry to one Cd(1), one H(10), and one H(14) atom. is represented by the CIF file [CIF]
data_CdH8(NO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.909
_cell_length_b   6.322
_cell_length_c   13.290
_cell_angle_alpha   84.008
_cell_angle_beta   77.165
_cell_angle_gamma   62.220
_symmetry_Int_Tables_number   1
_cell_volume   428.284
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.246  0.512  0.499  1.0
  Cd  Cd1  1  0.999  0.008  0.001  1.0
  H  H2  1  0.990  0.383  0.114  1.0
  H  H3  1  0.623  0.377  0.886  1.0
  H  H4  1  0.756  0.876  0.615  1.0
  H  H5  1  0.357  0.886  0.386  1.0
  H  H6  1  0.058  0.437  0.996  1.0
  H  H7  1  0.504  0.439  0.004  1.0
  H  H8  1  0.757  0.943  0.497  1.0
  H  H9  1  0.300  0.944  0.504  1.0
  H  H10  1  0.631  0.187  0.331  1.0
  H  H11  1  0.181  0.187  0.668  1.0
  H  H12  1  0.107  0.681  0.831  1.0
  H  H13  1  0.219  0.681  0.170  1.0
  H  H14  1  0.769  0.266  0.396  1.0
  H  H15  1  0.967  0.265  0.600  1.0
  H  H16  1  0.823  0.763  0.896  1.0
  H  H17  1  0.419  0.763  0.102  1.0
  N  N18  1  0.019  0.493  0.320  1.0
  N  N19  1  0.492  0.493  0.678  1.0
  N  N20  1  0.420  0.992  0.821  1.0
  N  N21  1  0.591  0.991  0.179  1.0
  O  O22  1  0.007  0.375  0.403  1.0
  O  O23  1  0.622  0.375  0.595  1.0
  O  O24  1  0.462  0.877  0.905  1.0
  O  O25  1  0.661  0.872  0.097  1.0
  O  O26  1  0.151  0.609  0.309  1.0
  O  O27  1  0.245  0.613  0.688  1.0
  O  O28  1  0.184  0.114  0.809  1.0
  O  O29  1  0.711  0.109  0.189  1.0
  O  O30  1  0.901  0.496  0.252  1.0
  O  O31  1  0.607  0.491  0.747  1.0
  O  O32  1  0.607  0.987  0.753  1.0
  O  O33  1  0.408  0.992  0.248  1.0
  O  O34  1  0.081  0.307  0.047  1.0
  O  O35  1  0.617  0.306  0.955  1.0
  O  O36  1  0.819  0.808  0.545  1.0
  O  O37  1  0.372  0.812  0.454  1.0
  O  O38  1  0.636  0.209  0.403  1.0
  O  O39  1  0.157  0.210  0.596  1.0
  O  O40  1  0.006  0.705  0.903  1.0
  O  O41  1  0.293  0.704  0.097  1.0
[/CIF]
.