The material described by Ag3SbS3 crystallizes in the monoclinic Cc space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent Sb(1), one S(2), and one S(3) atom. In the second Ag site, Ag(2) is bonded in a rectangular see-saw-like geometry to four equivalent S(1) atoms. In the third Ag site, Ag(3) is bonded in a trigonal planar geometry to one S(1), one S(2), and one S(3) atom. Sb(1) is bonded in a 5-coordinate geometry to two equivalent Ag(1), two equivalent Sb(1), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded to one Ag(3) and four equivalent Ag(2) atoms to form SAg5 trigonal bipyramids that share  a cornercorner with one S(3)Ag2SbS tetrahedra, corners with four equivalent S(1)Ag5 trigonal bipyramids, and edges with four equivalent S(1)Ag5 trigonal bipyramids. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(3), and one S(3) atom. In the third S site, S(3) is bonded to one Ag(1), one Ag(3), one Sb(1), and one S(2) atom to form distorted corner-sharing SAg2SbS tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag3SbS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.906
_cell_length_b   5.052
_cell_length_c   14.203
_cell_angle_alpha   89.925
_cell_angle_beta   99.945
_cell_angle_gamma   90.432
_symmetry_Int_Tables_number   1
_cell_volume   346.699
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.679  0.735  0.131  1.0
  Ag  Ag1  1  0.548  0.235  0.869  1.0
  Ag  Ag2  1  0.136  0.466  0.502  1.0
  Ag  Ag3  1  0.092  0.016  0.680  1.0
  Ag  Ag4  1  0.413  0.516  0.320  1.0
  Ag  Ag5  1  0.634  0.966  0.498  1.0
  Sb  Sb6  1  0.149  0.527  0.057  1.0
  Sb  Sb7  1  0.091  0.027  0.943  1.0
  S  S8  1  0.632  0.467  0.493  1.0
  S  S9  1  0.139  0.967  0.507  1.0
  S  S10  1  0.074  0.888  0.257  1.0
  S  S11  1  0.147  0.625  0.799  1.0
  S  S12  1  0.348  0.125  0.201  1.0
  S  S13  1  0.817  0.388  0.743  1.0
[/CIF]
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The material described by Ag3SbS3 crystallizes in the monoclinic Cc space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent Sb(1), one S(2), and one S(3) atom. In the second Ag site, Ag(2) is bonded in a rectangular see-saw-like geometry to four equivalent S(1) atoms. In the third Ag site, Ag(3) is bonded in a trigonal planar geometry to one S(1), one S(2), and one S(3) atom. Sb(1) is bonded in a 5-coordinate geometry to two equivalent Ag(1), two equivalent Sb(1), and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded to one Ag(3) and four equivalent Ag(2) atoms to form SAg5 trigonal bipyramids that share  a cornercorner with one S(3)Ag2SbS tetrahedra, corners with four equivalent S(1)Ag5 trigonal bipyramids, and edges with four equivalent S(1)Ag5 trigonal bipyramids. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(3), and one S(3) atom. In the third S site, S(3) is bonded to one Ag(1), one Ag(3), one Sb(1), and one S(2) atom to form distorted corner-sharing SAg2SbS tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ag3SbS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.906
_cell_length_b   5.052
_cell_length_c   14.203
_cell_angle_alpha   89.925
_cell_angle_beta   99.945
_cell_angle_gamma   90.432
_symmetry_Int_Tables_number   1
_cell_volume   346.699
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.679  0.735  0.131  1.0
  Ag  Ag1  1  0.548  0.235  0.869  1.0
  Ag  Ag2  1  0.136  0.466  0.502  1.0
  Ag  Ag3  1  0.092  0.016  0.680  1.0
  Ag  Ag4  1  0.413  0.516  0.320  1.0
  Ag  Ag5  1  0.634  0.966  0.498  1.0
  Sb  Sb6  1  0.149  0.527  0.057  1.0
  Sb  Sb7  1  0.091  0.027  0.943  1.0
  S  S8  1  0.632  0.467  0.493  1.0
  S  S9  1  0.139  0.967  0.507  1.0
  S  S10  1  0.074  0.888  0.257  1.0
  S  S11  1  0.147  0.625  0.799  1.0
  S  S12  1  0.348  0.125  0.201  1.0
  S  S13  1  0.817  0.388  0.743  1.0
[/CIF]
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