The material structure described by Ag3Cl crystallizes in the hexagonal P6_3/mmc space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 12-coordinate geometry to eight Ag(1,1) and four equivalent Cl(1) atoms. In the second Ag site, Ag(1) is bonded in a 12-coordinate geometry to eight Ag(1,1) and four equivalent Cl(1) atoms. In the third Ag site, Ag(1) is bonded in a 12-coordinate geometry to eight Ag(1,1) and four equivalent Cl(1) atoms. Cl(1) is bonded to twelve Ag(1,1,1) atoms to form a mixture of distorted face and corner-sharing ClAg12 cuboctahedra. is represented by the CIF card [CIF]
data_Ag3Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.270
_cell_length_b   6.270
_cell_length_c   4.773
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   162.515
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.155  0.309  0.250  1.0
  Ag  Ag1  1  0.691  0.845  0.250  1.0
  Ag  Ag2  1  0.155  0.845  0.250  1.0
  Ag  Ag3  1  0.845  0.691  0.750  1.0
  Ag  Ag4  1  0.309  0.155  0.750  1.0
  Ag  Ag5  1  0.845  0.155  0.750  1.0
  Cl  Cl6  1  0.333  0.667  0.750  1.0
  Cl  Cl7  1  0.667  0.333  0.250  1.0
[/CIF]
.
The material structure described by Ag3Cl crystallizes in the hexagonal P6_3/mmc space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 12-coordinate geometry to eight Ag(1,1) and four equivalent Cl(1) atoms. In the second Ag site, Ag(1) is bonded in a 12-coordinate geometry to eight Ag(1,1) and four equivalent Cl(1) atoms. In the third Ag site, Ag(1) is bonded in a 12-coordinate geometry to eight Ag(1,1) and four equivalent Cl(1) atoms. Cl(1) is bonded to twelve Ag(1,1,1) atoms to form a mixture of distorted face and corner-sharing ClAg12 cuboctahedra. is represented by the CIF card [CIF]
data_Ag3Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.270
_cell_length_b   6.270
_cell_length_c   4.773
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   162.515
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.155  0.309  0.250  1.0
  Ag  Ag1  1  0.691  0.845  0.250  1.0
  Ag  Ag2  1  0.155  0.845  0.250  1.0
  Ag  Ag3  1  0.845  0.691  0.750  1.0
  Ag  Ag4  1  0.309  0.155  0.750  1.0
  Ag  Ag5  1  0.845  0.155  0.750  1.0
  Cl  Cl6  1  0.333  0.667  0.750  1.0
  Cl  Cl7  1  0.667  0.333  0.250  1.0
[/CIF]
.