The structure described by NaAg(NO2)2 crystallizes in the triclinic P1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in an octahedral geometry to one N(1), one N(2), one O(1), one O(3), one O(6), and one O(7) atom. In the second Na site, Na(2) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(2), one O(4), one O(5), and one O(8) atom. In the second Ag site, Ag(2) is bonded in a linear geometry to one N(3) and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Na(1), one O(2), and one O(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Na(1), one O(4), and one O(5) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(2), one O(1), and one O(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(2), one O(3), and one O(7) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(3) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Na(2), one Ag(1), and one N(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(2), one Ag(1), and one N(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(2), one Ag(1), and one N(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(3) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(4) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Na(2), one Ag(1), and one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaAg(NO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.756
_cell_length_b   6.950
_cell_length_c   6.767
_cell_angle_alpha   68.845
_cell_angle_beta   56.695
_cell_angle_gamma   54.460
_symmetry_Int_Tables_number   1
_cell_volume   247.585
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.751  0.750  0.742  1.0
  Na  Na1  1  0.501  0.496  0.494  1.0
  Ag  Ag2  1  0.247  0.249  0.259  1.0
  Ag  Ag3  1  0.995  0.996  0.006  1.0
  N  N4  1  0.511  0.985  0.523  1.0
  N  N5  1  0.986  0.523  0.977  1.0
  N  N6  1  0.801  0.206  0.790  1.0
  N  N7  1  0.193  0.802  0.207  1.0
  O  O8  1  0.699  0.117  0.780  1.0
  O  O9  1  0.405  0.920  0.503  1.0
  O  O10  1  0.395  0.775  0.133  1.0
  O  O11  1  0.923  0.393  0.170  1.0
  O  O12  1  0.164  0.515  0.918  1.0
  O  O13  1  0.769  0.407  0.697  1.0
  O  O14  1  0.127  0.703  0.399  1.0
  O  O15  1  0.517  0.173  0.393  1.0
[/CIF]
.
The structure described by NaAg(NO2)2 crystallizes in the triclinic P1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in an octahedral geometry to one N(1), one N(2), one O(1), one O(3), one O(6), and one O(7) atom. In the second Na site, Na(2) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(2), one O(4), one O(5), and one O(8) atom. In the second Ag site, Ag(2) is bonded in a linear geometry to one N(3) and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Na(1), one O(2), and one O(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Na(1), one O(4), and one O(5) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(2), one O(1), and one O(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(2), one O(3), and one O(7) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(3) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Na(2), one Ag(1), and one N(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(4) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(2), one Ag(1), and one N(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(2), one Ag(1), and one N(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(3) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one N(4) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Na(2), one Ag(1), and one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaAg(NO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.756
_cell_length_b   6.950
_cell_length_c   6.767
_cell_angle_alpha   68.845
_cell_angle_beta   56.695
_cell_angle_gamma   54.460
_symmetry_Int_Tables_number   1
_cell_volume   247.585
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.751  0.750  0.742  1.0
  Na  Na1  1  0.501  0.496  0.494  1.0
  Ag  Ag2  1  0.247  0.249  0.259  1.0
  Ag  Ag3  1  0.995  0.996  0.006  1.0
  N  N4  1  0.511  0.985  0.523  1.0
  N  N5  1  0.986  0.523  0.977  1.0
  N  N6  1  0.801  0.206  0.790  1.0
  N  N7  1  0.193  0.802  0.207  1.0
  O  O8  1  0.699  0.117  0.780  1.0
  O  O9  1  0.405  0.920  0.503  1.0
  O  O10  1  0.395  0.775  0.133  1.0
  O  O11  1  0.923  0.393  0.170  1.0
  O  O12  1  0.164  0.515  0.918  1.0
  O  O13  1  0.769  0.407  0.697  1.0
  O  O14  1  0.127  0.703  0.399  1.0
  O  O15  1  0.517  0.173  0.393  1.0
[/CIF]
.