The structure described by RhCdF6 is Upper Bainite-derived structured and crystallizes in the trigonal R-3 space group. Rh(1) is bonded to six equivalent F(1) atoms to form RhF6 octahedra that share corners with six equivalent Cd(1)F6 octahedra. The corner-sharing octahedral tilt angles are 48°. Cd(1) is bonded to six equivalent F(1) atoms to form CdF6 octahedra that share corners with six equivalent Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles are 48°. F(1) is bonded in a bent 120 degrees geometry to one Rh(1) and one Cd(1) atom. is represented by the CIF file [CIF]
data_CdRhF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.622
_cell_length_b   5.622
_cell_length_c   5.622
_cell_angle_alpha   54.125
_cell_angle_beta   54.125
_cell_angle_gamma   54.125
_symmetry_Int_Tables_number   1
_cell_volume   108.399
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.500  0.500  1.0
  Rh  Rh1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.390  0.063  0.781  1.0
  F  F3  1  0.063  0.781  0.390  1.0
  F  F4  1  0.219  0.610  0.937  1.0
  F  F5  1  0.937  0.219  0.610  1.0
  F  F6  1  0.610  0.937  0.219  1.0
  F  F7  1  0.781  0.390  0.063  1.0
[/CIF]
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The structure described by RhCdF6 is Upper Bainite-derived structured and crystallizes in the trigonal R-3 space group. Rh(1) is bonded to six equivalent F(1) atoms to form RhF6 octahedra that share corners with six equivalent Cd(1)F6 octahedra. The corner-sharing octahedral tilt angles are 48°. Cd(1) is bonded to six equivalent F(1) atoms to form CdF6 octahedra that share corners with six equivalent Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles are 48°. F(1) is bonded in a bent 120 degrees geometry to one Rh(1) and one Cd(1) atom. is represented by the CIF file [CIF]
data_CdRhF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.622
_cell_length_b   5.622
_cell_length_c   5.622
_cell_angle_alpha   54.125
_cell_angle_beta   54.125
_cell_angle_gamma   54.125
_symmetry_Int_Tables_number   1
_cell_volume   108.399
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.500  0.500  1.0
  Rh  Rh1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.390  0.063  0.781  1.0
  F  F3  1  0.063  0.781  0.390  1.0
  F  F4  1  0.219  0.610  0.937  1.0
  F  F5  1  0.937  0.219  0.610  1.0
  F  F6  1  0.610  0.937  0.219  1.0
  F  F7  1  0.781  0.390  0.063  1.0
[/CIF]
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