The compound described by NF2H is Ammonia-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four difluoroamine molecules. N(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one F(1), and one F(2) atom. H(1) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one N(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_HNF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.064
_cell_length_b   5.817
_cell_length_c   6.953
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   204.803
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.253  0.101  0.696  1.0
  H  H1  1  0.747  0.601  0.304  1.0
  H  H2  1  0.253  0.601  0.804  1.0
  H  H3  1  0.747  0.101  0.196  1.0
  N  N4  1  0.282  0.265  0.639  1.0
  N  N5  1  0.718  0.765  0.361  1.0
  N  N6  1  0.282  0.765  0.861  1.0
  N  N7  1  0.718  0.265  0.139  1.0
  F  F8  1  0.546  0.242  0.573  1.0
  F  F9  1  0.454  0.742  0.427  1.0
  F  F10  1  0.546  0.742  0.927  1.0
  F  F11  1  0.454  0.242  0.073  1.0
  F  F12  1  0.129  0.247  0.468  1.0
  F  F13  1  0.871  0.747  0.532  1.0
  F  F14  1  0.129  0.747  0.032  1.0
  F  F15  1  0.871  0.247  0.968  1.0
[/CIF]
.
The compound described by NF2H is Ammonia-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four difluoroamine molecules. N(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one F(1), and one F(2) atom. H(1) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one N(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF file [CIF]
data_HNF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.064
_cell_length_b   5.817
_cell_length_c   6.953
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   204.803
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.253  0.101  0.696  1.0
  H  H1  1  0.747  0.601  0.304  1.0
  H  H2  1  0.253  0.601  0.804  1.0
  H  H3  1  0.747  0.101  0.196  1.0
  N  N4  1  0.282  0.265  0.639  1.0
  N  N5  1  0.718  0.765  0.361  1.0
  N  N6  1  0.282  0.765  0.861  1.0
  N  N7  1  0.718  0.265  0.139  1.0
  F  F8  1  0.546  0.242  0.573  1.0
  F  F9  1  0.454  0.742  0.427  1.0
  F  F10  1  0.546  0.742  0.927  1.0
  F  F11  1  0.454  0.242  0.073  1.0
  F  F12  1  0.129  0.247  0.468  1.0
  F  F13  1  0.871  0.747  0.532  1.0
  F  F14  1  0.129  0.747  0.032  1.0
  F  F15  1  0.871  0.247  0.968  1.0
[/CIF]
.