The crystal structure described by V3Fe2ZnO11 crystallizes in the triclinic P-1 space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(11), one O(2), and one O(9) atom to form VO4 tetrahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Zn(1)O6 octahedra, and corners with three equivalent Fe(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 40-72°. In the second V site, V(2) is bonded to one O(4), one O(6), one O(7), and two equivalent O(1) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent Fe(2)O6 octahedra,  a cornercorner with one V(3)O4 tetrahedra, corners with two equivalent Fe(1)O5 trigonal bipyramids,  an edgeedge with one Fe(2)O6 octahedra, and  an edgeedge with one V(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 36-46°. In the third V site, V(3) is bonded to one O(3), one O(5), one O(7), and one O(8) atom to form VO4 tetrahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with four equivalent Zn(1)O6 octahedra, and  a cornercorner with one V(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 18-63°. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(10), one O(11), one O(4), one O(6), and one O(9) atom to form FeO5 trigonal bipyramids that share  a cornercorner with one Zn(1)O6 octahedra, corners with three equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O5 trigonal bipyramids, and  an edgeedge with one Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles are 57°. In the second Fe site, Fe(2) is bonded to one O(1), one O(11), one O(2), one O(3), one O(4), and one O(7) atom to form distorted FeO6 octahedra that share corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, corners with two equivalent V(2)O5 trigonal bipyramids,  an edgeedge with one Zn(1)O6 octahedra,  an edgeedge with one V(2)O5 trigonal bipyramid, and  an edgeedge with one Fe(1)O5 trigonal bipyramid. Zn(1) is bonded to one O(2), one O(3), one O(5), one O(9), and two equivalent O(8) atoms to form distorted ZnO6 octahedra that share corners with two equivalent V(1)O4 tetrahedra, corners with four equivalent V(3)O4 tetrahedra,  a cornercorner with one Fe(1)O5 trigonal bipyramid,  an edgeedge with one Fe(2)O6 octahedra, and  an edgeedge with one Zn(1)O6 octahedra. There are eleven inequivalent O sites. In the first O site, O(11) is bonded in a distorted trigonal planar geometry to one V(1), one Fe(1), and one Fe(2) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent V(2) and one Fe(2) atom. In the third O site, O(2) is bonded in a 3-coordinate geometry to one V(1), one Fe(2), and one Zn(1) atom. In the fourth O site, O(3) is bonded in a distorted trigonal planar geometry to one V(3), one Fe(2), and one Zn(1) atom. In the fifth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(2), one Fe(1), and one Fe(2) atom. In the sixth O site, O(5) is bonded in a bent 150 degrees geometry to one V(3) and one Zn(1) atom. In the seventh O site, O(6) is bonded in a bent 150 degrees geometry to one V(2) and one Fe(1) atom. In the eighth O site, O(7) is bonded in a 3-coordinate geometry to one V(2), one V(3), and one Fe(2) atom. In the ninth O site, O(8) is bonded in a distorted trigonal planar geometry to one V(3) and two equivalent Zn(1) atoms. In the tenth O site, O(9) is bonded in a distorted trigonal planar geometry to one V(1), one Fe(1), and one Zn(1) atom. In the eleventh O site, O(10) is bonded in a bent 150 degrees geometry to one V(1) and one Fe(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V3ZnFe2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.516
_cell_length_b   6.926
_cell_length_c   10.354
_cell_angle_alpha   96.916
_cell_angle_beta   103.372
_cell_angle_gamma   101.257
_symmetry_Int_Tables_number   1
_cell_volume   439.091
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.175  0.490  0.301  1.0
  V  V1  1  0.825  0.510  0.699  1.0
  V  V2  1  0.189  0.073  0.625  1.0
  V  V3  1  0.811  0.927  0.375  1.0
  V  V4  1  0.239  0.173  0.971  1.0
  V  V5  1  0.761  0.827  0.029  1.0
  Zn  Zn6  1  0.199  0.673  0.009  1.0
  Zn  Zn7  1  0.801  0.327  0.991  1.0
  Fe  Fe8  1  0.674  0.380  0.340  1.0
  Fe  Fe9  1  0.326  0.620  0.660  1.0
  Fe  Fe10  1  0.261  0.006  0.273  1.0
  Fe  Fe11  1  0.739  0.994  0.727  1.0
  O  O12  1  0.125  0.014  0.434  1.0
  O  O13  1  0.875  0.986  0.566  1.0
  O  O14  1  0.239  0.698  0.232  1.0
  O  O15  1  0.761  0.302  0.768  1.0
  O  O16  1  0.221  0.982  0.067  1.0
  O  O17  1  0.779  0.018  0.933  1.0
  O  O18  1  0.618  0.074  0.339  1.0
  O  O19  1  0.382  0.926  0.661  1.0
  O  O20  1  0.497  0.719  0.004  1.0
  O  O21  1  0.503  0.281  0.996  1.0
  O  O22  1  0.306  0.319  0.652  1.0
  O  O23  1  0.694  0.681  0.348  1.0
  O  O24  1  0.116  0.072  0.796  1.0
  O  O25  1  0.884  0.928  0.204  1.0
  O  O26  1  0.123  0.369  0.024  1.0
  O  O27  1  0.877  0.631  0.976  1.0
  O  O28  1  0.891  0.379  0.238  1.0
  O  O29  1  0.109  0.621  0.762  1.0
  O  O30  1  0.211  0.571  0.470  1.0
  O  O31  1  0.789  0.429  0.530  1.0
  O  O32  1  0.358  0.327  0.290  1.0
  O  O33  1  0.642  0.673  0.710  1.0
[/CIF]
.
The crystal structure described by V3Fe2ZnO11 crystallizes in the triclinic P-1 space group. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(11), one O(2), and one O(9) atom to form VO4 tetrahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with two equivalent Zn(1)O6 octahedra, and corners with three equivalent Fe(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 40-72°. In the second V site, V(2) is bonded to one O(4), one O(6), one O(7), and two equivalent O(1) atoms to form distorted VO5 trigonal bipyramids that share corners with two equivalent Fe(2)O6 octahedra,  a cornercorner with one V(3)O4 tetrahedra, corners with two equivalent Fe(1)O5 trigonal bipyramids,  an edgeedge with one Fe(2)O6 octahedra, and  an edgeedge with one V(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 36-46°. In the third V site, V(3) is bonded to one O(3), one O(5), one O(7), and one O(8) atom to form VO4 tetrahedra that share corners with two equivalent Fe(2)O6 octahedra, corners with four equivalent Zn(1)O6 octahedra, and  a cornercorner with one V(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 18-63°. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(10), one O(11), one O(4), one O(6), and one O(9) atom to form FeO5 trigonal bipyramids that share  a cornercorner with one Zn(1)O6 octahedra, corners with three equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O5 trigonal bipyramids, and  an edgeedge with one Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles are 57°. In the second Fe site, Fe(2) is bonded to one O(1), one O(11), one O(2), one O(3), one O(4), and one O(7) atom to form distorted FeO6 octahedra that share corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, corners with two equivalent V(2)O5 trigonal bipyramids,  an edgeedge with one Zn(1)O6 octahedra,  an edgeedge with one V(2)O5 trigonal bipyramid, and  an edgeedge with one Fe(1)O5 trigonal bipyramid. Zn(1) is bonded to one O(2), one O(3), one O(5), one O(9), and two equivalent O(8) atoms to form distorted ZnO6 octahedra that share corners with two equivalent V(1)O4 tetrahedra, corners with four equivalent V(3)O4 tetrahedra,  a cornercorner with one Fe(1)O5 trigonal bipyramid,  an edgeedge with one Fe(2)O6 octahedra, and  an edgeedge with one Zn(1)O6 octahedra. There are eleven inequivalent O sites. In the first O site, O(11) is bonded in a distorted trigonal planar geometry to one V(1), one Fe(1), and one Fe(2) atom. In the second O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent V(2) and one Fe(2) atom. In the third O site, O(2) is bonded in a 3-coordinate geometry to one V(1), one Fe(2), and one Zn(1) atom. In the fourth O site, O(3) is bonded in a distorted trigonal planar geometry to one V(3), one Fe(2), and one Zn(1) atom. In the fifth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(2), one Fe(1), and one Fe(2) atom. In the sixth O site, O(5) is bonded in a bent 150 degrees geometry to one V(3) and one Zn(1) atom. In the seventh O site, O(6) is bonded in a bent 150 degrees geometry to one V(2) and one Fe(1) atom. In the eighth O site, O(7) is bonded in a 3-coordinate geometry to one V(2), one V(3), and one Fe(2) atom. In the ninth O site, O(8) is bonded in a distorted trigonal planar geometry to one V(3) and two equivalent Zn(1) atoms. In the tenth O site, O(9) is bonded in a distorted trigonal planar geometry to one V(1), one Fe(1), and one Zn(1) atom. In the eleventh O site, O(10) is bonded in a bent 150 degrees geometry to one V(1) and one Fe(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V3ZnFe2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.516
_cell_length_b   6.926
_cell_length_c   10.354
_cell_angle_alpha   96.916
_cell_angle_beta   103.372
_cell_angle_gamma   101.257
_symmetry_Int_Tables_number   1
_cell_volume   439.091
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.175  0.490  0.301  1.0
  V  V1  1  0.825  0.510  0.699  1.0
  V  V2  1  0.189  0.073  0.625  1.0
  V  V3  1  0.811  0.927  0.375  1.0
  V  V4  1  0.239  0.173  0.971  1.0
  V  V5  1  0.761  0.827  0.029  1.0
  Zn  Zn6  1  0.199  0.673  0.009  1.0
  Zn  Zn7  1  0.801  0.327  0.991  1.0
  Fe  Fe8  1  0.674  0.380  0.340  1.0
  Fe  Fe9  1  0.326  0.620  0.660  1.0
  Fe  Fe10  1  0.261  0.006  0.273  1.0
  Fe  Fe11  1  0.739  0.994  0.727  1.0
  O  O12  1  0.125  0.014  0.434  1.0
  O  O13  1  0.875  0.986  0.566  1.0
  O  O14  1  0.239  0.698  0.232  1.0
  O  O15  1  0.761  0.302  0.768  1.0
  O  O16  1  0.221  0.982  0.067  1.0
  O  O17  1  0.779  0.018  0.933  1.0
  O  O18  1  0.618  0.074  0.339  1.0
  O  O19  1  0.382  0.926  0.661  1.0
  O  O20  1  0.497  0.719  0.004  1.0
  O  O21  1  0.503  0.281  0.996  1.0
  O  O22  1  0.306  0.319  0.652  1.0
  O  O23  1  0.694  0.681  0.348  1.0
  O  O24  1  0.116  0.072  0.796  1.0
  O  O25  1  0.884  0.928  0.204  1.0
  O  O26  1  0.123  0.369  0.024  1.0
  O  O27  1  0.877  0.631  0.976  1.0
  O  O28  1  0.891  0.379  0.238  1.0
  O  O29  1  0.109  0.621  0.762  1.0
  O  O30  1  0.211  0.571  0.470  1.0
  O  O31  1  0.789  0.429  0.530  1.0
  O  O32  1  0.358  0.327  0.290  1.0
  O  O33  1  0.642  0.673  0.710  1.0
[/CIF]
.