The material structure described by La3SbO3 crystallizes in the monoclinic C2/m space group. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 4-coordinate geometry to four equivalent Sb(1), one O(2), and three equivalent O(1) atoms. In the second La site, La(2) is bonded in a distorted see-saw-like geometry to two equivalent Sb(1), one O(2), and three equivalent O(3) atoms. In the third La site, La(3) is bonded in a distorted see-saw-like geometry to two equivalent Sb(1), one O(1), one O(3), and two equivalent O(2) atoms. Sb(1) is bonded in a body-centered cubic geometry to two equivalent La(2), two equivalent La(3), and four equivalent La(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to one La(3) and three equivalent La(1) atoms to form a mixture of corner and edge-sharing OLa4 tetrahedra. In the second O site, O(2) is bonded to one La(1), one La(2), and two equivalent La(3) atoms to form a mixture of distorted corner and edge-sharing OLa4 trigonal pyramids. In the third O site, O(3) is bonded to one La(3) and three equivalent La(2) atoms to form a mixture of corner and edge-sharing OLa4 trigonal pyramids. is represented by the CIF file [CIF]
data_La3SbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.118
_cell_length_b   7.237
_cell_length_c   11.094
_cell_angle_alpha   81.896
_cell_angle_beta   79.302
_cell_angle_gamma   73.463
_symmetry_Int_Tables_number   1
_cell_volume   310.047
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.381  0.794  0.444  1.0
  La  La1  1  0.619  0.206  0.556  1.0
  La  La2  1  0.372  0.357  0.899  1.0
  La  La3  1  0.628  0.643  0.101  1.0
  La  La4  1  0.846  0.101  0.207  1.0
  La  La5  1  0.154  0.899  0.793  1.0
  Sb  Sb6  1  0.878  0.562  0.683  1.0
  Sb  Sb7  1  0.122  0.438  0.318  1.0
  O  O8  1  0.810  0.968  0.411  1.0
  O  O9  1  0.190  0.032  0.589  1.0
  O  O10  1  0.564  0.074  0.798  1.0
  O  O11  1  0.436  0.926  0.202  1.0
  O  O12  1  0.839  0.311  0.012  1.0
  O  O13  1  0.161  0.689  0.988  1.0
[/CIF]
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The material structure described by La3SbO3 crystallizes in the monoclinic C2/m space group. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 4-coordinate geometry to four equivalent Sb(1), one O(2), and three equivalent O(1) atoms. In the second La site, La(2) is bonded in a distorted see-saw-like geometry to two equivalent Sb(1), one O(2), and three equivalent O(3) atoms. In the third La site, La(3) is bonded in a distorted see-saw-like geometry to two equivalent Sb(1), one O(1), one O(3), and two equivalent O(2) atoms. Sb(1) is bonded in a body-centered cubic geometry to two equivalent La(2), two equivalent La(3), and four equivalent La(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to one La(3) and three equivalent La(1) atoms to form a mixture of corner and edge-sharing OLa4 tetrahedra. In the second O site, O(2) is bonded to one La(1), one La(2), and two equivalent La(3) atoms to form a mixture of distorted corner and edge-sharing OLa4 trigonal pyramids. In the third O site, O(3) is bonded to one La(3) and three equivalent La(2) atoms to form a mixture of corner and edge-sharing OLa4 trigonal pyramids. is represented by the CIF file [CIF]
data_La3SbO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.118
_cell_length_b   7.237
_cell_length_c   11.094
_cell_angle_alpha   81.896
_cell_angle_beta   79.302
_cell_angle_gamma   73.463
_symmetry_Int_Tables_number   1
_cell_volume   310.047
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.381  0.794  0.444  1.0
  La  La1  1  0.619  0.206  0.556  1.0
  La  La2  1  0.372  0.357  0.899  1.0
  La  La3  1  0.628  0.643  0.101  1.0
  La  La4  1  0.846  0.101  0.207  1.0
  La  La5  1  0.154  0.899  0.793  1.0
  Sb  Sb6  1  0.878  0.562  0.683  1.0
  Sb  Sb7  1  0.122  0.438  0.318  1.0
  O  O8  1  0.810  0.968  0.411  1.0
  O  O9  1  0.190  0.032  0.589  1.0
  O  O10  1  0.564  0.074  0.798  1.0
  O  O11  1  0.436  0.926  0.202  1.0
  O  O12  1  0.839  0.311  0.012  1.0
  O  O13  1  0.161  0.689  0.988  1.0
[/CIF]
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