The material described by WCl6 is Copper structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of three tungsten(vi) chloride molecules. W(1) is bonded in an octahedral geometry to six equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF file [CIF]
data_WCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.717
_cell_length_b   6.717
_cell_length_c   6.717
_cell_angle_alpha   55.315
_cell_angle_beta   55.315
_cell_angle_gamma   55.315
_symmetry_Int_Tables_number   1
_cell_volume   190.936
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.000  0.000  0.000  1.0
  Cl  Cl1  1  0.376  0.082  0.775  1.0
  Cl  Cl2  1  0.624  0.918  0.225  1.0
  Cl  Cl3  1  0.082  0.775  0.376  1.0
  Cl  Cl4  1  0.775  0.376  0.082  1.0
  Cl  Cl5  1  0.918  0.225  0.624  1.0
  Cl  Cl6  1  0.225  0.624  0.918  1.0
[/CIF]
.
The material described by WCl6 is Copper structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of three tungsten(vi) chloride molecules. W(1) is bonded in an octahedral geometry to six equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF file [CIF]
data_WCl6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.717
_cell_length_b   6.717
_cell_length_c   6.717
_cell_angle_alpha   55.315
_cell_angle_beta   55.315
_cell_angle_gamma   55.315
_symmetry_Int_Tables_number   1
_cell_volume   190.936
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.000  0.000  0.000  1.0
  Cl  Cl1  1  0.376  0.082  0.775  1.0
  Cl  Cl2  1  0.624  0.918  0.225  1.0
  Cl  Cl3  1  0.082  0.775  0.376  1.0
  Cl  Cl4  1  0.775  0.376  0.082  1.0
  Cl  Cl5  1  0.918  0.225  0.624  1.0
  Cl  Cl6  1  0.225  0.624  0.918  1.0
[/CIF]
.