The compound described by Re2Cl9PCl4 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two [pcl4]+1 molecules and two Re2Cl9 clusters. In each Re2Cl9 cluster, there are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one Cl(2), one Cl(6), two equivalent Cl(3), and two equivalent Cl(7) atoms to form face-sharing ReCl6 octahedra. In the second Re site, Re(2) is bonded to one Cl(2), one Cl(4), two equivalent Cl(3), and two equivalent Cl(5) atoms to form face-sharing ReCl6 octahedra. There are six inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a 2-coordinate geometry to one Re(1) and one Re(2) atom. In the second Cl site, Cl(3) is bonded in a 2-coordinate geometry to one Re(1) and one Re(2) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Re(2) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Re(2) atom. In the fifth Cl site, Cl(6) is bonded in a single-bond geometry to one Re(1) atom. In the sixth Cl site, Cl(7) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_Re2PCl13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.763
_cell_length_b   8.904
_cell_length_c   9.458
_cell_angle_alpha   80.626
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   894.241
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.250  0.832  0.094  1.0
  Re  Re1  1  0.750  0.168  0.906  1.0
  Re  Re2  1  0.250  0.681  0.863  1.0
  Re  Re3  1  0.750  0.319  0.137  1.0
  P  P4  1  0.250  0.263  0.511  1.0
  P  P5  1  0.750  0.737  0.489  1.0
  Cl  Cl6  1  0.603  0.808  0.579  1.0
  Cl  Cl7  1  0.103  0.192  0.421  1.0
  Cl  Cl8  1  0.750  0.444  0.889  1.0
  Cl  Cl9  1  0.250  0.556  0.111  1.0
  Cl  Cl10  1  0.913  0.144  0.087  1.0
  Cl  Cl11  1  0.413  0.856  0.913  1.0
  Cl  Cl12  1  0.087  0.856  0.913  1.0
  Cl  Cl13  1  0.587  0.144  0.087  1.0
  Cl  Cl14  1  0.750  0.195  0.373  1.0
  Cl  Cl15  1  0.250  0.805  0.627  1.0
  Cl  Cl16  1  0.904  0.482  0.184  1.0
  Cl  Cl17  1  0.404  0.518  0.816  1.0
  Cl  Cl18  1  0.096  0.518  0.816  1.0
  Cl  Cl19  1  0.596  0.482  0.184  1.0
  Cl  Cl20  1  0.750  0.906  0.927  1.0
  Cl  Cl21  1  0.250  0.094  0.073  1.0
  Cl  Cl22  1  0.903  0.192  0.732  1.0
  Cl  Cl23  1  0.403  0.808  0.268  1.0
  Cl  Cl24  1  0.097  0.808  0.268  1.0
  Cl  Cl25  1  0.597  0.192  0.732  1.0
  Cl  Cl26  1  0.750  0.814  0.286  1.0
  Cl  Cl27  1  0.250  0.186  0.714  1.0
  Cl  Cl28  1  0.750  0.517  0.519  1.0
  Cl  Cl29  1  0.250  0.483  0.481  1.0
  Cl  Cl30  1  0.897  0.808  0.579  1.0
  Cl  Cl31  1  0.397  0.192  0.421  1.0
[/CIF]
.
The compound described by Re2Cl9PCl4 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two [pcl4]+1 molecules and two Re2Cl9 clusters. In each Re2Cl9 cluster, there are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one Cl(2), one Cl(6), two equivalent Cl(3), and two equivalent Cl(7) atoms to form face-sharing ReCl6 octahedra. In the second Re site, Re(2) is bonded to one Cl(2), one Cl(4), two equivalent Cl(3), and two equivalent Cl(5) atoms to form face-sharing ReCl6 octahedra. There are six inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a 2-coordinate geometry to one Re(1) and one Re(2) atom. In the second Cl site, Cl(3) is bonded in a 2-coordinate geometry to one Re(1) and one Re(2) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Re(2) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Re(2) atom. In the fifth Cl site, Cl(6) is bonded in a single-bond geometry to one Re(1) atom. In the sixth Cl site, Cl(7) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_Re2PCl13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.763
_cell_length_b   8.904
_cell_length_c   9.458
_cell_angle_alpha   80.626
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   894.241
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.250  0.832  0.094  1.0
  Re  Re1  1  0.750  0.168  0.906  1.0
  Re  Re2  1  0.250  0.681  0.863  1.0
  Re  Re3  1  0.750  0.319  0.137  1.0
  P  P4  1  0.250  0.263  0.511  1.0
  P  P5  1  0.750  0.737  0.489  1.0
  Cl  Cl6  1  0.603  0.808  0.579  1.0
  Cl  Cl7  1  0.103  0.192  0.421  1.0
  Cl  Cl8  1  0.750  0.444  0.889  1.0
  Cl  Cl9  1  0.250  0.556  0.111  1.0
  Cl  Cl10  1  0.913  0.144  0.087  1.0
  Cl  Cl11  1  0.413  0.856  0.913  1.0
  Cl  Cl12  1  0.087  0.856  0.913  1.0
  Cl  Cl13  1  0.587  0.144  0.087  1.0
  Cl  Cl14  1  0.750  0.195  0.373  1.0
  Cl  Cl15  1  0.250  0.805  0.627  1.0
  Cl  Cl16  1  0.904  0.482  0.184  1.0
  Cl  Cl17  1  0.404  0.518  0.816  1.0
  Cl  Cl18  1  0.096  0.518  0.816  1.0
  Cl  Cl19  1  0.596  0.482  0.184  1.0
  Cl  Cl20  1  0.750  0.906  0.927  1.0
  Cl  Cl21  1  0.250  0.094  0.073  1.0
  Cl  Cl22  1  0.903  0.192  0.732  1.0
  Cl  Cl23  1  0.403  0.808  0.268  1.0
  Cl  Cl24  1  0.097  0.808  0.268  1.0
  Cl  Cl25  1  0.597  0.192  0.732  1.0
  Cl  Cl26  1  0.750  0.814  0.286  1.0
  Cl  Cl27  1  0.250  0.186  0.714  1.0
  Cl  Cl28  1  0.750  0.517  0.519  1.0
  Cl  Cl29  1  0.250  0.483  0.481  1.0
  Cl  Cl30  1  0.897  0.808  0.579  1.0
  Cl  Cl31  1  0.397  0.192  0.421  1.0
[/CIF]
.