The material structure described by SrV10O15 crystallizes in the orthorhombic Cmce space group. Sr(1) is bonded to two equivalent O(2), two equivalent O(3), four equivalent O(5), and four equivalent O(6) atoms to form distorted SrO12 cuboctahedra that share corners with eight equivalent V(2)O6 octahedra, corners with eight equivalent V(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with four equivalent V(2)O6 octahedra, faces with two equivalent V(1)O6 octahedra, and faces with four equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-51°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), two equivalent O(5), and two equivalent O(6) atoms to form VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with four equivalent V(3)O6 octahedra,  an edgeedge with one Sr(1)O12 cuboctahedra, edges with two equivalent V(3)O6 octahedra, edges with four equivalent V(2)O6 octahedra, and  a faceface with one Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-55°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Sr(1)O12 cuboctahedra,  a cornercorner with one V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one Sr(1)O12 cuboctahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-58°. In the third V site, V(3) is bonded to one O(2), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Sr(1)O12 cuboctahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with three equivalent V(2)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra, and  a faceface with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-52°. There are six inequivalent O sites. In the first O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Sr(1), one V(1), one V(2), and two equivalent V(3) atoms. In the second O site, O(1) is bonded to two equivalent V(1) and four equivalent V(2) atoms to form a mixture of corner and edge-sharing OV6 octahedra. In the third O site, O(2) is bonded in a distorted see-saw-like geometry to one Sr(1), two equivalent V(2), and two equivalent V(3) atoms. In the fourth O site, O(3) is bonded to one Sr(1), one V(1), and two equivalent V(2) atoms to form distorted OSrV3 tetrahedra that share  a cornercorner with one O(1)V6 octahedra,  a cornercorner with one O(3)SrV3 tetrahedra, and  an edgeedge with one O(1)V6 octahedra. The corner-sharing octahedral tilt angles are 5°. In the fifth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to two equivalent V(2) and two equivalent V(3) atoms. In the sixth O site, O(5) is bonded in a 4-coordinate geometry to one Sr(1), one V(1), one V(2), and two equivalent V(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_SrV10O15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.891
_cell_length_b   7.891
_cell_length_c   9.578
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   96.444
_symmetry_Int_Tables_number   1
_cell_volume   592.680
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.500  0.500  0.500  1.0
  Sr  Sr1  1  0.000  0.000  0.000  1.0
  V  V2  1  0.819  0.819  0.630  1.0
  V  V3  1  0.681  0.681  0.130  1.0
  V  V4  1  0.319  0.319  0.870  1.0
  V  V5  1  0.181  0.181  0.370  1.0
  V  V6  1  0.042  0.791  0.354  1.0
  V  V7  1  0.458  0.709  0.854  1.0
  V  V8  1  0.291  0.542  0.146  1.0
  V  V9  1  0.209  0.958  0.646  1.0
  V  V10  1  0.958  0.209  0.646  1.0
  V  V11  1  0.542  0.291  0.146  1.0
  V  V12  1  0.709  0.458  0.854  1.0
  V  V13  1  0.919  0.407  0.119  1.0
  V  V14  1  0.407  0.919  0.119  1.0
  V  V15  1  0.093  0.581  0.619  1.0
  V  V16  1  0.419  0.907  0.381  1.0
  V  V17  1  0.081  0.593  0.881  1.0
  V  V18  1  0.593  0.081  0.881  1.0
  V  V19  1  0.907  0.419  0.381  1.0
  V  V20  1  0.581  0.093  0.619  1.0
  V  V21  1  0.791  0.042  0.354  1.0
  O  O22  1  0.000  0.000  0.500  1.0
  O  O23  1  0.500  0.500  0.000  1.0
  O  O24  1  0.241  0.759  0.500  1.0
  O  O25  1  0.259  0.741  0.000  1.0
  O  O26  1  0.759  0.241  0.500  1.0
  O  O27  1  0.741  0.259  0.000  1.0
  O  O28  1  0.647  0.647  0.734  1.0
  O  O29  1  0.853  0.853  0.234  1.0
  O  O30  1  0.147  0.147  0.766  1.0
  O  O31  1  0.353  0.353  0.266  1.0
  O  O32  1  0.572  0.072  0.250  1.0
  O  O33  1  0.928  0.428  0.750  1.0
  O  O34  1  0.428  0.928  0.750  1.0
  O  O35  1  0.072  0.572  0.250  1.0
  O  O36  1  0.712  0.466  0.243  1.0
  O  O37  1  0.788  0.034  0.743  1.0
  O  O38  1  0.966  0.212  0.257  1.0
  O  O39  1  0.534  0.288  0.757  1.0
  O  O40  1  0.288  0.534  0.757  1.0
  O  O41  1  0.212  0.966  0.257  1.0
  O  O42  1  0.034  0.788  0.743  1.0
  O  O43  1  0.466  0.712  0.243  1.0
  O  O44  1  0.110  0.359  0.507  1.0
  O  O45  1  0.390  0.141  0.007  1.0
  O  O46  1  0.859  0.610  0.993  1.0
  O  O47  1  0.641  0.890  0.493  1.0
  O  O48  1  0.359  0.110  0.507  1.0
  O  O49  1  0.610  0.859  0.993  1.0
  O  O50  1  0.141  0.390  0.007  1.0
  O  O51  1  0.890  0.641  0.493  1.0
[/CIF]
.
The material structure described by SrV10O15 crystallizes in the orthorhombic Cmce space group. Sr(1) is bonded to two equivalent O(2), two equivalent O(3), four equivalent O(5), and four equivalent O(6) atoms to form distorted SrO12 cuboctahedra that share corners with eight equivalent V(2)O6 octahedra, corners with eight equivalent V(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with four equivalent V(2)O6 octahedra, faces with two equivalent V(1)O6 octahedra, and faces with four equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 21-51°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), two equivalent O(5), and two equivalent O(6) atoms to form VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with four equivalent V(3)O6 octahedra,  an edgeedge with one Sr(1)O12 cuboctahedra, edges with two equivalent V(3)O6 octahedra, edges with four equivalent V(2)O6 octahedra, and  a faceface with one Sr(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-55°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Sr(1)O12 cuboctahedra,  a cornercorner with one V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one Sr(1)O12 cuboctahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with three equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-58°. In the third V site, V(3) is bonded to one O(2), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent Sr(1)O12 cuboctahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with three equivalent V(2)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra, and  a faceface with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-52°. There are six inequivalent O sites. In the first O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Sr(1), one V(1), one V(2), and two equivalent V(3) atoms. In the second O site, O(1) is bonded to two equivalent V(1) and four equivalent V(2) atoms to form a mixture of corner and edge-sharing OV6 octahedra. In the third O site, O(2) is bonded in a distorted see-saw-like geometry to one Sr(1), two equivalent V(2), and two equivalent V(3) atoms. In the fourth O site, O(3) is bonded to one Sr(1), one V(1), and two equivalent V(2) atoms to form distorted OSrV3 tetrahedra that share  a cornercorner with one O(1)V6 octahedra,  a cornercorner with one O(3)SrV3 tetrahedra, and  an edgeedge with one O(1)V6 octahedra. The corner-sharing octahedral tilt angles are 5°. In the fifth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to two equivalent V(2) and two equivalent V(3) atoms. In the sixth O site, O(5) is bonded in a 4-coordinate geometry to one Sr(1), one V(1), one V(2), and two equivalent V(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_SrV10O15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.891
_cell_length_b   7.891
_cell_length_c   9.578
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   96.444
_symmetry_Int_Tables_number   1
_cell_volume   592.680
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.500  0.500  0.500  1.0
  Sr  Sr1  1  0.000  0.000  0.000  1.0
  V  V2  1  0.819  0.819  0.630  1.0
  V  V3  1  0.681  0.681  0.130  1.0
  V  V4  1  0.319  0.319  0.870  1.0
  V  V5  1  0.181  0.181  0.370  1.0
  V  V6  1  0.042  0.791  0.354  1.0
  V  V7  1  0.458  0.709  0.854  1.0
  V  V8  1  0.291  0.542  0.146  1.0
  V  V9  1  0.209  0.958  0.646  1.0
  V  V10  1  0.958  0.209  0.646  1.0
  V  V11  1  0.542  0.291  0.146  1.0
  V  V12  1  0.709  0.458  0.854  1.0
  V  V13  1  0.919  0.407  0.119  1.0
  V  V14  1  0.407  0.919  0.119  1.0
  V  V15  1  0.093  0.581  0.619  1.0
  V  V16  1  0.419  0.907  0.381  1.0
  V  V17  1  0.081  0.593  0.881  1.0
  V  V18  1  0.593  0.081  0.881  1.0
  V  V19  1  0.907  0.419  0.381  1.0
  V  V20  1  0.581  0.093  0.619  1.0
  V  V21  1  0.791  0.042  0.354  1.0
  O  O22  1  0.000  0.000  0.500  1.0
  O  O23  1  0.500  0.500  0.000  1.0
  O  O24  1  0.241  0.759  0.500  1.0
  O  O25  1  0.259  0.741  0.000  1.0
  O  O26  1  0.759  0.241  0.500  1.0
  O  O27  1  0.741  0.259  0.000  1.0
  O  O28  1  0.647  0.647  0.734  1.0
  O  O29  1  0.853  0.853  0.234  1.0
  O  O30  1  0.147  0.147  0.766  1.0
  O  O31  1  0.353  0.353  0.266  1.0
  O  O32  1  0.572  0.072  0.250  1.0
  O  O33  1  0.928  0.428  0.750  1.0
  O  O34  1  0.428  0.928  0.750  1.0
  O  O35  1  0.072  0.572  0.250  1.0
  O  O36  1  0.712  0.466  0.243  1.0
  O  O37  1  0.788  0.034  0.743  1.0
  O  O38  1  0.966  0.212  0.257  1.0
  O  O39  1  0.534  0.288  0.757  1.0
  O  O40  1  0.288  0.534  0.757  1.0
  O  O41  1  0.212  0.966  0.257  1.0
  O  O42  1  0.034  0.788  0.743  1.0
  O  O43  1  0.466  0.712  0.243  1.0
  O  O44  1  0.110  0.359  0.507  1.0
  O  O45  1  0.390  0.141  0.007  1.0
  O  O46  1  0.859  0.610  0.993  1.0
  O  O47  1  0.641  0.890  0.493  1.0
  O  O48  1  0.359  0.110  0.507  1.0
  O  O49  1  0.610  0.859  0.993  1.0
  O  O50  1  0.141  0.390  0.007  1.0
  O  O51  1  0.890  0.641  0.493  1.0
[/CIF]
.