The structure described by Pd(PbO3)2 crystallizes in the tetragonal P4_2/ncm space group. Pd(1) is bonded in a square co-planar geometry to four equivalent O(3) atoms. Pb(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to four equivalent Pb(1) atoms to form edge-sharing OPb4 tetrahedra. In the second O site, O(2) is bonded in a distorted square co-planar geometry to four equivalent O(3) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Pd(1), two equivalent Pb(1), and one O(2) atom. is represented by the CIF file [CIF]
data_Pd(PbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.939
_cell_length_b   8.939
_cell_length_c   5.943
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   474.847
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.250  0.750  0.750  1.0
  Pd  Pd1  1  0.750  0.750  0.250  1.0
  Pd  Pd2  1  0.250  0.250  0.250  1.0
  Pd  Pd3  1  0.750  0.250  0.750  1.0
  Pb  Pb4  1  0.136  0.364  0.721  1.0
  Pb  Pb5  1  0.864  0.364  0.221  1.0
  Pb  Pb6  1  0.364  0.864  0.279  1.0
  Pb  Pb7  1  0.636  0.864  0.779  1.0
  Pb  Pb8  1  0.864  0.636  0.721  1.0
  Pb  Pb9  1  0.136  0.636  0.221  1.0
  Pb  Pb10  1  0.636  0.136  0.279  1.0
  Pb  Pb11  1  0.364  0.136  0.779  1.0
  O  O12  1  0.000  0.500  0.451  1.0
  O  O13  1  0.000  0.500  0.951  1.0
  O  O14  1  0.500  0.000  0.549  1.0
  O  O15  1  0.500  0.000  0.049  1.0
  O  O16  1  0.500  0.500  0.500  1.0
  O  O17  1  0.500  0.500  0.000  1.0
  O  O18  1  0.000  0.000  0.500  1.0
  O  O19  1  0.000  0.000  0.000  1.0
  O  O20  1  0.068  0.791  0.560  1.0
  O  O21  1  0.932  0.791  0.060  1.0
  O  O22  1  0.432  0.291  0.440  1.0
  O  O23  1  0.568  0.291  0.940  1.0
  O  O24  1  0.932  0.209  0.560  1.0
  O  O25  1  0.068  0.209  0.060  1.0
  O  O26  1  0.568  0.709  0.440  1.0
  O  O27  1  0.432  0.709  0.940  1.0
  O  O28  1  0.209  0.068  0.440  1.0
  O  O29  1  0.209  0.932  0.940  1.0
  O  O30  1  0.709  0.432  0.560  1.0
  O  O31  1  0.709  0.568  0.060  1.0
  O  O32  1  0.791  0.932  0.440  1.0
  O  O33  1  0.791  0.068  0.940  1.0
  O  O34  1  0.291  0.568  0.560  1.0
  O  O35  1  0.291  0.432  0.060  1.0
[/CIF]
.
The structure described by Pd(PbO3)2 crystallizes in the tetragonal P4_2/ncm space group. Pd(1) is bonded in a square co-planar geometry to four equivalent O(3) atoms. Pb(1) is bonded in a 6-coordinate geometry to two equivalent O(1) and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to four equivalent Pb(1) atoms to form edge-sharing OPb4 tetrahedra. In the second O site, O(2) is bonded in a distorted square co-planar geometry to four equivalent O(3) atoms. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Pd(1), two equivalent Pb(1), and one O(2) atom. is represented by the CIF file [CIF]
data_Pd(PbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.939
_cell_length_b   8.939
_cell_length_c   5.943
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   474.847
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.250  0.750  0.750  1.0
  Pd  Pd1  1  0.750  0.750  0.250  1.0
  Pd  Pd2  1  0.250  0.250  0.250  1.0
  Pd  Pd3  1  0.750  0.250  0.750  1.0
  Pb  Pb4  1  0.136  0.364  0.721  1.0
  Pb  Pb5  1  0.864  0.364  0.221  1.0
  Pb  Pb6  1  0.364  0.864  0.279  1.0
  Pb  Pb7  1  0.636  0.864  0.779  1.0
  Pb  Pb8  1  0.864  0.636  0.721  1.0
  Pb  Pb9  1  0.136  0.636  0.221  1.0
  Pb  Pb10  1  0.636  0.136  0.279  1.0
  Pb  Pb11  1  0.364  0.136  0.779  1.0
  O  O12  1  0.000  0.500  0.451  1.0
  O  O13  1  0.000  0.500  0.951  1.0
  O  O14  1  0.500  0.000  0.549  1.0
  O  O15  1  0.500  0.000  0.049  1.0
  O  O16  1  0.500  0.500  0.500  1.0
  O  O17  1  0.500  0.500  0.000  1.0
  O  O18  1  0.000  0.000  0.500  1.0
  O  O19  1  0.000  0.000  0.000  1.0
  O  O20  1  0.068  0.791  0.560  1.0
  O  O21  1  0.932  0.791  0.060  1.0
  O  O22  1  0.432  0.291  0.440  1.0
  O  O23  1  0.568  0.291  0.940  1.0
  O  O24  1  0.932  0.209  0.560  1.0
  O  O25  1  0.068  0.209  0.060  1.0
  O  O26  1  0.568  0.709  0.440  1.0
  O  O27  1  0.432  0.709  0.940  1.0
  O  O28  1  0.209  0.068  0.440  1.0
  O  O29  1  0.209  0.932  0.940  1.0
  O  O30  1  0.709  0.432  0.560  1.0
  O  O31  1  0.709  0.568  0.060  1.0
  O  O32  1  0.791  0.932  0.440  1.0
  O  O33  1  0.791  0.068  0.940  1.0
  O  O34  1  0.291  0.568  0.560  1.0
  O  O35  1  0.291  0.432  0.060  1.0
[/CIF]
.