The material structure described by N2Se2SCl is Indium-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight N2Se2SCl clusters. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(2) and one S(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Se(1) and one S(1) atom. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a single-bond geometry to one N(2) and one Cl(1) atom. In the second Se site, Se(2) is bonded in a single-bond geometry to one N(1) and one Cl(1) atom. S(1) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. Cl(1) is bonded in a 2-coordinate geometry to one Se(1) and one Se(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Se2SN2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.283
_cell_length_b   8.852
_cell_length_c   15.519
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1137.802
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Se  Se0  1  0.821  0.964  0.078  1.0
  Se  Se1  1  0.321  0.036  0.422  1.0
  Se  Se2  1  0.054  0.299  0.545  1.0
  Se  Se3  1  0.554  0.201  0.545  1.0
  Se  Se4  1  0.054  0.799  0.955  1.0
  Se  Se5  1  0.946  0.201  0.045  1.0
  Se  Se6  1  0.946  0.701  0.455  1.0
  Se  Se7  1  0.554  0.701  0.955  1.0
  Se  Se8  1  0.179  0.036  0.922  1.0
  Se  Se9  1  0.446  0.299  0.045  1.0
  Se  Se10  1  0.679  0.964  0.578  1.0
  Se  Se11  1  0.446  0.799  0.455  1.0
  Se  Se12  1  0.179  0.536  0.578  1.0
  Se  Se13  1  0.821  0.464  0.422  1.0
  Se  Se14  1  0.679  0.464  0.922  1.0
  Se  Se15  1  0.321  0.536  0.078  1.0
  S  S16  1  0.513  0.410  0.219  1.0
  S  S17  1  0.513  0.910  0.281  1.0
  S  S18  1  0.987  0.910  0.781  1.0
  S  S19  1  0.487  0.090  0.719  1.0
  S  S20  1  0.487  0.590  0.781  1.0
  S  S21  1  0.013  0.590  0.281  1.0
  S  S22  1  0.013  0.090  0.219  1.0
  S  S23  1  0.987  0.410  0.719  1.0
  N  N24  1  0.540  0.281  0.151  1.0
  N  N25  1  0.101  0.040  0.812  1.0
  N  N26  1  0.960  0.281  0.651  1.0
  N  N27  1  0.399  0.540  0.188  1.0
  N  N28  1  0.601  0.960  0.688  1.0
  N  N29  1  0.899  0.960  0.188  1.0
  N  N30  1  0.960  0.781  0.849  1.0
  N  N31  1  0.540  0.781  0.349  1.0
  N  N32  1  0.399  0.040  0.312  1.0
  N  N33  1  0.601  0.460  0.812  1.0
  N  N34  1  0.040  0.219  0.151  1.0
  N  N35  1  0.101  0.540  0.688  1.0
  N  N36  1  0.460  0.719  0.849  1.0
  N  N37  1  0.899  0.460  0.312  1.0
  N  N38  1  0.040  0.719  0.349  1.0
  N  N39  1  0.460  0.219  0.651  1.0
  Cl  Cl40  1  0.281  0.904  0.084  1.0
  Cl  Cl41  1  0.281  0.404  0.416  1.0
  Cl  Cl42  1  0.781  0.596  0.084  1.0
  Cl  Cl43  1  0.719  0.596  0.584  1.0
  Cl  Cl44  1  0.219  0.904  0.584  1.0
  Cl  Cl45  1  0.219  0.404  0.916  1.0
  Cl  Cl46  1  0.781  0.096  0.416  1.0
  Cl  Cl47  1  0.719  0.096  0.916  1.0
[/CIF]
.
The material structure described by N2Se2SCl is Indium-like structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight N2Se2SCl clusters. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Se(2) and one S(1) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one Se(1) and one S(1) atom. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a single-bond geometry to one N(2) and one Cl(1) atom. In the second Se site, Se(2) is bonded in a single-bond geometry to one N(1) and one Cl(1) atom. S(1) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. Cl(1) is bonded in a 2-coordinate geometry to one Se(1) and one Se(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Se2SN2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.283
_cell_length_b   8.852
_cell_length_c   15.519
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1137.802
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Se  Se0  1  0.821  0.964  0.078  1.0
  Se  Se1  1  0.321  0.036  0.422  1.0
  Se  Se2  1  0.054  0.299  0.545  1.0
  Se  Se3  1  0.554  0.201  0.545  1.0
  Se  Se4  1  0.054  0.799  0.955  1.0
  Se  Se5  1  0.946  0.201  0.045  1.0
  Se  Se6  1  0.946  0.701  0.455  1.0
  Se  Se7  1  0.554  0.701  0.955  1.0
  Se  Se8  1  0.179  0.036  0.922  1.0
  Se  Se9  1  0.446  0.299  0.045  1.0
  Se  Se10  1  0.679  0.964  0.578  1.0
  Se  Se11  1  0.446  0.799  0.455  1.0
  Se  Se12  1  0.179  0.536  0.578  1.0
  Se  Se13  1  0.821  0.464  0.422  1.0
  Se  Se14  1  0.679  0.464  0.922  1.0
  Se  Se15  1  0.321  0.536  0.078  1.0
  S  S16  1  0.513  0.410  0.219  1.0
  S  S17  1  0.513  0.910  0.281  1.0
  S  S18  1  0.987  0.910  0.781  1.0
  S  S19  1  0.487  0.090  0.719  1.0
  S  S20  1  0.487  0.590  0.781  1.0
  S  S21  1  0.013  0.590  0.281  1.0
  S  S22  1  0.013  0.090  0.219  1.0
  S  S23  1  0.987  0.410  0.719  1.0
  N  N24  1  0.540  0.281  0.151  1.0
  N  N25  1  0.101  0.040  0.812  1.0
  N  N26  1  0.960  0.281  0.651  1.0
  N  N27  1  0.399  0.540  0.188  1.0
  N  N28  1  0.601  0.960  0.688  1.0
  N  N29  1  0.899  0.960  0.188  1.0
  N  N30  1  0.960  0.781  0.849  1.0
  N  N31  1  0.540  0.781  0.349  1.0
  N  N32  1  0.399  0.040  0.312  1.0
  N  N33  1  0.601  0.460  0.812  1.0
  N  N34  1  0.040  0.219  0.151  1.0
  N  N35  1  0.101  0.540  0.688  1.0
  N  N36  1  0.460  0.719  0.849  1.0
  N  N37  1  0.899  0.460  0.312  1.0
  N  N38  1  0.040  0.719  0.349  1.0
  N  N39  1  0.460  0.219  0.651  1.0
  Cl  Cl40  1  0.281  0.904  0.084  1.0
  Cl  Cl41  1  0.281  0.404  0.416  1.0
  Cl  Cl42  1  0.781  0.596  0.084  1.0
  Cl  Cl43  1  0.719  0.596  0.584  1.0
  Cl  Cl44  1  0.219  0.904  0.584  1.0
  Cl  Cl45  1  0.219  0.404  0.916  1.0
  Cl  Cl46  1  0.781  0.096  0.416  1.0
  Cl  Cl47  1  0.719  0.096  0.916  1.0
[/CIF]
.