The structure described by KrAsF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four KrAsF7 clusters. Kr(1) is bonded in a linear geometry to one F(3) and one F(4) atom. As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a bent 120 degrees geometry to one Kr(1) and one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Kr(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_AsKrF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.169
_cell_length_b   5.109
_cell_length_c   10.598
_cell_angle_alpha   84.327
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   547.900
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.988  0.904  0.769  1.0
  As  As1  1  0.488  0.096  0.731  1.0
  As  As2  1  0.012  0.096  0.231  1.0
  As  As3  1  0.512  0.904  0.269  1.0
  Kr  Kr4  1  0.227  0.532  0.971  1.0
  Kr  Kr5  1  0.727  0.468  0.529  1.0
  Kr  Kr6  1  0.773  0.468  0.029  1.0
  Kr  Kr7  1  0.273  0.532  0.471  1.0
  F  F8  1  0.094  0.149  0.806  1.0
  F  F9  1  0.594  0.851  0.694  1.0
  F  F10  1  0.906  0.851  0.194  1.0
  F  F11  1  0.406  0.149  0.306  1.0
  F  F12  1  0.869  0.022  0.865  1.0
  F  F13  1  0.369  0.978  0.635  1.0
  F  F14  1  0.131  0.978  0.135  1.0
  F  F15  1  0.631  0.022  0.365  1.0
  F  F16  1  0.455  0.712  0.425  1.0
  F  F17  1  0.955  0.288  0.075  1.0
  F  F18  1  0.545  0.288  0.575  1.0
  F  F19  1  0.045  0.712  0.925  1.0
  F  F20  1  0.121  0.365  0.519  1.0
  F  F21  1  0.621  0.635  0.981  1.0
  F  F22  1  0.879  0.635  0.481  1.0
  F  F23  1  0.379  0.365  0.019  1.0
  F  F24  1  0.385  0.755  0.197  1.0
  F  F25  1  0.885  0.245  0.303  1.0
  F  F26  1  0.615  0.245  0.803  1.0
  F  F27  1  0.115  0.755  0.697  1.0
  F  F28  1  0.569  0.077  0.134  1.0
  F  F29  1  0.069  0.923  0.366  1.0
  F  F30  1  0.431  0.923  0.866  1.0
  F  F31  1  0.931  0.077  0.634  1.0
  F  F32  1  0.611  0.634  0.252  1.0
  F  F33  1  0.111  0.366  0.248  1.0
  F  F34  1  0.389  0.366  0.748  1.0
  F  F35  1  0.889  0.634  0.752  1.0
[/CIF]
.
The structure described by KrAsF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four KrAsF7 clusters. Kr(1) is bonded in a linear geometry to one F(3) and one F(4) atom. As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(5), one F(6), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a bent 120 degrees geometry to one Kr(1) and one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Kr(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_AsKrF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.169
_cell_length_b   5.109
_cell_length_c   10.598
_cell_angle_alpha   84.327
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   547.900
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.988  0.904  0.769  1.0
  As  As1  1  0.488  0.096  0.731  1.0
  As  As2  1  0.012  0.096  0.231  1.0
  As  As3  1  0.512  0.904  0.269  1.0
  Kr  Kr4  1  0.227  0.532  0.971  1.0
  Kr  Kr5  1  0.727  0.468  0.529  1.0
  Kr  Kr6  1  0.773  0.468  0.029  1.0
  Kr  Kr7  1  0.273  0.532  0.471  1.0
  F  F8  1  0.094  0.149  0.806  1.0
  F  F9  1  0.594  0.851  0.694  1.0
  F  F10  1  0.906  0.851  0.194  1.0
  F  F11  1  0.406  0.149  0.306  1.0
  F  F12  1  0.869  0.022  0.865  1.0
  F  F13  1  0.369  0.978  0.635  1.0
  F  F14  1  0.131  0.978  0.135  1.0
  F  F15  1  0.631  0.022  0.365  1.0
  F  F16  1  0.455  0.712  0.425  1.0
  F  F17  1  0.955  0.288  0.075  1.0
  F  F18  1  0.545  0.288  0.575  1.0
  F  F19  1  0.045  0.712  0.925  1.0
  F  F20  1  0.121  0.365  0.519  1.0
  F  F21  1  0.621  0.635  0.981  1.0
  F  F22  1  0.879  0.635  0.481  1.0
  F  F23  1  0.379  0.365  0.019  1.0
  F  F24  1  0.385  0.755  0.197  1.0
  F  F25  1  0.885  0.245  0.303  1.0
  F  F26  1  0.615  0.245  0.803  1.0
  F  F27  1  0.115  0.755  0.697  1.0
  F  F28  1  0.569  0.077  0.134  1.0
  F  F29  1  0.069  0.923  0.366  1.0
  F  F30  1  0.431  0.923  0.866  1.0
  F  F31  1  0.931  0.077  0.634  1.0
  F  F32  1  0.611  0.634  0.252  1.0
  F  F33  1  0.111  0.366  0.248  1.0
  F  F34  1  0.389  0.366  0.748  1.0
  F  F35  1  0.889  0.634  0.752  1.0
[/CIF]
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