The material structure described by NaN(SO2F)2 crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded in a 7-coordinate geometry to one N(1), one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. N(1) is bonded in a 3-coordinate geometry to one Na(1), one S(1), and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one N(1), one O(1), one O(3), and one F(1) atom to form corner-sharing SNO2F tetrahedra. In the second S site, S(2) is bonded to one N(1), one O(2), one O(4), and one F(2) atom to form corner-sharing SNO2F tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Na(1) and one S(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one S(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to two equivalent Na(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one S(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF card [CIF]
data_NaS2N(O2F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.323
_cell_length_b   7.562
_cell_length_c   9.211
_cell_angle_alpha   73.494
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   622.611
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.484  0.245  0.068  1.0
  Na  Na1  1  0.016  0.245  0.568  1.0
  Na  Na2  1  0.516  0.755  0.932  1.0
  Na  Na3  1  0.984  0.755  0.432  1.0
  S  S4  1  0.725  0.136  0.388  1.0
  S  S5  1  0.775  0.136  0.888  1.0
  S  S6  1  0.275  0.864  0.612  1.0
  S  S7  1  0.225  0.864  0.112  1.0
  S  S8  1  0.719  0.521  0.270  1.0
  S  S9  1  0.781  0.521  0.770  1.0
  S  S10  1  0.281  0.479  0.730  1.0
  S  S11  1  0.219  0.479  0.230  1.0
  N  N12  1  0.794  0.334  0.360  1.0
  N  N13  1  0.706  0.334  0.860  1.0
  N  N14  1  0.206  0.666  0.640  1.0
  N  N15  1  0.294  0.666  0.140  1.0
  O  O16  1  0.634  0.107  0.271  1.0
  O  O17  1  0.866  0.107  0.771  1.0
  O  O18  1  0.366  0.893  0.729  1.0
  O  O19  1  0.134  0.893  0.229  1.0
  O  O20  1  0.638  0.517  0.138  1.0
  O  O21  1  0.862  0.517  0.638  1.0
  O  O22  1  0.362  0.483  0.862  1.0
  O  O23  1  0.138  0.483  0.362  1.0
  O  O24  1  0.836  0.004  0.449  1.0
  O  O25  1  0.664  0.004  0.949  1.0
  O  O26  1  0.164  0.996  0.551  1.0
  O  O27  1  0.336  0.996  0.051  1.0
  O  O28  1  0.820  0.668  0.258  1.0
  O  O29  1  0.680  0.668  0.758  1.0
  O  O30  1  0.180  0.332  0.742  1.0
  O  O31  1  0.320  0.332  0.242  1.0
  F  F32  1  0.619  0.124  0.527  1.0
  F  F33  1  0.881  0.124  0.027  1.0
  F  F34  1  0.381  0.876  0.473  1.0
  F  F35  1  0.119  0.876  0.973  1.0
  F  F36  1  0.599  0.551  0.386  1.0
  F  F37  1  0.901  0.551  0.886  1.0
  F  F38  1  0.401  0.449  0.614  1.0
  F  F39  1  0.099  0.449  0.114  1.0
[/CIF]
.
The material structure described by NaN(SO2F)2 crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded in a 7-coordinate geometry to one N(1), one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. N(1) is bonded in a 3-coordinate geometry to one Na(1), one S(1), and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one N(1), one O(1), one O(3), and one F(1) atom to form corner-sharing SNO2F tetrahedra. In the second S site, S(2) is bonded to one N(1), one O(2), one O(4), and one F(2) atom to form corner-sharing SNO2F tetrahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Na(1) and one S(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one S(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to two equivalent Na(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one S(2) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF card [CIF]
data_NaS2N(O2F)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.323
_cell_length_b   7.562
_cell_length_c   9.211
_cell_angle_alpha   73.494
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   622.611
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.484  0.245  0.068  1.0
  Na  Na1  1  0.016  0.245  0.568  1.0
  Na  Na2  1  0.516  0.755  0.932  1.0
  Na  Na3  1  0.984  0.755  0.432  1.0
  S  S4  1  0.725  0.136  0.388  1.0
  S  S5  1  0.775  0.136  0.888  1.0
  S  S6  1  0.275  0.864  0.612  1.0
  S  S7  1  0.225  0.864  0.112  1.0
  S  S8  1  0.719  0.521  0.270  1.0
  S  S9  1  0.781  0.521  0.770  1.0
  S  S10  1  0.281  0.479  0.730  1.0
  S  S11  1  0.219  0.479  0.230  1.0
  N  N12  1  0.794  0.334  0.360  1.0
  N  N13  1  0.706  0.334  0.860  1.0
  N  N14  1  0.206  0.666  0.640  1.0
  N  N15  1  0.294  0.666  0.140  1.0
  O  O16  1  0.634  0.107  0.271  1.0
  O  O17  1  0.866  0.107  0.771  1.0
  O  O18  1  0.366  0.893  0.729  1.0
  O  O19  1  0.134  0.893  0.229  1.0
  O  O20  1  0.638  0.517  0.138  1.0
  O  O21  1  0.862  0.517  0.638  1.0
  O  O22  1  0.362  0.483  0.862  1.0
  O  O23  1  0.138  0.483  0.362  1.0
  O  O24  1  0.836  0.004  0.449  1.0
  O  O25  1  0.664  0.004  0.949  1.0
  O  O26  1  0.164  0.996  0.551  1.0
  O  O27  1  0.336  0.996  0.051  1.0
  O  O28  1  0.820  0.668  0.258  1.0
  O  O29  1  0.680  0.668  0.758  1.0
  O  O30  1  0.180  0.332  0.742  1.0
  O  O31  1  0.320  0.332  0.242  1.0
  F  F32  1  0.619  0.124  0.527  1.0
  F  F33  1  0.881  0.124  0.027  1.0
  F  F34  1  0.381  0.876  0.473  1.0
  F  F35  1  0.119  0.876  0.973  1.0
  F  F36  1  0.599  0.551  0.386  1.0
  F  F37  1  0.901  0.551  0.886  1.0
  F  F38  1  0.401  0.449  0.614  1.0
  F  F39  1  0.099  0.449  0.114  1.0
[/CIF]
.