The material described by NO2AsF6 is Tetraauricupride structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two hydroxylamine, n-hydroxy- molecules and two AsF6 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to two equivalent F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_AsN(OF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.264
_cell_length_b   5.264
_cell_length_c   5.329
_cell_angle_alpha   85.788
_cell_angle_beta   85.788
_cell_angle_gamma   91.758
_symmetry_Int_Tables_number   1
_cell_volume   146.793
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.000  0.000  0.000  1.0
  N  N1  1  0.500  0.500  0.500  1.0
  O  O2  1  0.605  0.605  0.643  1.0
  O  O3  1  0.395  0.395  0.357  1.0
  F  F4  1  0.231  0.231  0.857  1.0
  F  F5  1  0.779  0.107  0.786  1.0
  F  F6  1  0.107  0.779  0.786  1.0
  F  F7  1  0.893  0.221  0.214  1.0
  F  F8  1  0.221  0.893  0.214  1.0
  F  F9  1  0.769  0.769  0.143  1.0
[/CIF]
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The material described by NO2AsF6 is Tetraauricupride structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two hydroxylamine, n-hydroxy- molecules and two AsF6 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to two equivalent F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. is represented by the CIF card [CIF]
data_AsN(OF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.264
_cell_length_b   5.264
_cell_length_c   5.329
_cell_angle_alpha   85.788
_cell_angle_beta   85.788
_cell_angle_gamma   91.758
_symmetry_Int_Tables_number   1
_cell_volume   146.793
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.000  0.000  0.000  1.0
  N  N1  1  0.500  0.500  0.500  1.0
  O  O2  1  0.605  0.605  0.643  1.0
  O  O3  1  0.395  0.395  0.357  1.0
  F  F4  1  0.231  0.231  0.857  1.0
  F  F5  1  0.779  0.107  0.786  1.0
  F  F6  1  0.107  0.779  0.786  1.0
  F  F7  1  0.893  0.221  0.214  1.0
  F  F8  1  0.221  0.893  0.214  1.0
  F  F9  1  0.769  0.769  0.143  1.0
[/CIF]
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