The material described by SnO2 is beta Vanadium nitride-like structured and crystallizes in the tetragonal I4_1/amd space group. Sn(1) is bonded to six equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles are 27°. O(1) is bonded in a distorted T-shaped geometry to three equivalent Sn(1) atoms. is represented by the CIF file [CIF]
data_SnO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.853
_cell_length_b   5.853
_cell_length_c   5.853
_cell_angle_alpha   140.034
_cell_angle_beta   140.034
_cell_angle_gamma   57.802
_symmetry_Int_Tables_number   1
_cell_volume   81.984
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.000  0.000  0.000  1.0
  Sn  Sn1  1  0.750  0.250  0.500  1.0
  O  O2  1  0.547  0.047  0.500  1.0
  O  O3  1  0.203  0.203  0.000  1.0
  O  O4  1  0.953  0.453  0.500  1.0
  O  O5  1  0.797  0.797  0.000  1.0
[/CIF]
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The material described by SnO2 is beta Vanadium nitride-like structured and crystallizes in the tetragonal I4_1/amd space group. Sn(1) is bonded to six equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles are 27°. O(1) is bonded in a distorted T-shaped geometry to three equivalent Sn(1) atoms. is represented by the CIF file [CIF]
data_SnO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.853
_cell_length_b   5.853
_cell_length_c   5.853
_cell_angle_alpha   140.034
_cell_angle_beta   140.034
_cell_angle_gamma   57.802
_symmetry_Int_Tables_number   1
_cell_volume   81.984
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.000  0.000  0.000  1.0
  Sn  Sn1  1  0.750  0.250  0.500  1.0
  O  O2  1  0.547  0.047  0.500  1.0
  O  O3  1  0.203  0.203  0.000  1.0
  O  O4  1  0.953  0.453  0.500  1.0
  O  O5  1  0.797  0.797  0.000  1.0
[/CIF]
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