The crystal structure described by Li4V3Sn3(TeO8)2 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(13), one O(14), one O(2), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, and corners with three equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-61°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(15), one O(16), one O(4), and one O(5) atom. In the third Li site, Li(3) is bonded to one O(10), one O(3), one O(6), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, corners with three equivalent Te(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, and  an edgeedge with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-61°. In the fourth Li site, Li(4) is bonded to one O(1), one O(11), one O(12), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, and corners with three equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-67°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(12), one O(15), one O(16), one O(2), and one O(3) atom to form VO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Sn(2)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the second V site, V(2) is bonded to one O(13), one O(4), one O(6), one O(7), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 53°. In the third V site, V(3) is bonded to one O(10), one O(14), one O(4), one O(6), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 53°. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(10), one O(13), one O(14), one O(4), one O(7), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 54°. In the second Sn site, Sn(2) is bonded to one O(1), one O(11), one O(15), one O(2), one O(3), and one O(5) atom to form SnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. In the third Sn site, Sn(3) is bonded to one O(1), one O(12), one O(16), one O(2), one O(3), and one O(5) atom to form SnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(6), and one O(9) atom to form distorted TeO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, and  an edgeedge with one Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. In the second Te site, Te(2) is bonded to one O(13), one O(14), one O(15), one O(16), one O(5), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, and  an edgeedge with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-56°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(4), one Sn(2), one Sn(3), and one Te(1) atom. In the second O site, O(2) is bonded to one Li(1), one V(1), one Sn(2), and one Sn(3) atom to form distorted OLiVSn2 trigonal pyramids that share corners with three equivalent O(3)LiVSn2 tetrahedra,  an edgeedge with one O(11)LiVSnTe tetrahedra, and  an edgeedge with one O(12)LiVSnTe tetrahedra. In the third O site, O(3) is bonded to one Li(3), one V(1), one Sn(2), and one Sn(3) atom to form distorted OLiVSn2 tetrahedra that share corners with two equivalent O(11)LiVSnTe tetrahedra, corners with two equivalent O(12)LiVSnTe tetrahedra, and corners with three equivalent O(2)LiVSn2 trigonal pyramids. In the fourth O site, O(4) is bonded in a tetrahedral geometry to one Li(2), one V(2), one V(3), and one Sn(1) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Sn(2), one Sn(3), and one Te(2) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(2), one V(3), and one Te(1) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(2), one V(3), and one Sn(1) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(2), one V(3), and one Te(2) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(2), one Sn(1), and one Te(1) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Sn(1), and one Te(1) atom. In the eleventh O site, O(11) is bonded to one Li(4), one V(1), one Sn(2), and one Te(1) atom to form distorted OLiVSnTe tetrahedra that share  a cornercorner with one O(12)LiVSnTe tetrahedra, corners with two equivalent O(3)LiVSn2 tetrahedra,  an edgeedge with one O(12)LiVSnTe tetrahedra, and  an edgeedge with one O(2)LiVSn2 trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(4), one V(1), one Sn(3), and one Te(1) atom to form distorted OLiVSnTe tetrahedra that share  a cornercorner with one O(11)LiVSnTe tetrahedra, corners with two equivalent O(3)LiVSn2 tetrahedra,  an edgeedge with one O(11)LiVSnTe tetrahedra, and  an edgeedge with one O(2)LiVSn2 trigonal pyramid. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(2), one Sn(1), and one Te(2) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(3), one Sn(1), and one Te(2) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(1), one Sn(2), and one Te(2) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(1), one Sn(3), and one Te(2) atom. is represented by the CIF card [CIF]
data_Li4V3Sn3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.242
_cell_length_b   6.287
_cell_length_c   10.154
_cell_angle_alpha   90.062
_cell_angle_beta   90.015
_cell_angle_gamma   60.272
_symmetry_Int_Tables_number   1
_cell_volume   345.995
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.331  0.337  0.096  1.0
  Li  Li1  1  0.007  0.986  0.013  1.0
  Li  Li2  1  0.004  0.992  0.501  1.0
  Li  Li3  1  0.667  0.666  0.602  1.0
  O  O4  1  0.489  0.022  0.669  1.0
  O  O5  1  0.335  0.330  0.896  1.0
  O  O6  1  0.000  1.000  0.682  1.0
  O  O7  1  0.001  0.997  0.195  1.0
  O  O8  1  0.852  0.297  0.903  1.0
  O  O9  1  0.160  0.679  0.402  1.0
  O  O10  1  0.674  0.655  0.394  1.0
  O  O11  1  0.520  0.963  0.151  1.0
  O  O12  1  0.673  0.168  0.401  1.0
  O  O13  1  0.158  0.169  0.401  1.0
  O  O14  1  0.479  0.490  0.670  1.0
  O  O15  1  0.031  0.490  0.670  1.0
  O  O16  1  0.959  0.521  0.156  1.0
  O  O17  1  0.521  0.520  0.156  1.0
  O  O18  1  0.855  0.843  0.898  1.0
  O  O19  1  0.302  0.843  0.898  1.0
  Sn  Sn20  1  0.833  0.334  0.285  1.0
  Sn  Sn21  1  0.665  0.166  0.786  1.0
  Sn  Sn22  1  0.169  0.166  0.786  1.0
  Te  Te23  1  0.321  0.357  0.501  1.0
  Te  Te24  1  0.662  0.675  0.019  1.0
  V  V25  1  0.168  0.665  0.787  1.0
  V  V26  1  0.816  0.835  0.286  1.0
  V  V27  1  0.348  0.835  0.287  1.0
[/CIF]
.
The crystal structure described by Li4V3Sn3(TeO8)2 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(13), one O(14), one O(2), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, and corners with three equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-61°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(15), one O(16), one O(4), and one O(5) atom. In the third Li site, Li(3) is bonded to one O(10), one O(3), one O(6), and one O(9) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Sn(2)O6 octahedra,  a cornercorner with one Sn(3)O6 octahedra, corners with three equivalent Te(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, and  an edgeedge with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 58-61°. In the fourth Li site, Li(4) is bonded to one O(1), one O(11), one O(12), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Sn(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, and corners with three equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-67°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(12), one O(15), one O(16), one O(2), and one O(3) atom to form VO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent Sn(2)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. In the second V site, V(2) is bonded to one O(13), one O(4), one O(6), one O(7), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 53°. In the third V site, V(3) is bonded to one O(10), one O(14), one O(4), one O(6), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Sn(1)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 53°. There are three inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(10), one O(13), one O(14), one O(4), one O(7), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  an edgeedge with one Te(2)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and  an edgeedge with one Li(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 54°. In the second Sn site, Sn(2) is bonded to one O(1), one O(11), one O(15), one O(2), one O(3), and one O(5) atom to form SnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. In the third Sn site, Sn(3) is bonded to one O(1), one O(12), one O(16), one O(2), one O(3), and one O(5) atom to form SnO6 octahedra that share corners with two equivalent Te(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  a cornercorner with one Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-56°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(10), one O(11), one O(12), one O(6), and one O(9) atom to form distorted TeO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Sn(1)O6 octahedra, corners with three equivalent Li(3)O4 tetrahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one Sn(2)O6 octahedra, and  an edgeedge with one Sn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-54°. In the second Te site, Te(2) is bonded to one O(13), one O(14), one O(15), one O(16), one O(5), and one O(8) atom to form TeO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent Sn(2)O6 octahedra, corners with two equivalent Sn(3)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, and  an edgeedge with one Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-56°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Li(4), one Sn(2), one Sn(3), and one Te(1) atom. In the second O site, O(2) is bonded to one Li(1), one V(1), one Sn(2), and one Sn(3) atom to form distorted OLiVSn2 trigonal pyramids that share corners with three equivalent O(3)LiVSn2 tetrahedra,  an edgeedge with one O(11)LiVSnTe tetrahedra, and  an edgeedge with one O(12)LiVSnTe tetrahedra. In the third O site, O(3) is bonded to one Li(3), one V(1), one Sn(2), and one Sn(3) atom to form distorted OLiVSn2 tetrahedra that share corners with two equivalent O(11)LiVSnTe tetrahedra, corners with two equivalent O(12)LiVSnTe tetrahedra, and corners with three equivalent O(2)LiVSn2 trigonal pyramids. In the fourth O site, O(4) is bonded in a tetrahedral geometry to one Li(2), one V(2), one V(3), and one Sn(1) atom. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one Sn(2), one Sn(3), and one Te(2) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(2), one V(3), and one Te(1) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(4), one V(2), one V(3), and one Sn(1) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(2), one V(3), and one Te(2) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(2), one Sn(1), and one Te(1) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Sn(1), and one Te(1) atom. In the eleventh O site, O(11) is bonded to one Li(4), one V(1), one Sn(2), and one Te(1) atom to form distorted OLiVSnTe tetrahedra that share  a cornercorner with one O(12)LiVSnTe tetrahedra, corners with two equivalent O(3)LiVSn2 tetrahedra,  an edgeedge with one O(12)LiVSnTe tetrahedra, and  an edgeedge with one O(2)LiVSn2 trigonal pyramid. In the twelfth O site, O(12) is bonded to one Li(4), one V(1), one Sn(3), and one Te(1) atom to form distorted OLiVSnTe tetrahedra that share  a cornercorner with one O(11)LiVSnTe tetrahedra, corners with two equivalent O(3)LiVSn2 tetrahedra,  an edgeedge with one O(11)LiVSnTe tetrahedra, and  an edgeedge with one O(2)LiVSn2 trigonal pyramid. In the thirteenth O site, O(13) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(2), one Sn(1), and one Te(2) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(3), one Sn(1), and one Te(2) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(1), one Sn(2), and one Te(2) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Li(2), one V(1), one Sn(3), and one Te(2) atom. is represented by the CIF card [CIF]
data_Li4V3Sn3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.242
_cell_length_b   6.287
_cell_length_c   10.154
_cell_angle_alpha   90.062
_cell_angle_beta   90.015
_cell_angle_gamma   60.272
_symmetry_Int_Tables_number   1
_cell_volume   345.995
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.331  0.337  0.096  1.0
  Li  Li1  1  0.007  0.986  0.013  1.0
  Li  Li2  1  0.004  0.992  0.501  1.0
  Li  Li3  1  0.667  0.666  0.602  1.0
  O  O4  1  0.489  0.022  0.669  1.0
  O  O5  1  0.335  0.330  0.896  1.0
  O  O6  1  0.000  1.000  0.682  1.0
  O  O7  1  0.001  0.997  0.195  1.0
  O  O8  1  0.852  0.297  0.903  1.0
  O  O9  1  0.160  0.679  0.402  1.0
  O  O10  1  0.674  0.655  0.394  1.0
  O  O11  1  0.520  0.963  0.151  1.0
  O  O12  1  0.673  0.168  0.401  1.0
  O  O13  1  0.158  0.169  0.401  1.0
  O  O14  1  0.479  0.490  0.670  1.0
  O  O15  1  0.031  0.490  0.670  1.0
  O  O16  1  0.959  0.521  0.156  1.0
  O  O17  1  0.521  0.520  0.156  1.0
  O  O18  1  0.855  0.843  0.898  1.0
  O  O19  1  0.302  0.843  0.898  1.0
  Sn  Sn20  1  0.833  0.334  0.285  1.0
  Sn  Sn21  1  0.665  0.166  0.786  1.0
  Sn  Sn22  1  0.169  0.166  0.786  1.0
  Te  Te23  1  0.321  0.357  0.501  1.0
  Te  Te24  1  0.662  0.675  0.019  1.0
  V  V25  1  0.168  0.665  0.787  1.0
  V  V26  1  0.816  0.835  0.286  1.0
  V  V27  1  0.348  0.835  0.287  1.0
[/CIF]
.