The structure described by LiV2F9 crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a rectangular see-saw-like geometry to two equivalent F(4) and two equivalent F(5) atoms. V(1) is bonded to one F(1), one F(3), one F(4), one F(5), and two equivalent F(2) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a linear geometry to two equivalent V(1) atoms. In the third F site, F(3) is bonded in a linear geometry to two equivalent V(1) atoms. In the fourth F site, F(4) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one V(1) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one Li(1) and one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiV2F9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.836
_cell_length_b   8.213
_cell_length_c   10.762
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   692.603
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.021  0.381  0.750  1.0
  Li  Li1  1  0.479  0.881  0.250  1.0
  Li  Li2  1  0.521  0.119  0.750  1.0
  Li  Li3  1  0.979  0.619  0.250  1.0
  V  V4  1  0.111  0.748  0.569  1.0
  V  V5  1  0.111  0.748  0.931  1.0
  V  V6  1  0.389  0.248  0.069  1.0
  V  V7  1  0.389  0.248  0.431  1.0
  V  V8  1  0.611  0.752  0.569  1.0
  V  V9  1  0.611  0.752  0.931  1.0
  V  V10  1  0.889  0.252  0.069  1.0
  V  V11  1  0.889  0.252  0.431  1.0
  F  F12  1  0.887  0.037  0.078  1.0
  F  F13  1  0.887  0.037  0.422  1.0
  F  F14  1  0.137  0.260  0.073  1.0
  F  F15  1  0.137  0.260  0.427  1.0
  F  F16  1  0.101  0.768  0.750  1.0
  F  F17  1  0.123  0.532  0.609  1.0
  F  F18  1  0.123  0.532  0.891  1.0
  F  F19  1  0.109  0.720  0.102  1.0
  F  F20  1  0.109  0.720  0.398  1.0
  F  F21  1  0.391  0.220  0.602  1.0
  F  F22  1  0.391  0.220  0.898  1.0
  F  F23  1  0.377  0.032  0.109  1.0
  F  F24  1  0.377  0.032  0.391  1.0
  F  F25  1  0.399  0.268  0.250  1.0
  F  F26  1  0.363  0.760  0.573  1.0
  F  F27  1  0.363  0.760  0.927  1.0
  F  F28  1  0.613  0.537  0.578  1.0
  F  F29  1  0.613  0.537  0.922  1.0
  F  F30  1  0.387  0.463  0.078  1.0
  F  F31  1  0.387  0.463  0.422  1.0
  F  F32  1  0.637  0.240  0.073  1.0
  F  F33  1  0.637  0.240  0.427  1.0
  F  F34  1  0.601  0.732  0.750  1.0
  F  F35  1  0.623  0.968  0.609  1.0
  F  F36  1  0.623  0.968  0.891  1.0
  F  F37  1  0.609  0.780  0.102  1.0
  F  F38  1  0.609  0.780  0.398  1.0
  F  F39  1  0.891  0.280  0.602  1.0
  F  F40  1  0.891  0.280  0.898  1.0
  F  F41  1  0.877  0.468  0.109  1.0
  F  F42  1  0.877  0.468  0.391  1.0
  F  F43  1  0.899  0.232  0.250  1.0
  F  F44  1  0.863  0.740  0.573  1.0
  F  F45  1  0.863  0.740  0.927  1.0
  F  F46  1  0.113  0.963  0.922  1.0
  F  F47  1  0.113  0.963  0.578  1.0
[/CIF]
.
The structure described by LiV2F9 crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a rectangular see-saw-like geometry to two equivalent F(4) and two equivalent F(5) atoms. V(1) is bonded to one F(1), one F(3), one F(4), one F(5), and two equivalent F(2) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 5-11°. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a linear geometry to two equivalent V(1) atoms. In the third F site, F(3) is bonded in a linear geometry to two equivalent V(1) atoms. In the fourth F site, F(4) is bonded in a distorted bent 150 degrees geometry to one Li(1) and one V(1) atom. In the fifth F site, F(5) is bonded in a bent 150 degrees geometry to one Li(1) and one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiV2F9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.836
_cell_length_b   8.213
_cell_length_c   10.762
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   692.603
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.021  0.381  0.750  1.0
  Li  Li1  1  0.479  0.881  0.250  1.0
  Li  Li2  1  0.521  0.119  0.750  1.0
  Li  Li3  1  0.979  0.619  0.250  1.0
  V  V4  1  0.111  0.748  0.569  1.0
  V  V5  1  0.111  0.748  0.931  1.0
  V  V6  1  0.389  0.248  0.069  1.0
  V  V7  1  0.389  0.248  0.431  1.0
  V  V8  1  0.611  0.752  0.569  1.0
  V  V9  1  0.611  0.752  0.931  1.0
  V  V10  1  0.889  0.252  0.069  1.0
  V  V11  1  0.889  0.252  0.431  1.0
  F  F12  1  0.887  0.037  0.078  1.0
  F  F13  1  0.887  0.037  0.422  1.0
  F  F14  1  0.137  0.260  0.073  1.0
  F  F15  1  0.137  0.260  0.427  1.0
  F  F16  1  0.101  0.768  0.750  1.0
  F  F17  1  0.123  0.532  0.609  1.0
  F  F18  1  0.123  0.532  0.891  1.0
  F  F19  1  0.109  0.720  0.102  1.0
  F  F20  1  0.109  0.720  0.398  1.0
  F  F21  1  0.391  0.220  0.602  1.0
  F  F22  1  0.391  0.220  0.898  1.0
  F  F23  1  0.377  0.032  0.109  1.0
  F  F24  1  0.377  0.032  0.391  1.0
  F  F25  1  0.399  0.268  0.250  1.0
  F  F26  1  0.363  0.760  0.573  1.0
  F  F27  1  0.363  0.760  0.927  1.0
  F  F28  1  0.613  0.537  0.578  1.0
  F  F29  1  0.613  0.537  0.922  1.0
  F  F30  1  0.387  0.463  0.078  1.0
  F  F31  1  0.387  0.463  0.422  1.0
  F  F32  1  0.637  0.240  0.073  1.0
  F  F33  1  0.637  0.240  0.427  1.0
  F  F34  1  0.601  0.732  0.750  1.0
  F  F35  1  0.623  0.968  0.609  1.0
  F  F36  1  0.623  0.968  0.891  1.0
  F  F37  1  0.609  0.780  0.102  1.0
  F  F38  1  0.609  0.780  0.398  1.0
  F  F39  1  0.891  0.280  0.602  1.0
  F  F40  1  0.891  0.280  0.898  1.0
  F  F41  1  0.877  0.468  0.109  1.0
  F  F42  1  0.877  0.468  0.391  1.0
  F  F43  1  0.899  0.232  0.250  1.0
  F  F44  1  0.863  0.740  0.573  1.0
  F  F45  1  0.863  0.740  0.927  1.0
  F  F46  1  0.113  0.963  0.922  1.0
  F  F47  1  0.113  0.963  0.578  1.0
[/CIF]
.