The compound described by HgSO3CF3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two trifluoromethane molecules and two HgSO3 clusters. In each HgSO3 cluster, Hg(1) is bonded in a single-bond geometry to one O(2) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Hg(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_HgCS(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.337
_cell_length_b   5.356
_cell_length_c   11.305
_cell_angle_alpha   97.060
_cell_angle_beta   98.509
_cell_angle_gamma   94.858
_symmetry_Int_Tables_number   1
_cell_volume   315.429
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.854  0.826  0.427  1.0
  Hg  Hg1  1  0.146  0.174  0.573  1.0
  C  C2  1  0.801  0.673  0.837  1.0
  C  C3  1  0.199  0.327  0.163  1.0
  S  S4  1  0.595  0.637  0.685  1.0
  S  S5  1  0.405  0.363  0.315  1.0
  O  O6  1  0.739  0.503  0.602  1.0
  O  O7  1  0.636  0.519  0.293  1.0
  O  O8  1  0.364  0.481  0.707  1.0
  O  O9  1  0.261  0.497  0.398  1.0
  O  O10  1  0.451  0.107  0.335  1.0
  O  O11  1  0.549  0.893  0.665  1.0
  F  F12  1  0.015  0.826  0.834  1.0
  F  F13  1  0.866  0.445  0.862  1.0
  F  F14  1  0.679  0.777  0.924  1.0
  F  F15  1  0.985  0.174  0.166  1.0
  F  F16  1  0.321  0.223  0.076  1.0
  F  F17  1  0.134  0.555  0.138  1.0
[/CIF]
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The compound described by HgSO3CF3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two trifluoromethane molecules and two HgSO3 clusters. In each HgSO3 cluster, Hg(1) is bonded in a single-bond geometry to one O(2) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Hg(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_HgCS(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.337
_cell_length_b   5.356
_cell_length_c   11.305
_cell_angle_alpha   97.060
_cell_angle_beta   98.509
_cell_angle_gamma   94.858
_symmetry_Int_Tables_number   1
_cell_volume   315.429
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.854  0.826  0.427  1.0
  Hg  Hg1  1  0.146  0.174  0.573  1.0
  C  C2  1  0.801  0.673  0.837  1.0
  C  C3  1  0.199  0.327  0.163  1.0
  S  S4  1  0.595  0.637  0.685  1.0
  S  S5  1  0.405  0.363  0.315  1.0
  O  O6  1  0.739  0.503  0.602  1.0
  O  O7  1  0.636  0.519  0.293  1.0
  O  O8  1  0.364  0.481  0.707  1.0
  O  O9  1  0.261  0.497  0.398  1.0
  O  O10  1  0.451  0.107  0.335  1.0
  O  O11  1  0.549  0.893  0.665  1.0
  F  F12  1  0.015  0.826  0.834  1.0
  F  F13  1  0.866  0.445  0.862  1.0
  F  F14  1  0.679  0.777  0.924  1.0
  F  F15  1  0.985  0.174  0.166  1.0
  F  F16  1  0.321  0.223  0.076  1.0
  F  F17  1  0.134  0.555  0.138  1.0
[/CIF]
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