The material structure described by Rb2V2Mn(O3Cl)2 crystallizes in the monoclinic C2 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), one O(4), two equivalent O(5), one Cl(2), one Cl(4), and two equivalent Cl(1) atoms. In the second Rb site, Rb(2) is bonded in a 9-coordinate geometry to one O(2), one O(5), one O(6), two equivalent O(4), one Cl(2), one Cl(4), and two equivalent Cl(3) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form VO4 tetrahedra that share  a cornercorner with one Mn(1)Cl4O2 octahedra and corners with two equivalent V(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 27°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form VO4 tetrahedra that share  a cornercorner with one Mn(2)Cl4O2 octahedra and corners with two equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 29°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(3), one Cl(1), one Cl(3), and two equivalent Cl(2) atoms to form distorted MnCl4O2 octahedra that share corners with two equivalent Mn(1)Cl4O2 octahedra, corners with two equivalent Mn(2)Cl4O2 octahedra, and corners with two equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the second Mn site, Mn(2) is bonded to two equivalent O(6), one Cl(1), one Cl(3), and two equivalent Cl(4) atoms to form distorted MnCl4O2 octahedra that share corners with two equivalent Mn(1)Cl4O2 octahedra, corners with two equivalent Mn(2)Cl4O2 octahedra, and corners with two equivalent V(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are six inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one Rb(2), two equivalent Rb(1), and one V(2) atom. In the second O site, O(6) is bonded in a bent 150 degrees geometry to one Rb(2), one V(2), and one Mn(2) atom. In the third O site, O(1) is bonded in a 2-coordinate geometry to one Rb(1), one V(1), and one V(2) atom. In the fourth O site, O(2) is bonded in a 2-coordinate geometry to one Rb(2), one V(1), and one V(2) atom. In the fifth O site, O(3) is bonded in a bent 150 degrees geometry to one Rb(1), one V(1), and one Mn(1) atom. In the sixth O site, O(4) is bonded in a single-bond geometry to one Rb(1), two equivalent Rb(2), and one V(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 6-coordinate geometry to four equivalent Rb(1), one Mn(1), and one Mn(2) atom. In the second Cl site, Cl(2) is bonded to two equivalent Rb(1), two equivalent Rb(2), and two equivalent Mn(1) atoms to form a mixture of distorted corner and edge-sharing ClRb4Mn2 octahedra. The corner-sharing octahedral tilt angles are 4°. In the third Cl site, Cl(3) is bonded in a 6-coordinate geometry to four equivalent Rb(2), one Mn(1), and one Mn(2) atom. In the fourth Cl site, Cl(4) is bonded to two equivalent Rb(1), two equivalent Rb(2), and two equivalent Mn(2) atoms to form a mixture of distorted corner and edge-sharing ClRb4Mn2 octahedra. The corner-sharing octahedral tilt angles are 4°. is represented by the CIF file [CIF]
data_Rb2MnV2(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.976
_cell_length_b   5.613
_cell_length_c   10.908
_cell_angle_alpha   104.646
_cell_angle_beta   59.794
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   555.359
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.200  0.370  0.743  1.0
  Rb  Rb1  1  0.446  0.630  0.252  1.0
  Rb  Rb2  1  0.698  0.370  0.748  1.0
  Rb  Rb3  1  0.943  0.630  0.257  1.0
  Mn  Mn4  1  0.309  0.000  0.000  1.0
  Mn  Mn5  1  0.810  0.000  0.000  1.0
  V  V6  1  0.132  0.222  0.402  1.0
  V  V7  1  0.032  0.818  0.600  1.0
  V  V8  1  0.633  0.182  0.400  1.0
  V  V9  1  0.533  0.778  0.598  1.0
  Cl  Cl10  1  0.040  0.000  0.000  1.0
  Cl  Cl11  1  0.301  0.500  0.000  1.0
  Cl  Cl12  1  0.539  0.000  0.000  1.0
  Cl  Cl13  1  0.801  0.500  0.000  1.0
  O  O14  1  0.037  0.534  0.472  1.0
  O  O15  1  0.009  0.063  0.530  1.0
  O  O16  1  0.174  0.093  0.224  1.0
  O  O17  1  0.277  0.228  0.411  1.0
  O  O18  1  0.187  0.812  0.592  1.0
  O  O19  1  0.509  0.466  0.528  1.0
  O  O20  1  0.539  0.937  0.470  1.0
  O  O21  1  0.398  0.907  0.776  1.0
  O  O22  1  0.673  0.138  0.222  1.0
  O  O23  1  0.778  0.188  0.408  1.0
  O  O24  1  0.688  0.772  0.589  1.0
  O  O25  1  0.896  0.862  0.778  1.0
[/CIF]
.
The material structure described by Rb2V2Mn(O3Cl)2 crystallizes in the monoclinic C2 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), one O(4), two equivalent O(5), one Cl(2), one Cl(4), and two equivalent Cl(1) atoms. In the second Rb site, Rb(2) is bonded in a 9-coordinate geometry to one O(2), one O(5), one O(6), two equivalent O(4), one Cl(2), one Cl(4), and two equivalent Cl(3) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form VO4 tetrahedra that share  a cornercorner with one Mn(1)Cl4O2 octahedra and corners with two equivalent V(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 27°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(5), and one O(6) atom to form VO4 tetrahedra that share  a cornercorner with one Mn(2)Cl4O2 octahedra and corners with two equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 29°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(3), one Cl(1), one Cl(3), and two equivalent Cl(2) atoms to form distorted MnCl4O2 octahedra that share corners with two equivalent Mn(1)Cl4O2 octahedra, corners with two equivalent Mn(2)Cl4O2 octahedra, and corners with two equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the second Mn site, Mn(2) is bonded to two equivalent O(6), one Cl(1), one Cl(3), and two equivalent Cl(4) atoms to form distorted MnCl4O2 octahedra that share corners with two equivalent Mn(1)Cl4O2 octahedra, corners with two equivalent Mn(2)Cl4O2 octahedra, and corners with two equivalent V(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are six inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one Rb(2), two equivalent Rb(1), and one V(2) atom. In the second O site, O(6) is bonded in a bent 150 degrees geometry to one Rb(2), one V(2), and one Mn(2) atom. In the third O site, O(1) is bonded in a 2-coordinate geometry to one Rb(1), one V(1), and one V(2) atom. In the fourth O site, O(2) is bonded in a 2-coordinate geometry to one Rb(2), one V(1), and one V(2) atom. In the fifth O site, O(3) is bonded in a bent 150 degrees geometry to one Rb(1), one V(1), and one Mn(1) atom. In the sixth O site, O(4) is bonded in a single-bond geometry to one Rb(1), two equivalent Rb(2), and one V(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 6-coordinate geometry to four equivalent Rb(1), one Mn(1), and one Mn(2) atom. In the second Cl site, Cl(2) is bonded to two equivalent Rb(1), two equivalent Rb(2), and two equivalent Mn(1) atoms to form a mixture of distorted corner and edge-sharing ClRb4Mn2 octahedra. The corner-sharing octahedral tilt angles are 4°. In the third Cl site, Cl(3) is bonded in a 6-coordinate geometry to four equivalent Rb(2), one Mn(1), and one Mn(2) atom. In the fourth Cl site, Cl(4) is bonded to two equivalent Rb(1), two equivalent Rb(2), and two equivalent Mn(2) atoms to form a mixture of distorted corner and edge-sharing ClRb4Mn2 octahedra. The corner-sharing octahedral tilt angles are 4°. is represented by the CIF file [CIF]
data_Rb2MnV2(ClO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.976
_cell_length_b   5.613
_cell_length_c   10.908
_cell_angle_alpha   104.646
_cell_angle_beta   59.794
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   555.359
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.200  0.370  0.743  1.0
  Rb  Rb1  1  0.446  0.630  0.252  1.0
  Rb  Rb2  1  0.698  0.370  0.748  1.0
  Rb  Rb3  1  0.943  0.630  0.257  1.0
  Mn  Mn4  1  0.309  0.000  0.000  1.0
  Mn  Mn5  1  0.810  0.000  0.000  1.0
  V  V6  1  0.132  0.222  0.402  1.0
  V  V7  1  0.032  0.818  0.600  1.0
  V  V8  1  0.633  0.182  0.400  1.0
  V  V9  1  0.533  0.778  0.598  1.0
  Cl  Cl10  1  0.040  0.000  0.000  1.0
  Cl  Cl11  1  0.301  0.500  0.000  1.0
  Cl  Cl12  1  0.539  0.000  0.000  1.0
  Cl  Cl13  1  0.801  0.500  0.000  1.0
  O  O14  1  0.037  0.534  0.472  1.0
  O  O15  1  0.009  0.063  0.530  1.0
  O  O16  1  0.174  0.093  0.224  1.0
  O  O17  1  0.277  0.228  0.411  1.0
  O  O18  1  0.187  0.812  0.592  1.0
  O  O19  1  0.509  0.466  0.528  1.0
  O  O20  1  0.539  0.937  0.470  1.0
  O  O21  1  0.398  0.907  0.776  1.0
  O  O22  1  0.673  0.138  0.222  1.0
  O  O23  1  0.778  0.188  0.408  1.0
  O  O24  1  0.688  0.772  0.589  1.0
  O  O25  1  0.896  0.862  0.778  1.0
[/CIF]
.