The compound described by Sn2CPO6 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(4) atom. In the second Sn site, Sn(2) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(5), and one O(6) atom. C(1) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(5) atom. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Sn(1), one Sn(2), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Sn(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Sn(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Sn(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Sn(2) and one C(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Sn(2) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sn2PCO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.033
_cell_length_b   4.828
_cell_length_c   22.746
_cell_angle_alpha   85.117
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   660.118
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.150  0.751  0.684  1.0
  Sn  Sn1  1  0.129  0.238  0.930  1.0
  Sn  Sn2  1  0.871  0.762  0.070  1.0
  Sn  Sn3  1  0.650  0.249  0.816  1.0
  Sn  Sn4  1  0.850  0.249  0.316  1.0
  Sn  Sn5  1  0.350  0.751  0.184  1.0
  Sn  Sn6  1  0.629  0.762  0.570  1.0
  Sn  Sn7  1  0.371  0.238  0.430  1.0
  P  P8  1  0.736  0.227  0.173  1.0
  P  P9  1  0.236  0.773  0.327  1.0
  P  P10  1  0.264  0.773  0.827  1.0
  P  P11  1  0.764  0.227  0.673  1.0
  C  C12  1  0.916  0.438  0.479  1.0
  C  C13  1  0.084  0.562  0.521  1.0
  C  C14  1  0.416  0.562  0.021  1.0
  C  C15  1  0.584  0.438  0.979  1.0
  O  O16  1  0.192  0.089  0.337  1.0
  O  O17  1  0.593  0.255  0.722  1.0
  O  O18  1  0.011  0.730  0.557  1.0
  O  O19  1  0.489  0.730  0.057  1.0
  O  O20  1  0.994  0.347  0.687  1.0
  O  O21  1  0.407  0.745  0.278  1.0
  O  O22  1  0.716  0.511  0.483  1.0
  O  O23  1  0.093  0.745  0.778  1.0
  O  O24  1  0.989  0.270  0.443  1.0
  O  O25  1  0.665  0.357  0.613  1.0
  O  O26  1  0.835  0.357  0.113  1.0
  O  O27  1  0.284  0.489  0.517  1.0
  O  O28  1  0.808  0.911  0.663  1.0
  O  O29  1  0.308  0.089  0.837  1.0
  O  O30  1  0.506  0.347  0.187  1.0
  O  O31  1  0.494  0.653  0.813  1.0
  O  O32  1  0.006  0.653  0.313  1.0
  O  O33  1  0.907  0.255  0.222  1.0
  O  O34  1  0.511  0.270  0.943  1.0
  O  O35  1  0.692  0.911  0.163  1.0
  O  O36  1  0.784  0.511  0.983  1.0
  O  O37  1  0.165  0.643  0.887  1.0
  O  O38  1  0.335  0.643  0.387  1.0
  O  O39  1  0.216  0.489  0.017  1.0
[/CIF]
.
The compound described by Sn2CPO6 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(4) atom. In the second Sn site, Sn(2) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(5), and one O(6) atom. C(1) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(5) atom. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Sn(1), one Sn(2), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Sn(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Sn(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Sn(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Sn(2) and one C(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Sn(2) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sn2PCO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.033
_cell_length_b   4.828
_cell_length_c   22.746
_cell_angle_alpha   85.117
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   660.118
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.150  0.751  0.684  1.0
  Sn  Sn1  1  0.129  0.238  0.930  1.0
  Sn  Sn2  1  0.871  0.762  0.070  1.0
  Sn  Sn3  1  0.650  0.249  0.816  1.0
  Sn  Sn4  1  0.850  0.249  0.316  1.0
  Sn  Sn5  1  0.350  0.751  0.184  1.0
  Sn  Sn6  1  0.629  0.762  0.570  1.0
  Sn  Sn7  1  0.371  0.238  0.430  1.0
  P  P8  1  0.736  0.227  0.173  1.0
  P  P9  1  0.236  0.773  0.327  1.0
  P  P10  1  0.264  0.773  0.827  1.0
  P  P11  1  0.764  0.227  0.673  1.0
  C  C12  1  0.916  0.438  0.479  1.0
  C  C13  1  0.084  0.562  0.521  1.0
  C  C14  1  0.416  0.562  0.021  1.0
  C  C15  1  0.584  0.438  0.979  1.0
  O  O16  1  0.192  0.089  0.337  1.0
  O  O17  1  0.593  0.255  0.722  1.0
  O  O18  1  0.011  0.730  0.557  1.0
  O  O19  1  0.489  0.730  0.057  1.0
  O  O20  1  0.994  0.347  0.687  1.0
  O  O21  1  0.407  0.745  0.278  1.0
  O  O22  1  0.716  0.511  0.483  1.0
  O  O23  1  0.093  0.745  0.778  1.0
  O  O24  1  0.989  0.270  0.443  1.0
  O  O25  1  0.665  0.357  0.613  1.0
  O  O26  1  0.835  0.357  0.113  1.0
  O  O27  1  0.284  0.489  0.517  1.0
  O  O28  1  0.808  0.911  0.663  1.0
  O  O29  1  0.308  0.089  0.837  1.0
  O  O30  1  0.506  0.347  0.187  1.0
  O  O31  1  0.494  0.653  0.813  1.0
  O  O32  1  0.006  0.653  0.313  1.0
  O  O33  1  0.907  0.255  0.222  1.0
  O  O34  1  0.511  0.270  0.943  1.0
  O  O35  1  0.692  0.911  0.163  1.0
  O  O36  1  0.784  0.511  0.983  1.0
  O  O37  1  0.165  0.643  0.887  1.0
  O  O38  1  0.335  0.643  0.387  1.0
  O  O39  1  0.216  0.489  0.017  1.0
[/CIF]
.