The crystal structure described by BaEuLaSbO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P-1 space group. Ba(1) is bonded in a 10-coordinate geometry to one O(1), one O(4), two equivalent O(2), two equivalent O(3), two equivalent O(5), and two equivalent O(6) atoms. Eu(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(5), one O(6), two equivalent O(1), and two equivalent O(4) atoms. There are two inequivalent La sites. In the first La site, La(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form LaO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-28°. In the second La site, La(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form LaO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-31°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form SbO6 octahedra that share corners with two equivalent La(2)O6 octahedra and corners with four equivalent La(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-31°. In the second Sb site, Sb(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form SbO6 octahedra that share corners with two equivalent La(1)O6 octahedra and corners with four equivalent La(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-30°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Ba(1), two equivalent Eu(1), one La(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Eu(1), one La(2), and one Sb(2) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Eu(1), one La(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Ba(1), two equivalent Eu(1), one La(2), and one Sb(2) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Eu(1), one La(2), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a distorted see-saw-like geometry to two equivalent Ba(1), one Eu(1), one La(1), and one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BaLaEuSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.067
_cell_length_b   6.117
_cell_length_c   8.623
_cell_angle_alpha   90.392
_cell_angle_beta   90.465
_cell_angle_gamma   90.057
_symmetry_Int_Tables_number   1
_cell_volume   320.003
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.506  0.527  0.250  1.0
  Ba  Ba1  1  0.494  0.473  0.750  1.0
  La  La2  1  0.000  0.500  0.000  1.0
  La  La3  1  0.500  0.000  0.500  1.0
  Eu  Eu4  1  0.991  0.037  0.253  1.0
  Eu  Eu5  1  0.009  0.963  0.747  1.0
  Sb  Sb6  1  0.500  0.000  0.000  1.0
  Sb  Sb7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.237  0.194  0.947  1.0
  O  O9  1  0.266  0.697  0.528  1.0
  O  O10  1  0.763  0.806  0.053  1.0
  O  O11  1  0.734  0.303  0.472  1.0
  O  O12  1  0.303  0.738  0.959  1.0
  O  O13  1  0.185  0.228  0.549  1.0
  O  O14  1  0.697  0.262  0.041  1.0
  O  O15  1  0.815  0.772  0.451  1.0
  O  O16  1  0.403  0.995  0.228  1.0
  O  O17  1  0.063  0.454  0.271  1.0
  O  O18  1  0.597  0.005  0.772  1.0
  O  O19  1  0.937  0.546  0.729  1.0
[/CIF]
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The crystal structure described by BaEuLaSbO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P-1 space group. Ba(1) is bonded in a 10-coordinate geometry to one O(1), one O(4), two equivalent O(2), two equivalent O(3), two equivalent O(5), and two equivalent O(6) atoms. Eu(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(5), one O(6), two equivalent O(1), and two equivalent O(4) atoms. There are two inequivalent La sites. In the first La site, La(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form LaO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-28°. In the second La site, La(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form LaO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-31°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form SbO6 octahedra that share corners with two equivalent La(2)O6 octahedra and corners with four equivalent La(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 24-31°. In the second Sb site, Sb(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form SbO6 octahedra that share corners with two equivalent La(1)O6 octahedra and corners with four equivalent La(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-30°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Ba(1), two equivalent Eu(1), one La(1), and one Sb(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Eu(1), one La(2), and one Sb(2) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Eu(1), one La(1), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Ba(1), two equivalent Eu(1), one La(2), and one Sb(2) atom. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Eu(1), one La(2), and one Sb(1) atom. In the sixth O site, O(6) is bonded in a distorted see-saw-like geometry to two equivalent Ba(1), one Eu(1), one La(1), and one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BaLaEuSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.067
_cell_length_b   6.117
_cell_length_c   8.623
_cell_angle_alpha   90.392
_cell_angle_beta   90.465
_cell_angle_gamma   90.057
_symmetry_Int_Tables_number   1
_cell_volume   320.003
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.506  0.527  0.250  1.0
  Ba  Ba1  1  0.494  0.473  0.750  1.0
  La  La2  1  0.000  0.500  0.000  1.0
  La  La3  1  0.500  0.000  0.500  1.0
  Eu  Eu4  1  0.991  0.037  0.253  1.0
  Eu  Eu5  1  0.009  0.963  0.747  1.0
  Sb  Sb6  1  0.500  0.000  0.000  1.0
  Sb  Sb7  1  0.000  0.500  0.500  1.0
  O  O8  1  0.237  0.194  0.947  1.0
  O  O9  1  0.266  0.697  0.528  1.0
  O  O10  1  0.763  0.806  0.053  1.0
  O  O11  1  0.734  0.303  0.472  1.0
  O  O12  1  0.303  0.738  0.959  1.0
  O  O13  1  0.185  0.228  0.549  1.0
  O  O14  1  0.697  0.262  0.041  1.0
  O  O15  1  0.815  0.772  0.451  1.0
  O  O16  1  0.403  0.995  0.228  1.0
  O  O17  1  0.063  0.454  0.271  1.0
  O  O18  1  0.597  0.005  0.772  1.0
  O  O19  1  0.937  0.546  0.729  1.0
[/CIF]
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