The crystal structure described by CoN4O3Cl2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CoN4O3Cl2 cluster. Co(1) is bonded to one N(1), one N(2), one N(4), and two equivalent O(1) atoms to form edge-sharing CoN3O2 trigonal bipyramids. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one Cl(2) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Co(1), one N(3), and one Cl(1) atom. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Co(1) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent Co(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(4) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one N(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_CoN4Cl2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.528
_cell_length_b   7.285
_cell_length_c   8.734
_cell_angle_alpha   81.883
_cell_angle_beta   83.904
_cell_angle_gamma   73.350
_symmetry_Int_Tables_number   1
_cell_volume   393.006
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.955  0.991  0.854  1.0
  Co  Co1  1  0.045  0.009  0.146  1.0
  N  N2  1  0.706  0.122  0.807  1.0
  N  N3  1  0.294  0.878  0.193  1.0
  N  N4  1  0.170  0.022  0.686  1.0
  N  N5  1  0.830  0.978  0.314  1.0
  N  N6  1  0.211  0.175  0.604  1.0
  N  N7  1  0.789  0.825  0.396  1.0
  N  N8  1  0.906  0.786  0.741  1.0
  N  N9  1  0.094  0.214  0.259  1.0
  Cl  Cl10  1  0.678  0.189  0.384  1.0
  Cl  Cl11  1  0.322  0.811  0.616  1.0
  Cl  Cl12  1  0.555  0.311  0.888  1.0
  Cl  Cl13  1  0.445  0.689  0.112  1.0
  O  O14  1  0.021  0.158  0.972  1.0
  O  O15  1  0.979  0.842  0.028  1.0
  O  O16  1  0.106  0.335  0.640  1.0
  O  O17  1  0.894  0.665  0.360  1.0
  O  O18  1  0.156  0.345  0.207  1.0
  O  O19  1  0.844  0.655  0.793  1.0
[/CIF]
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The crystal structure described by CoN4O3Cl2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CoN4O3Cl2 cluster. Co(1) is bonded to one N(1), one N(2), one N(4), and two equivalent O(1) atoms to form edge-sharing CoN3O2 trigonal bipyramids. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one Cl(2) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Co(1), one N(3), and one Cl(1) atom. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Co(1) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent Co(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(4) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one N(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the CIF card [CIF]
data_CoN4Cl2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.528
_cell_length_b   7.285
_cell_length_c   8.734
_cell_angle_alpha   81.883
_cell_angle_beta   83.904
_cell_angle_gamma   73.350
_symmetry_Int_Tables_number   1
_cell_volume   393.006
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.955  0.991  0.854  1.0
  Co  Co1  1  0.045  0.009  0.146  1.0
  N  N2  1  0.706  0.122  0.807  1.0
  N  N3  1  0.294  0.878  0.193  1.0
  N  N4  1  0.170  0.022  0.686  1.0
  N  N5  1  0.830  0.978  0.314  1.0
  N  N6  1  0.211  0.175  0.604  1.0
  N  N7  1  0.789  0.825  0.396  1.0
  N  N8  1  0.906  0.786  0.741  1.0
  N  N9  1  0.094  0.214  0.259  1.0
  Cl  Cl10  1  0.678  0.189  0.384  1.0
  Cl  Cl11  1  0.322  0.811  0.616  1.0
  Cl  Cl12  1  0.555  0.311  0.888  1.0
  Cl  Cl13  1  0.445  0.689  0.112  1.0
  O  O14  1  0.021  0.158  0.972  1.0
  O  O15  1  0.979  0.842  0.028  1.0
  O  O16  1  0.106  0.335  0.640  1.0
  O  O17  1  0.894  0.665  0.360  1.0
  O  O18  1  0.156  0.345  0.207  1.0
  O  O19  1  0.844  0.655  0.793  1.0
[/CIF]
.