The compound described by P2NHF4 is Ammonia-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four imidodiphosphorous tetrafluoride molecules. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one F(1), and one F(3) atom. In the second P site, P(2) is bonded in a distorted T-shaped geometry to one N(1), one F(2), and one F(4) atom. N(1) is bonded in a trigonal planar geometry to one P(1), one P(2), and one H(1) atom. H(1) is bonded in a single-bond geometry to one N(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one P(2) atom. is represented by the CIF file [CIF]
data_P2HNF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.815
_cell_length_b   8.895
_cell_length_c   14.024
_cell_angle_alpha   59.378
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   516.876
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.087  0.303  0.849  1.0
  P  P1  1  0.141  0.717  0.340  1.0
  P  P2  1  0.587  0.697  0.651  1.0
  P  P3  1  0.359  0.717  0.840  1.0
  P  P4  1  0.641  0.283  0.160  1.0
  P  P5  1  0.413  0.303  0.349  1.0
  P  P6  1  0.859  0.283  0.660  1.0
  P  P7  1  0.913  0.697  0.151  1.0
  H  H8  1  0.196  0.918  0.147  1.0
  H  H9  1  0.696  0.082  0.353  1.0
  H  H10  1  0.304  0.918  0.647  1.0
  H  H11  1  0.804  0.082  0.853  1.0
  N  N12  1  0.102  0.802  0.201  1.0
  N  N13  1  0.398  0.802  0.701  1.0
  N  N14  1  0.602  0.198  0.299  1.0
  N  N15  1  0.898  0.198  0.799  1.0
  F  F16  1  0.250  0.137  0.947  1.0
  F  F17  1  0.475  0.738  0.343  1.0
  F  F18  1  0.861  0.315  0.930  1.0
  F  F19  1  0.361  0.685  0.570  1.0
  F  F20  1  0.069  0.889  0.346  1.0
  F  F21  1  0.569  0.111  0.154  1.0
  F  F22  1  0.750  0.863  0.553  1.0
  F  F23  1  0.975  0.262  0.157  1.0
  F  F24  1  0.025  0.738  0.843  1.0
  F  F25  1  0.250  0.137  0.447  1.0
  F  F26  1  0.431  0.889  0.846  1.0
  F  F27  1  0.931  0.111  0.654  1.0
  F  F28  1  0.639  0.315  0.430  1.0
  F  F29  1  0.139  0.685  0.070  1.0
  F  F30  1  0.525  0.262  0.657  1.0
  F  F31  1  0.750  0.863  0.053  1.0
[/CIF]
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The compound described by P2NHF4 is Ammonia-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four imidodiphosphorous tetrafluoride molecules. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one F(1), and one F(3) atom. In the second P site, P(2) is bonded in a distorted T-shaped geometry to one N(1), one F(2), and one F(4) atom. N(1) is bonded in a trigonal planar geometry to one P(1), one P(2), and one H(1) atom. H(1) is bonded in a single-bond geometry to one N(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one P(2) atom. is represented by the CIF file [CIF]
data_P2HNF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.815
_cell_length_b   8.895
_cell_length_c   14.024
_cell_angle_alpha   59.378
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   516.876
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.087  0.303  0.849  1.0
  P  P1  1  0.141  0.717  0.340  1.0
  P  P2  1  0.587  0.697  0.651  1.0
  P  P3  1  0.359  0.717  0.840  1.0
  P  P4  1  0.641  0.283  0.160  1.0
  P  P5  1  0.413  0.303  0.349  1.0
  P  P6  1  0.859  0.283  0.660  1.0
  P  P7  1  0.913  0.697  0.151  1.0
  H  H8  1  0.196  0.918  0.147  1.0
  H  H9  1  0.696  0.082  0.353  1.0
  H  H10  1  0.304  0.918  0.647  1.0
  H  H11  1  0.804  0.082  0.853  1.0
  N  N12  1  0.102  0.802  0.201  1.0
  N  N13  1  0.398  0.802  0.701  1.0
  N  N14  1  0.602  0.198  0.299  1.0
  N  N15  1  0.898  0.198  0.799  1.0
  F  F16  1  0.250  0.137  0.947  1.0
  F  F17  1  0.475  0.738  0.343  1.0
  F  F18  1  0.861  0.315  0.930  1.0
  F  F19  1  0.361  0.685  0.570  1.0
  F  F20  1  0.069  0.889  0.346  1.0
  F  F21  1  0.569  0.111  0.154  1.0
  F  F22  1  0.750  0.863  0.553  1.0
  F  F23  1  0.975  0.262  0.157  1.0
  F  F24  1  0.025  0.738  0.843  1.0
  F  F25  1  0.250  0.137  0.447  1.0
  F  F26  1  0.431  0.889  0.846  1.0
  F  F27  1  0.931  0.111  0.654  1.0
  F  F28  1  0.639  0.315  0.430  1.0
  F  F29  1  0.139  0.685  0.070  1.0
  F  F30  1  0.525  0.262  0.657  1.0
  F  F31  1  0.750  0.863  0.053  1.0
[/CIF]
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