The material structure described by Sm2Au is Cotunnite structured and crystallizes in the orthorhombic Pnma space group. There are two inequivalent Sm sites. In the first Sm site, Sm(1) is bonded to four equivalent Au(1) atoms to form a mixture of corner and edge-sharing SmAu4 tetrahedra. In the second Sm site, Sm(2) is bonded in a 3-coordinate geometry to three equivalent Au(1) atoms. Au(1) is bonded in a 7-coordinate geometry to three equivalent Sm(2) and four equivalent Sm(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sm2Au
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.026
_cell_length_b   7.270
_cell_length_c   9.222
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   336.942
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.750  0.152  0.085  1.0
  Sm  Sm1  1  0.750  0.652  0.415  1.0
  Sm  Sm2  1  0.250  0.848  0.915  1.0
  Sm  Sm3  1  0.250  0.348  0.585  1.0
  Sm  Sm4  1  0.750  0.510  0.824  1.0
  Sm  Sm5  1  0.750  0.010  0.676  1.0
  Sm  Sm6  1  0.250  0.490  0.176  1.0
  Sm  Sm7  1  0.250  0.990  0.324  1.0
  Au  Au8  1  0.750  0.743  0.097  1.0
  Au  Au9  1  0.750  0.243  0.403  1.0
  Au  Au10  1  0.250  0.257  0.903  1.0
  Au  Au11  1  0.250  0.757  0.597  1.0
[/CIF]
.
The material structure described by Sm2Au is Cotunnite structured and crystallizes in the orthorhombic Pnma space group. There are two inequivalent Sm sites. In the first Sm site, Sm(1) is bonded to four equivalent Au(1) atoms to form a mixture of corner and edge-sharing SmAu4 tetrahedra. In the second Sm site, Sm(2) is bonded in a 3-coordinate geometry to three equivalent Au(1) atoms. Au(1) is bonded in a 7-coordinate geometry to three equivalent Sm(2) and four equivalent Sm(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sm2Au
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.026
_cell_length_b   7.270
_cell_length_c   9.222
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   336.942
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.750  0.152  0.085  1.0
  Sm  Sm1  1  0.750  0.652  0.415  1.0
  Sm  Sm2  1  0.250  0.848  0.915  1.0
  Sm  Sm3  1  0.250  0.348  0.585  1.0
  Sm  Sm4  1  0.750  0.510  0.824  1.0
  Sm  Sm5  1  0.750  0.010  0.676  1.0
  Sm  Sm6  1  0.250  0.490  0.176  1.0
  Sm  Sm7  1  0.250  0.990  0.324  1.0
  Au  Au8  1  0.750  0.743  0.097  1.0
  Au  Au9  1  0.750  0.243  0.403  1.0
  Au  Au10  1  0.250  0.257  0.903  1.0
  Au  Au11  1  0.250  0.757  0.597  1.0
[/CIF]
.