The material described by KNaPtC4N4H6O3 crystallizes in the monoclinic Cc space group. K(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one N(3), one N(4), one O(2), and one O(3) atom. Na(1) is bonded in a 5-coordinate geometry to one N(1), one N(4), one O(2), and two equivalent O(1) atoms. Pt(1) is bonded in a rectangular see-saw-like geometry to one C(1), one C(2), one C(3), and one C(4) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Pt(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Pt(1) and one N(2) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one Pt(1) and one N(3) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one Pt(1) and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one K(1), one Na(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one K(1) and one C(2) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one K(1) and one C(3) atom. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one K(1), one Na(1), and one C(4) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to two equivalent Na(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one K(1), one Na(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one K(1), one H(5), and one H(6) atom. is represented by the CIF file [CIF]
data_KNaH6PtC4N4O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.487
_cell_length_b   9.487
_cell_length_c   6.533
_cell_angle_alpha   73.158
_cell_angle_beta   73.158
_cell_angle_gamma   93.455
_symmetry_Int_Tables_number   1
_cell_volume   531.991
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.963  0.483  0.483  1.0
  K  K1  1  0.483  0.963  0.983  1.0
  Na  Na2  1  0.359  0.546  0.012  1.0
  Na  Na3  1  0.546  0.359  0.512  1.0
  H  H4  1  0.570  0.351  0.954  1.0
  H  H5  1  0.351  0.570  0.454  1.0
  H  H6  1  0.654  0.512  0.805  1.0
  H  H7  1  0.512  0.654  0.305  1.0
  H  H8  1  0.779  0.586  0.123  1.0
  H  H9  1  0.586  0.779  0.623  1.0
  H  H10  1  0.811  0.428  0.123  1.0
  H  H11  1  0.428  0.811  0.623  1.0
  H  H12  1  0.147  0.600  0.788  1.0
  H  H13  1  0.600  0.147  0.288  1.0
  H  H14  1  0.137  0.429  0.844  1.0
  H  H15  1  0.429  0.137  0.344  1.0
  Pt  Pt16  1  0.996  0.003  0.500  1.0
  Pt  Pt17  1  0.003  0.996  0.000  1.0
  C  C18  1  0.810  0.094  0.541  1.0
  C  C19  1  0.094  0.810  0.041  1.0
  C  C20  1  0.879  0.799  0.639  1.0
  C  C21  1  0.799  0.879  0.139  1.0
  C  C22  1  0.185  0.919  0.465  1.0
  C  C23  1  0.919  0.185  0.965  1.0
  C  C24  1  0.114  0.207  0.352  1.0
  C  C25  1  0.207  0.114  0.852  1.0
  N  N26  1  0.703  0.152  0.565  1.0
  N  N27  1  0.152  0.703  0.065  1.0
  N  N28  1  0.811  0.677  0.715  1.0
  N  N29  1  0.677  0.811  0.215  1.0
  N  N30  1  0.299  0.873  0.447  1.0
  N  N31  1  0.873  0.299  0.947  1.0
  N  N32  1  0.184  0.327  0.261  1.0
  N  N33  1  0.327  0.184  0.761  1.0
  O  O34  1  0.568  0.437  0.829  1.0
  O  O35  1  0.437  0.568  0.329  1.0
  O  O36  1  0.776  0.487  0.226  1.0
  O  O37  1  0.487  0.776  0.726  1.0
  O  O38  1  0.189  0.523  0.728  1.0
  O  O39  1  0.523  0.189  0.228  1.0
[/CIF]
.
The material described by KNaPtC4N4H6O3 crystallizes in the monoclinic Cc space group. K(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one N(3), one N(4), one O(2), and one O(3) atom. Na(1) is bonded in a 5-coordinate geometry to one N(1), one N(4), one O(2), and two equivalent O(1) atoms. Pt(1) is bonded in a rectangular see-saw-like geometry to one C(1), one C(2), one C(3), and one C(4) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Pt(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Pt(1) and one N(2) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one Pt(1) and one N(3) atom. In the fourth C site, C(4) is bonded in a distorted linear geometry to one Pt(1) and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one K(1), one Na(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one K(1) and one C(2) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one K(1) and one C(3) atom. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one K(1), one Na(1), and one C(4) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to two equivalent Na(1), one H(1), and one H(2) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one K(1), one Na(1), one H(3), and one H(4) atom. In the third O site, O(3) is bonded in a water-like geometry to one K(1), one H(5), and one H(6) atom. is represented by the CIF file [CIF]
data_KNaH6PtC4N4O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.487
_cell_length_b   9.487
_cell_length_c   6.533
_cell_angle_alpha   73.158
_cell_angle_beta   73.158
_cell_angle_gamma   93.455
_symmetry_Int_Tables_number   1
_cell_volume   531.991
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.963  0.483  0.483  1.0
  K  K1  1  0.483  0.963  0.983  1.0
  Na  Na2  1  0.359  0.546  0.012  1.0
  Na  Na3  1  0.546  0.359  0.512  1.0
  H  H4  1  0.570  0.351  0.954  1.0
  H  H5  1  0.351  0.570  0.454  1.0
  H  H6  1  0.654  0.512  0.805  1.0
  H  H7  1  0.512  0.654  0.305  1.0
  H  H8  1  0.779  0.586  0.123  1.0
  H  H9  1  0.586  0.779  0.623  1.0
  H  H10  1  0.811  0.428  0.123  1.0
  H  H11  1  0.428  0.811  0.623  1.0
  H  H12  1  0.147  0.600  0.788  1.0
  H  H13  1  0.600  0.147  0.288  1.0
  H  H14  1  0.137  0.429  0.844  1.0
  H  H15  1  0.429  0.137  0.344  1.0
  Pt  Pt16  1  0.996  0.003  0.500  1.0
  Pt  Pt17  1  0.003  0.996  0.000  1.0
  C  C18  1  0.810  0.094  0.541  1.0
  C  C19  1  0.094  0.810  0.041  1.0
  C  C20  1  0.879  0.799  0.639  1.0
  C  C21  1  0.799  0.879  0.139  1.0
  C  C22  1  0.185  0.919  0.465  1.0
  C  C23  1  0.919  0.185  0.965  1.0
  C  C24  1  0.114  0.207  0.352  1.0
  C  C25  1  0.207  0.114  0.852  1.0
  N  N26  1  0.703  0.152  0.565  1.0
  N  N27  1  0.152  0.703  0.065  1.0
  N  N28  1  0.811  0.677  0.715  1.0
  N  N29  1  0.677  0.811  0.215  1.0
  N  N30  1  0.299  0.873  0.447  1.0
  N  N31  1  0.873  0.299  0.947  1.0
  N  N32  1  0.184  0.327  0.261  1.0
  N  N33  1  0.327  0.184  0.761  1.0
  O  O34  1  0.568  0.437  0.829  1.0
  O  O35  1  0.437  0.568  0.329  1.0
  O  O36  1  0.776  0.487  0.226  1.0
  O  O37  1  0.487  0.776  0.726  1.0
  O  O38  1  0.189  0.523  0.728  1.0
  O  O39  1  0.523  0.189  0.228  1.0
[/CIF]
.