The material described by Pd(SeCl3)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Pd(SeCl3)2 clusters. Pd(1) is bonded in a distorted square co-planar geometry to two equivalent Se(1) and two equivalent Cl(3) atoms. Se(1) is bonded in a 3-coordinate geometry to one Pd(1), one Cl(1), and one Cl(2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Pd(1) atom. is represented by the CIF card [CIF]
data_Pd(SeCl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.250
_cell_length_b   8.471
_cell_length_c   9.431
_cell_angle_alpha   116.687
_cell_angle_beta   98.820
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   509.834
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.750  0.831  0.000  1.0
  Pd  Pd1  1  0.250  0.169  0.000  1.0
  Se  Se2  1  0.943  0.723  0.793  1.0
  Se  Se3  1  0.557  0.930  0.207  1.0
  Se  Se4  1  0.057  0.277  0.207  1.0
  Se  Se5  1  0.443  0.070  0.793  1.0
  Cl  Cl6  1  0.967  0.461  0.783  1.0
  Cl  Cl7  1  0.533  0.678  0.217  1.0
  Cl  Cl8  1  0.033  0.539  0.217  1.0
  Cl  Cl9  1  0.467  0.322  0.783  1.0
  Cl  Cl10  1  0.765  0.647  0.563  1.0
  Cl  Cl11  1  0.735  0.084  0.437  1.0
  Cl  Cl12  1  0.545  0.250  0.158  1.0
  Cl  Cl13  1  0.955  0.091  0.842  1.0
  Cl  Cl14  1  0.455  0.750  0.842  1.0
  Cl  Cl15  1  0.045  0.909  0.158  1.0
  Cl  Cl16  1  0.265  0.916  0.563  1.0
  Cl  Cl17  1  0.235  0.353  0.437  1.0
[/CIF]
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The material described by Pd(SeCl3)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Pd(SeCl3)2 clusters. Pd(1) is bonded in a distorted square co-planar geometry to two equivalent Se(1) and two equivalent Cl(3) atoms. Se(1) is bonded in a 3-coordinate geometry to one Pd(1), one Cl(1), and one Cl(2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Se(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Pd(1) atom. is represented by the CIF card [CIF]
data_Pd(SeCl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.250
_cell_length_b   8.471
_cell_length_c   9.431
_cell_angle_alpha   116.687
_cell_angle_beta   98.820
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   509.834
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.750  0.831  0.000  1.0
  Pd  Pd1  1  0.250  0.169  0.000  1.0
  Se  Se2  1  0.943  0.723  0.793  1.0
  Se  Se3  1  0.557  0.930  0.207  1.0
  Se  Se4  1  0.057  0.277  0.207  1.0
  Se  Se5  1  0.443  0.070  0.793  1.0
  Cl  Cl6  1  0.967  0.461  0.783  1.0
  Cl  Cl7  1  0.533  0.678  0.217  1.0
  Cl  Cl8  1  0.033  0.539  0.217  1.0
  Cl  Cl9  1  0.467  0.322  0.783  1.0
  Cl  Cl10  1  0.765  0.647  0.563  1.0
  Cl  Cl11  1  0.735  0.084  0.437  1.0
  Cl  Cl12  1  0.545  0.250  0.158  1.0
  Cl  Cl13  1  0.955  0.091  0.842  1.0
  Cl  Cl14  1  0.455  0.750  0.842  1.0
  Cl  Cl15  1  0.045  0.909  0.158  1.0
  Cl  Cl16  1  0.265  0.916  0.563  1.0
  Cl  Cl17  1  0.235  0.353  0.437  1.0
[/CIF]
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