The structure described by ThV2H4O9 crystallizes in the triclinic P-1 space group. Th(1) is bonded in a 9-coordinate geometry to one O(2), one O(4), one O(5), one O(8), one O(9), two equivalent O(1), and two equivalent O(3) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form corner-sharing VO4 tetrahedra. In the second V site, V(2) is bonded to one O(1), one O(3), one O(6), and one O(7) atom to form corner-sharing VO4 tetrahedra. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(8) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(8) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(2) and one O(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Th(1) and one V(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Th(1), one V(1), and one H(3) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Th(1) and one V(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Th(1) and one V(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Th(1) and one V(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one V(2) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Th(1), one H(1), and one H(2) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Th(1), one H(3), and one H(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ThV2H4O9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.126
_cell_length_b   7.488
_cell_length_c   7.839
_cell_angle_alpha   77.817
_cell_angle_beta   74.598
_cell_angle_gamma   85.049
_symmetry_Int_Tables_number   1
_cell_volume   393.999
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.642  0.755  0.917  1.0
  Th  Th1  1  0.358  0.245  0.083  1.0
  V  V2  1  0.206  0.664  0.746  1.0
  V  V3  1  0.794  0.336  0.254  1.0
  V  V4  1  0.272  0.707  0.293  1.0
  V  V5  1  0.728  0.293  0.707  1.0
  H  H6  1  0.602  0.827  0.509  1.0
  H  H7  1  0.398  0.173  0.491  1.0
  H  H8  1  0.830  0.789  0.487  1.0
  H  H9  1  0.170  0.211  0.513  1.0
  H  H10  1  0.767  0.009  0.134  1.0
  H  H11  1  0.233  0.991  0.866  1.0
  H  H12  1  0.905  0.824  0.157  1.0
  H  H13  1  0.095  0.176  0.843  1.0
  O  O14  1  0.383  0.547  0.158  1.0
  O  O15  1  0.617  0.453  0.842  1.0
  O  O16  1  0.343  0.804  0.814  1.0
  O  O17  1  0.657  0.196  0.186  1.0
  O  O18  1  0.393  0.904  0.159  1.0
  O  O19  1  0.607  0.096  0.841  1.0
  O  O20  1  0.971  0.749  0.765  1.0
  O  O21  1  0.029  0.251  0.235  1.0
  O  O22  1  0.210  0.455  0.881  1.0
  O  O23  1  0.790  0.545  0.119  1.0
  O  O24  1  0.327  0.658  0.510  1.0
  O  O25  1  0.673  0.342  0.490  1.0
  O  O26  1  0.032  0.729  0.318  1.0
  O  O27  1  0.968  0.271  0.682  1.0
  O  O28  1  0.706  0.826  0.569  1.0
  O  O29  1  0.294  0.174  0.431  1.0
  O  O30  1  0.811  0.892  0.090  1.0
  O  O31  1  0.189  0.108  0.910  1.0
[/CIF]
.
The structure described by ThV2H4O9 crystallizes in the triclinic P-1 space group. Th(1) is bonded in a 9-coordinate geometry to one O(2), one O(4), one O(5), one O(8), one O(9), two equivalent O(1), and two equivalent O(3) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(4), one O(5), and one O(6) atom to form corner-sharing VO4 tetrahedra. In the second V site, V(2) is bonded to one O(1), one O(3), one O(6), and one O(7) atom to form corner-sharing VO4 tetrahedra. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(8) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(8) atom. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(2) and one O(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to two equivalent Th(1) and one V(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Th(1), one V(1), and one H(3) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Th(1) and one V(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Th(1) and one V(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Th(1) and one V(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one V(1) and one V(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one V(2) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Th(1), one H(1), and one H(2) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Th(1), one H(3), and one H(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ThV2H4O9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.126
_cell_length_b   7.488
_cell_length_c   7.839
_cell_angle_alpha   77.817
_cell_angle_beta   74.598
_cell_angle_gamma   85.049
_symmetry_Int_Tables_number   1
_cell_volume   393.999
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.642  0.755  0.917  1.0
  Th  Th1  1  0.358  0.245  0.083  1.0
  V  V2  1  0.206  0.664  0.746  1.0
  V  V3  1  0.794  0.336  0.254  1.0
  V  V4  1  0.272  0.707  0.293  1.0
  V  V5  1  0.728  0.293  0.707  1.0
  H  H6  1  0.602  0.827  0.509  1.0
  H  H7  1  0.398  0.173  0.491  1.0
  H  H8  1  0.830  0.789  0.487  1.0
  H  H9  1  0.170  0.211  0.513  1.0
  H  H10  1  0.767  0.009  0.134  1.0
  H  H11  1  0.233  0.991  0.866  1.0
  H  H12  1  0.905  0.824  0.157  1.0
  H  H13  1  0.095  0.176  0.843  1.0
  O  O14  1  0.383  0.547  0.158  1.0
  O  O15  1  0.617  0.453  0.842  1.0
  O  O16  1  0.343  0.804  0.814  1.0
  O  O17  1  0.657  0.196  0.186  1.0
  O  O18  1  0.393  0.904  0.159  1.0
  O  O19  1  0.607  0.096  0.841  1.0
  O  O20  1  0.971  0.749  0.765  1.0
  O  O21  1  0.029  0.251  0.235  1.0
  O  O22  1  0.210  0.455  0.881  1.0
  O  O23  1  0.790  0.545  0.119  1.0
  O  O24  1  0.327  0.658  0.510  1.0
  O  O25  1  0.673  0.342  0.490  1.0
  O  O26  1  0.032  0.729  0.318  1.0
  O  O27  1  0.968  0.271  0.682  1.0
  O  O28  1  0.706  0.826  0.569  1.0
  O  O29  1  0.294  0.174  0.431  1.0
  O  O30  1  0.811  0.892  0.090  1.0
  O  O31  1  0.189  0.108  0.910  1.0
[/CIF]
.