The material structure described by RbCu3P3(O4F3)2 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(4), four equivalent O(2), and two equivalent F(1) atoms. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(3), one O(4), and one F(2) atom to form distorted CuO3F tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra and corners with two equivalent P(1)O2F2 tetrahedra. In the second Cu site, Cu(2) is bonded in a distorted square co-planar geometry to two equivalent O(3) and two equivalent F(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(3), one O(4), one F(1), and one F(3) atom to form PO2F2 tetrahedra that share corners with two equivalent Cu(1)O3F tetrahedra. In the second P site, P(2) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form PO4 tetrahedra that share corners with two equivalent Cu(1)O3F tetrahedra. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one P(2) atom. In the second O site, O(3) is bonded in a distorted trigonal planar geometry to one Cu(1), one Cu(2), and one P(1) atom. In the third O site, O(4) is bonded in a 2-coordinate geometry to one Rb(1), one Cu(1), and one P(1) atom. In the fourth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Cu(1), and one P(2) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a bent 150 degrees geometry to one Cu(1) and one Cu(2) atom. In the second F site, F(3) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Rb(1) and one P(1) atom. is represented by the CIF card [CIF]
data_RbCu3P3(O4F3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.316
_cell_length_b   11.316
_cell_length_c   7.686
_cell_angle_alpha   80.393
_cell_angle_beta   80.393
_cell_angle_gamma   40.401
_symmetry_Int_Tables_number   1
_cell_volume   627.712
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.153  0.847  0.750  1.0
  Rb  Rb1  1  0.847  0.153  0.250  1.0
  Cu  Cu2  1  0.335  0.387  0.778  1.0
  Cu  Cu3  1  0.613  0.665  0.722  1.0
  Cu  Cu4  1  0.665  0.613  0.222  1.0
  Cu  Cu5  1  0.387  0.335  0.278  1.0
  Cu  Cu6  1  0.000  0.500  0.500  1.0
  Cu  Cu7  1  0.500  0.000  0.000  1.0
  P  P8  1  0.018  0.648  0.097  1.0
  P  P9  1  0.352  0.982  0.403  1.0
  P  P10  1  0.982  0.352  0.903  1.0
  P  P11  1  0.648  0.018  0.597  1.0
  P  P12  1  0.656  0.344  0.750  1.0
  P  P13  1  0.344  0.656  0.250  1.0
  O  O14  1  0.589  0.518  0.798  1.0
  O  O15  1  0.482  0.411  0.702  1.0
  O  O16  1  0.411  0.482  0.202  1.0
  O  O17  1  0.518  0.589  0.298  1.0
  O  O18  1  0.793  0.259  0.590  1.0
  O  O19  1  0.741  0.207  0.910  1.0
  O  O20  1  0.207  0.741  0.410  1.0
  O  O21  1  0.259  0.793  0.090  1.0
  O  O22  1  0.517  0.102  0.759  1.0
  O  O23  1  0.898  0.483  0.741  1.0
  O  O24  1  0.483  0.898  0.241  1.0
  O  O25  1  0.102  0.517  0.259  1.0
  O  O26  1  0.127  0.598  0.928  1.0
  O  O27  1  0.402  0.873  0.572  1.0
  O  O28  1  0.873  0.402  0.072  1.0
  O  O29  1  0.598  0.127  0.428  1.0
  F  F30  1  0.917  0.837  0.145  1.0
  F  F31  1  0.163  0.083  0.355  1.0
  F  F32  1  0.083  0.163  0.855  1.0
  F  F33  1  0.837  0.917  0.645  1.0
  F  F34  1  0.181  0.448  0.597  1.0
  F  F35  1  0.552  0.819  0.903  1.0
  F  F36  1  0.819  0.552  0.403  1.0
  F  F37  1  0.448  0.181  0.097  1.0
  F  F38  1  0.155  0.296  0.935  1.0
  F  F39  1  0.704  0.845  0.565  1.0
  F  F40  1  0.845  0.704  0.065  1.0
  F  F41  1  0.296  0.155  0.435  1.0
[/CIF]
.
The material structure described by RbCu3P3(O4F3)2 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(4), four equivalent O(2), and two equivalent F(1) atoms. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(1), one O(3), one O(4), and one F(2) atom to form distorted CuO3F tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra and corners with two equivalent P(1)O2F2 tetrahedra. In the second Cu site, Cu(2) is bonded in a distorted square co-planar geometry to two equivalent O(3) and two equivalent F(2) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(3), one O(4), one F(1), and one F(3) atom to form PO2F2 tetrahedra that share corners with two equivalent Cu(1)O3F tetrahedra. In the second P site, P(2) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form PO4 tetrahedra that share corners with two equivalent Cu(1)O3F tetrahedra. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one P(2) atom. In the second O site, O(3) is bonded in a distorted trigonal planar geometry to one Cu(1), one Cu(2), and one P(1) atom. In the third O site, O(4) is bonded in a 2-coordinate geometry to one Rb(1), one Cu(1), and one P(1) atom. In the fourth O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one Cu(1), and one P(2) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a bent 150 degrees geometry to one Cu(1) and one Cu(2) atom. In the second F site, F(3) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Rb(1) and one P(1) atom. is represented by the CIF card [CIF]
data_RbCu3P3(O4F3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.316
_cell_length_b   11.316
_cell_length_c   7.686
_cell_angle_alpha   80.393
_cell_angle_beta   80.393
_cell_angle_gamma   40.401
_symmetry_Int_Tables_number   1
_cell_volume   627.712
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.153  0.847  0.750  1.0
  Rb  Rb1  1  0.847  0.153  0.250  1.0
  Cu  Cu2  1  0.335  0.387  0.778  1.0
  Cu  Cu3  1  0.613  0.665  0.722  1.0
  Cu  Cu4  1  0.665  0.613  0.222  1.0
  Cu  Cu5  1  0.387  0.335  0.278  1.0
  Cu  Cu6  1  0.000  0.500  0.500  1.0
  Cu  Cu7  1  0.500  0.000  0.000  1.0
  P  P8  1  0.018  0.648  0.097  1.0
  P  P9  1  0.352  0.982  0.403  1.0
  P  P10  1  0.982  0.352  0.903  1.0
  P  P11  1  0.648  0.018  0.597  1.0
  P  P12  1  0.656  0.344  0.750  1.0
  P  P13  1  0.344  0.656  0.250  1.0
  O  O14  1  0.589  0.518  0.798  1.0
  O  O15  1  0.482  0.411  0.702  1.0
  O  O16  1  0.411  0.482  0.202  1.0
  O  O17  1  0.518  0.589  0.298  1.0
  O  O18  1  0.793  0.259  0.590  1.0
  O  O19  1  0.741  0.207  0.910  1.0
  O  O20  1  0.207  0.741  0.410  1.0
  O  O21  1  0.259  0.793  0.090  1.0
  O  O22  1  0.517  0.102  0.759  1.0
  O  O23  1  0.898  0.483  0.741  1.0
  O  O24  1  0.483  0.898  0.241  1.0
  O  O25  1  0.102  0.517  0.259  1.0
  O  O26  1  0.127  0.598  0.928  1.0
  O  O27  1  0.402  0.873  0.572  1.0
  O  O28  1  0.873  0.402  0.072  1.0
  O  O29  1  0.598  0.127  0.428  1.0
  F  F30  1  0.917  0.837  0.145  1.0
  F  F31  1  0.163  0.083  0.355  1.0
  F  F32  1  0.083  0.163  0.855  1.0
  F  F33  1  0.837  0.917  0.645  1.0
  F  F34  1  0.181  0.448  0.597  1.0
  F  F35  1  0.552  0.819  0.903  1.0
  F  F36  1  0.819  0.552  0.403  1.0
  F  F37  1  0.448  0.181  0.097  1.0
  F  F38  1  0.155  0.296  0.935  1.0
  F  F39  1  0.704  0.845  0.565  1.0
  F  F40  1  0.845  0.704  0.065  1.0
  F  F41  1  0.296  0.155  0.435  1.0
[/CIF]
.