The material structure described by MnCo2TeO6 is Ilmenite-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(10), one O(3), one O(6), one O(7), and one O(9) atom to form distorted MnO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Mn(2)O6 pentagonal pyramids, corners with two equivalent Co(1)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Co(3)O6 pentagonal pyramid, and  an edgeedge with one Co(4)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 37-43°. In the second Mn site, Mn(2) is bonded to one O(1), one O(11), one O(2), one O(4), one O(7), and one O(8) atom to form distorted MnO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Mn(1)O6 pentagonal pyramids, corners with two equivalent Co(1)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Co(4)O6 pentagonal pyramid, and edges with two equivalent Co(3)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 38-43°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(12), one O(2), one O(3), one O(5), one O(8), and one O(9) atom to form distorted CoO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Mn(1)O6 pentagonal pyramids, corners with two equivalent Mn(2)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Co(3)O6 pentagonal pyramid, and edges with two equivalent Co(4)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 37-40°. In the second Co site, Co(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(3), one O(4), one O(6), and one O(7) atom. In the third Co site, Co(3) is bonded to one O(1), one O(10), one O(11), one O(4), one O(5), and one O(8) atom to form distorted CoO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Co(4)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Mn(1)O6 pentagonal pyramid,  an edgeedge with one Co(1)O6 pentagonal pyramid, and edges with two equivalent Mn(2)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 35-43°. In the fourth Co site, Co(4) is bonded to one O(11), one O(12), one O(2), one O(5), one O(6), and one O(9) atom to form distorted CoO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Co(3)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Mn(1)O6 pentagonal pyramid,  an edgeedge with one Mn(2)O6 pentagonal pyramid, and edges with two equivalent Co(1)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 37-43°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(10), one O(11), one O(12), one O(7), one O(8), and one O(9) atom to form TeO6 octahedra that share  a cornercorner with one Mn(1)O6 pentagonal pyramid,  a cornercorner with one Mn(2)O6 pentagonal pyramid,  a cornercorner with one Co(1)O6 pentagonal pyramid,  a cornercorner with one Co(3)O6 pentagonal pyramid,  a cornercorner with one Co(4)O6 pentagonal pyramid,  an edgeedge with one Mn(1)O6 pentagonal pyramid,  an edgeedge with one Mn(2)O6 pentagonal pyramid,  an edgeedge with one Co(1)O6 pentagonal pyramid,  an edgeedge with one Co(3)O6 pentagonal pyramid, and  an edgeedge with one Co(4)O6 pentagonal pyramid. In the second Te site, Te(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form TeO6 octahedra that share  a cornercorner with one Mn(1)O6 pentagonal pyramid,  a cornercorner with one Mn(2)O6 pentagonal pyramid,  a cornercorner with one Co(1)O6 pentagonal pyramid,  a cornercorner with one Co(3)O6 pentagonal pyramid,  a cornercorner with one Co(4)O6 pentagonal pyramid,  an edgeedge with one Mn(1)O6 pentagonal pyramid,  an edgeedge with one Mn(2)O6 pentagonal pyramid,  an edgeedge with one Co(1)O6 pentagonal pyramid,  an edgeedge with one Co(3)O6 pentagonal pyramid, and  an edgeedge with one Co(4)O6 pentagonal pyramid. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Mn(1), one Mn(2), one Co(3), and one Te(2) atom to form distorted OMn2CoTe tetrahedra that share  a cornercorner with one O(4)MnCo2Te tetrahedra, corners with two equivalent O(5)Co3Te tetrahedra, corners with two equivalent O(6)MnCo2Te tetrahedra, corners with two equivalent O(7)Mn2CoTe trigonal pyramids, corners with two equivalent O(11)MnCo2Te trigonal pyramids,  an edgeedge with one O(2)MnCo2Te tetrahedra,  an edgeedge with one O(3)MnCo2Te tetrahedra,  an edgeedge with one O(4)MnCo2Te tetrahedra, and  an edgeedge with one O(10)MnCo2Te trigonal pyramid. In the second O site, O(2) is bonded to one Mn(2), one Co(1), one Co(4), and one Te(2) atom to form distorted OMnCo2Te tetrahedra that share  a cornercorner with one O(5)Co3Te tetrahedra, corners with two equivalent O(4)MnCo2Te tetrahedra, corners with two equivalent O(6)MnCo2Te tetrahedra,  a cornercorner with one O(7)Mn2CoTe trigonal pyramid,  an edgeedge with one O(5)Co3Te tetrahedra,  an edgeedge with one O(1)Mn2CoTe tetrahedra,  an edgeedge with one O(3)MnCo2Te tetrahedra, and  an edgeedge with one O(11)MnCo2Te trigonal pyramid. In the third O site, O(3) is bonded to one Mn(1), one Co(1), one Co(2), and one Te(2) atom to form distorted OMnCo2Te tetrahedra that share  a cornercorner with one O(6)MnCo2Te tetrahedra, corners with two equivalent O(5)Co3Te tetrahedra, corners with two equivalent O(4)MnCo2Te tetrahedra, corners with two equivalent O(7)Mn2CoTe trigonal pyramids, corners with two equivalent O(10)MnCo2Te trigonal pyramids,  an edgeedge with one O(1)Mn2CoTe tetrahedra,  an edgeedge with one O(2)MnCo2Te tetrahedra, and  an edgeedge with one O(6)MnCo2Te tetrahedra. In the fourth O site, O(4) is bonded to one Mn(2), one Co(2), one Co(3), and one Te(2) atom to form distorted OMnCo2Te tetrahedra that share  a cornercorner with one O(1)Mn2CoTe tetrahedra, corners with two equivalent O(2)MnCo2Te tetrahedra, corners with two equivalent O(3)MnCo2Te tetrahedra, corners with two equivalent O(10)MnCo2Te trigonal pyramids, corners with two equivalent O(11)MnCo2Te trigonal pyramids,  an edgeedge with one O(5)Co3Te tetrahedra,  an edgeedge with one O(1)Mn2CoTe tetrahedra,  an edgeedge with one O(6)MnCo2Te tetrahedra, and  an edgeedge with one O(7)Mn2CoTe trigonal pyramid. In the fifth O site, O(5) is bonded to one Co(1), one Co(3), one Co(4), and one Te(2) atom to form distorted OCo3Te tetrahedra that share  a cornercorner with one O(2)MnCo2Te tetrahedra, corners with two equivalent O(1)Mn2CoTe tetrahedra, corners with two equivalent O(3)MnCo2Te tetrahedra,  a cornercorner with one O(10)MnCo2Te trigonal pyramid, corners with two equivalent O(11)MnCo2Te trigonal pyramids,  an edgeedge with one O(2)MnCo2Te tetrahedra,  an edgeedge with one O(4)MnCo2Te tetrahedra, and  an edgeedge with one O(6)MnCo2Te tetrahedra. In the sixth O site, O(6) is bonded to one Mn(1), one Co(2), one Co(4), and one Te(2) atom to form distorted OMnCo2Te tetrahedra that share  a cornercorner with one O(3)MnCo2Te tetrahedra, corners with two equivalent O(1)Mn2CoTe tetrahedra, corners with two equivalent O(2)MnCo2Te tetrahedra,  a cornercorner with one O(11)MnCo2Te trigonal pyramid, corners with two equivalent O(7)Mn2CoTe trigonal pyramids, corners with two equivalent O(10)MnCo2Te trigonal pyramids,  an edgeedge with one O(5)Co3Te tetrahedra,  an edgeedge with one O(3)MnCo2Te tetrahedra, and  an edgeedge with one O(4)MnCo2Te tetrahedra. In the seventh O site, O(7) is bonded to one Mn(1), one Mn(2), one Co(2), and one Te(1) atom to form distorted OMn2CoTe trigonal pyramids that share  a cornercorner with one O(2)MnCo2Te tetrahedra, corners with two equivalent O(1)Mn2CoTe tetrahedra, corners with two equivalent O(3)MnCo2Te tetrahedra, corners with two equivalent O(6)MnCo2Te tetrahedra,  a cornercorner with one O(10)MnCo2Te trigonal pyramid,  an edgeedge with one O(4)MnCo2Te tetrahedra,  an edgeedge with one O(10)MnCo2Te trigonal pyramid, and  an edgeedge with one O(11)MnCo2Te trigonal pyramid. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Mn(2), one Co(1), one Co(3), and one Te(1) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Mn(1), one Co(1), one Co(4), and one Te(1) atom. In the tenth O site, O(10) is bonded to one Mn(1), one Co(2), one Co(3), and one Te(1) atom to form distorted OMnCo2Te trigonal pyramids that share  a cornercorner with one O(5)Co3Te tetrahedra, corners with two equivalent O(3)MnCo2Te tetrahedra, corners with two equivalent O(4)MnCo2Te tetrahedra, corners with two equivalent O(6)MnCo2Te tetrahedra,  a cornercorner with one O(7)Mn2CoTe trigonal pyramid, corners with two equivalent O(11)MnCo2Te trigonal pyramids,  an edgeedge with one O(1)Mn2CoTe tetrahedra, and  an edgeedge with one O(7)Mn2CoTe trigonal pyramid. In the eleventh O site, O(11) is bonded to one Mn(2), one Co(3), one Co(4), and one Te(1) atom to form distorted OMnCo2Te trigonal pyramids that share  a cornercorner with one O(6)MnCo2Te tetrahedra, corners with two equivalent O(5)Co3Te tetrahedra, corners with two equivalent O(1)Mn2CoTe tetrahedra, corners with two equivalent O(4)MnCo2Te tetrahedra, corners with two equivalent O(10)MnCo2Te trigonal pyramids,  an edgeedge with one O(2)MnCo2Te tetrahedra, and  an edgeedge with one O(7)Mn2CoTe trigonal pyramid. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Co(1), one Co(2), one Co(4), and one Te(1) atom. is represented by the CIF file [CIF]
data_MnCo2TeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.191
_cell_length_b   6.206
_cell_length_c   6.231
_cell_angle_alpha   90.113
_cell_angle_beta   90.369
_cell_angle_gamma   90.313
_symmetry_Int_Tables_number   1
_cell_volume   239.377
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.946  0.437  0.251  1.0
  Mn  Mn1  1  0.252  0.947  0.436  1.0
  Co  Co2  1  0.437  0.258  0.946  1.0
  Co  Co3  1  0.053  0.565  0.744  1.0
  Co  Co4  1  0.742  0.053  0.567  1.0
  Co  Co5  1  0.563  0.743  0.053  1.0
  Te  Te6  1  0.504  0.501  0.504  1.0
  Te  Te7  1  0.999  0.000  0.997  1.0
  O  O8  1  0.949  0.087  0.296  1.0
  O  O9  1  0.301  0.954  0.085  1.0
  O  O10  1  0.095  0.299  0.946  1.0
  O  O11  1  0.043  0.907  0.702  1.0
  O  O12  1  0.698  0.051  0.906  1.0
  O  O13  1  0.906  0.703  0.044  1.0
  O  O14  1  0.202  0.570  0.441  1.0
  O  O15  1  0.438  0.200  0.574  1.0
  O  O16  1  0.564  0.436  0.201  1.0
  O  O17  1  0.801  0.426  0.574  1.0
  O  O18  1  0.576  0.798  0.428  1.0
  O  O19  1  0.431  0.567  0.804  1.0
[/CIF]
.
The material structure described by MnCo2TeO6 is Ilmenite-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(10), one O(3), one O(6), one O(7), and one O(9) atom to form distorted MnO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Mn(2)O6 pentagonal pyramids, corners with two equivalent Co(1)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Co(3)O6 pentagonal pyramid, and  an edgeedge with one Co(4)O6 pentagonal pyramid. The corner-sharing octahedral tilt angles range from 37-43°. In the second Mn site, Mn(2) is bonded to one O(1), one O(11), one O(2), one O(4), one O(7), and one O(8) atom to form distorted MnO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Mn(1)O6 pentagonal pyramids, corners with two equivalent Co(1)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Co(4)O6 pentagonal pyramid, and edges with two equivalent Co(3)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 38-43°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(12), one O(2), one O(3), one O(5), one O(8), and one O(9) atom to form distorted CoO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Mn(1)O6 pentagonal pyramids, corners with two equivalent Mn(2)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Co(3)O6 pentagonal pyramid, and edges with two equivalent Co(4)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 37-40°. In the second Co site, Co(2) is bonded in a 6-coordinate geometry to one O(10), one O(12), one O(3), one O(4), one O(6), and one O(7) atom. In the third Co site, Co(3) is bonded to one O(1), one O(10), one O(11), one O(4), one O(5), and one O(8) atom to form distorted CoO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Co(4)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Mn(1)O6 pentagonal pyramid,  an edgeedge with one Co(1)O6 pentagonal pyramid, and edges with two equivalent Mn(2)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 35-43°. In the fourth Co site, Co(4) is bonded to one O(11), one O(12), one O(2), one O(5), one O(6), and one O(9) atom to form distorted CoO6 pentagonal pyramids that share  a cornercorner with one Te(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, corners with two equivalent Co(3)O6 pentagonal pyramids,  an edgeedge with one Te(1)O6 octahedra,  an edgeedge with one Te(2)O6 octahedra,  an edgeedge with one Mn(1)O6 pentagonal pyramid,  an edgeedge with one Mn(2)O6 pentagonal pyramid, and edges with two equivalent Co(1)O6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 37-43°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(10), one O(11), one O(12), one O(7), one O(8), and one O(9) atom to form TeO6 octahedra that share  a cornercorner with one Mn(1)O6 pentagonal pyramid,  a cornercorner with one Mn(2)O6 pentagonal pyramid,  a cornercorner with one Co(1)O6 pentagonal pyramid,  a cornercorner with one Co(3)O6 pentagonal pyramid,  a cornercorner with one Co(4)O6 pentagonal pyramid,  an edgeedge with one Mn(1)O6 pentagonal pyramid,  an edgeedge with one Mn(2)O6 pentagonal pyramid,  an edgeedge with one Co(1)O6 pentagonal pyramid,  an edgeedge with one Co(3)O6 pentagonal pyramid, and  an edgeedge with one Co(4)O6 pentagonal pyramid. In the second Te site, Te(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form TeO6 octahedra that share  a cornercorner with one Mn(1)O6 pentagonal pyramid,  a cornercorner with one Mn(2)O6 pentagonal pyramid,  a cornercorner with one Co(1)O6 pentagonal pyramid,  a cornercorner with one Co(3)O6 pentagonal pyramid,  a cornercorner with one Co(4)O6 pentagonal pyramid,  an edgeedge with one Mn(1)O6 pentagonal pyramid,  an edgeedge with one Mn(2)O6 pentagonal pyramid,  an edgeedge with one Co(1)O6 pentagonal pyramid,  an edgeedge with one Co(3)O6 pentagonal pyramid, and  an edgeedge with one Co(4)O6 pentagonal pyramid. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Mn(1), one Mn(2), one Co(3), and one Te(2) atom to form distorted OMn2CoTe tetrahedra that share  a cornercorner with one O(4)MnCo2Te tetrahedra, corners with two equivalent O(5)Co3Te tetrahedra, corners with two equivalent O(6)MnCo2Te tetrahedra, corners with two equivalent O(7)Mn2CoTe trigonal pyramids, corners with two equivalent O(11)MnCo2Te trigonal pyramids,  an edgeedge with one O(2)MnCo2Te tetrahedra,  an edgeedge with one O(3)MnCo2Te tetrahedra,  an edgeedge with one O(4)MnCo2Te tetrahedra, and  an edgeedge with one O(10)MnCo2Te trigonal pyramid. In the second O site, O(2) is bonded to one Mn(2), one Co(1), one Co(4), and one Te(2) atom to form distorted OMnCo2Te tetrahedra that share  a cornercorner with one O(5)Co3Te tetrahedra, corners with two equivalent O(4)MnCo2Te tetrahedra, corners with two equivalent O(6)MnCo2Te tetrahedra,  a cornercorner with one O(7)Mn2CoTe trigonal pyramid,  an edgeedge with one O(5)Co3Te tetrahedra,  an edgeedge with one O(1)Mn2CoTe tetrahedra,  an edgeedge with one O(3)MnCo2Te tetrahedra, and  an edgeedge with one O(11)MnCo2Te trigonal pyramid. In the third O site, O(3) is bonded to one Mn(1), one Co(1), one Co(2), and one Te(2) atom to form distorted OMnCo2Te tetrahedra that share  a cornercorner with one O(6)MnCo2Te tetrahedra, corners with two equivalent O(5)Co3Te tetrahedra, corners with two equivalent O(4)MnCo2Te tetrahedra, corners with two equivalent O(7)Mn2CoTe trigonal pyramids, corners with two equivalent O(10)MnCo2Te trigonal pyramids,  an edgeedge with one O(1)Mn2CoTe tetrahedra,  an edgeedge with one O(2)MnCo2Te tetrahedra, and  an edgeedge with one O(6)MnCo2Te tetrahedra. In the fourth O site, O(4) is bonded to one Mn(2), one Co(2), one Co(3), and one Te(2) atom to form distorted OMnCo2Te tetrahedra that share  a cornercorner with one O(1)Mn2CoTe tetrahedra, corners with two equivalent O(2)MnCo2Te tetrahedra, corners with two equivalent O(3)MnCo2Te tetrahedra, corners with two equivalent O(10)MnCo2Te trigonal pyramids, corners with two equivalent O(11)MnCo2Te trigonal pyramids,  an edgeedge with one O(5)Co3Te tetrahedra,  an edgeedge with one O(1)Mn2CoTe tetrahedra,  an edgeedge with one O(6)MnCo2Te tetrahedra, and  an edgeedge with one O(7)Mn2CoTe trigonal pyramid. In the fifth O site, O(5) is bonded to one Co(1), one Co(3), one Co(4), and one Te(2) atom to form distorted OCo3Te tetrahedra that share  a cornercorner with one O(2)MnCo2Te tetrahedra, corners with two equivalent O(1)Mn2CoTe tetrahedra, corners with two equivalent O(3)MnCo2Te tetrahedra,  a cornercorner with one O(10)MnCo2Te trigonal pyramid, corners with two equivalent O(11)MnCo2Te trigonal pyramids,  an edgeedge with one O(2)MnCo2Te tetrahedra,  an edgeedge with one O(4)MnCo2Te tetrahedra, and  an edgeedge with one O(6)MnCo2Te tetrahedra. In the sixth O site, O(6) is bonded to one Mn(1), one Co(2), one Co(4), and one Te(2) atom to form distorted OMnCo2Te tetrahedra that share  a cornercorner with one O(3)MnCo2Te tetrahedra, corners with two equivalent O(1)Mn2CoTe tetrahedra, corners with two equivalent O(2)MnCo2Te tetrahedra,  a cornercorner with one O(11)MnCo2Te trigonal pyramid, corners with two equivalent O(7)Mn2CoTe trigonal pyramids, corners with two equivalent O(10)MnCo2Te trigonal pyramids,  an edgeedge with one O(5)Co3Te tetrahedra,  an edgeedge with one O(3)MnCo2Te tetrahedra, and  an edgeedge with one O(4)MnCo2Te tetrahedra. In the seventh O site, O(7) is bonded to one Mn(1), one Mn(2), one Co(2), and one Te(1) atom to form distorted OMn2CoTe trigonal pyramids that share  a cornercorner with one O(2)MnCo2Te tetrahedra, corners with two equivalent O(1)Mn2CoTe tetrahedra, corners with two equivalent O(3)MnCo2Te tetrahedra, corners with two equivalent O(6)MnCo2Te tetrahedra,  a cornercorner with one O(10)MnCo2Te trigonal pyramid,  an edgeedge with one O(4)MnCo2Te tetrahedra,  an edgeedge with one O(10)MnCo2Te trigonal pyramid, and  an edgeedge with one O(11)MnCo2Te trigonal pyramid. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Mn(2), one Co(1), one Co(3), and one Te(1) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Mn(1), one Co(1), one Co(4), and one Te(1) atom. In the tenth O site, O(10) is bonded to one Mn(1), one Co(2), one Co(3), and one Te(1) atom to form distorted OMnCo2Te trigonal pyramids that share  a cornercorner with one O(5)Co3Te tetrahedra, corners with two equivalent O(3)MnCo2Te tetrahedra, corners with two equivalent O(4)MnCo2Te tetrahedra, corners with two equivalent O(6)MnCo2Te tetrahedra,  a cornercorner with one O(7)Mn2CoTe trigonal pyramid, corners with two equivalent O(11)MnCo2Te trigonal pyramids,  an edgeedge with one O(1)Mn2CoTe tetrahedra, and  an edgeedge with one O(7)Mn2CoTe trigonal pyramid. In the eleventh O site, O(11) is bonded to one Mn(2), one Co(3), one Co(4), and one Te(1) atom to form distorted OMnCo2Te trigonal pyramids that share  a cornercorner with one O(6)MnCo2Te tetrahedra, corners with two equivalent O(5)Co3Te tetrahedra, corners with two equivalent O(1)Mn2CoTe tetrahedra, corners with two equivalent O(4)MnCo2Te tetrahedra, corners with two equivalent O(10)MnCo2Te trigonal pyramids,  an edgeedge with one O(2)MnCo2Te tetrahedra, and  an edgeedge with one O(7)Mn2CoTe trigonal pyramid. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Co(1), one Co(2), one Co(4), and one Te(1) atom. is represented by the CIF file [CIF]
data_MnCo2TeO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.191
_cell_length_b   6.206
_cell_length_c   6.231
_cell_angle_alpha   90.113
_cell_angle_beta   90.369
_cell_angle_gamma   90.313
_symmetry_Int_Tables_number   1
_cell_volume   239.377
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.946  0.437  0.251  1.0
  Mn  Mn1  1  0.252  0.947  0.436  1.0
  Co  Co2  1  0.437  0.258  0.946  1.0
  Co  Co3  1  0.053  0.565  0.744  1.0
  Co  Co4  1  0.742  0.053  0.567  1.0
  Co  Co5  1  0.563  0.743  0.053  1.0
  Te  Te6  1  0.504  0.501  0.504  1.0
  Te  Te7  1  0.999  0.000  0.997  1.0
  O  O8  1  0.949  0.087  0.296  1.0
  O  O9  1  0.301  0.954  0.085  1.0
  O  O10  1  0.095  0.299  0.946  1.0
  O  O11  1  0.043  0.907  0.702  1.0
  O  O12  1  0.698  0.051  0.906  1.0
  O  O13  1  0.906  0.703  0.044  1.0
  O  O14  1  0.202  0.570  0.441  1.0
  O  O15  1  0.438  0.200  0.574  1.0
  O  O16  1  0.564  0.436  0.201  1.0
  O  O17  1  0.801  0.426  0.574  1.0
  O  O18  1  0.576  0.798  0.428  1.0
  O  O19  1  0.431  0.567  0.804  1.0
[/CIF]
.