The structure described by K5H(CN2)2 crystallizes in the tetragonal P4/ncc space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 6-coordinate geometry to one C(1), four equivalent N(1), and one H(1) atom. In the second K site, K(2) is bonded to four equivalent N(1) and two equivalent H(1) atoms to form corner-sharing KH2N4 octahedra. The corner-sharing octahedra are not tilted. C(1) is bonded in a linear geometry to two equivalent K(1) and two equivalent N(1) atoms. N(1) is bonded in a distorted single-bond geometry to one K(2), four equivalent K(1), and one C(1) atom. H(1) is bonded to two equivalent K(2) and four equivalent K(1) atoms to form corner-sharing HK6 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_K5H(CN2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.132
_cell_length_b   9.132
_cell_length_c   11.104
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   926.025
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.295  0.396  0.102  1.0
  K  K1  1  0.295  0.604  0.602  1.0
  K  K2  1  0.396  0.295  0.398  1.0
  K  K3  1  0.396  0.705  0.898  1.0
  K  K4  1  0.500  0.000  0.152  1.0
  K  K5  1  0.500  0.000  0.652  1.0
  K  K6  1  0.604  0.295  0.898  1.0
  K  K7  1  0.604  0.705  0.398  1.0
  K  K8  1  0.705  0.396  0.602  1.0
  K  K9  1  0.705  0.604  0.102  1.0
  K  K10  1  0.795  0.896  0.898  1.0
  K  K11  1  0.795  0.104  0.398  1.0
  K  K12  1  0.896  0.795  0.602  1.0
  K  K13  1  0.896  0.205  0.102  1.0
  K  K14  1  0.000  0.500  0.348  1.0
  K  K15  1  0.000  0.500  0.848  1.0
  K  K16  1  0.104  0.795  0.102  1.0
  K  K17  1  0.104  0.205  0.602  1.0
  K  K18  1  0.205  0.104  0.898  1.0
  K  K19  1  0.205  0.896  0.398  1.0
  H  H20  1  0.500  0.000  0.400  1.0
  H  H21  1  0.500  0.000  0.900  1.0
  H  H22  1  0.000  0.500  0.100  1.0
  H  H23  1  0.000  0.500  0.600  1.0
  C  C24  1  0.353  0.353  0.750  1.0
  C  C25  1  0.353  0.647  0.250  1.0
  C  C26  1  0.647  0.353  0.250  1.0
  C  C27  1  0.647  0.647  0.750  1.0
  C  C28  1  0.853  0.853  0.250  1.0
  C  C29  1  0.853  0.147  0.750  1.0
  C  C30  1  0.147  0.853  0.750  1.0
  C  C31  1  0.147  0.147  0.250  1.0
  N  N32  1  0.306  0.599  0.348  1.0
  N  N33  1  0.306  0.401  0.848  1.0
  N  N34  1  0.401  0.694  0.152  1.0
  N  N35  1  0.401  0.306  0.652  1.0
  N  N36  1  0.599  0.306  0.152  1.0
  N  N37  1  0.599  0.694  0.652  1.0
  N  N38  1  0.694  0.401  0.348  1.0
  N  N39  1  0.694  0.599  0.848  1.0
  N  N40  1  0.806  0.901  0.152  1.0
  N  N41  1  0.806  0.099  0.652  1.0
  N  N42  1  0.901  0.806  0.348  1.0
  N  N43  1  0.901  0.194  0.848  1.0
  N  N44  1  0.099  0.194  0.348  1.0
  N  N45  1  0.099  0.806  0.848  1.0
  N  N46  1  0.194  0.901  0.652  1.0
  N  N47  1  0.194  0.099  0.152  1.0
[/CIF]
.
The structure described by K5H(CN2)2 crystallizes in the tetragonal P4/ncc space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 6-coordinate geometry to one C(1), four equivalent N(1), and one H(1) atom. In the second K site, K(2) is bonded to four equivalent N(1) and two equivalent H(1) atoms to form corner-sharing KH2N4 octahedra. The corner-sharing octahedra are not tilted. C(1) is bonded in a linear geometry to two equivalent K(1) and two equivalent N(1) atoms. N(1) is bonded in a distorted single-bond geometry to one K(2), four equivalent K(1), and one C(1) atom. H(1) is bonded to two equivalent K(2) and four equivalent K(1) atoms to form corner-sharing HK6 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_K5H(CN2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.132
_cell_length_b   9.132
_cell_length_c   11.104
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   926.025
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.295  0.396  0.102  1.0
  K  K1  1  0.295  0.604  0.602  1.0
  K  K2  1  0.396  0.295  0.398  1.0
  K  K3  1  0.396  0.705  0.898  1.0
  K  K4  1  0.500  0.000  0.152  1.0
  K  K5  1  0.500  0.000  0.652  1.0
  K  K6  1  0.604  0.295  0.898  1.0
  K  K7  1  0.604  0.705  0.398  1.0
  K  K8  1  0.705  0.396  0.602  1.0
  K  K9  1  0.705  0.604  0.102  1.0
  K  K10  1  0.795  0.896  0.898  1.0
  K  K11  1  0.795  0.104  0.398  1.0
  K  K12  1  0.896  0.795  0.602  1.0
  K  K13  1  0.896  0.205  0.102  1.0
  K  K14  1  0.000  0.500  0.348  1.0
  K  K15  1  0.000  0.500  0.848  1.0
  K  K16  1  0.104  0.795  0.102  1.0
  K  K17  1  0.104  0.205  0.602  1.0
  K  K18  1  0.205  0.104  0.898  1.0
  K  K19  1  0.205  0.896  0.398  1.0
  H  H20  1  0.500  0.000  0.400  1.0
  H  H21  1  0.500  0.000  0.900  1.0
  H  H22  1  0.000  0.500  0.100  1.0
  H  H23  1  0.000  0.500  0.600  1.0
  C  C24  1  0.353  0.353  0.750  1.0
  C  C25  1  0.353  0.647  0.250  1.0
  C  C26  1  0.647  0.353  0.250  1.0
  C  C27  1  0.647  0.647  0.750  1.0
  C  C28  1  0.853  0.853  0.250  1.0
  C  C29  1  0.853  0.147  0.750  1.0
  C  C30  1  0.147  0.853  0.750  1.0
  C  C31  1  0.147  0.147  0.250  1.0
  N  N32  1  0.306  0.599  0.348  1.0
  N  N33  1  0.306  0.401  0.848  1.0
  N  N34  1  0.401  0.694  0.152  1.0
  N  N35  1  0.401  0.306  0.652  1.0
  N  N36  1  0.599  0.306  0.152  1.0
  N  N37  1  0.599  0.694  0.652  1.0
  N  N38  1  0.694  0.401  0.348  1.0
  N  N39  1  0.694  0.599  0.848  1.0
  N  N40  1  0.806  0.901  0.152  1.0
  N  N41  1  0.806  0.099  0.652  1.0
  N  N42  1  0.901  0.806  0.348  1.0
  N  N43  1  0.901  0.194  0.848  1.0
  N  N44  1  0.099  0.194  0.348  1.0
  N  N45  1  0.099  0.806  0.848  1.0
  N  N46  1  0.194  0.901  0.652  1.0
  N  N47  1  0.194  0.099  0.152  1.0
[/CIF]
.