The crystal structure described by LaVH2O15I4 crystallizes in the monoclinic P2_1 space group. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(13), one O(2), one O(4), one O(6), one O(7), and one O(9) atom. V(1) is bonded in a 6-coordinate geometry to one O(11), one O(13), one O(14), one O(3), one O(5), and one O(8) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(15) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(15) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one La(1) and one I(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one La(1) and one I(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one V(1) and one I(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one La(1) and one I(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one V(1) and one I(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one La(1) and one I(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one La(1) and one I(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one V(1) and one I(3) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one La(1) and one I(3) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one I(4) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one V(1) and one I(4) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one La(1) and one I(4) atom. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to one La(1) and one V(1) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one V(1) atom. In the fifteenth O site, O(15) is bonded in a water-like geometry to one H(1), one H(2), and one I(4) atom. There are four inequivalent I sites. In the first I site, I(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(4), one O(5), and one O(6) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one O(7), one O(8), and one O(9) atom. In the fourth I site, I(4) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(11), one O(12), and one O(15) atom. is represented by the CIF file [CIF]
data_LaVH2I4O15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.284
_cell_length_b   7.254
_cell_length_c   7.359
_cell_angle_alpha   64.518
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   688.343
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.744  0.085  0.569  1.0
  La  La1  1  0.244  0.915  0.431  1.0
  V  V2  1  0.572  0.571  0.216  1.0
  V  V3  1  0.072  0.429  0.784  1.0
  H  H4  1  0.943  0.830  0.375  1.0
  H  H5  1  0.443  0.170  0.625  1.0
  H  H6  1  0.031  0.771  0.285  1.0
  H  H7  1  0.531  0.229  0.715  1.0
  I  I8  1  0.610  0.146  0.071  1.0
  I  I9  1  0.110  0.854  0.929  1.0
  I  I10  1  0.498  0.749  0.698  1.0
  I  I11  1  0.998  0.251  0.302  1.0
  I  I12  1  0.835  0.475  0.766  1.0
  I  I13  1  0.335  0.525  0.234  1.0
  I  I14  1  0.801  0.744  0.133  1.0
  I  I15  1  0.301  0.256  0.867  1.0
  O  O16  1  0.654  0.199  0.819  1.0
  O  O17  1  0.154  0.801  0.181  1.0
  O  O18  1  0.720  0.089  0.213  1.0
  O  O19  1  0.220  0.911  0.787  1.0
  O  O20  1  0.591  0.416  0.010  1.0
  O  O21  1  0.091  0.584  0.990  1.0
  O  O22  1  0.589  0.940  0.584  1.0
  O  O23  1  0.089  0.060  0.416  1.0
  O  O24  1  0.493  0.757  0.945  1.0
  O  O25  1  0.993  0.243  0.055  1.0
  O  O26  1  0.899  0.080  0.418  1.0
  O  O27  1  0.399  0.920  0.582  1.0
  O  O28  1  0.771  0.712  0.644  1.0
  O  O29  1  0.271  0.288  0.356  1.0
  O  O30  1  0.954  0.592  0.718  1.0
  O  O31  1  0.454  0.408  0.282  1.0
  O  O32  1  0.829  0.392  0.563  1.0
  O  O33  1  0.329  0.608  0.437  1.0
  O  O34  1  0.844  0.521  0.104  1.0
  O  O35  1  0.344  0.479  0.896  1.0
  O  O36  1  0.676  0.749  0.049  1.0
  O  O37  1  0.176  0.251  0.951  1.0
  O  O38  1  0.837  0.949  0.895  1.0
  O  O39  1  0.337  0.051  0.105  1.0
  O  O40  1  0.641  0.387  0.383  1.0
  O  O41  1  0.141  0.613  0.617  1.0
  O  O42  1  0.542  0.723  0.324  1.0
  O  O43  1  0.042  0.277  0.676  1.0
  O  O44  1  0.962  0.765  0.288  1.0
  O  O45  1  0.462  0.235  0.712  1.0
[/CIF]
.
The crystal structure described by LaVH2O15I4 crystallizes in the monoclinic P2_1 space group. La(1) is bonded in a 8-coordinate geometry to one O(1), one O(12), one O(13), one O(2), one O(4), one O(6), one O(7), and one O(9) atom. V(1) is bonded in a 6-coordinate geometry to one O(11), one O(13), one O(14), one O(3), one O(5), and one O(8) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(15) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(15) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one La(1) and one I(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one La(1) and one I(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one V(1) and one I(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one La(1) and one I(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one V(1) and one I(2) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one La(1) and one I(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one La(1) and one I(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one V(1) and one I(3) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one La(1) and one I(3) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one I(4) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one V(1) and one I(4) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one La(1) and one I(4) atom. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to one La(1) and one V(1) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one V(1) atom. In the fifteenth O site, O(15) is bonded in a water-like geometry to one H(1), one H(2), and one I(4) atom. There are four inequivalent I sites. In the first I site, I(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(4), one O(5), and one O(6) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one O(7), one O(8), and one O(9) atom. In the fourth I site, I(4) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(11), one O(12), and one O(15) atom. is represented by the CIF file [CIF]
data_LaVH2I4O15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.284
_cell_length_b   7.254
_cell_length_c   7.359
_cell_angle_alpha   64.518
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   688.343
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.744  0.085  0.569  1.0
  La  La1  1  0.244  0.915  0.431  1.0
  V  V2  1  0.572  0.571  0.216  1.0
  V  V3  1  0.072  0.429  0.784  1.0
  H  H4  1  0.943  0.830  0.375  1.0
  H  H5  1  0.443  0.170  0.625  1.0
  H  H6  1  0.031  0.771  0.285  1.0
  H  H7  1  0.531  0.229  0.715  1.0
  I  I8  1  0.610  0.146  0.071  1.0
  I  I9  1  0.110  0.854  0.929  1.0
  I  I10  1  0.498  0.749  0.698  1.0
  I  I11  1  0.998  0.251  0.302  1.0
  I  I12  1  0.835  0.475  0.766  1.0
  I  I13  1  0.335  0.525  0.234  1.0
  I  I14  1  0.801  0.744  0.133  1.0
  I  I15  1  0.301  0.256  0.867  1.0
  O  O16  1  0.654  0.199  0.819  1.0
  O  O17  1  0.154  0.801  0.181  1.0
  O  O18  1  0.720  0.089  0.213  1.0
  O  O19  1  0.220  0.911  0.787  1.0
  O  O20  1  0.591  0.416  0.010  1.0
  O  O21  1  0.091  0.584  0.990  1.0
  O  O22  1  0.589  0.940  0.584  1.0
  O  O23  1  0.089  0.060  0.416  1.0
  O  O24  1  0.493  0.757  0.945  1.0
  O  O25  1  0.993  0.243  0.055  1.0
  O  O26  1  0.899  0.080  0.418  1.0
  O  O27  1  0.399  0.920  0.582  1.0
  O  O28  1  0.771  0.712  0.644  1.0
  O  O29  1  0.271  0.288  0.356  1.0
  O  O30  1  0.954  0.592  0.718  1.0
  O  O31  1  0.454  0.408  0.282  1.0
  O  O32  1  0.829  0.392  0.563  1.0
  O  O33  1  0.329  0.608  0.437  1.0
  O  O34  1  0.844  0.521  0.104  1.0
  O  O35  1  0.344  0.479  0.896  1.0
  O  O36  1  0.676  0.749  0.049  1.0
  O  O37  1  0.176  0.251  0.951  1.0
  O  O38  1  0.837  0.949  0.895  1.0
  O  O39  1  0.337  0.051  0.105  1.0
  O  O40  1  0.641  0.387  0.383  1.0
  O  O41  1  0.141  0.613  0.617  1.0
  O  O42  1  0.542  0.723  0.324  1.0
  O  O43  1  0.042  0.277  0.676  1.0
  O  O44  1  0.962  0.765  0.288  1.0
  O  O45  1  0.462  0.235  0.712  1.0
[/CIF]
.