The material structure described by WMn2P12 crystallizes in the monoclinic C2/c space group. W(1) is bonded in a 8-coordinate geometry to two equivalent P(1), two equivalent P(2), two equivalent P(3), and two equivalent P(5) atoms. Mn(1) is bonded to one P(1), one P(2), one P(3), one P(6), and two equivalent P(4) atoms to form MnP6 octahedra that share corners with four equivalent P(5)P3W tetrahedra and  an edgeedge with one Mn(1)P6 octahedra. There are six inequivalent P sites. In the first P site, P(1) is bonded in a 4-coordinate geometry to one W(1), one Mn(1), one P(4), and one P(6) atom. In the second P site, P(2) is bonded in a 4-coordinate geometry to one W(1), one Mn(1), one P(2), and one P(5) atom. In the third P site, P(3) is bonded in a distorted single-bond geometry to one W(1), one Mn(1), one P(5), and one P(6) atom. In the fourth P site, P(4) is bonded in a 4-coordinate geometry to two equivalent Mn(1), one P(1), and one P(5) atom. In the fifth P site, P(5) is bonded to one W(1), one P(2), one P(3), and one P(4) atom to form distorted PP3W tetrahedra that share corners with four equivalent Mn(1)P6 octahedra and  a cornercorner with one P(5)P3W tetrahedra. The corner-sharing octahedral tilt angles range from 54-74°. In the sixth P site, P(6) is bonded in a distorted single-bond geometry to one Mn(1), one P(1), one P(3), and one P(6) atom. is represented by the CIF card [CIF]
data_Mn2P12W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.476
_cell_length_b   8.476
_cell_length_c   10.547
_cell_angle_alpha   65.663
_cell_angle_beta   65.663
_cell_angle_gamma   39.363
_symmetry_Int_Tables_number   1
_cell_volume   432.080
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.010  0.629  0.046  1.0
  Mn  Mn1  1  0.371  0.990  0.454  1.0
  Mn  Mn2  1  0.990  0.371  0.954  1.0
  Mn  Mn3  1  0.629  0.010  0.546  1.0
  P  P4  1  0.022  0.672  0.241  1.0
  P  P5  1  0.328  0.978  0.259  1.0
  P  P6  1  0.978  0.328  0.759  1.0
  P  P7  1  0.672  0.022  0.741  1.0
  P  P8  1  0.988  0.078  0.074  1.0
  P  P9  1  0.922  0.012  0.426  1.0
  P  P10  1  0.012  0.922  0.926  1.0
  P  P11  1  0.078  0.988  0.574  1.0
  P  P12  1  0.669  0.564  0.496  1.0
  P  P13  1  0.436  0.331  0.004  1.0
  P  P14  1  0.331  0.436  0.504  1.0
  P  P15  1  0.564  0.669  0.996  1.0
  P  P16  1  0.002  0.354  0.163  1.0
  P  P17  1  0.646  0.998  0.337  1.0
  P  P18  1  0.998  0.646  0.837  1.0
  P  P19  1  0.354  0.002  0.663  1.0
  P  P20  1  0.703  0.421  0.333  1.0
  P  P21  1  0.579  0.297  0.167  1.0
  P  P22  1  0.297  0.579  0.667  1.0
  P  P23  1  0.421  0.703  0.833  1.0
  P  P24  1  0.050  0.404  0.425  1.0
  P  P25  1  0.596  0.950  0.075  1.0
  P  P26  1  0.950  0.596  0.575  1.0
  P  P27  1  0.404  0.050  0.925  1.0
  W  W28  1  0.305  0.695  0.250  1.0
  W  W29  1  0.695  0.305  0.750  1.0
[/CIF]
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The material structure described by WMn2P12 crystallizes in the monoclinic C2/c space group. W(1) is bonded in a 8-coordinate geometry to two equivalent P(1), two equivalent P(2), two equivalent P(3), and two equivalent P(5) atoms. Mn(1) is bonded to one P(1), one P(2), one P(3), one P(6), and two equivalent P(4) atoms to form MnP6 octahedra that share corners with four equivalent P(5)P3W tetrahedra and  an edgeedge with one Mn(1)P6 octahedra. There are six inequivalent P sites. In the first P site, P(1) is bonded in a 4-coordinate geometry to one W(1), one Mn(1), one P(4), and one P(6) atom. In the second P site, P(2) is bonded in a 4-coordinate geometry to one W(1), one Mn(1), one P(2), and one P(5) atom. In the third P site, P(3) is bonded in a distorted single-bond geometry to one W(1), one Mn(1), one P(5), and one P(6) atom. In the fourth P site, P(4) is bonded in a 4-coordinate geometry to two equivalent Mn(1), one P(1), and one P(5) atom. In the fifth P site, P(5) is bonded to one W(1), one P(2), one P(3), and one P(4) atom to form distorted PP3W tetrahedra that share corners with four equivalent Mn(1)P6 octahedra and  a cornercorner with one P(5)P3W tetrahedra. The corner-sharing octahedral tilt angles range from 54-74°. In the sixth P site, P(6) is bonded in a distorted single-bond geometry to one Mn(1), one P(1), one P(3), and one P(6) atom. is represented by the CIF card [CIF]
data_Mn2P12W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.476
_cell_length_b   8.476
_cell_length_c   10.547
_cell_angle_alpha   65.663
_cell_angle_beta   65.663
_cell_angle_gamma   39.363
_symmetry_Int_Tables_number   1
_cell_volume   432.080
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.010  0.629  0.046  1.0
  Mn  Mn1  1  0.371  0.990  0.454  1.0
  Mn  Mn2  1  0.990  0.371  0.954  1.0
  Mn  Mn3  1  0.629  0.010  0.546  1.0
  P  P4  1  0.022  0.672  0.241  1.0
  P  P5  1  0.328  0.978  0.259  1.0
  P  P6  1  0.978  0.328  0.759  1.0
  P  P7  1  0.672  0.022  0.741  1.0
  P  P8  1  0.988  0.078  0.074  1.0
  P  P9  1  0.922  0.012  0.426  1.0
  P  P10  1  0.012  0.922  0.926  1.0
  P  P11  1  0.078  0.988  0.574  1.0
  P  P12  1  0.669  0.564  0.496  1.0
  P  P13  1  0.436  0.331  0.004  1.0
  P  P14  1  0.331  0.436  0.504  1.0
  P  P15  1  0.564  0.669  0.996  1.0
  P  P16  1  0.002  0.354  0.163  1.0
  P  P17  1  0.646  0.998  0.337  1.0
  P  P18  1  0.998  0.646  0.837  1.0
  P  P19  1  0.354  0.002  0.663  1.0
  P  P20  1  0.703  0.421  0.333  1.0
  P  P21  1  0.579  0.297  0.167  1.0
  P  P22  1  0.297  0.579  0.667  1.0
  P  P23  1  0.421  0.703  0.833  1.0
  P  P24  1  0.050  0.404  0.425  1.0
  P  P25  1  0.596  0.950  0.075  1.0
  P  P26  1  0.950  0.596  0.575  1.0
  P  P27  1  0.404  0.050  0.925  1.0
  W  W28  1  0.305  0.695  0.250  1.0
  W  W29  1  0.695  0.305  0.750  1.0
[/CIF]
.