The compound described by CNS2O2Cl is Indium-like structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four CNS2O2Cl clusters. C(1) is bonded in a 3-coordinate geometry to one S(1), one O(2), and one Cl(1) atom. N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one C(1) and one N(1) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one O(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Cl(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF file [CIF]
data_CS2NClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.512
_cell_length_b   7.560
_cell_length_c   15.360
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   640.145
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.423  0.920  0.905  1.0
  C  C1  1  0.923  0.080  0.095  1.0
  C  C2  1  0.423  0.080  0.405  1.0
  C  C3  1  0.923  0.920  0.595  1.0
  S  S4  1  0.660  0.835  0.646  1.0
  S  S5  1  0.160  0.165  0.354  1.0
  S  S6  1  0.660  0.165  0.146  1.0
  S  S7  1  0.160  0.835  0.854  1.0
  S  S8  1  0.950  0.497  0.884  1.0
  S  S9  1  0.450  0.503  0.116  1.0
  S  S10  1  0.950  0.503  0.384  1.0
  S  S11  1  0.450  0.497  0.616  1.0
  N  N12  1  0.143  0.641  0.902  1.0
  N  N13  1  0.643  0.359  0.098  1.0
  N  N14  1  0.143  0.359  0.402  1.0
  N  N15  1  0.643  0.641  0.598  1.0
  Cl  Cl16  1  0.975  0.132  0.642  1.0
  Cl  Cl17  1  0.475  0.868  0.358  1.0
  Cl  Cl18  1  0.975  0.868  0.142  1.0
  Cl  Cl19  1  0.475  0.132  0.858  1.0
  O  O20  1  0.761  0.533  0.819  1.0
  O  O21  1  0.261  0.467  0.181  1.0
  O  O22  1  0.761  0.467  0.319  1.0
  O  O23  1  0.261  0.533  0.681  1.0
  O  O24  1  0.050  0.854  0.541  1.0
  O  O25  1  0.550  0.146  0.459  1.0
  O  O26  1  0.050  0.146  0.041  1.0
  O  O27  1  0.550  0.854  0.959  1.0
[/CIF]
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The compound described by CNS2O2Cl is Indium-like structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of four CNS2O2Cl clusters. C(1) is bonded in a 3-coordinate geometry to one S(1), one O(2), and one Cl(1) atom. N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted water-like geometry to one C(1) and one N(1) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one O(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Cl(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF file [CIF]
data_CS2NClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.512
_cell_length_b   7.560
_cell_length_c   15.360
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   640.145
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.423  0.920  0.905  1.0
  C  C1  1  0.923  0.080  0.095  1.0
  C  C2  1  0.423  0.080  0.405  1.0
  C  C3  1  0.923  0.920  0.595  1.0
  S  S4  1  0.660  0.835  0.646  1.0
  S  S5  1  0.160  0.165  0.354  1.0
  S  S6  1  0.660  0.165  0.146  1.0
  S  S7  1  0.160  0.835  0.854  1.0
  S  S8  1  0.950  0.497  0.884  1.0
  S  S9  1  0.450  0.503  0.116  1.0
  S  S10  1  0.950  0.503  0.384  1.0
  S  S11  1  0.450  0.497  0.616  1.0
  N  N12  1  0.143  0.641  0.902  1.0
  N  N13  1  0.643  0.359  0.098  1.0
  N  N14  1  0.143  0.359  0.402  1.0
  N  N15  1  0.643  0.641  0.598  1.0
  Cl  Cl16  1  0.975  0.132  0.642  1.0
  Cl  Cl17  1  0.475  0.868  0.358  1.0
  Cl  Cl18  1  0.975  0.868  0.142  1.0
  Cl  Cl19  1  0.475  0.132  0.858  1.0
  O  O20  1  0.761  0.533  0.819  1.0
  O  O21  1  0.261  0.467  0.181  1.0
  O  O22  1  0.761  0.467  0.319  1.0
  O  O23  1  0.261  0.533  0.681  1.0
  O  O24  1  0.050  0.854  0.541  1.0
  O  O25  1  0.550  0.146  0.459  1.0
  O  O26  1  0.050  0.146  0.041  1.0
  O  O27  1  0.550  0.854  0.959  1.0
[/CIF]
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