The crystal structure described by BiVO4 crystallizes in the tetragonal I4_1/a space group. V(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. Bi(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Bi(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.835
_cell_length_b   6.835
_cell_length_c   6.835
_cell_angle_alpha   135.986
_cell_angle_beta   135.986
_cell_angle_gamma   64.001
_symmetry_Int_Tables_number   1
_cell_volume   152.065
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.000  1.0
  V  V1  1  0.250  0.750  0.500  1.0
  Bi  Bi2  1  0.000  0.000  0.000  1.0
  Bi  Bi3  1  0.750  0.250  0.500  1.0
  O  O4  1  0.171  0.562  0.891  1.0
  O  O5  1  0.312  0.921  0.891  1.0
  O  O6  1  0.030  0.421  0.109  1.0
  O  O7  1  0.671  0.280  0.109  1.0
  O  O8  1  0.079  0.970  0.391  1.0
  O  O9  1  0.720  0.829  0.391  1.0
  O  O10  1  0.579  0.688  0.609  1.0
  O  O11  1  0.438  0.329  0.609  1.0
[/CIF]
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The crystal structure described by BiVO4 crystallizes in the tetragonal I4_1/a space group. V(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. Bi(1) is bonded in a 8-coordinate geometry to eight equivalent O(1) atoms. O(1) is bonded in a distorted single-bond geometry to one V(1) and two equivalent Bi(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_VBiO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.835
_cell_length_b   6.835
_cell_length_c   6.835
_cell_angle_alpha   135.986
_cell_angle_beta   135.986
_cell_angle_gamma   64.001
_symmetry_Int_Tables_number   1
_cell_volume   152.065
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.500  0.500  0.000  1.0
  V  V1  1  0.250  0.750  0.500  1.0
  Bi  Bi2  1  0.000  0.000  0.000  1.0
  Bi  Bi3  1  0.750  0.250  0.500  1.0
  O  O4  1  0.171  0.562  0.891  1.0
  O  O5  1  0.312  0.921  0.891  1.0
  O  O6  1  0.030  0.421  0.109  1.0
  O  O7  1  0.671  0.280  0.109  1.0
  O  O8  1  0.079  0.970  0.391  1.0
  O  O9  1  0.720  0.829  0.391  1.0
  O  O10  1  0.579  0.688  0.609  1.0
  O  O11  1  0.438  0.329  0.609  1.0
[/CIF]
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