The material described by Zn(SbO2)4 crystallizes in the trigonal R-3m space group. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Sb(2)O6 octahedra and edges with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 8°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SbO6 octahedra that share edges with two equivalent Zn(1)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and edges with four equivalent Sb(1)O6 octahedra. In the second Sb site, Sb(2) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra and edges with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 8°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Zn(1), one Sb(2), and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to three equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_Zn(SbO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.328
_cell_length_b   6.328
_cell_length_c   6.328
_cell_angle_alpha   65.805
_cell_angle_beta   65.805
_cell_angle_gamma   65.805
_symmetry_Int_Tables_number   1
_cell_volume   201.698
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.500  0.500  1.0
  Sb  Sb1  1  0.000  0.500  0.500  1.0
  Sb  Sb2  1  0.500  0.000  0.500  1.0
  Sb  Sb3  1  0.500  0.500  0.000  1.0
  Sb  Sb4  1  0.000  0.000  0.000  1.0
  O  O5  1  0.282  0.743  0.743  1.0
  O  O6  1  0.257  0.257  0.718  1.0
  O  O7  1  0.718  0.257  0.257  1.0
  O  O8  1  0.257  0.718  0.257  1.0
  O  O9  1  0.267  0.267  0.267  1.0
  O  O10  1  0.733  0.733  0.733  1.0
  O  O11  1  0.743  0.282  0.743  1.0
  O  O12  1  0.743  0.743  0.282  1.0
[/CIF]
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The material described by Zn(SbO2)4 crystallizes in the trigonal R-3m space group. Zn(1) is bonded to six equivalent O(1) atoms to form ZnO6 octahedra that share corners with six equivalent Sb(2)O6 octahedra and edges with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 8°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SbO6 octahedra that share edges with two equivalent Zn(1)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and edges with four equivalent Sb(1)O6 octahedra. In the second Sb site, Sb(2) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Zn(1)O6 octahedra and edges with six equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 8°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Zn(1), one Sb(2), and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to three equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_Zn(SbO2)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.328
_cell_length_b   6.328
_cell_length_c   6.328
_cell_angle_alpha   65.805
_cell_angle_beta   65.805
_cell_angle_gamma   65.805
_symmetry_Int_Tables_number   1
_cell_volume   201.698
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.500  0.500  1.0
  Sb  Sb1  1  0.000  0.500  0.500  1.0
  Sb  Sb2  1  0.500  0.000  0.500  1.0
  Sb  Sb3  1  0.500  0.500  0.000  1.0
  Sb  Sb4  1  0.000  0.000  0.000  1.0
  O  O5  1  0.282  0.743  0.743  1.0
  O  O6  1  0.257  0.257  0.718  1.0
  O  O7  1  0.718  0.257  0.257  1.0
  O  O8  1  0.257  0.718  0.257  1.0
  O  O9  1  0.267  0.267  0.267  1.0
  O  O10  1  0.733  0.733  0.733  1.0
  O  O11  1  0.743  0.282  0.743  1.0
  O  O12  1  0.743  0.743  0.282  1.0
[/CIF]
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