The compound described by W3P crystallizes in the tetragonal I-42m space group. There are three inequivalent W sites. In the first W site, W(1) is bonded in a 2-coordinate geometry to two equivalent P(1) atoms. In the second W site, W(2) is bonded in a distorted bent 120 degrees geometry to two equivalent P(1) atoms. In the third W site, W(3) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. P(1) is bonded in a 8-coordinate geometry to two equivalent W(1), two equivalent W(2), and four equivalent W(3) atoms. is represented by the CIF card [CIF]
data_PW3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.399
_cell_length_b   7.399
_cell_length_c   7.399
_cell_angle_alpha   96.196
_cell_angle_beta   96.196
_cell_angle_gamma   141.641
_symmetry_Int_Tables_number   1
_cell_volume   237.465
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.292  0.000  0.292  1.0
  P  P1  1  0.708  0.000  0.708  1.0
  P  P2  1  0.000  0.708  0.708  1.0
  P  P3  1  0.000  0.292  0.292  1.0
  W  W4  1  0.362  0.362  0.188  1.0
  W  W5  1  0.174  0.174  0.812  1.0
  W  W6  1  0.826  0.638  0.000  1.0
  W  W7  1  0.638  0.826  0.000  1.0
  W  W8  1  0.574  0.574  0.601  1.0
  W  W9  1  0.972  0.972  0.399  1.0
  W  W10  1  0.028  0.426  0.000  1.0
  W  W11  1  0.426  0.028  0.000  1.0
  W  W12  1  0.854  0.500  0.354  1.0
  W  W13  1  0.146  0.500  0.646  1.0
  W  W14  1  0.500  0.146  0.646  1.0
  W  W15  1  0.500  0.854  0.354  1.0
[/CIF]
.
The compound described by W3P crystallizes in the tetragonal I-42m space group. There are three inequivalent W sites. In the first W site, W(1) is bonded in a 2-coordinate geometry to two equivalent P(1) atoms. In the second W site, W(2) is bonded in a distorted bent 120 degrees geometry to two equivalent P(1) atoms. In the third W site, W(3) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. P(1) is bonded in a 8-coordinate geometry to two equivalent W(1), two equivalent W(2), and four equivalent W(3) atoms. is represented by the CIF card [CIF]
data_PW3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.399
_cell_length_b   7.399
_cell_length_c   7.399
_cell_angle_alpha   96.196
_cell_angle_beta   96.196
_cell_angle_gamma   141.641
_symmetry_Int_Tables_number   1
_cell_volume   237.465
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.292  0.000  0.292  1.0
  P  P1  1  0.708  0.000  0.708  1.0
  P  P2  1  0.000  0.708  0.708  1.0
  P  P3  1  0.000  0.292  0.292  1.0
  W  W4  1  0.362  0.362  0.188  1.0
  W  W5  1  0.174  0.174  0.812  1.0
  W  W6  1  0.826  0.638  0.000  1.0
  W  W7  1  0.638  0.826  0.000  1.0
  W  W8  1  0.574  0.574  0.601  1.0
  W  W9  1  0.972  0.972  0.399  1.0
  W  W10  1  0.028  0.426  0.000  1.0
  W  W11  1  0.426  0.028  0.000  1.0
  W  W12  1  0.854  0.500  0.354  1.0
  W  W13  1  0.146  0.500  0.646  1.0
  W  W14  1  0.500  0.146  0.646  1.0
  W  W15  1  0.500  0.854  0.354  1.0
[/CIF]
.