The crystal structure described by Ce2Rh3Sb4 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 15-coordinate geometry to one Rh(3), two equivalent Rh(2), three equivalent Rh(1), one Sb(1), two equivalent Sb(4), three equivalent Sb(2), and three equivalent Sb(3) atoms. In the second Ce site, Ce(2) is bonded in a 17-coordinate geometry to two equivalent Rh(1), three equivalent Rh(2), three equivalent Rh(3), one Sb(3), two equivalent Sb(2), three equivalent Sb(1), and three equivalent Sb(4) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(3) is bonded in a 8-coordinate geometry to one Ce(1), three equivalent Ce(2), one Sb(2), and three equivalent Sb(4) atoms. In the second Rh site, Rh(1) is bonded in a 7-coordinate geometry to two equivalent Ce(2), three equivalent Ce(1), one Sb(1), one Sb(2), one Sb(4), and two equivalent Sb(3) atoms. In the third Rh site, Rh(2) is bonded in a 5-coordinate geometry to two equivalent Ce(1), three equivalent Ce(2), one Sb(2), one Sb(3), and three equivalent Sb(1) atoms. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to one Ce(1), three equivalent Ce(2), one Rh(1), and three equivalent Rh(2) atoms. In the second Sb site, Sb(2) is bonded in a 7-coordinate geometry to two equivalent Ce(2), three equivalent Ce(1), one Rh(1), one Rh(2), and one Rh(3) atom. In the third Sb site, Sb(3) is bonded in a 6-coordinate geometry to one Ce(2), three equivalent Ce(1), one Rh(2), and two equivalent Rh(1) atoms. In the fourth Sb site, Sb(4) is bonded in a 8-coordinate geometry to two equivalent Ce(1), three equivalent Ce(2), one Rh(1), and three equivalent Rh(3) atoms. is represented by the CIF card [CIF]
data_Ce2Sb4Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.579
_cell_length_b   10.937
_cell_length_c   16.253
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   813.843
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.250  0.584  0.750  1.0
  Ce  Ce1  1  0.250  0.916  0.250  1.0
  Ce  Ce2  1  0.750  0.416  0.250  1.0
  Ce  Ce3  1  0.750  0.084  0.750  1.0
  Ce  Ce4  1  0.250  0.746  0.503  1.0
  Ce  Ce5  1  0.250  0.754  0.003  1.0
  Ce  Ce6  1  0.750  0.254  0.497  1.0
  Ce  Ce7  1  0.750  0.246  0.997  1.0
  Sb  Sb8  1  0.250  0.445  0.932  1.0
  Sb  Sb9  1  0.250  0.055  0.432  1.0
  Sb  Sb10  1  0.750  0.555  0.068  1.0
  Sb  Sb11  1  0.750  0.945  0.568  1.0
  Sb  Sb12  1  0.250  0.271  0.651  1.0
  Sb  Sb13  1  0.250  0.229  0.151  1.0
  Sb  Sb14  1  0.750  0.729  0.349  1.0
  Sb  Sb15  1  0.750  0.771  0.849  1.0
  Sb  Sb16  1  0.250  0.883  0.710  1.0
  Sb  Sb17  1  0.250  0.617  0.210  1.0
  Sb  Sb18  1  0.750  0.117  0.290  1.0
  Sb  Sb19  1  0.750  0.383  0.790  1.0
  Sb  Sb20  1  0.250  0.063  0.896  1.0
  Sb  Sb21  1  0.250  0.437  0.396  1.0
  Sb  Sb22  1  0.750  0.937  0.104  1.0
  Sb  Sb23  1  0.750  0.563  0.604  1.0
  Rh  Rh24  1  0.250  0.274  0.817  1.0
  Rh  Rh25  1  0.250  0.226  0.317  1.0
  Rh  Rh26  1  0.750  0.726  0.183  1.0
  Rh  Rh27  1  0.750  0.774  0.683  1.0
  Rh  Rh28  1  0.250  0.053  0.593  1.0
  Rh  Rh29  1  0.250  0.447  0.093  1.0
  Rh  Rh30  1  0.750  0.947  0.407  1.0
  Rh  Rh31  1  0.750  0.553  0.907  1.0
  Rh  Rh32  1  0.250  0.465  0.557  1.0
  Rh  Rh33  1  0.250  0.035  0.057  1.0
  Rh  Rh34  1  0.750  0.535  0.443  1.0
  Rh  Rh35  1  0.750  0.965  0.943  1.0
[/CIF]
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The crystal structure described by Ce2Rh3Sb4 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 15-coordinate geometry to one Rh(3), two equivalent Rh(2), three equivalent Rh(1), one Sb(1), two equivalent Sb(4), three equivalent Sb(2), and three equivalent Sb(3) atoms. In the second Ce site, Ce(2) is bonded in a 17-coordinate geometry to two equivalent Rh(1), three equivalent Rh(2), three equivalent Rh(3), one Sb(3), two equivalent Sb(2), three equivalent Sb(1), and three equivalent Sb(4) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(3) is bonded in a 8-coordinate geometry to one Ce(1), three equivalent Ce(2), one Sb(2), and three equivalent Sb(4) atoms. In the second Rh site, Rh(1) is bonded in a 7-coordinate geometry to two equivalent Ce(2), three equivalent Ce(1), one Sb(1), one Sb(2), one Sb(4), and two equivalent Sb(3) atoms. In the third Rh site, Rh(2) is bonded in a 5-coordinate geometry to two equivalent Ce(1), three equivalent Ce(2), one Sb(2), one Sb(3), and three equivalent Sb(1) atoms. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to one Ce(1), three equivalent Ce(2), one Rh(1), and three equivalent Rh(2) atoms. In the second Sb site, Sb(2) is bonded in a 7-coordinate geometry to two equivalent Ce(2), three equivalent Ce(1), one Rh(1), one Rh(2), and one Rh(3) atom. In the third Sb site, Sb(3) is bonded in a 6-coordinate geometry to one Ce(2), three equivalent Ce(1), one Rh(2), and two equivalent Rh(1) atoms. In the fourth Sb site, Sb(4) is bonded in a 8-coordinate geometry to two equivalent Ce(1), three equivalent Ce(2), one Rh(1), and three equivalent Rh(3) atoms. is represented by the CIF card [CIF]
data_Ce2Sb4Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.579
_cell_length_b   10.937
_cell_length_c   16.253
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   813.843
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.250  0.584  0.750  1.0
  Ce  Ce1  1  0.250  0.916  0.250  1.0
  Ce  Ce2  1  0.750  0.416  0.250  1.0
  Ce  Ce3  1  0.750  0.084  0.750  1.0
  Ce  Ce4  1  0.250  0.746  0.503  1.0
  Ce  Ce5  1  0.250  0.754  0.003  1.0
  Ce  Ce6  1  0.750  0.254  0.497  1.0
  Ce  Ce7  1  0.750  0.246  0.997  1.0
  Sb  Sb8  1  0.250  0.445  0.932  1.0
  Sb  Sb9  1  0.250  0.055  0.432  1.0
  Sb  Sb10  1  0.750  0.555  0.068  1.0
  Sb  Sb11  1  0.750  0.945  0.568  1.0
  Sb  Sb12  1  0.250  0.271  0.651  1.0
  Sb  Sb13  1  0.250  0.229  0.151  1.0
  Sb  Sb14  1  0.750  0.729  0.349  1.0
  Sb  Sb15  1  0.750  0.771  0.849  1.0
  Sb  Sb16  1  0.250  0.883  0.710  1.0
  Sb  Sb17  1  0.250  0.617  0.210  1.0
  Sb  Sb18  1  0.750  0.117  0.290  1.0
  Sb  Sb19  1  0.750  0.383  0.790  1.0
  Sb  Sb20  1  0.250  0.063  0.896  1.0
  Sb  Sb21  1  0.250  0.437  0.396  1.0
  Sb  Sb22  1  0.750  0.937  0.104  1.0
  Sb  Sb23  1  0.750  0.563  0.604  1.0
  Rh  Rh24  1  0.250  0.274  0.817  1.0
  Rh  Rh25  1  0.250  0.226  0.317  1.0
  Rh  Rh26  1  0.750  0.726  0.183  1.0
  Rh  Rh27  1  0.750  0.774  0.683  1.0
  Rh  Rh28  1  0.250  0.053  0.593  1.0
  Rh  Rh29  1  0.250  0.447  0.093  1.0
  Rh  Rh30  1  0.750  0.947  0.407  1.0
  Rh  Rh31  1  0.750  0.553  0.907  1.0
  Rh  Rh32  1  0.250  0.465  0.557  1.0
  Rh  Rh33  1  0.250  0.035  0.057  1.0
  Rh  Rh34  1  0.750  0.535  0.443  1.0
  Rh  Rh35  1  0.750  0.965  0.943  1.0
[/CIF]
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