The structure described by Rb2Li4UO6 crystallizes in the trigonal P-3m1 space group. Rb(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. In the second Li site, Li(2) is bonded to six equivalent O(1) atoms to form distorted LiO6 octahedra that share faces with two equivalent U(1)O6 octahedra. U(1) is bonded to six equivalent O(1) atoms to form UO6 octahedra that share faces with two equivalent Li(2)O6 octahedra. O(1) is bonded in a 5-coordinate geometry to one Rb(1), one Li(2), two equivalent Li(1), and one U(1) atom. is represented by the CIF card [CIF]
data_Rb2Li4UO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.762
_cell_length_b   6.160
_cell_length_c   6.160
_cell_angle_alpha   120.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   189.330
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.551  0.667  0.333  1.0
  Rb  Rb1  1  0.449  0.333  0.667  1.0
  Li  Li2  1  0.000  0.500  0.500  1.0
  Li  Li3  1  0.000  0.000  0.500  1.0
  Li  Li4  1  0.000  0.500  0.000  1.0
  Li  Li5  1  0.500  0.000  0.000  1.0
  U  U6  1  0.000  0.000  0.000  1.0
  O  O7  1  0.799  0.163  0.326  1.0
  O  O8  1  0.201  0.837  0.674  1.0
  O  O9  1  0.799  0.163  0.837  1.0
  O  O10  1  0.201  0.837  0.163  1.0
  O  O11  1  0.799  0.674  0.837  1.0
  O  O12  1  0.201  0.326  0.163  1.0
[/CIF]
.
The structure described by Rb2Li4UO6 crystallizes in the trigonal P-3m1 space group. Rb(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. In the second Li site, Li(2) is bonded to six equivalent O(1) atoms to form distorted LiO6 octahedra that share faces with two equivalent U(1)O6 octahedra. U(1) is bonded to six equivalent O(1) atoms to form UO6 octahedra that share faces with two equivalent Li(2)O6 octahedra. O(1) is bonded in a 5-coordinate geometry to one Rb(1), one Li(2), two equivalent Li(1), and one U(1) atom. is represented by the CIF card [CIF]
data_Rb2Li4UO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.762
_cell_length_b   6.160
_cell_length_c   6.160
_cell_angle_alpha   120.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   189.330
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.551  0.667  0.333  1.0
  Rb  Rb1  1  0.449  0.333  0.667  1.0
  Li  Li2  1  0.000  0.500  0.500  1.0
  Li  Li3  1  0.000  0.000  0.500  1.0
  Li  Li4  1  0.000  0.500  0.000  1.0
  Li  Li5  1  0.500  0.000  0.000  1.0
  U  U6  1  0.000  0.000  0.000  1.0
  O  O7  1  0.799  0.163  0.326  1.0
  O  O8  1  0.201  0.837  0.674  1.0
  O  O9  1  0.799  0.163  0.837  1.0
  O  O10  1  0.201  0.837  0.163  1.0
  O  O11  1  0.799  0.674  0.837  1.0
  O  O12  1  0.201  0.326  0.163  1.0
[/CIF]
.