The compound described by LaOsN3 crystallizes in the monoclinic P2_1/m space group. La(1) is bonded in a 1-coordinate geometry to three equivalent N(2) and four equivalent N(3) atoms. Os(1) is bonded in a T-shaped geometry to one N(1) and two equivalent N(2) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one Os(1) and one N(3) atom. In the second N site, N(2) is bonded to three equivalent La(1) and two equivalent Os(1) atoms to form a mixture of distorted edge and corner-sharing NLa3Os2 trigonal bipyramids. In the third N site, N(3) is bonded in a 5-coordinate geometry to four equivalent La(1) and one N(1) atom. is represented by the CIF card [CIF]
data_LaOsN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.767
_cell_length_b   3.837
_cell_length_c   7.409
_cell_angle_alpha   82.885
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   134.457
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.250  0.919  0.287  1.0
  La  La1  1  0.750  0.081  0.713  1.0
  Os  Os2  1  0.750  0.484  0.094  1.0
  Os  Os3  1  0.250  0.516  0.906  1.0
  N  N4  1  0.250  0.539  0.632  1.0
  N  N5  1  0.750  0.461  0.368  1.0
  N  N6  1  0.750  0.985  0.093  1.0
  N  N7  1  0.250  0.297  0.535  1.0
  N  N8  1  0.750  0.703  0.465  1.0
  N  N9  1  0.250  0.015  0.907  1.0
[/CIF]
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The compound described by LaOsN3 crystallizes in the monoclinic P2_1/m space group. La(1) is bonded in a 1-coordinate geometry to three equivalent N(2) and four equivalent N(3) atoms. Os(1) is bonded in a T-shaped geometry to one N(1) and two equivalent N(2) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 2-coordinate geometry to one Os(1) and one N(3) atom. In the second N site, N(2) is bonded to three equivalent La(1) and two equivalent Os(1) atoms to form a mixture of distorted edge and corner-sharing NLa3Os2 trigonal bipyramids. In the third N site, N(3) is bonded in a 5-coordinate geometry to four equivalent La(1) and one N(1) atom. is represented by the CIF card [CIF]
data_LaOsN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.767
_cell_length_b   3.837
_cell_length_c   7.409
_cell_angle_alpha   82.885
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   134.457
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.250  0.919  0.287  1.0
  La  La1  1  0.750  0.081  0.713  1.0
  Os  Os2  1  0.750  0.484  0.094  1.0
  Os  Os3  1  0.250  0.516  0.906  1.0
  N  N4  1  0.250  0.539  0.632  1.0
  N  N5  1  0.750  0.461  0.368  1.0
  N  N6  1  0.750  0.985  0.093  1.0
  N  N7  1  0.250  0.297  0.535  1.0
  N  N8  1  0.750  0.703  0.465  1.0
  N  N9  1  0.250  0.015  0.907  1.0
[/CIF]
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