The material structure described by InGaO3(ZnO)3 is Aluminum carbonitride-derived structured and crystallizes in the trigonal R3m space group. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(6) and three equivalent O(1) atoms to form ZnO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra, corners with three equivalent Zn(3)O4 tetrahedra, and corners with six equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 60°. In the second Zn site, Zn(2) is bonded to one O(5) and three equivalent O(2) atoms to form ZnO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra, corners with six equivalent Zn(2)O4 tetrahedra, and corners with three equivalent Ga(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 60°. In the third Zn site, Zn(3) is bonded to one O(1) and three equivalent O(3) atoms to form ZnO4 tetrahedra that share corners with three equivalent Zn(1)O4 tetrahedra, corners with six equivalent Zn(3)O4 tetrahedra, and corners with three equivalent Ga(1)O5 trigonal bipyramids. In(1) is bonded to three equivalent O(5) and three equivalent O(6) atoms to form InO6 octahedra that share corners with three equivalent Zn(1)O4 tetrahedra, corners with three equivalent Zn(2)O4 tetrahedra, and edges with six equivalent In(1)O6 octahedra. Ga(1) is bonded to one O(2), one O(3), and three equivalent O(4) atoms to form GaO5 trigonal bipyramids that share corners with three equivalent Zn(2)O4 tetrahedra, corners with three equivalent Zn(3)O4 tetrahedra, and corners with six equivalent Ga(1)O5 trigonal bipyramids. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Zn(3) and three equivalent Zn(1) atoms to form OZn4 tetrahedra that share corners with three equivalent O(3)Zn3Ga tetrahedra, corners with three equivalent O(6)ZnIn3 tetrahedra, and corners with six equivalent O(1)Zn4 tetrahedra. In the second O site, O(2) is bonded to three equivalent Zn(2) and one Ga(1) atom to form OZn3Ga tetrahedra that share  a cornercorner with one O(3)Zn3Ga tetrahedra, corners with three equivalent O(5)ZnIn3 tetrahedra, and corners with six equivalent O(2)Zn3Ga tetrahedra. In the third O site, O(3) is bonded to three equivalent Zn(3) and one Ga(1) atom to form OZn3Ga tetrahedra that share  a cornercorner with one O(2)Zn3Ga tetrahedra, corners with three equivalent O(1)Zn4 tetrahedra, and corners with six equivalent O(3)Zn3Ga tetrahedra. In the fourth O site, O(4) is bonded in a trigonal planar geometry to three equivalent Ga(1) atoms. In the fifth O site, O(5) is bonded to one Zn(2) and three equivalent In(1) atoms to form distorted OZnIn3 tetrahedra that share corners with three equivalent O(2)Zn3Ga tetrahedra, corners with three equivalent O(6)ZnIn3 tetrahedra, corners with six equivalent O(5)ZnIn3 tetrahedra, and edges with three equivalent O(6)ZnIn3 tetrahedra. In the sixth O site, O(6) is bonded to one Zn(1) and three equivalent In(1) atoms to form distorted OZnIn3 tetrahedra that share corners with three equivalent O(1)Zn4 tetrahedra, corners with three equivalent O(5)ZnIn3 tetrahedra, corners with six equivalent O(6)ZnIn3 tetrahedra, and edges with three equivalent O(5)ZnIn3 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn3InGaO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.173
_cell_length_b   14.173
_cell_length_c   14.173
_cell_angle_alpha   13.521
_cell_angle_beta   13.521
_cell_angle_gamma   13.521
_symmetry_Int_Tables_number   1
_cell_volume   135.410
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.261  0.261  0.261  1.0
  Zn  Zn1  1  0.741  0.741  0.741  1.0
  Zn  Zn2  1  0.866  0.866  0.866  1.0
  In  In3  1  0.001  0.001  0.001  1.0
  Ga  Ga4  1  0.137  0.137  0.137  1.0
  O  O5  1  0.913  0.913  0.913  1.0
  O  O6  1  0.090  0.090  0.090  1.0
  O  O7  1  0.185  0.185  0.185  1.0
  O  O8  1  0.804  0.804  0.804  1.0
  O  O9  1  0.694  0.694  0.694  1.0
  O  O10  1  0.308  0.308  0.308  1.0
[/CIF]
.
The material structure described by InGaO3(ZnO)3 is Aluminum carbonitride-derived structured and crystallizes in the trigonal R3m space group. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(6) and three equivalent O(1) atoms to form ZnO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra, corners with three equivalent Zn(3)O4 tetrahedra, and corners with six equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 60°. In the second Zn site, Zn(2) is bonded to one O(5) and three equivalent O(2) atoms to form ZnO4 tetrahedra that share corners with three equivalent In(1)O6 octahedra, corners with six equivalent Zn(2)O4 tetrahedra, and corners with three equivalent Ga(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 60°. In the third Zn site, Zn(3) is bonded to one O(1) and three equivalent O(3) atoms to form ZnO4 tetrahedra that share corners with three equivalent Zn(1)O4 tetrahedra, corners with six equivalent Zn(3)O4 tetrahedra, and corners with three equivalent Ga(1)O5 trigonal bipyramids. In(1) is bonded to three equivalent O(5) and three equivalent O(6) atoms to form InO6 octahedra that share corners with three equivalent Zn(1)O4 tetrahedra, corners with three equivalent Zn(2)O4 tetrahedra, and edges with six equivalent In(1)O6 octahedra. Ga(1) is bonded to one O(2), one O(3), and three equivalent O(4) atoms to form GaO5 trigonal bipyramids that share corners with three equivalent Zn(2)O4 tetrahedra, corners with three equivalent Zn(3)O4 tetrahedra, and corners with six equivalent Ga(1)O5 trigonal bipyramids. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Zn(3) and three equivalent Zn(1) atoms to form OZn4 tetrahedra that share corners with three equivalent O(3)Zn3Ga tetrahedra, corners with three equivalent O(6)ZnIn3 tetrahedra, and corners with six equivalent O(1)Zn4 tetrahedra. In the second O site, O(2) is bonded to three equivalent Zn(2) and one Ga(1) atom to form OZn3Ga tetrahedra that share  a cornercorner with one O(3)Zn3Ga tetrahedra, corners with three equivalent O(5)ZnIn3 tetrahedra, and corners with six equivalent O(2)Zn3Ga tetrahedra. In the third O site, O(3) is bonded to three equivalent Zn(3) and one Ga(1) atom to form OZn3Ga tetrahedra that share  a cornercorner with one O(2)Zn3Ga tetrahedra, corners with three equivalent O(1)Zn4 tetrahedra, and corners with six equivalent O(3)Zn3Ga tetrahedra. In the fourth O site, O(4) is bonded in a trigonal planar geometry to three equivalent Ga(1) atoms. In the fifth O site, O(5) is bonded to one Zn(2) and three equivalent In(1) atoms to form distorted OZnIn3 tetrahedra that share corners with three equivalent O(2)Zn3Ga tetrahedra, corners with three equivalent O(6)ZnIn3 tetrahedra, corners with six equivalent O(5)ZnIn3 tetrahedra, and edges with three equivalent O(6)ZnIn3 tetrahedra. In the sixth O site, O(6) is bonded to one Zn(1) and three equivalent In(1) atoms to form distorted OZnIn3 tetrahedra that share corners with three equivalent O(1)Zn4 tetrahedra, corners with three equivalent O(5)ZnIn3 tetrahedra, corners with six equivalent O(6)ZnIn3 tetrahedra, and edges with three equivalent O(5)ZnIn3 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn3InGaO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.173
_cell_length_b   14.173
_cell_length_c   14.173
_cell_angle_alpha   13.521
_cell_angle_beta   13.521
_cell_angle_gamma   13.521
_symmetry_Int_Tables_number   1
_cell_volume   135.410
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.261  0.261  0.261  1.0
  Zn  Zn1  1  0.741  0.741  0.741  1.0
  Zn  Zn2  1  0.866  0.866  0.866  1.0
  In  In3  1  0.001  0.001  0.001  1.0
  Ga  Ga4  1  0.137  0.137  0.137  1.0
  O  O5  1  0.913  0.913  0.913  1.0
  O  O6  1  0.090  0.090  0.090  1.0
  O  O7  1  0.185  0.185  0.185  1.0
  O  O8  1  0.804  0.804  0.804  1.0
  O  O9  1  0.694  0.694  0.694  1.0
  O  O10  1  0.308  0.308  0.308  1.0
[/CIF]
.