The structure described by CaCd2(O2Cl3)2O2 crystallizes in the triclinic P-1 space group. The structure consists of two hydrogen peroxide molecules inside a CaCd2(O2Cl3)2 framework. In the CaCd2(O2Cl3)2 framework, Ca(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(5), one O(6), one Cl(1), one Cl(2), and one Cl(6) atom. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one Cl(1), one Cl(4), one Cl(5), one Cl(6), and two equivalent Cl(3) atoms to form edge-sharing CdCl6 octahedra. In the second Cd site, Cd(2) is bonded to one Cl(2), one Cl(3), one Cl(5), one Cl(6), and two equivalent Cl(4) atoms to form edge-sharing CdCl6 octahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Ca(1) and one O(5) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Ca(1) and one O(6) atom. In the third O site, O(5) is bonded in a distorted L-shaped geometry to one Ca(1) and one O(1) atom. In the fourth O site, O(6) is bonded in a 2-coordinate geometry to one Ca(1) and one O(2) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted bent 120 degrees geometry to one Ca(1) and one Cd(1) atom. In the second Cl site, Cl(2) is bonded in a distorted bent 150 degrees geometry to one Ca(1) and one Cd(2) atom. In the third Cl site, Cl(3) is bonded in a distorted T-shaped geometry to one Cd(2) and two equivalent Cd(1) atoms. In the fourth Cl site, Cl(4) is bonded in a distorted trigonal non-coplanar geometry to one Cd(1) and two equivalent Cd(2) atoms. In the fifth Cl site, Cl(5) is bonded in a water-like geometry to one Cd(1) and one Cd(2) atom. In the sixth Cl site, Cl(6) is bonded in a distorted trigonal planar geometry to one Ca(1), one Cd(1), and one Cd(2) atom. is represented by the CIF file [CIF]
data_CaCd2(ClO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.135
_cell_length_b   9.169
_cell_length_c   9.656
_cell_angle_alpha   102.487
_cell_angle_beta   89.299
_cell_angle_gamma   101.418
_symmetry_Int_Tables_number   1
_cell_volume   688.992
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.674  0.878  0.141  1.0
  Ca  Ca1  1  0.326  0.122  0.859  1.0
  Cd  Cd2  1  0.134  0.568  0.692  1.0
  Cd  Cd3  1  0.866  0.432  0.308  1.0
  Cd  Cd4  1  0.652  0.546  0.684  1.0
  Cd  Cd5  1  0.348  0.454  0.316  1.0
  Cl  Cl6  1  0.233  0.831  0.880  1.0
  Cl  Cl7  1  0.767  0.169  0.120  1.0
  Cl  Cl8  1  0.690  0.802  0.870  1.0
  Cl  Cl9  1  0.310  0.198  0.130  1.0
  Cl  Cl10  1  0.915  0.671  0.538  1.0
  Cl  Cl11  1  0.085  0.329  0.462  1.0
  Cl  Cl12  1  0.406  0.660  0.555  1.0
  Cl  Cl13  1  0.594  0.340  0.445  1.0
  Cl  Cl14  1  0.122  0.536  0.179  1.0
  Cl  Cl15  1  0.878  0.464  0.821  1.0
  Cl  Cl16  1  0.631  0.602  0.209  1.0
  Cl  Cl17  1  0.369  0.398  0.791  1.0
  O  O18  1  0.001  0.026  0.764  1.0
  O  O19  1  0.999  0.974  0.236  1.0
  O  O20  1  0.559  0.001  0.717  1.0
  O  O21  1  0.441  0.999  0.283  1.0
  O  O22  1  0.227  0.915  0.450  1.0
  O  O23  1  0.773  0.085  0.550  1.0
  O  O24  1  0.690  0.954  0.525  1.0
  O  O25  1  0.310  0.046  0.475  1.0
  O  O26  1  0.995  0.839  0.173  1.0
  O  O27  1  0.005  0.161  0.827  1.0
  O  O28  1  0.358  0.865  0.253  1.0
  O  O29  1  0.642  0.135  0.747  1.0
[/CIF]
.
The structure described by CaCd2(O2Cl3)2O2 crystallizes in the triclinic P-1 space group. The structure consists of two hydrogen peroxide molecules inside a CaCd2(O2Cl3)2 framework. In the CaCd2(O2Cl3)2 framework, Ca(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(5), one O(6), one Cl(1), one Cl(2), and one Cl(6) atom. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one Cl(1), one Cl(4), one Cl(5), one Cl(6), and two equivalent Cl(3) atoms to form edge-sharing CdCl6 octahedra. In the second Cd site, Cd(2) is bonded to one Cl(2), one Cl(3), one Cl(5), one Cl(6), and two equivalent Cl(4) atoms to form edge-sharing CdCl6 octahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Ca(1) and one O(5) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Ca(1) and one O(6) atom. In the third O site, O(5) is bonded in a distorted L-shaped geometry to one Ca(1) and one O(1) atom. In the fourth O site, O(6) is bonded in a 2-coordinate geometry to one Ca(1) and one O(2) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted bent 120 degrees geometry to one Ca(1) and one Cd(1) atom. In the second Cl site, Cl(2) is bonded in a distorted bent 150 degrees geometry to one Ca(1) and one Cd(2) atom. In the third Cl site, Cl(3) is bonded in a distorted T-shaped geometry to one Cd(2) and two equivalent Cd(1) atoms. In the fourth Cl site, Cl(4) is bonded in a distorted trigonal non-coplanar geometry to one Cd(1) and two equivalent Cd(2) atoms. In the fifth Cl site, Cl(5) is bonded in a water-like geometry to one Cd(1) and one Cd(2) atom. In the sixth Cl site, Cl(6) is bonded in a distorted trigonal planar geometry to one Ca(1), one Cd(1), and one Cd(2) atom. is represented by the CIF file [CIF]
data_CaCd2(ClO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.135
_cell_length_b   9.169
_cell_length_c   9.656
_cell_angle_alpha   102.487
_cell_angle_beta   89.299
_cell_angle_gamma   101.418
_symmetry_Int_Tables_number   1
_cell_volume   688.992
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.674  0.878  0.141  1.0
  Ca  Ca1  1  0.326  0.122  0.859  1.0
  Cd  Cd2  1  0.134  0.568  0.692  1.0
  Cd  Cd3  1  0.866  0.432  0.308  1.0
  Cd  Cd4  1  0.652  0.546  0.684  1.0
  Cd  Cd5  1  0.348  0.454  0.316  1.0
  Cl  Cl6  1  0.233  0.831  0.880  1.0
  Cl  Cl7  1  0.767  0.169  0.120  1.0
  Cl  Cl8  1  0.690  0.802  0.870  1.0
  Cl  Cl9  1  0.310  0.198  0.130  1.0
  Cl  Cl10  1  0.915  0.671  0.538  1.0
  Cl  Cl11  1  0.085  0.329  0.462  1.0
  Cl  Cl12  1  0.406  0.660  0.555  1.0
  Cl  Cl13  1  0.594  0.340  0.445  1.0
  Cl  Cl14  1  0.122  0.536  0.179  1.0
  Cl  Cl15  1  0.878  0.464  0.821  1.0
  Cl  Cl16  1  0.631  0.602  0.209  1.0
  Cl  Cl17  1  0.369  0.398  0.791  1.0
  O  O18  1  0.001  0.026  0.764  1.0
  O  O19  1  0.999  0.974  0.236  1.0
  O  O20  1  0.559  0.001  0.717  1.0
  O  O21  1  0.441  0.999  0.283  1.0
  O  O22  1  0.227  0.915  0.450  1.0
  O  O23  1  0.773  0.085  0.550  1.0
  O  O24  1  0.690  0.954  0.525  1.0
  O  O25  1  0.310  0.046  0.475  1.0
  O  O26  1  0.995  0.839  0.173  1.0
  O  O27  1  0.005  0.161  0.827  1.0
  O  O28  1  0.358  0.865  0.253  1.0
  O  O29  1  0.642  0.135  0.747  1.0
[/CIF]
.