The crystal structure described by KMoPO7 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 9-coordinate geometry to one O(3), one O(4), one O(5), one O(6), one O(7), two equivalent O(1), and two equivalent O(2) atoms. Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(7) atom. P(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(5), and one O(6) atom. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a distorted single-bond geometry to one K(1) and one P(1) atom. In the second O site, O(7) is bonded in a water-like geometry to one K(1) and one Mo(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Mo(1) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Mo(1) atom. In the fifth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one K(1), one Mo(1), and one P(1) atom. In the sixth O site, O(4) is bonded in a 2-coordinate geometry to one K(1), one Mo(1), and one P(1) atom. In the seventh O site, O(5) is bonded in a 3-coordinate geometry to one K(1), one Mo(1), and one P(1) atom. is represented by the CIF file [CIF]
data_KMoPO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.644
_cell_length_b   5.912
_cell_length_c   12.201
_cell_angle_alpha   80.902
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   615.657
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.611  0.172  0.329  1.0
  K  K1  1  0.889  0.672  0.829  1.0
  K  K2  1  0.389  0.828  0.671  1.0
  K  K3  1  0.111  0.328  0.171  1.0
  Mo  Mo4  1  0.757  0.812  0.110  1.0
  Mo  Mo5  1  0.743  0.312  0.610  1.0
  Mo  Mo6  1  0.243  0.188  0.890  1.0
  Mo  Mo7  1  0.257  0.688  0.390  1.0
  P  P8  1  0.868  0.645  0.371  1.0
  P  P9  1  0.632  0.145  0.871  1.0
  P  P10  1  0.132  0.355  0.629  1.0
  P  P11  1  0.368  0.855  0.129  1.0
  O  O12  1  0.846  0.051  0.149  1.0
  O  O13  1  0.654  0.551  0.649  1.0
  O  O14  1  0.154  0.949  0.851  1.0
  O  O15  1  0.346  0.449  0.351  1.0
  O  O16  1  0.908  0.652  0.067  1.0
  O  O17  1  0.592  0.152  0.567  1.0
  O  O18  1  0.092  0.348  0.933  1.0
  O  O19  1  0.408  0.848  0.433  1.0
  O  O20  1  0.811  0.436  0.457  1.0
  O  O21  1  0.689  0.936  0.957  1.0
  O  O22  1  0.189  0.564  0.543  1.0
  O  O23  1  0.311  0.064  0.043  1.0
  O  O24  1  0.759  0.633  0.269  1.0
  O  O25  1  0.741  0.133  0.769  1.0
  O  O26  1  0.241  0.367  0.731  1.0
  O  O27  1  0.259  0.867  0.231  1.0
  O  O28  1  0.034  0.593  0.337  1.0
  O  O29  1  0.466  0.093  0.837  1.0
  O  O30  1  0.966  0.407  0.663  1.0
  O  O31  1  0.534  0.907  0.163  1.0
  O  O32  1  0.852  0.874  0.414  1.0
  O  O33  1  0.648  0.374  0.914  1.0
  O  O34  1  0.148  0.126  0.586  1.0
  O  O35  1  0.352  0.626  0.086  1.0
  O  O36  1  0.603  0.495  0.107  1.0
  O  O37  1  0.897  0.995  0.607  1.0
  O  O38  1  0.397  0.505  0.893  1.0
  O  O39  1  0.103  0.005  0.393  1.0
[/CIF]
.
The crystal structure described by KMoPO7 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 9-coordinate geometry to one O(3), one O(4), one O(5), one O(6), one O(7), two equivalent O(1), and two equivalent O(2) atoms. Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(7) atom. P(1) is bonded in a tetrahedral geometry to one O(3), one O(4), one O(5), and one O(6) atom. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a distorted single-bond geometry to one K(1) and one P(1) atom. In the second O site, O(7) is bonded in a water-like geometry to one K(1) and one Mo(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Mo(1) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one Mo(1) atom. In the fifth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one K(1), one Mo(1), and one P(1) atom. In the sixth O site, O(4) is bonded in a 2-coordinate geometry to one K(1), one Mo(1), and one P(1) atom. In the seventh O site, O(5) is bonded in a 3-coordinate geometry to one K(1), one Mo(1), and one P(1) atom. is represented by the CIF file [CIF]
data_KMoPO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.644
_cell_length_b   5.912
_cell_length_c   12.201
_cell_angle_alpha   80.902
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   615.657
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.611  0.172  0.329  1.0
  K  K1  1  0.889  0.672  0.829  1.0
  K  K2  1  0.389  0.828  0.671  1.0
  K  K3  1  0.111  0.328  0.171  1.0
  Mo  Mo4  1  0.757  0.812  0.110  1.0
  Mo  Mo5  1  0.743  0.312  0.610  1.0
  Mo  Mo6  1  0.243  0.188  0.890  1.0
  Mo  Mo7  1  0.257  0.688  0.390  1.0
  P  P8  1  0.868  0.645  0.371  1.0
  P  P9  1  0.632  0.145  0.871  1.0
  P  P10  1  0.132  0.355  0.629  1.0
  P  P11  1  0.368  0.855  0.129  1.0
  O  O12  1  0.846  0.051  0.149  1.0
  O  O13  1  0.654  0.551  0.649  1.0
  O  O14  1  0.154  0.949  0.851  1.0
  O  O15  1  0.346  0.449  0.351  1.0
  O  O16  1  0.908  0.652  0.067  1.0
  O  O17  1  0.592  0.152  0.567  1.0
  O  O18  1  0.092  0.348  0.933  1.0
  O  O19  1  0.408  0.848  0.433  1.0
  O  O20  1  0.811  0.436  0.457  1.0
  O  O21  1  0.689  0.936  0.957  1.0
  O  O22  1  0.189  0.564  0.543  1.0
  O  O23  1  0.311  0.064  0.043  1.0
  O  O24  1  0.759  0.633  0.269  1.0
  O  O25  1  0.741  0.133  0.769  1.0
  O  O26  1  0.241  0.367  0.731  1.0
  O  O27  1  0.259  0.867  0.231  1.0
  O  O28  1  0.034  0.593  0.337  1.0
  O  O29  1  0.466  0.093  0.837  1.0
  O  O30  1  0.966  0.407  0.663  1.0
  O  O31  1  0.534  0.907  0.163  1.0
  O  O32  1  0.852  0.874  0.414  1.0
  O  O33  1  0.648  0.374  0.914  1.0
  O  O34  1  0.148  0.126  0.586  1.0
  O  O35  1  0.352  0.626  0.086  1.0
  O  O36  1  0.603  0.495  0.107  1.0
  O  O37  1  0.897  0.995  0.607  1.0
  O  O38  1  0.397  0.505  0.893  1.0
  O  O39  1  0.103  0.005  0.393  1.0
[/CIF]
.