The structure described by CsK2PdF5 crystallizes in the tetragonal P4/mbm space group. Cs(1) is bonded in a distorted q6 geometry to two equivalent F(2) and eight equivalent F(1) atoms. K(1) is bonded in a 8-coordinate geometry to two equivalent F(2) and six equivalent F(1) atoms. Pd(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Cs(1), three equivalent K(1), and one Pd(1) atom to form distorted FCs2K3Pd octahedra that share corners with four equivalent F(2)Cs2K4 octahedra, corners with thirteen equivalent F(1)Cs2K3Pd octahedra, edges with five equivalent F(1)Cs2K3Pd octahedra, faces with two equivalent F(2)Cs2K4 octahedra, and faces with three equivalent F(1)Cs2K3Pd octahedra. The corner-sharing octahedral tilt angles range from 0-79°. In the second F site, F(2) is bonded to two equivalent Cs(1) and four equivalent K(1) atoms to form FCs2K4 octahedra that share corners with six equivalent F(2)Cs2K4 octahedra, corners with sixteen equivalent F(1)Cs2K3Pd octahedra, and faces with eight equivalent F(1)Cs2K3Pd octahedra. The corner-sharing octahedral tilt angles range from 0-64°. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsK2PdF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.301
_cell_length_b   7.301
_cell_length_c   6.205
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   330.784
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.500  0.500  0.000  1.0
  Cs  Cs1  1  0.000  0.000  0.000  1.0
  K  K2  1  0.825  0.325  0.500  1.0
  K  K3  1  0.325  0.175  0.500  1.0
  K  K4  1  0.175  0.675  0.500  1.0
  K  K5  1  0.675  0.825  0.500  1.0
  Pd  Pd6  1  0.500  0.000  0.000  1.0
  Pd  Pd7  1  0.000  0.500  0.000  1.0
  F  F8  1  0.368  0.868  0.773  1.0
  F  F9  1  0.632  0.132  0.773  1.0
  F  F10  1  0.132  0.368  0.773  1.0
  F  F11  1  0.868  0.632  0.773  1.0
  F  F12  1  0.368  0.868  0.227  1.0
  F  F13  1  0.868  0.632  0.227  1.0
  F  F14  1  0.132  0.368  0.227  1.0
  F  F15  1  0.632  0.132  0.227  1.0
  F  F16  1  0.000  0.000  0.500  1.0
  F  F17  1  0.500  0.500  0.500  1.0
[/CIF]
.
The structure described by CsK2PdF5 crystallizes in the tetragonal P4/mbm space group. Cs(1) is bonded in a distorted q6 geometry to two equivalent F(2) and eight equivalent F(1) atoms. K(1) is bonded in a 8-coordinate geometry to two equivalent F(2) and six equivalent F(1) atoms. Pd(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Cs(1), three equivalent K(1), and one Pd(1) atom to form distorted FCs2K3Pd octahedra that share corners with four equivalent F(2)Cs2K4 octahedra, corners with thirteen equivalent F(1)Cs2K3Pd octahedra, edges with five equivalent F(1)Cs2K3Pd octahedra, faces with two equivalent F(2)Cs2K4 octahedra, and faces with three equivalent F(1)Cs2K3Pd octahedra. The corner-sharing octahedral tilt angles range from 0-79°. In the second F site, F(2) is bonded to two equivalent Cs(1) and four equivalent K(1) atoms to form FCs2K4 octahedra that share corners with six equivalent F(2)Cs2K4 octahedra, corners with sixteen equivalent F(1)Cs2K3Pd octahedra, and faces with eight equivalent F(1)Cs2K3Pd octahedra. The corner-sharing octahedral tilt angles range from 0-64°. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsK2PdF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.301
_cell_length_b   7.301
_cell_length_c   6.205
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   330.784
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.500  0.500  0.000  1.0
  Cs  Cs1  1  0.000  0.000  0.000  1.0
  K  K2  1  0.825  0.325  0.500  1.0
  K  K3  1  0.325  0.175  0.500  1.0
  K  K4  1  0.175  0.675  0.500  1.0
  K  K5  1  0.675  0.825  0.500  1.0
  Pd  Pd6  1  0.500  0.000  0.000  1.0
  Pd  Pd7  1  0.000  0.500  0.000  1.0
  F  F8  1  0.368  0.868  0.773  1.0
  F  F9  1  0.632  0.132  0.773  1.0
  F  F10  1  0.132  0.368  0.773  1.0
  F  F11  1  0.868  0.632  0.773  1.0
  F  F12  1  0.368  0.868  0.227  1.0
  F  F13  1  0.868  0.632  0.227  1.0
  F  F14  1  0.132  0.368  0.227  1.0
  F  F15  1  0.632  0.132  0.227  1.0
  F  F16  1  0.000  0.000  0.500  1.0
  F  F17  1  0.500  0.500  0.500  1.0
[/CIF]
.