The crystal structure described by V6O7F5 is Hydrophilite-derived structured and crystallizes in the monoclinic Pm space group. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(4), one F(1), one F(3), and one F(4) atom to form VO3F3 octahedra that share corners with four equivalent V(3)O4F2 octahedra, corners with four equivalent V(4)O4F2 octahedra,  an edgeedge with one V(1)O3F3 octahedra, and  an edgeedge with one V(2)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 44-56°. In the second V site, V(2) is bonded to one O(3), two equivalent O(1), one F(2), and two equivalent F(4) atoms to form VO3F3 octahedra that share corners with eight equivalent V(4)O4F2 octahedra and edges with two equivalent V(1)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 43-55°. In the third V site, V(3) is bonded to two equivalent O(2), two equivalent O(4), one F(1), and one F(3) atom to form VO4F2 octahedra that share corners with eight equivalent V(1)O3F3 octahedra and edges with two equivalent V(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 44-51°. In the fourth V site, V(4) is bonded to one O(1), one O(2), one O(3), one O(4), one F(2), and one F(4) atom to form VO4F2 octahedra that share corners with four equivalent V(1)O3F3 octahedra, corners with four equivalent V(2)O3F3 octahedra,  an edgeedge with one V(3)O4F2 octahedra, and  an edgeedge with one V(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-56°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(2) and two equivalent V(4) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one V(3) and two equivalent V(1) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(4) atoms. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(3) and two equivalent V(1) atoms. In the fourth F site, F(4) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V6O7F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.319
_cell_length_b   4.692
_cell_length_c   4.699
_cell_angle_alpha   87.301
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   205.229
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.327  0.992  0.984  1.0
  V  V1  1  0.673  0.992  0.984  1.0
  V  V2  1  0.000  0.957  0.007  1.0
  V  V3  1  0.500  0.500  0.489  1.0
  V  V4  1  0.175  0.525  0.514  1.0
  V  V5  1  0.825  0.525  0.514  1.0
  O  O6  1  0.831  0.804  0.807  1.0
  O  O7  1  0.169  0.804  0.807  1.0
  O  O8  1  0.344  0.702  0.300  1.0
  O  O9  1  0.656  0.702  0.300  1.0
  O  O10  1  0.000  0.687  0.318  1.0
  O  O11  1  0.342  0.307  0.689  1.0
  O  O12  1  0.658  0.307  0.689  1.0
  F  F13  1  0.500  0.800  0.793  1.0
  F  F14  1  0.000  0.300  0.717  1.0
  F  F15  1  0.500  0.198  0.184  1.0
  F  F16  1  0.165  0.198  0.202  1.0
  F  F17  1  0.835  0.198  0.202  1.0
[/CIF]
.
The crystal structure described by V6O7F5 is Hydrophilite-derived structured and crystallizes in the monoclinic Pm space group. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(4), one F(1), one F(3), and one F(4) atom to form VO3F3 octahedra that share corners with four equivalent V(3)O4F2 octahedra, corners with four equivalent V(4)O4F2 octahedra,  an edgeedge with one V(1)O3F3 octahedra, and  an edgeedge with one V(2)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 44-56°. In the second V site, V(2) is bonded to one O(3), two equivalent O(1), one F(2), and two equivalent F(4) atoms to form VO3F3 octahedra that share corners with eight equivalent V(4)O4F2 octahedra and edges with two equivalent V(1)O3F3 octahedra. The corner-sharing octahedral tilt angles range from 43-55°. In the third V site, V(3) is bonded to two equivalent O(2), two equivalent O(4), one F(1), and one F(3) atom to form VO4F2 octahedra that share corners with eight equivalent V(1)O3F3 octahedra and edges with two equivalent V(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 44-51°. In the fourth V site, V(4) is bonded to one O(1), one O(2), one O(3), one O(4), one F(2), and one F(4) atom to form VO4F2 octahedra that share corners with four equivalent V(1)O3F3 octahedra, corners with four equivalent V(2)O3F3 octahedra,  an edgeedge with one V(3)O4F2 octahedra, and  an edgeedge with one V(4)O4F2 octahedra. The corner-sharing octahedral tilt angles range from 43-56°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one V(1), one V(2), and one V(4) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(2) and two equivalent V(4) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one V(3), and one V(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one V(3) and two equivalent V(1) atoms. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one V(2) and two equivalent V(4) atoms. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one V(3) and two equivalent V(1) atoms. In the fourth F site, F(4) is bonded in a distorted T-shaped geometry to one V(1), one V(2), and one V(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V6O7F5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.319
_cell_length_b   4.692
_cell_length_c   4.699
_cell_angle_alpha   87.301
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   205.229
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.327  0.992  0.984  1.0
  V  V1  1  0.673  0.992  0.984  1.0
  V  V2  1  0.000  0.957  0.007  1.0
  V  V3  1  0.500  0.500  0.489  1.0
  V  V4  1  0.175  0.525  0.514  1.0
  V  V5  1  0.825  0.525  0.514  1.0
  O  O6  1  0.831  0.804  0.807  1.0
  O  O7  1  0.169  0.804  0.807  1.0
  O  O8  1  0.344  0.702  0.300  1.0
  O  O9  1  0.656  0.702  0.300  1.0
  O  O10  1  0.000  0.687  0.318  1.0
  O  O11  1  0.342  0.307  0.689  1.0
  O  O12  1  0.658  0.307  0.689  1.0
  F  F13  1  0.500  0.800  0.793  1.0
  F  F14  1  0.000  0.300  0.717  1.0
  F  F15  1  0.500  0.198  0.184  1.0
  F  F16  1  0.165  0.198  0.202  1.0
  F  F17  1  0.835  0.198  0.202  1.0
[/CIF]
.