The compound described by Zn(CN)12(AsF6)2 is Indium-derived structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of six AsF6 clusters and three Zn(CN)12 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to three equivalent F(1) and three equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In each Zn(CN)12 cluster, Zn(1) is bonded in an octahedral geometry to six equivalent N(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one C(2) and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one C(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Zn(1) and one C(2) atom. is represented by the CIF file [CIF]
data_ZnAs2C12(NF)12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.724
_cell_length_b   9.724
_cell_length_c   9.724
_cell_angle_alpha   59.216
_cell_angle_beta   59.216
_cell_angle_gamma   59.216
_symmetry_Int_Tables_number   1
_cell_volume   638.539
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.000  1.0
  As  As1  1  0.636  0.636  0.636  1.0
  As  As2  1  0.364  0.364  0.364  1.0
  C  C3  1  0.541  0.758  0.041  1.0
  C  C4  1  0.615  0.173  0.975  1.0
  C  C5  1  0.827  0.025  0.385  1.0
  C  C6  1  0.041  0.541  0.758  1.0
  C  C7  1  0.025  0.385  0.827  1.0
  C  C8  1  0.459  0.242  0.959  1.0
  C  C9  1  0.242  0.959  0.459  1.0
  C  C10  1  0.959  0.459  0.242  1.0
  C  C11  1  0.758  0.041  0.541  1.0
  C  C12  1  0.173  0.975  0.615  1.0
  C  C13  1  0.975  0.615  0.173  1.0
  C  C14  1  0.385  0.827  0.025  1.0
  N  N15  1  0.294  0.946  0.326  1.0
  N  N16  1  0.010  0.252  0.892  1.0
  N  N17  1  0.108  0.990  0.748  1.0
  N  N18  1  0.706  0.054  0.674  1.0
  N  N19  1  0.748  0.108  0.990  1.0
  N  N20  1  0.674  0.706  0.054  1.0
  N  N21  1  0.326  0.294  0.946  1.0
  N  N22  1  0.892  0.010  0.252  1.0
  N  N23  1  0.990  0.748  0.108  1.0
  N  N24  1  0.252  0.892  0.010  1.0
  N  N25  1  0.946  0.326  0.294  1.0
  N  N26  1  0.054  0.674  0.706  1.0
  F  F27  1  0.719  0.425  0.636  1.0
  F  F28  1  0.552  0.845  0.640  1.0
  F  F29  1  0.281  0.575  0.364  1.0
  F  F30  1  0.845  0.640  0.552  1.0
  F  F31  1  0.360  0.448  0.155  1.0
  F  F32  1  0.636  0.719  0.425  1.0
  F  F33  1  0.425  0.636  0.719  1.0
  F  F34  1  0.640  0.552  0.845  1.0
  F  F35  1  0.448  0.155  0.360  1.0
  F  F36  1  0.575  0.364  0.281  1.0
  F  F37  1  0.364  0.281  0.575  1.0
  F  F38  1  0.155  0.360  0.448  1.0
[/CIF]
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The compound described by Zn(CN)12(AsF6)2 is Indium-derived structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of six AsF6 clusters and three Zn(CN)12 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to three equivalent F(1) and three equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In each Zn(CN)12 cluster, Zn(1) is bonded in an octahedral geometry to six equivalent N(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one C(2) and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one C(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Zn(1) and one C(2) atom. is represented by the CIF file [CIF]
data_ZnAs2C12(NF)12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.724
_cell_length_b   9.724
_cell_length_c   9.724
_cell_angle_alpha   59.216
_cell_angle_beta   59.216
_cell_angle_gamma   59.216
_symmetry_Int_Tables_number   1
_cell_volume   638.539
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.000  1.0
  As  As1  1  0.636  0.636  0.636  1.0
  As  As2  1  0.364  0.364  0.364  1.0
  C  C3  1  0.541  0.758  0.041  1.0
  C  C4  1  0.615  0.173  0.975  1.0
  C  C5  1  0.827  0.025  0.385  1.0
  C  C6  1  0.041  0.541  0.758  1.0
  C  C7  1  0.025  0.385  0.827  1.0
  C  C8  1  0.459  0.242  0.959  1.0
  C  C9  1  0.242  0.959  0.459  1.0
  C  C10  1  0.959  0.459  0.242  1.0
  C  C11  1  0.758  0.041  0.541  1.0
  C  C12  1  0.173  0.975  0.615  1.0
  C  C13  1  0.975  0.615  0.173  1.0
  C  C14  1  0.385  0.827  0.025  1.0
  N  N15  1  0.294  0.946  0.326  1.0
  N  N16  1  0.010  0.252  0.892  1.0
  N  N17  1  0.108  0.990  0.748  1.0
  N  N18  1  0.706  0.054  0.674  1.0
  N  N19  1  0.748  0.108  0.990  1.0
  N  N20  1  0.674  0.706  0.054  1.0
  N  N21  1  0.326  0.294  0.946  1.0
  N  N22  1  0.892  0.010  0.252  1.0
  N  N23  1  0.990  0.748  0.108  1.0
  N  N24  1  0.252  0.892  0.010  1.0
  N  N25  1  0.946  0.326  0.294  1.0
  N  N26  1  0.054  0.674  0.706  1.0
  F  F27  1  0.719  0.425  0.636  1.0
  F  F28  1  0.552  0.845  0.640  1.0
  F  F29  1  0.281  0.575  0.364  1.0
  F  F30  1  0.845  0.640  0.552  1.0
  F  F31  1  0.360  0.448  0.155  1.0
  F  F32  1  0.636  0.719  0.425  1.0
  F  F33  1  0.425  0.636  0.719  1.0
  F  F34  1  0.640  0.552  0.845  1.0
  F  F35  1  0.448  0.155  0.360  1.0
  F  F36  1  0.575  0.364  0.281  1.0
  F  F37  1  0.364  0.281  0.575  1.0
  F  F38  1  0.155  0.360  0.448  1.0
[/CIF]
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