The material described by K2C2N2H2S2O crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 7-coordinate geometry to one N(1), one N(2), two equivalent S(1), two equivalent S(2), and one O(1) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one S(2) atom. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to two equivalent K(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one C(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 5-coordinate geometry to four equivalent K(1) and one C(1) atom. In the second S site, S(2) is bonded in a 5-coordinate geometry to four equivalent K(1) and one C(1) atom. O(1) is bonded in a distorted water-like geometry to two equivalent K(1), one H(1), and one H(2) atom. is represented by the CIF file [CIF]
data_K2H2C2S2N2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.118
_cell_length_b   9.880
_cell_length_c   10.361
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   831.066
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.499  0.767  0.666  1.0
  K  K1  1  0.001  0.733  0.166  1.0
  K  K2  1  0.999  0.233  0.334  1.0
  K  K3  1  0.501  0.267  0.834  1.0
  K  K4  1  0.501  0.233  0.334  1.0
  K  K5  1  0.999  0.267  0.834  1.0
  K  K6  1  0.001  0.767  0.666  1.0
  K  K7  1  0.499  0.733  0.166  1.0
  H  H8  1  0.250  0.491  0.995  1.0
  H  H9  1  0.250  0.009  0.495  1.0
  H  H10  1  0.750  0.509  0.005  1.0
  H  H11  1  0.750  0.991  0.505  1.0
  H  H12  1  0.250  0.339  0.045  1.0
  H  H13  1  0.250  0.161  0.545  1.0
  H  H14  1  0.750  0.661  0.955  1.0
  H  H15  1  0.750  0.839  0.455  1.0
  C  C16  1  0.250  0.613  0.433  1.0
  C  C17  1  0.250  0.887  0.933  1.0
  C  C18  1  0.750  0.387  0.567  1.0
  C  C19  1  0.750  0.113  0.067  1.0
  C  C20  1  0.250  0.444  0.590  1.0
  C  C21  1  0.250  0.056  0.090  1.0
  C  C22  1  0.750  0.556  0.410  1.0
  C  C23  1  0.750  0.944  0.910  1.0
  S  S24  1  0.250  0.503  0.304  1.0
  S  S25  1  0.250  0.997  0.804  1.0
  S  S26  1  0.750  0.497  0.696  1.0
  S  S27  1  0.750  0.003  0.196  1.0
  S  S28  1  0.250  0.785  0.407  1.0
  S  S29  1  0.250  0.715  0.907  1.0
  S  S30  1  0.750  0.215  0.593  1.0
  S  S31  1  0.750  0.285  0.093  1.0
  N  N32  1  0.250  0.571  0.558  1.0
  N  N33  1  0.250  0.929  0.058  1.0
  N  N34  1  0.750  0.429  0.442  1.0
  N  N35  1  0.750  0.071  0.942  1.0
  N  N36  1  0.250  0.332  0.631  1.0
  N  N37  1  0.250  0.168  0.131  1.0
  N  N38  1  0.750  0.668  0.369  1.0
  N  N39  1  0.750  0.832  0.869  1.0
  O  O40  1  0.250  0.396  0.967  1.0
  O  O41  1  0.250  0.104  0.467  1.0
  O  O42  1  0.750  0.604  0.033  1.0
  O  O43  1  0.750  0.896  0.533  1.0
[/CIF]
.
The material described by K2C2N2H2S2O crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 7-coordinate geometry to one N(1), one N(2), two equivalent S(1), two equivalent S(2), and one O(1) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one S(2) atom. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to two equivalent K(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one C(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 5-coordinate geometry to four equivalent K(1) and one C(1) atom. In the second S site, S(2) is bonded in a 5-coordinate geometry to four equivalent K(1) and one C(1) atom. O(1) is bonded in a distorted water-like geometry to two equivalent K(1), one H(1), and one H(2) atom. is represented by the CIF file [CIF]
data_K2H2C2S2N2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.118
_cell_length_b   9.880
_cell_length_c   10.361
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   831.066
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.499  0.767  0.666  1.0
  K  K1  1  0.001  0.733  0.166  1.0
  K  K2  1  0.999  0.233  0.334  1.0
  K  K3  1  0.501  0.267  0.834  1.0
  K  K4  1  0.501  0.233  0.334  1.0
  K  K5  1  0.999  0.267  0.834  1.0
  K  K6  1  0.001  0.767  0.666  1.0
  K  K7  1  0.499  0.733  0.166  1.0
  H  H8  1  0.250  0.491  0.995  1.0
  H  H9  1  0.250  0.009  0.495  1.0
  H  H10  1  0.750  0.509  0.005  1.0
  H  H11  1  0.750  0.991  0.505  1.0
  H  H12  1  0.250  0.339  0.045  1.0
  H  H13  1  0.250  0.161  0.545  1.0
  H  H14  1  0.750  0.661  0.955  1.0
  H  H15  1  0.750  0.839  0.455  1.0
  C  C16  1  0.250  0.613  0.433  1.0
  C  C17  1  0.250  0.887  0.933  1.0
  C  C18  1  0.750  0.387  0.567  1.0
  C  C19  1  0.750  0.113  0.067  1.0
  C  C20  1  0.250  0.444  0.590  1.0
  C  C21  1  0.250  0.056  0.090  1.0
  C  C22  1  0.750  0.556  0.410  1.0
  C  C23  1  0.750  0.944  0.910  1.0
  S  S24  1  0.250  0.503  0.304  1.0
  S  S25  1  0.250  0.997  0.804  1.0
  S  S26  1  0.750  0.497  0.696  1.0
  S  S27  1  0.750  0.003  0.196  1.0
  S  S28  1  0.250  0.785  0.407  1.0
  S  S29  1  0.250  0.715  0.907  1.0
  S  S30  1  0.750  0.215  0.593  1.0
  S  S31  1  0.750  0.285  0.093  1.0
  N  N32  1  0.250  0.571  0.558  1.0
  N  N33  1  0.250  0.929  0.058  1.0
  N  N34  1  0.750  0.429  0.442  1.0
  N  N35  1  0.750  0.071  0.942  1.0
  N  N36  1  0.250  0.332  0.631  1.0
  N  N37  1  0.250  0.168  0.131  1.0
  N  N38  1  0.750  0.668  0.369  1.0
  N  N39  1  0.750  0.832  0.869  1.0
  O  O40  1  0.250  0.396  0.967  1.0
  O  O41  1  0.250  0.104  0.467  1.0
  O  O42  1  0.750  0.604  0.033  1.0
  O  O43  1  0.750  0.896  0.533  1.0
[/CIF]
.