The structure described by Cr(OF)2 is Hg_xSn structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Cr(OF)2 clusters. Cr(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one F(2), and two equivalent F(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cr(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to two equivalent Cr(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one Cr(1) atom. is represented by the CIF file [CIF]
data_Cr(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.162
_cell_length_b   6.081
_cell_length_c   9.199
_cell_angle_alpha   88.178
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   288.584
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.935  0.691  0.622  1.0
  Cr  Cr1  1  0.435  0.309  0.878  1.0
  Cr  Cr2  1  0.565  0.691  0.122  1.0
  Cr  Cr3  1  0.065  0.309  0.378  1.0
  O  O4  1  0.899  0.117  0.313  1.0
  O  O5  1  0.399  0.883  0.187  1.0
  O  O6  1  0.601  0.117  0.813  1.0
  O  O7  1  0.101  0.883  0.687  1.0
  O  O8  1  0.182  0.196  0.941  1.0
  O  O9  1  0.818  0.804  0.059  1.0
  O  O10  1  0.318  0.196  0.441  1.0
  O  O11  1  0.682  0.804  0.559  1.0
  F  F12  1  0.134  0.645  0.459  1.0
  F  F13  1  0.177  0.448  0.217  1.0
  F  F14  1  0.823  0.552  0.783  1.0
  F  F15  1  0.366  0.645  0.959  1.0
  F  F16  1  0.634  0.355  0.041  1.0
  F  F17  1  0.866  0.355  0.541  1.0
  F  F18  1  0.323  0.448  0.717  1.0
  F  F19  1  0.677  0.552  0.283  1.0
[/CIF]
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The structure described by Cr(OF)2 is Hg_xSn structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Cr(OF)2 clusters. Cr(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one F(2), and two equivalent F(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cr(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cr(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to two equivalent Cr(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to one Cr(1) atom. is represented by the CIF file [CIF]
data_Cr(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.162
_cell_length_b   6.081
_cell_length_c   9.199
_cell_angle_alpha   88.178
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   288.584
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.935  0.691  0.622  1.0
  Cr  Cr1  1  0.435  0.309  0.878  1.0
  Cr  Cr2  1  0.565  0.691  0.122  1.0
  Cr  Cr3  1  0.065  0.309  0.378  1.0
  O  O4  1  0.899  0.117  0.313  1.0
  O  O5  1  0.399  0.883  0.187  1.0
  O  O6  1  0.601  0.117  0.813  1.0
  O  O7  1  0.101  0.883  0.687  1.0
  O  O8  1  0.182  0.196  0.941  1.0
  O  O9  1  0.818  0.804  0.059  1.0
  O  O10  1  0.318  0.196  0.441  1.0
  O  O11  1  0.682  0.804  0.559  1.0
  F  F12  1  0.134  0.645  0.459  1.0
  F  F13  1  0.177  0.448  0.217  1.0
  F  F14  1  0.823  0.552  0.783  1.0
  F  F15  1  0.366  0.645  0.959  1.0
  F  F16  1  0.634  0.355  0.041  1.0
  F  F17  1  0.866  0.355  0.541  1.0
  F  F18  1  0.323  0.448  0.717  1.0
  F  F19  1  0.677  0.552  0.283  1.0
[/CIF]
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