The structure described by Ti(CrTe2)2 crystallizes in the triclinic P1 space group. Ti(1) is bonded to one Te(1), one Te(2), two equivalent Te(3), and two equivalent Te(4) atoms to form distorted TiTe6 octahedra that share corners with six equivalent Cr(1)Te6 octahedra, edges with two equivalent Ti(1)Te6 octahedra, edges with four equivalent Cr(2)Te6 octahedra, and  a faceface with one Cr(1)Te6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one Te(2), one Te(3), two equivalent Te(1), and two equivalent Te(4) atoms to form distorted CrTe6 octahedra that share corners with six equivalent Ti(1)Te6 octahedra, corners with six equivalent Cr(2)Te6 octahedra, edges with two equivalent Cr(1)Te6 octahedra,  a faceface with one Ti(1)Te6 octahedra, and  a faceface with one Cr(2)Te6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the second Cr site, Cr(2) is bonded to one Te(3), one Te(4), two equivalent Te(1), and two equivalent Te(2) atoms to form CrTe6 octahedra that share corners with six equivalent Cr(1)Te6 octahedra, edges with two equivalent Cr(2)Te6 octahedra, edges with four equivalent Ti(1)Te6 octahedra, and  a faceface with one Cr(1)Te6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded to one Ti(1), two equivalent Cr(1), and two equivalent Cr(2) atoms to form distorted TeTiCr4 trigonal bipyramids that share corners with two equivalent Te(4)Ti2Cr3 square pyramids, edges with three equivalent Te(4)Ti2Cr3 square pyramids, and edges with two equivalent Te(1)TiCr4 trigonal bipyramids. In the second Te site, Te(2) is bonded in a distorted rectangular see-saw-like geometry to one Ti(1), one Cr(1), and two equivalent Cr(2) atoms. In the third Te site, Te(3) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Ti(1), one Cr(1), and one Cr(2) atom. In the fourth Te site, Te(4) is bonded to two equivalent Ti(1), one Cr(2), and two equivalent Cr(1) atoms to form distorted TeTi2Cr3 square pyramids that share corners with two equivalent Te(1)TiCr4 trigonal bipyramids, edges with two equivalent Te(4)Ti2Cr3 square pyramids, and edges with three equivalent Te(1)TiCr4 trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ti(CrTe2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.996
_cell_length_b   6.840
_cell_length_c   7.315
_cell_angle_alpha   116.770
_cell_angle_beta   105.936
_cell_angle_gamma   90.116
_symmetry_Int_Tables_number   1
_cell_volume   169.790
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.250  0.218  0.500  1.0
  Cr  Cr1  1  0.494  0.494  0.987  1.0
  Cr  Cr2  1  0.756  0.785  0.510  1.0
  Te  Te3  1  0.131  0.472  0.262  1.0
  Te  Te4  1  0.389  0.043  0.776  1.0
  Te  Te5  1  0.614  0.951  0.229  1.0
  Te  Te6  1  0.868  0.537  0.735  1.0
[/CIF]
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The structure described by Ti(CrTe2)2 crystallizes in the triclinic P1 space group. Ti(1) is bonded to one Te(1), one Te(2), two equivalent Te(3), and two equivalent Te(4) atoms to form distorted TiTe6 octahedra that share corners with six equivalent Cr(1)Te6 octahedra, edges with two equivalent Ti(1)Te6 octahedra, edges with four equivalent Cr(2)Te6 octahedra, and  a faceface with one Cr(1)Te6 octahedra. The corner-sharing octahedral tilt angles range from 51-54°. There are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one Te(2), one Te(3), two equivalent Te(1), and two equivalent Te(4) atoms to form distorted CrTe6 octahedra that share corners with six equivalent Ti(1)Te6 octahedra, corners with six equivalent Cr(2)Te6 octahedra, edges with two equivalent Cr(1)Te6 octahedra,  a faceface with one Ti(1)Te6 octahedra, and  a faceface with one Cr(2)Te6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the second Cr site, Cr(2) is bonded to one Te(3), one Te(4), two equivalent Te(1), and two equivalent Te(2) atoms to form CrTe6 octahedra that share corners with six equivalent Cr(1)Te6 octahedra, edges with two equivalent Cr(2)Te6 octahedra, edges with four equivalent Ti(1)Te6 octahedra, and  a faceface with one Cr(1)Te6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded to one Ti(1), two equivalent Cr(1), and two equivalent Cr(2) atoms to form distorted TeTiCr4 trigonal bipyramids that share corners with two equivalent Te(4)Ti2Cr3 square pyramids, edges with three equivalent Te(4)Ti2Cr3 square pyramids, and edges with two equivalent Te(1)TiCr4 trigonal bipyramids. In the second Te site, Te(2) is bonded in a distorted rectangular see-saw-like geometry to one Ti(1), one Cr(1), and two equivalent Cr(2) atoms. In the third Te site, Te(3) is bonded in a distorted rectangular see-saw-like geometry to two equivalent Ti(1), one Cr(1), and one Cr(2) atom. In the fourth Te site, Te(4) is bonded to two equivalent Ti(1), one Cr(2), and two equivalent Cr(1) atoms to form distorted TeTi2Cr3 square pyramids that share corners with two equivalent Te(1)TiCr4 trigonal bipyramids, edges with two equivalent Te(4)Ti2Cr3 square pyramids, and edges with three equivalent Te(1)TiCr4 trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ti(CrTe2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.996
_cell_length_b   6.840
_cell_length_c   7.315
_cell_angle_alpha   116.770
_cell_angle_beta   105.936
_cell_angle_gamma   90.116
_symmetry_Int_Tables_number   1
_cell_volume   169.790
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.250  0.218  0.500  1.0
  Cr  Cr1  1  0.494  0.494  0.987  1.0
  Cr  Cr2  1  0.756  0.785  0.510  1.0
  Te  Te3  1  0.131  0.472  0.262  1.0
  Te  Te4  1  0.389  0.043  0.776  1.0
  Te  Te5  1  0.614  0.951  0.229  1.0
  Te  Te6  1  0.868  0.537  0.735  1.0
[/CIF]
.