The material described by Dy2Rh3Si5 crystallizes in the monoclinic C2/c space group. Dy(1) is bonded in a 17-coordinate geometry to two equivalent Rh(2), five equivalent Rh(1), two equivalent Si(2), two equivalent Si(3), two equivalent Si(4), and four equivalent Si(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(2) is bonded in a 6-coordinate geometry to four equivalent Dy(1), one Si(2), one Si(4), and four equivalent Si(1) atoms. In the second Rh site, Rh(1) is bonded in a 5-coordinate geometry to five equivalent Dy(1), one Si(1), one Si(2), one Si(4), and two equivalent Si(3) atoms. There are four inequivalent Si sites. In the first Si site, Si(1) is bonded in a 9-coordinate geometry to four equivalent Dy(1), one Rh(1), two equivalent Rh(2), one Si(2), and one Si(4) atom. In the second Si site, Si(2) is bonded in a 3-coordinate geometry to four equivalent Dy(1), one Rh(2), two equivalent Rh(1), two equivalent Si(1), and two equivalent Si(4) atoms. In the third Si site, Si(3) is bonded in a 4-coordinate geometry to four equivalent Dy(1) and four equivalent Rh(1) atoms. In the fourth Si site, Si(4) is bonded in a 11-coordinate geometry to four equivalent Dy(1), one Rh(2), two equivalent Rh(1), two equivalent Si(1), and two equivalent Si(2) atoms. is represented by the CIF card [CIF]
data_Dy2Si5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.071
_cell_length_b   8.071
_cell_length_c   5.653
_cell_angle_alpha   71.172
_cell_angle_beta   71.172
_cell_angle_gamma   93.523
_symmetry_Int_Tables_number   1
_cell_volume   324.229
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.866  0.599  0.761  1.0
  Dy  Dy1  1  0.401  0.134  0.739  1.0
  Dy  Dy2  1  0.134  0.401  0.239  1.0
  Dy  Dy3  1  0.599  0.866  0.261  1.0
  Si  Si4  1  0.057  0.266  0.839  1.0
  Si  Si5  1  0.734  0.943  0.661  1.0
  Si  Si6  1  0.943  0.734  0.161  1.0
  Si  Si7  1  0.266  0.057  0.339  1.0
  Si  Si8  1  0.211  0.789  0.750  1.0
  Si  Si9  1  0.789  0.211  0.250  1.0
  Si  Si10  1  0.512  0.488  0.750  1.0
  Si  Si11  1  0.488  0.512  0.250  1.0
  Si  Si12  1  0.776  0.224  0.750  1.0
  Si  Si13  1  0.224  0.776  0.250  1.0
  Rh  Rh14  1  0.260  0.539  0.627  1.0
  Rh  Rh15  1  0.461  0.740  0.873  1.0
  Rh  Rh16  1  0.740  0.461  0.373  1.0
  Rh  Rh17  1  0.539  0.260  0.127  1.0
  Rh  Rh18  1  0.002  0.998  0.750  1.0
  Rh  Rh19  1  0.998  0.002  0.250  1.0
[/CIF]
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The material described by Dy2Rh3Si5 crystallizes in the monoclinic C2/c space group. Dy(1) is bonded in a 17-coordinate geometry to two equivalent Rh(2), five equivalent Rh(1), two equivalent Si(2), two equivalent Si(3), two equivalent Si(4), and four equivalent Si(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(2) is bonded in a 6-coordinate geometry to four equivalent Dy(1), one Si(2), one Si(4), and four equivalent Si(1) atoms. In the second Rh site, Rh(1) is bonded in a 5-coordinate geometry to five equivalent Dy(1), one Si(1), one Si(2), one Si(4), and two equivalent Si(3) atoms. There are four inequivalent Si sites. In the first Si site, Si(1) is bonded in a 9-coordinate geometry to four equivalent Dy(1), one Rh(1), two equivalent Rh(2), one Si(2), and one Si(4) atom. In the second Si site, Si(2) is bonded in a 3-coordinate geometry to four equivalent Dy(1), one Rh(2), two equivalent Rh(1), two equivalent Si(1), and two equivalent Si(4) atoms. In the third Si site, Si(3) is bonded in a 4-coordinate geometry to four equivalent Dy(1) and four equivalent Rh(1) atoms. In the fourth Si site, Si(4) is bonded in a 11-coordinate geometry to four equivalent Dy(1), one Rh(2), two equivalent Rh(1), two equivalent Si(1), and two equivalent Si(2) atoms. is represented by the CIF card [CIF]
data_Dy2Si5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.071
_cell_length_b   8.071
_cell_length_c   5.653
_cell_angle_alpha   71.172
_cell_angle_beta   71.172
_cell_angle_gamma   93.523
_symmetry_Int_Tables_number   1
_cell_volume   324.229
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.866  0.599  0.761  1.0
  Dy  Dy1  1  0.401  0.134  0.739  1.0
  Dy  Dy2  1  0.134  0.401  0.239  1.0
  Dy  Dy3  1  0.599  0.866  0.261  1.0
  Si  Si4  1  0.057  0.266  0.839  1.0
  Si  Si5  1  0.734  0.943  0.661  1.0
  Si  Si6  1  0.943  0.734  0.161  1.0
  Si  Si7  1  0.266  0.057  0.339  1.0
  Si  Si8  1  0.211  0.789  0.750  1.0
  Si  Si9  1  0.789  0.211  0.250  1.0
  Si  Si10  1  0.512  0.488  0.750  1.0
  Si  Si11  1  0.488  0.512  0.250  1.0
  Si  Si12  1  0.776  0.224  0.750  1.0
  Si  Si13  1  0.224  0.776  0.250  1.0
  Rh  Rh14  1  0.260  0.539  0.627  1.0
  Rh  Rh15  1  0.461  0.740  0.873  1.0
  Rh  Rh16  1  0.740  0.461  0.373  1.0
  Rh  Rh17  1  0.539  0.260  0.127  1.0
  Rh  Rh18  1  0.002  0.998  0.750  1.0
  Rh  Rh19  1  0.998  0.002  0.250  1.0
[/CIF]
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