The compound described by Li2TiO3 is Caswellsilverite-like structured and crystallizes in the monoclinic C2/c space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one O(3), one O(4), one O(6), and two equivalent O(5) atoms to form LiO6 octahedra that share  a cornercorner with one Ti(3)O6 octahedra, corners with five equivalent Ti(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. In the second Li site, Li(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form LiO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with four equivalent Ti(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-8°. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(5), one O(6), and two equivalent O(3) atoms to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with five equivalent Li(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-11°. In the fourth Li site, Li(4) is bonded to one O(1), one O(2), one O(3), one O(5), and two equivalent O(6) atoms to form LiO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra, corners with five equivalent Li(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the fifth Li site, Li(5) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form LiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent Ti(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(3), one O(4), one O(5), one O(6), and two equivalent O(2) atoms to form TiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra, corners with five equivalent Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. In the second Ti site, Ti(2) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(6) atoms to form TiO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with four equivalent Li(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the third Ti site, Ti(3) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent Li(5)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(3), one Li(4), one Li(5), one Ti(2), and one Ti(3) atom to form OLi4Ti2 octahedra that share  a cornercorner with one O(6)Li4Ti2 octahedra,  a cornercorner with one O(3)Li5Ti octahedra, corners with four equivalent O(1)Li4Ti2 octahedra, edges with two equivalent O(2)Li4Ti2 octahedra, edges with two equivalent O(5)Li4Ti2 octahedra, edges with two equivalent O(6)Li4Ti2 octahedra, edges with two equivalent O(3)Li5Ti octahedra, and edges with four equivalent O(4)Li3Ti3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second O site, O(2) is bonded to one Li(1), one Li(3), one Li(4), one Li(5), and two equivalent Ti(1) atoms to form OLi4Ti2 octahedra that share  a cornercorner with one O(4)Li3Ti3 octahedra,  a cornercorner with one O(2)Li4Ti2 octahedra, corners with four equivalent O(5)Li4Ti2 octahedra,  an edgeedge with one O(2)Li4Ti2 octahedra,  an edgeedge with one O(5)Li4Ti2 octahedra, edges with two equivalent O(4)Li3Ti3 octahedra, edges with two equivalent O(1)Li4Ti2 octahedra, edges with three equivalent O(6)Li4Ti2 octahedra, and edges with three equivalent O(3)Li5Ti octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(4), two equivalent Li(3), and one Ti(1) atom to form OLi5Ti octahedra that share  a cornercorner with one O(1)Li4Ti2 octahedra,  a cornercorner with one O(3)Li5Ti octahedra, corners with four equivalent O(6)Li4Ti2 octahedra,  an edgeedge with one O(6)Li4Ti2 octahedra,  an edgeedge with one O(3)Li5Ti octahedra, edges with two equivalent O(4)Li3Ti3 octahedra, edges with two equivalent O(1)Li4Ti2 octahedra, edges with three equivalent O(2)Li4Ti2 octahedra, and edges with three equivalent O(5)Li4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(5), one Ti(1), one Ti(2), and one Ti(3) atom to form OLi3Ti3 octahedra that share  a cornercorner with one O(2)Li4Ti2 octahedra,  a cornercorner with one O(5)Li4Ti2 octahedra, corners with four equivalent O(4)Li3Ti3 octahedra, edges with two equivalent O(2)Li4Ti2 octahedra, edges with two equivalent O(5)Li4Ti2 octahedra, edges with two equivalent O(6)Li4Ti2 octahedra, edges with two equivalent O(3)Li5Ti octahedra, and edges with four equivalent O(1)Li4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the fifth O site, O(5) is bonded to one Li(3), one Li(4), two equivalent Li(1), one Ti(1), and one Ti(3) atom to form OLi4Ti2 octahedra that share  a cornercorner with one O(4)Li3Ti3 octahedra,  a cornercorner with one O(5)Li4Ti2 octahedra, corners with four equivalent O(2)Li4Ti2 octahedra,  an edgeedge with one O(2)Li4Ti2 octahedra,  an edgeedge with one O(5)Li4Ti2 octahedra, edges with two equivalent O(4)Li3Ti3 octahedra, edges with two equivalent O(1)Li4Ti2 octahedra, edges with three equivalent O(6)Li4Ti2 octahedra, and edges with three equivalent O(3)Li5Ti octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the sixth O site, O(6) is bonded to one Li(1), one Li(3), two equivalent Li(4), one Ti(1), and one Ti(2) atom to form OLi4Ti2 octahedra that share  a cornercorner with one O(1)Li4Ti2 octahedra,  a cornercorner with one O(6)Li4Ti2 octahedra, corners with four equivalent O(3)Li5Ti octahedra,  an edgeedge with one O(6)Li4Ti2 octahedra,  an edgeedge with one O(3)Li5Ti octahedra, edges with two equivalent O(4)Li3Ti3 octahedra, edges with two equivalent O(1)Li4Ti2 octahedra, edges with three equivalent O(2)Li4Ti2 octahedra, and edges with three equivalent O(5)Li4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-12°. is represented by the CIF card [CIF]
data_Li2TiO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.916
_cell_length_b   5.916
_cell_length_c   13.229
_cell_angle_alpha   77.042
_cell_angle_beta   77.042
_cell_angle_gamma   89.282
_symmetry_Int_Tables_number   1
_cell_volume   439.405
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.331  0.835  0.831  1.0
  Li  Li1  1  0.000  0.000  0.000  1.0
  Li  Li2  1  0.669  0.165  0.169  1.0
  Li  Li3  1  0.835  0.836  0.833  1.0
  Li  Li4  1  0.331  0.335  0.330  1.0
  Li  Li5  1  0.500  0.000  0.000  1.0
  Li  Li6  1  0.165  0.164  0.167  1.0
  Li  Li7  1  0.000  0.500  0.500  1.0
  Li  Li8  1  0.000  0.000  0.500  1.0
  Li  Li9  1  0.669  0.665  0.670  1.0
  Li  Li10  1  0.835  0.331  0.331  1.0
  Li  Li11  1  0.836  0.835  0.333  1.0
  Li  Li12  1  0.335  0.331  0.830  1.0
  Li  Li13  1  0.165  0.669  0.669  1.0
  Li  Li14  1  0.164  0.165  0.667  1.0
  Li  Li15  1  0.665  0.669  0.170  1.0
  Ti  Ti16  1  0.329  0.856  0.325  1.0
  Ti  Ti17  1  0.671  0.144  0.675  1.0
  Ti  Ti18  1  0.500  0.500  0.500  1.0
  Ti  Ti19  1  0.500  0.000  0.500  1.0
  Ti  Ti20  1  0.000  0.500  0.000  1.0
  Ti  Ti21  1  0.856  0.329  0.825  1.0
  Ti  Ti22  1  0.500  0.500  0.000  1.0
  Ti  Ti23  1  0.144  0.671  0.175  1.0
  O  O24  1  0.752  0.722  0.001  1.0
  O  O25  1  0.403  0.900  0.175  1.0
  O  O26  1  0.099  0.064  0.336  1.0
  O  O27  1  0.246  0.733  0.003  1.0
  O  O28  1  0.722  0.752  0.501  1.0
  O  O29  1  0.936  0.901  0.164  1.0
  O  O30  1  0.733  0.246  0.503  1.0
  O  O31  1  0.432  0.934  0.658  1.0
  O  O32  1  0.433  0.415  0.653  1.0
  O  O33  1  0.568  0.066  0.342  1.0
  O  O34  1  0.064  0.099  0.836  1.0
  O  O35  1  0.066  0.568  0.842  1.0
  O  O36  1  0.267  0.754  0.497  1.0
  O  O37  1  0.278  0.248  0.499  1.0
  O  O38  1  0.901  0.936  0.664  1.0
  O  O39  1  0.754  0.267  0.997  1.0
  O  O40  1  0.900  0.403  0.675  1.0
  O  O41  1  0.415  0.433  0.153  1.0
  O  O42  1  0.597  0.100  0.825  1.0
  O  O43  1  0.585  0.567  0.847  1.0
  O  O44  1  0.248  0.278  0.999  1.0
  O  O45  1  0.100  0.597  0.325  1.0
  O  O46  1  0.934  0.432  0.158  1.0
  O  O47  1  0.567  0.585  0.347  1.0
[/CIF]
.
The compound described by Li2TiO3 is Caswellsilverite-like structured and crystallizes in the monoclinic C2/c space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one O(3), one O(4), one O(6), and two equivalent O(5) atoms to form LiO6 octahedra that share  a cornercorner with one Ti(3)O6 octahedra, corners with five equivalent Ti(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. In the second Li site, Li(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form LiO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with four equivalent Ti(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-8°. In the third Li site, Li(3) is bonded to one O(1), one O(2), one O(5), one O(6), and two equivalent O(3) atoms to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with five equivalent Li(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-11°. In the fourth Li site, Li(4) is bonded to one O(1), one O(2), one O(3), one O(5), and two equivalent O(6) atoms to form LiO6 octahedra that share  a cornercorner with one Ti(2)O6 octahedra, corners with five equivalent Li(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Ti(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the fifth Li site, Li(5) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form LiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent Ti(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-8°. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(3), one O(4), one O(5), one O(6), and two equivalent O(2) atoms to form TiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra, corners with five equivalent Li(1)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra,  an edgeedge with one Ti(3)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. In the second Ti site, Ti(2) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(6) atoms to form TiO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with four equivalent Li(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-7°. In the third Ti site, Ti(3) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms to form TiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent Li(5)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Ti(1)O6 octahedra, and edges with two equivalent Ti(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(3), one Li(4), one Li(5), one Ti(2), and one Ti(3) atom to form OLi4Ti2 octahedra that share  a cornercorner with one O(6)Li4Ti2 octahedra,  a cornercorner with one O(3)Li5Ti octahedra, corners with four equivalent O(1)Li4Ti2 octahedra, edges with two equivalent O(2)Li4Ti2 octahedra, edges with two equivalent O(5)Li4Ti2 octahedra, edges with two equivalent O(6)Li4Ti2 octahedra, edges with two equivalent O(3)Li5Ti octahedra, and edges with four equivalent O(4)Li3Ti3 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second O site, O(2) is bonded to one Li(1), one Li(3), one Li(4), one Li(5), and two equivalent Ti(1) atoms to form OLi4Ti2 octahedra that share  a cornercorner with one O(4)Li3Ti3 octahedra,  a cornercorner with one O(2)Li4Ti2 octahedra, corners with four equivalent O(5)Li4Ti2 octahedra,  an edgeedge with one O(2)Li4Ti2 octahedra,  an edgeedge with one O(5)Li4Ti2 octahedra, edges with two equivalent O(4)Li3Ti3 octahedra, edges with two equivalent O(1)Li4Ti2 octahedra, edges with three equivalent O(6)Li4Ti2 octahedra, and edges with three equivalent O(3)Li5Ti octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(4), two equivalent Li(3), and one Ti(1) atom to form OLi5Ti octahedra that share  a cornercorner with one O(1)Li4Ti2 octahedra,  a cornercorner with one O(3)Li5Ti octahedra, corners with four equivalent O(6)Li4Ti2 octahedra,  an edgeedge with one O(6)Li4Ti2 octahedra,  an edgeedge with one O(3)Li5Ti octahedra, edges with two equivalent O(4)Li3Ti3 octahedra, edges with two equivalent O(1)Li4Ti2 octahedra, edges with three equivalent O(2)Li4Ti2 octahedra, and edges with three equivalent O(5)Li4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(5), one Ti(1), one Ti(2), and one Ti(3) atom to form OLi3Ti3 octahedra that share  a cornercorner with one O(2)Li4Ti2 octahedra,  a cornercorner with one O(5)Li4Ti2 octahedra, corners with four equivalent O(4)Li3Ti3 octahedra, edges with two equivalent O(2)Li4Ti2 octahedra, edges with two equivalent O(5)Li4Ti2 octahedra, edges with two equivalent O(6)Li4Ti2 octahedra, edges with two equivalent O(3)Li5Ti octahedra, and edges with four equivalent O(1)Li4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the fifth O site, O(5) is bonded to one Li(3), one Li(4), two equivalent Li(1), one Ti(1), and one Ti(3) atom to form OLi4Ti2 octahedra that share  a cornercorner with one O(4)Li3Ti3 octahedra,  a cornercorner with one O(5)Li4Ti2 octahedra, corners with four equivalent O(2)Li4Ti2 octahedra,  an edgeedge with one O(2)Li4Ti2 octahedra,  an edgeedge with one O(5)Li4Ti2 octahedra, edges with two equivalent O(4)Li3Ti3 octahedra, edges with two equivalent O(1)Li4Ti2 octahedra, edges with three equivalent O(6)Li4Ti2 octahedra, and edges with three equivalent O(3)Li5Ti octahedra. The corner-sharing octahedral tilt angles range from 0-9°. In the sixth O site, O(6) is bonded to one Li(1), one Li(3), two equivalent Li(4), one Ti(1), and one Ti(2) atom to form OLi4Ti2 octahedra that share  a cornercorner with one O(1)Li4Ti2 octahedra,  a cornercorner with one O(6)Li4Ti2 octahedra, corners with four equivalent O(3)Li5Ti octahedra,  an edgeedge with one O(6)Li4Ti2 octahedra,  an edgeedge with one O(3)Li5Ti octahedra, edges with two equivalent O(4)Li3Ti3 octahedra, edges with two equivalent O(1)Li4Ti2 octahedra, edges with three equivalent O(2)Li4Ti2 octahedra, and edges with three equivalent O(5)Li4Ti2 octahedra. The corner-sharing octahedral tilt angles range from 0-12°. is represented by the CIF card [CIF]
data_Li2TiO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.916
_cell_length_b   5.916
_cell_length_c   13.229
_cell_angle_alpha   77.042
_cell_angle_beta   77.042
_cell_angle_gamma   89.282
_symmetry_Int_Tables_number   1
_cell_volume   439.405
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.331  0.835  0.831  1.0
  Li  Li1  1  0.000  0.000  0.000  1.0
  Li  Li2  1  0.669  0.165  0.169  1.0
  Li  Li3  1  0.835  0.836  0.833  1.0
  Li  Li4  1  0.331  0.335  0.330  1.0
  Li  Li5  1  0.500  0.000  0.000  1.0
  Li  Li6  1  0.165  0.164  0.167  1.0
  Li  Li7  1  0.000  0.500  0.500  1.0
  Li  Li8  1  0.000  0.000  0.500  1.0
  Li  Li9  1  0.669  0.665  0.670  1.0
  Li  Li10  1  0.835  0.331  0.331  1.0
  Li  Li11  1  0.836  0.835  0.333  1.0
  Li  Li12  1  0.335  0.331  0.830  1.0
  Li  Li13  1  0.165  0.669  0.669  1.0
  Li  Li14  1  0.164  0.165  0.667  1.0
  Li  Li15  1  0.665  0.669  0.170  1.0
  Ti  Ti16  1  0.329  0.856  0.325  1.0
  Ti  Ti17  1  0.671  0.144  0.675  1.0
  Ti  Ti18  1  0.500  0.500  0.500  1.0
  Ti  Ti19  1  0.500  0.000  0.500  1.0
  Ti  Ti20  1  0.000  0.500  0.000  1.0
  Ti  Ti21  1  0.856  0.329  0.825  1.0
  Ti  Ti22  1  0.500  0.500  0.000  1.0
  Ti  Ti23  1  0.144  0.671  0.175  1.0
  O  O24  1  0.752  0.722  0.001  1.0
  O  O25  1  0.403  0.900  0.175  1.0
  O  O26  1  0.099  0.064  0.336  1.0
  O  O27  1  0.246  0.733  0.003  1.0
  O  O28  1  0.722  0.752  0.501  1.0
  O  O29  1  0.936  0.901  0.164  1.0
  O  O30  1  0.733  0.246  0.503  1.0
  O  O31  1  0.432  0.934  0.658  1.0
  O  O32  1  0.433  0.415  0.653  1.0
  O  O33  1  0.568  0.066  0.342  1.0
  O  O34  1  0.064  0.099  0.836  1.0
  O  O35  1  0.066  0.568  0.842  1.0
  O  O36  1  0.267  0.754  0.497  1.0
  O  O37  1  0.278  0.248  0.499  1.0
  O  O38  1  0.901  0.936  0.664  1.0
  O  O39  1  0.754  0.267  0.997  1.0
  O  O40  1  0.900  0.403  0.675  1.0
  O  O41  1  0.415  0.433  0.153  1.0
  O  O42  1  0.597  0.100  0.825  1.0
  O  O43  1  0.585  0.567  0.847  1.0
  O  O44  1  0.248  0.278  0.999  1.0
  O  O45  1  0.100  0.597  0.325  1.0
  O  O46  1  0.934  0.432  0.158  1.0
  O  O47  1  0.567  0.585  0.347  1.0
[/CIF]
.