The structure described by WF8(NO)2 is Cotunnite structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight nitroxyl molecules and four WF8 clusters. In each WF8 cluster, W(1) is bonded in a 8-coordinate geometry to one F(1), one F(2), two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF file [CIF]
data_WN2(OF4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.295
_cell_length_b   5.880
_cell_length_c   12.596
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   688.462
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.228  0.250  0.129  1.0
  W  W1  1  0.728  0.250  0.371  1.0
  W  W2  1  0.772  0.750  0.871  1.0
  W  W3  1  0.272  0.750  0.629  1.0
  N  N4  1  0.496  0.250  0.771  1.0
  N  N5  1  0.996  0.250  0.729  1.0
  N  N6  1  0.504  0.750  0.229  1.0
  N  N7  1  0.004  0.750  0.271  1.0
  N  N8  1  0.246  0.250  0.435  1.0
  N  N9  1  0.746  0.250  0.065  1.0
  N  N10  1  0.754  0.750  0.565  1.0
  N  N11  1  0.254  0.750  0.935  1.0
  O  O12  1  0.549  0.250  0.693  1.0
  O  O13  1  0.049  0.250  0.807  1.0
  O  O14  1  0.451  0.750  0.307  1.0
  O  O15  1  0.951  0.750  0.193  1.0
  O  O16  1  0.132  0.250  0.457  1.0
  O  O17  1  0.632  0.250  0.043  1.0
  O  O18  1  0.868  0.750  0.543  1.0
  O  O19  1  0.368  0.750  0.957  1.0
  F  F20  1  0.275  0.250  0.977  1.0
  F  F21  1  0.775  0.250  0.523  1.0
  F  F22  1  0.725  0.750  0.023  1.0
  F  F23  1  0.225  0.750  0.477  1.0
  F  F24  1  0.025  0.250  0.170  1.0
  F  F25  1  0.525  0.250  0.330  1.0
  F  F26  1  0.975  0.750  0.830  1.0
  F  F27  1  0.475  0.750  0.670  1.0
  F  F28  1  0.141  0.973  0.068  1.0
  F  F29  1  0.641  0.527  0.432  1.0
  F  F30  1  0.859  0.473  0.932  1.0
  F  F31  1  0.359  0.027  0.568  1.0
  F  F32  1  0.859  0.027  0.932  1.0
  F  F33  1  0.359  0.473  0.568  1.0
  F  F34  1  0.141  0.527  0.068  1.0
  F  F35  1  0.641  0.973  0.432  1.0
  F  F36  1  0.400  0.456  0.121  1.0
  F  F37  1  0.900  0.044  0.379  1.0
  F  F38  1  0.600  0.956  0.879  1.0
  F  F39  1  0.100  0.544  0.621  1.0
  F  F40  1  0.600  0.544  0.879  1.0
  F  F41  1  0.100  0.956  0.621  1.0
  F  F42  1  0.400  0.044  0.121  1.0
  F  F43  1  0.900  0.456  0.379  1.0
  F  F44  1  0.225  0.455  0.256  1.0
  F  F45  1  0.725  0.045  0.244  1.0
  F  F46  1  0.775  0.955  0.744  1.0
  F  F47  1  0.275  0.545  0.756  1.0
  F  F48  1  0.775  0.545  0.744  1.0
  F  F49  1  0.275  0.955  0.756  1.0
  F  F50  1  0.225  0.045  0.256  1.0
  F  F51  1  0.725  0.455  0.244  1.0
[/CIF]
.
The structure described by WF8(NO)2 is Cotunnite structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight nitroxyl molecules and four WF8 clusters. In each WF8 cluster, W(1) is bonded in a 8-coordinate geometry to one F(1), one F(2), two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one W(1) atom. In the third F site, F(1) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one W(1) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF file [CIF]
data_WN2(OF4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.295
_cell_length_b   5.880
_cell_length_c   12.596
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   688.462
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.228  0.250  0.129  1.0
  W  W1  1  0.728  0.250  0.371  1.0
  W  W2  1  0.772  0.750  0.871  1.0
  W  W3  1  0.272  0.750  0.629  1.0
  N  N4  1  0.496  0.250  0.771  1.0
  N  N5  1  0.996  0.250  0.729  1.0
  N  N6  1  0.504  0.750  0.229  1.0
  N  N7  1  0.004  0.750  0.271  1.0
  N  N8  1  0.246  0.250  0.435  1.0
  N  N9  1  0.746  0.250  0.065  1.0
  N  N10  1  0.754  0.750  0.565  1.0
  N  N11  1  0.254  0.750  0.935  1.0
  O  O12  1  0.549  0.250  0.693  1.0
  O  O13  1  0.049  0.250  0.807  1.0
  O  O14  1  0.451  0.750  0.307  1.0
  O  O15  1  0.951  0.750  0.193  1.0
  O  O16  1  0.132  0.250  0.457  1.0
  O  O17  1  0.632  0.250  0.043  1.0
  O  O18  1  0.868  0.750  0.543  1.0
  O  O19  1  0.368  0.750  0.957  1.0
  F  F20  1  0.275  0.250  0.977  1.0
  F  F21  1  0.775  0.250  0.523  1.0
  F  F22  1  0.725  0.750  0.023  1.0
  F  F23  1  0.225  0.750  0.477  1.0
  F  F24  1  0.025  0.250  0.170  1.0
  F  F25  1  0.525  0.250  0.330  1.0
  F  F26  1  0.975  0.750  0.830  1.0
  F  F27  1  0.475  0.750  0.670  1.0
  F  F28  1  0.141  0.973  0.068  1.0
  F  F29  1  0.641  0.527  0.432  1.0
  F  F30  1  0.859  0.473  0.932  1.0
  F  F31  1  0.359  0.027  0.568  1.0
  F  F32  1  0.859  0.027  0.932  1.0
  F  F33  1  0.359  0.473  0.568  1.0
  F  F34  1  0.141  0.527  0.068  1.0
  F  F35  1  0.641  0.973  0.432  1.0
  F  F36  1  0.400  0.456  0.121  1.0
  F  F37  1  0.900  0.044  0.379  1.0
  F  F38  1  0.600  0.956  0.879  1.0
  F  F39  1  0.100  0.544  0.621  1.0
  F  F40  1  0.600  0.544  0.879  1.0
  F  F41  1  0.100  0.956  0.621  1.0
  F  F42  1  0.400  0.044  0.121  1.0
  F  F43  1  0.900  0.456  0.379  1.0
  F  F44  1  0.225  0.455  0.256  1.0
  F  F45  1  0.725  0.045  0.244  1.0
  F  F46  1  0.775  0.955  0.744  1.0
  F  F47  1  0.275  0.545  0.756  1.0
  F  F48  1  0.775  0.545  0.744  1.0
  F  F49  1  0.275  0.955  0.756  1.0
  F  F50  1  0.225  0.045  0.256  1.0
  F  F51  1  0.725  0.455  0.244  1.0
[/CIF]
.