The material described by KP2(W3O11)2 is Potassium Silver Cyanide-like structured and crystallizes in the monoclinic Pm space group. K(1) is bonded in a 8-coordinate geometry to one O(3), one O(7), two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. There are six inequivalent W sites. In the first W site, W(1) is bonded to one O(13), one O(3), two equivalent O(2), and two equivalent O(5) atoms to form WO6 octahedra that share  a cornercorner with one W(5)O6 octahedra, corners with two equivalent W(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 1-12°. In the second W site, W(2) is bonded to one O(14), one O(4), two equivalent O(1), and two equivalent O(6) atoms to form WO6 octahedra that share  a cornercorner with one W(6)O6 octahedra, corners with two equivalent W(3)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 2-13°. In the third W site, W(3) is bonded to one O(7), one O(9), two equivalent O(12), and two equivalent O(6) atoms to form WO6 octahedra that share  a cornercorner with one W(5)O6 octahedra, corners with two equivalent W(2)O6 octahedra, corners with two equivalent W(6)O6 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 3-13°. In the fourth W site, W(4) is bonded to one O(10), one O(8), two equivalent O(11), and two equivalent O(5) atoms to form WO6 octahedra that share  a cornercorner with one W(6)O6 octahedra, corners with two equivalent W(1)O6 octahedra, corners with two equivalent W(5)O6 octahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the fifth W site, W(5) is bonded to one O(13), one O(9), two equivalent O(11), and two equivalent O(15) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the sixth W site, W(6) is bonded to one O(10), one O(14), two equivalent O(12), and two equivalent O(15) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(3), one O(7), and two equivalent O(1) atoms to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(3)O6 octahedra, and corners with two equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-39°. In the second P site, P(2) is bonded to one O(4), one O(8), and two equivalent O(2) atoms to form PO4 tetrahedra that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(4)O6 octahedra, and corners with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-40°. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one W(2) and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one K(1), one W(1), and one P(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one K(1), one W(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent K(1), one W(2), and one P(2) atom. In the fifth O site, O(5) is bonded in a linear geometry to one W(1) and one W(4) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one K(1), one W(2), and one W(3) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one K(1), one W(3), and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one W(4) and one P(2) atom. In the ninth O site, O(9) is bonded in a linear geometry to one W(3) and one W(5) atom. In the tenth O site, O(10) is bonded in a linear geometry to one W(4) and one W(6) atom. In the eleventh O site, O(11) is bonded in a linear geometry to one W(4) and one W(5) atom. In the twelfth O site, O(12) is bonded in a linear geometry to one W(3) and one W(6) atom. In the thirteenth O site, O(13) is bonded in a linear geometry to one W(1) and one W(5) atom. In the fourteenth O site, O(14) is bonded in a linear geometry to one W(2) and one W(6) atom. In the fifteenth O site, O(15) is bonded in a linear geometry to one W(5) and one W(6) atom. is represented by the CIF card [CIF]
data_KP2(W3O11)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.452
_cell_length_b   6.811
_cell_length_c   12.139
_cell_angle_alpha   87.253
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   450.250
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.139  0.502  1.0
  P  P1  1  0.000  0.667  0.597  1.0
  P  P2  1  0.500  0.334  0.402  1.0
  W  W3  1  0.000  0.647  0.314  1.0
  W  W4  1  0.500  0.357  0.685  1.0
  W  W5  1  0.000  0.008  0.810  1.0
  W  W6  1  0.500  0.992  0.191  1.0
  W  W7  1  0.000  0.329  0.061  1.0
  W  W8  1  0.500  0.671  0.940  1.0
  O  O9  1  0.233  0.544  0.618  1.0
  O  O10  1  0.737  0.452  0.382  1.0
  O  O11  1  0.263  0.452  0.382  1.0
  O  O12  1  0.767  0.544  0.618  1.0
  O  O13  1  0.000  0.745  0.474  1.0
  O  O14  1  0.500  0.255  0.526  1.0
  O  O15  1  0.752  0.821  0.271  1.0
  O  O16  1  0.251  0.180  0.728  1.0
  O  O17  1  0.749  0.180  0.728  1.0
  O  O18  1  0.248  0.821  0.271  1.0
  O  O19  1  0.000  0.852  0.665  1.0
  O  O20  1  0.500  0.148  0.335  1.0
  O  O21  1  0.000  0.170  0.928  1.0
  O  O22  1  0.500  0.830  0.071  1.0
  O  O23  1  0.750  0.158  0.132  1.0
  O  O24  1  0.250  0.842  0.868  1.0
  O  O25  1  0.750  0.842  0.868  1.0
  O  O26  1  0.250  0.158  0.132  1.0
  O  O27  1  0.000  0.499  0.193  1.0
  O  O28  1  0.500  0.502  0.807  1.0
  O  O29  1  0.251  0.501  1.000  1.0
  O  O30  1  0.749  0.501  1.000  1.0
[/CIF]
.
The material described by KP2(W3O11)2 is Potassium Silver Cyanide-like structured and crystallizes in the monoclinic Pm space group. K(1) is bonded in a 8-coordinate geometry to one O(3), one O(7), two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. There are six inequivalent W sites. In the first W site, W(1) is bonded to one O(13), one O(3), two equivalent O(2), and two equivalent O(5) atoms to form WO6 octahedra that share  a cornercorner with one W(5)O6 octahedra, corners with two equivalent W(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 1-12°. In the second W site, W(2) is bonded to one O(14), one O(4), two equivalent O(1), and two equivalent O(6) atoms to form WO6 octahedra that share  a cornercorner with one W(6)O6 octahedra, corners with two equivalent W(3)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 2-13°. In the third W site, W(3) is bonded to one O(7), one O(9), two equivalent O(12), and two equivalent O(6) atoms to form WO6 octahedra that share  a cornercorner with one W(5)O6 octahedra, corners with two equivalent W(2)O6 octahedra, corners with two equivalent W(6)O6 octahedra, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 3-13°. In the fourth W site, W(4) is bonded to one O(10), one O(8), two equivalent O(11), and two equivalent O(5) atoms to form WO6 octahedra that share  a cornercorner with one W(6)O6 octahedra, corners with two equivalent W(1)O6 octahedra, corners with two equivalent W(5)O6 octahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 3-12°. In the fifth W site, W(5) is bonded to one O(13), one O(9), two equivalent O(11), and two equivalent O(15) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the sixth W site, W(6) is bonded to one O(10), one O(14), two equivalent O(12), and two equivalent O(15) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(3), one O(7), and two equivalent O(1) atoms to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(3)O6 octahedra, and corners with two equivalent W(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 15-39°. In the second P site, P(2) is bonded to one O(4), one O(8), and two equivalent O(2) atoms to form PO4 tetrahedra that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(4)O6 octahedra, and corners with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-40°. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one W(2) and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one K(1), one W(1), and one P(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one K(1), one W(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent K(1), one W(2), and one P(2) atom. In the fifth O site, O(5) is bonded in a linear geometry to one W(1) and one W(4) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one K(1), one W(2), and one W(3) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one K(1), one W(3), and one P(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one W(4) and one P(2) atom. In the ninth O site, O(9) is bonded in a linear geometry to one W(3) and one W(5) atom. In the tenth O site, O(10) is bonded in a linear geometry to one W(4) and one W(6) atom. In the eleventh O site, O(11) is bonded in a linear geometry to one W(4) and one W(5) atom. In the twelfth O site, O(12) is bonded in a linear geometry to one W(3) and one W(6) atom. In the thirteenth O site, O(13) is bonded in a linear geometry to one W(1) and one W(5) atom. In the fourteenth O site, O(14) is bonded in a linear geometry to one W(2) and one W(6) atom. In the fifteenth O site, O(15) is bonded in a linear geometry to one W(5) and one W(6) atom. is represented by the CIF card [CIF]
data_KP2(W3O11)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.452
_cell_length_b   6.811
_cell_length_c   12.139
_cell_angle_alpha   87.253
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   450.250
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.000  0.139  0.502  1.0
  P  P1  1  0.000  0.667  0.597  1.0
  P  P2  1  0.500  0.334  0.402  1.0
  W  W3  1  0.000  0.647  0.314  1.0
  W  W4  1  0.500  0.357  0.685  1.0
  W  W5  1  0.000  0.008  0.810  1.0
  W  W6  1  0.500  0.992  0.191  1.0
  W  W7  1  0.000  0.329  0.061  1.0
  W  W8  1  0.500  0.671  0.940  1.0
  O  O9  1  0.233  0.544  0.618  1.0
  O  O10  1  0.737  0.452  0.382  1.0
  O  O11  1  0.263  0.452  0.382  1.0
  O  O12  1  0.767  0.544  0.618  1.0
  O  O13  1  0.000  0.745  0.474  1.0
  O  O14  1  0.500  0.255  0.526  1.0
  O  O15  1  0.752  0.821  0.271  1.0
  O  O16  1  0.251  0.180  0.728  1.0
  O  O17  1  0.749  0.180  0.728  1.0
  O  O18  1  0.248  0.821  0.271  1.0
  O  O19  1  0.000  0.852  0.665  1.0
  O  O20  1  0.500  0.148  0.335  1.0
  O  O21  1  0.000  0.170  0.928  1.0
  O  O22  1  0.500  0.830  0.071  1.0
  O  O23  1  0.750  0.158  0.132  1.0
  O  O24  1  0.250  0.842  0.868  1.0
  O  O25  1  0.750  0.842  0.868  1.0
  O  O26  1  0.250  0.158  0.132  1.0
  O  O27  1  0.000  0.499  0.193  1.0
  O  O28  1  0.500  0.502  0.807  1.0
  O  O29  1  0.251  0.501  1.000  1.0
  O  O30  1  0.749  0.501  1.000  1.0
[/CIF]
.