The structure described by B5NO12 is Indium-like structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two B5NO12 clusters. There are five inequivalent B sites. In the first B site, B(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(6) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(7) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(8) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(9) atom. In the fifth B site, B(5) is bonded in a trigonal planar geometry to one O(10), one O(5), and one O(6) atom. N(1) is bonded in a single-bond geometry to one O(7) atom. There are twelve inequivalent O sites. In the first O site, O(11) is bonded in a single-bond geometry to one O(9) atom. In the second O site, O(12) is bonded in a single-bond geometry to one O(8) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one B(1) and one B(2) atom. In the fourth O site, O(2) is bonded in a water-like geometry to one B(2) and one B(3) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one B(1) and one B(3) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one B(1) and one B(4) atom. In the seventh O site, O(5) is bonded in a bent 120 degrees geometry to one B(4) and one B(5) atom. In the eighth O site, O(6) is bonded in a bent 120 degrees geometry to one B(1) and one B(5) atom. In the ninth O site, O(7) is bonded in a bent 120 degrees geometry to one B(2) and one N(1) atom. In the tenth O site, O(8) is bonded in a distorted single-bond geometry to one B(3) and one O(12) atom. In the eleventh O site, O(9) is bonded in a distorted single-bond geometry to one B(4) and one O(11) atom. In the twelfth O site, O(10) is bonded in a single-bond geometry to one B(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_B5NO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.573
_cell_length_b   7.470
_cell_length_c   9.990
_cell_angle_alpha   51.484
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   558.967
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.254  0.817  0.580  1.0
  B  B1  1  0.746  0.817  0.080  1.0
  B  B2  1  0.495  0.893  0.479  1.0
  B  B3  1  0.505  0.893  0.979  1.0
  B  B4  1  0.463  0.624  0.766  1.0
  B  B5  1  0.537  0.624  0.266  1.0
  B  B6  1  0.035  0.982  0.573  1.0
  B  B7  1  0.965  0.982  0.073  1.0
  B  B8  1  0.028  0.704  0.534  1.0
  B  B9  1  0.972  0.704  0.034  1.0
  N  N10  1  0.723  0.023  0.339  1.0
  N  N11  1  0.277  0.023  0.839  1.0
  O  O12  1  0.363  0.947  0.438  1.0
  O  O13  1  0.637  0.947  0.938  1.0
  O  O14  1  0.558  0.735  0.631  1.0
  O  O15  1  0.442  0.735  0.131  1.0
  O  O16  1  0.326  0.661  0.748  1.0
  O  O17  1  0.674  0.661  0.248  1.0
  O  O18  1  0.174  0.988  0.578  1.0
  O  O19  1  0.826  0.988  0.078  1.0
  O  O20  1  0.954  0.848  0.557  1.0
  O  O21  1  0.046  0.848  0.057  1.0
  O  O22  1  0.169  0.684  0.550  1.0
  O  O23  1  0.831  0.684  0.050  1.0
  O  O24  1  0.595  0.042  0.327  1.0
  O  O25  1  0.405  0.042  0.827  1.0
  O  O26  1  0.514  0.464  0.939  1.0
  O  O27  1  0.486  0.464  0.439  1.0
  O  O28  1  0.962  0.148  0.584  1.0
  O  O29  1  0.038  0.148  0.084  1.0
  O  O30  1  0.951  0.595  0.491  1.0
  O  O31  1  0.049  0.595  0.991  1.0
  O  O32  1  0.827  0.169  0.556  1.0
  O  O33  1  0.173  0.169  0.056  1.0
  O  O34  1  0.654  0.440  0.952  1.0
  O  O35  1  0.346  0.440  0.452  1.0
[/CIF]
.
The structure described by B5NO12 is Indium-like structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two B5NO12 clusters. There are five inequivalent B sites. In the first B site, B(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(6) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(7) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(2), one O(3), and one O(8) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(4), one O(5), and one O(9) atom. In the fifth B site, B(5) is bonded in a trigonal planar geometry to one O(10), one O(5), and one O(6) atom. N(1) is bonded in a single-bond geometry to one O(7) atom. There are twelve inequivalent O sites. In the first O site, O(11) is bonded in a single-bond geometry to one O(9) atom. In the second O site, O(12) is bonded in a single-bond geometry to one O(8) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one B(1) and one B(2) atom. In the fourth O site, O(2) is bonded in a water-like geometry to one B(2) and one B(3) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one B(1) and one B(3) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one B(1) and one B(4) atom. In the seventh O site, O(5) is bonded in a bent 120 degrees geometry to one B(4) and one B(5) atom. In the eighth O site, O(6) is bonded in a bent 120 degrees geometry to one B(1) and one B(5) atom. In the ninth O site, O(7) is bonded in a bent 120 degrees geometry to one B(2) and one N(1) atom. In the tenth O site, O(8) is bonded in a distorted single-bond geometry to one B(3) and one O(12) atom. In the eleventh O site, O(9) is bonded in a distorted single-bond geometry to one B(4) and one O(11) atom. In the twelfth O site, O(10) is bonded in a single-bond geometry to one B(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_B5NO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.573
_cell_length_b   7.470
_cell_length_c   9.990
_cell_angle_alpha   51.484
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   558.967
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.254  0.817  0.580  1.0
  B  B1  1  0.746  0.817  0.080  1.0
  B  B2  1  0.495  0.893  0.479  1.0
  B  B3  1  0.505  0.893  0.979  1.0
  B  B4  1  0.463  0.624  0.766  1.0
  B  B5  1  0.537  0.624  0.266  1.0
  B  B6  1  0.035  0.982  0.573  1.0
  B  B7  1  0.965  0.982  0.073  1.0
  B  B8  1  0.028  0.704  0.534  1.0
  B  B9  1  0.972  0.704  0.034  1.0
  N  N10  1  0.723  0.023  0.339  1.0
  N  N11  1  0.277  0.023  0.839  1.0
  O  O12  1  0.363  0.947  0.438  1.0
  O  O13  1  0.637  0.947  0.938  1.0
  O  O14  1  0.558  0.735  0.631  1.0
  O  O15  1  0.442  0.735  0.131  1.0
  O  O16  1  0.326  0.661  0.748  1.0
  O  O17  1  0.674  0.661  0.248  1.0
  O  O18  1  0.174  0.988  0.578  1.0
  O  O19  1  0.826  0.988  0.078  1.0
  O  O20  1  0.954  0.848  0.557  1.0
  O  O21  1  0.046  0.848  0.057  1.0
  O  O22  1  0.169  0.684  0.550  1.0
  O  O23  1  0.831  0.684  0.050  1.0
  O  O24  1  0.595  0.042  0.327  1.0
  O  O25  1  0.405  0.042  0.827  1.0
  O  O26  1  0.514  0.464  0.939  1.0
  O  O27  1  0.486  0.464  0.439  1.0
  O  O28  1  0.962  0.148  0.584  1.0
  O  O29  1  0.038  0.148  0.084  1.0
  O  O30  1  0.951  0.595  0.491  1.0
  O  O31  1  0.049  0.595  0.991  1.0
  O  O32  1  0.827  0.169  0.556  1.0
  O  O33  1  0.173  0.169  0.056  1.0
  O  O34  1  0.654  0.440  0.952  1.0
  O  O35  1  0.346  0.440  0.452  1.0
[/CIF]
.