The material structure described by Tb(CoGa)6 crystallizes in the orthorhombic Immm space group. Tb(1) is bonded in a 20-coordinate geometry to four equivalent Co(2), eight equivalent Co(1), two equivalent Ga(2), two equivalent Ga(3), and four equivalent Ga(1) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent Tb(1), two equivalent Co(1), two equivalent Co(2), two equivalent Ga(1), two equivalent Ga(2), and two equivalent Ga(3) atoms to form a mixture of distorted edge, face, and corner-sharing CoTb2Ga6Co4 cuboctahedra. In the second Co site, Co(2) is bonded to two equivalent Tb(1), four equivalent Co(1), two equivalent Ga(1), two equivalent Ga(2), and two equivalent Ga(3) atoms to form a mixture of distorted edge, face, and corner-sharing CoTb2Ga6Co4 cuboctahedra. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 8-coordinate geometry to two equivalent Tb(1), two equivalent Co(2), four equivalent Co(1), and two equivalent Ga(3) atoms. In the second Ga site, Ga(2) is bonded in a 8-coordinate geometry to one Tb(1), two equivalent Co(2), four equivalent Co(1), and one Ga(2) atom. In the third Ga site, Ga(3) is bonded in a 10-coordinate geometry to one Tb(1), two equivalent Co(2), four equivalent Co(1), one Ga(3), and two equivalent Ga(1) atoms. is represented by the CIF card [CIF]
data_Tb(GaCo)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.051
_cell_length_b   6.481
_cell_length_c   6.481
_cell_angle_alpha   83.336
_cell_angle_beta   67.064
_cell_angle_gamma   67.064
_symmetry_Int_Tables_number   1
_cell_volume   179.808
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.000  0.000  0.000  1.0
  Ga  Ga1  1  0.500  0.190  0.810  1.0
  Ga  Ga2  1  0.500  0.810  0.190  1.0
  Ga  Ga3  1  0.341  0.659  0.659  1.0
  Ga  Ga4  1  0.659  0.341  0.341  1.0
  Ga  Ga5  1  0.000  0.345  0.655  1.0
  Ga  Ga6  1  0.000  0.655  0.345  1.0
  Co  Co7  1  0.500  0.000  0.500  1.0
  Co  Co8  1  0.500  0.500  0.000  1.0
  Co  Co9  1  0.000  0.500  0.000  1.0
  Co  Co10  1  0.000  0.000  0.500  1.0
  Co  Co11  1  0.262  0.238  0.238  1.0
  Co  Co12  1  0.738  0.762  0.762  1.0
[/CIF]
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The material structure described by Tb(CoGa)6 crystallizes in the orthorhombic Immm space group. Tb(1) is bonded in a 20-coordinate geometry to four equivalent Co(2), eight equivalent Co(1), two equivalent Ga(2), two equivalent Ga(3), and four equivalent Ga(1) atoms. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent Tb(1), two equivalent Co(1), two equivalent Co(2), two equivalent Ga(1), two equivalent Ga(2), and two equivalent Ga(3) atoms to form a mixture of distorted edge, face, and corner-sharing CoTb2Ga6Co4 cuboctahedra. In the second Co site, Co(2) is bonded to two equivalent Tb(1), four equivalent Co(1), two equivalent Ga(1), two equivalent Ga(2), and two equivalent Ga(3) atoms to form a mixture of distorted edge, face, and corner-sharing CoTb2Ga6Co4 cuboctahedra. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 8-coordinate geometry to two equivalent Tb(1), two equivalent Co(2), four equivalent Co(1), and two equivalent Ga(3) atoms. In the second Ga site, Ga(2) is bonded in a 8-coordinate geometry to one Tb(1), two equivalent Co(2), four equivalent Co(1), and one Ga(2) atom. In the third Ga site, Ga(3) is bonded in a 10-coordinate geometry to one Tb(1), two equivalent Co(2), four equivalent Co(1), one Ga(3), and two equivalent Ga(1) atoms. is represented by the CIF card [CIF]
data_Tb(GaCo)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.051
_cell_length_b   6.481
_cell_length_c   6.481
_cell_angle_alpha   83.336
_cell_angle_beta   67.064
_cell_angle_gamma   67.064
_symmetry_Int_Tables_number   1
_cell_volume   179.808
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.000  0.000  0.000  1.0
  Ga  Ga1  1  0.500  0.190  0.810  1.0
  Ga  Ga2  1  0.500  0.810  0.190  1.0
  Ga  Ga3  1  0.341  0.659  0.659  1.0
  Ga  Ga4  1  0.659  0.341  0.341  1.0
  Ga  Ga5  1  0.000  0.345  0.655  1.0
  Ga  Ga6  1  0.000  0.655  0.345  1.0
  Co  Co7  1  0.500  0.000  0.500  1.0
  Co  Co8  1  0.500  0.500  0.000  1.0
  Co  Co9  1  0.000  0.500  0.000  1.0
  Co  Co10  1  0.000  0.000  0.500  1.0
  Co  Co11  1  0.262  0.238  0.238  1.0
  Co  Co12  1  0.738  0.762  0.762  1.0
[/CIF]
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