The structure described by Na4Ni2C4SO16 crystallizes in the triclinic P1 space group. There are eight inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(10), one O(13), one O(14), one O(3), one O(4), and one O(9) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(3)O6 octahedra,  a cornercorner with one Na(5)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra, and  an edgeedge with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 62-82°. In the second Na site, Na(2) is bonded in a distorted hexagonal planar geometry to one O(14), one O(16), one O(27), one O(29), one O(31), and one O(8) atom. In the third Na site, Na(3) is bonded to one O(13), one O(15), one O(28), one O(30), one O(32), and one O(7) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one Na(7)O6 octahedra,  a cornercorner with one Na(8)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, and  an edgeedge with one S(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-87°. In the fourth Na site, Na(4) is bonded in a distorted hexagonal planar geometry to one O(18), one O(19), one O(2), one O(26), one O(4), and one O(6) atom. In the fifth Na site, Na(5) is bonded to one O(1), one O(17), one O(20), one O(25), one O(3), and one O(5) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one Na(7)O6 octahedra,  a cornercorner with one Na(8)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, and  an edgeedge with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 59-81°. In the sixth Na site, Na(6) is bonded in a distorted hexagonal planar geometry to one O(16), one O(2), one O(22), one O(24), one O(3), and one O(7) atom. In the seventh Na site, Na(7) is bonded to one O(19), one O(20), one O(23), one O(24), one O(29), and one O(30) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(3)O6 octahedra,  a cornercorner with one Na(5)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra, and  an edgeedge with one S(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-81°. In the eighth Na site, Na(8) is bonded to one O(1), one O(11), one O(12), one O(2), one O(27), and one O(28) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(3)O6 octahedra,  a cornercorner with one Na(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, and  an edgeedge with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 59-87°. There are four inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(11), one O(22), one O(25), one O(28), one O(5), and one O(7) atom to form NiO6 octahedra that share  an edgeedge with one Na(3)O6 octahedra,  an edgeedge with one Na(5)O6 octahedra, and  an edgeedge with one Na(8)O6 octahedra. In the second Ni site, Ni(2) is bonded to one O(12), one O(21), one O(26), one O(27), one O(6), and one O(8) atom to form NiO6 octahedra that share  an edgeedge with one Na(8)O6 octahedra. In the third Ni site, Ni(3) is bonded to one O(10), one O(13), one O(15), one O(17), one O(20), and one O(23) atom to form NiO6 octahedra that share  an edgeedge with one Na(1)O6 octahedra,  an edgeedge with one Na(3)O6 octahedra,  an edgeedge with one Na(5)O6 octahedra, and  an edgeedge with one Na(7)O6 octahedra. In the fourth Ni site, Ni(4) is bonded to one O(14), one O(16), one O(18), one O(19), one O(24), and one O(9) atom to form NiO6 octahedra that share  an edgeedge with one Na(1)O6 octahedra and  an edgeedge with one Na(7)O6 octahedra. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(10), one O(6), and one O(7) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(5), one O(8), and one O(9) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(11), one O(15), and one O(19) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(12), one O(16), and one O(20) atom. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one O(14), one O(17), and one O(22) atom. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one O(13), one O(18), and one O(21) atom. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one O(23), one O(25), and one O(27) atom. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one O(24), one O(26), and one O(28) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share  an edgeedge with one Na(1)O6 octahedra,  an edgeedge with one Na(5)O6 octahedra, and  an edgeedge with one Na(8)O6 octahedra. In the second S site, S(2) is bonded to one O(29), one O(30), one O(31), and one O(32) atom to form SO4 tetrahedra that share  an edgeedge with one Na(3)O6 octahedra and  an edgeedge with one Na(7)O6 octahedra. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(5), one Na(8), and one S(1) atom. In the second O site, O(2) is bonded to one Na(4), one Na(6), one Na(8), and one S(1) atom to form distorted edge-sharing ONa3S trigonal pyramids. In the third O site, O(3) is bonded to one Na(1), one Na(5), one Na(6), and one S(1) atom to form distorted edge-sharing ONa3S trigonal pyramids. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(1), one Na(4), and one S(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(5), one Ni(1), and one C(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(4), one Ni(2), and one C(1) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Na(3), one Na(6), one Ni(1), and one C(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Na(2), one Ni(2), and one C(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Na(1), one Ni(4), and one C(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Na(1), one Ni(3), and one C(1) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Na(8), one Ni(1), and one C(3) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Na(8), one Ni(2), and one C(4) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Na(1), one Na(3), one Ni(3), and one C(6) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(2), one Ni(4), and one C(5) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Na(3), one Ni(3), and one C(3) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(6), one Ni(4), and one C(4) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Na(5), one Ni(3), and one C(5) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Na(4), one Ni(4), and one C(6) atom. In the nineteenth O site, O(19) is bonded in a distorted rectangular see-saw-like geometry to one Na(4), one Na(7), one Ni(4), and one C(3) atom. In the twentieth O site, O(20) is bonded in a distorted rectangular see-saw-like geometry to one Na(5), one Na(7), one Ni(3), and one C(4) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 120 degrees geometry to one Ni(2) and one C(6) atom. In the twenty-second O site, O(22) is bonded in a distorted trigonal planar geometry to one Na(6), one Ni(1), and one C(5) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one Na(7), one Ni(3), and one C(7) atom. In the twenty-fourth O site, O(24) is bonded in a distorted rectangular see-saw-like geometry to one Na(6), one Na(7), one Ni(4), and one C(8) atom. In the twenty-fifth O site, O(25) is bonded in a 3-coordinate geometry to one Na(5), one Ni(1), and one C(7) atom. In the twenty-sixth O site, O(26) is bonded in a 3-coordinate geometry to one Na(4), one Ni(2), and one C(8) atom. In the twenty-seventh O site, O(27) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(8), one Ni(2), and one C(7) atom. In the twenty-eighth O site, O(28) is bonded in a distorted rectangular see-saw-like geometry to one Na(3), one Na(8), one Ni(1), and one C(8) atom. In the twenty-ninth O site, O(29) is bonded in a 3-coordinate geometry to one Na(2), one Na(7), and one S(2) atom. In the thirtieth O site, O(30) is bonded in a distorted T-shaped geometry to one Na(3), one Na(7), and one S(2) atom. In the thirty-first O site, O(31) is bonded in an L-shaped geometry to one Na(2) and one S(2) atom. In the thirty-second O site, O(32) is bonded in an L-shaped geometry to one Na(3) and one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na4Ni2C4SO16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.800
_cell_length_b   9.844
_cell_length_c   9.880
_cell_angle_alpha   119.614
_cell_angle_beta   119.329
_cell_angle_gamma   90.185
_symmetry_Int_Tables_number   1
_cell_volume   683.455
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.413  0.088  0.749  1.0
  Na  Na1  1  0.169  0.910  0.255  1.0
  Na  Na2  1  0.582  0.347  0.255  1.0
  Na  Na3  1  0.845  0.091  0.760  1.0
  Na  Na4  1  0.409  0.650  0.734  1.0
  Na  Na5  1  0.846  0.092  0.176  1.0
  Na  Na6  1  0.586  0.908  0.255  1.0
  Na  Na7  1  0.837  0.659  0.749  1.0
  Ni  Ni8  1  0.001  0.500  0.500  1.0
  Ni  Ni9  1  1.000  0.499  0.999  1.0
  Ni  Ni10  1  0.499  0.501  0.998  1.0
  Ni  Ni11  1  0.999  0.001  0.501  1.0
  C  C12  1  0.783  0.353  0.070  1.0
  C  C13  1  0.144  0.715  0.427  1.0
  C  C14  1  0.784  0.713  0.427  1.0
  C  C15  1  0.786  0.718  0.071  1.0
  C  C16  1  0.213  0.285  0.572  1.0
  C  C17  1  0.214  0.285  0.928  1.0
  C  C18  1  0.215  0.645  0.928  1.0
  C  C19  1  0.854  0.284  0.569  1.0
  S  S20  1  0.627  0.876  0.752  1.0
  S  S21  1  0.377  0.124  0.251  1.0
  O  O22  1  0.570  0.692  0.634  1.0
  O  O23  1  0.813  0.937  0.876  1.0
  O  O24  1  0.564  0.937  0.876  1.0
  O  O25  1  0.569  0.943  0.635  1.0
  O  O26  1  0.148  0.602  0.458  1.0
  O  O27  1  0.899  0.352  0.043  1.0
  O  O28  1  0.806  0.349  0.209  1.0
  O  O29  1  0.137  0.690  0.284  1.0
  O  O30  1  0.152  0.860  0.548  1.0
  O  O31  1  0.641  0.350  0.953  1.0
  O  O32  1  0.896  0.689  0.546  1.0
  O  O33  1  0.812  0.603  0.956  1.0
  O  O34  1  0.361  0.305  0.960  1.0
  O  O35  1  0.194  0.139  0.541  1.0
  O  O36  1  0.648  0.594  0.282  1.0
  O  O37  1  0.902  0.861  0.210  1.0
  O  O38  1  0.349  0.404  0.714  1.0
  O  O39  1  0.097  0.147  0.787  1.0
  O  O40  1  0.806  0.859  0.459  1.0
  O  O41  1  0.642  0.696  0.043  1.0
  O  O42  1  0.189  0.402  0.041  1.0
  O  O43  1  0.096  0.308  0.455  1.0
  O  O44  1  0.357  0.651  0.048  1.0
  O  O45  1  0.844  0.139  0.445  1.0
  O  O46  1  0.192  0.637  0.785  1.0
  O  O47  1  0.866  0.308  0.715  1.0
  O  O48  1  0.099  0.654  0.958  1.0
  O  O49  1  0.846  0.400  0.540  1.0
  O  O50  1  0.434  0.057  0.369  1.0
  O  O51  1  0.445  0.068  0.134  1.0
  O  O52  1  0.192  0.064  0.130  1.0
  O  O53  1  0.434  0.309  0.373  1.0
[/CIF]
.
The structure described by Na4Ni2C4SO16 crystallizes in the triclinic P1 space group. There are eight inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(10), one O(13), one O(14), one O(3), one O(4), and one O(9) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(3)O6 octahedra,  a cornercorner with one Na(5)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra, and  an edgeedge with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 62-82°. In the second Na site, Na(2) is bonded in a distorted hexagonal planar geometry to one O(14), one O(16), one O(27), one O(29), one O(31), and one O(8) atom. In the third Na site, Na(3) is bonded to one O(13), one O(15), one O(28), one O(30), one O(32), and one O(7) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one Na(7)O6 octahedra,  a cornercorner with one Na(8)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, and  an edgeedge with one S(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-87°. In the fourth Na site, Na(4) is bonded in a distorted hexagonal planar geometry to one O(18), one O(19), one O(2), one O(26), one O(4), and one O(6) atom. In the fifth Na site, Na(5) is bonded to one O(1), one O(17), one O(20), one O(25), one O(3), and one O(5) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one Na(7)O6 octahedra,  a cornercorner with one Na(8)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra, and  an edgeedge with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 59-81°. In the sixth Na site, Na(6) is bonded in a distorted hexagonal planar geometry to one O(16), one O(2), one O(22), one O(24), one O(3), and one O(7) atom. In the seventh Na site, Na(7) is bonded to one O(19), one O(20), one O(23), one O(24), one O(29), and one O(30) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(3)O6 octahedra,  a cornercorner with one Na(5)O6 octahedra,  an edgeedge with one Ni(3)O6 octahedra,  an edgeedge with one Ni(4)O6 octahedra, and  an edgeedge with one S(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 56-81°. In the eighth Na site, Na(8) is bonded to one O(1), one O(11), one O(12), one O(2), one O(27), and one O(28) atom to form distorted NaO6 octahedra that share  a cornercorner with one Na(3)O6 octahedra,  a cornercorner with one Na(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, and  an edgeedge with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 59-87°. There are four inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(11), one O(22), one O(25), one O(28), one O(5), and one O(7) atom to form NiO6 octahedra that share  an edgeedge with one Na(3)O6 octahedra,  an edgeedge with one Na(5)O6 octahedra, and  an edgeedge with one Na(8)O6 octahedra. In the second Ni site, Ni(2) is bonded to one O(12), one O(21), one O(26), one O(27), one O(6), and one O(8) atom to form NiO6 octahedra that share  an edgeedge with one Na(8)O6 octahedra. In the third Ni site, Ni(3) is bonded to one O(10), one O(13), one O(15), one O(17), one O(20), and one O(23) atom to form NiO6 octahedra that share  an edgeedge with one Na(1)O6 octahedra,  an edgeedge with one Na(3)O6 octahedra,  an edgeedge with one Na(5)O6 octahedra, and  an edgeedge with one Na(7)O6 octahedra. In the fourth Ni site, Ni(4) is bonded to one O(14), one O(16), one O(18), one O(19), one O(24), and one O(9) atom to form NiO6 octahedra that share  an edgeedge with one Na(1)O6 octahedra and  an edgeedge with one Na(7)O6 octahedra. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one O(10), one O(6), and one O(7) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one O(5), one O(8), and one O(9) atom. In the third C site, C(3) is bonded in a trigonal planar geometry to one O(11), one O(15), and one O(19) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one O(12), one O(16), and one O(20) atom. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one O(14), one O(17), and one O(22) atom. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one O(13), one O(18), and one O(21) atom. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one O(23), one O(25), and one O(27) atom. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one O(24), one O(26), and one O(28) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share  an edgeedge with one Na(1)O6 octahedra,  an edgeedge with one Na(5)O6 octahedra, and  an edgeedge with one Na(8)O6 octahedra. In the second S site, S(2) is bonded to one O(29), one O(30), one O(31), and one O(32) atom to form SO4 tetrahedra that share  an edgeedge with one Na(3)O6 octahedra and  an edgeedge with one Na(7)O6 octahedra. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(5), one Na(8), and one S(1) atom. In the second O site, O(2) is bonded to one Na(4), one Na(6), one Na(8), and one S(1) atom to form distorted edge-sharing ONa3S trigonal pyramids. In the third O site, O(3) is bonded to one Na(1), one Na(5), one Na(6), and one S(1) atom to form distorted edge-sharing ONa3S trigonal pyramids. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Na(1), one Na(4), and one S(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(5), one Ni(1), and one C(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(4), one Ni(2), and one C(1) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Na(3), one Na(6), one Ni(1), and one C(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Na(2), one Ni(2), and one C(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Na(1), one Ni(4), and one C(2) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Na(1), one Ni(3), and one C(1) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Na(8), one Ni(1), and one C(3) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Na(8), one Ni(2), and one C(4) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Na(1), one Na(3), one Ni(3), and one C(6) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(2), one Ni(4), and one C(5) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Na(3), one Ni(3), and one C(3) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(6), one Ni(4), and one C(4) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Na(5), one Ni(3), and one C(5) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Na(4), one Ni(4), and one C(6) atom. In the nineteenth O site, O(19) is bonded in a distorted rectangular see-saw-like geometry to one Na(4), one Na(7), one Ni(4), and one C(3) atom. In the twentieth O site, O(20) is bonded in a distorted rectangular see-saw-like geometry to one Na(5), one Na(7), one Ni(3), and one C(4) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 120 degrees geometry to one Ni(2) and one C(6) atom. In the twenty-second O site, O(22) is bonded in a distorted trigonal planar geometry to one Na(6), one Ni(1), and one C(5) atom. In the twenty-third O site, O(23) is bonded in a 3-coordinate geometry to one Na(7), one Ni(3), and one C(7) atom. In the twenty-fourth O site, O(24) is bonded in a distorted rectangular see-saw-like geometry to one Na(6), one Na(7), one Ni(4), and one C(8) atom. In the twenty-fifth O site, O(25) is bonded in a 3-coordinate geometry to one Na(5), one Ni(1), and one C(7) atom. In the twenty-sixth O site, O(26) is bonded in a 3-coordinate geometry to one Na(4), one Ni(2), and one C(8) atom. In the twenty-seventh O site, O(27) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(8), one Ni(2), and one C(7) atom. In the twenty-eighth O site, O(28) is bonded in a distorted rectangular see-saw-like geometry to one Na(3), one Na(8), one Ni(1), and one C(8) atom. In the twenty-ninth O site, O(29) is bonded in a 3-coordinate geometry to one Na(2), one Na(7), and one S(2) atom. In the thirtieth O site, O(30) is bonded in a distorted T-shaped geometry to one Na(3), one Na(7), and one S(2) atom. In the thirty-first O site, O(31) is bonded in an L-shaped geometry to one Na(2) and one S(2) atom. In the thirty-second O site, O(32) is bonded in an L-shaped geometry to one Na(3) and one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na4Ni2C4SO16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.800
_cell_length_b   9.844
_cell_length_c   9.880
_cell_angle_alpha   119.614
_cell_angle_beta   119.329
_cell_angle_gamma   90.185
_symmetry_Int_Tables_number   1
_cell_volume   683.455
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.413  0.088  0.749  1.0
  Na  Na1  1  0.169  0.910  0.255  1.0
  Na  Na2  1  0.582  0.347  0.255  1.0
  Na  Na3  1  0.845  0.091  0.760  1.0
  Na  Na4  1  0.409  0.650  0.734  1.0
  Na  Na5  1  0.846  0.092  0.176  1.0
  Na  Na6  1  0.586  0.908  0.255  1.0
  Na  Na7  1  0.837  0.659  0.749  1.0
  Ni  Ni8  1  0.001  0.500  0.500  1.0
  Ni  Ni9  1  1.000  0.499  0.999  1.0
  Ni  Ni10  1  0.499  0.501  0.998  1.0
  Ni  Ni11  1  0.999  0.001  0.501  1.0
  C  C12  1  0.783  0.353  0.070  1.0
  C  C13  1  0.144  0.715  0.427  1.0
  C  C14  1  0.784  0.713  0.427  1.0
  C  C15  1  0.786  0.718  0.071  1.0
  C  C16  1  0.213  0.285  0.572  1.0
  C  C17  1  0.214  0.285  0.928  1.0
  C  C18  1  0.215  0.645  0.928  1.0
  C  C19  1  0.854  0.284  0.569  1.0
  S  S20  1  0.627  0.876  0.752  1.0
  S  S21  1  0.377  0.124  0.251  1.0
  O  O22  1  0.570  0.692  0.634  1.0
  O  O23  1  0.813  0.937  0.876  1.0
  O  O24  1  0.564  0.937  0.876  1.0
  O  O25  1  0.569  0.943  0.635  1.0
  O  O26  1  0.148  0.602  0.458  1.0
  O  O27  1  0.899  0.352  0.043  1.0
  O  O28  1  0.806  0.349  0.209  1.0
  O  O29  1  0.137  0.690  0.284  1.0
  O  O30  1  0.152  0.860  0.548  1.0
  O  O31  1  0.641  0.350  0.953  1.0
  O  O32  1  0.896  0.689  0.546  1.0
  O  O33  1  0.812  0.603  0.956  1.0
  O  O34  1  0.361  0.305  0.960  1.0
  O  O35  1  0.194  0.139  0.541  1.0
  O  O36  1  0.648  0.594  0.282  1.0
  O  O37  1  0.902  0.861  0.210  1.0
  O  O38  1  0.349  0.404  0.714  1.0
  O  O39  1  0.097  0.147  0.787  1.0
  O  O40  1  0.806  0.859  0.459  1.0
  O  O41  1  0.642  0.696  0.043  1.0
  O  O42  1  0.189  0.402  0.041  1.0
  O  O43  1  0.096  0.308  0.455  1.0
  O  O44  1  0.357  0.651  0.048  1.0
  O  O45  1  0.844  0.139  0.445  1.0
  O  O46  1  0.192  0.637  0.785  1.0
  O  O47  1  0.866  0.308  0.715  1.0
  O  O48  1  0.099  0.654  0.958  1.0
  O  O49  1  0.846  0.400  0.540  1.0
  O  O50  1  0.434  0.057  0.369  1.0
  O  O51  1  0.445  0.068  0.134  1.0
  O  O52  1  0.192  0.064  0.130  1.0
  O  O53  1  0.434  0.309  0.373  1.0
[/CIF]
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