The compound described by ZrTiRh crystallizes in the orthorhombic Amm2 space group. There are six inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 16-coordinate geometry to one Zr(1); three Zr(2,2); one Ti(3); two equivalent Ti(1); two equivalent Ti(2); three equivalent Rh(1); and four equivalent Rh(2) atoms. In the second Zr site, Zr(2) is bonded in a 16-coordinate geometry to one Zr(2); three Zr(1,1); one Ti(1); two equivalent Ti(3); four equivalent Ti(2); two equivalent Rh(2); and three equivalent Rh(1) atoms. In the third Zr site, Zr(1) is bonded in a 16-coordinate geometry to one Zr(1); three Zr(2,2); one Ti(3); two equivalent Ti(1); two equivalent Ti(2); three equivalent Rh(1); and four equivalent Rh(2) atoms. In the fourth Zr site, Zr(1) is bonded in a 16-coordinate geometry to one Zr(1); three Zr(2,2); one Ti(3); two equivalent Ti(1); two equivalent Ti(2); three equivalent Rh(1); and four equivalent Rh(2) atoms. In the fifth Zr site, Zr(2) is bonded in a 16-coordinate geometry to one Zr(2); three Zr(1,1); one Ti(1); two equivalent Ti(3); four equivalent Ti(2); two equivalent Rh(2); and three equivalent Rh(1) atoms. In the sixth Zr site, Zr(2) is bonded in a 16-coordinate geometry to one Zr(2), three equivalent Zr(1), one Ti(1), two equivalent Ti(3), four equivalent Ti(2), two equivalent Rh(2), and three equivalent Rh(1) atoms. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 6-coordinate geometry to two equivalent Zr(2); four Zr(1,1); two equivalent Rh(1); and four equivalent Rh(2) atoms. In the second Ti site, Ti(2) is bonded in a distorted water-like geometry to two Zr(1,1); four Zr(2,2,2); and two equivalent Rh(1) atoms. In the third Ti site, Ti(3) is bonded in a distorted water-like geometry to two Zr(1,1); four Zr(2,2); and two equivalent Rh(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 12-coordinate geometry to three Zr(1,1); three Zr(2,2); one Ti(1); one Ti(3); two equivalent Ti(2); and two equivalent Rh(2) atoms. In the second Rh site, Rh(2) is bonded in a 12-coordinate geometry to two equivalent Zr(2); four Zr(1,1,1); two equivalent Ti(1); two equivalent Rh(1); and two equivalent Rh(2) atoms. is represented by the CIF file [CIF]
data_ZrTiRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.295
_cell_length_b   5.541
_cell_length_c   8.556
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   121.554
_symmetry_Int_Tables_number   1
_cell_volume   213.879
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.657  0.328  0.566  1.0
  Zr  Zr1  1  0.329  0.665  0.451  1.0
  Zr  Zr2  1  0.329  0.665  0.049  1.0
  Zr  Zr3  1  0.657  0.328  0.934  1.0
  Ti  Ti4  1  0.689  0.844  0.750  1.0
  Ti  Ti5  1  0.826  0.652  0.250  1.0
  Ti  Ti6  1  0.826  0.174  0.250  1.0
  Ti  Ti7  1  0.331  0.166  0.250  1.0
  Rh  Rh8  1  0.988  0.994  0.492  1.0
  Rh  Rh9  1  0.988  0.994  0.008  1.0
  Rh  Rh10  1  0.189  0.350  0.750  1.0
  Rh  Rh11  1  0.189  0.839  0.750  1.0
[/CIF]
.
The compound described by ZrTiRh crystallizes in the orthorhombic Amm2 space group. There are six inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a 16-coordinate geometry to one Zr(1); three Zr(2,2); one Ti(3); two equivalent Ti(1); two equivalent Ti(2); three equivalent Rh(1); and four equivalent Rh(2) atoms. In the second Zr site, Zr(2) is bonded in a 16-coordinate geometry to one Zr(2); three Zr(1,1); one Ti(1); two equivalent Ti(3); four equivalent Ti(2); two equivalent Rh(2); and three equivalent Rh(1) atoms. In the third Zr site, Zr(1) is bonded in a 16-coordinate geometry to one Zr(1); three Zr(2,2); one Ti(3); two equivalent Ti(1); two equivalent Ti(2); three equivalent Rh(1); and four equivalent Rh(2) atoms. In the fourth Zr site, Zr(1) is bonded in a 16-coordinate geometry to one Zr(1); three Zr(2,2); one Ti(3); two equivalent Ti(1); two equivalent Ti(2); three equivalent Rh(1); and four equivalent Rh(2) atoms. In the fifth Zr site, Zr(2) is bonded in a 16-coordinate geometry to one Zr(2); three Zr(1,1); one Ti(1); two equivalent Ti(3); four equivalent Ti(2); two equivalent Rh(2); and three equivalent Rh(1) atoms. In the sixth Zr site, Zr(2) is bonded in a 16-coordinate geometry to one Zr(2), three equivalent Zr(1), one Ti(1), two equivalent Ti(3), four equivalent Ti(2), two equivalent Rh(2), and three equivalent Rh(1) atoms. There are three inequivalent Ti sites. In the first Ti site, Ti(1) is bonded in a 6-coordinate geometry to two equivalent Zr(2); four Zr(1,1); two equivalent Rh(1); and four equivalent Rh(2) atoms. In the second Ti site, Ti(2) is bonded in a distorted water-like geometry to two Zr(1,1); four Zr(2,2,2); and two equivalent Rh(1) atoms. In the third Ti site, Ti(3) is bonded in a distorted water-like geometry to two Zr(1,1); four Zr(2,2); and two equivalent Rh(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 12-coordinate geometry to three Zr(1,1); three Zr(2,2); one Ti(1); one Ti(3); two equivalent Ti(2); and two equivalent Rh(2) atoms. In the second Rh site, Rh(2) is bonded in a 12-coordinate geometry to two equivalent Zr(2); four Zr(1,1,1); two equivalent Ti(1); two equivalent Rh(1); and two equivalent Rh(2) atoms. is represented by the CIF file [CIF]
data_ZrTiRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.295
_cell_length_b   5.541
_cell_length_c   8.556
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   121.554
_symmetry_Int_Tables_number   1
_cell_volume   213.879
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.657  0.328  0.566  1.0
  Zr  Zr1  1  0.329  0.665  0.451  1.0
  Zr  Zr2  1  0.329  0.665  0.049  1.0
  Zr  Zr3  1  0.657  0.328  0.934  1.0
  Ti  Ti4  1  0.689  0.844  0.750  1.0
  Ti  Ti5  1  0.826  0.652  0.250  1.0
  Ti  Ti6  1  0.826  0.174  0.250  1.0
  Ti  Ti7  1  0.331  0.166  0.250  1.0
  Rh  Rh8  1  0.988  0.994  0.492  1.0
  Rh  Rh9  1  0.988  0.994  0.008  1.0
  Rh  Rh10  1  0.189  0.350  0.750  1.0
  Rh  Rh11  1  0.189  0.839  0.750  1.0
[/CIF]
.