The material described by CoN2(OCl)2(N2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 7727-37-9 molecules and four CoN2(OCl)2 clusters. In each CoN2(OCl)2 cluster, Co(1) is bonded in a trigonal planar geometry to one N(2) and two equivalent Cl(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one N(2) and two equivalent O(1) atoms. In the second N site, N(2) is bonded in a distorted linear geometry to one Co(1) and one N(1) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. Cl(1) is bonded in a single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoN6(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.709
_cell_length_b   7.709
_cell_length_c   10.243
_cell_angle_alpha   71.059
_cell_angle_beta   71.059
_cell_angle_gamma   92.568
_symmetry_Int_Tables_number   1
_cell_volume   536.839
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.969  0.031  0.250  1.0
  Co  Co1  1  0.031  0.969  0.750  1.0
  N  N2  1  0.696  0.304  0.250  1.0
  N  N3  1  0.304  0.696  0.750  1.0
  N  N4  1  0.811  0.189  0.250  1.0
  N  N5  1  0.189  0.811  0.750  1.0
  N  N6  1  0.514  0.812  0.323  1.0
  N  N7  1  0.188  0.486  0.177  1.0
  N  N8  1  0.486  0.188  0.677  1.0
  N  N9  1  0.812  0.514  0.823  1.0
  N  N10  1  0.365  0.747  0.365  1.0
  N  N11  1  0.253  0.635  0.135  1.0
  N  N12  1  0.635  0.253  0.635  1.0
  N  N13  1  0.747  0.365  0.865  1.0
  Cl  Cl14  1  0.796  0.915  0.942  1.0
  Cl  Cl15  1  0.085  0.204  0.558  1.0
  Cl  Cl16  1  0.204  0.085  0.058  1.0
  Cl  Cl17  1  0.915  0.796  0.442  1.0
  O  O18  1  0.574  0.288  0.196  1.0
  O  O19  1  0.712  0.426  0.304  1.0
  O  O20  1  0.426  0.712  0.804  1.0
  O  O21  1  0.288  0.574  0.696  1.0
[/CIF]
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The material described by CoN2(OCl)2(N2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 7727-37-9 molecules and four CoN2(OCl)2 clusters. In each CoN2(OCl)2 cluster, Co(1) is bonded in a trigonal planar geometry to one N(2) and two equivalent Cl(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one N(2) and two equivalent O(1) atoms. In the second N site, N(2) is bonded in a distorted linear geometry to one Co(1) and one N(1) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. Cl(1) is bonded in a single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CoN6(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.709
_cell_length_b   7.709
_cell_length_c   10.243
_cell_angle_alpha   71.059
_cell_angle_beta   71.059
_cell_angle_gamma   92.568
_symmetry_Int_Tables_number   1
_cell_volume   536.839
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.969  0.031  0.250  1.0
  Co  Co1  1  0.031  0.969  0.750  1.0
  N  N2  1  0.696  0.304  0.250  1.0
  N  N3  1  0.304  0.696  0.750  1.0
  N  N4  1  0.811  0.189  0.250  1.0
  N  N5  1  0.189  0.811  0.750  1.0
  N  N6  1  0.514  0.812  0.323  1.0
  N  N7  1  0.188  0.486  0.177  1.0
  N  N8  1  0.486  0.188  0.677  1.0
  N  N9  1  0.812  0.514  0.823  1.0
  N  N10  1  0.365  0.747  0.365  1.0
  N  N11  1  0.253  0.635  0.135  1.0
  N  N12  1  0.635  0.253  0.635  1.0
  N  N13  1  0.747  0.365  0.865  1.0
  Cl  Cl14  1  0.796  0.915  0.942  1.0
  Cl  Cl15  1  0.085  0.204  0.558  1.0
  Cl  Cl16  1  0.204  0.085  0.058  1.0
  Cl  Cl17  1  0.915  0.796  0.442  1.0
  O  O18  1  0.574  0.288  0.196  1.0
  O  O19  1  0.712  0.426  0.304  1.0
  O  O20  1  0.426  0.712  0.804  1.0
  O  O21  1  0.288  0.574  0.696  1.0
[/CIF]
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