The compound described by NaRuO2 is Caswellsilverite-like structured and crystallizes in the triclinic P1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms to form edge-sharing RuO6 octahedra. In the second Ru site, Ru(2) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms to form edge-sharing RuO6 octahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), two equivalent Na(2), one Ru(2), and two equivalent Ru(1) atoms to form edge-sharing ONa3Ru3 octahedra. In the second O site, O(2) is bonded to one Na(2), two equivalent Na(1), one Ru(1), and two equivalent Ru(2) atoms to form edge-sharing ONa3Ru3 octahedra. In the third O site, O(3) is bonded in a 6-coordinate geometry to one Na(2), two equivalent Na(1), one Ru(1), and two equivalent Ru(2) atoms. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Na(1), two equivalent Na(2), one Ru(2), and two equivalent Ru(1) atoms. is represented by the CIF file [CIF]
data_NaRuO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.009
_cell_length_b   3.010
_cell_length_c   5.692
_cell_angle_alpha   100.907
_cell_angle_beta   102.532
_cell_angle_gamma   65.531
_symmetry_Int_Tables_number   1
_cell_volume   45.511
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.456  0.264  0.987  1.0
  O  O1  1  0.021  0.851  0.703  1.0
  O  O2  1  0.187  0.050  0.305  1.0
  Ru  Ru3  1  0.604  0.451  0.504  1.0
[/CIF]
.
The compound described by NaRuO2 is Caswellsilverite-like structured and crystallizes in the triclinic P1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms to form edge-sharing RuO6 octahedra. In the second Ru site, Ru(2) is bonded to one O(1), one O(4), two equivalent O(2), and two equivalent O(3) atoms to form edge-sharing RuO6 octahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded to one Na(1), two equivalent Na(2), one Ru(2), and two equivalent Ru(1) atoms to form edge-sharing ONa3Ru3 octahedra. In the second O site, O(2) is bonded to one Na(2), two equivalent Na(1), one Ru(1), and two equivalent Ru(2) atoms to form edge-sharing ONa3Ru3 octahedra. In the third O site, O(3) is bonded in a 6-coordinate geometry to one Na(2), two equivalent Na(1), one Ru(1), and two equivalent Ru(2) atoms. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Na(1), two equivalent Na(2), one Ru(2), and two equivalent Ru(1) atoms. is represented by the CIF file [CIF]
data_NaRuO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.009
_cell_length_b   3.010
_cell_length_c   5.692
_cell_angle_alpha   100.907
_cell_angle_beta   102.532
_cell_angle_gamma   65.531
_symmetry_Int_Tables_number   1
_cell_volume   45.511
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.456  0.264  0.987  1.0
  O  O1  1  0.021  0.851  0.703  1.0
  O  O2  1  0.187  0.050  0.305  1.0
  Ru  Ru3  1  0.604  0.451  0.504  1.0
[/CIF]
.