The structure described by CaLa3(CoO4)2 is (La,Ba)CuO4-derived structured and crystallizes in the monoclinic Pm space group. There are two inequivalent Ca sites. In the first Ca site, Ca(1) is bonded in a 9-coordinate geometry to one O(1), two equivalent O(10), two equivalent O(12), two equivalent O(5), and two equivalent O(7) atoms. In the second Ca site, Ca(2) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(11), two equivalent O(6), two equivalent O(8), and two equivalent O(9) atoms. There are six inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(3), two equivalent O(10), two equivalent O(12), two equivalent O(5), and two equivalent O(7) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(4), two equivalent O(11), two equivalent O(6), two equivalent O(8), and two equivalent O(9) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(5), two equivalent O(1), two equivalent O(11), two equivalent O(3), and two equivalent O(9) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(6), two equivalent O(10), two equivalent O(12), two equivalent O(2), and two equivalent O(4) atoms. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one O(7), two equivalent O(1), two equivalent O(11), two equivalent O(3), and two equivalent O(9) atoms. In the sixth La site, La(6) is bonded in a 9-coordinate geometry to one O(8), two equivalent O(10), two equivalent O(12), two equivalent O(2), and two equivalent O(4) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(8), two equivalent O(11), and two equivalent O(9) atoms to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 6-7°. In the second Co site, Co(2) is bonded to one O(2), one O(7), two equivalent O(10), and two equivalent O(12) atoms to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 5-6°. In the third Co site, Co(3) is bonded to one O(4), one O(5), two equivalent O(10), and two equivalent O(12) atoms to form distorted corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 5-6°. In the fourth Co site, Co(4) is bonded to one O(3), one O(6), two equivalent O(11), and two equivalent O(9) atoms to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 6-7°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Ca(1), two equivalent La(3), two equivalent La(5), and one Co(1) atom to form distorted OCaLa4Co octahedra that share  a cornercorner with one O(8)Ca2La3Co octahedra, corners with two equivalent O(10)CaLa3Co2 octahedra, corners with two equivalent O(12)CaLa3Co2 octahedra, corners with four equivalent O(11)CaLa3Co2 octahedra, corners with four equivalent O(9)CaLa3Co2 octahedra, corners with four equivalent O(1)CaLa4Co octahedra, edges with two equivalent O(5)Ca2La3Co octahedra, edges with two equivalent O(7)Ca2La3Co octahedra, edges with four equivalent O(3)La5Co octahedra, faces with two equivalent O(11)CaLa3Co2 octahedra, and faces with two equivalent O(9)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the second O site, O(2) is bonded to one Ca(2), two equivalent La(4), two equivalent La(6), and one Co(2) atom to form distorted OCaLa4Co octahedra that share  a cornercorner with one O(7)Ca2La3Co octahedra, corners with two equivalent O(11)CaLa3Co2 octahedra, corners with two equivalent O(9)CaLa3Co2 octahedra, corners with four equivalent O(10)CaLa3Co2 octahedra, corners with four equivalent O(12)CaLa3Co2 octahedra, corners with four equivalent O(2)CaLa4Co octahedra, edges with two equivalent O(6)Ca2La3Co octahedra, edges with two equivalent O(8)Ca2La3Co octahedra, edges with four equivalent O(4)La5Co octahedra, faces with two equivalent O(10)CaLa3Co2 octahedra, and faces with two equivalent O(12)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-54°. In the third O site, O(3) is bonded to one La(1), two equivalent La(3), two equivalent La(5), and one Co(4) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(6)Ca2La3Co octahedra, corners with two equivalent O(10)CaLa3Co2 octahedra, corners with two equivalent O(12)CaLa3Co2 octahedra, corners with four equivalent O(11)CaLa3Co2 octahedra, corners with four equivalent O(9)CaLa3Co2 octahedra, corners with four equivalent O(3)La5Co octahedra, edges with two equivalent O(5)Ca2La3Co octahedra, edges with two equivalent O(7)Ca2La3Co octahedra, edges with four equivalent O(1)CaLa4Co octahedra, faces with two equivalent O(11)CaLa3Co2 octahedra, and faces with two equivalent O(9)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-53°. In the fourth O site, O(4) is bonded to one La(2), two equivalent La(4), two equivalent La(6), and one Co(3) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(5)Ca2La3Co octahedra, corners with two equivalent O(11)CaLa3Co2 octahedra, corners with two equivalent O(9)CaLa3Co2 octahedra, corners with four equivalent O(10)CaLa3Co2 octahedra, corners with four equivalent O(12)CaLa3Co2 octahedra, corners with four equivalent O(4)La5Co octahedra, edges with two equivalent O(6)Ca2La3Co octahedra, edges with two equivalent O(8)Ca2La3Co octahedra, edges with four equivalent O(2)CaLa4Co octahedra, faces with two equivalent O(10)CaLa3Co2 octahedra, and faces with two equivalent O(12)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the fifth O site, O(5) is bonded to two equivalent Ca(1), one La(3), two equivalent La(1), and one Co(3) atom to form distorted OCa2La3Co octahedra that share  a cornercorner with one O(4)La5Co octahedra, corners with two equivalent O(11)CaLa3Co2 octahedra, corners with two equivalent O(9)CaLa3Co2 octahedra, corners with four equivalent O(5)Ca2La3Co octahedra, corners with four equivalent O(10)CaLa3Co2 octahedra, corners with four equivalent O(12)CaLa3Co2 octahedra, edges with two equivalent O(1)CaLa4Co octahedra, edges with two equivalent O(3)La5Co octahedra, edges with four equivalent O(7)Ca2La3Co octahedra, faces with two equivalent O(10)CaLa3Co2 octahedra, and faces with two equivalent O(12)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-52°. In the sixth O site, O(6) is bonded to two equivalent Ca(2), one La(4), two equivalent La(2), and one Co(4) atom to form distorted OCa2La3Co octahedra that share  a cornercorner with one O(3)La5Co octahedra, corners with two equivalent O(10)CaLa3Co2 octahedra, corners with two equivalent O(12)CaLa3Co2 octahedra, corners with four equivalent O(6)Ca2La3Co octahedra, corners with four equivalent O(11)CaLa3Co2 octahedra, corners with four equivalent O(9)CaLa3Co2 octahedra, edges with two equivalent O(2)CaLa4Co octahedra, edges with two equivalent O(4)La5Co octahedra, edges with four equivalent O(8)Ca2La3Co octahedra, faces with two equivalent O(11)CaLa3Co2 octahedra, and faces with two equivalent O(9)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-54°. In the seventh O site, O(7) is bonded to two equivalent Ca(1), one La(5), two equivalent La(1), and one Co(2) atom to form distorted OCa2La3Co octahedra that share  a cornercorner with one O(2)CaLa4Co octahedra, corners with two equivalent O(11)CaLa3Co2 octahedra, corners with two equivalent O(9)CaLa3Co2 octahedra, corners with four equivalent O(7)Ca2La3Co octahedra, corners with four equivalent O(10)CaLa3Co2 octahedra, corners with four equivalent O(12)CaLa3Co2 octahedra, edges with two equivalent O(1)CaLa4Co octahedra, edges with two equivalent O(3)La5Co octahedra, edges with four equivalent O(5)Ca2La3Co octahedra, faces with two equivalent O(10)CaLa3Co2 octahedra, and faces with two equivalent O(12)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-53°. In the eighth O site, O(8) is bonded to two equivalent Ca(2), one La(6), two equivalent La(2), and one Co(1) atom to form distorted OCa2La3Co octahedra that share  a cornercorner with one O(1)CaLa4Co octahedra, corners with two equivalent O(10)CaLa3Co2 octahedra, corners with two equivalent O(12)CaLa3Co2 octahedra, corners with four equivalent O(8)Ca2La3Co octahedra, corners with four equivalent O(11)CaLa3Co2 octahedra, corners with four equivalent O(9)CaLa3Co2 octahedra, edges with two equivalent O(2)CaLa4Co octahedra, edges with two equivalent O(4)La5Co octahedra, edges with four equivalent O(6)Ca2La3Co octahedra, faces with two equivalent O(11)CaLa3Co2 octahedra, and faces with two equivalent O(9)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the ninth O site, O(9) is bonded to one Ca(2), one La(2), one La(3), one La(5), one Co(1), and one Co(4) atom to form distorted OCaLa3Co2 octahedra that share  a cornercorner with one O(5)Ca2La3Co octahedra,  a cornercorner with one O(7)Ca2La3Co octahedra,  a cornercorner with one O(2)CaLa4Co octahedra,  a cornercorner with one O(4)La5Co octahedra, corners with two equivalent O(6)Ca2La3Co octahedra, corners with two equivalent O(8)Ca2La3Co octahedra, corners with two equivalent O(11)CaLa3Co2 octahedra, corners with two equivalent O(1)CaLa4Co octahedra, corners with two equivalent O(3)La5Co octahedra, edges with two equivalent O(11)CaLa3Co2 octahedra,  a faceface with one O(6)Ca2La3Co octahedra,  a faceface with one O(8)Ca2La3Co octahedra,  a faceface with one O(1)CaLa4Co octahedra,  a faceface with one O(3)La5Co octahedra, faces with two equivalent O(11)CaLa3Co2 octahedra, and faces with two equivalent O(9)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-54°. In the tenth O site, O(10) is bonded to one Ca(1), one La(1), one La(4), one La(6), one Co(2), and one Co(3) atom to form distorted OCaLa3Co2 octahedra that share  a cornercorner with one O(6)Ca2La3Co octahedra,  a cornercorner with one O(8)Ca2La3Co octahedra,  a cornercorner with one O(1)CaLa4Co octahedra,  a cornercorner with one O(3)La5Co octahedra, corners with two equivalent O(5)Ca2La3Co octahedra, corners with two equivalent O(7)Ca2La3Co octahedra, corners with two equivalent O(12)CaLa3Co2 octahedra, corners with two equivalent O(2)CaLa4Co octahedra, corners with two equivalent O(4)La5Co octahedra, edges with two equivalent O(12)CaLa3Co2 octahedra,  a faceface with one O(5)Ca2La3Co octahedra,  a faceface with one O(7)Ca2La3Co octahedra,  a faceface with one O(2)CaLa4Co octahedra,  a faceface with one O(4)La5Co octahedra, faces with two equivalent O(10)CaLa3Co2 octahedra, and faces with two equivalent O(12)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 5-53°. In the eleventh O site, O(11) is bonded to one Ca(2), one La(2), one La(3), one La(5), one Co(1), and one Co(4) atom to form distorted OCaLa3Co2 octahedra that share  a cornercorner with one O(5)Ca2La3Co octahedra,  a cornercorner with one O(7)Ca2La3Co octahedra,  a cornercorner with one O(2)CaLa4Co octahedra,  a cornercorner with one O(4)La5Co octahedra, corners with two equivalent O(6)Ca2La3Co octahedra, corners with two equivalent O(8)Ca2La3Co octahedra, corners with two equivalent O(9)CaLa3Co2 octahedra, corners with two equivalent O(1)CaLa4Co octahedra, corners with two equivalent O(3)La5Co octahedra, edges with two equivalent O(9)CaLa3Co2 octahedra,  a faceface with one O(6)Ca2La3Co octahedra,  a faceface with one O(8)Ca2La3Co octahedra,  a faceface with one O(1)CaLa4Co octahedra,  a faceface with one O(3)La5Co octahedra, faces with two equivalent O(11)CaLa3Co2 octahedra, and faces with two equivalent O(9)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-53°. In the twelfth O site, O(12) is bonded to one Ca(1), one La(1), one La(4), one La(6), one Co(2), and one Co(3) atom to form distorted OCaLa3Co2 octahedra that share  a cornercorner with one O(6)Ca2La3Co octahedra,  a cornercorner with one O(8)Ca2La3Co octahedra,  a cornercorner with one O(1)CaLa4Co octahedra,  a cornercorner with one O(3)La5Co octahedra, corners with two equivalent O(5)Ca2La3Co octahedra, corners with two equivalent O(7)Ca2La3Co octahedra, corners with two equivalent O(10)CaLa3Co2 octahedra, corners with two equivalent O(2)CaLa4Co octahedra, corners with two equivalent O(4)La5Co octahedra, edges with two equivalent O(10)CaLa3Co2 octahedra,  a faceface with one O(5)Ca2La3Co octahedra,  a faceface with one O(7)Ca2La3Co octahedra,  a faceface with one O(2)CaLa4Co octahedra,  a faceface with one O(4)La5Co octahedra, faces with two equivalent O(10)CaLa3Co2 octahedra, and faces with two equivalent O(12)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 5-54°. is represented by the CIF card [CIF]
data_CaLa3(CoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.378
_cell_length_b   5.382
_cell_length_c   6.966
_cell_angle_alpha   67.285
_cell_angle_beta   90.021
_cell_angle_gamma   90.028
_symmetry_Int_Tables_number   1
_cell_volume   185.987
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.500  0.144  0.714  1.0
  Co  Co1  1  0.500  0.508  0.992  1.0
  Co  Co2  1  1.000  0.012  0.985  1.0
  La  La3  1  0.000  0.642  0.720  1.0
  La  La4  1  1.000  0.360  0.286  1.0
  La  La5  1  0.500  0.861  0.281  1.0
  O  O6  1  0.500  0.333  0.354  1.0
  O  O7  1  0.000  0.827  0.360  1.0
  O  O8  1  0.000  0.187  0.645  1.0
  O  O9  1  0.500  0.687  0.644  1.0
  O  O10  1  0.251  0.253  0.005  1.0
  O  O11  1  0.749  0.253  0.005  1.0
  O  O12  1  0.751  0.750  0.003  1.0
  O  O13  1  0.249  0.750  0.003  1.0
[/CIF]
.
The structure described by CaLa3(CoO4)2 is (La,Ba)CuO4-derived structured and crystallizes in the monoclinic Pm space group. There are two inequivalent Ca sites. In the first Ca site, Ca(1) is bonded in a 9-coordinate geometry to one O(1), two equivalent O(10), two equivalent O(12), two equivalent O(5), and two equivalent O(7) atoms. In the second Ca site, Ca(2) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(11), two equivalent O(6), two equivalent O(8), and two equivalent O(9) atoms. There are six inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(3), two equivalent O(10), two equivalent O(12), two equivalent O(5), and two equivalent O(7) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(4), two equivalent O(11), two equivalent O(6), two equivalent O(8), and two equivalent O(9) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(5), two equivalent O(1), two equivalent O(11), two equivalent O(3), and two equivalent O(9) atoms. In the fourth La site, La(4) is bonded in a 9-coordinate geometry to one O(6), two equivalent O(10), two equivalent O(12), two equivalent O(2), and two equivalent O(4) atoms. In the fifth La site, La(5) is bonded in a 9-coordinate geometry to one O(7), two equivalent O(1), two equivalent O(11), two equivalent O(3), and two equivalent O(9) atoms. In the sixth La site, La(6) is bonded in a 9-coordinate geometry to one O(8), two equivalent O(10), two equivalent O(12), two equivalent O(2), and two equivalent O(4) atoms. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(8), two equivalent O(11), and two equivalent O(9) atoms to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 6-7°. In the second Co site, Co(2) is bonded to one O(2), one O(7), two equivalent O(10), and two equivalent O(12) atoms to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 5-6°. In the third Co site, Co(3) is bonded to one O(4), one O(5), two equivalent O(10), and two equivalent O(12) atoms to form distorted corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 5-6°. In the fourth Co site, Co(4) is bonded to one O(3), one O(6), two equivalent O(11), and two equivalent O(9) atoms to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 6-7°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Ca(1), two equivalent La(3), two equivalent La(5), and one Co(1) atom to form distorted OCaLa4Co octahedra that share  a cornercorner with one O(8)Ca2La3Co octahedra, corners with two equivalent O(10)CaLa3Co2 octahedra, corners with two equivalent O(12)CaLa3Co2 octahedra, corners with four equivalent O(11)CaLa3Co2 octahedra, corners with four equivalent O(9)CaLa3Co2 octahedra, corners with four equivalent O(1)CaLa4Co octahedra, edges with two equivalent O(5)Ca2La3Co octahedra, edges with two equivalent O(7)Ca2La3Co octahedra, edges with four equivalent O(3)La5Co octahedra, faces with two equivalent O(11)CaLa3Co2 octahedra, and faces with two equivalent O(9)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the second O site, O(2) is bonded to one Ca(2), two equivalent La(4), two equivalent La(6), and one Co(2) atom to form distorted OCaLa4Co octahedra that share  a cornercorner with one O(7)Ca2La3Co octahedra, corners with two equivalent O(11)CaLa3Co2 octahedra, corners with two equivalent O(9)CaLa3Co2 octahedra, corners with four equivalent O(10)CaLa3Co2 octahedra, corners with four equivalent O(12)CaLa3Co2 octahedra, corners with four equivalent O(2)CaLa4Co octahedra, edges with two equivalent O(6)Ca2La3Co octahedra, edges with two equivalent O(8)Ca2La3Co octahedra, edges with four equivalent O(4)La5Co octahedra, faces with two equivalent O(10)CaLa3Co2 octahedra, and faces with two equivalent O(12)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-54°. In the third O site, O(3) is bonded to one La(1), two equivalent La(3), two equivalent La(5), and one Co(4) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(6)Ca2La3Co octahedra, corners with two equivalent O(10)CaLa3Co2 octahedra, corners with two equivalent O(12)CaLa3Co2 octahedra, corners with four equivalent O(11)CaLa3Co2 octahedra, corners with four equivalent O(9)CaLa3Co2 octahedra, corners with four equivalent O(3)La5Co octahedra, edges with two equivalent O(5)Ca2La3Co octahedra, edges with two equivalent O(7)Ca2La3Co octahedra, edges with four equivalent O(1)CaLa4Co octahedra, faces with two equivalent O(11)CaLa3Co2 octahedra, and faces with two equivalent O(9)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-53°. In the fourth O site, O(4) is bonded to one La(2), two equivalent La(4), two equivalent La(6), and one Co(3) atom to form distorted OLa5Co octahedra that share  a cornercorner with one O(5)Ca2La3Co octahedra, corners with two equivalent O(11)CaLa3Co2 octahedra, corners with two equivalent O(9)CaLa3Co2 octahedra, corners with four equivalent O(10)CaLa3Co2 octahedra, corners with four equivalent O(12)CaLa3Co2 octahedra, corners with four equivalent O(4)La5Co octahedra, edges with two equivalent O(6)Ca2La3Co octahedra, edges with two equivalent O(8)Ca2La3Co octahedra, edges with four equivalent O(2)CaLa4Co octahedra, faces with two equivalent O(10)CaLa3Co2 octahedra, and faces with two equivalent O(12)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the fifth O site, O(5) is bonded to two equivalent Ca(1), one La(3), two equivalent La(1), and one Co(3) atom to form distorted OCa2La3Co octahedra that share  a cornercorner with one O(4)La5Co octahedra, corners with two equivalent O(11)CaLa3Co2 octahedra, corners with two equivalent O(9)CaLa3Co2 octahedra, corners with four equivalent O(5)Ca2La3Co octahedra, corners with four equivalent O(10)CaLa3Co2 octahedra, corners with four equivalent O(12)CaLa3Co2 octahedra, edges with two equivalent O(1)CaLa4Co octahedra, edges with two equivalent O(3)La5Co octahedra, edges with four equivalent O(7)Ca2La3Co octahedra, faces with two equivalent O(10)CaLa3Co2 octahedra, and faces with two equivalent O(12)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-52°. In the sixth O site, O(6) is bonded to two equivalent Ca(2), one La(4), two equivalent La(2), and one Co(4) atom to form distorted OCa2La3Co octahedra that share  a cornercorner with one O(3)La5Co octahedra, corners with two equivalent O(10)CaLa3Co2 octahedra, corners with two equivalent O(12)CaLa3Co2 octahedra, corners with four equivalent O(6)Ca2La3Co octahedra, corners with four equivalent O(11)CaLa3Co2 octahedra, corners with four equivalent O(9)CaLa3Co2 octahedra, edges with two equivalent O(2)CaLa4Co octahedra, edges with two equivalent O(4)La5Co octahedra, edges with four equivalent O(8)Ca2La3Co octahedra, faces with two equivalent O(11)CaLa3Co2 octahedra, and faces with two equivalent O(9)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-54°. In the seventh O site, O(7) is bonded to two equivalent Ca(1), one La(5), two equivalent La(1), and one Co(2) atom to form distorted OCa2La3Co octahedra that share  a cornercorner with one O(2)CaLa4Co octahedra, corners with two equivalent O(11)CaLa3Co2 octahedra, corners with two equivalent O(9)CaLa3Co2 octahedra, corners with four equivalent O(7)Ca2La3Co octahedra, corners with four equivalent O(10)CaLa3Co2 octahedra, corners with four equivalent O(12)CaLa3Co2 octahedra, edges with two equivalent O(1)CaLa4Co octahedra, edges with two equivalent O(3)La5Co octahedra, edges with four equivalent O(5)Ca2La3Co octahedra, faces with two equivalent O(10)CaLa3Co2 octahedra, and faces with two equivalent O(12)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-53°. In the eighth O site, O(8) is bonded to two equivalent Ca(2), one La(6), two equivalent La(2), and one Co(1) atom to form distorted OCa2La3Co octahedra that share  a cornercorner with one O(1)CaLa4Co octahedra, corners with two equivalent O(10)CaLa3Co2 octahedra, corners with two equivalent O(12)CaLa3Co2 octahedra, corners with four equivalent O(8)Ca2La3Co octahedra, corners with four equivalent O(11)CaLa3Co2 octahedra, corners with four equivalent O(9)CaLa3Co2 octahedra, edges with two equivalent O(2)CaLa4Co octahedra, edges with two equivalent O(4)La5Co octahedra, edges with four equivalent O(6)Ca2La3Co octahedra, faces with two equivalent O(11)CaLa3Co2 octahedra, and faces with two equivalent O(9)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 1-51°. In the ninth O site, O(9) is bonded to one Ca(2), one La(2), one La(3), one La(5), one Co(1), and one Co(4) atom to form distorted OCaLa3Co2 octahedra that share  a cornercorner with one O(5)Ca2La3Co octahedra,  a cornercorner with one O(7)Ca2La3Co octahedra,  a cornercorner with one O(2)CaLa4Co octahedra,  a cornercorner with one O(4)La5Co octahedra, corners with two equivalent O(6)Ca2La3Co octahedra, corners with two equivalent O(8)Ca2La3Co octahedra, corners with two equivalent O(11)CaLa3Co2 octahedra, corners with two equivalent O(1)CaLa4Co octahedra, corners with two equivalent O(3)La5Co octahedra, edges with two equivalent O(11)CaLa3Co2 octahedra,  a faceface with one O(6)Ca2La3Co octahedra,  a faceface with one O(8)Ca2La3Co octahedra,  a faceface with one O(1)CaLa4Co octahedra,  a faceface with one O(3)La5Co octahedra, faces with two equivalent O(11)CaLa3Co2 octahedra, and faces with two equivalent O(9)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-54°. In the tenth O site, O(10) is bonded to one Ca(1), one La(1), one La(4), one La(6), one Co(2), and one Co(3) atom to form distorted OCaLa3Co2 octahedra that share  a cornercorner with one O(6)Ca2La3Co octahedra,  a cornercorner with one O(8)Ca2La3Co octahedra,  a cornercorner with one O(1)CaLa4Co octahedra,  a cornercorner with one O(3)La5Co octahedra, corners with two equivalent O(5)Ca2La3Co octahedra, corners with two equivalent O(7)Ca2La3Co octahedra, corners with two equivalent O(12)CaLa3Co2 octahedra, corners with two equivalent O(2)CaLa4Co octahedra, corners with two equivalent O(4)La5Co octahedra, edges with two equivalent O(12)CaLa3Co2 octahedra,  a faceface with one O(5)Ca2La3Co octahedra,  a faceface with one O(7)Ca2La3Co octahedra,  a faceface with one O(2)CaLa4Co octahedra,  a faceface with one O(4)La5Co octahedra, faces with two equivalent O(10)CaLa3Co2 octahedra, and faces with two equivalent O(12)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 5-53°. In the eleventh O site, O(11) is bonded to one Ca(2), one La(2), one La(3), one La(5), one Co(1), and one Co(4) atom to form distorted OCaLa3Co2 octahedra that share  a cornercorner with one O(5)Ca2La3Co octahedra,  a cornercorner with one O(7)Ca2La3Co octahedra,  a cornercorner with one O(2)CaLa4Co octahedra,  a cornercorner with one O(4)La5Co octahedra, corners with two equivalent O(6)Ca2La3Co octahedra, corners with two equivalent O(8)Ca2La3Co octahedra, corners with two equivalent O(9)CaLa3Co2 octahedra, corners with two equivalent O(1)CaLa4Co octahedra, corners with two equivalent O(3)La5Co octahedra, edges with two equivalent O(9)CaLa3Co2 octahedra,  a faceface with one O(6)Ca2La3Co octahedra,  a faceface with one O(8)Ca2La3Co octahedra,  a faceface with one O(1)CaLa4Co octahedra,  a faceface with one O(3)La5Co octahedra, faces with two equivalent O(11)CaLa3Co2 octahedra, and faces with two equivalent O(9)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 4-53°. In the twelfth O site, O(12) is bonded to one Ca(1), one La(1), one La(4), one La(6), one Co(2), and one Co(3) atom to form distorted OCaLa3Co2 octahedra that share  a cornercorner with one O(6)Ca2La3Co octahedra,  a cornercorner with one O(8)Ca2La3Co octahedra,  a cornercorner with one O(1)CaLa4Co octahedra,  a cornercorner with one O(3)La5Co octahedra, corners with two equivalent O(5)Ca2La3Co octahedra, corners with two equivalent O(7)Ca2La3Co octahedra, corners with two equivalent O(10)CaLa3Co2 octahedra, corners with two equivalent O(2)CaLa4Co octahedra, corners with two equivalent O(4)La5Co octahedra, edges with two equivalent O(10)CaLa3Co2 octahedra,  a faceface with one O(5)Ca2La3Co octahedra,  a faceface with one O(7)Ca2La3Co octahedra,  a faceface with one O(2)CaLa4Co octahedra,  a faceface with one O(4)La5Co octahedra, faces with two equivalent O(10)CaLa3Co2 octahedra, and faces with two equivalent O(12)CaLa3Co2 octahedra. The corner-sharing octahedral tilt angles range from 5-54°. is represented by the CIF card [CIF]
data_CaLa3(CoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.378
_cell_length_b   5.382
_cell_length_c   6.966
_cell_angle_alpha   67.285
_cell_angle_beta   90.021
_cell_angle_gamma   90.028
_symmetry_Int_Tables_number   1
_cell_volume   185.987
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.500  0.144  0.714  1.0
  Co  Co1  1  0.500  0.508  0.992  1.0
  Co  Co2  1  1.000  0.012  0.985  1.0
  La  La3  1  0.000  0.642  0.720  1.0
  La  La4  1  1.000  0.360  0.286  1.0
  La  La5  1  0.500  0.861  0.281  1.0
  O  O6  1  0.500  0.333  0.354  1.0
  O  O7  1  0.000  0.827  0.360  1.0
  O  O8  1  0.000  0.187  0.645  1.0
  O  O9  1  0.500  0.687  0.644  1.0
  O  O10  1  0.251  0.253  0.005  1.0
  O  O11  1  0.749  0.253  0.005  1.0
  O  O12  1  0.751  0.750  0.003  1.0
  O  O13  1  0.249  0.750  0.003  1.0
[/CIF]
.