The compound described by Na4Li5(WO3)10 crystallizes in the triclinic P1 space group. There are four inequivalent Na sites. In the first Na site, Na(1) is bonded in a 10-coordinate geometry to one O(10), one O(15), one O(17), one O(26), one O(27), one O(29), one O(3), one O(30), one O(8), and one O(9) atom. In the second Na site, Na(2) is bonded in a 9-coordinate geometry to one O(11), one O(13), one O(14), one O(16), one O(23), one O(26), one O(27), one O(4), and one O(6) atom. In the third Na site, Na(3) is bonded in a 9-coordinate geometry to one O(12), one O(15), one O(17), one O(18), one O(26), one O(4), one O(5), one O(6), and one O(7) atom. In the fourth Na site, Na(4) is bonded in a 8-coordinate geometry to one O(1), one O(23), one O(24), one O(27), one O(28), one O(3), one O(5), and one O(7) atom. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(2), one O(25), one O(28), and one O(8) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(11), one O(14), one O(28), one O(4), and one O(8) atom. In the third Li site, Li(3) is bonded in a 3-coordinate geometry to one O(10), one O(17), one O(20), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a 3-coordinate geometry to one O(10), one O(13), and one O(16) atom. In the fifth Li site, Li(5) is bonded in a 3-coordinate geometry to one O(2), one O(20), one O(29), and one O(30) atom. There are ten inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(11), one O(12), one O(21), one O(23), and one O(4) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 6-22°. In the second W site, W(2) is bonded to one O(12), one O(19), one O(2), one O(22), one O(28), and one O(5) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 8-15°. In the third W site, W(3) is bonded to one O(13), one O(18), one O(23), one O(29), one O(3), and one O(6) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 6-25°. In the fourth W site, W(4) is bonded to one O(14), one O(15), one O(24), one O(26), one O(3), and one O(4) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 1-20°. In the fifth W site, W(5) is bonded to one O(11), one O(15), one O(25), one O(27), one O(5), and one O(8) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 6-22°. In the sixth W site, W(6) is bonded to one O(16), one O(17), one O(21), one O(26), one O(6), and one O(9) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 1-16°. In the seventh W site, W(7) is bonded to one O(10), one O(13), one O(17), one O(22), one O(27), and one O(7) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 12-22°. In the eighth W site, W(8) is bonded to one O(14), one O(18), one O(28), one O(30), one O(7), and one O(8) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 8-24°. In the ninth W site, W(9) is bonded to one O(1), one O(19), one O(20), one O(24), one O(29), and one O(9) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 6-25°. In the tenth W site, W(10) is bonded to one O(10), one O(16), one O(2), one O(20), one O(25), and one O(30) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 6-21°. There are thirty inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Na(4), one W(1), and one W(9) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Li(1), one Li(5), one W(10), and one W(2) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(4), one W(3), and one W(4) atom. In the fourth O site, O(4) is bonded to one Na(2), one Na(3), one Li(2), one W(1), and one W(4) atom to form distorted face-sharing ONa2LiW2 square pyramids. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Na(3), one Na(4), one W(2), and one W(5) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(3), one W(3), and one W(6) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Na(3), one Na(4), one W(7), and one W(8) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Na(1), one Li(1), one Li(2), one W(5), and one W(8) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Li(3), one W(6), and one W(9) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Na(1), one Li(3), one Li(4), one W(10), and one W(7) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Na(2), one Li(2), one W(1), and one W(5) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to one Na(3), one W(1), and one W(2) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Na(2), one Li(4), one W(3), and one W(7) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Li(2), one W(4), and one W(8) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(3), one W(4), and one W(5) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Li(4), one W(10), and one W(6) atom. In the seventeenth O site, O(17) is bonded in a 5-coordinate geometry to one Na(1), one Na(3), one Li(3), one W(6), and one W(7) atom. In the eighteenth O site, O(18) is bonded in a distorted T-shaped geometry to one Na(3), one W(3), and one W(8) atom. In the nineteenth O site, O(19) is bonded in a distorted linear geometry to one W(2) and one W(9) atom. In the twentieth O site, O(20) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(5), one W(10), and one W(9) atom. In the twenty-first O site, O(21) is bonded in a linear geometry to one W(1) and one W(6) atom. In the twenty-second O site, O(22) is bonded in a 2-coordinate geometry to one W(2) and one W(7) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Na(2), one Na(4), one W(1), and one W(3) atom. In the twenty-fourth O site, O(24) is bonded in a distorted T-shaped geometry to one Na(4), one W(4), and one W(9) atom. In the twenty-fifth O site, O(25) is bonded in a T-shaped geometry to one Li(1), one W(10), and one W(5) atom. In the twenty-sixth O site, O(26) is bonded to one Na(1), one Na(2), one Na(3), one W(4), and one W(6) atom to form distorted face-sharing ONa3W2 square pyramids. In the twenty-seventh O site, O(27) is bonded in a 5-coordinate geometry to one Na(1), one Na(2), one Na(4), one W(5), and one W(7) atom. In the twenty-eighth O site, O(28) is bonded in a 5-coordinate geometry to one Na(4), one Li(1), one Li(2), one W(2), and one W(8) atom. In the twenty-ninth O site, O(29) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Li(5), one W(3), and one W(9) atom. In the thirtieth O site, O(30) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Li(5), one W(10), and one W(8) atom. is represented by the CIF card [CIF]
data_Na4Li5(WO3)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.830
_cell_length_b   8.853
_cell_length_c   8.866
_cell_angle_alpha   113.979
_cell_angle_beta   89.712
_cell_angle_gamma   101.761
_symmetry_Int_Tables_number   1
_cell_volume   617.584
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.108  0.497  0.199  1.0
  Na  Na1  1  0.201  0.008  0.404  1.0
  Na  Na2  1  0.302  0.491  0.600  1.0
  Na  Na3  1  0.402  0.002  0.804  1.0
  Li  Li4  1  0.527  0.601  0.041  1.0
  Li  Li5  1  0.504  0.987  0.229  1.0
  Li  Li6  1  0.774  0.505  0.343  1.0
  Li  Li7  1  0.842  0.942  0.557  1.0
  Li  Li8  1  0.903  0.500  0.890  1.0
  W  W9  1  0.548  0.250  0.603  1.0
  W  W10  1  0.653  0.750  0.799  1.0
  W  W11  1  0.147  0.250  0.802  1.0
  W  W12  1  0.348  0.248  0.199  1.0
  W  W13  1  0.450  0.751  0.401  1.0
  W  W14  1  0.949  0.255  0.404  1.0
  W  W15  1  0.050  0.752  0.601  1.0
  W  W16  1  0.247  0.747  0.993  1.0
  W  W17  1  0.751  0.245  0.998  1.0
  W  W18  1  0.847  0.753  0.196  1.0
  O  O19  1  0.646  0.235  0.785  1.0
  O  O20  1  0.744  0.735  0.993  1.0
  O  O21  1  0.242  0.236  0.989  1.0
  O  O22  1  0.453  0.263  0.411  1.0
  O  O23  1  0.540  0.767  0.604  1.0
  O  O24  1  0.059  0.244  0.599  1.0
  O  O25  1  0.168  0.770  0.807  1.0
  O  O26  1  0.358  0.739  0.186  1.0
  O  O27  1  0.851  0.284  0.217  1.0
  O  O28  1  0.927  0.724  0.395  1.0
  O  O29  1  0.517  0.007  0.465  1.0
  O  O30  1  0.575  0.492  0.714  1.0
  O  O31  1  0.053  0.990  0.692  1.0
  O  O32  1  0.297  0.998  0.135  1.0
  O  O33  1  0.379  0.500  0.301  1.0
  O  O34  1  0.903  0.993  0.309  1.0
  O  O35  1  0.025  0.509  0.508  1.0
  O  O36  1  0.240  0.498  0.875  1.0
  O  O37  1  0.724  0.008  0.895  1.0
  O  O38  1  0.770  0.493  0.093  1.0
  O  O39  1  0.759  0.270  0.510  1.0
  O  O40  1  0.831  0.721  0.682  1.0
  O  O41  1  0.347  0.206  0.681  1.0
  O  O42  1  0.537  0.229  0.094  1.0
  O  O43  1  0.644  0.738  0.290  1.0
  O  O44  1  0.146  0.249  0.302  1.0
  O  O45  1  0.248  0.783  0.499  1.0
  O  O46  1  0.466  0.782  0.913  1.0
  O  O47  1  0.957  0.302  0.915  1.0
  O  O48  1  0.040  0.704  0.080  1.0
[/CIF]
.
The compound described by Na4Li5(WO3)10 crystallizes in the triclinic P1 space group. There are four inequivalent Na sites. In the first Na site, Na(1) is bonded in a 10-coordinate geometry to one O(10), one O(15), one O(17), one O(26), one O(27), one O(29), one O(3), one O(30), one O(8), and one O(9) atom. In the second Na site, Na(2) is bonded in a 9-coordinate geometry to one O(11), one O(13), one O(14), one O(16), one O(23), one O(26), one O(27), one O(4), and one O(6) atom. In the third Na site, Na(3) is bonded in a 9-coordinate geometry to one O(12), one O(15), one O(17), one O(18), one O(26), one O(4), one O(5), one O(6), and one O(7) atom. In the fourth Na site, Na(4) is bonded in a 8-coordinate geometry to one O(1), one O(23), one O(24), one O(27), one O(28), one O(3), one O(5), and one O(7) atom. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded in a 4-coordinate geometry to one O(2), one O(25), one O(28), and one O(8) atom. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(11), one O(14), one O(28), one O(4), and one O(8) atom. In the third Li site, Li(3) is bonded in a 3-coordinate geometry to one O(10), one O(17), one O(20), and one O(9) atom. In the fourth Li site, Li(4) is bonded in a 3-coordinate geometry to one O(10), one O(13), and one O(16) atom. In the fifth Li site, Li(5) is bonded in a 3-coordinate geometry to one O(2), one O(20), one O(29), and one O(30) atom. There are ten inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(11), one O(12), one O(21), one O(23), and one O(4) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 6-22°. In the second W site, W(2) is bonded to one O(12), one O(19), one O(2), one O(22), one O(28), and one O(5) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 8-15°. In the third W site, W(3) is bonded to one O(13), one O(18), one O(23), one O(29), one O(3), and one O(6) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 6-25°. In the fourth W site, W(4) is bonded to one O(14), one O(15), one O(24), one O(26), one O(3), and one O(4) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 1-20°. In the fifth W site, W(5) is bonded to one O(11), one O(15), one O(25), one O(27), one O(5), and one O(8) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 6-22°. In the sixth W site, W(6) is bonded to one O(16), one O(17), one O(21), one O(26), one O(6), and one O(9) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 1-16°. In the seventh W site, W(7) is bonded to one O(10), one O(13), one O(17), one O(22), one O(27), and one O(7) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 12-22°. In the eighth W site, W(8) is bonded to one O(14), one O(18), one O(28), one O(30), one O(7), and one O(8) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 8-24°. In the ninth W site, W(9) is bonded to one O(1), one O(19), one O(20), one O(24), one O(29), and one O(9) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 6-25°. In the tenth W site, W(10) is bonded to one O(10), one O(16), one O(2), one O(20), one O(25), and one O(30) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 6-21°. There are thirty inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Na(4), one W(1), and one W(9) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Li(1), one Li(5), one W(10), and one W(2) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(4), one W(3), and one W(4) atom. In the fourth O site, O(4) is bonded to one Na(2), one Na(3), one Li(2), one W(1), and one W(4) atom to form distorted face-sharing ONa2LiW2 square pyramids. In the fifth O site, O(5) is bonded in a distorted rectangular see-saw-like geometry to one Na(3), one Na(4), one W(2), and one W(5) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Na(3), one W(3), and one W(6) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Na(3), one Na(4), one W(7), and one W(8) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Na(1), one Li(1), one Li(2), one W(5), and one W(8) atom. In the ninth O site, O(9) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Li(3), one W(6), and one W(9) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Na(1), one Li(3), one Li(4), one W(10), and one W(7) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Na(2), one Li(2), one W(1), and one W(5) atom. In the twelfth O site, O(12) is bonded in a distorted T-shaped geometry to one Na(3), one W(1), and one W(2) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Na(2), one Li(4), one W(3), and one W(7) atom. In the fourteenth O site, O(14) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Li(2), one W(4), and one W(8) atom. In the fifteenth O site, O(15) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Na(3), one W(4), and one W(5) atom. In the sixteenth O site, O(16) is bonded in a distorted rectangular see-saw-like geometry to one Na(2), one Li(4), one W(10), and one W(6) atom. In the seventeenth O site, O(17) is bonded in a 5-coordinate geometry to one Na(1), one Na(3), one Li(3), one W(6), and one W(7) atom. In the eighteenth O site, O(18) is bonded in a distorted T-shaped geometry to one Na(3), one W(3), and one W(8) atom. In the nineteenth O site, O(19) is bonded in a distorted linear geometry to one W(2) and one W(9) atom. In the twentieth O site, O(20) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one Li(5), one W(10), and one W(9) atom. In the twenty-first O site, O(21) is bonded in a linear geometry to one W(1) and one W(6) atom. In the twenty-second O site, O(22) is bonded in a 2-coordinate geometry to one W(2) and one W(7) atom. In the twenty-third O site, O(23) is bonded in a 4-coordinate geometry to one Na(2), one Na(4), one W(1), and one W(3) atom. In the twenty-fourth O site, O(24) is bonded in a distorted T-shaped geometry to one Na(4), one W(4), and one W(9) atom. In the twenty-fifth O site, O(25) is bonded in a T-shaped geometry to one Li(1), one W(10), and one W(5) atom. In the twenty-sixth O site, O(26) is bonded to one Na(1), one Na(2), one Na(3), one W(4), and one W(6) atom to form distorted face-sharing ONa3W2 square pyramids. In the twenty-seventh O site, O(27) is bonded in a 5-coordinate geometry to one Na(1), one Na(2), one Na(4), one W(5), and one W(7) atom. In the twenty-eighth O site, O(28) is bonded in a 5-coordinate geometry to one Na(4), one Li(1), one Li(2), one W(2), and one W(8) atom. In the twenty-ninth O site, O(29) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Li(5), one W(3), and one W(9) atom. In the thirtieth O site, O(30) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), one Li(5), one W(10), and one W(8) atom. is represented by the CIF card [CIF]
data_Na4Li5(WO3)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.830
_cell_length_b   8.853
_cell_length_c   8.866
_cell_angle_alpha   113.979
_cell_angle_beta   89.712
_cell_angle_gamma   101.761
_symmetry_Int_Tables_number   1
_cell_volume   617.584
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.108  0.497  0.199  1.0
  Na  Na1  1  0.201  0.008  0.404  1.0
  Na  Na2  1  0.302  0.491  0.600  1.0
  Na  Na3  1  0.402  0.002  0.804  1.0
  Li  Li4  1  0.527  0.601  0.041  1.0
  Li  Li5  1  0.504  0.987  0.229  1.0
  Li  Li6  1  0.774  0.505  0.343  1.0
  Li  Li7  1  0.842  0.942  0.557  1.0
  Li  Li8  1  0.903  0.500  0.890  1.0
  W  W9  1  0.548  0.250  0.603  1.0
  W  W10  1  0.653  0.750  0.799  1.0
  W  W11  1  0.147  0.250  0.802  1.0
  W  W12  1  0.348  0.248  0.199  1.0
  W  W13  1  0.450  0.751  0.401  1.0
  W  W14  1  0.949  0.255  0.404  1.0
  W  W15  1  0.050  0.752  0.601  1.0
  W  W16  1  0.247  0.747  0.993  1.0
  W  W17  1  0.751  0.245  0.998  1.0
  W  W18  1  0.847  0.753  0.196  1.0
  O  O19  1  0.646  0.235  0.785  1.0
  O  O20  1  0.744  0.735  0.993  1.0
  O  O21  1  0.242  0.236  0.989  1.0
  O  O22  1  0.453  0.263  0.411  1.0
  O  O23  1  0.540  0.767  0.604  1.0
  O  O24  1  0.059  0.244  0.599  1.0
  O  O25  1  0.168  0.770  0.807  1.0
  O  O26  1  0.358  0.739  0.186  1.0
  O  O27  1  0.851  0.284  0.217  1.0
  O  O28  1  0.927  0.724  0.395  1.0
  O  O29  1  0.517  0.007  0.465  1.0
  O  O30  1  0.575  0.492  0.714  1.0
  O  O31  1  0.053  0.990  0.692  1.0
  O  O32  1  0.297  0.998  0.135  1.0
  O  O33  1  0.379  0.500  0.301  1.0
  O  O34  1  0.903  0.993  0.309  1.0
  O  O35  1  0.025  0.509  0.508  1.0
  O  O36  1  0.240  0.498  0.875  1.0
  O  O37  1  0.724  0.008  0.895  1.0
  O  O38  1  0.770  0.493  0.093  1.0
  O  O39  1  0.759  0.270  0.510  1.0
  O  O40  1  0.831  0.721  0.682  1.0
  O  O41  1  0.347  0.206  0.681  1.0
  O  O42  1  0.537  0.229  0.094  1.0
  O  O43  1  0.644  0.738  0.290  1.0
  O  O44  1  0.146  0.249  0.302  1.0
  O  O45  1  0.248  0.783  0.499  1.0
  O  O46  1  0.466  0.782  0.913  1.0
  O  O47  1  0.957  0.302  0.915  1.0
  O  O48  1  0.040  0.704  0.080  1.0
[/CIF]
.