The material described by Li5Co5(NiO6)2 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(12), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with three equivalent Li(4)O6 octahedra, and edges with three equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. In the second Li site, Li(2) is bonded to one O(10), one O(11), one O(2), one O(3), one O(4), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the third Li site, Li(3) is bonded to one O(10), one O(11), one O(2), one O(3), one O(4), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the fourth Li site, Li(4) is bonded to one O(1), one O(12), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. In the fifth Li site, Li(5) is bonded to one O(10), one O(12), one O(2), one O(5), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with three equivalent Co(5)O6 octahedra, and edges with three equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(11), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with three equivalent Co(2)O6 octahedra, and edges with three equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the second Co site, Co(2) is bonded to one O(1), one O(11), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the third Co site, Co(3) is bonded to one O(1), one O(12), one O(5), one O(6), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-10°. In the fourth Co site, Co(4) is bonded to one O(10), one O(11), one O(2), one O(3), one O(4), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the fifth Co site, Co(5) is bonded to one O(10), one O(12), one O(2), one O(5), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with three equivalent Li(5)O6 octahedra, and edges with three equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(10), one O(12), one O(2), one O(5), one O(6), and one O(9) atom to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with three equivalent Li(5)O6 octahedra, and edges with three equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the second Ni site, Ni(2) is bonded to one O(1), one O(11), one O(3), one O(4), one O(7), and one O(8) atom to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(4), one Co(1), one Co(2), one Co(3), and one Ni(2) atom to form OLi2Co3Ni octahedra that share  a cornercorner with one O(11)Li2Co3Ni octahedra,  a cornercorner with one O(3)Li2Co3Ni octahedra,  a cornercorner with one O(4)Li2Co3Ni octahedra,  a cornercorner with one O(12)Li3Co2Ni octahedra,  a cornercorner with one O(5)Li3Co2Ni octahedra,  a cornercorner with one O(6)Li3Co2Ni octahedra,  an edgeedge with one O(11)Li2Co3Ni octahedra,  an edgeedge with one O(3)Li2Co3Ni octahedra,  an edgeedge with one O(4)Li2Co3Ni octahedra,  an edgeedge with one O(12)Li3Co2Ni octahedra,  an edgeedge with one O(5)Li3Co2Ni octahedra,  an edgeedge with one O(6)Li3Co2Ni octahedra, edges with three equivalent O(7)Li2Co3Ni octahedra, and edges with three equivalent O(8)Li2Co3Ni octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the second O site, O(2) is bonded to one Li(2), one Li(3), one Li(5), one Co(4), one Co(5), and one Ni(1) atom to form OLi3Co2Ni octahedra that share  a cornercorner with one O(11)Li2Co3Ni octahedra,  a cornercorner with one O(3)Li2Co3Ni octahedra,  a cornercorner with one O(4)Li2Co3Ni octahedra,  a cornercorner with one O(12)Li3Co2Ni octahedra,  a cornercorner with one O(5)Li3Co2Ni octahedra,  a cornercorner with one O(6)Li3Co2Ni octahedra,  an edgeedge with one O(11)Li2Co3Ni octahedra,  an edgeedge with one O(3)Li2Co3Ni octahedra,  an edgeedge with one O(4)Li2Co3Ni octahedra,  an edgeedge with one O(12)Li3Co2Ni octahedra,  an edgeedge with one O(5)Li3Co2Ni octahedra,  an edgeedge with one O(6)Li3Co2Ni octahedra, edges with three equivalent O(10)Li3Co2Ni octahedra, and edges with three equivalent O(9)Li3Co2Ni octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the third O site, O(3) is bonded to one Li(2), one Li(3), one Co(1), one Co(2), one Co(4), and one Ni(2) atom to form OLi2Co3Ni octahedra that share  a cornercorner with one O(1)Li2Co3Ni octahedra,  a cornercorner with one O(7)Li2Co3Ni octahedra,  a cornercorner with one O(8)Li2Co3Ni octahedra,  a cornercorner with one O(10)Li3Co2Ni octahedra,  a cornercorner with one O(2)Li3Co2Ni octahedra,  a cornercorner with one O(9)Li3Co2Ni octahedra,  an edgeedge with one O(1)Li2Co3Ni octahedra,  an edgeedge with one O(7)Li2Co3Ni octahedra,  an edgeedge with one O(8)Li2Co3Ni octahedra,  an edgeedge with one O(10)Li3Co2Ni octahedra,  an edgeedge with one O(2)Li3Co2Ni octahedra,  an edgeedge with one O(9)Li3Co2Ni octahedra, edges with three equivalent O(11)Li2Co3Ni octahedra, and edges with three equivalent O(4)Li2Co3Ni octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Co(1), one Co(2), one Co(4), and one Ni(2) atom to form OLi2Co3Ni octahedra that share  a cornercorner with one O(1)Li2Co3Ni octahedra,  a cornercorner with one O(7)Li2Co3Ni octahedra,  a cornercorner with one O(8)Li2Co3Ni octahedra,  a cornercorner with one O(10)Li3Co2Ni octahedra,  a cornercorner with one O(2)Li3Co2Ni octahedra,  a cornercorner with one O(9)Li3Co2Ni octahedra,  an edgeedge with one O(1)Li2Co3Ni octahedra,  an edgeedge with one O(7)Li2Co3Ni octahedra,  an edgeedge with one O(8)Li2Co3Ni octahedra,  an edgeedge with one O(10)Li3Co2Ni octahedra,  an edgeedge with one O(2)Li3Co2Ni octahedra,  an edgeedge with one O(9)Li3Co2Ni octahedra, edges with three equivalent O(11)Li2Co3Ni octahedra, and edges with three equivalent O(3)Li2Co3Ni octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the fifth O site, O(5) is bonded to one Li(1), one Li(4), one Li(5), one Co(3), one Co(5), and one Ni(1) atom to form OLi3Co2Ni octahedra that share  a cornercorner with one O(1)Li2Co3Ni octahedra,  a cornercorner with one O(7)Li2Co3Ni octahedra,  a cornercorner with one O(8)Li2Co3Ni octahedra,  a cornercorner with one O(10)Li3Co2Ni octahedra,  a cornercorner with one O(2)Li3Co2Ni octahedra,  a cornercorner with one O(9)Li3Co2Ni octahedra,  an edgeedge with one O(1)Li2Co3Ni octahedra,  an edgeedge with one O(7)Li2Co3Ni octahedra,  an edgeedge with one O(8)Li2Co3Ni octahedra,  an edgeedge with one O(10)Li3Co2Ni octahedra,  an edgeedge with one O(2)Li3Co2Ni octahedra,  an edgeedge with one O(9)Li3Co2Ni octahedra, edges with three equivalent O(12)Li3Co2Ni octahedra, and edges with three equivalent O(6)Li3Co2Ni octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the sixth O site, O(6) is bonded to one Li(1), one Li(4), one Li(5), one Co(3), one Co(5), and one Ni(1) atom to form OLi3Co2Ni octahedra that share  a cornercorner with one O(1)Li2Co3Ni octahedra,  a cornercorner with one O(7)Li2Co3Ni octahedra,  a cornercorner with one O(8)Li2Co3Ni octahedra,  a cornercorner with one O(10)Li3Co2Ni octahedra,  a cornercorner with one O(2)Li3Co2Ni octahedra,  a cornercorner with one O(9)Li3Co2Ni octahedra,  an edgeedge with one O(1)Li2Co3Ni octahedra,  an edgeedge with one O(7)Li2Co3Ni octahedra,  an edgeedge with one O(8)Li2Co3Ni octahedra,  an edgeedge with one O(10)Li3Co2Ni octahedra,  an edgeedge with one O(2)Li3Co2Ni octahedra,  an edgeedge with one O(9)Li3Co2Ni octahedra, edges with three equivalent O(12)Li3Co2Ni octahedra, and edges with three equivalent O(5)Li3Co2Ni octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the seventh O site, O(7) is bonded to one Li(1), one Li(4), one Co(1), one Co(2), one Co(3), and one Ni(2) atom to form OLi2Co3Ni octahedra that share  a cornercorner with one O(11)Li2Co3Ni octahedra,  a cornercorner with one O(3)Li2Co3Ni octahedra,  a cornercorner with one O(4)Li2Co3Ni octahedra,  a cornercorner with one O(12)Li3Co2Ni octahedra,  a cornercorner with one O(5)Li3Co2Ni octahedra,  a cornercorner with one O(6)Li3Co2Ni octahedra,  an edgeedge with one O(11)Li2Co3Ni octahedra,  an edgeedge with one O(3)Li2Co3Ni octahedra,  an edgeedge with one O(4)Li2Co3Ni octahedra,  an edgeedge with one O(12)Li3Co2Ni octahedra,  an edgeedge with one O(5)Li3Co2Ni octahedra,  an edgeedge with one O(6)Li3Co2Ni octahedra, edges with three equivalent O(1)Li2Co3Ni octahedra, and edges with three equivalent O(8)Li2Co3Ni octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the eighth O site, O(8) is bonded to one Li(1), one Li(4), one Co(1), one Co(2), one Co(3), and one Ni(2) atom to form OLi2Co3Ni octahedra that share  a cornercorner with one O(11)Li2Co3Ni octahedra,  a cornercorner with one O(3)Li2Co3Ni octahedra,  a cornercorner with one O(4)Li2Co3Ni octahedra,  a cornercorner with one O(12)Li3Co2Ni octahedra,  a cornercorner with one O(5)Li3Co2Ni octahedra,  a cornercorner with one O(6)Li3Co2Ni octahedra,  an edgeedge with one O(11)Li2Co3Ni octahedra,  an edgeedge with one O(3)Li2Co3Ni octahedra,  an edgeedge with one O(4)Li2Co3Ni octahedra,  an edgeedge with one O(12)Li3Co2Ni octahedra,  an edgeedge with one O(5)Li3Co2Ni octahedra,  an edgeedge with one O(6)Li3Co2Ni octahedra, edges with three equivalent O(1)Li2Co3Ni octahedra, and edges with three equivalent O(7)Li2Co3Ni octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the ninth O site, O(9) is bonded to one Li(2), one Li(3), one Li(5), one Co(4), one Co(5), and one Ni(1) atom to form OLi3Co2Ni octahedra that share  a cornercorner with one O(11)Li2Co3Ni octahedra,  a cornercorner with one O(3)Li2Co3Ni octahedra,  a cornercorner with one O(4)Li2Co3Ni octahedra,  a cornercorner with one O(12)Li3Co2Ni octahedra,  a cornercorner with one O(5)Li3Co2Ni octahedra,  a cornercorner with one O(6)Li3Co2Ni octahedra,  an edgeedge with one O(11)Li2Co3Ni octahedra,  an edgeedge with one O(3)Li2Co3Ni octahedra,  an edgeedge with one O(4)Li2Co3Ni octahedra,  an edgeedge with one O(12)Li3Co2Ni octahedra,  an edgeedge with one O(5)Li3Co2Ni octahedra,  an edgeedge with one O(6)Li3Co2Ni octahedra, edges with three equivalent O(10)Li3Co2Ni octahedra, and edges with three equivalent O(2)Li3Co2Ni octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the tenth O site, O(10) is bonded to one Li(2), one Li(3), one Li(5), one Co(4), one Co(5), and one Ni(1) atom to form OLi3Co2Ni octahedra that share  a cornercorner with one O(11)Li2Co3Ni octahedra,  a cornercorner with one O(3)Li2Co3Ni octahedra,  a cornercorner with one O(4)Li2Co3Ni octahedra,  a cornercorner with one O(12)Li3Co2Ni octahedra,  a cornercorner with one O(5)Li3Co2Ni octahedra,  a cornercorner with one O(6)Li3Co2Ni octahedra,  an edgeedge with one O(11)Li2Co3Ni octahedra,  an edgeedge with one O(3)Li2Co3Ni octahedra,  an edgeedge with one O(4)Li2Co3Ni octahedra,  an edgeedge with one O(12)Li3Co2Ni octahedra,  an edgeedge with one O(5)Li3Co2Ni octahedra,  an edgeedge with one O(6)Li3Co2Ni octahedra, edges with three equivalent O(2)Li3Co2Ni octahedra, and edges with three equivalent O(9)Li3Co2Ni octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the eleventh O site, O(11) is bonded to one Li(2), one Li(3), one Co(1), one Co(2), one Co(4), and one Ni(2) atom to form OLi2Co3Ni octahedra that share  a cornercorner with one O(1)Li2Co3Ni octahedra,  a cornercorner with one O(7)Li2Co3Ni octahedra,  a cornercorner with one O(8)Li2Co3Ni octahedra,  a cornercorner with one O(10)Li3Co2Ni octahedra,  a cornercorner with one O(2)Li3Co2Ni octahedra,  a cornercorner with one O(9)Li3Co2Ni octahedra,  an edgeedge with one O(1)Li2Co3Ni octahedra,  an edgeedge with one O(7)Li2Co3Ni octahedra,  an edgeedge with one O(8)Li2Co3Ni octahedra,  an edgeedge with one O(10)Li3Co2Ni octahedra,  an edgeedge with one O(2)Li3Co2Ni octahedra,  an edgeedge with one O(9)Li3Co2Ni octahedra, edges with three equivalent O(3)Li2Co3Ni octahedra, and edges with three equivalent O(4)Li2Co3Ni octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the twelfth O site, O(12) is bonded to one Li(1), one Li(4), one Li(5), one Co(3), one Co(5), and one Ni(1) atom to form OLi3Co2Ni octahedra that share  a cornercorner with one O(1)Li2Co3Ni octahedra,  a cornercorner with one O(7)Li2Co3Ni octahedra,  a cornercorner with one O(8)Li2Co3Ni octahedra,  a cornercorner with one O(10)Li3Co2Ni octahedra,  a cornercorner with one O(2)Li3Co2Ni octahedra,  a cornercorner with one O(9)Li3Co2Ni octahedra,  an edgeedge with one O(1)Li2Co3Ni octahedra,  an edgeedge with one O(7)Li2Co3Ni octahedra,  an edgeedge with one O(8)Li2Co3Ni octahedra,  an edgeedge with one O(10)Li3Co2Ni octahedra,  an edgeedge with one O(2)Li3Co2Ni octahedra,  an edgeedge with one O(9)Li3Co2Ni octahedra, edges with three equivalent O(5)Li3Co2Ni octahedra, and edges with three equivalent O(6)Li3Co2Ni octahedra. The corner-sharing octahedral tilt angles range from 4-9°. is represented by the CIF file [CIF]
data_Li5Co5(NiO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.004
_cell_length_b   5.009
_cell_length_c   9.615
_cell_angle_alpha   94.726
_cell_angle_beta   94.862
_cell_angle_gamma   119.306
_symmetry_Int_Tables_number   1
_cell_volume   207.264
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.828  0.668  0.496  1.0
  Li  Li1  1  0.676  0.844  0.003  1.0
  Li  Li2  1  0.331  0.171  0.002  1.0
  Li  Li3  1  0.155  0.323  0.496  1.0
  Li  Li4  1  0.087  0.915  0.252  1.0
  Co  Co5  1  0.913  0.089  0.752  1.0
  Co  Co6  1  0.578  0.423  0.752  1.0
  Co  Co7  1  0.483  0.994  0.495  1.0
  Co  Co8  1  0.002  0.516  0.008  1.0
  Co  Co9  1  0.421  0.581  0.249  1.0
  Ni  Ni10  1  0.759  0.251  0.251  1.0
  Ni  Ni11  1  0.245  0.755  0.749  1.0
  O  O12  1  0.848  0.360  0.637  1.0
  O  O13  1  0.707  0.519  0.128  1.0
  O  O14  1  0.932  0.782  0.867  1.0
  O  O15  1  0.643  0.153  0.867  1.0
  O  O16  1  0.484  0.301  0.363  1.0
  O  O17  1  0.767  0.945  0.358  1.0
  O  O18  1  0.214  0.074  0.639  1.0
  O  O19  1  0.563  0.726  0.639  1.0
  O  O20  1  0.369  0.838  0.122  1.0
  O  O21  1  0.050  0.233  0.136  1.0
  O  O22  1  0.268  0.440  0.866  1.0
  O  O23  1  0.156  0.619  0.371  1.0
[/CIF]
.
The material described by Li5Co5(NiO6)2 is Caswellsilverite-derived structured and crystallizes in the triclinic P1 space group. There are five inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(12), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with three equivalent Li(4)O6 octahedra, and edges with three equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. In the second Li site, Li(2) is bonded to one O(10), one O(11), one O(2), one O(3), one O(4), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with three equivalent Li(3)O6 octahedra, and edges with three equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-10°. In the third Li site, Li(3) is bonded to one O(10), one O(11), one O(2), one O(3), one O(4), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the fourth Li site, Li(4) is bonded to one O(1), one O(12), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-12°. In the fifth Li site, Li(5) is bonded to one O(10), one O(12), one O(2), one O(5), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with three equivalent Co(5)O6 octahedra, and edges with three equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(11), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with three equivalent Co(2)O6 octahedra, and edges with three equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the second Co site, Co(2) is bonded to one O(1), one O(11), one O(3), one O(4), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Ni(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the third Co site, Co(3) is bonded to one O(1), one O(12), one O(5), one O(6), one O(7), and one O(8) atom to form CoO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-10°. In the fourth Co site, Co(4) is bonded to one O(10), one O(11), one O(2), one O(3), one O(4), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Ni(1)O6 octahedra,  a cornercorner with one Ni(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Ni(1)O6 octahedra,  an edgeedge with one Ni(2)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with three equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the fifth Co site, Co(5) is bonded to one O(10), one O(12), one O(2), one O(5), one O(6), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with three equivalent Li(5)O6 octahedra, and edges with three equivalent Ni(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one O(10), one O(12), one O(2), one O(5), one O(6), and one O(9) atom to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with three equivalent Li(5)O6 octahedra, and edges with three equivalent Co(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-10°. In the second Ni site, Ni(2) is bonded to one O(1), one O(11), one O(3), one O(4), one O(7), and one O(8) atom to form NiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(4)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 7-12°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), one Li(4), one Co(1), one Co(2), one Co(3), and one Ni(2) atom to form OLi2Co3Ni octahedra that share  a cornercorner with one O(11)Li2Co3Ni octahedra,  a cornercorner with one O(3)Li2Co3Ni octahedra,  a cornercorner with one O(4)Li2Co3Ni octahedra,  a cornercorner with one O(12)Li3Co2Ni octahedra,  a cornercorner with one O(5)Li3Co2Ni octahedra,  a cornercorner with one O(6)Li3Co2Ni octahedra,  an edgeedge with one O(11)Li2Co3Ni octahedra,  an edgeedge with one O(3)Li2Co3Ni octahedra,  an edgeedge with one O(4)Li2Co3Ni octahedra,  an edgeedge with one O(12)Li3Co2Ni octahedra,  an edgeedge with one O(5)Li3Co2Ni octahedra,  an edgeedge with one O(6)Li3Co2Ni octahedra, edges with three equivalent O(7)Li2Co3Ni octahedra, and edges with three equivalent O(8)Li2Co3Ni octahedra. The corner-sharing octahedral tilt angles range from 1-7°. In the second O site, O(2) is bonded to one Li(2), one Li(3), one Li(5), one Co(4), one Co(5), and one Ni(1) atom to form OLi3Co2Ni octahedra that share  a cornercorner with one O(11)Li2Co3Ni octahedra,  a cornercorner with one O(3)Li2Co3Ni octahedra,  a cornercorner with one O(4)Li2Co3Ni octahedra,  a cornercorner with one O(12)Li3Co2Ni octahedra,  a cornercorner with one O(5)Li3Co2Ni octahedra,  a cornercorner with one O(6)Li3Co2Ni octahedra,  an edgeedge with one O(11)Li2Co3Ni octahedra,  an edgeedge with one O(3)Li2Co3Ni octahedra,  an edgeedge with one O(4)Li2Co3Ni octahedra,  an edgeedge with one O(12)Li3Co2Ni octahedra,  an edgeedge with one O(5)Li3Co2Ni octahedra,  an edgeedge with one O(6)Li3Co2Ni octahedra, edges with three equivalent O(10)Li3Co2Ni octahedra, and edges with three equivalent O(9)Li3Co2Ni octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the third O site, O(3) is bonded to one Li(2), one Li(3), one Co(1), one Co(2), one Co(4), and one Ni(2) atom to form OLi2Co3Ni octahedra that share  a cornercorner with one O(1)Li2Co3Ni octahedra,  a cornercorner with one O(7)Li2Co3Ni octahedra,  a cornercorner with one O(8)Li2Co3Ni octahedra,  a cornercorner with one O(10)Li3Co2Ni octahedra,  a cornercorner with one O(2)Li3Co2Ni octahedra,  a cornercorner with one O(9)Li3Co2Ni octahedra,  an edgeedge with one O(1)Li2Co3Ni octahedra,  an edgeedge with one O(7)Li2Co3Ni octahedra,  an edgeedge with one O(8)Li2Co3Ni octahedra,  an edgeedge with one O(10)Li3Co2Ni octahedra,  an edgeedge with one O(2)Li3Co2Ni octahedra,  an edgeedge with one O(9)Li3Co2Ni octahedra, edges with three equivalent O(11)Li2Co3Ni octahedra, and edges with three equivalent O(4)Li2Co3Ni octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the fourth O site, O(4) is bonded to one Li(2), one Li(3), one Co(1), one Co(2), one Co(4), and one Ni(2) atom to form OLi2Co3Ni octahedra that share  a cornercorner with one O(1)Li2Co3Ni octahedra,  a cornercorner with one O(7)Li2Co3Ni octahedra,  a cornercorner with one O(8)Li2Co3Ni octahedra,  a cornercorner with one O(10)Li3Co2Ni octahedra,  a cornercorner with one O(2)Li3Co2Ni octahedra,  a cornercorner with one O(9)Li3Co2Ni octahedra,  an edgeedge with one O(1)Li2Co3Ni octahedra,  an edgeedge with one O(7)Li2Co3Ni octahedra,  an edgeedge with one O(8)Li2Co3Ni octahedra,  an edgeedge with one O(10)Li3Co2Ni octahedra,  an edgeedge with one O(2)Li3Co2Ni octahedra,  an edgeedge with one O(9)Li3Co2Ni octahedra, edges with three equivalent O(11)Li2Co3Ni octahedra, and edges with three equivalent O(3)Li2Co3Ni octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the fifth O site, O(5) is bonded to one Li(1), one Li(4), one Li(5), one Co(3), one Co(5), and one Ni(1) atom to form OLi3Co2Ni octahedra that share  a cornercorner with one O(1)Li2Co3Ni octahedra,  a cornercorner with one O(7)Li2Co3Ni octahedra,  a cornercorner with one O(8)Li2Co3Ni octahedra,  a cornercorner with one O(10)Li3Co2Ni octahedra,  a cornercorner with one O(2)Li3Co2Ni octahedra,  a cornercorner with one O(9)Li3Co2Ni octahedra,  an edgeedge with one O(1)Li2Co3Ni octahedra,  an edgeedge with one O(7)Li2Co3Ni octahedra,  an edgeedge with one O(8)Li2Co3Ni octahedra,  an edgeedge with one O(10)Li3Co2Ni octahedra,  an edgeedge with one O(2)Li3Co2Ni octahedra,  an edgeedge with one O(9)Li3Co2Ni octahedra, edges with three equivalent O(12)Li3Co2Ni octahedra, and edges with three equivalent O(6)Li3Co2Ni octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the sixth O site, O(6) is bonded to one Li(1), one Li(4), one Li(5), one Co(3), one Co(5), and one Ni(1) atom to form OLi3Co2Ni octahedra that share  a cornercorner with one O(1)Li2Co3Ni octahedra,  a cornercorner with one O(7)Li2Co3Ni octahedra,  a cornercorner with one O(8)Li2Co3Ni octahedra,  a cornercorner with one O(10)Li3Co2Ni octahedra,  a cornercorner with one O(2)Li3Co2Ni octahedra,  a cornercorner with one O(9)Li3Co2Ni octahedra,  an edgeedge with one O(1)Li2Co3Ni octahedra,  an edgeedge with one O(7)Li2Co3Ni octahedra,  an edgeedge with one O(8)Li2Co3Ni octahedra,  an edgeedge with one O(10)Li3Co2Ni octahedra,  an edgeedge with one O(2)Li3Co2Ni octahedra,  an edgeedge with one O(9)Li3Co2Ni octahedra, edges with three equivalent O(12)Li3Co2Ni octahedra, and edges with three equivalent O(5)Li3Co2Ni octahedra. The corner-sharing octahedral tilt angles range from 1-8°. In the seventh O site, O(7) is bonded to one Li(1), one Li(4), one Co(1), one Co(2), one Co(3), and one Ni(2) atom to form OLi2Co3Ni octahedra that share  a cornercorner with one O(11)Li2Co3Ni octahedra,  a cornercorner with one O(3)Li2Co3Ni octahedra,  a cornercorner with one O(4)Li2Co3Ni octahedra,  a cornercorner with one O(12)Li3Co2Ni octahedra,  a cornercorner with one O(5)Li3Co2Ni octahedra,  a cornercorner with one O(6)Li3Co2Ni octahedra,  an edgeedge with one O(11)Li2Co3Ni octahedra,  an edgeedge with one O(3)Li2Co3Ni octahedra,  an edgeedge with one O(4)Li2Co3Ni octahedra,  an edgeedge with one O(12)Li3Co2Ni octahedra,  an edgeedge with one O(5)Li3Co2Ni octahedra,  an edgeedge with one O(6)Li3Co2Ni octahedra, edges with three equivalent O(1)Li2Co3Ni octahedra, and edges with three equivalent O(8)Li2Co3Ni octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the eighth O site, O(8) is bonded to one Li(1), one Li(4), one Co(1), one Co(2), one Co(3), and one Ni(2) atom to form OLi2Co3Ni octahedra that share  a cornercorner with one O(11)Li2Co3Ni octahedra,  a cornercorner with one O(3)Li2Co3Ni octahedra,  a cornercorner with one O(4)Li2Co3Ni octahedra,  a cornercorner with one O(12)Li3Co2Ni octahedra,  a cornercorner with one O(5)Li3Co2Ni octahedra,  a cornercorner with one O(6)Li3Co2Ni octahedra,  an edgeedge with one O(11)Li2Co3Ni octahedra,  an edgeedge with one O(3)Li2Co3Ni octahedra,  an edgeedge with one O(4)Li2Co3Ni octahedra,  an edgeedge with one O(12)Li3Co2Ni octahedra,  an edgeedge with one O(5)Li3Co2Ni octahedra,  an edgeedge with one O(6)Li3Co2Ni octahedra, edges with three equivalent O(1)Li2Co3Ni octahedra, and edges with three equivalent O(7)Li2Co3Ni octahedra. The corner-sharing octahedral tilt angles range from 1-9°. In the ninth O site, O(9) is bonded to one Li(2), one Li(3), one Li(5), one Co(4), one Co(5), and one Ni(1) atom to form OLi3Co2Ni octahedra that share  a cornercorner with one O(11)Li2Co3Ni octahedra,  a cornercorner with one O(3)Li2Co3Ni octahedra,  a cornercorner with one O(4)Li2Co3Ni octahedra,  a cornercorner with one O(12)Li3Co2Ni octahedra,  a cornercorner with one O(5)Li3Co2Ni octahedra,  a cornercorner with one O(6)Li3Co2Ni octahedra,  an edgeedge with one O(11)Li2Co3Ni octahedra,  an edgeedge with one O(3)Li2Co3Ni octahedra,  an edgeedge with one O(4)Li2Co3Ni octahedra,  an edgeedge with one O(12)Li3Co2Ni octahedra,  an edgeedge with one O(5)Li3Co2Ni octahedra,  an edgeedge with one O(6)Li3Co2Ni octahedra, edges with three equivalent O(10)Li3Co2Ni octahedra, and edges with three equivalent O(2)Li3Co2Ni octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the tenth O site, O(10) is bonded to one Li(2), one Li(3), one Li(5), one Co(4), one Co(5), and one Ni(1) atom to form OLi3Co2Ni octahedra that share  a cornercorner with one O(11)Li2Co3Ni octahedra,  a cornercorner with one O(3)Li2Co3Ni octahedra,  a cornercorner with one O(4)Li2Co3Ni octahedra,  a cornercorner with one O(12)Li3Co2Ni octahedra,  a cornercorner with one O(5)Li3Co2Ni octahedra,  a cornercorner with one O(6)Li3Co2Ni octahedra,  an edgeedge with one O(11)Li2Co3Ni octahedra,  an edgeedge with one O(3)Li2Co3Ni octahedra,  an edgeedge with one O(4)Li2Co3Ni octahedra,  an edgeedge with one O(12)Li3Co2Ni octahedra,  an edgeedge with one O(5)Li3Co2Ni octahedra,  an edgeedge with one O(6)Li3Co2Ni octahedra, edges with three equivalent O(2)Li3Co2Ni octahedra, and edges with three equivalent O(9)Li3Co2Ni octahedra. The corner-sharing octahedral tilt angles range from 2-6°. In the eleventh O site, O(11) is bonded to one Li(2), one Li(3), one Co(1), one Co(2), one Co(4), and one Ni(2) atom to form OLi2Co3Ni octahedra that share  a cornercorner with one O(1)Li2Co3Ni octahedra,  a cornercorner with one O(7)Li2Co3Ni octahedra,  a cornercorner with one O(8)Li2Co3Ni octahedra,  a cornercorner with one O(10)Li3Co2Ni octahedra,  a cornercorner with one O(2)Li3Co2Ni octahedra,  a cornercorner with one O(9)Li3Co2Ni octahedra,  an edgeedge with one O(1)Li2Co3Ni octahedra,  an edgeedge with one O(7)Li2Co3Ni octahedra,  an edgeedge with one O(8)Li2Co3Ni octahedra,  an edgeedge with one O(10)Li3Co2Ni octahedra,  an edgeedge with one O(2)Li3Co2Ni octahedra,  an edgeedge with one O(9)Li3Co2Ni octahedra, edges with three equivalent O(3)Li2Co3Ni octahedra, and edges with three equivalent O(4)Li2Co3Ni octahedra. The corner-sharing octahedral tilt angles range from 2-9°. In the twelfth O site, O(12) is bonded to one Li(1), one Li(4), one Li(5), one Co(3), one Co(5), and one Ni(1) atom to form OLi3Co2Ni octahedra that share  a cornercorner with one O(1)Li2Co3Ni octahedra,  a cornercorner with one O(7)Li2Co3Ni octahedra,  a cornercorner with one O(8)Li2Co3Ni octahedra,  a cornercorner with one O(10)Li3Co2Ni octahedra,  a cornercorner with one O(2)Li3Co2Ni octahedra,  a cornercorner with one O(9)Li3Co2Ni octahedra,  an edgeedge with one O(1)Li2Co3Ni octahedra,  an edgeedge with one O(7)Li2Co3Ni octahedra,  an edgeedge with one O(8)Li2Co3Ni octahedra,  an edgeedge with one O(10)Li3Co2Ni octahedra,  an edgeedge with one O(2)Li3Co2Ni octahedra,  an edgeedge with one O(9)Li3Co2Ni octahedra, edges with three equivalent O(5)Li3Co2Ni octahedra, and edges with three equivalent O(6)Li3Co2Ni octahedra. The corner-sharing octahedral tilt angles range from 4-9°. is represented by the CIF file [CIF]
data_Li5Co5(NiO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.004
_cell_length_b   5.009
_cell_length_c   9.615
_cell_angle_alpha   94.726
_cell_angle_beta   94.862
_cell_angle_gamma   119.306
_symmetry_Int_Tables_number   1
_cell_volume   207.264
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.828  0.668  0.496  1.0
  Li  Li1  1  0.676  0.844  0.003  1.0
  Li  Li2  1  0.331  0.171  0.002  1.0
  Li  Li3  1  0.155  0.323  0.496  1.0
  Li  Li4  1  0.087  0.915  0.252  1.0
  Co  Co5  1  0.913  0.089  0.752  1.0
  Co  Co6  1  0.578  0.423  0.752  1.0
  Co  Co7  1  0.483  0.994  0.495  1.0
  Co  Co8  1  0.002  0.516  0.008  1.0
  Co  Co9  1  0.421  0.581  0.249  1.0
  Ni  Ni10  1  0.759  0.251  0.251  1.0
  Ni  Ni11  1  0.245  0.755  0.749  1.0
  O  O12  1  0.848  0.360  0.637  1.0
  O  O13  1  0.707  0.519  0.128  1.0
  O  O14  1  0.932  0.782  0.867  1.0
  O  O15  1  0.643  0.153  0.867  1.0
  O  O16  1  0.484  0.301  0.363  1.0
  O  O17  1  0.767  0.945  0.358  1.0
  O  O18  1  0.214  0.074  0.639  1.0
  O  O19  1  0.563  0.726  0.639  1.0
  O  O20  1  0.369  0.838  0.122  1.0
  O  O21  1  0.050  0.233  0.136  1.0
  O  O22  1  0.268  0.440  0.866  1.0
  O  O23  1  0.156  0.619  0.371  1.0
[/CIF]
.