The structure described by MnOF crystallizes in the orthorhombic Pnma space group. Mn(1) is bonded to three equivalent O(1) and two equivalent F(1) atoms to form a mixture of corner and edge-sharing MnO3F2 trigonal bipyramids. O(1) is bonded in a T-shaped geometry to three equivalent Mn(1) atoms. F(1) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.725
_cell_length_b   8.936
_cell_length_c   5.459
_cell_angle_alpha   90.003
_cell_angle_beta   90.000
_cell_angle_gamma   89.998
_symmetry_Int_Tables_number   1
_cell_volume   181.709
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.750  0.405  0.367  1.0
  Mn  Mn1  1  0.750  0.095  0.867  1.0
  Mn  Mn2  1  0.250  0.905  0.133  1.0
  Mn  Mn3  1  0.250  0.595  0.633  1.0
  O  O4  1  0.750  0.959  0.139  1.0
  O  O5  1  0.250  0.459  0.361  1.0
  O  O6  1  0.750  0.541  0.639  1.0
  O  O7  1  0.250  0.041  0.861  1.0
  F  F8  1  0.750  0.296  0.067  1.0
  F  F9  1  0.250  0.796  0.433  1.0
  F  F10  1  0.750  0.204  0.567  1.0
  F  F11  1  0.250  0.704  0.933  1.0
[/CIF]
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The structure described by MnOF crystallizes in the orthorhombic Pnma space group. Mn(1) is bonded to three equivalent O(1) and two equivalent F(1) atoms to form a mixture of corner and edge-sharing MnO3F2 trigonal bipyramids. O(1) is bonded in a T-shaped geometry to three equivalent Mn(1) atoms. F(1) is bonded in a bent 150 degrees geometry to two equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.725
_cell_length_b   8.936
_cell_length_c   5.459
_cell_angle_alpha   90.003
_cell_angle_beta   90.000
_cell_angle_gamma   89.998
_symmetry_Int_Tables_number   1
_cell_volume   181.709
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.750  0.405  0.367  1.0
  Mn  Mn1  1  0.750  0.095  0.867  1.0
  Mn  Mn2  1  0.250  0.905  0.133  1.0
  Mn  Mn3  1  0.250  0.595  0.633  1.0
  O  O4  1  0.750  0.959  0.139  1.0
  O  O5  1  0.250  0.459  0.361  1.0
  O  O6  1  0.750  0.541  0.639  1.0
  O  O7  1  0.250  0.041  0.861  1.0
  F  F8  1  0.750  0.296  0.067  1.0
  F  F9  1  0.250  0.796  0.433  1.0
  F  F10  1  0.750  0.204  0.567  1.0
  F  F11  1  0.250  0.704  0.933  1.0
[/CIF]
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