The structure described by XeTe4(OF5)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one XeTe4(OF5)4 cluster. Xe(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in an octahedral geometry to one O(1), one F(1), one F(3), one F(5), one F(8), and one F(9) atom. In the second Te site, Te(2) is bonded in an octahedral geometry to one O(2), one F(10), one F(2), one F(4), one F(6), and one F(7) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Xe(1) and one Te(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Xe(1) and one Te(2) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(2) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Te(2) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Te(2) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Te(1) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Te(1) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Te(2) atom. is represented by the CIF card [CIF]
data_Te4Xe(OF5)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.711
_cell_length_b   8.847
_cell_length_c   10.556
_cell_angle_alpha   109.774
_cell_angle_beta   97.923
_cell_angle_gamma   91.240
_symmetry_Int_Tables_number   1
_cell_volume   495.776
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.263  0.100  0.741  1.0
  Te  Te1  1  0.737  0.900  0.259  1.0
  Te  Te2  1  0.227  0.393  0.252  1.0
  Te  Te3  1  0.773  0.607  0.748  1.0
  Xe  Xe4  1  0.000  0.000  0.000  1.0
  O  O5  1  0.764  0.033  0.149  1.0
  O  O6  1  0.236  0.967  0.851  1.0
  O  O7  1  0.263  0.170  0.150  1.0
  O  O8  1  0.737  0.830  0.850  1.0
  F  F9  1  0.132  0.271  0.864  1.0
  F  F10  1  0.868  0.729  0.136  1.0
  F  F11  1  0.084  0.335  0.380  1.0
  F  F12  1  0.916  0.665  0.620  1.0
  F  F13  1  0.301  0.229  0.637  1.0
  F  F14  1  0.699  0.771  0.363  1.0
  F  F15  1  0.928  0.386  0.149  1.0
  F  F16  1  0.072  0.614  0.851  1.0
  F  F17  1  0.609  0.069  0.384  1.0
  F  F18  1  0.391  0.931  0.616  1.0
  F  F19  1  0.371  0.465  0.132  1.0
  F  F20  1  0.629  0.535  0.868  1.0
  F  F21  1  0.527  0.401  0.353  1.0
  F  F22  1  0.473  0.599  0.647  1.0
  F  F23  1  0.042  0.969  0.357  1.0
  F  F24  1  0.958  0.031  0.643  1.0
  F  F25  1  0.432  0.824  0.163  1.0
  F  F26  1  0.568  0.176  0.837  1.0
  F  F27  1  0.194  0.607  0.353  1.0
  F  F28  1  0.806  0.393  0.647  1.0
[/CIF]
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The structure described by XeTe4(OF5)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one XeTe4(OF5)4 cluster. Xe(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in an octahedral geometry to one O(1), one F(1), one F(3), one F(5), one F(8), and one F(9) atom. In the second Te site, Te(2) is bonded in an octahedral geometry to one O(2), one F(10), one F(2), one F(4), one F(6), and one F(7) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Xe(1) and one Te(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Xe(1) and one Te(2) atom. There are ten inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Te(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Te(2) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Te(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Te(2) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one Te(2) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one Te(1) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one Te(1) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one Te(2) atom. is represented by the CIF card [CIF]
data_Te4Xe(OF5)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.711
_cell_length_b   8.847
_cell_length_c   10.556
_cell_angle_alpha   109.774
_cell_angle_beta   97.923
_cell_angle_gamma   91.240
_symmetry_Int_Tables_number   1
_cell_volume   495.776
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.263  0.100  0.741  1.0
  Te  Te1  1  0.737  0.900  0.259  1.0
  Te  Te2  1  0.227  0.393  0.252  1.0
  Te  Te3  1  0.773  0.607  0.748  1.0
  Xe  Xe4  1  0.000  0.000  0.000  1.0
  O  O5  1  0.764  0.033  0.149  1.0
  O  O6  1  0.236  0.967  0.851  1.0
  O  O7  1  0.263  0.170  0.150  1.0
  O  O8  1  0.737  0.830  0.850  1.0
  F  F9  1  0.132  0.271  0.864  1.0
  F  F10  1  0.868  0.729  0.136  1.0
  F  F11  1  0.084  0.335  0.380  1.0
  F  F12  1  0.916  0.665  0.620  1.0
  F  F13  1  0.301  0.229  0.637  1.0
  F  F14  1  0.699  0.771  0.363  1.0
  F  F15  1  0.928  0.386  0.149  1.0
  F  F16  1  0.072  0.614  0.851  1.0
  F  F17  1  0.609  0.069  0.384  1.0
  F  F18  1  0.391  0.931  0.616  1.0
  F  F19  1  0.371  0.465  0.132  1.0
  F  F20  1  0.629  0.535  0.868  1.0
  F  F21  1  0.527  0.401  0.353  1.0
  F  F22  1  0.473  0.599  0.647  1.0
  F  F23  1  0.042  0.969  0.357  1.0
  F  F24  1  0.958  0.031  0.643  1.0
  F  F25  1  0.432  0.824  0.163  1.0
  F  F26  1  0.568  0.176  0.837  1.0
  F  F27  1  0.194  0.607  0.353  1.0
  F  F28  1  0.806  0.393  0.647  1.0
[/CIF]
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