The structure described by Li4V3Mn3(SnO8)2 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with three equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-63°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with three equivalent Sn(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 62-66°. In the third Li site, Li(3) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with three equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-66°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Sn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sn(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 47-51°. In the second V site, V(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Sn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sn(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 52°. In the third V site, V(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Sn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-49°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Sn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sn(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 57°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent Sn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent Sn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-57°. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form SnO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-57°. In the second Sn site, Sn(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 trigonal pyramids,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-57°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Mn(2), and one Sn(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one V(1), one V(2), and one Sn(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one V(2), and one Mn(1) atom. In the fourth O site, O(4) is bonded to one Li(3), one V(1), one V(2), and one Mn(1) atom to form corner-sharing OLiMnV2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one V(3), one Mn(2), and one Mn(3) atom to form OLiMn2V tetrahedra that share corners with two equivalent O(15)LiMn2Sn tetrahedra, corners with three equivalent O(13)LiMn2V tetrahedra, and corners with two equivalent O(11)LiMnVSn trigonal pyramids. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Mn(3), and one Sn(1) atom. In the seventh O site, O(7) is bonded to one Li(4), one V(1), one Mn(1), and one Sn(1) atom to form distorted OLiMnVSn trigonal pyramids that share  a cornercorner with one O(13)LiMn2V tetrahedra,  a cornercorner with one O(8)LiMnVSn tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra, and  an edgeedge with one O(8)LiMnVSn tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one V(2), one Mn(1), and one Sn(1) atom to form distorted OLiMnVSn tetrahedra that share  a cornercorner with one O(13)LiMn2V tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra,  a cornercorner with one O(7)LiMnVSn trigonal pyramid, and  an edgeedge with one O(7)LiMnVSn trigonal pyramid. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one V(2), and one Sn(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(2), one Mn(3), and one Sn(1) atom. In the eleventh O site, O(11) is bonded to one Li(1), one V(3), one Mn(2), and one Sn(2) atom to form distorted OLiMnVSn trigonal pyramids that share  a cornercorner with one O(15)LiMn2Sn tetrahedra, corners with two equivalent O(5)LiMn2V tetrahedra,  an edgeedge with one O(15)LiMn2Sn tetrahedra, and  an edgeedge with one O(13)LiMn2V tetrahedra. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(3), one Mn(3), and one Sn(2) atom. In the thirteenth O site, O(13) is bonded to one Li(4), one V(3), one Mn(2), and one Mn(3) atom to form distorted OLiMn2V tetrahedra that share  a cornercorner with one O(8)LiMnVSn tetrahedra, corners with three equivalent O(5)LiMn2V tetrahedra,  a cornercorner with one O(7)LiMnVSn trigonal pyramid,  an edgeedge with one O(15)LiMn2Sn tetrahedra, and  an edgeedge with one O(11)LiMnVSn trigonal pyramid. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one Mn(1), and one Sn(2) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one Mn(2), one Mn(3), and one Sn(2) atom to form distorted OLiMn2Sn tetrahedra that share corners with two equivalent O(5)LiMn2V tetrahedra,  a cornercorner with one O(11)LiMnVSn trigonal pyramid,  an edgeedge with one O(13)LiMn2V tetrahedra, and  an edgeedge with one O(11)LiMnVSn trigonal pyramid. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Mn(1), and one Sn(2) atom. is represented by the CIF card [CIF]
data_Li4Mn3V3(SnO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.087
_cell_length_b   5.913
_cell_length_c   9.850
_cell_angle_alpha   89.403
_cell_angle_beta   91.776
_cell_angle_gamma   119.902
_symmetry_Int_Tables_number   1
_cell_volume   307.187
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.315  0.658  0.897  1.0
  Li  Li1  1  1.000  0.991  0.992  1.0
  Li  Li2  1  0.015  0.012  0.492  1.0
  Li  Li3  1  0.666  0.338  0.399  1.0
  Mn  Mn4  1  0.665  0.835  0.213  1.0
  Mn  Mn5  1  0.831  0.664  0.713  1.0
  Mn  Mn6  1  0.825  0.167  0.714  1.0
  V  V7  1  0.165  0.820  0.214  1.0
  V  V8  1  0.173  0.340  0.215  1.0
  V  V9  1  0.337  0.175  0.716  1.0
  Sn  Sn10  1  0.350  0.681  0.489  1.0
  Sn  Sn11  1  0.655  0.315  0.991  1.0
  O  O12  1  0.199  0.869  0.602  1.0
  O  O13  1  0.035  0.528  0.337  1.0
  O  O14  1  0.339  0.679  0.110  1.0
  O  O15  1  0.999  0.991  0.305  1.0
  O  O16  1  0.998  0.000  0.804  1.0
  O  O17  1  0.187  0.340  0.597  1.0
  O  O18  1  0.464  0.975  0.343  1.0
  O  O19  1  0.484  0.523  0.336  1.0
  O  O20  1  0.319  0.146  0.104  1.0
  O  O21  1  0.699  0.851  0.595  1.0
  O  O22  1  0.481  0.454  0.841  1.0
  O  O23  1  0.491  0.021  0.845  1.0
  O  O24  1  0.666  0.336  0.613  1.0
  O  O25  1  0.852  0.664  0.095  1.0
  O  O26  1  0.949  0.475  0.839  1.0
  O  O27  1  0.842  0.152  0.097  1.0
[/CIF]
.
The structure described by Li4V3Mn3(SnO8)2 is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(12), one O(15), and one O(3) atom to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Mn(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with three equivalent Sn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 56-63°. In the second Li site, Li(2) is bonded to one O(14), one O(16), one O(5), and one O(9) atom to form distorted LiO4 trigonal pyramids that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with three equivalent Sn(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 62-66°. In the third Li site, Li(3) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(10), one O(4), and one O(6) atom. In the fourth Li site, Li(4) is bonded to one O(13), one O(2), one O(7), and one O(8) atom to form LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, and corners with three equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-66°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Sn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sn(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles range from 47-51°. In the second V site, V(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form VO6 octahedra that share corners with two equivalent Sn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sn(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 52°. In the third V site, V(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Sn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-49°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Sn(2)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Sn(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and  an edgeedge with one Li(2)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 57°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent Sn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-55°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent Sn(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra,  a cornercorner with one Li(2)O4 trigonal pyramid,  an edgeedge with one Sn(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-57°. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form SnO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-57°. In the second Sn site, Sn(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form SnO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Mn(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(2)O4 trigonal pyramids,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-57°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Mn(2), and one Sn(1) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one V(1), one V(2), and one Sn(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one V(2), and one Mn(1) atom. In the fourth O site, O(4) is bonded to one Li(3), one V(1), one V(2), and one Mn(1) atom to form corner-sharing OLiMnV2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), one V(3), one Mn(2), and one Mn(3) atom to form OLiMn2V tetrahedra that share corners with two equivalent O(15)LiMn2Sn tetrahedra, corners with three equivalent O(13)LiMn2V tetrahedra, and corners with two equivalent O(11)LiMnVSn trigonal pyramids. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(3), one Mn(3), and one Sn(1) atom. In the seventh O site, O(7) is bonded to one Li(4), one V(1), one Mn(1), and one Sn(1) atom to form distorted OLiMnVSn trigonal pyramids that share  a cornercorner with one O(13)LiMn2V tetrahedra,  a cornercorner with one O(8)LiMnVSn tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra, and  an edgeedge with one O(8)LiMnVSn tetrahedra. In the eighth O site, O(8) is bonded to one Li(4), one V(2), one Mn(1), and one Sn(1) atom to form distorted OLiMnVSn tetrahedra that share  a cornercorner with one O(13)LiMn2V tetrahedra, corners with two equivalent O(4)LiMnV2 tetrahedra,  a cornercorner with one O(7)LiMnVSn trigonal pyramid, and  an edgeedge with one O(7)LiMnVSn trigonal pyramid. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one V(2), and one Sn(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(2), one Mn(3), and one Sn(1) atom. In the eleventh O site, O(11) is bonded to one Li(1), one V(3), one Mn(2), and one Sn(2) atom to form distorted OLiMnVSn trigonal pyramids that share  a cornercorner with one O(15)LiMn2Sn tetrahedra, corners with two equivalent O(5)LiMn2V tetrahedra,  an edgeedge with one O(15)LiMn2Sn tetrahedra, and  an edgeedge with one O(13)LiMn2V tetrahedra. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(3), one Mn(3), and one Sn(2) atom. In the thirteenth O site, O(13) is bonded to one Li(4), one V(3), one Mn(2), and one Mn(3) atom to form distorted OLiMn2V tetrahedra that share  a cornercorner with one O(8)LiMnVSn tetrahedra, corners with three equivalent O(5)LiMn2V tetrahedra,  a cornercorner with one O(7)LiMnVSn trigonal pyramid,  an edgeedge with one O(15)LiMn2Sn tetrahedra, and  an edgeedge with one O(11)LiMnVSn trigonal pyramid. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one Mn(1), and one Sn(2) atom. In the fifteenth O site, O(15) is bonded to one Li(1), one Mn(2), one Mn(3), and one Sn(2) atom to form distorted OLiMn2Sn tetrahedra that share corners with two equivalent O(5)LiMn2V tetrahedra,  a cornercorner with one O(11)LiMnVSn trigonal pyramid,  an edgeedge with one O(13)LiMn2V tetrahedra, and  an edgeedge with one O(11)LiMnVSn trigonal pyramid. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one Mn(1), and one Sn(2) atom. is represented by the CIF card [CIF]
data_Li4Mn3V3(SnO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.087
_cell_length_b   5.913
_cell_length_c   9.850
_cell_angle_alpha   89.403
_cell_angle_beta   91.776
_cell_angle_gamma   119.902
_symmetry_Int_Tables_number   1
_cell_volume   307.187
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.315  0.658  0.897  1.0
  Li  Li1  1  1.000  0.991  0.992  1.0
  Li  Li2  1  0.015  0.012  0.492  1.0
  Li  Li3  1  0.666  0.338  0.399  1.0
  Mn  Mn4  1  0.665  0.835  0.213  1.0
  Mn  Mn5  1  0.831  0.664  0.713  1.0
  Mn  Mn6  1  0.825  0.167  0.714  1.0
  V  V7  1  0.165  0.820  0.214  1.0
  V  V8  1  0.173  0.340  0.215  1.0
  V  V9  1  0.337  0.175  0.716  1.0
  Sn  Sn10  1  0.350  0.681  0.489  1.0
  Sn  Sn11  1  0.655  0.315  0.991  1.0
  O  O12  1  0.199  0.869  0.602  1.0
  O  O13  1  0.035  0.528  0.337  1.0
  O  O14  1  0.339  0.679  0.110  1.0
  O  O15  1  0.999  0.991  0.305  1.0
  O  O16  1  0.998  0.000  0.804  1.0
  O  O17  1  0.187  0.340  0.597  1.0
  O  O18  1  0.464  0.975  0.343  1.0
  O  O19  1  0.484  0.523  0.336  1.0
  O  O20  1  0.319  0.146  0.104  1.0
  O  O21  1  0.699  0.851  0.595  1.0
  O  O22  1  0.481  0.454  0.841  1.0
  O  O23  1  0.491  0.021  0.845  1.0
  O  O24  1  0.666  0.336  0.613  1.0
  O  O25  1  0.852  0.664  0.095  1.0
  O  O26  1  0.949  0.475  0.839  1.0
  O  O27  1  0.842  0.152  0.097  1.0
[/CIF]
.