The material structure described by Li10V3Cr3Mn2O16 crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(14), one O(15), and one O(8) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Cr(3)O6 octahedra, corners with three equivalent Li(7)O6 octahedra, corners with three equivalent Mn(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-63°. In the second Li site, Li(2) is bonded to one O(1), one O(16), one O(3), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Cr(1)O6 octahedra, corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Mn(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and  an edgeedge with one Cr(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-63°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(13), one O(3), one O(6), and one O(9) atom to form distorted LiO6 octahedra that share corners with three equivalent Mn(2)O6 octahedra, corners with three equivalent Li(2)O4 tetrahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-12°. In the fourth Li site, Li(4) is bonded in a 5-coordinate geometry to one O(13), one O(14), one O(15), one O(4), one O(8), and one O(9) atom. In the fifth Li site, Li(5) is bonded in a 3-coordinate geometry to one O(10), one O(13), one O(15), one O(4), and one O(8) atom. In the sixth Li site, Li(6) is bonded in a 5-coordinate geometry to one O(10), one O(14), one O(15), one O(4), and one O(9) atom. In the seventh Li site, Li(7) is bonded to one O(12), one O(14), one O(2), one O(5), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and  a faceface with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 11°. In the eighth Li site, Li(8) is bonded in a 3-coordinate geometry to one O(1), one O(11), one O(16), one O(5), and one O(7) atom. In the ninth Li site, Li(9) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(16), one O(2), one O(6), and one O(7) atom. In the tenth Li site, Li(10) is bonded in a 6-coordinate geometry to one O(11), one O(16), one O(2), one O(3), one O(5), and one O(6) atom. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(16), one O(2), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and  an edgeedge with one Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 52°. In the second V site, V(2) is bonded to one O(12), one O(14), one O(16), one O(4), one O(5), and one O(7) atom to form VO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and  an edgeedge with one Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-53°. In the third V site, V(3) is bonded to one O(10), one O(11), one O(13), one O(15), one O(3), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-53°. There are three inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(12), one O(16), one O(2), one O(4), one O(5), and one O(8) atom to form CrO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and  an edgeedge with one Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-50°. In the second Cr site, Cr(2) is bonded to one O(1), one O(10), one O(11), one O(15), one O(3), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 50°. In the third Cr site, Cr(3) is bonded to one O(1), one O(11), one O(13), one O(15), one O(6), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 52°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(5), one O(6), and one O(7) atom to form distorted MnO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, corners with three equivalent Li(7)O6 octahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, and  a faceface with one Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-53°. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), one O(13), one O(14), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Cr(3)O6 octahedra, and  a faceface with one Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-53°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a 7-coordinate geometry to one Li(2), one Li(3), one Li(8), one Li(9), one Cr(2), one Cr(3), and one Mn(1) atom. In the second O site, O(2) is bonded to one Li(10), one Li(7), one Li(9), one V(1), one Cr(1), and one Mn(1) atom to form OLi3MnVCr octahedra that share edges with two equivalent O(7)Li3MnV2 octahedra, edges with two equivalent O(5)Li3MnVCr octahedra,  an edgeedge with one O(4)Li3V2Cr pentagonal pyramid, and  an edgeedge with one O(11)Li3VCr2 pentagonal pyramid. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Li(10), one Li(2), one Li(3), one V(3), one Cr(2), and one Mn(1) atom. In the fourth O site, O(4) is bonded to one Li(4), one Li(5), one Li(6), one V(1), one V(2), and one Cr(1) atom to form distorted OLi3V2Cr pentagonal pyramids that share  an edgeedge with one O(9)Li3MnCr2 octahedra,  an edgeedge with one O(7)Li3MnV2 octahedra,  an edgeedge with one O(10)Li3MnVCr octahedra,  an edgeedge with one O(13)Li3MnVCr octahedra,  an edgeedge with one O(2)Li3MnVCr octahedra, and  an edgeedge with one O(5)Li3MnVCr octahedra. In the fifth O site, O(5) is bonded to one Li(10), one Li(7), one Li(8), one V(2), one Cr(1), and one Mn(1) atom to form OLi3MnVCr octahedra that share edges with two equivalent O(7)Li3MnV2 octahedra, edges with two equivalent O(2)Li3MnVCr octahedra,  an edgeedge with one O(4)Li3V2Cr pentagonal pyramid, and  an edgeedge with one O(11)Li3VCr2 pentagonal pyramid. In the sixth O site, O(6) is bonded in a 7-coordinate geometry to one Li(10), one Li(2), one Li(3), one Li(9), one V(3), one Cr(3), and one Mn(1) atom. In the seventh O site, O(7) is bonded to one Li(7), one Li(8), one Li(9), one V(1), one V(2), and one Mn(1) atom to form OLi3MnV2 octahedra that share edges with two equivalent O(2)Li3MnVCr octahedra, edges with two equivalent O(5)Li3MnVCr octahedra,  an edgeedge with one O(4)Li3V2Cr pentagonal pyramid, and  an edgeedge with one O(11)Li3VCr2 pentagonal pyramid. In the eighth O site, O(8) is bonded in a 7-coordinate geometry to one Li(1), one Li(4), one Li(5), one Li(7), one V(1), one Cr(1), and one Mn(2) atom. In the ninth O site, O(9) is bonded to one Li(3), one Li(4), one Li(6), one Cr(2), one Cr(3), and one Mn(2) atom to form OLi3MnCr2 octahedra that share edges with two equivalent O(10)Li3MnVCr octahedra, edges with two equivalent O(13)Li3MnVCr octahedra,  an edgeedge with one O(4)Li3V2Cr pentagonal pyramid, and  an edgeedge with one O(11)Li3VCr2 pentagonal pyramid. In the tenth O site, O(10) is bonded to one Li(3), one Li(5), one Li(6), one V(3), one Cr(2), and one Mn(2) atom to form OLi3MnVCr octahedra that share edges with two equivalent O(9)Li3MnCr2 octahedra, edges with two equivalent O(13)Li3MnVCr octahedra,  an edgeedge with one O(4)Li3V2Cr pentagonal pyramid, and  an edgeedge with one O(11)Li3VCr2 pentagonal pyramid. In the eleventh O site, O(11) is bonded to one Li(10), one Li(8), one Li(9), one V(3), one Cr(2), and one Cr(3) atom to form distorted OLi3VCr2 pentagonal pyramids that share  an edgeedge with one O(9)Li3MnCr2 octahedra,  an edgeedge with one O(7)Li3MnV2 octahedra,  an edgeedge with one O(10)Li3MnVCr octahedra,  an edgeedge with one O(13)Li3MnVCr octahedra,  an edgeedge with one O(2)Li3MnVCr octahedra, and  an edgeedge with one O(5)Li3MnVCr octahedra. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one Li(1), one Li(7), one V(2), one Cr(1), and one Mn(2) atom. In the thirteenth O site, O(13) is bonded to one Li(3), one Li(4), one Li(5), one V(3), one Cr(3), and one Mn(2) atom to form OLi3MnVCr octahedra that share edges with two equivalent O(9)Li3MnCr2 octahedra, edges with two equivalent O(10)Li3MnVCr octahedra,  an edgeedge with one O(4)Li3V2Cr pentagonal pyramid, and  an edgeedge with one O(11)Li3VCr2 pentagonal pyramid. In the fourteenth O site, O(14) is bonded in a 7-coordinate geometry to one Li(1), one Li(4), one Li(6), one Li(7), one V(1), one V(2), and one Mn(2) atom. In the fifteenth O site, O(15) is bonded in a 7-coordinate geometry to one Li(1), one Li(4), one Li(5), one Li(6), one V(3), one Cr(2), and one Cr(3) atom. In the sixteenth O site, O(16) is bonded in a 7-coordinate geometry to one Li(10), one Li(2), one Li(8), one Li(9), one V(1), one V(2), and one Cr(1) atom. is represented by the CIF card [CIF]
data_Li10Mn2V3Cr3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.005
_cell_length_b   6.049
_cell_length_c   9.987
_cell_angle_alpha   90.396
_cell_angle_beta   90.208
_cell_angle_gamma   119.557
_symmetry_Int_Tables_number   1
_cell_volume   315.571
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.985  0.973  0.514  1.0
  Li  Li1  1  0.977  0.985  0.015  1.0
  Li  Li2  1  0.650  0.319  0.225  1.0
  Li  Li3  1  0.804  0.190  0.436  1.0
  Li  Li4  1  0.786  0.588  0.440  1.0
  Li  Li5  1  0.378  0.191  0.437  1.0
  Li  Li6  1  0.319  0.647  0.725  1.0
  Li  Li7  1  0.582  0.780  0.943  1.0
  Li  Li8  1  0.183  0.797  0.937  1.0
  Li  Li9  1  0.187  0.376  0.936  1.0
  Mn  Mn10  1  0.656  0.323  0.976  1.0
  Mn  Mn11  1  0.323  0.659  0.474  1.0
  V  V12  1  0.820  0.150  0.714  1.0
  V  V13  1  0.326  0.151  0.712  1.0
  V  V14  1  0.153  0.325  0.213  1.0
  Cr  Cr15  1  0.821  0.648  0.715  1.0
  Cr  Cr16  1  0.649  0.822  0.215  1.0
  Cr  Cr17  1  0.152  0.822  0.214  1.0
  O  O18  1  0.824  0.672  0.099  1.0
  O  O19  1  0.977  0.476  0.828  1.0
  O  O20  1  0.824  0.147  0.102  1.0
  O  O21  1  0.652  0.323  0.596  1.0
  O  O22  1  0.497  0.483  0.830  1.0
  O  O23  1  0.298  0.146  0.099  1.0
  O  O24  1  0.497  0.998  0.829  1.0
  O  O25  1  0.670  0.824  0.601  1.0
  O  O26  1  0.479  0.978  0.330  1.0
  O  O27  1  0.480  0.496  0.327  1.0
  O  O28  1  0.321  0.663  0.097  1.0
  O  O29  1  0.142  0.815  0.601  1.0
  O  O30  1  0.999  0.497  0.327  1.0
  O  O31  1  0.141  0.293  0.596  1.0
  O  O32  1  0.982  0.983  0.327  1.0
  O  O33  1  0.995  0.980  0.827  1.0
[/CIF]
.
The material structure described by Li10V3Cr3Mn2O16 crystallizes in the triclinic P1 space group. There are ten inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(14), one O(15), and one O(8) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Cr(2)O6 octahedra,  a cornercorner with one Cr(3)O6 octahedra, corners with three equivalent Li(7)O6 octahedra, corners with three equivalent Mn(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-63°. In the second Li site, Li(2) is bonded to one O(1), one O(16), one O(3), and one O(6) atom to form distorted LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Cr(1)O6 octahedra, corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Mn(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra, and  an edgeedge with one Cr(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-63°. In the third Li site, Li(3) is bonded to one O(1), one O(10), one O(13), one O(3), one O(6), and one O(9) atom to form distorted LiO6 octahedra that share corners with three equivalent Mn(2)O6 octahedra, corners with three equivalent Li(2)O4 tetrahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and  a faceface with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-12°. In the fourth Li site, Li(4) is bonded in a 5-coordinate geometry to one O(13), one O(14), one O(15), one O(4), one O(8), and one O(9) atom. In the fifth Li site, Li(5) is bonded in a 3-coordinate geometry to one O(10), one O(13), one O(15), one O(4), and one O(8) atom. In the sixth Li site, Li(6) is bonded in a 5-coordinate geometry to one O(10), one O(14), one O(15), one O(4), and one O(9) atom. In the seventh Li site, Li(7) is bonded to one O(12), one O(14), one O(2), one O(5), one O(7), and one O(8) atom to form LiO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and  a faceface with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 11°. In the eighth Li site, Li(8) is bonded in a 3-coordinate geometry to one O(1), one O(11), one O(16), one O(5), and one O(7) atom. In the ninth Li site, Li(9) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(16), one O(2), one O(6), and one O(7) atom. In the tenth Li site, Li(10) is bonded in a 6-coordinate geometry to one O(11), one O(16), one O(2), one O(3), one O(5), and one O(6) atom. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(14), one O(16), one O(2), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent V(2)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and  an edgeedge with one Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 52°. In the second V site, V(2) is bonded to one O(12), one O(14), one O(16), one O(4), one O(5), and one O(7) atom to form VO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and  an edgeedge with one Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-53°. In the third V site, V(3) is bonded to one O(10), one O(11), one O(13), one O(15), one O(3), and one O(6) atom to form VO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-53°. There are three inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(12), one O(16), one O(2), one O(4), one O(5), and one O(8) atom to form CrO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Li(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, edges with two equivalent Li(7)O6 octahedra, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and  an edgeedge with one Li(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-50°. In the second Cr site, Cr(2) is bonded to one O(1), one O(10), one O(11), one O(15), one O(3), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Cr(3)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 50°. In the third Cr site, Cr(3) is bonded to one O(1), one O(11), one O(13), one O(15), one O(6), and one O(9) atom to form CrO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Li(1)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(3)O6 octahedra, edges with two equivalent Cr(2)O6 octahedra, and  an edgeedge with one Li(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 52°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(5), one O(6), and one O(7) atom to form distorted MnO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with two equivalent Cr(2)O6 octahedra, corners with two equivalent Cr(3)O6 octahedra, corners with three equivalent Li(7)O6 octahedra, corners with three equivalent Li(2)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Cr(1)O6 octahedra, and  a faceface with one Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-53°. In the second Mn site, Mn(2) is bonded to one O(10), one O(12), one O(13), one O(14), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, corners with three equivalent Li(3)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Cr(2)O6 octahedra,  an edgeedge with one Cr(3)O6 octahedra, and  a faceface with one Li(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 10-53°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a 7-coordinate geometry to one Li(2), one Li(3), one Li(8), one Li(9), one Cr(2), one Cr(3), and one Mn(1) atom. In the second O site, O(2) is bonded to one Li(10), one Li(7), one Li(9), one V(1), one Cr(1), and one Mn(1) atom to form OLi3MnVCr octahedra that share edges with two equivalent O(7)Li3MnV2 octahedra, edges with two equivalent O(5)Li3MnVCr octahedra,  an edgeedge with one O(4)Li3V2Cr pentagonal pyramid, and  an edgeedge with one O(11)Li3VCr2 pentagonal pyramid. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Li(10), one Li(2), one Li(3), one V(3), one Cr(2), and one Mn(1) atom. In the fourth O site, O(4) is bonded to one Li(4), one Li(5), one Li(6), one V(1), one V(2), and one Cr(1) atom to form distorted OLi3V2Cr pentagonal pyramids that share  an edgeedge with one O(9)Li3MnCr2 octahedra,  an edgeedge with one O(7)Li3MnV2 octahedra,  an edgeedge with one O(10)Li3MnVCr octahedra,  an edgeedge with one O(13)Li3MnVCr octahedra,  an edgeedge with one O(2)Li3MnVCr octahedra, and  an edgeedge with one O(5)Li3MnVCr octahedra. In the fifth O site, O(5) is bonded to one Li(10), one Li(7), one Li(8), one V(2), one Cr(1), and one Mn(1) atom to form OLi3MnVCr octahedra that share edges with two equivalent O(7)Li3MnV2 octahedra, edges with two equivalent O(2)Li3MnVCr octahedra,  an edgeedge with one O(4)Li3V2Cr pentagonal pyramid, and  an edgeedge with one O(11)Li3VCr2 pentagonal pyramid. In the sixth O site, O(6) is bonded in a 7-coordinate geometry to one Li(10), one Li(2), one Li(3), one Li(9), one V(3), one Cr(3), and one Mn(1) atom. In the seventh O site, O(7) is bonded to one Li(7), one Li(8), one Li(9), one V(1), one V(2), and one Mn(1) atom to form OLi3MnV2 octahedra that share edges with two equivalent O(2)Li3MnVCr octahedra, edges with two equivalent O(5)Li3MnVCr octahedra,  an edgeedge with one O(4)Li3V2Cr pentagonal pyramid, and  an edgeedge with one O(11)Li3VCr2 pentagonal pyramid. In the eighth O site, O(8) is bonded in a 7-coordinate geometry to one Li(1), one Li(4), one Li(5), one Li(7), one V(1), one Cr(1), and one Mn(2) atom. In the ninth O site, O(9) is bonded to one Li(3), one Li(4), one Li(6), one Cr(2), one Cr(3), and one Mn(2) atom to form OLi3MnCr2 octahedra that share edges with two equivalent O(10)Li3MnVCr octahedra, edges with two equivalent O(13)Li3MnVCr octahedra,  an edgeedge with one O(4)Li3V2Cr pentagonal pyramid, and  an edgeedge with one O(11)Li3VCr2 pentagonal pyramid. In the tenth O site, O(10) is bonded to one Li(3), one Li(5), one Li(6), one V(3), one Cr(2), and one Mn(2) atom to form OLi3MnVCr octahedra that share edges with two equivalent O(9)Li3MnCr2 octahedra, edges with two equivalent O(13)Li3MnVCr octahedra,  an edgeedge with one O(4)Li3V2Cr pentagonal pyramid, and  an edgeedge with one O(11)Li3VCr2 pentagonal pyramid. In the eleventh O site, O(11) is bonded to one Li(10), one Li(8), one Li(9), one V(3), one Cr(2), and one Cr(3) atom to form distorted OLi3VCr2 pentagonal pyramids that share  an edgeedge with one O(9)Li3MnCr2 octahedra,  an edgeedge with one O(7)Li3MnV2 octahedra,  an edgeedge with one O(10)Li3MnVCr octahedra,  an edgeedge with one O(13)Li3MnVCr octahedra,  an edgeedge with one O(2)Li3MnVCr octahedra, and  an edgeedge with one O(5)Li3MnVCr octahedra. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one Li(1), one Li(7), one V(2), one Cr(1), and one Mn(2) atom. In the thirteenth O site, O(13) is bonded to one Li(3), one Li(4), one Li(5), one V(3), one Cr(3), and one Mn(2) atom to form OLi3MnVCr octahedra that share edges with two equivalent O(9)Li3MnCr2 octahedra, edges with two equivalent O(10)Li3MnVCr octahedra,  an edgeedge with one O(4)Li3V2Cr pentagonal pyramid, and  an edgeedge with one O(11)Li3VCr2 pentagonal pyramid. In the fourteenth O site, O(14) is bonded in a 7-coordinate geometry to one Li(1), one Li(4), one Li(6), one Li(7), one V(1), one V(2), and one Mn(2) atom. In the fifteenth O site, O(15) is bonded in a 7-coordinate geometry to one Li(1), one Li(4), one Li(5), one Li(6), one V(3), one Cr(2), and one Cr(3) atom. In the sixteenth O site, O(16) is bonded in a 7-coordinate geometry to one Li(10), one Li(2), one Li(8), one Li(9), one V(1), one V(2), and one Cr(1) atom. is represented by the CIF card [CIF]
data_Li10Mn2V3Cr3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.005
_cell_length_b   6.049
_cell_length_c   9.987
_cell_angle_alpha   90.396
_cell_angle_beta   90.208
_cell_angle_gamma   119.557
_symmetry_Int_Tables_number   1
_cell_volume   315.571
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.985  0.973  0.514  1.0
  Li  Li1  1  0.977  0.985  0.015  1.0
  Li  Li2  1  0.650  0.319  0.225  1.0
  Li  Li3  1  0.804  0.190  0.436  1.0
  Li  Li4  1  0.786  0.588  0.440  1.0
  Li  Li5  1  0.378  0.191  0.437  1.0
  Li  Li6  1  0.319  0.647  0.725  1.0
  Li  Li7  1  0.582  0.780  0.943  1.0
  Li  Li8  1  0.183  0.797  0.937  1.0
  Li  Li9  1  0.187  0.376  0.936  1.0
  Mn  Mn10  1  0.656  0.323  0.976  1.0
  Mn  Mn11  1  0.323  0.659  0.474  1.0
  V  V12  1  0.820  0.150  0.714  1.0
  V  V13  1  0.326  0.151  0.712  1.0
  V  V14  1  0.153  0.325  0.213  1.0
  Cr  Cr15  1  0.821  0.648  0.715  1.0
  Cr  Cr16  1  0.649  0.822  0.215  1.0
  Cr  Cr17  1  0.152  0.822  0.214  1.0
  O  O18  1  0.824  0.672  0.099  1.0
  O  O19  1  0.977  0.476  0.828  1.0
  O  O20  1  0.824  0.147  0.102  1.0
  O  O21  1  0.652  0.323  0.596  1.0
  O  O22  1  0.497  0.483  0.830  1.0
  O  O23  1  0.298  0.146  0.099  1.0
  O  O24  1  0.497  0.998  0.829  1.0
  O  O25  1  0.670  0.824  0.601  1.0
  O  O26  1  0.479  0.978  0.330  1.0
  O  O27  1  0.480  0.496  0.327  1.0
  O  O28  1  0.321  0.663  0.097  1.0
  O  O29  1  0.142  0.815  0.601  1.0
  O  O30  1  0.999  0.497  0.327  1.0
  O  O31  1  0.141  0.293  0.596  1.0
  O  O32  1  0.982  0.983  0.327  1.0
  O  O33  1  0.995  0.980  0.827  1.0
[/CIF]
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