The material structure described by Ag4(NSO2N) crystallizes in the orthorhombic Pna2_1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one N(1) and one N(2) atom. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one N(1) and one N(2) atom. In the third Ag site, Ag(3) is bonded in a distorted linear geometry to one N(1) and one N(2) atom. In the fourth Ag site, Ag(4) is bonded in a linear geometry to one N(1) and one O(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded to one Ag(1), one Ag(2), one Ag(3), one Ag(4), and one S(1) atom to form distorted corner-sharing NAg4S trigonal bipyramids. In the second N site, N(2) is bonded to one Ag(1), one Ag(2), one Ag(3), and one S(1) atom to form corner-sharing NAg3S tetrahedra. S(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ag(4) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_Ag4S(NO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.874
_cell_length_b   9.198
_cell_length_c   10.522
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   568.471
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.425  0.539  0.860  1.0
  Ag  Ag1  1  0.925  0.039  0.640  1.0
  Ag  Ag2  1  0.200  0.774  0.554  1.0
  Ag  Ag3  1  0.405  0.063  0.399  1.0
  Ag  Ag4  1  0.522  0.216  0.693  1.0
  Ag  Ag5  1  0.300  0.774  0.054  1.0
  Ag  Ag6  1  0.575  0.039  0.140  1.0
  Ag  Ag7  1  0.075  0.539  0.360  1.0
  Ag  Ag8  1  0.700  0.274  0.946  1.0
  Ag  Ag9  1  0.978  0.216  0.193  1.0
  Ag  Ag10  1  0.595  0.563  0.601  1.0
  Ag  Ag11  1  0.800  0.274  0.446  1.0
  Ag  Ag12  1  0.905  0.563  0.101  1.0
  Ag  Ag13  1  0.478  0.716  0.307  1.0
  Ag  Ag14  1  0.022  0.716  0.807  1.0
  Ag  Ag15  1  0.095  0.063  0.899  1.0
  S  S16  1  0.902  0.937  0.359  1.0
  S  S17  1  0.402  0.437  0.141  1.0
  S  S18  1  0.098  0.437  0.641  1.0
  S  S19  1  0.598  0.937  0.859  1.0
  N  N20  1  0.754  0.085  0.319  1.0
  N  N21  1  0.246  0.585  0.681  1.0
  N  N22  1  0.746  0.085  0.819  1.0
  N  N23  1  0.914  0.477  0.535  1.0
  N  N24  1  0.254  0.585  0.181  1.0
  N  N25  1  0.414  0.977  0.965  1.0
  N  N26  1  0.086  0.977  0.465  1.0
  N  N27  1  0.586  0.477  0.035  1.0
  O  O28  1  0.736  0.831  0.419  1.0
  O  O29  1  0.504  0.378  0.258  1.0
  O  O30  1  0.496  0.878  0.742  1.0
  O  O31  1  0.004  0.878  0.242  1.0
  O  O32  1  0.236  0.331  0.081  1.0
  O  O33  1  0.764  0.831  0.919  1.0
  O  O34  1  0.996  0.378  0.758  1.0
  O  O35  1  0.264  0.331  0.581  1.0
[/CIF]
.
The material structure described by Ag4(NSO2N) crystallizes in the orthorhombic Pna2_1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one N(1) and one N(2) atom. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one N(1) and one N(2) atom. In the third Ag site, Ag(3) is bonded in a distorted linear geometry to one N(1) and one N(2) atom. In the fourth Ag site, Ag(4) is bonded in a linear geometry to one N(1) and one O(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded to one Ag(1), one Ag(2), one Ag(3), one Ag(4), and one S(1) atom to form distorted corner-sharing NAg4S trigonal bipyramids. In the second N site, N(2) is bonded to one Ag(1), one Ag(2), one Ag(3), and one S(1) atom to form corner-sharing NAg3S tetrahedra. S(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ag(4) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_Ag4S(NO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.874
_cell_length_b   9.198
_cell_length_c   10.522
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   568.471
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.425  0.539  0.860  1.0
  Ag  Ag1  1  0.925  0.039  0.640  1.0
  Ag  Ag2  1  0.200  0.774  0.554  1.0
  Ag  Ag3  1  0.405  0.063  0.399  1.0
  Ag  Ag4  1  0.522  0.216  0.693  1.0
  Ag  Ag5  1  0.300  0.774  0.054  1.0
  Ag  Ag6  1  0.575  0.039  0.140  1.0
  Ag  Ag7  1  0.075  0.539  0.360  1.0
  Ag  Ag8  1  0.700  0.274  0.946  1.0
  Ag  Ag9  1  0.978  0.216  0.193  1.0
  Ag  Ag10  1  0.595  0.563  0.601  1.0
  Ag  Ag11  1  0.800  0.274  0.446  1.0
  Ag  Ag12  1  0.905  0.563  0.101  1.0
  Ag  Ag13  1  0.478  0.716  0.307  1.0
  Ag  Ag14  1  0.022  0.716  0.807  1.0
  Ag  Ag15  1  0.095  0.063  0.899  1.0
  S  S16  1  0.902  0.937  0.359  1.0
  S  S17  1  0.402  0.437  0.141  1.0
  S  S18  1  0.098  0.437  0.641  1.0
  S  S19  1  0.598  0.937  0.859  1.0
  N  N20  1  0.754  0.085  0.319  1.0
  N  N21  1  0.246  0.585  0.681  1.0
  N  N22  1  0.746  0.085  0.819  1.0
  N  N23  1  0.914  0.477  0.535  1.0
  N  N24  1  0.254  0.585  0.181  1.0
  N  N25  1  0.414  0.977  0.965  1.0
  N  N26  1  0.086  0.977  0.465  1.0
  N  N27  1  0.586  0.477  0.035  1.0
  O  O28  1  0.736  0.831  0.419  1.0
  O  O29  1  0.504  0.378  0.258  1.0
  O  O30  1  0.496  0.878  0.742  1.0
  O  O31  1  0.004  0.878  0.242  1.0
  O  O32  1  0.236  0.331  0.081  1.0
  O  O33  1  0.764  0.831  0.919  1.0
  O  O34  1  0.996  0.378  0.758  1.0
  O  O35  1  0.264  0.331  0.581  1.0
[/CIF]
.