The crystal structure described by CuZn3InS5 is Stannite-like structured and crystallizes in the triclinic P1 space group. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one S(1), one S(6), one S(7), and one S(8) atom to form CuS4 tetrahedra that share  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent In(1)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. In the second Cu site, Cu(2) is bonded to one S(2), one S(3), one S(4), and one S(9) atom to form CuS4 tetrahedra that share  a cornercorner with one Zn(4)S4 tetrahedra,  a cornercorner with one In(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent In(1)S4 tetrahedra. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one S(10), one S(3), one S(8), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Zn(3)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent In(1)S4 tetrahedra. In the second Zn site, Zn(2) is bonded to one S(10), one S(4), one S(6), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one In(1)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. In the third Zn site, Zn(3) is bonded to one S(10), one S(5), one S(6), and one S(7) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one In(1)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. In the fourth Zn site, Zn(4) is bonded to one S(1), one S(2), one S(5), and one S(7) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Zn(6)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent In(1)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. In the fifth Zn site, Zn(5) is bonded to one S(1), one S(2), one S(3), and one S(8) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(6)S4 tetrahedra,  a cornercorner with one In(2)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent In(1)S4 tetrahedra. In the sixth Zn site, Zn(6) is bonded to one S(10), one S(3), one S(4), and one S(5) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(4)S4 tetrahedra,  a cornercorner with one Zn(5)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. There are two inequivalent In sites. In the first In site, In(1) is bonded to one S(2), one S(7), one S(8), and one S(9) atom to form InS4 tetrahedra that share  a cornercorner with one Zn(2)S4 tetrahedra,  a cornercorner with one Zn(3)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent Zn(5)S4 tetrahedra. In the second In site, In(2) is bonded to one S(1), one S(4), one S(5), and one S(6) atom to form InS4 tetrahedra that share  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Zn(5)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent Zn(6)S4 tetrahedra. There are ten inequivalent S sites. In the first S site, S(1) is bonded to one Cu(1), one Zn(4), one Zn(5), and one In(2) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(4)Zn2InCu tetrahedra,  a cornercorner with one S(3)Zn3Cu tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, and corners with two equivalent S(5)Zn3In tetrahedra. In the second S site, S(2) is bonded to one Cu(2), one Zn(4), one Zn(5), and one In(1) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(4)Zn2InCu tetrahedra,  a cornercorner with one S(5)Zn3In tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, and corners with two equivalent S(3)Zn3Cu tetrahedra. In the third S site, S(3) is bonded to one Cu(2), one Zn(1), one Zn(5), and one Zn(6) atom to form SZn3Cu tetrahedra that share  a cornercorner with one S(1)Zn2InCu tetrahedra,  a cornercorner with one S(5)Zn3In tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the fourth S site, S(4) is bonded to one Cu(2), one Zn(2), one Zn(6), and one In(2) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(1)Zn2InCu tetrahedra,  a cornercorner with one S(2)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, corners with two equivalent S(3)Zn3Cu tetrahedra, corners with two equivalent S(5)Zn3In tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the fifth S site, S(5) is bonded to one Zn(3), one Zn(4), one Zn(6), and one In(2) atom to form SZn3In tetrahedra that share  a cornercorner with one S(2)Zn2InCu tetrahedra,  a cornercorner with one S(3)Zn3Cu tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the sixth S site, S(6) is bonded to one Cu(1), one Zn(2), one Zn(3), and one In(2) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(8)Zn2InCu tetrahedra,  a cornercorner with one S(9)Zn2InCu tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, corners with two equivalent S(5)Zn3In tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the seventh S site, S(7) is bonded to one Cu(1), one Zn(3), one Zn(4), and one In(1) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(9)Zn2InCu tetrahedra,  a cornercorner with one S(10)Zn4 tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, and corners with two equivalent S(5)Zn3In tetrahedra. In the eighth S site, S(8) is bonded to one Cu(1), one Zn(1), one Zn(5), and one In(1) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(6)Zn2InCu tetrahedra,  a cornercorner with one S(10)Zn4 tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, and corners with two equivalent S(3)Zn3Cu tetrahedra. In the ninth S site, S(9) is bonded to one Cu(2), one Zn(1), one Zn(2), and one In(1) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(6)Zn2InCu tetrahedra,  a cornercorner with one S(7)Zn2InCu tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, corners with two equivalent S(3)Zn3Cu tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the tenth S site, S(10) is bonded to one Zn(1), one Zn(2), one Zn(3), and one Zn(6) atom to form SZn4 tetrahedra that share  a cornercorner with one S(7)Zn2InCu tetrahedra,  a cornercorner with one S(8)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, corners with two equivalent S(3)Zn3Cu tetrahedra, and corners with two equivalent S(5)Zn3In tetrahedra. is represented by the CIF card [CIF]
data_Zn3InCuS5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.365
_cell_length_b   6.719
_cell_length_c   10.263
_cell_angle_alpha   70.917
_cell_angle_beta   89.995
_cell_angle_gamma   90.006
_symmetry_Int_Tables_number   1
_cell_volume   414.800
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.493  0.131  0.401  1.0
  Zn  Zn1  1  0.500  0.536  0.599  1.0
  Zn  Zn2  1  0.506  0.933  0.798  1.0
  Zn  Zn3  1  0.998  0.664  0.003  1.0
  Zn  Zn4  1  0.001  0.067  0.205  1.0
  Zn  Zn5  1  0.999  0.871  0.593  1.0
  In  In6  1  0.500  0.734  0.201  1.0
  In  In7  1  0.998  0.271  0.800  1.0
  Cu  Cu8  1  0.499  0.333  0.000  1.0
  Cu  Cu9  1  0.000  0.463  0.400  1.0
  S  S10  1  0.135  0.336  0.009  1.0
  S  S11  1  0.107  0.731  0.202  1.0
  S  S12  1  0.125  0.136  0.400  1.0
  S  S13  1  0.129  0.544  0.589  1.0
  S  S14  1  0.131  0.919  0.800  1.0
  S  S15  1  0.606  0.267  0.802  1.0
  S  S16  1  0.629  0.661  0.991  1.0
  S  S17  1  0.629  0.085  0.198  1.0
  S  S18  1  0.635  0.454  0.409  1.0
  S  S19  1  0.627  0.865  0.600  1.0
[/CIF]
.
The crystal structure described by CuZn3InS5 is Stannite-like structured and crystallizes in the triclinic P1 space group. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one S(1), one S(6), one S(7), and one S(8) atom to form CuS4 tetrahedra that share  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent In(1)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. In the second Cu site, Cu(2) is bonded to one S(2), one S(3), one S(4), and one S(9) atom to form CuS4 tetrahedra that share  a cornercorner with one Zn(4)S4 tetrahedra,  a cornercorner with one In(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent In(1)S4 tetrahedra. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one S(10), one S(3), one S(8), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one Zn(3)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent In(1)S4 tetrahedra. In the second Zn site, Zn(2) is bonded to one S(10), one S(4), one S(6), and one S(9) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(1)S4 tetrahedra,  a cornercorner with one In(1)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. In the third Zn site, Zn(3) is bonded to one S(10), one S(5), one S(6), and one S(7) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(1)S4 tetrahedra,  a cornercorner with one In(1)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, corners with two equivalent Zn(6)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. In the fourth Zn site, Zn(4) is bonded to one S(1), one S(2), one S(5), and one S(7) atom to form ZnS4 tetrahedra that share  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Zn(6)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(5)S4 tetrahedra, corners with two equivalent In(1)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. In the fifth Zn site, Zn(5) is bonded to one S(1), one S(2), one S(3), and one S(8) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(6)S4 tetrahedra,  a cornercorner with one In(2)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent In(1)S4 tetrahedra. In the sixth Zn site, Zn(6) is bonded to one S(10), one S(3), one S(4), and one S(5) atom to form ZnS4 tetrahedra that share  a cornercorner with one Zn(4)S4 tetrahedra,  a cornercorner with one Zn(5)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, and corners with two equivalent In(2)S4 tetrahedra. There are two inequivalent In sites. In the first In site, In(1) is bonded to one S(2), one S(7), one S(8), and one S(9) atom to form InS4 tetrahedra that share  a cornercorner with one Zn(2)S4 tetrahedra,  a cornercorner with one Zn(3)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Cu(2)S4 tetrahedra, corners with two equivalent Zn(1)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent Zn(5)S4 tetrahedra. In the second In site, In(2) is bonded to one S(1), one S(4), one S(5), and one S(6) atom to form InS4 tetrahedra that share  a cornercorner with one Cu(2)S4 tetrahedra,  a cornercorner with one Zn(5)S4 tetrahedra, corners with two equivalent Cu(1)S4 tetrahedra, corners with two equivalent Zn(2)S4 tetrahedra, corners with two equivalent Zn(3)S4 tetrahedra, corners with two equivalent Zn(4)S4 tetrahedra, and corners with two equivalent Zn(6)S4 tetrahedra. There are ten inequivalent S sites. In the first S site, S(1) is bonded to one Cu(1), one Zn(4), one Zn(5), and one In(2) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(4)Zn2InCu tetrahedra,  a cornercorner with one S(3)Zn3Cu tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, and corners with two equivalent S(5)Zn3In tetrahedra. In the second S site, S(2) is bonded to one Cu(2), one Zn(4), one Zn(5), and one In(1) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(4)Zn2InCu tetrahedra,  a cornercorner with one S(5)Zn3In tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, and corners with two equivalent S(3)Zn3Cu tetrahedra. In the third S site, S(3) is bonded to one Cu(2), one Zn(1), one Zn(5), and one Zn(6) atom to form SZn3Cu tetrahedra that share  a cornercorner with one S(1)Zn2InCu tetrahedra,  a cornercorner with one S(5)Zn3In tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the fourth S site, S(4) is bonded to one Cu(2), one Zn(2), one Zn(6), and one In(2) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(1)Zn2InCu tetrahedra,  a cornercorner with one S(2)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, corners with two equivalent S(3)Zn3Cu tetrahedra, corners with two equivalent S(5)Zn3In tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the fifth S site, S(5) is bonded to one Zn(3), one Zn(4), one Zn(6), and one In(2) atom to form SZn3In tetrahedra that share  a cornercorner with one S(2)Zn2InCu tetrahedra,  a cornercorner with one S(3)Zn3Cu tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the sixth S site, S(6) is bonded to one Cu(1), one Zn(2), one Zn(3), and one In(2) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(8)Zn2InCu tetrahedra,  a cornercorner with one S(9)Zn2InCu tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, corners with two equivalent S(5)Zn3In tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the seventh S site, S(7) is bonded to one Cu(1), one Zn(3), one Zn(4), and one In(1) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(9)Zn2InCu tetrahedra,  a cornercorner with one S(10)Zn4 tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, and corners with two equivalent S(5)Zn3In tetrahedra. In the eighth S site, S(8) is bonded to one Cu(1), one Zn(1), one Zn(5), and one In(1) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(6)Zn2InCu tetrahedra,  a cornercorner with one S(10)Zn4 tetrahedra, corners with two equivalent S(1)Zn2InCu tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(7)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, and corners with two equivalent S(3)Zn3Cu tetrahedra. In the ninth S site, S(9) is bonded to one Cu(2), one Zn(1), one Zn(2), and one In(1) atom to form SZn2InCu tetrahedra that share  a cornercorner with one S(6)Zn2InCu tetrahedra,  a cornercorner with one S(7)Zn2InCu tetrahedra, corners with two equivalent S(2)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(8)Zn2InCu tetrahedra, corners with two equivalent S(3)Zn3Cu tetrahedra, and corners with two equivalent S(10)Zn4 tetrahedra. In the tenth S site, S(10) is bonded to one Zn(1), one Zn(2), one Zn(3), and one Zn(6) atom to form SZn4 tetrahedra that share  a cornercorner with one S(7)Zn2InCu tetrahedra,  a cornercorner with one S(8)Zn2InCu tetrahedra, corners with two equivalent S(4)Zn2InCu tetrahedra, corners with two equivalent S(6)Zn2InCu tetrahedra, corners with two equivalent S(9)Zn2InCu tetrahedra, corners with two equivalent S(3)Zn3Cu tetrahedra, and corners with two equivalent S(5)Zn3In tetrahedra. is represented by the CIF card [CIF]
data_Zn3InCuS5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.365
_cell_length_b   6.719
_cell_length_c   10.263
_cell_angle_alpha   70.917
_cell_angle_beta   89.995
_cell_angle_gamma   90.006
_symmetry_Int_Tables_number   1
_cell_volume   414.800
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.493  0.131  0.401  1.0
  Zn  Zn1  1  0.500  0.536  0.599  1.0
  Zn  Zn2  1  0.506  0.933  0.798  1.0
  Zn  Zn3  1  0.998  0.664  0.003  1.0
  Zn  Zn4  1  0.001  0.067  0.205  1.0
  Zn  Zn5  1  0.999  0.871  0.593  1.0
  In  In6  1  0.500  0.734  0.201  1.0
  In  In7  1  0.998  0.271  0.800  1.0
  Cu  Cu8  1  0.499  0.333  0.000  1.0
  Cu  Cu9  1  0.000  0.463  0.400  1.0
  S  S10  1  0.135  0.336  0.009  1.0
  S  S11  1  0.107  0.731  0.202  1.0
  S  S12  1  0.125  0.136  0.400  1.0
  S  S13  1  0.129  0.544  0.589  1.0
  S  S14  1  0.131  0.919  0.800  1.0
  S  S15  1  0.606  0.267  0.802  1.0
  S  S16  1  0.629  0.661  0.991  1.0
  S  S17  1  0.629  0.085  0.198  1.0
  S  S18  1  0.635  0.454  0.409  1.0
  S  S19  1  0.627  0.865  0.600  1.0
[/CIF]
.