The material structure described by PtH6(NO)4 is beta Polonium structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two PtH6(NO)4 clusters. Pt(1) is bonded in a square co-planar geometry to one N(1), one N(2), and two equivalent N(3) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Pt(1) and two equivalent O(1) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one Pt(1) and two equivalent O(2) atoms. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF file [CIF]
data_H6Pt(NO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.000
_cell_length_b   6.244
_cell_length_c   6.244
_cell_angle_alpha   98.743
_cell_angle_beta   99.055
_cell_angle_gamma   99.055
_symmetry_Int_Tables_number   1
_cell_volume   186.950
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.375  0.188  0.334  1.0
  H  H1  1  0.625  0.666  0.812  1.0
  H  H2  1  0.413  0.991  0.486  1.0
  H  H3  1  0.587  0.514  0.009  1.0
  H  H4  1  0.173  0.142  0.516  1.0
  H  H5  1  0.827  0.484  0.858  1.0
  Pt  Pt6  1  0.000  0.835  0.165  1.0
  N  N7  1  0.000  0.050  0.950  1.0
  N  N8  1  0.000  0.621  0.379  1.0
  N  N9  1  0.274  0.068  0.403  1.0
  N  N10  1  0.726  0.597  0.932  1.0
  O  O11  1  0.189  0.216  0.984  1.0
  O  O12  1  0.811  0.016  0.784  1.0
  O  O13  1  0.205  0.642  0.530  1.0
  O  O14  1  0.795  0.470  0.358  1.0
[/CIF]
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The material structure described by PtH6(NO)4 is beta Polonium structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of two PtH6(NO)4 clusters. Pt(1) is bonded in a square co-planar geometry to one N(1), one N(2), and two equivalent N(3) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Pt(1) and two equivalent O(1) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one Pt(1) and two equivalent O(2) atoms. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF file [CIF]
data_H6Pt(NO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.000
_cell_length_b   6.244
_cell_length_c   6.244
_cell_angle_alpha   98.743
_cell_angle_beta   99.055
_cell_angle_gamma   99.055
_symmetry_Int_Tables_number   1
_cell_volume   186.950
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.375  0.188  0.334  1.0
  H  H1  1  0.625  0.666  0.812  1.0
  H  H2  1  0.413  0.991  0.486  1.0
  H  H3  1  0.587  0.514  0.009  1.0
  H  H4  1  0.173  0.142  0.516  1.0
  H  H5  1  0.827  0.484  0.858  1.0
  Pt  Pt6  1  0.000  0.835  0.165  1.0
  N  N7  1  0.000  0.050  0.950  1.0
  N  N8  1  0.000  0.621  0.379  1.0
  N  N9  1  0.274  0.068  0.403  1.0
  N  N10  1  0.726  0.597  0.932  1.0
  O  O11  1  0.189  0.216  0.984  1.0
  O  O12  1  0.811  0.016  0.784  1.0
  O  O13  1  0.205  0.642  0.530  1.0
  O  O14  1  0.795  0.470  0.358  1.0
[/CIF]
.