The compound described by WCoZn2O6 crystallizes in the trigonal R3 space group. W(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form WO6 octahedra that share corners with six equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 41°. Co(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form CoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 41°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. In the second Zn site, Zn(2) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to one W(1), one Co(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted corner and edge-sharing OZn2CoW tetrahedra. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one W(1), one Co(1), and one Zn(1) atom. is represented by the CIF file [CIF]
data_Zn2CoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.259
_cell_length_b   5.260
_cell_length_c   5.575
_cell_angle_alpha   90.007
_cell_angle_beta   118.116
_cell_angle_gamma   119.993
_symmetry_Int_Tables_number   1
_cell_volume   112.042
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.998  0.499  0.483  1.0
  O  O1  1  0.515  0.890  0.712  1.0
  O  O2  1  0.465  0.096  0.206  1.0
  O  O3  1  0.851  0.754  0.206  1.0
  O  O4  1  0.124  0.369  0.206  1.0
  O  O5  1  0.836  0.623  0.712  1.0
  O  O6  1  0.101  0.210  0.711  1.0
  W  W7  1  0.003  0.001  0.989  1.0
  Zn  Zn8  1  0.575  0.787  0.347  1.0
  Zn  Zn9  1  0.497  0.248  0.732  1.0
[/CIF]
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The compound described by WCoZn2O6 crystallizes in the trigonal R3 space group. W(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form WO6 octahedra that share corners with six equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles are 41°. Co(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form CoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles are 41°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to three equivalent O(1) and three equivalent O(2) atoms. In the second Zn site, Zn(2) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to one W(1), one Co(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted corner and edge-sharing OZn2CoW tetrahedra. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one W(1), one Co(1), and one Zn(1) atom. is represented by the CIF file [CIF]
data_Zn2CoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.259
_cell_length_b   5.260
_cell_length_c   5.575
_cell_angle_alpha   90.007
_cell_angle_beta   118.116
_cell_angle_gamma   119.993
_symmetry_Int_Tables_number   1
_cell_volume   112.042
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.998  0.499  0.483  1.0
  O  O1  1  0.515  0.890  0.712  1.0
  O  O2  1  0.465  0.096  0.206  1.0
  O  O3  1  0.851  0.754  0.206  1.0
  O  O4  1  0.124  0.369  0.206  1.0
  O  O5  1  0.836  0.623  0.712  1.0
  O  O6  1  0.101  0.210  0.711  1.0
  W  W7  1  0.003  0.001  0.989  1.0
  Zn  Zn8  1  0.575  0.787  0.347  1.0
  Zn  Zn9  1  0.497  0.248  0.732  1.0
[/CIF]
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