The material structure described by BaTbEuBiO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P-1 space group. Ba(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(5), one O(6), two equivalent O(1), and two equivalent O(4) atoms. There are two inequivalent Tb sites. In the first Tb site, Tb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form TbO6 octahedra that share corners with two equivalent Bi(2)O6 octahedra and corners with four equivalent Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-33°. In the second Tb site, Tb(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form TbO6 octahedra that share corners with two equivalent Bi(1)O6 octahedra and corners with four equivalent Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-34°. Eu(1) is bonded in a 8-coordinate geometry to one O(1), one O(4), one O(5), one O(6), two equivalent O(2), and two equivalent O(3) atoms. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form BiO6 octahedra that share corners with two equivalent Tb(2)O6 octahedra and corners with four equivalent Tb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-34°. In the second Bi site, Bi(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form BiO6 octahedra that share corners with two equivalent Tb(1)O6 octahedra and corners with four equivalent Tb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-33°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Tb(1), one Eu(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Ba(1), one Tb(2), two equivalent Eu(1), and one Bi(2) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Ba(1), one Tb(1), two equivalent Eu(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Tb(2), one Eu(1), and one Bi(2) atom. In the fifth O site, O(5) is bonded to one Ba(1), one Tb(1), one Eu(1), and one Bi(2) atom to form distorted corner-sharing OBaTbEuBi tetrahedra. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Ba(1), one Tb(2), one Eu(1), and one Bi(1) atom. is represented by the CIF file [CIF]
data_BaTbEuBiO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.100
_cell_length_b   6.219
_cell_length_c   8.708
_cell_angle_alpha   90.072
_cell_angle_beta   89.927
_cell_angle_gamma   89.807
_symmetry_Int_Tables_number   1
_cell_volume   330.341
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.991  0.036  0.250  1.0
  Ba  Ba1  1  0.009  0.964  0.750  1.0
  Tb  Tb2  1  0.500  0.000  0.000  1.0
  Tb  Tb3  1  0.000  0.500  0.500  1.0
  Eu  Eu4  1  0.511  0.547  0.251  1.0
  Eu  Eu5  1  0.489  0.453  0.749  1.0
  Bi  Bi6  1  0.000  0.500  0.000  1.0
  Bi  Bi7  1  0.500  0.000  0.500  1.0
  O  O8  1  0.209  0.221  0.953  1.0
  O  O9  1  0.309  0.702  0.553  1.0
  O  O10  1  0.791  0.779  0.047  1.0
  O  O11  1  0.691  0.298  0.447  1.0
  O  O12  1  0.295  0.694  0.945  1.0
  O  O13  1  0.219  0.213  0.545  1.0
  O  O14  1  0.705  0.306  0.055  1.0
  O  O15  1  0.781  0.787  0.455  1.0
  O  O16  1  0.426  0.951  0.254  1.0
  O  O17  1  0.110  0.488  0.244  1.0
  O  O18  1  0.574  0.049  0.746  1.0
  O  O19  1  0.890  0.512  0.756  1.0
[/CIF]
.
The material structure described by BaTbEuBiO6 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P-1 space group. Ba(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(5), one O(6), two equivalent O(1), and two equivalent O(4) atoms. There are two inequivalent Tb sites. In the first Tb site, Tb(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form TbO6 octahedra that share corners with two equivalent Bi(2)O6 octahedra and corners with four equivalent Bi(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-33°. In the second Tb site, Tb(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms to form TbO6 octahedra that share corners with two equivalent Bi(1)O6 octahedra and corners with four equivalent Bi(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-34°. Eu(1) is bonded in a 8-coordinate geometry to one O(1), one O(4), one O(5), one O(6), two equivalent O(2), and two equivalent O(3) atoms. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form BiO6 octahedra that share corners with two equivalent Tb(2)O6 octahedra and corners with four equivalent Tb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-34°. In the second Bi site, Bi(2) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form BiO6 octahedra that share corners with two equivalent Tb(1)O6 octahedra and corners with four equivalent Tb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 26-33°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Tb(1), one Eu(1), and one Bi(1) atom. In the second O site, O(2) is bonded in a 5-coordinate geometry to one Ba(1), one Tb(2), two equivalent Eu(1), and one Bi(2) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Ba(1), one Tb(1), two equivalent Eu(1), and one Bi(1) atom. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to two equivalent Ba(1), one Tb(2), one Eu(1), and one Bi(2) atom. In the fifth O site, O(5) is bonded to one Ba(1), one Tb(1), one Eu(1), and one Bi(2) atom to form distorted corner-sharing OBaTbEuBi tetrahedra. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Ba(1), one Tb(2), one Eu(1), and one Bi(1) atom. is represented by the CIF file [CIF]
data_BaTbEuBiO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.100
_cell_length_b   6.219
_cell_length_c   8.708
_cell_angle_alpha   90.072
_cell_angle_beta   89.927
_cell_angle_gamma   89.807
_symmetry_Int_Tables_number   1
_cell_volume   330.341
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.991  0.036  0.250  1.0
  Ba  Ba1  1  0.009  0.964  0.750  1.0
  Tb  Tb2  1  0.500  0.000  0.000  1.0
  Tb  Tb3  1  0.000  0.500  0.500  1.0
  Eu  Eu4  1  0.511  0.547  0.251  1.0
  Eu  Eu5  1  0.489  0.453  0.749  1.0
  Bi  Bi6  1  0.000  0.500  0.000  1.0
  Bi  Bi7  1  0.500  0.000  0.500  1.0
  O  O8  1  0.209  0.221  0.953  1.0
  O  O9  1  0.309  0.702  0.553  1.0
  O  O10  1  0.791  0.779  0.047  1.0
  O  O11  1  0.691  0.298  0.447  1.0
  O  O12  1  0.295  0.694  0.945  1.0
  O  O13  1  0.219  0.213  0.545  1.0
  O  O14  1  0.705  0.306  0.055  1.0
  O  O15  1  0.781  0.787  0.455  1.0
  O  O16  1  0.426  0.951  0.254  1.0
  O  O17  1  0.110  0.488  0.244  1.0
  O  O18  1  0.574  0.049  0.746  1.0
  O  O19  1  0.890  0.512  0.756  1.0
[/CIF]
.