The compound described by (Ce2C5O14)4(O2)3 crystallizes in the triclinic P1 space group. The structure consists of one 7782-44-7 molecule and one water atom inside a Ce2C5O14 framework. In the Ce2C5O14 framework, there are four inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 9-coordinate geometry to one O(15), one O(19), one O(21), one O(24), one O(27), one O(3), one O(5), one O(7), and one O(9) atom. In the second Ce site, Ce(2) is bonded in a 9-coordinate geometry to one O(10), one O(16), one O(20), one O(22), one O(23), one O(28), one O(4), one O(6), and one O(8) atom. In the third Ce site, Ce(3) is bonded in a 10-coordinate geometry to one O(1), one O(13), one O(14), one O(17), one O(2), one O(21), one O(26), one O(27), one O(3), and one O(5) atom. In the fourth Ce site, Ce(4) is bonded in a 10-coordinate geometry to one O(1), one O(13), one O(14), one O(18), one O(2), one O(22), one O(25), one O(28), one O(4), and one O(6) atom. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(7) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(14) and one O(8) atom. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(23) and one O(9) atom. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(24) atom. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one O(1), one O(21), and one O(3) atom. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one O(2), one O(22), and one O(4) atom. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(25) and one O(27) atom. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(26) and one O(28) atom. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(17) and one O(19) atom. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(18) and one O(20) atom. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ce(3), one Ce(4), and one C(5) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ce(3), one Ce(4), and one C(6) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Ce(1), one Ce(3), and one C(5) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ce(2), one Ce(4), and one C(6) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Ce(1) and one Ce(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ce(2) and one Ce(4) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Ce(1) and one C(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Ce(2) and one C(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Ce(1) and one C(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Ce(2) and one C(4) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one O(15) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one O(16) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one Ce(3), one Ce(4), and one C(1) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Ce(3), one Ce(4), and one C(2) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one O(11) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Ce(2) and one O(12) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Ce(3) and one C(9) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Ce(4) and one C(10) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Ce(1) and one C(9) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Ce(2) and one C(10) atom. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one Ce(1), one Ce(3), and one C(5) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one Ce(2), one Ce(4), and one C(6) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Ce(2) and one C(3) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 120 degrees geometry to one Ce(1) and one C(4) atom. In the twenty-fifth O site, O(25) is bonded in a distorted bent 120 degrees geometry to one Ce(4) and one C(7) atom. In the twenty-sixth O site, O(26) is bonded in a distorted bent 120 degrees geometry to one Ce(3) and one C(8) atom. In the twenty-seventh O site, O(27) is bonded in a distorted single-bond geometry to one Ce(1), one Ce(3), and one C(7) atom. In the twenty-eighth O site, O(28) is bonded in a distorted single-bond geometry to one Ce(2), one Ce(4), and one C(8) atom. is represented by the CIF file [CIF]
data_Ce4C10O31
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.472
_cell_length_b   8.333
_cell_length_c   13.029
_cell_angle_alpha   106.786
_cell_angle_beta   90.933
_cell_angle_gamma   102.681
_symmetry_Int_Tables_number   1
_cell_volume   653.962
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.908  0.977  0.733  1.0
  Ce  Ce1  1  0.093  0.021  0.265  1.0
  Ce  Ce2  1  0.686  0.312  0.904  1.0
  Ce  Ce3  1  0.317  0.688  0.095  1.0
  C  C4  1  0.953  0.698  0.865  1.0
  C  C5  1  0.046  0.301  0.134  1.0
  C  C6  1  0.907  0.920  0.475  1.0
  C  C7  1  0.092  0.081  0.523  1.0
  C  C8  1  0.227  0.291  0.873  1.0
  C  C9  1  0.775  0.708  0.126  1.0
  C  C10  1  0.562  0.942  0.961  1.0
  C  C11  1  0.438  0.058  0.037  1.0
  C  C12  1  0.763  0.605  0.779  1.0
  C  C13  1  0.237  0.394  0.220  1.0
  O  O14  1  0.347  0.434  0.930  1.0
  O  O15  1  0.654  0.565  0.070  1.0
  O  O16  1  0.024  0.271  0.852  1.0
  O  O17  1  0.977  0.726  0.148  1.0
  O  O18  1  0.681  0.109  0.745  1.0
  O  O19  1  0.322  0.890  0.252  1.0
  O  O20  1  0.051  0.844  0.861  1.0
  O  O21  1  0.949  0.154  0.138  1.0
  O  O22  1  0.816  0.849  0.541  1.0
  O  O23  1  0.185  0.150  0.457  1.0
  O  O24  1  0.240  0.613  0.650  1.0
  O  O25  1  0.777  0.391  0.338  1.0
  O  O26  1  0.991  0.618  0.930  1.0
  O  O27  1  0.008  0.381  0.069  1.0
  O  O28  1  0.182  0.741  0.641  1.0
  O  O29  1  0.772  0.245  0.343  1.0
  O  O30  1  0.662  0.456  0.778  1.0
  O  O31  1  0.338  0.543  0.222  1.0
  O  O32  1  0.723  0.686  0.715  1.0
  O  O33  1  0.275  0.313  0.284  1.0
  O  O34  1  0.307  0.160  0.833  1.0
  O  O35  1  0.697  0.840  0.165  1.0
  O  O36  1  0.868  0.876  0.374  1.0
  O  O37  1  0.132  0.126  0.624  1.0
  O  O38  1  0.517  0.784  0.954  1.0
  O  O39  1  0.484  0.216  0.045  1.0
  O  O40  1  0.699  0.018  0.912  1.0
  O  O41  1  0.300  0.983  0.087  1.0
  O  O42  1  0.361  0.578  0.494  1.0
  O  O43  1  0.302  0.702  0.484  1.0
  O  O44  1  0.819  0.284  0.563  1.0
[/CIF]
.
The compound described by (Ce2C5O14)4(O2)3 crystallizes in the triclinic P1 space group. The structure consists of one 7782-44-7 molecule and one water atom inside a Ce2C5O14 framework. In the Ce2C5O14 framework, there are four inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 9-coordinate geometry to one O(15), one O(19), one O(21), one O(24), one O(27), one O(3), one O(5), one O(7), and one O(9) atom. In the second Ce site, Ce(2) is bonded in a 9-coordinate geometry to one O(10), one O(16), one O(20), one O(22), one O(23), one O(28), one O(4), one O(6), and one O(8) atom. In the third Ce site, Ce(3) is bonded in a 10-coordinate geometry to one O(1), one O(13), one O(14), one O(17), one O(2), one O(21), one O(26), one O(27), one O(3), and one O(5) atom. In the fourth Ce site, Ce(4) is bonded in a 10-coordinate geometry to one O(1), one O(13), one O(14), one O(18), one O(2), one O(22), one O(25), one O(28), one O(4), and one O(6) atom. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(7) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(14) and one O(8) atom. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(23) and one O(9) atom. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(24) atom. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one O(1), one O(21), and one O(3) atom. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one O(2), one O(22), and one O(4) atom. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(25) and one O(27) atom. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(26) and one O(28) atom. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(17) and one O(19) atom. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(18) and one O(20) atom. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ce(3), one Ce(4), and one C(5) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ce(3), one Ce(4), and one C(6) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Ce(1), one Ce(3), and one C(5) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ce(2), one Ce(4), and one C(6) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Ce(1) and one Ce(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ce(2) and one Ce(4) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Ce(1) and one C(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Ce(2) and one C(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Ce(1) and one C(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Ce(2) and one C(4) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one O(15) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one O(16) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one Ce(3), one Ce(4), and one C(1) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Ce(3), one Ce(4), and one C(2) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one O(11) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Ce(2) and one O(12) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Ce(3) and one C(9) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Ce(4) and one C(10) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Ce(1) and one C(9) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Ce(2) and one C(10) atom. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one Ce(1), one Ce(3), and one C(5) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one Ce(2), one Ce(4), and one C(6) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Ce(2) and one C(3) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 120 degrees geometry to one Ce(1) and one C(4) atom. In the twenty-fifth O site, O(25) is bonded in a distorted bent 120 degrees geometry to one Ce(4) and one C(7) atom. In the twenty-sixth O site, O(26) is bonded in a distorted bent 120 degrees geometry to one Ce(3) and one C(8) atom. In the twenty-seventh O site, O(27) is bonded in a distorted single-bond geometry to one Ce(1), one Ce(3), and one C(7) atom. In the twenty-eighth O site, O(28) is bonded in a distorted single-bond geometry to one Ce(2), one Ce(4), and one C(8) atom. is represented by the CIF file [CIF]
data_Ce4C10O31
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.472
_cell_length_b   8.333
_cell_length_c   13.029
_cell_angle_alpha   106.786
_cell_angle_beta   90.933
_cell_angle_gamma   102.681
_symmetry_Int_Tables_number   1
_cell_volume   653.962
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.908  0.977  0.733  1.0
  Ce  Ce1  1  0.093  0.021  0.265  1.0
  Ce  Ce2  1  0.686  0.312  0.904  1.0
  Ce  Ce3  1  0.317  0.688  0.095  1.0
  C  C4  1  0.953  0.698  0.865  1.0
  C  C5  1  0.046  0.301  0.134  1.0
  C  C6  1  0.907  0.920  0.475  1.0
  C  C7  1  0.092  0.081  0.523  1.0
  C  C8  1  0.227  0.291  0.873  1.0
  C  C9  1  0.775  0.708  0.126  1.0
  C  C10  1  0.562  0.942  0.961  1.0
  C  C11  1  0.438  0.058  0.037  1.0
  C  C12  1  0.763  0.605  0.779  1.0
  C  C13  1  0.237  0.394  0.220  1.0
  O  O14  1  0.347  0.434  0.930  1.0
  O  O15  1  0.654  0.565  0.070  1.0
  O  O16  1  0.024  0.271  0.852  1.0
  O  O17  1  0.977  0.726  0.148  1.0
  O  O18  1  0.681  0.109  0.745  1.0
  O  O19  1  0.322  0.890  0.252  1.0
  O  O20  1  0.051  0.844  0.861  1.0
  O  O21  1  0.949  0.154  0.138  1.0
  O  O22  1  0.816  0.849  0.541  1.0
  O  O23  1  0.185  0.150  0.457  1.0
  O  O24  1  0.240  0.613  0.650  1.0
  O  O25  1  0.777  0.391  0.338  1.0
  O  O26  1  0.991  0.618  0.930  1.0
  O  O27  1  0.008  0.381  0.069  1.0
  O  O28  1  0.182  0.741  0.641  1.0
  O  O29  1  0.772  0.245  0.343  1.0
  O  O30  1  0.662  0.456  0.778  1.0
  O  O31  1  0.338  0.543  0.222  1.0
  O  O32  1  0.723  0.686  0.715  1.0
  O  O33  1  0.275  0.313  0.284  1.0
  O  O34  1  0.307  0.160  0.833  1.0
  O  O35  1  0.697  0.840  0.165  1.0
  O  O36  1  0.868  0.876  0.374  1.0
  O  O37  1  0.132  0.126  0.624  1.0
  O  O38  1  0.517  0.784  0.954  1.0
  O  O39  1  0.484  0.216  0.045  1.0
  O  O40  1  0.699  0.018  0.912  1.0
  O  O41  1  0.300  0.983  0.087  1.0
  O  O42  1  0.361  0.578  0.494  1.0
  O  O43  1  0.302  0.702  0.484  1.0
  O  O44  1  0.819  0.284  0.563  1.0
[/CIF]
.