The compound described by (Ag2AsS4)2N2 crystallizes in the tetragonal I-42m space group. The structure consists of two ammonia atoms inside a Ag2AsS4 framework. In the Ag2AsS4 framework, Ag(1) is bonded to four equivalent S(1) atoms to form distorted AgS4 trigonal pyramids that share corners with four equivalent As(1)S4 tetrahedra and corners with four equivalent Ag(1)S4 trigonal pyramids. As(1) is bonded to four equivalent S(1) atoms to form AsS4 tetrahedra that share corners with eight equivalent Ag(1)S4 trigonal pyramids. S(1) is bonded in a trigonal non-coplanar geometry to two equivalent Ag(1) and one As(1) atom. is represented by the CIF file [CIF]
data_Ag2AsS4N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.326
_cell_length_b   6.326
_cell_length_c   6.326
_cell_angle_alpha   118.098
_cell_angle_beta   118.098
_cell_angle_gamma   93.328
_symmetry_Int_Tables_number   1
_cell_volume   183.827
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.750  0.250  0.500  1.0
  Ag  Ag1  1  0.250  0.750  0.500  1.0
  As  As2  1  0.000  0.000  0.000  1.0
  S  S3  1  0.073  0.073  0.411  1.0
  S  S4  1  0.662  0.662  0.589  1.0
  S  S5  1  0.338  0.927  0.000  1.0
  S  S6  1  0.927  0.338  0.000  1.0
  N  N7  1  0.500  0.500  0.000  1.0
[/CIF]
.
The compound described by (Ag2AsS4)2N2 crystallizes in the tetragonal I-42m space group. The structure consists of two ammonia atoms inside a Ag2AsS4 framework. In the Ag2AsS4 framework, Ag(1) is bonded to four equivalent S(1) atoms to form distorted AgS4 trigonal pyramids that share corners with four equivalent As(1)S4 tetrahedra and corners with four equivalent Ag(1)S4 trigonal pyramids. As(1) is bonded to four equivalent S(1) atoms to form AsS4 tetrahedra that share corners with eight equivalent Ag(1)S4 trigonal pyramids. S(1) is bonded in a trigonal non-coplanar geometry to two equivalent Ag(1) and one As(1) atom. is represented by the CIF file [CIF]
data_Ag2AsS4N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.326
_cell_length_b   6.326
_cell_length_c   6.326
_cell_angle_alpha   118.098
_cell_angle_beta   118.098
_cell_angle_gamma   93.328
_symmetry_Int_Tables_number   1
_cell_volume   183.827
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.750  0.250  0.500  1.0
  Ag  Ag1  1  0.250  0.750  0.500  1.0
  As  As2  1  0.000  0.000  0.000  1.0
  S  S3  1  0.073  0.073  0.411  1.0
  S  S4  1  0.662  0.662  0.589  1.0
  S  S5  1  0.338  0.927  0.000  1.0
  S  S6  1  0.927  0.338  0.000  1.0
  N  N7  1  0.500  0.500  0.000  1.0
[/CIF]
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