The material described by K3VC4H6O13 crystallizes in the triclinic P-1 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 10-coordinate geometry to one H(1), one O(10), one O(11), one O(12), one O(2), one O(7), two equivalent O(1), and two equivalent O(9) atoms. In the second K site, K(2) is bonded in a 10-coordinate geometry to one H(4), one O(1), one O(11), one O(12), one O(2), one O(3), one O(5), one O(6), one O(8), and one O(9) atom. In the third K site, K(3) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(11), one O(3), one O(5), and two equivalent O(13) atoms. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(5) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(9) atom. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(8) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one K(1) and one O(11) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(11) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(12) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one K(2) and one O(12) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(13) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(13) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(2), one K(3), two equivalent K(1), and one V(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one K(1), one K(2), and one V(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one K(2), one K(3), one V(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one V(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(2), one K(3), and one C(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one K(2) and one C(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one K(1), one V(1), and one C(3) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one K(2), one V(1), and one C(4) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(1), and one C(3) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one K(1), one K(3), and one C(4) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one K(1), one K(2), one K(3), one H(1), and one H(2) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one K(1), one K(2), one H(3), and one H(4) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to two equivalent K(3), one H(5), and one H(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K3VH6C4O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.893
_cell_length_b   7.938
_cell_length_c   11.713
_cell_angle_alpha   91.114
_cell_angle_beta   94.402
_cell_angle_gamma   110.190
_symmetry_Int_Tables_number   1
_cell_volume   685.953
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.431  0.725  0.520  1.0
  K  K1  1  0.569  0.275  0.480  1.0
  K  K2  1  0.842  0.731  0.771  1.0
  K  K3  1  0.158  0.269  0.229  1.0
  K  K4  1  0.412  0.968  0.827  1.0
  K  K5  1  0.588  0.032  0.173  1.0
  V  V6  1  0.844  0.186  0.707  1.0
  V  V7  1  0.156  0.814  0.293  1.0
  H  H8  1  0.095  0.667  0.607  1.0
  H  H9  1  0.905  0.333  0.393  1.0
  H  H10  1  0.126  0.571  0.717  1.0
  H  H11  1  0.874  0.429  0.283  1.0
  H  H12  1  0.378  0.499  0.788  1.0
  H  H13  1  0.622  0.501  0.212  1.0
  H  H14  1  0.522  0.426  0.742  1.0
  H  H15  1  0.478  0.574  0.258  1.0
  H  H16  1  0.594  0.717  0.986  1.0
  H  H17  1  0.406  0.283  0.014  1.0
  H  H18  1  0.391  0.634  0.009  1.0
  H  H19  1  0.609  0.366  0.991  1.0
  C  C20  1  0.916  0.170  0.953  1.0
  C  C21  1  0.084  0.830  0.047  1.0
  C  C22  1  0.087  0.328  0.925  1.0
  C  C23  1  0.913  0.672  0.075  1.0
  C  C24  1  0.129  0.267  0.551  1.0
  C  C25  1  0.871  0.733  0.449  1.0
  C  C26  1  0.173  0.131  0.630  1.0
  C  C27  1  0.827  0.869  0.370  1.0
  O  O28  1  0.681  0.004  0.647  1.0
  O  O29  1  0.319  0.996  0.353  1.0
  O  O30  1  0.748  0.344  0.715  1.0
  O  O31  1  0.252  0.656  0.285  1.0
  O  O32  1  0.808  0.087  0.863  1.0
  O  O33  1  0.192  0.913  0.137  1.0
  O  O34  1  0.087  0.369  0.820  1.0
  O  O35  1  0.913  0.631  0.180  1.0
  O  O36  1  0.889  0.128  0.053  1.0
  O  O37  1  0.111  0.872  0.947  1.0
  O  O38  1  0.210  0.401  0.004  1.0
  O  O39  1  0.790  0.599  0.996  1.0
  O  O40  1  0.980  0.295  0.570  1.0
  O  O41  1  0.020  0.705  0.430  1.0
  O  O42  1  0.050  0.062  0.699  1.0
  O  O43  1  0.950  0.938  0.301  1.0
  O  O44  1  0.229  0.341  0.476  1.0
  O  O45  1  0.771  0.659  0.524  1.0
  O  O46  1  0.317  0.099  0.624  1.0
  O  O47  1  0.683  0.901  0.376  1.0
  O  O48  1  0.162  0.688  0.683  1.0
  O  O49  1  0.838  0.312  0.317  1.0
  O  O50  1  0.475  0.525  0.736  1.0
  O  O51  1  0.525  0.475  0.264  1.0
  O  O52  1  0.489  0.750  0.002  1.0
  O  O53  1  0.511  0.250  0.998  1.0
[/CIF]
.
The material described by K3VC4H6O13 crystallizes in the triclinic P-1 space group. There are three inequivalent K sites. In the first K site, K(1) is bonded in a 10-coordinate geometry to one H(1), one O(10), one O(11), one O(12), one O(2), one O(7), two equivalent O(1), and two equivalent O(9) atoms. In the second K site, K(2) is bonded in a 10-coordinate geometry to one H(4), one O(1), one O(11), one O(12), one O(2), one O(3), one O(5), one O(6), one O(8), and one O(9) atom. In the third K site, K(3) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(11), one O(3), one O(5), and two equivalent O(13) atoms. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(5) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(9) atom. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(8) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one K(1) and one O(11) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(11) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(12) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one K(2) and one O(12) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(13) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(13) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(2), one K(3), two equivalent K(1), and one V(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one K(1), one K(2), and one V(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one K(2), one K(3), one V(1), and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one V(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one K(2), one K(3), and one C(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one K(2) and one C(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one K(1), one V(1), and one C(3) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one K(2), one V(1), and one C(4) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one K(2), two equivalent K(1), and one C(3) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one K(1), one K(3), and one C(4) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one K(1), one K(2), one K(3), one H(1), and one H(2) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one K(1), one K(2), one H(3), and one H(4) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to two equivalent K(3), one H(5), and one H(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K3VH6C4O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.893
_cell_length_b   7.938
_cell_length_c   11.713
_cell_angle_alpha   91.114
_cell_angle_beta   94.402
_cell_angle_gamma   110.190
_symmetry_Int_Tables_number   1
_cell_volume   685.953
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.431  0.725  0.520  1.0
  K  K1  1  0.569  0.275  0.480  1.0
  K  K2  1  0.842  0.731  0.771  1.0
  K  K3  1  0.158  0.269  0.229  1.0
  K  K4  1  0.412  0.968  0.827  1.0
  K  K5  1  0.588  0.032  0.173  1.0
  V  V6  1  0.844  0.186  0.707  1.0
  V  V7  1  0.156  0.814  0.293  1.0
  H  H8  1  0.095  0.667  0.607  1.0
  H  H9  1  0.905  0.333  0.393  1.0
  H  H10  1  0.126  0.571  0.717  1.0
  H  H11  1  0.874  0.429  0.283  1.0
  H  H12  1  0.378  0.499  0.788  1.0
  H  H13  1  0.622  0.501  0.212  1.0
  H  H14  1  0.522  0.426  0.742  1.0
  H  H15  1  0.478  0.574  0.258  1.0
  H  H16  1  0.594  0.717  0.986  1.0
  H  H17  1  0.406  0.283  0.014  1.0
  H  H18  1  0.391  0.634  0.009  1.0
  H  H19  1  0.609  0.366  0.991  1.0
  C  C20  1  0.916  0.170  0.953  1.0
  C  C21  1  0.084  0.830  0.047  1.0
  C  C22  1  0.087  0.328  0.925  1.0
  C  C23  1  0.913  0.672  0.075  1.0
  C  C24  1  0.129  0.267  0.551  1.0
  C  C25  1  0.871  0.733  0.449  1.0
  C  C26  1  0.173  0.131  0.630  1.0
  C  C27  1  0.827  0.869  0.370  1.0
  O  O28  1  0.681  0.004  0.647  1.0
  O  O29  1  0.319  0.996  0.353  1.0
  O  O30  1  0.748  0.344  0.715  1.0
  O  O31  1  0.252  0.656  0.285  1.0
  O  O32  1  0.808  0.087  0.863  1.0
  O  O33  1  0.192  0.913  0.137  1.0
  O  O34  1  0.087  0.369  0.820  1.0
  O  O35  1  0.913  0.631  0.180  1.0
  O  O36  1  0.889  0.128  0.053  1.0
  O  O37  1  0.111  0.872  0.947  1.0
  O  O38  1  0.210  0.401  0.004  1.0
  O  O39  1  0.790  0.599  0.996  1.0
  O  O40  1  0.980  0.295  0.570  1.0
  O  O41  1  0.020  0.705  0.430  1.0
  O  O42  1  0.050  0.062  0.699  1.0
  O  O43  1  0.950  0.938  0.301  1.0
  O  O44  1  0.229  0.341  0.476  1.0
  O  O45  1  0.771  0.659  0.524  1.0
  O  O46  1  0.317  0.099  0.624  1.0
  O  O47  1  0.683  0.901  0.376  1.0
  O  O48  1  0.162  0.688  0.683  1.0
  O  O49  1  0.838  0.312  0.317  1.0
  O  O50  1  0.475  0.525  0.736  1.0
  O  O51  1  0.525  0.475  0.264  1.0
  O  O52  1  0.489  0.750  0.002  1.0
  O  O53  1  0.511  0.250  0.998  1.0
[/CIF]
.