The material structure described by AgBiO2 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. Bi(1) is bonded in a 5-coordinate geometry to two equivalent O(2) and three equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ag(2) and three equivalent Bi(1) atoms to form a mixture of distorted corner and edge-sharing OAgBi3 tetrahedra. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Ag(1) and two equivalent Bi(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgBiO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.642
_cell_length_b   6.642
_cell_length_c   6.701
_cell_angle_alpha   82.077
_cell_angle_beta   82.077
_cell_angle_gamma   31.483
_symmetry_Int_Tables_number   1
_cell_volume   152.800
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.000  1.0
  Ag  Ag1  1  0.500  0.500  0.500  1.0
  Bi  Bi2  1  0.754  0.754  0.739  1.0
  Bi  Bi3  1  0.246  0.246  0.261  1.0
  O  O4  1  0.336  0.336  0.517  1.0
  O  O5  1  0.664  0.664  0.483  1.0
  O  O6  1  0.839  0.839  0.117  1.0
  O  O7  1  0.161  0.161  0.883  1.0
[/CIF]
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The material structure described by AgBiO2 crystallizes in the monoclinic C2/m space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. Bi(1) is bonded in a 5-coordinate geometry to two equivalent O(2) and three equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Ag(2) and three equivalent Bi(1) atoms to form a mixture of distorted corner and edge-sharing OAgBi3 tetrahedra. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Ag(1) and two equivalent Bi(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgBiO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.642
_cell_length_b   6.642
_cell_length_c   6.701
_cell_angle_alpha   82.077
_cell_angle_beta   82.077
_cell_angle_gamma   31.483
_symmetry_Int_Tables_number   1
_cell_volume   152.800
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.000  1.0
  Ag  Ag1  1  0.500  0.500  0.500  1.0
  Bi  Bi2  1  0.754  0.754  0.739  1.0
  Bi  Bi3  1  0.246  0.246  0.261  1.0
  O  O4  1  0.336  0.336  0.517  1.0
  O  O5  1  0.664  0.664  0.483  1.0
  O  O6  1  0.839  0.839  0.117  1.0
  O  O7  1  0.161  0.161  0.883  1.0
[/CIF]
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