The crystal structure described by Ag5CF4 crystallizes in the tetragonal P-4 space group. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one C(1), one F(3), and three equivalent F(4) atoms. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one F(4) and three equivalent F(3) atoms. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one C(1), one F(1), and three equivalent F(2) atoms. In the fourth Ag site, Ag(4) is bonded in a 3-coordinate geometry to one C(1), one F(1), and one F(2) atom. In the fifth Ag site, Ag(5) is bonded in a 4-coordinate geometry to two equivalent F(1) and two equivalent F(2) atoms. In the sixth Ag site, Ag(6) is bonded in a 4-coordinate geometry to two equivalent F(3) and two equivalent F(4) atoms. C(1) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(3), one Ag(4), and one C(1) atom. There are four inequivalent F sites. In the first F site, F(3) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(6), and three equivalent Ag(2) atoms. In the second F site, F(4) is bonded in a 5-coordinate geometry to one Ag(2), one Ag(6), and three equivalent Ag(1) atoms. In the third F site, F(1) is bonded in a 3-coordinate geometry to one Ag(3), one Ag(4), and one Ag(5) atom. In the fourth F site, F(2) is bonded in a 5-coordinate geometry to one Ag(4), one Ag(5), and three equivalent Ag(3) atoms. is represented by the CIF file [CIF]
data_Ag5CF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.540
_cell_length_b   7.540
_cell_length_c   10.633
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   604.557
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.769  0.102  0.878  1.0
  Ag  Ag1  1  0.102  0.231  0.122  1.0
  Ag  Ag2  1  0.898  0.769  0.122  1.0
  Ag  Ag3  1  0.231  0.898  0.878  1.0
  Ag  Ag4  1  0.406  0.264  0.876  1.0
  Ag  Ag5  1  0.264  0.594  0.124  1.0
  Ag  Ag6  1  0.736  0.406  0.124  1.0
  Ag  Ag7  1  0.594  0.736  0.876  1.0
  Ag  Ag8  1  0.622  0.298  0.652  1.0
  Ag  Ag9  1  0.298  0.378  0.348  1.0
  Ag  Ag10  1  0.702  0.622  0.348  1.0
  Ag  Ag11  1  0.378  0.702  0.652  1.0
  Ag  Ag12  1  0.202  0.109  0.656  1.0
  Ag  Ag13  1  0.109  0.798  0.344  1.0
  Ag  Ag14  1  0.891  0.202  0.344  1.0
  Ag  Ag15  1  0.798  0.891  0.656  1.0
  Ag  Ag16  1  0.000  0.500  0.503  1.0
  Ag  Ag17  1  0.500  0.000  0.497  1.0
  Ag  Ag18  1  0.000  0.500  0.798  1.0
  Ag  Ag19  1  0.500  0.000  0.202  1.0
  C  C20  1  0.578  0.038  0.735  1.0
  C  C21  1  0.038  0.422  0.265  1.0
  C  C22  1  0.962  0.578  0.265  1.0
  C  C23  1  0.422  0.962  0.735  1.0
  F  F24  1  0.776  0.943  0.396  1.0
  F  F25  1  0.574  0.294  0.398  1.0
  F  F26  1  0.426  0.706  0.398  1.0
  F  F27  1  0.294  0.426  0.602  1.0
  F  F28  1  0.943  0.224  0.604  1.0
  F  F29  1  0.706  0.574  0.602  1.0
  F  F30  1  0.224  0.057  0.396  1.0
  F  F31  1  0.057  0.776  0.604  1.0
  F  F32  1  0.289  0.555  0.898  1.0
  F  F33  1  0.555  0.711  0.102  1.0
  F  F34  1  0.445  0.289  0.102  1.0
  F  F35  1  0.711  0.445  0.898  1.0
  F  F36  1  0.062  0.210  0.905  1.0
  F  F37  1  0.210  0.938  0.095  1.0
  F  F38  1  0.790  0.062  0.095  1.0
  F  F39  1  0.938  0.790  0.905  1.0
[/CIF]
.
The crystal structure described by Ag5CF4 crystallizes in the tetragonal P-4 space group. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one C(1), one F(3), and three equivalent F(4) atoms. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one F(4) and three equivalent F(3) atoms. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one C(1), one F(1), and three equivalent F(2) atoms. In the fourth Ag site, Ag(4) is bonded in a 3-coordinate geometry to one C(1), one F(1), and one F(2) atom. In the fifth Ag site, Ag(5) is bonded in a 4-coordinate geometry to two equivalent F(1) and two equivalent F(2) atoms. In the sixth Ag site, Ag(6) is bonded in a 4-coordinate geometry to two equivalent F(3) and two equivalent F(4) atoms. C(1) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(3), one Ag(4), and one C(1) atom. There are four inequivalent F sites. In the first F site, F(3) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(6), and three equivalent Ag(2) atoms. In the second F site, F(4) is bonded in a 5-coordinate geometry to one Ag(2), one Ag(6), and three equivalent Ag(1) atoms. In the third F site, F(1) is bonded in a 3-coordinate geometry to one Ag(3), one Ag(4), and one Ag(5) atom. In the fourth F site, F(2) is bonded in a 5-coordinate geometry to one Ag(4), one Ag(5), and three equivalent Ag(3) atoms. is represented by the CIF file [CIF]
data_Ag5CF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.540
_cell_length_b   7.540
_cell_length_c   10.633
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   604.557
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.769  0.102  0.878  1.0
  Ag  Ag1  1  0.102  0.231  0.122  1.0
  Ag  Ag2  1  0.898  0.769  0.122  1.0
  Ag  Ag3  1  0.231  0.898  0.878  1.0
  Ag  Ag4  1  0.406  0.264  0.876  1.0
  Ag  Ag5  1  0.264  0.594  0.124  1.0
  Ag  Ag6  1  0.736  0.406  0.124  1.0
  Ag  Ag7  1  0.594  0.736  0.876  1.0
  Ag  Ag8  1  0.622  0.298  0.652  1.0
  Ag  Ag9  1  0.298  0.378  0.348  1.0
  Ag  Ag10  1  0.702  0.622  0.348  1.0
  Ag  Ag11  1  0.378  0.702  0.652  1.0
  Ag  Ag12  1  0.202  0.109  0.656  1.0
  Ag  Ag13  1  0.109  0.798  0.344  1.0
  Ag  Ag14  1  0.891  0.202  0.344  1.0
  Ag  Ag15  1  0.798  0.891  0.656  1.0
  Ag  Ag16  1  0.000  0.500  0.503  1.0
  Ag  Ag17  1  0.500  0.000  0.497  1.0
  Ag  Ag18  1  0.000  0.500  0.798  1.0
  Ag  Ag19  1  0.500  0.000  0.202  1.0
  C  C20  1  0.578  0.038  0.735  1.0
  C  C21  1  0.038  0.422  0.265  1.0
  C  C22  1  0.962  0.578  0.265  1.0
  C  C23  1  0.422  0.962  0.735  1.0
  F  F24  1  0.776  0.943  0.396  1.0
  F  F25  1  0.574  0.294  0.398  1.0
  F  F26  1  0.426  0.706  0.398  1.0
  F  F27  1  0.294  0.426  0.602  1.0
  F  F28  1  0.943  0.224  0.604  1.0
  F  F29  1  0.706  0.574  0.602  1.0
  F  F30  1  0.224  0.057  0.396  1.0
  F  F31  1  0.057  0.776  0.604  1.0
  F  F32  1  0.289  0.555  0.898  1.0
  F  F33  1  0.555  0.711  0.102  1.0
  F  F34  1  0.445  0.289  0.102  1.0
  F  F35  1  0.711  0.445  0.898  1.0
  F  F36  1  0.062  0.210  0.905  1.0
  F  F37  1  0.210  0.938  0.095  1.0
  F  F38  1  0.790  0.062  0.095  1.0
  F  F39  1  0.938  0.790  0.905  1.0
[/CIF]
.