The material described by AlBiN2 crystallizes in the orthorhombic Pna2_1 space group. Al(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form corner-sharing AlN4 tetrahedra. Bi(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent Al(1) and two equivalent Bi(1) atoms to form corner-sharing NAl2Bi2 tetrahedra. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Al(1) and one Bi(1) atom. is represented by the CIF card [CIF]
data_AlBiN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.134
_cell_length_b   7.510
_cell_length_c   5.245
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   241.629
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.525  0.370  0.000  1.0
  Al  Al1  1  0.475  0.630  0.500  1.0
  Al  Al2  1  0.975  0.870  0.500  1.0
  Al  Al3  1  0.025  0.130  0.000  1.0
  Bi  Bi4  1  0.619  0.867  0.018  1.0
  Bi  Bi5  1  0.381  0.133  0.518  1.0
  Bi  Bi6  1  0.881  0.367  0.518  1.0
  Bi  Bi7  1  0.119  0.633  0.018  1.0
  N  N8  1  0.523  0.392  0.364  1.0
  N  N9  1  0.477  0.608  0.864  1.0
  N  N10  1  0.977  0.892  0.864  1.0
  N  N11  1  0.023  0.108  0.364  1.0
  N  N12  1  0.720  0.760  0.387  1.0
  N  N13  1  0.280  0.240  0.887  1.0
  N  N14  1  0.780  0.260  0.887  1.0
  N  N15  1  0.220  0.740  0.387  1.0
[/CIF]
.
The material described by AlBiN2 crystallizes in the orthorhombic Pna2_1 space group. Al(1) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form corner-sharing AlN4 tetrahedra. Bi(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded to two equivalent Al(1) and two equivalent Bi(1) atoms to form corner-sharing NAl2Bi2 tetrahedra. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Al(1) and one Bi(1) atom. is represented by the CIF card [CIF]
data_AlBiN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.134
_cell_length_b   7.510
_cell_length_c   5.245
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   241.629
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.525  0.370  0.000  1.0
  Al  Al1  1  0.475  0.630  0.500  1.0
  Al  Al2  1  0.975  0.870  0.500  1.0
  Al  Al3  1  0.025  0.130  0.000  1.0
  Bi  Bi4  1  0.619  0.867  0.018  1.0
  Bi  Bi5  1  0.381  0.133  0.518  1.0
  Bi  Bi6  1  0.881  0.367  0.518  1.0
  Bi  Bi7  1  0.119  0.633  0.018  1.0
  N  N8  1  0.523  0.392  0.364  1.0
  N  N9  1  0.477  0.608  0.864  1.0
  N  N10  1  0.977  0.892  0.864  1.0
  N  N11  1  0.023  0.108  0.364  1.0
  N  N12  1  0.720  0.760  0.387  1.0
  N  N13  1  0.280  0.240  0.887  1.0
  N  N14  1  0.780  0.260  0.887  1.0
  N  N15  1  0.220  0.740  0.387  1.0
[/CIF]
.