The material described by VC2H6O3Cl is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one VC2H6O3Cl cluster. V(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), two equivalent O(2), and one Cl(1) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a tetrahedral geometry to one H(1), one H(2), one H(3), and one O(3) atom. In the second C site, C(2) is bonded in a tetrahedral geometry to one H(4), one H(5), one H(6), and one O(2) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent V(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(1) and one C(1) atom. Cl(1) is bonded in a single-bond geometry to one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VH6C2ClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.305
_cell_length_b   6.608
_cell_length_c   8.874
_cell_angle_alpha   83.337
_cell_angle_beta   72.728
_cell_angle_gamma   81.674
_symmetry_Int_Tables_number   1
_cell_volume   348.292
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.502  0.512  0.706  1.0
  V  V1  1  0.498  0.488  0.294  1.0
  H  H2  1  0.217  0.873  0.895  1.0
  H  H3  1  0.783  0.127  0.105  1.0
  H  H4  1  0.951  0.827  0.876  1.0
  H  H5  1  0.049  0.173  0.124  1.0
  H  H6  1  0.076  0.665  0.011  1.0
  H  H7  1  0.924  0.335  0.989  1.0
  H  H8  1  0.912  0.723  0.558  1.0
  H  H9  1  0.088  0.277  0.442  1.0
  H  H10  1  0.939  0.704  0.353  1.0
  H  H11  1  0.061  0.296  0.647  1.0
  H  H12  1  0.748  0.904  0.459  1.0
  H  H13  1  0.252  0.096  0.541  1.0
  C  C14  1  0.110  0.755  0.896  1.0
  C  C15  1  0.890  0.245  0.104  1.0
  C  C16  1  0.822  0.743  0.468  1.0
  C  C17  1  0.178  0.257  0.532  1.0
  Cl  Cl18  1  0.550  0.174  0.765  1.0
  Cl  Cl19  1  0.450  0.826  0.235  1.0
  O  O20  1  0.626  0.602  0.813  1.0
  O  O21  1  0.374  0.398  0.187  1.0
  O  O22  1  0.650  0.610  0.509  1.0
  O  O23  1  0.350  0.390  0.491  1.0
  O  O24  1  0.219  0.624  0.772  1.0
  O  O25  1  0.781  0.376  0.228  1.0
[/CIF]
.
The material described by VC2H6O3Cl is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one VC2H6O3Cl cluster. V(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), two equivalent O(2), and one Cl(1) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a tetrahedral geometry to one H(1), one H(2), one H(3), and one O(3) atom. In the second C site, C(2) is bonded in a tetrahedral geometry to one H(4), one H(5), one H(6), and one O(2) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one V(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to two equivalent V(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(1) and one C(1) atom. Cl(1) is bonded in a single-bond geometry to one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VH6C2ClO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.305
_cell_length_b   6.608
_cell_length_c   8.874
_cell_angle_alpha   83.337
_cell_angle_beta   72.728
_cell_angle_gamma   81.674
_symmetry_Int_Tables_number   1
_cell_volume   348.292
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.502  0.512  0.706  1.0
  V  V1  1  0.498  0.488  0.294  1.0
  H  H2  1  0.217  0.873  0.895  1.0
  H  H3  1  0.783  0.127  0.105  1.0
  H  H4  1  0.951  0.827  0.876  1.0
  H  H5  1  0.049  0.173  0.124  1.0
  H  H6  1  0.076  0.665  0.011  1.0
  H  H7  1  0.924  0.335  0.989  1.0
  H  H8  1  0.912  0.723  0.558  1.0
  H  H9  1  0.088  0.277  0.442  1.0
  H  H10  1  0.939  0.704  0.353  1.0
  H  H11  1  0.061  0.296  0.647  1.0
  H  H12  1  0.748  0.904  0.459  1.0
  H  H13  1  0.252  0.096  0.541  1.0
  C  C14  1  0.110  0.755  0.896  1.0
  C  C15  1  0.890  0.245  0.104  1.0
  C  C16  1  0.822  0.743  0.468  1.0
  C  C17  1  0.178  0.257  0.532  1.0
  Cl  Cl18  1  0.550  0.174  0.765  1.0
  Cl  Cl19  1  0.450  0.826  0.235  1.0
  O  O20  1  0.626  0.602  0.813  1.0
  O  O21  1  0.374  0.398  0.187  1.0
  O  O22  1  0.650  0.610  0.509  1.0
  O  O23  1  0.350  0.390  0.491  1.0
  O  O24  1  0.219  0.624  0.772  1.0
  O  O25  1  0.781  0.376  0.228  1.0
[/CIF]
.