The material structure described by (AuCl4)6N2(NO)4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four ammonia atoms, eight nitroxyl molecules, and twelve AuCl4 clusters. In four of the AuCl4 clusters, Au(2) is bonded in a rectangular see-saw-like geometry to two equivalent Cl(5) and two equivalent Cl(6) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Au(2) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Au(2) atom. In eight of the AuCl4 clusters, Au(1) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Au(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. is represented by the CIF file [CIF]
data_Au3N3(Cl6O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.905
_cell_length_b   8.905
_cell_length_c   14.803
_cell_angle_alpha   82.114
_cell_angle_beta   82.114
_cell_angle_gamma   76.669
_symmetry_Int_Tables_number   1
_cell_volume   1124.542
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.002  0.859  0.388  1.0
  Au  Au1  1  0.141  0.998  0.112  1.0
  Au  Au2  1  0.998  0.141  0.612  1.0
  Au  Au3  1  0.859  0.002  0.888  1.0
  Au  Au4  1  0.568  0.432  0.250  1.0
  Au  Au5  1  0.432  0.568  0.750  1.0
  N  N6  1  0.000  0.500  0.000  1.0
  N  N7  1  0.500  0.000  0.500  1.0
  N  N8  1  0.132  0.430  0.280  1.0
  N  N9  1  0.570  0.868  0.220  1.0
  N  N10  1  0.868  0.570  0.720  1.0
  N  N11  1  0.430  0.132  0.780  1.0
  Cl  Cl12  1  0.825  0.705  0.438  1.0
  Cl  Cl13  1  0.295  0.175  0.062  1.0
  Cl  Cl14  1  0.175  0.295  0.562  1.0
  Cl  Cl15  1  0.705  0.825  0.938  1.0
  Cl  Cl16  1  0.176  0.021  0.340  1.0
  Cl  Cl17  1  0.979  0.824  0.160  1.0
  Cl  Cl18  1  0.824  0.979  0.660  1.0
  Cl  Cl19  1  0.021  0.176  0.840  1.0
  Cl  Cl20  1  0.801  0.075  0.398  1.0
  Cl  Cl21  1  0.925  0.199  0.102  1.0
  Cl  Cl22  1  0.199  0.925  0.602  1.0
  Cl  Cl23  1  0.075  0.801  0.898  1.0
  Cl  Cl24  1  0.199  0.637  0.376  1.0
  Cl  Cl25  1  0.363  0.801  0.124  1.0
  Cl  Cl26  1  0.801  0.363  0.624  1.0
  Cl  Cl27  1  0.637  0.199  0.876  1.0
  Cl  Cl28  1  0.726  0.605  0.196  1.0
  Cl  Cl29  1  0.395  0.274  0.304  1.0
  Cl  Cl30  1  0.274  0.395  0.804  1.0
  Cl  Cl31  1  0.605  0.726  0.696  1.0
  Cl  Cl32  1  0.604  0.450  0.400  1.0
  Cl  Cl33  1  0.550  0.396  0.100  1.0
  Cl  Cl34  1  0.396  0.550  0.600  1.0
  Cl  Cl35  1  0.450  0.604  0.900  1.0
  O  O36  1  0.115  0.469  0.206  1.0
  O  O37  1  0.531  0.885  0.294  1.0
  O  O38  1  0.885  0.531  0.794  1.0
  O  O39  1  0.469  0.115  0.706  1.0
[/CIF]
.
The material structure described by (AuCl4)6N2(NO)4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four ammonia atoms, eight nitroxyl molecules, and twelve AuCl4 clusters. In four of the AuCl4 clusters, Au(2) is bonded in a rectangular see-saw-like geometry to two equivalent Cl(5) and two equivalent Cl(6) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(5) is bonded in a single-bond geometry to one Au(2) atom. In the second Cl site, Cl(6) is bonded in a single-bond geometry to one Au(2) atom. In eight of the AuCl4 clusters, Au(1) is bonded in a rectangular see-saw-like geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Au(1) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one Au(1) atom. In the third Cl site, Cl(1) is bonded in a single-bond geometry to one Au(1) atom. In the fourth Cl site, Cl(2) is bonded in a single-bond geometry to one Au(1) atom. is represented by the CIF file [CIF]
data_Au3N3(Cl6O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.905
_cell_length_b   8.905
_cell_length_c   14.803
_cell_angle_alpha   82.114
_cell_angle_beta   82.114
_cell_angle_gamma   76.669
_symmetry_Int_Tables_number   1
_cell_volume   1124.542
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.002  0.859  0.388  1.0
  Au  Au1  1  0.141  0.998  0.112  1.0
  Au  Au2  1  0.998  0.141  0.612  1.0
  Au  Au3  1  0.859  0.002  0.888  1.0
  Au  Au4  1  0.568  0.432  0.250  1.0
  Au  Au5  1  0.432  0.568  0.750  1.0
  N  N6  1  0.000  0.500  0.000  1.0
  N  N7  1  0.500  0.000  0.500  1.0
  N  N8  1  0.132  0.430  0.280  1.0
  N  N9  1  0.570  0.868  0.220  1.0
  N  N10  1  0.868  0.570  0.720  1.0
  N  N11  1  0.430  0.132  0.780  1.0
  Cl  Cl12  1  0.825  0.705  0.438  1.0
  Cl  Cl13  1  0.295  0.175  0.062  1.0
  Cl  Cl14  1  0.175  0.295  0.562  1.0
  Cl  Cl15  1  0.705  0.825  0.938  1.0
  Cl  Cl16  1  0.176  0.021  0.340  1.0
  Cl  Cl17  1  0.979  0.824  0.160  1.0
  Cl  Cl18  1  0.824  0.979  0.660  1.0
  Cl  Cl19  1  0.021  0.176  0.840  1.0
  Cl  Cl20  1  0.801  0.075  0.398  1.0
  Cl  Cl21  1  0.925  0.199  0.102  1.0
  Cl  Cl22  1  0.199  0.925  0.602  1.0
  Cl  Cl23  1  0.075  0.801  0.898  1.0
  Cl  Cl24  1  0.199  0.637  0.376  1.0
  Cl  Cl25  1  0.363  0.801  0.124  1.0
  Cl  Cl26  1  0.801  0.363  0.624  1.0
  Cl  Cl27  1  0.637  0.199  0.876  1.0
  Cl  Cl28  1  0.726  0.605  0.196  1.0
  Cl  Cl29  1  0.395  0.274  0.304  1.0
  Cl  Cl30  1  0.274  0.395  0.804  1.0
  Cl  Cl31  1  0.605  0.726  0.696  1.0
  Cl  Cl32  1  0.604  0.450  0.400  1.0
  Cl  Cl33  1  0.550  0.396  0.100  1.0
  Cl  Cl34  1  0.396  0.550  0.600  1.0
  Cl  Cl35  1  0.450  0.604  0.900  1.0
  O  O36  1  0.115  0.469  0.206  1.0
  O  O37  1  0.531  0.885  0.294  1.0
  O  O38  1  0.885  0.531  0.794  1.0
  O  O39  1  0.469  0.115  0.706  1.0
[/CIF]
.