The structure described by LiV5O7F is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(4), one O(5), one O(8), and one F(2) atom to form LiO3F tetrahedra that share  a cornercorner with one V(7)O5F octahedra,  a cornercorner with one V(8)O5F octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent V(4)O5F octahedra, corners with two equivalent V(5)O5F octahedra, corners with two equivalent V(3)O6 octahedra, and corners with three equivalent V(10)O5F octahedra. The corner-sharing octahedral tilt angles range from 53-63°. In the second Li site, Li(2) is bonded to one O(3), one O(6), one O(7), and one F(1) atom to form LiO3F tetrahedra that share  a cornercorner with one V(4)O5F octahedra,  a cornercorner with one V(5)O5F octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent V(7)O5F octahedra, corners with two equivalent V(8)O5F octahedra, corners with two equivalent V(2)O6 octahedra, and corners with three equivalent V(9)O5F octahedra. The corner-sharing octahedral tilt angles range from 54-65°. There are ten inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(11), one O(14), and one O(9) atom to form VO4 tetrahedra that share  a cornercorner with one V(7)O5F octahedra,  a cornercorner with one V(8)O5F octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent V(4)O5F octahedra, corners with two equivalent V(5)O5F octahedra, corners with two equivalent V(3)O6 octahedra, and corners with three equivalent V(9)O5F octahedra. The corner-sharing octahedral tilt angles range from 55-61°. In the second V site, V(2) is bonded to one O(10), one O(12), one O(14), one O(3), one O(5), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra, corners with two equivalent Li(2)O3F tetrahedra, corners with two equivalent V(6)O4 tetrahedra,  an edgeedge with one V(10)O5F octahedra,  an edgeedge with one V(9)O5F octahedra, edges with two equivalent V(7)O5F octahedra, and edges with two equivalent V(8)O5F octahedra. In the third V site, V(3) is bonded to one O(11), one O(13), one O(4), one O(6), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(6)O4 tetrahedra, corners with two equivalent Li(1)O3F tetrahedra, corners with two equivalent V(1)O4 tetrahedra,  an edgeedge with one V(10)O5F octahedra,  an edgeedge with one V(9)O5F octahedra, edges with two equivalent V(4)O5F octahedra, and edges with two equivalent V(5)O5F octahedra. In the fourth V site, V(4) is bonded to one O(1), one O(11), one O(13), one O(4), one O(6), and one F(2) atom to form VO5F octahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(6)O4 tetrahedra, corners with two equivalent Li(1)O3F tetrahedra, corners with two equivalent V(1)O4 tetrahedra,  an edgeedge with one V(10)O5F octahedra,  an edgeedge with one V(9)O5F octahedra, edges with two equivalent V(5)O5F octahedra, and edges with two equivalent V(3)O6 octahedra. In the fifth V site, V(5) is bonded to one O(1), one O(13), one O(6), one O(8), one O(9), and one F(2) atom to form VO5F octahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(6)O4 tetrahedra, corners with two equivalent Li(1)O3F tetrahedra, corners with two equivalent V(1)O4 tetrahedra,  an edgeedge with one V(10)O5F octahedra,  an edgeedge with one V(9)O5F octahedra, edges with two equivalent V(4)O5F octahedra, and edges with two equivalent V(3)O6 octahedra. In the sixth V site, V(6) is bonded to one O(10), one O(12), one O(13), and one O(2) atom to form VO4 tetrahedra that share  a cornercorner with one V(4)O5F octahedra,  a cornercorner with one V(5)O5F octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent V(7)O5F octahedra, corners with two equivalent V(8)O5F octahedra, corners with two equivalent V(2)O6 octahedra, and corners with three equivalent V(10)O5F octahedra. The corner-sharing octahedral tilt angles range from 53-61°. In the seventh V site, V(7) is bonded to one O(12), one O(14), one O(2), one O(3), one O(5), and one F(1) atom to form VO5F octahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra, corners with two equivalent Li(2)O3F tetrahedra, corners with two equivalent V(6)O4 tetrahedra,  an edgeedge with one V(10)O5F octahedra,  an edgeedge with one V(9)O5F octahedra, edges with two equivalent V(8)O5F octahedra, and edges with two equivalent V(2)O6 octahedra. In the eighth V site, V(8) is bonded to one O(10), one O(14), one O(2), one O(5), one O(7), and one F(1) atom to form VO5F octahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra, corners with two equivalent Li(2)O3F tetrahedra, corners with two equivalent V(6)O4 tetrahedra,  an edgeedge with one V(10)O5F octahedra,  an edgeedge with one V(9)O5F octahedra, edges with two equivalent V(7)O5F octahedra, and edges with two equivalent V(2)O6 octahedra. In the ninth V site, V(9) is bonded to one O(1), one O(11), one O(3), one O(7), one O(9), and one F(1) atom to form VO5F octahedra that share corners with three equivalent Li(2)O3F tetrahedra, corners with three equivalent V(1)O4 tetrahedra,  an edgeedge with one V(4)O5F octahedra,  an edgeedge with one V(5)O5F octahedra,  an edgeedge with one V(7)O5F octahedra,  an edgeedge with one V(8)O5F octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. In the tenth V site, V(10) is bonded to one O(10), one O(12), one O(2), one O(4), one O(8), and one F(2) atom to form VO5F octahedra that share corners with three equivalent Li(1)O3F tetrahedra, corners with three equivalent V(6)O4 tetrahedra,  an edgeedge with one V(4)O5F octahedra,  an edgeedge with one V(5)O5F octahedra,  an edgeedge with one V(7)O5F octahedra,  an edgeedge with one V(8)O5F octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one V(1), one V(4), one V(5), and one V(9) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one V(10), one V(6), one V(7), and one V(8) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one V(7), and one V(9) atom. In the fourth O site, O(4) is bonded to one Li(1), one V(10), one V(3), and one V(4) atom to form distorted OLiV3 trigonal pyramids that share  a cornercorner with one O(5)LiV3 trigonal pyramid, corners with two equivalent O(13)V4 trigonal pyramids, and  an edgeedge with one O(6)LiV3 trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(1), one V(2), one V(7), and one V(8) atom to form a mixture of distorted corner and edge-sharing OLiV3 trigonal pyramids. In the sixth O site, O(6) is bonded to one Li(2), one V(3), one V(4), and one V(5) atom to form distorted OLiV3 trigonal pyramids that share  a cornercorner with one O(7)LiV3 trigonal pyramid, corners with three equivalent O(13)V4 trigonal pyramids, and  an edgeedge with one O(4)LiV3 trigonal pyramid. In the seventh O site, O(7) is bonded to one Li(2), one V(2), one V(8), and one V(9) atom to form a mixture of distorted corner and edge-sharing OLiV3 trigonal pyramids. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(10), one V(3), and one V(5) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one V(1), one V(3), one V(5), and one V(9) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one V(10), one V(2), one V(6), and one V(8) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one V(1), one V(3), one V(4), and one V(9) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one V(10), one V(2), one V(6), and one V(7) atom. In the thirteenth O site, O(13) is bonded to one V(3), one V(4), one V(5), and one V(6) atom to form distorted corner-sharing OV4 trigonal pyramids. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one V(1), one V(2), one V(7), and one V(8) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(7), one V(8), and one V(9) atom. In the second F site, F(2) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(10), one V(4), and one V(5) atom. is represented by the CIF file [CIF]
data_LiV5O7F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.047
_cell_length_b   6.050
_cell_length_c   6.057
_cell_angle_alpha   60.358
_cell_angle_beta   60.587
_cell_angle_gamma   61.048
_symmetry_Int_Tables_number   1
_cell_volume   158.999
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  F  F0  1  0.622  0.618  0.622  1.0
  Li  Li1  1  0.764  0.756  0.759  1.0
  O  O2  1  0.123  0.130  0.128  1.0
  O  O3  1  0.162  0.608  0.627  1.0
  O  O4  1  0.624  0.615  0.157  1.0
  O  O5  1  0.618  0.156  0.625  1.0
  O  O6  1  0.128  0.601  0.130  1.0
  O  O7  1  0.600  0.141  0.127  1.0
  O  O8  1  0.129  0.138  0.596  1.0
  V  V9  1  0.994  0.997  0.991  1.0
  V  V10  1  0.379  0.380  0.377  1.0
  V  V11  1  0.370  0.874  0.366  1.0
  V  V12  1  0.869  0.369  0.369  1.0
  V  V13  1  0.368  0.365  0.877  1.0
[/CIF]
.
The structure described by LiV5O7F is Spinel-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(4), one O(5), one O(8), and one F(2) atom to form LiO3F tetrahedra that share  a cornercorner with one V(7)O5F octahedra,  a cornercorner with one V(8)O5F octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent V(4)O5F octahedra, corners with two equivalent V(5)O5F octahedra, corners with two equivalent V(3)O6 octahedra, and corners with three equivalent V(10)O5F octahedra. The corner-sharing octahedral tilt angles range from 53-63°. In the second Li site, Li(2) is bonded to one O(3), one O(6), one O(7), and one F(1) atom to form LiO3F tetrahedra that share  a cornercorner with one V(4)O5F octahedra,  a cornercorner with one V(5)O5F octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent V(7)O5F octahedra, corners with two equivalent V(8)O5F octahedra, corners with two equivalent V(2)O6 octahedra, and corners with three equivalent V(9)O5F octahedra. The corner-sharing octahedral tilt angles range from 54-65°. There are ten inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(11), one O(14), and one O(9) atom to form VO4 tetrahedra that share  a cornercorner with one V(7)O5F octahedra,  a cornercorner with one V(8)O5F octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent V(4)O5F octahedra, corners with two equivalent V(5)O5F octahedra, corners with two equivalent V(3)O6 octahedra, and corners with three equivalent V(9)O5F octahedra. The corner-sharing octahedral tilt angles range from 55-61°. In the second V site, V(2) is bonded to one O(10), one O(12), one O(14), one O(3), one O(5), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra, corners with two equivalent Li(2)O3F tetrahedra, corners with two equivalent V(6)O4 tetrahedra,  an edgeedge with one V(10)O5F octahedra,  an edgeedge with one V(9)O5F octahedra, edges with two equivalent V(7)O5F octahedra, and edges with two equivalent V(8)O5F octahedra. In the third V site, V(3) is bonded to one O(11), one O(13), one O(4), one O(6), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(6)O4 tetrahedra, corners with two equivalent Li(1)O3F tetrahedra, corners with two equivalent V(1)O4 tetrahedra,  an edgeedge with one V(10)O5F octahedra,  an edgeedge with one V(9)O5F octahedra, edges with two equivalent V(4)O5F octahedra, and edges with two equivalent V(5)O5F octahedra. In the fourth V site, V(4) is bonded to one O(1), one O(11), one O(13), one O(4), one O(6), and one F(2) atom to form VO5F octahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(6)O4 tetrahedra, corners with two equivalent Li(1)O3F tetrahedra, corners with two equivalent V(1)O4 tetrahedra,  an edgeedge with one V(10)O5F octahedra,  an edgeedge with one V(9)O5F octahedra, edges with two equivalent V(5)O5F octahedra, and edges with two equivalent V(3)O6 octahedra. In the fifth V site, V(5) is bonded to one O(1), one O(13), one O(6), one O(8), one O(9), and one F(2) atom to form VO5F octahedra that share  a cornercorner with one Li(2)O3F tetrahedra,  a cornercorner with one V(6)O4 tetrahedra, corners with two equivalent Li(1)O3F tetrahedra, corners with two equivalent V(1)O4 tetrahedra,  an edgeedge with one V(10)O5F octahedra,  an edgeedge with one V(9)O5F octahedra, edges with two equivalent V(4)O5F octahedra, and edges with two equivalent V(3)O6 octahedra. In the sixth V site, V(6) is bonded to one O(10), one O(12), one O(13), and one O(2) atom to form VO4 tetrahedra that share  a cornercorner with one V(4)O5F octahedra,  a cornercorner with one V(5)O5F octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent V(7)O5F octahedra, corners with two equivalent V(8)O5F octahedra, corners with two equivalent V(2)O6 octahedra, and corners with three equivalent V(10)O5F octahedra. The corner-sharing octahedral tilt angles range from 53-61°. In the seventh V site, V(7) is bonded to one O(12), one O(14), one O(2), one O(3), one O(5), and one F(1) atom to form VO5F octahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra, corners with two equivalent Li(2)O3F tetrahedra, corners with two equivalent V(6)O4 tetrahedra,  an edgeedge with one V(10)O5F octahedra,  an edgeedge with one V(9)O5F octahedra, edges with two equivalent V(8)O5F octahedra, and edges with two equivalent V(2)O6 octahedra. In the eighth V site, V(8) is bonded to one O(10), one O(14), one O(2), one O(5), one O(7), and one F(1) atom to form VO5F octahedra that share  a cornercorner with one Li(1)O3F tetrahedra,  a cornercorner with one V(1)O4 tetrahedra, corners with two equivalent Li(2)O3F tetrahedra, corners with two equivalent V(6)O4 tetrahedra,  an edgeedge with one V(10)O5F octahedra,  an edgeedge with one V(9)O5F octahedra, edges with two equivalent V(7)O5F octahedra, and edges with two equivalent V(2)O6 octahedra. In the ninth V site, V(9) is bonded to one O(1), one O(11), one O(3), one O(7), one O(9), and one F(1) atom to form VO5F octahedra that share corners with three equivalent Li(2)O3F tetrahedra, corners with three equivalent V(1)O4 tetrahedra,  an edgeedge with one V(4)O5F octahedra,  an edgeedge with one V(5)O5F octahedra,  an edgeedge with one V(7)O5F octahedra,  an edgeedge with one V(8)O5F octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. In the tenth V site, V(10) is bonded to one O(10), one O(12), one O(2), one O(4), one O(8), and one F(2) atom to form VO5F octahedra that share corners with three equivalent Li(1)O3F tetrahedra, corners with three equivalent V(6)O4 tetrahedra,  an edgeedge with one V(4)O5F octahedra,  an edgeedge with one V(5)O5F octahedra,  an edgeedge with one V(7)O5F octahedra,  an edgeedge with one V(8)O5F octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one V(1), one V(4), one V(5), and one V(9) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one V(10), one V(6), one V(7), and one V(8) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one V(7), and one V(9) atom. In the fourth O site, O(4) is bonded to one Li(1), one V(10), one V(3), and one V(4) atom to form distorted OLiV3 trigonal pyramids that share  a cornercorner with one O(5)LiV3 trigonal pyramid, corners with two equivalent O(13)V4 trigonal pyramids, and  an edgeedge with one O(6)LiV3 trigonal pyramid. In the fifth O site, O(5) is bonded to one Li(1), one V(2), one V(7), and one V(8) atom to form a mixture of distorted corner and edge-sharing OLiV3 trigonal pyramids. In the sixth O site, O(6) is bonded to one Li(2), one V(3), one V(4), and one V(5) atom to form distorted OLiV3 trigonal pyramids that share  a cornercorner with one O(7)LiV3 trigonal pyramid, corners with three equivalent O(13)V4 trigonal pyramids, and  an edgeedge with one O(4)LiV3 trigonal pyramid. In the seventh O site, O(7) is bonded to one Li(2), one V(2), one V(8), and one V(9) atom to form a mixture of distorted corner and edge-sharing OLiV3 trigonal pyramids. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(10), one V(3), and one V(5) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one V(1), one V(3), one V(5), and one V(9) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one V(10), one V(2), one V(6), and one V(8) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one V(1), one V(3), one V(4), and one V(9) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one V(10), one V(2), one V(6), and one V(7) atom. In the thirteenth O site, O(13) is bonded to one V(3), one V(4), one V(5), and one V(6) atom to form distorted corner-sharing OV4 trigonal pyramids. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one V(1), one V(2), one V(7), and one V(8) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(7), one V(8), and one V(9) atom. In the second F site, F(2) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(10), one V(4), and one V(5) atom. is represented by the CIF file [CIF]
data_LiV5O7F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.047
_cell_length_b   6.050
_cell_length_c   6.057
_cell_angle_alpha   60.358
_cell_angle_beta   60.587
_cell_angle_gamma   61.048
_symmetry_Int_Tables_number   1
_cell_volume   158.999
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  F  F0  1  0.622  0.618  0.622  1.0
  Li  Li1  1  0.764  0.756  0.759  1.0
  O  O2  1  0.123  0.130  0.128  1.0
  O  O3  1  0.162  0.608  0.627  1.0
  O  O4  1  0.624  0.615  0.157  1.0
  O  O5  1  0.618  0.156  0.625  1.0
  O  O6  1  0.128  0.601  0.130  1.0
  O  O7  1  0.600  0.141  0.127  1.0
  O  O8  1  0.129  0.138  0.596  1.0
  V  V9  1  0.994  0.997  0.991  1.0
  V  V10  1  0.379  0.380  0.377  1.0
  V  V11  1  0.370  0.874  0.366  1.0
  V  V12  1  0.869  0.369  0.369  1.0
  V  V13  1  0.368  0.365  0.877  1.0
[/CIF]
.