The compound described by LiAg(CO2)2 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a see-saw-like geometry to one O(1), one O(4), and two equivalent O(3) atoms. Ag(1) is bonded in a 5-coordinate geometry to one O(1), one O(4), and three equivalent O(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one C(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to three equivalent Ag(1) and one C(2) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to two equivalent Li(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(1), and one C(2) atom. is represented by the CIF card [CIF]
data_LiAg(CO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.898
_cell_length_b   3.961
_cell_length_c   10.361
_cell_angle_alpha   87.521
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   200.815
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.443  0.108  0.898  1.0
  Li  Li1  1  0.943  0.892  0.102  1.0
  Ag  Ag2  1  0.546  0.610  0.586  1.0
  Ag  Ag3  1  0.046  0.390  0.414  1.0
  C  C4  1  0.442  0.108  0.175  1.0
  C  C5  1  0.942  0.892  0.825  1.0
  C  C6  1  0.564  0.901  0.295  1.0
  C  C7  1  0.064  0.099  0.705  1.0
  O  O8  1  0.707  0.763  0.814  1.0
  O  O9  1  0.207  0.237  0.186  1.0
  O  O10  1  0.935  0.087  0.600  1.0
  O  O11  1  0.435  0.913  0.400  1.0
  O  O12  1  0.087  0.886  0.926  1.0
  O  O13  1  0.587  0.114  0.074  1.0
  O  O14  1  0.278  0.268  0.727  1.0
  O  O15  1  0.778  0.732  0.273  1.0
[/CIF]
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The compound described by LiAg(CO2)2 crystallizes in the monoclinic P2_1 space group. Li(1) is bonded in a see-saw-like geometry to one O(1), one O(4), and two equivalent O(3) atoms. Ag(1) is bonded in a 5-coordinate geometry to one O(1), one O(4), and three equivalent O(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1), one Ag(1), and one C(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to three equivalent Ag(1) and one C(2) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to two equivalent Li(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Ag(1), and one C(2) atom. is represented by the CIF card [CIF]
data_LiAg(CO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.898
_cell_length_b   3.961
_cell_length_c   10.361
_cell_angle_alpha   87.521
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   200.815
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.443  0.108  0.898  1.0
  Li  Li1  1  0.943  0.892  0.102  1.0
  Ag  Ag2  1  0.546  0.610  0.586  1.0
  Ag  Ag3  1  0.046  0.390  0.414  1.0
  C  C4  1  0.442  0.108  0.175  1.0
  C  C5  1  0.942  0.892  0.825  1.0
  C  C6  1  0.564  0.901  0.295  1.0
  C  C7  1  0.064  0.099  0.705  1.0
  O  O8  1  0.707  0.763  0.814  1.0
  O  O9  1  0.207  0.237  0.186  1.0
  O  O10  1  0.935  0.087  0.600  1.0
  O  O11  1  0.435  0.913  0.400  1.0
  O  O12  1  0.087  0.886  0.926  1.0
  O  O13  1  0.587  0.114  0.074  1.0
  O  O14  1  0.278  0.268  0.727  1.0
  O  O15  1  0.778  0.732  0.273  1.0
[/CIF]
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