The material structure described by CsNa3U4(MoO10)2 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(10), two equivalent O(8), and two equivalent O(9) atoms. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 7-coordinate geometry to one O(10), one O(2), one O(4), one O(6), one O(8), and two equivalent O(3) atoms. In the second Na site, Na(2) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms to form distorted NaO6 octahedra that share corners with four equivalent U(1)O7 pentagonal bipyramids. There are two inequivalent U sites. In the first U site, U(1) is bonded to one O(3), one O(4), one O(5), two equivalent O(2), and two equivalent O(7) atoms to form distorted UO7 pentagonal bipyramids that share corners with two equivalent Na(2)O6 octahedra and edges with two equivalent U(1)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles range from 54-61°. In the second U site, U(2) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. Mo(1) is bonded in a 5-coordinate geometry to one O(10), one O(5), one O(9), and two equivalent O(1) atoms. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Cs(1), one U(2), and two equivalent Mo(1) atoms. In the second O site, O(2) is bonded to one Na(1), one U(2), and two equivalent U(1) atoms to form distorted edge-sharing ONaU3 trigonal pyramids. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Na(2), two equivalent Na(1), and one U(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one Na(2), and one U(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one U(1), one U(2), and one Mo(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one U(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one U(2) and two equivalent U(1) atoms. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Cs(1), one Na(1), and one U(2) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one U(2), and one Mo(1) atom. In the tenth O site, O(10) is bonded in a 1-coordinate geometry to one Cs(1), one Na(1), and one Mo(1) atom. is represented by the CIF file [CIF]
data_CsNa3U4(MoO10)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.730
_cell_length_b   6.928
_cell_length_c   11.589
_cell_angle_alpha   84.023
_cell_angle_beta   77.130
_cell_angle_gamma   81.136
_symmetry_Int_Tables_number   1
_cell_volume   519.094
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.000  0.500  0.000  1.0
  Na  Na1  1  0.945  0.022  0.332  1.0
  Na  Na2  1  0.055  0.978  0.668  1.0
  Na  Na3  1  0.000  0.500  0.500  1.0
  U  U4  1  0.508  0.242  0.563  1.0
  U  U5  1  0.492  0.758  0.437  1.0
  U  U6  1  0.461  0.267  0.247  1.0
  U  U7  1  0.539  0.733  0.753  1.0
  Mo  Mo8  1  0.392  0.830  0.102  1.0
  Mo  Mo9  1  0.608  0.170  0.898  1.0
  O  O10  1  0.555  0.842  0.947  1.0
  O  O11  1  0.445  0.158  0.053  1.0
  O  O12  1  0.531  0.080  0.398  1.0
  O  O13  1  0.469  0.920  0.602  1.0
  O  O14  1  0.796  0.198  0.527  1.0
  O  O15  1  0.204  0.802  0.473  1.0
  O  O16  1  0.220  0.281  0.604  1.0
  O  O17  1  0.780  0.719  0.396  1.0
  O  O18  1  0.472  0.895  0.233  1.0
  O  O19  1  0.528  0.105  0.767  1.0
  O  O20  1  0.179  0.272  0.298  1.0
  O  O21  1  0.821  0.728  0.702  1.0
  O  O22  1  0.530  0.542  0.608  1.0
  O  O23  1  0.470  0.458  0.392  1.0
  O  O24  1  0.742  0.254  0.191  1.0
  O  O25  1  0.258  0.746  0.809  1.0
  O  O26  1  0.412  0.568  0.133  1.0
  O  O27  1  0.588  0.432  0.867  1.0
  O  O28  1  0.128  0.903  0.114  1.0
  O  O29  1  0.872  0.097  0.886  1.0
[/CIF]
.
The material structure described by CsNa3U4(MoO10)2 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(10), two equivalent O(8), and two equivalent O(9) atoms. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 7-coordinate geometry to one O(10), one O(2), one O(4), one O(6), one O(8), and two equivalent O(3) atoms. In the second Na site, Na(2) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms to form distorted NaO6 octahedra that share corners with four equivalent U(1)O7 pentagonal bipyramids. There are two inequivalent U sites. In the first U site, U(1) is bonded to one O(3), one O(4), one O(5), two equivalent O(2), and two equivalent O(7) atoms to form distorted UO7 pentagonal bipyramids that share corners with two equivalent Na(2)O6 octahedra and edges with two equivalent U(1)O7 pentagonal bipyramids. The corner-sharing octahedral tilt angles range from 54-61°. In the second U site, U(2) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. Mo(1) is bonded in a 5-coordinate geometry to one O(10), one O(5), one O(9), and two equivalent O(1) atoms. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Cs(1), one U(2), and two equivalent Mo(1) atoms. In the second O site, O(2) is bonded to one Na(1), one U(2), and two equivalent U(1) atoms to form distorted edge-sharing ONaU3 trigonal pyramids. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Na(2), two equivalent Na(1), and one U(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one Na(2), and one U(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one U(1), one U(2), and one Mo(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one U(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one U(2) and two equivalent U(1) atoms. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Cs(1), one Na(1), and one U(2) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one U(2), and one Mo(1) atom. In the tenth O site, O(10) is bonded in a 1-coordinate geometry to one Cs(1), one Na(1), and one Mo(1) atom. is represented by the CIF file [CIF]
data_CsNa3U4(MoO10)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.730
_cell_length_b   6.928
_cell_length_c   11.589
_cell_angle_alpha   84.023
_cell_angle_beta   77.130
_cell_angle_gamma   81.136
_symmetry_Int_Tables_number   1
_cell_volume   519.094
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.000  0.500  0.000  1.0
  Na  Na1  1  0.945  0.022  0.332  1.0
  Na  Na2  1  0.055  0.978  0.668  1.0
  Na  Na3  1  0.000  0.500  0.500  1.0
  U  U4  1  0.508  0.242  0.563  1.0
  U  U5  1  0.492  0.758  0.437  1.0
  U  U6  1  0.461  0.267  0.247  1.0
  U  U7  1  0.539  0.733  0.753  1.0
  Mo  Mo8  1  0.392  0.830  0.102  1.0
  Mo  Mo9  1  0.608  0.170  0.898  1.0
  O  O10  1  0.555  0.842  0.947  1.0
  O  O11  1  0.445  0.158  0.053  1.0
  O  O12  1  0.531  0.080  0.398  1.0
  O  O13  1  0.469  0.920  0.602  1.0
  O  O14  1  0.796  0.198  0.527  1.0
  O  O15  1  0.204  0.802  0.473  1.0
  O  O16  1  0.220  0.281  0.604  1.0
  O  O17  1  0.780  0.719  0.396  1.0
  O  O18  1  0.472  0.895  0.233  1.0
  O  O19  1  0.528  0.105  0.767  1.0
  O  O20  1  0.179  0.272  0.298  1.0
  O  O21  1  0.821  0.728  0.702  1.0
  O  O22  1  0.530  0.542  0.608  1.0
  O  O23  1  0.470  0.458  0.392  1.0
  O  O24  1  0.742  0.254  0.191  1.0
  O  O25  1  0.258  0.746  0.809  1.0
  O  O26  1  0.412  0.568  0.133  1.0
  O  O27  1  0.588  0.432  0.867  1.0
  O  O28  1  0.128  0.903  0.114  1.0
  O  O29  1  0.872  0.097  0.886  1.0
[/CIF]
.