The crystal structure described by ThWTeO7 crystallizes in the monoclinic P2_1/c space group. Th(1) is bonded in a 9-coordinate geometry to one O(1), two equivalent O(2), two equivalent O(4), two equivalent O(5), and two equivalent O(7) atoms. W(1) is bonded to one O(6), one O(7), two equivalent O(1), and two equivalent O(3) atoms to form a mixture of distorted corner and edge-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 3°. Te(1) is bonded in a 3-coordinate geometry to one O(4), one O(5), and two equivalent O(2) atoms. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a single-bond geometry to one W(1) atom. In the second O site, O(7) is bonded in a trigonal planar geometry to two equivalent Th(1) and one W(1) atom. In the third O site, O(1) is bonded in a 3-coordinate geometry to one Th(1) and two equivalent W(1) atoms. In the fourth O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Th(1) and two equivalent Te(1) atoms. In the fifth O site, O(3) is bonded in a linear geometry to two equivalent W(1) atoms. In the sixth O site, O(4) is bonded in a trigonal planar geometry to two equivalent Th(1) and one Te(1) atom. In the seventh O site, O(5) is bonded in a trigonal planar geometry to two equivalent Th(1) and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ThTeWO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.096
_cell_length_b   8.681
_cell_length_c   15.683
_cell_angle_alpha   90.000
_cell_angle_beta   92.722
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   556.997
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.497  0.863  0.724  1.0
  Th  Th1  1  0.503  0.363  0.776  1.0
  Th  Th2  1  0.503  0.137  0.276  1.0
  Th  Th3  1  0.497  0.637  0.224  1.0
  Te  Te4  1  0.076  0.075  0.892  1.0
  Te  Te5  1  0.924  0.575  0.608  1.0
  Te  Te6  1  0.924  0.925  0.108  1.0
  Te  Te7  1  0.076  0.425  0.392  1.0
  W  W8  1  0.412  0.652  0.945  1.0
  W  W9  1  0.588  0.152  0.555  1.0
  W  W10  1  0.588  0.348  0.055  1.0
  W  W11  1  0.412  0.848  0.445  1.0
  O  O12  1  0.498  0.586  0.065  1.0
  O  O13  1  0.502  0.086  0.435  1.0
  O  O14  1  0.502  0.414  0.935  1.0
  O  O15  1  0.498  0.914  0.565  1.0
  O  O16  1  0.511  0.097  0.846  1.0
  O  O17  1  0.489  0.597  0.654  1.0
  O  O18  1  0.489  0.903  0.154  1.0
  O  O19  1  0.511  0.403  0.346  1.0
  O  O20  1  0.971  0.646  0.945  1.0
  O  O21  1  0.029  0.146  0.555  1.0
  O  O22  1  0.029  0.354  0.055  1.0
  O  O23  1  0.971  0.854  0.445  1.0
  O  O24  1  0.009  0.268  0.831  1.0
  O  O25  1  0.991  0.768  0.669  1.0
  O  O26  1  0.991  0.732  0.169  1.0
  O  O27  1  0.009  0.232  0.331  1.0
  O  O28  1  0.007  0.931  0.799  1.0
  O  O29  1  0.993  0.431  0.701  1.0
  O  O30  1  0.993  0.069  0.201  1.0
  O  O31  1  0.007  0.569  0.299  1.0
  O  O32  1  0.475  0.856  0.960  1.0
  O  O33  1  0.525  0.356  0.540  1.0
  O  O34  1  0.525  0.144  0.040  1.0
  O  O35  1  0.475  0.644  0.460  1.0
  O  O36  1  0.466  0.641  0.823  1.0
  O  O37  1  0.534  0.141  0.677  1.0
  O  O38  1  0.534  0.359  0.177  1.0
  O  O39  1  0.466  0.859  0.323  1.0
[/CIF]
.
The crystal structure described by ThWTeO7 crystallizes in the monoclinic P2_1/c space group. Th(1) is bonded in a 9-coordinate geometry to one O(1), two equivalent O(2), two equivalent O(4), two equivalent O(5), and two equivalent O(7) atoms. W(1) is bonded to one O(6), one O(7), two equivalent O(1), and two equivalent O(3) atoms to form a mixture of distorted corner and edge-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 3°. Te(1) is bonded in a 3-coordinate geometry to one O(4), one O(5), and two equivalent O(2) atoms. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a single-bond geometry to one W(1) atom. In the second O site, O(7) is bonded in a trigonal planar geometry to two equivalent Th(1) and one W(1) atom. In the third O site, O(1) is bonded in a 3-coordinate geometry to one Th(1) and two equivalent W(1) atoms. In the fourth O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Th(1) and two equivalent Te(1) atoms. In the fifth O site, O(3) is bonded in a linear geometry to two equivalent W(1) atoms. In the sixth O site, O(4) is bonded in a trigonal planar geometry to two equivalent Th(1) and one Te(1) atom. In the seventh O site, O(5) is bonded in a trigonal planar geometry to two equivalent Th(1) and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ThTeWO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.096
_cell_length_b   8.681
_cell_length_c   15.683
_cell_angle_alpha   90.000
_cell_angle_beta   92.722
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   556.997
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.497  0.863  0.724  1.0
  Th  Th1  1  0.503  0.363  0.776  1.0
  Th  Th2  1  0.503  0.137  0.276  1.0
  Th  Th3  1  0.497  0.637  0.224  1.0
  Te  Te4  1  0.076  0.075  0.892  1.0
  Te  Te5  1  0.924  0.575  0.608  1.0
  Te  Te6  1  0.924  0.925  0.108  1.0
  Te  Te7  1  0.076  0.425  0.392  1.0
  W  W8  1  0.412  0.652  0.945  1.0
  W  W9  1  0.588  0.152  0.555  1.0
  W  W10  1  0.588  0.348  0.055  1.0
  W  W11  1  0.412  0.848  0.445  1.0
  O  O12  1  0.498  0.586  0.065  1.0
  O  O13  1  0.502  0.086  0.435  1.0
  O  O14  1  0.502  0.414  0.935  1.0
  O  O15  1  0.498  0.914  0.565  1.0
  O  O16  1  0.511  0.097  0.846  1.0
  O  O17  1  0.489  0.597  0.654  1.0
  O  O18  1  0.489  0.903  0.154  1.0
  O  O19  1  0.511  0.403  0.346  1.0
  O  O20  1  0.971  0.646  0.945  1.0
  O  O21  1  0.029  0.146  0.555  1.0
  O  O22  1  0.029  0.354  0.055  1.0
  O  O23  1  0.971  0.854  0.445  1.0
  O  O24  1  0.009  0.268  0.831  1.0
  O  O25  1  0.991  0.768  0.669  1.0
  O  O26  1  0.991  0.732  0.169  1.0
  O  O27  1  0.009  0.232  0.331  1.0
  O  O28  1  0.007  0.931  0.799  1.0
  O  O29  1  0.993  0.431  0.701  1.0
  O  O30  1  0.993  0.069  0.201  1.0
  O  O31  1  0.007  0.569  0.299  1.0
  O  O32  1  0.475  0.856  0.960  1.0
  O  O33  1  0.525  0.356  0.540  1.0
  O  O34  1  0.525  0.144  0.040  1.0
  O  O35  1  0.475  0.644  0.460  1.0
  O  O36  1  0.466  0.641  0.823  1.0
  O  O37  1  0.534  0.141  0.677  1.0
  O  O38  1  0.534  0.359  0.177  1.0
  O  O39  1  0.466  0.859  0.323  1.0
[/CIF]
.