The material structure described by Cs2SnO3 crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded in a 7-coordinate geometry to three equivalent O(2) and four equivalent O(1) atoms. Sn(1) is bonded to one O(2) and four equivalent O(1) atoms to form distorted edge-sharing SnO5 trigonal bipyramids. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1) and two equivalent Sn(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to six equivalent Cs(1) and one Sn(1) atom. is represented by the CIF file [CIF]
data_Cs2SnO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.865
_cell_length_b   6.865
_cell_length_c   5.837
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   110.763
_symmetry_Int_Tables_number   1
_cell_volume   257.237
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.516  0.193  0.750  1.0
  Cs  Cs1  1  0.807  0.484  0.250  1.0
  Cs  Cs2  1  0.484  0.807  0.250  1.0
  Cs  Cs3  1  0.193  0.516  0.750  1.0
  Sn  Sn4  1  0.083  0.083  0.250  1.0
  Sn  Sn5  1  0.917  0.917  0.750  1.0
  O  O6  1  0.882  0.118  0.000  1.0
  O  O7  1  0.882  0.118  0.500  1.0
  O  O8  1  0.667  0.667  0.750  1.0
  O  O9  1  0.333  0.333  0.250  1.0
  O  O10  1  0.118  0.882  0.000  1.0
  O  O11  1  0.118  0.882  0.500  1.0
[/CIF]
.
The material structure described by Cs2SnO3 crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded in a 7-coordinate geometry to three equivalent O(2) and four equivalent O(1) atoms. Sn(1) is bonded to one O(2) and four equivalent O(1) atoms to form distorted edge-sharing SnO5 trigonal bipyramids. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1) and two equivalent Sn(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to six equivalent Cs(1) and one Sn(1) atom. is represented by the CIF file [CIF]
data_Cs2SnO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.865
_cell_length_b   6.865
_cell_length_c   5.837
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   110.763
_symmetry_Int_Tables_number   1
_cell_volume   257.237
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.516  0.193  0.750  1.0
  Cs  Cs1  1  0.807  0.484  0.250  1.0
  Cs  Cs2  1  0.484  0.807  0.250  1.0
  Cs  Cs3  1  0.193  0.516  0.750  1.0
  Sn  Sn4  1  0.083  0.083  0.250  1.0
  Sn  Sn5  1  0.917  0.917  0.750  1.0
  O  O6  1  0.882  0.118  0.000  1.0
  O  O7  1  0.882  0.118  0.500  1.0
  O  O8  1  0.667  0.667  0.750  1.0
  O  O9  1  0.333  0.333  0.250  1.0
  O  O10  1  0.118  0.882  0.000  1.0
  O  O11  1  0.118  0.882  0.500  1.0
[/CIF]
.