The crystal structure described by V2Mn3O10 crystallizes in the triclinic P-1 space group. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form a mixture of distorted edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles are 18°. In the second Mn site, Mn(2) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(2) atoms to form a mixture of edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles are 18°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one V(1), one Mn(1), and two equivalent Mn(2) atoms. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one V(1), one Mn(1), and two equivalent Mn(2) atoms. In the third O site, O(3) is bonded in an L-shaped geometry to two equivalent V(1) atoms. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one V(1), one Mn(1), and one Mn(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one V(1) and one Mn(2) atom. is represented by the CIF file [CIF]
data_Mn3V2O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.014
_cell_length_b   5.575
_cell_length_c   7.733
_cell_angle_alpha   109.664
_cell_angle_beta   106.870
_cell_angle_gamma   76.849
_symmetry_Int_Tables_number   1
_cell_volume   192.768
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  1.000  0.500  0.000  1.0
  Mn  Mn1  1  0.304  0.985  0.100  1.0
  Mn  Mn2  1  0.696  0.015  0.900  1.0
  O  O3  1  0.944  0.201  0.145  1.0
  O  O4  1  0.056  0.799  0.855  1.0
  O  O5  1  0.660  0.797  0.045  1.0
  O  O6  1  0.340  0.203  0.954  1.0
  O  O7  1  0.921  0.789  0.457  1.0
  O  O8  1  0.079  0.211  0.543  1.0
  O  O9  1  0.803  0.212  0.784  1.0
  O  O10  1  0.197  0.788  0.216  1.0
  O  O11  1  0.545  0.168  0.319  1.0
  O  O12  1  0.455  0.832  0.681  1.0
  V  V13  1  0.901  0.043  0.324  1.0
  V  V14  1  0.099  0.957  0.676  1.0
[/CIF]
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The crystal structure described by V2Mn3O10 crystallizes in the triclinic P-1 space group. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(4) atoms to form a mixture of distorted edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles are 18°. In the second Mn site, Mn(2) is bonded to one O(4), one O(5), two equivalent O(1), and two equivalent O(2) atoms to form a mixture of edge and corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles are 18°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one V(1), one Mn(1), and two equivalent Mn(2) atoms. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one V(1), one Mn(1), and two equivalent Mn(2) atoms. In the third O site, O(3) is bonded in an L-shaped geometry to two equivalent V(1) atoms. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one V(1), one Mn(1), and one Mn(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one V(1) and one Mn(2) atom. is represented by the CIF file [CIF]
data_Mn3V2O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.014
_cell_length_b   5.575
_cell_length_c   7.733
_cell_angle_alpha   109.664
_cell_angle_beta   106.870
_cell_angle_gamma   76.849
_symmetry_Int_Tables_number   1
_cell_volume   192.768
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  1.000  0.500  0.000  1.0
  Mn  Mn1  1  0.304  0.985  0.100  1.0
  Mn  Mn2  1  0.696  0.015  0.900  1.0
  O  O3  1  0.944  0.201  0.145  1.0
  O  O4  1  0.056  0.799  0.855  1.0
  O  O5  1  0.660  0.797  0.045  1.0
  O  O6  1  0.340  0.203  0.954  1.0
  O  O7  1  0.921  0.789  0.457  1.0
  O  O8  1  0.079  0.211  0.543  1.0
  O  O9  1  0.803  0.212  0.784  1.0
  O  O10  1  0.197  0.788  0.216  1.0
  O  O11  1  0.545  0.168  0.319  1.0
  O  O12  1  0.455  0.832  0.681  1.0
  V  V13  1  0.901  0.043  0.324  1.0
  V  V14  1  0.099  0.957  0.676  1.0
[/CIF]
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