The material structure described by LiSnPO4 crystallizes in the orthorhombic P2_12_12_1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), and two equivalent O(3) atoms. Sn(1) is bonded in a distorted pentagonal planar geometry to one O(1), one O(2), one O(3), and two equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Li(1), one Sn(1), and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Sn(1), and one P(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Li(1), one Sn(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Sn(1) and one P(1) atom. is represented by the CIF file [CIF]
data_LiSnPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.375
_cell_length_b   5.622
_cell_length_c   14.191
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   428.868
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.201  0.638  0.250  1.0
  Li  Li1  1  0.299  0.362  0.750  1.0
  Li  Li2  1  0.799  0.138  0.250  1.0
  Li  Li3  1  0.701  0.862  0.750  1.0
  Sn  Sn4  1  0.707  0.971  0.028  1.0
  Sn  Sn5  1  0.793  0.029  0.528  1.0
  Sn  Sn6  1  0.293  0.471  0.472  1.0
  Sn  Sn7  1  0.207  0.529  0.972  1.0
  P  P8  1  0.245  0.835  0.627  1.0
  P  P9  1  0.255  0.165  0.127  1.0
  P  P10  1  0.755  0.335  0.873  1.0
  P  P11  1  0.745  0.665  0.373  1.0
  O  O12  1  0.804  0.926  0.353  1.0
  O  O13  1  0.512  0.079  0.165  1.0
  O  O14  1  0.044  0.997  0.158  1.0
  O  O15  1  0.209  0.850  0.514  1.0
  O  O16  1  0.291  0.150  0.014  1.0
  O  O17  1  0.456  0.003  0.658  1.0
  O  O18  1  0.988  0.921  0.665  1.0
  O  O19  1  0.696  0.074  0.853  1.0
  O  O20  1  0.196  0.426  0.147  1.0
  O  O21  1  0.488  0.579  0.335  1.0
  O  O22  1  0.956  0.497  0.342  1.0
  O  O23  1  0.791  0.350  0.986  1.0
  O  O24  1  0.709  0.650  0.486  1.0
  O  O25  1  0.544  0.503  0.842  1.0
  O  O26  1  0.012  0.421  0.835  1.0
  O  O27  1  0.304  0.574  0.647  1.0
[/CIF]
.
The material structure described by LiSnPO4 crystallizes in the orthorhombic P2_12_12_1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), and two equivalent O(3) atoms. Sn(1) is bonded in a distorted pentagonal planar geometry to one O(1), one O(2), one O(3), and two equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Li(1), one Sn(1), and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Sn(1), and one P(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Li(1), one Sn(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to two equivalent Sn(1) and one P(1) atom. is represented by the CIF file [CIF]
data_LiSnPO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.375
_cell_length_b   5.622
_cell_length_c   14.191
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   428.868
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.201  0.638  0.250  1.0
  Li  Li1  1  0.299  0.362  0.750  1.0
  Li  Li2  1  0.799  0.138  0.250  1.0
  Li  Li3  1  0.701  0.862  0.750  1.0
  Sn  Sn4  1  0.707  0.971  0.028  1.0
  Sn  Sn5  1  0.793  0.029  0.528  1.0
  Sn  Sn6  1  0.293  0.471  0.472  1.0
  Sn  Sn7  1  0.207  0.529  0.972  1.0
  P  P8  1  0.245  0.835  0.627  1.0
  P  P9  1  0.255  0.165  0.127  1.0
  P  P10  1  0.755  0.335  0.873  1.0
  P  P11  1  0.745  0.665  0.373  1.0
  O  O12  1  0.804  0.926  0.353  1.0
  O  O13  1  0.512  0.079  0.165  1.0
  O  O14  1  0.044  0.997  0.158  1.0
  O  O15  1  0.209  0.850  0.514  1.0
  O  O16  1  0.291  0.150  0.014  1.0
  O  O17  1  0.456  0.003  0.658  1.0
  O  O18  1  0.988  0.921  0.665  1.0
  O  O19  1  0.696  0.074  0.853  1.0
  O  O20  1  0.196  0.426  0.147  1.0
  O  O21  1  0.488  0.579  0.335  1.0
  O  O22  1  0.956  0.497  0.342  1.0
  O  O23  1  0.791  0.350  0.986  1.0
  O  O24  1  0.709  0.650  0.486  1.0
  O  O25  1  0.544  0.503  0.842  1.0
  O  O26  1  0.012  0.421  0.835  1.0
  O  O27  1  0.304  0.574  0.647  1.0
[/CIF]
.