The crystal structure described by K2Ru2H13(SO6)4(H2)2 crystallizes in the triclinic P-1 space group. The structure consists of two 1333-74-0 molecules inside a K2Ru2H13(SO6)4 framework. In the K2Ru2H13(SO6)4 framework, K(1) is bonded in a 6-coordinate geometry to one O(11), one O(2), one O(3), one O(4), and two equivalent O(6) atoms. Ru(1) is bonded to one H(1), one O(1), one O(7), one O(9), and two equivalent O(12) atoms to form distorted RuHO5 octahedra that share  a cornercorner with one S(2)O4 tetrahedra and  an edgeedge with one Ru(1)HO5 octahedra. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one O(5) atom. In the fourth H site, H(6) is bonded in a distorted linear geometry to one O(8) and one O(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one O(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. In the seventh H site, H(9) is bonded in a linear geometry to two equivalent O(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one O(12) and one O(3) atom. In the second S site, S(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form SO4 tetrahedra that share  a cornercorner with one Ru(1)HO5 octahedra. The corner-sharing octahedral tilt angles are 37°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ru(1) and one O(10) atom. In the second O site, O(2) is bonded in a single-bond geometry to one K(1), one H(9), and one O(11) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one K(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one K(1), one H(2), and one H(8) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one H(5) and one S(2) atom. In the sixth O site, O(6) is bonded in a 1-coordinate geometry to two equivalent K(1) and one S(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Ru(1) and one S(2) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one H(6) and one S(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(6), and one H(7) atom. In the tenth O site, O(10) is bonded in a 1-coordinate geometry to one O(1) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one K(1) and one O(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to two equivalent Ru(1) and one S(1) atom. is represented by the CIF file [CIF]
data_K2H17Ru2(SO6)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.134
_cell_length_b   9.252
_cell_length_c   9.646
_cell_angle_alpha   68.898
_cell_angle_beta   66.080
_cell_angle_gamma   77.181
_symmetry_Int_Tables_number   1
_cell_volume   692.346
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.559  0.498  0.787  1.0
  K  K1  1  0.441  0.502  0.213  1.0
  H  H2  1  0.207  0.231  0.014  1.0
  H  H3  1  0.793  0.769  0.986  1.0
  H  H4  1  0.097  0.388  0.147  1.0
  H  H5  1  0.903  0.612  0.853  1.0
  H  H6  1  0.150  0.628  0.572  1.0
  H  H7  1  0.850  0.372  0.428  1.0
  H  H8  1  0.876  0.377  0.491  1.0
  H  H9  1  0.124  0.623  0.509  1.0
  H  H10  1  0.339  0.076  0.649  1.0
  H  H11  1  0.661  0.924  0.351  1.0
  H  H12  1  0.242  0.018  0.275  1.0
  H  H13  1  0.758  0.982  0.725  1.0
  H  H14  1  0.862  0.113  0.696  1.0
  H  H15  1  0.138  0.887  0.304  1.0
  H  H16  1  0.832  0.487  0.012  1.0
  H  H17  1  0.168  0.513  0.988  1.0
  H  H18  1  0.500  0.500  0.500  1.0
  Ru  Ru19  1  0.112  0.092  0.055  1.0
  Ru  Ru20  1  0.888  0.908  0.945  1.0
  S  S21  1  0.983  0.309  0.790  1.0
  S  S22  1  0.017  0.691  0.210  1.0
  S  S23  1  0.562  0.082  0.183  1.0
  S  S24  1  0.438  0.918  0.817  1.0
  O  O25  1  0.926  0.223  0.108  1.0
  O  O26  1  0.074  0.777  0.892  1.0
  O  O27  1  0.450  0.382  0.606  1.0
  O  O28  1  0.550  0.618  0.394  1.0
  O  O29  1  0.850  0.309  0.740  1.0
  O  O30  1  0.150  0.691  0.260  1.0
  O  O31  1  0.808  0.551  0.915  1.0
  O  O32  1  0.192  0.449  0.085  1.0
  O  O33  1  0.658  0.038  0.300  1.0
  O  O34  1  0.342  0.962  0.700  1.0
  O  O35  1  0.548  0.251  0.123  1.0
  O  O36  1  0.452  0.749  0.877  1.0
  O  O37  1  0.341  0.987  0.949  1.0
  O  O38  1  0.659  0.013  0.051  1.0
  O  O39  1  0.411  0.011  0.277  1.0
  O  O40  1  0.589  0.989  0.723  1.0
  O  O41  1  0.136  0.001  0.276  1.0
  O  O42  1  0.864  0.999  0.724  1.0
  O  O43  1  0.903  0.335  0.176  1.0
  O  O44  1  0.097  0.665  0.824  1.0
  O  O45  1  0.378  0.319  0.546  1.0
  O  O46  1  0.622  0.681  0.454  1.0
  O  O47  1  0.957  0.861  0.140  1.0
  O  O48  1  0.043  0.139  0.860  1.0
[/CIF]
.
The crystal structure described by K2Ru2H13(SO6)4(H2)2 crystallizes in the triclinic P-1 space group. The structure consists of two 1333-74-0 molecules inside a K2Ru2H13(SO6)4 framework. In the K2Ru2H13(SO6)4 framework, K(1) is bonded in a 6-coordinate geometry to one O(11), one O(2), one O(3), one O(4), and two equivalent O(6) atoms. Ru(1) is bonded to one H(1), one O(1), one O(7), one O(9), and two equivalent O(12) atoms to form distorted RuHO5 octahedra that share  a cornercorner with one S(2)O4 tetrahedra and  an edgeedge with one Ru(1)HO5 octahedra. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one O(5) atom. In the fourth H site, H(6) is bonded in a distorted linear geometry to one O(8) and one O(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one O(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one O(4) atom. In the seventh H site, H(9) is bonded in a linear geometry to two equivalent O(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one O(12) and one O(3) atom. In the second S site, S(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form SO4 tetrahedra that share  a cornercorner with one Ru(1)HO5 octahedra. The corner-sharing octahedral tilt angles are 37°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ru(1) and one O(10) atom. In the second O site, O(2) is bonded in a single-bond geometry to one K(1), one H(9), and one O(11) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one K(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one K(1), one H(2), and one H(8) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one H(5) and one S(2) atom. In the sixth O site, O(6) is bonded in a 1-coordinate geometry to two equivalent K(1) and one S(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Ru(1) and one S(2) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one H(6) and one S(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Ru(1), one H(6), and one H(7) atom. In the tenth O site, O(10) is bonded in a 1-coordinate geometry to one O(1) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one K(1) and one O(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to two equivalent Ru(1) and one S(1) atom. is represented by the CIF file [CIF]
data_K2H17Ru2(SO6)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.134
_cell_length_b   9.252
_cell_length_c   9.646
_cell_angle_alpha   68.898
_cell_angle_beta   66.080
_cell_angle_gamma   77.181
_symmetry_Int_Tables_number   1
_cell_volume   692.346
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.559  0.498  0.787  1.0
  K  K1  1  0.441  0.502  0.213  1.0
  H  H2  1  0.207  0.231  0.014  1.0
  H  H3  1  0.793  0.769  0.986  1.0
  H  H4  1  0.097  0.388  0.147  1.0
  H  H5  1  0.903  0.612  0.853  1.0
  H  H6  1  0.150  0.628  0.572  1.0
  H  H7  1  0.850  0.372  0.428  1.0
  H  H8  1  0.876  0.377  0.491  1.0
  H  H9  1  0.124  0.623  0.509  1.0
  H  H10  1  0.339  0.076  0.649  1.0
  H  H11  1  0.661  0.924  0.351  1.0
  H  H12  1  0.242  0.018  0.275  1.0
  H  H13  1  0.758  0.982  0.725  1.0
  H  H14  1  0.862  0.113  0.696  1.0
  H  H15  1  0.138  0.887  0.304  1.0
  H  H16  1  0.832  0.487  0.012  1.0
  H  H17  1  0.168  0.513  0.988  1.0
  H  H18  1  0.500  0.500  0.500  1.0
  Ru  Ru19  1  0.112  0.092  0.055  1.0
  Ru  Ru20  1  0.888  0.908  0.945  1.0
  S  S21  1  0.983  0.309  0.790  1.0
  S  S22  1  0.017  0.691  0.210  1.0
  S  S23  1  0.562  0.082  0.183  1.0
  S  S24  1  0.438  0.918  0.817  1.0
  O  O25  1  0.926  0.223  0.108  1.0
  O  O26  1  0.074  0.777  0.892  1.0
  O  O27  1  0.450  0.382  0.606  1.0
  O  O28  1  0.550  0.618  0.394  1.0
  O  O29  1  0.850  0.309  0.740  1.0
  O  O30  1  0.150  0.691  0.260  1.0
  O  O31  1  0.808  0.551  0.915  1.0
  O  O32  1  0.192  0.449  0.085  1.0
  O  O33  1  0.658  0.038  0.300  1.0
  O  O34  1  0.342  0.962  0.700  1.0
  O  O35  1  0.548  0.251  0.123  1.0
  O  O36  1  0.452  0.749  0.877  1.0
  O  O37  1  0.341  0.987  0.949  1.0
  O  O38  1  0.659  0.013  0.051  1.0
  O  O39  1  0.411  0.011  0.277  1.0
  O  O40  1  0.589  0.989  0.723  1.0
  O  O41  1  0.136  0.001  0.276  1.0
  O  O42  1  0.864  0.999  0.724  1.0
  O  O43  1  0.903  0.335  0.176  1.0
  O  O44  1  0.097  0.665  0.824  1.0
  O  O45  1  0.378  0.319  0.546  1.0
  O  O46  1  0.622  0.681  0.454  1.0
  O  O47  1  0.957  0.861  0.140  1.0
  O  O48  1  0.043  0.139  0.860  1.0
[/CIF]
.