The material described by OsN5H12OClCl2 is Indium-derived structured and crystallizes in the tetragonal I4mm space group. The structure is zero-dimensional and consists of four hydrochloric acid atoms and two OsN5H12OCl clusters. In each OsN5H12OCl cluster, Os(1) is bonded in an octahedral geometry to one N(1), four equivalent N(2), and one Cl(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Os(1) and one O(1) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one Os(1), one H(1), and two equivalent H(2) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. Cl(2) is bonded in a single-bond geometry to one Os(1) atom. is represented by the CIF card [CIF]
data_H12OsN5Cl3O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.918
_cell_length_b   6.918
_cell_length_c   6.918
_cell_angle_alpha   113.070
_cell_angle_beta   113.070
_cell_angle_gamma   102.490
_symmetry_Int_Tables_number   1
_cell_volume   252.051
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.132  0.132  0.451  1.0
  H  H1  1  0.132  0.681  0.000  1.0
  H  H2  1  0.681  0.132  0.000  1.0
  H  H3  1  0.681  0.681  0.549  1.0
  H  H4  1  0.760  0.916  0.530  1.0
  H  H5  1  0.385  0.230  0.470  1.0
  H  H6  1  0.230  0.760  0.844  1.0
  H  H7  1  0.916  0.385  0.156  1.0
  H  H8  1  0.916  0.760  0.530  1.0
  H  H9  1  0.760  0.230  0.844  1.0
  H  H10  1  0.230  0.385  0.470  1.0
  H  H11  1  0.385  0.916  0.156  1.0
  Os  Os12  1  0.032  0.032  0.000  1.0
  N  N13  1  0.234  0.234  0.000  1.0
  N  N14  1  0.821  0.821  0.604  1.0
  N  N15  1  0.821  0.218  0.000  1.0
  N  N16  1  0.218  0.821  0.000  1.0
  N  N17  1  0.218  0.218  0.396  1.0
  Cl  Cl18  1  0.730  0.230  0.500  1.0
  Cl  Cl19  1  0.230  0.730  0.500  1.0
  Cl  Cl20  1  0.763  0.763  0.000  1.0
  O  O21  1  0.371  0.371  0.000  1.0
[/CIF]
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The material described by OsN5H12OClCl2 is Indium-derived structured and crystallizes in the tetragonal I4mm space group. The structure is zero-dimensional and consists of four hydrochloric acid atoms and two OsN5H12OCl clusters. In each OsN5H12OCl cluster, Os(1) is bonded in an octahedral geometry to one N(1), four equivalent N(2), and one Cl(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Os(1) and one O(1) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one Os(1), one H(1), and two equivalent H(2) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. O(1) is bonded in a single-bond geometry to one N(1) atom. Cl(2) is bonded in a single-bond geometry to one Os(1) atom. is represented by the CIF card [CIF]
data_H12OsN5Cl3O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.918
_cell_length_b   6.918
_cell_length_c   6.918
_cell_angle_alpha   113.070
_cell_angle_beta   113.070
_cell_angle_gamma   102.490
_symmetry_Int_Tables_number   1
_cell_volume   252.051
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.132  0.132  0.451  1.0
  H  H1  1  0.132  0.681  0.000  1.0
  H  H2  1  0.681  0.132  0.000  1.0
  H  H3  1  0.681  0.681  0.549  1.0
  H  H4  1  0.760  0.916  0.530  1.0
  H  H5  1  0.385  0.230  0.470  1.0
  H  H6  1  0.230  0.760  0.844  1.0
  H  H7  1  0.916  0.385  0.156  1.0
  H  H8  1  0.916  0.760  0.530  1.0
  H  H9  1  0.760  0.230  0.844  1.0
  H  H10  1  0.230  0.385  0.470  1.0
  H  H11  1  0.385  0.916  0.156  1.0
  Os  Os12  1  0.032  0.032  0.000  1.0
  N  N13  1  0.234  0.234  0.000  1.0
  N  N14  1  0.821  0.821  0.604  1.0
  N  N15  1  0.821  0.218  0.000  1.0
  N  N16  1  0.218  0.821  0.000  1.0
  N  N17  1  0.218  0.218  0.396  1.0
  Cl  Cl18  1  0.730  0.230  0.500  1.0
  Cl  Cl19  1  0.230  0.730  0.500  1.0
  Cl  Cl20  1  0.763  0.763  0.000  1.0
  O  O21  1  0.371  0.371  0.000  1.0
[/CIF]
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