The material described by Ca2WPdO6 crystallizes in the orthorhombic Imm2 space group. Ca(1) is bonded in a 7-coordinate geometry to two equivalent O(2), two equivalent O(3), and three equivalent O(1) atoms. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent Pd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-13°. Pd(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form PdO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-13°. There are three inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Ca(1), one W(1), and one Pd(1) atom to form distorted corner-sharing OCa3PdW trigonal bipyramids. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to two equivalent Ca(1), one W(1), and one Pd(1) atom. In the third O site, O(3) is bonded in a see-saw-like geometry to two equivalent Ca(1), one W(1), and one Pd(1) atom. is represented by the CIF card [CIF]
data_Ca2PdWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.811
_cell_length_b   5.811
_cell_length_c   5.811
_cell_angle_alpha   121.995
_cell_angle_beta   116.652
_cell_angle_gamma   91.237
_symmetry_Int_Tables_number   1
_cell_volume   139.785
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.827  0.252  0.576  1.0
  Ca  Ca1  1  0.324  0.748  0.576  1.0
  Pd  Pd2  1  0.484  0.500  0.984  1.0
  W  W3  1  0.975  0.000  0.975  1.0
  O  O4  1  0.195  0.237  0.957  1.0
  O  O5  1  0.720  0.763  0.957  1.0
  O  O6  1  0.180  0.743  0.923  1.0
  O  O7  1  0.180  0.257  0.437  1.0
  O  O8  1  0.722  0.777  0.500  1.0
  O  O9  1  0.722  0.223  0.945  1.0
[/CIF]
.
The material described by Ca2WPdO6 crystallizes in the orthorhombic Imm2 space group. Ca(1) is bonded in a 7-coordinate geometry to two equivalent O(2), two equivalent O(3), and three equivalent O(1) atoms. W(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form WO6 octahedra that share corners with six equivalent Pd(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-13°. Pd(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form PdO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 8-13°. There are three inequivalent O sites. In the first O site, O(1) is bonded to three equivalent Ca(1), one W(1), and one Pd(1) atom to form distorted corner-sharing OCa3PdW trigonal bipyramids. In the second O site, O(2) is bonded in a distorted see-saw-like geometry to two equivalent Ca(1), one W(1), and one Pd(1) atom. In the third O site, O(3) is bonded in a see-saw-like geometry to two equivalent Ca(1), one W(1), and one Pd(1) atom. is represented by the CIF card [CIF]
data_Ca2PdWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.811
_cell_length_b   5.811
_cell_length_c   5.811
_cell_angle_alpha   121.995
_cell_angle_beta   116.652
_cell_angle_gamma   91.237
_symmetry_Int_Tables_number   1
_cell_volume   139.785
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ca  Ca0  1  0.827  0.252  0.576  1.0
  Ca  Ca1  1  0.324  0.748  0.576  1.0
  Pd  Pd2  1  0.484  0.500  0.984  1.0
  W  W3  1  0.975  0.000  0.975  1.0
  O  O4  1  0.195  0.237  0.957  1.0
  O  O5  1  0.720  0.763  0.957  1.0
  O  O6  1  0.180  0.743  0.923  1.0
  O  O7  1  0.180  0.257  0.437  1.0
  O  O8  1  0.722  0.777  0.500  1.0
  O  O9  1  0.722  0.223  0.945  1.0
[/CIF]
.