The compound described by Gd5B3O13 crystallizes in the hexagonal P6_3/m space group. There are two inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(4), and four equivalent O(2) atoms. In the second Gd site, Gd(2) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(3) atoms. B(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one Gd(1), two equivalent Gd(2), and one B(1) atom. In the second O site, O(4) is bonded in a trigonal planar geometry to three equivalent Gd(1) atoms. In the third O site, O(1) is bonded in a 4-coordinate geometry to one Gd(1), two equivalent Gd(2), and one B(1) atom. In the fourth O site, O(2) is bonded in a 1-coordinate geometry to one Gd(2), two equivalent Gd(1), and one B(1) atom. is represented by the CIF card [CIF]
data_Gd5B3O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.062
_cell_length_b   9.062
_cell_length_c   6.842
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   486.585
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.251  0.239  0.250  1.0
  Gd  Gd1  1  0.749  0.761  0.750  1.0
  Gd  Gd2  1  0.761  0.011  0.250  1.0
  Gd  Gd3  1  0.239  0.989  0.750  1.0
  Gd  Gd4  1  0.989  0.749  0.250  1.0
  Gd  Gd5  1  0.011  0.251  0.750  1.0
  Gd  Gd6  1  0.333  0.667  0.001  1.0
  Gd  Gd7  1  0.667  0.333  0.999  1.0
  Gd  Gd8  1  0.667  0.333  0.501  1.0
  Gd  Gd9  1  0.333  0.667  0.499  1.0
  B  B10  1  0.030  0.400  0.250  1.0
  B  B11  1  0.970  0.600  0.750  1.0
  B  B12  1  0.600  0.630  0.250  1.0
  B  B13  1  0.400  0.370  0.750  1.0
  B  B14  1  0.370  0.970  0.250  1.0
  B  B15  1  0.630  0.030  0.750  1.0
  O  O16  1  0.124  0.589  0.250  1.0
  O  O17  1  0.876  0.411  0.750  1.0
  O  O18  1  0.411  0.535  0.250  1.0
  O  O19  1  0.589  0.465  0.750  1.0
  O  O20  1  0.465  0.876  0.250  1.0
  O  O21  1  0.535  0.124  0.750  1.0
  O  O22  1  0.089  0.347  0.074  1.0
  O  O23  1  0.911  0.653  0.926  1.0
  O  O24  1  0.653  0.742  0.074  1.0
  O  O25  1  0.911  0.653  0.574  1.0
  O  O26  1  0.347  0.258  0.926  1.0
  O  O27  1  0.089  0.347  0.426  1.0
  O  O28  1  0.258  0.911  0.074  1.0
  O  O29  1  0.347  0.258  0.574  1.0
  O  O30  1  0.742  0.089  0.926  1.0
  O  O31  1  0.653  0.742  0.426  1.0
  O  O32  1  0.742  0.089  0.574  1.0
  O  O33  1  0.258  0.911  0.426  1.0
  O  O34  1  0.482  0.155  0.250  1.0
  O  O35  1  0.518  0.845  0.750  1.0
  O  O36  1  0.845  0.327  0.250  1.0
  O  O37  1  0.155  0.673  0.750  1.0
  O  O38  1  0.673  0.518  0.250  1.0
  O  O39  1  0.327  0.482  0.750  1.0
  O  O40  1  0.000  0.000  0.250  1.0
  O  O41  1  0.000  0.000  0.750  1.0
[/CIF]
.
The compound described by Gd5B3O13 crystallizes in the hexagonal P6_3/m space group. There are two inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(4), and four equivalent O(2) atoms. In the second Gd site, Gd(2) is bonded in a 9-coordinate geometry to three equivalent O(1), three equivalent O(2), and three equivalent O(3) atoms. B(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one Gd(1), two equivalent Gd(2), and one B(1) atom. In the second O site, O(4) is bonded in a trigonal planar geometry to three equivalent Gd(1) atoms. In the third O site, O(1) is bonded in a 4-coordinate geometry to one Gd(1), two equivalent Gd(2), and one B(1) atom. In the fourth O site, O(2) is bonded in a 1-coordinate geometry to one Gd(2), two equivalent Gd(1), and one B(1) atom. is represented by the CIF card [CIF]
data_Gd5B3O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.062
_cell_length_b   9.062
_cell_length_c   6.842
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   486.585
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.251  0.239  0.250  1.0
  Gd  Gd1  1  0.749  0.761  0.750  1.0
  Gd  Gd2  1  0.761  0.011  0.250  1.0
  Gd  Gd3  1  0.239  0.989  0.750  1.0
  Gd  Gd4  1  0.989  0.749  0.250  1.0
  Gd  Gd5  1  0.011  0.251  0.750  1.0
  Gd  Gd6  1  0.333  0.667  0.001  1.0
  Gd  Gd7  1  0.667  0.333  0.999  1.0
  Gd  Gd8  1  0.667  0.333  0.501  1.0
  Gd  Gd9  1  0.333  0.667  0.499  1.0
  B  B10  1  0.030  0.400  0.250  1.0
  B  B11  1  0.970  0.600  0.750  1.0
  B  B12  1  0.600  0.630  0.250  1.0
  B  B13  1  0.400  0.370  0.750  1.0
  B  B14  1  0.370  0.970  0.250  1.0
  B  B15  1  0.630  0.030  0.750  1.0
  O  O16  1  0.124  0.589  0.250  1.0
  O  O17  1  0.876  0.411  0.750  1.0
  O  O18  1  0.411  0.535  0.250  1.0
  O  O19  1  0.589  0.465  0.750  1.0
  O  O20  1  0.465  0.876  0.250  1.0
  O  O21  1  0.535  0.124  0.750  1.0
  O  O22  1  0.089  0.347  0.074  1.0
  O  O23  1  0.911  0.653  0.926  1.0
  O  O24  1  0.653  0.742  0.074  1.0
  O  O25  1  0.911  0.653  0.574  1.0
  O  O26  1  0.347  0.258  0.926  1.0
  O  O27  1  0.089  0.347  0.426  1.0
  O  O28  1  0.258  0.911  0.074  1.0
  O  O29  1  0.347  0.258  0.574  1.0
  O  O30  1  0.742  0.089  0.926  1.0
  O  O31  1  0.653  0.742  0.426  1.0
  O  O32  1  0.742  0.089  0.574  1.0
  O  O33  1  0.258  0.911  0.426  1.0
  O  O34  1  0.482  0.155  0.250  1.0
  O  O35  1  0.518  0.845  0.750  1.0
  O  O36  1  0.845  0.327  0.250  1.0
  O  O37  1  0.155  0.673  0.750  1.0
  O  O38  1  0.673  0.518  0.250  1.0
  O  O39  1  0.327  0.482  0.750  1.0
  O  O40  1  0.000  0.000  0.250  1.0
  O  O41  1  0.000  0.000  0.750  1.0
[/CIF]
.