The compound described by Sn(H2O)3(ClO4)2 is Indium-derived structured and crystallizes in the hexagonal P6_3 space group. The structure is zero-dimensional and consists of four hypochlorous acid;trihydrate molecules and two Sn(H2O)3 clusters. In each Sn(H2O)3 cluster, Sn(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. There are two inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted water-like geometry to one Sn(1), one H(1), and one H(2) atom. is represented by the CIF file [CIF]
data_SnH6Cl2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.266
_cell_length_b   7.266
_cell_length_c   9.984
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   456.493
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.000  0.000  0.524  1.0
  Sn  Sn1  1  0.000  0.000  0.024  1.0
  H  H2  1  0.819  0.217  0.662  1.0
  H  H3  1  0.783  0.602  0.662  1.0
  H  H4  1  0.398  0.181  0.662  1.0
  H  H5  1  0.181  0.783  0.162  1.0
  H  H6  1  0.217  0.398  0.162  1.0
  H  H7  1  0.602  0.819  0.162  1.0
  H  H8  1  0.048  0.297  0.725  1.0
  H  H9  1  0.703  0.751  0.725  1.0
  H  H10  1  0.249  0.952  0.725  1.0
  H  H11  1  0.952  0.703  0.225  1.0
  H  H12  1  0.297  0.249  0.225  1.0
  H  H13  1  0.751  0.048  0.225  1.0
  Cl  Cl14  1  0.667  0.333  0.407  1.0
  Cl  Cl15  1  0.333  0.667  0.907  1.0
  Cl  Cl16  1  0.333  0.667  0.479  1.0
  Cl  Cl17  1  0.667  0.333  0.979  1.0
  O  O18  1  0.922  0.172  0.686  1.0
  O  O19  1  0.828  0.750  0.686  1.0
  O  O20  1  0.250  0.078  0.686  1.0
  O  O21  1  0.078  0.828  0.186  1.0
  O  O22  1  0.172  0.250  0.186  1.0
  O  O23  1  0.750  0.922  0.186  1.0
  O  O24  1  0.160  0.695  0.529  1.0
  O  O25  1  0.305  0.464  0.529  1.0
  O  O26  1  0.536  0.840  0.529  1.0
  O  O27  1  0.840  0.305  0.029  1.0
  O  O28  1  0.695  0.536  0.029  1.0
  O  O29  1  0.464  0.160  0.029  1.0
  O  O30  1  0.333  0.667  0.334  1.0
  O  O31  1  0.667  0.333  0.834  1.0
  O  O32  1  0.743  0.550  0.360  1.0
  O  O33  1  0.450  0.193  0.360  1.0
  O  O34  1  0.807  0.257  0.360  1.0
  O  O35  1  0.257  0.450  0.860  1.0
  O  O36  1  0.550  0.807  0.860  1.0
  O  O37  1  0.193  0.743  0.860  1.0
  O  O38  1  0.667  0.333  0.556  1.0
  O  O39  1  0.333  0.667  0.056  1.0
[/CIF]
.
The compound described by Sn(H2O)3(ClO4)2 is Indium-derived structured and crystallizes in the hexagonal P6_3 space group. The structure is zero-dimensional and consists of four hypochlorous acid;trihydrate molecules and two Sn(H2O)3 clusters. In each Sn(H2O)3 cluster, Sn(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. There are two inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(1) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted water-like geometry to one Sn(1), one H(1), and one H(2) atom. is represented by the CIF file [CIF]
data_SnH6Cl2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.266
_cell_length_b   7.266
_cell_length_c   9.984
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   456.493
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.000  0.000  0.524  1.0
  Sn  Sn1  1  0.000  0.000  0.024  1.0
  H  H2  1  0.819  0.217  0.662  1.0
  H  H3  1  0.783  0.602  0.662  1.0
  H  H4  1  0.398  0.181  0.662  1.0
  H  H5  1  0.181  0.783  0.162  1.0
  H  H6  1  0.217  0.398  0.162  1.0
  H  H7  1  0.602  0.819  0.162  1.0
  H  H8  1  0.048  0.297  0.725  1.0
  H  H9  1  0.703  0.751  0.725  1.0
  H  H10  1  0.249  0.952  0.725  1.0
  H  H11  1  0.952  0.703  0.225  1.0
  H  H12  1  0.297  0.249  0.225  1.0
  H  H13  1  0.751  0.048  0.225  1.0
  Cl  Cl14  1  0.667  0.333  0.407  1.0
  Cl  Cl15  1  0.333  0.667  0.907  1.0
  Cl  Cl16  1  0.333  0.667  0.479  1.0
  Cl  Cl17  1  0.667  0.333  0.979  1.0
  O  O18  1  0.922  0.172  0.686  1.0
  O  O19  1  0.828  0.750  0.686  1.0
  O  O20  1  0.250  0.078  0.686  1.0
  O  O21  1  0.078  0.828  0.186  1.0
  O  O22  1  0.172  0.250  0.186  1.0
  O  O23  1  0.750  0.922  0.186  1.0
  O  O24  1  0.160  0.695  0.529  1.0
  O  O25  1  0.305  0.464  0.529  1.0
  O  O26  1  0.536  0.840  0.529  1.0
  O  O27  1  0.840  0.305  0.029  1.0
  O  O28  1  0.695  0.536  0.029  1.0
  O  O29  1  0.464  0.160  0.029  1.0
  O  O30  1  0.333  0.667  0.334  1.0
  O  O31  1  0.667  0.333  0.834  1.0
  O  O32  1  0.743  0.550  0.360  1.0
  O  O33  1  0.450  0.193  0.360  1.0
  O  O34  1  0.807  0.257  0.360  1.0
  O  O35  1  0.257  0.450  0.860  1.0
  O  O36  1  0.550  0.807  0.860  1.0
  O  O37  1  0.193  0.743  0.860  1.0
  O  O38  1  0.667  0.333  0.556  1.0
  O  O39  1  0.333  0.667  0.056  1.0
[/CIF]
.