The crystal structure described by Hf9W4P crystallizes in the hexagonal P6_3/mmc space group. There are four inequivalent Hf sites. In the first Hf site, Hf(1) is bonded in a 5-coordinate geometry to one W(1), one W(3), two equivalent W(2), and one P(1) atom. In the second Hf site, Hf(2,3) is bonded in a 6-coordinate geometry to one Hf(2,3); two equivalent Hf(5); two equivalent W(2); and one P(1) atom. In the third Hf site, Hf(4) is bonded in a single-bond geometry to one P(1) atom. In the fourth Hf site, Hf(5) is bonded in a distorted linear geometry to four equivalent Hf(2,3); one W(1); and one W(2) atom. There are three inequivalent W sites. In the first W site, W(3) is bonded in a linear geometry to two equivalent Hf(1) atoms. In the second W site, W(1) is bonded in a 4-coordinate geometry to two equivalent Hf(1) and two equivalent Hf(5) atoms. In the third W site, W(2) is bonded in a 7-coordinate geometry to one Hf(5); two equivalent Hf(1); and four equivalent Hf(2,3) atoms. P(1) is bonded in a 7-coordinate geometry to one Hf(4); two equivalent Hf(1); and four equivalent Hf(2,3) atoms. is represented by the CIF card [CIF]
data_Hf9PW4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.661
_cell_length_b   8.666
_cell_length_c   8.666
_cell_angle_alpha   120.074
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   562.876
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf0  1  0.549  0.803  0.606  1.0
  Hf  Hf1  1  0.549  0.803  0.197  1.0
  Hf  Hf2  1  0.549  0.394  0.197  1.0
  Hf  Hf3  1  0.451  0.197  0.394  1.0
  Hf  Hf4  1  0.451  0.197  0.803  1.0
  Hf  Hf5  1  0.451  0.606  0.803  1.0
  Hf  Hf6  1  0.049  0.197  0.394  1.0
  Hf  Hf7  1  0.049  0.197  0.803  1.0
  Hf  Hf8  1  0.049  0.606  0.803  1.0
  Hf  Hf9  1  0.951  0.803  0.606  1.0
  Hf  Hf10  1  0.951  0.803  0.197  1.0
  Hf  Hf11  1  0.951  0.394  0.197  1.0
  Hf  Hf12  1  0.750  0.461  0.922  1.0
  Hf  Hf13  1  0.750  0.461  0.539  1.0
  Hf  Hf14  1  0.750  0.078  0.539  1.0
  Hf  Hf15  1  0.250  0.539  0.078  1.0
  Hf  Hf16  1  0.250  0.539  0.461  1.0
  Hf  Hf17  1  0.250  0.922  0.461  1.0
  P  P18  1  0.750  0.667  0.333  1.0
  P  P19  1  0.250  0.333  0.667  1.0
  W  W20  1  0.750  0.110  0.221  1.0
  W  W21  1  0.750  0.111  0.889  1.0
  W  W22  1  0.750  0.779  0.890  1.0
  W  W23  1  0.250  0.890  0.779  1.0
  W  W24  1  0.250  0.889  0.111  1.0
  W  W25  1  0.250  0.221  0.110  1.0
  W  W26  1  0.500  0.000  0.000  1.0
  W  W27  1  0.000  0.000  0.000  1.0
[/CIF]
.
The crystal structure described by Hf9W4P crystallizes in the hexagonal P6_3/mmc space group. There are four inequivalent Hf sites. In the first Hf site, Hf(1) is bonded in a 5-coordinate geometry to one W(1), one W(3), two equivalent W(2), and one P(1) atom. In the second Hf site, Hf(2,3) is bonded in a 6-coordinate geometry to one Hf(2,3); two equivalent Hf(5); two equivalent W(2); and one P(1) atom. In the third Hf site, Hf(4) is bonded in a single-bond geometry to one P(1) atom. In the fourth Hf site, Hf(5) is bonded in a distorted linear geometry to four equivalent Hf(2,3); one W(1); and one W(2) atom. There are three inequivalent W sites. In the first W site, W(3) is bonded in a linear geometry to two equivalent Hf(1) atoms. In the second W site, W(1) is bonded in a 4-coordinate geometry to two equivalent Hf(1) and two equivalent Hf(5) atoms. In the third W site, W(2) is bonded in a 7-coordinate geometry to one Hf(5); two equivalent Hf(1); and four equivalent Hf(2,3) atoms. P(1) is bonded in a 7-coordinate geometry to one Hf(4); two equivalent Hf(1); and four equivalent Hf(2,3) atoms. is represented by the CIF card [CIF]
data_Hf9PW4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.661
_cell_length_b   8.666
_cell_length_c   8.666
_cell_angle_alpha   120.074
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   562.876
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hf  Hf0  1  0.549  0.803  0.606  1.0
  Hf  Hf1  1  0.549  0.803  0.197  1.0
  Hf  Hf2  1  0.549  0.394  0.197  1.0
  Hf  Hf3  1  0.451  0.197  0.394  1.0
  Hf  Hf4  1  0.451  0.197  0.803  1.0
  Hf  Hf5  1  0.451  0.606  0.803  1.0
  Hf  Hf6  1  0.049  0.197  0.394  1.0
  Hf  Hf7  1  0.049  0.197  0.803  1.0
  Hf  Hf8  1  0.049  0.606  0.803  1.0
  Hf  Hf9  1  0.951  0.803  0.606  1.0
  Hf  Hf10  1  0.951  0.803  0.197  1.0
  Hf  Hf11  1  0.951  0.394  0.197  1.0
  Hf  Hf12  1  0.750  0.461  0.922  1.0
  Hf  Hf13  1  0.750  0.461  0.539  1.0
  Hf  Hf14  1  0.750  0.078  0.539  1.0
  Hf  Hf15  1  0.250  0.539  0.078  1.0
  Hf  Hf16  1  0.250  0.539  0.461  1.0
  Hf  Hf17  1  0.250  0.922  0.461  1.0
  P  P18  1  0.750  0.667  0.333  1.0
  P  P19  1  0.250  0.333  0.667  1.0
  W  W20  1  0.750  0.110  0.221  1.0
  W  W21  1  0.750  0.111  0.889  1.0
  W  W22  1  0.750  0.779  0.890  1.0
  W  W23  1  0.250  0.890  0.779  1.0
  W  W24  1  0.250  0.889  0.111  1.0
  W  W25  1  0.250  0.221  0.110  1.0
  W  W26  1  0.500  0.000  0.000  1.0
  W  W27  1  0.000  0.000  0.000  1.0
[/CIF]
.