The structure described by Na3SbF6 crystallizes in the triclinic P-1 space group. There are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a linear geometry to two equivalent F(2) atoms. In the second Na site, Na(2) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(3) atoms. In the third Na site, Na(3) is bonded in a linear geometry to two equivalent F(1) atoms. Sb(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal non-coplanar geometry to one Na(2), one Na(3), and one Sb(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one Sb(1) atom. In the third F site, F(3) is bonded in a water-like geometry to one Na(2) and one Sb(1) atom. is represented by the CIF file [CIF]
data_Na3SbF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.768
_cell_length_b   7.553
_cell_length_c   8.016
_cell_angle_alpha   72.857
_cell_angle_beta   112.226
_cell_angle_gamma   125.555
_symmetry_Int_Tables_number   1
_cell_volume   307.062
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.500  1.0
  Na  Na1  1  0.500  0.500  0.000  1.0
  Na  Na2  1  0.000  0.500  0.000  1.0
  Sb  Sb3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.080  0.335  0.877  1.0
  F  F5  1  0.920  0.665  0.123  1.0
  F  F6  1  0.948  0.869  0.762  1.0
  F  F7  1  0.052  0.131  0.238  1.0
  F  F8  1  0.592  0.836  0.939  1.0
  F  F9  1  0.408  0.164  0.061  1.0
[/CIF]
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The structure described by Na3SbF6 crystallizes in the triclinic P-1 space group. There are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a linear geometry to two equivalent F(2) atoms. In the second Na site, Na(2) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(3) atoms. In the third Na site, Na(3) is bonded in a linear geometry to two equivalent F(1) atoms. Sb(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal non-coplanar geometry to one Na(2), one Na(3), and one Sb(1) atom. In the second F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one Sb(1) atom. In the third F site, F(3) is bonded in a water-like geometry to one Na(2) and one Sb(1) atom. is represented by the CIF file [CIF]
data_Na3SbF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.768
_cell_length_b   7.553
_cell_length_c   8.016
_cell_angle_alpha   72.857
_cell_angle_beta   112.226
_cell_angle_gamma   125.555
_symmetry_Int_Tables_number   1
_cell_volume   307.062
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.000  0.000  0.500  1.0
  Na  Na1  1  0.500  0.500  0.000  1.0
  Na  Na2  1  0.000  0.500  0.000  1.0
  Sb  Sb3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.080  0.335  0.877  1.0
  F  F5  1  0.920  0.665  0.123  1.0
  F  F6  1  0.948  0.869  0.762  1.0
  F  F7  1  0.052  0.131  0.238  1.0
  F  F8  1  0.592  0.836  0.939  1.0
  F  F9  1  0.408  0.164  0.061  1.0
[/CIF]
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