The structure described by GaBr4SeBr3 is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two GaBr4 clusters and two SeBr3 clusters. In each GaBr4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Br(2), one Br(3), one Br(4), and one Br(5) atom. There are four inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one Ga(1) atom. In the second Br site, Br(3) is bonded in a single-bond geometry to one Ga(1) atom. In the third Br site, Br(4) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth Br site, Br(5) is bonded in a single-bond geometry to one Ga(1) atom. In each SeBr3 cluster, Se(1) is bonded in a 3-coordinate geometry to one Br(1), one Br(6), and one Br(7) atom. There are three inequivalent Br sites. In the first Br site, Br(7) is bonded in a single-bond geometry to one Se(1) atom. In the second Br site, Br(1) is bonded in a single-bond geometry to one Se(1) atom. In the third Br site, Br(6) is bonded in a single-bond geometry to one Se(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_GaSeBr7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.580
_cell_length_b   6.719
_cell_length_c   14.898
_cell_angle_alpha   102.637
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   642.780
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.996  0.661  0.501  1.0
  Ga  Ga1  1  0.004  0.661  0.001  1.0
  Se  Se2  1  0.588  0.952  0.663  1.0
  Se  Se3  1  0.412  0.952  0.163  1.0
  Br  Br4  1  0.612  0.826  0.268  1.0
  Br  Br5  1  0.388  0.826  0.768  1.0
  Br  Br6  1  0.122  0.991  0.001  1.0
  Br  Br7  1  0.878  0.991  0.501  1.0
  Br  Br8  1  0.124  0.581  0.138  1.0
  Br  Br9  1  0.876  0.581  0.638  1.0
  Br  Br10  1  0.149  0.441  0.873  1.0
  Br  Br11  1  0.851  0.441  0.373  1.0
  Br  Br12  1  0.651  0.632  0.994  1.0
  Br  Br13  1  0.349  0.632  0.494  1.0
  Br  Br14  1  0.380  0.212  0.633  1.0
  Br  Br15  1  0.620  0.212  0.133  1.0
  Br  Br16  1  0.817  0.152  0.766  1.0
  Br  Br17  1  0.183  0.152  0.266  1.0
[/CIF]
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The structure described by GaBr4SeBr3 is Indium-derived structured and crystallizes in the monoclinic Pc space group. The structure is zero-dimensional and consists of two GaBr4 clusters and two SeBr3 clusters. In each GaBr4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Br(2), one Br(3), one Br(4), and one Br(5) atom. There are four inequivalent Br sites. In the first Br site, Br(2) is bonded in a single-bond geometry to one Ga(1) atom. In the second Br site, Br(3) is bonded in a single-bond geometry to one Ga(1) atom. In the third Br site, Br(4) is bonded in a single-bond geometry to one Ga(1) atom. In the fourth Br site, Br(5) is bonded in a single-bond geometry to one Ga(1) atom. In each SeBr3 cluster, Se(1) is bonded in a 3-coordinate geometry to one Br(1), one Br(6), and one Br(7) atom. There are three inequivalent Br sites. In the first Br site, Br(7) is bonded in a single-bond geometry to one Se(1) atom. In the second Br site, Br(1) is bonded in a single-bond geometry to one Se(1) atom. In the third Br site, Br(6) is bonded in a single-bond geometry to one Se(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_GaSeBr7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.580
_cell_length_b   6.719
_cell_length_c   14.898
_cell_angle_alpha   102.637
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   642.780
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.996  0.661  0.501  1.0
  Ga  Ga1  1  0.004  0.661  0.001  1.0
  Se  Se2  1  0.588  0.952  0.663  1.0
  Se  Se3  1  0.412  0.952  0.163  1.0
  Br  Br4  1  0.612  0.826  0.268  1.0
  Br  Br5  1  0.388  0.826  0.768  1.0
  Br  Br6  1  0.122  0.991  0.001  1.0
  Br  Br7  1  0.878  0.991  0.501  1.0
  Br  Br8  1  0.124  0.581  0.138  1.0
  Br  Br9  1  0.876  0.581  0.638  1.0
  Br  Br10  1  0.149  0.441  0.873  1.0
  Br  Br11  1  0.851  0.441  0.373  1.0
  Br  Br12  1  0.651  0.632  0.994  1.0
  Br  Br13  1  0.349  0.632  0.494  1.0
  Br  Br14  1  0.380  0.212  0.633  1.0
  Br  Br15  1  0.620  0.212  0.133  1.0
  Br  Br16  1  0.817  0.152  0.766  1.0
  Br  Br17  1  0.183  0.152  0.266  1.0
[/CIF]
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