The compound described by PNCl2 is Ammonia-derived structured and crystallizes in the tetragonal P4_2/n space group. The structure is zero-dimensional and consists of eight dichloro(imino)phosphanium molecules. P(1) is bonded in a distorted trigonal planar geometry to one N(1), one Cl(1), and one Cl(2) atom. N(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_PNCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.561
_cell_length_b   13.561
_cell_length_c   7.724
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1420.363
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.068  0.795  0.714  1.0
  P  P1  1  0.568  0.295  0.786  1.0
  P  P2  1  0.932  0.205  0.714  1.0
  P  P3  1  0.432  0.705  0.786  1.0
  P  P4  1  0.205  0.068  0.286  1.0
  P  P5  1  0.705  0.568  0.214  1.0
  P  P6  1  0.295  0.432  0.214  1.0
  P  P7  1  0.795  0.932  0.286  1.0
  N  N8  1  0.344  0.344  0.293  1.0
  N  N9  1  0.656  0.656  0.293  1.0
  N  N10  1  0.844  0.844  0.207  1.0
  N  N11  1  0.156  0.844  0.793  1.0
  N  N12  1  0.344  0.656  0.707  1.0
  N  N13  1  0.844  0.156  0.793  1.0
  N  N14  1  0.156  0.156  0.207  1.0
  N  N15  1  0.656  0.344  0.707  1.0
  Cl  Cl16  1  0.254  0.944  0.171  1.0
  Cl  Cl17  1  0.273  0.460  0.960  1.0
  Cl  Cl18  1  0.727  0.540  0.960  1.0
  Cl  Cl19  1  0.960  0.227  0.460  1.0
  Cl  Cl20  1  0.460  0.727  0.040  1.0
  Cl  Cl21  1  0.556  0.754  0.671  1.0
  Cl  Cl22  1  0.040  0.773  0.460  1.0
  Cl  Cl23  1  0.944  0.746  0.829  1.0
  Cl  Cl24  1  0.227  0.040  0.540  1.0
  Cl  Cl25  1  0.754  0.444  0.329  1.0
  Cl  Cl26  1  0.246  0.556  0.329  1.0
  Cl  Cl27  1  0.540  0.273  0.040  1.0
  Cl  Cl28  1  0.056  0.254  0.829  1.0
  Cl  Cl29  1  0.746  0.056  0.171  1.0
  Cl  Cl30  1  0.444  0.246  0.671  1.0
  Cl  Cl31  1  0.773  0.960  0.540  1.0
[/CIF]
.
The compound described by PNCl2 is Ammonia-derived structured and crystallizes in the tetragonal P4_2/n space group. The structure is zero-dimensional and consists of eight dichloro(imino)phosphanium molecules. P(1) is bonded in a distorted trigonal planar geometry to one N(1), one Cl(1), and one Cl(2) atom. N(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_PNCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.561
_cell_length_b   13.561
_cell_length_c   7.724
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1420.363
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.068  0.795  0.714  1.0
  P  P1  1  0.568  0.295  0.786  1.0
  P  P2  1  0.932  0.205  0.714  1.0
  P  P3  1  0.432  0.705  0.786  1.0
  P  P4  1  0.205  0.068  0.286  1.0
  P  P5  1  0.705  0.568  0.214  1.0
  P  P6  1  0.295  0.432  0.214  1.0
  P  P7  1  0.795  0.932  0.286  1.0
  N  N8  1  0.344  0.344  0.293  1.0
  N  N9  1  0.656  0.656  0.293  1.0
  N  N10  1  0.844  0.844  0.207  1.0
  N  N11  1  0.156  0.844  0.793  1.0
  N  N12  1  0.344  0.656  0.707  1.0
  N  N13  1  0.844  0.156  0.793  1.0
  N  N14  1  0.156  0.156  0.207  1.0
  N  N15  1  0.656  0.344  0.707  1.0
  Cl  Cl16  1  0.254  0.944  0.171  1.0
  Cl  Cl17  1  0.273  0.460  0.960  1.0
  Cl  Cl18  1  0.727  0.540  0.960  1.0
  Cl  Cl19  1  0.960  0.227  0.460  1.0
  Cl  Cl20  1  0.460  0.727  0.040  1.0
  Cl  Cl21  1  0.556  0.754  0.671  1.0
  Cl  Cl22  1  0.040  0.773  0.460  1.0
  Cl  Cl23  1  0.944  0.746  0.829  1.0
  Cl  Cl24  1  0.227  0.040  0.540  1.0
  Cl  Cl25  1  0.754  0.444  0.329  1.0
  Cl  Cl26  1  0.246  0.556  0.329  1.0
  Cl  Cl27  1  0.540  0.273  0.040  1.0
  Cl  Cl28  1  0.056  0.254  0.829  1.0
  Cl  Cl29  1  0.746  0.056  0.171  1.0
  Cl  Cl30  1  0.444  0.246  0.671  1.0
  Cl  Cl31  1  0.773  0.960  0.540  1.0
[/CIF]
.