The compound described by Cs5CoAgCl8 crystallizes in the orthorhombic Fmm2 space group. There are four inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 10-coordinate geometry to two equivalent Cl(2), two equivalent Cl(3), two equivalent Cl(7), and four equivalent Cl(1) atoms. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), one Cl(5), one Cl(6), and two equivalent Cl(7) atoms. In the third Cs site, Cs(3) is bonded in a 8-coordinate geometry to one Cl(2), one Cl(5), two equivalent Cl(1), two equivalent Cl(4), and two equivalent Cl(7) atoms. In the fourth Cs site, Cs(4) is bonded in a 8-coordinate geometry to one Cl(3), one Cl(6), two equivalent Cl(1), two equivalent Cl(4), and two equivalent Cl(7) atoms. Co(1) is bonded in a tetrahedral geometry to one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. Ag(1) is bonded in a 3-coordinate geometry to one Cl(4) and two equivalent Cl(7) atoms. There are seven inequivalent Cl sites. In the first Cl site, Cl(4) is bonded to two equivalent Cs(2), two equivalent Cs(3), two equivalent Cs(4), and one Ag(1) atom to form distorted ClCs6Ag pentagonal bipyramids that share corners with four equivalent Cl(7)Cs5Ag octahedra, edges with two equivalent Cl(7)Cs5Ag octahedra, edges with two equivalent Cl(5)Cs6 pentagonal pyramids, edges with two equivalent Cl(6)Cs6 pentagonal pyramids, faces with two equivalent Cl(7)Cs5Ag octahedra, and  a faceface with one Cl(4)Cs6Ag pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 43-44°. In the second Cl site, Cl(5) is bonded to two equivalent Cs(3) and four equivalent Cs(2) atoms to form distorted ClCs6 pentagonal pyramids that share corners with four equivalent Cl(7)Cs5Ag octahedra, edges with four equivalent Cl(7)Cs5Ag octahedra, edges with four equivalent Cl(4)Cs6Ag pentagonal bipyramids, and  a faceface with one Cl(6)Cs6 pentagonal pyramid. The corner-sharing octahedral tilt angles are 43°. In the third Cl site, Cl(6) is bonded to two equivalent Cs(4) and four equivalent Cs(2) atoms to form distorted ClCs6 pentagonal pyramids that share corners with four equivalent Cl(7)Cs5Ag octahedra, edges with four equivalent Cl(7)Cs5Ag octahedra, edges with four equivalent Cl(4)Cs6Ag pentagonal bipyramids, and  a faceface with one Cl(5)Cs6 pentagonal pyramid. The corner-sharing octahedral tilt angles are 44°. In the fourth Cl site, Cl(7) is bonded to one Cs(1), one Cs(3), one Cs(4), two equivalent Cs(2), and one Ag(1) atom to form distorted ClCs5Ag octahedra that share corners with six equivalent Cl(7)Cs5Ag octahedra, corners with two equivalent Cl(4)Cs6Ag pentagonal bipyramids,  a cornercorner with one Cl(5)Cs6 pentagonal pyramid,  a cornercorner with one Cl(6)Cs6 pentagonal pyramid,  an edgeedge with one Cl(4)Cs6Ag pentagonal bipyramid,  an edgeedge with one Cl(5)Cs6 pentagonal pyramid,  an edgeedge with one Cl(6)Cs6 pentagonal pyramid, and  a faceface with one Cl(4)Cs6Ag pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 1-42°. In the fifth Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), one Cs(4), two equivalent Cs(1), and one Co(1) atom. In the sixth Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Cs(3), two equivalent Cs(1), two equivalent Cs(2), and one Co(1) atom. In the seventh Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Cs(4), two equivalent Cs(1), two equivalent Cs(2), and one Co(1) atom. is represented by the CIF card [CIF]
data_Cs5CoAgCl8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.773
_cell_length_b   13.769
_cell_length_c   9.438
_cell_angle_alpha   69.984
_cell_angle_beta   69.937
_cell_angle_gamma   40.079
_symmetry_Int_Tables_number   1
_cell_volume   1072.899
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.249  0.251  0.251  1.0
  Cs  Cs1  1  0.749  0.751  0.751  1.0
  Cs  Cs2  1  0.060  0.753  0.256  1.0
  Cs  Cs3  1  0.744  0.068  0.940  1.0
  Cs  Cs4  1  0.248  0.566  0.752  1.0
  Cs  Cs5  1  0.566  0.247  0.434  1.0
  Cs  Cs6  1  0.932  0.256  0.753  1.0
  Cs  Cs7  1  0.247  0.940  0.068  1.0
  Cs  Cs8  1  0.753  0.434  0.247  1.0
  Cs  Cs9  1  0.434  0.752  0.566  1.0
  Co  Co10  1  0.250  0.250  0.750  1.0
  Co  Co11  1  0.750  0.750  0.250  1.0
  Ag  Ag12  1  0.470  0.530  0.032  1.0
  Ag  Ag13  1  0.968  0.032  0.530  1.0
  Cl  Cl14  1  0.170  0.443  0.558  1.0
  Cl  Cl15  1  0.442  0.170  0.830  1.0
  Cl  Cl16  1  0.942  0.670  0.058  1.0
  Cl  Cl17  1  0.669  0.943  0.331  1.0
  Cl  Cl18  1  0.830  0.558  0.443  1.0
  Cl  Cl19  1  0.557  0.830  0.170  1.0
  Cl  Cl20  1  0.057  0.331  0.943  1.0
  Cl  Cl21  1  0.330  0.058  0.670  1.0
  Cl  Cl22  1  0.362  0.638  0.342  1.0
  Cl  Cl23  1  0.658  0.342  0.638  1.0
  Cl  Cl24  1  0.146  0.854  0.854  1.0
  Cl  Cl25  1  0.854  0.146  0.146  1.0
  Cl  Cl26  1  0.395  0.406  0.103  1.0
  Cl  Cl27  1  0.897  0.903  0.605  1.0
  Cl  Cl28  1  0.594  0.605  0.903  1.0
  Cl  Cl29  1  0.097  0.103  0.406  1.0
[/CIF]
.
The compound described by Cs5CoAgCl8 crystallizes in the orthorhombic Fmm2 space group. There are four inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 10-coordinate geometry to two equivalent Cl(2), two equivalent Cl(3), two equivalent Cl(7), and four equivalent Cl(1) atoms. In the second Cs site, Cs(2) is bonded in a 8-coordinate geometry to one Cl(1), one Cl(2), one Cl(3), one Cl(4), one Cl(5), one Cl(6), and two equivalent Cl(7) atoms. In the third Cs site, Cs(3) is bonded in a 8-coordinate geometry to one Cl(2), one Cl(5), two equivalent Cl(1), two equivalent Cl(4), and two equivalent Cl(7) atoms. In the fourth Cs site, Cs(4) is bonded in a 8-coordinate geometry to one Cl(3), one Cl(6), two equivalent Cl(1), two equivalent Cl(4), and two equivalent Cl(7) atoms. Co(1) is bonded in a tetrahedral geometry to one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. Ag(1) is bonded in a 3-coordinate geometry to one Cl(4) and two equivalent Cl(7) atoms. There are seven inequivalent Cl sites. In the first Cl site, Cl(4) is bonded to two equivalent Cs(2), two equivalent Cs(3), two equivalent Cs(4), and one Ag(1) atom to form distorted ClCs6Ag pentagonal bipyramids that share corners with four equivalent Cl(7)Cs5Ag octahedra, edges with two equivalent Cl(7)Cs5Ag octahedra, edges with two equivalent Cl(5)Cs6 pentagonal pyramids, edges with two equivalent Cl(6)Cs6 pentagonal pyramids, faces with two equivalent Cl(7)Cs5Ag octahedra, and  a faceface with one Cl(4)Cs6Ag pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 43-44°. In the second Cl site, Cl(5) is bonded to two equivalent Cs(3) and four equivalent Cs(2) atoms to form distorted ClCs6 pentagonal pyramids that share corners with four equivalent Cl(7)Cs5Ag octahedra, edges with four equivalent Cl(7)Cs5Ag octahedra, edges with four equivalent Cl(4)Cs6Ag pentagonal bipyramids, and  a faceface with one Cl(6)Cs6 pentagonal pyramid. The corner-sharing octahedral tilt angles are 43°. In the third Cl site, Cl(6) is bonded to two equivalent Cs(4) and four equivalent Cs(2) atoms to form distorted ClCs6 pentagonal pyramids that share corners with four equivalent Cl(7)Cs5Ag octahedra, edges with four equivalent Cl(7)Cs5Ag octahedra, edges with four equivalent Cl(4)Cs6Ag pentagonal bipyramids, and  a faceface with one Cl(5)Cs6 pentagonal pyramid. The corner-sharing octahedral tilt angles are 44°. In the fourth Cl site, Cl(7) is bonded to one Cs(1), one Cs(3), one Cs(4), two equivalent Cs(2), and one Ag(1) atom to form distorted ClCs5Ag octahedra that share corners with six equivalent Cl(7)Cs5Ag octahedra, corners with two equivalent Cl(4)Cs6Ag pentagonal bipyramids,  a cornercorner with one Cl(5)Cs6 pentagonal pyramid,  a cornercorner with one Cl(6)Cs6 pentagonal pyramid,  an edgeedge with one Cl(4)Cs6Ag pentagonal bipyramid,  an edgeedge with one Cl(5)Cs6 pentagonal pyramid,  an edgeedge with one Cl(6)Cs6 pentagonal pyramid, and  a faceface with one Cl(4)Cs6Ag pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 1-42°. In the fifth Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), one Cs(4), two equivalent Cs(1), and one Co(1) atom. In the sixth Cl site, Cl(2) is bonded in a distorted single-bond geometry to one Cs(3), two equivalent Cs(1), two equivalent Cs(2), and one Co(1) atom. In the seventh Cl site, Cl(3) is bonded in a distorted single-bond geometry to one Cs(4), two equivalent Cs(1), two equivalent Cs(2), and one Co(1) atom. is represented by the CIF card [CIF]
data_Cs5CoAgCl8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.773
_cell_length_b   13.769
_cell_length_c   9.438
_cell_angle_alpha   69.984
_cell_angle_beta   69.937
_cell_angle_gamma   40.079
_symmetry_Int_Tables_number   1
_cell_volume   1072.899
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.249  0.251  0.251  1.0
  Cs  Cs1  1  0.749  0.751  0.751  1.0
  Cs  Cs2  1  0.060  0.753  0.256  1.0
  Cs  Cs3  1  0.744  0.068  0.940  1.0
  Cs  Cs4  1  0.248  0.566  0.752  1.0
  Cs  Cs5  1  0.566  0.247  0.434  1.0
  Cs  Cs6  1  0.932  0.256  0.753  1.0
  Cs  Cs7  1  0.247  0.940  0.068  1.0
  Cs  Cs8  1  0.753  0.434  0.247  1.0
  Cs  Cs9  1  0.434  0.752  0.566  1.0
  Co  Co10  1  0.250  0.250  0.750  1.0
  Co  Co11  1  0.750  0.750  0.250  1.0
  Ag  Ag12  1  0.470  0.530  0.032  1.0
  Ag  Ag13  1  0.968  0.032  0.530  1.0
  Cl  Cl14  1  0.170  0.443  0.558  1.0
  Cl  Cl15  1  0.442  0.170  0.830  1.0
  Cl  Cl16  1  0.942  0.670  0.058  1.0
  Cl  Cl17  1  0.669  0.943  0.331  1.0
  Cl  Cl18  1  0.830  0.558  0.443  1.0
  Cl  Cl19  1  0.557  0.830  0.170  1.0
  Cl  Cl20  1  0.057  0.331  0.943  1.0
  Cl  Cl21  1  0.330  0.058  0.670  1.0
  Cl  Cl22  1  0.362  0.638  0.342  1.0
  Cl  Cl23  1  0.658  0.342  0.638  1.0
  Cl  Cl24  1  0.146  0.854  0.854  1.0
  Cl  Cl25  1  0.854  0.146  0.146  1.0
  Cl  Cl26  1  0.395  0.406  0.103  1.0
  Cl  Cl27  1  0.897  0.903  0.605  1.0
  Cl  Cl28  1  0.594  0.605  0.903  1.0
  Cl  Cl29  1  0.097  0.103  0.406  1.0
[/CIF]
.