The crystal structure described by WIn2O6 crystallizes in the orthorhombic P2_12_12_1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with four equivalent In(2)O6 octahedra and  an edgeedge with one In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 5-coordinate geometry to one O(2), one O(4), one O(6), and two equivalent O(1) atoms. In the second In site, In(2) is bonded to one O(2), one O(3), one O(4), one O(6), and two equivalent O(5) atoms to form InO6 octahedra that share corners with two equivalent In(2)O6 octahedra, corners with four equivalent W(1)O6 octahedra, and  an edgeedge with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1) and two equivalent In(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1), one In(1), and one In(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one W(1) and one In(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one In(1), and one In(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent In(2) atoms. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one W(1), one In(1), and one In(2) atom. is represented by the CIF file [CIF]
data_In2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.004
_cell_length_b   9.095
_cell_length_c   10.284
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   468.016
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.985  0.368  0.071  1.0
  In  In1  1  0.006  0.309  0.647  1.0
  In  In2  1  0.494  0.691  0.147  1.0
  In  In3  1  0.515  0.632  0.571  1.0
  In  In4  1  0.485  0.132  0.929  1.0
  In  In5  1  0.506  0.191  0.353  1.0
  In  In6  1  0.994  0.809  0.853  1.0
  In  In7  1  0.015  0.868  0.429  1.0
  W  W8  1  0.014  0.994  0.138  1.0
  W  W9  1  0.486  0.006  0.638  1.0
  W  W10  1  0.514  0.506  0.862  1.0
  W  W11  1  0.986  0.494  0.362  1.0
  O  O12  1  0.186  0.656  0.449  1.0
  O  O13  1  0.199  0.515  0.207  1.0
  O  O14  1  0.232  0.850  0.676  1.0
  O  O15  1  0.222  0.849  0.230  1.0
  O  O16  1  0.224  0.351  0.443  1.0
  O  O17  1  0.283  0.039  0.475  1.0
  O  O18  1  0.217  0.961  0.975  1.0
  O  O19  1  0.276  0.649  0.943  1.0
  O  O20  1  0.278  0.151  0.730  1.0
  O  O21  1  0.268  0.150  0.176  1.0
  O  O22  1  0.301  0.485  0.707  1.0
  O  O23  1  0.314  0.344  0.949  1.0
  O  O24  1  0.686  0.844  0.551  1.0
  O  O25  1  0.699  0.985  0.793  1.0
  O  O26  1  0.732  0.650  0.324  1.0
  O  O27  1  0.722  0.651  0.770  1.0
  O  O28  1  0.724  0.149  0.557  1.0
  O  O29  1  0.783  0.461  0.525  1.0
  O  O30  1  0.717  0.539  0.025  1.0
  O  O31  1  0.776  0.851  0.057  1.0
  O  O32  1  0.778  0.349  0.270  1.0
  O  O33  1  0.768  0.350  0.824  1.0
  O  O34  1  0.801  0.015  0.293  1.0
  O  O35  1  0.814  0.156  0.051  1.0
[/CIF]
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The crystal structure described by WIn2O6 crystallizes in the orthorhombic P2_12_12_1 space group. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with four equivalent In(2)O6 octahedra and  an edgeedge with one In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. There are two inequivalent In sites. In the first In site, In(1) is bonded in a 5-coordinate geometry to one O(2), one O(4), one O(6), and two equivalent O(1) atoms. In the second In site, In(2) is bonded to one O(2), one O(3), one O(4), one O(6), and two equivalent O(5) atoms to form InO6 octahedra that share corners with two equivalent In(2)O6 octahedra, corners with four equivalent W(1)O6 octahedra, and  an edgeedge with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-57°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one W(1) and two equivalent In(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one W(1), one In(1), and one In(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one W(1) and one In(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one W(1), one In(1), and one In(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one W(1) and two equivalent In(2) atoms. In the sixth O site, O(6) is bonded in a trigonal non-coplanar geometry to one W(1), one In(1), and one In(2) atom. is represented by the CIF file [CIF]
data_In2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.004
_cell_length_b   9.095
_cell_length_c   10.284
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   468.016
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.985  0.368  0.071  1.0
  In  In1  1  0.006  0.309  0.647  1.0
  In  In2  1  0.494  0.691  0.147  1.0
  In  In3  1  0.515  0.632  0.571  1.0
  In  In4  1  0.485  0.132  0.929  1.0
  In  In5  1  0.506  0.191  0.353  1.0
  In  In6  1  0.994  0.809  0.853  1.0
  In  In7  1  0.015  0.868  0.429  1.0
  W  W8  1  0.014  0.994  0.138  1.0
  W  W9  1  0.486  0.006  0.638  1.0
  W  W10  1  0.514  0.506  0.862  1.0
  W  W11  1  0.986  0.494  0.362  1.0
  O  O12  1  0.186  0.656  0.449  1.0
  O  O13  1  0.199  0.515  0.207  1.0
  O  O14  1  0.232  0.850  0.676  1.0
  O  O15  1  0.222  0.849  0.230  1.0
  O  O16  1  0.224  0.351  0.443  1.0
  O  O17  1  0.283  0.039  0.475  1.0
  O  O18  1  0.217  0.961  0.975  1.0
  O  O19  1  0.276  0.649  0.943  1.0
  O  O20  1  0.278  0.151  0.730  1.0
  O  O21  1  0.268  0.150  0.176  1.0
  O  O22  1  0.301  0.485  0.707  1.0
  O  O23  1  0.314  0.344  0.949  1.0
  O  O24  1  0.686  0.844  0.551  1.0
  O  O25  1  0.699  0.985  0.793  1.0
  O  O26  1  0.732  0.650  0.324  1.0
  O  O27  1  0.722  0.651  0.770  1.0
  O  O28  1  0.724  0.149  0.557  1.0
  O  O29  1  0.783  0.461  0.525  1.0
  O  O30  1  0.717  0.539  0.025  1.0
  O  O31  1  0.776  0.851  0.057  1.0
  O  O32  1  0.778  0.349  0.270  1.0
  O  O33  1  0.768  0.350  0.824  1.0
  O  O34  1  0.801  0.015  0.293  1.0
  O  O35  1  0.814  0.156  0.051  1.0
[/CIF]
.