The structure described by Cs7Au5O2 crystallizes in the orthorhombic Immm space group. There are three inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a distorted single-bond geometry to three equivalent Au(1), three equivalent Au(2), and one O(1) atom. In the second Cs site, Cs(2) is bonded in a distorted linear geometry to two equivalent Au(1), two equivalent Au(2), and two equivalent O(1) atoms. In the third Cs site, Cs(3) is bonded in a distorted linear geometry to four equivalent Au(1) and two equivalent O(1) atoms. There are three inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted q6 geometry to two equivalent Cs(2), two equivalent Cs(3), and six equivalent Cs(1) atoms. In the second Au site, Au(2) is bonded in a distorted body-centered cubic geometry to two equivalent Cs(2) and six equivalent Cs(1) atoms. In the third Au site, Au(3) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to one Cs(3), two equivalent Cs(1), two equivalent Cs(2), and one Au(3) atom to form corner-sharing OCs5Au octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_Cs7Au5O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.344
_cell_length_b   10.344
_cell_length_c   10.344
_cell_angle_alpha   146.068
_cell_angle_beta   124.142
_cell_angle_gamma   66.987
_symmetry_Int_Tables_number   1
_cell_volume   504.585
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.612  0.831  0.781  1.0
  Cs  Cs1  1  0.791  0.500  0.291  1.0
  Cs  Cs2  1  0.050  0.831  0.219  1.0
  Cs  Cs3  1  0.388  0.169  0.219  1.0
  Cs  Cs4  1  0.950  0.169  0.781  1.0
  Cs  Cs5  1  0.209  0.500  0.709  1.0
  Cs  Cs6  1  0.500  0.000  0.500  1.0
  Au  Au7  1  0.647  0.647  0.000  1.0
  Au  Au8  1  0.812  0.312  0.500  1.0
  Au  Au9  1  0.000  0.000  0.000  1.0
  Au  Au10  1  0.353  0.353  0.000  1.0
  Au  Au11  1  0.188  0.688  0.500  1.0
  O  O12  1  0.792  0.000  0.792  1.0
  O  O13  1  0.208  0.000  0.208  1.0
[/CIF]
.
The structure described by Cs7Au5O2 crystallizes in the orthorhombic Immm space group. There are three inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a distorted single-bond geometry to three equivalent Au(1), three equivalent Au(2), and one O(1) atom. In the second Cs site, Cs(2) is bonded in a distorted linear geometry to two equivalent Au(1), two equivalent Au(2), and two equivalent O(1) atoms. In the third Cs site, Cs(3) is bonded in a distorted linear geometry to four equivalent Au(1) and two equivalent O(1) atoms. There are three inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted q6 geometry to two equivalent Cs(2), two equivalent Cs(3), and six equivalent Cs(1) atoms. In the second Au site, Au(2) is bonded in a distorted body-centered cubic geometry to two equivalent Cs(2) and six equivalent Cs(1) atoms. In the third Au site, Au(3) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to one Cs(3), two equivalent Cs(1), two equivalent Cs(2), and one Au(3) atom to form corner-sharing OCs5Au octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_Cs7Au5O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.344
_cell_length_b   10.344
_cell_length_c   10.344
_cell_angle_alpha   146.068
_cell_angle_beta   124.142
_cell_angle_gamma   66.987
_symmetry_Int_Tables_number   1
_cell_volume   504.585
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.612  0.831  0.781  1.0
  Cs  Cs1  1  0.791  0.500  0.291  1.0
  Cs  Cs2  1  0.050  0.831  0.219  1.0
  Cs  Cs3  1  0.388  0.169  0.219  1.0
  Cs  Cs4  1  0.950  0.169  0.781  1.0
  Cs  Cs5  1  0.209  0.500  0.709  1.0
  Cs  Cs6  1  0.500  0.000  0.500  1.0
  Au  Au7  1  0.647  0.647  0.000  1.0
  Au  Au8  1  0.812  0.312  0.500  1.0
  Au  Au9  1  0.000  0.000  0.000  1.0
  Au  Au10  1  0.353  0.353  0.000  1.0
  Au  Au11  1  0.188  0.688  0.500  1.0
  O  O12  1  0.792  0.000  0.792  1.0
  O  O13  1  0.208  0.000  0.208  1.0
[/CIF]
.