The crystal structure described by K2LiAlP2 crystallizes in the orthorhombic Ibam space group. K(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. Li(1) is bonded to four equivalent P(1) atoms to form distorted LiP4 tetrahedra that share corners with four equivalent Al(1)P4 tetrahedra, edges with two equivalent Li(1)P4 tetrahedra, and edges with two equivalent Al(1)P4 tetrahedra. Al(1) is bonded to four equivalent P(1) atoms to form distorted AlP4 tetrahedra that share corners with four equivalent Li(1)P4 tetrahedra, edges with two equivalent Li(1)P4 tetrahedra, and edges with two equivalent Al(1)P4 tetrahedra. P(1) is bonded in a 9-coordinate geometry to five equivalent K(1), two equivalent Li(1), and two equivalent Al(1) atoms. is represented by the CIF card [CIF]
data_K2LiAlP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.124
_cell_length_b   6.163
_cell_length_c   8.629
_cell_angle_alpha   110.921
_cell_angle_beta   110.785
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   281.394
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.827  0.100  0.654  1.0
  K  K1  1  0.173  0.900  0.346  1.0
  K  K2  1  0.673  0.446  0.346  1.0
  K  K3  1  0.327  0.554  0.654  1.0
  Li  Li4  1  0.250  0.500  0.000  1.0
  Li  Li5  1  0.750  0.500  0.000  1.0
  Al  Al6  1  0.250  0.000  0.000  1.0
  Al  Al7  1  0.750  0.000  0.000  1.0
  P  P8  1  0.912  0.691  0.823  1.0
  P  P9  1  0.412  0.133  0.823  1.0
  P  P10  1  0.588  0.867  0.177  1.0
  P  P11  1  0.088  0.309  0.177  1.0
[/CIF]
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The crystal structure described by K2LiAlP2 crystallizes in the orthorhombic Ibam space group. K(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. Li(1) is bonded to four equivalent P(1) atoms to form distorted LiP4 tetrahedra that share corners with four equivalent Al(1)P4 tetrahedra, edges with two equivalent Li(1)P4 tetrahedra, and edges with two equivalent Al(1)P4 tetrahedra. Al(1) is bonded to four equivalent P(1) atoms to form distorted AlP4 tetrahedra that share corners with four equivalent Li(1)P4 tetrahedra, edges with two equivalent Li(1)P4 tetrahedra, and edges with two equivalent Al(1)P4 tetrahedra. P(1) is bonded in a 9-coordinate geometry to five equivalent K(1), two equivalent Li(1), and two equivalent Al(1) atoms. is represented by the CIF card [CIF]
data_K2LiAlP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.124
_cell_length_b   6.163
_cell_length_c   8.629
_cell_angle_alpha   110.921
_cell_angle_beta   110.785
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   281.394
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.827  0.100  0.654  1.0
  K  K1  1  0.173  0.900  0.346  1.0
  K  K2  1  0.673  0.446  0.346  1.0
  K  K3  1  0.327  0.554  0.654  1.0
  Li  Li4  1  0.250  0.500  0.000  1.0
  Li  Li5  1  0.750  0.500  0.000  1.0
  Al  Al6  1  0.250  0.000  0.000  1.0
  Al  Al7  1  0.750  0.000  0.000  1.0
  P  P8  1  0.912  0.691  0.823  1.0
  P  P9  1  0.412  0.133  0.823  1.0
  P  P10  1  0.588  0.867  0.177  1.0
  P  P11  1  0.088  0.309  0.177  1.0
[/CIF]
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