The material structure described by CsUPNO9 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 10-coordinate geometry to one O(1), one O(4), one O(5), one O(6), one O(7), one O(8), two equivalent O(2), and two equivalent O(9) atoms. U(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. P(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(8) atom. N(1) is bonded in a trigonal planar geometry to one O(5), one O(7), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cs(1), one U(1), and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent Cs(1) and one U(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one U(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Cs(1), one U(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cs(1), one U(1), and one N(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Cs(1) and one U(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Cs(1), one U(1), and one N(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Cs(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one N(1) atom. is represented by the CIF card [CIF]
data_CsUPNO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.163
_cell_length_b   7.685
_cell_length_c   9.871
_cell_angle_alpha   71.022
_cell_angle_beta   74.985
_cell_angle_gamma   79.484
_symmetry_Int_Tables_number   1
_cell_volume   493.414
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.291  0.669  0.820  1.0
  Cs  Cs1  1  0.709  0.331  0.180  1.0
  U  U2  1  0.742  0.268  0.686  1.0
  U  U3  1  0.258  0.732  0.314  1.0
  P  P4  1  0.732  0.717  0.414  1.0
  P  P5  1  0.268  0.283  0.586  1.0
  N  N6  1  0.766  0.861  0.833  1.0
  N  N7  1  0.234  0.139  0.167  1.0
  O  O8  1  0.708  0.576  0.569  1.0
  O  O9  1  0.292  0.424  0.431  1.0
  O  O10  1  0.657  0.315  0.862  1.0
  O  O11  1  0.343  0.685  0.138  1.0
  O  O12  1  0.941  0.689  0.325  1.0
  O  O13  1  0.059  0.311  0.675  1.0
  O  O14  1  0.583  0.692  0.334  1.0
  O  O15  1  0.417  0.308  0.666  1.0
  O  O16  1  0.612  0.952  0.791  1.0
  O  O17  1  0.388  0.048  0.209  1.0
  O  O18  1  0.824  0.220  0.511  1.0
  O  O19  1  0.176  0.780  0.489  1.0
  O  O20  1  0.905  0.959  0.811  1.0
  O  O21  1  0.095  0.041  0.189  1.0
  O  O22  1  0.691  0.919  0.420  1.0
  O  O23  1  0.309  0.081  0.580  1.0
  O  O24  1  0.782  0.692  0.889  1.0
  O  O25  1  0.218  0.308  0.111  1.0
[/CIF]
.
The material structure described by CsUPNO9 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 10-coordinate geometry to one O(1), one O(4), one O(5), one O(6), one O(7), one O(8), two equivalent O(2), and two equivalent O(9) atoms. U(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. P(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(8) atom. N(1) is bonded in a trigonal planar geometry to one O(5), one O(7), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cs(1), one U(1), and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent Cs(1) and one U(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one U(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Cs(1), one U(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cs(1), one U(1), and one N(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Cs(1) and one U(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Cs(1), one U(1), and one N(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Cs(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one N(1) atom. is represented by the CIF card [CIF]
data_CsUPNO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.163
_cell_length_b   7.685
_cell_length_c   9.871
_cell_angle_alpha   71.022
_cell_angle_beta   74.985
_cell_angle_gamma   79.484
_symmetry_Int_Tables_number   1
_cell_volume   493.414
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.291  0.669  0.820  1.0
  Cs  Cs1  1  0.709  0.331  0.180  1.0
  U  U2  1  0.742  0.268  0.686  1.0
  U  U3  1  0.258  0.732  0.314  1.0
  P  P4  1  0.732  0.717  0.414  1.0
  P  P5  1  0.268  0.283  0.586  1.0
  N  N6  1  0.766  0.861  0.833  1.0
  N  N7  1  0.234  0.139  0.167  1.0
  O  O8  1  0.708  0.576  0.569  1.0
  O  O9  1  0.292  0.424  0.431  1.0
  O  O10  1  0.657  0.315  0.862  1.0
  O  O11  1  0.343  0.685  0.138  1.0
  O  O12  1  0.941  0.689  0.325  1.0
  O  O13  1  0.059  0.311  0.675  1.0
  O  O14  1  0.583  0.692  0.334  1.0
  O  O15  1  0.417  0.308  0.666  1.0
  O  O16  1  0.612  0.952  0.791  1.0
  O  O17  1  0.388  0.048  0.209  1.0
  O  O18  1  0.824  0.220  0.511  1.0
  O  O19  1  0.176  0.780  0.489  1.0
  O  O20  1  0.905  0.959  0.811  1.0
  O  O21  1  0.095  0.041  0.189  1.0
  O  O22  1  0.691  0.919  0.420  1.0
  O  O23  1  0.309  0.081  0.580  1.0
  O  O24  1  0.782  0.692  0.889  1.0
  O  O25  1  0.218  0.308  0.111  1.0
[/CIF]
.