The crystal structure described by CrN2O3Cl2N2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 7727-37-9 molecules and one CrN2O3Cl2 cluster. In the CrN2O3Cl2 cluster, Cr(1) is bonded to one N(3), one N(4), one O(1), and two equivalent O(2) atoms to form distorted edge-sharing CrN2O3 trigonal bipyramids. There are two inequivalent N sites. In the first N site, N(3) is bonded in a single-bond geometry to one Cr(1) atom. In the second N site, N(4) is bonded in a bent 150 degrees geometry to one Cr(1) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cr(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent Cr(1) and one Cl(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(4) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one O(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one O(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CrN4Cl2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.994
_cell_length_b   6.984
_cell_length_c   10.082
_cell_angle_alpha   107.577
_cell_angle_beta   96.326
_cell_angle_gamma   99.205
_symmetry_Int_Tables_number   1
_cell_volume   391.507
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.863  0.958  0.840  1.0
  Cr  Cr1  1  0.137  0.042  0.160  1.0
  N  N2  1  0.933  0.491  0.736  1.0
  N  N3  1  0.067  0.509  0.264  1.0
  N  N4  1  0.954  0.391  0.630  1.0
  N  N5  1  0.046  0.609  0.370  1.0
  N  N6  1  0.267  0.865  0.159  1.0
  N  N7  1  0.733  0.135  0.841  1.0
  N  N8  1  0.580  0.740  0.734  1.0
  N  N9  1  0.420  0.260  0.266  1.0
  Cl  Cl10  1  0.749  0.021  0.346  1.0
  Cl  Cl11  1  0.251  0.979  0.654  1.0
  Cl  Cl12  1  0.281  0.337  0.969  1.0
  Cl  Cl13  1  0.719  0.663  0.031  1.0
  O  O14  1  0.989  0.882  0.672  1.0
  O  O15  1  0.011  0.118  0.328  1.0
  O  O16  1  0.156  0.105  0.975  1.0
  O  O17  1  0.844  0.895  0.025  1.0
  O  O18  1  0.441  0.609  0.743  1.0
  O  O19  1  0.559  0.391  0.257  1.0
[/CIF]
.
The crystal structure described by CrN2O3Cl2N2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 7727-37-9 molecules and one CrN2O3Cl2 cluster. In the CrN2O3Cl2 cluster, Cr(1) is bonded to one N(3), one N(4), one O(1), and two equivalent O(2) atoms to form distorted edge-sharing CrN2O3 trigonal bipyramids. There are two inequivalent N sites. In the first N site, N(3) is bonded in a single-bond geometry to one Cr(1) atom. In the second N site, N(4) is bonded in a bent 150 degrees geometry to one Cr(1) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cr(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent Cr(1) and one Cl(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(4) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one O(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one O(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CrN4Cl2O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.994
_cell_length_b   6.984
_cell_length_c   10.082
_cell_angle_alpha   107.577
_cell_angle_beta   96.326
_cell_angle_gamma   99.205
_symmetry_Int_Tables_number   1
_cell_volume   391.507
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.863  0.958  0.840  1.0
  Cr  Cr1  1  0.137  0.042  0.160  1.0
  N  N2  1  0.933  0.491  0.736  1.0
  N  N3  1  0.067  0.509  0.264  1.0
  N  N4  1  0.954  0.391  0.630  1.0
  N  N5  1  0.046  0.609  0.370  1.0
  N  N6  1  0.267  0.865  0.159  1.0
  N  N7  1  0.733  0.135  0.841  1.0
  N  N8  1  0.580  0.740  0.734  1.0
  N  N9  1  0.420  0.260  0.266  1.0
  Cl  Cl10  1  0.749  0.021  0.346  1.0
  Cl  Cl11  1  0.251  0.979  0.654  1.0
  Cl  Cl12  1  0.281  0.337  0.969  1.0
  Cl  Cl13  1  0.719  0.663  0.031  1.0
  O  O14  1  0.989  0.882  0.672  1.0
  O  O15  1  0.011  0.118  0.328  1.0
  O  O16  1  0.156  0.105  0.975  1.0
  O  O17  1  0.844  0.895  0.025  1.0
  O  O18  1  0.441  0.609  0.743  1.0
  O  O19  1  0.559  0.391  0.257  1.0
[/CIF]
.