The structure described by MnH3(CO2)3CN2H5 crystallizes in the monoclinic C2/c space group. The structure consists of four iminomethanaminium molecules inside a MnH3(CO2)3 framework. In the MnH3(CO2)3 framework, Mn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one H(1) and two equivalent O(3) atoms. In the second C site, C(2) is bonded in a trigonal planar geometry to one H(2), one O(1), and one O(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(2) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(2) atom. is represented by the CIF card [CIF]
data_MnH8C4(NO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.360
_cell_length_b   8.360
_cell_length_c   8.691
_cell_angle_alpha   64.149
_cell_angle_beta   64.149
_cell_angle_gamma   62.802
_symmetry_Int_Tables_number   1
_cell_volume   464.428
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.500  0.500  1.0
  Mn  Mn1  1  0.500  0.000  0.000  1.0
  H  H2  1  0.322  0.678  0.250  1.0
  H  H3  1  0.678  0.322  0.750  1.0
  H  H4  1  0.825  0.704  0.177  1.0
  H  H5  1  0.296  0.175  0.323  1.0
  H  H6  1  0.175  0.296  0.823  1.0
  H  H7  1  0.704  0.825  0.677  1.0
  H  H8  1  0.384  0.859  0.487  1.0
  H  H9  1  0.141  0.616  0.013  1.0
  H  H10  1  0.616  0.141  0.513  1.0
  H  H11  1  0.859  0.384  0.987  1.0
  H  H12  1  0.159  0.993  0.602  1.0
  H  H13  1  0.007  0.841  0.898  1.0
  H  H14  1  0.841  0.007  0.398  1.0
  H  H15  1  0.993  0.159  0.102  1.0
  H  H16  1  0.398  0.602  0.750  1.0
  H  H17  1  0.602  0.398  0.250  1.0
  C  C18  1  0.194  0.806  0.250  1.0
  C  C19  1  0.806  0.194  0.750  1.0
  C  C20  1  0.704  0.732  0.296  1.0
  C  C21  1  0.268  0.296  0.204  1.0
  C  C22  1  0.296  0.268  0.704  1.0
  C  C23  1  0.732  0.704  0.796  1.0
  C  C24  1  0.272  0.728  0.750  1.0
  C  C25  1  0.728  0.272  0.250  1.0
  N  N26  1  0.272  0.869  0.602  1.0
  N  N27  1  0.131  0.728  0.898  1.0
  N  N28  1  0.728  0.131  0.398  1.0
  N  N29  1  0.869  0.272  0.102  1.0
  O  O30  1  0.727  0.643  0.449  1.0
  O  O31  1  0.357  0.273  0.051  1.0
  O  O32  1  0.273  0.357  0.551  1.0
  O  O33  1  0.643  0.727  0.949  1.0
  O  O34  1  0.149  0.452  0.232  1.0
  O  O35  1  0.548  0.851  0.268  1.0
  O  O36  1  0.851  0.548  0.768  1.0
  O  O37  1  0.452  0.149  0.732  1.0
  O  O38  1  0.037  0.784  0.355  1.0
  O  O39  1  0.216  0.963  0.145  1.0
  O  O40  1  0.963  0.216  0.645  1.0
  O  O41  1  0.784  0.037  0.855  1.0
[/CIF]
.
The structure described by MnH3(CO2)3CN2H5 crystallizes in the monoclinic C2/c space group. The structure consists of four iminomethanaminium molecules inside a MnH3(CO2)3 framework. In the MnH3(CO2)3 framework, Mn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one H(1) and two equivalent O(3) atoms. In the second C site, C(2) is bonded in a trigonal planar geometry to one H(2), one O(1), and one O(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(2) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(2) atom. is represented by the CIF card [CIF]
data_MnH8C4(NO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.360
_cell_length_b   8.360
_cell_length_c   8.691
_cell_angle_alpha   64.149
_cell_angle_beta   64.149
_cell_angle_gamma   62.802
_symmetry_Int_Tables_number   1
_cell_volume   464.428
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.500  0.500  1.0
  Mn  Mn1  1  0.500  0.000  0.000  1.0
  H  H2  1  0.322  0.678  0.250  1.0
  H  H3  1  0.678  0.322  0.750  1.0
  H  H4  1  0.825  0.704  0.177  1.0
  H  H5  1  0.296  0.175  0.323  1.0
  H  H6  1  0.175  0.296  0.823  1.0
  H  H7  1  0.704  0.825  0.677  1.0
  H  H8  1  0.384  0.859  0.487  1.0
  H  H9  1  0.141  0.616  0.013  1.0
  H  H10  1  0.616  0.141  0.513  1.0
  H  H11  1  0.859  0.384  0.987  1.0
  H  H12  1  0.159  0.993  0.602  1.0
  H  H13  1  0.007  0.841  0.898  1.0
  H  H14  1  0.841  0.007  0.398  1.0
  H  H15  1  0.993  0.159  0.102  1.0
  H  H16  1  0.398  0.602  0.750  1.0
  H  H17  1  0.602  0.398  0.250  1.0
  C  C18  1  0.194  0.806  0.250  1.0
  C  C19  1  0.806  0.194  0.750  1.0
  C  C20  1  0.704  0.732  0.296  1.0
  C  C21  1  0.268  0.296  0.204  1.0
  C  C22  1  0.296  0.268  0.704  1.0
  C  C23  1  0.732  0.704  0.796  1.0
  C  C24  1  0.272  0.728  0.750  1.0
  C  C25  1  0.728  0.272  0.250  1.0
  N  N26  1  0.272  0.869  0.602  1.0
  N  N27  1  0.131  0.728  0.898  1.0
  N  N28  1  0.728  0.131  0.398  1.0
  N  N29  1  0.869  0.272  0.102  1.0
  O  O30  1  0.727  0.643  0.449  1.0
  O  O31  1  0.357  0.273  0.051  1.0
  O  O32  1  0.273  0.357  0.551  1.0
  O  O33  1  0.643  0.727  0.949  1.0
  O  O34  1  0.149  0.452  0.232  1.0
  O  O35  1  0.548  0.851  0.268  1.0
  O  O36  1  0.851  0.548  0.768  1.0
  O  O37  1  0.452  0.149  0.732  1.0
  O  O38  1  0.037  0.784  0.355  1.0
  O  O39  1  0.216  0.963  0.145  1.0
  O  O40  1  0.963  0.216  0.645  1.0
  O  O41  1  0.784  0.037  0.855  1.0
[/CIF]
.