The compound described by LiVS3 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a distorted pentagonal planar geometry to one S(1), two equivalent S(2), and two equivalent S(3) atoms. V(1) is bonded to one S(1), two equivalent S(2), and two equivalent S(3) atoms to form distorted edge-sharing VS5 trigonal bipyramids. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted bent 120 degrees geometry to one Li(1), one V(1), and one S(1) atom. In the second S site, S(2) is bonded to two equivalent Li(1) and two equivalent V(1) atoms to form distorted edge-sharing SLi2V2 trigonal pyramids. In the third S site, S(3) is bonded in a distorted see-saw-like geometry to two equivalent Li(1) and two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_LiVS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.808
_cell_length_b   6.487
_cell_length_c   6.670
_cell_angle_alpha   109.881
_cell_angle_beta   93.711
_cell_angle_gamma   115.053
_symmetry_Int_Tables_number   1
_cell_volume   207.547
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.529  0.685  0.828  1.0
  Li  Li1  1  0.471  0.315  0.172  1.0
  V  V2  1  0.786  0.067  0.566  1.0
  V  V3  1  0.214  0.933  0.434  1.0
  S  S4  1  0.076  0.437  0.866  1.0
  S  S5  1  0.536  0.971  0.242  1.0
  S  S6  1  0.174  0.259  0.446  1.0
  S  S7  1  0.826  0.741  0.554  1.0
  S  S8  1  0.464  0.029  0.758  1.0
  S  S9  1  0.924  0.563  0.134  1.0
[/CIF]
.
The compound described by LiVS3 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a distorted pentagonal planar geometry to one S(1), two equivalent S(2), and two equivalent S(3) atoms. V(1) is bonded to one S(1), two equivalent S(2), and two equivalent S(3) atoms to form distorted edge-sharing VS5 trigonal bipyramids. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted bent 120 degrees geometry to one Li(1), one V(1), and one S(1) atom. In the second S site, S(2) is bonded to two equivalent Li(1) and two equivalent V(1) atoms to form distorted edge-sharing SLi2V2 trigonal pyramids. In the third S site, S(3) is bonded in a distorted see-saw-like geometry to two equivalent Li(1) and two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_LiVS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.808
_cell_length_b   6.487
_cell_length_c   6.670
_cell_angle_alpha   109.881
_cell_angle_beta   93.711
_cell_angle_gamma   115.053
_symmetry_Int_Tables_number   1
_cell_volume   207.547
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.529  0.685  0.828  1.0
  Li  Li1  1  0.471  0.315  0.172  1.0
  V  V2  1  0.786  0.067  0.566  1.0
  V  V3  1  0.214  0.933  0.434  1.0
  S  S4  1  0.076  0.437  0.866  1.0
  S  S5  1  0.536  0.971  0.242  1.0
  S  S6  1  0.174  0.259  0.446  1.0
  S  S7  1  0.826  0.741  0.554  1.0
  S  S8  1  0.464  0.029  0.758  1.0
  S  S9  1  0.924  0.563  0.134  1.0
[/CIF]
.