The compound described by CsSbH4O5 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 4-coordinate geometry to one O(4), one O(5), and two equivalent O(1) atoms. Sb(1) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form edge-sharing SbO6 octahedra. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to two equivalent Cs(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Sb(1) and one H(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sb(1) and one H(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cs(1), one Sb(1), and one H(3) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Cs(1), one Sb(1), and one H(4) atom. is represented by the CIF file [CIF]
data_CsSbH4O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.751
_cell_length_b   6.780
_cell_length_c   7.597
_cell_angle_alpha   90.301
_cell_angle_beta   109.973
_cell_angle_gamma   113.634
_symmetry_Int_Tables_number   1
_cell_volume   295.300
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.828  0.991  0.714  1.0
  Cs  Cs1  1  0.172  0.009  0.286  1.0
  Sb  Sb2  1  0.537  0.367  0.859  1.0
  Sb  Sb3  1  0.463  0.633  0.141  1.0
  H  H4  1  0.286  0.542  0.684  1.0
  H  H5  1  0.714  0.458  0.316  1.0
  H  H6  1  0.905  0.374  0.120  1.0
  H  H7  1  0.095  0.626  0.880  1.0
  H  H8  1  0.720  0.480  0.614  1.0
  H  H9  1  0.280  0.520  0.386  1.0
  H  H10  1  0.342  0.954  0.810  1.0
  H  H11  1  0.658  0.046  0.190  1.0
  O  O12  1  0.314  0.328  0.993  1.0
  O  O13  1  0.686  0.672  0.007  1.0
  O  O14  1  0.340  0.452  0.629  1.0
  O  O15  1  0.660  0.548  0.371  1.0
  O  O16  1  0.739  0.266  0.068  1.0
  O  O17  1  0.261  0.734  0.932  1.0
  O  O18  1  0.780  0.441  0.742  1.0
  O  O19  1  0.220  0.559  0.258  1.0
  O  O20  1  0.357  0.061  0.720  1.0
  O  O21  1  0.643  0.939  0.280  1.0
[/CIF]
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The compound described by CsSbH4O5 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 4-coordinate geometry to one O(4), one O(5), and two equivalent O(1) atoms. Sb(1) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form edge-sharing SbO6 octahedra. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to two equivalent Cs(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Sb(1) and one H(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sb(1) and one H(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cs(1), one Sb(1), and one H(3) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Cs(1), one Sb(1), and one H(4) atom. is represented by the CIF file [CIF]
data_CsSbH4O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.751
_cell_length_b   6.780
_cell_length_c   7.597
_cell_angle_alpha   90.301
_cell_angle_beta   109.973
_cell_angle_gamma   113.634
_symmetry_Int_Tables_number   1
_cell_volume   295.300
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.828  0.991  0.714  1.0
  Cs  Cs1  1  0.172  0.009  0.286  1.0
  Sb  Sb2  1  0.537  0.367  0.859  1.0
  Sb  Sb3  1  0.463  0.633  0.141  1.0
  H  H4  1  0.286  0.542  0.684  1.0
  H  H5  1  0.714  0.458  0.316  1.0
  H  H6  1  0.905  0.374  0.120  1.0
  H  H7  1  0.095  0.626  0.880  1.0
  H  H8  1  0.720  0.480  0.614  1.0
  H  H9  1  0.280  0.520  0.386  1.0
  H  H10  1  0.342  0.954  0.810  1.0
  H  H11  1  0.658  0.046  0.190  1.0
  O  O12  1  0.314  0.328  0.993  1.0
  O  O13  1  0.686  0.672  0.007  1.0
  O  O14  1  0.340  0.452  0.629  1.0
  O  O15  1  0.660  0.548  0.371  1.0
  O  O16  1  0.739  0.266  0.068  1.0
  O  O17  1  0.261  0.734  0.932  1.0
  O  O18  1  0.780  0.441  0.742  1.0
  O  O19  1  0.220  0.559  0.258  1.0
  O  O20  1  0.357  0.061  0.720  1.0
  O  O21  1  0.643  0.939  0.280  1.0
[/CIF]
.