The compound described by LiMn9CdO10 crystallizes in the monoclinic Cm space group. Li(1) is bonded in a 4-coordinate geometry to one Cd(1), one O(4), one O(5), and two equivalent O(6) atoms. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(6), two equivalent O(2), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with two equivalent Mn(4)O6 octahedra, corners with two equivalent Mn(2)O5 trigonal bipyramids, edges with two equivalent Mn(1)O6 octahedra, edges with four equivalent Mn(4)O6 octahedra, edges with two equivalent Mn(2)O5 trigonal bipyramids, and edges with three equivalent Mn(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(6) atom to form MnO5 trigonal bipyramids that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O5 trigonal bipyramid, corners with four equivalent Mn(3)O5 trigonal bipyramids, edges with two equivalent Mn(1)O6 octahedra, and edges with three equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. In the third Mn site, Mn(3) is bonded to one O(1), one O(2), one O(3), one O(5), and one O(6) atom to form MnO5 trigonal bipyramids that share corners with two equivalent Mn(4)O6 octahedra,  a cornercorner with one Mn(3)O5 trigonal bipyramid, corners with four equivalent Mn(2)O5 trigonal bipyramids, edges with two equivalent Mn(4)O6 octahedra, and edges with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(6), two equivalent O(2), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(3)O5 trigonal bipyramids, edges with two equivalent Mn(4)O6 octahedra, edges with four equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(3)O5 trigonal bipyramids, and edges with three equivalent Mn(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. In the fifth Mn site, Mn(5) is bonded in a distorted rectangular see-saw-like geometry to one Cd(1), one O(4), one O(5), and two equivalent O(1) atoms. Cd(1) is bonded in a 6-coordinate geometry to one Li(1), one Mn(5), one O(4), one O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Mn(1), one Mn(2), one Mn(3), one Mn(4), and one Mn(5) atom to form OMn5 trigonal bipyramids that share corners with two equivalent O(3)Mn6 octahedra, corners with four equivalent O(6)LiMn4Cd octahedra,  a cornercorner with one O(1)Mn5 trigonal bipyramid, edges with two equivalent O(3)Mn6 octahedra, edges with three equivalent O(2)Mn6 octahedra, and  an edgeedge with one O(5)LiMn3Cd trigonal bipyramid. The corner-sharing octahedral tilt angles range from 4-79°. In the second O site, O(2) is bonded to one Mn(2), one Mn(3), two equivalent Mn(1), and two equivalent Mn(4) atoms to form OMn6 octahedra that share corners with two equivalent O(6)LiMn4Cd octahedra, corners with two equivalent O(3)Mn6 octahedra,  a cornercorner with one O(5)LiMn3Cd trigonal bipyramid, edges with two equivalent O(6)LiMn4Cd octahedra, edges with two equivalent O(2)Mn6 octahedra, edges with four equivalent O(3)Mn6 octahedra, and edges with three equivalent O(1)Mn5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-6°. In the third O site, O(3) is bonded to one Mn(2), one Mn(3), two equivalent Mn(1), and two equivalent Mn(4) atoms to form OMn6 octahedra that share corners with two equivalent O(2)Mn6 octahedra,  a cornercorner with one O(5)LiMn3Cd trigonal bipyramid, corners with two equivalent O(1)Mn5 trigonal bipyramids, edges with two equivalent O(3)Mn6 octahedra, edges with three equivalent O(6)LiMn4Cd octahedra, edges with four equivalent O(2)Mn6 octahedra, and edges with two equivalent O(1)Mn5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-2°. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Li(1), one Mn(5), two equivalent Mn(2), and one Cd(1) atom. In the fifth O site, O(5) is bonded to one Li(1), one Mn(5), two equivalent Mn(3), and one Cd(1) atom to form distorted OLiMn3Cd trigonal bipyramids that share corners with two equivalent O(6)LiMn4Cd octahedra, corners with two equivalent O(2)Mn6 octahedra, corners with two equivalent O(3)Mn6 octahedra, edges with two equivalent O(6)LiMn4Cd octahedra, and edges with two equivalent O(1)Mn5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 27-73°. In the sixth O site, O(6) is bonded to one Li(1), one Mn(1), one Mn(2), one Mn(3), one Mn(4), and one Cd(1) atom to form OLiMn4Cd octahedra that share corners with two equivalent O(2)Mn6 octahedra,  a cornercorner with one O(5)LiMn3Cd trigonal bipyramid, corners with four equivalent O(1)Mn5 trigonal bipyramids,  an edgeedge with one O(6)LiMn4Cd octahedra, edges with two equivalent O(2)Mn6 octahedra, edges with three equivalent O(3)Mn6 octahedra, and  an edgeedge with one O(5)LiMn3Cd trigonal bipyramid. The corner-sharing octahedral tilt angles range from 2-6°. is represented by the CIF card [CIF]
data_LiMn9CdO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.565
_cell_length_b   9.008
_cell_length_c   5.704
_cell_angle_alpha   71.556
_cell_angle_beta   104.064
_cell_angle_gamma   94.405
_symmetry_Int_Tables_number   1
_cell_volume   263.098
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.019  0.800  0.880  1.0
  Mn  Mn1  1  0.533  0.398  0.335  1.0
  Mn  Mn2  1  0.038  0.044  0.025  1.0
  Mn  Mn3  1  0.527  0.027  0.518  1.0
  Mn  Mn4  1  0.038  0.555  0.270  1.0
  Mn  Mn5  1  0.031  0.196  0.447  1.0
  Mn  Mn6  1  0.533  0.202  0.933  1.0
  Mn  Mn7  1  0.527  0.573  0.745  1.0
  Mn  Mn8  1  0.031  0.404  0.843  1.0
  Mn  Mn9  1  0.854  0.800  0.427  1.0
  Cd  Cd10  1  0.484  0.800  0.047  1.0
  O  O11  1  0.786  0.048  0.263  1.0
  O  O12  1  0.775  0.405  0.083  1.0
  O  O13  1  0.775  0.195  0.687  1.0
  O  O14  1  0.786  0.551  0.512  1.0
  O  O15  1  0.286  0.206  0.188  1.0
  O  O16  1  0.109  0.800  0.223  1.0
  O  O17  1  0.681  0.800  0.709  1.0
  O  O18  1  0.260  0.022  0.761  1.0
  O  O19  1  0.287  0.394  0.595  1.0
  O  O20  1  0.261  0.577  0.985  1.0
[/CIF]
.
The compound described by LiMn9CdO10 crystallizes in the monoclinic Cm space group. Li(1) is bonded in a 4-coordinate geometry to one Cd(1), one O(4), one O(5), and two equivalent O(6) atoms. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(6), two equivalent O(2), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with two equivalent Mn(4)O6 octahedra, corners with two equivalent Mn(2)O5 trigonal bipyramids, edges with two equivalent Mn(1)O6 octahedra, edges with four equivalent Mn(4)O6 octahedra, edges with two equivalent Mn(2)O5 trigonal bipyramids, and edges with three equivalent Mn(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(6) atom to form MnO5 trigonal bipyramids that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one Mn(2)O5 trigonal bipyramid, corners with four equivalent Mn(3)O5 trigonal bipyramids, edges with two equivalent Mn(1)O6 octahedra, and edges with three equivalent Mn(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-10°. In the third Mn site, Mn(3) is bonded to one O(1), one O(2), one O(3), one O(5), and one O(6) atom to form MnO5 trigonal bipyramids that share corners with two equivalent Mn(4)O6 octahedra,  a cornercorner with one Mn(3)O5 trigonal bipyramid, corners with four equivalent Mn(2)O5 trigonal bipyramids, edges with two equivalent Mn(4)O6 octahedra, and edges with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the fourth Mn site, Mn(4) is bonded to one O(1), one O(6), two equivalent O(2), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(3)O5 trigonal bipyramids, edges with two equivalent Mn(4)O6 octahedra, edges with four equivalent Mn(1)O6 octahedra, edges with two equivalent Mn(3)O5 trigonal bipyramids, and edges with three equivalent Mn(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 3°. In the fifth Mn site, Mn(5) is bonded in a distorted rectangular see-saw-like geometry to one Cd(1), one O(4), one O(5), and two equivalent O(1) atoms. Cd(1) is bonded in a 6-coordinate geometry to one Li(1), one Mn(5), one O(4), one O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Mn(1), one Mn(2), one Mn(3), one Mn(4), and one Mn(5) atom to form OMn5 trigonal bipyramids that share corners with two equivalent O(3)Mn6 octahedra, corners with four equivalent O(6)LiMn4Cd octahedra,  a cornercorner with one O(1)Mn5 trigonal bipyramid, edges with two equivalent O(3)Mn6 octahedra, edges with three equivalent O(2)Mn6 octahedra, and  an edgeedge with one O(5)LiMn3Cd trigonal bipyramid. The corner-sharing octahedral tilt angles range from 4-79°. In the second O site, O(2) is bonded to one Mn(2), one Mn(3), two equivalent Mn(1), and two equivalent Mn(4) atoms to form OMn6 octahedra that share corners with two equivalent O(6)LiMn4Cd octahedra, corners with two equivalent O(3)Mn6 octahedra,  a cornercorner with one O(5)LiMn3Cd trigonal bipyramid, edges with two equivalent O(6)LiMn4Cd octahedra, edges with two equivalent O(2)Mn6 octahedra, edges with four equivalent O(3)Mn6 octahedra, and edges with three equivalent O(1)Mn5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-6°. In the third O site, O(3) is bonded to one Mn(2), one Mn(3), two equivalent Mn(1), and two equivalent Mn(4) atoms to form OMn6 octahedra that share corners with two equivalent O(2)Mn6 octahedra,  a cornercorner with one O(5)LiMn3Cd trigonal bipyramid, corners with two equivalent O(1)Mn5 trigonal bipyramids, edges with two equivalent O(3)Mn6 octahedra, edges with three equivalent O(6)LiMn4Cd octahedra, edges with four equivalent O(2)Mn6 octahedra, and edges with two equivalent O(1)Mn5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 1-2°. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Li(1), one Mn(5), two equivalent Mn(2), and one Cd(1) atom. In the fifth O site, O(5) is bonded to one Li(1), one Mn(5), two equivalent Mn(3), and one Cd(1) atom to form distorted OLiMn3Cd trigonal bipyramids that share corners with two equivalent O(6)LiMn4Cd octahedra, corners with two equivalent O(2)Mn6 octahedra, corners with two equivalent O(3)Mn6 octahedra, edges with two equivalent O(6)LiMn4Cd octahedra, and edges with two equivalent O(1)Mn5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 27-73°. In the sixth O site, O(6) is bonded to one Li(1), one Mn(1), one Mn(2), one Mn(3), one Mn(4), and one Cd(1) atom to form OLiMn4Cd octahedra that share corners with two equivalent O(2)Mn6 octahedra,  a cornercorner with one O(5)LiMn3Cd trigonal bipyramid, corners with four equivalent O(1)Mn5 trigonal bipyramids,  an edgeedge with one O(6)LiMn4Cd octahedra, edges with two equivalent O(2)Mn6 octahedra, edges with three equivalent O(3)Mn6 octahedra, and  an edgeedge with one O(5)LiMn3Cd trigonal bipyramid. The corner-sharing octahedral tilt angles range from 2-6°. is represented by the CIF card [CIF]
data_LiMn9CdO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.565
_cell_length_b   9.008
_cell_length_c   5.704
_cell_angle_alpha   71.556
_cell_angle_beta   104.064
_cell_angle_gamma   94.405
_symmetry_Int_Tables_number   1
_cell_volume   263.098
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.019  0.800  0.880  1.0
  Mn  Mn1  1  0.533  0.398  0.335  1.0
  Mn  Mn2  1  0.038  0.044  0.025  1.0
  Mn  Mn3  1  0.527  0.027  0.518  1.0
  Mn  Mn4  1  0.038  0.555  0.270  1.0
  Mn  Mn5  1  0.031  0.196  0.447  1.0
  Mn  Mn6  1  0.533  0.202  0.933  1.0
  Mn  Mn7  1  0.527  0.573  0.745  1.0
  Mn  Mn8  1  0.031  0.404  0.843  1.0
  Mn  Mn9  1  0.854  0.800  0.427  1.0
  Cd  Cd10  1  0.484  0.800  0.047  1.0
  O  O11  1  0.786  0.048  0.263  1.0
  O  O12  1  0.775  0.405  0.083  1.0
  O  O13  1  0.775  0.195  0.687  1.0
  O  O14  1  0.786  0.551  0.512  1.0
  O  O15  1  0.286  0.206  0.188  1.0
  O  O16  1  0.109  0.800  0.223  1.0
  O  O17  1  0.681  0.800  0.709  1.0
  O  O18  1  0.260  0.022  0.761  1.0
  O  O19  1  0.287  0.394  0.595  1.0
  O  O20  1  0.261  0.577  0.985  1.0
[/CIF]
.