The structure described by V(TeO3)4 crystallizes in the triclinic P1 space group. V(1) is bonded to one O(1), one O(11), one O(4), one O(7), one O(8), and one O(9) atom to form distorted VO6 octahedra that share  a cornercorner with one Te(4)O5 square pyramid, corners with two equivalent Te(3)O4 trigonal pyramids,  an edgeedge with one Te(1)O6 octahedra, and edges with two equivalent Te(2)O6 octahedra. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form TeO6 octahedra that share corners with four equivalent Te(4)O5 square pyramids,  a cornercorner with one Te(3)O4 trigonal pyramid, and  an edgeedge with one V(1)O6 octahedra. In the second Te site, Te(2) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form TeO6 octahedra that share  a cornercorner with one Te(4)O5 square pyramid, corners with three equivalent Te(3)O4 trigonal pyramids, and edges with two equivalent V(1)O6 octahedra. In the third Te site, Te(3) is bonded to one O(12), one O(2), one O(4), and one O(9) atom to form distorted TeO4 trigonal pyramids that share  a cornercorner with one Te(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, and corners with three equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-87°. In the fourth Te site, Te(4) is bonded to one O(10), one O(3), one O(5), one O(6), and one O(8) atom to form distorted TeO5 square pyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-53°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one V(1) and one Te(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one Te(2), and one Te(3) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(4) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Te(2) and one Te(4) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one V(1) and one Te(2) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one V(1), one Te(1), and one Te(4) atom. In the ninth O site, O(9) is bonded in a T-shaped geometry to one V(1), one Te(2), and one Te(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(4) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one V(1) and one Te(1) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Te(2) and one Te(3) atom. is represented by the CIF card [CIF]
data_V(TeO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.153
_cell_length_b   5.842
_cell_length_c   8.139
_cell_angle_alpha   79.142
_cell_angle_beta   89.332
_cell_angle_gamma   88.196
_symmetry_Int_Tables_number   1
_cell_volume   240.486
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.682  0.752  0.401  1.0
  O  O1  1  0.876  0.980  0.735  1.0
  O  O2  1  0.706  0.121  0.012  1.0
  O  O3  1  0.797  0.331  0.426  1.0
  O  O4  1  0.181  0.267  0.910  1.0
  O  O5  1  0.621  0.493  0.724  1.0
  O  O6  1  0.293  0.453  0.297  1.0
  O  O7  1  0.868  0.648  0.076  1.0
  O  O8  1  0.172  0.662  0.534  1.0
  O  O9  1  0.310  0.782  0.897  1.0
  O  O10  1  0.120  0.928  0.205  1.0
  O  O11  1  0.347  0.172  0.599  1.0
  Te  Te12  1  0.025  0.955  0.967  1.0
  Te  Te13  1  0.484  0.482  0.503  1.0
  Te  Te14  1  0.042  0.031  0.521  1.0
  Te  Te15  1  0.492  0.423  0.956  1.0
  V  V16  1  0.984  0.638  0.295  1.0
[/CIF]
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The structure described by V(TeO3)4 crystallizes in the triclinic P1 space group. V(1) is bonded to one O(1), one O(11), one O(4), one O(7), one O(8), and one O(9) atom to form distorted VO6 octahedra that share  a cornercorner with one Te(4)O5 square pyramid, corners with two equivalent Te(3)O4 trigonal pyramids,  an edgeedge with one Te(1)O6 octahedra, and edges with two equivalent Te(2)O6 octahedra. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom to form TeO6 octahedra that share corners with four equivalent Te(4)O5 square pyramids,  a cornercorner with one Te(3)O4 trigonal pyramid, and  an edgeedge with one V(1)O6 octahedra. In the second Te site, Te(2) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form TeO6 octahedra that share  a cornercorner with one Te(4)O5 square pyramid, corners with three equivalent Te(3)O4 trigonal pyramids, and edges with two equivalent V(1)O6 octahedra. In the third Te site, Te(3) is bonded to one O(12), one O(2), one O(4), and one O(9) atom to form distorted TeO4 trigonal pyramids that share  a cornercorner with one Te(1)O6 octahedra, corners with two equivalent V(1)O6 octahedra, and corners with three equivalent Te(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-87°. In the fourth Te site, Te(4) is bonded to one O(10), one O(3), one O(5), one O(6), and one O(8) atom to form distorted TeO5 square pyramids that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Te(2)O6 octahedra, and corners with four equivalent Te(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-53°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one V(1) and one Te(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one Te(2), and one Te(3) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(4) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Te(2) and one Te(4) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one V(1) and one Te(2) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one V(1), one Te(1), and one Te(4) atom. In the ninth O site, O(9) is bonded in a T-shaped geometry to one V(1), one Te(2), and one Te(3) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(4) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one V(1) and one Te(1) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Te(2) and one Te(3) atom. is represented by the CIF card [CIF]
data_V(TeO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.153
_cell_length_b   5.842
_cell_length_c   8.139
_cell_angle_alpha   79.142
_cell_angle_beta   89.332
_cell_angle_gamma   88.196
_symmetry_Int_Tables_number   1
_cell_volume   240.486
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  O  O0  1  0.682  0.752  0.401  1.0
  O  O1  1  0.876  0.980  0.735  1.0
  O  O2  1  0.706  0.121  0.012  1.0
  O  O3  1  0.797  0.331  0.426  1.0
  O  O4  1  0.181  0.267  0.910  1.0
  O  O5  1  0.621  0.493  0.724  1.0
  O  O6  1  0.293  0.453  0.297  1.0
  O  O7  1  0.868  0.648  0.076  1.0
  O  O8  1  0.172  0.662  0.534  1.0
  O  O9  1  0.310  0.782  0.897  1.0
  O  O10  1  0.120  0.928  0.205  1.0
  O  O11  1  0.347  0.172  0.599  1.0
  Te  Te12  1  0.025  0.955  0.967  1.0
  Te  Te13  1  0.484  0.482  0.503  1.0
  Te  Te14  1  0.042  0.031  0.521  1.0
  Te  Te15  1  0.492  0.423  0.956  1.0
  V  V16  1  0.984  0.638  0.295  1.0
[/CIF]
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