The crystal structure described by CuC7NS2F4(CF3)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight trifluoromethane molecules and four CuC7NS2F4 clusters. In each CuC7NS2F4 cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent C(1) and two equivalent S(1) atoms. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one Cu(1), one F(1), and one F(2) atom. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one N(1) atom. In the third C site, C(4) is bonded in a single-bond geometry to one C(3) atom. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and two equivalent S(1) atoms. N(1) is bonded in a trigonal planar geometry to one C(5) and two equivalent C(3) atoms. S(1) is bonded in an L-shaped geometry to one Cu(1) and one C(5) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF file [CIF]
data_CuC9S2NF10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.755
_cell_length_b   9.755
_cell_length_c   9.566
_cell_angle_alpha   78.544
_cell_angle_beta   78.544
_cell_angle_gamma   68.041
_symmetry_Int_Tables_number   1
_cell_volume   819.626
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.063  0.937  0.750  1.0
  Cu  Cu1  1  0.937  0.063  0.250  1.0
  C  C2  1  0.104  0.736  0.695  1.0
  C  C3  1  0.264  0.896  0.805  1.0
  C  C4  1  0.896  0.264  0.305  1.0
  C  C5  1  0.736  0.104  0.195  1.0
  C  C6  1  0.052  0.627  0.818  1.0
  C  C7  1  0.373  0.948  0.682  1.0
  C  C8  1  0.948  0.373  0.182  1.0
  C  C9  1  0.627  0.052  0.318  1.0
  C  C10  1  0.555  0.296  0.771  1.0
  C  C11  1  0.704  0.445  0.729  1.0
  C  C12  1  0.445  0.704  0.229  1.0
  C  C13  1  0.296  0.555  0.271  1.0
  C  C14  1  0.438  0.270  0.841  1.0
  C  C15  1  0.730  0.562  0.659  1.0
  C  C16  1  0.562  0.730  0.159  1.0
  C  C17  1  0.270  0.438  0.341  1.0
  C  C18  1  0.822  0.178  0.750  1.0
  C  C19  1  0.178  0.822  0.250  1.0
  S  S20  1  0.816  0.021  0.711  1.0
  S  S21  1  0.979  0.184  0.789  1.0
  S  S22  1  0.184  0.979  0.289  1.0
  S  S23  1  0.021  0.816  0.211  1.0
  N  N24  1  0.685  0.315  0.750  1.0
  N  N25  1  0.315  0.685  0.250  1.0
  F  F26  1  0.250  0.664  0.644  1.0
  F  F27  1  0.336  0.750  0.856  1.0
  F  F28  1  0.750  0.336  0.356  1.0
  F  F29  1  0.664  0.250  0.144  1.0
  F  F30  1  0.024  0.758  0.582  1.0
  F  F31  1  0.242  0.976  0.918  1.0
  F  F32  1  0.976  0.242  0.418  1.0
  F  F33  1  0.758  0.024  0.082  1.0
  F  F34  1  0.904  0.686  0.862  1.0
  F  F35  1  0.314  0.096  0.638  1.0
  F  F36  1  0.096  0.314  0.138  1.0
  F  F37  1  0.686  0.904  0.362  1.0
  F  F38  1  0.080  0.495  0.773  1.0
  F  F39  1  0.505  0.920  0.727  1.0
  F  F40  1  0.920  0.505  0.227  1.0
  F  F41  1  0.495  0.080  0.273  1.0
  F  F42  1  0.125  0.600  0.933  1.0
  F  F43  1  0.400  0.875  0.567  1.0
  F  F44  1  0.875  0.400  0.067  1.0
  F  F45  1  0.600  0.125  0.433  1.0
[/CIF]
.
The crystal structure described by CuC7NS2F4(CF3)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight trifluoromethane molecules and four CuC7NS2F4 clusters. In each CuC7NS2F4 cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent C(1) and two equivalent S(1) atoms. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one Cu(1), one F(1), and one F(2) atom. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one N(1) atom. In the third C site, C(4) is bonded in a single-bond geometry to one C(3) atom. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one N(1) and two equivalent S(1) atoms. N(1) is bonded in a trigonal planar geometry to one C(5) and two equivalent C(3) atoms. S(1) is bonded in an L-shaped geometry to one Cu(1) and one C(5) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF file [CIF]
data_CuC9S2NF10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.755
_cell_length_b   9.755
_cell_length_c   9.566
_cell_angle_alpha   78.544
_cell_angle_beta   78.544
_cell_angle_gamma   68.041
_symmetry_Int_Tables_number   1
_cell_volume   819.626
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.063  0.937  0.750  1.0
  Cu  Cu1  1  0.937  0.063  0.250  1.0
  C  C2  1  0.104  0.736  0.695  1.0
  C  C3  1  0.264  0.896  0.805  1.0
  C  C4  1  0.896  0.264  0.305  1.0
  C  C5  1  0.736  0.104  0.195  1.0
  C  C6  1  0.052  0.627  0.818  1.0
  C  C7  1  0.373  0.948  0.682  1.0
  C  C8  1  0.948  0.373  0.182  1.0
  C  C9  1  0.627  0.052  0.318  1.0
  C  C10  1  0.555  0.296  0.771  1.0
  C  C11  1  0.704  0.445  0.729  1.0
  C  C12  1  0.445  0.704  0.229  1.0
  C  C13  1  0.296  0.555  0.271  1.0
  C  C14  1  0.438  0.270  0.841  1.0
  C  C15  1  0.730  0.562  0.659  1.0
  C  C16  1  0.562  0.730  0.159  1.0
  C  C17  1  0.270  0.438  0.341  1.0
  C  C18  1  0.822  0.178  0.750  1.0
  C  C19  1  0.178  0.822  0.250  1.0
  S  S20  1  0.816  0.021  0.711  1.0
  S  S21  1  0.979  0.184  0.789  1.0
  S  S22  1  0.184  0.979  0.289  1.0
  S  S23  1  0.021  0.816  0.211  1.0
  N  N24  1  0.685  0.315  0.750  1.0
  N  N25  1  0.315  0.685  0.250  1.0
  F  F26  1  0.250  0.664  0.644  1.0
  F  F27  1  0.336  0.750  0.856  1.0
  F  F28  1  0.750  0.336  0.356  1.0
  F  F29  1  0.664  0.250  0.144  1.0
  F  F30  1  0.024  0.758  0.582  1.0
  F  F31  1  0.242  0.976  0.918  1.0
  F  F32  1  0.976  0.242  0.418  1.0
  F  F33  1  0.758  0.024  0.082  1.0
  F  F34  1  0.904  0.686  0.862  1.0
  F  F35  1  0.314  0.096  0.638  1.0
  F  F36  1  0.096  0.314  0.138  1.0
  F  F37  1  0.686  0.904  0.362  1.0
  F  F38  1  0.080  0.495  0.773  1.0
  F  F39  1  0.505  0.920  0.727  1.0
  F  F40  1  0.920  0.505  0.227  1.0
  F  F41  1  0.495  0.080  0.273  1.0
  F  F42  1  0.125  0.600  0.933  1.0
  F  F43  1  0.400  0.875  0.567  1.0
  F  F44  1  0.875  0.400  0.067  1.0
  F  F45  1  0.600  0.125  0.433  1.0
[/CIF]
.