The material described by Co2N5(N2)4(NO3)3 is Indium-derived structured and crystallizes in the tetragonal P4_2nm space group. The structure is zero-dimensional and consists of four ammonia atoms, six nitric acid molecules, four triazane molecules, and two Co2N5 clusters. In each Co2N5 cluster, Co(1) is bonded in a trigonal planar geometry to one N(4) and two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(4) is bonded in a bent 150 degrees geometry to two equivalent Co(1) atoms. In the second N site, N(1) is bonded in a single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co2N16O9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.685
_cell_length_b   11.685
_cell_length_c   9.911
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1353.257
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.598  0.402  0.611  1.0
  Co  Co1  1  0.402  0.598  0.611  1.0
  Co  Co2  1  0.902  0.902  0.111  1.0
  Co  Co3  1  0.098  0.098  0.111  1.0
  N  N4  1  0.718  0.442  0.670  1.0
  N  N5  1  0.282  0.558  0.670  1.0
  N  N6  1  0.782  0.942  0.170  1.0
  N  N7  1  0.218  0.058  0.170  1.0
  N  N8  1  0.558  0.282  0.670  1.0
  N  N9  1  0.442  0.718  0.670  1.0
  N  N10  1  0.942  0.782  0.170  1.0
  N  N11  1  0.058  0.218  0.170  1.0
  N  N12  1  0.721  0.423  0.326  1.0
  N  N13  1  0.279  0.577  0.326  1.0
  N  N14  1  0.779  0.923  0.826  1.0
  N  N15  1  0.221  0.077  0.826  1.0
  N  N16  1  0.577  0.279  0.326  1.0
  N  N17  1  0.423  0.721  0.326  1.0
  N  N18  1  0.923  0.779  0.826  1.0
  N  N19  1  0.077  0.221  0.826  1.0
  N  N20  1  0.649  0.351  0.324  1.0
  N  N21  1  0.351  0.649  0.324  1.0
  N  N22  1  0.851  0.851  0.824  1.0
  N  N23  1  0.149  0.149  0.824  1.0
  N  N24  1  0.000  0.000  0.071  1.0
  N  N25  1  0.500  0.500  0.571  1.0
  N  N26  1  0.000  0.000  0.492  1.0
  N  N27  1  0.500  0.500  0.992  1.0
  N  N28  1  0.000  0.500  0.500  1.0
  N  N29  1  0.500  0.000  1.000  1.0
  N  N30  1  0.500  0.000  0.500  1.0
  N  N31  1  0.000  0.500  1.000  1.0
  N  N32  1  0.761  0.239  0.993  1.0
  N  N33  1  0.239  0.761  0.993  1.0
  N  N34  1  0.739  0.739  0.493  1.0
  N  N35  1  0.261  0.261  0.493  1.0
  O  O36  1  0.000  0.000  0.618  1.0
  O  O37  1  0.500  0.500  0.118  1.0
  O  O38  1  0.934  0.066  0.429  1.0
  O  O39  1  0.066  0.934  0.429  1.0
  O  O40  1  0.566  0.566  0.929  1.0
  O  O41  1  0.434  0.434  0.929  1.0
  O  O42  1  0.685  0.315  0.997  1.0
  O  O43  1  0.315  0.685  0.997  1.0
  O  O44  1  0.815  0.815  0.497  1.0
  O  O45  1  0.185  0.185  0.497  1.0
  O  O46  1  0.797  0.203  0.882  1.0
  O  O47  1  0.203  0.797  0.882  1.0
  O  O48  1  0.703  0.703  0.382  1.0
  O  O49  1  0.297  0.297  0.382  1.0
  O  O50  1  0.800  0.200  0.101  1.0
  O  O51  1  0.200  0.800  0.101  1.0
  O  O52  1  0.700  0.700  0.601  1.0
  O  O53  1  0.300  0.300  0.601  1.0
[/CIF]
.
The material described by Co2N5(N2)4(NO3)3 is Indium-derived structured and crystallizes in the tetragonal P4_2nm space group. The structure is zero-dimensional and consists of four ammonia atoms, six nitric acid molecules, four triazane molecules, and two Co2N5 clusters. In each Co2N5 cluster, Co(1) is bonded in a trigonal planar geometry to one N(4) and two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(4) is bonded in a bent 150 degrees geometry to two equivalent Co(1) atoms. In the second N site, N(1) is bonded in a single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co2N16O9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.685
_cell_length_b   11.685
_cell_length_c   9.911
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1353.257
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.598  0.402  0.611  1.0
  Co  Co1  1  0.402  0.598  0.611  1.0
  Co  Co2  1  0.902  0.902  0.111  1.0
  Co  Co3  1  0.098  0.098  0.111  1.0
  N  N4  1  0.718  0.442  0.670  1.0
  N  N5  1  0.282  0.558  0.670  1.0
  N  N6  1  0.782  0.942  0.170  1.0
  N  N7  1  0.218  0.058  0.170  1.0
  N  N8  1  0.558  0.282  0.670  1.0
  N  N9  1  0.442  0.718  0.670  1.0
  N  N10  1  0.942  0.782  0.170  1.0
  N  N11  1  0.058  0.218  0.170  1.0
  N  N12  1  0.721  0.423  0.326  1.0
  N  N13  1  0.279  0.577  0.326  1.0
  N  N14  1  0.779  0.923  0.826  1.0
  N  N15  1  0.221  0.077  0.826  1.0
  N  N16  1  0.577  0.279  0.326  1.0
  N  N17  1  0.423  0.721  0.326  1.0
  N  N18  1  0.923  0.779  0.826  1.0
  N  N19  1  0.077  0.221  0.826  1.0
  N  N20  1  0.649  0.351  0.324  1.0
  N  N21  1  0.351  0.649  0.324  1.0
  N  N22  1  0.851  0.851  0.824  1.0
  N  N23  1  0.149  0.149  0.824  1.0
  N  N24  1  0.000  0.000  0.071  1.0
  N  N25  1  0.500  0.500  0.571  1.0
  N  N26  1  0.000  0.000  0.492  1.0
  N  N27  1  0.500  0.500  0.992  1.0
  N  N28  1  0.000  0.500  0.500  1.0
  N  N29  1  0.500  0.000  1.000  1.0
  N  N30  1  0.500  0.000  0.500  1.0
  N  N31  1  0.000  0.500  1.000  1.0
  N  N32  1  0.761  0.239  0.993  1.0
  N  N33  1  0.239  0.761  0.993  1.0
  N  N34  1  0.739  0.739  0.493  1.0
  N  N35  1  0.261  0.261  0.493  1.0
  O  O36  1  0.000  0.000  0.618  1.0
  O  O37  1  0.500  0.500  0.118  1.0
  O  O38  1  0.934  0.066  0.429  1.0
  O  O39  1  0.066  0.934  0.429  1.0
  O  O40  1  0.566  0.566  0.929  1.0
  O  O41  1  0.434  0.434  0.929  1.0
  O  O42  1  0.685  0.315  0.997  1.0
  O  O43  1  0.315  0.685  0.997  1.0
  O  O44  1  0.815  0.815  0.497  1.0
  O  O45  1  0.185  0.185  0.497  1.0
  O  O46  1  0.797  0.203  0.882  1.0
  O  O47  1  0.203  0.797  0.882  1.0
  O  O48  1  0.703  0.703  0.382  1.0
  O  O49  1  0.297  0.297  0.382  1.0
  O  O50  1  0.800  0.200  0.101  1.0
  O  O51  1  0.200  0.800  0.101  1.0
  O  O52  1  0.700  0.700  0.601  1.0
  O  O53  1  0.300  0.300  0.601  1.0
[/CIF]
.