The structure described by VPbOF5 crystallizes in the orthorhombic Pbcm space group. V(1) is bonded to one O(1), one F(1), two equivalent F(2), and two equivalent F(3) atoms to form distorted VOF5 octahedra that share corners with six equivalent Pb(1)F6 pentagonal pyramids. Pb(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form distorted PbF6 pentagonal pyramids that share corners with six equivalent V(1)OF5 octahedra and corners with two equivalent Pb(1)F6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 35-71°. O(1) is bonded in a single-bond geometry to one V(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Pb(1) atoms. In the second F site, F(2) is bonded in a distorted single-bond geometry to one V(1) and one Pb(1) atom. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Pb(1) atom. is represented by the CIF card [CIF]
data_VPbOF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.030
_cell_length_b   9.488
_cell_length_c   9.993
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   476.882
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.107  0.250  0.448  1.0
  V  V1  1  0.893  0.750  0.552  1.0
  V  V2  1  0.107  0.750  0.052  1.0
  V  V3  1  0.893  0.250  0.948  1.0
  Pb  Pb4  1  0.447  0.000  0.750  1.0
  Pb  Pb5  1  0.553  0.500  0.250  1.0
  Pb  Pb6  1  0.553  0.000  0.250  1.0
  Pb  Pb7  1  0.447  0.500  0.750  1.0
  O  O8  1  0.864  0.250  0.552  1.0
  O  O9  1  0.136  0.750  0.448  1.0
  O  O10  1  0.864  0.750  0.948  1.0
  O  O11  1  0.136  0.250  0.052  1.0
  F  F12  1  0.564  0.750  0.690  1.0
  F  F13  1  0.436  0.250  0.310  1.0
  F  F14  1  0.564  0.250  0.810  1.0
  F  F15  1  0.436  0.750  0.190  1.0
  F  F16  1  0.019  0.113  0.830  1.0
  F  F17  1  0.981  0.613  0.170  1.0
  F  F18  1  0.019  0.887  0.670  1.0
  F  F19  1  0.981  0.387  0.330  1.0
  F  F20  1  0.981  0.887  0.170  1.0
  F  F21  1  0.019  0.387  0.830  1.0
  F  F22  1  0.981  0.113  0.330  1.0
  F  F23  1  0.019  0.613  0.670  1.0
  F  F24  1  0.316  0.111  0.530  1.0
  F  F25  1  0.684  0.611  0.470  1.0
  F  F26  1  0.316  0.889  0.970  1.0
  F  F27  1  0.684  0.389  0.030  1.0
  F  F28  1  0.684  0.889  0.470  1.0
  F  F29  1  0.316  0.389  0.530  1.0
  F  F30  1  0.684  0.111  0.030  1.0
  F  F31  1  0.316  0.611  0.970  1.0
[/CIF]
.
The structure described by VPbOF5 crystallizes in the orthorhombic Pbcm space group. V(1) is bonded to one O(1), one F(1), two equivalent F(2), and two equivalent F(3) atoms to form distorted VOF5 octahedra that share corners with six equivalent Pb(1)F6 pentagonal pyramids. Pb(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form distorted PbF6 pentagonal pyramids that share corners with six equivalent V(1)OF5 octahedra and corners with two equivalent Pb(1)F6 pentagonal pyramids. The corner-sharing octahedral tilt angles range from 35-71°. O(1) is bonded in a single-bond geometry to one V(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Pb(1) atoms. In the second F site, F(2) is bonded in a distorted single-bond geometry to one V(1) and one Pb(1) atom. In the third F site, F(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Pb(1) atom. is represented by the CIF card [CIF]
data_VPbOF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.030
_cell_length_b   9.488
_cell_length_c   9.993
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   476.882
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.107  0.250  0.448  1.0
  V  V1  1  0.893  0.750  0.552  1.0
  V  V2  1  0.107  0.750  0.052  1.0
  V  V3  1  0.893  0.250  0.948  1.0
  Pb  Pb4  1  0.447  0.000  0.750  1.0
  Pb  Pb5  1  0.553  0.500  0.250  1.0
  Pb  Pb6  1  0.553  0.000  0.250  1.0
  Pb  Pb7  1  0.447  0.500  0.750  1.0
  O  O8  1  0.864  0.250  0.552  1.0
  O  O9  1  0.136  0.750  0.448  1.0
  O  O10  1  0.864  0.750  0.948  1.0
  O  O11  1  0.136  0.250  0.052  1.0
  F  F12  1  0.564  0.750  0.690  1.0
  F  F13  1  0.436  0.250  0.310  1.0
  F  F14  1  0.564  0.250  0.810  1.0
  F  F15  1  0.436  0.750  0.190  1.0
  F  F16  1  0.019  0.113  0.830  1.0
  F  F17  1  0.981  0.613  0.170  1.0
  F  F18  1  0.019  0.887  0.670  1.0
  F  F19  1  0.981  0.387  0.330  1.0
  F  F20  1  0.981  0.887  0.170  1.0
  F  F21  1  0.019  0.387  0.830  1.0
  F  F22  1  0.981  0.113  0.330  1.0
  F  F23  1  0.019  0.613  0.670  1.0
  F  F24  1  0.316  0.111  0.530  1.0
  F  F25  1  0.684  0.611  0.470  1.0
  F  F26  1  0.316  0.889  0.970  1.0
  F  F27  1  0.684  0.389  0.030  1.0
  F  F28  1  0.684  0.889  0.470  1.0
  F  F29  1  0.316  0.389  0.530  1.0
  F  F30  1  0.684  0.111  0.030  1.0
  F  F31  1  0.316  0.611  0.970  1.0
[/CIF]
.