The material structure described by C2NS3F2AsF6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AsF6 clusters and two C2NS3F2 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(5), one F(7), and one F(8) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(8) is bonded in a single-bond geometry to one As(1) atom. In each C2NS3F2 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one C(2), one F(4), and one F(6) atom. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one S(1) atom. N(1) is bonded in a bent 120 degrees geometry to one C(2) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(2) and one S(2) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one S(1) and one S(3) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1) and one S(2) atom. There are two inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF card [CIF]
data_AsC2S3NF8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.719
_cell_length_b   7.888
_cell_length_c   9.816
_cell_angle_alpha   101.046
_cell_angle_beta   96.145
_cell_angle_gamma   106.945
_symmetry_Int_Tables_number   1
_cell_volume   481.087
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.556  0.304  0.223  1.0
  As  As1  1  0.444  0.696  0.777  1.0
  C  C2  1  0.051  0.106  0.532  1.0
  C  C3  1  0.949  0.894  0.468  1.0
  C  C4  1  0.023  0.829  0.331  1.0
  C  C5  1  0.977  0.171  0.669  1.0
  S  S6  1  0.204  0.708  0.342  1.0
  S  S7  1  0.796  0.292  0.658  1.0
  S  S8  1  0.251  0.678  0.139  1.0
  S  S9  1  0.749  0.322  0.861  1.0
  S  S10  1  0.023  0.796  0.070  1.0
  S  S11  1  0.977  0.204  0.930  1.0
  N  N12  1  0.051  0.142  0.785  1.0
  N  N13  1  0.949  0.858  0.215  1.0
  F  F14  1  0.513  0.108  0.293  1.0
  F  F15  1  0.487  0.892  0.707  1.0
  F  F16  1  0.402  0.167  0.059  1.0
  F  F17  1  0.598  0.833  0.941  1.0
  F  F18  1  0.603  0.501  0.152  1.0
  F  F19  1  0.397  0.499  0.848  1.0
  F  F20  1  0.997  0.195  0.435  1.0
  F  F21  1  0.003  0.805  0.565  1.0
  F  F22  1  0.328  0.343  0.278  1.0
  F  F23  1  0.672  0.657  0.722  1.0
  F  F24  1  0.265  0.143  0.557  1.0
  F  F25  1  0.735  0.857  0.443  1.0
  F  F26  1  0.285  0.559  0.615  1.0
  F  F27  1  0.715  0.441  0.385  1.0
  F  F28  1  0.787  0.270  0.162  1.0
  F  F29  1  0.213  0.730  0.838  1.0
[/CIF]
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The material structure described by C2NS3F2AsF6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AsF6 clusters and two C2NS3F2 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(5), one F(7), and one F(8) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(8) is bonded in a single-bond geometry to one As(1) atom. In each C2NS3F2 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one C(2), one F(4), and one F(6) atom. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one S(1) atom. N(1) is bonded in a bent 120 degrees geometry to one C(2) and one S(3) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(2) and one S(2) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one S(1) and one S(3) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1) and one S(2) atom. There are two inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one C(1) atom. In the second F site, F(6) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF card [CIF]
data_AsC2S3NF8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.719
_cell_length_b   7.888
_cell_length_c   9.816
_cell_angle_alpha   101.046
_cell_angle_beta   96.145
_cell_angle_gamma   106.945
_symmetry_Int_Tables_number   1
_cell_volume   481.087
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.556  0.304  0.223  1.0
  As  As1  1  0.444  0.696  0.777  1.0
  C  C2  1  0.051  0.106  0.532  1.0
  C  C3  1  0.949  0.894  0.468  1.0
  C  C4  1  0.023  0.829  0.331  1.0
  C  C5  1  0.977  0.171  0.669  1.0
  S  S6  1  0.204  0.708  0.342  1.0
  S  S7  1  0.796  0.292  0.658  1.0
  S  S8  1  0.251  0.678  0.139  1.0
  S  S9  1  0.749  0.322  0.861  1.0
  S  S10  1  0.023  0.796  0.070  1.0
  S  S11  1  0.977  0.204  0.930  1.0
  N  N12  1  0.051  0.142  0.785  1.0
  N  N13  1  0.949  0.858  0.215  1.0
  F  F14  1  0.513  0.108  0.293  1.0
  F  F15  1  0.487  0.892  0.707  1.0
  F  F16  1  0.402  0.167  0.059  1.0
  F  F17  1  0.598  0.833  0.941  1.0
  F  F18  1  0.603  0.501  0.152  1.0
  F  F19  1  0.397  0.499  0.848  1.0
  F  F20  1  0.997  0.195  0.435  1.0
  F  F21  1  0.003  0.805  0.565  1.0
  F  F22  1  0.328  0.343  0.278  1.0
  F  F23  1  0.672  0.657  0.722  1.0
  F  F24  1  0.265  0.143  0.557  1.0
  F  F25  1  0.735  0.857  0.443  1.0
  F  F26  1  0.285  0.559  0.615  1.0
  F  F27  1  0.715  0.441  0.385  1.0
  F  F28  1  0.787  0.270  0.162  1.0
  F  F29  1  0.213  0.730  0.838  1.0
[/CIF]
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