The compound described by SmLa7Ti3V5O24 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Cm space group. Sm(1) is bonded to one O(13), one O(9), two equivalent O(10), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form SmO12 cuboctahedra that share corners with four equivalent La(2)O12 cuboctahedra, corners with eight equivalent La(3)O12 cuboctahedra, faces with two equivalent La(5)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. There are five inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(13), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(10) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(4)O12 cuboctahedra, corners with four equivalent La(5)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. In the second La site, La(2) is bonded to one O(13), one O(9), two equivalent O(1), two equivalent O(10), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with eight equivalent La(3)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. In the third La site, La(3) is bonded to one O(1), one O(11), one O(14), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(12) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra, faces with two equivalent La(5)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. In the fourth La site, La(4) is bonded to one O(11), one O(14), two equivalent O(1), two equivalent O(12), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(5)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with four equivalent La(3)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. In the fifth La site, La(5) is bonded to one O(11), one O(14), two equivalent O(12), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(4)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with four equivalent La(3)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(11), one O(9), two equivalent O(1), and two equivalent O(5) atoms to form TiO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent Ti(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Ti site, Ti(2) is bonded to one O(1), one O(10), one O(12), one O(2), one O(5), and one O(6) atom to form TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(9), two equivalent O(3), and two equivalent O(7) atoms to form VO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second V site, V(2) is bonded to one O(10), one O(12), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(4)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third V site, V(3) is bonded to one O(13), one O(14), two equivalent O(2), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent V(4)O6 octahedra, corners with four equivalent Ti(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth V site, V(4) is bonded to one O(13), one O(14), two equivalent O(4), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one Ti(1), and one Ti(2) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one Ti(2), and one V(3) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one V(1), and one V(2) atom. In the fourth O site, O(4) is bonded to one La(1), one La(2), one La(3), one La(4), one V(2), and one V(4) atom to form distorted face-sharing OLa4V2 octahedra. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one Ti(1), and one Ti(2) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one Ti(2), and one V(3) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one V(1), and one V(2) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one V(2), and one V(4) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one Ti(1), and one V(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one Ti(2), and one V(2) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one Ti(1), and one V(1) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one Ti(2), and one V(2) atom. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one V(3), and one V(4) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one V(3), and one V(4) atom. is represented by the CIF file [CIF]
data_La7SmTi3V5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.918
_cell_length_b   7.918
_cell_length_c   7.913
_cell_angle_alpha   89.940
_cell_angle_beta   89.940
_cell_angle_gamma   89.723
_symmetry_Int_Tables_number   1
_cell_volume   496.163
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.748  0.252  0.746  1.0
  La  La1  1  0.749  0.749  0.746  1.0
  La  La2  1  0.748  0.252  0.254  1.0
  La  La3  1  0.748  0.748  0.254  1.0
  La  La4  1  0.252  0.748  0.746  1.0
  La  La5  1  0.251  0.251  0.254  1.0
  La  La6  1  0.252  0.748  0.254  1.0
  Sm  Sm7  1  0.253  0.253  0.744  1.0
  Ti  Ti8  1  0.001  0.001  0.999  1.0
  Ti  Ti9  1  0.001  0.499  0.999  1.0
  Ti  Ti10  1  0.499  0.001  0.999  1.0
  V  V11  1  0.000  0.000  0.500  1.0
  V  V12  1  0.000  0.500  0.500  1.0
  V  V13  1  0.500  0.500  0.000  1.0
  V  V14  1  0.500  0.000  0.500  1.0
  V  V15  1  0.500  0.500  0.501  1.0
  O  O16  1  0.750  0.001  0.999  1.0
  O  O17  1  0.755  0.500  1.000  1.0
  O  O18  1  0.746  0.001  0.500  1.0
  O  O19  1  0.751  0.501  0.500  1.0
  O  O20  1  0.250  0.002  0.999  1.0
  O  O21  1  0.245  0.498  0.998  1.0
  O  O22  1  0.254  0.002  0.503  1.0
  O  O23  1  0.249  0.496  0.503  1.0
  O  O24  1  0.002  0.002  0.756  1.0
  O  O25  1  0.002  0.498  0.755  1.0
  O  O26  1  1.000  1.000  0.243  1.0
  O  O27  1  0.000  0.500  0.245  1.0
  O  O28  1  0.498  0.002  0.755  1.0
  O  O29  1  0.497  0.497  0.746  1.0
  O  O30  1  0.500  0.000  0.245  1.0
  O  O31  1  0.500  0.500  0.254  1.0
  O  O32  1  0.002  0.250  0.999  1.0
  O  O33  1  0.001  0.750  0.999  1.0
  O  O34  1  0.002  0.254  0.503  1.0
  O  O35  1  0.001  0.746  0.500  1.0
  O  O36  1  0.498  0.245  0.998  1.0
  O  O37  1  0.500  0.755  1.000  1.0
  O  O38  1  0.496  0.249  0.503  1.0
  O  O39  1  0.501  0.751  0.500  1.0
[/CIF]
.
The compound described by SmLa7Ti3V5O24 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Cm space group. Sm(1) is bonded to one O(13), one O(9), two equivalent O(10), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form SmO12 cuboctahedra that share corners with four equivalent La(2)O12 cuboctahedra, corners with eight equivalent La(3)O12 cuboctahedra, faces with two equivalent La(5)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. There are five inequivalent La sites. In the first La site, La(1) is bonded to one O(1), one O(13), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(10) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(1)O12 cuboctahedra, corners with four equivalent La(4)O12 cuboctahedra, corners with four equivalent La(5)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with two equivalent La(3)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. In the second La site, La(2) is bonded to one O(13), one O(9), two equivalent O(1), two equivalent O(10), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with eight equivalent La(3)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra, faces with four equivalent La(1)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. In the third La site, La(3) is bonded to one O(1), one O(11), one O(14), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and two equivalent O(12) atoms to form LaO12 cuboctahedra that share corners with four equivalent Sm(1)O12 cuboctahedra, corners with four equivalent La(2)O12 cuboctahedra, corners with four equivalent La(3)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, faces with two equivalent La(4)O12 cuboctahedra, faces with two equivalent La(5)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. In the fourth La site, La(4) is bonded to one O(11), one O(14), two equivalent O(1), two equivalent O(12), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(5)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent La(2)O12 cuboctahedra, faces with four equivalent La(3)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. In the fifth La site, La(5) is bonded to one O(11), one O(14), two equivalent O(12), two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms to form LaO12 cuboctahedra that share corners with four equivalent La(4)O12 cuboctahedra, corners with eight equivalent La(1)O12 cuboctahedra, faces with two equivalent Sm(1)O12 cuboctahedra, faces with four equivalent La(3)O12 cuboctahedra,  a faceface with one Ti(1)O6 octahedra,  a faceface with one V(1)O6 octahedra,  a faceface with one V(3)O6 octahedra,  a faceface with one V(4)O6 octahedra, faces with two equivalent Ti(2)O6 octahedra, and faces with two equivalent V(2)O6 octahedra. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(11), one O(9), two equivalent O(1), and two equivalent O(5) atoms to form TiO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent Ti(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Ti site, Ti(2) is bonded to one O(1), one O(10), one O(12), one O(2), one O(5), and one O(6) atom to form TiO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(9), two equivalent O(3), and two equivalent O(7) atoms to form VO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second V site, V(2) is bonded to one O(10), one O(12), one O(3), one O(4), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(4)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the third V site, V(3) is bonded to one O(13), one O(14), two equivalent O(2), and two equivalent O(6) atoms to form VO6 octahedra that share corners with two equivalent V(4)O6 octahedra, corners with four equivalent Ti(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth V site, V(4) is bonded to one O(13), one O(14), two equivalent O(4), and two equivalent O(8) atoms to form VO6 octahedra that share corners with two equivalent V(3)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  a faceface with one Sm(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra,  a faceface with one La(4)O12 cuboctahedra,  a faceface with one La(5)O12 cuboctahedra, faces with two equivalent La(1)O12 cuboctahedra, and faces with two equivalent La(3)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-2°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one Ti(1), and one Ti(2) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one Ti(2), and one V(3) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one La(1), one La(2), one La(3), one La(4), one V(1), and one V(2) atom. In the fourth O site, O(4) is bonded to one La(1), one La(2), one La(3), one La(4), one V(2), and one V(4) atom to form distorted face-sharing OLa4V2 octahedra. In the fifth O site, O(5) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one Ti(1), and one Ti(2) atom. In the sixth O site, O(6) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one Ti(2), and one V(3) atom. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one V(1), and one V(2) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Sm(1), one La(1), one La(3), one La(5), one V(2), and one V(4) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one Ti(1), and one V(1) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one Ti(2), and one V(2) atom. In the eleventh O site, O(11) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one Ti(1), and one V(1) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one Ti(2), and one V(2) atom. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to one Sm(1), one La(2), two equivalent La(1), one V(3), and one V(4) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one La(4), one La(5), two equivalent La(3), one V(3), and one V(4) atom. is represented by the CIF file [CIF]
data_La7SmTi3V5O24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.918
_cell_length_b   7.918
_cell_length_c   7.913
_cell_angle_alpha   89.940
_cell_angle_beta   89.940
_cell_angle_gamma   89.723
_symmetry_Int_Tables_number   1
_cell_volume   496.163
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.748  0.252  0.746  1.0
  La  La1  1  0.749  0.749  0.746  1.0
  La  La2  1  0.748  0.252  0.254  1.0
  La  La3  1  0.748  0.748  0.254  1.0
  La  La4  1  0.252  0.748  0.746  1.0
  La  La5  1  0.251  0.251  0.254  1.0
  La  La6  1  0.252  0.748  0.254  1.0
  Sm  Sm7  1  0.253  0.253  0.744  1.0
  Ti  Ti8  1  0.001  0.001  0.999  1.0
  Ti  Ti9  1  0.001  0.499  0.999  1.0
  Ti  Ti10  1  0.499  0.001  0.999  1.0
  V  V11  1  0.000  0.000  0.500  1.0
  V  V12  1  0.000  0.500  0.500  1.0
  V  V13  1  0.500  0.500  0.000  1.0
  V  V14  1  0.500  0.000  0.500  1.0
  V  V15  1  0.500  0.500  0.501  1.0
  O  O16  1  0.750  0.001  0.999  1.0
  O  O17  1  0.755  0.500  1.000  1.0
  O  O18  1  0.746  0.001  0.500  1.0
  O  O19  1  0.751  0.501  0.500  1.0
  O  O20  1  0.250  0.002  0.999  1.0
  O  O21  1  0.245  0.498  0.998  1.0
  O  O22  1  0.254  0.002  0.503  1.0
  O  O23  1  0.249  0.496  0.503  1.0
  O  O24  1  0.002  0.002  0.756  1.0
  O  O25  1  0.002  0.498  0.755  1.0
  O  O26  1  1.000  1.000  0.243  1.0
  O  O27  1  0.000  0.500  0.245  1.0
  O  O28  1  0.498  0.002  0.755  1.0
  O  O29  1  0.497  0.497  0.746  1.0
  O  O30  1  0.500  0.000  0.245  1.0
  O  O31  1  0.500  0.500  0.254  1.0
  O  O32  1  0.002  0.250  0.999  1.0
  O  O33  1  0.001  0.750  0.999  1.0
  O  O34  1  0.002  0.254  0.503  1.0
  O  O35  1  0.001  0.746  0.500  1.0
  O  O36  1  0.498  0.245  0.998  1.0
  O  O37  1  0.500  0.755  1.000  1.0
  O  O38  1  0.496  0.249  0.503  1.0
  O  O39  1  0.501  0.751  0.500  1.0
[/CIF]
.