The material described by Rh(NCl3)2NO is Modderite structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four Rh(NCl3)2 clusters. In each Rh(NCl3)2 cluster, Rh(1) is bonded in an octahedral geometry to one Cl(1), one Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Cl(2) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Cl(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Rh(1) atom. In the second Cl site, Cl(1) is bonded in a water-like geometry to one Rh(1) and one N(2) atom. In the third Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one Rh(1) and one N(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one Rh(1) atom. is represented by the CIF file [CIF]
data_RhN3Cl6O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.911
_cell_length_b   11.804
_cell_length_c   13.667
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1114.923
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.250  0.730  0.595  1.0
  Rh  Rh1  1  0.250  0.230  0.905  1.0
  Rh  Rh2  1  0.750  0.270  0.405  1.0
  Rh  Rh3  1  0.750  0.770  0.095  1.0
  N  N4  1  0.250  0.973  0.032  1.0
  N  N5  1  0.250  0.473  0.468  1.0
  N  N6  1  0.750  0.027  0.968  1.0
  N  N7  1  0.750  0.527  0.532  1.0
  N  N8  1  0.250  0.502  0.797  1.0
  N  N9  1  0.250  0.002  0.703  1.0
  N  N10  1  0.750  0.498  0.203  1.0
  N  N11  1  0.750  0.998  0.297  1.0
  N  N12  1  0.250  0.608  0.130  1.0
  N  N13  1  0.250  0.108  0.370  1.0
  N  N14  1  0.750  0.392  0.870  1.0
  N  N15  1  0.750  0.892  0.630  1.0
  Cl  Cl16  1  0.250  0.874  0.742  1.0
  Cl  Cl17  1  0.250  0.374  0.758  1.0
  Cl  Cl18  1  0.750  0.126  0.258  1.0
  Cl  Cl19  1  0.750  0.626  0.242  1.0
  Cl  Cl20  1  0.250  0.605  0.455  1.0
  Cl  Cl21  1  0.250  0.105  0.045  1.0
  Cl  Cl22  1  0.750  0.395  0.545  1.0
  Cl  Cl23  1  0.750  0.895  0.955  1.0
  Cl  Cl24  1  0.013  0.627  0.673  1.0
  Cl  Cl25  1  0.487  0.127  0.827  1.0
  Cl  Cl26  1  0.513  0.373  0.327  1.0
  Cl  Cl27  1  0.987  0.873  0.173  1.0
  Cl  Cl28  1  0.987  0.373  0.327  1.0
  Cl  Cl29  1  0.513  0.873  0.173  1.0
  Cl  Cl30  1  0.487  0.627  0.673  1.0
  Cl  Cl31  1  0.013  0.127  0.827  1.0
  Cl  Cl32  1  0.013  0.842  0.514  1.0
  Cl  Cl33  1  0.487  0.342  0.986  1.0
  Cl  Cl34  1  0.513  0.158  0.486  1.0
  Cl  Cl35  1  0.987  0.658  0.014  1.0
  Cl  Cl36  1  0.987  0.158  0.486  1.0
  Cl  Cl37  1  0.513  0.658  0.014  1.0
  Cl  Cl38  1  0.487  0.842  0.514  1.0
  Cl  Cl39  1  0.013  0.342  0.986  1.0
  O  O40  1  0.250  0.013  0.355  1.0
  O  O41  1  0.250  0.513  0.145  1.0
  O  O42  1  0.750  0.987  0.645  1.0
  O  O43  1  0.750  0.487  0.855  1.0
[/CIF]
.
The material described by Rh(NCl3)2NO is Modderite structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four nitroxyl molecules and four Rh(NCl3)2 clusters. In each Rh(NCl3)2 cluster, Rh(1) is bonded in an octahedral geometry to one Cl(1), one Cl(2), two equivalent Cl(3), and two equivalent Cl(4) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Cl(2) atom. In the second N site, N(2) is bonded in a single-bond geometry to one Cl(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Rh(1) atom. In the second Cl site, Cl(1) is bonded in a water-like geometry to one Rh(1) and one N(2) atom. In the third Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one Rh(1) and one N(1) atom. In the fourth Cl site, Cl(3) is bonded in a single-bond geometry to one Rh(1) atom. is represented by the CIF file [CIF]
data_RhN3Cl6O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.911
_cell_length_b   11.804
_cell_length_c   13.667
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1114.923
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.250  0.730  0.595  1.0
  Rh  Rh1  1  0.250  0.230  0.905  1.0
  Rh  Rh2  1  0.750  0.270  0.405  1.0
  Rh  Rh3  1  0.750  0.770  0.095  1.0
  N  N4  1  0.250  0.973  0.032  1.0
  N  N5  1  0.250  0.473  0.468  1.0
  N  N6  1  0.750  0.027  0.968  1.0
  N  N7  1  0.750  0.527  0.532  1.0
  N  N8  1  0.250  0.502  0.797  1.0
  N  N9  1  0.250  0.002  0.703  1.0
  N  N10  1  0.750  0.498  0.203  1.0
  N  N11  1  0.750  0.998  0.297  1.0
  N  N12  1  0.250  0.608  0.130  1.0
  N  N13  1  0.250  0.108  0.370  1.0
  N  N14  1  0.750  0.392  0.870  1.0
  N  N15  1  0.750  0.892  0.630  1.0
  Cl  Cl16  1  0.250  0.874  0.742  1.0
  Cl  Cl17  1  0.250  0.374  0.758  1.0
  Cl  Cl18  1  0.750  0.126  0.258  1.0
  Cl  Cl19  1  0.750  0.626  0.242  1.0
  Cl  Cl20  1  0.250  0.605  0.455  1.0
  Cl  Cl21  1  0.250  0.105  0.045  1.0
  Cl  Cl22  1  0.750  0.395  0.545  1.0
  Cl  Cl23  1  0.750  0.895  0.955  1.0
  Cl  Cl24  1  0.013  0.627  0.673  1.0
  Cl  Cl25  1  0.487  0.127  0.827  1.0
  Cl  Cl26  1  0.513  0.373  0.327  1.0
  Cl  Cl27  1  0.987  0.873  0.173  1.0
  Cl  Cl28  1  0.987  0.373  0.327  1.0
  Cl  Cl29  1  0.513  0.873  0.173  1.0
  Cl  Cl30  1  0.487  0.627  0.673  1.0
  Cl  Cl31  1  0.013  0.127  0.827  1.0
  Cl  Cl32  1  0.013  0.842  0.514  1.0
  Cl  Cl33  1  0.487  0.342  0.986  1.0
  Cl  Cl34  1  0.513  0.158  0.486  1.0
  Cl  Cl35  1  0.987  0.658  0.014  1.0
  Cl  Cl36  1  0.987  0.158  0.486  1.0
  Cl  Cl37  1  0.513  0.658  0.014  1.0
  Cl  Cl38  1  0.487  0.842  0.514  1.0
  Cl  Cl39  1  0.013  0.342  0.986  1.0
  O  O40  1  0.250  0.013  0.355  1.0
  O  O41  1  0.250  0.513  0.145  1.0
  O  O42  1  0.750  0.987  0.645  1.0
  O  O43  1  0.750  0.487  0.855  1.0
[/CIF]
.