The material structure described by Li2V3CrO8 is Spinel-derived structured and crystallizes in the monoclinic Cc space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one O(3), one O(6), and one O(7) atom to form LiO4 tetrahedra that share corners with three equivalent V(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra, corners with three equivalent V(3)O6 octahedra, and corners with three equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-63°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(1), one O(4), one O(5), and one O(8) atom. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the second V site, V(2) is bonded to one O(2), one O(3), one O(4), one O(5), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the third V site, V(3) is bonded to one O(1), one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form VO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. Cr(1) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form CrO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. There are eight inequivalent O sites. In the first O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one V(2), and one Cr(1) atom. In the second O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one V(3), and one Cr(1) atom. In the third O site, O(2) is bonded to one Li(1), one V(1), one V(2), and one Cr(1) atom to form distorted OLiV2Cr tetrahedra that share  a cornercorner with one O(6)LiV2Cr tetrahedra, corners with two equivalent O(4)LiV3 tetrahedra,  a cornercorner with one O(7)LiV2Cr trigonal pyramid,  an edgeedge with one O(6)LiV2Cr tetrahedra, and  an edgeedge with one O(7)LiV2Cr trigonal pyramid. In the fourth O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one V(2), and one V(3) atom. In the fifth O site, O(4) is bonded to one Li(2), one V(1), one V(2), and one V(3) atom to form distorted corner-sharing OLiV3 tetrahedra. In the sixth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one V(3), and one Cr(1) atom. In the seventh O site, O(6) is bonded to one Li(1), one V(1), one V(3), and one Cr(1) atom to form distorted OLiV2Cr tetrahedra that share  a cornercorner with one O(2)LiV2Cr tetrahedra, corners with two equivalent O(4)LiV3 tetrahedra,  a cornercorner with one O(7)LiV2Cr trigonal pyramid,  an edgeedge with one O(2)LiV2Cr tetrahedra, and  an edgeedge with one O(7)LiV2Cr trigonal pyramid. In the eighth O site, O(7) is bonded to one Li(1), one V(2), one V(3), and one Cr(1) atom to form distorted OLiV2Cr trigonal pyramids that share  a cornercorner with one O(2)LiV2Cr tetrahedra,  a cornercorner with one O(6)LiV2Cr tetrahedra, corners with two equivalent O(4)LiV3 tetrahedra,  an edgeedge with one O(2)LiV2Cr tetrahedra, and  an edgeedge with one O(6)LiV2Cr tetrahedra. is represented by the CIF card [CIF]
data_Li2V3CrO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.909
_cell_length_b   5.909
_cell_length_c   9.622
_cell_angle_alpha   89.673
_cell_angle_beta   89.673
_cell_angle_gamma   120.290
_symmetry_Int_Tables_number   1
_cell_volume   290.115
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.666  0.332  0.895  1.0
  Li  Li1  1  0.997  1.000  0.996  1.0
  Li  Li2  1  1.000  0.997  0.496  1.0
  Li  Li3  1  0.332  0.666  0.395  1.0
  V  V4  1  0.340  0.170  0.209  1.0
  V  V5  1  0.824  0.658  0.215  1.0
  V  V6  1  0.826  0.166  0.214  1.0
  V  V7  1  0.166  0.826  0.714  1.0
  V  V8  1  0.170  0.340  0.709  1.0
  V  V9  1  0.658  0.824  0.715  1.0
  Cr  Cr10  1  0.669  0.332  0.485  1.0
  Cr  Cr11  1  0.332  0.669  0.985  1.0
  O  O12  1  0.327  0.156  0.604  1.0
  O  O13  1  0.528  0.488  0.339  1.0
  O  O14  1  0.689  0.346  0.100  1.0
  O  O15  1  0.989  0.994  0.311  1.0
  O  O16  1  0.994  0.989  0.811  1.0
  O  O17  1  0.835  0.668  0.605  1.0
  O  O18  1  0.530  0.040  0.337  1.0
  O  O19  1  0.962  0.481  0.339  1.0
  O  O20  1  0.157  0.832  0.104  1.0
  O  O21  1  0.832  0.157  0.604  1.0
  O  O22  1  0.040  0.530  0.837  1.0
  O  O23  1  0.481  0.962  0.839  1.0
  O  O24  1  0.346  0.689  0.600  1.0
  O  O25  1  0.156  0.327  0.104  1.0
  O  O26  1  0.488  0.528  0.839  1.0
  O  O27  1  0.668  0.835  0.105  1.0
[/CIF]
.
The material structure described by Li2V3CrO8 is Spinel-derived structured and crystallizes in the monoclinic Cc space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(2), one O(3), one O(6), and one O(7) atom to form LiO4 tetrahedra that share corners with three equivalent V(1)O6 octahedra, corners with three equivalent V(2)O6 octahedra, corners with three equivalent V(3)O6 octahedra, and corners with three equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-63°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(1), one O(4), one O(5), and one O(8) atom. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. In the second V site, V(2) is bonded to one O(2), one O(3), one O(4), one O(5), one O(7), and one O(8) atom to form VO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the third V site, V(3) is bonded to one O(1), one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form VO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one Cr(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. Cr(1) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form CrO6 octahedra that share corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with three equivalent Li(1)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, and  an edgeedge with one V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-53°. There are eight inequivalent O sites. In the first O site, O(8) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one V(2), and one Cr(1) atom. In the second O site, O(1) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one V(3), and one Cr(1) atom. In the third O site, O(2) is bonded to one Li(1), one V(1), one V(2), and one Cr(1) atom to form distorted OLiV2Cr tetrahedra that share  a cornercorner with one O(6)LiV2Cr tetrahedra, corners with two equivalent O(4)LiV3 tetrahedra,  a cornercorner with one O(7)LiV2Cr trigonal pyramid,  an edgeedge with one O(6)LiV2Cr tetrahedra, and  an edgeedge with one O(7)LiV2Cr trigonal pyramid. In the fourth O site, O(3) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(1), one V(2), and one V(3) atom. In the fifth O site, O(4) is bonded to one Li(2), one V(1), one V(2), and one V(3) atom to form distorted corner-sharing OLiV3 tetrahedra. In the sixth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(2), one V(3), and one Cr(1) atom. In the seventh O site, O(6) is bonded to one Li(1), one V(1), one V(3), and one Cr(1) atom to form distorted OLiV2Cr tetrahedra that share  a cornercorner with one O(2)LiV2Cr tetrahedra, corners with two equivalent O(4)LiV3 tetrahedra,  a cornercorner with one O(7)LiV2Cr trigonal pyramid,  an edgeedge with one O(2)LiV2Cr tetrahedra, and  an edgeedge with one O(7)LiV2Cr trigonal pyramid. In the eighth O site, O(7) is bonded to one Li(1), one V(2), one V(3), and one Cr(1) atom to form distorted OLiV2Cr trigonal pyramids that share  a cornercorner with one O(2)LiV2Cr tetrahedra,  a cornercorner with one O(6)LiV2Cr tetrahedra, corners with two equivalent O(4)LiV3 tetrahedra,  an edgeedge with one O(2)LiV2Cr tetrahedra, and  an edgeedge with one O(6)LiV2Cr tetrahedra. is represented by the CIF card [CIF]
data_Li2V3CrO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.909
_cell_length_b   5.909
_cell_length_c   9.622
_cell_angle_alpha   89.673
_cell_angle_beta   89.673
_cell_angle_gamma   120.290
_symmetry_Int_Tables_number   1
_cell_volume   290.115
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.666  0.332  0.895  1.0
  Li  Li1  1  0.997  1.000  0.996  1.0
  Li  Li2  1  1.000  0.997  0.496  1.0
  Li  Li3  1  0.332  0.666  0.395  1.0
  V  V4  1  0.340  0.170  0.209  1.0
  V  V5  1  0.824  0.658  0.215  1.0
  V  V6  1  0.826  0.166  0.214  1.0
  V  V7  1  0.166  0.826  0.714  1.0
  V  V8  1  0.170  0.340  0.709  1.0
  V  V9  1  0.658  0.824  0.715  1.0
  Cr  Cr10  1  0.669  0.332  0.485  1.0
  Cr  Cr11  1  0.332  0.669  0.985  1.0
  O  O12  1  0.327  0.156  0.604  1.0
  O  O13  1  0.528  0.488  0.339  1.0
  O  O14  1  0.689  0.346  0.100  1.0
  O  O15  1  0.989  0.994  0.311  1.0
  O  O16  1  0.994  0.989  0.811  1.0
  O  O17  1  0.835  0.668  0.605  1.0
  O  O18  1  0.530  0.040  0.337  1.0
  O  O19  1  0.962  0.481  0.339  1.0
  O  O20  1  0.157  0.832  0.104  1.0
  O  O21  1  0.832  0.157  0.604  1.0
  O  O22  1  0.040  0.530  0.837  1.0
  O  O23  1  0.481  0.962  0.839  1.0
  O  O24  1  0.346  0.689  0.600  1.0
  O  O25  1  0.156  0.327  0.104  1.0
  O  O26  1  0.488  0.528  0.839  1.0
  O  O27  1  0.668  0.835  0.105  1.0
[/CIF]
.