The material described by LaNH2SO7 crystallizes in the tetragonal P4_1 space group. La(1) is bonded in a 8-coordinate geometry to one N(1), one O(1), one O(3), one O(4), one O(6), one O(7), and two equivalent O(5) atoms. N(1) is bonded in a 3-coordinate geometry to one La(1), one O(5), and one O(6) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. S(1) is bonded in a trigonal non-coplanar geometry to one O(2), one O(3), and one O(4) atom. There are seven inequivalent O sites. In the first O site, O(4) is bonded in a linear geometry to one La(1) and one S(1) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to two equivalent La(1) and one N(1) atom. In the third O site, O(6) is bonded in a distorted water-like geometry to one La(1) and one N(1) atom. In the fourth O site, O(7) is bonded in a single-bond geometry to one La(1), one H(1), and one O(1) atom. In the fifth O site, O(1) is bonded in an L-shaped geometry to one La(1) and one O(7) atom. In the sixth O site, O(2) is bonded in a water-like geometry to one H(2) and one S(1) atom. In the seventh O site, O(3) is bonded in a bent 150 degrees geometry to one La(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LaH2SNO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.926
_cell_length_b   8.926
_cell_length_c   12.159
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   968.874
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.907  0.355  0.530  1.0
  La  La1  1  0.093  0.645  0.030  1.0
  La  La2  1  0.355  0.093  0.280  1.0
  La  La3  1  0.645  0.907  0.780  1.0
  H  H4  1  0.625  0.144  0.965  1.0
  H  H5  1  0.375  0.856  0.465  1.0
  H  H6  1  0.144  0.375  0.715  1.0
  H  H7  1  0.856  0.625  0.215  1.0
  H  H8  1  0.536  0.412  0.960  1.0
  H  H9  1  0.464  0.588  0.460  1.0
  H  H10  1  0.412  0.464  0.710  1.0
  H  H11  1  0.588  0.536  0.210  1.0
  S  S12  1  0.291  0.673  0.743  1.0
  S  S13  1  0.709  0.327  0.243  1.0
  S  S14  1  0.673  0.709  0.493  1.0
  S  S15  1  0.327  0.291  0.993  1.0
  N  N16  1  0.850  0.093  0.718  1.0
  N  N17  1  0.150  0.907  0.218  1.0
  N  N18  1  0.093  0.150  0.468  1.0
  N  N19  1  0.907  0.850  0.968  1.0
  O  O20  1  0.056  0.517  0.613  1.0
  O  O21  1  0.944  0.483  0.113  1.0
  O  O22  1  0.517  0.944  0.363  1.0
  O  O23  1  0.483  0.056  0.863  1.0
  O  O24  1  0.408  0.528  0.775  1.0
  O  O25  1  0.592  0.472  0.275  1.0
  O  O26  1  0.528  0.592  0.525  1.0
  O  O27  1  0.472  0.408  0.025  1.0
  O  O28  1  0.397  0.804  0.747  1.0
  O  O29  1  0.603  0.196  0.247  1.0
  O  O30  1  0.804  0.603  0.497  1.0
  O  O31  1  0.196  0.397  0.997  1.0
  O  O32  1  0.198  0.678  0.848  1.0
  O  O33  1  0.802  0.322  0.348  1.0
  O  O34  1  0.678  0.802  0.598  1.0
  O  O35  1  0.322  0.198  0.098  1.0
  O  O36  1  0.735  0.144  0.666  1.0
  O  O37  1  0.265  0.856  0.166  1.0
  O  O38  1  0.144  0.265  0.416  1.0
  O  O39  1  0.856  0.735  0.916  1.0
  O  O40  1  0.970  0.161  0.704  1.0
  O  O41  1  0.030  0.839  0.204  1.0
  O  O42  1  0.161  0.030  0.454  1.0
  O  O43  1  0.839  0.970  0.954  1.0
  O  O44  1  0.612  0.157  0.886  1.0
  O  O45  1  0.388  0.843  0.386  1.0
  O  O46  1  0.157  0.388  0.636  1.0
  O  O47  1  0.843  0.612  0.136  1.0
[/CIF]
.
The material described by LaNH2SO7 crystallizes in the tetragonal P4_1 space group. La(1) is bonded in a 8-coordinate geometry to one N(1), one O(1), one O(3), one O(4), one O(6), one O(7), and two equivalent O(5) atoms. N(1) is bonded in a 3-coordinate geometry to one La(1), one O(5), and one O(6) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. S(1) is bonded in a trigonal non-coplanar geometry to one O(2), one O(3), and one O(4) atom. There are seven inequivalent O sites. In the first O site, O(4) is bonded in a linear geometry to one La(1) and one S(1) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to two equivalent La(1) and one N(1) atom. In the third O site, O(6) is bonded in a distorted water-like geometry to one La(1) and one N(1) atom. In the fourth O site, O(7) is bonded in a single-bond geometry to one La(1), one H(1), and one O(1) atom. In the fifth O site, O(1) is bonded in an L-shaped geometry to one La(1) and one O(7) atom. In the sixth O site, O(2) is bonded in a water-like geometry to one H(2) and one S(1) atom. In the seventh O site, O(3) is bonded in a bent 150 degrees geometry to one La(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LaH2SNO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.926
_cell_length_b   8.926
_cell_length_c   12.159
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   968.874
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.907  0.355  0.530  1.0
  La  La1  1  0.093  0.645  0.030  1.0
  La  La2  1  0.355  0.093  0.280  1.0
  La  La3  1  0.645  0.907  0.780  1.0
  H  H4  1  0.625  0.144  0.965  1.0
  H  H5  1  0.375  0.856  0.465  1.0
  H  H6  1  0.144  0.375  0.715  1.0
  H  H7  1  0.856  0.625  0.215  1.0
  H  H8  1  0.536  0.412  0.960  1.0
  H  H9  1  0.464  0.588  0.460  1.0
  H  H10  1  0.412  0.464  0.710  1.0
  H  H11  1  0.588  0.536  0.210  1.0
  S  S12  1  0.291  0.673  0.743  1.0
  S  S13  1  0.709  0.327  0.243  1.0
  S  S14  1  0.673  0.709  0.493  1.0
  S  S15  1  0.327  0.291  0.993  1.0
  N  N16  1  0.850  0.093  0.718  1.0
  N  N17  1  0.150  0.907  0.218  1.0
  N  N18  1  0.093  0.150  0.468  1.0
  N  N19  1  0.907  0.850  0.968  1.0
  O  O20  1  0.056  0.517  0.613  1.0
  O  O21  1  0.944  0.483  0.113  1.0
  O  O22  1  0.517  0.944  0.363  1.0
  O  O23  1  0.483  0.056  0.863  1.0
  O  O24  1  0.408  0.528  0.775  1.0
  O  O25  1  0.592  0.472  0.275  1.0
  O  O26  1  0.528  0.592  0.525  1.0
  O  O27  1  0.472  0.408  0.025  1.0
  O  O28  1  0.397  0.804  0.747  1.0
  O  O29  1  0.603  0.196  0.247  1.0
  O  O30  1  0.804  0.603  0.497  1.0
  O  O31  1  0.196  0.397  0.997  1.0
  O  O32  1  0.198  0.678  0.848  1.0
  O  O33  1  0.802  0.322  0.348  1.0
  O  O34  1  0.678  0.802  0.598  1.0
  O  O35  1  0.322  0.198  0.098  1.0
  O  O36  1  0.735  0.144  0.666  1.0
  O  O37  1  0.265  0.856  0.166  1.0
  O  O38  1  0.144  0.265  0.416  1.0
  O  O39  1  0.856  0.735  0.916  1.0
  O  O40  1  0.970  0.161  0.704  1.0
  O  O41  1  0.030  0.839  0.204  1.0
  O  O42  1  0.161  0.030  0.454  1.0
  O  O43  1  0.839  0.970  0.954  1.0
  O  O44  1  0.612  0.157  0.886  1.0
  O  O45  1  0.388  0.843  0.386  1.0
  O  O46  1  0.157  0.388  0.636  1.0
  O  O47  1  0.843  0.612  0.136  1.0
[/CIF]
.