The compound described by PtPbF6 crystallizes in the trigonal R-3m space group. Pt(1) is bonded to six equivalent F(1) atoms to form PtF6 octahedra that share corners with six equivalent Pb(1)F12 cuboctahedra and faces with two equivalent Pb(1)F12 cuboctahedra. Pb(1) is bonded to twelve equivalent F(1) atoms to form PbF12 cuboctahedra that share corners with six equivalent Pt(1)F6 octahedra, edges with six equivalent Pb(1)F12 cuboctahedra, and faces with two equivalent Pt(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. F(1) is bonded in a single-bond geometry to one Pt(1) and two equivalent Pb(1) atoms. is represented by the CIF file [CIF]
data_PtPbF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.826
_cell_length_b   4.826
_cell_length_c   4.826
_cell_angle_alpha   97.965
_cell_angle_beta   97.965
_cell_angle_gamma   97.965
_symmetry_Int_Tables_number   1
_cell_volume   108.806
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.000  0.000  0.000  1.0
  Pb  Pb1  1  0.500  0.500  0.500  1.0
  F  F2  1  0.706  0.706  0.062  1.0
  F  F3  1  0.706  0.062  0.706  1.0
  F  F4  1  0.294  0.938  0.294  1.0
  F  F5  1  0.294  0.294  0.938  1.0
  F  F6  1  0.938  0.294  0.294  1.0
  F  F7  1  0.062  0.706  0.706  1.0
[/CIF]
.
The compound described by PtPbF6 crystallizes in the trigonal R-3m space group. Pt(1) is bonded to six equivalent F(1) atoms to form PtF6 octahedra that share corners with six equivalent Pb(1)F12 cuboctahedra and faces with two equivalent Pb(1)F12 cuboctahedra. Pb(1) is bonded to twelve equivalent F(1) atoms to form PbF12 cuboctahedra that share corners with six equivalent Pt(1)F6 octahedra, edges with six equivalent Pb(1)F12 cuboctahedra, and faces with two equivalent Pt(1)F6 octahedra. The corner-sharing octahedral tilt angles are 41°. F(1) is bonded in a single-bond geometry to one Pt(1) and two equivalent Pb(1) atoms. is represented by the CIF file [CIF]
data_PtPbF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.826
_cell_length_b   4.826
_cell_length_c   4.826
_cell_angle_alpha   97.965
_cell_angle_beta   97.965
_cell_angle_gamma   97.965
_symmetry_Int_Tables_number   1
_cell_volume   108.806
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.000  0.000  0.000  1.0
  Pb  Pb1  1  0.500  0.500  0.500  1.0
  F  F2  1  0.706  0.706  0.062  1.0
  F  F3  1  0.706  0.062  0.706  1.0
  F  F4  1  0.294  0.938  0.294  1.0
  F  F5  1  0.294  0.294  0.938  1.0
  F  F6  1  0.938  0.294  0.294  1.0
  F  F7  1  0.062  0.706  0.706  1.0
[/CIF]
.