The crystal structure described by WMnP2O8 crystallizes in the monoclinic P2_1/m space group. W(1) is bonded to one O(1), one O(3), two equivalent O(5), and two equivalent O(6) atoms to form WO6 octahedra that share corners with four equivalent Mn(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with three equivalent P(1)O4 tetrahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-54°. Mn(1) is bonded to one O(2), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form distorted MnO6 octahedra that share corners with four equivalent W(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-54°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), and two equivalent O(5) atoms to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with three equivalent W(1)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the second P site, P(2) is bonded to one O(3), one O(4), and two equivalent O(6) atoms to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra, corners with three equivalent Mn(1)O6 octahedra, and  an edgeedge with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-61°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one W(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one W(1), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(1), and one P(2) atom. is represented by the CIF file [CIF]
data_MnP2WO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.036
_cell_length_b   10.299
_cell_length_c   6.053
_cell_angle_alpha   90.002
_cell_angle_beta   90.003
_cell_angle_gamma   92.773
_symmetry_Int_Tables_number   1
_cell_volume   313.541
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.053  0.724  0.750  1.0
  Mn  Mn1  1  0.947  0.276  0.250  1.0
  P  P2  1  0.406  0.087  0.250  1.0
  P  P3  1  0.594  0.913  0.750  1.0
  P  P4  1  0.889  0.401  0.750  1.0
  P  P5  1  0.111  0.599  0.250  1.0
  W  W6  1  0.445  0.217  0.750  1.0
  W  W7  1  0.555  0.783  0.250  1.0
  O  O8  1  0.692  0.056  0.750  1.0
  O  O9  1  0.309  0.944  0.250  1.0
  O  O10  1  0.705  0.105  0.250  1.0
  O  O11  1  0.295  0.895  0.750  1.0
  O  O12  1  0.181  0.367  0.750  1.0
  O  O13  1  0.819  0.633  0.250  1.0
  O  O14  1  0.146  0.455  0.250  1.0
  O  O15  1  0.854  0.545  0.750  1.0
  O  O16  1  0.277  0.161  0.047  1.0
  O  O17  1  0.277  0.161  0.453  1.0
  O  O18  1  0.723  0.839  0.547  1.0
  O  O19  1  0.723  0.839  0.953  1.0
  O  O20  1  0.731  0.326  0.945  1.0
  O  O21  1  0.731  0.326  0.555  1.0
  O  O22  1  0.269  0.674  0.055  1.0
  O  O23  1  0.269  0.674  0.445  1.0
[/CIF]
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The crystal structure described by WMnP2O8 crystallizes in the monoclinic P2_1/m space group. W(1) is bonded to one O(1), one O(3), two equivalent O(5), and two equivalent O(6) atoms to form WO6 octahedra that share corners with four equivalent Mn(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, corners with three equivalent P(1)O4 tetrahedra, and  an edgeedge with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-54°. Mn(1) is bonded to one O(2), one O(4), two equivalent O(5), and two equivalent O(6) atoms to form distorted MnO6 octahedra that share corners with four equivalent W(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, corners with three equivalent P(2)O4 tetrahedra, and  an edgeedge with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-54°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), and two equivalent O(5) atoms to form PO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra, corners with three equivalent W(1)O6 octahedra, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-55°. In the second P site, P(2) is bonded to one O(3), one O(4), and two equivalent O(6) atoms to form PO4 tetrahedra that share  a cornercorner with one W(1)O6 octahedra, corners with three equivalent Mn(1)O6 octahedra, and  an edgeedge with one W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-61°. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one W(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mn(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one W(1), one Mn(1), and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one W(1), one Mn(1), and one P(2) atom. is represented by the CIF file [CIF]
data_MnP2WO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.036
_cell_length_b   10.299
_cell_length_c   6.053
_cell_angle_alpha   90.002
_cell_angle_beta   90.003
_cell_angle_gamma   92.773
_symmetry_Int_Tables_number   1
_cell_volume   313.541
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.053  0.724  0.750  1.0
  Mn  Mn1  1  0.947  0.276  0.250  1.0
  P  P2  1  0.406  0.087  0.250  1.0
  P  P3  1  0.594  0.913  0.750  1.0
  P  P4  1  0.889  0.401  0.750  1.0
  P  P5  1  0.111  0.599  0.250  1.0
  W  W6  1  0.445  0.217  0.750  1.0
  W  W7  1  0.555  0.783  0.250  1.0
  O  O8  1  0.692  0.056  0.750  1.0
  O  O9  1  0.309  0.944  0.250  1.0
  O  O10  1  0.705  0.105  0.250  1.0
  O  O11  1  0.295  0.895  0.750  1.0
  O  O12  1  0.181  0.367  0.750  1.0
  O  O13  1  0.819  0.633  0.250  1.0
  O  O14  1  0.146  0.455  0.250  1.0
  O  O15  1  0.854  0.545  0.750  1.0
  O  O16  1  0.277  0.161  0.047  1.0
  O  O17  1  0.277  0.161  0.453  1.0
  O  O18  1  0.723  0.839  0.547  1.0
  O  O19  1  0.723  0.839  0.953  1.0
  O  O20  1  0.731  0.326  0.945  1.0
  O  O21  1  0.731  0.326  0.555  1.0
  O  O22  1  0.269  0.674  0.055  1.0
  O  O23  1  0.269  0.674  0.445  1.0
[/CIF]
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