The compound described by GaC2NCl4 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four GaC2NCl4 clusters. Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(3), and two equivalent Cl(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one N(1) atom. In the second C site, C(2) is bonded in a trigonal non-coplanar geometry to one N(1) and two equivalent Cl(2) atoms. N(1) is bonded in a linear geometry to one C(1) and one C(2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(2) is bonded in an L-shaped geometry to one Ga(1) and one C(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. is represented by the CIF file [CIF]
data_GaC2NCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.378
_cell_length_b   10.261
_cell_length_c   12.217
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   924.900
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.250  0.239  0.021  1.0
  Ga  Ga1  1  0.250  0.261  0.521  1.0
  Ga  Ga2  1  0.750  0.761  0.979  1.0
  Ga  Ga3  1  0.750  0.739  0.479  1.0
  C  C4  1  0.250  0.785  0.134  1.0
  C  C5  1  0.250  0.715  0.634  1.0
  C  C6  1  0.750  0.215  0.866  1.0
  C  C7  1  0.750  0.285  0.366  1.0
  C  C8  1  0.250  0.018  0.200  1.0
  C  C9  1  0.250  0.482  0.700  1.0
  C  C10  1  0.750  0.982  0.800  1.0
  C  C11  1  0.750  0.518  0.300  1.0
  N  N12  1  0.250  0.900  0.151  1.0
  N  N13  1  0.250  0.600  0.651  1.0
  N  N14  1  0.750  0.100  0.849  1.0
  N  N15  1  0.750  0.400  0.349  1.0
  Cl  Cl16  1  0.250  0.178  0.854  1.0
  Cl  Cl17  1  0.250  0.322  0.354  1.0
  Cl  Cl18  1  0.750  0.822  0.146  1.0
  Cl  Cl19  1  0.750  0.678  0.646  1.0
  Cl  Cl20  1  0.041  0.118  0.123  1.0
  Cl  Cl21  1  0.459  0.382  0.623  1.0
  Cl  Cl22  1  0.541  0.882  0.877  1.0
  Cl  Cl23  1  0.959  0.618  0.377  1.0
  Cl  Cl24  1  0.959  0.882  0.877  1.0
  Cl  Cl25  1  0.541  0.618  0.377  1.0
  Cl  Cl26  1  0.459  0.118  0.123  1.0
  Cl  Cl27  1  0.041  0.382  0.623  1.0
  Cl  Cl28  1  0.250  0.439  0.063  1.0
  Cl  Cl29  1  0.250  0.061  0.563  1.0
  Cl  Cl30  1  0.750  0.561  0.937  1.0
  Cl  Cl31  1  0.750  0.939  0.437  1.0
[/CIF]
.
The compound described by GaC2NCl4 is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four GaC2NCl4 clusters. Ga(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(3), and two equivalent Cl(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one N(1) atom. In the second C site, C(2) is bonded in a trigonal non-coplanar geometry to one N(1) and two equivalent Cl(2) atoms. N(1) is bonded in a linear geometry to one C(1) and one C(2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ga(1) atom. In the second Cl site, Cl(2) is bonded in an L-shaped geometry to one Ga(1) and one C(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Ga(1) atom. is represented by the CIF file [CIF]
data_GaC2NCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.378
_cell_length_b   10.261
_cell_length_c   12.217
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   924.900
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.250  0.239  0.021  1.0
  Ga  Ga1  1  0.250  0.261  0.521  1.0
  Ga  Ga2  1  0.750  0.761  0.979  1.0
  Ga  Ga3  1  0.750  0.739  0.479  1.0
  C  C4  1  0.250  0.785  0.134  1.0
  C  C5  1  0.250  0.715  0.634  1.0
  C  C6  1  0.750  0.215  0.866  1.0
  C  C7  1  0.750  0.285  0.366  1.0
  C  C8  1  0.250  0.018  0.200  1.0
  C  C9  1  0.250  0.482  0.700  1.0
  C  C10  1  0.750  0.982  0.800  1.0
  C  C11  1  0.750  0.518  0.300  1.0
  N  N12  1  0.250  0.900  0.151  1.0
  N  N13  1  0.250  0.600  0.651  1.0
  N  N14  1  0.750  0.100  0.849  1.0
  N  N15  1  0.750  0.400  0.349  1.0
  Cl  Cl16  1  0.250  0.178  0.854  1.0
  Cl  Cl17  1  0.250  0.322  0.354  1.0
  Cl  Cl18  1  0.750  0.822  0.146  1.0
  Cl  Cl19  1  0.750  0.678  0.646  1.0
  Cl  Cl20  1  0.041  0.118  0.123  1.0
  Cl  Cl21  1  0.459  0.382  0.623  1.0
  Cl  Cl22  1  0.541  0.882  0.877  1.0
  Cl  Cl23  1  0.959  0.618  0.377  1.0
  Cl  Cl24  1  0.959  0.882  0.877  1.0
  Cl  Cl25  1  0.541  0.618  0.377  1.0
  Cl  Cl26  1  0.459  0.118  0.123  1.0
  Cl  Cl27  1  0.041  0.382  0.623  1.0
  Cl  Cl28  1  0.250  0.439  0.063  1.0
  Cl  Cl29  1  0.250  0.061  0.563  1.0
  Cl  Cl30  1  0.750  0.561  0.937  1.0
  Cl  Cl31  1  0.750  0.939  0.437  1.0
[/CIF]
.