The compound described by SmCoC6(N2O)3O2 crystallizes in the hexagonal P6_3/m space group. The structure consists of four water atoms inside a SmCoC6(N2O)3 framework. In the SmCoC6(N2O)3 framework, Sm(1) is bonded in a 9-coordinate geometry to six equivalent N(1) and three equivalent O(2) atoms. Co(1) is bonded in an octahedral geometry to six equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Co(1) and one N(1) atom. N(1) is bonded in a linear geometry to one Sm(1) and one C(1) atom. O(2) is bonded in a single-bond geometry to one Sm(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SmCoC6N6O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.682
_cell_length_b   7.682
_cell_length_c   12.891
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   658.826
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.333  0.667  0.750  1.0
  Sm  Sm1  1  0.667  0.333  0.250  1.0
  Co  Co2  1  0.000  0.000  0.000  1.0
  Co  Co3  1  0.000  0.000  0.500  1.0
  C  C4  1  0.769  0.897  0.918  1.0
  C  C5  1  0.231  0.103  0.082  1.0
  C  C6  1  0.128  0.231  0.918  1.0
  C  C7  1  0.231  0.103  0.418  1.0
  C  C8  1  0.872  0.769  0.082  1.0
  C  C9  1  0.769  0.897  0.582  1.0
  C  C10  1  0.103  0.872  0.918  1.0
  C  C11  1  0.872  0.769  0.418  1.0
  C  C12  1  0.897  0.128  0.082  1.0
  C  C13  1  0.128  0.231  0.582  1.0
  C  C14  1  0.897  0.128  0.418  1.0
  C  C15  1  0.103  0.872  0.582  1.0
  N  N16  1  0.622  0.830  0.869  1.0
  N  N17  1  0.378  0.170  0.131  1.0
  N  N18  1  0.208  0.378  0.869  1.0
  N  N19  1  0.378  0.170  0.369  1.0
  N  N20  1  0.792  0.622  0.131  1.0
  N  N21  1  0.622  0.830  0.631  1.0
  N  N22  1  0.170  0.792  0.869  1.0
  N  N23  1  0.792  0.622  0.369  1.0
  N  N24  1  0.830  0.208  0.131  1.0
  N  N25  1  0.208  0.378  0.631  1.0
  N  N26  1  0.830  0.208  0.369  1.0
  N  N27  1  0.170  0.792  0.631  1.0
  O  O28  1  0.667  0.333  0.840  1.0
  O  O29  1  0.333  0.667  0.160  1.0
  O  O30  1  0.333  0.667  0.340  1.0
  O  O31  1  0.667  0.333  0.660  1.0
  O  O32  1  0.931  0.441  0.750  1.0
  O  O33  1  0.069  0.559  0.250  1.0
  O  O34  1  0.510  0.069  0.750  1.0
  O  O35  1  0.490  0.931  0.250  1.0
  O  O36  1  0.559  0.490  0.750  1.0
  O  O37  1  0.441  0.510  0.250  1.0
[/CIF]
.
The compound described by SmCoC6(N2O)3O2 crystallizes in the hexagonal P6_3/m space group. The structure consists of four water atoms inside a SmCoC6(N2O)3 framework. In the SmCoC6(N2O)3 framework, Sm(1) is bonded in a 9-coordinate geometry to six equivalent N(1) and three equivalent O(2) atoms. Co(1) is bonded in an octahedral geometry to six equivalent C(1) atoms. C(1) is bonded in a linear geometry to one Co(1) and one N(1) atom. N(1) is bonded in a linear geometry to one Sm(1) and one C(1) atom. O(2) is bonded in a single-bond geometry to one Sm(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SmCoC6N6O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.682
_cell_length_b   7.682
_cell_length_c   12.891
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   658.826
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.333  0.667  0.750  1.0
  Sm  Sm1  1  0.667  0.333  0.250  1.0
  Co  Co2  1  0.000  0.000  0.000  1.0
  Co  Co3  1  0.000  0.000  0.500  1.0
  C  C4  1  0.769  0.897  0.918  1.0
  C  C5  1  0.231  0.103  0.082  1.0
  C  C6  1  0.128  0.231  0.918  1.0
  C  C7  1  0.231  0.103  0.418  1.0
  C  C8  1  0.872  0.769  0.082  1.0
  C  C9  1  0.769  0.897  0.582  1.0
  C  C10  1  0.103  0.872  0.918  1.0
  C  C11  1  0.872  0.769  0.418  1.0
  C  C12  1  0.897  0.128  0.082  1.0
  C  C13  1  0.128  0.231  0.582  1.0
  C  C14  1  0.897  0.128  0.418  1.0
  C  C15  1  0.103  0.872  0.582  1.0
  N  N16  1  0.622  0.830  0.869  1.0
  N  N17  1  0.378  0.170  0.131  1.0
  N  N18  1  0.208  0.378  0.869  1.0
  N  N19  1  0.378  0.170  0.369  1.0
  N  N20  1  0.792  0.622  0.131  1.0
  N  N21  1  0.622  0.830  0.631  1.0
  N  N22  1  0.170  0.792  0.869  1.0
  N  N23  1  0.792  0.622  0.369  1.0
  N  N24  1  0.830  0.208  0.131  1.0
  N  N25  1  0.208  0.378  0.631  1.0
  N  N26  1  0.830  0.208  0.369  1.0
  N  N27  1  0.170  0.792  0.631  1.0
  O  O28  1  0.667  0.333  0.840  1.0
  O  O29  1  0.333  0.667  0.160  1.0
  O  O30  1  0.333  0.667  0.340  1.0
  O  O31  1  0.667  0.333  0.660  1.0
  O  O32  1  0.931  0.441  0.750  1.0
  O  O33  1  0.069  0.559  0.250  1.0
  O  O34  1  0.510  0.069  0.750  1.0
  O  O35  1  0.490  0.931  0.250  1.0
  O  O36  1  0.559  0.490  0.750  1.0
  O  O37  1  0.441  0.510  0.250  1.0
[/CIF]
.