The crystal structure described by TmSbO4 crystallizes in the triclinic P-1 space group. There are two inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(5), one O(7), two equivalent O(6), and two equivalent O(8) atoms. In the second Tm site, Tm(2) is bonded in a 7-coordinate geometry to one O(3), one O(4), one O(6), one O(7), one O(8), and two equivalent O(5) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(7) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 42-49°. In the second Sb site, Sb(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(8) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 42-49°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Tm(1), one Sb(1), and one Sb(2) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Tm(1), one Sb(1), and one Sb(2) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Tm(2), one Sb(1), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Tm(2), one Sb(1), and one Sb(2) atom. In the fifth O site, O(5) is bonded to one Tm(1), two equivalent Tm(2), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OTm3Sb tetrahedra. In the sixth O site, O(6) is bonded to one Tm(2), two equivalent Tm(1), and one Sb(2) atom to form a mixture of distorted edge and corner-sharing OTm3Sb tetrahedra. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Tm(1), one Tm(2), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Tm(2), two equivalent Tm(1), and one Sb(2) atom. is represented by the CIF card [CIF]
data_TmSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.276
_cell_length_b   7.526
_cell_length_c   7.413
_cell_angle_alpha   81.477
_cell_angle_beta   90.321
_cell_angle_gamma   91.782
_symmetry_Int_Tables_number   1
_cell_volume   290.965
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.264  0.133  0.616  1.0
  Tm  Tm1  1  0.736  0.867  0.384  1.0
  Tm  Tm2  1  0.216  0.155  0.111  1.0
  Tm  Tm3  1  0.784  0.845  0.889  1.0
  Sb  Sb4  1  0.238  0.664  0.193  1.0
  Sb  Sb5  1  0.762  0.336  0.807  1.0
  Sb  Sb6  1  0.725  0.336  0.309  1.0
  Sb  Sb7  1  0.275  0.664  0.691  1.0
  O  O8  1  0.090  0.433  0.689  1.0
  O  O9  1  0.910  0.567  0.311  1.0
  O  O10  1  0.605  0.326  0.562  1.0
  O  O11  1  0.395  0.674  0.438  1.0
  O  O12  1  0.878  0.330  0.063  1.0
  O  O13  1  0.122  0.670  0.937  1.0
  O  O14  1  0.401  0.430  0.193  1.0
  O  O15  1  0.599  0.570  0.807  1.0
  O  O16  1  0.038  0.888  0.174  1.0
  O  O17  1  0.962  0.112  0.826  1.0
  O  O18  1  0.511  0.109  0.323  1.0
  O  O19  1  0.489  0.891  0.677  1.0
  O  O20  1  0.467  0.185  0.881  1.0
  O  O21  1  0.533  0.815  0.119  1.0
  O  O22  1  0.998  0.171  0.385  1.0
  O  O23  1  0.002  0.829  0.615  1.0
[/CIF]
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The crystal structure described by TmSbO4 crystallizes in the triclinic P-1 space group. There are two inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(5), one O(7), two equivalent O(6), and two equivalent O(8) atoms. In the second Tm site, Tm(2) is bonded in a 7-coordinate geometry to one O(3), one O(4), one O(6), one O(7), one O(8), and two equivalent O(5) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(7) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 42-49°. In the second Sb site, Sb(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), and one O(8) atom to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 42-49°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Tm(1), one Sb(1), and one Sb(2) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Tm(1), one Sb(1), and one Sb(2) atom. In the third O site, O(3) is bonded in a trigonal non-coplanar geometry to one Tm(2), one Sb(1), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Tm(2), one Sb(1), and one Sb(2) atom. In the fifth O site, O(5) is bonded to one Tm(1), two equivalent Tm(2), and one Sb(1) atom to form a mixture of distorted edge and corner-sharing OTm3Sb tetrahedra. In the sixth O site, O(6) is bonded to one Tm(2), two equivalent Tm(1), and one Sb(2) atom to form a mixture of distorted edge and corner-sharing OTm3Sb tetrahedra. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Tm(1), one Tm(2), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Tm(2), two equivalent Tm(1), and one Sb(2) atom. is represented by the CIF card [CIF]
data_TmSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.276
_cell_length_b   7.526
_cell_length_c   7.413
_cell_angle_alpha   81.477
_cell_angle_beta   90.321
_cell_angle_gamma   91.782
_symmetry_Int_Tables_number   1
_cell_volume   290.965
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.264  0.133  0.616  1.0
  Tm  Tm1  1  0.736  0.867  0.384  1.0
  Tm  Tm2  1  0.216  0.155  0.111  1.0
  Tm  Tm3  1  0.784  0.845  0.889  1.0
  Sb  Sb4  1  0.238  0.664  0.193  1.0
  Sb  Sb5  1  0.762  0.336  0.807  1.0
  Sb  Sb6  1  0.725  0.336  0.309  1.0
  Sb  Sb7  1  0.275  0.664  0.691  1.0
  O  O8  1  0.090  0.433  0.689  1.0
  O  O9  1  0.910  0.567  0.311  1.0
  O  O10  1  0.605  0.326  0.562  1.0
  O  O11  1  0.395  0.674  0.438  1.0
  O  O12  1  0.878  0.330  0.063  1.0
  O  O13  1  0.122  0.670  0.937  1.0
  O  O14  1  0.401  0.430  0.193  1.0
  O  O15  1  0.599  0.570  0.807  1.0
  O  O16  1  0.038  0.888  0.174  1.0
  O  O17  1  0.962  0.112  0.826  1.0
  O  O18  1  0.511  0.109  0.323  1.0
  O  O19  1  0.489  0.891  0.677  1.0
  O  O20  1  0.467  0.185  0.881  1.0
  O  O21  1  0.533  0.815  0.119  1.0
  O  O22  1  0.998  0.171  0.385  1.0
  O  O23  1  0.002  0.829  0.615  1.0
[/CIF]
.