The crystal structure described by WMoO6 crystallizes in the monoclinic Cm space group. W(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form WO6 octahedra that share corners with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-14°. Mo(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form MoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-14°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one W(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a linear geometry to one W(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a linear geometry to one W(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one W(1) and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.465
_cell_length_b   5.465
_cell_length_c   5.534
_cell_angle_alpha   59.810
_cell_angle_beta   59.810
_cell_angle_gamma   60.304
_symmetry_Int_Tables_number   1
_cell_volume   116.798
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.490  0.490  0.496  1.0
  W  W1  1  0.989  0.989  0.995  1.0
  O  O2  1  0.745  0.254  0.198  1.0
  O  O3  1  0.253  0.750  0.699  1.0
  O  O4  1  0.749  0.749  0.192  1.0
  O  O5  1  0.254  0.745  0.198  1.0
  O  O6  1  0.750  0.253  0.699  1.0
  O  O7  1  0.251  0.251  0.696  1.0
[/CIF]
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The crystal structure described by WMoO6 crystallizes in the monoclinic Cm space group. W(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form WO6 octahedra that share corners with six equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-14°. Mo(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form MoO6 octahedra that share corners with six equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 9-14°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one W(1) and one Mo(1) atom. In the second O site, O(2) is bonded in a linear geometry to one W(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a linear geometry to one W(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one W(1) and one Mo(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MoWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.465
_cell_length_b   5.465
_cell_length_c   5.534
_cell_angle_alpha   59.810
_cell_angle_beta   59.810
_cell_angle_gamma   60.304
_symmetry_Int_Tables_number   1
_cell_volume   116.798
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.490  0.490  0.496  1.0
  W  W1  1  0.989  0.989  0.995  1.0
  O  O2  1  0.745  0.254  0.198  1.0
  O  O3  1  0.253  0.750  0.699  1.0
  O  O4  1  0.749  0.749  0.192  1.0
  O  O5  1  0.254  0.745  0.198  1.0
  O  O6  1  0.750  0.253  0.699  1.0
  O  O7  1  0.251  0.251  0.696  1.0
[/CIF]
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