The compound described by (SnH5(OCl)3)2H2O is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four water molecules and four SnH5(OCl)3 clusters. In each SnH5(OCl)3 cluster, Sn(1) is bonded to one O(2), two equivalent O(1), one Cl(1), one Cl(2), and one Cl(3) atom to form edge-sharing SnCl3O3 octahedra. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(2) and one O(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Sn(1) and one H(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Sn(1), one H(2), and one H(3) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one H(3), one H(4), and one H(5) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the CIF file [CIF]
data_Sn2H12Cl6O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.340
_cell_length_b   7.340
_cell_length_c   17.447
_cell_angle_alpha   85.814
_cell_angle_beta   85.814
_cell_angle_gamma   63.174
_symmetry_Int_Tables_number   1
_cell_volume   835.721
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.080  0.369  0.918  1.0
  Sn  Sn1  1  0.631  0.920  0.582  1.0
  Sn  Sn2  1  0.920  0.631  0.082  1.0
  Sn  Sn3  1  0.369  0.080  0.418  1.0
  H  H4  1  0.158  0.222  0.069  1.0
  H  H5  1  0.778  0.842  0.431  1.0
  H  H6  1  0.842  0.778  0.931  1.0
  H  H7  1  0.222  0.158  0.569  1.0
  H  H8  1  0.765  0.316  0.004  1.0
  H  H9  1  0.684  0.235  0.496  1.0
  H  H10  1  0.235  0.684  0.996  1.0
  H  H11  1  0.316  0.765  0.504  1.0
  H  H12  1  0.818  0.170  0.928  1.0
  H  H13  1  0.830  0.182  0.572  1.0
  H  H14  1  0.182  0.830  0.072  1.0
  H  H15  1  0.170  0.818  0.428  1.0
  H  H16  1  0.897  0.973  0.831  1.0
  H  H17  1  0.027  0.103  0.669  1.0
  H  H18  1  0.103  0.027  0.169  1.0
  H  H19  1  0.973  0.897  0.331  1.0
  H  H20  1  0.664  0.058  0.857  1.0
  H  H21  1  0.942  0.336  0.643  1.0
  H  H22  1  0.336  0.942  0.143  1.0
  H  H23  1  0.058  0.664  0.357  1.0
  H  H24  1  0.213  0.894  0.770  1.0
  H  H25  1  0.106  0.787  0.730  1.0
  H  H26  1  0.787  0.106  0.230  1.0
  H  H27  1  0.894  0.213  0.270  1.0
  Cl  Cl28  1  0.335  0.497  0.891  1.0
  Cl  Cl29  1  0.503  0.665  0.609  1.0
  Cl  Cl30  1  0.665  0.503  0.109  1.0
  Cl  Cl31  1  0.497  0.335  0.391  1.0
  Cl  Cl32  1  0.925  0.461  0.796  1.0
  Cl  Cl33  1  0.539  0.075  0.704  1.0
  Cl  Cl34  1  0.075  0.539  0.204  1.0
  Cl  Cl35  1  0.461  0.925  0.296  1.0
  Cl  Cl36  1  0.317  0.016  0.900  1.0
  Cl  Cl37  1  0.984  0.683  0.600  1.0
  Cl  Cl38  1  0.683  0.984  0.100  1.0
  Cl  Cl39  1  0.016  0.317  0.400  1.0
  O  O40  1  0.134  0.349  0.037  1.0
  O  O41  1  0.651  0.866  0.463  1.0
  O  O42  1  0.866  0.651  0.963  1.0
  O  O43  1  0.349  0.134  0.537  1.0
  O  O44  1  0.859  0.257  0.959  1.0
  O  O45  1  0.743  0.141  0.541  1.0
  O  O46  1  0.141  0.743  0.041  1.0
  O  O47  1  0.257  0.859  0.459  1.0
  O  O48  1  0.801  0.004  0.876  1.0
  O  O49  1  0.996  0.199  0.624  1.0
  O  O50  1  0.199  0.996  0.124  1.0
  O  O51  1  0.004  0.801  0.376  1.0
  O  O52  1  0.083  0.917  0.750  1.0
  O  O53  1  0.917  0.083  0.250  1.0
[/CIF]
.
The compound described by (SnH5(OCl)3)2H2O is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four water molecules and four SnH5(OCl)3 clusters. In each SnH5(OCl)3 cluster, Sn(1) is bonded to one O(2), two equivalent O(1), one Cl(1), one Cl(2), and one Cl(3) atom to form edge-sharing SnCl3O3 octahedra. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. In the third H site, H(3) is bonded in a distorted linear geometry to one O(2) and one O(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Sn(1) and one H(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Sn(1), one H(2), and one H(3) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one H(3), one H(4), and one H(5) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the CIF file [CIF]
data_Sn2H12Cl6O7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.340
_cell_length_b   7.340
_cell_length_c   17.447
_cell_angle_alpha   85.814
_cell_angle_beta   85.814
_cell_angle_gamma   63.174
_symmetry_Int_Tables_number   1
_cell_volume   835.721
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.080  0.369  0.918  1.0
  Sn  Sn1  1  0.631  0.920  0.582  1.0
  Sn  Sn2  1  0.920  0.631  0.082  1.0
  Sn  Sn3  1  0.369  0.080  0.418  1.0
  H  H4  1  0.158  0.222  0.069  1.0
  H  H5  1  0.778  0.842  0.431  1.0
  H  H6  1  0.842  0.778  0.931  1.0
  H  H7  1  0.222  0.158  0.569  1.0
  H  H8  1  0.765  0.316  0.004  1.0
  H  H9  1  0.684  0.235  0.496  1.0
  H  H10  1  0.235  0.684  0.996  1.0
  H  H11  1  0.316  0.765  0.504  1.0
  H  H12  1  0.818  0.170  0.928  1.0
  H  H13  1  0.830  0.182  0.572  1.0
  H  H14  1  0.182  0.830  0.072  1.0
  H  H15  1  0.170  0.818  0.428  1.0
  H  H16  1  0.897  0.973  0.831  1.0
  H  H17  1  0.027  0.103  0.669  1.0
  H  H18  1  0.103  0.027  0.169  1.0
  H  H19  1  0.973  0.897  0.331  1.0
  H  H20  1  0.664  0.058  0.857  1.0
  H  H21  1  0.942  0.336  0.643  1.0
  H  H22  1  0.336  0.942  0.143  1.0
  H  H23  1  0.058  0.664  0.357  1.0
  H  H24  1  0.213  0.894  0.770  1.0
  H  H25  1  0.106  0.787  0.730  1.0
  H  H26  1  0.787  0.106  0.230  1.0
  H  H27  1  0.894  0.213  0.270  1.0
  Cl  Cl28  1  0.335  0.497  0.891  1.0
  Cl  Cl29  1  0.503  0.665  0.609  1.0
  Cl  Cl30  1  0.665  0.503  0.109  1.0
  Cl  Cl31  1  0.497  0.335  0.391  1.0
  Cl  Cl32  1  0.925  0.461  0.796  1.0
  Cl  Cl33  1  0.539  0.075  0.704  1.0
  Cl  Cl34  1  0.075  0.539  0.204  1.0
  Cl  Cl35  1  0.461  0.925  0.296  1.0
  Cl  Cl36  1  0.317  0.016  0.900  1.0
  Cl  Cl37  1  0.984  0.683  0.600  1.0
  Cl  Cl38  1  0.683  0.984  0.100  1.0
  Cl  Cl39  1  0.016  0.317  0.400  1.0
  O  O40  1  0.134  0.349  0.037  1.0
  O  O41  1  0.651  0.866  0.463  1.0
  O  O42  1  0.866  0.651  0.963  1.0
  O  O43  1  0.349  0.134  0.537  1.0
  O  O44  1  0.859  0.257  0.959  1.0
  O  O45  1  0.743  0.141  0.541  1.0
  O  O46  1  0.141  0.743  0.041  1.0
  O  O47  1  0.257  0.859  0.459  1.0
  O  O48  1  0.801  0.004  0.876  1.0
  O  O49  1  0.996  0.199  0.624  1.0
  O  O50  1  0.199  0.996  0.124  1.0
  O  O51  1  0.004  0.801  0.376  1.0
  O  O52  1  0.083  0.917  0.750  1.0
  O  O53  1  0.917  0.083  0.250  1.0
[/CIF]
.