The structure described by MgRhSbO4 is Corundum-derived structured and crystallizes in the monoclinic P2 space group. Mg(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form MgO6 octahedra that share edges with two equivalent Mg(1)O6 octahedra and edges with four equivalent Rh(1)O6 octahedra. Rh(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form RhO6 octahedra that share edges with two equivalent Rh(1)O6 octahedra and edges with four equivalent Mg(1)O6 octahedra. Sb(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Mg(1), two equivalent Rh(1), and one Sb(1) atom to form a mixture of edge and corner-sharing OMgSbRh2 trigonal pyramids. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to two equivalent Mg(1), one Rh(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_MgSbRhO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.146
_cell_length_b   5.091
_cell_length_c   5.679
_cell_angle_alpha   97.823
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   90.106
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.103  0.000  0.500  1.0
  Sb  Sb1  1  0.823  0.000  0.000  1.0
  Rh  Rh2  1  0.565  0.500  0.500  1.0
  O  O3  1  0.050  0.307  0.307  1.0
  O  O4  1  0.590  0.812  0.293  1.0
  O  O5  1  0.590  0.188  0.707  1.0
  O  O6  1  0.050  0.693  0.693  1.0
[/CIF]
.
The structure described by MgRhSbO4 is Corundum-derived structured and crystallizes in the monoclinic P2 space group. Mg(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form MgO6 octahedra that share edges with two equivalent Mg(1)O6 octahedra and edges with four equivalent Rh(1)O6 octahedra. Rh(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form RhO6 octahedra that share edges with two equivalent Rh(1)O6 octahedra and edges with four equivalent Mg(1)O6 octahedra. Sb(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded to one Mg(1), two equivalent Rh(1), and one Sb(1) atom to form a mixture of edge and corner-sharing OMgSbRh2 trigonal pyramids. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to two equivalent Mg(1), one Rh(1), and one Sb(1) atom. is represented by the CIF file [CIF]
data_MgSbRhO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.146
_cell_length_b   5.091
_cell_length_c   5.679
_cell_angle_alpha   97.823
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   90.106
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.103  0.000  0.500  1.0
  Sb  Sb1  1  0.823  0.000  0.000  1.0
  Rh  Rh2  1  0.565  0.500  0.500  1.0
  O  O3  1  0.050  0.307  0.307  1.0
  O  O4  1  0.590  0.812  0.293  1.0
  O  O5  1  0.590  0.188  0.707  1.0
  O  O6  1  0.050  0.693  0.693  1.0
[/CIF]
.