The compound described by Cs3Re6(S4Cl3)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 7-coordinate geometry to one S(1), one S(2), one Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. In the second Cs site, Cs(2) is bonded in a 10-coordinate geometry to two equivalent S(1), two equivalent S(2), two equivalent S(3), two equivalent Cl(1), and two equivalent Cl(3) atoms. There are three inequivalent Re sites. In the first Re site, Re(1) is bonded to one S(1), one S(2), one S(3), one S(4), and one Cl(1) atom to form distorted edge-sharing ReS4Cl square pyramids. In the second Re site, Re(2) is bonded to one S(1), one S(2), one S(3), one S(4), and one Cl(2) atom to form distorted edge-sharing ReS4Cl square pyramids. In the third Re site, Re(3) is bonded to one S(1), one S(2), one S(3), one S(4), and one Cl(3) atom to form distorted edge-sharing ReS4Cl square pyramids. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 5-coordinate geometry to one Cs(1), one Cs(2), one Re(1), one Re(2), and one Re(3) atom. In the second S site, S(2) is bonded in a 5-coordinate geometry to one Cs(1), one Cs(2), one Re(1), one Re(2), and one Re(3) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to one Cs(2), one Re(1), one Re(2), and one Re(3) atom. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted T-shaped geometry to one Cs(1), one Cs(2), and one Re(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Re(2) atom. In the third Cl site, Cl(3) is bonded to one Cs(2), two equivalent Cs(1), and one Re(3) atom to form distorted corner-sharing ClCs3Re tetrahedra. is represented by the CIF file [CIF]
data_Cs3Re6(S4Cl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.065
_cell_length_b   9.346
_cell_length_c   11.254
_cell_angle_alpha   72.968
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1314.005
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.259  0.477  0.635  1.0
  Cs  Cs1  1  0.741  0.523  0.365  1.0
  Cs  Cs2  1  0.759  0.523  0.865  1.0
  Cs  Cs3  1  0.241  0.477  0.135  1.0
  Cs  Cs4  1  0.500  0.000  0.500  1.0
  Cs  Cs5  1  0.000  0.000  0.000  1.0
  Re  Re6  1  0.456  0.883  0.900  1.0
  Re  Re7  1  0.544  0.117  0.100  1.0
  Re  Re8  1  0.956  0.117  0.600  1.0
  Re  Re9  1  0.044  0.883  0.400  1.0
  Re  Re10  1  0.053  0.863  0.637  1.0
  Re  Re11  1  0.947  0.137  0.363  1.0
  Re  Re12  1  0.553  0.137  0.863  1.0
  Re  Re13  1  0.447  0.863  0.137  1.0
  Re  Re14  1  0.875  0.897  0.526  1.0
  Re  Re15  1  0.125  0.103  0.474  1.0
  Re  Re16  1  0.375  0.103  0.974  1.0
  Re  Re17  1  0.625  0.897  0.026  1.0
  S  S18  1  0.892  0.887  0.741  1.0
  S  S19  1  0.108  0.113  0.259  1.0
  S  S20  1  0.392  0.113  0.759  1.0
  S  S21  1  0.608  0.887  0.241  1.0
  S  S22  1  0.206  0.863  0.510  1.0
  S  S23  1  0.794  0.137  0.490  1.0
  S  S24  1  0.706  0.137  0.990  1.0
  S  S25  1  0.294  0.863  0.010  1.0
  S  S26  1  0.625  0.926  0.806  1.0
  S  S27  1  0.375  0.074  0.194  1.0
  S  S28  1  0.125  0.074  0.694  1.0
  S  S29  1  0.875  0.926  0.306  1.0
  S  S30  1  0.974  0.671  0.557  1.0
  S  S31  1  0.026  0.329  0.443  1.0
  S  S32  1  0.474  0.329  0.943  1.0
  S  S33  1  0.526  0.671  0.057  1.0
  Cl  Cl34  1  0.405  0.729  0.769  1.0
  Cl  Cl35  1  0.595  0.271  0.231  1.0
  Cl  Cl36  1  0.905  0.271  0.731  1.0
  Cl  Cl37  1  0.095  0.729  0.269  1.0
  Cl  Cl38  1  0.114  0.674  0.823  1.0
  Cl  Cl39  1  0.886  0.326  0.177  1.0
  Cl  Cl40  1  0.614  0.326  0.677  1.0
  Cl  Cl41  1  0.386  0.674  0.323  1.0
  Cl  Cl42  1  0.713  0.755  0.562  1.0
  Cl  Cl43  1  0.287  0.245  0.438  1.0
  Cl  Cl44  1  0.213  0.245  0.938  1.0
  Cl  Cl45  1  0.787  0.755  0.062  1.0
[/CIF]
.
The compound described by Cs3Re6(S4Cl3)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 7-coordinate geometry to one S(1), one S(2), one Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. In the second Cs site, Cs(2) is bonded in a 10-coordinate geometry to two equivalent S(1), two equivalent S(2), two equivalent S(3), two equivalent Cl(1), and two equivalent Cl(3) atoms. There are three inequivalent Re sites. In the first Re site, Re(1) is bonded to one S(1), one S(2), one S(3), one S(4), and one Cl(1) atom to form distorted edge-sharing ReS4Cl square pyramids. In the second Re site, Re(2) is bonded to one S(1), one S(2), one S(3), one S(4), and one Cl(2) atom to form distorted edge-sharing ReS4Cl square pyramids. In the third Re site, Re(3) is bonded to one S(1), one S(2), one S(3), one S(4), and one Cl(3) atom to form distorted edge-sharing ReS4Cl square pyramids. There are four inequivalent S sites. In the first S site, S(1) is bonded in a 5-coordinate geometry to one Cs(1), one Cs(2), one Re(1), one Re(2), and one Re(3) atom. In the second S site, S(2) is bonded in a 5-coordinate geometry to one Cs(1), one Cs(2), one Re(1), one Re(2), and one Re(3) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to one Cs(2), one Re(1), one Re(2), and one Re(3) atom. In the fourth S site, S(4) is bonded in a 3-coordinate geometry to one Re(1), one Re(2), and one Re(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted T-shaped geometry to one Cs(1), one Cs(2), and one Re(1) atom. In the second Cl site, Cl(2) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Re(2) atom. In the third Cl site, Cl(3) is bonded to one Cs(2), two equivalent Cs(1), and one Re(3) atom to form distorted corner-sharing ClCs3Re tetrahedra. is represented by the CIF file [CIF]
data_Cs3Re6(S4Cl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.065
_cell_length_b   9.346
_cell_length_c   11.254
_cell_angle_alpha   72.968
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1314.005
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.259  0.477  0.635  1.0
  Cs  Cs1  1  0.741  0.523  0.365  1.0
  Cs  Cs2  1  0.759  0.523  0.865  1.0
  Cs  Cs3  1  0.241  0.477  0.135  1.0
  Cs  Cs4  1  0.500  0.000  0.500  1.0
  Cs  Cs5  1  0.000  0.000  0.000  1.0
  Re  Re6  1  0.456  0.883  0.900  1.0
  Re  Re7  1  0.544  0.117  0.100  1.0
  Re  Re8  1  0.956  0.117  0.600  1.0
  Re  Re9  1  0.044  0.883  0.400  1.0
  Re  Re10  1  0.053  0.863  0.637  1.0
  Re  Re11  1  0.947  0.137  0.363  1.0
  Re  Re12  1  0.553  0.137  0.863  1.0
  Re  Re13  1  0.447  0.863  0.137  1.0
  Re  Re14  1  0.875  0.897  0.526  1.0
  Re  Re15  1  0.125  0.103  0.474  1.0
  Re  Re16  1  0.375  0.103  0.974  1.0
  Re  Re17  1  0.625  0.897  0.026  1.0
  S  S18  1  0.892  0.887  0.741  1.0
  S  S19  1  0.108  0.113  0.259  1.0
  S  S20  1  0.392  0.113  0.759  1.0
  S  S21  1  0.608  0.887  0.241  1.0
  S  S22  1  0.206  0.863  0.510  1.0
  S  S23  1  0.794  0.137  0.490  1.0
  S  S24  1  0.706  0.137  0.990  1.0
  S  S25  1  0.294  0.863  0.010  1.0
  S  S26  1  0.625  0.926  0.806  1.0
  S  S27  1  0.375  0.074  0.194  1.0
  S  S28  1  0.125  0.074  0.694  1.0
  S  S29  1  0.875  0.926  0.306  1.0
  S  S30  1  0.974  0.671  0.557  1.0
  S  S31  1  0.026  0.329  0.443  1.0
  S  S32  1  0.474  0.329  0.943  1.0
  S  S33  1  0.526  0.671  0.057  1.0
  Cl  Cl34  1  0.405  0.729  0.769  1.0
  Cl  Cl35  1  0.595  0.271  0.231  1.0
  Cl  Cl36  1  0.905  0.271  0.731  1.0
  Cl  Cl37  1  0.095  0.729  0.269  1.0
  Cl  Cl38  1  0.114  0.674  0.823  1.0
  Cl  Cl39  1  0.886  0.326  0.177  1.0
  Cl  Cl40  1  0.614  0.326  0.677  1.0
  Cl  Cl41  1  0.386  0.674  0.323  1.0
  Cl  Cl42  1  0.713  0.755  0.562  1.0
  Cl  Cl43  1  0.287  0.245  0.438  1.0
  Cl  Cl44  1  0.213  0.245  0.938  1.0
  Cl  Cl45  1  0.787  0.755  0.062  1.0
[/CIF]
.