The compound described by DyP5 crystallizes in the monoclinic P2_1/m space group. Dy(1) is bonded in a 8-coordinate geometry to two equivalent P(1), two equivalent P(2), and four equivalent P(3) atoms. There are three inequivalent P sites. In the first P site, P(3) is bonded to two equivalent Dy(1), one P(2), and one P(3) atom to form PDy2P2 tetrahedra that share corners with four equivalent P(3)Dy2P2 tetrahedra, corners with five equivalent P(1)Dy2P2 tetrahedra, corners with six equivalent P(2)DyP3 tetrahedra, and  an edgeedge with one P(3)Dy2P2 tetrahedra. In the second P site, P(1) is bonded to two equivalent Dy(1) and two equivalent P(2) atoms to form distorted PDy2P2 tetrahedra that share corners with two equivalent P(1)Dy2P2 tetrahedra, corners with six equivalent P(2)DyP3 tetrahedra, and corners with ten equivalent P(3)Dy2P2 tetrahedra. In the third P site, P(2) is bonded to one Dy(1), one P(1), one P(2), and one P(3) atom to form distorted PDyP3 tetrahedra that share corners with three equivalent P(1)Dy2P2 tetrahedra, corners with six equivalent P(3)Dy2P2 tetrahedra, and  an edgeedge with one P(2)DyP3 tetrahedra. is represented by the CIF card [CIF]
data_DyP5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.958
_cell_length_b   5.350
_cell_length_c   9.389
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   102.287
_symmetry_Int_Tables_number   1
_cell_volume   243.334
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.003  0.347  0.250  1.0
  Dy  Dy1  1  0.997  0.653  0.750  1.0
  P  P2  1  0.281  0.894  0.250  1.0
  P  P3  1  0.719  0.106  0.750  1.0
  P  P4  1  0.615  0.954  0.408  1.0
  P  P5  1  0.385  0.046  0.908  1.0
  P  P6  1  0.385  0.046  0.592  1.0
  P  P7  1  0.615  0.954  0.092  1.0
  P  P8  1  0.712  0.597  0.471  1.0
  P  P9  1  0.288  0.403  0.971  1.0
  P  P10  1  0.288  0.403  0.529  1.0
  P  P11  1  0.712  0.597  0.029  1.0
[/CIF]
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The compound described by DyP5 crystallizes in the monoclinic P2_1/m space group. Dy(1) is bonded in a 8-coordinate geometry to two equivalent P(1), two equivalent P(2), and four equivalent P(3) atoms. There are three inequivalent P sites. In the first P site, P(3) is bonded to two equivalent Dy(1), one P(2), and one P(3) atom to form PDy2P2 tetrahedra that share corners with four equivalent P(3)Dy2P2 tetrahedra, corners with five equivalent P(1)Dy2P2 tetrahedra, corners with six equivalent P(2)DyP3 tetrahedra, and  an edgeedge with one P(3)Dy2P2 tetrahedra. In the second P site, P(1) is bonded to two equivalent Dy(1) and two equivalent P(2) atoms to form distorted PDy2P2 tetrahedra that share corners with two equivalent P(1)Dy2P2 tetrahedra, corners with six equivalent P(2)DyP3 tetrahedra, and corners with ten equivalent P(3)Dy2P2 tetrahedra. In the third P site, P(2) is bonded to one Dy(1), one P(1), one P(2), and one P(3) atom to form distorted PDyP3 tetrahedra that share corners with three equivalent P(1)Dy2P2 tetrahedra, corners with six equivalent P(3)Dy2P2 tetrahedra, and  an edgeedge with one P(2)DyP3 tetrahedra. is represented by the CIF card [CIF]
data_DyP5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.958
_cell_length_b   5.350
_cell_length_c   9.389
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   102.287
_symmetry_Int_Tables_number   1
_cell_volume   243.334
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.003  0.347  0.250  1.0
  Dy  Dy1  1  0.997  0.653  0.750  1.0
  P  P2  1  0.281  0.894  0.250  1.0
  P  P3  1  0.719  0.106  0.750  1.0
  P  P4  1  0.615  0.954  0.408  1.0
  P  P5  1  0.385  0.046  0.908  1.0
  P  P6  1  0.385  0.046  0.592  1.0
  P  P7  1  0.615  0.954  0.092  1.0
  P  P8  1  0.712  0.597  0.471  1.0
  P  P9  1  0.288  0.403  0.971  1.0
  P  P10  1  0.288  0.403  0.529  1.0
  P  P11  1  0.712  0.597  0.029  1.0
[/CIF]
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