The material structure described by (Sb5O13)2O2 crystallizes in the monoclinic P2_1/m space group. The structure consists of two water atoms inside a Sb5O13 framework. In the Sb5O13 framework, there are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(2), one O(3), one O(5), one O(6), and one O(7) atom to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 30-46°. In the second Sb site, Sb(2) is bonded to one O(3), one O(5), one O(6), one O(7), and two equivalent O(4) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 44-53°. In the third Sb site, Sb(3) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Sb(1) and one Sb(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one Sb(2) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Sb(3) and two equivalent Sb(2) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Sb(1), one Sb(2), and one Sb(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. is represented by the CIF file [CIF]
data_Sb5O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.890
_cell_length_b   5.611
_cell_length_c   5.626
_cell_angle_alpha   73.236
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   510.503
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.639  0.230  0.233  1.0
  Sb  Sb1  1  0.361  0.770  0.767  1.0
  Sb  Sb2  1  0.861  0.230  0.233  1.0
  Sb  Sb3  1  0.139  0.770  0.767  1.0
  Sb  Sb4  1  0.421  0.386  0.386  1.0
  Sb  Sb5  1  0.579  0.614  0.614  1.0
  Sb  Sb6  1  0.079  0.386  0.386  1.0
  Sb  Sb7  1  0.921  0.614  0.614  1.0
  Sb  Sb8  1  0.500  0.000  0.000  1.0
  Sb  Sb9  1  0.000  0.000  0.000  1.0
  O  O10  1  0.385  0.986  0.988  1.0
  O  O11  1  0.615  0.014  0.012  1.0
  O  O12  1  0.115  0.986  0.988  1.0
  O  O13  1  0.885  0.014  0.012  1.0
  O  O14  1  0.250  0.824  0.824  1.0
  O  O15  1  0.750  0.176  0.176  1.0
  O  O16  1  0.653  0.447  0.446  1.0
  O  O17  1  0.347  0.553  0.554  1.0
  O  O18  1  0.847  0.447  0.446  1.0
  O  O19  1  0.153  0.553  0.554  1.0
  O  O20  1  0.500  0.311  0.690  1.0
  O  O21  1  1.000  0.311  0.690  1.0
  O  O22  1  0.500  0.689  0.310  1.0
  O  O23  1  0.000  0.689  0.310  1.0
  O  O24  1  0.490  0.773  0.775  1.0
  O  O25  1  0.510  0.227  0.225  1.0
  O  O26  1  0.010  0.773  0.775  1.0
  O  O27  1  0.990  0.227  0.225  1.0
  O  O28  1  0.365  0.470  0.066  1.0
  O  O29  1  0.633  0.933  0.529  1.0
  O  O30  1  0.135  0.470  0.066  1.0
  O  O31  1  0.867  0.933  0.529  1.0
  O  O32  1  0.634  0.530  0.934  1.0
  O  O33  1  0.367  0.067  0.471  1.0
  O  O34  1  0.866  0.530  0.934  1.0
  O  O35  1  0.133  0.067  0.471  1.0
  O  O36  1  0.250  0.178  0.083  1.0
  O  O37  1  0.750  0.822  0.917  1.0
[/CIF]
.
The material structure described by (Sb5O13)2O2 crystallizes in the monoclinic P2_1/m space group. The structure consists of two water atoms inside a Sb5O13 framework. In the Sb5O13 framework, there are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(2), one O(3), one O(5), one O(6), and one O(7) atom to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 30-46°. In the second Sb site, Sb(2) is bonded to one O(3), one O(5), one O(6), one O(7), and two equivalent O(4) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 44-53°. In the third Sb site, Sb(3) is bonded to two equivalent O(1), two equivalent O(4), and two equivalent O(5) atoms to form a mixture of corner and edge-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 51-53°. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Sb(1) and one Sb(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one Sb(2) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Sb(3) and two equivalent Sb(2) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Sb(1), one Sb(2), and one Sb(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. is represented by the CIF file [CIF]
data_Sb5O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.890
_cell_length_b   5.611
_cell_length_c   5.626
_cell_angle_alpha   73.236
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   510.503
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.639  0.230  0.233  1.0
  Sb  Sb1  1  0.361  0.770  0.767  1.0
  Sb  Sb2  1  0.861  0.230  0.233  1.0
  Sb  Sb3  1  0.139  0.770  0.767  1.0
  Sb  Sb4  1  0.421  0.386  0.386  1.0
  Sb  Sb5  1  0.579  0.614  0.614  1.0
  Sb  Sb6  1  0.079  0.386  0.386  1.0
  Sb  Sb7  1  0.921  0.614  0.614  1.0
  Sb  Sb8  1  0.500  0.000  0.000  1.0
  Sb  Sb9  1  0.000  0.000  0.000  1.0
  O  O10  1  0.385  0.986  0.988  1.0
  O  O11  1  0.615  0.014  0.012  1.0
  O  O12  1  0.115  0.986  0.988  1.0
  O  O13  1  0.885  0.014  0.012  1.0
  O  O14  1  0.250  0.824  0.824  1.0
  O  O15  1  0.750  0.176  0.176  1.0
  O  O16  1  0.653  0.447  0.446  1.0
  O  O17  1  0.347  0.553  0.554  1.0
  O  O18  1  0.847  0.447  0.446  1.0
  O  O19  1  0.153  0.553  0.554  1.0
  O  O20  1  0.500  0.311  0.690  1.0
  O  O21  1  1.000  0.311  0.690  1.0
  O  O22  1  0.500  0.689  0.310  1.0
  O  O23  1  0.000  0.689  0.310  1.0
  O  O24  1  0.490  0.773  0.775  1.0
  O  O25  1  0.510  0.227  0.225  1.0
  O  O26  1  0.010  0.773  0.775  1.0
  O  O27  1  0.990  0.227  0.225  1.0
  O  O28  1  0.365  0.470  0.066  1.0
  O  O29  1  0.633  0.933  0.529  1.0
  O  O30  1  0.135  0.470  0.066  1.0
  O  O31  1  0.867  0.933  0.529  1.0
  O  O32  1  0.634  0.530  0.934  1.0
  O  O33  1  0.367  0.067  0.471  1.0
  O  O34  1  0.866  0.530  0.934  1.0
  O  O35  1  0.133  0.067  0.471  1.0
  O  O36  1  0.250  0.178  0.083  1.0
  O  O37  1  0.750  0.822  0.917  1.0
[/CIF]
.