The crystal structure described by SbF6(I)5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydriodic acid atoms, three I clusters, and three SbF6 clusters. In one of the I clusters, there are two inequivalent I sites. In the first I site, I(6) is bonded in a linear geometry to two equivalent I(7) atoms. In the second I site, I(7) is bonded in a 3-coordinate geometry to one I(6) atom. In two of the I clusters, there are five inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to one I(4) atom. In the second I site, I(2) is bonded in a distorted linear geometry to one I(3) and one I(8) atom. In the third I site, I(3) is bonded in a distorted L-shaped geometry to one I(2) and one I(4) atom. In the fourth I site, I(4) is bonded in a linear geometry to one I(1) and one I(3) atom. In the fifth I site, I(8) is bonded in a 2-coordinate geometry to one I(2) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(6), one F(7), one F(8), and one F(9) atom. There are six inequivalent F sites. In the first F site, F(9) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbI5F6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.240
_cell_length_b   8.456
_cell_length_c   15.511
_cell_angle_alpha   99.629
_cell_angle_beta   94.554
_cell_angle_gamma   110.412
_symmetry_Int_Tables_number   1
_cell_volume   987.402
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.480  0.144  0.347  1.0
  Sb  Sb1  1  0.520  0.856  0.653  1.0
  Sb  Sb2  1  0.000  0.000  0.000  1.0
  I  I3  1  0.040  0.331  0.260  1.0
  I  I4  1  0.658  0.419  0.091  1.0
  I  I5  1  0.451  0.823  0.066  1.0
  I  I6  1  0.549  0.177  0.934  1.0
  I  I7  1  0.244  0.584  0.163  1.0
  I  I8  1  0.756  0.416  0.837  1.0
  I  I9  1  0.342  0.581  0.909  1.0
  I  I10  1  0.960  0.669  0.740  1.0
  I  I11  1  0.169  0.541  0.419  1.0
  I  I12  1  0.831  0.459  0.581  1.0
  I  I13  1  0.000  0.000  0.500  1.0
  I  I14  1  0.302  0.273  0.610  1.0
  I  I15  1  0.698  0.727  0.390  1.0
  I  I16  1  0.162  0.252  0.762  1.0
  I  I17  1  0.838  0.748  0.238  1.0
  F  F18  1  0.749  0.958  0.716  1.0
  F  F19  1  0.287  0.750  0.588  1.0
  F  F20  1  0.713  0.250  0.412  1.0
  F  F21  1  0.027  0.165  0.927  1.0
  F  F22  1  0.973  0.835  0.073  1.0
  F  F23  1  0.093  0.874  0.917  1.0
  F  F24  1  0.907  0.126  0.083  1.0
  F  F25  1  0.228  0.129  0.062  1.0
  F  F26  1  0.772  0.871  0.938  1.0
  F  F27  1  0.404  0.263  0.442  1.0
  F  F28  1  0.251  0.042  0.284  1.0
  F  F29  1  0.570  0.034  0.256  1.0
  F  F30  1  0.430  0.966  0.744  1.0
  F  F31  1  0.438  0.956  0.404  1.0
  F  F32  1  0.562  0.044  0.596  1.0
  F  F33  1  0.522  0.336  0.293  1.0
  F  F34  1  0.478  0.664  0.707  1.0
  F  F35  1  0.596  0.737  0.558  1.0
[/CIF]
.
The crystal structure described by SbF6(I)5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydriodic acid atoms, three I clusters, and three SbF6 clusters. In one of the I clusters, there are two inequivalent I sites. In the first I site, I(6) is bonded in a linear geometry to two equivalent I(7) atoms. In the second I site, I(7) is bonded in a 3-coordinate geometry to one I(6) atom. In two of the I clusters, there are five inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to one I(4) atom. In the second I site, I(2) is bonded in a distorted linear geometry to one I(3) and one I(8) atom. In the third I site, I(3) is bonded in a distorted L-shaped geometry to one I(2) and one I(4) atom. In the fourth I site, I(4) is bonded in a linear geometry to one I(1) and one I(3) atom. In the fifth I site, I(8) is bonded in a 2-coordinate geometry to one I(2) atom. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(6), one F(7), one F(8), and one F(9) atom. There are six inequivalent F sites. In the first F site, F(9) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbI5F6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.240
_cell_length_b   8.456
_cell_length_c   15.511
_cell_angle_alpha   99.629
_cell_angle_beta   94.554
_cell_angle_gamma   110.412
_symmetry_Int_Tables_number   1
_cell_volume   987.402
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.480  0.144  0.347  1.0
  Sb  Sb1  1  0.520  0.856  0.653  1.0
  Sb  Sb2  1  0.000  0.000  0.000  1.0
  I  I3  1  0.040  0.331  0.260  1.0
  I  I4  1  0.658  0.419  0.091  1.0
  I  I5  1  0.451  0.823  0.066  1.0
  I  I6  1  0.549  0.177  0.934  1.0
  I  I7  1  0.244  0.584  0.163  1.0
  I  I8  1  0.756  0.416  0.837  1.0
  I  I9  1  0.342  0.581  0.909  1.0
  I  I10  1  0.960  0.669  0.740  1.0
  I  I11  1  0.169  0.541  0.419  1.0
  I  I12  1  0.831  0.459  0.581  1.0
  I  I13  1  0.000  0.000  0.500  1.0
  I  I14  1  0.302  0.273  0.610  1.0
  I  I15  1  0.698  0.727  0.390  1.0
  I  I16  1  0.162  0.252  0.762  1.0
  I  I17  1  0.838  0.748  0.238  1.0
  F  F18  1  0.749  0.958  0.716  1.0
  F  F19  1  0.287  0.750  0.588  1.0
  F  F20  1  0.713  0.250  0.412  1.0
  F  F21  1  0.027  0.165  0.927  1.0
  F  F22  1  0.973  0.835  0.073  1.0
  F  F23  1  0.093  0.874  0.917  1.0
  F  F24  1  0.907  0.126  0.083  1.0
  F  F25  1  0.228  0.129  0.062  1.0
  F  F26  1  0.772  0.871  0.938  1.0
  F  F27  1  0.404  0.263  0.442  1.0
  F  F28  1  0.251  0.042  0.284  1.0
  F  F29  1  0.570  0.034  0.256  1.0
  F  F30  1  0.430  0.966  0.744  1.0
  F  F31  1  0.438  0.956  0.404  1.0
  F  F32  1  0.562  0.044  0.596  1.0
  F  F33  1  0.522  0.336  0.293  1.0
  F  F34  1  0.478  0.664  0.707  1.0
  F  F35  1  0.596  0.737  0.558  1.0
[/CIF]
.