The material structure described by Zr2PdAgF11 crystallizes in the monoclinic C2/m space group. Zr(1) is bonded to one F(2), one F(4), one F(5), two equivalent F(1), and two equivalent F(3) atoms to form ZrF7 pentagonal bipyramids that share corners with three equivalent Pd(1)F6 octahedra,  a cornercorner with one Zr(1)F7 pentagonal bipyramid, and  an edgeedge with one Zr(1)F7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 7-32°. Pd(1) is bonded to two equivalent F(4) and four equivalent F(1) atoms to form PdF6 octahedra that share corners with six equivalent Zr(1)F7 pentagonal bipyramids. Ag(1) is bonded in a square co-planar geometry to two equivalent F(3) and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Zr(1) and one Pd(1) atom. In the second F site, F(2) is bonded in a linear geometry to two equivalent Zr(1) atoms. In the third F site, F(3) is bonded in a trigonal planar geometry to two equivalent Zr(1) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zr(1) and one Pd(1) atom. In the fifth F site, F(5) is bonded in a linear geometry to one Zr(1) and one Ag(1) atom. is represented by the CIF card [CIF]
data_Zr2AgPdF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.957
_cell_length_b   5.957
_cell_length_c   7.965
_cell_angle_alpha   69.556
_cell_angle_beta   69.556
_cell_angle_gamma   73.165
_symmetry_Int_Tables_number   1
_cell_volume   243.640
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.507  0.507  0.763  1.0
  Zr  Zr1  1  0.493  0.493  0.237  1.0
  Ag  Ag2  1  0.000  0.000  0.000  1.0
  Pd  Pd3  1  0.000  0.000  0.500  1.0
  F  F4  1  0.198  0.768  0.308  1.0
  F  F5  1  0.232  0.802  0.692  1.0
  F  F6  1  0.802  0.232  0.692  1.0
  F  F7  1  0.768  0.198  0.308  1.0
  F  F8  1  0.500  0.500  0.500  1.0
  F  F9  1  0.663  0.337  0.000  1.0
  F  F10  1  0.337  0.663  0.000  1.0
  F  F11  1  0.745  0.745  0.652  1.0
  F  F12  1  0.255  0.255  0.348  1.0
  F  F13  1  0.723  0.723  0.113  1.0
  F  F14  1  0.277  0.277  0.887  1.0
[/CIF]
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The material structure described by Zr2PdAgF11 crystallizes in the monoclinic C2/m space group. Zr(1) is bonded to one F(2), one F(4), one F(5), two equivalent F(1), and two equivalent F(3) atoms to form ZrF7 pentagonal bipyramids that share corners with three equivalent Pd(1)F6 octahedra,  a cornercorner with one Zr(1)F7 pentagonal bipyramid, and  an edgeedge with one Zr(1)F7 pentagonal bipyramid. The corner-sharing octahedral tilt angles range from 7-32°. Pd(1) is bonded to two equivalent F(4) and four equivalent F(1) atoms to form PdF6 octahedra that share corners with six equivalent Zr(1)F7 pentagonal bipyramids. Ag(1) is bonded in a square co-planar geometry to two equivalent F(3) and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to one Zr(1) and one Pd(1) atom. In the second F site, F(2) is bonded in a linear geometry to two equivalent Zr(1) atoms. In the third F site, F(3) is bonded in a trigonal planar geometry to two equivalent Zr(1) and one Ag(1) atom. In the fourth F site, F(4) is bonded in a linear geometry to one Zr(1) and one Pd(1) atom. In the fifth F site, F(5) is bonded in a linear geometry to one Zr(1) and one Ag(1) atom. is represented by the CIF card [CIF]
data_Zr2AgPdF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.957
_cell_length_b   5.957
_cell_length_c   7.965
_cell_angle_alpha   69.556
_cell_angle_beta   69.556
_cell_angle_gamma   73.165
_symmetry_Int_Tables_number   1
_cell_volume   243.640
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.507  0.507  0.763  1.0
  Zr  Zr1  1  0.493  0.493  0.237  1.0
  Ag  Ag2  1  0.000  0.000  0.000  1.0
  Pd  Pd3  1  0.000  0.000  0.500  1.0
  F  F4  1  0.198  0.768  0.308  1.0
  F  F5  1  0.232  0.802  0.692  1.0
  F  F6  1  0.802  0.232  0.692  1.0
  F  F7  1  0.768  0.198  0.308  1.0
  F  F8  1  0.500  0.500  0.500  1.0
  F  F9  1  0.663  0.337  0.000  1.0
  F  F10  1  0.337  0.663  0.000  1.0
  F  F11  1  0.745  0.745  0.652  1.0
  F  F12  1  0.255  0.255  0.348  1.0
  F  F13  1  0.723  0.723  0.113  1.0
  F  F14  1  0.277  0.277  0.887  1.0
[/CIF]
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