The structure described by Y2Pd14B5 crystallizes in the tetragonal I4_1/amd space group. Y(1) is bonded in a 18-coordinate geometry to two equivalent Pd(3), four equivalent Pd(1), four equivalent Pd(2), four equivalent Pd(4), and four equivalent B(2) atoms. There are four inequivalent Pd sites. In the first Pd site, Pd(3) is bonded in a distorted linear geometry to two equivalent Y(1) and two equivalent B(2) atoms. In the second Pd site, Pd(4) is bonded in a 2-coordinate geometry to two equivalent Y(1) and two equivalent B(2) atoms. In the third Pd site, Pd(1) is bonded in a 3-coordinate geometry to two equivalent Y(1) and two equivalent B(2) atoms. In the fourth Pd site, Pd(2) is bonded in a 3-coordinate geometry to two equivalent Y(1), one B(1), and two equivalent B(2) atoms. There are two inequivalent B sites. In the first B site, B(1) is bonded in a square co-planar geometry to four equivalent Pd(2) atoms. In the second B site, B(2) is bonded in a 7-coordinate geometry to two equivalent Y(1), one Pd(3), two equivalent Pd(1), two equivalent Pd(2), and two equivalent Pd(4) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Y2B5Pd14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.419
_cell_length_b   10.419
_cell_length_c   10.419
_cell_angle_alpha   133.036
_cell_angle_beta   133.036
_cell_angle_gamma   68.598
_symmetry_Int_Tables_number   1
_cell_volume   593.410
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.784  0.784  0.000  1.0
  Y  Y1  1  0.534  0.034  0.500  1.0
  Y  Y2  1  0.966  0.466  0.500  1.0
  Y  Y3  1  0.216  0.216  0.000  1.0
  B  B4  1  0.250  0.750  0.500  1.0
  B  B5  1  0.500  0.500  0.000  1.0
  B  B6  1  0.375  0.336  0.461  1.0
  B  B7  1  0.086  0.125  0.461  1.0
  B  B8  1  0.664  0.625  0.539  1.0
  B  B9  1  0.875  0.914  0.539  1.0
  B  B10  1  0.375  0.914  0.039  1.0
  B  B11  1  0.664  0.125  0.039  1.0
  B  B12  1  0.086  0.625  0.961  1.0
  B  B13  1  0.875  0.336  0.961  1.0
  Pd  Pd14  1  0.808  0.476  0.669  1.0
  Pd  Pd15  1  0.861  0.192  0.669  1.0
  Pd  Pd16  1  0.313  0.313  0.626  1.0
  Pd  Pd17  1  0.063  0.937  0.500  1.0
  Pd  Pd18  1  0.437  0.563  0.500  1.0
  Pd  Pd19  1  0.687  0.687  0.374  1.0
  Pd  Pd20  1  0.437  0.937  0.874  1.0
  Pd  Pd21  1  0.687  0.313  0.000  1.0
  Pd  Pd22  1  0.313  0.687  0.000  1.0
  Pd  Pd23  1  0.063  0.563  0.126  1.0
  Pd  Pd24  1  0.375  0.625  0.750  1.0
  Pd  Pd25  1  0.375  0.125  0.750  1.0
  Pd  Pd26  1  0.375  0.625  0.250  1.0
  Pd  Pd27  1  0.875  0.625  0.250  1.0
  Pd  Pd28  1  0.808  0.139  0.331  1.0
  Pd  Pd29  1  0.889  0.058  0.831  1.0
  Pd  Pd30  1  0.226  0.058  0.169  1.0
  Pd  Pd31  1  0.942  0.774  0.831  1.0
  Pd  Pd32  1  0.942  0.111  0.169  1.0
  Pd  Pd33  1  0.524  0.192  0.331  1.0
  Pd  Pd34  1  0.570  0.356  0.214  1.0
  Pd  Pd35  1  0.644  0.858  0.214  1.0
  Pd  Pd36  1  0.644  0.430  0.786  1.0
  Pd  Pd37  1  0.180  0.894  0.286  1.0
  Pd  Pd38  1  0.608  0.894  0.714  1.0
  Pd  Pd39  1  0.106  0.392  0.286  1.0
  Pd  Pd40  1  0.106  0.820  0.714  1.0
  Pd  Pd41  1  0.142  0.356  0.786  1.0
[/CIF]
.
The structure described by Y2Pd14B5 crystallizes in the tetragonal I4_1/amd space group. Y(1) is bonded in a 18-coordinate geometry to two equivalent Pd(3), four equivalent Pd(1), four equivalent Pd(2), four equivalent Pd(4), and four equivalent B(2) atoms. There are four inequivalent Pd sites. In the first Pd site, Pd(3) is bonded in a distorted linear geometry to two equivalent Y(1) and two equivalent B(2) atoms. In the second Pd site, Pd(4) is bonded in a 2-coordinate geometry to two equivalent Y(1) and two equivalent B(2) atoms. In the third Pd site, Pd(1) is bonded in a 3-coordinate geometry to two equivalent Y(1) and two equivalent B(2) atoms. In the fourth Pd site, Pd(2) is bonded in a 3-coordinate geometry to two equivalent Y(1), one B(1), and two equivalent B(2) atoms. There are two inequivalent B sites. In the first B site, B(1) is bonded in a square co-planar geometry to four equivalent Pd(2) atoms. In the second B site, B(2) is bonded in a 7-coordinate geometry to two equivalent Y(1), one Pd(3), two equivalent Pd(1), two equivalent Pd(2), and two equivalent Pd(4) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Y2B5Pd14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.419
_cell_length_b   10.419
_cell_length_c   10.419
_cell_angle_alpha   133.036
_cell_angle_beta   133.036
_cell_angle_gamma   68.598
_symmetry_Int_Tables_number   1
_cell_volume   593.410
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.784  0.784  0.000  1.0
  Y  Y1  1  0.534  0.034  0.500  1.0
  Y  Y2  1  0.966  0.466  0.500  1.0
  Y  Y3  1  0.216  0.216  0.000  1.0
  B  B4  1  0.250  0.750  0.500  1.0
  B  B5  1  0.500  0.500  0.000  1.0
  B  B6  1  0.375  0.336  0.461  1.0
  B  B7  1  0.086  0.125  0.461  1.0
  B  B8  1  0.664  0.625  0.539  1.0
  B  B9  1  0.875  0.914  0.539  1.0
  B  B10  1  0.375  0.914  0.039  1.0
  B  B11  1  0.664  0.125  0.039  1.0
  B  B12  1  0.086  0.625  0.961  1.0
  B  B13  1  0.875  0.336  0.961  1.0
  Pd  Pd14  1  0.808  0.476  0.669  1.0
  Pd  Pd15  1  0.861  0.192  0.669  1.0
  Pd  Pd16  1  0.313  0.313  0.626  1.0
  Pd  Pd17  1  0.063  0.937  0.500  1.0
  Pd  Pd18  1  0.437  0.563  0.500  1.0
  Pd  Pd19  1  0.687  0.687  0.374  1.0
  Pd  Pd20  1  0.437  0.937  0.874  1.0
  Pd  Pd21  1  0.687  0.313  0.000  1.0
  Pd  Pd22  1  0.313  0.687  0.000  1.0
  Pd  Pd23  1  0.063  0.563  0.126  1.0
  Pd  Pd24  1  0.375  0.625  0.750  1.0
  Pd  Pd25  1  0.375  0.125  0.750  1.0
  Pd  Pd26  1  0.375  0.625  0.250  1.0
  Pd  Pd27  1  0.875  0.625  0.250  1.0
  Pd  Pd28  1  0.808  0.139  0.331  1.0
  Pd  Pd29  1  0.889  0.058  0.831  1.0
  Pd  Pd30  1  0.226  0.058  0.169  1.0
  Pd  Pd31  1  0.942  0.774  0.831  1.0
  Pd  Pd32  1  0.942  0.111  0.169  1.0
  Pd  Pd33  1  0.524  0.192  0.331  1.0
  Pd  Pd34  1  0.570  0.356  0.214  1.0
  Pd  Pd35  1  0.644  0.858  0.214  1.0
  Pd  Pd36  1  0.644  0.430  0.786  1.0
  Pd  Pd37  1  0.180  0.894  0.286  1.0
  Pd  Pd38  1  0.608  0.894  0.714  1.0
  Pd  Pd39  1  0.106  0.392  0.286  1.0
  Pd  Pd40  1  0.106  0.820  0.714  1.0
  Pd  Pd41  1  0.142  0.356  0.786  1.0
[/CIF]
.