The structure described by YbVO2 is Caswellsilverite-like structured and crystallizes in the cubic Fd-3m space group. Yb(1) is bonded to six equivalent O(1) atoms to form YbO6 octahedra that share corners with six equivalent V(1)O6 octahedra, edges with six equivalent Yb(1)O6 octahedra, and edges with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 4°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Yb(1)O6 octahedra, edges with six equivalent Yb(1)O6 octahedra, and edges with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 4°. O(1) is bonded to three equivalent Yb(1) and three equivalent V(1) atoms to form a mixture of edge and corner-sharing OYb3V3 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_YbVO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.325
_cell_length_b   6.325
_cell_length_c   6.325
_cell_angle_alpha   120.000
_cell_angle_beta   120.000
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   178.884
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.625  0.875  0.250  1.0
  Yb  Yb1  1  0.625  0.375  0.250  1.0
  Yb  Yb2  1  0.625  0.375  0.750  1.0
  Yb  Yb3  1  0.125  0.375  0.750  1.0
  V  V4  1  0.125  0.375  0.250  1.0
  V  V5  1  0.125  0.875  0.250  1.0
  V  V6  1  0.125  0.875  0.750  1.0
  V  V7  1  0.625  0.875  0.750  1.0
  O  O8  1  0.356  0.119  0.237  1.0
  O  O9  1  0.881  0.119  0.237  1.0
  O  O10  1  0.369  0.106  0.737  1.0
  O  O11  1  0.894  0.631  0.263  1.0
  O  O12  1  0.369  0.631  0.737  1.0
  O  O13  1  0.369  0.631  0.263  1.0
  O  O14  1  0.881  0.644  0.763  1.0
  O  O15  1  0.881  0.119  0.763  1.0
[/CIF]
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The structure described by YbVO2 is Caswellsilverite-like structured and crystallizes in the cubic Fd-3m space group. Yb(1) is bonded to six equivalent O(1) atoms to form YbO6 octahedra that share corners with six equivalent V(1)O6 octahedra, edges with six equivalent Yb(1)O6 octahedra, and edges with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 4°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Yb(1)O6 octahedra, edges with six equivalent Yb(1)O6 octahedra, and edges with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 4°. O(1) is bonded to three equivalent Yb(1) and three equivalent V(1) atoms to form a mixture of edge and corner-sharing OYb3V3 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_YbVO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.325
_cell_length_b   6.325
_cell_length_c   6.325
_cell_angle_alpha   120.000
_cell_angle_beta   120.000
_cell_angle_gamma   90.001
_symmetry_Int_Tables_number   1
_cell_volume   178.884
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.625  0.875  0.250  1.0
  Yb  Yb1  1  0.625  0.375  0.250  1.0
  Yb  Yb2  1  0.625  0.375  0.750  1.0
  Yb  Yb3  1  0.125  0.375  0.750  1.0
  V  V4  1  0.125  0.375  0.250  1.0
  V  V5  1  0.125  0.875  0.250  1.0
  V  V6  1  0.125  0.875  0.750  1.0
  V  V7  1  0.625  0.875  0.750  1.0
  O  O8  1  0.356  0.119  0.237  1.0
  O  O9  1  0.881  0.119  0.237  1.0
  O  O10  1  0.369  0.106  0.737  1.0
  O  O11  1  0.894  0.631  0.263  1.0
  O  O12  1  0.369  0.631  0.737  1.0
  O  O13  1  0.369  0.631  0.263  1.0
  O  O14  1  0.881  0.644  0.763  1.0
  O  O15  1  0.881  0.119  0.763  1.0
[/CIF]
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