The material structure described by MnH8(N2Cl)2 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two MnH8(N2Cl)2 clusters. Mn(1) is bonded in an octahedral geometry to four equivalent N(1) and two equivalent Cl(1) atoms. N(1) is bonded in a distorted water-like geometry to one Mn(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. Cl(1) is bonded in a single-bond geometry to one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnH8(N2Cl)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.083
_cell_length_b   6.083
_cell_length_c   4.341
_cell_angle_alpha   79.317
_cell_angle_beta   79.317
_cell_angle_gamma   83.164
_symmetry_Int_Tables_number   1
_cell_volume   154.487
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  H  H1  1  0.982  0.329  0.472  1.0
  H  H2  1  0.329  0.982  0.472  1.0
  H  H3  1  0.018  0.671  0.528  1.0
  H  H4  1  0.671  0.018  0.528  1.0
  H  H5  1  0.736  0.364  0.708  1.0
  H  H6  1  0.364  0.736  0.708  1.0
  H  H7  1  0.264  0.636  0.292  1.0
  H  H8  1  0.636  0.264  0.292  1.0
  N  N9  1  0.851  0.247  0.608  1.0
  N  N10  1  0.247  0.851  0.608  1.0
  N  N11  1  0.149  0.753  0.392  1.0
  N  N12  1  0.753  0.149  0.392  1.0
  Cl  Cl13  1  0.282  0.282  0.001  1.0
  Cl  Cl14  1  0.718  0.718  0.999  1.0
[/CIF]
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The material structure described by MnH8(N2Cl)2 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two MnH8(N2Cl)2 clusters. Mn(1) is bonded in an octahedral geometry to four equivalent N(1) and two equivalent Cl(1) atoms. N(1) is bonded in a distorted water-like geometry to one Mn(1), one H(1), and one H(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. Cl(1) is bonded in a single-bond geometry to one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnH8(N2Cl)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.083
_cell_length_b   6.083
_cell_length_c   4.341
_cell_angle_alpha   79.317
_cell_angle_beta   79.317
_cell_angle_gamma   83.164
_symmetry_Int_Tables_number   1
_cell_volume   154.487
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  H  H1  1  0.982  0.329  0.472  1.0
  H  H2  1  0.329  0.982  0.472  1.0
  H  H3  1  0.018  0.671  0.528  1.0
  H  H4  1  0.671  0.018  0.528  1.0
  H  H5  1  0.736  0.364  0.708  1.0
  H  H6  1  0.364  0.736  0.708  1.0
  H  H7  1  0.264  0.636  0.292  1.0
  H  H8  1  0.636  0.264  0.292  1.0
  N  N9  1  0.851  0.247  0.608  1.0
  N  N10  1  0.247  0.851  0.608  1.0
  N  N11  1  0.149  0.753  0.392  1.0
  N  N12  1  0.753  0.149  0.392  1.0
  Cl  Cl13  1  0.282  0.282  0.001  1.0
  Cl  Cl14  1  0.718  0.718  0.999  1.0
[/CIF]
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