The structure described by NH3SbF6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight ammonia molecules and eight SbF6 clusters. In four of the SbF6 clusters, Sb(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In four of the SbF6 clusters, Sb(2) is bonded in an octahedral geometry to two equivalent F(4), two equivalent F(5), and two equivalent F(6) atoms. There are three inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Sb(2) atom. In the third F site, F(6) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF file [CIF]
data_SbH3NF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.265
_cell_length_b   7.265
_cell_length_c   10.907
_cell_angle_alpha   88.497
_cell_angle_beta   88.497
_cell_angle_gamma   117.408
_symmetry_Int_Tables_number   1
_cell_volume   510.445
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.500  0.500  0.500  1.0
  Sb  Sb1  1  0.500  0.500  0.000  1.0
  Sb  Sb2  1  0.153  0.847  0.750  1.0
  Sb  Sb3  1  0.847  0.153  0.250  1.0
  H  H4  1  0.251  0.004  0.334  1.0
  H  H5  1  0.996  0.749  0.166  1.0
  H  H6  1  0.749  0.996  0.666  1.0
  H  H7  1  0.004  0.251  0.834  1.0
  H  H8  1  0.028  0.777  0.361  1.0
  H  H9  1  0.223  0.972  0.139  1.0
  H  H10  1  0.972  0.223  0.639  1.0
  H  H11  1  0.777  0.028  0.861  1.0
  H  H12  1  0.263  0.774  0.348  1.0
  H  H13  1  0.226  0.737  0.152  1.0
  H  H14  1  0.737  0.226  0.652  1.0
  H  H15  1  0.774  0.263  0.848  1.0
  N  N16  1  0.176  0.847  0.316  1.0
  N  N17  1  0.153  0.824  0.184  1.0
  N  N18  1  0.824  0.153  0.684  1.0
  N  N19  1  0.847  0.176  0.816  1.0
  F  F20  1  0.473  0.297  0.385  1.0
  F  F21  1  0.703  0.527  0.115  1.0
  F  F22  1  0.527  0.703  0.615  1.0
  F  F23  1  0.297  0.473  0.885  1.0
  F  F24  1  0.216  0.330  0.557  1.0
  F  F25  1  0.670  0.784  0.943  1.0
  F  F26  1  0.784  0.670  0.443  1.0
  F  F27  1  0.330  0.216  0.057  1.0
  F  F28  1  0.403  0.638  0.384  1.0
  F  F29  1  0.362  0.597  0.116  1.0
  F  F30  1  0.597  0.362  0.616  1.0
  F  F31  1  0.638  0.403  0.884  1.0
  F  F32  1  0.877  0.798  0.717  1.0
  F  F33  1  0.202  0.123  0.783  1.0
  F  F34  1  0.123  0.202  0.283  1.0
  F  F35  1  0.798  0.877  0.217  1.0
  F  F36  1  0.074  0.562  0.718  1.0
  F  F37  1  0.438  0.926  0.782  1.0
  F  F38  1  0.926  0.438  0.282  1.0
  F  F39  1  0.562  0.074  0.218  1.0
  F  F40  1  0.230  0.914  0.579  1.0
  F  F41  1  0.086  0.770  0.921  1.0
  F  F42  1  0.770  0.086  0.421  1.0
  F  F43  1  0.914  0.230  0.079  1.0
[/CIF]
.
The structure described by NH3SbF6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight ammonia molecules and eight SbF6 clusters. In four of the SbF6 clusters, Sb(1) is bonded in an octahedral geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In four of the SbF6 clusters, Sb(2) is bonded in an octahedral geometry to two equivalent F(4), two equivalent F(5), and two equivalent F(6) atoms. There are three inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Sb(2) atom. In the third F site, F(6) is bonded in a single-bond geometry to one Sb(2) atom. is represented by the CIF file [CIF]
data_SbH3NF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.265
_cell_length_b   7.265
_cell_length_c   10.907
_cell_angle_alpha   88.497
_cell_angle_beta   88.497
_cell_angle_gamma   117.408
_symmetry_Int_Tables_number   1
_cell_volume   510.445
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.500  0.500  0.500  1.0
  Sb  Sb1  1  0.500  0.500  0.000  1.0
  Sb  Sb2  1  0.153  0.847  0.750  1.0
  Sb  Sb3  1  0.847  0.153  0.250  1.0
  H  H4  1  0.251  0.004  0.334  1.0
  H  H5  1  0.996  0.749  0.166  1.0
  H  H6  1  0.749  0.996  0.666  1.0
  H  H7  1  0.004  0.251  0.834  1.0
  H  H8  1  0.028  0.777  0.361  1.0
  H  H9  1  0.223  0.972  0.139  1.0
  H  H10  1  0.972  0.223  0.639  1.0
  H  H11  1  0.777  0.028  0.861  1.0
  H  H12  1  0.263  0.774  0.348  1.0
  H  H13  1  0.226  0.737  0.152  1.0
  H  H14  1  0.737  0.226  0.652  1.0
  H  H15  1  0.774  0.263  0.848  1.0
  N  N16  1  0.176  0.847  0.316  1.0
  N  N17  1  0.153  0.824  0.184  1.0
  N  N18  1  0.824  0.153  0.684  1.0
  N  N19  1  0.847  0.176  0.816  1.0
  F  F20  1  0.473  0.297  0.385  1.0
  F  F21  1  0.703  0.527  0.115  1.0
  F  F22  1  0.527  0.703  0.615  1.0
  F  F23  1  0.297  0.473  0.885  1.0
  F  F24  1  0.216  0.330  0.557  1.0
  F  F25  1  0.670  0.784  0.943  1.0
  F  F26  1  0.784  0.670  0.443  1.0
  F  F27  1  0.330  0.216  0.057  1.0
  F  F28  1  0.403  0.638  0.384  1.0
  F  F29  1  0.362  0.597  0.116  1.0
  F  F30  1  0.597  0.362  0.616  1.0
  F  F31  1  0.638  0.403  0.884  1.0
  F  F32  1  0.877  0.798  0.717  1.0
  F  F33  1  0.202  0.123  0.783  1.0
  F  F34  1  0.123  0.202  0.283  1.0
  F  F35  1  0.798  0.877  0.217  1.0
  F  F36  1  0.074  0.562  0.718  1.0
  F  F37  1  0.438  0.926  0.782  1.0
  F  F38  1  0.926  0.438  0.282  1.0
  F  F39  1  0.562  0.074  0.218  1.0
  F  F40  1  0.230  0.914  0.579  1.0
  F  F41  1  0.086  0.770  0.921  1.0
  F  F42  1  0.770  0.086  0.421  1.0
  F  F43  1  0.914  0.230  0.079  1.0
[/CIF]
.