The structure described by NdCO4 crystallizes in the orthorhombic Pnma space group. Nd(1) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(2), and six equivalent O(3) atoms. C(1) is bonded in a trigonal planar geometry to one O(2) and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent Nd(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Nd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Nd(1) and one C(1) atom. is represented by the CIF card [CIF]
data_NdCO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.990
_cell_length_b   7.357
_cell_length_c   8.454
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   310.358
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.250  0.355  0.334  1.0
  Nd  Nd1  1  0.250  0.855  0.166  1.0
  Nd  Nd2  1  0.750  0.645  0.666  1.0
  Nd  Nd3  1  0.750  0.145  0.834  1.0
  C  C4  1  0.250  0.303  0.680  1.0
  C  C5  1  0.250  0.803  0.820  1.0
  C  C6  1  0.750  0.697  0.320  1.0
  C  C7  1  0.750  0.197  0.180  1.0
  O  O8  1  0.250  0.037  0.400  1.0
  O  O9  1  0.250  0.537  0.100  1.0
  O  O10  1  0.750  0.963  0.600  1.0
  O  O11  1  0.750  0.463  0.900  1.0
  O  O12  1  0.750  0.295  0.306  1.0
  O  O13  1  0.750  0.795  0.194  1.0
  O  O14  1  0.250  0.705  0.694  1.0
  O  O15  1  0.250  0.205  0.806  1.0
  O  O16  1  0.975  0.651  0.386  1.0
  O  O17  1  0.525  0.151  0.114  1.0
  O  O18  1  0.475  0.349  0.614  1.0
  O  O19  1  0.025  0.849  0.886  1.0
  O  O20  1  0.025  0.349  0.614  1.0
  O  O21  1  0.475  0.849  0.886  1.0
  O  O22  1  0.525  0.651  0.386  1.0
  O  O23  1  0.975  0.151  0.114  1.0
[/CIF]
.
The structure described by NdCO4 crystallizes in the orthorhombic Pnma space group. Nd(1) is bonded in a 10-coordinate geometry to two equivalent O(1), two equivalent O(2), and six equivalent O(3) atoms. C(1) is bonded in a trigonal planar geometry to one O(2) and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to two equivalent Nd(1) atoms. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Nd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to three equivalent Nd(1) and one C(1) atom. is represented by the CIF card [CIF]
data_NdCO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.990
_cell_length_b   7.357
_cell_length_c   8.454
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   310.358
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.250  0.355  0.334  1.0
  Nd  Nd1  1  0.250  0.855  0.166  1.0
  Nd  Nd2  1  0.750  0.645  0.666  1.0
  Nd  Nd3  1  0.750  0.145  0.834  1.0
  C  C4  1  0.250  0.303  0.680  1.0
  C  C5  1  0.250  0.803  0.820  1.0
  C  C6  1  0.750  0.697  0.320  1.0
  C  C7  1  0.750  0.197  0.180  1.0
  O  O8  1  0.250  0.037  0.400  1.0
  O  O9  1  0.250  0.537  0.100  1.0
  O  O10  1  0.750  0.963  0.600  1.0
  O  O11  1  0.750  0.463  0.900  1.0
  O  O12  1  0.750  0.295  0.306  1.0
  O  O13  1  0.750  0.795  0.194  1.0
  O  O14  1  0.250  0.705  0.694  1.0
  O  O15  1  0.250  0.205  0.806  1.0
  O  O16  1  0.975  0.651  0.386  1.0
  O  O17  1  0.525  0.151  0.114  1.0
  O  O18  1  0.475  0.349  0.614  1.0
  O  O19  1  0.025  0.849  0.886  1.0
  O  O20  1  0.025  0.349  0.614  1.0
  O  O21  1  0.475  0.849  0.886  1.0
  O  O22  1  0.525  0.651  0.386  1.0
  O  O23  1  0.975  0.151  0.114  1.0
[/CIF]
.