The crystal structure described by CsAg2Cu(CN)4 crystallizes in the monoclinic P2/c space group. Cs(1) is bonded in a 12-coordinate geometry to two equivalent C(1), two equivalent C(2), four equivalent N(1), and four equivalent N(2) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent C(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent C(2) atoms. Cu(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Cs(1), one Ag(1), and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Cs(1), one Ag(2), and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted linear geometry to two equivalent Cs(1), one Cu(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Cs(1), one Cu(1), and one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsCuAg2(CN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.097
_cell_length_b   7.553
_cell_length_c   8.342
_cell_angle_alpha   104.078
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   494.829
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.245  0.500  0.250  1.0
  Cs  Cs1  1  0.755  0.500  0.750  1.0
  Cu  Cu2  1  0.258  0.500  0.750  1.0
  Cu  Cu3  1  0.742  0.500  0.250  1.0
  Ag  Ag4  1  0.000  0.000  0.500  1.0
  Ag  Ag5  1  0.000  0.000  0.000  1.0
  Ag  Ag6  1  0.441  0.000  0.250  1.0
  Ag  Ag7  1  0.559  0.000  0.750  1.0
  C  C8  1  0.080  0.789  0.596  1.0
  C  C9  1  0.080  0.211  0.904  1.0
  C  C10  1  0.920  0.211  0.404  1.0
  C  C11  1  0.920  0.789  0.096  1.0
  C  C12  1  0.418  0.790  0.041  1.0
  C  C13  1  0.418  0.210  0.459  1.0
  C  C14  1  0.582  0.210  0.959  1.0
  C  C15  1  0.582  0.790  0.541  1.0
  N  N16  1  0.131  0.669  0.650  1.0
  N  N17  1  0.131  0.331  0.850  1.0
  N  N18  1  0.869  0.331  0.350  1.0
  N  N19  1  0.869  0.669  0.150  1.0
  N  N20  1  0.385  0.670  0.926  1.0
  N  N21  1  0.385  0.330  0.574  1.0
  N  N22  1  0.615  0.330  0.074  1.0
  N  N23  1  0.615  0.670  0.426  1.0
[/CIF]
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The crystal structure described by CsAg2Cu(CN)4 crystallizes in the monoclinic P2/c space group. Cs(1) is bonded in a 12-coordinate geometry to two equivalent C(1), two equivalent C(2), four equivalent N(1), and four equivalent N(2) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent C(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent C(2) atoms. Cu(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Cs(1), one Ag(1), and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Cs(1), one Ag(2), and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted linear geometry to two equivalent Cs(1), one Cu(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Cs(1), one Cu(1), and one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsCuAg2(CN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.097
_cell_length_b   7.553
_cell_length_c   8.342
_cell_angle_alpha   104.078
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   494.829
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.245  0.500  0.250  1.0
  Cs  Cs1  1  0.755  0.500  0.750  1.0
  Cu  Cu2  1  0.258  0.500  0.750  1.0
  Cu  Cu3  1  0.742  0.500  0.250  1.0
  Ag  Ag4  1  0.000  0.000  0.500  1.0
  Ag  Ag5  1  0.000  0.000  0.000  1.0
  Ag  Ag6  1  0.441  0.000  0.250  1.0
  Ag  Ag7  1  0.559  0.000  0.750  1.0
  C  C8  1  0.080  0.789  0.596  1.0
  C  C9  1  0.080  0.211  0.904  1.0
  C  C10  1  0.920  0.211  0.404  1.0
  C  C11  1  0.920  0.789  0.096  1.0
  C  C12  1  0.418  0.790  0.041  1.0
  C  C13  1  0.418  0.210  0.459  1.0
  C  C14  1  0.582  0.210  0.959  1.0
  C  C15  1  0.582  0.790  0.541  1.0
  N  N16  1  0.131  0.669  0.650  1.0
  N  N17  1  0.131  0.331  0.850  1.0
  N  N18  1  0.869  0.331  0.350  1.0
  N  N19  1  0.869  0.669  0.150  1.0
  N  N20  1  0.385  0.670  0.926  1.0
  N  N21  1  0.385  0.330  0.574  1.0
  N  N22  1  0.615  0.330  0.074  1.0
  N  N23  1  0.615  0.670  0.426  1.0
[/CIF]
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