The material structure described by AgSbS2 is Caswellsilverite-like structured and crystallizes in the tetragonal P4/mmm space group. Ag(1) is bonded to two equivalent S(1) and four equivalent S(2) atoms to form AgS6 octahedra that share corners with six equivalent Ag(1)S6 octahedra, edges with four equivalent Ag(1)S6 octahedra, and edges with eight equivalent Sb(1)S6 octahedra. The corner-sharing octahedra are not tilted. Sb(1) is bonded to two equivalent S(2) and four equivalent S(1) atoms to form SbS6 octahedra that share corners with six equivalent Sb(1)S6 octahedra, edges with four equivalent Sb(1)S6 octahedra, and edges with eight equivalent Ag(1)S6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Ag(1) and four equivalent Sb(1) atoms to form SAg2Sb4 octahedra that share corners with six equivalent S(1)Ag2Sb4 octahedra, edges with four equivalent S(1)Ag2Sb4 octahedra, and edges with eight equivalent S(2)Ag4Sb2 octahedra. The corner-sharing octahedra are not tilted. In the second S site, S(2) is bonded to four equivalent Ag(1) and two equivalent Sb(1) atoms to form SAg4Sb2 octahedra that share corners with six equivalent S(2)Ag4Sb2 octahedra, edges with four equivalent S(2)Ag4Sb2 octahedra, and edges with eight equivalent S(1)Ag2Sb4 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_AgSbS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.970
_cell_length_b   3.970
_cell_length_c   5.408
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   85.236
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.000  1.0
  Sb  Sb1  1  0.500  0.500  0.500  1.0
  S  S2  1  0.000  0.000  0.500  1.0
  S  S3  1  0.500  0.500  0.000  1.0
[/CIF]
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The material structure described by AgSbS2 is Caswellsilverite-like structured and crystallizes in the tetragonal P4/mmm space group. Ag(1) is bonded to two equivalent S(1) and four equivalent S(2) atoms to form AgS6 octahedra that share corners with six equivalent Ag(1)S6 octahedra, edges with four equivalent Ag(1)S6 octahedra, and edges with eight equivalent Sb(1)S6 octahedra. The corner-sharing octahedra are not tilted. Sb(1) is bonded to two equivalent S(2) and four equivalent S(1) atoms to form SbS6 octahedra that share corners with six equivalent Sb(1)S6 octahedra, edges with four equivalent Sb(1)S6 octahedra, and edges with eight equivalent Ag(1)S6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Ag(1) and four equivalent Sb(1) atoms to form SAg2Sb4 octahedra that share corners with six equivalent S(1)Ag2Sb4 octahedra, edges with four equivalent S(1)Ag2Sb4 octahedra, and edges with eight equivalent S(2)Ag4Sb2 octahedra. The corner-sharing octahedra are not tilted. In the second S site, S(2) is bonded to four equivalent Ag(1) and two equivalent Sb(1) atoms to form SAg4Sb2 octahedra that share corners with six equivalent S(2)Ag4Sb2 octahedra, edges with four equivalent S(2)Ag4Sb2 octahedra, and edges with eight equivalent S(1)Ag2Sb4 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF card [CIF]
data_AgSbS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.970
_cell_length_b   3.970
_cell_length_c   5.408
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   85.236
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.000  1.0
  Sb  Sb1  1  0.500  0.500  0.500  1.0
  S  S2  1  0.000  0.000  0.500  1.0
  S  S3  1  0.500  0.500  0.000  1.0
[/CIF]
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