The crystal structure described by ThH2(SO4)3 crystallizes in the triclinic P-1 space group. Th(1) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(9) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(8) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(1) and one O(12) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(5), one O(6), one O(7), and one O(8) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one O(10), one O(11), one O(12), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(11) is bonded in a distorted single-bond geometry to one Th(1) and one S(3) atom. In the second O site, O(12) is bonded in a water-like geometry to one H(2) and one S(3) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one H(2) and one S(1) atom. In the fourth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Th(1) and one S(1) atom. In the fifth O site, O(3) is bonded in a distorted linear geometry to one Th(1) and one S(1) atom. In the sixth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Th(1) and one S(1) atom. In the seventh O site, O(5) is bonded in a distorted single-bond geometry to one Th(1) and one S(2) atom. In the eighth O site, O(6) is bonded in a distorted linear geometry to one Th(1) and one S(2) atom. In the ninth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Th(1) and one S(2) atom. In the tenth O site, O(8) is bonded in a water-like geometry to one H(1) and one S(2) atom. In the eleventh O site, O(9) is bonded in a distorted single-bond geometry to one Th(1) and one S(3) atom. In the twelfth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Th(1) and one S(3) atom. is represented by the CIF card [CIF]
data_ThH2(SO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.790
_cell_length_b   9.234
_cell_length_c   9.800
_cell_angle_alpha   65.031
_cell_angle_beta   87.901
_cell_angle_gamma   89.010
_symmetry_Int_Tables_number   1
_cell_volume   474.685
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.747  0.321  0.827  1.0
  Th  Th1  1  0.253  0.679  0.173  1.0
  H  H2  1  0.666  0.787  0.584  1.0
  H  H3  1  0.334  0.213  0.416  1.0
  H  H4  1  0.079  0.822  0.726  1.0
  H  H5  1  0.921  0.178  0.274  1.0
  S  S6  1  0.764  0.878  0.909  1.0
  S  S7  1  0.236  0.122  0.091  1.0
  S  S8  1  0.754  0.695  0.422  1.0
  S  S9  1  0.246  0.305  0.578  1.0
  S  S10  1  0.254  0.597  0.816  1.0
  S  S11  1  0.746  0.403  0.184  1.0
  O  O12  1  0.809  0.859  0.769  1.0
  O  O13  1  0.191  0.141  0.231  1.0
  O  O14  1  0.706  0.045  0.879  1.0
  O  O15  1  0.294  0.955  0.121  1.0
  O  O16  1  0.028  0.172  0.996  1.0
  O  O17  1  0.972  0.828  0.004  1.0
  O  O18  1  0.434  0.224  0.002  1.0
  O  O19  1  0.566  0.776  0.998  1.0
  O  O20  1  0.767  0.542  0.553  1.0
  O  O21  1  0.233  0.458  0.447  1.0
  O  O22  1  0.557  0.707  0.328  1.0
  O  O23  1  0.443  0.293  0.672  1.0
  O  O24  1  0.969  0.740  0.331  1.0
  O  O25  1  0.031  0.260  0.669  1.0
  O  O26  1  0.722  0.831  0.478  1.0
  O  O27  1  0.278  0.169  0.522  1.0
  O  O28  1  0.229  0.578  0.971  1.0
  O  O29  1  0.771  0.422  0.029  1.0
  O  O30  1  0.072  0.511  0.779  1.0
  O  O31  1  0.928  0.489  0.221  1.0
  O  O32  1  0.484  0.555  0.776  1.0
  O  O33  1  0.516  0.445  0.224  1.0
  O  O34  1  0.234  0.778  0.708  1.0
  O  O35  1  0.766  0.222  0.292  1.0
[/CIF]
.
The crystal structure described by ThH2(SO4)3 crystallizes in the triclinic P-1 space group. Th(1) is bonded in a 9-coordinate geometry to one O(10), one O(11), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(9) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(8) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(1) and one O(12) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(5), one O(6), one O(7), and one O(8) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one O(10), one O(11), one O(12), and one O(9) atom. There are twelve inequivalent O sites. In the first O site, O(11) is bonded in a distorted single-bond geometry to one Th(1) and one S(3) atom. In the second O site, O(12) is bonded in a water-like geometry to one H(2) and one S(3) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one H(2) and one S(1) atom. In the fourth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Th(1) and one S(1) atom. In the fifth O site, O(3) is bonded in a distorted linear geometry to one Th(1) and one S(1) atom. In the sixth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Th(1) and one S(1) atom. In the seventh O site, O(5) is bonded in a distorted single-bond geometry to one Th(1) and one S(2) atom. In the eighth O site, O(6) is bonded in a distorted linear geometry to one Th(1) and one S(2) atom. In the ninth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Th(1) and one S(2) atom. In the tenth O site, O(8) is bonded in a water-like geometry to one H(1) and one S(2) atom. In the eleventh O site, O(9) is bonded in a distorted single-bond geometry to one Th(1) and one S(3) atom. In the twelfth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Th(1) and one S(3) atom. is represented by the CIF card [CIF]
data_ThH2(SO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.790
_cell_length_b   9.234
_cell_length_c   9.800
_cell_angle_alpha   65.031
_cell_angle_beta   87.901
_cell_angle_gamma   89.010
_symmetry_Int_Tables_number   1
_cell_volume   474.685
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Th  Th0  1  0.747  0.321  0.827  1.0
  Th  Th1  1  0.253  0.679  0.173  1.0
  H  H2  1  0.666  0.787  0.584  1.0
  H  H3  1  0.334  0.213  0.416  1.0
  H  H4  1  0.079  0.822  0.726  1.0
  H  H5  1  0.921  0.178  0.274  1.0
  S  S6  1  0.764  0.878  0.909  1.0
  S  S7  1  0.236  0.122  0.091  1.0
  S  S8  1  0.754  0.695  0.422  1.0
  S  S9  1  0.246  0.305  0.578  1.0
  S  S10  1  0.254  0.597  0.816  1.0
  S  S11  1  0.746  0.403  0.184  1.0
  O  O12  1  0.809  0.859  0.769  1.0
  O  O13  1  0.191  0.141  0.231  1.0
  O  O14  1  0.706  0.045  0.879  1.0
  O  O15  1  0.294  0.955  0.121  1.0
  O  O16  1  0.028  0.172  0.996  1.0
  O  O17  1  0.972  0.828  0.004  1.0
  O  O18  1  0.434  0.224  0.002  1.0
  O  O19  1  0.566  0.776  0.998  1.0
  O  O20  1  0.767  0.542  0.553  1.0
  O  O21  1  0.233  0.458  0.447  1.0
  O  O22  1  0.557  0.707  0.328  1.0
  O  O23  1  0.443  0.293  0.672  1.0
  O  O24  1  0.969  0.740  0.331  1.0
  O  O25  1  0.031  0.260  0.669  1.0
  O  O26  1  0.722  0.831  0.478  1.0
  O  O27  1  0.278  0.169  0.522  1.0
  O  O28  1  0.229  0.578  0.971  1.0
  O  O29  1  0.771  0.422  0.029  1.0
  O  O30  1  0.072  0.511  0.779  1.0
  O  O31  1  0.928  0.489  0.221  1.0
  O  O32  1  0.484  0.555  0.776  1.0
  O  O33  1  0.516  0.445  0.224  1.0
  O  O34  1  0.234  0.778  0.708  1.0
  O  O35  1  0.766  0.222  0.292  1.0
[/CIF]
.