The compound described by MnSb4 crystallizes in the tetragonal P4/mmm space group. Mn(1) is bonded in a distorted linear geometry to two equivalent Sb(1) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted single-bond geometry to one Mn(1) and one Sb(2) atom. In the second Sb site, Sb(2) is bonded to one Sb(1) and five equivalent Sb(2) atoms to form a mixture of edge and corner-sharing SbSb6 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF file [CIF]
data_MnSb4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.080
_cell_length_b   3.080
_cell_length_c   14.994
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   142.287
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  Sb  Sb1  1  0.000  0.000  0.180  1.0
  Sb  Sb2  1  0.000  0.000  0.399  1.0
  Sb  Sb3  1  0.000  0.000  0.601  1.0
  Sb  Sb4  1  0.000  0.000  0.820  1.0
[/CIF]
.
The compound described by MnSb4 crystallizes in the tetragonal P4/mmm space group. Mn(1) is bonded in a distorted linear geometry to two equivalent Sb(1) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted single-bond geometry to one Mn(1) and one Sb(2) atom. In the second Sb site, Sb(2) is bonded to one Sb(1) and five equivalent Sb(2) atoms to form a mixture of edge and corner-sharing SbSb6 octahedra. The corner-sharing octahedra are not tilted. is represented by the CIF file [CIF]
data_MnSb4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.080
_cell_length_b   3.080
_cell_length_c   14.994
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   142.287
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.000  0.000  0.000  1.0
  Sb  Sb1  1  0.000  0.000  0.180  1.0
  Sb  Sb2  1  0.000  0.000  0.399  1.0
  Sb  Sb3  1  0.000  0.000  0.601  1.0
  Sb  Sb4  1  0.000  0.000  0.820  1.0
[/CIF]
.