The crystal structure described by V3Mn3(AgO6)2 crystallizes in the monoclinic C2/c space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(5) and two equivalent O(6) atoms to form VO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-59°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form VO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-62°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form distorted MnO6 octahedra that share corners with two equivalent V(1)O4 tetrahedra, corners with four equivalent V(2)O4 tetrahedra, and edges with two equivalent Mn(2)O6 octahedra. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(5), one O(6), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with two equivalent V(1)O4 tetrahedra, corners with four equivalent V(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and  an edgeedge with one Mn(2)O6 octahedra. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted hexagonal planar geometry to two equivalent O(6) and four equivalent O(4) atoms. In the second Ag site, Ag(2) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded to one V(2), one Mn(2), and two equivalent Ag(2) atoms to form a mixture of distorted edge and corner-sharing OMnVAg2 trigonal pyramids. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(2), one Mn(1), and one Mn(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one V(2) and two equivalent Mn(2) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one V(2), one Mn(1), and two equivalent Ag(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(1), one Mn(1), and one Mn(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one V(1), one Mn(2), and one Ag(1) atom. is represented by the CIF card [CIF]
data_Mn3V3(AgO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.026
_cell_length_b   9.026
_cell_length_c   6.932
_cell_angle_alpha   75.754
_cell_angle_beta   75.754
_cell_angle_gamma   96.109
_symmetry_Int_Tables_number   1
_cell_volume   522.066
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.270  0.730  0.750  1.0
  Mn  Mn1  1  0.730  0.270  0.250  1.0
  Mn  Mn2  1  0.953  0.631  0.617  1.0
  Mn  Mn3  1  0.369  0.047  0.883  1.0
  Mn  Mn4  1  0.047  0.369  0.383  1.0
  Mn  Mn5  1  0.631  0.953  0.117  1.0
  V  V6  1  0.293  0.707  0.250  1.0
  V  V7  1  0.707  0.293  0.750  1.0
  V  V8  1  0.661  0.884  0.619  1.0
  V  V9  1  0.116  0.339  0.881  1.0
  V  V10  1  0.339  0.116  0.381  1.0
  V  V11  1  0.884  0.661  0.119  1.0
  Ag  Ag12  1  0.500  0.500  0.500  1.0
  Ag  Ag13  1  0.500  0.500  0.000  1.0
  Ag  Ag14  1  0.993  0.007  0.750  1.0
  Ag  Ag15  1  0.007  0.993  0.250  1.0
  O  O16  1  0.848  0.837  0.598  1.0
  O  O17  1  0.163  0.152  0.902  1.0
  O  O18  1  0.152  0.163  0.402  1.0
  O  O19  1  0.837  0.848  0.098  1.0
  O  O20  1  0.012  0.665  0.878  1.0
  O  O21  1  0.335  0.988  0.622  1.0
  O  O22  1  0.988  0.335  0.122  1.0
  O  O23  1  0.665  0.012  0.378  1.0
  O  O24  1  0.605  0.967  0.826  1.0
  O  O25  1  0.033  0.395  0.674  1.0
  O  O26  1  0.395  0.033  0.174  1.0
  O  O27  1  0.967  0.605  0.326  1.0
  O  O28  1  0.522  0.721  0.674  1.0
  O  O29  1  0.279  0.478  0.826  1.0
  O  O30  1  0.478  0.279  0.326  1.0
  O  O31  1  0.721  0.522  0.174  1.0
  O  O32  1  0.183  0.739  0.482  1.0
  O  O33  1  0.261  0.817  0.018  1.0
  O  O34  1  0.817  0.261  0.518  1.0
  O  O35  1  0.739  0.183  0.982  1.0
  O  O36  1  0.259  0.512  0.258  1.0
  O  O37  1  0.488  0.741  0.242  1.0
  O  O38  1  0.741  0.488  0.742  1.0
  O  O39  1  0.512  0.259  0.758  1.0
[/CIF]
.
The crystal structure described by V3Mn3(AgO6)2 crystallizes in the monoclinic C2/c space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(5) and two equivalent O(6) atoms to form VO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-59°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form VO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with four equivalent Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-62°. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(5) atoms to form distorted MnO6 octahedra that share corners with two equivalent V(1)O4 tetrahedra, corners with four equivalent V(2)O4 tetrahedra, and edges with two equivalent Mn(2)O6 octahedra. In the second Mn site, Mn(2) is bonded to one O(1), one O(2), one O(5), one O(6), and two equivalent O(3) atoms to form MnO6 octahedra that share corners with two equivalent V(1)O4 tetrahedra, corners with four equivalent V(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and  an edgeedge with one Mn(2)O6 octahedra. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted hexagonal planar geometry to two equivalent O(6) and four equivalent O(4) atoms. In the second Ag site, Ag(2) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded to one V(2), one Mn(2), and two equivalent Ag(2) atoms to form a mixture of distorted edge and corner-sharing OMnVAg2 trigonal pyramids. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(2), one Mn(1), and one Mn(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one V(2) and two equivalent Mn(2) atoms. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one V(2), one Mn(1), and two equivalent Ag(1) atoms. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one V(1), one Mn(1), and one Mn(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one V(1), one Mn(2), and one Ag(1) atom. is represented by the CIF card [CIF]
data_Mn3V3(AgO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.026
_cell_length_b   9.026
_cell_length_c   6.932
_cell_angle_alpha   75.754
_cell_angle_beta   75.754
_cell_angle_gamma   96.109
_symmetry_Int_Tables_number   1
_cell_volume   522.066
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.270  0.730  0.750  1.0
  Mn  Mn1  1  0.730  0.270  0.250  1.0
  Mn  Mn2  1  0.953  0.631  0.617  1.0
  Mn  Mn3  1  0.369  0.047  0.883  1.0
  Mn  Mn4  1  0.047  0.369  0.383  1.0
  Mn  Mn5  1  0.631  0.953  0.117  1.0
  V  V6  1  0.293  0.707  0.250  1.0
  V  V7  1  0.707  0.293  0.750  1.0
  V  V8  1  0.661  0.884  0.619  1.0
  V  V9  1  0.116  0.339  0.881  1.0
  V  V10  1  0.339  0.116  0.381  1.0
  V  V11  1  0.884  0.661  0.119  1.0
  Ag  Ag12  1  0.500  0.500  0.500  1.0
  Ag  Ag13  1  0.500  0.500  0.000  1.0
  Ag  Ag14  1  0.993  0.007  0.750  1.0
  Ag  Ag15  1  0.007  0.993  0.250  1.0
  O  O16  1  0.848  0.837  0.598  1.0
  O  O17  1  0.163  0.152  0.902  1.0
  O  O18  1  0.152  0.163  0.402  1.0
  O  O19  1  0.837  0.848  0.098  1.0
  O  O20  1  0.012  0.665  0.878  1.0
  O  O21  1  0.335  0.988  0.622  1.0
  O  O22  1  0.988  0.335  0.122  1.0
  O  O23  1  0.665  0.012  0.378  1.0
  O  O24  1  0.605  0.967  0.826  1.0
  O  O25  1  0.033  0.395  0.674  1.0
  O  O26  1  0.395  0.033  0.174  1.0
  O  O27  1  0.967  0.605  0.326  1.0
  O  O28  1  0.522  0.721  0.674  1.0
  O  O29  1  0.279  0.478  0.826  1.0
  O  O30  1  0.478  0.279  0.326  1.0
  O  O31  1  0.721  0.522  0.174  1.0
  O  O32  1  0.183  0.739  0.482  1.0
  O  O33  1  0.261  0.817  0.018  1.0
  O  O34  1  0.817  0.261  0.518  1.0
  O  O35  1  0.739  0.183  0.982  1.0
  O  O36  1  0.259  0.512  0.258  1.0
  O  O37  1  0.488  0.741  0.242  1.0
  O  O38  1  0.741  0.488  0.742  1.0
  O  O39  1  0.512  0.259  0.758  1.0
[/CIF]
.