The structure described by Zr24P8H crystallizes in the monoclinic P2 space group. There are twelve inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a distorted bent 150 degrees geometry to one P(3) and one P(4) atom. In the second Zr site, Zr(2) is bonded in a distorted bent 150 degrees geometry to one P(3) and one P(4) atom. In the third Zr site, Zr(3) is bonded in a 1-coordinate geometry to one P(1), one P(2), and one H(1) atom. In the fourth Zr site, Zr(4) is bonded in a distorted single-bond geometry to one P(1), one P(2), and one H(1) atom. In the fifth Zr site, Zr(5) is bonded in a distorted see-saw-like geometry to two equivalent P(1) and two equivalent P(4) atoms. In the sixth Zr site, Zr(6) is bonded in a distorted see-saw-like geometry to two equivalent P(2) and two equivalent P(3) atoms. In the seventh Zr site, Zr(7) is bonded in a distorted see-saw-like geometry to two equivalent P(2) and two equivalent P(3) atoms. In the eighth Zr site, Zr(8) is bonded in a distorted see-saw-like geometry to two equivalent P(1) and two equivalent P(4) atoms. In the ninth Zr site, Zr(9) is bonded in a 3-coordinate geometry to one P(1), one P(3), and one P(4) atom. In the tenth Zr site, Zr(10) is bonded in a 3-coordinate geometry to one P(2), one P(3), and one P(4) atom. In the eleventh Zr site, Zr(11) is bonded in a 3-coordinate geometry to one P(1), one P(2), and one P(3) atom. In the twelfth Zr site, Zr(12) is bonded in a 3-coordinate geometry to one P(1), one P(2), and one P(4) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to one Zr(11), one Zr(12), one Zr(3), one Zr(4), one Zr(9), two equivalent Zr(5), and two equivalent Zr(8) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to one Zr(10), one Zr(11), one Zr(12), one Zr(3), one Zr(4), two equivalent Zr(6), and two equivalent Zr(7) atoms. In the third P site, P(3) is bonded in a 9-coordinate geometry to one Zr(1), one Zr(10), one Zr(11), one Zr(2), one Zr(9), two equivalent Zr(6), and two equivalent Zr(7) atoms. In the fourth P site, P(4) is bonded in a 9-coordinate geometry to one Zr(1), one Zr(10), one Zr(12), one Zr(2), one Zr(9), two equivalent Zr(5), and two equivalent Zr(8) atoms. H(1) is bonded in a tetrahedral geometry to two equivalent Zr(3) and two equivalent Zr(4) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zr24P8H
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.399
_cell_length_b   10.867
_cell_length_c   10.868
_cell_angle_alpha   89.927
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   637.553
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.788  0.393  0.915  1.0
  Zr  Zr1  1  0.788  0.607  0.085  1.0
  Zr  Zr2  1  0.289  0.585  0.893  1.0
  Zr  Zr3  1  0.289  0.415  0.107  1.0
  Zr  Zr4  1  0.220  0.110  0.587  1.0
  Zr  Zr5  1  0.220  0.890  0.413  1.0
  Zr  Zr6  1  0.713  0.913  0.611  1.0
  Zr  Zr7  1  0.713  0.087  0.389  1.0
  Zr  Zr8  1  0.975  0.027  0.863  1.0
  Zr  Zr9  1  0.975  0.973  0.137  1.0
  Zr  Zr10  1  0.475  0.638  0.527  1.0
  Zr  Zr11  1  0.475  0.362  0.473  1.0
  Zr  Zr12  1  0.031  0.474  0.637  1.0
  Zr  Zr13  1  0.031  0.526  0.363  1.0
  Zr  Zr14  1  0.529  0.863  0.973  1.0
  Zr  Zr15  1  0.529  0.137  0.027  1.0
  Zr  Zr16  1  0.267  0.285  0.821  1.0
  Zr  Zr17  1  0.267  0.715  0.179  1.0
  Zr  Zr18  1  0.766  0.680  0.785  1.0
  Zr  Zr19  1  0.766  0.320  0.215  1.0
  Zr  Zr20  1  0.739  0.217  0.681  1.0
  Zr  Zr21  1  0.739  0.783  0.319  1.0
  Zr  Zr22  1  0.235  0.819  0.717  1.0
  Zr  Zr23  1  0.235  0.181  0.283  1.0
  P  P24  1  0.467  0.041  0.794  1.0
  P  P25  1  0.467  0.959  0.206  1.0
  P  P26  1  0.966  0.706  0.541  1.0
  P  P27  1  0.966  0.294  0.459  1.0
  P  P28  1  0.538  0.459  0.707  1.0
  P  P29  1  0.538  0.541  0.293  1.0
  P  P30  1  0.038  0.793  0.959  1.0
  P  P31  1  0.038  0.207  0.041  1.0
  H  H32  1  0.966  0.000  0.500  1.0
[/CIF]
.
The structure described by Zr24P8H crystallizes in the monoclinic P2 space group. There are twelve inequivalent Zr sites. In the first Zr site, Zr(1) is bonded in a distorted bent 150 degrees geometry to one P(3) and one P(4) atom. In the second Zr site, Zr(2) is bonded in a distorted bent 150 degrees geometry to one P(3) and one P(4) atom. In the third Zr site, Zr(3) is bonded in a 1-coordinate geometry to one P(1), one P(2), and one H(1) atom. In the fourth Zr site, Zr(4) is bonded in a distorted single-bond geometry to one P(1), one P(2), and one H(1) atom. In the fifth Zr site, Zr(5) is bonded in a distorted see-saw-like geometry to two equivalent P(1) and two equivalent P(4) atoms. In the sixth Zr site, Zr(6) is bonded in a distorted see-saw-like geometry to two equivalent P(2) and two equivalent P(3) atoms. In the seventh Zr site, Zr(7) is bonded in a distorted see-saw-like geometry to two equivalent P(2) and two equivalent P(3) atoms. In the eighth Zr site, Zr(8) is bonded in a distorted see-saw-like geometry to two equivalent P(1) and two equivalent P(4) atoms. In the ninth Zr site, Zr(9) is bonded in a 3-coordinate geometry to one P(1), one P(3), and one P(4) atom. In the tenth Zr site, Zr(10) is bonded in a 3-coordinate geometry to one P(2), one P(3), and one P(4) atom. In the eleventh Zr site, Zr(11) is bonded in a 3-coordinate geometry to one P(1), one P(2), and one P(3) atom. In the twelfth Zr site, Zr(12) is bonded in a 3-coordinate geometry to one P(1), one P(2), and one P(4) atom. There are four inequivalent P sites. In the first P site, P(1) is bonded in a 9-coordinate geometry to one Zr(11), one Zr(12), one Zr(3), one Zr(4), one Zr(9), two equivalent Zr(5), and two equivalent Zr(8) atoms. In the second P site, P(2) is bonded in a 9-coordinate geometry to one Zr(10), one Zr(11), one Zr(12), one Zr(3), one Zr(4), two equivalent Zr(6), and two equivalent Zr(7) atoms. In the third P site, P(3) is bonded in a 9-coordinate geometry to one Zr(1), one Zr(10), one Zr(11), one Zr(2), one Zr(9), two equivalent Zr(6), and two equivalent Zr(7) atoms. In the fourth P site, P(4) is bonded in a 9-coordinate geometry to one Zr(1), one Zr(10), one Zr(12), one Zr(2), one Zr(9), two equivalent Zr(5), and two equivalent Zr(8) atoms. H(1) is bonded in a tetrahedral geometry to two equivalent Zr(3) and two equivalent Zr(4) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zr24P8H
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.399
_cell_length_b   10.867
_cell_length_c   10.868
_cell_angle_alpha   89.927
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   637.553
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.788  0.393  0.915  1.0
  Zr  Zr1  1  0.788  0.607  0.085  1.0
  Zr  Zr2  1  0.289  0.585  0.893  1.0
  Zr  Zr3  1  0.289  0.415  0.107  1.0
  Zr  Zr4  1  0.220  0.110  0.587  1.0
  Zr  Zr5  1  0.220  0.890  0.413  1.0
  Zr  Zr6  1  0.713  0.913  0.611  1.0
  Zr  Zr7  1  0.713  0.087  0.389  1.0
  Zr  Zr8  1  0.975  0.027  0.863  1.0
  Zr  Zr9  1  0.975  0.973  0.137  1.0
  Zr  Zr10  1  0.475  0.638  0.527  1.0
  Zr  Zr11  1  0.475  0.362  0.473  1.0
  Zr  Zr12  1  0.031  0.474  0.637  1.0
  Zr  Zr13  1  0.031  0.526  0.363  1.0
  Zr  Zr14  1  0.529  0.863  0.973  1.0
  Zr  Zr15  1  0.529  0.137  0.027  1.0
  Zr  Zr16  1  0.267  0.285  0.821  1.0
  Zr  Zr17  1  0.267  0.715  0.179  1.0
  Zr  Zr18  1  0.766  0.680  0.785  1.0
  Zr  Zr19  1  0.766  0.320  0.215  1.0
  Zr  Zr20  1  0.739  0.217  0.681  1.0
  Zr  Zr21  1  0.739  0.783  0.319  1.0
  Zr  Zr22  1  0.235  0.819  0.717  1.0
  Zr  Zr23  1  0.235  0.181  0.283  1.0
  P  P24  1  0.467  0.041  0.794  1.0
  P  P25  1  0.467  0.959  0.206  1.0
  P  P26  1  0.966  0.706  0.541  1.0
  P  P27  1  0.966  0.294  0.459  1.0
  P  P28  1  0.538  0.459  0.707  1.0
  P  P29  1  0.538  0.541  0.293  1.0
  P  P30  1  0.038  0.793  0.959  1.0
  P  P31  1  0.038  0.207  0.041  1.0
  H  H32  1  0.966  0.000  0.500  1.0
[/CIF]
.