The material structure described by La(NH2SO3)3 crystallizes in the triclinic P1 space group. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(11), one O(12), one O(13), one O(14), one O(15), one O(16), one O(17), one O(18), and one O(9) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one S(1) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(4), and one S(2) atom. In the third N site, N(3) is bonded in a trigonal non-coplanar geometry to one H(5), one H(6), and one S(4) atom. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one H(7), one H(8), and one S(3) atom. In the fifth N site, N(5) is bonded in a trigonal non-coplanar geometry to one H(10), one H(9), and one S(5) atom. In the sixth N site, N(6) is bonded in a distorted trigonal non-coplanar geometry to one H(11), one H(12), and one S(6) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(6) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(15), and one O(2) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one N(2), one O(7), one O(8), and one O(9) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one N(4), one O(16), one O(5), and one O(6) atom. In the fourth S site, S(4) is bonded in a tetrahedral geometry to one N(3), one O(13), one O(14), and one O(3) atom. In the fifth S site, S(5) is bonded in a tetrahedral geometry to one N(5), one O(10), one O(11), and one O(12) atom. In the sixth S site, S(6) is bonded in a tetrahedral geometry to one N(6), one O(17), one O(18), and one O(4) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one La(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one La(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one La(1) and one S(4) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one La(1) and one S(6) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one La(1) and one S(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one La(1) and one S(3) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one La(1) and one S(2) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one La(1) and one S(2) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one La(2) and one S(2) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one La(1) and one S(5) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one La(2) and one S(5) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one La(2) and one S(5) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one La(2) and one S(4) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one La(2) and one S(4) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one La(2) and one S(1) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one La(2) and one S(3) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one La(2) and one S(6) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one La(2) and one S(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LaH6S3(NO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.079
_cell_length_b   9.868
_cell_length_c   9.874
_cell_angle_alpha   119.906
_cell_angle_beta   90.630
_cell_angle_gamma   89.724
_symmetry_Int_Tables_number   1
_cell_volume   513.444
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.249  0.333  0.667  1.0
  La  La1  1  0.749  0.667  0.333  1.0
  H  H2  1  0.630  0.800  0.887  1.0
  H  H3  1  0.768  0.670  0.733  1.0
  H  H4  1  0.730  0.266  0.937  1.0
  H  H5  1  0.874  0.112  0.911  1.0
  H  H6  1  0.133  0.901  0.801  1.0
  H  H7  1  0.274  0.938  0.678  1.0
  H  H8  1  0.730  0.062  0.327  1.0
  H  H9  1  0.873  0.093  0.203  1.0
  H  H10  1  0.369  0.897  0.098  1.0
  H  H11  1  0.225  0.738  0.062  1.0
  H  H12  1  0.231  0.325  0.263  1.0
  H  H13  1  0.375  0.202  0.107  1.0
  S  S14  1  0.750  0.599  0.914  1.0
  S  S15  1  0.751  0.086  0.685  1.0
  S  S16  1  0.748  0.315  0.401  1.0
  S  S17  1  0.251  0.683  0.597  1.0
  S  S18  1  0.249  0.914  0.317  1.0
  S  S19  1  0.249  0.402  0.085  1.0
  N  N20  1  0.764  0.728  0.853  1.0
  N  N21  1  0.738  0.147  0.874  1.0
  N  N22  1  0.266  0.871  0.730  1.0
  N  N23  1  0.735  0.126  0.270  1.0
  N  N24  1  0.234  0.857  0.128  1.0
  N  N25  1  0.237  0.270  0.143  1.0
  O  O26  1  0.949  0.505  0.853  1.0
  O  O27  1  0.550  0.503  0.854  1.0
  O  O28  1  0.252  0.606  0.692  1.0
  O  O29  1  0.248  0.307  0.915  1.0
  O  O30  1  0.550  0.347  0.495  1.0
  O  O31  1  0.950  0.351  0.496  1.0
  O  O32  1  0.551  0.148  0.652  1.0
  O  O33  1  0.951  0.146  0.648  1.0
  O  O34  1  0.756  0.915  0.610  1.0
  O  O35  1  0.249  0.085  0.392  1.0
  O  O36  1  0.051  0.850  0.347  1.0
  O  O37  1  0.452  0.856  0.354  1.0
  O  O38  1  0.049  0.647  0.503  1.0
  O  O39  1  0.449  0.652  0.503  1.0
  O  O40  1  0.747  0.695  0.085  1.0
  O  O41  1  0.748  0.391  0.305  1.0
  O  O42  1  0.450  0.497  0.145  1.0
  O  O43  1  0.050  0.496  0.148  1.0
[/CIF]
.
The material structure described by La(NH2SO3)3 crystallizes in the triclinic P1 space group. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(11), one O(12), one O(13), one O(14), one O(15), one O(16), one O(17), one O(18), and one O(9) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one S(1) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(4), and one S(2) atom. In the third N site, N(3) is bonded in a trigonal non-coplanar geometry to one H(5), one H(6), and one S(4) atom. In the fourth N site, N(4) is bonded in a distorted trigonal non-coplanar geometry to one H(7), one H(8), and one S(3) atom. In the fifth N site, N(5) is bonded in a trigonal non-coplanar geometry to one H(10), one H(9), and one S(5) atom. In the sixth N site, N(6) is bonded in a distorted trigonal non-coplanar geometry to one H(11), one H(12), and one S(6) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(6) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(6) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(15), and one O(2) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one N(2), one O(7), one O(8), and one O(9) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one N(4), one O(16), one O(5), and one O(6) atom. In the fourth S site, S(4) is bonded in a tetrahedral geometry to one N(3), one O(13), one O(14), and one O(3) atom. In the fifth S site, S(5) is bonded in a tetrahedral geometry to one N(5), one O(10), one O(11), and one O(12) atom. In the sixth S site, S(6) is bonded in a tetrahedral geometry to one N(6), one O(17), one O(18), and one O(4) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one La(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one La(1) and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one La(1) and one S(4) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one La(1) and one S(6) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one La(1) and one S(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one La(1) and one S(3) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one La(1) and one S(2) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one La(1) and one S(2) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one La(2) and one S(2) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one La(1) and one S(5) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one La(2) and one S(5) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one La(2) and one S(5) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one La(2) and one S(4) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one La(2) and one S(4) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one La(2) and one S(1) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one La(2) and one S(3) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one La(2) and one S(6) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one La(2) and one S(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LaH6S3(NO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.079
_cell_length_b   9.868
_cell_length_c   9.874
_cell_angle_alpha   119.906
_cell_angle_beta   90.630
_cell_angle_gamma   89.724
_symmetry_Int_Tables_number   1
_cell_volume   513.444
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.249  0.333  0.667  1.0
  La  La1  1  0.749  0.667  0.333  1.0
  H  H2  1  0.630  0.800  0.887  1.0
  H  H3  1  0.768  0.670  0.733  1.0
  H  H4  1  0.730  0.266  0.937  1.0
  H  H5  1  0.874  0.112  0.911  1.0
  H  H6  1  0.133  0.901  0.801  1.0
  H  H7  1  0.274  0.938  0.678  1.0
  H  H8  1  0.730  0.062  0.327  1.0
  H  H9  1  0.873  0.093  0.203  1.0
  H  H10  1  0.369  0.897  0.098  1.0
  H  H11  1  0.225  0.738  0.062  1.0
  H  H12  1  0.231  0.325  0.263  1.0
  H  H13  1  0.375  0.202  0.107  1.0
  S  S14  1  0.750  0.599  0.914  1.0
  S  S15  1  0.751  0.086  0.685  1.0
  S  S16  1  0.748  0.315  0.401  1.0
  S  S17  1  0.251  0.683  0.597  1.0
  S  S18  1  0.249  0.914  0.317  1.0
  S  S19  1  0.249  0.402  0.085  1.0
  N  N20  1  0.764  0.728  0.853  1.0
  N  N21  1  0.738  0.147  0.874  1.0
  N  N22  1  0.266  0.871  0.730  1.0
  N  N23  1  0.735  0.126  0.270  1.0
  N  N24  1  0.234  0.857  0.128  1.0
  N  N25  1  0.237  0.270  0.143  1.0
  O  O26  1  0.949  0.505  0.853  1.0
  O  O27  1  0.550  0.503  0.854  1.0
  O  O28  1  0.252  0.606  0.692  1.0
  O  O29  1  0.248  0.307  0.915  1.0
  O  O30  1  0.550  0.347  0.495  1.0
  O  O31  1  0.950  0.351  0.496  1.0
  O  O32  1  0.551  0.148  0.652  1.0
  O  O33  1  0.951  0.146  0.648  1.0
  O  O34  1  0.756  0.915  0.610  1.0
  O  O35  1  0.249  0.085  0.392  1.0
  O  O36  1  0.051  0.850  0.347  1.0
  O  O37  1  0.452  0.856  0.354  1.0
  O  O38  1  0.049  0.647  0.503  1.0
  O  O39  1  0.449  0.652  0.503  1.0
  O  O40  1  0.747  0.695  0.085  1.0
  O  O41  1  0.748  0.391  0.305  1.0
  O  O42  1  0.450  0.497  0.145  1.0
  O  O43  1  0.050  0.496  0.148  1.0
[/CIF]
.