The compound described by P3N4Cl5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two P3N4Cl5 clusters. There are three inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(3), one Cl(1), and one Cl(2) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one P(2)N2Cl2 tetrahedra and  a cornercorner with one P(3)N3Cl tetrahedra. In the second P site, P(2) is bonded to one N(1), one N(2), one Cl(3), and one Cl(4) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one P(1)N2Cl2 tetrahedra and  a cornercorner with one P(3)N3Cl tetrahedra. In the third P site, P(3) is bonded to one N(2), one N(3), one N(4), and one Cl(5) atom to form corner-sharing PN3Cl tetrahedra. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one P(3) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(2) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P3N4Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.325
_cell_length_b   8.648
_cell_length_c   11.590
_cell_angle_alpha   100.252
_cell_angle_beta   104.741
_cell_angle_gamma   98.448
_symmetry_Int_Tables_number   1
_cell_volume   590.883
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.508  0.343  0.713  1.0
  P  P1  1  0.492  0.657  0.287  1.0
  P  P2  1  0.439  0.015  0.700  1.0
  P  P3  1  0.561  0.985  0.300  1.0
  P  P4  1  0.408  0.226  0.906  1.0
  P  P5  1  0.592  0.774  0.094  1.0
  N  N6  1  0.489  0.165  0.641  1.0
  N  N7  1  0.511  0.835  0.359  1.0
  N  N8  1  0.401  0.048  0.833  1.0
  N  N9  1  0.599  0.952  0.167  1.0
  N  N10  1  0.453  0.372  0.841  1.0
  N  N11  1  0.547  0.628  0.159  1.0
  N  N12  1  0.606  0.265  0.042  1.0
  N  N13  1  0.394  0.735  0.958  1.0
  Cl  Cl14  1  0.814  0.472  0.734  1.0
  Cl  Cl15  1  0.186  0.528  0.266  1.0
  Cl  Cl16  1  0.309  0.452  0.602  1.0
  Cl  Cl17  1  0.691  0.548  0.398  1.0
  Cl  Cl18  1  0.169  0.859  0.583  1.0
  Cl  Cl19  1  0.831  0.141  0.417  1.0
  Cl  Cl20  1  0.682  0.889  0.703  1.0
  Cl  Cl21  1  0.318  0.111  0.297  1.0
  Cl  Cl22  1  0.126  0.229  0.957  1.0
  Cl  Cl23  1  0.874  0.771  0.043  1.0
[/CIF]
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The compound described by P3N4Cl5 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two P3N4Cl5 clusters. There are three inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(3), one Cl(1), and one Cl(2) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one P(2)N2Cl2 tetrahedra and  a cornercorner with one P(3)N3Cl tetrahedra. In the second P site, P(2) is bonded to one N(1), one N(2), one Cl(3), and one Cl(4) atom to form PN2Cl2 tetrahedra that share  a cornercorner with one P(1)N2Cl2 tetrahedra and  a cornercorner with one P(3)N3Cl tetrahedra. In the third P site, P(3) is bonded to one N(2), one N(3), one N(4), and one Cl(5) atom to form corner-sharing PN3Cl tetrahedra. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one P(3) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one P(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one P(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one P(2) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one P(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P3N4Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.325
_cell_length_b   8.648
_cell_length_c   11.590
_cell_angle_alpha   100.252
_cell_angle_beta   104.741
_cell_angle_gamma   98.448
_symmetry_Int_Tables_number   1
_cell_volume   590.883
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.508  0.343  0.713  1.0
  P  P1  1  0.492  0.657  0.287  1.0
  P  P2  1  0.439  0.015  0.700  1.0
  P  P3  1  0.561  0.985  0.300  1.0
  P  P4  1  0.408  0.226  0.906  1.0
  P  P5  1  0.592  0.774  0.094  1.0
  N  N6  1  0.489  0.165  0.641  1.0
  N  N7  1  0.511  0.835  0.359  1.0
  N  N8  1  0.401  0.048  0.833  1.0
  N  N9  1  0.599  0.952  0.167  1.0
  N  N10  1  0.453  0.372  0.841  1.0
  N  N11  1  0.547  0.628  0.159  1.0
  N  N12  1  0.606  0.265  0.042  1.0
  N  N13  1  0.394  0.735  0.958  1.0
  Cl  Cl14  1  0.814  0.472  0.734  1.0
  Cl  Cl15  1  0.186  0.528  0.266  1.0
  Cl  Cl16  1  0.309  0.452  0.602  1.0
  Cl  Cl17  1  0.691  0.548  0.398  1.0
  Cl  Cl18  1  0.169  0.859  0.583  1.0
  Cl  Cl19  1  0.831  0.141  0.417  1.0
  Cl  Cl20  1  0.682  0.889  0.703  1.0
  Cl  Cl21  1  0.318  0.111  0.297  1.0
  Cl  Cl22  1  0.126  0.229  0.957  1.0
  Cl  Cl23  1  0.874  0.771  0.043  1.0
[/CIF]
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