The compound described by (ReC3O3F)2O2 is Indium-derived structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of two tetraoxetane molecules and two ReC3O3F clusters. In each ReC3O3F cluster, Re(1) is bonded to one C(1), one C(2), one C(3), and three equivalent F(1) atoms to form edge-sharing ReC3F3 octahedra. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Re(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Re(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Re(1) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. F(1) is bonded in a trigonal non-coplanar geometry to three equivalent Re(1) atoms. is represented by the CIF file [CIF]
data_ReC3O4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.639
_cell_length_b   9.639
_cell_length_c   9.639
_cell_angle_alpha   103.359
_cell_angle_beta   103.359
_cell_angle_gamma   122.541
_symmetry_Int_Tables_number   1
_cell_volume   661.959
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.280  0.170  0.187  1.0
  Re  Re1  1  0.984  0.094  0.813  1.0
  Re  Re2  1  0.830  0.016  0.110  1.0
  Re  Re3  1  0.906  0.720  0.890  1.0
  C  C4  1  0.364  0.312  0.402  1.0
  C  C5  1  0.910  0.962  0.598  1.0
  C  C6  1  0.688  0.090  0.052  1.0
  C  C7  1  0.038  0.636  0.948  1.0
  C  C8  1  0.411  0.089  0.256  1.0
  C  C9  1  0.833  0.155  0.744  1.0
  C  C10  1  0.911  0.167  0.322  1.0
  C  C11  1  0.845  0.589  0.678  1.0
  C  C12  1  0.500  0.368  0.197  1.0
  C  C13  1  0.171  0.303  0.803  1.0
  C  C14  1  0.632  0.829  0.132  1.0
  C  C15  1  0.697  0.500  0.868  1.0
  O  O16  1  0.415  0.402  0.535  1.0
  O  O17  1  0.866  0.880  0.465  1.0
  O  O18  1  0.598  0.134  0.014  1.0
  O  O19  1  0.120  0.585  0.986  1.0
  O  O20  1  0.490  0.036  0.298  1.0
  O  O21  1  0.738  0.192  0.702  1.0
  O  O22  1  0.964  0.262  0.453  1.0
  O  O23  1  0.808  0.510  0.547  1.0
  O  O24  1  0.635  0.487  0.201  1.0
  O  O25  1  0.286  0.434  0.799  1.0
  O  O26  1  0.513  0.714  0.148  1.0
  O  O27  1  0.566  0.365  0.852  1.0
  O  O28  1  0.184  0.775  0.421  1.0
  O  O29  1  0.354  0.763  0.579  1.0
  O  O30  1  0.225  0.646  0.409  1.0
  O  O31  1  0.237  0.816  0.591  1.0
  F  F32  1  0.001  0.925  0.132  1.0
  F  F33  1  0.793  0.868  0.868  1.0
  F  F34  1  0.075  0.207  0.076  1.0
  F  F35  1  0.132  0.999  0.924  1.0
[/CIF]
.
The compound described by (ReC3O3F)2O2 is Indium-derived structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of two tetraoxetane molecules and two ReC3O3F clusters. In each ReC3O3F cluster, Re(1) is bonded to one C(1), one C(2), one C(3), and three equivalent F(1) atoms to form edge-sharing ReC3F3 octahedra. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Re(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Re(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Re(1) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. F(1) is bonded in a trigonal non-coplanar geometry to three equivalent Re(1) atoms. is represented by the CIF file [CIF]
data_ReC3O4F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.639
_cell_length_b   9.639
_cell_length_c   9.639
_cell_angle_alpha   103.359
_cell_angle_beta   103.359
_cell_angle_gamma   122.541
_symmetry_Int_Tables_number   1
_cell_volume   661.959
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.280  0.170  0.187  1.0
  Re  Re1  1  0.984  0.094  0.813  1.0
  Re  Re2  1  0.830  0.016  0.110  1.0
  Re  Re3  1  0.906  0.720  0.890  1.0
  C  C4  1  0.364  0.312  0.402  1.0
  C  C5  1  0.910  0.962  0.598  1.0
  C  C6  1  0.688  0.090  0.052  1.0
  C  C7  1  0.038  0.636  0.948  1.0
  C  C8  1  0.411  0.089  0.256  1.0
  C  C9  1  0.833  0.155  0.744  1.0
  C  C10  1  0.911  0.167  0.322  1.0
  C  C11  1  0.845  0.589  0.678  1.0
  C  C12  1  0.500  0.368  0.197  1.0
  C  C13  1  0.171  0.303  0.803  1.0
  C  C14  1  0.632  0.829  0.132  1.0
  C  C15  1  0.697  0.500  0.868  1.0
  O  O16  1  0.415  0.402  0.535  1.0
  O  O17  1  0.866  0.880  0.465  1.0
  O  O18  1  0.598  0.134  0.014  1.0
  O  O19  1  0.120  0.585  0.986  1.0
  O  O20  1  0.490  0.036  0.298  1.0
  O  O21  1  0.738  0.192  0.702  1.0
  O  O22  1  0.964  0.262  0.453  1.0
  O  O23  1  0.808  0.510  0.547  1.0
  O  O24  1  0.635  0.487  0.201  1.0
  O  O25  1  0.286  0.434  0.799  1.0
  O  O26  1  0.513  0.714  0.148  1.0
  O  O27  1  0.566  0.365  0.852  1.0
  O  O28  1  0.184  0.775  0.421  1.0
  O  O29  1  0.354  0.763  0.579  1.0
  O  O30  1  0.225  0.646  0.409  1.0
  O  O31  1  0.237  0.816  0.591  1.0
  F  F32  1  0.001  0.925  0.132  1.0
  F  F33  1  0.793  0.868  0.868  1.0
  F  F34  1  0.075  0.207  0.076  1.0
  F  F35  1  0.132  0.999  0.924  1.0
[/CIF]
.