The material structure described by VOSb2O4 crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 5-coordinate geometry to one O(3) and four equivalent O(1) atoms. Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1) and three equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent V(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to three equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_VSb2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.949
_cell_length_b   5.627
_cell_length_c   18.038
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   502.292
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.879  0.675  0.250  1.0
  V  V1  1  0.379  0.825  0.750  1.0
  V  V2  1  0.621  0.175  0.250  1.0
  V  V3  1  0.121  0.325  0.750  1.0
  Sb  Sb4  1  0.034  0.676  0.588  1.0
  Sb  Sb5  1  0.966  0.324  0.412  1.0
  Sb  Sb6  1  0.466  0.176  0.912  1.0
  Sb  Sb7  1  0.034  0.676  0.912  1.0
  Sb  Sb8  1  0.534  0.824  0.412  1.0
  Sb  Sb9  1  0.466  0.176  0.588  1.0
  Sb  Sb10  1  0.966  0.324  0.088  1.0
  Sb  Sb11  1  0.534  0.824  0.088  1.0
  O  O12  1  0.241  0.073  0.679  1.0
  O  O13  1  0.660  0.135  0.043  1.0
  O  O14  1  0.160  0.365  0.543  1.0
  O  O15  1  0.289  0.160  0.250  1.0
  O  O16  1  0.340  0.865  0.957  1.0
  O  O17  1  0.741  0.427  0.321  1.0
  O  O18  1  0.660  0.135  0.457  1.0
  O  O19  1  0.741  0.427  0.179  1.0
  O  O20  1  0.211  0.660  0.250  1.0
  O  O21  1  0.789  0.340  0.750  1.0
  O  O22  1  0.840  0.635  0.457  1.0
  O  O23  1  0.759  0.927  0.321  1.0
  O  O24  1  0.259  0.573  0.679  1.0
  O  O25  1  0.711  0.840  0.750  1.0
  O  O26  1  0.759  0.927  0.179  1.0
  O  O27  1  0.259  0.573  0.821  1.0
  O  O28  1  0.160  0.365  0.957  1.0
  O  O29  1  0.840  0.635  0.043  1.0
  O  O30  1  0.340  0.865  0.543  1.0
  O  O31  1  0.241  0.073  0.821  1.0
[/CIF]
.
The material structure described by VOSb2O4 crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a 5-coordinate geometry to one O(3) and four equivalent O(1) atoms. Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1) and three equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent V(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to three equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_VSb2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.949
_cell_length_b   5.627
_cell_length_c   18.038
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   502.292
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.879  0.675  0.250  1.0
  V  V1  1  0.379  0.825  0.750  1.0
  V  V2  1  0.621  0.175  0.250  1.0
  V  V3  1  0.121  0.325  0.750  1.0
  Sb  Sb4  1  0.034  0.676  0.588  1.0
  Sb  Sb5  1  0.966  0.324  0.412  1.0
  Sb  Sb6  1  0.466  0.176  0.912  1.0
  Sb  Sb7  1  0.034  0.676  0.912  1.0
  Sb  Sb8  1  0.534  0.824  0.412  1.0
  Sb  Sb9  1  0.466  0.176  0.588  1.0
  Sb  Sb10  1  0.966  0.324  0.088  1.0
  Sb  Sb11  1  0.534  0.824  0.088  1.0
  O  O12  1  0.241  0.073  0.679  1.0
  O  O13  1  0.660  0.135  0.043  1.0
  O  O14  1  0.160  0.365  0.543  1.0
  O  O15  1  0.289  0.160  0.250  1.0
  O  O16  1  0.340  0.865  0.957  1.0
  O  O17  1  0.741  0.427  0.321  1.0
  O  O18  1  0.660  0.135  0.457  1.0
  O  O19  1  0.741  0.427  0.179  1.0
  O  O20  1  0.211  0.660  0.250  1.0
  O  O21  1  0.789  0.340  0.750  1.0
  O  O22  1  0.840  0.635  0.457  1.0
  O  O23  1  0.759  0.927  0.321  1.0
  O  O24  1  0.259  0.573  0.679  1.0
  O  O25  1  0.711  0.840  0.750  1.0
  O  O26  1  0.759  0.927  0.179  1.0
  O  O27  1  0.259  0.573  0.821  1.0
  O  O28  1  0.160  0.365  0.957  1.0
  O  O29  1  0.840  0.635  0.043  1.0
  O  O30  1  0.340  0.865  0.543  1.0
  O  O31  1  0.241  0.073  0.821  1.0
[/CIF]
.