The material described by Sr3La3RuZn2O12 is (La,Ba)CuO4-derived structured and crystallizes in the monoclinic Cm space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(3), one O(5), one O(6), two equivalent O(4), two equivalent O(8), and two equivalent O(9) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(2), one O(4), one O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to one O(1), one O(3), one O(6), two equivalent O(2), two equivalent O(7), and two equivalent O(8) atoms. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(4), one O(6), two equivalent O(5), two equivalent O(7), and two equivalent O(9) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(2), one O(3), one O(5), two equivalent O(1), two equivalent O(7), and two equivalent O(9) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(4), two equivalent O(3), two equivalent O(8), and two equivalent O(9) atoms. Ru(1) is bonded to one O(2), one O(6), two equivalent O(7), and two equivalent O(8) atoms to form RuO6 octahedra that share corners with two equivalent Zn(1)O6 octahedra and corners with two equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(5), two equivalent O(7), and two equivalent O(9) atoms to form distorted ZnO6 octahedra that share corners with two equivalent Ru(1)O6 octahedra and corners with two equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-8°. In the second Zn site, Zn(2) is bonded to one O(3), one O(4), two equivalent O(8), and two equivalent O(9) atoms to form ZnO6 octahedra that share corners with two equivalent Ru(1)O6 octahedra and corners with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Sr(3), one La(1), one La(3), two equivalent La(2), and one Zn(1) atom. In the second O site, O(2) is bonded to one Sr(2), two equivalent Sr(3), one La(2), one La(3), and one Ru(1) atom to form distorted OSr3La2Ru octahedra that share  a cornercorner with one O(3)Sr2La3Zn octahedra,  a cornercorner with one O(6)Sr4LaRu octahedra, corners with two equivalent O(2)Sr3La2Ru octahedra, corners with four equivalent O(7)Sr2La2ZnRu octahedra, corners with four equivalent O(8)Sr3LaZnRu octahedra, corners with four equivalent O(9)SrLa3Zn2 octahedra, edges with two equivalent O(3)Sr2La3Zn octahedra, edges with two equivalent O(6)Sr4LaRu octahedra, faces with two equivalent O(7)Sr2La2ZnRu octahedra, and faces with two equivalent O(8)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-58°. In the third O site, O(3) is bonded to one Sr(1), one Sr(3), one La(2), two equivalent La(3), and one Zn(2) atom to form distorted OSr2La3Zn octahedra that share  a cornercorner with one O(2)Sr3La2Ru octahedra, corners with two equivalent O(3)Sr2La3Zn octahedra, corners with four equivalent O(7)Sr2La2ZnRu octahedra, corners with four equivalent O(8)Sr3LaZnRu octahedra, corners with four equivalent O(9)SrLa3Zn2 octahedra,  an edgeedge with one O(6)Sr4LaRu octahedra, edges with two equivalent O(2)Sr3La2Ru octahedra, faces with two equivalent O(8)Sr3LaZnRu octahedra, and faces with two equivalent O(9)SrLa3Zn2 octahedra. The corner-sharing octahedral tilt angles range from 14-54°. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Sr(2), two equivalent Sr(1), one La(1), one La(3), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), one La(2), two equivalent La(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded to one Sr(1), one Sr(3), two equivalent Sr(2), one La(1), and one Ru(1) atom to form distorted OSr4LaRu octahedra that share  a cornercorner with one O(2)Sr3La2Ru octahedra, corners with two equivalent O(6)Sr4LaRu octahedra, corners with four equivalent O(7)Sr2La2ZnRu octahedra, corners with four equivalent O(8)Sr3LaZnRu octahedra, corners with four equivalent O(9)SrLa3Zn2 octahedra,  an edgeedge with one O(3)Sr2La3Zn octahedra, edges with two equivalent O(2)Sr3La2Ru octahedra, faces with two equivalent O(7)Sr2La2ZnRu octahedra, and faces with two equivalent O(8)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-58°. In the seventh O site, O(7) is bonded to one Sr(2), one Sr(3), one La(1), one La(2), one Ru(1), and one Zn(1) atom to form distorted OSr2La2ZnRu octahedra that share  a cornercorner with one O(8)Sr3LaZnRu octahedra,  a cornercorner with one O(9)SrLa3Zn2 octahedra, corners with two equivalent O(3)Sr2La3Zn octahedra, corners with two equivalent O(2)Sr3La2Ru octahedra, corners with two equivalent O(6)Sr4LaRu octahedra,  an edgeedge with one O(8)Sr3LaZnRu octahedra,  an edgeedge with one O(9)SrLa3Zn2 octahedra,  a faceface with one O(2)Sr3La2Ru octahedra,  a faceface with one O(8)Sr3LaZnRu octahedra,  a faceface with one O(6)Sr4LaRu octahedra,  a faceface with one O(9)SrLa3Zn2 octahedra, and faces with two equivalent O(7)Sr2La2ZnRu octahedra. The corner-sharing octahedral tilt angles range from 2-57°. In the eighth O site, O(8) is bonded to one Sr(1), one Sr(2), one Sr(3), one La(3), one Ru(1), and one Zn(2) atom to form distorted OSr3LaZnRu octahedra that share  a cornercorner with one O(7)Sr2La2ZnRu octahedra,  a cornercorner with one O(9)SrLa3Zn2 octahedra, corners with two equivalent O(3)Sr2La3Zn octahedra, corners with two equivalent O(2)Sr3La2Ru octahedra, corners with two equivalent O(6)Sr4LaRu octahedra,  an edgeedge with one O(7)Sr2La2ZnRu octahedra,  an edgeedge with one O(9)SrLa3Zn2 octahedra,  a faceface with one O(7)Sr2La2ZnRu octahedra,  a faceface with one O(3)Sr2La3Zn octahedra,  a faceface with one O(2)Sr3La2Ru octahedra,  a faceface with one O(6)Sr4LaRu octahedra,  a faceface with one O(9)SrLa3Zn2 octahedra, and faces with two equivalent O(8)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-55°. In the ninth O site, O(9) is bonded to one Sr(1), one La(1), one La(2), one La(3), one Zn(1), and one Zn(2) atom to form distorted OSrLa3Zn2 octahedra that share  a cornercorner with one O(7)Sr2La2ZnRu octahedra,  a cornercorner with one O(8)Sr3LaZnRu octahedra, corners with two equivalent O(3)Sr2La3Zn octahedra, corners with two equivalent O(2)Sr3La2Ru octahedra, corners with two equivalent O(6)Sr4LaRu octahedra,  an edgeedge with one O(7)Sr2La2ZnRu octahedra,  an edgeedge with one O(8)Sr3LaZnRu octahedra,  a faceface with one O(7)Sr2La2ZnRu octahedra,  a faceface with one O(3)Sr2La3Zn octahedra,  a faceface with one O(8)Sr3LaZnRu octahedra, and faces with two equivalent O(9)SrLa3Zn2 octahedra. The corner-sharing octahedral tilt angles range from 1-58°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr3La3Zn2RuO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.963
_cell_length_b   6.963
_cell_length_c   10.530
_cell_angle_alpha   56.549
_cell_angle_beta   56.549
_cell_angle_gamma   47.520
_symmetry_Int_Tables_number   1
_cell_volume   300.581
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.690  0.690  0.340  1.0
  Sr  Sr1  1  0.356  0.356  0.999  1.0
  Sr  Sr2  1  0.642  0.642  0.002  1.0
  La  La3  1  0.037  0.037  0.649  1.0
  La  La4  1  0.316  0.316  0.649  1.0
  La  La5  1  0.964  0.964  0.349  1.0
  Zn  Zn6  1  0.657  0.657  0.667  1.0
  Zn  Zn7  1  0.334  0.334  0.332  1.0
  Ru  Ru8  1  0.000  0.000  0.000  1.0
  O  O9  1  0.859  0.859  0.648  1.0
  O  O10  1  0.157  0.157  0.006  1.0
  O  O11  1  0.497  0.497  0.349  1.0
  O  O12  1  0.144  0.144  0.348  1.0
  O  O13  1  0.483  0.483  0.675  1.0
  O  O14  1  0.847  0.847  0.989  1.0
  O  O15  1  0.847  0.331  0.833  1.0
  O  O16  1  0.164  0.674  0.162  1.0
  O  O17  1  0.497  0.002  0.504  1.0
  O  O18  1  0.002  0.497  0.504  1.0
  O  O19  1  0.331  0.847  0.833  1.0
  O  O20  1  0.674  0.164  0.162  1.0
[/CIF]
.
The material described by Sr3La3RuZn2O12 is (La,Ba)CuO4-derived structured and crystallizes in the monoclinic Cm space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 9-coordinate geometry to one O(3), one O(5), one O(6), two equivalent O(4), two equivalent O(8), and two equivalent O(9) atoms. In the second Sr site, Sr(2) is bonded in a 9-coordinate geometry to one O(2), one O(4), one O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the third Sr site, Sr(3) is bonded in a 9-coordinate geometry to one O(1), one O(3), one O(6), two equivalent O(2), two equivalent O(7), and two equivalent O(8) atoms. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(4), one O(6), two equivalent O(5), two equivalent O(7), and two equivalent O(9) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(2), one O(3), one O(5), two equivalent O(1), two equivalent O(7), and two equivalent O(9) atoms. In the third La site, La(3) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(4), two equivalent O(3), two equivalent O(8), and two equivalent O(9) atoms. Ru(1) is bonded to one O(2), one O(6), two equivalent O(7), and two equivalent O(8) atoms to form RuO6 octahedra that share corners with two equivalent Zn(1)O6 octahedra and corners with two equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-8°. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(5), two equivalent O(7), and two equivalent O(9) atoms to form distorted ZnO6 octahedra that share corners with two equivalent Ru(1)O6 octahedra and corners with two equivalent Zn(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-8°. In the second Zn site, Zn(2) is bonded to one O(3), one O(4), two equivalent O(8), and two equivalent O(9) atoms to form ZnO6 octahedra that share corners with two equivalent Ru(1)O6 octahedra and corners with two equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-5°. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 6-coordinate geometry to one Sr(3), one La(1), one La(3), two equivalent La(2), and one Zn(1) atom. In the second O site, O(2) is bonded to one Sr(2), two equivalent Sr(3), one La(2), one La(3), and one Ru(1) atom to form distorted OSr3La2Ru octahedra that share  a cornercorner with one O(3)Sr2La3Zn octahedra,  a cornercorner with one O(6)Sr4LaRu octahedra, corners with two equivalent O(2)Sr3La2Ru octahedra, corners with four equivalent O(7)Sr2La2ZnRu octahedra, corners with four equivalent O(8)Sr3LaZnRu octahedra, corners with four equivalent O(9)SrLa3Zn2 octahedra, edges with two equivalent O(3)Sr2La3Zn octahedra, edges with two equivalent O(6)Sr4LaRu octahedra, faces with two equivalent O(7)Sr2La2ZnRu octahedra, and faces with two equivalent O(8)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-58°. In the third O site, O(3) is bonded to one Sr(1), one Sr(3), one La(2), two equivalent La(3), and one Zn(2) atom to form distorted OSr2La3Zn octahedra that share  a cornercorner with one O(2)Sr3La2Ru octahedra, corners with two equivalent O(3)Sr2La3Zn octahedra, corners with four equivalent O(7)Sr2La2ZnRu octahedra, corners with four equivalent O(8)Sr3LaZnRu octahedra, corners with four equivalent O(9)SrLa3Zn2 octahedra,  an edgeedge with one O(6)Sr4LaRu octahedra, edges with two equivalent O(2)Sr3La2Ru octahedra, faces with two equivalent O(8)Sr3LaZnRu octahedra, and faces with two equivalent O(9)SrLa3Zn2 octahedra. The corner-sharing octahedral tilt angles range from 14-54°. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to one Sr(2), two equivalent Sr(1), one La(1), one La(3), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to one Sr(1), one Sr(2), one La(2), two equivalent La(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded to one Sr(1), one Sr(3), two equivalent Sr(2), one La(1), and one Ru(1) atom to form distorted OSr4LaRu octahedra that share  a cornercorner with one O(2)Sr3La2Ru octahedra, corners with two equivalent O(6)Sr4LaRu octahedra, corners with four equivalent O(7)Sr2La2ZnRu octahedra, corners with four equivalent O(8)Sr3LaZnRu octahedra, corners with four equivalent O(9)SrLa3Zn2 octahedra,  an edgeedge with one O(3)Sr2La3Zn octahedra, edges with two equivalent O(2)Sr3La2Ru octahedra, faces with two equivalent O(7)Sr2La2ZnRu octahedra, and faces with two equivalent O(8)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-58°. In the seventh O site, O(7) is bonded to one Sr(2), one Sr(3), one La(1), one La(2), one Ru(1), and one Zn(1) atom to form distorted OSr2La2ZnRu octahedra that share  a cornercorner with one O(8)Sr3LaZnRu octahedra,  a cornercorner with one O(9)SrLa3Zn2 octahedra, corners with two equivalent O(3)Sr2La3Zn octahedra, corners with two equivalent O(2)Sr3La2Ru octahedra, corners with two equivalent O(6)Sr4LaRu octahedra,  an edgeedge with one O(8)Sr3LaZnRu octahedra,  an edgeedge with one O(9)SrLa3Zn2 octahedra,  a faceface with one O(2)Sr3La2Ru octahedra,  a faceface with one O(8)Sr3LaZnRu octahedra,  a faceface with one O(6)Sr4LaRu octahedra,  a faceface with one O(9)SrLa3Zn2 octahedra, and faces with two equivalent O(7)Sr2La2ZnRu octahedra. The corner-sharing octahedral tilt angles range from 2-57°. In the eighth O site, O(8) is bonded to one Sr(1), one Sr(2), one Sr(3), one La(3), one Ru(1), and one Zn(2) atom to form distorted OSr3LaZnRu octahedra that share  a cornercorner with one O(7)Sr2La2ZnRu octahedra,  a cornercorner with one O(9)SrLa3Zn2 octahedra, corners with two equivalent O(3)Sr2La3Zn octahedra, corners with two equivalent O(2)Sr3La2Ru octahedra, corners with two equivalent O(6)Sr4LaRu octahedra,  an edgeedge with one O(7)Sr2La2ZnRu octahedra,  an edgeedge with one O(9)SrLa3Zn2 octahedra,  a faceface with one O(7)Sr2La2ZnRu octahedra,  a faceface with one O(3)Sr2La3Zn octahedra,  a faceface with one O(2)Sr3La2Ru octahedra,  a faceface with one O(6)Sr4LaRu octahedra,  a faceface with one O(9)SrLa3Zn2 octahedra, and faces with two equivalent O(8)Sr3LaZnRu octahedra. The corner-sharing octahedral tilt angles range from 1-55°. In the ninth O site, O(9) is bonded to one Sr(1), one La(1), one La(2), one La(3), one Zn(1), and one Zn(2) atom to form distorted OSrLa3Zn2 octahedra that share  a cornercorner with one O(7)Sr2La2ZnRu octahedra,  a cornercorner with one O(8)Sr3LaZnRu octahedra, corners with two equivalent O(3)Sr2La3Zn octahedra, corners with two equivalent O(2)Sr3La2Ru octahedra, corners with two equivalent O(6)Sr4LaRu octahedra,  an edgeedge with one O(7)Sr2La2ZnRu octahedra,  an edgeedge with one O(8)Sr3LaZnRu octahedra,  a faceface with one O(7)Sr2La2ZnRu octahedra,  a faceface with one O(3)Sr2La3Zn octahedra,  a faceface with one O(8)Sr3LaZnRu octahedra, and faces with two equivalent O(9)SrLa3Zn2 octahedra. The corner-sharing octahedral tilt angles range from 1-58°. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr3La3Zn2RuO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.963
_cell_length_b   6.963
_cell_length_c   10.530
_cell_angle_alpha   56.549
_cell_angle_beta   56.549
_cell_angle_gamma   47.520
_symmetry_Int_Tables_number   1
_cell_volume   300.581
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.690  0.690  0.340  1.0
  Sr  Sr1  1  0.356  0.356  0.999  1.0
  Sr  Sr2  1  0.642  0.642  0.002  1.0
  La  La3  1  0.037  0.037  0.649  1.0
  La  La4  1  0.316  0.316  0.649  1.0
  La  La5  1  0.964  0.964  0.349  1.0
  Zn  Zn6  1  0.657  0.657  0.667  1.0
  Zn  Zn7  1  0.334  0.334  0.332  1.0
  Ru  Ru8  1  0.000  0.000  0.000  1.0
  O  O9  1  0.859  0.859  0.648  1.0
  O  O10  1  0.157  0.157  0.006  1.0
  O  O11  1  0.497  0.497  0.349  1.0
  O  O12  1  0.144  0.144  0.348  1.0
  O  O13  1  0.483  0.483  0.675  1.0
  O  O14  1  0.847  0.847  0.989  1.0
  O  O15  1  0.847  0.331  0.833  1.0
  O  O16  1  0.164  0.674  0.162  1.0
  O  O17  1  0.497  0.002  0.504  1.0
  O  O18  1  0.002  0.497  0.504  1.0
  O  O19  1  0.331  0.847  0.833  1.0
  O  O20  1  0.674  0.164  0.162  1.0
[/CIF]
.