The crystal structure described by La4MoCu2ZnO12 crystallizes in the triclinic P-1 space group. There are six inequivalent La sites. In the first La site, La(1) is bonded in a body-centered cubic geometry to two equivalent O(5), two equivalent O(7), two equivalent O(8), and two equivalent O(9) atoms. In the second La site, La(2) is bonded in a body-centered cubic geometry to one O(12), one O(2), one O(4), one O(5), two equivalent O(1), and two equivalent O(11) atoms. In the third La site, La(3) is bonded in a body-centered cubic geometry to two equivalent O(10), two equivalent O(2), two equivalent O(7), and two equivalent O(9) atoms. In the fourth La site, La(4) is bonded in a distorted body-centered cubic geometry to one O(1), one O(11), one O(3), one O(6), two equivalent O(12), and two equivalent O(4) atoms. In the fifth La site, La(5) is bonded in a body-centered cubic geometry to two equivalent O(10), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the sixth La site, La(6) is bonded in a body-centered cubic geometry to two equivalent O(10), two equivalent O(3), two equivalent O(8), and two equivalent O(9) atoms. Mo(1) is bonded in a trigonal bipyramidal geometry to one O(3), one O(4), one O(5), one O(6), and one O(8) atom. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(9) atom. In the second Cu site, Cu(2) is bonded in a distorted T-shaped geometry to one O(11), one O(2), and one O(7) atom. Zn(1) is bonded in a 3-coordinate geometry to one O(10), one O(12), and one O(2) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one La(4), two equivalent La(2), and one Cu(1) atom to form OLa3Cu tetrahedra that share  a cornercorner with one O(9)La3Cu tetrahedra, corners with two equivalent O(4)La3Mo tetrahedra, corners with two equivalent O(12)La3Zn tetrahedra, corners with five equivalent O(11)La3Cu tetrahedra,  a cornercorner with one O(2)La2ZnCu2 trigonal bipyramid,  an edgeedge with one O(1)La3Cu tetrahedra,  an edgeedge with one O(4)La3Mo tetrahedra,  an edgeedge with one O(12)La3Zn tetrahedra, and  an edgeedge with one O(2)La2ZnCu2 trigonal bipyramid. In the second O site, O(2) is bonded to one La(2), one La(3), one Cu(1), one Cu(2), and one Zn(1) atom to form distorted OLa2ZnCu2 trigonal bipyramids that share  a cornercorner with one O(1)La3Cu tetrahedra,  a cornercorner with one O(11)La3Cu tetrahedra,  a cornercorner with one O(7)La3Cu tetrahedra,  a cornercorner with one O(9)La3Cu tetrahedra,  a cornercorner with one O(4)La3Mo tetrahedra,  a cornercorner with one O(10)La3Zn tetrahedra,  a cornercorner with one O(2)La2ZnCu2 trigonal bipyramid,  an edgeedge with one O(1)La3Cu tetrahedra,  an edgeedge with one O(11)La3Cu tetrahedra,  an edgeedge with one O(7)La3Cu tetrahedra,  an edgeedge with one O(9)La3Cu tetrahedra,  an edgeedge with one O(10)La3Zn tetrahedra, and  an edgeedge with one O(12)La3Zn tetrahedra. In the third O site, O(3) is bonded in a distorted single-bond geometry to one La(4), one La(6), and one Mo(1) atom. In the fourth O site, O(4) is bonded to one La(2), two equivalent La(4), and one Mo(1) atom to form OLa3Mo tetrahedra that share  a cornercorner with one O(8)La3Mo tetrahedra, corners with two equivalent O(1)La3Cu tetrahedra, corners with two equivalent O(11)La3Cu tetrahedra, corners with five equivalent O(12)La3Zn tetrahedra,  a cornercorner with one O(2)La2ZnCu2 trigonal bipyramid,  an edgeedge with one O(1)La3Cu tetrahedra,  an edgeedge with one O(11)La3Cu tetrahedra, and  an edgeedge with one O(4)La3Mo tetrahedra. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one La(1), one La(2), and one Mo(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one La(4), one La(5), and one Mo(1) atom. In the seventh O site, O(7) is bonded to one La(1), one La(3), one La(5), and one Cu(2) atom to form OLa3Cu tetrahedra that share  a cornercorner with one O(11)La3Cu tetrahedra, corners with two equivalent O(9)La3Cu tetrahedra, corners with two equivalent O(8)La3Mo tetrahedra, corners with two equivalent O(10)La3Zn tetrahedra, corners with three equivalent O(7)La3Cu tetrahedra,  a cornercorner with one O(2)La2ZnCu2 trigonal bipyramid,  an edgeedge with one O(9)La3Cu tetrahedra,  an edgeedge with one O(8)La3Mo tetrahedra,  an edgeedge with one O(10)La3Zn tetrahedra, and  an edgeedge with one O(2)La2ZnCu2 trigonal bipyramid. In the eighth O site, O(8) is bonded to one La(1), one La(5), one La(6), and one Mo(1) atom to form OLa3Mo tetrahedra that share  a cornercorner with one O(4)La3Mo tetrahedra, corners with two equivalent O(7)La3Cu tetrahedra, corners with two equivalent O(9)La3Cu tetrahedra, corners with two equivalent O(10)La3Zn tetrahedra, corners with three equivalent O(8)La3Mo tetrahedra,  an edgeedge with one O(7)La3Cu tetrahedra,  an edgeedge with one O(9)La3Cu tetrahedra, and  an edgeedge with one O(10)La3Zn tetrahedra. In the ninth O site, O(9) is bonded to one La(1), one La(3), one La(6), and one Cu(1) atom to form OLa3Cu tetrahedra that share  a cornercorner with one O(1)La3Cu tetrahedra, corners with two equivalent O(7)La3Cu tetrahedra, corners with two equivalent O(8)La3Mo tetrahedra, corners with two equivalent O(10)La3Zn tetrahedra, corners with three equivalent O(9)La3Cu tetrahedra,  a cornercorner with one O(2)La2ZnCu2 trigonal bipyramid,  an edgeedge with one O(7)La3Cu tetrahedra,  an edgeedge with one O(8)La3Mo tetrahedra,  an edgeedge with one O(10)La3Zn tetrahedra, and  an edgeedge with one O(2)La2ZnCu2 trigonal bipyramid. In the tenth O site, O(10) is bonded to one La(3), one La(5), one La(6), and one Zn(1) atom to form OLa3Zn tetrahedra that share  a cornercorner with one O(12)La3Zn tetrahedra, corners with two equivalent O(7)La3Cu tetrahedra, corners with two equivalent O(9)La3Cu tetrahedra, corners with two equivalent O(8)La3Mo tetrahedra, corners with three equivalent O(10)La3Zn tetrahedra,  a cornercorner with one O(2)La2ZnCu2 trigonal bipyramid,  an edgeedge with one O(7)La3Cu tetrahedra,  an edgeedge with one O(9)La3Cu tetrahedra,  an edgeedge with one O(8)La3Mo tetrahedra, and  an edgeedge with one O(2)La2ZnCu2 trigonal bipyramid. In the eleventh O site, O(11) is bonded to one La(4), two equivalent La(2), and one Cu(2) atom to form OLa3Cu tetrahedra that share  a cornercorner with one O(7)La3Cu tetrahedra, corners with two equivalent O(4)La3Mo tetrahedra, corners with two equivalent O(12)La3Zn tetrahedra, corners with five equivalent O(1)La3Cu tetrahedra,  a cornercorner with one O(2)La2ZnCu2 trigonal bipyramid,  an edgeedge with one O(11)La3Cu tetrahedra,  an edgeedge with one O(4)La3Mo tetrahedra,  an edgeedge with one O(12)La3Zn tetrahedra, and  an edgeedge with one O(2)La2ZnCu2 trigonal bipyramid. In the twelfth O site, O(12) is bonded to one La(2), two equivalent La(4), and one Zn(1) atom to form OLa3Zn tetrahedra that share  a cornercorner with one O(10)La3Zn tetrahedra, corners with two equivalent O(1)La3Cu tetrahedra, corners with two equivalent O(11)La3Cu tetrahedra, corners with five equivalent O(4)La3Mo tetrahedra,  an edgeedge with one O(1)La3Cu tetrahedra,  an edgeedge with one O(11)La3Cu tetrahedra,  an edgeedge with one O(12)La3Zn tetrahedra, and  an edgeedge with one O(2)La2ZnCu2 trigonal bipyramid. is represented by the CIF file [CIF]
data_La4ZnCu2MoO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.997
_cell_length_b   8.031
_cell_length_c   11.687
_cell_angle_alpha   100.027
_cell_angle_beta   99.904
_cell_angle_gamma   119.688
_symmetry_Int_Tables_number   1
_cell_volume   612.217
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.000  0.500  0.000  1.0
  La  La1  1  0.251  0.755  0.506  1.0
  La  La2  1  0.749  0.245  0.494  1.0
  La  La3  1  0.500  0.000  0.000  1.0
  La  La4  1  0.760  0.759  0.498  1.0
  La  La5  1  0.240  0.241  0.502  1.0
  La  La6  1  0.000  0.000  0.000  1.0
  La  La7  1  0.500  0.500  0.000  1.0
  Zn  Zn8  1  0.225  0.012  0.753  1.0
  Zn  Zn9  1  0.775  0.988  0.247  1.0
  Cu  Cu10  1  0.228  0.577  0.750  1.0
  Cu  Cu11  1  0.772  0.423  0.250  1.0
  Cu  Cu12  1  0.669  0.020  0.749  1.0
  Cu  Cu13  1  0.331  0.980  0.251  1.0
  Mo  Mo14  1  0.709  0.540  0.746  1.0
  Mo  Mo15  1  0.291  0.460  0.254  1.0
  O  O16  1  0.881  0.547  0.417  1.0
  O  O17  1  0.119  0.453  0.583  1.0
  O  O18  1  0.384  0.859  0.749  1.0
  O  O19  1  0.616  0.141  0.251  1.0
  O  O20  1  0.442  0.403  0.747  1.0
  O  O21  1  0.558  0.597  0.253  1.0
  O  O22  1  0.381  0.547  0.429  1.0
  O  O23  1  0.619  0.453  0.571  1.0
  O  O24  1  0.160  0.592  0.252  1.0
  O  O25  1  0.840  0.408  0.748  1.0
  O  O26  1  0.147  0.194  0.251  1.0
  O  O27  1  0.853  0.806  0.749  1.0
  O  O28  1  0.206  0.874  0.084  1.0
  O  O29  1  0.794  0.126  0.916  1.0
  O  O30  1  0.205  0.370  0.076  1.0
  O  O31  1  0.795  0.630  0.924  1.0
  O  O32  1  0.712  0.378  0.084  1.0
  O  O33  1  0.288  0.622  0.916  1.0
  O  O34  1  0.292  0.130  0.919  1.0
  O  O35  1  0.708  0.870  0.081  1.0
  O  O36  1  0.369  0.039  0.418  1.0
  O  O37  1  0.631  0.961  0.582  1.0
  O  O38  1  0.123  0.961  0.586  1.0
  O  O39  1  0.877  0.039  0.414  1.0
[/CIF]
.
The crystal structure described by La4MoCu2ZnO12 crystallizes in the triclinic P-1 space group. There are six inequivalent La sites. In the first La site, La(1) is bonded in a body-centered cubic geometry to two equivalent O(5), two equivalent O(7), two equivalent O(8), and two equivalent O(9) atoms. In the second La site, La(2) is bonded in a body-centered cubic geometry to one O(12), one O(2), one O(4), one O(5), two equivalent O(1), and two equivalent O(11) atoms. In the third La site, La(3) is bonded in a body-centered cubic geometry to two equivalent O(10), two equivalent O(2), two equivalent O(7), and two equivalent O(9) atoms. In the fourth La site, La(4) is bonded in a distorted body-centered cubic geometry to one O(1), one O(11), one O(3), one O(6), two equivalent O(12), and two equivalent O(4) atoms. In the fifth La site, La(5) is bonded in a body-centered cubic geometry to two equivalent O(10), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the sixth La site, La(6) is bonded in a body-centered cubic geometry to two equivalent O(10), two equivalent O(3), two equivalent O(8), and two equivalent O(9) atoms. Mo(1) is bonded in a trigonal bipyramidal geometry to one O(3), one O(4), one O(5), one O(6), and one O(8) atom. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted T-shaped geometry to one O(1), one O(2), and one O(9) atom. In the second Cu site, Cu(2) is bonded in a distorted T-shaped geometry to one O(11), one O(2), and one O(7) atom. Zn(1) is bonded in a 3-coordinate geometry to one O(10), one O(12), and one O(2) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one La(4), two equivalent La(2), and one Cu(1) atom to form OLa3Cu tetrahedra that share  a cornercorner with one O(9)La3Cu tetrahedra, corners with two equivalent O(4)La3Mo tetrahedra, corners with two equivalent O(12)La3Zn tetrahedra, corners with five equivalent O(11)La3Cu tetrahedra,  a cornercorner with one O(2)La2ZnCu2 trigonal bipyramid,  an edgeedge with one O(1)La3Cu tetrahedra,  an edgeedge with one O(4)La3Mo tetrahedra,  an edgeedge with one O(12)La3Zn tetrahedra, and  an edgeedge with one O(2)La2ZnCu2 trigonal bipyramid. In the second O site, O(2) is bonded to one La(2), one La(3), one Cu(1), one Cu(2), and one Zn(1) atom to form distorted OLa2ZnCu2 trigonal bipyramids that share  a cornercorner with one O(1)La3Cu tetrahedra,  a cornercorner with one O(11)La3Cu tetrahedra,  a cornercorner with one O(7)La3Cu tetrahedra,  a cornercorner with one O(9)La3Cu tetrahedra,  a cornercorner with one O(4)La3Mo tetrahedra,  a cornercorner with one O(10)La3Zn tetrahedra,  a cornercorner with one O(2)La2ZnCu2 trigonal bipyramid,  an edgeedge with one O(1)La3Cu tetrahedra,  an edgeedge with one O(11)La3Cu tetrahedra,  an edgeedge with one O(7)La3Cu tetrahedra,  an edgeedge with one O(9)La3Cu tetrahedra,  an edgeedge with one O(10)La3Zn tetrahedra, and  an edgeedge with one O(12)La3Zn tetrahedra. In the third O site, O(3) is bonded in a distorted single-bond geometry to one La(4), one La(6), and one Mo(1) atom. In the fourth O site, O(4) is bonded to one La(2), two equivalent La(4), and one Mo(1) atom to form OLa3Mo tetrahedra that share  a cornercorner with one O(8)La3Mo tetrahedra, corners with two equivalent O(1)La3Cu tetrahedra, corners with two equivalent O(11)La3Cu tetrahedra, corners with five equivalent O(12)La3Zn tetrahedra,  a cornercorner with one O(2)La2ZnCu2 trigonal bipyramid,  an edgeedge with one O(1)La3Cu tetrahedra,  an edgeedge with one O(11)La3Cu tetrahedra, and  an edgeedge with one O(4)La3Mo tetrahedra. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one La(1), one La(2), and one Mo(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one La(4), one La(5), and one Mo(1) atom. In the seventh O site, O(7) is bonded to one La(1), one La(3), one La(5), and one Cu(2) atom to form OLa3Cu tetrahedra that share  a cornercorner with one O(11)La3Cu tetrahedra, corners with two equivalent O(9)La3Cu tetrahedra, corners with two equivalent O(8)La3Mo tetrahedra, corners with two equivalent O(10)La3Zn tetrahedra, corners with three equivalent O(7)La3Cu tetrahedra,  a cornercorner with one O(2)La2ZnCu2 trigonal bipyramid,  an edgeedge with one O(9)La3Cu tetrahedra,  an edgeedge with one O(8)La3Mo tetrahedra,  an edgeedge with one O(10)La3Zn tetrahedra, and  an edgeedge with one O(2)La2ZnCu2 trigonal bipyramid. In the eighth O site, O(8) is bonded to one La(1), one La(5), one La(6), and one Mo(1) atom to form OLa3Mo tetrahedra that share  a cornercorner with one O(4)La3Mo tetrahedra, corners with two equivalent O(7)La3Cu tetrahedra, corners with two equivalent O(9)La3Cu tetrahedra, corners with two equivalent O(10)La3Zn tetrahedra, corners with three equivalent O(8)La3Mo tetrahedra,  an edgeedge with one O(7)La3Cu tetrahedra,  an edgeedge with one O(9)La3Cu tetrahedra, and  an edgeedge with one O(10)La3Zn tetrahedra. In the ninth O site, O(9) is bonded to one La(1), one La(3), one La(6), and one Cu(1) atom to form OLa3Cu tetrahedra that share  a cornercorner with one O(1)La3Cu tetrahedra, corners with two equivalent O(7)La3Cu tetrahedra, corners with two equivalent O(8)La3Mo tetrahedra, corners with two equivalent O(10)La3Zn tetrahedra, corners with three equivalent O(9)La3Cu tetrahedra,  a cornercorner with one O(2)La2ZnCu2 trigonal bipyramid,  an edgeedge with one O(7)La3Cu tetrahedra,  an edgeedge with one O(8)La3Mo tetrahedra,  an edgeedge with one O(10)La3Zn tetrahedra, and  an edgeedge with one O(2)La2ZnCu2 trigonal bipyramid. In the tenth O site, O(10) is bonded to one La(3), one La(5), one La(6), and one Zn(1) atom to form OLa3Zn tetrahedra that share  a cornercorner with one O(12)La3Zn tetrahedra, corners with two equivalent O(7)La3Cu tetrahedra, corners with two equivalent O(9)La3Cu tetrahedra, corners with two equivalent O(8)La3Mo tetrahedra, corners with three equivalent O(10)La3Zn tetrahedra,  a cornercorner with one O(2)La2ZnCu2 trigonal bipyramid,  an edgeedge with one O(7)La3Cu tetrahedra,  an edgeedge with one O(9)La3Cu tetrahedra,  an edgeedge with one O(8)La3Mo tetrahedra, and  an edgeedge with one O(2)La2ZnCu2 trigonal bipyramid. In the eleventh O site, O(11) is bonded to one La(4), two equivalent La(2), and one Cu(2) atom to form OLa3Cu tetrahedra that share  a cornercorner with one O(7)La3Cu tetrahedra, corners with two equivalent O(4)La3Mo tetrahedra, corners with two equivalent O(12)La3Zn tetrahedra, corners with five equivalent O(1)La3Cu tetrahedra,  a cornercorner with one O(2)La2ZnCu2 trigonal bipyramid,  an edgeedge with one O(11)La3Cu tetrahedra,  an edgeedge with one O(4)La3Mo tetrahedra,  an edgeedge with one O(12)La3Zn tetrahedra, and  an edgeedge with one O(2)La2ZnCu2 trigonal bipyramid. In the twelfth O site, O(12) is bonded to one La(2), two equivalent La(4), and one Zn(1) atom to form OLa3Zn tetrahedra that share  a cornercorner with one O(10)La3Zn tetrahedra, corners with two equivalent O(1)La3Cu tetrahedra, corners with two equivalent O(11)La3Cu tetrahedra, corners with five equivalent O(4)La3Mo tetrahedra,  an edgeedge with one O(1)La3Cu tetrahedra,  an edgeedge with one O(11)La3Cu tetrahedra,  an edgeedge with one O(12)La3Zn tetrahedra, and  an edgeedge with one O(2)La2ZnCu2 trigonal bipyramid. is represented by the CIF file [CIF]
data_La4ZnCu2MoO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.997
_cell_length_b   8.031
_cell_length_c   11.687
_cell_angle_alpha   100.027
_cell_angle_beta   99.904
_cell_angle_gamma   119.688
_symmetry_Int_Tables_number   1
_cell_volume   612.217
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.000  0.500  0.000  1.0
  La  La1  1  0.251  0.755  0.506  1.0
  La  La2  1  0.749  0.245  0.494  1.0
  La  La3  1  0.500  0.000  0.000  1.0
  La  La4  1  0.760  0.759  0.498  1.0
  La  La5  1  0.240  0.241  0.502  1.0
  La  La6  1  0.000  0.000  0.000  1.0
  La  La7  1  0.500  0.500  0.000  1.0
  Zn  Zn8  1  0.225  0.012  0.753  1.0
  Zn  Zn9  1  0.775  0.988  0.247  1.0
  Cu  Cu10  1  0.228  0.577  0.750  1.0
  Cu  Cu11  1  0.772  0.423  0.250  1.0
  Cu  Cu12  1  0.669  0.020  0.749  1.0
  Cu  Cu13  1  0.331  0.980  0.251  1.0
  Mo  Mo14  1  0.709  0.540  0.746  1.0
  Mo  Mo15  1  0.291  0.460  0.254  1.0
  O  O16  1  0.881  0.547  0.417  1.0
  O  O17  1  0.119  0.453  0.583  1.0
  O  O18  1  0.384  0.859  0.749  1.0
  O  O19  1  0.616  0.141  0.251  1.0
  O  O20  1  0.442  0.403  0.747  1.0
  O  O21  1  0.558  0.597  0.253  1.0
  O  O22  1  0.381  0.547  0.429  1.0
  O  O23  1  0.619  0.453  0.571  1.0
  O  O24  1  0.160  0.592  0.252  1.0
  O  O25  1  0.840  0.408  0.748  1.0
  O  O26  1  0.147  0.194  0.251  1.0
  O  O27  1  0.853  0.806  0.749  1.0
  O  O28  1  0.206  0.874  0.084  1.0
  O  O29  1  0.794  0.126  0.916  1.0
  O  O30  1  0.205  0.370  0.076  1.0
  O  O31  1  0.795  0.630  0.924  1.0
  O  O32  1  0.712  0.378  0.084  1.0
  O  O33  1  0.288  0.622  0.916  1.0
  O  O34  1  0.292  0.130  0.919  1.0
  O  O35  1  0.708  0.870  0.081  1.0
  O  O36  1  0.369  0.039  0.418  1.0
  O  O37  1  0.631  0.961  0.582  1.0
  O  O38  1  0.123  0.961  0.586  1.0
  O  O39  1  0.877  0.039  0.414  1.0
[/CIF]
.