The crystal structure described by Ce2CdSb4 crystallizes in the tetragonal P-4m2 space group. Ce(1) is bonded in a 10-coordinate geometry to two equivalent Cd(1), two equivalent Sb(2), two equivalent Sb(3), and four equivalent Sb(1) atoms. Cd(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Sb(1) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to four equivalent Ce(1) and two equivalent Cd(1) atoms to form a mixture of distorted corner, face, and edge-sharing SbCe4Cd2 pentagonal pyramids. In the second Sb site, Sb(2) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Sb(3) atoms. In the third Sb site, Sb(3) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Sb(2) atoms. is represented by the CIF file [CIF]
data_Ce2CdSb4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.385
_cell_length_b   4.385
_cell_length_c   10.738
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   206.490
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.500  0.000  0.765  1.0
  Ce  Ce1  1  0.000  0.500  0.235  1.0
  Cd  Cd2  1  0.500  0.500  0.500  1.0
  Sb  Sb3  1  0.500  0.000  0.328  1.0
  Sb  Sb4  1  0.000  0.500  0.671  1.0
  Sb  Sb5  1  0.500  0.500  0.000  1.0
  Sb  Sb6  1  0.000  0.000  0.000  1.0
[/CIF]
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The crystal structure described by Ce2CdSb4 crystallizes in the tetragonal P-4m2 space group. Ce(1) is bonded in a 10-coordinate geometry to two equivalent Cd(1), two equivalent Sb(2), two equivalent Sb(3), and four equivalent Sb(1) atoms. Cd(1) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Sb(1) atoms. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to four equivalent Ce(1) and two equivalent Cd(1) atoms to form a mixture of distorted corner, face, and edge-sharing SbCe4Cd2 pentagonal pyramids. In the second Sb site, Sb(2) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Sb(3) atoms. In the third Sb site, Sb(3) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Sb(2) atoms. is represented by the CIF file [CIF]
data_Ce2CdSb4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.385
_cell_length_b   4.385
_cell_length_c   10.738
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   206.490
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.500  0.000  0.765  1.0
  Ce  Ce1  1  0.000  0.500  0.235  1.0
  Cd  Cd2  1  0.500  0.500  0.500  1.0
  Sb  Sb3  1  0.500  0.000  0.328  1.0
  Sb  Sb4  1  0.000  0.500  0.671  1.0
  Sb  Sb5  1  0.500  0.500  0.000  1.0
  Sb  Sb6  1  0.000  0.000  0.000  1.0
[/CIF]
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