The structure described by WOF4 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight WOF4 clusters. W(1) is bonded in a 5-coordinate geometry to one O(2), one F(1), one F(2), one F(3), and one F(5) atom. O(2) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF card [CIF]
data_WOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.121
_cell_length_b   11.079
_cell_length_c   16.248
_cell_angle_alpha   63.619
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   825.769
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.575  0.419  0.921  1.0
  W  W1  1  0.075  0.581  0.579  1.0
  W  W2  1  0.516  0.083  0.329  1.0
  W  W3  1  0.016  0.917  0.171  1.0
  W  W4  1  0.984  0.083  0.829  1.0
  W  W5  1  0.484  0.917  0.671  1.0
  W  W6  1  0.925  0.419  0.421  1.0
  W  W7  1  0.425  0.581  0.079  1.0
  O  O8  1  0.699  0.820  0.645  1.0
  O  O9  1  0.288  0.686  0.597  1.0
  O  O10  1  0.788  0.314  0.903  1.0
  O  O11  1  0.199  0.180  0.855  1.0
  O  O12  1  0.801  0.820  0.145  1.0
  O  O13  1  0.212  0.686  0.097  1.0
  O  O14  1  0.712  0.314  0.403  1.0
  O  O15  1  0.301  0.180  0.355  1.0
  F  F16  1  0.744  0.587  0.857  1.0
  F  F17  1  0.708  0.425  0.031  1.0
  F  F18  1  0.826  0.704  0.501  1.0
  F  F19  1  0.764  0.207  0.251  1.0
  F  F20  1  0.338  0.471  0.823  1.0
  F  F21  1  0.838  0.529  0.677  1.0
  F  F22  1  0.766  0.028  0.424  1.0
  F  F23  1  0.326  0.296  0.999  1.0
  F  F24  1  0.363  0.083  0.221  1.0
  F  F25  1  0.244  0.413  0.643  1.0
  F  F26  1  0.371  0.909  0.391  1.0
  F  F27  1  0.871  0.091  0.109  1.0
  F  F28  1  0.792  0.425  0.531  1.0
  F  F29  1  0.863  0.917  0.279  1.0
  F  F30  1  0.736  0.207  0.751  1.0
  F  F31  1  0.266  0.972  0.076  1.0
  F  F32  1  0.734  0.028  0.924  1.0
  F  F33  1  0.264  0.793  0.249  1.0
  F  F34  1  0.137  0.083  0.721  1.0
  F  F35  1  0.208  0.575  0.469  1.0
  F  F36  1  0.129  0.909  0.891  1.0
  F  F37  1  0.629  0.091  0.609  1.0
  F  F38  1  0.756  0.587  0.357  1.0
  F  F39  1  0.637  0.917  0.779  1.0
  F  F40  1  0.674  0.704  0.001  1.0
  F  F41  1  0.234  0.972  0.576  1.0
  F  F42  1  0.162  0.471  0.323  1.0
  F  F43  1  0.662  0.529  0.177  1.0
  F  F44  1  0.236  0.793  0.749  1.0
  F  F45  1  0.174  0.296  0.499  1.0
  F  F46  1  0.292  0.575  0.969  1.0
  F  F47  1  0.256  0.413  0.143  1.0
[/CIF]
.
The structure described by WOF4 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight WOF4 clusters. W(1) is bonded in a 5-coordinate geometry to one O(2), one F(1), one F(2), one F(3), and one F(5) atom. O(2) is bonded in a single-bond geometry to one W(1) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one W(1) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one W(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one W(1) atom. In the fourth F site, F(5) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF card [CIF]
data_WOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.121
_cell_length_b   11.079
_cell_length_c   16.248
_cell_angle_alpha   63.619
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   825.769
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.575  0.419  0.921  1.0
  W  W1  1  0.075  0.581  0.579  1.0
  W  W2  1  0.516  0.083  0.329  1.0
  W  W3  1  0.016  0.917  0.171  1.0
  W  W4  1  0.984  0.083  0.829  1.0
  W  W5  1  0.484  0.917  0.671  1.0
  W  W6  1  0.925  0.419  0.421  1.0
  W  W7  1  0.425  0.581  0.079  1.0
  O  O8  1  0.699  0.820  0.645  1.0
  O  O9  1  0.288  0.686  0.597  1.0
  O  O10  1  0.788  0.314  0.903  1.0
  O  O11  1  0.199  0.180  0.855  1.0
  O  O12  1  0.801  0.820  0.145  1.0
  O  O13  1  0.212  0.686  0.097  1.0
  O  O14  1  0.712  0.314  0.403  1.0
  O  O15  1  0.301  0.180  0.355  1.0
  F  F16  1  0.744  0.587  0.857  1.0
  F  F17  1  0.708  0.425  0.031  1.0
  F  F18  1  0.826  0.704  0.501  1.0
  F  F19  1  0.764  0.207  0.251  1.0
  F  F20  1  0.338  0.471  0.823  1.0
  F  F21  1  0.838  0.529  0.677  1.0
  F  F22  1  0.766  0.028  0.424  1.0
  F  F23  1  0.326  0.296  0.999  1.0
  F  F24  1  0.363  0.083  0.221  1.0
  F  F25  1  0.244  0.413  0.643  1.0
  F  F26  1  0.371  0.909  0.391  1.0
  F  F27  1  0.871  0.091  0.109  1.0
  F  F28  1  0.792  0.425  0.531  1.0
  F  F29  1  0.863  0.917  0.279  1.0
  F  F30  1  0.736  0.207  0.751  1.0
  F  F31  1  0.266  0.972  0.076  1.0
  F  F32  1  0.734  0.028  0.924  1.0
  F  F33  1  0.264  0.793  0.249  1.0
  F  F34  1  0.137  0.083  0.721  1.0
  F  F35  1  0.208  0.575  0.469  1.0
  F  F36  1  0.129  0.909  0.891  1.0
  F  F37  1  0.629  0.091  0.609  1.0
  F  F38  1  0.756  0.587  0.357  1.0
  F  F39  1  0.637  0.917  0.779  1.0
  F  F40  1  0.674  0.704  0.001  1.0
  F  F41  1  0.234  0.972  0.576  1.0
  F  F42  1  0.162  0.471  0.323  1.0
  F  F43  1  0.662  0.529  0.177  1.0
  F  F44  1  0.236  0.793  0.749  1.0
  F  F45  1  0.174  0.296  0.499  1.0
  F  F46  1  0.292  0.575  0.969  1.0
  F  F47  1  0.256  0.413  0.143  1.0
[/CIF]
.