The compound described by Rb2CdC2O5Cl2 crystallizes in the orthorhombic Pbcm space group. Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and four equivalent Cl(1) atoms. Cd(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), and two equivalent Cl(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. There are five inequivalent O sites. In the first O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one Cd(1), and one C(2) atom. In the second O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Cd(1), and one C(2) atom. In the third O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Cd(1), and one C(1) atom. In the fourth O site, O(5) is bonded in an L-shaped geometry to two equivalent Rb(1) atoms. In the fifth O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Cd(1), and one C(1) atom. Cl(1) is bonded in a 5-coordinate geometry to four equivalent Rb(1) and one Cd(1) atom. is represented by the CIF card [CIF]
data_Rb2CdC2Cl2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.117
_cell_length_b   11.051
_cell_length_c   15.827
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1069.848
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.162  0.111  0.614  1.0
  Rb  Rb1  1  0.838  0.889  0.114  1.0
  Rb  Rb2  1  0.162  0.389  0.386  1.0
  Rb  Rb3  1  0.838  0.611  0.886  1.0
  Rb  Rb4  1  0.838  0.889  0.386  1.0
  Rb  Rb5  1  0.162  0.111  0.886  1.0
  Rb  Rb6  1  0.838  0.611  0.614  1.0
  Rb  Rb7  1  0.162  0.389  0.114  1.0
  Cd  Cd8  1  0.649  0.914  0.750  1.0
  Cd  Cd9  1  0.351  0.086  0.250  1.0
  Cd  Cd10  1  0.649  0.586  0.250  1.0
  Cd  Cd11  1  0.351  0.414  0.750  1.0
  C  C12  1  0.311  0.701  0.750  1.0
  C  C13  1  0.689  0.299  0.250  1.0
  C  C14  1  0.311  0.799  0.250  1.0
  C  C15  1  0.689  0.201  0.750  1.0
  C  C16  1  0.172  0.820  0.750  1.0
  C  C17  1  0.828  0.180  0.250  1.0
  C  C18  1  0.172  0.680  0.250  1.0
  C  C19  1  0.828  0.320  0.750  1.0
  Cl  Cl20  1  0.659  0.915  0.915  1.0
  Cl  Cl21  1  0.341  0.085  0.415  1.0
  Cl  Cl22  1  0.659  0.585  0.085  1.0
  Cl  Cl23  1  0.341  0.415  0.585  1.0
  Cl  Cl24  1  0.341  0.085  0.085  1.0
  Cl  Cl25  1  0.659  0.915  0.585  1.0
  Cl  Cl26  1  0.341  0.415  0.915  1.0
  Cl  Cl27  1  0.659  0.585  0.415  1.0
  O  O28  1  0.200  0.604  0.750  1.0
  O  O29  1  0.800  0.396  0.250  1.0
  O  O30  1  0.200  0.896  0.250  1.0
  O  O31  1  0.800  0.104  0.750  1.0
  O  O32  1  0.967  0.803  0.750  1.0
  O  O33  1  0.033  0.197  0.250  1.0
  O  O34  1  0.967  0.697  0.250  1.0
  O  O35  1  0.033  0.303  0.750  1.0
  O  O36  1  0.268  0.922  0.750  1.0
  O  O37  1  0.732  0.078  0.250  1.0
  O  O38  1  0.268  0.578  0.250  1.0
  O  O39  1  0.732  0.422  0.750  1.0
  O  O40  1  0.517  0.709  0.750  1.0
  O  O41  1  0.483  0.291  0.250  1.0
  O  O42  1  0.517  0.791  0.250  1.0
  O  O43  1  0.483  0.209  0.750  1.0
  O  O44  1  0.780  0.250  0.500  1.0
  O  O45  1  0.220  0.750  0.000  1.0
  O  O46  1  0.220  0.750  0.500  1.0
  O  O47  1  0.780  0.250  0.000  1.0
[/CIF]
.
The compound described by Rb2CdC2O5Cl2 crystallizes in the orthorhombic Pbcm space group. Rb(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and four equivalent Cl(1) atoms. Cd(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), and two equivalent Cl(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. There are five inequivalent O sites. In the first O site, O(2) is bonded in a 2-coordinate geometry to two equivalent Rb(1), one Cd(1), and one C(2) atom. In the second O site, O(3) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Cd(1), and one C(2) atom. In the third O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Cd(1), and one C(1) atom. In the fourth O site, O(5) is bonded in an L-shaped geometry to two equivalent Rb(1) atoms. In the fifth O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one Cd(1), and one C(1) atom. Cl(1) is bonded in a 5-coordinate geometry to four equivalent Rb(1) and one Cd(1) atom. is represented by the CIF card [CIF]
data_Rb2CdC2Cl2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.117
_cell_length_b   11.051
_cell_length_c   15.827
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1069.848
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.162  0.111  0.614  1.0
  Rb  Rb1  1  0.838  0.889  0.114  1.0
  Rb  Rb2  1  0.162  0.389  0.386  1.0
  Rb  Rb3  1  0.838  0.611  0.886  1.0
  Rb  Rb4  1  0.838  0.889  0.386  1.0
  Rb  Rb5  1  0.162  0.111  0.886  1.0
  Rb  Rb6  1  0.838  0.611  0.614  1.0
  Rb  Rb7  1  0.162  0.389  0.114  1.0
  Cd  Cd8  1  0.649  0.914  0.750  1.0
  Cd  Cd9  1  0.351  0.086  0.250  1.0
  Cd  Cd10  1  0.649  0.586  0.250  1.0
  Cd  Cd11  1  0.351  0.414  0.750  1.0
  C  C12  1  0.311  0.701  0.750  1.0
  C  C13  1  0.689  0.299  0.250  1.0
  C  C14  1  0.311  0.799  0.250  1.0
  C  C15  1  0.689  0.201  0.750  1.0
  C  C16  1  0.172  0.820  0.750  1.0
  C  C17  1  0.828  0.180  0.250  1.0
  C  C18  1  0.172  0.680  0.250  1.0
  C  C19  1  0.828  0.320  0.750  1.0
  Cl  Cl20  1  0.659  0.915  0.915  1.0
  Cl  Cl21  1  0.341  0.085  0.415  1.0
  Cl  Cl22  1  0.659  0.585  0.085  1.0
  Cl  Cl23  1  0.341  0.415  0.585  1.0
  Cl  Cl24  1  0.341  0.085  0.085  1.0
  Cl  Cl25  1  0.659  0.915  0.585  1.0
  Cl  Cl26  1  0.341  0.415  0.915  1.0
  Cl  Cl27  1  0.659  0.585  0.415  1.0
  O  O28  1  0.200  0.604  0.750  1.0
  O  O29  1  0.800  0.396  0.250  1.0
  O  O30  1  0.200  0.896  0.250  1.0
  O  O31  1  0.800  0.104  0.750  1.0
  O  O32  1  0.967  0.803  0.750  1.0
  O  O33  1  0.033  0.197  0.250  1.0
  O  O34  1  0.967  0.697  0.250  1.0
  O  O35  1  0.033  0.303  0.750  1.0
  O  O36  1  0.268  0.922  0.750  1.0
  O  O37  1  0.732  0.078  0.250  1.0
  O  O38  1  0.268  0.578  0.250  1.0
  O  O39  1  0.732  0.422  0.750  1.0
  O  O40  1  0.517  0.709  0.750  1.0
  O  O41  1  0.483  0.291  0.250  1.0
  O  O42  1  0.517  0.791  0.250  1.0
  O  O43  1  0.483  0.209  0.750  1.0
  O  O44  1  0.780  0.250  0.500  1.0
  O  O45  1  0.220  0.750  0.000  1.0
  O  O46  1  0.220  0.750  0.500  1.0
  O  O47  1  0.780  0.250  0.000  1.0
[/CIF]
.