The crystal structure described by V2Ag6As2O13 crystallizes in the monoclinic C2/c space group. V(1) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(7) atom to form VO5 trigonal bipyramids that share corners with two equivalent As(1)O4 tetrahedra,  a cornercorner with one V(1)O5 trigonal bipyramid, corners with three equivalent Ag(3)O5 trigonal bipyramids, and  an edgeedge with one Ag(3)O5 trigonal bipyramid. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one O(5), one O(6), one O(7), and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(3), one O(6), and one O(7) atom. In the third Ag site, Ag(3) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(6) atom to form distorted AgO5 trigonal bipyramids that share corners with three equivalent As(1)O4 tetrahedra,  a cornercorner with one Ag(3)O5 trigonal bipyramid, corners with three equivalent V(1)O5 trigonal bipyramids, and  an edgeedge with one V(1)O5 trigonal bipyramid. As(1) is bonded to one O(2), one O(3), one O(4), and one O(6) atom to form AsO4 tetrahedra that share corners with two equivalent V(1)O5 trigonal bipyramids and corners with three equivalent Ag(3)O5 trigonal bipyramids. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent V(1) and two equivalent Ag(3) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1), one Ag(3), and one As(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Ag(2), two equivalent Ag(1), and one As(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one V(1), one Ag(3), and one As(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one V(1), one Ag(1), and one Ag(3) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), and one As(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one V(1), one Ag(1), and one Ag(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2Ag6As2O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.999
_cell_length_b   9.999
_cell_length_c   13.206
_cell_angle_alpha   67.685
_cell_angle_beta   67.685
_cell_angle_gamma   31.838
_symmetry_Int_Tables_number   1
_cell_volume   639.947
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.382  0.435  0.775  1.0
  V  V1  1  0.565  0.618  0.725  1.0
  V  V2  1  0.618  0.565  0.225  1.0
  V  V3  1  0.435  0.382  0.275  1.0
  Ag  Ag4  1  0.223  0.188  0.294  1.0
  Ag  Ag5  1  0.812  0.777  0.206  1.0
  Ag  Ag6  1  0.777  0.812  0.706  1.0
  Ag  Ag7  1  0.188  0.223  0.794  1.0
  Ag  Ag8  1  0.194  0.202  0.542  1.0
  Ag  Ag9  1  0.798  0.806  0.958  1.0
  Ag  Ag10  1  0.806  0.798  0.458  1.0
  Ag  Ag11  1  0.202  0.194  0.042  1.0
  Ag  Ag12  1  0.982  0.026  0.611  1.0
  Ag  Ag13  1  0.974  0.018  0.889  1.0
  Ag  Ag14  1  0.018  0.974  0.389  1.0
  Ag  Ag15  1  0.026  0.982  0.111  1.0
  As  As16  1  0.378  0.378  0.044  1.0
  As  As17  1  0.622  0.622  0.456  1.0
  As  As18  1  0.622  0.622  0.956  1.0
  As  As19  1  0.378  0.378  0.544  1.0
  O  O20  1  0.364  0.636  0.250  1.0
  O  O21  1  0.636  0.364  0.750  1.0
  O  O22  1  0.330  0.526  0.121  1.0
  O  O23  1  0.474  0.670  0.379  1.0
  O  O24  1  0.670  0.474  0.879  1.0
  O  O25  1  0.526  0.330  0.621  1.0
  O  O26  1  0.181  0.391  0.111  1.0
  O  O27  1  0.609  0.819  0.389  1.0
  O  O28  1  0.819  0.609  0.889  1.0
  O  O29  1  0.391  0.181  0.611  1.0
  O  O30  1  0.264  0.566  0.919  1.0
  O  O31  1  0.434  0.736  0.581  1.0
  O  O32  1  0.736  0.434  0.081  1.0
  O  O33  1  0.566  0.264  0.419  1.0
  O  O34  1  0.075  0.724  0.744  1.0
  O  O35  1  0.276  0.925  0.756  1.0
  O  O36  1  0.925  0.276  0.256  1.0
  O  O37  1  0.724  0.075  0.244  1.0
  O  O38  1  0.695  0.069  0.029  1.0
  O  O39  1  0.931  0.305  0.471  1.0
  O  O40  1  0.305  0.931  0.971  1.0
  O  O41  1  0.069  0.695  0.529  1.0
  O  O42  1  0.437  0.212  0.837  1.0
  O  O43  1  0.788  0.563  0.663  1.0
  O  O44  1  0.563  0.788  0.163  1.0
  O  O45  1  0.212  0.437  0.337  1.0
[/CIF]
.
The crystal structure described by V2Ag6As2O13 crystallizes in the monoclinic C2/c space group. V(1) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(7) atom to form VO5 trigonal bipyramids that share corners with two equivalent As(1)O4 tetrahedra,  a cornercorner with one V(1)O5 trigonal bipyramid, corners with three equivalent Ag(3)O5 trigonal bipyramids, and  an edgeedge with one Ag(3)O5 trigonal bipyramid. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one O(5), one O(6), one O(7), and two equivalent O(3) atoms. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(3), one O(6), and one O(7) atom. In the third Ag site, Ag(3) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(6) atom to form distorted AgO5 trigonal bipyramids that share corners with three equivalent As(1)O4 tetrahedra,  a cornercorner with one Ag(3)O5 trigonal bipyramid, corners with three equivalent V(1)O5 trigonal bipyramids, and  an edgeedge with one V(1)O5 trigonal bipyramid. As(1) is bonded to one O(2), one O(3), one O(4), and one O(6) atom to form AsO4 tetrahedra that share corners with two equivalent V(1)O5 trigonal bipyramids and corners with three equivalent Ag(3)O5 trigonal bipyramids. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to two equivalent V(1) and two equivalent Ag(3) atoms. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1), one Ag(3), and one As(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Ag(2), two equivalent Ag(1), and one As(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one V(1), one Ag(3), and one As(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one V(1), one Ag(1), and one Ag(3) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), and one As(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one V(1), one Ag(1), and one Ag(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V2Ag6As2O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.999
_cell_length_b   9.999
_cell_length_c   13.206
_cell_angle_alpha   67.685
_cell_angle_beta   67.685
_cell_angle_gamma   31.838
_symmetry_Int_Tables_number   1
_cell_volume   639.947
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.382  0.435  0.775  1.0
  V  V1  1  0.565  0.618  0.725  1.0
  V  V2  1  0.618  0.565  0.225  1.0
  V  V3  1  0.435  0.382  0.275  1.0
  Ag  Ag4  1  0.223  0.188  0.294  1.0
  Ag  Ag5  1  0.812  0.777  0.206  1.0
  Ag  Ag6  1  0.777  0.812  0.706  1.0
  Ag  Ag7  1  0.188  0.223  0.794  1.0
  Ag  Ag8  1  0.194  0.202  0.542  1.0
  Ag  Ag9  1  0.798  0.806  0.958  1.0
  Ag  Ag10  1  0.806  0.798  0.458  1.0
  Ag  Ag11  1  0.202  0.194  0.042  1.0
  Ag  Ag12  1  0.982  0.026  0.611  1.0
  Ag  Ag13  1  0.974  0.018  0.889  1.0
  Ag  Ag14  1  0.018  0.974  0.389  1.0
  Ag  Ag15  1  0.026  0.982  0.111  1.0
  As  As16  1  0.378  0.378  0.044  1.0
  As  As17  1  0.622  0.622  0.456  1.0
  As  As18  1  0.622  0.622  0.956  1.0
  As  As19  1  0.378  0.378  0.544  1.0
  O  O20  1  0.364  0.636  0.250  1.0
  O  O21  1  0.636  0.364  0.750  1.0
  O  O22  1  0.330  0.526  0.121  1.0
  O  O23  1  0.474  0.670  0.379  1.0
  O  O24  1  0.670  0.474  0.879  1.0
  O  O25  1  0.526  0.330  0.621  1.0
  O  O26  1  0.181  0.391  0.111  1.0
  O  O27  1  0.609  0.819  0.389  1.0
  O  O28  1  0.819  0.609  0.889  1.0
  O  O29  1  0.391  0.181  0.611  1.0
  O  O30  1  0.264  0.566  0.919  1.0
  O  O31  1  0.434  0.736  0.581  1.0
  O  O32  1  0.736  0.434  0.081  1.0
  O  O33  1  0.566  0.264  0.419  1.0
  O  O34  1  0.075  0.724  0.744  1.0
  O  O35  1  0.276  0.925  0.756  1.0
  O  O36  1  0.925  0.276  0.256  1.0
  O  O37  1  0.724  0.075  0.244  1.0
  O  O38  1  0.695  0.069  0.029  1.0
  O  O39  1  0.931  0.305  0.471  1.0
  O  O40  1  0.305  0.931  0.971  1.0
  O  O41  1  0.069  0.695  0.529  1.0
  O  O42  1  0.437  0.212  0.837  1.0
  O  O43  1  0.788  0.563  0.663  1.0
  O  O44  1  0.563  0.788  0.163  1.0
  O  O45  1  0.212  0.437  0.337  1.0
[/CIF]
.