The crystal structure described by SnSe2(OCl4)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four SnSe2(OCl4)2 clusters. Sn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent Cl(2), and two equivalent Cl(4) atoms. Se(1) is bonded in a 3-coordinate geometry to one O(1), one Cl(1), and one Cl(3) atom. O(1) is bonded in a bent 120 degrees geometry to one Sn(1) and one Se(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Se(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SnSe2(Cl4O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.844
_cell_length_b   6.844
_cell_length_c   16.848
_cell_angle_alpha   86.035
_cell_angle_beta   86.035
_cell_angle_gamma   89.375
_symmetry_Int_Tables_number   1
_cell_volume   785.329
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.199  0.801  0.750  1.0
  Sn  Sn1  1  0.801  0.199  0.250  1.0
  Se  Se2  1  0.787  0.902  0.866  1.0
  Se  Se3  1  0.098  0.213  0.634  1.0
  Se  Se4  1  0.213  0.098  0.134  1.0
  Se  Se5  1  0.902  0.787  0.366  1.0
  Cl  Cl6  1  0.167  0.695  0.426  1.0
  Cl  Cl7  1  0.833  0.305  0.574  1.0
  Cl  Cl8  1  0.305  0.833  0.074  1.0
  Cl  Cl9  1  0.409  0.089  0.741  1.0
  Cl  Cl10  1  0.911  0.591  0.759  1.0
  Cl  Cl11  1  0.089  0.409  0.241  1.0
  Cl  Cl12  1  0.707  0.819  0.474  1.0
  Cl  Cl13  1  0.642  0.363  0.142  1.0
  Cl  Cl14  1  0.358  0.637  0.858  1.0
  Cl  Cl15  1  0.363  0.642  0.642  1.0
  Cl  Cl16  1  0.695  0.167  0.926  1.0
  Cl  Cl17  1  0.819  0.707  0.975  1.0
  Cl  Cl18  1  0.181  0.293  0.025  1.0
  Cl  Cl19  1  0.637  0.358  0.358  1.0
  Cl  Cl20  1  0.293  0.181  0.525  1.0
  Cl  Cl21  1  0.591  0.911  0.259  1.0
  O  O22  1  0.028  0.982  0.663  1.0
  O  O23  1  0.972  0.018  0.337  1.0
  O  O24  1  0.982  0.028  0.163  1.0
  O  O25  1  0.018  0.972  0.837  1.0
[/CIF]
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The crystal structure described by SnSe2(OCl4)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four SnSe2(OCl4)2 clusters. Sn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent Cl(2), and two equivalent Cl(4) atoms. Se(1) is bonded in a 3-coordinate geometry to one O(1), one Cl(1), and one Cl(3) atom. O(1) is bonded in a bent 120 degrees geometry to one Sn(1) and one Se(1) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Se(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Se(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SnSe2(Cl4O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.844
_cell_length_b   6.844
_cell_length_c   16.848
_cell_angle_alpha   86.035
_cell_angle_beta   86.035
_cell_angle_gamma   89.375
_symmetry_Int_Tables_number   1
_cell_volume   785.329
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.199  0.801  0.750  1.0
  Sn  Sn1  1  0.801  0.199  0.250  1.0
  Se  Se2  1  0.787  0.902  0.866  1.0
  Se  Se3  1  0.098  0.213  0.634  1.0
  Se  Se4  1  0.213  0.098  0.134  1.0
  Se  Se5  1  0.902  0.787  0.366  1.0
  Cl  Cl6  1  0.167  0.695  0.426  1.0
  Cl  Cl7  1  0.833  0.305  0.574  1.0
  Cl  Cl8  1  0.305  0.833  0.074  1.0
  Cl  Cl9  1  0.409  0.089  0.741  1.0
  Cl  Cl10  1  0.911  0.591  0.759  1.0
  Cl  Cl11  1  0.089  0.409  0.241  1.0
  Cl  Cl12  1  0.707  0.819  0.474  1.0
  Cl  Cl13  1  0.642  0.363  0.142  1.0
  Cl  Cl14  1  0.358  0.637  0.858  1.0
  Cl  Cl15  1  0.363  0.642  0.642  1.0
  Cl  Cl16  1  0.695  0.167  0.926  1.0
  Cl  Cl17  1  0.819  0.707  0.975  1.0
  Cl  Cl18  1  0.181  0.293  0.025  1.0
  Cl  Cl19  1  0.637  0.358  0.358  1.0
  Cl  Cl20  1  0.293  0.181  0.525  1.0
  Cl  Cl21  1  0.591  0.911  0.259  1.0
  O  O22  1  0.028  0.982  0.663  1.0
  O  O23  1  0.972  0.018  0.337  1.0
  O  O24  1  0.982  0.028  0.163  1.0
  O  O25  1  0.018  0.972  0.837  1.0
[/CIF]
.