The compound described by La2Rh3Sn5 crystallizes in the monoclinic C2/c space group. La(1) is bonded in a 13-coordinate geometry to three equivalent Rh(1); two equivalent Sn(2); four equivalent Sn(1); and four Sn(3,3) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(2) is bonded in a 6-coordinate geometry to two Sn(3,3) and four equivalent Sn(1) atoms. In the second Rh site, Rh(1) is bonded in a 5-coordinate geometry to three equivalent La(1); one Sn(1); two equivalent Sn(2); and two Sn(3,3) atoms. There are four inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 9-coordinate geometry to four equivalent La(1); one Rh(1); two equivalent Rh(2); and two Sn(3,3) atoms. In the second Sn site, Sn(2) is bonded in a 4-coordinate geometry to four equivalent La(1) and four equivalent Rh(1) atoms. In the third Sn site, Sn(3) is bonded in a 11-coordinate geometry to four equivalent La(1), one Rh(2), two equivalent Rh(1), two equivalent Sn(1), and two equivalent Sn(3) atoms. In the fourth Sn site, Sn(3) is bonded in a 11-coordinate geometry to four equivalent La(1), one Rh(2), two equivalent Rh(1), two equivalent Sn(1), and two equivalent Sn(3) atoms. is represented by the CIF card [CIF]
data_La2Sn5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.056
_cell_length_b   9.062
_cell_length_c   9.059
_cell_angle_alpha   138.297
_cell_angle_beta   105.640
_cell_angle_gamma   89.057
_symmetry_Int_Tables_number   1
_cell_volume   456.032
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.913  0.142  0.770  1.0
  La  La1  1  0.087  0.858  0.230  1.0
  La  La2  1  0.629  0.358  0.271  1.0
  La  La3  1  0.371  0.642  0.729  1.0
  Sn  Sn4  1  0.576  0.911  0.665  1.0
  Sn  Sn5  1  0.247  0.412  0.836  1.0
  Sn  Sn6  1  0.424  0.089  0.335  1.0
  Sn  Sn7  1  0.753  0.588  0.164  1.0
  Sn  Sn8  1  1.000  0.250  0.250  1.0
  Sn  Sn9  1  0.000  0.750  0.750  1.0
  Sn  Sn10  1  0.725  0.974  0.250  1.0
  Sn  Sn11  1  0.276  0.525  0.250  1.0
  Sn  Sn12  1  0.275  0.026  0.750  1.0
  Sn  Sn13  1  0.724  0.475  0.750  1.0
  Rh  Rh14  1  0.248  0.140  0.107  1.0
  Rh  Rh15  1  0.967  0.360  0.608  1.0
  Rh  Rh16  1  0.033  0.640  0.392  1.0
  Rh  Rh17  1  0.752  0.860  0.893  1.0
  Rh  Rh18  1  0.500  0.250  0.750  1.0
  Rh  Rh19  1  0.500  0.750  0.250  1.0
[/CIF]
.
The compound described by La2Rh3Sn5 crystallizes in the monoclinic C2/c space group. La(1) is bonded in a 13-coordinate geometry to three equivalent Rh(1); two equivalent Sn(2); four equivalent Sn(1); and four Sn(3,3) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(2) is bonded in a 6-coordinate geometry to two Sn(3,3) and four equivalent Sn(1) atoms. In the second Rh site, Rh(1) is bonded in a 5-coordinate geometry to three equivalent La(1); one Sn(1); two equivalent Sn(2); and two Sn(3,3) atoms. There are four inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a 9-coordinate geometry to four equivalent La(1); one Rh(1); two equivalent Rh(2); and two Sn(3,3) atoms. In the second Sn site, Sn(2) is bonded in a 4-coordinate geometry to four equivalent La(1) and four equivalent Rh(1) atoms. In the third Sn site, Sn(3) is bonded in a 11-coordinate geometry to four equivalent La(1), one Rh(2), two equivalent Rh(1), two equivalent Sn(1), and two equivalent Sn(3) atoms. In the fourth Sn site, Sn(3) is bonded in a 11-coordinate geometry to four equivalent La(1), one Rh(2), two equivalent Rh(1), two equivalent Sn(1), and two equivalent Sn(3) atoms. is represented by the CIF card [CIF]
data_La2Sn5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.056
_cell_length_b   9.062
_cell_length_c   9.059
_cell_angle_alpha   138.297
_cell_angle_beta   105.640
_cell_angle_gamma   89.057
_symmetry_Int_Tables_number   1
_cell_volume   456.032
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.913  0.142  0.770  1.0
  La  La1  1  0.087  0.858  0.230  1.0
  La  La2  1  0.629  0.358  0.271  1.0
  La  La3  1  0.371  0.642  0.729  1.0
  Sn  Sn4  1  0.576  0.911  0.665  1.0
  Sn  Sn5  1  0.247  0.412  0.836  1.0
  Sn  Sn6  1  0.424  0.089  0.335  1.0
  Sn  Sn7  1  0.753  0.588  0.164  1.0
  Sn  Sn8  1  1.000  0.250  0.250  1.0
  Sn  Sn9  1  0.000  0.750  0.750  1.0
  Sn  Sn10  1  0.725  0.974  0.250  1.0
  Sn  Sn11  1  0.276  0.525  0.250  1.0
  Sn  Sn12  1  0.275  0.026  0.750  1.0
  Sn  Sn13  1  0.724  0.475  0.750  1.0
  Rh  Rh14  1  0.248  0.140  0.107  1.0
  Rh  Rh15  1  0.967  0.360  0.608  1.0
  Rh  Rh16  1  0.033  0.640  0.392  1.0
  Rh  Rh17  1  0.752  0.860  0.893  1.0
  Rh  Rh18  1  0.500  0.250  0.750  1.0
  Rh  Rh19  1  0.500  0.750  0.250  1.0
[/CIF]
.