The structure described by Ag6Mo10O33 crystallizes in the triclinic P-1 space group. There are five inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(14), one O(17), one O(2), one O(5), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(12), one O(16), one O(17), and one O(9) atom. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(13), one O(14), one O(15), and one O(9) atom. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(7), and two equivalent O(6) atoms. In the fifth Mo site, Mo(5) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(8), and two equivalent O(5) atoms. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(13), one O(17), one O(3), and one O(7) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(12), one O(4), and one O(8) atom. In the third Ag site, Ag(3) is bonded in a distorted trigonal bipyramidal geometry to one O(11), one O(15), one O(16), one O(5), and one O(6) atom. There are seventeen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(4), and one Mo(5) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(4), and one Mo(5) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mo(5) and one Ag(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one Mo(4) and one Ag(2) atom. In the fifth O site, O(5) is bonded to one Mo(1), two equivalent Mo(5), and one Ag(3) atom to form a mixture of corner and edge-sharing OAgMo3 tetrahedra. In the sixth O site, O(6) is bonded to one Mo(1), two equivalent Mo(4), and one Ag(3) atom to form a mixture of corner and edge-sharing OAgMo3 tetrahedra. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Mo(4) and one Ag(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Mo(5) and one Ag(2) atom. In the ninth O site, O(9) is bonded in a square co-planar geometry to two equivalent Mo(2) and two equivalent Mo(3) atoms. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Mo(2), one Mo(3), and one Ag(3) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one Mo(2) and one Ag(2) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Mo(3) and one Ag(1) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Mo(1) and one Mo(3) atom. In the fifteenth O site, O(15) is bonded in a 2-coordinate geometry to one Mo(3) and one Ag(3) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Mo(2) and one Ag(3) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Mo(1), one Mo(2), and one Ag(1) atom. is represented by the CIF file [CIF]
data_Ag6Mo10O33
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.688
_cell_length_b   8.481
_cell_length_c   11.552
_cell_angle_alpha   86.850
_cell_angle_beta   78.120
_cell_angle_gamma   76.363
_symmetry_Int_Tables_number   1
_cell_volume   716.366
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.823  0.474  0.235  1.0
  Ag  Ag1  1  0.177  0.526  0.765  1.0
  Ag  Ag2  1  0.267  0.471  0.222  1.0
  Ag  Ag3  1  0.733  0.529  0.778  1.0
  Ag  Ag4  1  0.351  0.998  0.247  1.0
  Ag  Ag5  1  0.649  0.002  0.753  1.0
  Mo  Mo6  1  0.812  0.999  0.319  1.0
  Mo  Mo7  1  0.188  0.001  0.681  1.0
  Mo  Mo8  1  0.713  0.199  0.021  1.0
  Mo  Mo9  1  0.287  0.801  0.979  1.0
  Mo  Mo10  1  0.848  0.807  0.019  1.0
  Mo  Mo11  1  0.152  0.193  0.981  1.0
  Mo  Mo12  1  0.940  0.225  0.501  1.0
  Mo  Mo13  1  0.060  0.775  0.499  1.0
  Mo  Mo14  1  0.558  0.777  0.498  1.0
  Mo  Mo15  1  0.442  0.223  0.502  1.0
  O  O16  1  0.807  0.828  0.476  1.0
  O  O17  1  0.193  0.172  0.524  1.0
  O  O18  1  0.711  0.171  0.479  1.0
  O  O19  1  0.289  0.829  0.521  1.0
  O  O20  1  0.606  0.626  0.393  1.0
  O  O21  1  0.394  0.374  0.607  1.0
  O  O22  1  0.158  0.650  0.377  1.0
  O  O23  1  0.842  0.350  0.623  1.0
  O  O24  1  0.554  0.987  0.379  1.0
  O  O25  1  0.446  0.013  0.621  1.0
  O  O26  1  0.029  0.003  0.381  1.0
  O  O27  1  0.971  0.997  0.619  1.0
  O  O28  1  0.968  0.356  0.379  1.0
  O  O29  1  0.032  0.644  0.621  1.0
  O  O30  1  0.417  0.326  0.369  1.0
  O  O31  1  0.583  0.674  0.631  1.0
  O  O32  1  0.000  0.000  0.000  1.0
  O  O33  1  0.900  0.319  0.004  1.0
  O  O34  1  0.100  0.681  0.996  1.0
  O  O35  1  0.347  0.004  0.923  1.0
  O  O36  1  0.653  0.996  0.077  1.0
  O  O37  1  0.479  0.659  0.909  1.0
  O  O38  1  0.521  0.341  0.091  1.0
  O  O39  1  0.249  0.347  0.906  1.0
  O  O40  1  0.892  0.838  0.220  1.0
  O  O41  1  0.808  0.800  0.874  1.0
  O  O42  1  0.192  0.200  0.126  1.0
  O  O43  1  0.685  0.198  0.875  1.0
  O  O44  1  0.315  0.802  0.125  1.0
  O  O45  1  0.214  0.829  0.775  1.0
  O  O46  1  0.786  0.171  0.225  1.0
  O  O47  1  0.108  0.162  0.780  1.0
  O  O48  1  0.751  0.653  0.094  1.0
[/CIF]
.
The structure described by Ag6Mo10O33 crystallizes in the triclinic P-1 space group. There are five inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(14), one O(17), one O(2), one O(5), and one O(6) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(12), one O(16), one O(17), and one O(9) atom. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(13), one O(14), one O(15), and one O(9) atom. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(4), one O(7), and two equivalent O(6) atoms. In the fifth Mo site, Mo(5) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(8), and two equivalent O(5) atoms. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(13), one O(17), one O(3), and one O(7) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(12), one O(4), and one O(8) atom. In the third Ag site, Ag(3) is bonded in a distorted trigonal bipyramidal geometry to one O(11), one O(15), one O(16), one O(5), and one O(6) atom. There are seventeen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(4), and one Mo(5) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(4), and one Mo(5) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mo(5) and one Ag(1) atom. In the fourth O site, O(4) is bonded in a linear geometry to one Mo(4) and one Ag(2) atom. In the fifth O site, O(5) is bonded to one Mo(1), two equivalent Mo(5), and one Ag(3) atom to form a mixture of corner and edge-sharing OAgMo3 tetrahedra. In the sixth O site, O(6) is bonded to one Mo(1), two equivalent Mo(4), and one Ag(3) atom to form a mixture of corner and edge-sharing OAgMo3 tetrahedra. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Mo(4) and one Ag(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Mo(5) and one Ag(2) atom. In the ninth O site, O(9) is bonded in a square co-planar geometry to two equivalent Mo(2) and two equivalent Mo(3) atoms. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Mo(2), one Mo(3), and one Ag(3) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one Mo(2) and one Ag(2) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Mo(3) and one Ag(1) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Mo(1) and one Mo(3) atom. In the fifteenth O site, O(15) is bonded in a 2-coordinate geometry to one Mo(3) and one Ag(3) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Mo(2) and one Ag(3) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Mo(1), one Mo(2), and one Ag(1) atom. is represented by the CIF file [CIF]
data_Ag6Mo10O33
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.688
_cell_length_b   8.481
_cell_length_c   11.552
_cell_angle_alpha   86.850
_cell_angle_beta   78.120
_cell_angle_gamma   76.363
_symmetry_Int_Tables_number   1
_cell_volume   716.366
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.823  0.474  0.235  1.0
  Ag  Ag1  1  0.177  0.526  0.765  1.0
  Ag  Ag2  1  0.267  0.471  0.222  1.0
  Ag  Ag3  1  0.733  0.529  0.778  1.0
  Ag  Ag4  1  0.351  0.998  0.247  1.0
  Ag  Ag5  1  0.649  0.002  0.753  1.0
  Mo  Mo6  1  0.812  0.999  0.319  1.0
  Mo  Mo7  1  0.188  0.001  0.681  1.0
  Mo  Mo8  1  0.713  0.199  0.021  1.0
  Mo  Mo9  1  0.287  0.801  0.979  1.0
  Mo  Mo10  1  0.848  0.807  0.019  1.0
  Mo  Mo11  1  0.152  0.193  0.981  1.0
  Mo  Mo12  1  0.940  0.225  0.501  1.0
  Mo  Mo13  1  0.060  0.775  0.499  1.0
  Mo  Mo14  1  0.558  0.777  0.498  1.0
  Mo  Mo15  1  0.442  0.223  0.502  1.0
  O  O16  1  0.807  0.828  0.476  1.0
  O  O17  1  0.193  0.172  0.524  1.0
  O  O18  1  0.711  0.171  0.479  1.0
  O  O19  1  0.289  0.829  0.521  1.0
  O  O20  1  0.606  0.626  0.393  1.0
  O  O21  1  0.394  0.374  0.607  1.0
  O  O22  1  0.158  0.650  0.377  1.0
  O  O23  1  0.842  0.350  0.623  1.0
  O  O24  1  0.554  0.987  0.379  1.0
  O  O25  1  0.446  0.013  0.621  1.0
  O  O26  1  0.029  0.003  0.381  1.0
  O  O27  1  0.971  0.997  0.619  1.0
  O  O28  1  0.968  0.356  0.379  1.0
  O  O29  1  0.032  0.644  0.621  1.0
  O  O30  1  0.417  0.326  0.369  1.0
  O  O31  1  0.583  0.674  0.631  1.0
  O  O32  1  0.000  0.000  0.000  1.0
  O  O33  1  0.900  0.319  0.004  1.0
  O  O34  1  0.100  0.681  0.996  1.0
  O  O35  1  0.347  0.004  0.923  1.0
  O  O36  1  0.653  0.996  0.077  1.0
  O  O37  1  0.479  0.659  0.909  1.0
  O  O38  1  0.521  0.341  0.091  1.0
  O  O39  1  0.249  0.347  0.906  1.0
  O  O40  1  0.892  0.838  0.220  1.0
  O  O41  1  0.808  0.800  0.874  1.0
  O  O42  1  0.192  0.200  0.126  1.0
  O  O43  1  0.685  0.198  0.875  1.0
  O  O44  1  0.315  0.802  0.125  1.0
  O  O45  1  0.214  0.829  0.775  1.0
  O  O46  1  0.786  0.171  0.225  1.0
  O  O47  1  0.108  0.162  0.780  1.0
  O  O48  1  0.751  0.653  0.094  1.0
[/CIF]
.