The structure described by NaV3F10 crystallizes in the orthorhombic Fdd2 space group. Na(1) is bonded in a 8-coordinate geometry to two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 1-34°. In the second V site, V(2) is bonded to one F(1), one F(3), one F(4), one F(5), and two equivalent F(2) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 1-36°. There are five inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Na(1) and one V(2) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Na(1) and two equivalent V(2) atoms. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Na(1), one V(1), and one V(2) atom. In the fourth F site, F(4) is bonded in a linear geometry to one V(1) and one V(2) atom. In the fifth F site, F(5) is bonded in a distorted bent 150 degrees geometry to one Na(1), one V(1), and one V(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaV3F10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.360
_cell_length_b   8.822
_cell_length_c   7.639
_cell_angle_alpha   77.635
_cell_angle_beta   56.285
_cell_angle_gamma   46.079
_symmetry_Int_Tables_number   1
_cell_volume   400.928
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.987  0.013  0.013  1.0
  Na  Na1  1  0.237  0.263  0.263  1.0
  V  V2  1  0.505  0.495  0.495  1.0
  V  V3  1  0.755  0.745  0.745  1.0
  V  V4  1  0.258  0.242  0.742  1.0
  V  V5  1  0.758  0.742  0.242  1.0
  V  V6  1  0.508  0.492  0.992  1.0
  V  V7  1  0.008  0.992  0.492  1.0
  F  F8  1  0.146  0.120  0.848  1.0
  F  F9  1  0.886  0.848  0.120  1.0
  F  F10  1  0.402  0.364  0.104  1.0
  F  F11  1  0.130  0.104  0.364  1.0
  F  F12  1  0.808  0.199  0.785  1.0
  F  F13  1  0.208  0.785  0.199  1.0
  F  F14  1  0.465  0.042  0.442  1.0
  F  F15  1  0.051  0.442  0.042  1.0
  F  F16  1  0.844  0.652  0.452  1.0
  F  F17  1  0.051  0.452  0.652  1.0
  F  F18  1  0.798  0.199  0.406  1.0
  F  F19  1  0.598  0.406  0.199  1.0
  F  F20  1  0.627  0.621  0.373  1.0
  F  F21  1  0.380  0.373  0.621  1.0
  F  F22  1  0.877  0.870  0.623  1.0
  F  F23  1  0.629  0.623  0.870  1.0
  F  F24  1  0.466  0.037  0.827  1.0
  F  F25  1  0.670  0.827  0.037  1.0
  F  F26  1  0.423  0.580  0.784  1.0
  F  F27  1  0.213  0.784  0.580  1.0
[/CIF]
.
The structure described by NaV3F10 crystallizes in the orthorhombic Fdd2 space group. Na(1) is bonded in a 8-coordinate geometry to two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(5) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent F(3), two equivalent F(4), and two equivalent F(5) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 1-34°. In the second V site, V(2) is bonded to one F(1), one F(3), one F(4), one F(5), and two equivalent F(2) atoms to form corner-sharing VF6 octahedra. The corner-sharing octahedral tilt angles range from 1-36°. There are five inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to one Na(1) and one V(2) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Na(1) and two equivalent V(2) atoms. In the third F site, F(3) is bonded in a 3-coordinate geometry to one Na(1), one V(1), and one V(2) atom. In the fourth F site, F(4) is bonded in a linear geometry to one V(1) and one V(2) atom. In the fifth F site, F(5) is bonded in a distorted bent 150 degrees geometry to one Na(1), one V(1), and one V(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaV3F10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.360
_cell_length_b   8.822
_cell_length_c   7.639
_cell_angle_alpha   77.635
_cell_angle_beta   56.285
_cell_angle_gamma   46.079
_symmetry_Int_Tables_number   1
_cell_volume   400.928
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.987  0.013  0.013  1.0
  Na  Na1  1  0.237  0.263  0.263  1.0
  V  V2  1  0.505  0.495  0.495  1.0
  V  V3  1  0.755  0.745  0.745  1.0
  V  V4  1  0.258  0.242  0.742  1.0
  V  V5  1  0.758  0.742  0.242  1.0
  V  V6  1  0.508  0.492  0.992  1.0
  V  V7  1  0.008  0.992  0.492  1.0
  F  F8  1  0.146  0.120  0.848  1.0
  F  F9  1  0.886  0.848  0.120  1.0
  F  F10  1  0.402  0.364  0.104  1.0
  F  F11  1  0.130  0.104  0.364  1.0
  F  F12  1  0.808  0.199  0.785  1.0
  F  F13  1  0.208  0.785  0.199  1.0
  F  F14  1  0.465  0.042  0.442  1.0
  F  F15  1  0.051  0.442  0.042  1.0
  F  F16  1  0.844  0.652  0.452  1.0
  F  F17  1  0.051  0.452  0.652  1.0
  F  F18  1  0.798  0.199  0.406  1.0
  F  F19  1  0.598  0.406  0.199  1.0
  F  F20  1  0.627  0.621  0.373  1.0
  F  F21  1  0.380  0.373  0.621  1.0
  F  F22  1  0.877  0.870  0.623  1.0
  F  F23  1  0.629  0.623  0.870  1.0
  F  F24  1  0.466  0.037  0.827  1.0
  F  F25  1  0.670  0.827  0.037  1.0
  F  F26  1  0.423  0.580  0.784  1.0
  F  F27  1  0.213  0.784  0.580  1.0
[/CIF]
.