The structure described by CN5S5O3F is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two CN5S5O3F clusters. C(1) is bonded in a trigonal planar geometry to one N(1), one N(5), and one O(2) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one S(1), and one S(5) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(4) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one S(3) and one S(4) atom. In the fourth N site, N(4) is bonded in a bent 150 degrees geometry to one S(3) and one S(5) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(1) and one S(2) atom. There are five inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one N(5), one O(1), one O(3), and one F(1) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(3) and one N(4) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one N(1) and one N(4) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(2) atom. F(1) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF card [CIF]
data_CS5N5O3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.344
_cell_length_b   8.395
_cell_length_c   8.976
_cell_angle_alpha   96.818
_cell_angle_beta   92.588
_cell_angle_gamma   106.804
_symmetry_Int_Tables_number   1
_cell_volume   524.229
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.894  0.479  0.807  1.0
  C  C1  1  0.106  0.521  0.193  1.0
  S  S2  1  0.912  0.187  0.165  1.0
  S  S3  1  0.088  0.813  0.835  1.0
  S  S4  1  0.662  0.183  0.763  1.0
  S  S5  1  0.492  0.330  0.304  1.0
  S  S6  1  0.508  0.670  0.696  1.0
  S  S7  1  0.868  0.785  0.544  1.0
  S  S8  1  0.132  0.215  0.456  1.0
  S  S9  1  0.256  0.297  0.020  1.0
  S  S10  1  0.744  0.703  0.980  1.0
  S  S11  1  0.338  0.817  0.237  1.0
  N  N12  1  0.088  0.349  0.119  1.0
  N  N13  1  0.034  0.846  0.671  1.0
  N  N14  1  0.665  0.672  0.580  1.0
  N  N15  1  0.335  0.328  0.420  1.0
  N  N16  1  0.432  0.300  0.131  1.0
  N  N17  1  0.966  0.154  0.329  1.0
  N  N18  1  0.720  0.377  0.825  1.0
  N  N19  1  0.568  0.700  0.869  1.0
  N  N20  1  0.280  0.623  0.175  1.0
  N  N21  1  0.912  0.651  0.881  1.0
  O  O22  1  0.797  0.096  0.804  1.0
  O  O23  1  0.968  0.539  0.258  1.0
  O  O24  1  0.032  0.461  0.742  1.0
  O  O25  1  0.536  0.891  0.220  1.0
  O  O26  1  0.203  0.904  0.196  1.0
  O  O27  1  0.464  0.109  0.780  1.0
  F  F28  1  0.327  0.819  0.419  1.0
  F  F29  1  0.673  0.181  0.581  1.0
[/CIF]
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The structure described by CN5S5O3F is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two CN5S5O3F clusters. C(1) is bonded in a trigonal planar geometry to one N(1), one N(5), and one O(2) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one S(1), and one S(5) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(4) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one S(3) and one S(4) atom. In the fourth N site, N(4) is bonded in a bent 150 degrees geometry to one S(3) and one S(5) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(1) and one S(2) atom. There are five inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one N(5), one O(1), one O(3), and one F(1) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one N(3) and one N(4) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one N(1) and one N(4) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(2) atom. F(1) is bonded in a single-bond geometry to one S(2) atom. is represented by the CIF card [CIF]
data_CS5N5O3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.344
_cell_length_b   8.395
_cell_length_c   8.976
_cell_angle_alpha   96.818
_cell_angle_beta   92.588
_cell_angle_gamma   106.804
_symmetry_Int_Tables_number   1
_cell_volume   524.229
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.894  0.479  0.807  1.0
  C  C1  1  0.106  0.521  0.193  1.0
  S  S2  1  0.912  0.187  0.165  1.0
  S  S3  1  0.088  0.813  0.835  1.0
  S  S4  1  0.662  0.183  0.763  1.0
  S  S5  1  0.492  0.330  0.304  1.0
  S  S6  1  0.508  0.670  0.696  1.0
  S  S7  1  0.868  0.785  0.544  1.0
  S  S8  1  0.132  0.215  0.456  1.0
  S  S9  1  0.256  0.297  0.020  1.0
  S  S10  1  0.744  0.703  0.980  1.0
  S  S11  1  0.338  0.817  0.237  1.0
  N  N12  1  0.088  0.349  0.119  1.0
  N  N13  1  0.034  0.846  0.671  1.0
  N  N14  1  0.665  0.672  0.580  1.0
  N  N15  1  0.335  0.328  0.420  1.0
  N  N16  1  0.432  0.300  0.131  1.0
  N  N17  1  0.966  0.154  0.329  1.0
  N  N18  1  0.720  0.377  0.825  1.0
  N  N19  1  0.568  0.700  0.869  1.0
  N  N20  1  0.280  0.623  0.175  1.0
  N  N21  1  0.912  0.651  0.881  1.0
  O  O22  1  0.797  0.096  0.804  1.0
  O  O23  1  0.968  0.539  0.258  1.0
  O  O24  1  0.032  0.461  0.742  1.0
  O  O25  1  0.536  0.891  0.220  1.0
  O  O26  1  0.203  0.904  0.196  1.0
  O  O27  1  0.464  0.109  0.780  1.0
  F  F28  1  0.327  0.819  0.419  1.0
  F  F29  1  0.673  0.181  0.581  1.0
[/CIF]
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