The crystal structure described by CsRuF6 crystallizes in the trigonal R-3m space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form CsF12 cuboctahedra that share corners with six equivalent Ru(1)F6 octahedra, edges with six equivalent Cs(1)F12 cuboctahedra, and faces with two equivalent Ru(1)F6 octahedra. The corner-sharing octahedral tilt angles are 32°. Ru(1) is bonded to six equivalent F(1) atoms to form RuF6 octahedra that share corners with six equivalent Cs(1)F12 cuboctahedra and faces with two equivalent Cs(1)F12 cuboctahedra. F(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Ru(1) atom. is represented by the CIF card [CIF]
data_CsRuF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.303
_cell_length_b   5.303
_cell_length_c   5.303
_cell_angle_alpha   97.396
_cell_angle_beta   97.396
_cell_angle_gamma   97.396
_symmetry_Int_Tables_number   1
_cell_volume   145.037
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.500  0.500  0.500  1.0
  Ru  Ru1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.249  0.249  0.919  1.0
  F  F3  1  0.249  0.919  0.249  1.0
  F  F4  1  0.751  0.081  0.751  1.0
  F  F5  1  0.751  0.751  0.081  1.0
  F  F6  1  0.081  0.751  0.751  1.0
  F  F7  1  0.919  0.249  0.249  1.0
[/CIF]
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The crystal structure described by CsRuF6 crystallizes in the trigonal R-3m space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form CsF12 cuboctahedra that share corners with six equivalent Ru(1)F6 octahedra, edges with six equivalent Cs(1)F12 cuboctahedra, and faces with two equivalent Ru(1)F6 octahedra. The corner-sharing octahedral tilt angles are 32°. Ru(1) is bonded to six equivalent F(1) atoms to form RuF6 octahedra that share corners with six equivalent Cs(1)F12 cuboctahedra and faces with two equivalent Cs(1)F12 cuboctahedra. F(1) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Ru(1) atom. is represented by the CIF card [CIF]
data_CsRuF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.303
_cell_length_b   5.303
_cell_length_c   5.303
_cell_angle_alpha   97.396
_cell_angle_beta   97.396
_cell_angle_gamma   97.396
_symmetry_Int_Tables_number   1
_cell_volume   145.037
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.500  0.500  0.500  1.0
  Ru  Ru1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.249  0.249  0.919  1.0
  F  F3  1  0.249  0.919  0.249  1.0
  F  F4  1  0.751  0.081  0.751  1.0
  F  F5  1  0.751  0.751  0.081  1.0
  F  F6  1  0.081  0.751  0.751  1.0
  F  F7  1  0.919  0.249  0.249  1.0
[/CIF]
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