The crystal structure described by XeBiF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeBiF7 clusters. Xe(1) is bonded in a linear geometry to one F(1) and one F(3) atom. Bi(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(4), one F(5), one F(6), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Bi(1) atom. In the second F site, F(1) is bonded in a bent 150 degrees geometry to one Xe(1) and one Bi(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Bi(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Bi(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Bi(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiXeF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.901
_cell_length_b   5.143
_cell_length_c   12.530
_cell_angle_alpha   88.823
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   637.869
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.017  0.611  0.720  1.0
  Bi  Bi1  1  0.517  0.389  0.780  1.0
  Bi  Bi2  1  0.983  0.389  0.280  1.0
  Bi  Bi3  1  0.483  0.611  0.220  1.0
  Xe  Xe4  1  0.734  0.009  0.522  1.0
  Xe  Xe5  1  0.234  0.991  0.978  1.0
  Xe  Xe6  1  0.266  0.991  0.478  1.0
  Xe  Xe7  1  0.766  0.009  0.022  1.0
  F  F8  1  0.908  0.791  0.588  1.0
  F  F9  1  0.408  0.209  0.912  1.0
  F  F10  1  0.092  0.209  0.412  1.0
  F  F11  1  0.592  0.791  0.088  1.0
  F  F12  1  0.124  0.943  0.721  1.0
  F  F13  1  0.624  0.057  0.779  1.0
  F  F14  1  0.876  0.057  0.279  1.0
  F  F15  1  0.376  0.943  0.221  1.0
  F  F16  1  0.584  0.213  0.458  1.0
  F  F17  1  0.084  0.787  0.042  1.0
  F  F18  1  0.416  0.787  0.542  1.0
  F  F19  1  0.916  0.213  0.958  1.0
  F  F20  1  0.136  0.488  0.602  1.0
  F  F21  1  0.636  0.512  0.898  1.0
  F  F22  1  0.864  0.512  0.398  1.0
  F  F23  1  0.364  0.488  0.102  1.0
  F  F24  1  0.128  0.461  0.840  1.0
  F  F25  1  0.628  0.539  0.660  1.0
  F  F26  1  0.872  0.539  0.160  1.0
  F  F27  1  0.372  0.461  0.340  1.0
  F  F28  1  0.880  0.767  0.817  1.0
  F  F29  1  0.380  0.233  0.683  1.0
  F  F30  1  0.120  0.233  0.183  1.0
  F  F31  1  0.620  0.767  0.317  1.0
  F  F32  1  0.897  0.302  0.701  1.0
  F  F33  1  0.397  0.698  0.799  1.0
  F  F34  1  0.103  0.698  0.299  1.0
  F  F35  1  0.603  0.302  0.201  1.0
[/CIF]
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The crystal structure described by XeBiF7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeBiF7 clusters. Xe(1) is bonded in a linear geometry to one F(1) and one F(3) atom. Bi(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(4), one F(5), one F(6), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Bi(1) atom. In the second F site, F(1) is bonded in a bent 150 degrees geometry to one Xe(1) and one Bi(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one Bi(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Bi(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Bi(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one Bi(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiXeF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.901
_cell_length_b   5.143
_cell_length_c   12.530
_cell_angle_alpha   88.823
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   637.869
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.017  0.611  0.720  1.0
  Bi  Bi1  1  0.517  0.389  0.780  1.0
  Bi  Bi2  1  0.983  0.389  0.280  1.0
  Bi  Bi3  1  0.483  0.611  0.220  1.0
  Xe  Xe4  1  0.734  0.009  0.522  1.0
  Xe  Xe5  1  0.234  0.991  0.978  1.0
  Xe  Xe6  1  0.266  0.991  0.478  1.0
  Xe  Xe7  1  0.766  0.009  0.022  1.0
  F  F8  1  0.908  0.791  0.588  1.0
  F  F9  1  0.408  0.209  0.912  1.0
  F  F10  1  0.092  0.209  0.412  1.0
  F  F11  1  0.592  0.791  0.088  1.0
  F  F12  1  0.124  0.943  0.721  1.0
  F  F13  1  0.624  0.057  0.779  1.0
  F  F14  1  0.876  0.057  0.279  1.0
  F  F15  1  0.376  0.943  0.221  1.0
  F  F16  1  0.584  0.213  0.458  1.0
  F  F17  1  0.084  0.787  0.042  1.0
  F  F18  1  0.416  0.787  0.542  1.0
  F  F19  1  0.916  0.213  0.958  1.0
  F  F20  1  0.136  0.488  0.602  1.0
  F  F21  1  0.636  0.512  0.898  1.0
  F  F22  1  0.864  0.512  0.398  1.0
  F  F23  1  0.364  0.488  0.102  1.0
  F  F24  1  0.128  0.461  0.840  1.0
  F  F25  1  0.628  0.539  0.660  1.0
  F  F26  1  0.872  0.539  0.160  1.0
  F  F27  1  0.372  0.461  0.340  1.0
  F  F28  1  0.880  0.767  0.817  1.0
  F  F29  1  0.380  0.233  0.683  1.0
  F  F30  1  0.120  0.233  0.183  1.0
  F  F31  1  0.620  0.767  0.317  1.0
  F  F32  1  0.897  0.302  0.701  1.0
  F  F33  1  0.397  0.698  0.799  1.0
  F  F34  1  0.103  0.698  0.299  1.0
  F  F35  1  0.603  0.302  0.201  1.0
[/CIF]
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