The structure described by K2LiC3(NS)3 crystallizes in the orthorhombic Pna2_1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one N(1), one N(2), one N(3), one S(2), two equivalent S(1), and two equivalent S(3) atoms. In the second K site, K(2) is bonded in a 8-coordinate geometry to one N(1), one N(2), one N(3), one S(2), two equivalent S(1), and two equivalent S(3) atoms. Li(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(2), one N(3), and one S(2) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(2) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one N(3) and one S(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one K(1), one K(2), one Li(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one K(1), one K(2), one Li(1), and one C(2) atom. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one K(1), one K(2), one Li(1), and one C(3) atom. There are three inequivalent S sites. In the first S site, S(3) is bonded in a 5-coordinate geometry to two equivalent K(1), two equivalent K(2), and one C(3) atom. In the second S site, S(1) is bonded in a 5-coordinate geometry to two equivalent K(1), two equivalent K(2), and one C(1) atom. In the third S site, S(2) is bonded in a distorted trigonal pyramidal geometry to one K(1), one K(2), one Li(1), and one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2LiC3(SN)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.726
_cell_length_b   9.664
_cell_length_c   12.393
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1045.052
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.032  0.870  0.676  1.0
  K  K1  1  0.532  0.130  0.324  1.0
  K  K2  1  0.532  0.370  0.824  1.0
  K  K3  1  0.032  0.630  0.176  1.0
  K  K4  1  0.531  0.882  0.670  1.0
  K  K5  1  0.031  0.118  0.330  1.0
  K  K6  1  0.031  0.382  0.830  1.0
  K  K7  1  0.531  0.618  0.170  1.0
  Li  Li8  1  0.890  0.535  0.582  1.0
  Li  Li9  1  0.390  0.465  0.418  1.0
  Li  Li10  1  0.390  0.035  0.918  1.0
  Li  Li11  1  0.890  0.965  0.082  1.0
  C  C12  1  0.779  0.769  0.453  1.0
  C  C13  1  0.279  0.231  0.547  1.0
  C  C14  1  0.279  0.269  0.047  1.0
  C  C15  1  0.779  0.731  0.953  1.0
  C  C16  1  0.239  0.566  0.632  1.0
  C  C17  1  0.739  0.434  0.368  1.0
  C  C18  1  0.739  0.066  0.868  1.0
  C  C19  1  0.239  0.934  0.132  1.0
  C  C20  1  0.286  0.750  0.888  1.0
  C  C21  1  0.786  0.250  0.112  1.0
  C  C22  1  0.786  0.250  0.612  1.0
  C  C23  1  0.286  0.750  0.388  1.0
  S  S24  1  0.262  0.169  0.669  1.0
  S  S25  1  0.762  0.831  0.331  1.0
  S  S26  1  0.762  0.669  0.831  1.0
  S  S27  1  0.262  0.331  0.169  1.0
  S  S28  1  0.924  0.063  0.883  1.0
  S  S29  1  0.424  0.937  0.117  1.0
  S  S30  1  0.424  0.563  0.617  1.0
  S  S31  1  0.924  0.437  0.383  1.0
  S  S32  1  0.776  0.102  0.549  1.0
  S  S33  1  0.276  0.898  0.451  1.0
  S  S34  1  0.276  0.602  0.951  1.0
  S  S35  1  0.776  0.398  0.049  1.0
  N  N36  1  0.792  0.724  0.542  1.0
  N  N37  1  0.292  0.276  0.458  1.0
  N  N38  1  0.292  0.224  0.958  1.0
  N  N39  1  0.792  0.776  0.042  1.0
  N  N40  1  0.103  0.568  0.642  1.0
  N  N41  1  0.603  0.432  0.358  1.0
  N  N42  1  0.603  0.068  0.858  1.0
  N  N43  1  0.103  0.932  0.142  1.0
  N  N44  1  0.295  0.858  0.843  1.0
  N  N45  1  0.795  0.142  0.157  1.0
  N  N46  1  0.795  0.358  0.657  1.0
  N  N47  1  0.295  0.642  0.343  1.0
[/CIF]
.
The structure described by K2LiC3(NS)3 crystallizes in the orthorhombic Pna2_1 space group. There are two inequivalent K sites. In the first K site, K(1) is bonded in a 8-coordinate geometry to one N(1), one N(2), one N(3), one S(2), two equivalent S(1), and two equivalent S(3) atoms. In the second K site, K(2) is bonded in a 8-coordinate geometry to one N(1), one N(2), one N(3), one S(2), two equivalent S(1), and two equivalent S(3) atoms. Li(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(2), one N(3), and one S(2) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one N(2) and one S(2) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one N(3) and one S(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one K(1), one K(2), one Li(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one K(1), one K(2), one Li(1), and one C(2) atom. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one K(1), one K(2), one Li(1), and one C(3) atom. There are three inequivalent S sites. In the first S site, S(3) is bonded in a 5-coordinate geometry to two equivalent K(1), two equivalent K(2), and one C(3) atom. In the second S site, S(1) is bonded in a 5-coordinate geometry to two equivalent K(1), two equivalent K(2), and one C(1) atom. In the third S site, S(2) is bonded in a distorted trigonal pyramidal geometry to one K(1), one K(2), one Li(1), and one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2LiC3(SN)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.726
_cell_length_b   9.664
_cell_length_c   12.393
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1045.052
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.032  0.870  0.676  1.0
  K  K1  1  0.532  0.130  0.324  1.0
  K  K2  1  0.532  0.370  0.824  1.0
  K  K3  1  0.032  0.630  0.176  1.0
  K  K4  1  0.531  0.882  0.670  1.0
  K  K5  1  0.031  0.118  0.330  1.0
  K  K6  1  0.031  0.382  0.830  1.0
  K  K7  1  0.531  0.618  0.170  1.0
  Li  Li8  1  0.890  0.535  0.582  1.0
  Li  Li9  1  0.390  0.465  0.418  1.0
  Li  Li10  1  0.390  0.035  0.918  1.0
  Li  Li11  1  0.890  0.965  0.082  1.0
  C  C12  1  0.779  0.769  0.453  1.0
  C  C13  1  0.279  0.231  0.547  1.0
  C  C14  1  0.279  0.269  0.047  1.0
  C  C15  1  0.779  0.731  0.953  1.0
  C  C16  1  0.239  0.566  0.632  1.0
  C  C17  1  0.739  0.434  0.368  1.0
  C  C18  1  0.739  0.066  0.868  1.0
  C  C19  1  0.239  0.934  0.132  1.0
  C  C20  1  0.286  0.750  0.888  1.0
  C  C21  1  0.786  0.250  0.112  1.0
  C  C22  1  0.786  0.250  0.612  1.0
  C  C23  1  0.286  0.750  0.388  1.0
  S  S24  1  0.262  0.169  0.669  1.0
  S  S25  1  0.762  0.831  0.331  1.0
  S  S26  1  0.762  0.669  0.831  1.0
  S  S27  1  0.262  0.331  0.169  1.0
  S  S28  1  0.924  0.063  0.883  1.0
  S  S29  1  0.424  0.937  0.117  1.0
  S  S30  1  0.424  0.563  0.617  1.0
  S  S31  1  0.924  0.437  0.383  1.0
  S  S32  1  0.776  0.102  0.549  1.0
  S  S33  1  0.276  0.898  0.451  1.0
  S  S34  1  0.276  0.602  0.951  1.0
  S  S35  1  0.776  0.398  0.049  1.0
  N  N36  1  0.792  0.724  0.542  1.0
  N  N37  1  0.292  0.276  0.458  1.0
  N  N38  1  0.292  0.224  0.958  1.0
  N  N39  1  0.792  0.776  0.042  1.0
  N  N40  1  0.103  0.568  0.642  1.0
  N  N41  1  0.603  0.432  0.358  1.0
  N  N42  1  0.603  0.068  0.858  1.0
  N  N43  1  0.103  0.932  0.142  1.0
  N  N44  1  0.295  0.858  0.843  1.0
  N  N45  1  0.795  0.142  0.157  1.0
  N  N46  1  0.795  0.358  0.657  1.0
  N  N47  1  0.295  0.642  0.343  1.0
[/CIF]
.