The material described by Mn5SnO8 is Spinel-like structured and crystallizes in the triclinic P1 space group. There are ten inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(14), one O(15), and one O(9) atom to form corner-sharing MnO4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-63°. In the second Mn site, Mn(2) is bonded to one O(11), one O(14), one O(16), one O(2), one O(6), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Mn(6)O4 tetrahedra,  a cornercorner with one Sn(2)O4 tetrahedra, corners with two equivalent Mn(1)O4 tetrahedra, corners with two equivalent Sn(1)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. In the third Mn site, Mn(3) is bonded to one O(14), one O(16), one O(4), one O(6), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Mn(6)O4 tetrahedra,  a cornercorner with one Sn(2)O4 tetrahedra, corners with two equivalent Mn(1)O4 tetrahedra, corners with two equivalent Sn(1)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. In the fourth Mn site, Mn(4) is bonded to one O(11), one O(16), one O(2), one O(4), one O(6), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Mn(6)O4 tetrahedra,  a cornercorner with one Sn(2)O4 tetrahedra, corners with two equivalent Mn(1)O4 tetrahedra, corners with two equivalent Sn(1)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(10), one O(12), one O(15), one O(3), and one O(5) atom to form MnO6 octahedra that share  a cornercorner with one Mn(1)O4 tetrahedra,  a cornercorner with one Sn(1)O4 tetrahedra, corners with two equivalent Mn(6)O4 tetrahedra, corners with two equivalent Sn(2)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Mn(7)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. In the sixth Mn site, Mn(6) is bonded to one O(10), one O(12), one O(13), and one O(16) atom to form corner-sharing MnO4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-64°. In the seventh Mn site, Mn(7) is bonded to one O(1), one O(12), one O(13), one O(15), one O(5), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Mn(1)O4 tetrahedra,  a cornercorner with one Sn(1)O4 tetrahedra, corners with two equivalent Mn(6)O4 tetrahedra, corners with two equivalent Sn(2)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. In the eighth Mn site, Mn(8) is bonded to one O(10), one O(13), one O(15), one O(3), one O(5), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Mn(1)O4 tetrahedra,  a cornercorner with one Sn(1)O4 tetrahedra, corners with two equivalent Mn(6)O4 tetrahedra, corners with two equivalent Sn(2)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Mn(7)O6 octahedra. In the ninth Mn site, Mn(9) is bonded to one O(1), one O(11), one O(14), one O(3), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with three equivalent Mn(1)O4 tetrahedra, corners with three equivalent Sn(2)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. In the tenth Mn site, Mn(10) is bonded to one O(10), one O(12), one O(13), one O(2), one O(4), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent Mn(6)O4 tetrahedra, corners with three equivalent Sn(1)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(2), one O(4), one O(5), and one O(8) atom to form SnO4 tetrahedra that share  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, and corners with three equivalent Mn(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-63°. In the second Sn site, Sn(2) is bonded to one O(1), one O(3), one O(6), and one O(7) atom to form SnO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra, corners with two equivalent Mn(7)O6 octahedra, corners with two equivalent Mn(8)O6 octahedra, and corners with three equivalent Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-61°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Mn(5), one Mn(7), one Mn(9), and one Sn(2) atom. In the second O site, O(2) is bonded in a distorted trigonal pyramidal geometry to one Mn(10), one Mn(2), one Mn(4), and one Sn(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Mn(5), one Mn(8), one Mn(9), and one Sn(2) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Mn(10), one Mn(3), one Mn(4), and one Sn(1) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Mn(5), one Mn(7), one Mn(8), and one Sn(1) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Mn(2), one Mn(3), one Mn(4), and one Sn(2) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Mn(7), one Mn(8), one Mn(9), and one Sn(2) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Mn(10), one Mn(2), one Mn(3), and one Sn(1) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Mn(1), one Mn(3), one Mn(4), and one Mn(9) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Mn(10), one Mn(5), one Mn(6), and one Mn(8) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Mn(1), one Mn(2), one Mn(4), and one Mn(9) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Mn(10), one Mn(5), one Mn(6), and one Mn(7) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Mn(10), one Mn(6), one Mn(7), and one Mn(8) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Mn(1), one Mn(2), one Mn(3), and one Mn(9) atom. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one Mn(1), one Mn(5), one Mn(7), and one Mn(8) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Mn(2), one Mn(3), one Mn(4), and one Mn(6) atom. is represented by the CIF card [CIF]
data_Mn5SnO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.164
_cell_length_b   10.671
_cell_length_c   6.296
_cell_angle_alpha   87.828
_cell_angle_beta   61.375
_cell_angle_gamma   73.617
_symmetry_Int_Tables_number   1
_cell_volume   346.408
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.242  0.626  0.870  1.0
  Mn  Mn1  1  0.624  0.811  0.428  1.0
  Mn  Mn2  1  0.141  0.809  0.418  1.0
  Mn  Mn3  1  0.624  0.813  0.942  1.0
  Mn  Mn4  1  0.622  0.311  0.451  1.0
  Mn  Mn5  1  0.235  0.124  0.385  1.0
  Mn  Mn6  1  0.615  0.313  0.942  1.0
  Mn  Mn7  1  0.134  0.311  0.937  1.0
  Mn  Mn8  1  0.624  0.569  0.189  1.0
  Mn  Mn9  1  0.620  0.067  0.696  1.0
  Sn  Sn10  1  0.015  0.001  0.997  1.0
  Sn  Sn11  1  0.015  0.500  0.502  1.0
  O  O12  1  0.398  0.432  0.298  1.0
  O  O13  1  0.412  0.933  0.800  1.0
  O  O14  1  0.866  0.440  0.321  1.0
  O  O15  1  0.845  0.942  0.823  1.0
  O  O16  1  0.887  0.198  0.062  1.0
  O  O17  1  0.893  0.700  0.547  1.0
  O  O18  1  0.890  0.428  0.829  1.0
  O  O19  1  0.890  0.929  0.323  1.0
  O  O20  1  0.401  0.699  0.043  1.0
  O  O21  1  0.395  0.175  0.579  1.0
  O  O22  1  0.842  0.705  0.061  1.0
  O  O23  1  0.837  0.181  0.598  1.0
  O  O24  1  0.355  0.194  0.048  1.0
  O  O25  1  0.358  0.698  0.535  1.0
  O  O26  1  0.358  0.422  0.816  1.0
  O  O27  1  0.362  0.922  0.310  1.0
[/CIF]
.
The material described by Mn5SnO8 is Spinel-like structured and crystallizes in the triclinic P1 space group. There are ten inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(11), one O(14), one O(15), and one O(9) atom to form corner-sharing MnO4 tetrahedra. The corner-sharing octahedral tilt angles range from 48-63°. In the second Mn site, Mn(2) is bonded to one O(11), one O(14), one O(16), one O(2), one O(6), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Mn(6)O4 tetrahedra,  a cornercorner with one Sn(2)O4 tetrahedra, corners with two equivalent Mn(1)O4 tetrahedra, corners with two equivalent Sn(1)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. In the third Mn site, Mn(3) is bonded to one O(14), one O(16), one O(4), one O(6), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Mn(6)O4 tetrahedra,  a cornercorner with one Sn(2)O4 tetrahedra, corners with two equivalent Mn(1)O4 tetrahedra, corners with two equivalent Sn(1)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(4)O6 octahedra. In the fourth Mn site, Mn(4) is bonded to one O(11), one O(16), one O(2), one O(4), one O(6), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Mn(6)O4 tetrahedra,  a cornercorner with one Sn(2)O4 tetrahedra, corners with two equivalent Mn(1)O4 tetrahedra, corners with two equivalent Sn(1)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. In the fifth Mn site, Mn(5) is bonded to one O(1), one O(10), one O(12), one O(15), one O(3), and one O(5) atom to form MnO6 octahedra that share  a cornercorner with one Mn(1)O4 tetrahedra,  a cornercorner with one Sn(1)O4 tetrahedra, corners with two equivalent Mn(6)O4 tetrahedra, corners with two equivalent Sn(2)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Mn(7)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. In the sixth Mn site, Mn(6) is bonded to one O(10), one O(12), one O(13), and one O(16) atom to form corner-sharing MnO4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-64°. In the seventh Mn site, Mn(7) is bonded to one O(1), one O(12), one O(13), one O(15), one O(5), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Mn(1)O4 tetrahedra,  a cornercorner with one Sn(1)O4 tetrahedra, corners with two equivalent Mn(6)O4 tetrahedra, corners with two equivalent Sn(2)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. In the eighth Mn site, Mn(8) is bonded to one O(10), one O(13), one O(15), one O(3), one O(5), and one O(7) atom to form MnO6 octahedra that share  a cornercorner with one Mn(1)O4 tetrahedra,  a cornercorner with one Sn(1)O4 tetrahedra, corners with two equivalent Mn(6)O4 tetrahedra, corners with two equivalent Sn(2)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(9)O6 octahedra, edges with two equivalent Mn(5)O6 octahedra, and edges with two equivalent Mn(7)O6 octahedra. In the ninth Mn site, Mn(9) is bonded to one O(1), one O(11), one O(14), one O(3), one O(7), and one O(9) atom to form MnO6 octahedra that share corners with three equivalent Mn(1)O4 tetrahedra, corners with three equivalent Sn(2)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. In the tenth Mn site, Mn(10) is bonded to one O(10), one O(12), one O(13), one O(2), one O(4), and one O(8) atom to form MnO6 octahedra that share corners with three equivalent Mn(6)O4 tetrahedra, corners with three equivalent Sn(1)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra, and  an edgeedge with one Mn(8)O6 octahedra. There are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one O(2), one O(4), one O(5), and one O(8) atom to form SnO4 tetrahedra that share  a cornercorner with one Mn(5)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, and corners with three equivalent Mn(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-63°. In the second Sn site, Sn(2) is bonded to one O(1), one O(3), one O(6), and one O(7) atom to form SnO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra,  a cornercorner with one Mn(4)O6 octahedra, corners with two equivalent Mn(5)O6 octahedra, corners with two equivalent Mn(7)O6 octahedra, corners with two equivalent Mn(8)O6 octahedra, and corners with three equivalent Mn(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-61°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Mn(5), one Mn(7), one Mn(9), and one Sn(2) atom. In the second O site, O(2) is bonded in a distorted trigonal pyramidal geometry to one Mn(10), one Mn(2), one Mn(4), and one Sn(1) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Mn(5), one Mn(8), one Mn(9), and one Sn(2) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Mn(10), one Mn(3), one Mn(4), and one Sn(1) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Mn(5), one Mn(7), one Mn(8), and one Sn(1) atom. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Mn(2), one Mn(3), one Mn(4), and one Sn(2) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Mn(7), one Mn(8), one Mn(9), and one Sn(2) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Mn(10), one Mn(2), one Mn(3), and one Sn(1) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Mn(1), one Mn(3), one Mn(4), and one Mn(9) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Mn(10), one Mn(5), one Mn(6), and one Mn(8) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Mn(1), one Mn(2), one Mn(4), and one Mn(9) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Mn(10), one Mn(5), one Mn(6), and one Mn(7) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Mn(10), one Mn(6), one Mn(7), and one Mn(8) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Mn(1), one Mn(2), one Mn(3), and one Mn(9) atom. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one Mn(1), one Mn(5), one Mn(7), and one Mn(8) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Mn(2), one Mn(3), one Mn(4), and one Mn(6) atom. is represented by the CIF card [CIF]
data_Mn5SnO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.164
_cell_length_b   10.671
_cell_length_c   6.296
_cell_angle_alpha   87.828
_cell_angle_beta   61.375
_cell_angle_gamma   73.617
_symmetry_Int_Tables_number   1
_cell_volume   346.408
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.242  0.626  0.870  1.0
  Mn  Mn1  1  0.624  0.811  0.428  1.0
  Mn  Mn2  1  0.141  0.809  0.418  1.0
  Mn  Mn3  1  0.624  0.813  0.942  1.0
  Mn  Mn4  1  0.622  0.311  0.451  1.0
  Mn  Mn5  1  0.235  0.124  0.385  1.0
  Mn  Mn6  1  0.615  0.313  0.942  1.0
  Mn  Mn7  1  0.134  0.311  0.937  1.0
  Mn  Mn8  1  0.624  0.569  0.189  1.0
  Mn  Mn9  1  0.620  0.067  0.696  1.0
  Sn  Sn10  1  0.015  0.001  0.997  1.0
  Sn  Sn11  1  0.015  0.500  0.502  1.0
  O  O12  1  0.398  0.432  0.298  1.0
  O  O13  1  0.412  0.933  0.800  1.0
  O  O14  1  0.866  0.440  0.321  1.0
  O  O15  1  0.845  0.942  0.823  1.0
  O  O16  1  0.887  0.198  0.062  1.0
  O  O17  1  0.893  0.700  0.547  1.0
  O  O18  1  0.890  0.428  0.829  1.0
  O  O19  1  0.890  0.929  0.323  1.0
  O  O20  1  0.401  0.699  0.043  1.0
  O  O21  1  0.395  0.175  0.579  1.0
  O  O22  1  0.842  0.705  0.061  1.0
  O  O23  1  0.837  0.181  0.598  1.0
  O  O24  1  0.355  0.194  0.048  1.0
  O  O25  1  0.358  0.698  0.535  1.0
  O  O26  1  0.358  0.422  0.816  1.0
  O  O27  1  0.362  0.922  0.310  1.0
[/CIF]
.