The crystal structure described by TlCo(CO)4 is Indium-derived structured and crystallizes in the cubic P2_13 space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and four Co(CO)4 clusters. In each Co(CO)4 cluster, Co(1) is bonded in a tetrahedral geometry to one C(2) and three equivalent C(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TlCo(CO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.119
_cell_length_b   9.119
_cell_length_c   9.119
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   758.350
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.190  0.310  0.690  1.0
  Tl  Tl1  1  0.310  0.690  0.190  1.0
  Tl  Tl2  1  0.810  0.810  0.810  1.0
  Tl  Tl3  1  0.690  0.190  0.310  1.0
  Co  Co4  1  0.198  0.698  0.802  1.0
  Co  Co5  1  0.802  0.198  0.698  1.0
  Co  Co6  1  0.698  0.802  0.198  1.0
  Co  Co7  1  0.302  0.302  0.302  1.0
  C  C8  1  0.813  0.385  0.654  1.0
  C  C9  1  0.413  0.413  0.413  1.0
  C  C10  1  0.615  0.154  0.687  1.0
  C  C11  1  0.846  0.187  0.885  1.0
  C  C12  1  0.385  0.654  0.813  1.0
  C  C13  1  0.587  0.913  0.087  1.0
  C  C14  1  0.654  0.813  0.385  1.0
  C  C15  1  0.313  0.115  0.346  1.0
  C  C16  1  0.687  0.615  0.154  1.0
  C  C17  1  0.885  0.846  0.187  1.0
  C  C18  1  0.187  0.885  0.846  1.0
  C  C19  1  0.115  0.346  0.313  1.0
  C  C20  1  0.913  0.087  0.587  1.0
  C  C21  1  0.154  0.687  0.615  1.0
  C  C22  1  0.346  0.313  0.115  1.0
  C  C23  1  0.087  0.587  0.913  1.0
  O  O24  1  0.989  0.369  0.318  1.0
  O  O25  1  0.011  0.869  0.182  1.0
  O  O26  1  0.487  0.487  0.487  1.0
  O  O27  1  0.182  0.011  0.869  1.0
  O  O28  1  0.631  0.818  0.511  1.0
  O  O29  1  0.682  0.489  0.131  1.0
  O  O30  1  0.511  0.631  0.818  1.0
  O  O31  1  0.987  0.013  0.513  1.0
  O  O32  1  0.818  0.511  0.631  1.0
  O  O33  1  0.013  0.513  0.987  1.0
  O  O34  1  0.489  0.131  0.682  1.0
  O  O35  1  0.318  0.989  0.369  1.0
  O  O36  1  0.513  0.987  0.013  1.0
  O  O37  1  0.869  0.182  0.011  1.0
  O  O38  1  0.131  0.682  0.489  1.0
  O  O39  1  0.369  0.318  0.989  1.0
[/CIF]
.
The crystal structure described by TlCo(CO)4 is Indium-derived structured and crystallizes in the cubic P2_13 space group. The structure is zero-dimensional and consists of four 7440-28-0 atoms and four Co(CO)4 clusters. In each Co(CO)4 cluster, Co(1) is bonded in a tetrahedral geometry to one C(2) and three equivalent C(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Co(1) and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TlCo(CO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.119
_cell_length_b   9.119
_cell_length_c   9.119
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   758.350
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.190  0.310  0.690  1.0
  Tl  Tl1  1  0.310  0.690  0.190  1.0
  Tl  Tl2  1  0.810  0.810  0.810  1.0
  Tl  Tl3  1  0.690  0.190  0.310  1.0
  Co  Co4  1  0.198  0.698  0.802  1.0
  Co  Co5  1  0.802  0.198  0.698  1.0
  Co  Co6  1  0.698  0.802  0.198  1.0
  Co  Co7  1  0.302  0.302  0.302  1.0
  C  C8  1  0.813  0.385  0.654  1.0
  C  C9  1  0.413  0.413  0.413  1.0
  C  C10  1  0.615  0.154  0.687  1.0
  C  C11  1  0.846  0.187  0.885  1.0
  C  C12  1  0.385  0.654  0.813  1.0
  C  C13  1  0.587  0.913  0.087  1.0
  C  C14  1  0.654  0.813  0.385  1.0
  C  C15  1  0.313  0.115  0.346  1.0
  C  C16  1  0.687  0.615  0.154  1.0
  C  C17  1  0.885  0.846  0.187  1.0
  C  C18  1  0.187  0.885  0.846  1.0
  C  C19  1  0.115  0.346  0.313  1.0
  C  C20  1  0.913  0.087  0.587  1.0
  C  C21  1  0.154  0.687  0.615  1.0
  C  C22  1  0.346  0.313  0.115  1.0
  C  C23  1  0.087  0.587  0.913  1.0
  O  O24  1  0.989  0.369  0.318  1.0
  O  O25  1  0.011  0.869  0.182  1.0
  O  O26  1  0.487  0.487  0.487  1.0
  O  O27  1  0.182  0.011  0.869  1.0
  O  O28  1  0.631  0.818  0.511  1.0
  O  O29  1  0.682  0.489  0.131  1.0
  O  O30  1  0.511  0.631  0.818  1.0
  O  O31  1  0.987  0.013  0.513  1.0
  O  O32  1  0.818  0.511  0.631  1.0
  O  O33  1  0.013  0.513  0.987  1.0
  O  O34  1  0.489  0.131  0.682  1.0
  O  O35  1  0.318  0.989  0.369  1.0
  O  O36  1  0.513  0.987  0.013  1.0
  O  O37  1  0.869  0.182  0.011  1.0
  O  O38  1  0.131  0.682  0.489  1.0
  O  O39  1  0.369  0.318  0.989  1.0
[/CIF]
.