The compound described by Be2Co(NF7)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Be2Co(NF7)2 clusters. Be(1) is bonded in a trigonal planar geometry to one F(2), one F(3), and one F(4) atom. Co(1) is bonded in an octahedral geometry to two equivalent F(3), two equivalent F(5), and two equivalent F(6) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one F(1), one F(2), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one N(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one N(1) atom. In the third F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Be(1) and one N(1) atom. In the fourth F site, F(3) is bonded in a 2-coordinate geometry to one Be(1) and one Co(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Be(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Co(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Be2Co(NF7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.405
_cell_length_b   5.665
_cell_length_c   8.359
_cell_angle_alpha   67.414
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   586.045
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Be  Be0  1  0.415  0.007  0.839  1.0
  Be  Be1  1  0.585  0.993  0.161  1.0
  Be  Be2  1  0.915  0.993  0.661  1.0
  Be  Be3  1  0.085  0.007  0.339  1.0
  Co  Co4  1  0.500  0.500  0.500  1.0
  Co  Co5  1  0.000  0.500  0.000  1.0
  N  N6  1  0.643  0.884  0.839  1.0
  N  N7  1  0.357  0.116  0.161  1.0
  N  N8  1  0.143  0.116  0.661  1.0
  N  N9  1  0.857  0.884  0.339  1.0
  F  F10  1  0.304  0.308  0.050  1.0
  F  F11  1  0.696  0.692  0.950  1.0
  F  F12  1  0.804  0.692  0.450  1.0
  F  F13  1  0.196  0.308  0.550  1.0
  F  F14  1  0.120  0.933  0.538  1.0
  F  F15  1  0.880  0.067  0.462  1.0
  F  F16  1  0.620  0.067  0.962  1.0
  F  F17  1  0.380  0.933  0.038  1.0
  F  F18  1  0.419  0.279  0.732  1.0
  F  F19  1  0.581  0.721  0.268  1.0
  F  F20  1  0.919  0.721  0.768  1.0
  F  F21  1  0.081  0.279  0.232  1.0
  F  F22  1  0.430  0.772  0.819  1.0
  F  F23  1  0.570  0.228  0.181  1.0
  F  F24  1  0.930  0.228  0.681  1.0
  F  F25  1  0.070  0.772  0.319  1.0
  F  F26  1  0.102  0.451  0.876  1.0
  F  F27  1  0.898  0.549  0.124  1.0
  F  F28  1  0.602  0.549  0.624  1.0
  F  F29  1  0.398  0.451  0.376  1.0
  F  F30  1  0.444  0.781  0.489  1.0
  F  F31  1  0.556  0.219  0.511  1.0
  F  F32  1  0.944  0.219  0.011  1.0
  F  F33  1  0.056  0.781  0.989  1.0
  F  F34  1  0.212  0.961  0.767  1.0
  F  F35  1  0.788  0.039  0.233  1.0
  F  F36  1  0.712  0.039  0.733  1.0
  F  F37  1  0.288  0.961  0.267  1.0
[/CIF]
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The compound described by Be2Co(NF7)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Be2Co(NF7)2 clusters. Be(1) is bonded in a trigonal planar geometry to one F(2), one F(3), and one F(4) atom. Co(1) is bonded in an octahedral geometry to two equivalent F(3), two equivalent F(5), and two equivalent F(6) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one F(1), one F(2), and one F(7) atom. There are seven inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one N(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one N(1) atom. In the third F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Be(1) and one N(1) atom. In the fourth F site, F(3) is bonded in a 2-coordinate geometry to one Be(1) and one Co(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one Be(1) atom. In the sixth F site, F(5) is bonded in a single-bond geometry to one Co(1) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Be2Co(NF7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.405
_cell_length_b   5.665
_cell_length_c   8.359
_cell_angle_alpha   67.414
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   586.045
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Be  Be0  1  0.415  0.007  0.839  1.0
  Be  Be1  1  0.585  0.993  0.161  1.0
  Be  Be2  1  0.915  0.993  0.661  1.0
  Be  Be3  1  0.085  0.007  0.339  1.0
  Co  Co4  1  0.500  0.500  0.500  1.0
  Co  Co5  1  0.000  0.500  0.000  1.0
  N  N6  1  0.643  0.884  0.839  1.0
  N  N7  1  0.357  0.116  0.161  1.0
  N  N8  1  0.143  0.116  0.661  1.0
  N  N9  1  0.857  0.884  0.339  1.0
  F  F10  1  0.304  0.308  0.050  1.0
  F  F11  1  0.696  0.692  0.950  1.0
  F  F12  1  0.804  0.692  0.450  1.0
  F  F13  1  0.196  0.308  0.550  1.0
  F  F14  1  0.120  0.933  0.538  1.0
  F  F15  1  0.880  0.067  0.462  1.0
  F  F16  1  0.620  0.067  0.962  1.0
  F  F17  1  0.380  0.933  0.038  1.0
  F  F18  1  0.419  0.279  0.732  1.0
  F  F19  1  0.581  0.721  0.268  1.0
  F  F20  1  0.919  0.721  0.768  1.0
  F  F21  1  0.081  0.279  0.232  1.0
  F  F22  1  0.430  0.772  0.819  1.0
  F  F23  1  0.570  0.228  0.181  1.0
  F  F24  1  0.930  0.228  0.681  1.0
  F  F25  1  0.070  0.772  0.319  1.0
  F  F26  1  0.102  0.451  0.876  1.0
  F  F27  1  0.898  0.549  0.124  1.0
  F  F28  1  0.602  0.549  0.624  1.0
  F  F29  1  0.398  0.451  0.376  1.0
  F  F30  1  0.444  0.781  0.489  1.0
  F  F31  1  0.556  0.219  0.511  1.0
  F  F32  1  0.944  0.219  0.011  1.0
  F  F33  1  0.056  0.781  0.989  1.0
  F  F34  1  0.212  0.961  0.767  1.0
  F  F35  1  0.788  0.039  0.233  1.0
  F  F36  1  0.712  0.039  0.733  1.0
  F  F37  1  0.288  0.961  0.267  1.0
[/CIF]
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