The compound described by Ag(AgF4)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. In the second Ag site, Ag(2) is bonded in a distorted octahedral geometry to two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Ag(1) and one Ag(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ag(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Ag(1) and one Ag(2) atom. In the fourth F site, F(4) is bonded in a 2-coordinate geometry to one Ag(1) and one Ag(2) atom. is represented by the CIF card [CIF]
data_Ag3F8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.906
_cell_length_b   5.430
_cell_length_c   11.112
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   96.298
_symmetry_Int_Tables_number   1
_cell_volume   294.266
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.275  0.024  0.685  1.0
  Ag  Ag1  1  0.725  0.976  0.315  1.0
  Ag  Ag2  1  0.225  0.476  0.185  1.0
  Ag  Ag3  1  0.775  0.524  0.815  1.0
  Ag  Ag4  1  0.500  0.000  0.000  1.0
  Ag  Ag5  1  0.000  0.500  0.500  1.0
  F  F6  1  0.203  0.168  0.092  1.0
  F  F7  1  0.213  0.767  0.283  1.0
  F  F8  1  0.797  0.832  0.908  1.0
  F  F9  1  0.703  0.668  0.408  1.0
  F  F10  1  0.748  0.161  0.466  1.0
  F  F11  1  0.794  0.712  0.668  1.0
  F  F12  1  0.206  0.288  0.332  1.0
  F  F13  1  0.787  0.233  0.717  1.0
  F  F14  1  0.294  0.212  0.832  1.0
  F  F15  1  0.713  0.267  0.217  1.0
  F  F16  1  0.752  0.339  0.966  1.0
  F  F17  1  0.252  0.839  0.534  1.0
  F  F18  1  0.287  0.733  0.783  1.0
  F  F19  1  0.248  0.661  0.034  1.0
  F  F20  1  0.297  0.332  0.592  1.0
  F  F21  1  0.706  0.788  0.168  1.0
[/CIF]
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The compound described by Ag(AgF4)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. In the second Ag site, Ag(2) is bonded in a distorted octahedral geometry to two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Ag(1) and one Ag(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Ag(1) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Ag(1) and one Ag(2) atom. In the fourth F site, F(4) is bonded in a 2-coordinate geometry to one Ag(1) and one Ag(2) atom. is represented by the CIF card [CIF]
data_Ag3F8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.906
_cell_length_b   5.430
_cell_length_c   11.112
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   96.298
_symmetry_Int_Tables_number   1
_cell_volume   294.266
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.275  0.024  0.685  1.0
  Ag  Ag1  1  0.725  0.976  0.315  1.0
  Ag  Ag2  1  0.225  0.476  0.185  1.0
  Ag  Ag3  1  0.775  0.524  0.815  1.0
  Ag  Ag4  1  0.500  0.000  0.000  1.0
  Ag  Ag5  1  0.000  0.500  0.500  1.0
  F  F6  1  0.203  0.168  0.092  1.0
  F  F7  1  0.213  0.767  0.283  1.0
  F  F8  1  0.797  0.832  0.908  1.0
  F  F9  1  0.703  0.668  0.408  1.0
  F  F10  1  0.748  0.161  0.466  1.0
  F  F11  1  0.794  0.712  0.668  1.0
  F  F12  1  0.206  0.288  0.332  1.0
  F  F13  1  0.787  0.233  0.717  1.0
  F  F14  1  0.294  0.212  0.832  1.0
  F  F15  1  0.713  0.267  0.217  1.0
  F  F16  1  0.752  0.339  0.966  1.0
  F  F17  1  0.252  0.839  0.534  1.0
  F  F18  1  0.287  0.733  0.783  1.0
  F  F19  1  0.248  0.661  0.034  1.0
  F  F20  1  0.297  0.332  0.592  1.0
  F  F21  1  0.706  0.788  0.168  1.0
[/CIF]
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