The compound described by VF5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four mfcd00137321 molecules. V(1) is bonded in a trigonal bipyramidal geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_VF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.591
_cell_length_b   7.214
_cell_length_c   8.701
_cell_angle_alpha   87.027
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   413.142
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.781  0.746  0.568  1.0
  V  V1  1  0.719  0.746  0.068  1.0
  V  V2  1  0.281  0.254  0.932  1.0
  V  V3  1  0.219  0.254  0.432  1.0
  F  F4  1  0.234  0.023  0.885  1.0
  F  F5  1  0.266  0.023  0.385  1.0
  F  F6  1  0.652  0.746  0.874  1.0
  F  F7  1  0.848  0.746  0.374  1.0
  F  F8  1  0.026  0.773  0.647  1.0
  F  F9  1  0.474  0.773  0.147  1.0
  F  F10  1  0.517  0.718  0.546  1.0
  F  F11  1  0.983  0.718  0.046  1.0
  F  F12  1  0.288  0.485  0.856  1.0
  F  F13  1  0.212  0.485  0.356  1.0
  F  F14  1  0.788  0.515  0.644  1.0
  F  F15  1  0.712  0.515  0.144  1.0
  F  F16  1  0.017  0.282  0.954  1.0
  F  F17  1  0.483  0.282  0.454  1.0
  F  F18  1  0.526  0.227  0.853  1.0
  F  F19  1  0.974  0.227  0.353  1.0
  F  F20  1  0.152  0.254  0.626  1.0
  F  F21  1  0.348  0.254  0.126  1.0
  F  F22  1  0.734  0.977  0.615  1.0
  F  F23  1  0.766  0.977  0.115  1.0
[/CIF]
.
The compound described by VF5 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four mfcd00137321 molecules. V(1) is bonded in a trigonal bipyramidal geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one V(1) atom. is represented by the CIF card [CIF]
data_VF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.591
_cell_length_b   7.214
_cell_length_c   8.701
_cell_angle_alpha   87.027
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   413.142
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.781  0.746  0.568  1.0
  V  V1  1  0.719  0.746  0.068  1.0
  V  V2  1  0.281  0.254  0.932  1.0
  V  V3  1  0.219  0.254  0.432  1.0
  F  F4  1  0.234  0.023  0.885  1.0
  F  F5  1  0.266  0.023  0.385  1.0
  F  F6  1  0.652  0.746  0.874  1.0
  F  F7  1  0.848  0.746  0.374  1.0
  F  F8  1  0.026  0.773  0.647  1.0
  F  F9  1  0.474  0.773  0.147  1.0
  F  F10  1  0.517  0.718  0.546  1.0
  F  F11  1  0.983  0.718  0.046  1.0
  F  F12  1  0.288  0.485  0.856  1.0
  F  F13  1  0.212  0.485  0.356  1.0
  F  F14  1  0.788  0.515  0.644  1.0
  F  F15  1  0.712  0.515  0.144  1.0
  F  F16  1  0.017  0.282  0.954  1.0
  F  F17  1  0.483  0.282  0.454  1.0
  F  F18  1  0.526  0.227  0.853  1.0
  F  F19  1  0.974  0.227  0.353  1.0
  F  F20  1  0.152  0.254  0.626  1.0
  F  F21  1  0.348  0.254  0.126  1.0
  F  F22  1  0.734  0.977  0.615  1.0
  F  F23  1  0.766  0.977  0.115  1.0
[/CIF]
.