The crystal structure described by Ce2Rh3Bi5 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 13-coordinate geometry to one Rh(2), four equivalent Rh(3), two equivalent Bi(1), two equivalent Bi(3), and four equivalent Bi(5) atoms. In the second Ce site, Ce(2) is bonded in a 8-coordinate geometry to two equivalent Rh(2), one Bi(5), two equivalent Bi(1), two equivalent Bi(2), and two equivalent Bi(4) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 7-coordinate geometry to one Bi(3), three equivalent Bi(2), and three equivalent Bi(4) atoms. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to one Ce(1), two equivalent Ce(2), one Bi(1), one Bi(4), two equivalent Bi(3), and two equivalent Bi(5) atoms. In the third Rh site, Rh(3) is bonded in a 9-coordinate geometry to four equivalent Ce(1), one Bi(3), two equivalent Bi(1), and two equivalent Bi(5) atoms. There are five inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 7-coordinate geometry to two equivalent Ce(1), two equivalent Ce(2), one Rh(2), and two equivalent Rh(3) atoms. In the second Bi site, Bi(2) is bonded in a 5-coordinate geometry to two equivalent Ce(2) and three equivalent Rh(1) atoms. In the third Bi site, Bi(3) is bonded in a 4-coordinate geometry to two equivalent Ce(1), one Rh(1), one Rh(3), and two equivalent Rh(2) atoms. In the fourth Bi site, Bi(4) is bonded in a 6-coordinate geometry to two equivalent Ce(2), one Rh(2), and three equivalent Rh(1) atoms. In the fifth Bi site, Bi(5) is bonded in a 9-coordinate geometry to one Ce(2), four equivalent Ce(1), two equivalent Rh(2), and two equivalent Rh(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ce2Bi5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.890
_cell_length_b   13.890
_cell_length_c   7.577
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   160.665
_symmetry_Int_Tables_number   1
_cell_volume   483.983
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.474  0.526  0.240  1.0
  Ce  Ce1  1  0.171  0.829  0.274  1.0
  Ce  Ce2  1  0.829  0.171  0.774  1.0
  Ce  Ce3  1  0.526  0.474  0.740  1.0
  Bi  Bi4  1  0.404  0.596  0.615  1.0
  Bi  Bi5  1  0.289  0.711  0.490  1.0
  Bi  Bi6  1  0.711  0.289  0.990  1.0
  Bi  Bi7  1  0.121  0.879  0.748  1.0
  Bi  Bi8  1  0.295  0.705  0.062  1.0
  Bi  Bi9  1  0.953  0.047  0.908  1.0
  Bi  Bi10  1  0.705  0.295  0.562  1.0
  Bi  Bi11  1  0.879  0.121  0.248  1.0
  Bi  Bi12  1  0.047  0.953  0.408  1.0
  Bi  Bi13  1  0.596  0.404  0.115  1.0
  Rh  Rh14  1  0.776  0.224  0.280  1.0
  Rh  Rh15  1  0.603  0.397  0.492  1.0
  Rh  Rh16  1  0.050  0.950  0.025  1.0
  Rh  Rh17  1  0.224  0.776  0.780  1.0
  Rh  Rh18  1  0.950  0.050  0.525  1.0
  Rh  Rh19  1  0.397  0.603  0.992  1.0
[/CIF]
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The crystal structure described by Ce2Rh3Bi5 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 13-coordinate geometry to one Rh(2), four equivalent Rh(3), two equivalent Bi(1), two equivalent Bi(3), and four equivalent Bi(5) atoms. In the second Ce site, Ce(2) is bonded in a 8-coordinate geometry to two equivalent Rh(2), one Bi(5), two equivalent Bi(1), two equivalent Bi(2), and two equivalent Bi(4) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 7-coordinate geometry to one Bi(3), three equivalent Bi(2), and three equivalent Bi(4) atoms. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to one Ce(1), two equivalent Ce(2), one Bi(1), one Bi(4), two equivalent Bi(3), and two equivalent Bi(5) atoms. In the third Rh site, Rh(3) is bonded in a 9-coordinate geometry to four equivalent Ce(1), one Bi(3), two equivalent Bi(1), and two equivalent Bi(5) atoms. There are five inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 7-coordinate geometry to two equivalent Ce(1), two equivalent Ce(2), one Rh(2), and two equivalent Rh(3) atoms. In the second Bi site, Bi(2) is bonded in a 5-coordinate geometry to two equivalent Ce(2) and three equivalent Rh(1) atoms. In the third Bi site, Bi(3) is bonded in a 4-coordinate geometry to two equivalent Ce(1), one Rh(1), one Rh(3), and two equivalent Rh(2) atoms. In the fourth Bi site, Bi(4) is bonded in a 6-coordinate geometry to two equivalent Ce(2), one Rh(2), and three equivalent Rh(1) atoms. In the fifth Bi site, Bi(5) is bonded in a 9-coordinate geometry to one Ce(2), four equivalent Ce(1), two equivalent Rh(2), and two equivalent Rh(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ce2Bi5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.890
_cell_length_b   13.890
_cell_length_c   7.577
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   160.665
_symmetry_Int_Tables_number   1
_cell_volume   483.983
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.474  0.526  0.240  1.0
  Ce  Ce1  1  0.171  0.829  0.274  1.0
  Ce  Ce2  1  0.829  0.171  0.774  1.0
  Ce  Ce3  1  0.526  0.474  0.740  1.0
  Bi  Bi4  1  0.404  0.596  0.615  1.0
  Bi  Bi5  1  0.289  0.711  0.490  1.0
  Bi  Bi6  1  0.711  0.289  0.990  1.0
  Bi  Bi7  1  0.121  0.879  0.748  1.0
  Bi  Bi8  1  0.295  0.705  0.062  1.0
  Bi  Bi9  1  0.953  0.047  0.908  1.0
  Bi  Bi10  1  0.705  0.295  0.562  1.0
  Bi  Bi11  1  0.879  0.121  0.248  1.0
  Bi  Bi12  1  0.047  0.953  0.408  1.0
  Bi  Bi13  1  0.596  0.404  0.115  1.0
  Rh  Rh14  1  0.776  0.224  0.280  1.0
  Rh  Rh15  1  0.603  0.397  0.492  1.0
  Rh  Rh16  1  0.050  0.950  0.025  1.0
  Rh  Rh17  1  0.224  0.776  0.780  1.0
  Rh  Rh18  1  0.950  0.050  0.525  1.0
  Rh  Rh19  1  0.397  0.603  0.992  1.0
[/CIF]
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