The compound described by Ni(WB)2 crystallizes in the orthorhombic Immm space group. W(1) is bonded in a 10-coordinate geometry to four equivalent Ni(1) and six equivalent B(1) atoms. Ni(1) is bonded to eight equivalent W(1) and four equivalent B(1) atoms to form a mixture of distorted edge and face-sharing NiB4W8 cuboctahedra. B(1) is bonded in a 9-coordinate geometry to six equivalent W(1), two equivalent Ni(1), and one B(1) atom. is represented by the CIF file [CIF]
data_Ni(BW)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.494
_cell_length_b   4.494
_cell_length_c   4.494
_cell_angle_alpha   138.398
_cell_angle_beta   119.220
_cell_angle_gamma   76.353
_symmetry_Int_Tables_number   1
_cell_volume   51.287
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.000  0.000  0.000  1.0
  B  B1  1  0.704  0.500  0.204  1.0
  B  B2  1  0.296  0.500  0.796  1.0
  W  W3  1  0.701  0.201  0.500  1.0
  W  W4  1  0.299  0.799  0.500  1.0
[/CIF]
.
The compound described by Ni(WB)2 crystallizes in the orthorhombic Immm space group. W(1) is bonded in a 10-coordinate geometry to four equivalent Ni(1) and six equivalent B(1) atoms. Ni(1) is bonded to eight equivalent W(1) and four equivalent B(1) atoms to form a mixture of distorted edge and face-sharing NiB4W8 cuboctahedra. B(1) is bonded in a 9-coordinate geometry to six equivalent W(1), two equivalent Ni(1), and one B(1) atom. is represented by the CIF file [CIF]
data_Ni(BW)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.494
_cell_length_b   4.494
_cell_length_c   4.494
_cell_angle_alpha   138.398
_cell_angle_beta   119.220
_cell_angle_gamma   76.353
_symmetry_Int_Tables_number   1
_cell_volume   51.287
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.000  0.000  0.000  1.0
  B  B1  1  0.704  0.500  0.204  1.0
  B  B2  1  0.296  0.500  0.796  1.0
  W  W3  1  0.701  0.201  0.500  1.0
  W  W4  1  0.299  0.799  0.500  1.0
[/CIF]
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