The crystal structure described by ReS2O9Cl is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one ReS2O9Cl cluster. Re(1) is bonded to one O(1), one O(2), one O(4), one O(5), one O(9), and one Cl(1) atom to form distorted ReClO5 octahedra that share  a cornercorner with one S(2)O4 tetrahedra and corners with two equivalent S(1)O4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form SO4 tetrahedra that share corners with two equivalent Re(1)ClO5 octahedra and  a cornercorner with one S(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 37-40°. In the second S site, S(2) is bonded to one O(6), one O(7), one O(8), and one O(9) atom to form SO4 tetrahedra that share  a cornercorner with one Re(1)ClO5 octahedra and  a cornercorner with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Re(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Re(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(2) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one S(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Re(1) and one S(2) atom. Cl(1) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_ReS2ClO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.277
_cell_length_b   7.923
_cell_length_c   8.283
_cell_angle_alpha   89.987
_cell_angle_beta   100.670
_cell_angle_gamma   112.197
_symmetry_Int_Tables_number   1
_cell_volume   433.248
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.768  0.303  0.698  1.0
  Re  Re1  1  0.232  0.697  0.302  1.0
  S  S2  1  0.090  0.735  0.876  1.0
  S  S3  1  0.910  0.265  0.124  1.0
  S  S4  1  0.659  0.651  0.780  1.0
  S  S5  1  0.341  0.349  0.220  1.0
  Cl  Cl6  1  1.000  0.184  0.685  1.0
  Cl  Cl7  1  0.000  0.816  0.315  1.0
  O  O8  1  0.552  0.110  0.649  1.0
  O  O9  1  0.448  0.890  0.351  1.0
  O  O10  1  0.778  0.408  0.518  1.0
  O  O11  1  0.222  0.592  0.482  1.0
  O  O12  1  0.165  0.856  0.756  1.0
  O  O13  1  0.835  0.144  0.244  1.0
  O  O14  1  0.215  0.785  0.043  1.0
  O  O15  1  0.785  0.215  0.957  1.0
  O  O16  1  0.031  0.537  0.829  1.0
  O  O17  1  0.969  0.463  0.171  1.0
  O  O18  1  0.879  0.750  0.910  1.0
  O  O19  1  0.121  0.250  0.090  1.0
  O  O20  1  0.520  0.683  0.863  1.0
  O  O21  1  0.480  0.317  0.137  1.0
  O  O22  1  0.685  0.709  0.619  1.0
  O  O23  1  0.315  0.291  0.381  1.0
  O  O24  1  0.629  0.445  0.789  1.0
  O  O25  1  0.371  0.555  0.211  1.0
[/CIF]
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The crystal structure described by ReS2O9Cl is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one ReS2O9Cl cluster. Re(1) is bonded to one O(1), one O(2), one O(4), one O(5), one O(9), and one Cl(1) atom to form distorted ReClO5 octahedra that share  a cornercorner with one S(2)O4 tetrahedra and corners with two equivalent S(1)O4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form SO4 tetrahedra that share corners with two equivalent Re(1)ClO5 octahedra and  a cornercorner with one S(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 37-40°. In the second S site, S(2) is bonded to one O(6), one O(7), one O(8), and one O(9) atom to form SO4 tetrahedra that share  a cornercorner with one Re(1)ClO5 octahedra and  a cornercorner with one S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Re(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Re(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Re(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(2) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one S(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Re(1) and one S(2) atom. Cl(1) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_ReS2ClO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.277
_cell_length_b   7.923
_cell_length_c   8.283
_cell_angle_alpha   89.987
_cell_angle_beta   100.670
_cell_angle_gamma   112.197
_symmetry_Int_Tables_number   1
_cell_volume   433.248
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.768  0.303  0.698  1.0
  Re  Re1  1  0.232  0.697  0.302  1.0
  S  S2  1  0.090  0.735  0.876  1.0
  S  S3  1  0.910  0.265  0.124  1.0
  S  S4  1  0.659  0.651  0.780  1.0
  S  S5  1  0.341  0.349  0.220  1.0
  Cl  Cl6  1  1.000  0.184  0.685  1.0
  Cl  Cl7  1  0.000  0.816  0.315  1.0
  O  O8  1  0.552  0.110  0.649  1.0
  O  O9  1  0.448  0.890  0.351  1.0
  O  O10  1  0.778  0.408  0.518  1.0
  O  O11  1  0.222  0.592  0.482  1.0
  O  O12  1  0.165  0.856  0.756  1.0
  O  O13  1  0.835  0.144  0.244  1.0
  O  O14  1  0.215  0.785  0.043  1.0
  O  O15  1  0.785  0.215  0.957  1.0
  O  O16  1  0.031  0.537  0.829  1.0
  O  O17  1  0.969  0.463  0.171  1.0
  O  O18  1  0.879  0.750  0.910  1.0
  O  O19  1  0.121  0.250  0.090  1.0
  O  O20  1  0.520  0.683  0.863  1.0
  O  O21  1  0.480  0.317  0.137  1.0
  O  O22  1  0.685  0.709  0.619  1.0
  O  O23  1  0.315  0.291  0.381  1.0
  O  O24  1  0.629  0.445  0.789  1.0
  O  O25  1  0.371  0.555  0.211  1.0
[/CIF]
.