The material structure described by Ho4LiGe4 crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a distorted T-shaped geometry to one Ge(2), two equivalent Ge(1), and two equivalent Ge(3) atoms. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 7-coordinate geometry to one Ge(2), two equivalent Ge(3), and four equivalent Ge(1) atoms. In the second Ho site, Ho(2) is bonded in a 6-coordinate geometry to one Ge(3), two equivalent Ge(2), and three equivalent Ge(1) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(3) is bonded in a 9-coordinate geometry to two equivalent Li(1), two equivalent Ho(2), four equivalent Ho(1), and one Ge(2) atom. In the second Ge site, Ge(1) is bonded in a 9-coordinate geometry to one Li(1), three equivalent Ho(2), four equivalent Ho(1), and one Ge(1) atom. In the third Ge site, Ge(2) is bonded in a 8-coordinate geometry to one Li(1), two equivalent Ho(1), four equivalent Ho(2), and one Ge(3) atom. is represented by the CIF card [CIF]
data_Li(HoGe)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.091
_cell_length_b   7.648
_cell_length_c   14.571
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   790.180
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.663  0.972  0.750  1.0
  Li  Li1  1  0.163  0.528  0.750  1.0
  Li  Li2  1  0.337  0.028  0.250  1.0
  Li  Li3  1  0.837  0.472  0.250  1.0
  Ho  Ho4  1  0.517  0.313  0.098  1.0
  Ho  Ho5  1  0.017  0.187  0.402  1.0
  Ho  Ho6  1  0.483  0.687  0.598  1.0
  Ho  Ho7  1  0.983  0.813  0.902  1.0
  Ho  Ho8  1  0.483  0.687  0.902  1.0
  Ho  Ho9  1  0.983  0.813  0.598  1.0
  Ho  Ho10  1  0.517  0.313  0.402  1.0
  Ho  Ho11  1  0.017  0.187  0.098  1.0
  Ho  Ho12  1  0.829  0.323  0.628  1.0
  Ho  Ho13  1  0.329  0.177  0.872  1.0
  Ho  Ho14  1  0.171  0.677  0.128  1.0
  Ho  Ho15  1  0.671  0.823  0.372  1.0
  Ho  Ho16  1  0.171  0.677  0.372  1.0
  Ho  Ho17  1  0.671  0.823  0.128  1.0
  Ho  Ho18  1  0.829  0.323  0.872  1.0
  Ho  Ho19  1  0.329  0.177  0.628  1.0
  Ge  Ge20  1  0.667  0.034  0.536  1.0
  Ge  Ge21  1  0.167  0.466  0.964  1.0
  Ge  Ge22  1  0.333  0.966  0.036  1.0
  Ge  Ge23  1  0.833  0.534  0.464  1.0
  Ge  Ge24  1  0.333  0.966  0.464  1.0
  Ge  Ge25  1  0.833  0.534  0.036  1.0
  Ge  Ge26  1  0.667  0.034  0.964  1.0
  Ge  Ge27  1  0.167  0.466  0.536  1.0
  Ge  Ge28  1  0.518  0.414  0.750  1.0
  Ge  Ge29  1  0.018  0.086  0.750  1.0
  Ge  Ge30  1  0.482  0.586  0.250  1.0
  Ge  Ge31  1  0.982  0.914  0.250  1.0
  Ge  Ge32  1  0.782  0.635  0.750  1.0
  Ge  Ge33  1  0.282  0.865  0.750  1.0
  Ge  Ge34  1  0.218  0.365  0.250  1.0
  Ge  Ge35  1  0.718  0.135  0.250  1.0
[/CIF]
.
The material structure described by Ho4LiGe4 crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a distorted T-shaped geometry to one Ge(2), two equivalent Ge(1), and two equivalent Ge(3) atoms. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 7-coordinate geometry to one Ge(2), two equivalent Ge(3), and four equivalent Ge(1) atoms. In the second Ho site, Ho(2) is bonded in a 6-coordinate geometry to one Ge(3), two equivalent Ge(2), and three equivalent Ge(1) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(3) is bonded in a 9-coordinate geometry to two equivalent Li(1), two equivalent Ho(2), four equivalent Ho(1), and one Ge(2) atom. In the second Ge site, Ge(1) is bonded in a 9-coordinate geometry to one Li(1), three equivalent Ho(2), four equivalent Ho(1), and one Ge(1) atom. In the third Ge site, Ge(2) is bonded in a 8-coordinate geometry to one Li(1), two equivalent Ho(1), four equivalent Ho(2), and one Ge(3) atom. is represented by the CIF card [CIF]
data_Li(HoGe)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.091
_cell_length_b   7.648
_cell_length_c   14.571
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   790.180
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.663  0.972  0.750  1.0
  Li  Li1  1  0.163  0.528  0.750  1.0
  Li  Li2  1  0.337  0.028  0.250  1.0
  Li  Li3  1  0.837  0.472  0.250  1.0
  Ho  Ho4  1  0.517  0.313  0.098  1.0
  Ho  Ho5  1  0.017  0.187  0.402  1.0
  Ho  Ho6  1  0.483  0.687  0.598  1.0
  Ho  Ho7  1  0.983  0.813  0.902  1.0
  Ho  Ho8  1  0.483  0.687  0.902  1.0
  Ho  Ho9  1  0.983  0.813  0.598  1.0
  Ho  Ho10  1  0.517  0.313  0.402  1.0
  Ho  Ho11  1  0.017  0.187  0.098  1.0
  Ho  Ho12  1  0.829  0.323  0.628  1.0
  Ho  Ho13  1  0.329  0.177  0.872  1.0
  Ho  Ho14  1  0.171  0.677  0.128  1.0
  Ho  Ho15  1  0.671  0.823  0.372  1.0
  Ho  Ho16  1  0.171  0.677  0.372  1.0
  Ho  Ho17  1  0.671  0.823  0.128  1.0
  Ho  Ho18  1  0.829  0.323  0.872  1.0
  Ho  Ho19  1  0.329  0.177  0.628  1.0
  Ge  Ge20  1  0.667  0.034  0.536  1.0
  Ge  Ge21  1  0.167  0.466  0.964  1.0
  Ge  Ge22  1  0.333  0.966  0.036  1.0
  Ge  Ge23  1  0.833  0.534  0.464  1.0
  Ge  Ge24  1  0.333  0.966  0.464  1.0
  Ge  Ge25  1  0.833  0.534  0.036  1.0
  Ge  Ge26  1  0.667  0.034  0.964  1.0
  Ge  Ge27  1  0.167  0.466  0.536  1.0
  Ge  Ge28  1  0.518  0.414  0.750  1.0
  Ge  Ge29  1  0.018  0.086  0.750  1.0
  Ge  Ge30  1  0.482  0.586  0.250  1.0
  Ge  Ge31  1  0.982  0.914  0.250  1.0
  Ge  Ge32  1  0.782  0.635  0.750  1.0
  Ge  Ge33  1  0.282  0.865  0.750  1.0
  Ge  Ge34  1  0.218  0.365  0.250  1.0
  Ge  Ge35  1  0.718  0.135  0.250  1.0
[/CIF]
.