The material described by SiH2SO3CF3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and four SiH2SO3 clusters. In each SiH2SO3 cluster, Si(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one O(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Si(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Si(1) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Si(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_SiH2CS(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.018
_cell_length_b   9.562
_cell_length_c   11.401
_cell_angle_alpha   69.098
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   714.811
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Si  Si0  1  0.453  0.006  0.099  1.0
  Si  Si1  1  0.953  0.994  0.401  1.0
  Si  Si2  1  0.547  0.994  0.901  1.0
  Si  Si3  1  0.047  0.006  0.599  1.0
  H  H4  1  0.391  0.863  0.195  1.0
  H  H5  1  0.891  0.137  0.305  1.0
  H  H6  1  0.609  0.137  0.805  1.0
  H  H7  1  0.109  0.863  0.695  1.0
  H  H8  1  0.582  0.097  0.146  1.0
  H  H9  1  0.082  0.903  0.354  1.0
  H  H10  1  0.418  0.903  0.854  1.0
  H  H11  1  0.918  0.097  0.646  1.0
  C  C12  1  0.244  0.394  0.932  1.0
  C  C13  1  0.744  0.606  0.568  1.0
  C  C14  1  0.756  0.606  0.068  1.0
  C  C15  1  0.256  0.394  0.432  1.0
  S  S16  1  0.144  0.207  0.949  1.0
  S  S17  1  0.644  0.793  0.551  1.0
  S  S18  1  0.856  0.793  0.051  1.0
  S  S19  1  0.356  0.207  0.449  1.0
  O  O20  1  0.240  0.109  0.073  1.0
  O  O21  1  0.740  0.891  0.427  1.0
  O  O22  1  0.760  0.891  0.927  1.0
  O  O23  1  0.260  0.109  0.573  1.0
  O  O24  1  0.943  0.215  0.968  1.0
  O  O25  1  0.443  0.785  0.532  1.0
  O  O26  1  0.057  0.785  0.032  1.0
  O  O27  1  0.557  0.215  0.468  1.0
  O  O28  1  0.219  0.173  0.844  1.0
  O  O29  1  0.719  0.827  0.656  1.0
  O  O30  1  0.781  0.827  0.156  1.0
  O  O31  1  0.281  0.173  0.344  1.0
  F  F32  1  0.436  0.389  0.925  1.0
  F  F33  1  0.936  0.611  0.575  1.0
  F  F34  1  0.564  0.611  0.075  1.0
  F  F35  1  0.064  0.389  0.425  1.0
  F  F36  1  0.197  0.431  0.032  1.0
  F  F37  1  0.697  0.569  0.468  1.0
  F  F38  1  0.803  0.569  0.968  1.0
  F  F39  1  0.303  0.431  0.532  1.0
  F  F40  1  0.175  0.498  0.826  1.0
  F  F41  1  0.675  0.502  0.674  1.0
  F  F42  1  0.825  0.502  0.174  1.0
  F  F43  1  0.325  0.498  0.326  1.0
[/CIF]
.
The material described by SiH2SO3CF3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trifluoromethane molecules and four SiH2SO3 clusters. In each SiH2SO3 cluster, Si(1) is bonded in a distorted trigonal non-coplanar geometry to one H(1), one H(2), and one O(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Si(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Si(1) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Si(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_SiH2CS(OF)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.018
_cell_length_b   9.562
_cell_length_c   11.401
_cell_angle_alpha   69.098
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   714.811
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Si  Si0  1  0.453  0.006  0.099  1.0
  Si  Si1  1  0.953  0.994  0.401  1.0
  Si  Si2  1  0.547  0.994  0.901  1.0
  Si  Si3  1  0.047  0.006  0.599  1.0
  H  H4  1  0.391  0.863  0.195  1.0
  H  H5  1  0.891  0.137  0.305  1.0
  H  H6  1  0.609  0.137  0.805  1.0
  H  H7  1  0.109  0.863  0.695  1.0
  H  H8  1  0.582  0.097  0.146  1.0
  H  H9  1  0.082  0.903  0.354  1.0
  H  H10  1  0.418  0.903  0.854  1.0
  H  H11  1  0.918  0.097  0.646  1.0
  C  C12  1  0.244  0.394  0.932  1.0
  C  C13  1  0.744  0.606  0.568  1.0
  C  C14  1  0.756  0.606  0.068  1.0
  C  C15  1  0.256  0.394  0.432  1.0
  S  S16  1  0.144  0.207  0.949  1.0
  S  S17  1  0.644  0.793  0.551  1.0
  S  S18  1  0.856  0.793  0.051  1.0
  S  S19  1  0.356  0.207  0.449  1.0
  O  O20  1  0.240  0.109  0.073  1.0
  O  O21  1  0.740  0.891  0.427  1.0
  O  O22  1  0.760  0.891  0.927  1.0
  O  O23  1  0.260  0.109  0.573  1.0
  O  O24  1  0.943  0.215  0.968  1.0
  O  O25  1  0.443  0.785  0.532  1.0
  O  O26  1  0.057  0.785  0.032  1.0
  O  O27  1  0.557  0.215  0.468  1.0
  O  O28  1  0.219  0.173  0.844  1.0
  O  O29  1  0.719  0.827  0.656  1.0
  O  O30  1  0.781  0.827  0.156  1.0
  O  O31  1  0.281  0.173  0.344  1.0
  F  F32  1  0.436  0.389  0.925  1.0
  F  F33  1  0.936  0.611  0.575  1.0
  F  F34  1  0.564  0.611  0.075  1.0
  F  F35  1  0.064  0.389  0.425  1.0
  F  F36  1  0.197  0.431  0.032  1.0
  F  F37  1  0.697  0.569  0.468  1.0
  F  F38  1  0.803  0.569  0.968  1.0
  F  F39  1  0.303  0.431  0.532  1.0
  F  F40  1  0.175  0.498  0.826  1.0
  F  F41  1  0.675  0.502  0.674  1.0
  F  F42  1  0.825  0.502  0.174  1.0
  F  F43  1  0.325  0.498  0.326  1.0
[/CIF]
.