The structure described by NaBaN crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a distorted trigonal planar geometry to three equivalent N(1) atoms. Ba(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted corner and edge-sharing BaN4 tetrahedra. N(1) is bonded to three equivalent Na(1) and four equivalent Ba(1) atoms to form a mixture of distorted corner and edge-sharing NBa4Na3 pentagonal bipyramids. is represented by the CIF file [CIF]
data_BaNaN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.874
_cell_length_b   4.336
_cell_length_c   6.514
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   278.874
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.653  0.250  0.469  1.0
  Ba  Ba1  1  0.153  0.250  0.031  1.0
  Ba  Ba2  1  0.347  0.750  0.531  1.0
  Ba  Ba3  1  0.847  0.750  0.969  1.0
  Na  Na4  1  0.562  0.250  0.931  1.0
  Na  Na5  1  0.062  0.250  0.569  1.0
  Na  Na6  1  0.438  0.750  0.069  1.0
  Na  Na7  1  0.938  0.750  0.431  1.0
  N  N8  1  0.898  0.250  0.241  1.0
  N  N9  1  0.398  0.250  0.259  1.0
  N  N10  1  0.102  0.750  0.759  1.0
  N  N11  1  0.602  0.750  0.741  1.0
[/CIF]
.
The structure described by NaBaN crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a distorted trigonal planar geometry to three equivalent N(1) atoms. Ba(1) is bonded to four equivalent N(1) atoms to form a mixture of distorted corner and edge-sharing BaN4 tetrahedra. N(1) is bonded to three equivalent Na(1) and four equivalent Ba(1) atoms to form a mixture of distorted corner and edge-sharing NBa4Na3 pentagonal bipyramids. is represented by the CIF file [CIF]
data_BaNaN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.874
_cell_length_b   4.336
_cell_length_c   6.514
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   278.874
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.653  0.250  0.469  1.0
  Ba  Ba1  1  0.153  0.250  0.031  1.0
  Ba  Ba2  1  0.347  0.750  0.531  1.0
  Ba  Ba3  1  0.847  0.750  0.969  1.0
  Na  Na4  1  0.562  0.250  0.931  1.0
  Na  Na5  1  0.062  0.250  0.569  1.0
  Na  Na6  1  0.438  0.750  0.069  1.0
  Na  Na7  1  0.938  0.750  0.431  1.0
  N  N8  1  0.898  0.250  0.241  1.0
  N  N9  1  0.398  0.250  0.259  1.0
  N  N10  1  0.102  0.750  0.759  1.0
  N  N11  1  0.602  0.750  0.741  1.0
[/CIF]
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