The compound described by GeH4 is Silicon tetrafluoride-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four 619p6j82ae molecules. Ge(1) is bonded in a tetrahedral geometry to one H(1), one H(2), one H(3), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Ge(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Ge(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one Ge(1) atom. is represented by the CIF card [CIF]
data_GeH4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.909
_cell_length_b   8.733
_cell_length_c   4.844
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   334.572
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.508  0.856  0.149  1.0
  Ge  Ge1  1  0.992  0.144  0.649  1.0
  Ge  Ge2  1  0.008  0.644  0.851  1.0
  Ge  Ge3  1  0.492  0.356  0.351  1.0
  H  H4  1  0.375  0.823  0.370  1.0
  H  H5  1  0.125  0.177  0.870  1.0
  H  H6  1  0.875  0.677  0.630  1.0
  H  H7  1  0.625  0.323  0.130  1.0
  H  H8  1  0.673  0.903  0.292  1.0
  H  H9  1  0.827  0.097  0.792  1.0
  H  H10  1  0.173  0.597  0.708  1.0
  H  H11  1  0.327  0.403  0.208  1.0
  H  H12  1  0.538  0.711  0.977  1.0
  H  H13  1  0.962  0.289  0.477  1.0
  H  H14  1  0.038  0.789  0.023  1.0
  H  H15  1  0.462  0.211  0.523  1.0
  H  H16  1  0.451  0.986  0.958  1.0
  H  H17  1  0.049  0.014  0.458  1.0
  H  H18  1  0.951  0.514  0.042  1.0
  H  H19  1  0.549  0.486  0.542  1.0
[/CIF]
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The compound described by GeH4 is Silicon tetrafluoride-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four 619p6j82ae molecules. Ge(1) is bonded in a tetrahedral geometry to one H(1), one H(2), one H(3), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one Ge(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one Ge(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one Ge(1) atom. is represented by the CIF card [CIF]
data_GeH4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.909
_cell_length_b   8.733
_cell_length_c   4.844
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   334.572
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.508  0.856  0.149  1.0
  Ge  Ge1  1  0.992  0.144  0.649  1.0
  Ge  Ge2  1  0.008  0.644  0.851  1.0
  Ge  Ge3  1  0.492  0.356  0.351  1.0
  H  H4  1  0.375  0.823  0.370  1.0
  H  H5  1  0.125  0.177  0.870  1.0
  H  H6  1  0.875  0.677  0.630  1.0
  H  H7  1  0.625  0.323  0.130  1.0
  H  H8  1  0.673  0.903  0.292  1.0
  H  H9  1  0.827  0.097  0.792  1.0
  H  H10  1  0.173  0.597  0.708  1.0
  H  H11  1  0.327  0.403  0.208  1.0
  H  H12  1  0.538  0.711  0.977  1.0
  H  H13  1  0.962  0.289  0.477  1.0
  H  H14  1  0.038  0.789  0.023  1.0
  H  H15  1  0.462  0.211  0.523  1.0
  H  H16  1  0.451  0.986  0.958  1.0
  H  H17  1  0.049  0.014  0.458  1.0
  H  H18  1  0.951  0.514  0.042  1.0
  H  H19  1  0.549  0.486  0.542  1.0
[/CIF]
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