The material described by (TcCO4)2C4NC2N is Indium-derived structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of two aziridine molecules, two C4N clusters, and four TcCO4 clusters. In each C4N cluster, there are two inequivalent C sites. In the first C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one C(2), and one N(1) atom. In the second C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one N(1) atom. N(1) is bonded in a distorted bent 150 degrees geometry to two equivalent C(1) and two equivalent C(2) atoms. In each TcCO4 cluster, Tc(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. C(3) is bonded in a distorted single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Tc(1) atom. In the second O site, O(4) is bonded in a bent 150 degrees geometry to one Tc(1) and one C(3) atom. In the third O site, O(1) is bonded in a single-bond geometry to one Tc(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one Tc(1) atom. is represented by the CIF file [CIF]
data_TcC4NO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.547
_cell_length_b   9.902
_cell_length_c   10.854
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   703.565
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  0.447  0.225  0.768  1.0
  Tc  Tc1  1  0.447  0.775  0.232  1.0
  Tc  Tc2  1  0.553  0.725  0.732  1.0
  Tc  Tc3  1  0.553  0.275  0.268  1.0
  C  C4  1  0.018  0.887  0.566  1.0
  C  C5  1  0.018  0.113  0.434  1.0
  C  C6  1  0.982  0.387  0.934  1.0
  C  C7  1  0.982  0.613  0.066  1.0
  C  C8  1  0.827  0.070  0.491  1.0
  C  C9  1  0.827  0.930  0.509  1.0
  C  C10  1  0.173  0.570  0.009  1.0
  C  C11  1  0.173  0.430  0.991  1.0
  C  C12  1  0.807  0.546  0.548  1.0
  C  C13  1  0.807  0.454  0.452  1.0
  C  C14  1  0.193  0.046  0.952  1.0
  C  C15  1  0.193  0.954  0.048  1.0
  C  C16  1  0.026  0.561  0.562  1.0
  C  C17  1  0.026  0.439  0.438  1.0
  C  C18  1  0.974  0.061  0.938  1.0
  C  C19  1  0.974  0.939  0.062  1.0
  N  N20  1  0.071  0.000  0.500  1.0
  N  N21  1  0.929  0.500  0.000  1.0
  N  N22  1  0.180  0.500  0.500  1.0
  N  N23  1  0.820  0.000  0.000  1.0
  O  O24  1  0.706  0.209  0.761  1.0
  O  O25  1  0.706  0.791  0.239  1.0
  O  O26  1  0.294  0.709  0.739  1.0
  O  O27  1  0.294  0.291  0.261  1.0
  O  O28  1  0.352  0.198  0.623  1.0
  O  O29  1  0.352  0.802  0.377  1.0
  O  O30  1  0.648  0.698  0.877  1.0
  O  O31  1  0.648  0.302  0.123  1.0
  O  O32  1  0.391  0.389  0.808  1.0
  O  O33  1  0.391  0.611  0.192  1.0
  O  O34  1  0.609  0.889  0.692  1.0
  O  O35  1  0.609  0.111  0.308  1.0
  O  O36  1  0.339  0.106  0.888  1.0
  O  O37  1  0.339  0.894  0.112  1.0
  O  O38  1  0.661  0.606  0.612  1.0
  O  O39  1  0.661  0.394  0.388  1.0
[/CIF]
.
The material described by (TcCO4)2C4NC2N is Indium-derived structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of two aziridine molecules, two C4N clusters, and four TcCO4 clusters. In each C4N cluster, there are two inequivalent C sites. In the first C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one C(2), and one N(1) atom. In the second C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one N(1) atom. N(1) is bonded in a distorted bent 150 degrees geometry to two equivalent C(1) and two equivalent C(2) atoms. In each TcCO4 cluster, Tc(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. C(3) is bonded in a distorted single-bond geometry to one O(4) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Tc(1) atom. In the second O site, O(4) is bonded in a bent 150 degrees geometry to one Tc(1) and one C(3) atom. In the third O site, O(1) is bonded in a single-bond geometry to one Tc(1) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one Tc(1) atom. is represented by the CIF file [CIF]
data_TcC4NO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.547
_cell_length_b   9.902
_cell_length_c   10.854
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   703.565
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  0.447  0.225  0.768  1.0
  Tc  Tc1  1  0.447  0.775  0.232  1.0
  Tc  Tc2  1  0.553  0.725  0.732  1.0
  Tc  Tc3  1  0.553  0.275  0.268  1.0
  C  C4  1  0.018  0.887  0.566  1.0
  C  C5  1  0.018  0.113  0.434  1.0
  C  C6  1  0.982  0.387  0.934  1.0
  C  C7  1  0.982  0.613  0.066  1.0
  C  C8  1  0.827  0.070  0.491  1.0
  C  C9  1  0.827  0.930  0.509  1.0
  C  C10  1  0.173  0.570  0.009  1.0
  C  C11  1  0.173  0.430  0.991  1.0
  C  C12  1  0.807  0.546  0.548  1.0
  C  C13  1  0.807  0.454  0.452  1.0
  C  C14  1  0.193  0.046  0.952  1.0
  C  C15  1  0.193  0.954  0.048  1.0
  C  C16  1  0.026  0.561  0.562  1.0
  C  C17  1  0.026  0.439  0.438  1.0
  C  C18  1  0.974  0.061  0.938  1.0
  C  C19  1  0.974  0.939  0.062  1.0
  N  N20  1  0.071  0.000  0.500  1.0
  N  N21  1  0.929  0.500  0.000  1.0
  N  N22  1  0.180  0.500  0.500  1.0
  N  N23  1  0.820  0.000  0.000  1.0
  O  O24  1  0.706  0.209  0.761  1.0
  O  O25  1  0.706  0.791  0.239  1.0
  O  O26  1  0.294  0.709  0.739  1.0
  O  O27  1  0.294  0.291  0.261  1.0
  O  O28  1  0.352  0.198  0.623  1.0
  O  O29  1  0.352  0.802  0.377  1.0
  O  O30  1  0.648  0.698  0.877  1.0
  O  O31  1  0.648  0.302  0.123  1.0
  O  O32  1  0.391  0.389  0.808  1.0
  O  O33  1  0.391  0.611  0.192  1.0
  O  O34  1  0.609  0.889  0.692  1.0
  O  O35  1  0.609  0.111  0.308  1.0
  O  O36  1  0.339  0.106  0.888  1.0
  O  O37  1  0.339  0.894  0.112  1.0
  O  O38  1  0.661  0.606  0.612  1.0
  O  O39  1  0.661  0.394  0.388  1.0
[/CIF]
.