The structure described by CP3(NCl3)3SbCl6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two CP3(NCl3)3 clusters and two SbCl6 clusters. In each CP3(NCl3)3 cluster, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one N(2), one Cl(11), one Cl(12), and one Cl(6) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one N(3), one Cl(15), one Cl(8), and one Cl(9) atom. In the third P site, P(3) is bonded in a tetrahedral geometry to one N(1), one Cl(10), one Cl(2), and one Cl(7) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one P(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one P(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one P(2) atom. There are nine inequivalent Cl sites. In the first Cl site, Cl(15) is bonded in a single-bond geometry to one P(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(3) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one P(3) atom. In the fifth Cl site, Cl(8) is bonded in a single-bond geometry to one P(2) atom. In the sixth Cl site, Cl(9) is bonded in a single-bond geometry to one P(2) atom. In the seventh Cl site, Cl(10) is bonded in a single-bond geometry to one P(3) atom. In the eighth Cl site, Cl(11) is bonded in a single-bond geometry to one P(1) atom. In the ninth Cl site, Cl(12) is bonded in a single-bond geometry to one P(1) atom. In each SbCl6 cluster, Sb(1) is bonded in an octahedral geometry to one Cl(1), one Cl(13), one Cl(14), one Cl(3), one Cl(4), and one Cl(5) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(13) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(14) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_SbP3C(NCl5)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.226
_cell_length_b   10.488
_cell_length_c   13.207
_cell_angle_alpha   85.376
_cell_angle_beta   88.958
_cell_angle_gamma   76.829
_symmetry_Int_Tables_number   1
_cell_volume   1240.246
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.313  0.253  0.308  1.0
  Sb  Sb1  1  0.687  0.747  0.692  1.0
  P  P2  1  0.865  0.216  0.650  1.0
  P  P3  1  0.592  0.707  0.217  1.0
  P  P4  1  0.212  0.793  0.005  1.0
  P  P5  1  0.408  0.293  0.783  1.0
  P  P6  1  0.135  0.784  0.350  1.0
  P  P7  1  0.788  0.207  0.995  1.0
  C  C8  1  0.307  0.762  0.188  1.0
  C  C9  1  0.693  0.238  0.812  1.0
  N  N10  1  0.191  0.788  0.123  1.0
  N  N11  1  0.716  0.240  0.711  1.0
  N  N12  1  0.446  0.739  0.151  1.0
  N  N13  1  0.284  0.760  0.289  1.0
  N  N14  1  0.809  0.212  0.877  1.0
  N  N15  1  0.554  0.261  0.849  1.0
  Cl  Cl16  1  0.954  0.689  0.696  1.0
  Cl  Cl17  1  0.987  0.169  0.058  1.0
  Cl  Cl18  1  0.308  0.079  0.435  1.0
  Cl  Cl19  1  0.321  0.398  0.436  1.0
  Cl  Cl20  1  0.316  0.425  0.178  1.0
  Cl  Cl21  1  0.985  0.348  0.662  1.0
  Cl  Cl22  1  0.321  0.629  0.948  1.0
  Cl  Cl23  1  0.242  0.303  0.880  1.0
  Cl  Cl24  1  0.631  0.536  0.298  1.0
  Cl  Cl25  1  0.309  0.931  0.945  1.0
  Cl  Cl26  1  0.812  0.226  0.507  1.0
  Cl  Cl27  1  0.997  0.957  0.320  1.0
  Cl  Cl28  1  0.312  0.103  0.178  1.0
  Cl  Cl29  1  0.015  0.652  0.338  1.0
  Cl  Cl30  1  0.691  0.069  0.055  1.0
  Cl  Cl31  1  0.419  0.806  0.693  1.0
  Cl  Cl32  1  0.046  0.311  0.304  1.0
  Cl  Cl33  1  0.188  0.774  0.493  1.0
  Cl  Cl34  1  0.613  0.837  0.312  1.0
  Cl  Cl35  1  0.387  0.163  0.688  1.0
  Cl  Cl36  1  0.679  0.371  0.052  1.0
  Cl  Cl37  1  0.684  0.575  0.822  1.0
  Cl  Cl38  1  0.013  0.831  0.942  1.0
  Cl  Cl39  1  0.679  0.602  0.564  1.0
  Cl  Cl40  1  0.003  0.043  0.680  1.0
  Cl  Cl41  1  0.581  0.194  0.307  1.0
  Cl  Cl42  1  0.688  0.897  0.822  1.0
  Cl  Cl43  1  0.758  0.697  0.120  1.0
  Cl  Cl44  1  0.369  0.464  0.702  1.0
  Cl  Cl45  1  0.692  0.921  0.565  1.0
[/CIF]
.
The structure described by CP3(NCl3)3SbCl6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two CP3(NCl3)3 clusters and two SbCl6 clusters. In each CP3(NCl3)3 cluster, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are three inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one N(2), one Cl(11), one Cl(12), and one Cl(6) atom. In the second P site, P(2) is bonded in a tetrahedral geometry to one N(3), one Cl(15), one Cl(8), and one Cl(9) atom. In the third P site, P(3) is bonded in a tetrahedral geometry to one N(1), one Cl(10), one Cl(2), and one Cl(7) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one P(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one P(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one P(2) atom. There are nine inequivalent Cl sites. In the first Cl site, Cl(15) is bonded in a single-bond geometry to one P(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(3) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one P(1) atom. In the fourth Cl site, Cl(7) is bonded in a single-bond geometry to one P(3) atom. In the fifth Cl site, Cl(8) is bonded in a single-bond geometry to one P(2) atom. In the sixth Cl site, Cl(9) is bonded in a single-bond geometry to one P(2) atom. In the seventh Cl site, Cl(10) is bonded in a single-bond geometry to one P(3) atom. In the eighth Cl site, Cl(11) is bonded in a single-bond geometry to one P(1) atom. In the ninth Cl site, Cl(12) is bonded in a single-bond geometry to one P(1) atom. In each SbCl6 cluster, Sb(1) is bonded in an octahedral geometry to one Cl(1), one Cl(13), one Cl(14), one Cl(3), one Cl(4), and one Cl(5) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth Cl site, Cl(5) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth Cl site, Cl(13) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth Cl site, Cl(14) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_SbP3C(NCl5)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.226
_cell_length_b   10.488
_cell_length_c   13.207
_cell_angle_alpha   85.376
_cell_angle_beta   88.958
_cell_angle_gamma   76.829
_symmetry_Int_Tables_number   1
_cell_volume   1240.246
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.313  0.253  0.308  1.0
  Sb  Sb1  1  0.687  0.747  0.692  1.0
  P  P2  1  0.865  0.216  0.650  1.0
  P  P3  1  0.592  0.707  0.217  1.0
  P  P4  1  0.212  0.793  0.005  1.0
  P  P5  1  0.408  0.293  0.783  1.0
  P  P6  1  0.135  0.784  0.350  1.0
  P  P7  1  0.788  0.207  0.995  1.0
  C  C8  1  0.307  0.762  0.188  1.0
  C  C9  1  0.693  0.238  0.812  1.0
  N  N10  1  0.191  0.788  0.123  1.0
  N  N11  1  0.716  0.240  0.711  1.0
  N  N12  1  0.446  0.739  0.151  1.0
  N  N13  1  0.284  0.760  0.289  1.0
  N  N14  1  0.809  0.212  0.877  1.0
  N  N15  1  0.554  0.261  0.849  1.0
  Cl  Cl16  1  0.954  0.689  0.696  1.0
  Cl  Cl17  1  0.987  0.169  0.058  1.0
  Cl  Cl18  1  0.308  0.079  0.435  1.0
  Cl  Cl19  1  0.321  0.398  0.436  1.0
  Cl  Cl20  1  0.316  0.425  0.178  1.0
  Cl  Cl21  1  0.985  0.348  0.662  1.0
  Cl  Cl22  1  0.321  0.629  0.948  1.0
  Cl  Cl23  1  0.242  0.303  0.880  1.0
  Cl  Cl24  1  0.631  0.536  0.298  1.0
  Cl  Cl25  1  0.309  0.931  0.945  1.0
  Cl  Cl26  1  0.812  0.226  0.507  1.0
  Cl  Cl27  1  0.997  0.957  0.320  1.0
  Cl  Cl28  1  0.312  0.103  0.178  1.0
  Cl  Cl29  1  0.015  0.652  0.338  1.0
  Cl  Cl30  1  0.691  0.069  0.055  1.0
  Cl  Cl31  1  0.419  0.806  0.693  1.0
  Cl  Cl32  1  0.046  0.311  0.304  1.0
  Cl  Cl33  1  0.188  0.774  0.493  1.0
  Cl  Cl34  1  0.613  0.837  0.312  1.0
  Cl  Cl35  1  0.387  0.163  0.688  1.0
  Cl  Cl36  1  0.679  0.371  0.052  1.0
  Cl  Cl37  1  0.684  0.575  0.822  1.0
  Cl  Cl38  1  0.013  0.831  0.942  1.0
  Cl  Cl39  1  0.679  0.602  0.564  1.0
  Cl  Cl40  1  0.003  0.043  0.680  1.0
  Cl  Cl41  1  0.581  0.194  0.307  1.0
  Cl  Cl42  1  0.688  0.897  0.822  1.0
  Cl  Cl43  1  0.758  0.697  0.120  1.0
  Cl  Cl44  1  0.369  0.464  0.702  1.0
  Cl  Cl45  1  0.692  0.921  0.565  1.0
[/CIF]
.