The material structure described by Li2BiS2 crystallizes in the orthorhombic Imm2 space group. Li(1) is bonded to four equivalent S(1) atoms to form a mixture of corner and edge-sharing LiS4 tetrahedra. Bi(1) is bonded in a rectangular see-saw-like geometry to four equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to four equivalent Li(1) and two equivalent Bi(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2BiS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.286
_cell_length_b   7.286
_cell_length_c   7.286
_cell_angle_alpha   148.012
_cell_angle_beta   147.524
_cell_angle_gamma   46.230
_symmetry_Int_Tables_number   1
_cell_volume   109.643
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.260  0.264  0.003  1.0
  Li  Li1  1  0.740  0.743  0.003  1.0
  Bi  Bi2  1  0.000  0.016  0.016  1.0
  S  S3  1  0.852  0.365  0.513  1.0
  S  S4  1  0.148  0.661  0.513  1.0
[/CIF]
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The material structure described by Li2BiS2 crystallizes in the orthorhombic Imm2 space group. Li(1) is bonded to four equivalent S(1) atoms to form a mixture of corner and edge-sharing LiS4 tetrahedra. Bi(1) is bonded in a rectangular see-saw-like geometry to four equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to four equivalent Li(1) and two equivalent Bi(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2BiS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.286
_cell_length_b   7.286
_cell_length_c   7.286
_cell_angle_alpha   148.012
_cell_angle_beta   147.524
_cell_angle_gamma   46.230
_symmetry_Int_Tables_number   1
_cell_volume   109.643
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.260  0.264  0.003  1.0
  Li  Li1  1  0.740  0.743  0.003  1.0
  Bi  Bi2  1  0.000  0.016  0.016  1.0
  S  S3  1  0.852  0.365  0.513  1.0
  S  S4  1  0.148  0.661  0.513  1.0
[/CIF]
.