The structure described by HSbO3 crystallizes in the tetragonal I4_1/amd space group. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 41-48°. H(1) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Sb(1) and one H(1) atom. In the second O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_SbHO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.360
_cell_length_b   7.360
_cell_length_c   7.360
_cell_angle_alpha   117.607
_cell_angle_beta   117.607
_cell_angle_gamma   94.198
_symmetry_Int_Tables_number   1
_cell_volume   291.302
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.875  0.625  0.750  1.0
  Sb  Sb1  1  0.375  0.125  0.250  1.0
  Sb  Sb2  1  0.875  0.125  0.750  1.0
  Sb  Sb3  1  0.875  0.125  0.250  1.0
  H  H4  1  0.692  0.692  0.000  1.0
  H  H5  1  0.308  0.308  0.000  1.0
  H  H6  1  0.058  0.558  0.500  1.0
  H  H7  1  0.442  0.942  0.500  1.0
  O  O8  1  0.812  0.188  0.000  1.0
  O  O9  1  0.188  0.812  0.000  1.0
  O  O10  1  0.188  0.188  0.377  1.0
  O  O11  1  0.812  0.812  0.623  1.0
  O  O12  1  0.790  0.790  0.000  1.0
  O  O13  1  0.210  0.210  0.000  1.0
  O  O14  1  0.938  0.062  0.500  1.0
  O  O15  1  0.562  0.438  0.500  1.0
  O  O16  1  0.562  0.062  0.123  1.0
  O  O17  1  0.938  0.438  0.877  1.0
  O  O18  1  0.960  0.460  0.500  1.0
  O  O19  1  0.540  0.040  0.500  1.0
[/CIF]
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The structure described by HSbO3 crystallizes in the tetragonal I4_1/amd space group. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form corner-sharing SbO6 octahedra. The corner-sharing octahedral tilt angles range from 41-48°. H(1) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Sb(1) and one H(1) atom. In the second O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_SbHO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.360
_cell_length_b   7.360
_cell_length_c   7.360
_cell_angle_alpha   117.607
_cell_angle_beta   117.607
_cell_angle_gamma   94.198
_symmetry_Int_Tables_number   1
_cell_volume   291.302
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.875  0.625  0.750  1.0
  Sb  Sb1  1  0.375  0.125  0.250  1.0
  Sb  Sb2  1  0.875  0.125  0.750  1.0
  Sb  Sb3  1  0.875  0.125  0.250  1.0
  H  H4  1  0.692  0.692  0.000  1.0
  H  H5  1  0.308  0.308  0.000  1.0
  H  H6  1  0.058  0.558  0.500  1.0
  H  H7  1  0.442  0.942  0.500  1.0
  O  O8  1  0.812  0.188  0.000  1.0
  O  O9  1  0.188  0.812  0.000  1.0
  O  O10  1  0.188  0.188  0.377  1.0
  O  O11  1  0.812  0.812  0.623  1.0
  O  O12  1  0.790  0.790  0.000  1.0
  O  O13  1  0.210  0.210  0.000  1.0
  O  O14  1  0.938  0.062  0.500  1.0
  O  O15  1  0.562  0.438  0.500  1.0
  O  O16  1  0.562  0.062  0.123  1.0
  O  O17  1  0.938  0.438  0.877  1.0
  O  O18  1  0.960  0.460  0.500  1.0
  O  O19  1  0.540  0.040  0.500  1.0
[/CIF]
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