The material described by (PtS2O9)2N2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonia atoms and one PtS2O9 cluster. In the PtS2O9 cluster, Pt(1) is bonded to one O(1), one O(2), one O(7), one O(8), and one O(9) atom to form PtO5 square pyramids that share corners with two equivalent S(1)O4 tetrahedra and corners with two equivalent S(2)O4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with two equivalent Pt(1)O5 square pyramids. In the second S site, S(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form SO4 tetrahedra that share corners with two equivalent Pt(1)O5 square pyramids. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(2) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PtS2NO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.663
_cell_length_b   7.731
_cell_length_c   7.821
_cell_angle_alpha   102.548
_cell_angle_beta   110.262
_cell_angle_gamma   100.540
_symmetry_Int_Tables_number   1
_cell_volume   407.054
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.633  0.956  0.125  1.0
  Pt  Pt1  1  0.367  0.044  0.875  1.0
  S  S2  1  0.718  0.381  0.175  1.0
  S  S3  1  0.282  0.619  0.825  1.0
  S  S4  1  0.700  0.958  0.750  1.0
  S  S5  1  0.300  0.042  0.250  1.0
  N  N6  1  0.724  0.473  0.725  1.0
  N  N7  1  0.276  0.527  0.275  1.0
  O  O8  1  0.549  0.300  0.969  1.0
  O  O9  1  0.451  0.700  0.031  1.0
  O  O10  1  0.806  0.217  0.211  1.0
  O  O11  1  0.194  0.783  0.789  1.0
  O  O12  1  0.638  0.436  0.313  1.0
  O  O13  1  0.362  0.564  0.687  1.0
  O  O14  1  0.865  0.518  0.162  1.0
  O  O15  1  0.135  0.482  0.838  1.0
  O  O16  1  0.709  0.818  0.602  1.0
  O  O17  1  0.291  0.182  0.398  1.0
  O  O18  1  0.823  0.144  0.807  1.0
  O  O19  1  0.177  0.856  0.193  1.0
  O  O20  1  0.742  0.885  0.929  1.0
  O  O21  1  0.258  0.115  0.071  1.0
  O  O22  1  0.482  0.962  0.685  1.0
  O  O23  1  0.518  0.038  0.315  1.0
  O  O24  1  0.838  0.892  0.317  1.0
  O  O25  1  0.162  0.108  0.683  1.0
[/CIF]
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The material described by (PtS2O9)2N2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ammonia atoms and one PtS2O9 cluster. In the PtS2O9 cluster, Pt(1) is bonded to one O(1), one O(2), one O(7), one O(8), and one O(9) atom to form PtO5 square pyramids that share corners with two equivalent S(1)O4 tetrahedra and corners with two equivalent S(2)O4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with two equivalent Pt(1)O5 square pyramids. In the second S site, S(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form SO4 tetrahedra that share corners with two equivalent Pt(1)O5 square pyramids. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Pt(1) and one S(2) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PtS2NO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.663
_cell_length_b   7.731
_cell_length_c   7.821
_cell_angle_alpha   102.548
_cell_angle_beta   110.262
_cell_angle_gamma   100.540
_symmetry_Int_Tables_number   1
_cell_volume   407.054
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.633  0.956  0.125  1.0
  Pt  Pt1  1  0.367  0.044  0.875  1.0
  S  S2  1  0.718  0.381  0.175  1.0
  S  S3  1  0.282  0.619  0.825  1.0
  S  S4  1  0.700  0.958  0.750  1.0
  S  S5  1  0.300  0.042  0.250  1.0
  N  N6  1  0.724  0.473  0.725  1.0
  N  N7  1  0.276  0.527  0.275  1.0
  O  O8  1  0.549  0.300  0.969  1.0
  O  O9  1  0.451  0.700  0.031  1.0
  O  O10  1  0.806  0.217  0.211  1.0
  O  O11  1  0.194  0.783  0.789  1.0
  O  O12  1  0.638  0.436  0.313  1.0
  O  O13  1  0.362  0.564  0.687  1.0
  O  O14  1  0.865  0.518  0.162  1.0
  O  O15  1  0.135  0.482  0.838  1.0
  O  O16  1  0.709  0.818  0.602  1.0
  O  O17  1  0.291  0.182  0.398  1.0
  O  O18  1  0.823  0.144  0.807  1.0
  O  O19  1  0.177  0.856  0.193  1.0
  O  O20  1  0.742  0.885  0.929  1.0
  O  O21  1  0.258  0.115  0.071  1.0
  O  O22  1  0.482  0.962  0.685  1.0
  O  O23  1  0.518  0.038  0.315  1.0
  O  O24  1  0.838  0.892  0.317  1.0
  O  O25  1  0.162  0.108  0.683  1.0
[/CIF]
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