The structure described by Pr2(WO4)3 crystallizes in the monoclinic C2/c space group. Pr(1) is bonded in a 8-coordinate geometry to one O(2), one O(4), one O(5), one O(6), two equivalent O(1), and two equivalent O(3) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 5-coordinate geometry to one O(3), one O(5), one O(6), and two equivalent O(4) atoms. In the second W site, W(2) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are six inequivalent O sites. In the first O site, O(4) is bonded in a trigonal non-coplanar geometry to one Pr(1) and two equivalent W(1) atoms. In the second O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one W(1) atom. In the third O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one W(1) atom. In the fourth O site, O(1) is bonded in a trigonal planar geometry to two equivalent Pr(1) and one W(2) atom. In the fifth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one W(2) atom. In the sixth O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Pr(1) and one W(1) atom. is represented by the CIF card [CIF]
data_Pr2(WO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.130
_cell_length_b   7.130
_cell_length_c   11.780
_cell_angle_alpha   79.179
_cell_angle_beta   79.179
_cell_angle_gamma   111.890
_symmetry_Int_Tables_number   1
_cell_volume   523.495
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.194  0.447  0.594  1.0
  Pr  Pr1  1  0.806  0.553  0.406  1.0
  Pr  Pr2  1  0.553  0.806  0.906  1.0
  Pr  Pr3  1  0.447  0.194  0.094  1.0
  W  W4  1  0.009  0.300  0.952  1.0
  W  W5  1  0.991  0.700  0.048  1.0
  W  W6  1  0.700  0.991  0.548  1.0
  W  W7  1  0.300  0.009  0.452  1.0
  W  W8  1  0.618  0.382  0.750  1.0
  W  W9  1  0.382  0.618  0.250  1.0
  O  O10  1  0.551  0.468  0.611  1.0
  O  O11  1  0.449  0.532  0.389  1.0
  O  O12  1  0.532  0.449  0.889  1.0
  O  O13  1  0.468  0.551  0.111  1.0
  O  O14  1  0.514  0.100  0.781  1.0
  O  O15  1  0.486  0.900  0.219  1.0
  O  O16  1  0.900  0.486  0.719  1.0
  O  O17  1  0.100  0.514  0.281  1.0
  O  O18  1  0.729  0.128  0.961  1.0
  O  O19  1  0.271  0.872  0.039  1.0
  O  O20  1  0.872  0.271  0.539  1.0
  O  O21  1  0.128  0.729  0.461  1.0
  O  O22  1  0.401  0.829  0.575  1.0
  O  O23  1  0.599  0.171  0.425  1.0
  O  O24  1  0.171  0.599  0.925  1.0
  O  O25  1  0.829  0.401  0.075  1.0
  O  O26  1  0.148  0.297  0.805  1.0
  O  O27  1  0.852  0.703  0.195  1.0
  O  O28  1  0.703  0.852  0.695  1.0
  O  O29  1  0.297  0.148  0.305  1.0
  O  O30  1  0.894  0.824  0.943  1.0
  O  O31  1  0.106  0.176  0.057  1.0
  O  O32  1  0.176  0.106  0.557  1.0
  O  O33  1  0.824  0.894  0.443  1.0
[/CIF]
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The structure described by Pr2(WO4)3 crystallizes in the monoclinic C2/c space group. Pr(1) is bonded in a 8-coordinate geometry to one O(2), one O(4), one O(5), one O(6), two equivalent O(1), and two equivalent O(3) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 5-coordinate geometry to one O(3), one O(5), one O(6), and two equivalent O(4) atoms. In the second W site, W(2) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. There are six inequivalent O sites. In the first O site, O(4) is bonded in a trigonal non-coplanar geometry to one Pr(1) and two equivalent W(1) atoms. In the second O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one W(1) atom. In the third O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one W(1) atom. In the fourth O site, O(1) is bonded in a trigonal planar geometry to two equivalent Pr(1) and one W(2) atom. In the fifth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one W(2) atom. In the sixth O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Pr(1) and one W(1) atom. is represented by the CIF card [CIF]
data_Pr2(WO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.130
_cell_length_b   7.130
_cell_length_c   11.780
_cell_angle_alpha   79.179
_cell_angle_beta   79.179
_cell_angle_gamma   111.890
_symmetry_Int_Tables_number   1
_cell_volume   523.495
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.194  0.447  0.594  1.0
  Pr  Pr1  1  0.806  0.553  0.406  1.0
  Pr  Pr2  1  0.553  0.806  0.906  1.0
  Pr  Pr3  1  0.447  0.194  0.094  1.0
  W  W4  1  0.009  0.300  0.952  1.0
  W  W5  1  0.991  0.700  0.048  1.0
  W  W6  1  0.700  0.991  0.548  1.0
  W  W7  1  0.300  0.009  0.452  1.0
  W  W8  1  0.618  0.382  0.750  1.0
  W  W9  1  0.382  0.618  0.250  1.0
  O  O10  1  0.551  0.468  0.611  1.0
  O  O11  1  0.449  0.532  0.389  1.0
  O  O12  1  0.532  0.449  0.889  1.0
  O  O13  1  0.468  0.551  0.111  1.0
  O  O14  1  0.514  0.100  0.781  1.0
  O  O15  1  0.486  0.900  0.219  1.0
  O  O16  1  0.900  0.486  0.719  1.0
  O  O17  1  0.100  0.514  0.281  1.0
  O  O18  1  0.729  0.128  0.961  1.0
  O  O19  1  0.271  0.872  0.039  1.0
  O  O20  1  0.872  0.271  0.539  1.0
  O  O21  1  0.128  0.729  0.461  1.0
  O  O22  1  0.401  0.829  0.575  1.0
  O  O23  1  0.599  0.171  0.425  1.0
  O  O24  1  0.171  0.599  0.925  1.0
  O  O25  1  0.829  0.401  0.075  1.0
  O  O26  1  0.148  0.297  0.805  1.0
  O  O27  1  0.852  0.703  0.195  1.0
  O  O28  1  0.703  0.852  0.695  1.0
  O  O29  1  0.297  0.148  0.305  1.0
  O  O30  1  0.894  0.824  0.943  1.0
  O  O31  1  0.106  0.176  0.057  1.0
  O  O32  1  0.176  0.106  0.557  1.0
  O  O33  1  0.824  0.894  0.443  1.0
[/CIF]
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