The material structure described by MgMo10Ag6O33 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a distorted tetrahedral geometry to one O(16), one O(20), one O(28), and one O(8) atom. There are ten inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(18), one O(24), one O(25), one O(29), one O(30), and one O(33) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(19), one O(24), one O(25), one O(28), one O(31), and one O(32) atom. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(20), one O(22), one O(23), one O(27), one O(30), and one O(33) atom. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(21), one O(22), one O(23), one O(26), one O(31), and one O(32) atom. In the fifth Mo site, Mo(5) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(2), one O(4), and one O(8) atom. In the sixth Mo site, Mo(6) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(17), one O(3), one O(5), and one O(9) atom. In the seventh Mo site, Mo(7) is bonded in a 6-coordinate geometry to one O(1), one O(13), one O(14), one O(3), one O(4), and one O(6) atom. In the eighth Mo site, Mo(8) is bonded in a 5-coordinate geometry to one O(12), one O(15), one O(2), one O(5), and one O(7) atom. In the ninth Mo site, Mo(9) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(22), one O(24), one O(30), and one O(32) atom. In the tenth Mo site, Mo(10) is bonded in a 6-coordinate geometry to one O(15), one O(17), one O(23), one O(25), one O(31), and one O(33) atom. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(22), one O(24), and one O(4) atom. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(13), one O(23), and one O(25) atom. In the third Ag site, Ag(3) is bonded in a rectangular see-saw-like geometry to one O(10), one O(18), one O(20), and one O(6) atom. In the fourth Ag site, Ag(4) is bonded in a 5-coordinate geometry to one O(11), one O(19), one O(21), one O(3), and one O(7) atom. In the fifth Ag site, Ag(5) is bonded in a 5-coordinate geometry to one O(12), one O(18), one O(26), one O(28), and one O(8) atom. In the sixth Ag site, Ag(6) is bonded in a 4-coordinate geometry to one O(13), one O(19), one O(29), and one O(9) atom. There are thirty-three inequivalent O sites. In the first O site, O(1) is bonded in a T-shaped geometry to one Mo(5), one Mo(6), and one Mo(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mo(5) and one Mo(8) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Mo(6), one Mo(7), and one Ag(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mo(5), one Mo(7), and one Ag(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mo(6) and one Mo(8) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(7) and one Ag(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Mo(8) and one Ag(4) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Mg(1), one Mo(5), and one Ag(5) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mo(6) and one Ag(6) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Mo(6), one Ag(1), and one Ag(3) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Mo(5), one Ag(2), and one Ag(4) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Mo(8), one Ag(1), and one Ag(5) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Mo(7), one Ag(2), and one Ag(6) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Mo(7) and one Mo(9) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Mo(10) and one Mo(8) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one Mo(9) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Mo(10) and one Mo(6) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Mo(1), one Ag(3), and one Ag(5) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Mo(2), one Ag(4), and one Ag(6) atom. In the twentieth O site, O(20) is bonded in a trigonal planar geometry to one Mg(1), one Mo(3), and one Ag(3) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Mo(4) and one Ag(4) atom. In the twenty-second O site, O(22) is bonded to one Mo(3), one Mo(4), one Mo(9), and one Ag(1) atom to form a mixture of distorted corner and edge-sharing OAgMo3 tetrahedra. In the twenty-third O site, O(23) is bonded to one Mo(10), one Mo(3), one Mo(4), and one Ag(2) atom to form a mixture of corner and edge-sharing OAgMo3 tetrahedra. In the twenty-fourth O site, O(24) is bonded to one Mo(1), one Mo(2), one Mo(9), and one Ag(1) atom to form a mixture of corner and edge-sharing OAgMo3 tetrahedra. In the twenty-fifth O site, O(25) is bonded to one Mo(1), one Mo(10), one Mo(2), and one Ag(2) atom to form a mixture of corner and edge-sharing OAgMo3 tetrahedra. In the twenty-sixth O site, O(26) is bonded in a distorted bent 120 degrees geometry to one Mo(4) and one Ag(5) atom. In the twenty-seventh O site, O(27) is bonded in a single-bond geometry to one Mo(3) atom. In the twenty-eighth O site, O(28) is bonded in a distorted trigonal planar geometry to one Mg(1), one Mo(2), and one Ag(5) atom. In the twenty-ninth O site, O(29) is bonded in a bent 150 degrees geometry to one Mo(1) and one Ag(6) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(3), and one Mo(9) atom. In the thirty-first O site, O(31) is bonded in a distorted T-shaped geometry to one Mo(10), one Mo(2), and one Mo(4) atom. In the thirty-second O site, O(32) is bonded in a 3-coordinate geometry to one Mo(2), one Mo(4), and one Mo(9) atom. In the thirty-third O site, O(33) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(10), and one Mo(3) atom. is represented by the CIF file [CIF]
data_MgAg6Mo10O33
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.758
_cell_length_b   8.714
_cell_length_c   11.691
_cell_angle_alpha   77.307
_cell_angle_beta   76.531
_cell_angle_gamma   74.978
_symmetry_Int_Tables_number   1
_cell_volume   731.582
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.859  0.609  0.308  1.0
  Ag  Ag1  1  0.348  0.998  0.249  1.0
  Ag  Ag2  1  0.660  0.004  0.748  1.0
  Ag  Ag3  1  0.241  0.356  0.204  1.0
  Ag  Ag4  1  0.802  0.564  0.812  1.0
  Ag  Ag5  1  0.448  0.646  0.291  1.0
  Ag  Ag6  1  0.496  0.422  0.745  1.0
  Mo  Mo7  1  0.452  0.232  0.475  1.0
  Mo  Mo8  1  0.558  0.792  0.533  1.0
  Mo  Mo9  1  0.951  0.227  0.483  1.0
  Mo  Mo10  1  0.060  0.777  0.527  1.0
  Mo  Mo11  1  0.843  0.815  0.041  1.0
  Mo  Mo12  1  0.137  0.188  0.950  1.0
  Mo  Mo13  1  0.701  0.192  0.009  1.0
  Mo  Mo14  1  0.308  0.779  0.981  1.0
  Mo  Mo15  1  0.817  0.018  0.322  1.0
  Mo  Mo16  1  0.192  0.998  0.679  1.0
  O  O17  1  0.955  0.012  0.997  1.0
  O  O18  1  0.098  0.692  0.027  1.0
  O  O19  1  0.888  0.321  0.955  1.0
  O  O20  1  0.636  0.986  0.091  1.0
  O  O21  1  0.331  0.994  0.916  1.0
  O  O22  1  0.505  0.320  0.075  1.0
  O  O23  1  0.492  0.639  0.921  1.0
  O  O24  1  0.770  0.652  0.149  1.0
  O  O25  1  0.251  0.339  0.873  1.0
  O  O26  1  0.168  0.170  0.097  1.0
  O  O27  1  0.792  0.800  0.906  1.0
  O  O28  1  0.347  0.775  0.125  1.0
  O  O29  1  0.656  0.193  0.867  1.0
  O  O30  1  0.791  0.168  0.196  1.0
  O  O31  1  0.214  0.829  0.794  1.0
  O  O32  1  0.895  0.839  0.252  1.0
  O  O33  1  0.114  0.156  0.763  1.0
  O  O34  1  0.426  0.371  0.342  1.0
  O  O35  1  0.590  0.657  0.666  1.0
  O  O36  1  0.989  0.386  0.340  1.0
  O  O37  1  0.023  0.637  0.658  1.0
  O  O38  1  0.035  0.022  0.374  1.0
  O  O39  1  0.976  0.998  0.620  1.0
  O  O40  1  0.556  0.010  0.383  1.0
  O  O41  1  0.455  0.002  0.624  1.0
  O  O42  1  0.153  0.661  0.413  1.0
  O  O43  1  0.835  0.337  0.594  1.0
  O  O44  1  0.623  0.663  0.412  1.0
  O  O45  1  0.420  0.350  0.584  1.0
  O  O46  1  0.719  0.182  0.447  1.0
  O  O47  1  0.286  0.829  0.542  1.0
  O  O48  1  0.815  0.839  0.497  1.0
  O  O49  1  0.213  0.176  0.506  1.0
[/CIF]
.
The material structure described by MgMo10Ag6O33 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a distorted tetrahedral geometry to one O(16), one O(20), one O(28), and one O(8) atom. There are ten inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(18), one O(24), one O(25), one O(29), one O(30), and one O(33) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(19), one O(24), one O(25), one O(28), one O(31), and one O(32) atom. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(20), one O(22), one O(23), one O(27), one O(30), and one O(33) atom. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(21), one O(22), one O(23), one O(26), one O(31), and one O(32) atom. In the fifth Mo site, Mo(5) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(2), one O(4), and one O(8) atom. In the sixth Mo site, Mo(6) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(17), one O(3), one O(5), and one O(9) atom. In the seventh Mo site, Mo(7) is bonded in a 6-coordinate geometry to one O(1), one O(13), one O(14), one O(3), one O(4), and one O(6) atom. In the eighth Mo site, Mo(8) is bonded in a 5-coordinate geometry to one O(12), one O(15), one O(2), one O(5), and one O(7) atom. In the ninth Mo site, Mo(9) is bonded in a 6-coordinate geometry to one O(14), one O(16), one O(22), one O(24), one O(30), and one O(32) atom. In the tenth Mo site, Mo(10) is bonded in a 6-coordinate geometry to one O(15), one O(17), one O(23), one O(25), one O(31), and one O(33) atom. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(22), one O(24), and one O(4) atom. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(13), one O(23), and one O(25) atom. In the third Ag site, Ag(3) is bonded in a rectangular see-saw-like geometry to one O(10), one O(18), one O(20), and one O(6) atom. In the fourth Ag site, Ag(4) is bonded in a 5-coordinate geometry to one O(11), one O(19), one O(21), one O(3), and one O(7) atom. In the fifth Ag site, Ag(5) is bonded in a 5-coordinate geometry to one O(12), one O(18), one O(26), one O(28), and one O(8) atom. In the sixth Ag site, Ag(6) is bonded in a 4-coordinate geometry to one O(13), one O(19), one O(29), and one O(9) atom. There are thirty-three inequivalent O sites. In the first O site, O(1) is bonded in a T-shaped geometry to one Mo(5), one Mo(6), and one Mo(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mo(5) and one Mo(8) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Mo(6), one Mo(7), and one Ag(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mo(5), one Mo(7), and one Ag(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mo(6) and one Mo(8) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(7) and one Ag(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Mo(8) and one Ag(4) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Mg(1), one Mo(5), and one Ag(5) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mo(6) and one Ag(6) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Mo(6), one Ag(1), and one Ag(3) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Mo(5), one Ag(2), and one Ag(4) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Mo(8), one Ag(1), and one Ag(5) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Mo(7), one Ag(2), and one Ag(6) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Mo(7) and one Mo(9) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Mo(10) and one Mo(8) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one Mo(9) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Mo(10) and one Mo(6) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Mo(1), one Ag(3), and one Ag(5) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Mo(2), one Ag(4), and one Ag(6) atom. In the twentieth O site, O(20) is bonded in a trigonal planar geometry to one Mg(1), one Mo(3), and one Ag(3) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Mo(4) and one Ag(4) atom. In the twenty-second O site, O(22) is bonded to one Mo(3), one Mo(4), one Mo(9), and one Ag(1) atom to form a mixture of distorted corner and edge-sharing OAgMo3 tetrahedra. In the twenty-third O site, O(23) is bonded to one Mo(10), one Mo(3), one Mo(4), and one Ag(2) atom to form a mixture of corner and edge-sharing OAgMo3 tetrahedra. In the twenty-fourth O site, O(24) is bonded to one Mo(1), one Mo(2), one Mo(9), and one Ag(1) atom to form a mixture of corner and edge-sharing OAgMo3 tetrahedra. In the twenty-fifth O site, O(25) is bonded to one Mo(1), one Mo(10), one Mo(2), and one Ag(2) atom to form a mixture of corner and edge-sharing OAgMo3 tetrahedra. In the twenty-sixth O site, O(26) is bonded in a distorted bent 120 degrees geometry to one Mo(4) and one Ag(5) atom. In the twenty-seventh O site, O(27) is bonded in a single-bond geometry to one Mo(3) atom. In the twenty-eighth O site, O(28) is bonded in a distorted trigonal planar geometry to one Mg(1), one Mo(2), and one Ag(5) atom. In the twenty-ninth O site, O(29) is bonded in a bent 150 degrees geometry to one Mo(1) and one Ag(6) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(3), and one Mo(9) atom. In the thirty-first O site, O(31) is bonded in a distorted T-shaped geometry to one Mo(10), one Mo(2), and one Mo(4) atom. In the thirty-second O site, O(32) is bonded in a 3-coordinate geometry to one Mo(2), one Mo(4), and one Mo(9) atom. In the thirty-third O site, O(33) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(10), and one Mo(3) atom. is represented by the CIF file [CIF]
data_MgAg6Mo10O33
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.758
_cell_length_b   8.714
_cell_length_c   11.691
_cell_angle_alpha   77.307
_cell_angle_beta   76.531
_cell_angle_gamma   74.978
_symmetry_Int_Tables_number   1
_cell_volume   731.582
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.859  0.609  0.308  1.0
  Ag  Ag1  1  0.348  0.998  0.249  1.0
  Ag  Ag2  1  0.660  0.004  0.748  1.0
  Ag  Ag3  1  0.241  0.356  0.204  1.0
  Ag  Ag4  1  0.802  0.564  0.812  1.0
  Ag  Ag5  1  0.448  0.646  0.291  1.0
  Ag  Ag6  1  0.496  0.422  0.745  1.0
  Mo  Mo7  1  0.452  0.232  0.475  1.0
  Mo  Mo8  1  0.558  0.792  0.533  1.0
  Mo  Mo9  1  0.951  0.227  0.483  1.0
  Mo  Mo10  1  0.060  0.777  0.527  1.0
  Mo  Mo11  1  0.843  0.815  0.041  1.0
  Mo  Mo12  1  0.137  0.188  0.950  1.0
  Mo  Mo13  1  0.701  0.192  0.009  1.0
  Mo  Mo14  1  0.308  0.779  0.981  1.0
  Mo  Mo15  1  0.817  0.018  0.322  1.0
  Mo  Mo16  1  0.192  0.998  0.679  1.0
  O  O17  1  0.955  0.012  0.997  1.0
  O  O18  1  0.098  0.692  0.027  1.0
  O  O19  1  0.888  0.321  0.955  1.0
  O  O20  1  0.636  0.986  0.091  1.0
  O  O21  1  0.331  0.994  0.916  1.0
  O  O22  1  0.505  0.320  0.075  1.0
  O  O23  1  0.492  0.639  0.921  1.0
  O  O24  1  0.770  0.652  0.149  1.0
  O  O25  1  0.251  0.339  0.873  1.0
  O  O26  1  0.168  0.170  0.097  1.0
  O  O27  1  0.792  0.800  0.906  1.0
  O  O28  1  0.347  0.775  0.125  1.0
  O  O29  1  0.656  0.193  0.867  1.0
  O  O30  1  0.791  0.168  0.196  1.0
  O  O31  1  0.214  0.829  0.794  1.0
  O  O32  1  0.895  0.839  0.252  1.0
  O  O33  1  0.114  0.156  0.763  1.0
  O  O34  1  0.426  0.371  0.342  1.0
  O  O35  1  0.590  0.657  0.666  1.0
  O  O36  1  0.989  0.386  0.340  1.0
  O  O37  1  0.023  0.637  0.658  1.0
  O  O38  1  0.035  0.022  0.374  1.0
  O  O39  1  0.976  0.998  0.620  1.0
  O  O40  1  0.556  0.010  0.383  1.0
  O  O41  1  0.455  0.002  0.624  1.0
  O  O42  1  0.153  0.661  0.413  1.0
  O  O43  1  0.835  0.337  0.594  1.0
  O  O44  1  0.623  0.663  0.412  1.0
  O  O45  1  0.420  0.350  0.584  1.0
  O  O46  1  0.719  0.182  0.447  1.0
  O  O47  1  0.286  0.829  0.542  1.0
  O  O48  1  0.815  0.839  0.497  1.0
  O  O49  1  0.213  0.176  0.506  1.0
[/CIF]
.