The material described by Lu(RhB)4 crystallizes in the orthorhombic Ccce space group. There are two inequivalent Lu sites. In the first Lu site, Lu(1) is bonded in a 24-coordinate geometry to four equivalent Rh(2), eight equivalent Rh(1), four equivalent B(3), and eight equivalent B(1) atoms. In the second Lu site, Lu(2) is bonded in a 24-coordinate geometry to two equivalent Rh(1), four equivalent Rh(2), six equivalent Rh(3), two equivalent B(1), four equivalent B(3), and six equivalent B(2) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(2) is bonded in a 6-coordinate geometry to one Lu(1), two equivalent Lu(2), one B(1), one B(2), and three equivalent B(3) atoms. In the second Rh site, Rh(3) is bonded in a 5-coordinate geometry to three equivalent Lu(2), one B(3), and four equivalent B(2) atoms. In the third Rh site, Rh(1) is bonded in a 5-coordinate geometry to one Lu(2), two equivalent Lu(1), one B(3), and four equivalent B(1) atoms. There are three inequivalent B sites. In the first B site, B(1) is bonded in a 6-coordinate geometry to one Lu(2), two equivalent Lu(1), one Rh(2), four equivalent Rh(1), and one B(3) atom. In the second B site, B(2) is bonded in a 6-coordinate geometry to three equivalent Lu(2), one Rh(2), four equivalent Rh(3), and one B(2) atom. In the third B site, B(3) is bonded in a 6-coordinate geometry to one Lu(1), two equivalent Lu(2), one Rh(1), one Rh(3), three equivalent Rh(2), and one B(1) atom. is represented by the CIF card [CIF]
data_Lu(BRh)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.805
_cell_length_b   11.805
_cell_length_c   7.513
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   142.921
_symmetry_Int_Tables_number   1
_cell_volume   631.280
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Lu  Lu0  1  0.000  0.000  0.500  1.0
  Lu  Lu1  1  0.500  0.500  0.000  1.0
  Lu  Lu2  1  0.667  0.333  0.500  1.0
  Lu  Lu3  1  0.333  0.667  0.500  1.0
  Lu  Lu4  1  0.833  0.167  0.000  1.0
  Lu  Lu5  1  0.167  0.833  0.000  1.0
  B  B6  1  0.409  0.302  0.334  1.0
  B  B7  1  0.302  0.409  0.666  1.0
  B  B8  1  0.591  0.698  0.334  1.0
  B  B9  1  0.698  0.591  0.666  1.0
  B  B10  1  0.091  0.198  0.166  1.0
  B  B11  1  0.198  0.091  0.834  1.0
  B  B12  1  0.948  0.391  0.636  1.0
  B  B13  1  0.391  0.948  0.364  1.0
  B  B14  1  0.052  0.609  0.636  1.0
  B  B15  1  0.609  0.052  0.364  1.0
  B  B16  1  0.552  0.109  0.864  1.0
  B  B17  1  0.109  0.552  0.136  1.0
  B  B18  1  0.448  0.891  0.864  1.0
  B  B19  1  0.891  0.448  0.136  1.0
  B  B20  1  0.027  0.247  0.328  1.0
  B  B21  1  0.247  0.027  0.672  1.0
  B  B22  1  0.973  0.753  0.328  1.0
  B  B23  1  0.753  0.973  0.672  1.0
  B  B24  1  0.473  0.253  0.172  1.0
  B  B25  1  0.253  0.473  0.828  1.0
  B  B26  1  0.527  0.747  0.172  1.0
  B  B27  1  0.747  0.527  0.828  1.0
  B  B28  1  0.909  0.802  0.166  1.0
  B  B29  1  0.802  0.909  0.834  1.0
  Rh  Rh30  1  0.106  0.192  0.876  1.0
  Rh  Rh31  1  0.192  0.106  0.124  1.0
  Rh  Rh32  1  0.606  0.692  0.624  1.0
  Rh  Rh33  1  0.692  0.606  0.376  1.0
  Rh  Rh34  1  0.394  0.308  0.624  1.0
  Rh  Rh35  1  0.308  0.394  0.376  1.0
  Rh  Rh36  1  0.029  0.280  0.614  1.0
  Rh  Rh37  1  0.280  0.029  0.386  1.0
  Rh  Rh38  1  0.971  0.720  0.614  1.0
  Rh  Rh39  1  0.720  0.971  0.386  1.0
  Rh  Rh40  1  0.471  0.220  0.886  1.0
  Rh  Rh41  1  0.220  0.471  0.114  1.0
  Rh  Rh42  1  0.529  0.780  0.886  1.0
  Rh  Rh43  1  0.780  0.529  0.114  1.0
  Rh  Rh44  1  0.908  0.325  0.344  1.0
  Rh  Rh45  1  0.325  0.908  0.656  1.0
  Rh  Rh46  1  0.092  0.675  0.344  1.0
  Rh  Rh47  1  0.675  0.092  0.656  1.0
  Rh  Rh48  1  0.592  0.175  0.156  1.0
  Rh  Rh49  1  0.175  0.592  0.844  1.0
  Rh  Rh50  1  0.408  0.825  0.156  1.0
  Rh  Rh51  1  0.825  0.408  0.844  1.0
  Rh  Rh52  1  0.808  0.894  0.124  1.0
  Rh  Rh53  1  0.894  0.808  0.876  1.0
[/CIF]
.
The material described by Lu(RhB)4 crystallizes in the orthorhombic Ccce space group. There are two inequivalent Lu sites. In the first Lu site, Lu(1) is bonded in a 24-coordinate geometry to four equivalent Rh(2), eight equivalent Rh(1), four equivalent B(3), and eight equivalent B(1) atoms. In the second Lu site, Lu(2) is bonded in a 24-coordinate geometry to two equivalent Rh(1), four equivalent Rh(2), six equivalent Rh(3), two equivalent B(1), four equivalent B(3), and six equivalent B(2) atoms. There are three inequivalent Rh sites. In the first Rh site, Rh(2) is bonded in a 6-coordinate geometry to one Lu(1), two equivalent Lu(2), one B(1), one B(2), and three equivalent B(3) atoms. In the second Rh site, Rh(3) is bonded in a 5-coordinate geometry to three equivalent Lu(2), one B(3), and four equivalent B(2) atoms. In the third Rh site, Rh(1) is bonded in a 5-coordinate geometry to one Lu(2), two equivalent Lu(1), one B(3), and four equivalent B(1) atoms. There are three inequivalent B sites. In the first B site, B(1) is bonded in a 6-coordinate geometry to one Lu(2), two equivalent Lu(1), one Rh(2), four equivalent Rh(1), and one B(3) atom. In the second B site, B(2) is bonded in a 6-coordinate geometry to three equivalent Lu(2), one Rh(2), four equivalent Rh(3), and one B(2) atom. In the third B site, B(3) is bonded in a 6-coordinate geometry to one Lu(1), two equivalent Lu(2), one Rh(1), one Rh(3), three equivalent Rh(2), and one B(1) atom. is represented by the CIF card [CIF]
data_Lu(BRh)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.805
_cell_length_b   11.805
_cell_length_c   7.513
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   142.921
_symmetry_Int_Tables_number   1
_cell_volume   631.280
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Lu  Lu0  1  0.000  0.000  0.500  1.0
  Lu  Lu1  1  0.500  0.500  0.000  1.0
  Lu  Lu2  1  0.667  0.333  0.500  1.0
  Lu  Lu3  1  0.333  0.667  0.500  1.0
  Lu  Lu4  1  0.833  0.167  0.000  1.0
  Lu  Lu5  1  0.167  0.833  0.000  1.0
  B  B6  1  0.409  0.302  0.334  1.0
  B  B7  1  0.302  0.409  0.666  1.0
  B  B8  1  0.591  0.698  0.334  1.0
  B  B9  1  0.698  0.591  0.666  1.0
  B  B10  1  0.091  0.198  0.166  1.0
  B  B11  1  0.198  0.091  0.834  1.0
  B  B12  1  0.948  0.391  0.636  1.0
  B  B13  1  0.391  0.948  0.364  1.0
  B  B14  1  0.052  0.609  0.636  1.0
  B  B15  1  0.609  0.052  0.364  1.0
  B  B16  1  0.552  0.109  0.864  1.0
  B  B17  1  0.109  0.552  0.136  1.0
  B  B18  1  0.448  0.891  0.864  1.0
  B  B19  1  0.891  0.448  0.136  1.0
  B  B20  1  0.027  0.247  0.328  1.0
  B  B21  1  0.247  0.027  0.672  1.0
  B  B22  1  0.973  0.753  0.328  1.0
  B  B23  1  0.753  0.973  0.672  1.0
  B  B24  1  0.473  0.253  0.172  1.0
  B  B25  1  0.253  0.473  0.828  1.0
  B  B26  1  0.527  0.747  0.172  1.0
  B  B27  1  0.747  0.527  0.828  1.0
  B  B28  1  0.909  0.802  0.166  1.0
  B  B29  1  0.802  0.909  0.834  1.0
  Rh  Rh30  1  0.106  0.192  0.876  1.0
  Rh  Rh31  1  0.192  0.106  0.124  1.0
  Rh  Rh32  1  0.606  0.692  0.624  1.0
  Rh  Rh33  1  0.692  0.606  0.376  1.0
  Rh  Rh34  1  0.394  0.308  0.624  1.0
  Rh  Rh35  1  0.308  0.394  0.376  1.0
  Rh  Rh36  1  0.029  0.280  0.614  1.0
  Rh  Rh37  1  0.280  0.029  0.386  1.0
  Rh  Rh38  1  0.971  0.720  0.614  1.0
  Rh  Rh39  1  0.720  0.971  0.386  1.0
  Rh  Rh40  1  0.471  0.220  0.886  1.0
  Rh  Rh41  1  0.220  0.471  0.114  1.0
  Rh  Rh42  1  0.529  0.780  0.886  1.0
  Rh  Rh43  1  0.780  0.529  0.114  1.0
  Rh  Rh44  1  0.908  0.325  0.344  1.0
  Rh  Rh45  1  0.325  0.908  0.656  1.0
  Rh  Rh46  1  0.092  0.675  0.344  1.0
  Rh  Rh47  1  0.675  0.092  0.656  1.0
  Rh  Rh48  1  0.592  0.175  0.156  1.0
  Rh  Rh49  1  0.175  0.592  0.844  1.0
  Rh  Rh50  1  0.408  0.825  0.156  1.0
  Rh  Rh51  1  0.825  0.408  0.844  1.0
  Rh  Rh52  1  0.808  0.894  0.124  1.0
  Rh  Rh53  1  0.894  0.808  0.876  1.0
[/CIF]
.