The material described by KCo2H(SeO5)2H2 crystallizes in the monoclinic Cm space group. The structure consists of two 1333-74-0 molecules inside a KCo2H(SeO5)2 framework. In the KCo2H(SeO5)2 framework, K(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(6), one O(7), one O(8), and two equivalent O(4) atoms. Co(1) is bonded to one O(1), one O(3), one O(4), one O(5), and one O(6) atom to form a mixture of distorted corner and edge-sharing CoO5 trigonal bipyramids. H(2) is bonded in a single-bond geometry to one O(8) atom. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a distorted trigonal non-coplanar geometry to one O(6) and two equivalent O(5) atoms. In the second Se site, Se(2) is bonded in a distorted trigonal non-coplanar geometry to one O(3) and two equivalent O(4) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Co(1) and one O(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one K(1) and one O(8) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one K(1), two equivalent Co(1), and one Se(2) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one K(1), one Co(1), and one Se(2) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one Co(1) and one Se(1) atom. In the sixth O site, O(6) is bonded in a distorted see-saw-like geometry to one K(1), two equivalent Co(1), and one Se(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one K(1) and one O(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one K(1), one H(2), and one O(2) atom. is represented by the CIF card [CIF]
data_KCo2H3(SeO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.799
_cell_length_b   7.799
_cell_length_c   7.083
_cell_angle_alpha   67.687
_cell_angle_beta   67.687
_cell_angle_gamma   54.502
_symmetry_Int_Tables_number   1
_cell_volume   317.184
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.483  0.483  0.420  1.0
  Co  Co1  1  0.501  0.957  0.587  1.0
  Co  Co2  1  0.957  0.501  0.587  1.0
  H  H3  1  0.027  0.027  0.498  1.0
  H  H4  1  0.506  0.506  0.915  1.0
  H  H5  1  0.982  0.982  0.467  1.0
  Se  Se6  1  0.118  0.118  0.880  1.0
  Se  Se7  1  0.824  0.824  0.223  1.0
  O  O8  1  0.725  0.725  0.759  1.0
  O  O9  1  0.371  0.371  0.919  1.0
  O  O10  1  0.690  0.690  0.415  1.0
  O  O11  1  0.053  0.670  0.326  1.0
  O  O12  1  0.273  0.888  0.782  1.0
  O  O13  1  0.670  0.053  0.326  1.0
  O  O14  1  0.888  0.273  0.782  1.0
  O  O15  1  0.252  0.252  0.682  1.0
  O  O16  1  0.691  0.691  0.966  1.0
  O  O17  1  0.432  0.432  0.023  1.0
[/CIF]
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The material described by KCo2H(SeO5)2H2 crystallizes in the monoclinic Cm space group. The structure consists of two 1333-74-0 molecules inside a KCo2H(SeO5)2 framework. In the KCo2H(SeO5)2 framework, K(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(6), one O(7), one O(8), and two equivalent O(4) atoms. Co(1) is bonded to one O(1), one O(3), one O(4), one O(5), and one O(6) atom to form a mixture of distorted corner and edge-sharing CoO5 trigonal bipyramids. H(2) is bonded in a single-bond geometry to one O(8) atom. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a distorted trigonal non-coplanar geometry to one O(6) and two equivalent O(5) atoms. In the second Se site, Se(2) is bonded in a distorted trigonal non-coplanar geometry to one O(3) and two equivalent O(4) atoms. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Co(1) and one O(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one K(1) and one O(8) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one K(1), two equivalent Co(1), and one Se(2) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one K(1), one Co(1), and one Se(2) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one Co(1) and one Se(1) atom. In the sixth O site, O(6) is bonded in a distorted see-saw-like geometry to one K(1), two equivalent Co(1), and one Se(1) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one K(1) and one O(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one K(1), one H(2), and one O(2) atom. is represented by the CIF card [CIF]
data_KCo2H3(SeO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.799
_cell_length_b   7.799
_cell_length_c   7.083
_cell_angle_alpha   67.687
_cell_angle_beta   67.687
_cell_angle_gamma   54.502
_symmetry_Int_Tables_number   1
_cell_volume   317.184
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.483  0.483  0.420  1.0
  Co  Co1  1  0.501  0.957  0.587  1.0
  Co  Co2  1  0.957  0.501  0.587  1.0
  H  H3  1  0.027  0.027  0.498  1.0
  H  H4  1  0.506  0.506  0.915  1.0
  H  H5  1  0.982  0.982  0.467  1.0
  Se  Se6  1  0.118  0.118  0.880  1.0
  Se  Se7  1  0.824  0.824  0.223  1.0
  O  O8  1  0.725  0.725  0.759  1.0
  O  O9  1  0.371  0.371  0.919  1.0
  O  O10  1  0.690  0.690  0.415  1.0
  O  O11  1  0.053  0.670  0.326  1.0
  O  O12  1  0.273  0.888  0.782  1.0
  O  O13  1  0.670  0.053  0.326  1.0
  O  O14  1  0.888  0.273  0.782  1.0
  O  O15  1  0.252  0.252  0.682  1.0
  O  O16  1  0.691  0.691  0.966  1.0
  O  O17  1  0.432  0.432  0.023  1.0
[/CIF]
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