The crystal structure described by Rb4Th(MoO4)4 crystallizes in the monoclinic C2/c space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 7-coordinate geometry to one O(4), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. Th(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(5), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(8) is bonded in a 4-coordinate geometry to one Rb(2), two equivalent Rb(1), and one Mo(2) atom. In the second O site, O(1) is bonded in a 3-coordinate geometry to one Rb(2), one Th(1), and one Mo(1) atom. In the third O site, O(2) is bonded in a 3-coordinate geometry to one Rb(2), one Th(1), and one Mo(1) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one Rb(2), one Th(1), and one Mo(1) atom. In the fifth O site, O(4) is bonded in a 3-coordinate geometry to one Rb(1), one Rb(2), and one Mo(1) atom. In the sixth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Rb(2), one Th(1), and one Mo(2) atom. In the seventh O site, O(6) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one Mo(2) atom. In the eighth O site, O(7) is bonded in a 4-coordinate geometry to one Rb(2), two equivalent Rb(1), and one Mo(2) atom. is represented by the CIF file [CIF]
data_Rb4Th(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.517
_cell_length_b   11.575
_cell_length_c   14.045
_cell_angle_alpha   113.215
_cell_angle_beta   103.415
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   942.162
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.029  0.851  0.549  1.0
  Rb  Rb1  1  0.480  0.649  0.451  1.0
  Rb  Rb2  1  0.971  0.149  0.451  1.0
  Rb  Rb3  1  0.520  0.351  0.549  1.0
  Rb  Rb4  1  0.857  0.703  0.219  1.0
  Rb  Rb5  1  0.638  0.797  0.781  1.0
  Rb  Rb6  1  0.143  0.297  0.781  1.0
  Rb  Rb7  1  0.362  0.203  0.219  1.0
  Th  Th8  1  0.250  0.750  0.000  1.0
  Th  Th9  1  0.750  0.250  0.000  1.0
  Mo  Mo10  1  0.202  0.027  0.899  1.0
  Mo  Mo11  1  0.303  0.473  0.101  1.0
  Mo  Mo12  1  0.798  0.973  0.101  1.0
  Mo  Mo13  1  0.697  0.527  0.899  1.0
  Mo  Mo14  1  0.444  0.916  0.326  1.0
  Mo  Mo15  1  0.118  0.584  0.674  1.0
  Mo  Mo16  1  0.556  0.084  0.674  1.0
  Mo  Mo17  1  0.882  0.416  0.326  1.0
  O  O18  1  0.110  0.908  0.938  1.0
  O  O19  1  0.172  0.592  0.062  1.0
  O  O20  1  0.890  0.092  0.062  1.0
  O  O21  1  0.828  0.408  0.938  1.0
  O  O22  1  0.998  0.866  0.109  1.0
  O  O23  1  0.889  0.634  0.891  1.0
  O  O24  1  0.002  0.134  0.891  1.0
  O  O25  1  0.111  0.366  0.109  1.0
  O  O26  1  0.548  0.619  0.993  1.0
  O  O27  1  0.555  0.881  0.007  1.0
  O  O28  1  0.452  0.381  0.007  1.0
  O  O29  1  0.445  0.119  0.993  1.0
  O  O30  1  0.247  0.946  0.772  1.0
  O  O31  1  0.475  0.554  0.228  1.0
  O  O32  1  0.753  0.054  0.228  1.0
  O  O33  1  0.525  0.446  0.772  1.0
  O  O34  1  0.429  0.838  0.180  1.0
  O  O35  1  0.248  0.662  0.820  1.0
  O  O36  1  0.571  0.162  0.820  1.0
  O  O37  1  0.752  0.338  0.180  1.0
  O  O38  1  0.406  0.080  0.368  1.0
  O  O39  1  0.039  0.420  0.632  1.0
  O  O40  1  0.594  0.920  0.632  1.0
  O  O41  1  0.961  0.580  0.368  1.0
  O  O42  1  0.252  0.840  0.360  1.0
  O  O43  1  0.892  0.660  0.640  1.0
  O  O44  1  0.748  0.160  0.640  1.0
  O  O45  1  0.108  0.340  0.360  1.0
  O  O46  1  0.702  0.899  0.395  1.0
  O  O47  1  0.307  0.601  0.605  1.0
  O  O48  1  0.298  0.101  0.605  1.0
  O  O49  1  0.693  0.399  0.395  1.0
[/CIF]
.
The crystal structure described by Rb4Th(MoO4)4 crystallizes in the monoclinic C2/c space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 7-coordinate geometry to one O(4), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. Th(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(5), one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(8) is bonded in a 4-coordinate geometry to one Rb(2), two equivalent Rb(1), and one Mo(2) atom. In the second O site, O(1) is bonded in a 3-coordinate geometry to one Rb(2), one Th(1), and one Mo(1) atom. In the third O site, O(2) is bonded in a 3-coordinate geometry to one Rb(2), one Th(1), and one Mo(1) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one Rb(2), one Th(1), and one Mo(1) atom. In the fifth O site, O(4) is bonded in a 3-coordinate geometry to one Rb(1), one Rb(2), and one Mo(1) atom. In the sixth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Rb(2), one Th(1), and one Mo(2) atom. In the seventh O site, O(6) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one Mo(2) atom. In the eighth O site, O(7) is bonded in a 4-coordinate geometry to one Rb(2), two equivalent Rb(1), and one Mo(2) atom. is represented by the CIF file [CIF]
data_Rb4Th(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.517
_cell_length_b   11.575
_cell_length_c   14.045
_cell_angle_alpha   113.215
_cell_angle_beta   103.415
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   942.162
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.029  0.851  0.549  1.0
  Rb  Rb1  1  0.480  0.649  0.451  1.0
  Rb  Rb2  1  0.971  0.149  0.451  1.0
  Rb  Rb3  1  0.520  0.351  0.549  1.0
  Rb  Rb4  1  0.857  0.703  0.219  1.0
  Rb  Rb5  1  0.638  0.797  0.781  1.0
  Rb  Rb6  1  0.143  0.297  0.781  1.0
  Rb  Rb7  1  0.362  0.203  0.219  1.0
  Th  Th8  1  0.250  0.750  0.000  1.0
  Th  Th9  1  0.750  0.250  0.000  1.0
  Mo  Mo10  1  0.202  0.027  0.899  1.0
  Mo  Mo11  1  0.303  0.473  0.101  1.0
  Mo  Mo12  1  0.798  0.973  0.101  1.0
  Mo  Mo13  1  0.697  0.527  0.899  1.0
  Mo  Mo14  1  0.444  0.916  0.326  1.0
  Mo  Mo15  1  0.118  0.584  0.674  1.0
  Mo  Mo16  1  0.556  0.084  0.674  1.0
  Mo  Mo17  1  0.882  0.416  0.326  1.0
  O  O18  1  0.110  0.908  0.938  1.0
  O  O19  1  0.172  0.592  0.062  1.0
  O  O20  1  0.890  0.092  0.062  1.0
  O  O21  1  0.828  0.408  0.938  1.0
  O  O22  1  0.998  0.866  0.109  1.0
  O  O23  1  0.889  0.634  0.891  1.0
  O  O24  1  0.002  0.134  0.891  1.0
  O  O25  1  0.111  0.366  0.109  1.0
  O  O26  1  0.548  0.619  0.993  1.0
  O  O27  1  0.555  0.881  0.007  1.0
  O  O28  1  0.452  0.381  0.007  1.0
  O  O29  1  0.445  0.119  0.993  1.0
  O  O30  1  0.247  0.946  0.772  1.0
  O  O31  1  0.475  0.554  0.228  1.0
  O  O32  1  0.753  0.054  0.228  1.0
  O  O33  1  0.525  0.446  0.772  1.0
  O  O34  1  0.429  0.838  0.180  1.0
  O  O35  1  0.248  0.662  0.820  1.0
  O  O36  1  0.571  0.162  0.820  1.0
  O  O37  1  0.752  0.338  0.180  1.0
  O  O38  1  0.406  0.080  0.368  1.0
  O  O39  1  0.039  0.420  0.632  1.0
  O  O40  1  0.594  0.920  0.632  1.0
  O  O41  1  0.961  0.580  0.368  1.0
  O  O42  1  0.252  0.840  0.360  1.0
  O  O43  1  0.892  0.660  0.640  1.0
  O  O44  1  0.748  0.160  0.640  1.0
  O  O45  1  0.108  0.340  0.360  1.0
  O  O46  1  0.702  0.899  0.395  1.0
  O  O47  1  0.307  0.601  0.605  1.0
  O  O48  1  0.298  0.101  0.605  1.0
  O  O49  1  0.693  0.399  0.395  1.0
[/CIF]
.