The structure described by ZnZn(WF4)2 crystallizes in the monoclinic C2 space group. The structure consists of two 7440-66-6 atoms inside a Zn(WF4)2 framework. In the Zn(WF4)2 framework, W(1) is bonded in a square co-planar geometry to one F(1), one F(2), one F(3), and one F(4) atom. Zn(2) is bonded in a 8-coordinate geometry to two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. is represented by the CIF file [CIF]
data_ZnWF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.878
_cell_length_b   6.878
_cell_length_c   5.888
_cell_angle_alpha   64.730
_cell_angle_beta   64.730
_cell_angle_gamma   50.833
_symmetry_Int_Tables_number   1
_cell_volume   190.293
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.243  0.757  0.500  1.0
  Zn  Zn1  1  0.744  0.256  0.000  1.0
  W  W2  1  0.497  0.002  0.750  1.0
  W  W3  1  0.998  0.503  0.250  1.0
  F  F4  1  0.452  0.302  0.802  1.0
  F  F5  1  0.190  0.048  0.051  1.0
  F  F6  1  0.546  0.698  0.702  1.0
  F  F7  1  0.042  0.200  0.556  1.0
  F  F8  1  0.800  0.958  0.444  1.0
  F  F9  1  0.302  0.454  0.298  1.0
  F  F10  1  0.952  0.810  0.949  1.0
  F  F11  1  0.698  0.548  0.198  1.0
[/CIF]
.
The structure described by ZnZn(WF4)2 crystallizes in the monoclinic C2 space group. The structure consists of two 7440-66-6 atoms inside a Zn(WF4)2 framework. In the Zn(WF4)2 framework, W(1) is bonded in a square co-planar geometry to one F(1), one F(2), one F(3), and one F(4) atom. Zn(2) is bonded in a 8-coordinate geometry to two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the second F site, F(2) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one W(1) and one Zn(2) atom. is represented by the CIF file [CIF]
data_ZnWF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.878
_cell_length_b   6.878
_cell_length_c   5.888
_cell_angle_alpha   64.730
_cell_angle_beta   64.730
_cell_angle_gamma   50.833
_symmetry_Int_Tables_number   1
_cell_volume   190.293
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.243  0.757  0.500  1.0
  Zn  Zn1  1  0.744  0.256  0.000  1.0
  W  W2  1  0.497  0.002  0.750  1.0
  W  W3  1  0.998  0.503  0.250  1.0
  F  F4  1  0.452  0.302  0.802  1.0
  F  F5  1  0.190  0.048  0.051  1.0
  F  F6  1  0.546  0.698  0.702  1.0
  F  F7  1  0.042  0.200  0.556  1.0
  F  F8  1  0.800  0.958  0.444  1.0
  F  F9  1  0.302  0.454  0.298  1.0
  F  F10  1  0.952  0.810  0.949  1.0
  F  F11  1  0.698  0.548  0.198  1.0
[/CIF]
.