The structure described by Sb5S3O5 crystallizes in the triclinic P1 space group. There are twenty inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one O(13), one O(17), one O(2), and one O(6) atom. In the second Sb site, Sb(2) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(14), one O(18), and one O(5) atom. In the third Sb site, Sb(3) is bonded in a distorted rectangular see-saw-like geometry to one O(15), one O(19), one O(4), and one O(8) atom. In the fourth Sb site, Sb(4) is bonded in a distorted rectangular see-saw-like geometry to one O(16), one O(20), one O(3), and one O(7) atom. In the fifth Sb site, Sb(5) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(17), one O(2), and one O(4) atom. In the sixth Sb site, Sb(6) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(18), one O(3), and one O(9) atom. In the seventh Sb site, Sb(7) is bonded in a distorted rectangular see-saw-like geometry to one O(12), one O(19), one O(2), and one O(4) atom. In the eighth Sb site, Sb(8) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(11), one O(20), and one O(3) atom. In the ninth Sb site, Sb(9) is bonded in a distorted T-shaped geometry to one O(13), one O(18), and one O(9) atom. In the tenth Sb site, Sb(10) is bonded in a distorted T-shaped geometry to one O(10), one O(14), and one O(17) atom. In the eleventh Sb site, Sb(11) is bonded in a distorted T-shaped geometry to one O(11), one O(15), and one O(20) atom. In the twelfth Sb site, Sb(12) is bonded in a distorted T-shaped geometry to one O(12), one O(16), and one O(19) atom. In the thirteenth Sb site, Sb(13) is bonded in a distorted single-bond geometry to one S(11), one S(2), one S(5), and one O(5) atom. In the fourteenth Sb site, Sb(14) is bonded in a distorted single-bond geometry to one S(1), one S(12), one S(6), and one O(6) atom. In the fifteenth Sb site, Sb(15) is bonded in a distorted single-bond geometry to one S(4), one S(7), one S(9), and one O(7) atom. In the sixteenth Sb site, Sb(16) is bonded in a distorted single-bond geometry to one S(10), one S(3), one S(8), and one O(8) atom. In the seventeenth Sb site, Sb(17) is bonded in a distorted T-shaped geometry to one S(10), one S(3), and one S(6) atom. In the eighteenth Sb site, Sb(18) is bonded in a distorted T-shaped geometry to one S(4), one S(5), and one S(9) atom. In the nineteenth Sb site, Sb(19) is bonded in a distorted trigonal non-coplanar geometry to one S(1), one S(12), and one S(8) atom. In the twentieth Sb site, Sb(20) is bonded in a distorted T-shaped geometry to one S(11), one S(2), and one S(7) atom. There are twelve inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Sb(14) and one Sb(19) atom. In the second S site, S(2) is bonded in a water-like geometry to one Sb(13) and one Sb(20) atom. In the third S site, S(3) is bonded in a water-like geometry to one Sb(16) and one Sb(17) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one Sb(15) and one Sb(18) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one Sb(13) and one Sb(18) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one Sb(14) and one Sb(17) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one Sb(15) and one Sb(20) atom. In the eighth S site, S(8) is bonded in a water-like geometry to one Sb(16) and one Sb(19) atom. In the ninth S site, S(9) is bonded in an L-shaped geometry to one Sb(15) and one Sb(18) atom. In the tenth S site, S(10) is bonded in an L-shaped geometry to one Sb(16) and one Sb(17) atom. In the eleventh S site, S(11) is bonded in an L-shaped geometry to one Sb(13) and one Sb(20) atom. In the twelfth S site, S(12) is bonded in an L-shaped geometry to one Sb(14) and one Sb(19) atom. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Sb(2), one Sb(6), and one Sb(8) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Sb(1), one Sb(5), and one Sb(7) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Sb(4), one Sb(6), and one Sb(8) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Sb(3), one Sb(5), and one Sb(7) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Sb(13) and one Sb(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(14) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Sb(15) and one Sb(4) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Sb(16) and one Sb(3) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Sb(6) and one Sb(9) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Sb(10) and one Sb(5) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Sb(11) and one Sb(8) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Sb(12) and one Sb(7) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one Sb(9) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Sb(10) and one Sb(2) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Sb(11) and one Sb(3) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Sb(12) and one Sb(4) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Sb(1), one Sb(10), and one Sb(5) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Sb(2), one Sb(6), and one Sb(9) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Sb(12), one Sb(3), and one Sb(7) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Sb(11), one Sb(4), and one Sb(8) atom. is represented by the CIF card [CIF]
data_Sb5S3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.833
_cell_length_b   13.601
_cell_length_c   16.771
_cell_angle_alpha   67.429
_cell_angle_beta   79.817
_cell_angle_gamma   77.424
_symmetry_Int_Tables_number   1
_cell_volume   1192.758
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.031  0.820  0.086  1.0
  Sb  Sb1  1  0.940  0.679  0.414  1.0
  Sb  Sb2  1  0.966  0.180  0.914  1.0
  Sb  Sb3  1  0.061  0.321  0.586  1.0
  Sb  Sb4  1  0.522  0.024  0.085  1.0
  Sb  Sb5  1  0.633  0.477  0.414  1.0
  Sb  Sb6  1  0.479  0.976  0.915  1.0
  Sb  Sb7  1  0.372  0.524  0.585  1.0
  Sb  Sb8  1  0.206  0.563  0.259  1.0
  Sb  Sb9  1  0.026  0.937  0.242  1.0
  Sb  Sb10  1  0.797  0.437  0.742  1.0
  Sb  Sb11  1  0.975  0.064  0.758  1.0
  Sb  Sb12  1  0.470  0.874  0.456  1.0
  Sb  Sb13  1  0.793  0.628  0.044  1.0
  Sb  Sb14  1  0.530  0.128  0.544  1.0
  Sb  Sb15  1  0.202  0.373  0.955  1.0
  Sb  Sb16  1  0.690  0.331  0.133  1.0
  Sb  Sb17  1  0.154  0.171  0.367  1.0
  Sb  Sb18  1  0.307  0.669  0.867  1.0
  Sb  Sb19  1  0.844  0.831  0.634  1.0
  S  S20  1  0.233  0.561  0.025  1.0
  S  S21  1  0.823  0.939  0.476  1.0
  S  S22  1  0.763  0.439  0.975  1.0
  S  S23  1  0.179  0.061  0.525  1.0
  S  S24  1  0.413  0.032  0.315  1.0
  S  S25  1  0.757  0.469  0.185  1.0
  S  S26  1  0.591  0.970  0.686  1.0
  S  S27  1  0.240  0.531  0.814  1.0
  S  S28  1  0.428  0.282  0.366  1.0
  S  S29  1  0.072  0.218  0.137  1.0
  S  S30  1  0.566  0.722  0.636  1.0
  S  S31  1  0.925  0.782  0.863  1.0
  O  O32  1  0.641  0.568  0.483  1.0
  O  O33  1  0.694  0.933  0.016  1.0
  O  O34  1  0.361  0.433  0.516  1.0
  O  O35  1  0.309  0.068  0.983  1.0
  O  O36  1  0.648  0.791  0.385  1.0
  O  O37  1  0.822  0.710  0.115  1.0
  O  O38  1  0.352  0.209  0.615  1.0
  O  O39  1  0.175  0.291  0.884  1.0
  O  O40  1  0.396  0.577  0.339  1.0
  O  O41  1  0.312  0.923  0.161  1.0
  O  O42  1  0.611  0.424  0.660  1.0
  O  O43  1  0.689  0.077  0.839  1.0
  O  O44  1  0.243  0.704  0.171  1.0
  O  O45  1  0.120  0.795  0.327  1.0
  O  O46  1  0.758  0.295  0.827  1.0
  O  O47  1  0.882  0.206  0.673  1.0
  O  O48  1  0.847  0.898  0.167  1.0
  O  O49  1  0.912  0.603  0.333  1.0
  O  O50  1  0.152  0.102  0.834  1.0
  O  O51  1  0.090  0.397  0.667  1.0
[/CIF]
.
The structure described by Sb5S3O5 crystallizes in the triclinic P1 space group. There are twenty inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted rectangular see-saw-like geometry to one O(13), one O(17), one O(2), and one O(6) atom. In the second Sb site, Sb(2) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(14), one O(18), and one O(5) atom. In the third Sb site, Sb(3) is bonded in a distorted rectangular see-saw-like geometry to one O(15), one O(19), one O(4), and one O(8) atom. In the fourth Sb site, Sb(4) is bonded in a distorted rectangular see-saw-like geometry to one O(16), one O(20), one O(3), and one O(7) atom. In the fifth Sb site, Sb(5) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(17), one O(2), and one O(4) atom. In the sixth Sb site, Sb(6) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(18), one O(3), and one O(9) atom. In the seventh Sb site, Sb(7) is bonded in a distorted rectangular see-saw-like geometry to one O(12), one O(19), one O(2), and one O(4) atom. In the eighth Sb site, Sb(8) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(11), one O(20), and one O(3) atom. In the ninth Sb site, Sb(9) is bonded in a distorted T-shaped geometry to one O(13), one O(18), and one O(9) atom. In the tenth Sb site, Sb(10) is bonded in a distorted T-shaped geometry to one O(10), one O(14), and one O(17) atom. In the eleventh Sb site, Sb(11) is bonded in a distorted T-shaped geometry to one O(11), one O(15), and one O(20) atom. In the twelfth Sb site, Sb(12) is bonded in a distorted T-shaped geometry to one O(12), one O(16), and one O(19) atom. In the thirteenth Sb site, Sb(13) is bonded in a distorted single-bond geometry to one S(11), one S(2), one S(5), and one O(5) atom. In the fourteenth Sb site, Sb(14) is bonded in a distorted single-bond geometry to one S(1), one S(12), one S(6), and one O(6) atom. In the fifteenth Sb site, Sb(15) is bonded in a distorted single-bond geometry to one S(4), one S(7), one S(9), and one O(7) atom. In the sixteenth Sb site, Sb(16) is bonded in a distorted single-bond geometry to one S(10), one S(3), one S(8), and one O(8) atom. In the seventeenth Sb site, Sb(17) is bonded in a distorted T-shaped geometry to one S(10), one S(3), and one S(6) atom. In the eighteenth Sb site, Sb(18) is bonded in a distorted T-shaped geometry to one S(4), one S(5), and one S(9) atom. In the nineteenth Sb site, Sb(19) is bonded in a distorted trigonal non-coplanar geometry to one S(1), one S(12), and one S(8) atom. In the twentieth Sb site, Sb(20) is bonded in a distorted T-shaped geometry to one S(11), one S(2), and one S(7) atom. There are twelve inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Sb(14) and one Sb(19) atom. In the second S site, S(2) is bonded in a water-like geometry to one Sb(13) and one Sb(20) atom. In the third S site, S(3) is bonded in a water-like geometry to one Sb(16) and one Sb(17) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one Sb(15) and one Sb(18) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one Sb(13) and one Sb(18) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one Sb(14) and one Sb(17) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one Sb(15) and one Sb(20) atom. In the eighth S site, S(8) is bonded in a water-like geometry to one Sb(16) and one Sb(19) atom. In the ninth S site, S(9) is bonded in an L-shaped geometry to one Sb(15) and one Sb(18) atom. In the tenth S site, S(10) is bonded in an L-shaped geometry to one Sb(16) and one Sb(17) atom. In the eleventh S site, S(11) is bonded in an L-shaped geometry to one Sb(13) and one Sb(20) atom. In the twelfth S site, S(12) is bonded in an L-shaped geometry to one Sb(14) and one Sb(19) atom. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Sb(2), one Sb(6), and one Sb(8) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Sb(1), one Sb(5), and one Sb(7) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Sb(4), one Sb(6), and one Sb(8) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Sb(3), one Sb(5), and one Sb(7) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Sb(13) and one Sb(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(14) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Sb(15) and one Sb(4) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Sb(16) and one Sb(3) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Sb(6) and one Sb(9) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Sb(10) and one Sb(5) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Sb(11) and one Sb(8) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Sb(12) and one Sb(7) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one Sb(9) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Sb(10) and one Sb(2) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Sb(11) and one Sb(3) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Sb(12) and one Sb(4) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Sb(1), one Sb(10), and one Sb(5) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Sb(2), one Sb(6), and one Sb(9) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Sb(12), one Sb(3), and one Sb(7) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Sb(11), one Sb(4), and one Sb(8) atom. is represented by the CIF card [CIF]
data_Sb5S3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.833
_cell_length_b   13.601
_cell_length_c   16.771
_cell_angle_alpha   67.429
_cell_angle_beta   79.817
_cell_angle_gamma   77.424
_symmetry_Int_Tables_number   1
_cell_volume   1192.758
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.031  0.820  0.086  1.0
  Sb  Sb1  1  0.940  0.679  0.414  1.0
  Sb  Sb2  1  0.966  0.180  0.914  1.0
  Sb  Sb3  1  0.061  0.321  0.586  1.0
  Sb  Sb4  1  0.522  0.024  0.085  1.0
  Sb  Sb5  1  0.633  0.477  0.414  1.0
  Sb  Sb6  1  0.479  0.976  0.915  1.0
  Sb  Sb7  1  0.372  0.524  0.585  1.0
  Sb  Sb8  1  0.206  0.563  0.259  1.0
  Sb  Sb9  1  0.026  0.937  0.242  1.0
  Sb  Sb10  1  0.797  0.437  0.742  1.0
  Sb  Sb11  1  0.975  0.064  0.758  1.0
  Sb  Sb12  1  0.470  0.874  0.456  1.0
  Sb  Sb13  1  0.793  0.628  0.044  1.0
  Sb  Sb14  1  0.530  0.128  0.544  1.0
  Sb  Sb15  1  0.202  0.373  0.955  1.0
  Sb  Sb16  1  0.690  0.331  0.133  1.0
  Sb  Sb17  1  0.154  0.171  0.367  1.0
  Sb  Sb18  1  0.307  0.669  0.867  1.0
  Sb  Sb19  1  0.844  0.831  0.634  1.0
  S  S20  1  0.233  0.561  0.025  1.0
  S  S21  1  0.823  0.939  0.476  1.0
  S  S22  1  0.763  0.439  0.975  1.0
  S  S23  1  0.179  0.061  0.525  1.0
  S  S24  1  0.413  0.032  0.315  1.0
  S  S25  1  0.757  0.469  0.185  1.0
  S  S26  1  0.591  0.970  0.686  1.0
  S  S27  1  0.240  0.531  0.814  1.0
  S  S28  1  0.428  0.282  0.366  1.0
  S  S29  1  0.072  0.218  0.137  1.0
  S  S30  1  0.566  0.722  0.636  1.0
  S  S31  1  0.925  0.782  0.863  1.0
  O  O32  1  0.641  0.568  0.483  1.0
  O  O33  1  0.694  0.933  0.016  1.0
  O  O34  1  0.361  0.433  0.516  1.0
  O  O35  1  0.309  0.068  0.983  1.0
  O  O36  1  0.648  0.791  0.385  1.0
  O  O37  1  0.822  0.710  0.115  1.0
  O  O38  1  0.352  0.209  0.615  1.0
  O  O39  1  0.175  0.291  0.884  1.0
  O  O40  1  0.396  0.577  0.339  1.0
  O  O41  1  0.312  0.923  0.161  1.0
  O  O42  1  0.611  0.424  0.660  1.0
  O  O43  1  0.689  0.077  0.839  1.0
  O  O44  1  0.243  0.704  0.171  1.0
  O  O45  1  0.120  0.795  0.327  1.0
  O  O46  1  0.758  0.295  0.827  1.0
  O  O47  1  0.882  0.206  0.673  1.0
  O  O48  1  0.847  0.898  0.167  1.0
  O  O49  1  0.912  0.603  0.333  1.0
  O  O50  1  0.152  0.102  0.834  1.0
  O  O51  1  0.090  0.397  0.667  1.0
[/CIF]
.