The compound described by TlMnF3 is (Cubic) Perovskite structured and crystallizes in the monoclinic Cm space group. The structure consists of two 7440-28-0 atoms inside a MnF3 framework. In the MnF3 framework, Mn(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Mn(1) atoms. In the second F site, F(2) is bonded in a linear geometry to two equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnTlF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.234
_cell_length_b   4.236
_cell_length_c   4.235
_cell_angle_alpha   90.004
_cell_angle_beta   90.032
_cell_angle_gamma   89.997
_symmetry_Int_Tables_number   1
_cell_volume   75.962
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.512  0.500  0.502  1.0
  Tl  Tl1  1  0.009  0.998  0.005  1.0
  F  F2  1  0.514  0.000  0.502  1.0
  F  F3  1  0.012  0.502  0.499  1.0
  F  F4  1  0.513  0.500  0.002  1.0
[/CIF]
.
The compound described by TlMnF3 is (Cubic) Perovskite structured and crystallizes in the monoclinic Cm space group. The structure consists of two 7440-28-0 atoms inside a MnF3 framework. In the MnF3 framework, Mn(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Mn(1) atoms. In the second F site, F(2) is bonded in a linear geometry to two equivalent Mn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_MnTlF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.234
_cell_length_b   4.236
_cell_length_c   4.235
_cell_angle_alpha   90.004
_cell_angle_beta   90.032
_cell_angle_gamma   89.997
_symmetry_Int_Tables_number   1
_cell_volume   75.962
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.512  0.500  0.502  1.0
  Tl  Tl1  1  0.009  0.998  0.005  1.0
  F  F2  1  0.514  0.000  0.502  1.0
  F  F3  1  0.012  0.502  0.499  1.0
  F  F4  1  0.513  0.500  0.002  1.0
[/CIF]
.