The crystal structure described by BF4ClO2 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four hydroxychloride hydrate molecules and four BF4 clusters. In each BF4 cluster, B(1) is bonded in a tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one B(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BCl(OF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.179
_cell_length_b   5.179
_cell_length_c   9.966
_cell_angle_alpha   85.294
_cell_angle_beta   85.294
_cell_angle_gamma   118.846
_symmetry_Int_Tables_number   1
_cell_volume   231.024
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.582  0.447  0.520  1.0
  B  B1  1  0.447  0.582  0.020  1.0
  Cl  Cl2  1  0.145  0.674  0.753  1.0
  Cl  Cl3  1  0.674  0.145  0.253  1.0
  O  O4  1  0.916  0.380  0.806  1.0
  O  O5  1  0.136  0.918  0.805  1.0
  O  O6  1  0.380  0.916  0.306  1.0
  O  O7  1  0.918  0.136  0.305  1.0
  F  F8  1  0.812  0.692  0.569  1.0
  F  F9  1  0.503  0.639  0.871  1.0
  F  F10  1  0.692  0.812  0.069  1.0
  F  F11  1  0.639  0.503  0.371  1.0
  F  F12  1  0.586  0.183  0.561  1.0
  F  F13  1  0.305  0.423  0.561  1.0
  F  F14  1  0.183  0.586  0.061  1.0
  F  F15  1  0.423  0.305  0.061  1.0
[/CIF]
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The crystal structure described by BF4ClO2 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four hydroxychloride hydrate molecules and four BF4 clusters. In each BF4 cluster, B(1) is bonded in a tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one B(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_BCl(OF2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.179
_cell_length_b   5.179
_cell_length_c   9.966
_cell_angle_alpha   85.294
_cell_angle_beta   85.294
_cell_angle_gamma   118.846
_symmetry_Int_Tables_number   1
_cell_volume   231.024
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.582  0.447  0.520  1.0
  B  B1  1  0.447  0.582  0.020  1.0
  Cl  Cl2  1  0.145  0.674  0.753  1.0
  Cl  Cl3  1  0.674  0.145  0.253  1.0
  O  O4  1  0.916  0.380  0.806  1.0
  O  O5  1  0.136  0.918  0.805  1.0
  O  O6  1  0.380  0.916  0.306  1.0
  O  O7  1  0.918  0.136  0.305  1.0
  F  F8  1  0.812  0.692  0.569  1.0
  F  F9  1  0.503  0.639  0.871  1.0
  F  F10  1  0.692  0.812  0.069  1.0
  F  F11  1  0.639  0.503  0.371  1.0
  F  F12  1  0.586  0.183  0.561  1.0
  F  F13  1  0.305  0.423  0.561  1.0
  F  F14  1  0.183  0.586  0.061  1.0
  F  F15  1  0.423  0.305  0.061  1.0
[/CIF]
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