The structure described by BiH(NO3)3(H2)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 1333-74-0 atoms and two BiH(NO3)3 clusters. In each BiH(NO3)3 cluster, Bi(1) is bonded in a 6-coordinate geometry to one H(1), one O(1), one O(2), one O(4), one O(6), and one O(9) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(6), and one O(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(7), and one O(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. H(1) is bonded in a single-bond geometry to one Bi(1) atom. There are nine inequivalent O sites. In the first O site, O(8) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(9) is bonded in a distorted single-bond geometry to one Bi(1) and one N(2) atom. In the third O site, O(1) is bonded in a distorted water-like geometry to one Bi(1) and one N(2) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one Bi(1) and one N(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one N(3) atom. In the sixth O site, O(4) is bonded in a distorted water-like geometry to one Bi(1) and one N(3) atom. In the seventh O site, O(5) is bonded in a single-bond geometry to one N(3) atom. In the eighth O site, O(6) is bonded in a distorted water-like geometry to one Bi(1) and one N(1) atom. In the ninth O site, O(7) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF file [CIF]
data_BiH5(NO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.833
_cell_length_b   8.833
_cell_length_c   10.863
_cell_angle_alpha   85.285
_cell_angle_beta   82.212
_cell_angle_gamma   73.179
_symmetry_Int_Tables_number   1
_cell_volume   621.206
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.308  0.295  0.311  1.0
  Bi  Bi1  1  0.692  0.705  0.689  1.0
  H  H2  1  0.076  0.474  0.336  1.0
  H  H3  1  0.924  0.526  0.664  1.0
  H  H4  1  0.682  0.180  0.079  1.0
  H  H5  1  0.318  0.820  0.921  1.0
  H  H6  1  0.726  0.215  0.452  1.0
  H  H7  1  0.274  0.785  0.548  1.0
  H  H8  1  0.126  0.206  0.910  1.0
  H  H9  1  0.874  0.794  0.090  1.0
  H  H10  1  0.132  0.419  0.124  1.0
  H  H11  1  0.868  0.581  0.876  1.0
  N  N12  1  0.296  0.188  0.567  1.0
  N  N13  1  0.704  0.812  0.433  1.0
  N  N14  1  0.146  0.080  0.196  1.0
  N  N15  1  0.854  0.920  0.804  1.0
  N  N16  1  0.500  0.583  0.203  1.0
  N  N17  1  0.500  0.417  0.797  1.0
  O  O18  1  0.034  0.197  0.265  1.0
  O  O19  1  0.966  0.803  0.735  1.0
  O  O20  1  0.294  0.333  0.537  1.0
  O  O21  1  0.706  0.667  0.463  1.0
  O  O22  1  0.600  0.661  0.136  1.0
  O  O23  1  0.400  0.339  0.864  1.0
  O  O24  1  0.573  0.430  0.208  1.0
  O  O25  1  0.427  0.570  0.792  1.0
  O  O26  1  0.331  0.645  0.266  1.0
  O  O27  1  0.669  0.355  0.734  1.0
  O  O28  1  0.280  0.105  0.475  1.0
  O  O29  1  0.720  0.895  0.525  1.0
  O  O30  1  0.072  0.982  0.163  1.0
  O  O31  1  0.928  0.018  0.837  1.0
  O  O32  1  0.311  0.128  0.671  1.0
  O  O33  1  0.689  0.872  0.329  1.0
  O  O34  1  0.337  0.076  0.167  1.0
  O  O35  1  0.663  0.924  0.833  1.0
[/CIF]
.
The structure described by BiH(NO3)3(H2)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 1333-74-0 atoms and two BiH(NO3)3 clusters. In each BiH(NO3)3 cluster, Bi(1) is bonded in a 6-coordinate geometry to one H(1), one O(1), one O(2), one O(4), one O(6), and one O(9) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(6), and one O(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(7), and one O(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. H(1) is bonded in a single-bond geometry to one Bi(1) atom. There are nine inequivalent O sites. In the first O site, O(8) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(9) is bonded in a distorted single-bond geometry to one Bi(1) and one N(2) atom. In the third O site, O(1) is bonded in a distorted water-like geometry to one Bi(1) and one N(2) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one Bi(1) and one N(1) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one N(3) atom. In the sixth O site, O(4) is bonded in a distorted water-like geometry to one Bi(1) and one N(3) atom. In the seventh O site, O(5) is bonded in a single-bond geometry to one N(3) atom. In the eighth O site, O(6) is bonded in a distorted water-like geometry to one Bi(1) and one N(1) atom. In the ninth O site, O(7) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF file [CIF]
data_BiH5(NO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.833
_cell_length_b   8.833
_cell_length_c   10.863
_cell_angle_alpha   85.285
_cell_angle_beta   82.212
_cell_angle_gamma   73.179
_symmetry_Int_Tables_number   1
_cell_volume   621.206
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.308  0.295  0.311  1.0
  Bi  Bi1  1  0.692  0.705  0.689  1.0
  H  H2  1  0.076  0.474  0.336  1.0
  H  H3  1  0.924  0.526  0.664  1.0
  H  H4  1  0.682  0.180  0.079  1.0
  H  H5  1  0.318  0.820  0.921  1.0
  H  H6  1  0.726  0.215  0.452  1.0
  H  H7  1  0.274  0.785  0.548  1.0
  H  H8  1  0.126  0.206  0.910  1.0
  H  H9  1  0.874  0.794  0.090  1.0
  H  H10  1  0.132  0.419  0.124  1.0
  H  H11  1  0.868  0.581  0.876  1.0
  N  N12  1  0.296  0.188  0.567  1.0
  N  N13  1  0.704  0.812  0.433  1.0
  N  N14  1  0.146  0.080  0.196  1.0
  N  N15  1  0.854  0.920  0.804  1.0
  N  N16  1  0.500  0.583  0.203  1.0
  N  N17  1  0.500  0.417  0.797  1.0
  O  O18  1  0.034  0.197  0.265  1.0
  O  O19  1  0.966  0.803  0.735  1.0
  O  O20  1  0.294  0.333  0.537  1.0
  O  O21  1  0.706  0.667  0.463  1.0
  O  O22  1  0.600  0.661  0.136  1.0
  O  O23  1  0.400  0.339  0.864  1.0
  O  O24  1  0.573  0.430  0.208  1.0
  O  O25  1  0.427  0.570  0.792  1.0
  O  O26  1  0.331  0.645  0.266  1.0
  O  O27  1  0.669  0.355  0.734  1.0
  O  O28  1  0.280  0.105  0.475  1.0
  O  O29  1  0.720  0.895  0.525  1.0
  O  O30  1  0.072  0.982  0.163  1.0
  O  O31  1  0.928  0.018  0.837  1.0
  O  O32  1  0.311  0.128  0.671  1.0
  O  O33  1  0.689  0.872  0.329  1.0
  O  O34  1  0.337  0.076  0.167  1.0
  O  O35  1  0.663  0.924  0.833  1.0
[/CIF]
.