The compound described by Hg11As4(GaBr4)4 crystallizes in the monoclinic C2/m space group. The structure consists of eight GaBr4 clusters inside a Hg11As4 framework. In each GaBr4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Br(3), one Br(6), and two equivalent Br(1) atoms. There are three inequivalent Br sites. In the first Br site, Br(3) is bonded in a single-bond geometry to one Ga(1) atom. In the second Br site, Br(6) is bonded in a single-bond geometry to one Ga(1) atom. In the third Br site, Br(1) is bonded in a single-bond geometry to one Ga(1) atom. In the Hg11As4 framework, there are five inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a linear geometry to one Hg(5) and one As(1) atom. In the second Hg site, Hg(2) is bonded in a linear geometry to one As(1) and one As(2) atom. In the third Hg site, Hg(3) is bonded in a linear geometry to one Hg(3) and one As(2) atom. In the fourth Hg site, Hg(4) is bonded in a linear geometry to one As(1) and one As(2) atom. In the fifth Hg site, Hg(5) is bonded in a linear geometry to two equivalent Hg(1) atoms. There are two inequivalent As sites. In the first As site, As(2) is bonded to one Hg(2), one Hg(3), and two equivalent Hg(4) atoms to form corner-sharing AsHg4 tetrahedra. In the second As site, As(1) is bonded to one Hg(1), one Hg(2), and two equivalent Hg(4) atoms to form corner-sharing AsHg4 tetrahedra. is represented by the CIF card [CIF]
data_Ga4Hg11(AsBr4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.930
_cell_length_b   7.930
_cell_length_c   23.324
_cell_angle_alpha   82.501
_cell_angle_beta   82.501
_cell_angle_gamma   59.363
_symmetry_Int_Tables_number   1
_cell_volume   1247.659
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.639  0.639  0.110  1.0
  Ga  Ga1  1  0.361  0.361  0.890  1.0
  Ga  Ga2  1  0.759  0.759  0.614  1.0
  Ga  Ga3  1  0.241  0.241  0.386  1.0
  Hg  Hg4  1  0.032  0.032  0.884  1.0
  Hg  Hg5  1  0.766  0.766  0.283  1.0
  Hg  Hg6  1  0.471  0.471  0.557  1.0
  Hg  Hg7  1  0.733  0.235  0.721  1.0
  Hg  Hg8  1  0.267  0.765  0.279  1.0
  Hg  Hg9  1  0.765  0.267  0.279  1.0
  Hg  Hg10  1  0.235  0.733  0.721  1.0
  Hg  Hg11  1  0.529  0.529  0.443  1.0
  Hg  Hg12  1  0.968  0.968  0.116  1.0
  Hg  Hg13  1  0.000  0.000  0.000  1.0
  Hg  Hg14  1  0.234  0.234  0.717  1.0
  As  As15  1  0.943  0.943  0.231  1.0
  As  As16  1  0.057  0.057  0.769  1.0
  As  As17  1  0.586  0.586  0.330  1.0
  As  As18  1  0.414  0.414  0.670  1.0
  Br  Br19  1  0.534  0.049  0.851  1.0
  Br  Br20  1  0.071  0.071  0.421  1.0
  Br  Br21  1  0.531  0.531  0.851  1.0
  Br  Br22  1  0.434  0.930  0.585  1.0
  Br  Br23  1  0.738  0.738  0.717  1.0
  Br  Br24  1  0.337  0.337  0.991  1.0
  Br  Br25  1  0.466  0.951  0.149  1.0
  Br  Br26  1  0.951  0.466  0.149  1.0
  Br  Br27  1  0.469  0.469  0.149  1.0
  Br  Br28  1  0.566  0.070  0.415  1.0
  Br  Br29  1  0.663  0.663  0.009  1.0
  Br  Br30  1  0.930  0.434  0.585  1.0
  Br  Br31  1  0.262  0.262  0.283  1.0
  Br  Br32  1  0.070  0.566  0.415  1.0
  Br  Br33  1  0.929  0.929  0.579  1.0
  Br  Br34  1  0.049  0.534  0.851  1.0
[/CIF]
.
The compound described by Hg11As4(GaBr4)4 crystallizes in the monoclinic C2/m space group. The structure consists of eight GaBr4 clusters inside a Hg11As4 framework. In each GaBr4 cluster, Ga(1) is bonded in a tetrahedral geometry to one Br(3), one Br(6), and two equivalent Br(1) atoms. There are three inequivalent Br sites. In the first Br site, Br(3) is bonded in a single-bond geometry to one Ga(1) atom. In the second Br site, Br(6) is bonded in a single-bond geometry to one Ga(1) atom. In the third Br site, Br(1) is bonded in a single-bond geometry to one Ga(1) atom. In the Hg11As4 framework, there are five inequivalent Hg sites. In the first Hg site, Hg(1) is bonded in a linear geometry to one Hg(5) and one As(1) atom. In the second Hg site, Hg(2) is bonded in a linear geometry to one As(1) and one As(2) atom. In the third Hg site, Hg(3) is bonded in a linear geometry to one Hg(3) and one As(2) atom. In the fourth Hg site, Hg(4) is bonded in a linear geometry to one As(1) and one As(2) atom. In the fifth Hg site, Hg(5) is bonded in a linear geometry to two equivalent Hg(1) atoms. There are two inequivalent As sites. In the first As site, As(2) is bonded to one Hg(2), one Hg(3), and two equivalent Hg(4) atoms to form corner-sharing AsHg4 tetrahedra. In the second As site, As(1) is bonded to one Hg(1), one Hg(2), and two equivalent Hg(4) atoms to form corner-sharing AsHg4 tetrahedra. is represented by the CIF card [CIF]
data_Ga4Hg11(AsBr4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.930
_cell_length_b   7.930
_cell_length_c   23.324
_cell_angle_alpha   82.501
_cell_angle_beta   82.501
_cell_angle_gamma   59.363
_symmetry_Int_Tables_number   1
_cell_volume   1247.659
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.639  0.639  0.110  1.0
  Ga  Ga1  1  0.361  0.361  0.890  1.0
  Ga  Ga2  1  0.759  0.759  0.614  1.0
  Ga  Ga3  1  0.241  0.241  0.386  1.0
  Hg  Hg4  1  0.032  0.032  0.884  1.0
  Hg  Hg5  1  0.766  0.766  0.283  1.0
  Hg  Hg6  1  0.471  0.471  0.557  1.0
  Hg  Hg7  1  0.733  0.235  0.721  1.0
  Hg  Hg8  1  0.267  0.765  0.279  1.0
  Hg  Hg9  1  0.765  0.267  0.279  1.0
  Hg  Hg10  1  0.235  0.733  0.721  1.0
  Hg  Hg11  1  0.529  0.529  0.443  1.0
  Hg  Hg12  1  0.968  0.968  0.116  1.0
  Hg  Hg13  1  0.000  0.000  0.000  1.0
  Hg  Hg14  1  0.234  0.234  0.717  1.0
  As  As15  1  0.943  0.943  0.231  1.0
  As  As16  1  0.057  0.057  0.769  1.0
  As  As17  1  0.586  0.586  0.330  1.0
  As  As18  1  0.414  0.414  0.670  1.0
  Br  Br19  1  0.534  0.049  0.851  1.0
  Br  Br20  1  0.071  0.071  0.421  1.0
  Br  Br21  1  0.531  0.531  0.851  1.0
  Br  Br22  1  0.434  0.930  0.585  1.0
  Br  Br23  1  0.738  0.738  0.717  1.0
  Br  Br24  1  0.337  0.337  0.991  1.0
  Br  Br25  1  0.466  0.951  0.149  1.0
  Br  Br26  1  0.951  0.466  0.149  1.0
  Br  Br27  1  0.469  0.469  0.149  1.0
  Br  Br28  1  0.566  0.070  0.415  1.0
  Br  Br29  1  0.663  0.663  0.009  1.0
  Br  Br30  1  0.930  0.434  0.585  1.0
  Br  Br31  1  0.262  0.262  0.283  1.0
  Br  Br32  1  0.070  0.566  0.415  1.0
  Br  Br33  1  0.929  0.929  0.579  1.0
  Br  Br34  1  0.049  0.534  0.851  1.0
[/CIF]
.