The crystal structure described by VAu4 crystallizes in the tetragonal I4/m space group. V(1) is bonded to twelve equivalent Au(1) atoms to form a mixture of face and edge-sharing VAu12 cuboctahedra. Au(1) is bonded to three equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing AuV3 cuboctahedra. is represented by the CIF card [CIF]
data_VAu4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.012
_cell_length_b   5.012
_cell_length_c   5.013
_cell_angle_alpha   99.298
_cell_angle_beta   99.301
_cell_angle_gamma   132.589
_symmetry_Int_Tables_number   1
_cell_volume   84.901
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  Au  Au1  1  0.397  0.205  0.601  1.0
  Au  Au2  1  0.603  0.795  0.399  1.0
  Au  Au3  1  0.795  0.397  0.192  1.0
  Au  Au4  1  0.205  0.603  0.808  1.0
[/CIF]
.
The crystal structure described by VAu4 crystallizes in the tetragonal I4/m space group. V(1) is bonded to twelve equivalent Au(1) atoms to form a mixture of face and edge-sharing VAu12 cuboctahedra. Au(1) is bonded to three equivalent V(1) atoms to form a mixture of distorted corner and edge-sharing AuV3 cuboctahedra. is represented by the CIF card [CIF]
data_VAu4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.012
_cell_length_b   5.012
_cell_length_c   5.013
_cell_angle_alpha   99.298
_cell_angle_beta   99.301
_cell_angle_gamma   132.589
_symmetry_Int_Tables_number   1
_cell_volume   84.901
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  Au  Au1  1  0.397  0.205  0.601  1.0
  Au  Au2  1  0.603  0.795  0.399  1.0
  Au  Au3  1  0.795  0.397  0.192  1.0
  Au  Au4  1  0.205  0.603  0.808  1.0
[/CIF]
.