The material described by Sn3As2F15AsF6 is Indium-derived structured and crystallizes in the trigonal R32 space group. The structure is zero-dimensional and consists of three AsF6 clusters and three Sn3As2F15 clusters. In each AsF6 cluster, As(2) is bonded in an octahedral geometry to six equivalent F(3) atoms. F(3) is bonded in a single-bond geometry to one As(2) atom. In each Sn3As2F15 cluster, Sn(1) is bonded in a distorted L-shaped geometry to two equivalent F(1) and two equivalent F(2) atoms. As(1) is bonded in an octahedral geometry to three equivalent F(2) and three equivalent F(4) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Sn(1) atoms. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Sn(1) and one As(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one As(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SnAsF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.866
_cell_length_b   7.866
_cell_length_c   7.866
_cell_angle_alpha   72.921
_cell_angle_beta   72.921
_cell_angle_gamma   72.921
_symmetry_Int_Tables_number   1
_cell_volume   433.144
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.500  0.242  0.758  1.0
  Sn  Sn1  1  0.758  0.500  0.242  1.0
  Sn  Sn2  1  0.242  0.758  0.500  1.0
  As  As3  1  0.701  0.701  0.701  1.0
  As  As4  1  0.299  0.299  0.299  1.0
  As  As5  1  0.000  0.000  0.000  1.0
  F  F6  1  0.321  0.500  0.679  1.0
  F  F7  1  0.679  0.321  0.500  1.0
  F  F8  1  0.500  0.679  0.321  1.0
  F  F9  1  0.798  0.636  0.486  1.0
  F  F10  1  0.486  0.798  0.636  1.0
  F  F11  1  0.636  0.486  0.798  1.0
  F  F12  1  0.150  0.149  0.881  1.0
  F  F13  1  0.149  0.881  0.150  1.0
  F  F14  1  0.881  0.150  0.149  1.0
  F  F15  1  0.851  0.850  0.119  1.0
  F  F16  1  0.850  0.119  0.851  1.0
  F  F17  1  0.119  0.851  0.850  1.0
  F  F18  1  0.239  0.397  0.086  1.0
  F  F19  1  0.397  0.086  0.239  1.0
  F  F20  1  0.086  0.239  0.397  1.0
  F  F21  1  0.603  0.761  0.914  1.0
  F  F22  1  0.761  0.914  0.603  1.0
  F  F23  1  0.914  0.603  0.761  1.0
  F  F24  1  0.514  0.364  0.202  1.0
  F  F25  1  0.364  0.202  0.514  1.0
  F  F26  1  0.202  0.514  0.364  1.0
[/CIF]
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The material described by Sn3As2F15AsF6 is Indium-derived structured and crystallizes in the trigonal R32 space group. The structure is zero-dimensional and consists of three AsF6 clusters and three Sn3As2F15 clusters. In each AsF6 cluster, As(2) is bonded in an octahedral geometry to six equivalent F(3) atoms. F(3) is bonded in a single-bond geometry to one As(2) atom. In each Sn3As2F15 cluster, Sn(1) is bonded in a distorted L-shaped geometry to two equivalent F(1) and two equivalent F(2) atoms. As(1) is bonded in an octahedral geometry to three equivalent F(2) and three equivalent F(4) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Sn(1) atoms. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Sn(1) and one As(1) atom. In the third F site, F(4) is bonded in a single-bond geometry to one As(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SnAsF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.866
_cell_length_b   7.866
_cell_length_c   7.866
_cell_angle_alpha   72.921
_cell_angle_beta   72.921
_cell_angle_gamma   72.921
_symmetry_Int_Tables_number   1
_cell_volume   433.144
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.500  0.242  0.758  1.0
  Sn  Sn1  1  0.758  0.500  0.242  1.0
  Sn  Sn2  1  0.242  0.758  0.500  1.0
  As  As3  1  0.701  0.701  0.701  1.0
  As  As4  1  0.299  0.299  0.299  1.0
  As  As5  1  0.000  0.000  0.000  1.0
  F  F6  1  0.321  0.500  0.679  1.0
  F  F7  1  0.679  0.321  0.500  1.0
  F  F8  1  0.500  0.679  0.321  1.0
  F  F9  1  0.798  0.636  0.486  1.0
  F  F10  1  0.486  0.798  0.636  1.0
  F  F11  1  0.636  0.486  0.798  1.0
  F  F12  1  0.150  0.149  0.881  1.0
  F  F13  1  0.149  0.881  0.150  1.0
  F  F14  1  0.881  0.150  0.149  1.0
  F  F15  1  0.851  0.850  0.119  1.0
  F  F16  1  0.850  0.119  0.851  1.0
  F  F17  1  0.119  0.851  0.850  1.0
  F  F18  1  0.239  0.397  0.086  1.0
  F  F19  1  0.397  0.086  0.239  1.0
  F  F20  1  0.086  0.239  0.397  1.0
  F  F21  1  0.603  0.761  0.914  1.0
  F  F22  1  0.761  0.914  0.603  1.0
  F  F23  1  0.914  0.603  0.761  1.0
  F  F24  1  0.514  0.364  0.202  1.0
  F  F25  1  0.364  0.202  0.514  1.0
  F  F26  1  0.202  0.514  0.364  1.0
[/CIF]
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