The structure described by Mo3S13(N(CH3)4)2 is Indium-derived structured and crystallizes in the trigonal P31m space group. The structure is zero-dimensional and consists of two tetramethylammonium molecules and one Mo3S13 cluster. In the Mo3S13 cluster, Mo(1) is bonded in a 7-coordinate geometry to one S(3), one S(4), one S(5), two equivalent S(1), and two equivalent S(2) atoms. There are five inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and one S(2) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and one S(1) atom. In the third S site, S(3) is bonded in a 2-coordinate geometry to one Mo(1) and one S(4) atom. In the fourth S site, S(4) is bonded in a 2-coordinate geometry to one Mo(1) and one S(3) atom. In the fifth S site, S(5) is bonded in a 3-coordinate geometry to three equivalent Mo(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mo3H24C8S13N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.167
_cell_length_b   11.167
_cell_length_c   6.972
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   752.991
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.000  0.142  0.015  1.0
  Mo  Mo1  1  0.858  0.858  0.015  1.0
  Mo  Mo2  1  0.142  0.000  0.015  1.0
  H  H3  1  0.450  0.246  0.487  1.0
  H  H4  1  0.203  0.754  0.487  1.0
  H  H5  1  0.548  0.432  0.478  1.0
  H  H6  1  0.116  0.568  0.478  1.0
  H  H7  1  0.206  0.657  0.693  1.0
  H  H8  1  0.550  0.343  0.693  1.0
  H  H9  1  0.328  0.757  0.198  1.0
  H  H10  1  0.243  0.570  0.198  1.0
  H  H11  1  0.452  0.884  0.478  1.0
  H  H12  1  0.568  0.116  0.478  1.0
  H  H13  1  0.450  0.794  0.693  1.0
  H  H14  1  0.657  0.206  0.693  1.0
  H  H15  1  0.430  0.672  0.198  1.0
  H  H16  1  0.550  0.797  0.487  1.0
  H  H17  1  0.754  0.203  0.487  1.0
  H  H18  1  0.570  0.243  0.198  1.0
  H  H19  1  0.672  0.430  0.198  1.0
  H  H20  1  0.797  0.550  0.487  1.0
  H  H21  1  0.246  0.450  0.487  1.0
  H  H22  1  0.794  0.450  0.693  1.0
  H  H23  1  0.343  0.550  0.693  1.0
  H  H24  1  0.757  0.328  0.198  1.0
  H  H25  1  0.884  0.452  0.478  1.0
  H  H26  1  0.432  0.548  0.478  1.0
  C  C27  1  0.543  0.339  0.536  1.0
  C  C28  1  0.205  0.661  0.536  1.0
  C  C29  1  0.333  0.667  0.246  1.0
  C  C30  1  0.457  0.795  0.536  1.0
  C  C31  1  0.661  0.205  0.536  1.0
  C  C32  1  0.667  0.333  0.246  1.0
  C  C33  1  0.795  0.457  0.536  1.0
  C  C34  1  0.339  0.543  0.536  1.0
  S  S35  1  0.000  0.826  0.775  1.0
  S  S36  1  0.174  0.174  0.775  1.0
  S  S37  1  0.000  0.742  0.034  1.0
  S  S38  1  0.258  0.258  0.034  1.0
  S  S39  1  0.000  0.363  0.951  1.0
  S  S40  1  0.637  0.637  0.951  1.0
  S  S41  1  0.000  0.309  0.235  1.0
  S  S42  1  0.691  0.691  0.235  1.0
  S  S43  1  0.000  0.000  0.270  1.0
  S  S44  1  0.309  0.000  0.235  1.0
  S  S45  1  0.363  0.000  0.951  1.0
  S  S46  1  0.742  0.000  0.034  1.0
  S  S47  1  0.826  0.000  0.775  1.0
  N  N48  1  0.333  0.667  0.462  1.0
  N  N49  1  0.667  0.333  0.462  1.0
[/CIF]
.
The structure described by Mo3S13(N(CH3)4)2 is Indium-derived structured and crystallizes in the trigonal P31m space group. The structure is zero-dimensional and consists of two tetramethylammonium molecules and one Mo3S13 cluster. In the Mo3S13 cluster, Mo(1) is bonded in a 7-coordinate geometry to one S(3), one S(4), one S(5), two equivalent S(1), and two equivalent S(2) atoms. There are five inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and one S(2) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to two equivalent Mo(1) and one S(1) atom. In the third S site, S(3) is bonded in a 2-coordinate geometry to one Mo(1) and one S(4) atom. In the fourth S site, S(4) is bonded in a 2-coordinate geometry to one Mo(1) and one S(3) atom. In the fifth S site, S(5) is bonded in a 3-coordinate geometry to three equivalent Mo(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mo3H24C8S13N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.167
_cell_length_b   11.167
_cell_length_c   6.972
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   752.991
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.000  0.142  0.015  1.0
  Mo  Mo1  1  0.858  0.858  0.015  1.0
  Mo  Mo2  1  0.142  0.000  0.015  1.0
  H  H3  1  0.450  0.246  0.487  1.0
  H  H4  1  0.203  0.754  0.487  1.0
  H  H5  1  0.548  0.432  0.478  1.0
  H  H6  1  0.116  0.568  0.478  1.0
  H  H7  1  0.206  0.657  0.693  1.0
  H  H8  1  0.550  0.343  0.693  1.0
  H  H9  1  0.328  0.757  0.198  1.0
  H  H10  1  0.243  0.570  0.198  1.0
  H  H11  1  0.452  0.884  0.478  1.0
  H  H12  1  0.568  0.116  0.478  1.0
  H  H13  1  0.450  0.794  0.693  1.0
  H  H14  1  0.657  0.206  0.693  1.0
  H  H15  1  0.430  0.672  0.198  1.0
  H  H16  1  0.550  0.797  0.487  1.0
  H  H17  1  0.754  0.203  0.487  1.0
  H  H18  1  0.570  0.243  0.198  1.0
  H  H19  1  0.672  0.430  0.198  1.0
  H  H20  1  0.797  0.550  0.487  1.0
  H  H21  1  0.246  0.450  0.487  1.0
  H  H22  1  0.794  0.450  0.693  1.0
  H  H23  1  0.343  0.550  0.693  1.0
  H  H24  1  0.757  0.328  0.198  1.0
  H  H25  1  0.884  0.452  0.478  1.0
  H  H26  1  0.432  0.548  0.478  1.0
  C  C27  1  0.543  0.339  0.536  1.0
  C  C28  1  0.205  0.661  0.536  1.0
  C  C29  1  0.333  0.667  0.246  1.0
  C  C30  1  0.457  0.795  0.536  1.0
  C  C31  1  0.661  0.205  0.536  1.0
  C  C32  1  0.667  0.333  0.246  1.0
  C  C33  1  0.795  0.457  0.536  1.0
  C  C34  1  0.339  0.543  0.536  1.0
  S  S35  1  0.000  0.826  0.775  1.0
  S  S36  1  0.174  0.174  0.775  1.0
  S  S37  1  0.000  0.742  0.034  1.0
  S  S38  1  0.258  0.258  0.034  1.0
  S  S39  1  0.000  0.363  0.951  1.0
  S  S40  1  0.637  0.637  0.951  1.0
  S  S41  1  0.000  0.309  0.235  1.0
  S  S42  1  0.691  0.691  0.235  1.0
  S  S43  1  0.000  0.000  0.270  1.0
  S  S44  1  0.309  0.000  0.235  1.0
  S  S45  1  0.363  0.000  0.951  1.0
  S  S46  1  0.742  0.000  0.034  1.0
  S  S47  1  0.826  0.000  0.775  1.0
  N  N48  1  0.333  0.667  0.462  1.0
  N  N49  1  0.667  0.333  0.462  1.0
[/CIF]
.