The material described by Cs2RhF6 crystallizes in the trigonal P-3m1 space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form distorted CsF12 cuboctahedra that share corners with six equivalent Cs(1)F12 cuboctahedra, corners with three equivalent Rh(1)F6 octahedra, faces with eight equivalent Cs(1)F12 cuboctahedra, and faces with three equivalent Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles are 17°. Rh(1) is bonded to six equivalent F(1) atoms to form RhF6 octahedra that share corners with six equivalent Cs(1)F12 cuboctahedra and faces with six equivalent Cs(1)F12 cuboctahedra. F(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Rh(1) atom. is represented by the CIF file [CIF]
data_Cs2RhF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.969
_cell_length_b   6.202
_cell_length_c   6.202
_cell_angle_alpha   120.000
_cell_angle_beta   90.000
_cell_angle_gamma   89.999
_symmetry_Int_Tables_number   1
_cell_volume   165.540
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.705  0.667  0.333  1.0
  Cs  Cs1  1  0.295  0.333  0.667  1.0
  Rh  Rh2  1  1.000  0.000  0.000  1.0
  F  F3  1  0.783  0.149  0.298  1.0
  F  F4  1  0.217  0.851  0.702  1.0
  F  F5  1  0.783  0.149  0.851  1.0
  F  F6  1  0.217  0.851  0.149  1.0
  F  F7  1  0.783  0.702  0.851  1.0
  F  F8  1  0.217  0.298  0.149  1.0
[/CIF]
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The material described by Cs2RhF6 crystallizes in the trigonal P-3m1 space group. Cs(1) is bonded to twelve equivalent F(1) atoms to form distorted CsF12 cuboctahedra that share corners with six equivalent Cs(1)F12 cuboctahedra, corners with three equivalent Rh(1)F6 octahedra, faces with eight equivalent Cs(1)F12 cuboctahedra, and faces with three equivalent Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles are 17°. Rh(1) is bonded to six equivalent F(1) atoms to form RhF6 octahedra that share corners with six equivalent Cs(1)F12 cuboctahedra and faces with six equivalent Cs(1)F12 cuboctahedra. F(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one Rh(1) atom. is represented by the CIF file [CIF]
data_Cs2RhF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.969
_cell_length_b   6.202
_cell_length_c   6.202
_cell_angle_alpha   120.000
_cell_angle_beta   90.000
_cell_angle_gamma   89.999
_symmetry_Int_Tables_number   1
_cell_volume   165.540
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.705  0.667  0.333  1.0
  Cs  Cs1  1  0.295  0.333  0.667  1.0
  Rh  Rh2  1  1.000  0.000  0.000  1.0
  F  F3  1  0.783  0.149  0.298  1.0
  F  F4  1  0.217  0.851  0.702  1.0
  F  F5  1  0.783  0.149  0.851  1.0
  F  F6  1  0.217  0.851  0.149  1.0
  F  F7  1  0.783  0.702  0.851  1.0
  F  F8  1  0.217  0.298  0.149  1.0
[/CIF]
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