The material structure described by NiC2H4(NS2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four NiC2H4(NS2)2 clusters. Ni(1) is bonded in a square co-planar geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1), one S(3), and one S(4) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2), one S(1), and one S(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(2), and one H(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one H(1), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. There are four inequivalent S sites. In the first S site, S(3) is bonded in an L-shaped geometry to one Ni(1) and one C(1) atom. In the second S site, S(4) is bonded in an L-shaped geometry to one Ni(1) and one C(1) atom. In the third S site, S(1) is bonded in an L-shaped geometry to one Ni(1) and one C(2) atom. In the fourth S site, S(2) is bonded in an L-shaped geometry to one Ni(1) and one C(2) atom. is represented by the CIF card [CIF]
data_NiH4C2(S2N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.116
_cell_length_b   7.232
_cell_length_c   11.164
_cell_angle_alpha   49.636
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   806.843
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.129  0.115  0.023  1.0
  Ni  Ni1  1  0.629  0.885  0.477  1.0
  Ni  Ni2  1  0.871  0.885  0.977  1.0
  Ni  Ni3  1  0.371  0.115  0.523  1.0
  H  H4  1  0.233  0.618  0.023  1.0
  H  H5  1  0.733  0.382  0.477  1.0
  H  H6  1  0.495  0.639  0.032  1.0
  H  H7  1  0.917  0.876  0.435  1.0
  H  H8  1  0.005  0.639  0.532  1.0
  H  H9  1  0.853  0.625  0.878  1.0
  H  H10  1  0.647  0.625  0.378  1.0
  H  H11  1  0.417  0.124  0.065  1.0
  H  H12  1  0.995  0.361  0.468  1.0
  H  H13  1  0.767  0.382  0.977  1.0
  H  H14  1  0.267  0.618  0.523  1.0
  H  H15  1  0.505  0.361  0.968  1.0
  H  H16  1  0.583  0.876  0.935  1.0
  H  H17  1  0.353  0.375  0.622  1.0
  H  H18  1  0.083  0.124  0.565  1.0
  H  H19  1  0.147  0.375  0.122  1.0
  C  C20  1  0.474  0.897  0.794  1.0
  C  C21  1  0.762  0.652  0.243  1.0
  C  C22  1  0.526  0.103  0.206  1.0
  C  C23  1  0.238  0.348  0.757  1.0
  C  C24  1  0.262  0.348  0.257  1.0
  C  C25  1  0.026  0.897  0.294  1.0
  C  C26  1  0.974  0.103  0.706  1.0
  C  C27  1  0.738  0.652  0.743  1.0
  S  S28  1  0.130  0.458  0.778  1.0
  S  S29  1  0.870  0.542  0.222  1.0
  S  S30  1  0.630  0.542  0.722  1.0
  S  S31  1  0.730  0.926  0.064  1.0
  S  S32  1  0.992  0.165  0.116  1.0
  S  S33  1  0.508  0.165  0.616  1.0
  S  S34  1  0.370  0.458  0.278  1.0
  S  S35  1  0.631  0.220  0.228  1.0
  S  S36  1  0.270  0.074  0.936  1.0
  S  S37  1  0.131  0.780  0.272  1.0
  S  S38  1  0.230  0.074  0.436  1.0
  S  S39  1  0.369  0.780  0.772  1.0
  S  S40  1  0.869  0.220  0.728  1.0
  S  S41  1  0.770  0.926  0.564  1.0
  S  S42  1  0.492  0.835  0.384  1.0
  S  S43  1  0.008  0.835  0.884  1.0
  N  N44  1  0.021  0.203  0.571  1.0
  N  N45  1  0.710  0.546  0.375  1.0
  N  N46  1  0.290  0.454  0.625  1.0
  N  N47  1  0.521  0.797  0.929  1.0
  N  N48  1  0.210  0.454  0.125  1.0
  N  N49  1  0.479  0.203  0.071  1.0
  N  N50  1  0.790  0.546  0.875  1.0
  N  N51  1  0.979  0.797  0.429  1.0
[/CIF]
.
The material structure described by NiC2H4(NS2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four NiC2H4(NS2)2 clusters. Ni(1) is bonded in a square co-planar geometry to one S(1), one S(2), one S(3), and one S(4) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1), one S(3), and one S(4) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2), one S(1), and one S(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(2), and one H(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one H(1), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. There are four inequivalent S sites. In the first S site, S(3) is bonded in an L-shaped geometry to one Ni(1) and one C(1) atom. In the second S site, S(4) is bonded in an L-shaped geometry to one Ni(1) and one C(1) atom. In the third S site, S(1) is bonded in an L-shaped geometry to one Ni(1) and one C(2) atom. In the fourth S site, S(2) is bonded in an L-shaped geometry to one Ni(1) and one C(2) atom. is represented by the CIF card [CIF]
data_NiH4C2(S2N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.116
_cell_length_b   7.232
_cell_length_c   11.164
_cell_angle_alpha   49.636
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   806.843
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.129  0.115  0.023  1.0
  Ni  Ni1  1  0.629  0.885  0.477  1.0
  Ni  Ni2  1  0.871  0.885  0.977  1.0
  Ni  Ni3  1  0.371  0.115  0.523  1.0
  H  H4  1  0.233  0.618  0.023  1.0
  H  H5  1  0.733  0.382  0.477  1.0
  H  H6  1  0.495  0.639  0.032  1.0
  H  H7  1  0.917  0.876  0.435  1.0
  H  H8  1  0.005  0.639  0.532  1.0
  H  H9  1  0.853  0.625  0.878  1.0
  H  H10  1  0.647  0.625  0.378  1.0
  H  H11  1  0.417  0.124  0.065  1.0
  H  H12  1  0.995  0.361  0.468  1.0
  H  H13  1  0.767  0.382  0.977  1.0
  H  H14  1  0.267  0.618  0.523  1.0
  H  H15  1  0.505  0.361  0.968  1.0
  H  H16  1  0.583  0.876  0.935  1.0
  H  H17  1  0.353  0.375  0.622  1.0
  H  H18  1  0.083  0.124  0.565  1.0
  H  H19  1  0.147  0.375  0.122  1.0
  C  C20  1  0.474  0.897  0.794  1.0
  C  C21  1  0.762  0.652  0.243  1.0
  C  C22  1  0.526  0.103  0.206  1.0
  C  C23  1  0.238  0.348  0.757  1.0
  C  C24  1  0.262  0.348  0.257  1.0
  C  C25  1  0.026  0.897  0.294  1.0
  C  C26  1  0.974  0.103  0.706  1.0
  C  C27  1  0.738  0.652  0.743  1.0
  S  S28  1  0.130  0.458  0.778  1.0
  S  S29  1  0.870  0.542  0.222  1.0
  S  S30  1  0.630  0.542  0.722  1.0
  S  S31  1  0.730  0.926  0.064  1.0
  S  S32  1  0.992  0.165  0.116  1.0
  S  S33  1  0.508  0.165  0.616  1.0
  S  S34  1  0.370  0.458  0.278  1.0
  S  S35  1  0.631  0.220  0.228  1.0
  S  S36  1  0.270  0.074  0.936  1.0
  S  S37  1  0.131  0.780  0.272  1.0
  S  S38  1  0.230  0.074  0.436  1.0
  S  S39  1  0.369  0.780  0.772  1.0
  S  S40  1  0.869  0.220  0.728  1.0
  S  S41  1  0.770  0.926  0.564  1.0
  S  S42  1  0.492  0.835  0.384  1.0
  S  S43  1  0.008  0.835  0.884  1.0
  N  N44  1  0.021  0.203  0.571  1.0
  N  N45  1  0.710  0.546  0.375  1.0
  N  N46  1  0.290  0.454  0.625  1.0
  N  N47  1  0.521  0.797  0.929  1.0
  N  N48  1  0.210  0.454  0.125  1.0
  N  N49  1  0.479  0.203  0.071  1.0
  N  N50  1  0.790  0.546  0.875  1.0
  N  N51  1  0.979  0.797  0.429  1.0
[/CIF]
.