The crystal structure described by CdV2O6 is Brookite-derived structured and crystallizes in the orthorhombic Pbcn space group. V(1) is bonded in a 6-coordinate geometry to one O(2), two equivalent O(3), and three equivalent O(1) atoms. Cd(1) is bonded in a 6-coordinate geometry to two equivalent O(3) and four equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to three equivalent V(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Cd(1) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to two equivalent V(1) and one Cd(1) atom. is represented by the CIF file [CIF]
data_V2CdO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.970
_cell_length_b   5.855
_cell_length_c   14.382
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   418.495
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.221  0.183  0.333  1.0
  V  V1  1  0.221  0.683  0.167  1.0
  V  V2  1  0.721  0.317  0.167  1.0
  V  V3  1  0.279  0.183  0.667  1.0
  V  V4  1  0.279  0.683  0.833  1.0
  V  V5  1  0.779  0.317  0.833  1.0
  V  V6  1  0.721  0.817  0.333  1.0
  V  V7  1  0.779  0.817  0.667  1.0
  Cd  Cd8  1  0.250  0.218  0.000  1.0
  Cd  Cd9  1  0.750  0.282  0.500  1.0
  Cd  Cd10  1  0.750  0.782  0.000  1.0
  Cd  Cd11  1  0.250  0.718  0.500  1.0
  O  O12  1  0.894  0.651  0.246  1.0
  O  O13  1  0.387  0.880  0.910  1.0
  O  O14  1  0.387  0.380  0.590  1.0
  O  O15  1  0.482  0.422  0.894  1.0
  O  O16  1  0.018  0.922  0.394  1.0
  O  O17  1  0.518  0.078  0.394  1.0
  O  O18  1  0.113  0.880  0.090  1.0
  O  O19  1  0.982  0.078  0.606  1.0
  O  O20  1  0.106  0.349  0.754  1.0
  O  O21  1  0.113  0.380  0.410  1.0
  O  O22  1  0.887  0.620  0.590  1.0
  O  O23  1  0.482  0.922  0.606  1.0
  O  O24  1  0.894  0.151  0.254  1.0
  O  O25  1  0.018  0.422  0.106  1.0
  O  O26  1  0.518  0.578  0.106  1.0
  O  O27  1  0.982  0.578  0.894  1.0
  O  O28  1  0.613  0.120  0.090  1.0
  O  O29  1  0.394  0.849  0.254  1.0
  O  O30  1  0.106  0.849  0.746  1.0
  O  O31  1  0.887  0.120  0.910  1.0
  O  O32  1  0.613  0.620  0.410  1.0
  O  O33  1  0.394  0.349  0.246  1.0
  O  O34  1  0.606  0.651  0.754  1.0
  O  O35  1  0.606  0.151  0.746  1.0
[/CIF]
.
The crystal structure described by CdV2O6 is Brookite-derived structured and crystallizes in the orthorhombic Pbcn space group. V(1) is bonded in a 6-coordinate geometry to one O(2), two equivalent O(3), and three equivalent O(1) atoms. Cd(1) is bonded in a 6-coordinate geometry to two equivalent O(3) and four equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to three equivalent V(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Cd(1) atoms. In the third O site, O(3) is bonded in a trigonal planar geometry to two equivalent V(1) and one Cd(1) atom. is represented by the CIF file [CIF]
data_V2CdO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.970
_cell_length_b   5.855
_cell_length_c   14.382
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   418.495
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.221  0.183  0.333  1.0
  V  V1  1  0.221  0.683  0.167  1.0
  V  V2  1  0.721  0.317  0.167  1.0
  V  V3  1  0.279  0.183  0.667  1.0
  V  V4  1  0.279  0.683  0.833  1.0
  V  V5  1  0.779  0.317  0.833  1.0
  V  V6  1  0.721  0.817  0.333  1.0
  V  V7  1  0.779  0.817  0.667  1.0
  Cd  Cd8  1  0.250  0.218  0.000  1.0
  Cd  Cd9  1  0.750  0.282  0.500  1.0
  Cd  Cd10  1  0.750  0.782  0.000  1.0
  Cd  Cd11  1  0.250  0.718  0.500  1.0
  O  O12  1  0.894  0.651  0.246  1.0
  O  O13  1  0.387  0.880  0.910  1.0
  O  O14  1  0.387  0.380  0.590  1.0
  O  O15  1  0.482  0.422  0.894  1.0
  O  O16  1  0.018  0.922  0.394  1.0
  O  O17  1  0.518  0.078  0.394  1.0
  O  O18  1  0.113  0.880  0.090  1.0
  O  O19  1  0.982  0.078  0.606  1.0
  O  O20  1  0.106  0.349  0.754  1.0
  O  O21  1  0.113  0.380  0.410  1.0
  O  O22  1  0.887  0.620  0.590  1.0
  O  O23  1  0.482  0.922  0.606  1.0
  O  O24  1  0.894  0.151  0.254  1.0
  O  O25  1  0.018  0.422  0.106  1.0
  O  O26  1  0.518  0.578  0.106  1.0
  O  O27  1  0.982  0.578  0.894  1.0
  O  O28  1  0.613  0.120  0.090  1.0
  O  O29  1  0.394  0.849  0.254  1.0
  O  O30  1  0.106  0.849  0.746  1.0
  O  O31  1  0.887  0.120  0.910  1.0
  O  O32  1  0.613  0.620  0.410  1.0
  O  O33  1  0.394  0.349  0.246  1.0
  O  O34  1  0.606  0.651  0.754  1.0
  O  O35  1  0.606  0.151  0.746  1.0
[/CIF]
.