The crystal structure described by V(CO3)2 crystallizes in the tetragonal I-42d space group. V(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one V(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one C(1) atom. is represented by the CIF card [CIF]
data_V(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.469
_cell_length_b   8.469
_cell_length_c   8.469
_cell_angle_alpha   107.430
_cell_angle_beta   107.430
_cell_angle_gamma   113.635
_symmetry_Int_Tables_number   1
_cell_volume   465.711
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.405  0.875  0.030  1.0
  V  V1  1  0.125  0.155  0.530  1.0
  V  V2  1  0.845  0.375  0.970  1.0
  V  V3  1  0.625  0.595  0.470  1.0
  C  C4  1  0.947  0.608  0.766  1.0
  C  C5  1  0.392  0.158  0.339  1.0
  C  C6  1  0.431  0.592  0.734  1.0
  C  C7  1  0.842  0.181  0.234  1.0
  C  C8  1  0.819  0.053  0.661  1.0
  C  C9  1  0.303  0.569  0.161  1.0
  C  C10  1  0.408  0.142  0.839  1.0
  C  C11  1  0.858  0.697  0.266  1.0
  O  O12  1  0.529  0.313  0.358  1.0
  O  O13  1  0.135  0.688  0.856  1.0
  O  O14  1  0.483  0.766  0.847  1.0
  O  O15  1  0.828  0.471  0.783  1.0
  O  O16  1  0.332  0.984  0.217  1.0
  O  O17  1  0.528  0.581  0.644  1.0
  O  O18  1  0.016  0.233  0.347  1.0
  O  O19  1  0.295  0.437  0.717  1.0
  O  O20  1  0.687  0.045  0.217  1.0
  O  O21  1  0.955  0.172  0.642  1.0
  O  O22  1  0.312  0.169  0.447  1.0
  O  O23  1  0.422  0.705  0.142  1.0
  O  O24  1  0.722  0.865  0.553  1.0
  O  O25  1  0.115  0.472  0.053  1.0
  O  O26  1  0.938  0.885  0.356  1.0
  O  O27  1  0.563  0.279  0.858  1.0
  O  O28  1  0.234  0.082  0.717  1.0
  O  O29  1  0.365  0.517  0.283  1.0
  O  O30  1  0.419  0.062  0.947  1.0
  O  O31  1  0.918  0.635  0.153  1.0
  O  O32  1  0.721  0.578  0.283  1.0
  O  O33  1  0.767  0.115  0.783  1.0
  O  O34  1  0.885  0.668  0.653  1.0
  O  O35  1  0.831  0.278  0.144  1.0
[/CIF]
.
The crystal structure described by V(CO3)2 crystallizes in the tetragonal I-42d space group. V(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one V(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one C(1) atom. is represented by the CIF card [CIF]
data_V(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.469
_cell_length_b   8.469
_cell_length_c   8.469
_cell_angle_alpha   107.430
_cell_angle_beta   107.430
_cell_angle_gamma   113.635
_symmetry_Int_Tables_number   1
_cell_volume   465.711
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.405  0.875  0.030  1.0
  V  V1  1  0.125  0.155  0.530  1.0
  V  V2  1  0.845  0.375  0.970  1.0
  V  V3  1  0.625  0.595  0.470  1.0
  C  C4  1  0.947  0.608  0.766  1.0
  C  C5  1  0.392  0.158  0.339  1.0
  C  C6  1  0.431  0.592  0.734  1.0
  C  C7  1  0.842  0.181  0.234  1.0
  C  C8  1  0.819  0.053  0.661  1.0
  C  C9  1  0.303  0.569  0.161  1.0
  C  C10  1  0.408  0.142  0.839  1.0
  C  C11  1  0.858  0.697  0.266  1.0
  O  O12  1  0.529  0.313  0.358  1.0
  O  O13  1  0.135  0.688  0.856  1.0
  O  O14  1  0.483  0.766  0.847  1.0
  O  O15  1  0.828  0.471  0.783  1.0
  O  O16  1  0.332  0.984  0.217  1.0
  O  O17  1  0.528  0.581  0.644  1.0
  O  O18  1  0.016  0.233  0.347  1.0
  O  O19  1  0.295  0.437  0.717  1.0
  O  O20  1  0.687  0.045  0.217  1.0
  O  O21  1  0.955  0.172  0.642  1.0
  O  O22  1  0.312  0.169  0.447  1.0
  O  O23  1  0.422  0.705  0.142  1.0
  O  O24  1  0.722  0.865  0.553  1.0
  O  O25  1  0.115  0.472  0.053  1.0
  O  O26  1  0.938  0.885  0.356  1.0
  O  O27  1  0.563  0.279  0.858  1.0
  O  O28  1  0.234  0.082  0.717  1.0
  O  O29  1  0.365  0.517  0.283  1.0
  O  O30  1  0.419  0.062  0.947  1.0
  O  O31  1  0.918  0.635  0.153  1.0
  O  O32  1  0.721  0.578  0.283  1.0
  O  O33  1  0.767  0.115  0.783  1.0
  O  O34  1  0.885  0.668  0.653  1.0
  O  O35  1  0.831  0.278  0.144  1.0
[/CIF]
.