The structure described by RhZn3F6 crystallizes in the triclinic P-1 space group. Rh(1) is bonded in a distorted linear geometry to two equivalent F(1) atoms. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a linear geometry to two equivalent F(2) atoms. In the second Zn site, Zn(2) is bonded in a distorted linear geometry to two equivalent F(2) and two equivalent F(3) atoms. In the third Zn site, Zn(3) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in an L-shaped geometry to one Rh(1) and one Zn(3) atom. In the second F site, F(2) is bonded in a distorted linear geometry to one Zn(1) and one Zn(2) atom. In the third F site, F(3) is bonded in a water-like geometry to one Zn(2) and one Zn(3) atom. is represented by the CIF file [CIF]
data_Zn3RhF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.388
_cell_length_b   5.654
_cell_length_c   8.392
_cell_angle_alpha   71.790
_cell_angle_beta   89.840
_cell_angle_gamma   127.130
_symmetry_Int_Tables_number   1
_cell_volume   222.110
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.500  1.0
  Zn  Zn1  1  0.500  0.500  0.000  1.0
  Zn  Zn2  1  0.000  0.500  0.000  1.0
  Rh  Rh3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.968  0.300  0.822  1.0
  F  F5  1  0.032  0.700  0.178  1.0
  F  F6  1  0.788  0.736  0.713  1.0
  F  F7  1  0.212  0.264  0.287  1.0
  F  F8  1  0.392  0.759  0.926  1.0
  F  F9  1  0.608  0.241  0.074  1.0
[/CIF]
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The structure described by RhZn3F6 crystallizes in the triclinic P-1 space group. Rh(1) is bonded in a distorted linear geometry to two equivalent F(1) atoms. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a linear geometry to two equivalent F(2) atoms. In the second Zn site, Zn(2) is bonded in a distorted linear geometry to two equivalent F(2) and two equivalent F(3) atoms. In the third Zn site, Zn(3) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in an L-shaped geometry to one Rh(1) and one Zn(3) atom. In the second F site, F(2) is bonded in a distorted linear geometry to one Zn(1) and one Zn(2) atom. In the third F site, F(3) is bonded in a water-like geometry to one Zn(2) and one Zn(3) atom. is represented by the CIF file [CIF]
data_Zn3RhF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.388
_cell_length_b   5.654
_cell_length_c   8.392
_cell_angle_alpha   71.790
_cell_angle_beta   89.840
_cell_angle_gamma   127.130
_symmetry_Int_Tables_number   1
_cell_volume   222.110
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.000  0.000  0.500  1.0
  Zn  Zn1  1  0.500  0.500  0.000  1.0
  Zn  Zn2  1  0.000  0.500  0.000  1.0
  Rh  Rh3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.968  0.300  0.822  1.0
  F  F5  1  0.032  0.700  0.178  1.0
  F  F6  1  0.788  0.736  0.713  1.0
  F  F7  1  0.212  0.264  0.287  1.0
  F  F8  1  0.392  0.759  0.926  1.0
  F  F9  1  0.608  0.241  0.074  1.0
[/CIF]
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