The compound described by VP(H2O3)2 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form VO6 octahedra that share corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-45°. There are four inequivalent H sites. In the first H site, H(1) is bonded in a distorted bent 150 degrees geometry to one O(1) and one O(5) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(4) and one O(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(6) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one P(1), and one H(2) atom. In the third O site, O(5) is bonded in a 3-coordinate geometry to one V(1), one H(1), and one H(2) atom. In the fourth O site, O(6) is bonded in a distorted water-like geometry to one V(1), one H(3), and one H(4) atom. In the fifth O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one P(1), and one H(1) atom. In the sixth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(1) atom. is represented by the CIF card [CIF]
data_VP(H2O3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.981
_cell_length_b   5.340
_cell_length_c   10.195
_cell_angle_alpha   60.028
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   470.695
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.823  0.395  0.697  1.0
  V  V1  1  0.677  0.395  0.197  1.0
  V  V2  1  0.177  0.605  0.303  1.0
  V  V3  1  0.323  0.605  0.803  1.0
  P  P4  1  0.644  0.771  0.820  1.0
  P  P5  1  0.856  0.771  0.320  1.0
  P  P6  1  0.356  0.229  0.180  1.0
  P  P7  1  0.144  0.229  0.680  1.0
  H  H8  1  0.039  0.617  0.724  1.0
  H  H9  1  0.461  0.617  0.224  1.0
  H  H10  1  0.961  0.383  0.276  1.0
  H  H11  1  0.539  0.383  0.776  1.0
  H  H12  1  0.943  0.903  0.669  1.0
  H  H13  1  0.557  0.903  0.169  1.0
  H  H14  1  0.057  0.097  0.331  1.0
  H  H15  1  0.443  0.097  0.831  1.0
  H  H16  1  0.842  0.210  0.001  1.0
  H  H17  1  0.658  0.210  0.501  1.0
  H  H18  1  0.158  0.790  0.999  1.0
  H  H19  1  0.342  0.790  0.499  1.0
  H  H20  1  0.835  0.940  0.976  1.0
  H  H21  1  0.665  0.940  0.476  1.0
  H  H22  1  0.165  0.060  0.024  1.0
  H  H23  1  0.335  0.060  0.524  1.0
  O  O24  1  0.666  0.586  0.742  1.0
  O  O25  1  0.834  0.586  0.242  1.0
  O  O26  1  0.334  0.414  0.258  1.0
  O  O27  1  0.166  0.414  0.758  1.0
  O  O28  1  0.719  0.639  0.973  1.0
  O  O29  1  0.781  0.639  0.473  1.0
  O  O30  1  0.281  0.361  0.027  1.0
  O  O31  1  0.219  0.361  0.527  1.0
  O  O32  1  0.697  0.080  0.713  1.0
  O  O33  1  0.803  0.080  0.213  1.0
  O  O34  1  0.303  0.920  0.287  1.0
  O  O35  1  0.197  0.920  0.787  1.0
  O  O36  1  0.490  0.785  0.842  1.0
  O  O37  1  0.010  0.785  0.342  1.0
  O  O38  1  0.510  0.215  0.158  1.0
  O  O39  1  0.990  0.215  0.658  1.0
  O  O40  1  0.946  0.697  0.693  1.0
  O  O41  1  0.554  0.697  0.193  1.0
  O  O42  1  0.054  0.303  0.307  1.0
  O  O43  1  0.446  0.303  0.807  1.0
  O  O44  1  0.862  0.145  0.927  1.0
  O  O45  1  0.638  0.145  0.427  1.0
  O  O46  1  0.138  0.855  0.073  1.0
  O  O47  1  0.362  0.855  0.573  1.0
[/CIF]
.
The compound described by VP(H2O3)2 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form VO6 octahedra that share corners with four equivalent P(1)O4 tetrahedra. P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with four equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-45°. There are four inequivalent H sites. In the first H site, H(1) is bonded in a distorted bent 150 degrees geometry to one O(1) and one O(5) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(4) and one O(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(6) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a bent 150 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one P(1), and one H(2) atom. In the third O site, O(5) is bonded in a 3-coordinate geometry to one V(1), one H(1), and one H(2) atom. In the fourth O site, O(6) is bonded in a distorted water-like geometry to one V(1), one H(3), and one H(4) atom. In the fifth O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one V(1), one P(1), and one H(1) atom. In the sixth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(1) atom. is represented by the CIF card [CIF]
data_VP(H2O3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.981
_cell_length_b   5.340
_cell_length_c   10.195
_cell_angle_alpha   60.028
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   470.695
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.823  0.395  0.697  1.0
  V  V1  1  0.677  0.395  0.197  1.0
  V  V2  1  0.177  0.605  0.303  1.0
  V  V3  1  0.323  0.605  0.803  1.0
  P  P4  1  0.644  0.771  0.820  1.0
  P  P5  1  0.856  0.771  0.320  1.0
  P  P6  1  0.356  0.229  0.180  1.0
  P  P7  1  0.144  0.229  0.680  1.0
  H  H8  1  0.039  0.617  0.724  1.0
  H  H9  1  0.461  0.617  0.224  1.0
  H  H10  1  0.961  0.383  0.276  1.0
  H  H11  1  0.539  0.383  0.776  1.0
  H  H12  1  0.943  0.903  0.669  1.0
  H  H13  1  0.557  0.903  0.169  1.0
  H  H14  1  0.057  0.097  0.331  1.0
  H  H15  1  0.443  0.097  0.831  1.0
  H  H16  1  0.842  0.210  0.001  1.0
  H  H17  1  0.658  0.210  0.501  1.0
  H  H18  1  0.158  0.790  0.999  1.0
  H  H19  1  0.342  0.790  0.499  1.0
  H  H20  1  0.835  0.940  0.976  1.0
  H  H21  1  0.665  0.940  0.476  1.0
  H  H22  1  0.165  0.060  0.024  1.0
  H  H23  1  0.335  0.060  0.524  1.0
  O  O24  1  0.666  0.586  0.742  1.0
  O  O25  1  0.834  0.586  0.242  1.0
  O  O26  1  0.334  0.414  0.258  1.0
  O  O27  1  0.166  0.414  0.758  1.0
  O  O28  1  0.719  0.639  0.973  1.0
  O  O29  1  0.781  0.639  0.473  1.0
  O  O30  1  0.281  0.361  0.027  1.0
  O  O31  1  0.219  0.361  0.527  1.0
  O  O32  1  0.697  0.080  0.713  1.0
  O  O33  1  0.803  0.080  0.213  1.0
  O  O34  1  0.303  0.920  0.287  1.0
  O  O35  1  0.197  0.920  0.787  1.0
  O  O36  1  0.490  0.785  0.842  1.0
  O  O37  1  0.010  0.785  0.342  1.0
  O  O38  1  0.510  0.215  0.158  1.0
  O  O39  1  0.990  0.215  0.658  1.0
  O  O40  1  0.946  0.697  0.693  1.0
  O  O41  1  0.554  0.697  0.193  1.0
  O  O42  1  0.054  0.303  0.307  1.0
  O  O43  1  0.446  0.303  0.807  1.0
  O  O44  1  0.862  0.145  0.927  1.0
  O  O45  1  0.638  0.145  0.427  1.0
  O  O46  1  0.138  0.855  0.073  1.0
  O  O47  1  0.362  0.855  0.573  1.0
[/CIF]
.