The structure described by NH5OBr is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four azane;hydrate;hydrobromide molecules. N(1) is bonded in a trigonal non-coplanar geometry to one H(3), one H(4), and one H(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) and one Br(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) and one Br(1) atom. O(1) is bonded in a water-like geometry to one H(1) and one H(2) atom. Br(1) is bonded in a distorted water-like geometry to one H(2) and one H(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H5BrNO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.331
_cell_length_b   6.727
_cell_length_c   7.830
_cell_angle_alpha   68.326
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   358.856
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.195  0.870  0.134  1.0
  H  H1  1  0.695  0.130  0.366  1.0
  H  H2  1  0.805  0.130  0.866  1.0
  H  H3  1  0.305  0.870  0.634  1.0
  H  H4  1  0.093  0.762  0.014  1.0
  H  H5  1  0.593  0.238  0.486  1.0
  H  H6  1  0.907  0.238  0.986  1.0
  H  H7  1  0.407  0.762  0.514  1.0
  H  H8  1  0.043  0.597  0.301  1.0
  H  H9  1  0.543  0.403  0.199  1.0
  H  H10  1  0.957  0.403  0.699  1.0
  H  H11  1  0.457  0.597  0.801  1.0
  H  H12  1  0.628  0.405  0.905  1.0
  H  H13  1  0.128  0.595  0.595  1.0
  H  H14  1  0.372  0.595  0.095  1.0
  H  H15  1  0.872  0.405  0.405  1.0
  H  H16  1  0.353  0.345  0.096  1.0
  H  H17  1  0.853  0.655  0.404  1.0
  H  H18  1  0.647  0.655  0.904  1.0
  H  H19  1  0.147  0.345  0.596  1.0
  Br  Br20  1  0.393  0.160  0.709  1.0
  Br  Br21  1  0.893  0.840  0.791  1.0
  Br  Br22  1  0.607  0.840  0.291  1.0
  Br  Br23  1  0.107  0.160  0.209  1.0
  N  N24  1  0.550  0.533  0.914  1.0
  N  N25  1  0.050  0.467  0.586  1.0
  N  N26  1  0.950  0.533  0.414  1.0
  N  N27  1  0.450  0.467  0.086  1.0
  O  O28  1  0.177  0.729  0.122  1.0
  O  O29  1  0.823  0.271  0.878  1.0
  O  O30  1  0.677  0.271  0.378  1.0
  O  O31  1  0.323  0.729  0.622  1.0
[/CIF]
.
The structure described by NH5OBr is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four azane;hydrate;hydrobromide molecules. N(1) is bonded in a trigonal non-coplanar geometry to one H(3), one H(4), and one H(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) and one Br(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) and one Br(1) atom. O(1) is bonded in a water-like geometry to one H(1) and one H(2) atom. Br(1) is bonded in a distorted water-like geometry to one H(2) and one H(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H5BrNO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.331
_cell_length_b   6.727
_cell_length_c   7.830
_cell_angle_alpha   68.326
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   358.856
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.195  0.870  0.134  1.0
  H  H1  1  0.695  0.130  0.366  1.0
  H  H2  1  0.805  0.130  0.866  1.0
  H  H3  1  0.305  0.870  0.634  1.0
  H  H4  1  0.093  0.762  0.014  1.0
  H  H5  1  0.593  0.238  0.486  1.0
  H  H6  1  0.907  0.238  0.986  1.0
  H  H7  1  0.407  0.762  0.514  1.0
  H  H8  1  0.043  0.597  0.301  1.0
  H  H9  1  0.543  0.403  0.199  1.0
  H  H10  1  0.957  0.403  0.699  1.0
  H  H11  1  0.457  0.597  0.801  1.0
  H  H12  1  0.628  0.405  0.905  1.0
  H  H13  1  0.128  0.595  0.595  1.0
  H  H14  1  0.372  0.595  0.095  1.0
  H  H15  1  0.872  0.405  0.405  1.0
  H  H16  1  0.353  0.345  0.096  1.0
  H  H17  1  0.853  0.655  0.404  1.0
  H  H18  1  0.647  0.655  0.904  1.0
  H  H19  1  0.147  0.345  0.596  1.0
  Br  Br20  1  0.393  0.160  0.709  1.0
  Br  Br21  1  0.893  0.840  0.791  1.0
  Br  Br22  1  0.607  0.840  0.291  1.0
  Br  Br23  1  0.107  0.160  0.209  1.0
  N  N24  1  0.550  0.533  0.914  1.0
  N  N25  1  0.050  0.467  0.586  1.0
  N  N26  1  0.950  0.533  0.414  1.0
  N  N27  1  0.450  0.467  0.086  1.0
  O  O28  1  0.177  0.729  0.122  1.0
  O  O29  1  0.823  0.271  0.878  1.0
  O  O30  1  0.677  0.271  0.378  1.0
  O  O31  1  0.323  0.729  0.622  1.0
[/CIF]
.