The crystal structure described by Co4Zn3(SbO6)2 is Spinel-derived structured and crystallizes in the triclinic P-1 space group. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(10), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Zn(2)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra, corners with three equivalent Zn(3)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. In the second Co site, Co(2) is bonded to one O(11), one O(12), one O(2), one O(3), one O(8), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with three equivalent Zn(3)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. In the third Co site, Co(3) is bonded to two equivalent O(1), two equivalent O(10), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with two equivalent Zn(2)O4 tetrahedra, corners with four equivalent Zn(1)O4 tetrahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. In the fourth Co site, Co(4) is bonded to one O(1), one O(2), one O(4), one O(5), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. In the fifth Co site, Co(5) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(10), one O(3), one O(5), and one O(7) atom to form ZnO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, and corners with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-63°. In the second Zn site, Zn(2) is bonded to one O(1), one O(11), one O(6), and one O(8) atom to form ZnO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, and corners with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-62°. In the third Zn site, Zn(3) is bonded to one O(12), one O(2), one O(4), and one O(9) atom to form ZnO4 tetrahedra that share  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with three equivalent Co(1)O6 octahedra, and corners with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-63°. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(11), two equivalent O(5), and two equivalent O(8) atoms to form SbO6 octahedra that share corners with two equivalent Zn(1)O4 tetrahedra, corners with four equivalent Zn(2)O4 tetrahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. In the second Sb site, Sb(2) is bonded to one O(1), one O(10), one O(11), one O(2), one O(4), and one O(5) atom to form SbO6 octahedra that share corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. In the third Sb site, Sb(3) is bonded to two equivalent O(12), two equivalent O(3), and two equivalent O(6) atoms to form SbO6 octahedra that share corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Co(3), one Co(4), one Zn(2), and one Sb(2) atom. In the second O site, O(2) is bonded in a distorted tetrahedral geometry to one Co(2), one Co(4), one Zn(3), and one Sb(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Co(2), one Co(5), one Zn(1), and one Sb(3) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Co(1), one Co(4), one Zn(3), and one Sb(2) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Co(4), one Zn(1), one Sb(1), and one Sb(2) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Co(1), one Co(5), one Zn(2), and one Sb(3) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Co(1), one Co(3), one Co(4), and one Zn(1) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Co(2), one Co(4), one Zn(2), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Co(1), one Co(2), one Co(5), and one Zn(3) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Co(1), one Co(3), one Zn(1), and one Sb(2) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Co(2), one Zn(2), one Sb(1), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Co(1), one Co(2), one Zn(3), and one Sb(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn3Co4(SbO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.148
_cell_length_b   8.518
_cell_length_c   10.284
_cell_angle_alpha   113.097
_cell_angle_beta   105.801
_cell_angle_gamma   92.701
_symmetry_Int_Tables_number   1
_cell_volume   469.393
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.885  0.798  0.821  1.0
  Zn  Zn1  1  0.557  0.456  0.165  1.0
  Zn  Zn2  1  0.226  0.140  0.495  1.0
  Zn  Zn3  1  0.443  0.544  0.835  1.0
  Zn  Zn4  1  0.115  0.202  0.179  1.0
  Zn  Zn5  1  0.774  0.860  0.505  1.0
  Co  Co6  1  0.666  0.168  0.331  1.0
  Co  Co7  1  0.334  0.832  0.669  1.0
  Co  Co8  1  0.831  0.326  0.653  1.0
  Co  Co9  1  0.500  0.000  0.000  1.0
  Co  Co10  1  0.169  0.674  0.347  1.0
  Co  Co11  1  0.656  0.152  0.824  1.0
  Co  Co12  1  0.344  0.848  0.176  1.0
  Co  Co13  1  0.000  0.500  0.500  1.0
  Sb  Sb14  1  0.000  0.500  0.000  1.0
  Sb  Sb15  1  0.166  0.159  0.827  1.0
  Sb  Sb16  1  0.834  0.841  0.173  1.0
  Sb  Sb17  1  0.500  0.500  0.500  1.0
  O  O18  1  0.472  0.241  0.981  1.0
  O  O19  1  0.145  0.904  0.319  1.0
  O  O20  1  0.810  0.569  0.653  1.0
  O  O21  1  0.323  0.092  0.676  1.0
  O  O22  1  0.995  0.741  0.010  1.0
  O  O23  1  0.663  0.426  0.347  1.0
  O  O24  1  0.636  0.926  0.834  1.0
  O  O25  1  0.296  0.591  0.160  1.0
  O  O26  1  0.971  0.266  0.491  1.0
  O  O27  1  0.168  0.935  0.838  1.0
  O  O28  1  0.843  0.590  0.159  1.0
  O  O29  1  0.505  0.264  0.496  1.0
  O  O30  1  0.855  0.096  0.681  1.0
  O  O31  1  0.528  0.759  0.019  1.0
  O  O32  1  0.190  0.431  0.347  1.0
  O  O33  1  0.005  0.259  0.990  1.0
  O  O34  1  0.677  0.908  0.324  1.0
  O  O35  1  0.337  0.574  0.653  1.0
  O  O36  1  0.704  0.409  0.840  1.0
  O  O37  1  0.364  0.074  0.166  1.0
  O  O38  1  0.029  0.734  0.509  1.0
  O  O39  1  0.157  0.410  0.841  1.0
  O  O40  1  0.832  0.065  0.162  1.0
  O  O41  1  0.495  0.736  0.504  1.0
[/CIF]
.
The crystal structure described by Co4Zn3(SbO6)2 is Spinel-derived structured and crystallizes in the triclinic P-1 space group. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(10), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Zn(2)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra, corners with three equivalent Zn(3)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. In the second Co site, Co(2) is bonded to one O(11), one O(12), one O(2), one O(3), one O(8), and one O(9) atom to form CoO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with three equivalent Zn(3)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Co(5)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. In the third Co site, Co(3) is bonded to two equivalent O(1), two equivalent O(10), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with two equivalent Zn(2)O4 tetrahedra, corners with four equivalent Zn(1)O4 tetrahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. In the fourth Co site, Co(4) is bonded to one O(1), one O(2), one O(4), one O(5), one O(7), and one O(8) atom to form CoO6 octahedra that share corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. In the fifth Co site, Co(5) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(10), one O(3), one O(5), and one O(7) atom to form ZnO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Sb(1)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, and corners with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-63°. In the second Zn site, Zn(2) is bonded to one O(1), one O(11), one O(6), and one O(8) atom to form ZnO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra,  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, and corners with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-62°. In the third Zn site, Zn(3) is bonded to one O(12), one O(2), one O(4), and one O(9) atom to form ZnO4 tetrahedra that share  a cornercorner with one Co(5)O6 octahedra,  a cornercorner with one Sb(3)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with three equivalent Co(1)O6 octahedra, and corners with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-63°. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(11), two equivalent O(5), and two equivalent O(8) atoms to form SbO6 octahedra that share corners with two equivalent Zn(1)O4 tetrahedra, corners with four equivalent Zn(2)O4 tetrahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. In the second Sb site, Sb(2) is bonded to one O(1), one O(10), one O(11), one O(2), one O(4), and one O(5) atom to form SbO6 octahedra that share corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. In the third Sb site, Sb(3) is bonded to two equivalent O(12), two equivalent O(3), and two equivalent O(6) atoms to form SbO6 octahedra that share corners with two equivalent Zn(1)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(3)O4 tetrahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Co(5)O6 octahedra. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Co(3), one Co(4), one Zn(2), and one Sb(2) atom. In the second O site, O(2) is bonded in a distorted tetrahedral geometry to one Co(2), one Co(4), one Zn(3), and one Sb(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Co(2), one Co(5), one Zn(1), and one Sb(3) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Co(1), one Co(4), one Zn(3), and one Sb(2) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Co(4), one Zn(1), one Sb(1), and one Sb(2) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Co(1), one Co(5), one Zn(2), and one Sb(3) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Co(1), one Co(3), one Co(4), and one Zn(1) atom. In the eighth O site, O(8) is bonded in a distorted rectangular see-saw-like geometry to one Co(2), one Co(4), one Zn(2), and one Sb(1) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Co(1), one Co(2), one Co(5), and one Zn(3) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Co(1), one Co(3), one Zn(1), and one Sb(2) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Co(2), one Zn(2), one Sb(1), and one Sb(2) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one Co(1), one Co(2), one Zn(3), and one Sb(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn3Co4(SbO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.148
_cell_length_b   8.518
_cell_length_c   10.284
_cell_angle_alpha   113.097
_cell_angle_beta   105.801
_cell_angle_gamma   92.701
_symmetry_Int_Tables_number   1
_cell_volume   469.393
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.885  0.798  0.821  1.0
  Zn  Zn1  1  0.557  0.456  0.165  1.0
  Zn  Zn2  1  0.226  0.140  0.495  1.0
  Zn  Zn3  1  0.443  0.544  0.835  1.0
  Zn  Zn4  1  0.115  0.202  0.179  1.0
  Zn  Zn5  1  0.774  0.860  0.505  1.0
  Co  Co6  1  0.666  0.168  0.331  1.0
  Co  Co7  1  0.334  0.832  0.669  1.0
  Co  Co8  1  0.831  0.326  0.653  1.0
  Co  Co9  1  0.500  0.000  0.000  1.0
  Co  Co10  1  0.169  0.674  0.347  1.0
  Co  Co11  1  0.656  0.152  0.824  1.0
  Co  Co12  1  0.344  0.848  0.176  1.0
  Co  Co13  1  0.000  0.500  0.500  1.0
  Sb  Sb14  1  0.000  0.500  0.000  1.0
  Sb  Sb15  1  0.166  0.159  0.827  1.0
  Sb  Sb16  1  0.834  0.841  0.173  1.0
  Sb  Sb17  1  0.500  0.500  0.500  1.0
  O  O18  1  0.472  0.241  0.981  1.0
  O  O19  1  0.145  0.904  0.319  1.0
  O  O20  1  0.810  0.569  0.653  1.0
  O  O21  1  0.323  0.092  0.676  1.0
  O  O22  1  0.995  0.741  0.010  1.0
  O  O23  1  0.663  0.426  0.347  1.0
  O  O24  1  0.636  0.926  0.834  1.0
  O  O25  1  0.296  0.591  0.160  1.0
  O  O26  1  0.971  0.266  0.491  1.0
  O  O27  1  0.168  0.935  0.838  1.0
  O  O28  1  0.843  0.590  0.159  1.0
  O  O29  1  0.505  0.264  0.496  1.0
  O  O30  1  0.855  0.096  0.681  1.0
  O  O31  1  0.528  0.759  0.019  1.0
  O  O32  1  0.190  0.431  0.347  1.0
  O  O33  1  0.005  0.259  0.990  1.0
  O  O34  1  0.677  0.908  0.324  1.0
  O  O35  1  0.337  0.574  0.653  1.0
  O  O36  1  0.704  0.409  0.840  1.0
  O  O37  1  0.364  0.074  0.166  1.0
  O  O38  1  0.029  0.734  0.509  1.0
  O  O39  1  0.157  0.410  0.841  1.0
  O  O40  1  0.832  0.065  0.162  1.0
  O  O41  1  0.495  0.736  0.504  1.0
[/CIF]
.