The crystal structure described by CH3CSb2H2SO5Cl6CF3 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two trifluoromethane molecules, and two CSb2H2SO5Cl6 clusters. In each CSb2H2SO5Cl6 cluster, C(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(1) and one O(1) atom. Sb(1) is bonded to one O(1), one O(2), one O(3), one Cl(1), one Cl(2), and one Cl(3) atom to form edge-sharing SbCl3O3 octahedra. H(1) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(4) and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one C(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a water-like geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_Sb2H5C3SCl6O5F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.481
_cell_length_b   7.069
_cell_length_c   10.041
_cell_angle_alpha   74.901
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   992.340
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.361  0.660  0.727  1.0
  Sb  Sb1  1  0.861  0.340  0.273  1.0
  Sb  Sb2  1  0.639  0.340  0.273  1.0
  Sb  Sb3  1  0.139  0.660  0.727  1.0
  H  H4  1  0.312  0.132  0.660  1.0
  H  H5  1  0.812  0.868  0.340  1.0
  H  H6  1  0.688  0.868  0.340  1.0
  H  H7  1  0.188  0.132  0.660  1.0
  H  H8  1  0.250  0.302  0.427  1.0
  H  H9  1  0.750  0.698  0.573  1.0
  H  H10  1  0.188  0.088  0.419  1.0
  H  H11  1  0.688  0.912  0.581  1.0
  H  H12  1  0.812  0.912  0.581  1.0
  H  H13  1  0.312  0.088  0.419  1.0
  C  C14  1  0.250  0.080  0.617  1.0
  C  C15  1  0.750  0.920  0.383  1.0
  C  C16  1  0.250  0.141  0.461  1.0
  C  C17  1  0.750  0.859  0.539  1.0
  C  C18  1  0.250  0.916  0.079  1.0
  C  C19  1  0.750  0.084  0.921  1.0
  S  S20  1  0.250  0.678  0.026  1.0
  S  S21  1  0.750  0.322  0.974  1.0
  Cl  Cl22  1  0.385  0.641  0.500  1.0
  Cl  Cl23  1  0.885  0.359  0.500  1.0
  Cl  Cl24  1  0.615  0.359  0.500  1.0
  Cl  Cl25  1  0.115  0.641  0.500  1.0
  Cl  Cl26  1  0.458  0.400  0.831  1.0
  Cl  Cl27  1  0.958  0.600  0.169  1.0
  Cl  Cl28  1  0.542  0.600  0.169  1.0
  Cl  Cl29  1  0.042  0.400  0.831  1.0
  Cl  Cl30  1  0.470  0.908  0.717  1.0
  Cl  Cl31  1  0.970  0.092  0.283  1.0
  Cl  Cl32  1  0.530  0.092  0.283  1.0
  Cl  Cl33  1  0.030  0.908  0.717  1.0
  O  O34  1  0.250  0.865  0.673  1.0
  O  O35  1  0.750  0.135  0.327  1.0
  O  O36  1  0.250  0.493  0.762  1.0
  O  O37  1  0.750  0.507  0.238  1.0
  O  O38  1  0.336  0.695  0.940  1.0
  O  O39  1  0.836  0.305  0.060  1.0
  O  O40  1  0.664  0.305  0.060  1.0
  O  O41  1  0.164  0.695  0.940  1.0
  O  O42  1  0.250  0.525  0.151  1.0
  O  O43  1  0.750  0.475  0.849  1.0
  F  F44  1  0.250  0.069  0.967  1.0
  F  F45  1  0.750  0.931  0.033  1.0
  F  F46  1  0.326  0.923  0.155  1.0
  F  F47  1  0.826  0.077  0.845  1.0
  F  F48  1  0.674  0.077  0.845  1.0
  F  F49  1  0.174  0.923  0.155  1.0
[/CIF]
.
The crystal structure described by CH3CSb2H2SO5Cl6CF3 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two 02329_fluka molecules, two trifluoromethane molecules, and two CSb2H2SO5Cl6 clusters. In each CSb2H2SO5Cl6 cluster, C(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(1) and one O(1) atom. Sb(1) is bonded to one O(1), one O(2), one O(3), one Cl(1), one Cl(2), and one Cl(3) atom to form edge-sharing SbCl3O3 octahedra. H(1) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one O(4) and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one C(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a water-like geometry to two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF file [CIF]
data_Sb2H5C3SCl6O5F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.481
_cell_length_b   7.069
_cell_length_c   10.041
_cell_angle_alpha   74.901
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   992.340
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.361  0.660  0.727  1.0
  Sb  Sb1  1  0.861  0.340  0.273  1.0
  Sb  Sb2  1  0.639  0.340  0.273  1.0
  Sb  Sb3  1  0.139  0.660  0.727  1.0
  H  H4  1  0.312  0.132  0.660  1.0
  H  H5  1  0.812  0.868  0.340  1.0
  H  H6  1  0.688  0.868  0.340  1.0
  H  H7  1  0.188  0.132  0.660  1.0
  H  H8  1  0.250  0.302  0.427  1.0
  H  H9  1  0.750  0.698  0.573  1.0
  H  H10  1  0.188  0.088  0.419  1.0
  H  H11  1  0.688  0.912  0.581  1.0
  H  H12  1  0.812  0.912  0.581  1.0
  H  H13  1  0.312  0.088  0.419  1.0
  C  C14  1  0.250  0.080  0.617  1.0
  C  C15  1  0.750  0.920  0.383  1.0
  C  C16  1  0.250  0.141  0.461  1.0
  C  C17  1  0.750  0.859  0.539  1.0
  C  C18  1  0.250  0.916  0.079  1.0
  C  C19  1  0.750  0.084  0.921  1.0
  S  S20  1  0.250  0.678  0.026  1.0
  S  S21  1  0.750  0.322  0.974  1.0
  Cl  Cl22  1  0.385  0.641  0.500  1.0
  Cl  Cl23  1  0.885  0.359  0.500  1.0
  Cl  Cl24  1  0.615  0.359  0.500  1.0
  Cl  Cl25  1  0.115  0.641  0.500  1.0
  Cl  Cl26  1  0.458  0.400  0.831  1.0
  Cl  Cl27  1  0.958  0.600  0.169  1.0
  Cl  Cl28  1  0.542  0.600  0.169  1.0
  Cl  Cl29  1  0.042  0.400  0.831  1.0
  Cl  Cl30  1  0.470  0.908  0.717  1.0
  Cl  Cl31  1  0.970  0.092  0.283  1.0
  Cl  Cl32  1  0.530  0.092  0.283  1.0
  Cl  Cl33  1  0.030  0.908  0.717  1.0
  O  O34  1  0.250  0.865  0.673  1.0
  O  O35  1  0.750  0.135  0.327  1.0
  O  O36  1  0.250  0.493  0.762  1.0
  O  O37  1  0.750  0.507  0.238  1.0
  O  O38  1  0.336  0.695  0.940  1.0
  O  O39  1  0.836  0.305  0.060  1.0
  O  O40  1  0.664  0.305  0.060  1.0
  O  O41  1  0.164  0.695  0.940  1.0
  O  O42  1  0.250  0.525  0.151  1.0
  O  O43  1  0.750  0.475  0.849  1.0
  F  F44  1  0.250  0.069  0.967  1.0
  F  F45  1  0.750  0.931  0.033  1.0
  F  F46  1  0.326  0.923  0.155  1.0
  F  F47  1  0.826  0.077  0.845  1.0
  F  F48  1  0.674  0.077  0.845  1.0
  F  F49  1  0.174  0.923  0.155  1.0
[/CIF]
.