The compound described by Pd25Ge9 crystallizes in the trigonal P-3 space group. There are seven inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 3-coordinate geometry to one Pd(4), one Ge(1), one Ge(3), and two equivalent Ge(2) atoms. In the second Pd site, Pd(2) is bonded in a 3-coordinate geometry to one Pd(4), one Ge(2), and two equivalent Ge(3) atoms. In the third Pd site, Pd(3) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Ge(3) atoms. In the fourth Pd site, Pd(4) is bonded in a 13-coordinate geometry to three equivalent Pd(1), three equivalent Pd(2), three equivalent Pd(7), one Ge(2), and three equivalent Ge(3) atoms. In the fifth Pd site, Pd(5) is bonded in a 4-coordinate geometry to one Pd(6), one Ge(1), and three equivalent Ge(3) atoms. In the sixth Pd site, Pd(6) is bonded in a distorted body-centered cubic geometry to two equivalent Pd(5), six equivalent Pd(7), and six equivalent Ge(3) atoms. In the seventh Pd site, Pd(7) is bonded in a 3-coordinate geometry to one Pd(4), one Pd(6), and three equivalent Ge(3) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a body-centered cubic geometry to two equivalent Pd(5) and six equivalent Pd(1) atoms. In the second Ge site, Ge(2) is bonded in a 10-coordinate geometry to one Pd(4), three equivalent Pd(2), and six equivalent Pd(1) atoms. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to one Pd(1), one Pd(3), one Pd(4), one Pd(5), one Pd(6), two equivalent Pd(2), and three equivalent Pd(7) atoms. is represented by the CIF card [CIF]
data_Ge9Pd25
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.409
_cell_length_b   7.409
_cell_length_c   10.662
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   506.863
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.000  0.000  0.000  1.0
  Ge  Ge1  1  0.667  0.333  0.020  1.0
  Ge  Ge2  1  0.333  0.667  0.980  1.0
  Ge  Ge3  1  0.343  0.336  0.321  1.0
  Ge  Ge4  1  0.993  0.657  0.321  1.0
  Ge  Ge5  1  0.664  0.007  0.321  1.0
  Ge  Ge6  1  0.657  0.664  0.679  1.0
  Ge  Ge7  1  0.007  0.343  0.679  1.0
  Ge  Ge8  1  0.336  0.993  0.679  1.0
  Pd  Pd9  1  0.656  0.929  0.080  1.0
  Pd  Pd10  1  0.071  0.727  0.080  1.0
  Pd  Pd11  1  0.273  0.344  0.080  1.0
  Pd  Pd12  1  0.419  0.093  0.186  1.0
  Pd  Pd13  1  0.907  0.326  0.186  1.0
  Pd  Pd14  1  0.674  0.581  0.186  1.0
  Pd  Pd15  1  0.581  0.907  0.814  1.0
  Pd  Pd16  1  0.093  0.674  0.814  1.0
  Pd  Pd17  1  0.326  0.419  0.814  1.0
  Pd  Pd18  1  0.333  0.667  0.607  1.0
  Pd  Pd19  1  0.667  0.333  0.393  1.0
  Pd  Pd20  1  0.333  0.667  0.242  1.0
  Pd  Pd21  1  0.667  0.333  0.758  1.0
  Pd  Pd22  1  0.000  0.000  0.250  1.0
  Pd  Pd23  1  0.000  0.000  0.750  1.0
  Pd  Pd24  1  0.000  0.000  0.500  1.0
  Pd  Pd25  1  0.727  0.656  0.920  1.0
  Pd  Pd26  1  0.929  0.273  0.920  1.0
  Pd  Pd27  1  0.344  0.071  0.920  1.0
  Pd  Pd28  1  0.380  0.307  0.569  1.0
  Pd  Pd29  1  0.927  0.620  0.569  1.0
  Pd  Pd30  1  0.693  0.073  0.569  1.0
  Pd  Pd31  1  0.620  0.693  0.431  1.0
  Pd  Pd32  1  0.073  0.380  0.431  1.0
  Pd  Pd33  1  0.307  0.927  0.431  1.0
[/CIF]
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The compound described by Pd25Ge9 crystallizes in the trigonal P-3 space group. There are seven inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 3-coordinate geometry to one Pd(4), one Ge(1), one Ge(3), and two equivalent Ge(2) atoms. In the second Pd site, Pd(2) is bonded in a 3-coordinate geometry to one Pd(4), one Ge(2), and two equivalent Ge(3) atoms. In the third Pd site, Pd(3) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Ge(3) atoms. In the fourth Pd site, Pd(4) is bonded in a 13-coordinate geometry to three equivalent Pd(1), three equivalent Pd(2), three equivalent Pd(7), one Ge(2), and three equivalent Ge(3) atoms. In the fifth Pd site, Pd(5) is bonded in a 4-coordinate geometry to one Pd(6), one Ge(1), and three equivalent Ge(3) atoms. In the sixth Pd site, Pd(6) is bonded in a distorted body-centered cubic geometry to two equivalent Pd(5), six equivalent Pd(7), and six equivalent Ge(3) atoms. In the seventh Pd site, Pd(7) is bonded in a 3-coordinate geometry to one Pd(4), one Pd(6), and three equivalent Ge(3) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a body-centered cubic geometry to two equivalent Pd(5) and six equivalent Pd(1) atoms. In the second Ge site, Ge(2) is bonded in a 10-coordinate geometry to one Pd(4), three equivalent Pd(2), and six equivalent Pd(1) atoms. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to one Pd(1), one Pd(3), one Pd(4), one Pd(5), one Pd(6), two equivalent Pd(2), and three equivalent Pd(7) atoms. is represented by the CIF card [CIF]
data_Ge9Pd25
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.409
_cell_length_b   7.409
_cell_length_c   10.662
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   506.863
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ge  Ge0  1  0.000  0.000  0.000  1.0
  Ge  Ge1  1  0.667  0.333  0.020  1.0
  Ge  Ge2  1  0.333  0.667  0.980  1.0
  Ge  Ge3  1  0.343  0.336  0.321  1.0
  Ge  Ge4  1  0.993  0.657  0.321  1.0
  Ge  Ge5  1  0.664  0.007  0.321  1.0
  Ge  Ge6  1  0.657  0.664  0.679  1.0
  Ge  Ge7  1  0.007  0.343  0.679  1.0
  Ge  Ge8  1  0.336  0.993  0.679  1.0
  Pd  Pd9  1  0.656  0.929  0.080  1.0
  Pd  Pd10  1  0.071  0.727  0.080  1.0
  Pd  Pd11  1  0.273  0.344  0.080  1.0
  Pd  Pd12  1  0.419  0.093  0.186  1.0
  Pd  Pd13  1  0.907  0.326  0.186  1.0
  Pd  Pd14  1  0.674  0.581  0.186  1.0
  Pd  Pd15  1  0.581  0.907  0.814  1.0
  Pd  Pd16  1  0.093  0.674  0.814  1.0
  Pd  Pd17  1  0.326  0.419  0.814  1.0
  Pd  Pd18  1  0.333  0.667  0.607  1.0
  Pd  Pd19  1  0.667  0.333  0.393  1.0
  Pd  Pd20  1  0.333  0.667  0.242  1.0
  Pd  Pd21  1  0.667  0.333  0.758  1.0
  Pd  Pd22  1  0.000  0.000  0.250  1.0
  Pd  Pd23  1  0.000  0.000  0.750  1.0
  Pd  Pd24  1  0.000  0.000  0.500  1.0
  Pd  Pd25  1  0.727  0.656  0.920  1.0
  Pd  Pd26  1  0.929  0.273  0.920  1.0
  Pd  Pd27  1  0.344  0.071  0.920  1.0
  Pd  Pd28  1  0.380  0.307  0.569  1.0
  Pd  Pd29  1  0.927  0.620  0.569  1.0
  Pd  Pd30  1  0.693  0.073  0.569  1.0
  Pd  Pd31  1  0.620  0.693  0.431  1.0
  Pd  Pd32  1  0.073  0.380  0.431  1.0
  Pd  Pd33  1  0.307  0.927  0.431  1.0
[/CIF]
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