The compound described by CsRbMo3O10 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 10-coordinate geometry to one O(4), one O(6), one O(8), one O(9), two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms. Rb(1) is bonded in a 8-coordinate geometry to one O(10), one O(2), one O(5), one O(7), two equivalent O(8), and two equivalent O(9) atoms. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(10), one O(4), one O(6), one O(7), and two equivalent O(3) atoms. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(1), one O(4), one O(6), one O(9), and two equivalent O(2) atoms. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to two equivalent Cs(1), one Mo(2), and one Mo(3) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Rb(1), one Mo(3), and two equivalent Mo(2) atoms. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Mo(3) and two equivalent Mo(1) atoms. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to one Cs(1), one Mo(1), one Mo(2), and one Mo(3) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Cs(1), one Rb(1), and one Mo(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Cs(1), one Mo(1), and one Mo(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to two equivalent Cs(1), one Rb(1), and one Mo(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Cs(1), two equivalent Rb(1), and one Mo(3) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Cs(1), two equivalent Rb(1), and one Mo(2) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Rb(1) and one Mo(1) atom. is represented by the CIF file [CIF]
data_CsRbMo3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.547
_cell_length_b   8.653
_cell_length_c   8.759
_cell_angle_alpha   63.237
_cell_angle_beta   85.649
_cell_angle_gamma   74.633
_symmetry_Int_Tables_number   1
_cell_volume   556.976
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.309  0.734  0.090  1.0
  Cs  Cs1  1  0.691  0.266  0.910  1.0
  Rb  Rb2  1  0.154  0.476  0.726  1.0
  Rb  Rb3  1  0.846  0.524  0.274  1.0
  Mo  Mo4  1  0.547  0.196  0.465  1.0
  Mo  Mo5  1  0.453  0.804  0.535  1.0
  Mo  Mo6  1  0.033  0.061  0.644  1.0
  Mo  Mo7  1  0.967  0.939  0.356  1.0
  Mo  Mo8  1  0.235  0.159  0.198  1.0
  Mo  Mo9  1  0.765  0.841  0.802  1.0
  O  O10  1  0.055  0.093  0.140  1.0
  O  O11  1  0.945  0.907  0.860  1.0
  O  O12  1  0.032  0.147  0.402  1.0
  O  O13  1  0.968  0.853  0.598  1.0
  O  O14  1  0.404  0.097  0.376  1.0
  O  O15  1  0.596  0.903  0.624  1.0
  O  O16  1  0.733  0.132  0.605  1.0
  O  O17  1  0.267  0.868  0.395  1.0
  O  O18  1  0.360  0.136  0.039  1.0
  O  O19  1  0.640  0.864  0.961  1.0
  O  O20  1  0.758  0.035  0.304  1.0
  O  O21  1  0.242  0.965  0.696  1.0
  O  O22  1  0.574  0.373  0.271  1.0
  O  O23  1  0.426  0.627  0.729  1.0
  O  O24  1  0.171  0.392  0.121  1.0
  O  O25  1  0.829  0.608  0.879  1.0
  O  O26  1  0.011  0.738  0.338  1.0
  O  O27  1  0.989  0.262  0.662  1.0
  O  O28  1  0.400  0.299  0.561  1.0
  O  O29  1  0.600  0.701  0.439  1.0
[/CIF]
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The compound described by CsRbMo3O10 crystallizes in the triclinic P-1 space group. Cs(1) is bonded in a 10-coordinate geometry to one O(4), one O(6), one O(8), one O(9), two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms. Rb(1) is bonded in a 8-coordinate geometry to one O(10), one O(2), one O(5), one O(7), two equivalent O(8), and two equivalent O(9) atoms. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(10), one O(4), one O(6), one O(7), and two equivalent O(3) atoms. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(1), one O(4), one O(6), one O(9), and two equivalent O(2) atoms. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to two equivalent Cs(1), one Mo(2), and one Mo(3) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Rb(1), one Mo(3), and two equivalent Mo(2) atoms. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Mo(3) and two equivalent Mo(1) atoms. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to one Cs(1), one Mo(1), one Mo(2), and one Mo(3) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Cs(1), one Rb(1), and one Mo(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Cs(1), one Mo(1), and one Mo(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to two equivalent Cs(1), one Rb(1), and one Mo(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Cs(1), two equivalent Rb(1), and one Mo(3) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Cs(1), two equivalent Rb(1), and one Mo(2) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Rb(1) and one Mo(1) atom. is represented by the CIF file [CIF]
data_CsRbMo3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.547
_cell_length_b   8.653
_cell_length_c   8.759
_cell_angle_alpha   63.237
_cell_angle_beta   85.649
_cell_angle_gamma   74.633
_symmetry_Int_Tables_number   1
_cell_volume   556.976
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.309  0.734  0.090  1.0
  Cs  Cs1  1  0.691  0.266  0.910  1.0
  Rb  Rb2  1  0.154  0.476  0.726  1.0
  Rb  Rb3  1  0.846  0.524  0.274  1.0
  Mo  Mo4  1  0.547  0.196  0.465  1.0
  Mo  Mo5  1  0.453  0.804  0.535  1.0
  Mo  Mo6  1  0.033  0.061  0.644  1.0
  Mo  Mo7  1  0.967  0.939  0.356  1.0
  Mo  Mo8  1  0.235  0.159  0.198  1.0
  Mo  Mo9  1  0.765  0.841  0.802  1.0
  O  O10  1  0.055  0.093  0.140  1.0
  O  O11  1  0.945  0.907  0.860  1.0
  O  O12  1  0.032  0.147  0.402  1.0
  O  O13  1  0.968  0.853  0.598  1.0
  O  O14  1  0.404  0.097  0.376  1.0
  O  O15  1  0.596  0.903  0.624  1.0
  O  O16  1  0.733  0.132  0.605  1.0
  O  O17  1  0.267  0.868  0.395  1.0
  O  O18  1  0.360  0.136  0.039  1.0
  O  O19  1  0.640  0.864  0.961  1.0
  O  O20  1  0.758  0.035  0.304  1.0
  O  O21  1  0.242  0.965  0.696  1.0
  O  O22  1  0.574  0.373  0.271  1.0
  O  O23  1  0.426  0.627  0.729  1.0
  O  O24  1  0.171  0.392  0.121  1.0
  O  O25  1  0.829  0.608  0.879  1.0
  O  O26  1  0.011  0.738  0.338  1.0
  O  O27  1  0.989  0.262  0.662  1.0
  O  O28  1  0.400  0.299  0.561  1.0
  O  O29  1  0.600  0.701  0.439  1.0
[/CIF]
.