The material described by ZnSbF5 crystallizes in the monoclinic P2_1/c space group. Zn(1) is bonded in a distorted tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. Sb(1) is bonded in a 6-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one Sb(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the fifth F site, F(5) is bonded in a distorted single-bond geometry to two equivalent Sb(1) atoms. is represented by the CIF file [CIF]
data_ZnSbF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.392
_cell_length_b   5.742
_cell_length_c   8.485
_cell_angle_alpha   61.203
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   443.702
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.991  0.473  0.788  1.0
  Zn  Zn1  1  0.491  0.527  0.712  1.0
  Zn  Zn2  1  0.009  0.527  0.212  1.0
  Zn  Zn3  1  0.509  0.473  0.288  1.0
  Sb  Sb4  1  0.761  0.064  0.657  1.0
  Sb  Sb5  1  0.261  0.936  0.843  1.0
  Sb  Sb6  1  0.239  0.936  0.343  1.0
  Sb  Sb7  1  0.739  0.064  0.157  1.0
  F  F8  1  0.890  0.376  0.626  1.0
  F  F9  1  0.390  0.624  0.874  1.0
  F  F10  1  0.110  0.624  0.374  1.0
  F  F11  1  0.610  0.376  0.126  1.0
  F  F12  1  0.611  0.352  0.522  1.0
  F  F13  1  0.111  0.648  0.978  1.0
  F  F14  1  0.389  0.648  0.478  1.0
  F  F15  1  0.889  0.352  0.022  1.0
  F  F16  1  0.434  0.164  0.810  1.0
  F  F17  1  0.934  0.836  0.690  1.0
  F  F18  1  0.566  0.836  0.190  1.0
  F  F19  1  0.066  0.164  0.310  1.0
  F  F20  1  0.130  0.220  0.878  1.0
  F  F21  1  0.630  0.780  0.622  1.0
  F  F22  1  0.870  0.780  0.122  1.0
  F  F23  1  0.370  0.220  0.378  1.0
  F  F24  1  0.691  0.201  0.898  1.0
  F  F25  1  0.191  0.799  0.602  1.0
  F  F26  1  0.309  0.799  0.102  1.0
  F  F27  1  0.809  0.201  0.398  1.0
[/CIF]
.
The material described by ZnSbF5 crystallizes in the monoclinic P2_1/c space group. Zn(1) is bonded in a distorted tetrahedral geometry to one F(1), one F(2), one F(3), and one F(4) atom. Sb(1) is bonded in a 6-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and two equivalent F(5) atoms. There are five inequivalent F sites. In the first F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the second F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one Sb(1) atom. In the third F site, F(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the fourth F site, F(4) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. In the fifth F site, F(5) is bonded in a distorted single-bond geometry to two equivalent Sb(1) atoms. is represented by the CIF file [CIF]
data_ZnSbF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.392
_cell_length_b   5.742
_cell_length_c   8.485
_cell_angle_alpha   61.203
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   443.702
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.991  0.473  0.788  1.0
  Zn  Zn1  1  0.491  0.527  0.712  1.0
  Zn  Zn2  1  0.009  0.527  0.212  1.0
  Zn  Zn3  1  0.509  0.473  0.288  1.0
  Sb  Sb4  1  0.761  0.064  0.657  1.0
  Sb  Sb5  1  0.261  0.936  0.843  1.0
  Sb  Sb6  1  0.239  0.936  0.343  1.0
  Sb  Sb7  1  0.739  0.064  0.157  1.0
  F  F8  1  0.890  0.376  0.626  1.0
  F  F9  1  0.390  0.624  0.874  1.0
  F  F10  1  0.110  0.624  0.374  1.0
  F  F11  1  0.610  0.376  0.126  1.0
  F  F12  1  0.611  0.352  0.522  1.0
  F  F13  1  0.111  0.648  0.978  1.0
  F  F14  1  0.389  0.648  0.478  1.0
  F  F15  1  0.889  0.352  0.022  1.0
  F  F16  1  0.434  0.164  0.810  1.0
  F  F17  1  0.934  0.836  0.690  1.0
  F  F18  1  0.566  0.836  0.190  1.0
  F  F19  1  0.066  0.164  0.310  1.0
  F  F20  1  0.130  0.220  0.878  1.0
  F  F21  1  0.630  0.780  0.622  1.0
  F  F22  1  0.870  0.780  0.122  1.0
  F  F23  1  0.370  0.220  0.378  1.0
  F  F24  1  0.691  0.201  0.898  1.0
  F  F25  1  0.191  0.799  0.602  1.0
  F  F26  1  0.309  0.799  0.102  1.0
  F  F27  1  0.809  0.201  0.398  1.0
[/CIF]
.