The material described by PtCl6((CH3)2NH2)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four dimethylazanium molecules and two PtCl6 clusters. In each PtCl6 cluster, Pt(1) is bonded in an octahedral geometry to two equivalent Cl(2) and four equivalent Cl(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the CIF file [CIF]
data_H16PtC4(NCl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.065
_cell_length_b   8.065
_cell_length_c   7.379
_cell_angle_alpha   64.115
_cell_angle_beta   64.115
_cell_angle_gamma   75.023
_symmetry_Int_Tables_number   1
_cell_volume   387.109
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.936  0.504  0.281  1.0
  H  H1  1  0.504  0.936  0.281  1.0
  H  H2  1  0.496  0.064  0.719  1.0
  H  H3  1  0.064  0.496  0.719  1.0
  H  H4  1  0.290  0.032  0.958  1.0
  H  H5  1  0.032  0.290  0.958  1.0
  H  H6  1  0.354  0.354  0.757  1.0
  H  H7  1  0.650  0.650  0.463  1.0
  H  H8  1  0.973  0.714  0.282  1.0
  H  H9  1  0.714  0.973  0.282  1.0
  H  H10  1  0.286  0.027  0.718  1.0
  H  H11  1  0.027  0.286  0.718  1.0
  H  H12  1  0.350  0.350  0.537  1.0
  H  H13  1  0.646  0.646  0.243  1.0
  H  H14  1  0.968  0.710  0.042  1.0
  H  H15  1  0.710  0.968  0.042  1.0
  Pt  Pt16  1  0.500  0.500  0.000  1.0
  C  C17  1  0.909  0.656  0.220  1.0
  C  C18  1  0.656  0.909  0.220  1.0
  C  C19  1  0.344  0.091  0.780  1.0
  C  C20  1  0.091  0.344  0.780  1.0
  N  N21  1  0.707  0.707  0.295  1.0
  N  N22  1  0.293  0.293  0.705  1.0
  Cl  Cl23  1  0.334  0.664  0.769  1.0
  Cl  Cl24  1  0.664  0.334  0.769  1.0
  Cl  Cl25  1  0.666  0.336  0.231  1.0
  Cl  Cl26  1  0.336  0.666  0.231  1.0
  Cl  Cl27  1  0.722  0.722  0.787  1.0
  Cl  Cl28  1  0.278  0.278  0.213  1.0
[/CIF]
.
The material described by PtCl6((CH3)2NH2)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four dimethylazanium molecules and two PtCl6 clusters. In each PtCl6 cluster, Pt(1) is bonded in an octahedral geometry to two equivalent Cl(2) and four equivalent Cl(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the CIF file [CIF]
data_H16PtC4(NCl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.065
_cell_length_b   8.065
_cell_length_c   7.379
_cell_angle_alpha   64.115
_cell_angle_beta   64.115
_cell_angle_gamma   75.023
_symmetry_Int_Tables_number   1
_cell_volume   387.109
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.936  0.504  0.281  1.0
  H  H1  1  0.504  0.936  0.281  1.0
  H  H2  1  0.496  0.064  0.719  1.0
  H  H3  1  0.064  0.496  0.719  1.0
  H  H4  1  0.290  0.032  0.958  1.0
  H  H5  1  0.032  0.290  0.958  1.0
  H  H6  1  0.354  0.354  0.757  1.0
  H  H7  1  0.650  0.650  0.463  1.0
  H  H8  1  0.973  0.714  0.282  1.0
  H  H9  1  0.714  0.973  0.282  1.0
  H  H10  1  0.286  0.027  0.718  1.0
  H  H11  1  0.027  0.286  0.718  1.0
  H  H12  1  0.350  0.350  0.537  1.0
  H  H13  1  0.646  0.646  0.243  1.0
  H  H14  1  0.968  0.710  0.042  1.0
  H  H15  1  0.710  0.968  0.042  1.0
  Pt  Pt16  1  0.500  0.500  0.000  1.0
  C  C17  1  0.909  0.656  0.220  1.0
  C  C18  1  0.656  0.909  0.220  1.0
  C  C19  1  0.344  0.091  0.780  1.0
  C  C20  1  0.091  0.344  0.780  1.0
  N  N21  1  0.707  0.707  0.295  1.0
  N  N22  1  0.293  0.293  0.705  1.0
  Cl  Cl23  1  0.334  0.664  0.769  1.0
  Cl  Cl24  1  0.664  0.334  0.769  1.0
  Cl  Cl25  1  0.666  0.336  0.231  1.0
  Cl  Cl26  1  0.336  0.666  0.231  1.0
  Cl  Cl27  1  0.722  0.722  0.787  1.0
  Cl  Cl28  1  0.278  0.278  0.213  1.0
[/CIF]
.