The material structure described by Ti2Mn3Fe3O16 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form distorted TiO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra, and  an edgeedge with one Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. In the second Ti site, Ti(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form distorted TiO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. In the second Fe site, Fe(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. In the third Fe site, Fe(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form FeO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ti(1), one Mn(2), and one Fe(3) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Ti(1), one Fe(1), and one Fe(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Mn(1), one Fe(1), and one Fe(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Fe(1), and one Fe(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one Mn(3), and one Fe(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Ti(1), one Mn(3), and one Fe(3) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Ti(1), one Mn(1), and one Fe(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Ti(1), one Mn(1), and one Fe(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Ti(2), one Fe(1), and one Fe(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Ti(1), one Mn(2), and one Mn(3) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one Ti(2), one Mn(2), and one Fe(3) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Ti(2), one Mn(3), and one Fe(3) atom. In the thirteenth O site, O(13) is bonded in a distorted T-shaped geometry to one Mn(2), one Mn(3), and one Fe(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Ti(2), one Mn(1), and one Fe(1) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal non-coplanar geometry to one Ti(2), one Mn(2), and one Mn(3) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Ti(2), one Mn(1), and one Fe(2) atom. is represented by the CIF card [CIF]
data_Ti2Mn3Fe3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.899
_cell_length_b   5.863
_cell_length_c   9.035
_cell_angle_alpha   90.065
_cell_angle_beta   88.481
_cell_angle_gamma   119.698
_symmetry_Int_Tables_number   1
_cell_volume   271.352
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.348  0.674  0.500  1.0
  Ti  Ti1  1  0.675  0.337  0.001  1.0
  Mn  Mn2  1  0.657  0.829  0.213  1.0
  Mn  Mn3  1  0.832  0.663  0.712  1.0
  Mn  Mn4  1  0.832  0.170  0.712  1.0
  Fe  Fe5  1  0.165  0.834  0.210  1.0
  Fe  Fe6  1  0.165  0.332  0.210  1.0
  Fe  Fe7  1  0.331  0.165  0.709  1.0
  O  O8  1  0.166  0.830  0.599  1.0
  O  O9  1  0.048  0.522  0.339  1.0
  O  O10  1  0.344  0.674  0.100  1.0
  O  O11  1  0.983  0.990  0.314  1.0
  O  O12  1  0.986  0.993  0.815  1.0
  O  O13  1  0.166  0.336  0.599  1.0
  O  O14  1  0.481  0.954  0.340  1.0
  O  O15  1  0.483  0.528  0.339  1.0
  O  O16  1  0.335  0.168  0.098  1.0
  O  O17  1  0.667  0.833  0.604  1.0
  O  O18  1  0.525  0.477  0.836  1.0
  O  O19  1  0.525  0.048  0.836  1.0
  O  O20  1  0.681  0.340  0.600  1.0
  O  O21  1  0.824  0.660  0.098  1.0
  O  O22  1  0.956  0.478  0.833  1.0
  O  O23  1  0.823  0.163  0.098  1.0
[/CIF]
.
The material structure described by Ti2Mn3Fe3O16 is Hydrophilite-derived structured and crystallizes in the triclinic P1 space group. There are two inequivalent Ti sites. In the first Ti site, Ti(1) is bonded to one O(1), one O(10), one O(2), one O(6), one O(7), and one O(8) atom to form distorted TiO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, corners with two equivalent Fe(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Fe(1)O6 octahedra, and  an edgeedge with one Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-54°. In the second Ti site, Ti(2) is bonded to one O(11), one O(12), one O(14), one O(15), one O(16), and one O(9) atom to form distorted TiO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Fe(1)O6 octahedra, corners with two equivalent Fe(2)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra, and  an edgeedge with one Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-53°. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(14), one O(16), one O(3), one O(4), one O(7), and one O(8) atom to form MnO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent Fe(1)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. In the second Mn site, Mn(2) is bonded to one O(1), one O(10), one O(11), one O(13), one O(15), and one O(5) atom to form MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, edges with two equivalent Mn(3)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. In the third Mn site, Mn(3) is bonded to one O(10), one O(12), one O(13), one O(15), one O(5), and one O(6) atom to form MnO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Fe(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-51°. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(14), one O(2), one O(3), one O(4), one O(7), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. In the second Fe site, Fe(2) is bonded to one O(16), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form FeO6 octahedra that share corners with two equivalent Ti(2)O6 octahedra,  an edgeedge with one Ti(1)O6 octahedra, edges with two equivalent Mn(1)O6 octahedra, and edges with two equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-53°. In the third Fe site, Fe(3) is bonded to one O(1), one O(11), one O(12), one O(13), one O(5), and one O(6) atom to form FeO6 octahedra that share corners with two equivalent Ti(1)O6 octahedra,  an edgeedge with one Ti(2)O6 octahedra, edges with two equivalent Mn(2)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Ti(1), one Mn(2), and one Fe(3) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Ti(1), one Fe(1), and one Fe(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Mn(1), one Fe(1), and one Fe(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Fe(1), and one Fe(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one Mn(3), and one Fe(3) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Ti(1), one Mn(3), and one Fe(3) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Ti(1), one Mn(1), and one Fe(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Ti(1), one Mn(1), and one Fe(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Ti(2), one Fe(1), and one Fe(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Ti(1), one Mn(2), and one Mn(3) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one Ti(2), one Mn(2), and one Fe(3) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Ti(2), one Mn(3), and one Fe(3) atom. In the thirteenth O site, O(13) is bonded in a distorted T-shaped geometry to one Mn(2), one Mn(3), and one Fe(3) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Ti(2), one Mn(1), and one Fe(1) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal non-coplanar geometry to one Ti(2), one Mn(2), and one Mn(3) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Ti(2), one Mn(1), and one Fe(2) atom. is represented by the CIF card [CIF]
data_Ti2Mn3Fe3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.899
_cell_length_b   5.863
_cell_length_c   9.035
_cell_angle_alpha   90.065
_cell_angle_beta   88.481
_cell_angle_gamma   119.698
_symmetry_Int_Tables_number   1
_cell_volume   271.352
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.348  0.674  0.500  1.0
  Ti  Ti1  1  0.675  0.337  0.001  1.0
  Mn  Mn2  1  0.657  0.829  0.213  1.0
  Mn  Mn3  1  0.832  0.663  0.712  1.0
  Mn  Mn4  1  0.832  0.170  0.712  1.0
  Fe  Fe5  1  0.165  0.834  0.210  1.0
  Fe  Fe6  1  0.165  0.332  0.210  1.0
  Fe  Fe7  1  0.331  0.165  0.709  1.0
  O  O8  1  0.166  0.830  0.599  1.0
  O  O9  1  0.048  0.522  0.339  1.0
  O  O10  1  0.344  0.674  0.100  1.0
  O  O11  1  0.983  0.990  0.314  1.0
  O  O12  1  0.986  0.993  0.815  1.0
  O  O13  1  0.166  0.336  0.599  1.0
  O  O14  1  0.481  0.954  0.340  1.0
  O  O15  1  0.483  0.528  0.339  1.0
  O  O16  1  0.335  0.168  0.098  1.0
  O  O17  1  0.667  0.833  0.604  1.0
  O  O18  1  0.525  0.477  0.836  1.0
  O  O19  1  0.525  0.048  0.836  1.0
  O  O20  1  0.681  0.340  0.600  1.0
  O  O21  1  0.824  0.660  0.098  1.0
  O  O22  1  0.956  0.478  0.833  1.0
  O  O23  1  0.823  0.163  0.098  1.0
[/CIF]
.