The structure described by MgMn2Te2(MoO6)2 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(10), one O(7), one O(8), and one O(9) atom to form MgO4 tetrahedra that share corners with two equivalent Mo(1)O4 tetrahedra and corners with two equivalent Mo(2)O4 tetrahedra. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(11), one O(5), one O(8), and one O(9) atom to form distorted MoO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with two equivalent Mg(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 63-64°. In the second Mo site, Mo(2) is bonded to one O(10), one O(12), one O(6), and one O(7) atom to form MoO4 tetrahedra that share corners with two equivalent Mg(1)O4 tetrahedra. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(11), one O(2), one O(3), one O(4), and one O(5) atom to form distorted MnO6 octahedra that share corners with two equivalent Mo(1)O4 tetrahedra. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(1), one O(12), one O(2), one O(3), one O(4), and one O(6) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted see-saw-like geometry to one O(11), one O(2), one O(3), and one O(5) atom. In the second Te site, Te(2) is bonded in a distorted see-saw-like geometry to one O(1), one O(12), one O(4), and one O(6) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Te(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Te(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Te(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Mo(1), one Mn(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mo(2), one Mn(2), and one Te(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Mg(1) and one Mo(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(1) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(1) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Mg(1) and one Mo(2) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Mo(1), one Mn(1), and one Te(1) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Mo(2), one Mn(2), and one Te(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgMn2Te2(MoO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.176
_cell_length_b   5.390
_cell_length_c   10.284
_cell_angle_alpha   90.026
_cell_angle_beta   89.820
_cell_angle_gamma   90.355
_symmetry_Int_Tables_number   1
_cell_volume   286.924
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.999  1.000  0.003  1.0
  Mn  Mn1  1  0.001  1.000  0.481  1.0
  Mn  Mn2  1  0.500  0.499  0.525  1.0
  Te  Te3  1  0.001  0.500  0.283  1.0
  Te  Te4  1  0.499  1.000  0.725  1.0
  Mo  Mo5  1  0.498  0.004  0.227  1.0
  Mo  Mo6  1  1.000  0.500  0.777  1.0
  O  O7  1  0.719  0.175  0.604  1.0
  O  O8  1  0.216  0.316  0.400  1.0
  O  O9  1  0.789  0.680  0.403  1.0
  O  O10  1  0.281  0.824  0.605  1.0
  O  O11  1  0.744  0.203  0.320  1.0
  O  O12  1  0.265  0.315  0.691  1.0
  O  O13  1  0.132  0.744  0.884  1.0
  O  O14  1  0.729  0.852  0.116  1.0
  O  O15  1  0.268  0.150  0.115  1.0
  O  O16  1  0.867  0.256  0.884  1.0
  O  O17  1  0.259  0.798  0.321  1.0
  O  O18  1  0.733  0.684  0.692  1.0
[/CIF]
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The structure described by MgMn2Te2(MoO6)2 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(10), one O(7), one O(8), and one O(9) atom to form MgO4 tetrahedra that share corners with two equivalent Mo(1)O4 tetrahedra and corners with two equivalent Mo(2)O4 tetrahedra. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(11), one O(5), one O(8), and one O(9) atom to form distorted MoO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with two equivalent Mg(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 63-64°. In the second Mo site, Mo(2) is bonded to one O(10), one O(12), one O(6), and one O(7) atom to form MoO4 tetrahedra that share corners with two equivalent Mg(1)O4 tetrahedra. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(11), one O(2), one O(3), one O(4), and one O(5) atom to form distorted MnO6 octahedra that share corners with two equivalent Mo(1)O4 tetrahedra. In the second Mn site, Mn(2) is bonded in a 6-coordinate geometry to one O(1), one O(12), one O(2), one O(3), one O(4), and one O(6) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted see-saw-like geometry to one O(11), one O(2), one O(3), and one O(5) atom. In the second Te site, Te(2) is bonded in a distorted see-saw-like geometry to one O(1), one O(12), one O(4), and one O(6) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Te(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Te(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Mn(2), and one Te(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(2), and one Te(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Mo(1), one Mn(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mo(2), one Mn(2), and one Te(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Mg(1) and one Mo(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(1) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(1) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Mg(1) and one Mo(2) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Mo(1), one Mn(1), and one Te(1) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Mo(2), one Mn(2), and one Te(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgMn2Te2(MoO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.176
_cell_length_b   5.390
_cell_length_c   10.284
_cell_angle_alpha   90.026
_cell_angle_beta   89.820
_cell_angle_gamma   90.355
_symmetry_Int_Tables_number   1
_cell_volume   286.924
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.999  1.000  0.003  1.0
  Mn  Mn1  1  0.001  1.000  0.481  1.0
  Mn  Mn2  1  0.500  0.499  0.525  1.0
  Te  Te3  1  0.001  0.500  0.283  1.0
  Te  Te4  1  0.499  1.000  0.725  1.0
  Mo  Mo5  1  0.498  0.004  0.227  1.0
  Mo  Mo6  1  1.000  0.500  0.777  1.0
  O  O7  1  0.719  0.175  0.604  1.0
  O  O8  1  0.216  0.316  0.400  1.0
  O  O9  1  0.789  0.680  0.403  1.0
  O  O10  1  0.281  0.824  0.605  1.0
  O  O11  1  0.744  0.203  0.320  1.0
  O  O12  1  0.265  0.315  0.691  1.0
  O  O13  1  0.132  0.744  0.884  1.0
  O  O14  1  0.729  0.852  0.116  1.0
  O  O15  1  0.268  0.150  0.115  1.0
  O  O16  1  0.867  0.256  0.884  1.0
  O  O17  1  0.259  0.798  0.321  1.0
  O  O18  1  0.733  0.684  0.692  1.0
[/CIF]
.