The material described by ZnSbF6 crystallizes in the trigonal R-3 space group. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Sb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 29°. Sb(1) is bonded to six equivalent F(1) atoms to form SbF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 29°. F(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. is represented by the CIF file [CIF]
data_ZnSbF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.716
_cell_length_b   5.716
_cell_length_c   5.716
_cell_angle_alpha   58.073
_cell_angle_beta   58.073
_cell_angle_gamma   58.073
_symmetry_Int_Tables_number   1
_cell_volume   126.225
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.500  0.500  1.0
  Sb  Sb1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.658  0.842  0.248  1.0
  F  F3  1  0.842  0.248  0.658  1.0
  F  F4  1  0.752  0.342  0.158  1.0
  F  F5  1  0.158  0.752  0.342  1.0
  F  F6  1  0.342  0.158  0.752  1.0
  F  F7  1  0.248  0.658  0.842  1.0
[/CIF]
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The material described by ZnSbF6 crystallizes in the trigonal R-3 space group. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Sb(1)F6 octahedra. The corner-sharing octahedral tilt angles are 29°. Sb(1) is bonded to six equivalent F(1) atoms to form SbF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 29°. F(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. is represented by the CIF file [CIF]
data_ZnSbF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.716
_cell_length_b   5.716
_cell_length_c   5.716
_cell_angle_alpha   58.073
_cell_angle_beta   58.073
_cell_angle_gamma   58.073
_symmetry_Int_Tables_number   1
_cell_volume   126.225
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.500  0.500  1.0
  Sb  Sb1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.658  0.842  0.248  1.0
  F  F3  1  0.842  0.248  0.658  1.0
  F  F4  1  0.752  0.342  0.158  1.0
  F  F5  1  0.158  0.752  0.342  1.0
  F  F6  1  0.342  0.158  0.752  1.0
  F  F7  1  0.248  0.658  0.842  1.0
[/CIF]
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