The crystal structure described by AgTeO3 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and two equivalent O(5) atoms. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one O(4), one O(5), one O(6), and two equivalent O(1) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(2), one O(4), one O(5), one O(6), and two equivalent O(3) atoms to form edge-sharing TeO6 octahedra. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to one O(2), one O(4), one O(6), and two equivalent O(1) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Ag(1), two equivalent Ag(2), and two equivalent Te(2) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ag(1), one Te(1), and one Te(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Ag(1) and two equivalent Te(1) atoms. In the fourth O site, O(4) is bonded in a distorted tetrahedral geometry to one Ag(1), one Ag(2), one Te(1), and one Te(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Ag(2), two equivalent Ag(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), one Te(1), and one Te(2) atom. is represented by the CIF file [CIF]
data_AgTeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.827
_cell_length_b   6.025
_cell_length_c   9.221
_cell_angle_alpha   61.033
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   574.826
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.673  0.428  0.723  1.0
  Ag  Ag1  1  0.645  0.608  0.970  1.0
  Ag  Ag2  1  0.827  0.428  0.223  1.0
  Ag  Ag3  1  0.145  0.392  0.530  1.0
  Ag  Ag4  1  0.173  0.572  0.777  1.0
  Ag  Ag5  1  0.355  0.392  0.030  1.0
  Ag  Ag6  1  0.855  0.608  0.470  1.0
  Ag  Ag7  1  0.327  0.572  0.277  1.0
  Te  Te8  1  0.623  0.091  0.508  1.0
  Te  Te9  1  0.076  0.066  0.314  1.0
  Te  Te10  1  0.576  0.934  0.186  1.0
  Te  Te11  1  0.123  0.909  0.992  1.0
  Te  Te12  1  0.924  0.934  0.686  1.0
  Te  Te13  1  0.424  0.066  0.814  1.0
  Te  Te14  1  0.877  0.091  0.008  1.0
  Te  Te15  1  0.377  0.909  0.492  1.0
  O  O16  1  0.958  0.232  0.484  1.0
  O  O17  1  0.147  0.858  0.224  1.0
  O  O18  1  0.463  0.227  0.445  1.0
  O  O19  1  0.037  0.227  0.945  1.0
  O  O20  1  0.088  0.977  0.763  1.0
  O  O21  1  0.853  0.142  0.776  1.0
  O  O22  1  0.315  0.585  0.561  1.0
  O  O23  1  0.412  0.977  0.263  1.0
  O  O24  1  0.741  0.887  0.088  1.0
  O  O25  1  0.588  0.023  0.737  1.0
  O  O26  1  0.759  0.887  0.588  1.0
  O  O27  1  0.458  0.768  0.016  1.0
  O  O28  1  0.042  0.768  0.516  1.0
  O  O29  1  0.259  0.113  0.912  1.0
  O  O30  1  0.185  0.585  0.061  1.0
  O  O31  1  0.963  0.773  0.055  1.0
  O  O32  1  0.542  0.232  0.984  1.0
  O  O33  1  0.685  0.415  0.439  1.0
  O  O34  1  0.647  0.142  0.276  1.0
  O  O35  1  0.912  0.023  0.237  1.0
  O  O36  1  0.353  0.858  0.724  1.0
  O  O37  1  0.815  0.415  0.939  1.0
  O  O38  1  0.537  0.773  0.555  1.0
  O  O39  1  0.241  0.113  0.412  1.0
[/CIF]
.
The crystal structure described by AgTeO3 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(6), and two equivalent O(5) atoms. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one O(4), one O(5), one O(6), and two equivalent O(1) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(2), one O(4), one O(5), one O(6), and two equivalent O(3) atoms to form edge-sharing TeO6 octahedra. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to one O(2), one O(4), one O(6), and two equivalent O(1) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 5-coordinate geometry to one Ag(1), two equivalent Ag(2), and two equivalent Te(2) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Ag(1), one Te(1), and one Te(2) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Ag(1) and two equivalent Te(1) atoms. In the fourth O site, O(4) is bonded in a distorted tetrahedral geometry to one Ag(1), one Ag(2), one Te(1), and one Te(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Ag(2), two equivalent Ag(1), and one Te(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), one Te(1), and one Te(2) atom. is represented by the CIF file [CIF]
data_AgTeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.827
_cell_length_b   6.025
_cell_length_c   9.221
_cell_angle_alpha   61.033
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   574.826
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.673  0.428  0.723  1.0
  Ag  Ag1  1  0.645  0.608  0.970  1.0
  Ag  Ag2  1  0.827  0.428  0.223  1.0
  Ag  Ag3  1  0.145  0.392  0.530  1.0
  Ag  Ag4  1  0.173  0.572  0.777  1.0
  Ag  Ag5  1  0.355  0.392  0.030  1.0
  Ag  Ag6  1  0.855  0.608  0.470  1.0
  Ag  Ag7  1  0.327  0.572  0.277  1.0
  Te  Te8  1  0.623  0.091  0.508  1.0
  Te  Te9  1  0.076  0.066  0.314  1.0
  Te  Te10  1  0.576  0.934  0.186  1.0
  Te  Te11  1  0.123  0.909  0.992  1.0
  Te  Te12  1  0.924  0.934  0.686  1.0
  Te  Te13  1  0.424  0.066  0.814  1.0
  Te  Te14  1  0.877  0.091  0.008  1.0
  Te  Te15  1  0.377  0.909  0.492  1.0
  O  O16  1  0.958  0.232  0.484  1.0
  O  O17  1  0.147  0.858  0.224  1.0
  O  O18  1  0.463  0.227  0.445  1.0
  O  O19  1  0.037  0.227  0.945  1.0
  O  O20  1  0.088  0.977  0.763  1.0
  O  O21  1  0.853  0.142  0.776  1.0
  O  O22  1  0.315  0.585  0.561  1.0
  O  O23  1  0.412  0.977  0.263  1.0
  O  O24  1  0.741  0.887  0.088  1.0
  O  O25  1  0.588  0.023  0.737  1.0
  O  O26  1  0.759  0.887  0.588  1.0
  O  O27  1  0.458  0.768  0.016  1.0
  O  O28  1  0.042  0.768  0.516  1.0
  O  O29  1  0.259  0.113  0.912  1.0
  O  O30  1  0.185  0.585  0.061  1.0
  O  O31  1  0.963  0.773  0.055  1.0
  O  O32  1  0.542  0.232  0.984  1.0
  O  O33  1  0.685  0.415  0.439  1.0
  O  O34  1  0.647  0.142  0.276  1.0
  O  O35  1  0.912  0.023  0.237  1.0
  O  O36  1  0.353  0.858  0.724  1.0
  O  O37  1  0.815  0.415  0.939  1.0
  O  O38  1  0.537  0.773  0.555  1.0
  O  O39  1  0.241  0.113  0.412  1.0
[/CIF]
.