The structure described by TaTeBr9 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two TaTeBr9 clusters. Ta(1) is bonded to one Br(2), one Br(4), two equivalent Br(1), and two equivalent Br(5) atoms to form TaBr6 octahedra that share  a faceface with one Te(1)Br6 octahedra. Te(1) is bonded to one Br(3), one Br(4), two equivalent Br(1), and two equivalent Br(6) atoms to form distorted TeBr6 octahedra that share  a faceface with one Ta(1)Br6 octahedra. There are six inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to one Ta(1) and one Te(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Ta(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Br site, Br(4) is bonded in an L-shaped geometry to one Ta(1) and one Te(1) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one Ta(1) atom. In the sixth Br site, Br(6) is bonded in a single-bond geometry to one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TaTeBr9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.671
_cell_length_b   6.787
_cell_length_c   10.176
_cell_angle_alpha   76.201
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   782.800
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta0  1  0.250  0.645  0.857  1.0
  Ta  Ta1  1  0.750  0.355  0.143  1.0
  Te  Te2  1  0.250  0.761  0.462  1.0
  Te  Te3  1  0.750  0.239  0.538  1.0
  Br  Br4  1  0.599  0.457  0.306  1.0
  Br  Br5  1  0.099  0.543  0.694  1.0
  Br  Br6  1  0.401  0.543  0.694  1.0
  Br  Br7  1  0.901  0.457  0.306  1.0
  Br  Br8  1  0.750  0.703  0.006  1.0
  Br  Br9  1  0.250  0.297  0.994  1.0
  Br  Br10  1  0.750  0.526  0.657  1.0
  Br  Br11  1  0.250  0.474  0.343  1.0
  Br  Br12  1  0.750  0.002  0.319  1.0
  Br  Br13  1  0.250  0.998  0.681  1.0
  Br  Br14  1  0.905  0.237  0.020  1.0
  Br  Br15  1  0.405  0.763  0.980  1.0
  Br  Br16  1  0.095  0.763  0.980  1.0
  Br  Br17  1  0.595  0.237  0.020  1.0
  Br  Br18  1  0.912  0.039  0.672  1.0
  Br  Br19  1  0.412  0.961  0.328  1.0
  Br  Br20  1  0.088  0.961  0.328  1.0
  Br  Br21  1  0.588  0.039  0.672  1.0
[/CIF]
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The structure described by TaTeBr9 is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two TaTeBr9 clusters. Ta(1) is bonded to one Br(2), one Br(4), two equivalent Br(1), and two equivalent Br(5) atoms to form TaBr6 octahedra that share  a faceface with one Te(1)Br6 octahedra. Te(1) is bonded to one Br(3), one Br(4), two equivalent Br(1), and two equivalent Br(6) atoms to form distorted TeBr6 octahedra that share  a faceface with one Ta(1)Br6 octahedra. There are six inequivalent Br sites. In the first Br site, Br(1) is bonded in an L-shaped geometry to one Ta(1) and one Te(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Ta(1) atom. In the third Br site, Br(3) is bonded in a single-bond geometry to one Te(1) atom. In the fourth Br site, Br(4) is bonded in an L-shaped geometry to one Ta(1) and one Te(1) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one Ta(1) atom. In the sixth Br site, Br(6) is bonded in a single-bond geometry to one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TaTeBr9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.671
_cell_length_b   6.787
_cell_length_c   10.176
_cell_angle_alpha   76.201
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   782.800
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta0  1  0.250  0.645  0.857  1.0
  Ta  Ta1  1  0.750  0.355  0.143  1.0
  Te  Te2  1  0.250  0.761  0.462  1.0
  Te  Te3  1  0.750  0.239  0.538  1.0
  Br  Br4  1  0.599  0.457  0.306  1.0
  Br  Br5  1  0.099  0.543  0.694  1.0
  Br  Br6  1  0.401  0.543  0.694  1.0
  Br  Br7  1  0.901  0.457  0.306  1.0
  Br  Br8  1  0.750  0.703  0.006  1.0
  Br  Br9  1  0.250  0.297  0.994  1.0
  Br  Br10  1  0.750  0.526  0.657  1.0
  Br  Br11  1  0.250  0.474  0.343  1.0
  Br  Br12  1  0.750  0.002  0.319  1.0
  Br  Br13  1  0.250  0.998  0.681  1.0
  Br  Br14  1  0.905  0.237  0.020  1.0
  Br  Br15  1  0.405  0.763  0.980  1.0
  Br  Br16  1  0.095  0.763  0.980  1.0
  Br  Br17  1  0.595  0.237  0.020  1.0
  Br  Br18  1  0.912  0.039  0.672  1.0
  Br  Br19  1  0.412  0.961  0.328  1.0
  Br  Br20  1  0.088  0.961  0.328  1.0
  Br  Br21  1  0.588  0.039  0.672  1.0
[/CIF]
.