The structure described by CNH6F is gamma nitrogen structured and crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four methylazanium;hydrofluoride molecules. C(1) is bonded in a tetrahedral geometry to one N(1), one H(3), and two equivalent H(4) atoms. N(1) is bonded in a tetrahedral geometry to one C(1), one H(1), and two equivalent H(2) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one N(1) and one F(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. F(1) is bonded in a single-bond geometry to one H(1) atom. is represented by the CIF card [CIF]
data_H6CNF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.384
_cell_length_b   5.908
_cell_length_c   9.159
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   291.328
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.250  0.243  0.834  1.0
  H  H1  1  0.750  0.757  0.166  1.0
  H  H2  1  0.250  0.743  0.166  1.0
  H  H3  1  0.750  0.257  0.834  1.0
  H  H4  1  0.412  0.999  0.865  1.0
  H  H5  1  0.588  0.001  0.135  1.0
  H  H6  1  0.912  0.001  0.135  1.0
  H  H7  1  0.088  0.999  0.865  1.0
  H  H8  1  0.088  0.499  0.135  1.0
  H  H9  1  0.912  0.501  0.865  1.0
  H  H10  1  0.588  0.501  0.865  1.0
  H  H11  1  0.412  0.499  0.135  1.0
  H  H12  1  0.250  0.817  0.650  1.0
  H  H13  1  0.750  0.183  0.350  1.0
  H  H14  1  0.250  0.317  0.350  1.0
  H  H15  1  0.750  0.683  0.650  1.0
  H  H16  1  0.084  0.071  0.609  1.0
  H  H17  1  0.916  0.929  0.391  1.0
  H  H18  1  0.584  0.929  0.391  1.0
  H  H19  1  0.416  0.071  0.609  1.0
  H  H20  1  0.416  0.571  0.391  1.0
  H  H21  1  0.584  0.429  0.609  1.0
  H  H22  1  0.916  0.429  0.609  1.0
  H  H23  1  0.084  0.571  0.391  1.0
  C  C24  1  0.250  0.002  0.661  1.0
  C  C25  1  0.750  0.998  0.339  1.0
  C  C26  1  0.250  0.502  0.339  1.0
  C  C27  1  0.750  0.498  0.661  1.0
  N  N28  1  0.250  0.061  0.818  1.0
  N  N29  1  0.750  0.939  0.182  1.0
  N  N30  1  0.250  0.561  0.182  1.0
  N  N31  1  0.750  0.439  0.818  1.0
  F  F32  1  0.250  0.001  0.146  1.0
  F  F33  1  0.750  0.999  0.854  1.0
  F  F34  1  0.250  0.501  0.854  1.0
  F  F35  1  0.750  0.499  0.146  1.0
[/CIF]
.
The structure described by CNH6F is gamma nitrogen structured and crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four methylazanium;hydrofluoride molecules. C(1) is bonded in a tetrahedral geometry to one N(1), one H(3), and two equivalent H(4) atoms. N(1) is bonded in a tetrahedral geometry to one C(1), one H(1), and two equivalent H(2) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one N(1) and one F(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. F(1) is bonded in a single-bond geometry to one H(1) atom. is represented by the CIF card [CIF]
data_H6CNF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.384
_cell_length_b   5.908
_cell_length_c   9.159
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   291.328
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.250  0.243  0.834  1.0
  H  H1  1  0.750  0.757  0.166  1.0
  H  H2  1  0.250  0.743  0.166  1.0
  H  H3  1  0.750  0.257  0.834  1.0
  H  H4  1  0.412  0.999  0.865  1.0
  H  H5  1  0.588  0.001  0.135  1.0
  H  H6  1  0.912  0.001  0.135  1.0
  H  H7  1  0.088  0.999  0.865  1.0
  H  H8  1  0.088  0.499  0.135  1.0
  H  H9  1  0.912  0.501  0.865  1.0
  H  H10  1  0.588  0.501  0.865  1.0
  H  H11  1  0.412  0.499  0.135  1.0
  H  H12  1  0.250  0.817  0.650  1.0
  H  H13  1  0.750  0.183  0.350  1.0
  H  H14  1  0.250  0.317  0.350  1.0
  H  H15  1  0.750  0.683  0.650  1.0
  H  H16  1  0.084  0.071  0.609  1.0
  H  H17  1  0.916  0.929  0.391  1.0
  H  H18  1  0.584  0.929  0.391  1.0
  H  H19  1  0.416  0.071  0.609  1.0
  H  H20  1  0.416  0.571  0.391  1.0
  H  H21  1  0.584  0.429  0.609  1.0
  H  H22  1  0.916  0.429  0.609  1.0
  H  H23  1  0.084  0.571  0.391  1.0
  C  C24  1  0.250  0.002  0.661  1.0
  C  C25  1  0.750  0.998  0.339  1.0
  C  C26  1  0.250  0.502  0.339  1.0
  C  C27  1  0.750  0.498  0.661  1.0
  N  N28  1  0.250  0.061  0.818  1.0
  N  N29  1  0.750  0.939  0.182  1.0
  N  N30  1  0.250  0.561  0.182  1.0
  N  N31  1  0.750  0.439  0.818  1.0
  F  F32  1  0.250  0.001  0.146  1.0
  F  F33  1  0.750  0.999  0.854  1.0
  F  F34  1  0.250  0.501  0.854  1.0
  F  F35  1  0.750  0.499  0.146  1.0
[/CIF]
.