The compound described by CsAu(SO4)2 crystallizes in the triclinic P1 space group. There are four inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 11-coordinate geometry to one O(15), one O(18), one O(22), one O(28), one O(29), one O(3), one O(30), one O(32), one O(5), one O(6), and one O(9) atom. In the second Cs site, Cs(2) is bonded in a 11-coordinate geometry to one O(10), one O(11), one O(12), one O(13), one O(16), one O(2), one O(21), one O(24), one O(25), one O(26), and one O(8) atom. In the third Cs site, Cs(3) is bonded in a 11-coordinate geometry to one O(13), one O(14), one O(16), one O(17), one O(20), one O(21), one O(26), one O(29), one O(31), one O(7), and one O(9) atom. In the fourth Cs site, Cs(4) is bonded in a 11-coordinate geometry to one O(1), one O(12), one O(19), one O(22), one O(23), one O(25), one O(27), one O(28), one O(32), one O(4), and one O(6) atom. There are four inequivalent Au sites. In the first Au site, Au(1) is bonded in a rectangular see-saw-like geometry to one O(19), one O(2), one O(3), and one O(7) atom. In the second Au site, Au(2) is bonded in a rectangular see-saw-like geometry to one O(11), one O(20), one O(23), and one O(30) atom. In the third Au site, Au(3) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(31), and one O(5) atom. In the fourth Au site, Au(4) is bonded in a square co-planar geometry to one O(14), one O(18), one O(24), and one O(4) atom. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(18), one O(26), one O(27), and one O(31) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(12), one O(21), one O(3), and one O(4) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one O(1), one O(13), one O(15), and one O(24) atom. In the fourth S site, S(4) is bonded in a tetrahedral geometry to one O(30), one O(6), one O(7), and one O(8) atom. In the fifth S site, S(5) is bonded in a tetrahedral geometry to one O(10), one O(20), one O(32), and one O(9) atom. In the sixth S site, S(6) is bonded in a tetrahedral geometry to one O(16), one O(23), one O(29), and one O(5) atom. In the seventh S site, S(7) is bonded in a tetrahedral geometry to one O(11), one O(17), one O(19), and one O(28) atom. In the eighth S site, S(8) is bonded in a tetrahedral geometry to one O(14), one O(2), one O(22), and one O(25) atom. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cs(4), one Au(3), and one S(3) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cs(2), one Au(1), and one S(8) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cs(1), one Au(1), and one S(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cs(4), one Au(4), and one S(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Au(3), and one S(6) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(4), and one S(4) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Cs(3), one Au(1), and one S(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Cs(2) and one S(4) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Cs(1), one Cs(3), and one S(5) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Cs(2), one Au(3), and one S(5) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Cs(2), one Au(2), and one S(7) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Cs(2), one Cs(4), and one S(2) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), and one S(3) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Cs(3), one Au(4), and one S(8) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one Cs(1) and one S(3) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one Cs(2), one Cs(3), and one S(6) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one Cs(3) and one S(7) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Au(4), and one S(1) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Cs(4), one Au(1), and one S(7) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Cs(3), one Au(2), and one S(5) atom. In the twenty-first O site, O(21) is bonded in a single-bond geometry to one Cs(2), one Cs(3), and one S(2) atom. In the twenty-second O site, O(22) is bonded in a single-bond geometry to one Cs(1), one Cs(4), and one S(8) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 120 degrees geometry to one Cs(4), one Au(2), and one S(6) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Cs(2), one Au(4), and one S(3) atom. In the twenty-fifth O site, O(25) is bonded in a single-bond geometry to one Cs(2), one Cs(4), and one S(8) atom. In the twenty-sixth O site, O(26) is bonded in a single-bond geometry to one Cs(2), one Cs(3), and one S(1) atom. In the twenty-seventh O site, O(27) is bonded in a single-bond geometry to one Cs(4) and one S(1) atom. In the twenty-eighth O site, O(28) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(4), and one S(7) atom. In the twenty-ninth O site, O(29) is bonded in a single-bond geometry to one Cs(1), one Cs(3), and one S(6) atom. In the thirtieth O site, O(30) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Au(2), and one S(4) atom. In the thirty-first O site, O(31) is bonded in a distorted bent 120 degrees geometry to one Cs(3), one Au(3), and one S(1) atom. In the thirty-second O site, O(32) is bonded in a single-bond geometry to one Cs(1), one Cs(4), and one S(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsAu(SO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.307
_cell_length_b   9.247
_cell_length_c   10.551
_cell_angle_alpha   68.589
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   845.334
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.862  0.382  0.758  1.0
  Cs  Cs1  1  0.364  0.114  0.245  1.0
  Cs  Cs2  1  0.145  0.615  0.243  1.0
  Cs  Cs3  1  0.642  0.887  0.752  1.0
  Au  Au4  1  0.647  0.629  0.288  1.0
  Au  Au5  1  0.850  0.131  0.290  1.0
  Au  Au6  1  0.142  0.862  0.713  1.0
  Au  Au7  1  0.356  0.361  0.714  1.0
  S  S8  1  0.254  0.536  0.901  1.0
  S  S9  1  0.524  0.303  0.476  1.0
  S  S10  1  0.239  0.042  0.898  1.0
  S  S11  1  0.744  0.461  0.103  1.0
  S  S12  1  0.029  0.201  0.523  1.0
  S  S13  1  0.976  0.807  0.475  1.0
  S  S14  1  0.755  0.955  0.101  1.0
  S  S15  1  0.470  0.697  0.530  1.0
  O  O16  1  0.291  0.958  0.804  1.0
  O  O17  1  0.504  0.743  0.375  1.0
  O  O18  1  0.649  0.435  0.451  1.0
  O  O19  1  0.496  0.256  0.631  1.0
  O  O20  1  0.007  0.751  0.634  1.0
  O  O21  1  0.771  0.567  0.961  1.0
  O  O22  1  0.791  0.541  0.202  1.0
  O  O23  1  0.599  0.393  0.139  1.0
  O  O24  1  0.097  0.330  0.542  1.0
  O  O25  1  0.141  0.069  0.543  1.0
  O  O26  1  0.706  0.033  0.199  1.0
  O  O27  1  0.594  0.164  0.467  1.0
  O  O28  1  0.266  0.932  0.037  1.0
  O  O29  1  0.351  0.566  0.549  1.0
  O  O30  1  0.102  0.106  0.861  1.0
  O  O31  1  0.099  0.870  0.386  1.0
  O  O32  1  0.897  0.897  0.138  1.0
  O  O33  1  0.208  0.462  0.796  1.0
  O  O34  1  0.638  0.831  0.124  1.0
  O  O35  1  0.995  0.243  0.369  1.0
  O  O36  1  0.401  0.368  0.391  1.0
  O  O37  1  0.591  0.628  0.613  1.0
  O  O38  1  0.852  0.929  0.459  1.0
  O  O39  1  0.361  0.169  0.875  1.0
  O  O40  1  0.404  0.830  0.535  1.0
  O  O41  1  0.237  0.434  0.038  1.0
  O  O42  1  0.396  0.610  0.863  1.0
  O  O43  1  0.729  0.063  0.962  1.0
  O  O44  1  0.907  0.662  0.463  1.0
  O  O45  1  0.859  0.337  0.116  1.0
  O  O46  1  0.145  0.671  0.880  1.0
  O  O47  1  0.906  0.132  0.607  1.0
[/CIF]
.
The compound described by CsAu(SO4)2 crystallizes in the triclinic P1 space group. There are four inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 11-coordinate geometry to one O(15), one O(18), one O(22), one O(28), one O(29), one O(3), one O(30), one O(32), one O(5), one O(6), and one O(9) atom. In the second Cs site, Cs(2) is bonded in a 11-coordinate geometry to one O(10), one O(11), one O(12), one O(13), one O(16), one O(2), one O(21), one O(24), one O(25), one O(26), and one O(8) atom. In the third Cs site, Cs(3) is bonded in a 11-coordinate geometry to one O(13), one O(14), one O(16), one O(17), one O(20), one O(21), one O(26), one O(29), one O(31), one O(7), and one O(9) atom. In the fourth Cs site, Cs(4) is bonded in a 11-coordinate geometry to one O(1), one O(12), one O(19), one O(22), one O(23), one O(25), one O(27), one O(28), one O(32), one O(4), and one O(6) atom. There are four inequivalent Au sites. In the first Au site, Au(1) is bonded in a rectangular see-saw-like geometry to one O(19), one O(2), one O(3), and one O(7) atom. In the second Au site, Au(2) is bonded in a rectangular see-saw-like geometry to one O(11), one O(20), one O(23), and one O(30) atom. In the third Au site, Au(3) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(31), and one O(5) atom. In the fourth Au site, Au(4) is bonded in a square co-planar geometry to one O(14), one O(18), one O(24), and one O(4) atom. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(18), one O(26), one O(27), and one O(31) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(12), one O(21), one O(3), and one O(4) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one O(1), one O(13), one O(15), and one O(24) atom. In the fourth S site, S(4) is bonded in a tetrahedral geometry to one O(30), one O(6), one O(7), and one O(8) atom. In the fifth S site, S(5) is bonded in a tetrahedral geometry to one O(10), one O(20), one O(32), and one O(9) atom. In the sixth S site, S(6) is bonded in a tetrahedral geometry to one O(16), one O(23), one O(29), and one O(5) atom. In the seventh S site, S(7) is bonded in a tetrahedral geometry to one O(11), one O(17), one O(19), and one O(28) atom. In the eighth S site, S(8) is bonded in a tetrahedral geometry to one O(14), one O(2), one O(22), and one O(25) atom. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cs(4), one Au(3), and one S(3) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cs(2), one Au(1), and one S(8) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cs(1), one Au(1), and one S(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cs(4), one Au(4), and one S(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Au(3), and one S(6) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(4), and one S(4) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Cs(3), one Au(1), and one S(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Cs(2) and one S(4) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Cs(1), one Cs(3), and one S(5) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Cs(2), one Au(3), and one S(5) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Cs(2), one Au(2), and one S(7) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Cs(2), one Cs(4), and one S(2) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Cs(2), one Cs(3), and one S(3) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Cs(3), one Au(4), and one S(8) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one Cs(1) and one S(3) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one Cs(2), one Cs(3), and one S(6) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one Cs(3) and one S(7) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Au(4), and one S(1) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Cs(4), one Au(1), and one S(7) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Cs(3), one Au(2), and one S(5) atom. In the twenty-first O site, O(21) is bonded in a single-bond geometry to one Cs(2), one Cs(3), and one S(2) atom. In the twenty-second O site, O(22) is bonded in a single-bond geometry to one Cs(1), one Cs(4), and one S(8) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 120 degrees geometry to one Cs(4), one Au(2), and one S(6) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Cs(2), one Au(4), and one S(3) atom. In the twenty-fifth O site, O(25) is bonded in a single-bond geometry to one Cs(2), one Cs(4), and one S(8) atom. In the twenty-sixth O site, O(26) is bonded in a single-bond geometry to one Cs(2), one Cs(3), and one S(1) atom. In the twenty-seventh O site, O(27) is bonded in a single-bond geometry to one Cs(4) and one S(1) atom. In the twenty-eighth O site, O(28) is bonded in a distorted single-bond geometry to one Cs(1), one Cs(4), and one S(7) atom. In the twenty-ninth O site, O(29) is bonded in a single-bond geometry to one Cs(1), one Cs(3), and one S(6) atom. In the thirtieth O site, O(30) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one Au(2), and one S(4) atom. In the thirty-first O site, O(31) is bonded in a distorted bent 120 degrees geometry to one Cs(3), one Au(3), and one S(1) atom. In the thirty-second O site, O(32) is bonded in a single-bond geometry to one Cs(1), one Cs(4), and one S(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsAu(SO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.307
_cell_length_b   9.247
_cell_length_c   10.551
_cell_angle_alpha   68.589
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   845.334
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.862  0.382  0.758  1.0
  Cs  Cs1  1  0.364  0.114  0.245  1.0
  Cs  Cs2  1  0.145  0.615  0.243  1.0
  Cs  Cs3  1  0.642  0.887  0.752  1.0
  Au  Au4  1  0.647  0.629  0.288  1.0
  Au  Au5  1  0.850  0.131  0.290  1.0
  Au  Au6  1  0.142  0.862  0.713  1.0
  Au  Au7  1  0.356  0.361  0.714  1.0
  S  S8  1  0.254  0.536  0.901  1.0
  S  S9  1  0.524  0.303  0.476  1.0
  S  S10  1  0.239  0.042  0.898  1.0
  S  S11  1  0.744  0.461  0.103  1.0
  S  S12  1  0.029  0.201  0.523  1.0
  S  S13  1  0.976  0.807  0.475  1.0
  S  S14  1  0.755  0.955  0.101  1.0
  S  S15  1  0.470  0.697  0.530  1.0
  O  O16  1  0.291  0.958  0.804  1.0
  O  O17  1  0.504  0.743  0.375  1.0
  O  O18  1  0.649  0.435  0.451  1.0
  O  O19  1  0.496  0.256  0.631  1.0
  O  O20  1  0.007  0.751  0.634  1.0
  O  O21  1  0.771  0.567  0.961  1.0
  O  O22  1  0.791  0.541  0.202  1.0
  O  O23  1  0.599  0.393  0.139  1.0
  O  O24  1  0.097  0.330  0.542  1.0
  O  O25  1  0.141  0.069  0.543  1.0
  O  O26  1  0.706  0.033  0.199  1.0
  O  O27  1  0.594  0.164  0.467  1.0
  O  O28  1  0.266  0.932  0.037  1.0
  O  O29  1  0.351  0.566  0.549  1.0
  O  O30  1  0.102  0.106  0.861  1.0
  O  O31  1  0.099  0.870  0.386  1.0
  O  O32  1  0.897  0.897  0.138  1.0
  O  O33  1  0.208  0.462  0.796  1.0
  O  O34  1  0.638  0.831  0.124  1.0
  O  O35  1  0.995  0.243  0.369  1.0
  O  O36  1  0.401  0.368  0.391  1.0
  O  O37  1  0.591  0.628  0.613  1.0
  O  O38  1  0.852  0.929  0.459  1.0
  O  O39  1  0.361  0.169  0.875  1.0
  O  O40  1  0.404  0.830  0.535  1.0
  O  O41  1  0.237  0.434  0.038  1.0
  O  O42  1  0.396  0.610  0.863  1.0
  O  O43  1  0.729  0.063  0.962  1.0
  O  O44  1  0.907  0.662  0.463  1.0
  O  O45  1  0.859  0.337  0.116  1.0
  O  O46  1  0.145  0.671  0.880  1.0
  O  O47  1  0.906  0.132  0.607  1.0
[/CIF]
.