The material described by N2NONSO4 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight ammonia atoms, four nitroxyl molecules, and four NSO4 clusters. In each NSO4 cluster, N(1) is bonded in a 1-coordinate geometry to one S(1) and one O(3) atom. S(1) is bonded in a distorted trigonal pyramidal geometry to one N(1), one O(1), and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SN4O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.297
_cell_length_b   8.496
_cell_length_c   10.728
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   756.277
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.250  0.838  0.495  1.0
  S  S1  1  0.250  0.338  0.005  1.0
  S  S2  1  0.750  0.162  0.505  1.0
  S  S3  1  0.750  0.662  0.995  1.0
  N  N4  1  0.250  0.078  0.539  1.0
  N  N5  1  0.250  0.578  0.961  1.0
  N  N6  1  0.750  0.922  0.461  1.0
  N  N7  1  0.750  0.422  0.039  1.0
  N  N8  1  0.250  0.253  0.406  1.0
  N  N9  1  0.250  0.753  0.094  1.0
  N  N10  1  0.750  0.747  0.594  1.0
  N  N11  1  0.750  0.247  0.906  1.0
  N  N12  1  0.990  0.551  0.307  1.0
  N  N13  1  0.510  0.051  0.193  1.0
  N  N14  1  0.490  0.449  0.693  1.0
  N  N15  1  0.010  0.949  0.807  1.0
  N  N16  1  0.010  0.449  0.693  1.0
  N  N17  1  0.490  0.949  0.807  1.0
  N  N18  1  0.510  0.551  0.307  1.0
  N  N19  1  0.990  0.051  0.193  1.0
  O  O20  1  0.250  0.863  0.362  1.0
  O  O21  1  0.250  0.363  0.138  1.0
  O  O22  1  0.750  0.137  0.638  1.0
  O  O23  1  0.750  0.637  0.862  1.0
  O  O24  1  0.101  0.788  0.554  1.0
  O  O25  1  0.399  0.288  0.946  1.0
  O  O26  1  0.601  0.212  0.446  1.0
  O  O27  1  0.899  0.712  0.054  1.0
  O  O28  1  0.899  0.212  0.446  1.0
  O  O29  1  0.601  0.712  0.054  1.0
  O  O30  1  0.399  0.788  0.554  1.0
  O  O31  1  0.101  0.288  0.946  1.0
  O  O32  1  0.250  0.131  0.640  1.0
  O  O33  1  0.250  0.631  0.860  1.0
  O  O34  1  0.750  0.869  0.360  1.0
  O  O35  1  0.750  0.369  0.140  1.0
  O  O36  1  0.250  0.367  0.461  1.0
  O  O37  1  0.250  0.867  0.039  1.0
  O  O38  1  0.750  0.633  0.539  1.0
  O  O39  1  0.750  0.133  0.961  1.0
[/CIF]
.
The material described by N2NONSO4 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight ammonia atoms, four nitroxyl molecules, and four NSO4 clusters. In each NSO4 cluster, N(1) is bonded in a 1-coordinate geometry to one S(1) and one O(3) atom. S(1) is bonded in a distorted trigonal pyramidal geometry to one N(1), one O(1), and two equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SN4O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.297
_cell_length_b   8.496
_cell_length_c   10.728
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   756.277
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.250  0.838  0.495  1.0
  S  S1  1  0.250  0.338  0.005  1.0
  S  S2  1  0.750  0.162  0.505  1.0
  S  S3  1  0.750  0.662  0.995  1.0
  N  N4  1  0.250  0.078  0.539  1.0
  N  N5  1  0.250  0.578  0.961  1.0
  N  N6  1  0.750  0.922  0.461  1.0
  N  N7  1  0.750  0.422  0.039  1.0
  N  N8  1  0.250  0.253  0.406  1.0
  N  N9  1  0.250  0.753  0.094  1.0
  N  N10  1  0.750  0.747  0.594  1.0
  N  N11  1  0.750  0.247  0.906  1.0
  N  N12  1  0.990  0.551  0.307  1.0
  N  N13  1  0.510  0.051  0.193  1.0
  N  N14  1  0.490  0.449  0.693  1.0
  N  N15  1  0.010  0.949  0.807  1.0
  N  N16  1  0.010  0.449  0.693  1.0
  N  N17  1  0.490  0.949  0.807  1.0
  N  N18  1  0.510  0.551  0.307  1.0
  N  N19  1  0.990  0.051  0.193  1.0
  O  O20  1  0.250  0.863  0.362  1.0
  O  O21  1  0.250  0.363  0.138  1.0
  O  O22  1  0.750  0.137  0.638  1.0
  O  O23  1  0.750  0.637  0.862  1.0
  O  O24  1  0.101  0.788  0.554  1.0
  O  O25  1  0.399  0.288  0.946  1.0
  O  O26  1  0.601  0.212  0.446  1.0
  O  O27  1  0.899  0.712  0.054  1.0
  O  O28  1  0.899  0.212  0.446  1.0
  O  O29  1  0.601  0.712  0.054  1.0
  O  O30  1  0.399  0.788  0.554  1.0
  O  O31  1  0.101  0.288  0.946  1.0
  O  O32  1  0.250  0.131  0.640  1.0
  O  O33  1  0.250  0.631  0.860  1.0
  O  O34  1  0.750  0.869  0.360  1.0
  O  O35  1  0.750  0.369  0.140  1.0
  O  O36  1  0.250  0.367  0.461  1.0
  O  O37  1  0.250  0.867  0.039  1.0
  O  O38  1  0.750  0.633  0.539  1.0
  O  O39  1  0.750  0.133  0.961  1.0
[/CIF]
.