The crystal structure described by NbS4(S)2 is Indium-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is zero-dimensional and consists of four hydrogen sulfide atoms and two NbS4 clusters. In each NbS4 cluster, Nb(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent S(2) atoms. S(2) is bonded in a distorted single-bond geometry to one Nb(1) atom. is represented by the CIF file [CIF]
data_NbS6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.573
_cell_length_b   9.573
_cell_length_c   51.726
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   123.161
_symmetry_Int_Tables_number   1
_cell_volume   3967.992
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.000  0.000  0.000  1.0
  S  S1  1  0.000  0.000  0.250  1.0
  S  S2  1  0.000  0.000  0.750  1.0
  S  S3  1  0.242  0.991  0.000  1.0
  S  S4  1  0.758  0.009  0.000  1.0
  S  S5  1  0.991  0.242  0.000  1.0
  S  S6  1  0.009  0.758  0.000  1.0
[/CIF]
.
The crystal structure described by NbS4(S)2 is Indium-derived structured and crystallizes in the orthorhombic Cmmm space group. The structure is zero-dimensional and consists of four hydrogen sulfide atoms and two NbS4 clusters. In each NbS4 cluster, Nb(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent S(2) atoms. S(2) is bonded in a distorted single-bond geometry to one Nb(1) atom. is represented by the CIF file [CIF]
data_NbS6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.573
_cell_length_b   9.573
_cell_length_c   51.726
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   123.161
_symmetry_Int_Tables_number   1
_cell_volume   3967.992
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nb  Nb0  1  0.000  0.000  0.000  1.0
  S  S1  1  0.000  0.000  0.250  1.0
  S  S2  1  0.000  0.000  0.750  1.0
  S  S3  1  0.242  0.991  0.000  1.0
  S  S4  1  0.758  0.009  0.000  1.0
  S  S5  1  0.991  0.242  0.000  1.0
  S  S6  1  0.009  0.758  0.000  1.0
[/CIF]
.