The structure described by B3N3H5 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 1-(1,3,5,2,4,6-triazatriborinan-2-yl)-1,3,5,2,4,6-triazatriborinane molecules. There are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(5) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(6) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one N(1) and two equivalent N(3) atoms. In the fourth B site, B(4) is bonded in a trigonal planar geometry to two equivalent N(2) and one H(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one B(3) and two equivalent B(2) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one B(2), one B(4), and one H(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one B(1), one B(3), and one H(1) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to two equivalent B(1) and one H(2) atom. There are six inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one B(4) atom. In the second H site, H(5) is bonded in a single-bond geometry to one B(1) atom. In the third H site, H(6) is bonded in a single-bond geometry to one B(2) atom. In the fourth H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(3) is bonded in a single-bond geometry to one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_B3H5N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.201
_cell_length_b   9.669
_cell_length_c   11.644
_cell_angle_alpha   111.435
_cell_angle_beta   100.879
_cell_angle_gamma   100.765
_symmetry_Int_Tables_number   1
_cell_volume   612.715
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.834  0.972  0.793  1.0
  B  B1  1  0.166  0.028  0.207  1.0
  B  B2  1  0.459  0.821  0.793  1.0
  B  B3  1  0.541  0.179  0.207  1.0
  B  B4  1  0.622  0.756  0.368  1.0
  B  B5  1  0.378  0.244  0.632  1.0
  B  B6  1  0.246  0.612  0.368  1.0
  B  B7  1  0.754  0.388  0.632  1.0
  B  B8  1  0.541  0.791  0.582  1.0
  B  B9  1  0.459  0.209  0.418  1.0
  B  B10  1  0.329  0.579  0.158  1.0
  B  B11  1  0.671  0.421  0.842  1.0
  H  H12  1  0.873  0.925  0.608  1.0
  H  H13  1  0.127  0.075  0.392  1.0
  H  H14  1  0.236  0.683  0.608  1.0
  H  H15  1  0.764  0.317  0.392  1.0
  H  H16  1  0.729  0.979  0.958  1.0
  H  H17  1  0.271  0.021  0.042  1.0
  H  H18  1  0.663  0.709  0.184  1.0
  H  H19  1  0.337  0.291  0.816  1.0
  H  H20  1  0.021  0.474  0.184  1.0
  H  H21  1  0.979  0.526  0.816  1.0
  H  H22  1  0.271  0.521  0.042  1.0
  H  H23  1  0.729  0.479  0.958  1.0
  H  H24  1  0.017  0.067  0.850  1.0
  H  H25  1  0.983  0.933  0.150  1.0
  H  H26  1  0.333  0.783  0.850  1.0
  H  H27  1  0.667  0.217  0.150  1.0
  H  H28  1  0.808  0.848  0.421  1.0
  H  H29  1  0.192  0.152  0.579  1.0
  H  H30  1  0.112  0.573  0.421  1.0
  H  H31  1  0.888  0.427  0.579  1.0
  N  N32  1  0.470  0.720  0.440  1.0
  N  N33  1  0.530  0.280  0.560  1.0
  N  N34  1  0.551  0.682  0.231  1.0
  N  N35  1  0.449  0.318  0.769  1.0
  N  N36  1  0.179  0.549  0.231  1.0
  N  N37  1  0.821  0.451  0.769  1.0
  N  N38  1  0.763  0.898  0.656  1.0
  N  N39  1  0.237  0.102  0.344  1.0
  N  N40  1  0.394  0.758  0.656  1.0
  N  N41  1  0.606  0.242  0.344  1.0
  N  N42  1  0.680  0.930  0.861  1.0
  N  N43  1  0.320  0.070  0.139  1.0
[/CIF]
.
The structure described by B3N3H5 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 1-(1,3,5,2,4,6-triazatriborinan-2-yl)-1,3,5,2,4,6-triazatriborinane molecules. There are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(5) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(6) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one N(1) and two equivalent N(3) atoms. In the fourth B site, B(4) is bonded in a trigonal planar geometry to two equivalent N(2) and one H(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one B(3) and two equivalent B(2) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one B(2), one B(4), and one H(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one B(1), one B(3), and one H(1) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to two equivalent B(1) and one H(2) atom. There are six inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one B(4) atom. In the second H site, H(5) is bonded in a single-bond geometry to one B(1) atom. In the third H site, H(6) is bonded in a single-bond geometry to one B(2) atom. In the fourth H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(3) is bonded in a single-bond geometry to one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_B3H5N3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.201
_cell_length_b   9.669
_cell_length_c   11.644
_cell_angle_alpha   111.435
_cell_angle_beta   100.879
_cell_angle_gamma   100.765
_symmetry_Int_Tables_number   1
_cell_volume   612.715
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.834  0.972  0.793  1.0
  B  B1  1  0.166  0.028  0.207  1.0
  B  B2  1  0.459  0.821  0.793  1.0
  B  B3  1  0.541  0.179  0.207  1.0
  B  B4  1  0.622  0.756  0.368  1.0
  B  B5  1  0.378  0.244  0.632  1.0
  B  B6  1  0.246  0.612  0.368  1.0
  B  B7  1  0.754  0.388  0.632  1.0
  B  B8  1  0.541  0.791  0.582  1.0
  B  B9  1  0.459  0.209  0.418  1.0
  B  B10  1  0.329  0.579  0.158  1.0
  B  B11  1  0.671  0.421  0.842  1.0
  H  H12  1  0.873  0.925  0.608  1.0
  H  H13  1  0.127  0.075  0.392  1.0
  H  H14  1  0.236  0.683  0.608  1.0
  H  H15  1  0.764  0.317  0.392  1.0
  H  H16  1  0.729  0.979  0.958  1.0
  H  H17  1  0.271  0.021  0.042  1.0
  H  H18  1  0.663  0.709  0.184  1.0
  H  H19  1  0.337  0.291  0.816  1.0
  H  H20  1  0.021  0.474  0.184  1.0
  H  H21  1  0.979  0.526  0.816  1.0
  H  H22  1  0.271  0.521  0.042  1.0
  H  H23  1  0.729  0.479  0.958  1.0
  H  H24  1  0.017  0.067  0.850  1.0
  H  H25  1  0.983  0.933  0.150  1.0
  H  H26  1  0.333  0.783  0.850  1.0
  H  H27  1  0.667  0.217  0.150  1.0
  H  H28  1  0.808  0.848  0.421  1.0
  H  H29  1  0.192  0.152  0.579  1.0
  H  H30  1  0.112  0.573  0.421  1.0
  H  H31  1  0.888  0.427  0.579  1.0
  N  N32  1  0.470  0.720  0.440  1.0
  N  N33  1  0.530  0.280  0.560  1.0
  N  N34  1  0.551  0.682  0.231  1.0
  N  N35  1  0.449  0.318  0.769  1.0
  N  N36  1  0.179  0.549  0.231  1.0
  N  N37  1  0.821  0.451  0.769  1.0
  N  N38  1  0.763  0.898  0.656  1.0
  N  N39  1  0.237  0.102  0.344  1.0
  N  N40  1  0.394  0.758  0.656  1.0
  N  N41  1  0.606  0.242  0.344  1.0
  N  N42  1  0.680  0.930  0.861  1.0
  N  N43  1  0.320  0.070  0.139  1.0
[/CIF]
.