The material structure described by Li2VO2F3 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent F(3) atoms. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to four equivalent O(1) and one F(2) atom. V(1) is bonded to two equivalent O(1), one F(2), one F(3), and two equivalent F(1) atoms to form distorted corner-sharing VO2F4 octahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a 4-coordinate geometry to one Li(1), two equivalent Li(2), and one V(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent V(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Li(2) and one V(1) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to two equivalent Li(1) and one V(1) atom. is represented by the CIF card [CIF]
data_Li2VO2F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.399
_cell_length_b   7.167
_cell_length_c   9.461
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   366.061
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.750  0.968  0.273  1.0
  Li  Li1  1  0.250  0.141  0.435  1.0
  Li  Li2  1  0.750  0.359  0.935  1.0
  Li  Li3  1  0.250  0.532  0.773  1.0
  Li  Li4  1  0.750  0.468  0.227  1.0
  Li  Li5  1  0.250  0.641  0.065  1.0
  Li  Li6  1  0.750  0.859  0.565  1.0
  Li  Li7  1  0.250  0.032  0.727  1.0
  V  V8  1  0.250  0.215  0.057  1.0
  V  V9  1  0.750  0.285  0.557  1.0
  V  V10  1  0.250  0.715  0.443  1.0
  V  V11  1  0.750  0.785  0.943  1.0
  O  O12  1  0.508  0.144  0.586  1.0
  O  O13  1  0.992  0.144  0.586  1.0
  O  O14  1  0.008  0.356  0.086  1.0
  O  O15  1  0.492  0.356  0.086  1.0
  O  O16  1  0.508  0.644  0.914  1.0
  O  O17  1  0.992  0.644  0.914  1.0
  O  O18  1  0.008  0.856  0.414  1.0
  O  O19  1  0.492  0.856  0.414  1.0
  F  F20  1  0.000  0.000  0.000  1.0
  F  F21  1  0.500  0.000  0.000  1.0
  F  F22  1  0.250  0.107  0.237  1.0
  F  F23  1  0.750  0.245  0.351  1.0
  F  F24  1  0.250  0.255  0.851  1.0
  F  F25  1  0.750  0.393  0.737  1.0
  F  F26  1  0.000  0.500  0.500  1.0
  F  F27  1  0.500  0.500  0.500  1.0
  F  F28  1  0.250  0.607  0.263  1.0
  F  F29  1  0.750  0.745  0.149  1.0
  F  F30  1  0.250  0.755  0.649  1.0
  F  F31  1  0.750  0.893  0.763  1.0
[/CIF]
.
The material structure described by Li2VO2F3 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent F(3) atoms. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to four equivalent O(1) and one F(2) atom. V(1) is bonded to two equivalent O(1), one F(2), one F(3), and two equivalent F(1) atoms to form distorted corner-sharing VO2F4 octahedra. The corner-sharing octahedra are not tilted. O(1) is bonded in a 4-coordinate geometry to one Li(1), two equivalent Li(2), and one V(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent V(1) atoms. In the second F site, F(2) is bonded in a bent 150 degrees geometry to one Li(2) and one V(1) atom. In the third F site, F(3) is bonded in a trigonal planar geometry to two equivalent Li(1) and one V(1) atom. is represented by the CIF card [CIF]
data_Li2VO2F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.399
_cell_length_b   7.167
_cell_length_c   9.461
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   366.061
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.750  0.968  0.273  1.0
  Li  Li1  1  0.250  0.141  0.435  1.0
  Li  Li2  1  0.750  0.359  0.935  1.0
  Li  Li3  1  0.250  0.532  0.773  1.0
  Li  Li4  1  0.750  0.468  0.227  1.0
  Li  Li5  1  0.250  0.641  0.065  1.0
  Li  Li6  1  0.750  0.859  0.565  1.0
  Li  Li7  1  0.250  0.032  0.727  1.0
  V  V8  1  0.250  0.215  0.057  1.0
  V  V9  1  0.750  0.285  0.557  1.0
  V  V10  1  0.250  0.715  0.443  1.0
  V  V11  1  0.750  0.785  0.943  1.0
  O  O12  1  0.508  0.144  0.586  1.0
  O  O13  1  0.992  0.144  0.586  1.0
  O  O14  1  0.008  0.356  0.086  1.0
  O  O15  1  0.492  0.356  0.086  1.0
  O  O16  1  0.508  0.644  0.914  1.0
  O  O17  1  0.992  0.644  0.914  1.0
  O  O18  1  0.008  0.856  0.414  1.0
  O  O19  1  0.492  0.856  0.414  1.0
  F  F20  1  0.000  0.000  0.000  1.0
  F  F21  1  0.500  0.000  0.000  1.0
  F  F22  1  0.250  0.107  0.237  1.0
  F  F23  1  0.750  0.245  0.351  1.0
  F  F24  1  0.250  0.255  0.851  1.0
  F  F25  1  0.750  0.393  0.737  1.0
  F  F26  1  0.000  0.500  0.500  1.0
  F  F27  1  0.500  0.500  0.500  1.0
  F  F28  1  0.250  0.607  0.263  1.0
  F  F29  1  0.750  0.745  0.149  1.0
  F  F30  1  0.250  0.755  0.649  1.0
  F  F31  1  0.750  0.893  0.763  1.0
[/CIF]
.