The material described by AlSbI6 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two AlSbI6 clusters. Al(1) is bonded to one I(3), one I(4), and two equivalent I(2) atoms to form AlI4 tetrahedra that share corners with two equivalent Sb(1)I4 trigonal pyramids. Sb(1) is bonded to two equivalent I(1) and two equivalent I(2) atoms to form distorted SbI4 trigonal pyramids that share corners with two equivalent Al(1)I4 tetrahedra. There are four inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second I site, I(2) is bonded in an L-shaped geometry to one Al(1) and one Sb(1) atom. In the third I site, I(3) is bonded in a single-bond geometry to one Al(1) atom. In the fourth I site, I(4) is bonded in a single-bond geometry to one Al(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AlSbI6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.515
_cell_length_b   10.550
_cell_length_c   10.550
_cell_angle_alpha   79.312
_cell_angle_beta   70.498
_cell_angle_gamma   70.498
_symmetry_Int_Tables_number   1
_cell_volume   740.676
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.359  0.800  0.800  1.0
  Al  Al1  1  0.641  0.200  0.200  1.0
  Sb  Sb2  1  0.000  0.198  0.802  1.0
  Sb  Sb3  1  0.000  0.802  0.198  1.0
  I  I4  1  0.074  0.780  0.439  1.0
  I  I5  1  0.926  0.561  0.220  1.0
  I  I6  1  0.926  0.220  0.561  1.0
  I  I7  1  0.074  0.439  0.780  1.0
  I  I8  1  0.553  0.975  0.286  1.0
  I  I9  1  0.447  0.714  0.025  1.0
  I  I10  1  0.447  0.025  0.714  1.0
  I  I11  1  0.553  0.286  0.975  1.0
  I  I12  1  0.017  0.145  0.145  1.0
  I  I13  1  0.983  0.855  0.855  1.0
  I  I14  1  0.457  0.369  0.369  1.0
  I  I15  1  0.543  0.631  0.631  1.0
[/CIF]
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The material described by AlSbI6 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two AlSbI6 clusters. Al(1) is bonded to one I(3), one I(4), and two equivalent I(2) atoms to form AlI4 tetrahedra that share corners with two equivalent Sb(1)I4 trigonal pyramids. Sb(1) is bonded to two equivalent I(1) and two equivalent I(2) atoms to form distorted SbI4 trigonal pyramids that share corners with two equivalent Al(1)I4 tetrahedra. There are four inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second I site, I(2) is bonded in an L-shaped geometry to one Al(1) and one Sb(1) atom. In the third I site, I(3) is bonded in a single-bond geometry to one Al(1) atom. In the fourth I site, I(4) is bonded in a single-bond geometry to one Al(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AlSbI6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.515
_cell_length_b   10.550
_cell_length_c   10.550
_cell_angle_alpha   79.312
_cell_angle_beta   70.498
_cell_angle_gamma   70.498
_symmetry_Int_Tables_number   1
_cell_volume   740.676
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.359  0.800  0.800  1.0
  Al  Al1  1  0.641  0.200  0.200  1.0
  Sb  Sb2  1  0.000  0.198  0.802  1.0
  Sb  Sb3  1  0.000  0.802  0.198  1.0
  I  I4  1  0.074  0.780  0.439  1.0
  I  I5  1  0.926  0.561  0.220  1.0
  I  I6  1  0.926  0.220  0.561  1.0
  I  I7  1  0.074  0.439  0.780  1.0
  I  I8  1  0.553  0.975  0.286  1.0
  I  I9  1  0.447  0.714  0.025  1.0
  I  I10  1  0.447  0.025  0.714  1.0
  I  I11  1  0.553  0.286  0.975  1.0
  I  I12  1  0.017  0.145  0.145  1.0
  I  I13  1  0.983  0.855  0.855  1.0
  I  I14  1  0.457  0.369  0.369  1.0
  I  I15  1  0.543  0.631  0.631  1.0
[/CIF]
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