The crystal structure described by SmRh5Ge3 crystallizes in the hexagonal P6_3/m space group. Sm(1) is bonded in a 12-coordinate geometry to two equivalent Rh(1), two equivalent Rh(2), two equivalent Rh(5), two equivalent Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. There are five inequivalent Rh sites. In the first Rh site, Rh(3) is bonded in a 3-coordinate geometry to three equivalent Ge(2) atoms. In the second Rh site, Rh(4) is bonded in a 5-coordinate geometry to one Ge(3) and four equivalent Ge(1) atoms. In the third Rh site, Rh(5) is bonded in a 4-coordinate geometry to two equivalent Sm(1), one Ge(3), and three equivalent Ge(2) atoms. In the fourth Rh site, Rh(1) is bonded in a 6-coordinate geometry to two equivalent Sm(1), one Ge(1), one Ge(2), and two equivalent Ge(3) atoms. In the fifth Rh site, Rh(2) is bonded in a 4-coordinate geometry to two equivalent Sm(1), one Ge(1), and three equivalent Ge(3) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 8-coordinate geometry to two equivalent Sm(1), one Rh(1), one Rh(2), and four equivalent Rh(4) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to two equivalent Sm(1), one Rh(1), three equivalent Rh(3), and three equivalent Rh(5) atoms. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to two equivalent Sm(1), one Rh(4), one Rh(5), two equivalent Rh(1), and three equivalent Rh(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_SmGe3Rh5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.037
_cell_length_b   16.037
_cell_length_c   3.969
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   883.945
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.294  0.395  0.750  1.0
  Sm  Sm1  1  0.706  0.605  0.250  1.0
  Sm  Sm2  1  0.605  0.899  0.750  1.0
  Sm  Sm3  1  0.395  0.101  0.250  1.0
  Sm  Sm4  1  0.101  0.706  0.750  1.0
  Sm  Sm5  1  0.899  0.294  0.250  1.0
  Ge  Ge6  1  0.556  0.238  0.750  1.0
  Ge  Ge7  1  0.444  0.762  0.250  1.0
  Ge  Ge8  1  0.762  0.318  0.750  1.0
  Ge  Ge9  1  0.238  0.682  0.250  1.0
  Ge  Ge10  1  0.682  0.444  0.750  1.0
  Ge  Ge11  1  0.318  0.556  0.250  1.0
  Ge  Ge12  1  0.250  0.118  0.750  1.0
  Ge  Ge13  1  0.750  0.882  0.250  1.0
  Ge  Ge14  1  0.882  0.131  0.750  1.0
  Ge  Ge15  1  0.118  0.869  0.250  1.0
  Ge  Ge16  1  0.869  0.750  0.750  1.0
  Ge  Ge17  1  0.131  0.250  0.250  1.0
  Ge  Ge18  1  0.059  0.430  0.750  1.0
  Ge  Ge19  1  0.941  0.570  0.250  1.0
  Ge  Ge20  1  0.570  0.629  0.750  1.0
  Ge  Ge21  1  0.430  0.371  0.250  1.0
  Ge  Ge22  1  0.371  0.941  0.750  1.0
  Ge  Ge23  1  0.629  0.059  0.250  1.0
  Rh  Rh24  1  0.413  0.262  0.750  1.0
  Rh  Rh25  1  0.587  0.738  0.250  1.0
  Rh  Rh26  1  0.738  0.151  0.750  1.0
  Rh  Rh27  1  0.262  0.849  0.250  1.0
  Rh  Rh28  1  0.849  0.587  0.750  1.0
  Rh  Rh29  1  0.151  0.413  0.250  1.0
  Rh  Rh30  1  0.538  0.075  0.750  1.0
  Rh  Rh31  1  0.462  0.925  0.250  1.0
  Rh  Rh32  1  0.925  0.463  0.750  1.0
  Rh  Rh33  1  0.075  0.537  0.250  1.0
  Rh  Rh34  1  0.537  0.462  0.750  1.0
  Rh  Rh35  1  0.463  0.538  0.250  1.0
  Rh  Rh36  1  0.105  0.132  0.750  1.0
  Rh  Rh37  1  0.895  0.868  0.250  1.0
  Rh  Rh38  1  0.868  0.973  0.750  1.0
  Rh  Rh39  1  0.132  0.027  0.250  1.0
  Rh  Rh40  1  0.027  0.895  0.750  1.0
  Rh  Rh41  1  0.973  0.105  0.250  1.0
  Rh  Rh42  1  0.223  0.570  0.750  1.0
  Rh  Rh43  1  0.777  0.430  0.250  1.0
  Rh  Rh44  1  0.430  0.653  0.750  1.0
  Rh  Rh45  1  0.570  0.347  0.250  1.0
  Rh  Rh46  1  0.347  0.777  0.750  1.0
  Rh  Rh47  1  0.653  0.223  0.250  1.0
  Rh  Rh48  1  0.045  0.268  0.750  1.0
  Rh  Rh49  1  0.955  0.732  0.250  1.0
  Rh  Rh50  1  0.732  0.777  0.750  1.0
  Rh  Rh51  1  0.268  0.223  0.250  1.0
  Rh  Rh52  1  0.223  0.955  0.750  1.0
  Rh  Rh53  1  0.777  0.045  0.250  1.0
[/CIF]
.
The crystal structure described by SmRh5Ge3 crystallizes in the hexagonal P6_3/m space group. Sm(1) is bonded in a 12-coordinate geometry to two equivalent Rh(1), two equivalent Rh(2), two equivalent Rh(5), two equivalent Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. There are five inequivalent Rh sites. In the first Rh site, Rh(3) is bonded in a 3-coordinate geometry to three equivalent Ge(2) atoms. In the second Rh site, Rh(4) is bonded in a 5-coordinate geometry to one Ge(3) and four equivalent Ge(1) atoms. In the third Rh site, Rh(5) is bonded in a 4-coordinate geometry to two equivalent Sm(1), one Ge(3), and three equivalent Ge(2) atoms. In the fourth Rh site, Rh(1) is bonded in a 6-coordinate geometry to two equivalent Sm(1), one Ge(1), one Ge(2), and two equivalent Ge(3) atoms. In the fifth Rh site, Rh(2) is bonded in a 4-coordinate geometry to two equivalent Sm(1), one Ge(1), and three equivalent Ge(3) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 8-coordinate geometry to two equivalent Sm(1), one Rh(1), one Rh(2), and four equivalent Rh(4) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to two equivalent Sm(1), one Rh(1), three equivalent Rh(3), and three equivalent Rh(5) atoms. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to two equivalent Sm(1), one Rh(4), one Rh(5), two equivalent Rh(1), and three equivalent Rh(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_SmGe3Rh5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.037
_cell_length_b   16.037
_cell_length_c   3.969
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   883.945
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.294  0.395  0.750  1.0
  Sm  Sm1  1  0.706  0.605  0.250  1.0
  Sm  Sm2  1  0.605  0.899  0.750  1.0
  Sm  Sm3  1  0.395  0.101  0.250  1.0
  Sm  Sm4  1  0.101  0.706  0.750  1.0
  Sm  Sm5  1  0.899  0.294  0.250  1.0
  Ge  Ge6  1  0.556  0.238  0.750  1.0
  Ge  Ge7  1  0.444  0.762  0.250  1.0
  Ge  Ge8  1  0.762  0.318  0.750  1.0
  Ge  Ge9  1  0.238  0.682  0.250  1.0
  Ge  Ge10  1  0.682  0.444  0.750  1.0
  Ge  Ge11  1  0.318  0.556  0.250  1.0
  Ge  Ge12  1  0.250  0.118  0.750  1.0
  Ge  Ge13  1  0.750  0.882  0.250  1.0
  Ge  Ge14  1  0.882  0.131  0.750  1.0
  Ge  Ge15  1  0.118  0.869  0.250  1.0
  Ge  Ge16  1  0.869  0.750  0.750  1.0
  Ge  Ge17  1  0.131  0.250  0.250  1.0
  Ge  Ge18  1  0.059  0.430  0.750  1.0
  Ge  Ge19  1  0.941  0.570  0.250  1.0
  Ge  Ge20  1  0.570  0.629  0.750  1.0
  Ge  Ge21  1  0.430  0.371  0.250  1.0
  Ge  Ge22  1  0.371  0.941  0.750  1.0
  Ge  Ge23  1  0.629  0.059  0.250  1.0
  Rh  Rh24  1  0.413  0.262  0.750  1.0
  Rh  Rh25  1  0.587  0.738  0.250  1.0
  Rh  Rh26  1  0.738  0.151  0.750  1.0
  Rh  Rh27  1  0.262  0.849  0.250  1.0
  Rh  Rh28  1  0.849  0.587  0.750  1.0
  Rh  Rh29  1  0.151  0.413  0.250  1.0
  Rh  Rh30  1  0.538  0.075  0.750  1.0
  Rh  Rh31  1  0.462  0.925  0.250  1.0
  Rh  Rh32  1  0.925  0.463  0.750  1.0
  Rh  Rh33  1  0.075  0.537  0.250  1.0
  Rh  Rh34  1  0.537  0.462  0.750  1.0
  Rh  Rh35  1  0.463  0.538  0.250  1.0
  Rh  Rh36  1  0.105  0.132  0.750  1.0
  Rh  Rh37  1  0.895  0.868  0.250  1.0
  Rh  Rh38  1  0.868  0.973  0.750  1.0
  Rh  Rh39  1  0.132  0.027  0.250  1.0
  Rh  Rh40  1  0.027  0.895  0.750  1.0
  Rh  Rh41  1  0.973  0.105  0.250  1.0
  Rh  Rh42  1  0.223  0.570  0.750  1.0
  Rh  Rh43  1  0.777  0.430  0.250  1.0
  Rh  Rh44  1  0.430  0.653  0.750  1.0
  Rh  Rh45  1  0.570  0.347  0.250  1.0
  Rh  Rh46  1  0.347  0.777  0.750  1.0
  Rh  Rh47  1  0.653  0.223  0.250  1.0
  Rh  Rh48  1  0.045  0.268  0.750  1.0
  Rh  Rh49  1  0.955  0.732  0.250  1.0
  Rh  Rh50  1  0.732  0.777  0.750  1.0
  Rh  Rh51  1  0.268  0.223  0.250  1.0
  Rh  Rh52  1  0.223  0.955  0.750  1.0
  Rh  Rh53  1  0.777  0.045  0.250  1.0
[/CIF]
.