The material structure described by OsC3O3I is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two OsC3O3I clusters. Os(1) is bonded in a 3-coordinate geometry to one C(1), one C(2), one C(3), one I(1), and one I(2) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Os(1) and one O(3) atom. In the second C site, C(2) is bonded in a linear geometry to one Os(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Os(1) and one O(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to two equivalent Os(1) atoms. In the second I site, I(2) is bonded in a 2-coordinate geometry to two equivalent Os(1) atoms. is represented by the CIF file [CIF]
data_OsC3IO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.185
_cell_length_b   6.519
_cell_length_c   7.430
_cell_angle_alpha   88.885
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   686.892
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.651  0.249  0.718  1.0
  Os  Os1  1  0.349  0.751  0.282  1.0
  Os  Os2  1  0.151  0.751  0.282  1.0
  Os  Os3  1  0.849  0.249  0.718  1.0
  C  C4  1  0.873  0.122  0.496  1.0
  C  C5  1  0.468  0.615  0.255  1.0
  C  C6  1  0.119  0.992  0.151  1.0
  C  C7  1  0.381  0.992  0.151  1.0
  C  C8  1  0.532  0.385  0.745  1.0
  C  C9  1  0.619  0.008  0.849  1.0
  C  C10  1  0.127  0.878  0.504  1.0
  C  C11  1  0.881  0.008  0.849  1.0
  C  C12  1  0.968  0.385  0.745  1.0
  C  C13  1  0.032  0.615  0.255  1.0
  C  C14  1  0.373  0.878  0.504  1.0
  C  C15  1  0.627  0.122  0.496  1.0
  I  I16  1  0.750  0.563  0.539  1.0
  I  I17  1  0.250  0.437  0.461  1.0
  I  I18  1  0.750  0.390  0.013  1.0
  I  I19  1  0.250  0.610  0.987  1.0
  O  O20  1  0.598  0.859  0.927  1.0
  O  O21  1  0.541  0.533  0.246  1.0
  O  O22  1  0.110  0.960  0.638  1.0
  O  O23  1  0.390  0.960  0.638  1.0
  O  O24  1  0.610  0.040  0.362  1.0
  O  O25  1  0.459  0.467  0.754  1.0
  O  O26  1  0.098  0.141  0.073  1.0
  O  O27  1  0.890  0.040  0.362  1.0
  O  O28  1  0.959  0.533  0.246  1.0
  O  O29  1  0.902  0.859  0.927  1.0
  O  O30  1  0.402  0.141  0.073  1.0
  O  O31  1  0.041  0.467  0.754  1.0
[/CIF]
.
The material structure described by OsC3O3I is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two OsC3O3I clusters. Os(1) is bonded in a 3-coordinate geometry to one C(1), one C(2), one C(3), one I(1), and one I(2) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Os(1) and one O(3) atom. In the second C site, C(2) is bonded in a linear geometry to one Os(1) and one O(2) atom. In the third C site, C(3) is bonded in a linear geometry to one Os(1) and one O(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 2-coordinate geometry to two equivalent Os(1) atoms. In the second I site, I(2) is bonded in a 2-coordinate geometry to two equivalent Os(1) atoms. is represented by the CIF file [CIF]
data_OsC3IO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.185
_cell_length_b   6.519
_cell_length_c   7.430
_cell_angle_alpha   88.885
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   686.892
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.651  0.249  0.718  1.0
  Os  Os1  1  0.349  0.751  0.282  1.0
  Os  Os2  1  0.151  0.751  0.282  1.0
  Os  Os3  1  0.849  0.249  0.718  1.0
  C  C4  1  0.873  0.122  0.496  1.0
  C  C5  1  0.468  0.615  0.255  1.0
  C  C6  1  0.119  0.992  0.151  1.0
  C  C7  1  0.381  0.992  0.151  1.0
  C  C8  1  0.532  0.385  0.745  1.0
  C  C9  1  0.619  0.008  0.849  1.0
  C  C10  1  0.127  0.878  0.504  1.0
  C  C11  1  0.881  0.008  0.849  1.0
  C  C12  1  0.968  0.385  0.745  1.0
  C  C13  1  0.032  0.615  0.255  1.0
  C  C14  1  0.373  0.878  0.504  1.0
  C  C15  1  0.627  0.122  0.496  1.0
  I  I16  1  0.750  0.563  0.539  1.0
  I  I17  1  0.250  0.437  0.461  1.0
  I  I18  1  0.750  0.390  0.013  1.0
  I  I19  1  0.250  0.610  0.987  1.0
  O  O20  1  0.598  0.859  0.927  1.0
  O  O21  1  0.541  0.533  0.246  1.0
  O  O22  1  0.110  0.960  0.638  1.0
  O  O23  1  0.390  0.960  0.638  1.0
  O  O24  1  0.610  0.040  0.362  1.0
  O  O25  1  0.459  0.467  0.754  1.0
  O  O26  1  0.098  0.141  0.073  1.0
  O  O27  1  0.890  0.040  0.362  1.0
  O  O28  1  0.959  0.533  0.246  1.0
  O  O29  1  0.902  0.859  0.927  1.0
  O  O30  1  0.402  0.141  0.073  1.0
  O  O31  1  0.041  0.467  0.754  1.0
[/CIF]
.