The crystal structure described by CoN14CoN10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CoN10 cluster and one CoN14 cluster. In the CoN10 cluster, Co(2) is bonded in a 4-coordinate geometry to two equivalent N(11), two equivalent N(12), two equivalent N(7), and two equivalent N(8) atoms. There are five inequivalent N sites. In the first N site, N(7) is bonded in a distorted single-bond geometry to one Co(2) and one N(8) atom. In the second N site, N(8) is bonded in a distorted linear geometry to one Co(2), one N(7), and one N(9) atom. In the third N site, N(9) is bonded in a single-bond geometry to one N(8) atom. In the fourth N site, N(11) is bonded in a single-bond geometry to one Co(2) atom. In the fifth N site, N(12) is bonded in a single-bond geometry to one Co(2) atom. In the CoN14 cluster, Co(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent N(10) atoms. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Co(1) and one N(2) atom. In the second N site, N(2) is bonded in a distorted T-shaped geometry to one N(1), one N(3), and one N(4) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a distorted single-bond geometry to one N(2) and one N(5) atom. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom. In the seventh N site, N(10) is bonded in a single-bond geometry to one Co(1) atom. is represented by the CIF file [CIF]
data_CoN12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.088
_cell_length_b   7.893
_cell_length_c   9.994
_cell_angle_alpha   110.713
_cell_angle_beta   86.699
_cell_angle_gamma   115.844
_symmetry_Int_Tables_number   1
_cell_volume   467.533
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.500  0.500  0.500  1.0
  N  N2  1  0.846  0.070  0.080  1.0
  N  N3  1  0.154  0.930  0.920  1.0
  N  N4  1  0.787  0.211  0.013  1.0
  N  N5  1  0.213  0.789  0.987  1.0
  N  N6  1  0.726  0.342  0.958  1.0
  N  N7  1  0.274  0.658  0.042  1.0
  N  N8  1  0.113  0.871  0.190  1.0
  N  N9  1  0.887  0.129  0.810  1.0
  N  N10  1  0.109  0.905  0.294  1.0
  N  N11  1  0.891  0.095  0.706  1.0
  N  N12  1  0.112  0.929  0.398  1.0
  N  N13  1  0.888  0.071  0.602  1.0
  N  N14  1  0.340  0.514  0.609  1.0
  N  N15  1  0.660  0.486  0.391  1.0
  N  N16  1  0.385  0.642  0.661  1.0
  N  N17  1  0.615  0.358  0.339  1.0
  N  N18  1  0.408  0.753  0.715  1.0
  N  N19  1  0.592  0.247  0.285  1.0
  N  N20  1  0.231  0.250  0.989  1.0
  N  N21  1  0.769  0.750  0.011  1.0
  N  N22  1  0.444  0.226  0.620  1.0
  N  N23  1  0.556  0.774  0.380  1.0
  N  N24  1  0.755  0.584  0.618  1.0
  N  N25  1  0.245  0.416  0.382  1.0
[/CIF]
.
The crystal structure described by CoN14CoN10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one CoN10 cluster and one CoN14 cluster. In the CoN10 cluster, Co(2) is bonded in a 4-coordinate geometry to two equivalent N(11), two equivalent N(12), two equivalent N(7), and two equivalent N(8) atoms. There are five inequivalent N sites. In the first N site, N(7) is bonded in a distorted single-bond geometry to one Co(2) and one N(8) atom. In the second N site, N(8) is bonded in a distorted linear geometry to one Co(2), one N(7), and one N(9) atom. In the third N site, N(9) is bonded in a single-bond geometry to one N(8) atom. In the fourth N site, N(11) is bonded in a single-bond geometry to one Co(2) atom. In the fifth N site, N(12) is bonded in a single-bond geometry to one Co(2) atom. In the CoN14 cluster, Co(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent N(10) atoms. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Co(1) and one N(2) atom. In the second N site, N(2) is bonded in a distorted T-shaped geometry to one N(1), one N(3), and one N(4) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a distorted single-bond geometry to one N(2) and one N(5) atom. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom. In the seventh N site, N(10) is bonded in a single-bond geometry to one Co(1) atom. is represented by the CIF file [CIF]
data_CoN12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.088
_cell_length_b   7.893
_cell_length_c   9.994
_cell_angle_alpha   110.713
_cell_angle_beta   86.699
_cell_angle_gamma   115.844
_symmetry_Int_Tables_number   1
_cell_volume   467.533
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.000  0.000  1.0
  Co  Co1  1  0.500  0.500  0.500  1.0
  N  N2  1  0.846  0.070  0.080  1.0
  N  N3  1  0.154  0.930  0.920  1.0
  N  N4  1  0.787  0.211  0.013  1.0
  N  N5  1  0.213  0.789  0.987  1.0
  N  N6  1  0.726  0.342  0.958  1.0
  N  N7  1  0.274  0.658  0.042  1.0
  N  N8  1  0.113  0.871  0.190  1.0
  N  N9  1  0.887  0.129  0.810  1.0
  N  N10  1  0.109  0.905  0.294  1.0
  N  N11  1  0.891  0.095  0.706  1.0
  N  N12  1  0.112  0.929  0.398  1.0
  N  N13  1  0.888  0.071  0.602  1.0
  N  N14  1  0.340  0.514  0.609  1.0
  N  N15  1  0.660  0.486  0.391  1.0
  N  N16  1  0.385  0.642  0.661  1.0
  N  N17  1  0.615  0.358  0.339  1.0
  N  N18  1  0.408  0.753  0.715  1.0
  N  N19  1  0.592  0.247  0.285  1.0
  N  N20  1  0.231  0.250  0.989  1.0
  N  N21  1  0.769  0.750  0.011  1.0
  N  N22  1  0.444  0.226  0.620  1.0
  N  N23  1  0.556  0.774  0.380  1.0
  N  N24  1  0.755  0.584  0.618  1.0
  N  N25  1  0.245  0.416  0.382  1.0
[/CIF]
.