The material described by H3OClO4 is Indium-derived structured and crystallizes in the monoclinic Pm space group. The structure is zero-dimensional and consists of one hydrogen hydrate molecule, one hypochlorous acid;trihydrate molecule, and three H3OClO4 clusters. In each H3OClO4 cluster, there are two inequivalent H sites. In the first H site, H(3,5) is bonded in a single-bond geometry to one O(14) atom. In the second H site, H(4) is bonded in a linear geometry to one O(14) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(14) is bonded in a trigonal planar geometry to one H(4) and two equivalent H(3,5) atoms. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one H(4) and one Cl(4) atom. In the third O site, O(8) is bonded in a single-bond geometry to one Cl(4) atom. In the fourth O site, O(12) is bonded in a single-bond geometry to one Cl(4) atom. Cl(4) is bonded in a tetrahedral geometry to one O(4), one O(8), and two equivalent O(12) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_H3ClO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.857
_cell_length_b   6.951
_cell_length_c   9.295
_cell_angle_alpha   88.231
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   378.227
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.137  0.909  0.146  1.0
  H  H1  1  0.863  0.909  0.146  1.0
  H  H2  1  0.000  0.737  0.242  1.0
  H  H3  1  0.000  0.610  0.593  1.0
  H  H4  1  0.000  0.836  0.680  1.0
  H  H5  1  0.000  0.605  0.772  1.0
  H  H6  1  0.500  0.113  0.916  1.0
  H  H7  1  0.500  0.334  0.821  1.0
  H  H8  1  0.500  0.108  0.736  1.0
  H  H9  1  0.500  0.380  0.413  1.0
  H  H10  1  0.500  0.399  0.233  1.0
  H  H11  1  0.500  0.168  0.317  1.0
  Cl  Cl12  1  0.500  0.681  0.935  1.0
  Cl  Cl13  1  0.500  0.814  0.422  1.0
  Cl  Cl14  1  0.000  0.297  0.075  1.0
  Cl  Cl15  1  0.000  0.184  0.572  1.0
  O  O16  1  0.500  0.542  0.817  1.0
  O  O17  1  0.500  0.958  0.299  1.0
  O  O18  1  0.000  0.427  0.193  1.0
  O  O19  1  0.000  0.037  0.693  1.0
  O  O20  1  0.500  0.579  0.074  1.0
  O  O21  1  0.500  0.912  0.557  1.0
  O  O22  1  0.000  0.402  0.938  1.0
  O  O23  1  0.000  0.088  0.437  1.0
  O  O24  1  0.298  0.801  0.920  1.0
  O  O25  1  0.703  0.694  0.409  1.0
  O  O26  1  0.796  0.171  0.084  1.0
  O  O27  1  0.202  0.304  0.588  1.0
  O  O28  1  0.204  0.171  0.084  1.0
  O  O29  1  0.798  0.304  0.588  1.0
  O  O30  1  0.702  0.801  0.920  1.0
  O  O31  1  0.297  0.694  0.409  1.0
  O  O32  1  0.000  0.824  0.157  1.0
  O  O33  1  0.000  0.682  0.681  1.0
  O  O34  1  0.500  0.183  0.823  1.0
  O  O35  1  0.500  0.317  0.321  1.0
[/CIF]
.
The material described by H3OClO4 is Indium-derived structured and crystallizes in the monoclinic Pm space group. The structure is zero-dimensional and consists of one hydrogen hydrate molecule, one hypochlorous acid;trihydrate molecule, and three H3OClO4 clusters. In each H3OClO4 cluster, there are two inequivalent H sites. In the first H site, H(3,5) is bonded in a single-bond geometry to one O(14) atom. In the second H site, H(4) is bonded in a linear geometry to one O(14) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(14) is bonded in a trigonal planar geometry to one H(4) and two equivalent H(3,5) atoms. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one H(4) and one Cl(4) atom. In the third O site, O(8) is bonded in a single-bond geometry to one Cl(4) atom. In the fourth O site, O(12) is bonded in a single-bond geometry to one Cl(4) atom. Cl(4) is bonded in a tetrahedral geometry to one O(4), one O(8), and two equivalent O(12) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_H3ClO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.857
_cell_length_b   6.951
_cell_length_c   9.295
_cell_angle_alpha   88.231
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   378.227
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.137  0.909  0.146  1.0
  H  H1  1  0.863  0.909  0.146  1.0
  H  H2  1  0.000  0.737  0.242  1.0
  H  H3  1  0.000  0.610  0.593  1.0
  H  H4  1  0.000  0.836  0.680  1.0
  H  H5  1  0.000  0.605  0.772  1.0
  H  H6  1  0.500  0.113  0.916  1.0
  H  H7  1  0.500  0.334  0.821  1.0
  H  H8  1  0.500  0.108  0.736  1.0
  H  H9  1  0.500  0.380  0.413  1.0
  H  H10  1  0.500  0.399  0.233  1.0
  H  H11  1  0.500  0.168  0.317  1.0
  Cl  Cl12  1  0.500  0.681  0.935  1.0
  Cl  Cl13  1  0.500  0.814  0.422  1.0
  Cl  Cl14  1  0.000  0.297  0.075  1.0
  Cl  Cl15  1  0.000  0.184  0.572  1.0
  O  O16  1  0.500  0.542  0.817  1.0
  O  O17  1  0.500  0.958  0.299  1.0
  O  O18  1  0.000  0.427  0.193  1.0
  O  O19  1  0.000  0.037  0.693  1.0
  O  O20  1  0.500  0.579  0.074  1.0
  O  O21  1  0.500  0.912  0.557  1.0
  O  O22  1  0.000  0.402  0.938  1.0
  O  O23  1  0.000  0.088  0.437  1.0
  O  O24  1  0.298  0.801  0.920  1.0
  O  O25  1  0.703  0.694  0.409  1.0
  O  O26  1  0.796  0.171  0.084  1.0
  O  O27  1  0.202  0.304  0.588  1.0
  O  O28  1  0.204  0.171  0.084  1.0
  O  O29  1  0.798  0.304  0.588  1.0
  O  O30  1  0.702  0.801  0.920  1.0
  O  O31  1  0.297  0.694  0.409  1.0
  O  O32  1  0.000  0.824  0.157  1.0
  O  O33  1  0.000  0.682  0.681  1.0
  O  O34  1  0.500  0.183  0.823  1.0
  O  O35  1  0.500  0.317  0.321  1.0
[/CIF]
.