The material described by FeCl4SCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tetrachloroferrat(iii) molecules and four SCl3 clusters. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(6) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_FeSCl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.153
_cell_length_b   6.461
_cell_length_c   13.896
_cell_angle_alpha   79.150
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1071.652
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.517  0.606  0.759  1.0
  Fe  Fe1  1  0.017  0.394  0.741  1.0
  Fe  Fe2  1  0.483  0.394  0.241  1.0
  Fe  Fe3  1  0.983  0.606  0.259  1.0
  S  S4  1  0.255  0.970  0.087  1.0
  S  S5  1  0.755  0.030  0.413  1.0
  S  S6  1  0.745  0.030  0.913  1.0
  S  S7  1  0.245  0.970  0.587  1.0
  Cl  Cl8  1  0.358  0.147  0.993  1.0
  Cl  Cl9  1  0.861  0.822  0.893  1.0
  Cl  Cl10  1  0.935  0.384  0.394  1.0
  Cl  Cl11  1  0.565  0.384  0.894  1.0
  Cl  Cl12  1  0.139  0.178  0.107  1.0
  Cl  Cl13  1  0.950  0.476  0.127  1.0
  Cl  Cl14  1  0.050  0.524  0.873  1.0
  Cl  Cl15  1  0.450  0.524  0.373  1.0
  Cl  Cl16  1  0.391  0.097  0.253  1.0
  Cl  Cl17  1  0.065  0.616  0.606  1.0
  Cl  Cl18  1  0.177  0.804  0.000  1.0
  Cl  Cl19  1  0.160  0.664  0.267  1.0
  Cl  Cl20  1  0.639  0.822  0.393  1.0
  Cl  Cl21  1  0.340  0.664  0.767  1.0
  Cl  Cl22  1  0.435  0.616  0.106  1.0
  Cl  Cl23  1  0.891  0.903  0.247  1.0
  Cl  Cl24  1  0.142  0.147  0.493  1.0
  Cl  Cl25  1  0.109  0.097  0.753  1.0
  Cl  Cl26  1  0.550  0.476  0.627  1.0
  Cl  Cl27  1  0.823  0.196  1.000  1.0
  Cl  Cl28  1  0.840  0.336  0.733  1.0
  Cl  Cl29  1  0.323  0.804  0.500  1.0
  Cl  Cl30  1  0.361  0.178  0.607  1.0
  Cl  Cl31  1  0.677  0.196  0.500  1.0
  Cl  Cl32  1  0.660  0.336  0.233  1.0
  Cl  Cl33  1  0.642  0.853  0.007  1.0
  Cl  Cl34  1  0.858  0.853  0.507  1.0
  Cl  Cl35  1  0.609  0.903  0.747  1.0
[/CIF]
.
The material described by FeCl4SCl3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four tetrachloroferrat(iii) molecules and four SCl3 clusters. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(1), one Cl(2), and one Cl(6) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(6) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_FeSCl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.153
_cell_length_b   6.461
_cell_length_c   13.896
_cell_angle_alpha   79.150
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1071.652
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.517  0.606  0.759  1.0
  Fe  Fe1  1  0.017  0.394  0.741  1.0
  Fe  Fe2  1  0.483  0.394  0.241  1.0
  Fe  Fe3  1  0.983  0.606  0.259  1.0
  S  S4  1  0.255  0.970  0.087  1.0
  S  S5  1  0.755  0.030  0.413  1.0
  S  S6  1  0.745  0.030  0.913  1.0
  S  S7  1  0.245  0.970  0.587  1.0
  Cl  Cl8  1  0.358  0.147  0.993  1.0
  Cl  Cl9  1  0.861  0.822  0.893  1.0
  Cl  Cl10  1  0.935  0.384  0.394  1.0
  Cl  Cl11  1  0.565  0.384  0.894  1.0
  Cl  Cl12  1  0.139  0.178  0.107  1.0
  Cl  Cl13  1  0.950  0.476  0.127  1.0
  Cl  Cl14  1  0.050  0.524  0.873  1.0
  Cl  Cl15  1  0.450  0.524  0.373  1.0
  Cl  Cl16  1  0.391  0.097  0.253  1.0
  Cl  Cl17  1  0.065  0.616  0.606  1.0
  Cl  Cl18  1  0.177  0.804  0.000  1.0
  Cl  Cl19  1  0.160  0.664  0.267  1.0
  Cl  Cl20  1  0.639  0.822  0.393  1.0
  Cl  Cl21  1  0.340  0.664  0.767  1.0
  Cl  Cl22  1  0.435  0.616  0.106  1.0
  Cl  Cl23  1  0.891  0.903  0.247  1.0
  Cl  Cl24  1  0.142  0.147  0.493  1.0
  Cl  Cl25  1  0.109  0.097  0.753  1.0
  Cl  Cl26  1  0.550  0.476  0.627  1.0
  Cl  Cl27  1  0.823  0.196  1.000  1.0
  Cl  Cl28  1  0.840  0.336  0.733  1.0
  Cl  Cl29  1  0.323  0.804  0.500  1.0
  Cl  Cl30  1  0.361  0.178  0.607  1.0
  Cl  Cl31  1  0.677  0.196  0.500  1.0
  Cl  Cl32  1  0.660  0.336  0.233  1.0
  Cl  Cl33  1  0.642  0.853  0.007  1.0
  Cl  Cl34  1  0.858  0.853  0.507  1.0
  Cl  Cl35  1  0.609  0.903  0.747  1.0
[/CIF]
.