The compound described by K2MgMo2P2(O5Cl)2 crystallizes in the monoclinic Cm space group. K(1) is bonded in a 2-coordinate geometry to one O(5), one O(6), and one Cl(2) atom. Mg(1) is bonded to one O(3), two equivalent O(1), one Cl(1), and one Cl(2) atom to form distorted MgCl2O3 trigonal bipyramids that share corners with two equivalent P(1)O4 tetrahedra. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(6), two equivalent O(1), two equivalent O(4), and one Cl(2) atom. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(3), two equivalent O(2), and two equivalent O(5) atoms. P(1) is bonded to one O(1), one O(2), one O(4), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Mg(1)Cl2O3 trigonal bipyramid. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mg(1), one Mo(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mo(2) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(2) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Mo(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one K(1), one Mo(2), and one P(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Mo(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 1-coordinate geometry to one Mg(1) atom. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to two equivalent K(1), one Mg(1), and one Mo(1) atom. is represented by the CIF card [CIF]
data_K2MgMo2P2(ClO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.662
_cell_length_b   6.662
_cell_length_c   7.558
_cell_angle_alpha   96.713
_cell_angle_beta   83.287
_cell_angle_gamma   87.890
_symmetry_Int_Tables_number   1
_cell_volume   330.411
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.601  0.270  0.571  1.0
  K  K1  1  0.230  0.899  0.571  1.0
  Mg  Mg2  1  0.946  0.554  0.264  1.0
  Mo  Mo3  1  0.264  0.236  0.079  1.0
  Mo  Mo4  1  0.779  0.721  0.903  1.0
  P  P5  1  0.261  0.737  0.995  1.0
  P  P6  1  0.763  0.239  0.995  1.0
  Cl  Cl7  1  0.774  0.726  0.545  1.0
  Cl  Cl8  1  0.163  0.337  0.439  1.0
  O  O9  1  0.224  0.566  0.119  1.0
  O  O10  1  0.793  0.032  0.879  1.0
  O  O11  1  0.468  0.707  0.879  1.0
  O  O12  1  0.771  0.729  0.146  1.0
  O  O13  1  0.566  0.256  0.128  1.0
  O  O14  1  0.934  0.276  0.119  1.0
  O  O15  1  0.771  0.401  0.863  1.0
  O  O16  1  0.099  0.729  0.863  1.0
  O  O17  1  0.310  0.190  0.836  1.0
  O  O18  1  0.244  0.934  0.128  1.0
[/CIF]
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The compound described by K2MgMo2P2(O5Cl)2 crystallizes in the monoclinic Cm space group. K(1) is bonded in a 2-coordinate geometry to one O(5), one O(6), and one Cl(2) atom. Mg(1) is bonded to one O(3), two equivalent O(1), one Cl(1), and one Cl(2) atom to form distorted MgCl2O3 trigonal bipyramids that share corners with two equivalent P(1)O4 tetrahedra. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 5-coordinate geometry to one O(6), two equivalent O(1), two equivalent O(4), and one Cl(2) atom. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(3), two equivalent O(2), and two equivalent O(5) atoms. P(1) is bonded to one O(1), one O(2), one O(4), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one Mg(1)Cl2O3 trigonal bipyramid. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mg(1), one Mo(1), and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mo(2) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mg(1) and one Mo(2) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Mo(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one K(1), one Mo(2), and one P(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to two equivalent K(1) and one Mo(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a 1-coordinate geometry to one Mg(1) atom. In the second Cl site, Cl(2) is bonded in a 4-coordinate geometry to two equivalent K(1), one Mg(1), and one Mo(1) atom. is represented by the CIF card [CIF]
data_K2MgMo2P2(ClO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.662
_cell_length_b   6.662
_cell_length_c   7.558
_cell_angle_alpha   96.713
_cell_angle_beta   83.287
_cell_angle_gamma   87.890
_symmetry_Int_Tables_number   1
_cell_volume   330.411
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.601  0.270  0.571  1.0
  K  K1  1  0.230  0.899  0.571  1.0
  Mg  Mg2  1  0.946  0.554  0.264  1.0
  Mo  Mo3  1  0.264  0.236  0.079  1.0
  Mo  Mo4  1  0.779  0.721  0.903  1.0
  P  P5  1  0.261  0.737  0.995  1.0
  P  P6  1  0.763  0.239  0.995  1.0
  Cl  Cl7  1  0.774  0.726  0.545  1.0
  Cl  Cl8  1  0.163  0.337  0.439  1.0
  O  O9  1  0.224  0.566  0.119  1.0
  O  O10  1  0.793  0.032  0.879  1.0
  O  O11  1  0.468  0.707  0.879  1.0
  O  O12  1  0.771  0.729  0.146  1.0
  O  O13  1  0.566  0.256  0.128  1.0
  O  O14  1  0.934  0.276  0.119  1.0
  O  O15  1  0.771  0.401  0.863  1.0
  O  O16  1  0.099  0.729  0.863  1.0
  O  O17  1  0.310  0.190  0.836  1.0
  O  O18  1  0.244  0.934  0.128  1.0
[/CIF]
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