The material described by ZnC2N4H8(OCl)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnC2N4H8(OCl)2 clusters. Zn(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one Cl(1), and one Cl(2) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one O(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(4), and one O(2) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one H(7), and one H(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(2), one H(5), and one H(6) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnH8C2N4(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.395
_cell_length_b   6.960
_cell_length_c   11.977
_cell_angle_alpha   88.614
_cell_angle_beta   103.917
_cell_angle_gamma   113.503
_symmetry_Int_Tables_number   1
_cell_volume   472.987
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.523  0.337  0.749  1.0
  Zn  Zn1  1  0.477  0.663  0.251  1.0
  H  H2  1  0.765  0.016  0.593  1.0
  H  H3  1  0.235  0.984  0.407  1.0
  H  H4  1  0.732  0.754  0.577  1.0
  H  H5  1  0.268  0.246  0.423  1.0
  H  H6  1  0.068  0.681  0.643  1.0
  H  H7  1  0.932  0.319  0.357  1.0
  H  H8  1  0.333  0.877  0.719  1.0
  H  H9  1  0.667  0.123  0.281  1.0
  H  H10  1  0.167  0.347  0.952  1.0
  H  H11  1  0.011  0.670  0.186  1.0
  H  H12  1  0.689  0.053  0.072  1.0
  H  H13  1  0.311  0.947  0.928  1.0
  H  H14  1  0.999  0.173  0.095  1.0
  H  H15  1  0.989  0.330  0.814  1.0
  H  H16  1  0.001  0.827  0.905  1.0
  H  H17  1  0.833  0.653  0.048  1.0
  C  C18  1  0.066  0.975  0.657  1.0
  C  C19  1  0.191  0.804  0.065  1.0
  C  C20  1  0.809  0.196  0.935  1.0
  C  C21  1  0.934  0.025  0.343  1.0
  N  N22  1  0.836  0.908  0.604  1.0
  N  N23  1  0.164  0.092  0.396  1.0
  N  N24  1  0.165  0.870  0.959  1.0
  N  N25  1  0.835  0.130  0.041  1.0
  N  N26  1  0.832  0.164  0.333  1.0
  N  N27  1  0.168  0.836  0.667  1.0
  N  N28  1  0.997  0.687  0.100  1.0
  N  N29  1  0.003  0.313  0.900  1.0
  Cl  Cl30  1  0.576  0.635  0.841  1.0
  Cl  Cl31  1  0.293  0.640  0.393  1.0
  Cl  Cl32  1  0.707  0.360  0.607  1.0
  Cl  Cl33  1  0.424  0.365  0.159  1.0
  O  O34  1  0.180  0.168  0.694  1.0
  O  O35  1  0.399  0.854  0.131  1.0
  O  O36  1  0.601  0.146  0.869  1.0
  O  O37  1  0.820  0.832  0.306  1.0
[/CIF]
.
The material described by ZnC2N4H8(OCl)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnC2N4H8(OCl)2 clusters. Zn(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one Cl(1), and one Cl(2) atom. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one O(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(4), and one O(2) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one H(7), and one H(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(2), one H(5), and one H(6) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnH8C2N4(ClO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.395
_cell_length_b   6.960
_cell_length_c   11.977
_cell_angle_alpha   88.614
_cell_angle_beta   103.917
_cell_angle_gamma   113.503
_symmetry_Int_Tables_number   1
_cell_volume   472.987
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.523  0.337  0.749  1.0
  Zn  Zn1  1  0.477  0.663  0.251  1.0
  H  H2  1  0.765  0.016  0.593  1.0
  H  H3  1  0.235  0.984  0.407  1.0
  H  H4  1  0.732  0.754  0.577  1.0
  H  H5  1  0.268  0.246  0.423  1.0
  H  H6  1  0.068  0.681  0.643  1.0
  H  H7  1  0.932  0.319  0.357  1.0
  H  H8  1  0.333  0.877  0.719  1.0
  H  H9  1  0.667  0.123  0.281  1.0
  H  H10  1  0.167  0.347  0.952  1.0
  H  H11  1  0.011  0.670  0.186  1.0
  H  H12  1  0.689  0.053  0.072  1.0
  H  H13  1  0.311  0.947  0.928  1.0
  H  H14  1  0.999  0.173  0.095  1.0
  H  H15  1  0.989  0.330  0.814  1.0
  H  H16  1  0.001  0.827  0.905  1.0
  H  H17  1  0.833  0.653  0.048  1.0
  C  C18  1  0.066  0.975  0.657  1.0
  C  C19  1  0.191  0.804  0.065  1.0
  C  C20  1  0.809  0.196  0.935  1.0
  C  C21  1  0.934  0.025  0.343  1.0
  N  N22  1  0.836  0.908  0.604  1.0
  N  N23  1  0.164  0.092  0.396  1.0
  N  N24  1  0.165  0.870  0.959  1.0
  N  N25  1  0.835  0.130  0.041  1.0
  N  N26  1  0.832  0.164  0.333  1.0
  N  N27  1  0.168  0.836  0.667  1.0
  N  N28  1  0.997  0.687  0.100  1.0
  N  N29  1  0.003  0.313  0.900  1.0
  Cl  Cl30  1  0.576  0.635  0.841  1.0
  Cl  Cl31  1  0.293  0.640  0.393  1.0
  Cl  Cl32  1  0.707  0.360  0.607  1.0
  Cl  Cl33  1  0.424  0.365  0.159  1.0
  O  O34  1  0.180  0.168  0.694  1.0
  O  O35  1  0.399  0.854  0.131  1.0
  O  O36  1  0.601  0.146  0.869  1.0
  O  O37  1  0.820  0.832  0.306  1.0
[/CIF]
.