The crystal structure described by MnH8(SO6)2(CN3H6)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two guanidinium molecules and one MnH8(SO6)2 cluster. In the MnH8(SO6)2 cluster, Mn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent S(1)O4 tetrahedra. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. S(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form SO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 31°. There are six inequivalent O sites. In the first O site, O(2) is bonded in a distorted water-like geometry to one Mn(1), one H(3), and one H(4) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(5) is bonded in a bent 150 degrees geometry to one Mn(1) and one S(1) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(1) is bonded in a distorted water-like geometry to one Mn(1), one H(1), and one H(2) atom. is represented by the CIF card [CIF]
data_MnH20C2S2(NO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.444
_cell_length_b   6.477
_cell_length_c   10.144
_cell_angle_alpha   89.633
_cell_angle_beta   95.972
_cell_angle_gamma   109.558
_symmetry_Int_Tables_number   1
_cell_volume   396.629
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.500  0.500  0.500  1.0
  H  H1  1  0.676  0.931  0.612  1.0
  H  H2  1  0.324  0.069  0.388  1.0
  H  H3  1  0.414  0.871  0.611  1.0
  H  H4  1  0.586  0.129  0.389  1.0
  H  H5  1  0.883  0.409  0.628  1.0
  H  H6  1  0.117  0.591  0.372  1.0
  H  H7  1  0.946  0.670  0.622  1.0
  H  H8  1  0.054  0.330  0.378  1.0
  H  H9  1  0.808  0.172  0.844  1.0
  H  H10  1  0.192  0.828  0.156  1.0
  H  H11  1  0.760  0.036  0.994  1.0
  H  H12  1  0.240  0.964  0.006  1.0
  H  H13  1  0.683  0.456  0.171  1.0
  H  H14  1  0.317  0.544  0.829  1.0
  H  H15  1  0.724  0.203  0.179  1.0
  H  H16  1  0.276  0.797  0.821  1.0
  H  H17  1  0.746  0.521  0.828  1.0
  H  H18  1  0.254  0.479  0.172  1.0
  H  H19  1  0.747  0.651  0.982  1.0
  H  H20  1  0.253  0.349  0.018  1.0
  C  C21  1  0.731  0.335  0.994  1.0
  C  C22  1  0.269  0.665  0.006  1.0
  S  S23  1  0.838  0.859  0.284  1.0
  S  S24  1  0.162  0.141  0.716  1.0
  N  N25  1  0.746  0.159  0.934  1.0
  N  N26  1  0.254  0.841  0.066  1.0
  N  N27  1  0.701  0.327  0.123  1.0
  N  N28  1  0.299  0.673  0.877  1.0
  N  N29  1  0.738  0.515  0.928  1.0
  N  N30  1  0.262  0.485  0.072  1.0
  O  O31  1  0.532  0.811  0.595  1.0
  O  O32  1  0.468  0.189  0.405  1.0
  O  O33  1  0.821  0.530  0.622  1.0
  O  O34  1  0.179  0.470  0.378  1.0
  O  O35  1  0.795  0.855  0.137  1.0
  O  O36  1  0.205  0.145  0.863  1.0
  O  O37  1  0.824  0.066  0.341  1.0
  O  O38  1  0.176  0.934  0.659  1.0
  O  O39  1  0.671  0.663  0.334  1.0
  O  O40  1  0.329  0.337  0.666  1.0
  O  O41  1  0.065  0.846  0.322  1.0
  O  O42  1  0.935  0.154  0.678  1.0
[/CIF]
.
The crystal structure described by MnH8(SO6)2(CN3H6)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two guanidinium molecules and one MnH8(SO6)2 cluster. In the MnH8(SO6)2 cluster, Mn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with two equivalent S(1)O4 tetrahedra. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(2) atom. S(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form SO4 tetrahedra that share  a cornercorner with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 31°. There are six inequivalent O sites. In the first O site, O(2) is bonded in a distorted water-like geometry to one Mn(1), one H(3), and one H(4) atom. In the second O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(5) is bonded in a bent 150 degrees geometry to one Mn(1) and one S(1) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(1) is bonded in a distorted water-like geometry to one Mn(1), one H(1), and one H(2) atom. is represented by the CIF card [CIF]
data_MnH20C2S2(NO2)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.444
_cell_length_b   6.477
_cell_length_c   10.144
_cell_angle_alpha   89.633
_cell_angle_beta   95.972
_cell_angle_gamma   109.558
_symmetry_Int_Tables_number   1
_cell_volume   396.629
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.500  0.500  0.500  1.0
  H  H1  1  0.676  0.931  0.612  1.0
  H  H2  1  0.324  0.069  0.388  1.0
  H  H3  1  0.414  0.871  0.611  1.0
  H  H4  1  0.586  0.129  0.389  1.0
  H  H5  1  0.883  0.409  0.628  1.0
  H  H6  1  0.117  0.591  0.372  1.0
  H  H7  1  0.946  0.670  0.622  1.0
  H  H8  1  0.054  0.330  0.378  1.0
  H  H9  1  0.808  0.172  0.844  1.0
  H  H10  1  0.192  0.828  0.156  1.0
  H  H11  1  0.760  0.036  0.994  1.0
  H  H12  1  0.240  0.964  0.006  1.0
  H  H13  1  0.683  0.456  0.171  1.0
  H  H14  1  0.317  0.544  0.829  1.0
  H  H15  1  0.724  0.203  0.179  1.0
  H  H16  1  0.276  0.797  0.821  1.0
  H  H17  1  0.746  0.521  0.828  1.0
  H  H18  1  0.254  0.479  0.172  1.0
  H  H19  1  0.747  0.651  0.982  1.0
  H  H20  1  0.253  0.349  0.018  1.0
  C  C21  1  0.731  0.335  0.994  1.0
  C  C22  1  0.269  0.665  0.006  1.0
  S  S23  1  0.838  0.859  0.284  1.0
  S  S24  1  0.162  0.141  0.716  1.0
  N  N25  1  0.746  0.159  0.934  1.0
  N  N26  1  0.254  0.841  0.066  1.0
  N  N27  1  0.701  0.327  0.123  1.0
  N  N28  1  0.299  0.673  0.877  1.0
  N  N29  1  0.738  0.515  0.928  1.0
  N  N30  1  0.262  0.485  0.072  1.0
  O  O31  1  0.532  0.811  0.595  1.0
  O  O32  1  0.468  0.189  0.405  1.0
  O  O33  1  0.821  0.530  0.622  1.0
  O  O34  1  0.179  0.470  0.378  1.0
  O  O35  1  0.795  0.855  0.137  1.0
  O  O36  1  0.205  0.145  0.863  1.0
  O  O37  1  0.824  0.066  0.341  1.0
  O  O38  1  0.176  0.934  0.659  1.0
  O  O39  1  0.671  0.663  0.334  1.0
  O  O40  1  0.329  0.337  0.666  1.0
  O  O41  1  0.065  0.846  0.322  1.0
  O  O42  1  0.935  0.154  0.678  1.0
[/CIF]
.