The crystal structure described by Re3O10 crystallizes in the monoclinic C2 space group. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one O(2), one O(3), one O(4), and two equivalent O(1) atoms to form corner-sharing ReO5 square pyramids. In the second Re site, Re(2) is bonded in a 6-coordinate geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to two equivalent Re(1) atoms. In the second O site, O(2) is bonded in a linear geometry to two equivalent Re(1) atoms. In the third O site, O(3) is bonded in a linear geometry to two equivalent Re(1) atoms. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Re(1) and one Re(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Re(2) and one O(6) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Re(2) and one O(5) atom. is represented by the CIF card [CIF]
data_Re3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.298
_cell_length_b   5.298
_cell_length_c   8.401
_cell_angle_alpha   74.102
_cell_angle_beta   74.102
_cell_angle_gamma   90.252
_symmetry_Int_Tables_number   1
_cell_volume   217.295
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.018  0.513  0.964  1.0
  Re  Re1  1  0.487  0.982  0.036  1.0
  Re  Re2  1  0.166  0.834  0.500  1.0
  O  O3  1  0.753  0.748  0.997  1.0
  O  O4  1  0.252  0.247  0.003  1.0
  O  O5  1  0.252  0.748  0.000  1.0
  O  O6  1  0.751  0.249  0.000  1.0
  O  O7  1  0.127  0.616  0.721  1.0
  O  O8  1  0.384  0.873  0.279  1.0
  O  O9  1  0.141  0.171  0.540  1.0
  O  O10  1  0.403  0.094  0.539  1.0
  O  O11  1  0.906  0.597  0.461  1.0
  O  O12  1  0.829  0.859  0.460  1.0
[/CIF]
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The crystal structure described by Re3O10 crystallizes in the monoclinic C2 space group. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded to one O(2), one O(3), one O(4), and two equivalent O(1) atoms to form corner-sharing ReO5 square pyramids. In the second Re site, Re(2) is bonded in a 6-coordinate geometry to two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to two equivalent Re(1) atoms. In the second O site, O(2) is bonded in a linear geometry to two equivalent Re(1) atoms. In the third O site, O(3) is bonded in a linear geometry to two equivalent Re(1) atoms. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Re(1) and one Re(2) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Re(2) and one O(6) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Re(2) and one O(5) atom. is represented by the CIF card [CIF]
data_Re3O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.298
_cell_length_b   5.298
_cell_length_c   8.401
_cell_angle_alpha   74.102
_cell_angle_beta   74.102
_cell_angle_gamma   90.252
_symmetry_Int_Tables_number   1
_cell_volume   217.295
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.018  0.513  0.964  1.0
  Re  Re1  1  0.487  0.982  0.036  1.0
  Re  Re2  1  0.166  0.834  0.500  1.0
  O  O3  1  0.753  0.748  0.997  1.0
  O  O4  1  0.252  0.247  0.003  1.0
  O  O5  1  0.252  0.748  0.000  1.0
  O  O6  1  0.751  0.249  0.000  1.0
  O  O7  1  0.127  0.616  0.721  1.0
  O  O8  1  0.384  0.873  0.279  1.0
  O  O9  1  0.141  0.171  0.540  1.0
  O  O10  1  0.403  0.094  0.539  1.0
  O  O11  1  0.906  0.597  0.461  1.0
  O  O12  1  0.829  0.859  0.460  1.0
[/CIF]
.