The compound described by PdAg2Cl4 crystallizes in the orthorhombic Cmce space group. Pd(1) is bonded in a square co-planar geometry to two equivalent Cl(1) and two equivalent Cl(2) atoms. Ag(1) is bonded to two equivalent Cl(1) and four equivalent Cl(2) atoms to form a mixture of distorted corner and edge-sharing AgCl6 octahedra. The corner-sharing octahedral tilt angles range from 7-34°. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1) and two equivalent Ag(1) atoms. In the second Cl site, Cl(2) is bonded to one Pd(1) and four equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing ClAg4Pd square pyramids. is represented by the CIF card [CIF]
data_Ag2PdCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.459
_cell_length_b   6.459
_cell_length_c   8.101
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   101.594
_symmetry_Int_Tables_number   1
_cell_volume   331.053
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.529  0.029  0.750  1.0
  Ag  Ag1  1  0.971  0.471  0.250  1.0
  Ag  Ag2  1  0.029  0.529  0.750  1.0
  Ag  Ag3  1  0.471  0.971  0.250  1.0
  Pd  Pd4  1  0.000  0.000  0.000  1.0
  Pd  Pd5  1  0.500  0.500  0.500  1.0
  Cl  Cl6  1  0.195  0.195  0.793  1.0
  Cl  Cl7  1  0.305  0.305  0.293  1.0
  Cl  Cl8  1  0.695  0.695  0.707  1.0
  Cl  Cl9  1  0.805  0.805  0.207  1.0
  Cl  Cl10  1  0.268  0.732  0.500  1.0
  Cl  Cl11  1  0.232  0.768  0.000  1.0
  Cl  Cl12  1  0.768  0.232  0.000  1.0
  Cl  Cl13  1  0.732  0.268  0.500  1.0
[/CIF]
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The compound described by PdAg2Cl4 crystallizes in the orthorhombic Cmce space group. Pd(1) is bonded in a square co-planar geometry to two equivalent Cl(1) and two equivalent Cl(2) atoms. Ag(1) is bonded to two equivalent Cl(1) and four equivalent Cl(2) atoms to form a mixture of distorted corner and edge-sharing AgCl6 octahedra. The corner-sharing octahedral tilt angles range from 7-34°. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1) and two equivalent Ag(1) atoms. In the second Cl site, Cl(2) is bonded to one Pd(1) and four equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing ClAg4Pd square pyramids. is represented by the CIF card [CIF]
data_Ag2PdCl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.459
_cell_length_b   6.459
_cell_length_c   8.101
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   101.594
_symmetry_Int_Tables_number   1
_cell_volume   331.053
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.529  0.029  0.750  1.0
  Ag  Ag1  1  0.971  0.471  0.250  1.0
  Ag  Ag2  1  0.029  0.529  0.750  1.0
  Ag  Ag3  1  0.471  0.971  0.250  1.0
  Pd  Pd4  1  0.000  0.000  0.000  1.0
  Pd  Pd5  1  0.500  0.500  0.500  1.0
  Cl  Cl6  1  0.195  0.195  0.793  1.0
  Cl  Cl7  1  0.305  0.305  0.293  1.0
  Cl  Cl8  1  0.695  0.695  0.707  1.0
  Cl  Cl9  1  0.805  0.805  0.207  1.0
  Cl  Cl10  1  0.268  0.732  0.500  1.0
  Cl  Cl11  1  0.232  0.768  0.000  1.0
  Cl  Cl12  1  0.768  0.232  0.000  1.0
  Cl  Cl13  1  0.732  0.268  0.500  1.0
[/CIF]
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