The material structure described by KC(NO2)3 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 11-coordinate geometry to one O(6), two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one O(4), and one O(5) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one O(1), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a single-bond geometry to one K(1) and one N(3) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(3) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the sixth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. is represented by the CIF card [CIF]
data_KC(NO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.366
_cell_length_b   7.778
_cell_length_c   11.199
_cell_angle_alpha   55.677
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   601.821
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.605  0.114  0.134  1.0
  K  K1  1  0.395  0.886  0.866  1.0
  K  K2  1  0.105  0.886  0.366  1.0
  K  K3  1  0.895  0.114  0.634  1.0
  C  C4  1  0.879  0.589  0.122  1.0
  C  C5  1  0.379  0.411  0.378  1.0
  C  C6  1  0.121  0.411  0.878  1.0
  C  C7  1  0.621  0.589  0.622  1.0
  N  N8  1  0.266  0.332  0.490  1.0
  N  N9  1  0.429  0.620  0.299  1.0
  N  N10  1  0.234  0.332  0.990  1.0
  N  N11  1  0.571  0.380  0.701  1.0
  N  N12  1  0.547  0.724  0.654  1.0
  N  N13  1  0.071  0.620  0.799  1.0
  N  N14  1  0.047  0.276  0.846  1.0
  N  N15  1  0.929  0.380  0.201  1.0
  N  N16  1  0.766  0.668  0.010  1.0
  N  N17  1  0.734  0.668  0.510  1.0
  N  N18  1  0.953  0.724  0.154  1.0
  N  N19  1  0.453  0.276  0.346  1.0
  O  O20  1  0.872  0.862  0.149  1.0
  O  O21  1  0.128  0.138  0.851  1.0
  O  O22  1  0.628  0.862  0.649  1.0
  O  O23  1  0.752  0.862  0.430  1.0
  O  O24  1  0.185  0.453  0.506  1.0
  O  O25  1  0.815  0.547  0.494  1.0
  O  O26  1  0.012  0.698  0.676  1.0
  O  O27  1  0.414  0.724  0.353  1.0
  O  O28  1  0.315  0.453  0.006  1.0
  O  O29  1  0.252  0.138  0.070  1.0
  O  O30  1  0.248  0.138  0.570  1.0
  O  O31  1  0.586  0.276  0.647  1.0
  O  O32  1  0.512  0.302  0.824  1.0
  O  O33  1  0.086  0.724  0.853  1.0
  O  O34  1  0.372  0.138  0.351  1.0
  O  O35  1  0.988  0.302  0.324  1.0
  O  O36  1  0.598  0.305  0.313  1.0
  O  O37  1  0.748  0.862  0.930  1.0
  O  O38  1  0.685  0.547  0.994  1.0
  O  O39  1  0.902  0.305  0.813  1.0
  O  O40  1  0.488  0.698  0.176  1.0
  O  O41  1  0.914  0.276  0.147  1.0
  O  O42  1  0.098  0.695  0.187  1.0
  O  O43  1  0.402  0.695  0.687  1.0
[/CIF]
.
The material structure described by KC(NO2)3 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 11-coordinate geometry to one O(6), two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one O(2), and one O(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one O(4), and one O(5) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one O(1), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a single-bond geometry to one K(1) and one N(3) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(3) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. In the sixth O site, O(5) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(2) atom. is represented by the CIF card [CIF]
data_KC(NO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.366
_cell_length_b   7.778
_cell_length_c   11.199
_cell_angle_alpha   55.677
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   601.821
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.605  0.114  0.134  1.0
  K  K1  1  0.395  0.886  0.866  1.0
  K  K2  1  0.105  0.886  0.366  1.0
  K  K3  1  0.895  0.114  0.634  1.0
  C  C4  1  0.879  0.589  0.122  1.0
  C  C5  1  0.379  0.411  0.378  1.0
  C  C6  1  0.121  0.411  0.878  1.0
  C  C7  1  0.621  0.589  0.622  1.0
  N  N8  1  0.266  0.332  0.490  1.0
  N  N9  1  0.429  0.620  0.299  1.0
  N  N10  1  0.234  0.332  0.990  1.0
  N  N11  1  0.571  0.380  0.701  1.0
  N  N12  1  0.547  0.724  0.654  1.0
  N  N13  1  0.071  0.620  0.799  1.0
  N  N14  1  0.047  0.276  0.846  1.0
  N  N15  1  0.929  0.380  0.201  1.0
  N  N16  1  0.766  0.668  0.010  1.0
  N  N17  1  0.734  0.668  0.510  1.0
  N  N18  1  0.953  0.724  0.154  1.0
  N  N19  1  0.453  0.276  0.346  1.0
  O  O20  1  0.872  0.862  0.149  1.0
  O  O21  1  0.128  0.138  0.851  1.0
  O  O22  1  0.628  0.862  0.649  1.0
  O  O23  1  0.752  0.862  0.430  1.0
  O  O24  1  0.185  0.453  0.506  1.0
  O  O25  1  0.815  0.547  0.494  1.0
  O  O26  1  0.012  0.698  0.676  1.0
  O  O27  1  0.414  0.724  0.353  1.0
  O  O28  1  0.315  0.453  0.006  1.0
  O  O29  1  0.252  0.138  0.070  1.0
  O  O30  1  0.248  0.138  0.570  1.0
  O  O31  1  0.586  0.276  0.647  1.0
  O  O32  1  0.512  0.302  0.824  1.0
  O  O33  1  0.086  0.724  0.853  1.0
  O  O34  1  0.372  0.138  0.351  1.0
  O  O35  1  0.988  0.302  0.324  1.0
  O  O36  1  0.598  0.305  0.313  1.0
  O  O37  1  0.748  0.862  0.930  1.0
  O  O38  1  0.685  0.547  0.994  1.0
  O  O39  1  0.902  0.305  0.813  1.0
  O  O40  1  0.488  0.698  0.176  1.0
  O  O41  1  0.914  0.276  0.147  1.0
  O  O42  1  0.098  0.695  0.187  1.0
  O  O43  1  0.402  0.695  0.687  1.0
[/CIF]
.