The crystal structure described by Co(IO3)2 crystallizes in the monoclinic P2_1 space group. Co(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one I(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one I(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Co(1) and one I(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(2) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(4), one O(5), and one O(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(IO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.020
_cell_length_b   5.500
_cell_length_c   9.429
_cell_angle_alpha   89.792
_cell_angle_beta   89.999
_cell_angle_gamma   89.996
_symmetry_Int_Tables_number   1
_cell_volume   260.287
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.566  0.017  0.996  1.0
  Co  Co1  1  0.066  0.482  0.504  1.0
  I  I2  1  0.983  0.517  0.848  1.0
  I  I3  1  0.483  0.983  0.652  1.0
  I  I4  1  0.005  0.988  0.318  1.0
  I  I5  1  0.505  0.512  0.182  1.0
  O  O6  1  0.792  0.800  0.854  1.0
  O  O7  1  0.292  0.700  0.646  1.0
  O  O8  1  0.782  0.339  0.973  1.0
  O  O9  1  0.282  0.160  0.527  1.0
  O  O10  1  0.352  0.102  0.818  1.0
  O  O11  1  0.852  0.398  0.682  1.0
  O  O12  1  0.833  0.264  0.373  1.0
  O  O13  1  0.333  0.235  0.127  1.0
  O  O14  1  0.846  0.783  0.446  1.0
  O  O15  1  0.346  0.716  0.054  1.0
  O  O16  1  0.288  0.588  0.331  1.0
  O  O17  1  0.788  0.911  0.169  1.0
[/CIF]
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The crystal structure described by Co(IO3)2 crystallizes in the monoclinic P2_1 space group. Co(1) is bonded in an octahedral geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one I(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one I(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Co(1) and one I(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one I(2) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(4), one O(5), and one O(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Co(IO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.020
_cell_length_b   5.500
_cell_length_c   9.429
_cell_angle_alpha   89.792
_cell_angle_beta   89.999
_cell_angle_gamma   89.996
_symmetry_Int_Tables_number   1
_cell_volume   260.287
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.566  0.017  0.996  1.0
  Co  Co1  1  0.066  0.482  0.504  1.0
  I  I2  1  0.983  0.517  0.848  1.0
  I  I3  1  0.483  0.983  0.652  1.0
  I  I4  1  0.005  0.988  0.318  1.0
  I  I5  1  0.505  0.512  0.182  1.0
  O  O6  1  0.792  0.800  0.854  1.0
  O  O7  1  0.292  0.700  0.646  1.0
  O  O8  1  0.782  0.339  0.973  1.0
  O  O9  1  0.282  0.160  0.527  1.0
  O  O10  1  0.352  0.102  0.818  1.0
  O  O11  1  0.852  0.398  0.682  1.0
  O  O12  1  0.833  0.264  0.373  1.0
  O  O13  1  0.333  0.235  0.127  1.0
  O  O14  1  0.846  0.783  0.446  1.0
  O  O15  1  0.346  0.716  0.054  1.0
  O  O16  1  0.288  0.588  0.331  1.0
  O  O17  1  0.788  0.911  0.169  1.0
[/CIF]
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