The crystal structure described by (NaHCO3)2CuH2(CO)2(CuCHO2)2(CHO)2O2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one copper;methanol molecule, two meoh h2 molecules, two sodium;formic acid;hydroxide molecules, two water atoms, and one CuCHO2 cluster. In the CuCHO2 cluster, Cu(2) is bonded in a 3-coordinate geometry to one C(3), one O(6), and one O(7) atom. C(3) is bonded in a 4-coordinate geometry to one Cu(2), one H(2), one O(6), and one O(7) atom. H(2) is bonded in an L-shaped geometry to one C(3) and one O(6) atom. There are two inequivalent O sites. In the first O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Cu(2) and one C(3) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Cu(2), one C(3), and one H(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na2Cu3H8(CO2)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.832
_cell_length_b   8.041
_cell_length_c   9.044
_cell_angle_alpha   113.682
_cell_angle_beta   108.657
_cell_angle_gamma   97.531
_symmetry_Int_Tables_number   1
_cell_volume   471.540
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.480  0.248  0.479  1.0
  Na  Na1  1  0.520  0.752  0.521  1.0
  Cu  Cu2  1  0.500  0.500  0.000  1.0
  Cu  Cu3  1  0.807  0.456  0.580  1.0
  Cu  Cu4  1  0.193  0.544  0.420  1.0
  H  H5  1  0.056  0.992  0.246  1.0
  H  H6  1  0.944  0.008  0.754  1.0
  H  H7  1  0.009  0.628  0.832  1.0
  H  H8  1  0.991  0.372  0.168  1.0
  H  H9  1  0.218  0.190  0.875  1.0
  H  H10  1  0.782  0.810  0.125  1.0
  H  H11  1  0.397  0.864  0.935  1.0
  H  H12  1  0.603  0.136  0.065  1.0
  C  C13  1  0.414  0.835  0.823  1.0
  C  C14  1  0.586  0.165  0.177  1.0
  C  C15  1  0.036  0.842  0.322  1.0
  C  C16  1  0.964  0.158  0.678  1.0
  C  C17  1  0.005  0.586  0.733  1.0
  C  C18  1  0.995  0.414  0.267  1.0
  C  C19  1  0.351  0.293  0.847  1.0
  C  C20  1  0.649  0.707  0.153  1.0
  O  O21  1  0.530  0.307  0.183  1.0
  O  O22  1  0.470  0.693  0.817  1.0
  O  O23  1  0.196  0.804  0.289  1.0
  O  O24  1  0.804  0.196  0.711  1.0
  O  O25  1  0.378  0.938  0.709  1.0
  O  O26  1  0.622  0.062  0.291  1.0
  O  O27  1  0.857  0.732  0.431  1.0
  O  O28  1  0.143  0.268  0.569  1.0
  O  O29  1  0.491  0.381  0.688  1.0
  O  O30  1  0.509  0.619  0.312  1.0
  O  O31  1  0.835  0.525  0.754  1.0
  O  O32  1  0.165  0.475  0.246  1.0
  O  O33  1  0.827  0.395  0.387  1.0
  O  O34  1  0.173  0.605  0.613  1.0
  O  O35  1  0.339  0.305  0.983  1.0
  O  O36  1  0.661  0.695  0.017  1.0
[/CIF]
.
The crystal structure described by (NaHCO3)2CuH2(CO)2(CuCHO2)2(CHO)2O2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one copper;methanol molecule, two meoh h2 molecules, two sodium;formic acid;hydroxide molecules, two water atoms, and one CuCHO2 cluster. In the CuCHO2 cluster, Cu(2) is bonded in a 3-coordinate geometry to one C(3), one O(6), and one O(7) atom. C(3) is bonded in a 4-coordinate geometry to one Cu(2), one H(2), one O(6), and one O(7) atom. H(2) is bonded in an L-shaped geometry to one C(3) and one O(6) atom. There are two inequivalent O sites. In the first O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Cu(2) and one C(3) atom. In the second O site, O(6) is bonded in a 3-coordinate geometry to one Cu(2), one C(3), and one H(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na2Cu3H8(CO2)8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.832
_cell_length_b   8.041
_cell_length_c   9.044
_cell_angle_alpha   113.682
_cell_angle_beta   108.657
_cell_angle_gamma   97.531
_symmetry_Int_Tables_number   1
_cell_volume   471.540
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.480  0.248  0.479  1.0
  Na  Na1  1  0.520  0.752  0.521  1.0
  Cu  Cu2  1  0.500  0.500  0.000  1.0
  Cu  Cu3  1  0.807  0.456  0.580  1.0
  Cu  Cu4  1  0.193  0.544  0.420  1.0
  H  H5  1  0.056  0.992  0.246  1.0
  H  H6  1  0.944  0.008  0.754  1.0
  H  H7  1  0.009  0.628  0.832  1.0
  H  H8  1  0.991  0.372  0.168  1.0
  H  H9  1  0.218  0.190  0.875  1.0
  H  H10  1  0.782  0.810  0.125  1.0
  H  H11  1  0.397  0.864  0.935  1.0
  H  H12  1  0.603  0.136  0.065  1.0
  C  C13  1  0.414  0.835  0.823  1.0
  C  C14  1  0.586  0.165  0.177  1.0
  C  C15  1  0.036  0.842  0.322  1.0
  C  C16  1  0.964  0.158  0.678  1.0
  C  C17  1  0.005  0.586  0.733  1.0
  C  C18  1  0.995  0.414  0.267  1.0
  C  C19  1  0.351  0.293  0.847  1.0
  C  C20  1  0.649  0.707  0.153  1.0
  O  O21  1  0.530  0.307  0.183  1.0
  O  O22  1  0.470  0.693  0.817  1.0
  O  O23  1  0.196  0.804  0.289  1.0
  O  O24  1  0.804  0.196  0.711  1.0
  O  O25  1  0.378  0.938  0.709  1.0
  O  O26  1  0.622  0.062  0.291  1.0
  O  O27  1  0.857  0.732  0.431  1.0
  O  O28  1  0.143  0.268  0.569  1.0
  O  O29  1  0.491  0.381  0.688  1.0
  O  O30  1  0.509  0.619  0.312  1.0
  O  O31  1  0.835  0.525  0.754  1.0
  O  O32  1  0.165  0.475  0.246  1.0
  O  O33  1  0.827  0.395  0.387  1.0
  O  O34  1  0.173  0.605  0.613  1.0
  O  O35  1  0.339  0.305  0.983  1.0
  O  O36  1  0.661  0.695  0.017  1.0
[/CIF]
.