The structure described by Mo3Ag3AsO13 crystallizes in the triclinic P-1 space group. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(11), one O(12), one O(2), one O(3), one O(5), and one O(8) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(1), one O(12), one O(13), one O(5), one O(7), and one O(9) atom. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(10), one O(3), one O(6), one O(9), and two equivalent O(8) atoms. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(10), one O(11), one O(2), and one O(4) atom. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one O(11), one O(12), one O(13), and two equivalent O(4) atoms. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(6), and one O(7) atom. As(1) is bonded in a tetrahedral geometry to one O(4), one O(5), one O(6), and one O(7) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Mo(2) and one Ag(3) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mo(1), one Ag(1), and one Ag(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(3), and one Ag(3) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Ag(1), two equivalent Ag(2), and one As(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one As(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mo(3), one Ag(3), and one As(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Mo(2), one Ag(3), and one As(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Mo(1) and two equivalent Mo(3) atoms. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mo(2) and one Mo(3) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Mo(3) and one Ag(1) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Mo(1), one Ag(1), and one Ag(2) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Mo(1), one Mo(2), and one Ag(2) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Mo(2) and one Ag(2) atom. is represented by the CIF file [CIF]
data_Ag3Mo3AsO13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.185
_cell_length_b   8.370
_cell_length_c   9.865
_cell_angle_alpha   113.871
_cell_angle_beta   99.028
_cell_angle_gamma   105.651
_symmetry_Int_Tables_number   1
_cell_volume   567.288
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.391  0.654  0.420  1.0
  Ag  Ag1  1  0.609  0.346  0.580  1.0
  Ag  Ag2  1  0.090  0.349  0.558  1.0
  Ag  Ag3  1  0.910  0.651  0.442  1.0
  Ag  Ag4  1  0.256  0.530  0.035  1.0
  Ag  Ag5  1  0.744  0.470  0.965  1.0
  Mo  Mo6  1  0.302  0.089  0.756  1.0
  Mo  Mo7  1  0.698  0.911  0.244  1.0
  Mo  Mo8  1  0.117  0.943  0.232  1.0
  Mo  Mo9  1  0.883  0.057  0.768  1.0
  Mo  Mo10  1  0.487  0.210  0.142  1.0
  Mo  Mo11  1  0.513  0.790  0.858  1.0
  As  As12  1  0.947  0.277  0.169  1.0
  As  As13  1  0.053  0.723  0.831  1.0
  O  O14  1  0.218  0.788  0.243  1.0
  O  O15  1  0.782  0.212  0.757  1.0
  O  O16  1  0.461  0.262  0.737  1.0
  O  O17  1  0.539  0.738  0.263  1.0
  O  O18  1  0.409  0.316  0.031  1.0
  O  O19  1  0.591  0.684  0.969  1.0
  O  O20  1  0.081  0.461  0.346  1.0
  O  O21  1  0.919  0.539  0.654  1.0
  O  O22  1  0.915  0.067  0.177  1.0
  O  O23  1  0.085  0.933  0.823  1.0
  O  O24  1  0.748  0.315  0.131  1.0
  O  O25  1  0.252  0.685  0.869  1.0
  O  O26  1  0.030  0.268  0.018  1.0
  O  O27  1  0.970  0.732  0.982  1.0
  O  O28  1  0.442  0.008  0.877  1.0
  O  O29  1  0.558  0.992  0.123  1.0
  O  O30  1  0.262  0.066  0.137  1.0
  O  O31  1  0.738  0.934  0.863  1.0
  O  O32  1  0.558  0.376  0.341  1.0
  O  O33  1  0.442  0.624  0.659  1.0
  O  O34  1  0.765  0.111  0.424  1.0
  O  O35  1  0.235  0.889  0.576  1.0
  O  O36  1  0.113  0.187  0.748  1.0
  O  O37  1  0.887  0.813  0.252  1.0
  O  O38  1  0.210  0.140  0.420  1.0
  O  O39  1  0.790  0.860  0.580  1.0
[/CIF]
.
The structure described by Mo3Ag3AsO13 crystallizes in the triclinic P-1 space group. There are three inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(11), one O(12), one O(2), one O(3), one O(5), and one O(8) atom. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(1), one O(12), one O(13), one O(5), one O(7), and one O(9) atom. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(10), one O(3), one O(6), one O(9), and two equivalent O(8) atoms. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(10), one O(11), one O(2), and one O(4) atom. In the second Ag site, Ag(2) is bonded in a 5-coordinate geometry to one O(11), one O(12), one O(13), and two equivalent O(4) atoms. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(6), and one O(7) atom. As(1) is bonded in a tetrahedral geometry to one O(4), one O(5), one O(6), and one O(7) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Mo(2) and one Ag(3) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mo(1), one Ag(1), and one Ag(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(3), and one Ag(3) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Ag(1), two equivalent Ag(2), and one As(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one As(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mo(3), one Ag(3), and one As(1) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Mo(2), one Ag(3), and one As(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Mo(1) and two equivalent Mo(3) atoms. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mo(2) and one Mo(3) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Mo(3) and one Ag(1) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Mo(1), one Ag(1), and one Ag(2) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Mo(1), one Mo(2), and one Ag(2) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Mo(2) and one Ag(2) atom. is represented by the CIF file [CIF]
data_Ag3Mo3AsO13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.185
_cell_length_b   8.370
_cell_length_c   9.865
_cell_angle_alpha   113.871
_cell_angle_beta   99.028
_cell_angle_gamma   105.651
_symmetry_Int_Tables_number   1
_cell_volume   567.288
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.391  0.654  0.420  1.0
  Ag  Ag1  1  0.609  0.346  0.580  1.0
  Ag  Ag2  1  0.090  0.349  0.558  1.0
  Ag  Ag3  1  0.910  0.651  0.442  1.0
  Ag  Ag4  1  0.256  0.530  0.035  1.0
  Ag  Ag5  1  0.744  0.470  0.965  1.0
  Mo  Mo6  1  0.302  0.089  0.756  1.0
  Mo  Mo7  1  0.698  0.911  0.244  1.0
  Mo  Mo8  1  0.117  0.943  0.232  1.0
  Mo  Mo9  1  0.883  0.057  0.768  1.0
  Mo  Mo10  1  0.487  0.210  0.142  1.0
  Mo  Mo11  1  0.513  0.790  0.858  1.0
  As  As12  1  0.947  0.277  0.169  1.0
  As  As13  1  0.053  0.723  0.831  1.0
  O  O14  1  0.218  0.788  0.243  1.0
  O  O15  1  0.782  0.212  0.757  1.0
  O  O16  1  0.461  0.262  0.737  1.0
  O  O17  1  0.539  0.738  0.263  1.0
  O  O18  1  0.409  0.316  0.031  1.0
  O  O19  1  0.591  0.684  0.969  1.0
  O  O20  1  0.081  0.461  0.346  1.0
  O  O21  1  0.919  0.539  0.654  1.0
  O  O22  1  0.915  0.067  0.177  1.0
  O  O23  1  0.085  0.933  0.823  1.0
  O  O24  1  0.748  0.315  0.131  1.0
  O  O25  1  0.252  0.685  0.869  1.0
  O  O26  1  0.030  0.268  0.018  1.0
  O  O27  1  0.970  0.732  0.982  1.0
  O  O28  1  0.442  0.008  0.877  1.0
  O  O29  1  0.558  0.992  0.123  1.0
  O  O30  1  0.262  0.066  0.137  1.0
  O  O31  1  0.738  0.934  0.863  1.0
  O  O32  1  0.558  0.376  0.341  1.0
  O  O33  1  0.442  0.624  0.659  1.0
  O  O34  1  0.765  0.111  0.424  1.0
  O  O35  1  0.235  0.889  0.576  1.0
  O  O36  1  0.113  0.187  0.748  1.0
  O  O37  1  0.887  0.813  0.252  1.0
  O  O38  1  0.210  0.140  0.420  1.0
  O  O39  1  0.790  0.860  0.580  1.0
[/CIF]
.