The compound described by Sn(SO2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Sn(SO2)2 clusters. Sn(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one O(1) and one O(3) atom. In the second S site, S(2) is bonded in a water-like geometry to one O(2) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sn(1) and one S(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Sn(1) and one S(2) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Sn(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Sn(1) and one S(2) atom. is represented by the CIF card [CIF]
data_Sn(SO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.742
_cell_length_b   7.420
_cell_length_c   11.232
_cell_angle_alpha   59.962
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   558.591
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.742  0.595  0.584  1.0
  Sn  Sn1  1  0.242  0.405  0.916  1.0
  Sn  Sn2  1  0.258  0.405  0.416  1.0
  Sn  Sn3  1  0.758  0.595  0.084  1.0
  S  S4  1  0.517  0.122  0.713  1.0
  S  S5  1  0.017  0.878  0.787  1.0
  S  S6  1  0.483  0.878  0.287  1.0
  S  S7  1  0.983  0.122  0.213  1.0
  S  S8  1  0.681  0.191  0.509  1.0
  S  S9  1  0.181  0.809  0.991  1.0
  S  S10  1  0.319  0.809  0.491  1.0
  S  S11  1  0.819  0.191  0.009  1.0
  O  O12  1  0.342  0.192  0.641  1.0
  O  O13  1  0.842  0.808  0.859  1.0
  O  O14  1  0.658  0.808  0.359  1.0
  O  O15  1  0.158  0.192  0.141  1.0
  O  O16  1  0.528  0.271  0.410  1.0
  O  O17  1  0.028  0.729  0.090  1.0
  O  O18  1  0.472  0.729  0.590  1.0
  O  O19  1  0.972  0.271  0.910  1.0
  O  O20  1  0.601  0.294  0.730  1.0
  O  O21  1  0.101  0.706  0.770  1.0
  O  O22  1  0.399  0.706  0.270  1.0
  O  O23  1  0.899  0.294  0.230  1.0
  O  O24  1  0.714  0.371  0.001  1.0
  O  O25  1  0.214  0.629  0.499  1.0
  O  O26  1  0.286  0.629  0.999  1.0
  O  O27  1  0.786  0.371  0.501  1.0
[/CIF]
.
The compound described by Sn(SO2)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Sn(SO2)2 clusters. Sn(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one O(1) and one O(3) atom. In the second S site, S(2) is bonded in a water-like geometry to one O(2) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sn(1) and one S(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Sn(1) and one S(2) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Sn(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Sn(1) and one S(2) atom. is represented by the CIF card [CIF]
data_Sn(SO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.742
_cell_length_b   7.420
_cell_length_c   11.232
_cell_angle_alpha   59.962
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   558.591
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.742  0.595  0.584  1.0
  Sn  Sn1  1  0.242  0.405  0.916  1.0
  Sn  Sn2  1  0.258  0.405  0.416  1.0
  Sn  Sn3  1  0.758  0.595  0.084  1.0
  S  S4  1  0.517  0.122  0.713  1.0
  S  S5  1  0.017  0.878  0.787  1.0
  S  S6  1  0.483  0.878  0.287  1.0
  S  S7  1  0.983  0.122  0.213  1.0
  S  S8  1  0.681  0.191  0.509  1.0
  S  S9  1  0.181  0.809  0.991  1.0
  S  S10  1  0.319  0.809  0.491  1.0
  S  S11  1  0.819  0.191  0.009  1.0
  O  O12  1  0.342  0.192  0.641  1.0
  O  O13  1  0.842  0.808  0.859  1.0
  O  O14  1  0.658  0.808  0.359  1.0
  O  O15  1  0.158  0.192  0.141  1.0
  O  O16  1  0.528  0.271  0.410  1.0
  O  O17  1  0.028  0.729  0.090  1.0
  O  O18  1  0.472  0.729  0.590  1.0
  O  O19  1  0.972  0.271  0.910  1.0
  O  O20  1  0.601  0.294  0.730  1.0
  O  O21  1  0.101  0.706  0.770  1.0
  O  O22  1  0.399  0.706  0.270  1.0
  O  O23  1  0.899  0.294  0.230  1.0
  O  O24  1  0.714  0.371  0.001  1.0
  O  O25  1  0.214  0.629  0.499  1.0
  O  O26  1  0.286  0.629  0.999  1.0
  O  O27  1  0.786  0.371  0.501  1.0
[/CIF]
.