The material described by Ce4SnO10 is Fluorite-derived structured and crystallizes in the orthorhombic Immm space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a body-centered cubic geometry to two equivalent O(1), two equivalent O(3), and four equivalent O(2) atoms. In the second Ce site, Ce(2) is bonded in a body-centered cubic geometry to two equivalent O(2) and six equivalent O(1) atoms. Sn(1) is bonded in a body-centered cubic geometry to four equivalent O(2) and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Ce(1) and three equivalent Ce(2) atoms to form OCe4 tetrahedra that share corners with two equivalent O(3)Ce2Sn2 tetrahedra, corners with six equivalent O(2)Ce3Sn tetrahedra, corners with eight equivalent O(1)Ce4 tetrahedra, edges with two equivalent O(2)Ce3Sn tetrahedra, and edges with four equivalent O(1)Ce4 tetrahedra. In the second O site, O(2) is bonded to one Ce(2), two equivalent Ce(1), and one Sn(1) atom to form OCe3Sn tetrahedra that share corners with four equivalent O(3)Ce2Sn2 tetrahedra, corners with six equivalent O(2)Ce3Sn tetrahedra, corners with six equivalent O(1)Ce4 tetrahedra, edges with two equivalent O(3)Ce2Sn2 tetrahedra, edges with two equivalent O(2)Ce3Sn tetrahedra, and edges with two equivalent O(1)Ce4 tetrahedra. In the third O site, O(3) is bonded to two equivalent Ce(1) and two equivalent Sn(1) atoms to form OCe2Sn2 tetrahedra that share corners with four equivalent O(3)Ce2Sn2 tetrahedra, corners with four equivalent O(1)Ce4 tetrahedra, corners with eight equivalent O(2)Ce3Sn tetrahedra, edges with two equivalent O(3)Ce2Sn2 tetrahedra, and edges with four equivalent O(2)Ce3Sn tetrahedra. is represented by the CIF file [CIF]
data_Ce4SnO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.155
_cell_length_b   10.155
_cell_length_c   10.155
_cell_angle_alpha   158.351
_cell_angle_beta   149.056
_cell_angle_gamma   38.082
_symmetry_Int_Tables_number   1
_cell_volume   198.406
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.598  0.598  0.000  1.0
  Ce  Ce1  1  0.199  0.199  0.000  1.0
  Ce  Ce2  1  0.801  0.801  0.000  1.0
  Ce  Ce3  1  0.402  0.402  0.000  1.0
  Sn  Sn4  1  0.000  0.000  0.000  1.0
  O  O5  1  0.549  0.301  0.249  1.0
  O  O6  1  0.148  0.905  0.243  1.0
  O  O7  1  0.765  0.500  0.265  1.0
  O  O8  1  0.338  0.095  0.243  1.0
  O  O9  1  0.948  0.699  0.249  1.0
  O  O10  1  0.052  0.301  0.751  1.0
  O  O11  1  0.662  0.905  0.757  1.0
  O  O12  1  0.235  0.500  0.735  1.0
  O  O13  1  0.852  0.095  0.757  1.0
  O  O14  1  0.451  0.699  0.751  1.0
[/CIF]
.
The material described by Ce4SnO10 is Fluorite-derived structured and crystallizes in the orthorhombic Immm space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a body-centered cubic geometry to two equivalent O(1), two equivalent O(3), and four equivalent O(2) atoms. In the second Ce site, Ce(2) is bonded in a body-centered cubic geometry to two equivalent O(2) and six equivalent O(1) atoms. Sn(1) is bonded in a body-centered cubic geometry to four equivalent O(2) and four equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Ce(1) and three equivalent Ce(2) atoms to form OCe4 tetrahedra that share corners with two equivalent O(3)Ce2Sn2 tetrahedra, corners with six equivalent O(2)Ce3Sn tetrahedra, corners with eight equivalent O(1)Ce4 tetrahedra, edges with two equivalent O(2)Ce3Sn tetrahedra, and edges with four equivalent O(1)Ce4 tetrahedra. In the second O site, O(2) is bonded to one Ce(2), two equivalent Ce(1), and one Sn(1) atom to form OCe3Sn tetrahedra that share corners with four equivalent O(3)Ce2Sn2 tetrahedra, corners with six equivalent O(2)Ce3Sn tetrahedra, corners with six equivalent O(1)Ce4 tetrahedra, edges with two equivalent O(3)Ce2Sn2 tetrahedra, edges with two equivalent O(2)Ce3Sn tetrahedra, and edges with two equivalent O(1)Ce4 tetrahedra. In the third O site, O(3) is bonded to two equivalent Ce(1) and two equivalent Sn(1) atoms to form OCe2Sn2 tetrahedra that share corners with four equivalent O(3)Ce2Sn2 tetrahedra, corners with four equivalent O(1)Ce4 tetrahedra, corners with eight equivalent O(2)Ce3Sn tetrahedra, edges with two equivalent O(3)Ce2Sn2 tetrahedra, and edges with four equivalent O(2)Ce3Sn tetrahedra. is represented by the CIF file [CIF]
data_Ce4SnO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.155
_cell_length_b   10.155
_cell_length_c   10.155
_cell_angle_alpha   158.351
_cell_angle_beta   149.056
_cell_angle_gamma   38.082
_symmetry_Int_Tables_number   1
_cell_volume   198.406
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.598  0.598  0.000  1.0
  Ce  Ce1  1  0.199  0.199  0.000  1.0
  Ce  Ce2  1  0.801  0.801  0.000  1.0
  Ce  Ce3  1  0.402  0.402  0.000  1.0
  Sn  Sn4  1  0.000  0.000  0.000  1.0
  O  O5  1  0.549  0.301  0.249  1.0
  O  O6  1  0.148  0.905  0.243  1.0
  O  O7  1  0.765  0.500  0.265  1.0
  O  O8  1  0.338  0.095  0.243  1.0
  O  O9  1  0.948  0.699  0.249  1.0
  O  O10  1  0.052  0.301  0.751  1.0
  O  O11  1  0.662  0.905  0.757  1.0
  O  O12  1  0.235  0.500  0.735  1.0
  O  O13  1  0.852  0.095  0.757  1.0
  O  O14  1  0.451  0.699  0.751  1.0
[/CIF]
.