The structure described by (WO3)4N2 crystallizes in the cubic Fd-3m space group. The structure consists of eight ammonia atoms inside a WO3 framework. In the WO3 framework, W(1) is bonded to six equivalent O(1) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 36°. O(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. is represented by the CIF card [CIF]
data_W2NO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.373
_cell_length_b   7.373
_cell_length_c   7.373
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   283.452
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.125  0.625  0.625  1.0
  W  W1  1  0.625  0.125  0.625  1.0
  W  W2  1  0.625  0.625  0.125  1.0
  W  W3  1  0.625  0.625  0.625  1.0
  N  N4  1  0.250  0.250  0.250  1.0
  N  N5  1  0.000  0.000  0.000  1.0
  O  O6  1  0.683  0.683  0.317  1.0
  O  O7  1  0.317  0.317  0.683  1.0
  O  O8  1  0.683  0.317  0.683  1.0
  O  O9  1  0.317  0.683  0.317  1.0
  O  O10  1  0.317  0.683  0.683  1.0
  O  O11  1  0.683  0.317  0.317  1.0
  O  O12  1  0.567  0.567  0.933  1.0
  O  O13  1  0.933  0.933  0.567  1.0
  O  O14  1  0.567  0.933  0.567  1.0
  O  O15  1  0.933  0.567  0.933  1.0
  O  O16  1  0.933  0.567  0.567  1.0
  O  O17  1  0.567  0.933  0.933  1.0
[/CIF]
.
The structure described by (WO3)4N2 crystallizes in the cubic Fd-3m space group. The structure consists of eight ammonia atoms inside a WO3 framework. In the WO3 framework, W(1) is bonded to six equivalent O(1) atoms to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 36°. O(1) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. is represented by the CIF card [CIF]
data_W2NO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.373
_cell_length_b   7.373
_cell_length_c   7.373
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   283.452
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.125  0.625  0.625  1.0
  W  W1  1  0.625  0.125  0.625  1.0
  W  W2  1  0.625  0.625  0.125  1.0
  W  W3  1  0.625  0.625  0.625  1.0
  N  N4  1  0.250  0.250  0.250  1.0
  N  N5  1  0.000  0.000  0.000  1.0
  O  O6  1  0.683  0.683  0.317  1.0
  O  O7  1  0.317  0.317  0.683  1.0
  O  O8  1  0.683  0.317  0.683  1.0
  O  O9  1  0.317  0.683  0.317  1.0
  O  O10  1  0.317  0.683  0.683  1.0
  O  O11  1  0.683  0.317  0.317  1.0
  O  O12  1  0.567  0.567  0.933  1.0
  O  O13  1  0.933  0.933  0.567  1.0
  O  O14  1  0.567  0.933  0.567  1.0
  O  O15  1  0.933  0.567  0.933  1.0
  O  O16  1  0.933  0.567  0.567  1.0
  O  O17  1  0.567  0.933  0.933  1.0
[/CIF]
.