The crystal structure described by (RhC3(NCl)3)2(N2)3 is Cyanogen Chloride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, four ammonia atoms, and four RhC3(NCl)3 clusters. In each RhC3(NCl)3 cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(1), one N(5), one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one C(2) and one N(1) atom. In the second C site, C(2) is bonded in a bent 150 degrees geometry to one C(1) and one C(3) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one N(2) atom. There are three inequivalent N sites. In the first N site, N(5) is bonded in a single-bond geometry to one Rh(1) atom. In the second N site, N(1) is bonded in a linear geometry to one Rh(1) and one C(1) atom. In the third N site, N(2) is bonded in a single-bond geometry to one C(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Rh(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Rh(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Rh(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RhC3(N2Cl)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.982
_cell_length_b   10.026
_cell_length_c   17.459
_cell_angle_alpha   80.994
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   2071.507
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.750  0.782  0.944  1.0
  Rh  Rh1  1  0.250  0.218  0.556  1.0
  Rh  Rh2  1  0.250  0.218  0.056  1.0
  Rh  Rh3  1  0.750  0.782  0.444  1.0
  C  C4  1  0.022  0.845  0.863  1.0
  C  C5  1  0.522  0.155  0.637  1.0
  C  C6  1  0.978  0.155  0.137  1.0
  C  C7  1  0.478  0.845  0.363  1.0
  C  C8  1  0.120  0.880  0.833  1.0
  C  C9  1  0.620  0.120  0.667  1.0
  C  C10  1  0.880  0.120  0.167  1.0
  C  C11  1  0.380  0.880  0.333  1.0
  C  C12  1  0.229  0.886  0.823  1.0
  C  C13  1  0.729  0.114  0.677  1.0
  C  C14  1  0.771  0.114  0.177  1.0
  C  C15  1  0.271  0.886  0.323  1.0
  N  N16  1  0.933  0.814  0.891  1.0
  N  N17  1  0.433  0.186  0.609  1.0
  N  N18  1  0.067  0.186  0.109  1.0
  N  N19  1  0.567  0.814  0.391  1.0
  N  N20  1  0.329  0.892  0.816  1.0
  N  N21  1  0.829  0.108  0.684  1.0
  N  N22  1  0.671  0.108  0.184  1.0
  N  N23  1  0.171  0.892  0.316  1.0
  N  N24  1  0.843  0.716  0.110  1.0
  N  N25  1  0.343  0.284  0.390  1.0
  N  N26  1  0.157  0.284  0.890  1.0
  N  N27  1  0.657  0.716  0.610  1.0
  N  N28  1  0.084  0.548  0.344  1.0
  N  N29  1  0.584  0.452  0.156  1.0
  N  N30  1  0.916  0.452  0.656  1.0
  N  N31  1  0.416  0.548  0.844  1.0
  N  N32  1  0.633  0.767  0.995  1.0
  N  N33  1  0.133  0.233  0.505  1.0
  N  N34  1  0.367  0.233  0.005  1.0
  N  N35  1  0.867  0.767  0.495  1.0
  N  N36  1  0.784  0.696  0.160  1.0
  N  N37  1  0.284  0.304  0.340  1.0
  N  N38  1  0.216  0.304  0.840  1.0
  N  N39  1  0.716  0.696  0.660  1.0
  Cl  Cl40  1  0.799  0.561  0.940  1.0
  Cl  Cl41  1  0.299  0.439  0.560  1.0
  Cl  Cl42  1  0.201  0.439  0.060  1.0
  Cl  Cl43  1  0.701  0.561  0.440  1.0
  Cl  Cl44  1  0.700  0.828  0.816  1.0
  Cl  Cl45  1  0.200  0.172  0.684  1.0
  Cl  Cl46  1  0.300  0.172  0.184  1.0
  Cl  Cl47  1  0.800  0.828  0.316  1.0
  Cl  Cl48  1  0.800  0.000  0.962  1.0
  Cl  Cl49  1  0.300  1.000  0.538  1.0
  Cl  Cl50  1  0.200  1.000  0.038  1.0
  Cl  Cl51  1  0.700  0.000  0.462  1.0
[/CIF]
.
The crystal structure described by (RhC3(NCl)3)2(N2)3 is Cyanogen Chloride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, four ammonia atoms, and four RhC3(NCl)3 clusters. In each RhC3(NCl)3 cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(1), one N(5), one Cl(1), one Cl(2), and one Cl(3) atom. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one C(2) and one N(1) atom. In the second C site, C(2) is bonded in a bent 150 degrees geometry to one C(1) and one C(3) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one N(2) atom. There are three inequivalent N sites. In the first N site, N(5) is bonded in a single-bond geometry to one Rh(1) atom. In the second N site, N(1) is bonded in a linear geometry to one Rh(1) and one C(1) atom. In the third N site, N(2) is bonded in a single-bond geometry to one C(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Rh(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Rh(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Rh(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RhC3(N2Cl)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.982
_cell_length_b   10.026
_cell_length_c   17.459
_cell_angle_alpha   80.994
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   2071.507
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.750  0.782  0.944  1.0
  Rh  Rh1  1  0.250  0.218  0.556  1.0
  Rh  Rh2  1  0.250  0.218  0.056  1.0
  Rh  Rh3  1  0.750  0.782  0.444  1.0
  C  C4  1  0.022  0.845  0.863  1.0
  C  C5  1  0.522  0.155  0.637  1.0
  C  C6  1  0.978  0.155  0.137  1.0
  C  C7  1  0.478  0.845  0.363  1.0
  C  C8  1  0.120  0.880  0.833  1.0
  C  C9  1  0.620  0.120  0.667  1.0
  C  C10  1  0.880  0.120  0.167  1.0
  C  C11  1  0.380  0.880  0.333  1.0
  C  C12  1  0.229  0.886  0.823  1.0
  C  C13  1  0.729  0.114  0.677  1.0
  C  C14  1  0.771  0.114  0.177  1.0
  C  C15  1  0.271  0.886  0.323  1.0
  N  N16  1  0.933  0.814  0.891  1.0
  N  N17  1  0.433  0.186  0.609  1.0
  N  N18  1  0.067  0.186  0.109  1.0
  N  N19  1  0.567  0.814  0.391  1.0
  N  N20  1  0.329  0.892  0.816  1.0
  N  N21  1  0.829  0.108  0.684  1.0
  N  N22  1  0.671  0.108  0.184  1.0
  N  N23  1  0.171  0.892  0.316  1.0
  N  N24  1  0.843  0.716  0.110  1.0
  N  N25  1  0.343  0.284  0.390  1.0
  N  N26  1  0.157  0.284  0.890  1.0
  N  N27  1  0.657  0.716  0.610  1.0
  N  N28  1  0.084  0.548  0.344  1.0
  N  N29  1  0.584  0.452  0.156  1.0
  N  N30  1  0.916  0.452  0.656  1.0
  N  N31  1  0.416  0.548  0.844  1.0
  N  N32  1  0.633  0.767  0.995  1.0
  N  N33  1  0.133  0.233  0.505  1.0
  N  N34  1  0.367  0.233  0.005  1.0
  N  N35  1  0.867  0.767  0.495  1.0
  N  N36  1  0.784  0.696  0.160  1.0
  N  N37  1  0.284  0.304  0.340  1.0
  N  N38  1  0.216  0.304  0.840  1.0
  N  N39  1  0.716  0.696  0.660  1.0
  Cl  Cl40  1  0.799  0.561  0.940  1.0
  Cl  Cl41  1  0.299  0.439  0.560  1.0
  Cl  Cl42  1  0.201  0.439  0.060  1.0
  Cl  Cl43  1  0.701  0.561  0.440  1.0
  Cl  Cl44  1  0.700  0.828  0.816  1.0
  Cl  Cl45  1  0.200  0.172  0.684  1.0
  Cl  Cl46  1  0.300  0.172  0.184  1.0
  Cl  Cl47  1  0.800  0.828  0.316  1.0
  Cl  Cl48  1  0.800  0.000  0.962  1.0
  Cl  Cl49  1  0.300  1.000  0.538  1.0
  Cl  Cl50  1  0.200  1.000  0.038  1.0
  Cl  Cl51  1  0.700  0.000  0.462  1.0
[/CIF]
.