The compound described by V3BO6 is beta indium sulfide-derived structured and crystallizes in the orthorhombic Pnma space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form VO6 octahedra that share corners with eight equivalent V(2)O6 octahedra, corners with two equivalent B(1)O4 tetrahedra, edges with two equivalent V(2)O6 octahedra, and  an edgeedge with one B(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-62°. In the second V site, V(2) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form VO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with four equivalent V(1)O6 octahedra, corners with two equivalent B(1)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and  an edgeedge with one B(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-62°. B(1) is bonded to one O(2), one O(4), and two equivalent O(3) atoms to form BO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-60°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one V(1) and two equivalent V(2) atoms. In the second O site, O(2) is bonded in a distorted trigonal pyramidal geometry to one V(1), two equivalent V(2), and one B(1) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one V(1), two equivalent V(2), and one B(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one V(1), two equivalent V(2), and one B(1) atom. is represented by the CIF file [CIF]
data_V3BO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.452
_cell_length_b   8.590
_cell_length_c   9.943
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   380.263
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.480  0.750  0.099  1.0
  V  V1  1  0.993  0.067  0.123  1.0
  V  V2  1  0.993  0.433  0.123  1.0
  V  V3  1  0.493  0.567  0.377  1.0
  V  V4  1  0.493  0.933  0.377  1.0
  V  V5  1  0.980  0.250  0.401  1.0
  V  V6  1  0.020  0.750  0.599  1.0
  V  V7  1  0.507  0.067  0.623  1.0
  V  V8  1  0.507  0.433  0.623  1.0
  V  V9  1  0.007  0.567  0.877  1.0
  V  V10  1  0.007  0.933  0.877  1.0
  V  V11  1  0.520  0.250  0.901  1.0
  B  B12  1  0.419  0.250  0.216  1.0
  B  B13  1  0.919  0.750  0.284  1.0
  B  B14  1  0.081  0.250  0.716  1.0
  B  B15  1  0.581  0.750  0.784  1.0
  O  O16  1  0.238  0.588  0.034  1.0
  O  O17  1  0.238  0.912  0.034  1.0
  O  O18  1  0.279  0.250  0.078  1.0
  O  O19  1  0.776  0.889  0.216  1.0
  O  O20  1  0.776  0.611  0.216  1.0
  O  O21  1  0.742  0.250  0.217  1.0
  O  O22  1  0.242  0.750  0.283  1.0
  O  O23  1  0.276  0.111  0.284  1.0
  O  O24  1  0.276  0.389  0.284  1.0
  O  O25  1  0.779  0.750  0.422  1.0
  O  O26  1  0.738  0.088  0.466  1.0
  O  O27  1  0.738  0.412  0.466  1.0
  O  O28  1  0.262  0.588  0.534  1.0
  O  O29  1  0.262  0.912  0.534  1.0
  O  O30  1  0.221  0.250  0.578  1.0
  O  O31  1  0.724  0.611  0.716  1.0
  O  O32  1  0.724  0.889  0.716  1.0
  O  O33  1  0.758  0.250  0.717  1.0
  O  O34  1  0.258  0.750  0.783  1.0
  O  O35  1  0.224  0.111  0.784  1.0
  O  O36  1  0.224  0.389  0.784  1.0
  O  O37  1  0.721  0.750  0.922  1.0
  O  O38  1  0.762  0.088  0.966  1.0
  O  O39  1  0.762  0.412  0.966  1.0
[/CIF]
.
The compound described by V3BO6 is beta indium sulfide-derived structured and crystallizes in the orthorhombic Pnma space group. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form VO6 octahedra that share corners with eight equivalent V(2)O6 octahedra, corners with two equivalent B(1)O4 tetrahedra, edges with two equivalent V(2)O6 octahedra, and  an edgeedge with one B(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-62°. In the second V site, V(2) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form VO6 octahedra that share corners with two equivalent V(2)O6 octahedra, corners with four equivalent V(1)O6 octahedra, corners with two equivalent B(1)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and  an edgeedge with one B(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 47-62°. B(1) is bonded to one O(2), one O(4), and two equivalent O(3) atoms to form BO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra, corners with four equivalent V(2)O6 octahedra,  an edgeedge with one V(1)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-60°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one V(1) and two equivalent V(2) atoms. In the second O site, O(2) is bonded in a distorted trigonal pyramidal geometry to one V(1), two equivalent V(2), and one B(1) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one V(1), two equivalent V(2), and one B(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one V(1), two equivalent V(2), and one B(1) atom. is represented by the CIF file [CIF]
data_V3BO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.452
_cell_length_b   8.590
_cell_length_c   9.943
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   380.263
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.480  0.750  0.099  1.0
  V  V1  1  0.993  0.067  0.123  1.0
  V  V2  1  0.993  0.433  0.123  1.0
  V  V3  1  0.493  0.567  0.377  1.0
  V  V4  1  0.493  0.933  0.377  1.0
  V  V5  1  0.980  0.250  0.401  1.0
  V  V6  1  0.020  0.750  0.599  1.0
  V  V7  1  0.507  0.067  0.623  1.0
  V  V8  1  0.507  0.433  0.623  1.0
  V  V9  1  0.007  0.567  0.877  1.0
  V  V10  1  0.007  0.933  0.877  1.0
  V  V11  1  0.520  0.250  0.901  1.0
  B  B12  1  0.419  0.250  0.216  1.0
  B  B13  1  0.919  0.750  0.284  1.0
  B  B14  1  0.081  0.250  0.716  1.0
  B  B15  1  0.581  0.750  0.784  1.0
  O  O16  1  0.238  0.588  0.034  1.0
  O  O17  1  0.238  0.912  0.034  1.0
  O  O18  1  0.279  0.250  0.078  1.0
  O  O19  1  0.776  0.889  0.216  1.0
  O  O20  1  0.776  0.611  0.216  1.0
  O  O21  1  0.742  0.250  0.217  1.0
  O  O22  1  0.242  0.750  0.283  1.0
  O  O23  1  0.276  0.111  0.284  1.0
  O  O24  1  0.276  0.389  0.284  1.0
  O  O25  1  0.779  0.750  0.422  1.0
  O  O26  1  0.738  0.088  0.466  1.0
  O  O27  1  0.738  0.412  0.466  1.0
  O  O28  1  0.262  0.588  0.534  1.0
  O  O29  1  0.262  0.912  0.534  1.0
  O  O30  1  0.221  0.250  0.578  1.0
  O  O31  1  0.724  0.611  0.716  1.0
  O  O32  1  0.724  0.889  0.716  1.0
  O  O33  1  0.758  0.250  0.717  1.0
  O  O34  1  0.258  0.750  0.783  1.0
  O  O35  1  0.224  0.111  0.784  1.0
  O  O36  1  0.224  0.389  0.784  1.0
  O  O37  1  0.721  0.750  0.922  1.0
  O  O38  1  0.762  0.088  0.966  1.0
  O  O39  1  0.762  0.412  0.966  1.0
[/CIF]
.