The structure described by MgV4Tl3(TeO5)4Tl crystallizes in the triclinic P1 space group. The structure consists of one 7440-28-0 atom inside a MgV4Tl3(TeO5)4 framework. In the MgV4Tl3(TeO5)4 framework, Mg(1) is bonded in a 5-coordinate geometry to one Tl(4), one O(1), one O(10), one O(11), one O(17), and one O(18) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(12), one O(14), one O(19), one O(3), one O(5), and one O(6) atom. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(20), one O(8), and one O(9) atom. In the third V site, V(3) is bonded in a distorted octahedral geometry to one O(13), one O(18), one O(3), one O(4), one O(6), and one O(7) atom. In the fourth V site, V(4) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(15), one O(16), one O(17), and one O(9) atom. There are three inequivalent Tl sites. In the first Tl site, Tl(2) is bonded in a bent 120 degrees geometry to one O(15) and one O(2) atom. In the second Tl site, Tl(3) is bonded in a 3-coordinate geometry to one O(12), one O(19), and one O(4) atom. In the third Tl site, Tl(4) is bonded in a 5-coordinate geometry to one Mg(1), one O(12), one O(13), one O(3), and one O(4) atom. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to one O(15), one O(2), and one O(7) atom. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to one O(16), one O(19), one O(20), one O(4), and one O(7) atom. In the third Te site, Te(3) is bonded in a distorted see-saw-like geometry to one O(10), one O(12), one O(13), and one O(14) atom. In the fourth Te site, Te(4) is bonded in a 3-coordinate geometry to one O(10), one O(11), one O(14), and one O(17) atom. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mg(1), one V(2), and one V(4) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Tl(2) and one Te(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one V(1), one V(3), and one Tl(4) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one V(3), one Tl(3), one Tl(4), and one Te(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one V(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(3), one Te(1), and one Te(2) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one V(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Mg(1), one V(4), one Te(3), and one Te(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Mg(1), one V(2), and one Te(4) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one V(1), one Tl(3), one Tl(4), and one Te(3) atom. In the thirteenth O site, O(13) is bonded in a 2-coordinate geometry to one V(3), one Tl(4), and one Te(3) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one V(1), one Te(3), and one Te(4) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one V(4), one Tl(2), and one Te(1) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one V(4) and one Te(2) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one V(4), and one Te(4) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one Mg(1) and one V(3) atom. In the nineteenth O site, O(19) is bonded in a 2-coordinate geometry to one V(1), one Tl(3), and one Te(2) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one V(2) and one Te(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgTl4V4(TeO5)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.128
_cell_length_b   8.053
_cell_length_c   9.357
_cell_angle_alpha   86.885
_cell_angle_beta   87.896
_cell_angle_gamma   88.829
_symmetry_Int_Tables_number   1
_cell_volume   535.862
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.863  0.164  0.998  1.0
  Tl  Tl1  1  0.057  0.816  0.879  1.0
  Tl  Tl2  1  0.486  0.900  0.601  1.0
  Tl  Tl3  1  0.512  0.410  0.409  1.0
  Tl  Tl4  1  0.047  0.441  0.146  1.0
  V  V5  1  0.300  0.792  0.260  1.0
  V  V6  1  0.185  0.306  0.752  1.0
  V  V7  1  0.808  0.799  0.238  1.0
  V  V8  1  0.687  0.288  0.738  1.0
  Te  Te9  1  0.974  0.090  0.473  1.0
  Te  Te10  1  0.997  0.609  0.532  1.0
  Te  Te11  1  0.544  0.587  0.983  1.0
  Te  Te12  1  0.441  0.092  0.033  1.0
  O  O13  1  0.937  0.245  0.806  1.0
  O  O14  1  0.125  0.018  0.623  1.0
  O  O15  1  0.076  0.740  0.181  1.0
  O  O16  1  0.861  0.560  0.370  1.0
  O  O17  1  0.256  0.990  0.304  1.0
  O  O18  1  0.550  0.775  0.303  1.0
  O  O19  1  0.878  0.870  0.438  1.0
  O  O20  1  0.203  0.491  0.824  1.0
  O  O21  1  0.417  0.253  0.699  1.0
  O  O22  1  0.639  0.360  0.959  1.0
  O  O23  1  0.215  0.146  0.932  1.0
  O  O24  1  0.389  0.531  0.145  1.0
  O  O25  1  0.764  0.657  0.074  1.0
  O  O26  1  0.385  0.859  0.051  1.0
  O  O27  1  0.740  0.149  0.575  1.0
  O  O28  1  0.704  0.489  0.671  1.0
  O  O29  1  0.634  0.062  0.888  1.0
  O  O30  1  0.813  0.001  0.160  1.0
  O  O31  1  0.237  0.665  0.433  1.0
  O  O32  1  0.099  0.378  0.565  1.0
[/CIF]
.
The structure described by MgV4Tl3(TeO5)4Tl crystallizes in the triclinic P1 space group. The structure consists of one 7440-28-0 atom inside a MgV4Tl3(TeO5)4 framework. In the MgV4Tl3(TeO5)4 framework, Mg(1) is bonded in a 5-coordinate geometry to one Tl(4), one O(1), one O(10), one O(11), one O(17), and one O(18) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to one O(12), one O(14), one O(19), one O(3), one O(5), and one O(6) atom. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(20), one O(8), and one O(9) atom. In the third V site, V(3) is bonded in a distorted octahedral geometry to one O(13), one O(18), one O(3), one O(4), one O(6), and one O(7) atom. In the fourth V site, V(4) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(15), one O(16), one O(17), and one O(9) atom. There are three inequivalent Tl sites. In the first Tl site, Tl(2) is bonded in a bent 120 degrees geometry to one O(15) and one O(2) atom. In the second Tl site, Tl(3) is bonded in a 3-coordinate geometry to one O(12), one O(19), and one O(4) atom. In the third Tl site, Tl(4) is bonded in a 5-coordinate geometry to one Mg(1), one O(12), one O(13), one O(3), and one O(4) atom. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to one O(15), one O(2), and one O(7) atom. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to one O(16), one O(19), one O(20), one O(4), and one O(7) atom. In the third Te site, Te(3) is bonded in a distorted see-saw-like geometry to one O(10), one O(12), one O(13), and one O(14) atom. In the fourth Te site, Te(4) is bonded in a 3-coordinate geometry to one O(10), one O(11), one O(14), and one O(17) atom. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mg(1), one V(2), and one V(4) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Tl(2) and one Te(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one V(1), one V(3), and one Tl(4) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one V(3), one Tl(3), one Tl(4), and one Te(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one V(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one V(1) and one V(3) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one V(3), one Te(1), and one Te(2) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one V(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Mg(1), one V(4), one Te(3), and one Te(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Mg(1), one V(2), and one Te(4) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one V(1), one Tl(3), one Tl(4), and one Te(3) atom. In the thirteenth O site, O(13) is bonded in a 2-coordinate geometry to one V(3), one Tl(4), and one Te(3) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one V(1), one Te(3), and one Te(4) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one V(4), one Tl(2), and one Te(1) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one V(4) and one Te(2) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one V(4), and one Te(4) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one Mg(1) and one V(3) atom. In the nineteenth O site, O(19) is bonded in a 2-coordinate geometry to one V(1), one Tl(3), and one Te(2) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one V(2) and one Te(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgTl4V4(TeO5)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.128
_cell_length_b   8.053
_cell_length_c   9.357
_cell_angle_alpha   86.885
_cell_angle_beta   87.896
_cell_angle_gamma   88.829
_symmetry_Int_Tables_number   1
_cell_volume   535.862
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.863  0.164  0.998  1.0
  Tl  Tl1  1  0.057  0.816  0.879  1.0
  Tl  Tl2  1  0.486  0.900  0.601  1.0
  Tl  Tl3  1  0.512  0.410  0.409  1.0
  Tl  Tl4  1  0.047  0.441  0.146  1.0
  V  V5  1  0.300  0.792  0.260  1.0
  V  V6  1  0.185  0.306  0.752  1.0
  V  V7  1  0.808  0.799  0.238  1.0
  V  V8  1  0.687  0.288  0.738  1.0
  Te  Te9  1  0.974  0.090  0.473  1.0
  Te  Te10  1  0.997  0.609  0.532  1.0
  Te  Te11  1  0.544  0.587  0.983  1.0
  Te  Te12  1  0.441  0.092  0.033  1.0
  O  O13  1  0.937  0.245  0.806  1.0
  O  O14  1  0.125  0.018  0.623  1.0
  O  O15  1  0.076  0.740  0.181  1.0
  O  O16  1  0.861  0.560  0.370  1.0
  O  O17  1  0.256  0.990  0.304  1.0
  O  O18  1  0.550  0.775  0.303  1.0
  O  O19  1  0.878  0.870  0.438  1.0
  O  O20  1  0.203  0.491  0.824  1.0
  O  O21  1  0.417  0.253  0.699  1.0
  O  O22  1  0.639  0.360  0.959  1.0
  O  O23  1  0.215  0.146  0.932  1.0
  O  O24  1  0.389  0.531  0.145  1.0
  O  O25  1  0.764  0.657  0.074  1.0
  O  O26  1  0.385  0.859  0.051  1.0
  O  O27  1  0.740  0.149  0.575  1.0
  O  O28  1  0.704  0.489  0.671  1.0
  O  O29  1  0.634  0.062  0.888  1.0
  O  O30  1  0.813  0.001  0.160  1.0
  O  O31  1  0.237  0.665  0.433  1.0
  O  O32  1  0.099  0.378  0.565  1.0
[/CIF]
.