The material structure described by Na3Zn2(MoO4)3 crystallizes in the monoclinic C2/c space group. There are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. In the second Na site, Na(2) is bonded in a distorted hexagonal planar geometry to two equivalent O(4) and four equivalent O(3) atoms. In the third Na site, Na(3) is bonded in a 4-coordinate geometry to four equivalent O(6) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to two equivalent O(4) and two equivalent O(5) atoms. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(6) atom. Zn(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Mo(2) and one Zn(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Na(1), one Mo(2), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), two equivalent Na(2), and one Mo(2) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Na(2), one Mo(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(1), one Mo(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded to two equivalent Na(3), one Mo(2), and one Zn(1) atom to form a mixture of distorted corner and edge-sharing ONa2ZnMo tetrahedra. is represented by the CIF card [CIF]
data_Na3Zn2(MoO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.331
_cell_length_b   9.331
_cell_length_c   7.315
_cell_angle_alpha   74.504
_cell_angle_beta   74.504
_cell_angle_gamma   97.934
_symmetry_Int_Tables_number   1
_cell_volume   576.154
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.235  0.765  0.250  1.0
  Na  Na1  1  0.765  0.235  0.750  1.0
  Na  Na2  1  0.000  0.000  0.000  1.0
  Na  Na3  1  0.000  0.000  0.500  1.0
  Na  Na4  1  0.523  0.477  0.250  1.0
  Na  Na5  1  0.477  0.523  0.750  1.0
  Zn  Zn6  1  0.557  0.867  0.373  1.0
  Zn  Zn7  1  0.443  0.133  0.627  1.0
  Zn  Zn8  1  0.133  0.443  0.127  1.0
  Zn  Zn9  1  0.867  0.557  0.873  1.0
  Mo  Mo10  1  0.778  0.222  0.250  1.0
  Mo  Mo11  1  0.222  0.778  0.750  1.0
  Mo  Mo12  1  0.375  0.169  0.120  1.0
  Mo  Mo13  1  0.625  0.831  0.880  1.0
  Mo  Mo14  1  0.831  0.625  0.380  1.0
  Mo  Mo15  1  0.169  0.375  0.620  1.0
  O  O16  1  0.458  0.116  0.319  1.0
  O  O17  1  0.542  0.884  0.681  1.0
  O  O18  1  0.884  0.542  0.181  1.0
  O  O19  1  0.116  0.458  0.819  1.0
  O  O20  1  0.508  0.838  0.115  1.0
  O  O21  1  0.492  0.162  0.885  1.0
  O  O22  1  0.162  0.492  0.385  1.0
  O  O23  1  0.838  0.508  0.615  1.0
  O  O24  1  0.197  0.039  0.194  1.0
  O  O25  1  0.803  0.961  0.806  1.0
  O  O26  1  0.961  0.803  0.306  1.0
  O  O27  1  0.039  0.197  0.694  1.0
  O  O28  1  0.751  0.022  0.237  1.0
  O  O29  1  0.249  0.978  0.763  1.0
  O  O30  1  0.978  0.249  0.263  1.0
  O  O31  1  0.022  0.751  0.737  1.0
  O  O32  1  0.657  0.254  0.480  1.0
  O  O33  1  0.343  0.746  0.520  1.0
  O  O34  1  0.746  0.343  0.020  1.0
  O  O35  1  0.254  0.657  0.980  1.0
  O  O36  1  0.638  0.655  0.413  1.0
  O  O37  1  0.362  0.345  0.587  1.0
  O  O38  1  0.345  0.362  0.087  1.0
  O  O39  1  0.655  0.638  0.913  1.0
[/CIF]
.
The material structure described by Na3Zn2(MoO4)3 crystallizes in the monoclinic C2/c space group. There are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(3), and two equivalent O(5) atoms. In the second Na site, Na(2) is bonded in a distorted hexagonal planar geometry to two equivalent O(4) and four equivalent O(3) atoms. In the third Na site, Na(3) is bonded in a 4-coordinate geometry to four equivalent O(6) atoms. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a tetrahedral geometry to two equivalent O(4) and two equivalent O(5) atoms. In the second Mo site, Mo(2) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(6) atom. Zn(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(4), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Mo(2) and one Zn(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Na(1), one Mo(2), and one Zn(1) atom. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Na(1), two equivalent Na(2), and one Mo(2) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Na(2), one Mo(1), and one Zn(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(1), one Mo(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded to two equivalent Na(3), one Mo(2), and one Zn(1) atom to form a mixture of distorted corner and edge-sharing ONa2ZnMo tetrahedra. is represented by the CIF card [CIF]
data_Na3Zn2(MoO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.331
_cell_length_b   9.331
_cell_length_c   7.315
_cell_angle_alpha   74.504
_cell_angle_beta   74.504
_cell_angle_gamma   97.934
_symmetry_Int_Tables_number   1
_cell_volume   576.154
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.235  0.765  0.250  1.0
  Na  Na1  1  0.765  0.235  0.750  1.0
  Na  Na2  1  0.000  0.000  0.000  1.0
  Na  Na3  1  0.000  0.000  0.500  1.0
  Na  Na4  1  0.523  0.477  0.250  1.0
  Na  Na5  1  0.477  0.523  0.750  1.0
  Zn  Zn6  1  0.557  0.867  0.373  1.0
  Zn  Zn7  1  0.443  0.133  0.627  1.0
  Zn  Zn8  1  0.133  0.443  0.127  1.0
  Zn  Zn9  1  0.867  0.557  0.873  1.0
  Mo  Mo10  1  0.778  0.222  0.250  1.0
  Mo  Mo11  1  0.222  0.778  0.750  1.0
  Mo  Mo12  1  0.375  0.169  0.120  1.0
  Mo  Mo13  1  0.625  0.831  0.880  1.0
  Mo  Mo14  1  0.831  0.625  0.380  1.0
  Mo  Mo15  1  0.169  0.375  0.620  1.0
  O  O16  1  0.458  0.116  0.319  1.0
  O  O17  1  0.542  0.884  0.681  1.0
  O  O18  1  0.884  0.542  0.181  1.0
  O  O19  1  0.116  0.458  0.819  1.0
  O  O20  1  0.508  0.838  0.115  1.0
  O  O21  1  0.492  0.162  0.885  1.0
  O  O22  1  0.162  0.492  0.385  1.0
  O  O23  1  0.838  0.508  0.615  1.0
  O  O24  1  0.197  0.039  0.194  1.0
  O  O25  1  0.803  0.961  0.806  1.0
  O  O26  1  0.961  0.803  0.306  1.0
  O  O27  1  0.039  0.197  0.694  1.0
  O  O28  1  0.751  0.022  0.237  1.0
  O  O29  1  0.249  0.978  0.763  1.0
  O  O30  1  0.978  0.249  0.263  1.0
  O  O31  1  0.022  0.751  0.737  1.0
  O  O32  1  0.657  0.254  0.480  1.0
  O  O33  1  0.343  0.746  0.520  1.0
  O  O34  1  0.746  0.343  0.020  1.0
  O  O35  1  0.254  0.657  0.980  1.0
  O  O36  1  0.638  0.655  0.413  1.0
  O  O37  1  0.362  0.345  0.587  1.0
  O  O38  1  0.345  0.362  0.087  1.0
  O  O39  1  0.655  0.638  0.913  1.0
[/CIF]
.