The crystal structure described by Li(SO2)4(BCl)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve chloroborane molecules and one Li(SO2)4 cluster. In the Li(SO2)4 cluster, Li(1) is bonded in a trigonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(5), and one O(7) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one O(3) and one O(4) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one O(5) and one O(6) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one O(7) and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Li(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Li(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Li(1) and one S(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Li(1) and one S(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Li(1) and one S(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one S(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiB6S4(Cl3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.238
_cell_length_b   10.580
_cell_length_c   10.637
_cell_angle_alpha   116.371
_cell_angle_beta   94.930
_cell_angle_gamma   101.279
_symmetry_Int_Tables_number   1
_cell_volume   992.595
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.839  0.912  0.242  1.0
  Li  Li1  1  0.161  0.088  0.758  1.0
  B  B2  1  0.596  0.650  0.651  1.0
  B  B3  1  0.404  0.350  0.349  1.0
  B  B4  1  0.652  0.587  0.483  1.0
  B  B5  1  0.348  0.413  0.517  1.0
  B  B6  1  0.510  0.665  0.506  1.0
  B  B7  1  0.490  0.335  0.494  1.0
  B  B8  1  0.414  0.608  0.613  1.0
  B  B9  1  0.586  0.392  0.387  1.0
  B  B10  1  0.496  0.494  0.658  1.0
  B  B11  1  0.504  0.505  0.342  1.0
  B  B12  1  0.643  0.480  0.577  1.0
  B  B13  1  0.357  0.520  0.423  1.0
  S  S14  1  0.829  0.099  0.606  1.0
  S  S15  1  0.171  0.901  0.394  1.0
  S  S16  1  0.969  0.193  0.172  1.0
  S  S17  1  0.031  0.807  0.828  1.0
  S  S18  1  0.494  0.885  0.118  1.0
  S  S19  1  0.506  0.115  0.882  1.0
  S  S20  1  0.818  0.547  0.049  1.0
  S  S21  1  0.182  0.453  0.951  1.0
  Cl  Cl22  1  0.695  0.810  0.809  1.0
  Cl  Cl23  1  0.305  0.190  0.191  1.0
  Cl  Cl24  1  0.810  0.679  0.466  1.0
  Cl  Cl25  1  0.190  0.321  0.534  1.0
  Cl  Cl26  1  0.519  0.840  0.514  1.0
  Cl  Cl27  1  0.481  0.160  0.486  1.0
  Cl  Cl28  1  0.326  0.724  0.736  1.0
  Cl  Cl29  1  0.674  0.276  0.264  1.0
  Cl  Cl30  1  0.490  0.491  0.824  1.0
  Cl  Cl31  1  0.510  0.509  0.176  1.0
  Cl  Cl32  1  0.793  0.458  0.657  1.0
  Cl  Cl33  1  0.207  0.542  0.343  1.0
  O  O34  1  0.829  0.044  0.455  1.0
  O  O35  1  0.171  0.956  0.545  1.0
  O  O36  1  0.947  0.099  0.692  1.0
  O  O37  1  0.053  0.901  0.308  1.0
  O  O38  1  0.909  0.055  0.170  1.0
  O  O39  1  0.091  0.945  0.830  1.0
  O  O40  1  0.952  0.193  0.036  1.0
  O  O41  1  0.048  0.807  0.964  1.0
  O  O42  1  0.623  0.884  0.185  1.0
  O  O43  1  0.377  0.116  0.815  1.0
  O  O44  1  0.372  0.805  0.138  1.0
  O  O45  1  0.628  0.195  0.862  1.0
  O  O46  1  0.804  0.695  0.097  1.0
  O  O47  1  0.196  0.305  0.903  1.0
  O  O48  1  0.926  0.530  0.133  1.0
  O  O49  1  0.074  0.470  0.867  1.0
[/CIF]
.
The crystal structure described by Li(SO2)4(BCl)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve chloroborane molecules and one Li(SO2)4 cluster. In the Li(SO2)4 cluster, Li(1) is bonded in a trigonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(5), and one O(7) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one O(3) and one O(4) atom. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one O(5) and one O(6) atom. In the fourth S site, S(4) is bonded in a bent 120 degrees geometry to one O(7) and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Li(1) and one S(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Li(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Li(1) and one S(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Li(1) and one S(3) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Li(1) and one S(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one S(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiB6S4(Cl3O4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.238
_cell_length_b   10.580
_cell_length_c   10.637
_cell_angle_alpha   116.371
_cell_angle_beta   94.930
_cell_angle_gamma   101.279
_symmetry_Int_Tables_number   1
_cell_volume   992.595
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.839  0.912  0.242  1.0
  Li  Li1  1  0.161  0.088  0.758  1.0
  B  B2  1  0.596  0.650  0.651  1.0
  B  B3  1  0.404  0.350  0.349  1.0
  B  B4  1  0.652  0.587  0.483  1.0
  B  B5  1  0.348  0.413  0.517  1.0
  B  B6  1  0.510  0.665  0.506  1.0
  B  B7  1  0.490  0.335  0.494  1.0
  B  B8  1  0.414  0.608  0.613  1.0
  B  B9  1  0.586  0.392  0.387  1.0
  B  B10  1  0.496  0.494  0.658  1.0
  B  B11  1  0.504  0.505  0.342  1.0
  B  B12  1  0.643  0.480  0.577  1.0
  B  B13  1  0.357  0.520  0.423  1.0
  S  S14  1  0.829  0.099  0.606  1.0
  S  S15  1  0.171  0.901  0.394  1.0
  S  S16  1  0.969  0.193  0.172  1.0
  S  S17  1  0.031  0.807  0.828  1.0
  S  S18  1  0.494  0.885  0.118  1.0
  S  S19  1  0.506  0.115  0.882  1.0
  S  S20  1  0.818  0.547  0.049  1.0
  S  S21  1  0.182  0.453  0.951  1.0
  Cl  Cl22  1  0.695  0.810  0.809  1.0
  Cl  Cl23  1  0.305  0.190  0.191  1.0
  Cl  Cl24  1  0.810  0.679  0.466  1.0
  Cl  Cl25  1  0.190  0.321  0.534  1.0
  Cl  Cl26  1  0.519  0.840  0.514  1.0
  Cl  Cl27  1  0.481  0.160  0.486  1.0
  Cl  Cl28  1  0.326  0.724  0.736  1.0
  Cl  Cl29  1  0.674  0.276  0.264  1.0
  Cl  Cl30  1  0.490  0.491  0.824  1.0
  Cl  Cl31  1  0.510  0.509  0.176  1.0
  Cl  Cl32  1  0.793  0.458  0.657  1.0
  Cl  Cl33  1  0.207  0.542  0.343  1.0
  O  O34  1  0.829  0.044  0.455  1.0
  O  O35  1  0.171  0.956  0.545  1.0
  O  O36  1  0.947  0.099  0.692  1.0
  O  O37  1  0.053  0.901  0.308  1.0
  O  O38  1  0.909  0.055  0.170  1.0
  O  O39  1  0.091  0.945  0.830  1.0
  O  O40  1  0.952  0.193  0.036  1.0
  O  O41  1  0.048  0.807  0.964  1.0
  O  O42  1  0.623  0.884  0.185  1.0
  O  O43  1  0.377  0.116  0.815  1.0
  O  O44  1  0.372  0.805  0.138  1.0
  O  O45  1  0.628  0.195  0.862  1.0
  O  O46  1  0.804  0.695  0.097  1.0
  O  O47  1  0.196  0.305  0.903  1.0
  O  O48  1  0.926  0.530  0.133  1.0
  O  O49  1  0.074  0.470  0.867  1.0
[/CIF]
.