The crystal structure described by ZrS2O13 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one ZrS2O13 cluster. Zr(1) is bonded to one O(11), one O(12), one O(3), one O(4), one O(5), one O(6), and one O(8) atom to form distorted ZrO7 pentagonal bipyramids that share corners with two equivalent S(2)O4 tetrahedra and  an edgeedge with one S(1)O4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(6), one O(7), one O(8), and one O(9) atom to form SO4 tetrahedra that share  an edgeedge with one Zr(1)O7 pentagonal bipyramid. In the second S site, S(2) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with two equivalent Zr(1)O7 pentagonal bipyramids. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Zr(1) atom. In the sixth O site, O(6) is bonded in a distorted L-shaped geometry to one Zr(1) and one S(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Zr(1) and one S(1) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one O(12) and one O(13) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Zr(1) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Zr(1) and one O(10) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one O(10) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZrS2O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.866
_cell_length_b   8.035
_cell_length_c   8.942
_cell_angle_alpha   100.187
_cell_angle_beta   88.488
_cell_angle_gamma   100.725
_symmetry_Int_Tables_number   1
_cell_volume   546.530
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.773  0.592  0.811  1.0
  Zr  Zr1  1  0.227  0.408  0.189  1.0
  S  S2  1  0.529  0.815  0.807  1.0
  S  S3  1  0.471  0.185  0.193  1.0
  S  S4  1  0.092  0.335  0.802  1.0
  S  S5  1  0.908  0.665  0.198  1.0
  O  O6  1  0.974  0.170  0.798  1.0
  O  O7  1  0.026  0.830  0.202  1.0
  O  O8  1  0.235  0.312  0.698  1.0
  O  O9  1  0.765  0.688  0.302  1.0
  O  O10  1  0.157  0.410  0.961  1.0
  O  O11  1  0.843  0.590  0.039  1.0
  O  O12  1  0.997  0.467  0.757  1.0
  O  O13  1  0.003  0.533  0.243  1.0
  O  O14  1  0.585  0.388  0.821  1.0
  O  O15  1  0.415  0.612  0.179  1.0
  O  O16  1  0.551  0.654  0.692  1.0
  O  O17  1  0.449  0.346  0.308  1.0
  O  O18  1  0.536  0.959  0.727  1.0
  O  O19  1  0.464  0.041  0.273  1.0
  O  O20  1  0.687  0.833  0.908  1.0
  O  O21  1  0.313  0.167  0.092  1.0
  O  O22  1  0.369  0.785  0.893  1.0
  O  O23  1  0.631  0.215  0.107  1.0
  O  O24  1  0.029  0.811  0.586  1.0
  O  O25  1  0.971  0.189  0.414  1.0
  O  O26  1  0.735  0.420  0.602  1.0
  O  O27  1  0.265  0.580  0.398  1.0
  O  O28  1  0.009  0.796  0.731  1.0
  O  O29  1  0.991  0.204  0.269  1.0
  O  O30  1  0.172  0.889  0.549  1.0
  O  O31  1  0.828  0.111  0.451  1.0
[/CIF]
.
The crystal structure described by ZrS2O13 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one ZrS2O13 cluster. Zr(1) is bonded to one O(11), one O(12), one O(3), one O(4), one O(5), one O(6), and one O(8) atom to form distorted ZrO7 pentagonal bipyramids that share corners with two equivalent S(2)O4 tetrahedra and  an edgeedge with one S(1)O4 tetrahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(6), one O(7), one O(8), and one O(9) atom to form SO4 tetrahedra that share  an edgeedge with one Zr(1)O7 pentagonal bipyramid. In the second S site, S(2) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share corners with two equivalent Zr(1)O7 pentagonal bipyramids. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Zr(1) and one S(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Zr(1) atom. In the sixth O site, O(6) is bonded in a distorted L-shaped geometry to one Zr(1) and one S(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(1) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Zr(1) and one S(1) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one S(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one O(12) and one O(13) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Zr(1) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Zr(1) and one O(10) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one O(10) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZrS2O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.866
_cell_length_b   8.035
_cell_length_c   8.942
_cell_angle_alpha   100.187
_cell_angle_beta   88.488
_cell_angle_gamma   100.725
_symmetry_Int_Tables_number   1
_cell_volume   546.530
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.773  0.592  0.811  1.0
  Zr  Zr1  1  0.227  0.408  0.189  1.0
  S  S2  1  0.529  0.815  0.807  1.0
  S  S3  1  0.471  0.185  0.193  1.0
  S  S4  1  0.092  0.335  0.802  1.0
  S  S5  1  0.908  0.665  0.198  1.0
  O  O6  1  0.974  0.170  0.798  1.0
  O  O7  1  0.026  0.830  0.202  1.0
  O  O8  1  0.235  0.312  0.698  1.0
  O  O9  1  0.765  0.688  0.302  1.0
  O  O10  1  0.157  0.410  0.961  1.0
  O  O11  1  0.843  0.590  0.039  1.0
  O  O12  1  0.997  0.467  0.757  1.0
  O  O13  1  0.003  0.533  0.243  1.0
  O  O14  1  0.585  0.388  0.821  1.0
  O  O15  1  0.415  0.612  0.179  1.0
  O  O16  1  0.551  0.654  0.692  1.0
  O  O17  1  0.449  0.346  0.308  1.0
  O  O18  1  0.536  0.959  0.727  1.0
  O  O19  1  0.464  0.041  0.273  1.0
  O  O20  1  0.687  0.833  0.908  1.0
  O  O21  1  0.313  0.167  0.092  1.0
  O  O22  1  0.369  0.785  0.893  1.0
  O  O23  1  0.631  0.215  0.107  1.0
  O  O24  1  0.029  0.811  0.586  1.0
  O  O25  1  0.971  0.189  0.414  1.0
  O  O26  1  0.735  0.420  0.602  1.0
  O  O27  1  0.265  0.580  0.398  1.0
  O  O28  1  0.009  0.796  0.731  1.0
  O  O29  1  0.991  0.204  0.269  1.0
  O  O30  1  0.172  0.889  0.549  1.0
  O  O31  1  0.828  0.111  0.451  1.0
[/CIF]
.