The compound described by TbTiSi is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Tb(1) is bonded in a 5-coordinate geometry to five equivalent Si(1) atoms. Ti(1) is bonded to four equivalent Si(1) atoms to form a mixture of distorted corner and edge-sharing TiSi4 cuboctahedra. Si(1) is bonded in a 9-coordinate geometry to five equivalent Tb(1) and four equivalent Ti(1) atoms. is represented by the CIF file [CIF]
data_TbTiSi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.021
_cell_length_b   4.021
_cell_length_c   7.718
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   124.799
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.750  0.750  0.349  1.0
  Tb  Tb1  1  0.250  0.250  0.651  1.0
  Ti  Ti2  1  0.750  0.250  0.000  1.0
  Ti  Ti3  1  0.250  0.750  0.000  1.0
  Si  Si4  1  0.750  0.750  0.767  1.0
  Si  Si5  1  0.250  0.250  0.233  1.0
[/CIF]
.
The compound described by TbTiSi is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Tb(1) is bonded in a 5-coordinate geometry to five equivalent Si(1) atoms. Ti(1) is bonded to four equivalent Si(1) atoms to form a mixture of distorted corner and edge-sharing TiSi4 cuboctahedra. Si(1) is bonded in a 9-coordinate geometry to five equivalent Tb(1) and four equivalent Ti(1) atoms. is represented by the CIF file [CIF]
data_TbTiSi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.021
_cell_length_b   4.021
_cell_length_c   7.718
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   124.799
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.750  0.750  0.349  1.0
  Tb  Tb1  1  0.250  0.250  0.651  1.0
  Ti  Ti2  1  0.750  0.250  0.000  1.0
  Ti  Ti3  1  0.250  0.750  0.000  1.0
  Si  Si4  1  0.750  0.750  0.767  1.0
  Si  Si5  1  0.250  0.250  0.233  1.0
[/CIF]
.