The structure described by Rb3H6Te(O2Cl)3 crystallizes in the trigonal R-3c space group. Rb(1) is bonded in a 5-coordinate geometry to two equivalent O(1) and three equivalent Cl(1) atoms. H(1) is bonded in a single-bond geometry to one O(1) atom. Te(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. O(1) is bonded in a 1-coordinate geometry to one Rb(1), one H(1), and one Te(1) atom. Cl(1) is bonded in a distorted T-shaped geometry to three equivalent Rb(1) atoms. is represented by the CIF file [CIF]
data_Rb3TeH6(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.262
_cell_length_b   9.262
_cell_length_c   9.262
_cell_angle_alpha   106.206
_cell_angle_beta   106.206
_cell_angle_gamma   106.206
_symmetry_Int_Tables_number   1
_cell_volume   675.492
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.796  0.704  1.0
  Rb  Rb1  1  0.704  0.250  0.796  1.0
  Rb  Rb2  1  0.796  0.704  0.250  1.0
  Rb  Rb3  1  0.204  0.296  0.750  1.0
  Rb  Rb4  1  0.750  0.204  0.296  1.0
  Rb  Rb5  1  0.296  0.750  0.204  1.0
  Te  Te6  1  0.500  0.500  0.500  1.0
  Te  Te7  1  0.000  0.000  0.000  1.0
  H  H8  1  0.201  0.427  0.403  1.0
  H  H9  1  0.403  0.201  0.427  1.0
  H  H10  1  0.427  0.403  0.201  1.0
  H  H11  1  0.903  0.927  0.701  1.0
  H  H12  1  0.701  0.903  0.927  1.0
  H  H13  1  0.927  0.701  0.903  1.0
  H  H14  1  0.799  0.573  0.597  1.0
  H  H15  1  0.597  0.799  0.573  1.0
  H  H16  1  0.573  0.597  0.799  1.0
  H  H17  1  0.097  0.073  0.299  1.0
  H  H18  1  0.299  0.097  0.073  1.0
  H  H19  1  0.073  0.299  0.097  1.0
  Cl  Cl20  1  0.250  0.017  0.483  1.0
  Cl  Cl21  1  0.483  0.250  0.017  1.0
  Cl  Cl22  1  0.017  0.483  0.250  1.0
  Cl  Cl23  1  0.983  0.517  0.750  1.0
  Cl  Cl24  1  0.750  0.983  0.517  1.0
  Cl  Cl25  1  0.517  0.750  0.983  1.0
  O  O26  1  0.280  0.420  0.497  1.0
  O  O27  1  0.497  0.280  0.420  1.0
  O  O28  1  0.420  0.497  0.280  1.0
  O  O29  1  0.997  0.920  0.780  1.0
  O  O30  1  0.780  0.997  0.920  1.0
  O  O31  1  0.920  0.780  0.997  1.0
  O  O32  1  0.720  0.580  0.503  1.0
  O  O33  1  0.503  0.720  0.580  1.0
  O  O34  1  0.580  0.503  0.720  1.0
  O  O35  1  0.003  0.080  0.220  1.0
  O  O36  1  0.220  0.003  0.080  1.0
  O  O37  1  0.080  0.220  0.003  1.0
[/CIF]
.
The structure described by Rb3H6Te(O2Cl)3 crystallizes in the trigonal R-3c space group. Rb(1) is bonded in a 5-coordinate geometry to two equivalent O(1) and three equivalent Cl(1) atoms. H(1) is bonded in a single-bond geometry to one O(1) atom. Te(1) is bonded in an octahedral geometry to six equivalent O(1) atoms. O(1) is bonded in a 1-coordinate geometry to one Rb(1), one H(1), and one Te(1) atom. Cl(1) is bonded in a distorted T-shaped geometry to three equivalent Rb(1) atoms. is represented by the CIF file [CIF]
data_Rb3TeH6(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.262
_cell_length_b   9.262
_cell_length_c   9.262
_cell_angle_alpha   106.206
_cell_angle_beta   106.206
_cell_angle_gamma   106.206
_symmetry_Int_Tables_number   1
_cell_volume   675.492
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.796  0.704  1.0
  Rb  Rb1  1  0.704  0.250  0.796  1.0
  Rb  Rb2  1  0.796  0.704  0.250  1.0
  Rb  Rb3  1  0.204  0.296  0.750  1.0
  Rb  Rb4  1  0.750  0.204  0.296  1.0
  Rb  Rb5  1  0.296  0.750  0.204  1.0
  Te  Te6  1  0.500  0.500  0.500  1.0
  Te  Te7  1  0.000  0.000  0.000  1.0
  H  H8  1  0.201  0.427  0.403  1.0
  H  H9  1  0.403  0.201  0.427  1.0
  H  H10  1  0.427  0.403  0.201  1.0
  H  H11  1  0.903  0.927  0.701  1.0
  H  H12  1  0.701  0.903  0.927  1.0
  H  H13  1  0.927  0.701  0.903  1.0
  H  H14  1  0.799  0.573  0.597  1.0
  H  H15  1  0.597  0.799  0.573  1.0
  H  H16  1  0.573  0.597  0.799  1.0
  H  H17  1  0.097  0.073  0.299  1.0
  H  H18  1  0.299  0.097  0.073  1.0
  H  H19  1  0.073  0.299  0.097  1.0
  Cl  Cl20  1  0.250  0.017  0.483  1.0
  Cl  Cl21  1  0.483  0.250  0.017  1.0
  Cl  Cl22  1  0.017  0.483  0.250  1.0
  Cl  Cl23  1  0.983  0.517  0.750  1.0
  Cl  Cl24  1  0.750  0.983  0.517  1.0
  Cl  Cl25  1  0.517  0.750  0.983  1.0
  O  O26  1  0.280  0.420  0.497  1.0
  O  O27  1  0.497  0.280  0.420  1.0
  O  O28  1  0.420  0.497  0.280  1.0
  O  O29  1  0.997  0.920  0.780  1.0
  O  O30  1  0.780  0.997  0.920  1.0
  O  O31  1  0.920  0.780  0.997  1.0
  O  O32  1  0.720  0.580  0.503  1.0
  O  O33  1  0.503  0.720  0.580  1.0
  O  O34  1  0.580  0.503  0.720  1.0
  O  O35  1  0.003  0.080  0.220  1.0
  O  O36  1  0.220  0.003  0.080  1.0
  O  O37  1  0.080  0.220  0.003  1.0
[/CIF]
.