The compound described by LiSbPO5 crystallizes in the monoclinic Cc space group. Li(1) is bonded in a see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. Sb(1) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 45°. P(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-50°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Sb(1), and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Sb(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(1), one Sb(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. is represented by the CIF file [CIF]
data_LiSbPO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.543
_cell_length_b   5.543
_cell_length_c   7.493
_cell_angle_alpha   73.825
_cell_angle_beta   73.825
_cell_angle_gamma   98.289
_symmetry_Int_Tables_number   1
_cell_volume   206.127
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.792  0.413  0.644  1.0
  Li  Li1  1  0.413  0.792  0.144  1.0
  Sb  Sb2  1  0.014  0.009  0.490  1.0
  Sb  Sb3  1  0.009  0.014  0.990  1.0
  P  P4  1  0.653  0.340  0.252  1.0
  P  P5  1  0.340  0.653  0.752  1.0
  O  O6  1  0.914  0.100  0.741  1.0
  O  O7  1  0.847  0.330  0.370  1.0
  O  O8  1  0.619  0.703  0.607  1.0
  O  O9  1  0.673  0.138  0.142  1.0
  O  O10  1  0.703  0.619  0.107  1.0
  O  O11  1  0.275  0.374  0.903  1.0
  O  O12  1  0.330  0.847  0.870  1.0
  O  O13  1  0.374  0.275  0.403  1.0
  O  O14  1  0.138  0.673  0.642  1.0
  O  O15  1  0.100  0.914  0.241  1.0
[/CIF]
.
The compound described by LiSbPO5 crystallizes in the monoclinic Cc space group. Li(1) is bonded in a see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. Sb(1) is bonded to one O(2), one O(3), one O(4), one O(5), and two equivalent O(1) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 45°. P(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form PO4 tetrahedra that share corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 41-50°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Li(1), one Sb(1), and one P(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Li(1), one Sb(1), and one P(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Li(1), one Sb(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. is represented by the CIF file [CIF]
data_LiSbPO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.543
_cell_length_b   5.543
_cell_length_c   7.493
_cell_angle_alpha   73.825
_cell_angle_beta   73.825
_cell_angle_gamma   98.289
_symmetry_Int_Tables_number   1
_cell_volume   206.127
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.792  0.413  0.644  1.0
  Li  Li1  1  0.413  0.792  0.144  1.0
  Sb  Sb2  1  0.014  0.009  0.490  1.0
  Sb  Sb3  1  0.009  0.014  0.990  1.0
  P  P4  1  0.653  0.340  0.252  1.0
  P  P5  1  0.340  0.653  0.752  1.0
  O  O6  1  0.914  0.100  0.741  1.0
  O  O7  1  0.847  0.330  0.370  1.0
  O  O8  1  0.619  0.703  0.607  1.0
  O  O9  1  0.673  0.138  0.142  1.0
  O  O10  1  0.703  0.619  0.107  1.0
  O  O11  1  0.275  0.374  0.903  1.0
  O  O12  1  0.330  0.847  0.870  1.0
  O  O13  1  0.374  0.275  0.403  1.0
  O  O14  1  0.138  0.673  0.642  1.0
  O  O15  1  0.100  0.914  0.241  1.0
[/CIF]
.