The crystal structure described by VPbPO6 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to one O(1), one O(2), one O(3), one O(4), and two equivalent O(5) atoms to form distorted VO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra and  an edgeedge with one V(1)O6 octahedra. Pb(1) is bonded in a 5-coordinate geometry to one O(1), one O(4), one O(5), and two equivalent O(6) atoms. P(1) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form PO4 tetrahedra that share corners with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-61°. There are six inequivalent O sites. In the first O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one P(1) atom. In the second O site, O(1) is bonded in a 2-coordinate geometry to one V(1), one Pb(1), and one P(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. In the fourth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one V(1) and one Pb(1) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent V(1) and one Pb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VPPbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.964
_cell_length_b   5.701
_cell_length_c   8.576
_cell_angle_alpha   88.777
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   486.995
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.411  0.347  0.589  1.0
  V  V1  1  0.911  0.653  0.911  1.0
  V  V2  1  0.589  0.653  0.411  1.0
  V  V3  1  0.089  0.347  0.089  1.0
  P  P4  1  0.609  0.662  0.786  1.0
  P  P5  1  0.109  0.338  0.714  1.0
  P  P6  1  0.391  0.338  0.214  1.0
  P  P7  1  0.891  0.662  0.286  1.0
  Pb  Pb8  1  0.315  0.876  0.926  1.0
  Pb  Pb9  1  0.815  0.124  0.574  1.0
  Pb  Pb10  1  0.685  0.124  0.074  1.0
  Pb  Pb11  1  0.185  0.876  0.426  1.0
  O  O12  1  0.341  0.254  0.380  1.0
  O  O13  1  0.841  0.746  0.120  1.0
  O  O14  1  0.659  0.746  0.620  1.0
  O  O15  1  0.159  0.254  0.880  1.0
  O  O16  1  0.474  0.521  0.773  1.0
  O  O17  1  0.974  0.479  0.727  1.0
  O  O18  1  0.526  0.479  0.227  1.0
  O  O19  1  0.026  0.521  0.273  1.0
  O  O20  1  0.220  0.497  0.639  1.0
  O  O21  1  0.720  0.503  0.861  1.0
  O  O22  1  0.780  0.503  0.361  1.0
  O  O23  1  0.280  0.497  0.139  1.0
  O  O24  1  0.367  0.090  0.673  1.0
  O  O25  1  0.867  0.910  0.827  1.0
  O  O26  1  0.633  0.910  0.327  1.0
  O  O27  1  0.133  0.090  0.173  1.0
  O  O28  1  0.424  0.679  0.472  1.0
  O  O29  1  0.924  0.321  0.028  1.0
  O  O30  1  0.576  0.321  0.528  1.0
  O  O31  1  0.076  0.679  0.972  1.0
  O  O32  1  0.575  0.873  0.888  1.0
  O  O33  1  0.075  0.127  0.612  1.0
  O  O34  1  0.425  0.127  0.112  1.0
  O  O35  1  0.925  0.873  0.388  1.0
[/CIF]
.
The crystal structure described by VPbPO6 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to one O(1), one O(2), one O(3), one O(4), and two equivalent O(5) atoms to form distorted VO6 octahedra that share corners with three equivalent P(1)O4 tetrahedra and  an edgeedge with one V(1)O6 octahedra. Pb(1) is bonded in a 5-coordinate geometry to one O(1), one O(4), one O(5), and two equivalent O(6) atoms. P(1) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form PO4 tetrahedra that share corners with three equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-61°. There are six inequivalent O sites. In the first O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Pb(1) and one P(1) atom. In the second O site, O(1) is bonded in a 2-coordinate geometry to one V(1), one Pb(1), and one P(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. In the fourth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one V(1) and one P(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one V(1) and one Pb(1) atom. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent V(1) and one Pb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VPPbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.964
_cell_length_b   5.701
_cell_length_c   8.576
_cell_angle_alpha   88.777
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   486.995
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.411  0.347  0.589  1.0
  V  V1  1  0.911  0.653  0.911  1.0
  V  V2  1  0.589  0.653  0.411  1.0
  V  V3  1  0.089  0.347  0.089  1.0
  P  P4  1  0.609  0.662  0.786  1.0
  P  P5  1  0.109  0.338  0.714  1.0
  P  P6  1  0.391  0.338  0.214  1.0
  P  P7  1  0.891  0.662  0.286  1.0
  Pb  Pb8  1  0.315  0.876  0.926  1.0
  Pb  Pb9  1  0.815  0.124  0.574  1.0
  Pb  Pb10  1  0.685  0.124  0.074  1.0
  Pb  Pb11  1  0.185  0.876  0.426  1.0
  O  O12  1  0.341  0.254  0.380  1.0
  O  O13  1  0.841  0.746  0.120  1.0
  O  O14  1  0.659  0.746  0.620  1.0
  O  O15  1  0.159  0.254  0.880  1.0
  O  O16  1  0.474  0.521  0.773  1.0
  O  O17  1  0.974  0.479  0.727  1.0
  O  O18  1  0.526  0.479  0.227  1.0
  O  O19  1  0.026  0.521  0.273  1.0
  O  O20  1  0.220  0.497  0.639  1.0
  O  O21  1  0.720  0.503  0.861  1.0
  O  O22  1  0.780  0.503  0.361  1.0
  O  O23  1  0.280  0.497  0.139  1.0
  O  O24  1  0.367  0.090  0.673  1.0
  O  O25  1  0.867  0.910  0.827  1.0
  O  O26  1  0.633  0.910  0.327  1.0
  O  O27  1  0.133  0.090  0.173  1.0
  O  O28  1  0.424  0.679  0.472  1.0
  O  O29  1  0.924  0.321  0.028  1.0
  O  O30  1  0.576  0.321  0.528  1.0
  O  O31  1  0.076  0.679  0.972  1.0
  O  O32  1  0.575  0.873  0.888  1.0
  O  O33  1  0.075  0.127  0.612  1.0
  O  O34  1  0.425  0.127  0.112  1.0
  O  O35  1  0.925  0.873  0.388  1.0
[/CIF]
.