The material structure described by Sc(VGe)5 crystallizes in the monoclinic C2/m space group. Sc(1) is bonded in a 7-coordinate geometry to one Ge(1), one Ge(5), two equivalent Ge(3), and three equivalent Ge(4) atoms. There are four inequivalent V sites. In the first V site, V(1) is bonded in a 7-coordinate geometry to one Ge(4), two equivalent Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. In the second V site, V(2) is bonded in a 7-coordinate geometry to one Ge(5), two equivalent Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. In the third V site, V(3) is bonded in a 6-coordinate geometry to one Ge(1), one Ge(2), two equivalent Ge(4), and two equivalent Ge(5) atoms. In the fourth V site, V(4) is bonded in a 7-coordinate geometry to one Ge(2), one Ge(4), two equivalent Ge(3), and three equivalent Ge(5) atoms. There are five inequivalent Ge sites. In the first Ge site, Ge(5) is bonded in a 9-coordinate geometry to one Sc(1), one V(2), three equivalent V(4), and four equivalent V(3) atoms. In the second Ge site, Ge(1) is bonded in a 10-coordinate geometry to one Sc(1), two equivalent V(1), two equivalent V(2), two equivalent V(3), one Ge(1), and two equivalent Ge(2) atoms. In the third Ge site, Ge(2) is bonded in a 7-coordinate geometry to one V(4), two equivalent V(1), two equivalent V(2), two equivalent V(3), and two equivalent Ge(1) atoms. In the fourth Ge site, Ge(3) is bonded in a 10-coordinate geometry to two equivalent Sc(1), two equivalent V(1), two equivalent V(2), two equivalent V(4), and two equivalent Ge(3) atoms. In the fifth Ge site, Ge(4) is bonded in a 9-coordinate geometry to three equivalent Sc(1), one V(1), one V(4), and four equivalent V(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sc(VGe)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.087
_cell_length_b   7.771
_cell_length_c   9.485
_cell_angle_alpha   65.762
_cell_angle_beta   74.445
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   326.801
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.357  0.745  0.286  1.0
  Sc  Sc1  1  0.643  0.255  0.714  1.0
  V  V2  1  0.064  0.322  0.872  1.0
  V  V3  1  0.936  0.678  0.128  1.0
  V  V4  1  0.435  0.190  0.130  1.0
  V  V5  1  0.565  0.810  0.870  1.0
  V  V6  1  0.942  0.691  0.619  1.0
  V  V7  1  0.561  0.309  0.381  1.0
  V  V8  1  0.058  0.309  0.381  1.0
  V  V9  1  0.439  0.691  0.619  1.0
  V  V10  1  0.144  0.030  0.712  1.0
  V  V11  1  0.856  0.970  0.288  1.0
  Ge  Ge12  1  0.434  0.522  0.132  1.0
  Ge  Ge13  1  0.566  0.478  0.868  1.0
  Ge  Ge14  1  0.068  0.665  0.865  1.0
  Ge  Ge15  1  0.932  0.335  0.135  1.0
  Ge  Ge16  1  0.246  0.000  0.000  1.0
  Ge  Ge17  1  0.754  0.000  0.000  1.0
  Ge  Ge18  1  0.211  0.408  0.579  1.0
  Ge  Ge19  1  0.789  0.592  0.421  1.0
  Ge  Ge20  1  0.286  0.992  0.428  1.0
  Ge  Ge21  1  0.714  0.008  0.572  1.0
[/CIF]
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The material structure described by Sc(VGe)5 crystallizes in the monoclinic C2/m space group. Sc(1) is bonded in a 7-coordinate geometry to one Ge(1), one Ge(5), two equivalent Ge(3), and three equivalent Ge(4) atoms. There are four inequivalent V sites. In the first V site, V(1) is bonded in a 7-coordinate geometry to one Ge(4), two equivalent Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. In the second V site, V(2) is bonded in a 7-coordinate geometry to one Ge(5), two equivalent Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. In the third V site, V(3) is bonded in a 6-coordinate geometry to one Ge(1), one Ge(2), two equivalent Ge(4), and two equivalent Ge(5) atoms. In the fourth V site, V(4) is bonded in a 7-coordinate geometry to one Ge(2), one Ge(4), two equivalent Ge(3), and three equivalent Ge(5) atoms. There are five inequivalent Ge sites. In the first Ge site, Ge(5) is bonded in a 9-coordinate geometry to one Sc(1), one V(2), three equivalent V(4), and four equivalent V(3) atoms. In the second Ge site, Ge(1) is bonded in a 10-coordinate geometry to one Sc(1), two equivalent V(1), two equivalent V(2), two equivalent V(3), one Ge(1), and two equivalent Ge(2) atoms. In the third Ge site, Ge(2) is bonded in a 7-coordinate geometry to one V(4), two equivalent V(1), two equivalent V(2), two equivalent V(3), and two equivalent Ge(1) atoms. In the fourth Ge site, Ge(3) is bonded in a 10-coordinate geometry to two equivalent Sc(1), two equivalent V(1), two equivalent V(2), two equivalent V(4), and two equivalent Ge(3) atoms. In the fifth Ge site, Ge(4) is bonded in a 9-coordinate geometry to three equivalent Sc(1), one V(1), one V(4), and four equivalent V(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sc(VGe)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.087
_cell_length_b   7.771
_cell_length_c   9.485
_cell_angle_alpha   65.762
_cell_angle_beta   74.445
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   326.801
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.357  0.745  0.286  1.0
  Sc  Sc1  1  0.643  0.255  0.714  1.0
  V  V2  1  0.064  0.322  0.872  1.0
  V  V3  1  0.936  0.678  0.128  1.0
  V  V4  1  0.435  0.190  0.130  1.0
  V  V5  1  0.565  0.810  0.870  1.0
  V  V6  1  0.942  0.691  0.619  1.0
  V  V7  1  0.561  0.309  0.381  1.0
  V  V8  1  0.058  0.309  0.381  1.0
  V  V9  1  0.439  0.691  0.619  1.0
  V  V10  1  0.144  0.030  0.712  1.0
  V  V11  1  0.856  0.970  0.288  1.0
  Ge  Ge12  1  0.434  0.522  0.132  1.0
  Ge  Ge13  1  0.566  0.478  0.868  1.0
  Ge  Ge14  1  0.068  0.665  0.865  1.0
  Ge  Ge15  1  0.932  0.335  0.135  1.0
  Ge  Ge16  1  0.246  0.000  0.000  1.0
  Ge  Ge17  1  0.754  0.000  0.000  1.0
  Ge  Ge18  1  0.211  0.408  0.579  1.0
  Ge  Ge19  1  0.789  0.592  0.421  1.0
  Ge  Ge20  1  0.286  0.992  0.428  1.0
  Ge  Ge21  1  0.714  0.008  0.572  1.0
[/CIF]
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