The material described by RbAuC2(NS)2 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted linear geometry to two equivalent S(1) atoms. In the second Au site, Au(2) is bonded in a distorted linear geometry to two equivalent S(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2) and one S(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one C(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one C(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 2-coordinate geometry to one Au(1) and one C(1) atom. In the second S site, S(2) is bonded in a 2-coordinate geometry to one Au(2) and one C(2) atom. is represented by the CIF card [CIF]
data_RbAuC2(SN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.409
_cell_length_b   7.409
_cell_length_c   18.052
_cell_angle_alpha   73.223
_cell_angle_beta   73.223
_cell_angle_gamma   50.390
_symmetry_Int_Tables_number   1
_cell_volume   723.597
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.191  0.162  0.439  1.0
  Rb  Rb1  1  0.838  0.809  0.061  1.0
  Rb  Rb2  1  0.162  0.191  0.939  1.0
  Rb  Rb3  1  0.809  0.838  0.561  1.0
  Au  Au4  1  0.664  0.336  0.250  1.0
  Au  Au5  1  0.336  0.664  0.750  1.0
  Au  Au6  1  0.166  0.834  0.250  1.0
  Au  Au7  1  0.834  0.166  0.750  1.0
  C  C8  1  0.585  0.455  0.587  1.0
  C  C9  1  0.827  0.717  0.356  1.0
  C  C10  1  0.173  0.283  0.644  1.0
  C  C11  1  0.545  0.415  0.913  1.0
  C  C12  1  0.415  0.545  0.413  1.0
  C  C13  1  0.283  0.173  0.144  1.0
  C  C14  1  0.717  0.827  0.856  1.0
  C  C15  1  0.455  0.585  0.087  1.0
  S  S16  1  0.708  0.336  0.115  1.0
  S  S17  1  0.005  0.361  0.729  1.0
  S  S18  1  0.336  0.708  0.615  1.0
  S  S19  1  0.292  0.664  0.885  1.0
  S  S20  1  0.639  0.995  0.771  1.0
  S  S21  1  0.361  0.005  0.229  1.0
  S  S22  1  0.664  0.292  0.385  1.0
  S  S23  1  0.995  0.639  0.271  1.0
  N  N24  1  0.760  0.280  0.564  1.0
  N  N25  1  0.286  0.240  0.581  1.0
  N  N26  1  0.720  0.240  0.936  1.0
  N  N27  1  0.760  0.714  0.919  1.0
  N  N28  1  0.240  0.286  0.081  1.0
  N  N29  1  0.280  0.760  0.064  1.0
  N  N30  1  0.714  0.760  0.419  1.0
  N  N31  1  0.240  0.720  0.436  1.0
[/CIF]
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The material described by RbAuC2(NS)2 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent N(2) atoms. There are two inequivalent Au sites. In the first Au site, Au(1) is bonded in a distorted linear geometry to two equivalent S(1) atoms. In the second Au site, Au(2) is bonded in a distorted linear geometry to two equivalent S(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2) and one S(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one C(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one C(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 2-coordinate geometry to one Au(1) and one C(1) atom. In the second S site, S(2) is bonded in a 2-coordinate geometry to one Au(2) and one C(2) atom. is represented by the CIF card [CIF]
data_RbAuC2(SN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.409
_cell_length_b   7.409
_cell_length_c   18.052
_cell_angle_alpha   73.223
_cell_angle_beta   73.223
_cell_angle_gamma   50.390
_symmetry_Int_Tables_number   1
_cell_volume   723.597
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.191  0.162  0.439  1.0
  Rb  Rb1  1  0.838  0.809  0.061  1.0
  Rb  Rb2  1  0.162  0.191  0.939  1.0
  Rb  Rb3  1  0.809  0.838  0.561  1.0
  Au  Au4  1  0.664  0.336  0.250  1.0
  Au  Au5  1  0.336  0.664  0.750  1.0
  Au  Au6  1  0.166  0.834  0.250  1.0
  Au  Au7  1  0.834  0.166  0.750  1.0
  C  C8  1  0.585  0.455  0.587  1.0
  C  C9  1  0.827  0.717  0.356  1.0
  C  C10  1  0.173  0.283  0.644  1.0
  C  C11  1  0.545  0.415  0.913  1.0
  C  C12  1  0.415  0.545  0.413  1.0
  C  C13  1  0.283  0.173  0.144  1.0
  C  C14  1  0.717  0.827  0.856  1.0
  C  C15  1  0.455  0.585  0.087  1.0
  S  S16  1  0.708  0.336  0.115  1.0
  S  S17  1  0.005  0.361  0.729  1.0
  S  S18  1  0.336  0.708  0.615  1.0
  S  S19  1  0.292  0.664  0.885  1.0
  S  S20  1  0.639  0.995  0.771  1.0
  S  S21  1  0.361  0.005  0.229  1.0
  S  S22  1  0.664  0.292  0.385  1.0
  S  S23  1  0.995  0.639  0.271  1.0
  N  N24  1  0.760  0.280  0.564  1.0
  N  N25  1  0.286  0.240  0.581  1.0
  N  N26  1  0.720  0.240  0.936  1.0
  N  N27  1  0.760  0.714  0.919  1.0
  N  N28  1  0.240  0.286  0.081  1.0
  N  N29  1  0.280  0.760  0.064  1.0
  N  N30  1  0.714  0.760  0.419  1.0
  N  N31  1  0.240  0.720  0.436  1.0
[/CIF]
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