The material described by MgVWZn2O6 is Aluminum carbonitride-derived structured and crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(6) atom to form distorted MgO5 trigonal bipyramids that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one Zn(1)O4 trigonal pyramid, edges with two equivalent W(1)O6 octahedra, and  an edgeedge with one Zn(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 23°. V(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(4), one O(5), and one O(6) atom. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share  a cornercorner with one Mg(1)O5 trigonal bipyramid, corners with four equivalent Zn(1)O4 trigonal pyramids, and edges with two equivalent Mg(1)O5 trigonal bipyramids. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form distorted ZnO4 trigonal pyramids that share corners with four equivalent W(1)O6 octahedra,  a cornercorner with one Mg(1)O5 trigonal bipyramid, and  an edgeedge with one Mg(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 59-70°. In the second Zn site, Zn(2) is bonded in a 4-coordinate geometry to one O(2), one O(3), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Mg(1), one V(1), one W(1), and one Zn(1) atom to form distorted corner-sharing OMgVZnW trigonal pyramids. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Mg(1), one W(1), one Zn(1), and one Zn(2) atom. In the third O site, O(3) is bonded to one V(1), one W(1), one Zn(1), and one Zn(2) atom to form distorted corner-sharing OVZn2W tetrahedra. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Mg(1), one V(1), one W(1), one Zn(1), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Mg(1), one V(1), and one W(1) atom. In the sixth O site, O(6) is bonded in a distorted see-saw-like geometry to one Mg(1), one V(1), one W(1), and one Zn(2) atom. is represented by the CIF card [CIF]
data_MgVZn2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.333
_cell_length_b   5.753
_cell_length_c   8.793
_cell_angle_alpha   102.859
_cell_angle_beta   135.563
_cell_angle_gamma   107.321
_symmetry_Int_Tables_number   1
_cell_volume   136.843
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.635  0.125  0.617  1.0
  V  V1  1  0.585  0.765  0.244  1.0
  Zn  Zn2  1  0.877  0.459  0.210  1.0
  Zn  Zn3  1  0.991  0.696  0.671  1.0
  W  W4  1  0.997  0.968  0.021  1.0
  O  O5  1  0.903  0.837  0.202  1.0
  O  O6  1  0.190  0.133  0.897  1.0
  O  O7  1  0.297  0.464  0.262  1.0
  O  O8  1  0.289  0.809  0.611  1.0
  O  O9  1  0.683  0.126  0.405  1.0
  O  O10  1  0.934  0.576  0.846  1.0
[/CIF]
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The material described by MgVWZn2O6 is Aluminum carbonitride-derived structured and crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(2), one O(4), one O(5), and one O(6) atom to form distorted MgO5 trigonal bipyramids that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one Zn(1)O4 trigonal pyramid, edges with two equivalent W(1)O6 octahedra, and  an edgeedge with one Zn(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 23°. V(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), one O(4), one O(5), and one O(6) atom. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share  a cornercorner with one Mg(1)O5 trigonal bipyramid, corners with four equivalent Zn(1)O4 trigonal pyramids, and edges with two equivalent Mg(1)O5 trigonal bipyramids. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form distorted ZnO4 trigonal pyramids that share corners with four equivalent W(1)O6 octahedra,  a cornercorner with one Mg(1)O5 trigonal bipyramid, and  an edgeedge with one Mg(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 59-70°. In the second Zn site, Zn(2) is bonded in a 4-coordinate geometry to one O(2), one O(3), one O(4), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded to one Mg(1), one V(1), one W(1), and one Zn(1) atom to form distorted corner-sharing OMgVZnW trigonal pyramids. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Mg(1), one W(1), one Zn(1), and one Zn(2) atom. In the third O site, O(3) is bonded to one V(1), one W(1), one Zn(1), and one Zn(2) atom to form distorted corner-sharing OVZn2W tetrahedra. In the fourth O site, O(4) is bonded in a 5-coordinate geometry to one Mg(1), one V(1), one W(1), one Zn(1), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Mg(1), one V(1), and one W(1) atom. In the sixth O site, O(6) is bonded in a distorted see-saw-like geometry to one Mg(1), one V(1), one W(1), and one Zn(2) atom. is represented by the CIF card [CIF]
data_MgVZn2WO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.333
_cell_length_b   5.753
_cell_length_c   8.793
_cell_angle_alpha   102.859
_cell_angle_beta   135.563
_cell_angle_gamma   107.321
_symmetry_Int_Tables_number   1
_cell_volume   136.843
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.635  0.125  0.617  1.0
  V  V1  1  0.585  0.765  0.244  1.0
  Zn  Zn2  1  0.877  0.459  0.210  1.0
  Zn  Zn3  1  0.991  0.696  0.671  1.0
  W  W4  1  0.997  0.968  0.021  1.0
  O  O5  1  0.903  0.837  0.202  1.0
  O  O6  1  0.190  0.133  0.897  1.0
  O  O7  1  0.297  0.464  0.262  1.0
  O  O8  1  0.289  0.809  0.611  1.0
  O  O9  1  0.683  0.126  0.405  1.0
  O  O10  1  0.934  0.576  0.846  1.0
[/CIF]
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