The compound described by MgV(CO3)2 is Calcite-derived structured and crystallizes in the trigonal R-3 space group. Mg(1) is bonded to six equivalent O(1) atoms to form MgO6 octahedra that share corners with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 60°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles are 60°. C(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. O(1) is bonded in a trigonal planar geometry to one Mg(1), one V(1), and one C(1) atom. is represented by the CIF card [CIF]
data_MgV(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.749
_cell_length_b   5.796
_cell_length_c   4.749
_cell_angle_alpha   65.815
_cell_angle_beta   119.998
_cell_angle_gamma   114.184
_symmetry_Int_Tables_number   1
_cell_volume   99.743
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.500  0.500  0.500  1.0
  C  C2  1  0.252  0.756  0.748  1.0
  C  C3  1  0.748  0.244  0.252  1.0
  O  O4  1  0.017  0.245  0.243  1.0
  O  O5  1  0.529  0.755  0.017  1.0
  O  O6  1  0.243  0.755  0.471  1.0
  O  O7  1  0.757  0.245  0.529  1.0
  O  O8  1  0.471  0.245  0.983  1.0
  O  O9  1  0.983  0.755  0.757  1.0
[/CIF]
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The compound described by MgV(CO3)2 is Calcite-derived structured and crystallizes in the trigonal R-3 space group. Mg(1) is bonded to six equivalent O(1) atoms to form MgO6 octahedra that share corners with six equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles are 60°. V(1) is bonded to six equivalent O(1) atoms to form VO6 octahedra that share corners with six equivalent Mg(1)O6 octahedra. The corner-sharing octahedral tilt angles are 60°. C(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. O(1) is bonded in a trigonal planar geometry to one Mg(1), one V(1), and one C(1) atom. is represented by the CIF card [CIF]
data_MgV(CO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.749
_cell_length_b   5.796
_cell_length_c   4.749
_cell_angle_alpha   65.815
_cell_angle_beta   119.998
_cell_angle_gamma   114.184
_symmetry_Int_Tables_number   1
_cell_volume   99.743
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.500  0.500  0.500  1.0
  C  C2  1  0.252  0.756  0.748  1.0
  C  C3  1  0.748  0.244  0.252  1.0
  O  O4  1  0.017  0.245  0.243  1.0
  O  O5  1  0.529  0.755  0.017  1.0
  O  O6  1  0.243  0.755  0.471  1.0
  O  O7  1  0.757  0.245  0.529  1.0
  O  O8  1  0.471  0.245  0.983  1.0
  O  O9  1  0.983  0.755  0.757  1.0
[/CIF]
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