The crystal structure described by IrCl6(RuN3Cl2)2(N2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, two IrCl6 clusters, and four RuN3Cl2 clusters. In each IrCl6 cluster, Ir(1) is bonded in an octahedral geometry to two equivalent Cl(4) and four equivalent Cl(1,5) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(1,5) is bonded in a single-bond geometry to one Ir(1) atom. In each RuN3Cl2 cluster, Ru(1) is bonded in a tetrahedral geometry to one N(3), two equivalent N(1), and one Cl(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second N site, N(3) is bonded in a distorted bent 150 degrees geometry to one Ru(1) and one Cl(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one N(3) atom. is represented by the CIF card [CIF]
data_IrRu2(NCl)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.330
_cell_length_b   7.330
_cell_length_c   15.807
_cell_angle_alpha   74.527
_cell_angle_beta   74.527
_cell_angle_gamma   74.724
_symmetry_Int_Tables_number   1
_cell_volume   771.755
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ir  Ir0  1  0.000  0.000  0.000  1.0
  Ru  Ru1  1  0.368  0.368  0.412  1.0
  Ru  Ru2  1  0.632  0.632  0.588  1.0
  N  N3  1  0.532  0.224  0.473  1.0
  N  N4  1  0.468  0.776  0.527  1.0
  N  N5  1  0.776  0.468  0.527  1.0
  N  N6  1  0.224  0.532  0.473  1.0
  N  N7  1  0.347  0.222  0.162  1.0
  N  N8  1  0.653  0.778  0.838  1.0
  N  N9  1  0.778  0.653  0.838  1.0
  N  N10  1  0.222  0.347  0.162  1.0
  N  N11  1  0.504  0.504  0.304  1.0
  N  N12  1  0.496  0.496  0.696  1.0
  Cl  Cl13  1  0.742  0.258  0.000  1.0
  Cl  Cl14  1  0.258  0.742  0.000  1.0
  Cl  Cl15  1  0.815  0.815  0.606  1.0
  Cl  Cl16  1  0.185  0.185  0.394  1.0
  Cl  Cl17  1  0.649  0.649  0.275  1.0
  Cl  Cl18  1  0.351  0.351  0.725  1.0
  Cl  Cl19  1  0.977  0.977  0.152  1.0
  Cl  Cl20  1  0.023  0.023  0.848  1.0
  Cl  Cl21  1  0.793  0.793  0.036  1.0
  Cl  Cl22  1  0.207  0.207  0.964  1.0
[/CIF]
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The crystal structure described by IrCl6(RuN3Cl2)2(N2)2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four 7727-37-9 molecules, two IrCl6 clusters, and four RuN3Cl2 clusters. In each IrCl6 cluster, Ir(1) is bonded in an octahedral geometry to two equivalent Cl(4) and four equivalent Cl(1,5) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(4) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(1,5) is bonded in a single-bond geometry to one Ir(1) atom. In each RuN3Cl2 cluster, Ru(1) is bonded in a tetrahedral geometry to one N(3), two equivalent N(1), and one Cl(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one Ru(1) atom. In the second N site, N(3) is bonded in a distorted bent 150 degrees geometry to one Ru(1) and one Cl(3) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Ru(1) atom. In the second Cl site, Cl(3) is bonded in a single-bond geometry to one N(3) atom. is represented by the CIF card [CIF]
data_IrRu2(NCl)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.330
_cell_length_b   7.330
_cell_length_c   15.807
_cell_angle_alpha   74.527
_cell_angle_beta   74.527
_cell_angle_gamma   74.724
_symmetry_Int_Tables_number   1
_cell_volume   771.755
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ir  Ir0  1  0.000  0.000  0.000  1.0
  Ru  Ru1  1  0.368  0.368  0.412  1.0
  Ru  Ru2  1  0.632  0.632  0.588  1.0
  N  N3  1  0.532  0.224  0.473  1.0
  N  N4  1  0.468  0.776  0.527  1.0
  N  N5  1  0.776  0.468  0.527  1.0
  N  N6  1  0.224  0.532  0.473  1.0
  N  N7  1  0.347  0.222  0.162  1.0
  N  N8  1  0.653  0.778  0.838  1.0
  N  N9  1  0.778  0.653  0.838  1.0
  N  N10  1  0.222  0.347  0.162  1.0
  N  N11  1  0.504  0.504  0.304  1.0
  N  N12  1  0.496  0.496  0.696  1.0
  Cl  Cl13  1  0.742  0.258  0.000  1.0
  Cl  Cl14  1  0.258  0.742  0.000  1.0
  Cl  Cl15  1  0.815  0.815  0.606  1.0
  Cl  Cl16  1  0.185  0.185  0.394  1.0
  Cl  Cl17  1  0.649  0.649  0.275  1.0
  Cl  Cl18  1  0.351  0.351  0.725  1.0
  Cl  Cl19  1  0.977  0.977  0.152  1.0
  Cl  Cl20  1  0.023  0.023  0.848  1.0
  Cl  Cl21  1  0.793  0.793  0.036  1.0
  Cl  Cl22  1  0.207  0.207  0.964  1.0
[/CIF]
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