The material structure described by Na2Pt(OCl)6 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one Cl(1), one Cl(2), and one Cl(3) atom. Pt(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one O(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Na(1) and one O(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Na(1) and one O(2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a bent 150 degrees geometry to one Na(1) and one Pt(1) atom. In the second Cl site, Cl(2) is bonded in an L-shaped geometry to one Na(1) and one Pt(1) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to one Na(1) and one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na2Pt(ClO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.987
_cell_length_b   7.229
_cell_length_c   7.587
_cell_angle_alpha   103.524
_cell_angle_beta   87.279
_cell_angle_gamma   112.107
_symmetry_Int_Tables_number   1
_cell_volume   344.811
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.749  0.440  0.726  1.0
  Na  Na1  1  0.251  0.560  0.274  1.0
  Pt  Pt2  1  0.000  0.000  0.000  1.0
  Cl  Cl3  1  0.213  0.835  0.064  1.0
  Cl  Cl4  1  0.787  0.165  0.936  1.0
  Cl  Cl5  1  0.006  0.857  0.689  1.0
  Cl  Cl6  1  0.994  0.143  0.311  1.0
  Cl  Cl7  1  0.697  0.716  0.015  1.0
  Cl  Cl8  1  0.303  0.284  0.985  1.0
  O  O9  1  0.503  0.937  0.430  1.0
  O  O10  1  0.497  0.063  0.570  1.0
  O  O11  1  0.698  0.498  0.380  1.0
  O  O12  1  0.302  0.502  0.620  1.0
  O  O13  1  0.152  0.479  0.718  1.0
  O  O14  1  0.848  0.521  0.282  1.0
[/CIF]
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The material structure described by Na2Pt(OCl)6 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one Cl(1), one Cl(2), and one Cl(3) atom. Pt(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one O(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Na(1) and one O(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Na(1) and one O(2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a bent 150 degrees geometry to one Na(1) and one Pt(1) atom. In the second Cl site, Cl(2) is bonded in an L-shaped geometry to one Na(1) and one Pt(1) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to one Na(1) and one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na2Pt(ClO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.987
_cell_length_b   7.229
_cell_length_c   7.587
_cell_angle_alpha   103.524
_cell_angle_beta   87.279
_cell_angle_gamma   112.107
_symmetry_Int_Tables_number   1
_cell_volume   344.811
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.749  0.440  0.726  1.0
  Na  Na1  1  0.251  0.560  0.274  1.0
  Pt  Pt2  1  0.000  0.000  0.000  1.0
  Cl  Cl3  1  0.213  0.835  0.064  1.0
  Cl  Cl4  1  0.787  0.165  0.936  1.0
  Cl  Cl5  1  0.006  0.857  0.689  1.0
  Cl  Cl6  1  0.994  0.143  0.311  1.0
  Cl  Cl7  1  0.697  0.716  0.015  1.0
  Cl  Cl8  1  0.303  0.284  0.985  1.0
  O  O9  1  0.503  0.937  0.430  1.0
  O  O10  1  0.497  0.063  0.570  1.0
  O  O11  1  0.698  0.498  0.380  1.0
  O  O12  1  0.302  0.502  0.620  1.0
  O  O13  1  0.152  0.479  0.718  1.0
  O  O14  1  0.848  0.521  0.282  1.0
[/CIF]
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