The structure described by K5MoC7N7O crystallizes in the triclinic P1 space group. There are five inequivalent K sites. In the first K site, K(1) is bonded in a 2-coordinate geometry to one N(2) and one O(1) atom. In the second K site, K(2) is bonded in a 4-coordinate geometry to one N(1), one N(2), one N(3), and one N(7) atom. In the third K site, K(3) is bonded in a 4-coordinate geometry to one N(4), one N(5), one N(6), and one O(1) atom. In the fourth K site, K(4) is bonded in a 6-coordinate geometry to one N(1), one N(2), one N(4), one N(5), one N(6), and one N(7) atom. In the fifth K site, K(5) is bonded in a 5-coordinate geometry to one N(1), one N(3), one N(4), one N(6), and one O(1) atom. Mo(1) is bonded in a pentagonal bipyramidal geometry to one C(1), one C(2), one C(3), one C(4), one C(5), one C(6), and one C(7) atom. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one Mo(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one Mo(1) and one N(2) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one Mo(1) and one N(3) atom. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one Mo(1) and one N(4) atom. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one Mo(1) and one N(5) atom. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one Mo(1) and one N(6) atom. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one Mo(1) and one N(7) atom. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one K(2), one K(4), one K(5), and one C(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), one K(4), and one C(2) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one K(2), one K(5), and one C(3) atom. In the fourth N site, N(4) is bonded in a distorted single-bond geometry to one K(3), one K(4), one K(5), and one C(4) atom. In the fifth N site, N(5) is bonded in a distorted single-bond geometry to one K(3), one K(4), and one C(5) atom. In the sixth N site, N(6) is bonded in a distorted single-bond geometry to one K(3), one K(4), one K(5), and one C(6) atom. In the seventh N site, N(7) is bonded in a distorted single-bond geometry to one K(2), one K(4), and one C(7) atom. O(1) is bonded in a trigonal non-coplanar geometry to one K(1), one K(3), and one K(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K5MoC7N7O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.873
_cell_length_b   7.927
_cell_length_c   8.137
_cell_angle_alpha   107.970
_cell_angle_beta   109.256
_cell_angle_gamma   108.168
_symmetry_Int_Tables_number   1
_cell_volume   404.830
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.604  0.252  0.084  1.0
  K  K1  1  0.835  0.314  0.679  1.0
  K  K2  1  0.094  0.827  0.451  1.0
  K  K3  1  0.356  0.482  0.611  1.0
  K  K4  1  0.488  0.726  0.231  1.0
  Mo  Mo5  1  0.998  0.999  0.994  1.0
  C  C6  1  0.115  0.802  0.871  1.0
  C  C7  1  0.822  0.709  0.966  1.0
  C  C8  1  0.891  0.047  0.212  1.0
  C  C9  1  0.068  0.316  0.125  1.0
  C  C10  1  0.140  0.140  0.851  1.0
  C  C11  1  0.705  0.938  0.771  1.0
  C  C12  1  0.286  0.102  0.245  1.0
  N  N13  1  0.193  0.705  0.822  1.0
  N  N14  1  0.718  0.552  0.945  1.0
  N  N15  1  0.839  0.082  0.333  1.0
  N  N16  1  0.110  0.486  0.204  1.0
  N  N17  1  0.214  0.222  0.775  1.0
  N  N18  1  0.546  0.911  0.660  1.0
  N  N19  1  0.444  0.167  0.383  1.0
  O  O20  1  0.733  0.593  0.375  1.0
[/CIF]
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The structure described by K5MoC7N7O crystallizes in the triclinic P1 space group. There are five inequivalent K sites. In the first K site, K(1) is bonded in a 2-coordinate geometry to one N(2) and one O(1) atom. In the second K site, K(2) is bonded in a 4-coordinate geometry to one N(1), one N(2), one N(3), and one N(7) atom. In the third K site, K(3) is bonded in a 4-coordinate geometry to one N(4), one N(5), one N(6), and one O(1) atom. In the fourth K site, K(4) is bonded in a 6-coordinate geometry to one N(1), one N(2), one N(4), one N(5), one N(6), and one N(7) atom. In the fifth K site, K(5) is bonded in a 5-coordinate geometry to one N(1), one N(3), one N(4), one N(6), and one O(1) atom. Mo(1) is bonded in a pentagonal bipyramidal geometry to one C(1), one C(2), one C(3), one C(4), one C(5), one C(6), and one C(7) atom. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one Mo(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one Mo(1) and one N(2) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one Mo(1) and one N(3) atom. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one Mo(1) and one N(4) atom. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one Mo(1) and one N(5) atom. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one Mo(1) and one N(6) atom. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one Mo(1) and one N(7) atom. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one K(2), one K(4), one K(5), and one C(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one K(1), one K(2), one K(4), and one C(2) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one K(2), one K(5), and one C(3) atom. In the fourth N site, N(4) is bonded in a distorted single-bond geometry to one K(3), one K(4), one K(5), and one C(4) atom. In the fifth N site, N(5) is bonded in a distorted single-bond geometry to one K(3), one K(4), and one C(5) atom. In the sixth N site, N(6) is bonded in a distorted single-bond geometry to one K(3), one K(4), one K(5), and one C(6) atom. In the seventh N site, N(7) is bonded in a distorted single-bond geometry to one K(2), one K(4), and one C(7) atom. O(1) is bonded in a trigonal non-coplanar geometry to one K(1), one K(3), and one K(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K5MoC7N7O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.873
_cell_length_b   7.927
_cell_length_c   8.137
_cell_angle_alpha   107.970
_cell_angle_beta   109.256
_cell_angle_gamma   108.168
_symmetry_Int_Tables_number   1
_cell_volume   404.830
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.604  0.252  0.084  1.0
  K  K1  1  0.835  0.314  0.679  1.0
  K  K2  1  0.094  0.827  0.451  1.0
  K  K3  1  0.356  0.482  0.611  1.0
  K  K4  1  0.488  0.726  0.231  1.0
  Mo  Mo5  1  0.998  0.999  0.994  1.0
  C  C6  1  0.115  0.802  0.871  1.0
  C  C7  1  0.822  0.709  0.966  1.0
  C  C8  1  0.891  0.047  0.212  1.0
  C  C9  1  0.068  0.316  0.125  1.0
  C  C10  1  0.140  0.140  0.851  1.0
  C  C11  1  0.705  0.938  0.771  1.0
  C  C12  1  0.286  0.102  0.245  1.0
  N  N13  1  0.193  0.705  0.822  1.0
  N  N14  1  0.718  0.552  0.945  1.0
  N  N15  1  0.839  0.082  0.333  1.0
  N  N16  1  0.110  0.486  0.204  1.0
  N  N17  1  0.214  0.222  0.775  1.0
  N  N18  1  0.546  0.911  0.660  1.0
  N  N19  1  0.444  0.167  0.383  1.0
  O  O20  1  0.733  0.593  0.375  1.0
[/CIF]
.