The structure described by XeF5AuF4 is Indium-derived structured and crystallizes in the tetragonal I4/m space group. The structure is zero-dimensional and consists of four AuF4 clusters and four XeF5 clusters. In each AuF4 cluster, Au(1) is bonded in a square co-planar geometry to four equivalent F(2) atoms. F(2) is bonded in a single-bond geometry to one Au(1) atom. In each XeF5 cluster, Xe(1) is bonded in a distorted square pyramidal geometry to one F(3) and four equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the CIF file [CIF]
data_AuXeF9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.140
_cell_length_b   11.140
_cell_length_c   11.140
_cell_angle_alpha   149.474
_cell_angle_beta   149.474
_cell_angle_gamma   43.714
_symmetry_Int_Tables_number   1
_cell_volume   355.665
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.500  0.000  0.500  1.0
  Au  Au1  1  0.000  0.500  0.500  1.0
  Xe  Xe2  1  0.154  0.154  0.000  1.0
  Xe  Xe3  1  0.846  0.846  0.000  1.0
  F  F4  1  0.475  0.310  0.440  1.0
  F  F5  1  0.525  0.690  0.560  1.0
  F  F6  1  0.870  0.035  0.560  1.0
  F  F7  1  0.310  0.870  0.835  1.0
  F  F8  1  0.130  0.965  0.440  1.0
  F  F9  1  0.690  0.130  0.165  1.0
  F  F10  1  0.035  0.475  0.165  1.0
  F  F11  1  0.965  0.525  0.835  1.0
  F  F12  1  0.214  0.371  0.454  1.0
  F  F13  1  0.786  0.629  0.546  1.0
  F  F14  1  0.917  0.760  0.546  1.0
  F  F15  1  0.371  0.917  0.157  1.0
  F  F16  1  0.083  0.240  0.454  1.0
  F  F17  1  0.629  0.083  0.843  1.0
  F  F18  1  0.760  0.214  0.843  1.0
  F  F19  1  0.240  0.786  0.157  1.0
  F  F20  1  0.250  0.250  0.000  1.0
  F  F21  1  0.750  0.750  0.000  1.0
[/CIF]
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The structure described by XeF5AuF4 is Indium-derived structured and crystallizes in the tetragonal I4/m space group. The structure is zero-dimensional and consists of four AuF4 clusters and four XeF5 clusters. In each AuF4 cluster, Au(1) is bonded in a square co-planar geometry to four equivalent F(2) atoms. F(2) is bonded in a single-bond geometry to one Au(1) atom. In each XeF5 cluster, Xe(1) is bonded in a distorted square pyramidal geometry to one F(3) and four equivalent F(1) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the CIF file [CIF]
data_AuXeF9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.140
_cell_length_b   11.140
_cell_length_c   11.140
_cell_angle_alpha   149.474
_cell_angle_beta   149.474
_cell_angle_gamma   43.714
_symmetry_Int_Tables_number   1
_cell_volume   355.665
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Au  Au0  1  0.500  0.000  0.500  1.0
  Au  Au1  1  0.000  0.500  0.500  1.0
  Xe  Xe2  1  0.154  0.154  0.000  1.0
  Xe  Xe3  1  0.846  0.846  0.000  1.0
  F  F4  1  0.475  0.310  0.440  1.0
  F  F5  1  0.525  0.690  0.560  1.0
  F  F6  1  0.870  0.035  0.560  1.0
  F  F7  1  0.310  0.870  0.835  1.0
  F  F8  1  0.130  0.965  0.440  1.0
  F  F9  1  0.690  0.130  0.165  1.0
  F  F10  1  0.035  0.475  0.165  1.0
  F  F11  1  0.965  0.525  0.835  1.0
  F  F12  1  0.214  0.371  0.454  1.0
  F  F13  1  0.786  0.629  0.546  1.0
  F  F14  1  0.917  0.760  0.546  1.0
  F  F15  1  0.371  0.917  0.157  1.0
  F  F16  1  0.083  0.240  0.454  1.0
  F  F17  1  0.629  0.083  0.843  1.0
  F  F18  1  0.760  0.214  0.843  1.0
  F  F19  1  0.240  0.786  0.157  1.0
  F  F20  1  0.250  0.250  0.000  1.0
  F  F21  1  0.750  0.750  0.000  1.0
[/CIF]
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