The compound described by Rb2SnF6 crystallizes in the trigonal P-3m1 space group. Rb(1) is bonded to twelve equivalent F(1) atoms to form distorted RbF12 cuboctahedra that share corners with six equivalent Rb(1)F12 cuboctahedra, corners with three equivalent Sn(1)F6 octahedra, faces with eight equivalent Rb(1)F12 cuboctahedra, and faces with three equivalent Sn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 18°. Sn(1) is bonded to six equivalent F(1) atoms to form SnF6 octahedra that share corners with six equivalent Rb(1)F12 cuboctahedra and faces with six equivalent Rb(1)F12 cuboctahedra. F(1) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2SnF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.786
_cell_length_b   6.031
_cell_length_c   6.031
_cell_angle_alpha   120.001
_cell_angle_beta   90.002
_cell_angle_gamma   90.010
_symmetry_Int_Tables_number   1
_cell_volume   150.753
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.698  0.667  0.333  1.0
  Rb  Rb1  1  0.302  0.333  0.667  1.0
  Sn  Sn2  1  0.000  1.000  1.000  1.0
  F  F3  1  0.772  0.159  0.317  1.0
  F  F4  1  0.228  0.841  0.683  1.0
  F  F5  1  0.772  0.159  0.841  1.0
  F  F6  1  0.228  0.841  0.159  1.0
  F  F7  1  0.772  0.683  0.841  1.0
  F  F8  1  0.228  0.317  0.159  1.0
[/CIF]
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The compound described by Rb2SnF6 crystallizes in the trigonal P-3m1 space group. Rb(1) is bonded to twelve equivalent F(1) atoms to form distorted RbF12 cuboctahedra that share corners with six equivalent Rb(1)F12 cuboctahedra, corners with three equivalent Sn(1)F6 octahedra, faces with eight equivalent Rb(1)F12 cuboctahedra, and faces with three equivalent Sn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 18°. Sn(1) is bonded to six equivalent F(1) atoms to form SnF6 octahedra that share corners with six equivalent Rb(1)F12 cuboctahedra and faces with six equivalent Rb(1)F12 cuboctahedra. F(1) is bonded in a distorted single-bond geometry to four equivalent Rb(1) and one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2SnF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.786
_cell_length_b   6.031
_cell_length_c   6.031
_cell_angle_alpha   120.001
_cell_angle_beta   90.002
_cell_angle_gamma   90.010
_symmetry_Int_Tables_number   1
_cell_volume   150.753
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.698  0.667  0.333  1.0
  Rb  Rb1  1  0.302  0.333  0.667  1.0
  Sn  Sn2  1  0.000  1.000  1.000  1.0
  F  F3  1  0.772  0.159  0.317  1.0
  F  F4  1  0.228  0.841  0.683  1.0
  F  F5  1  0.772  0.159  0.841  1.0
  F  F6  1  0.228  0.841  0.159  1.0
  F  F7  1  0.772  0.683  0.841  1.0
  F  F8  1  0.228  0.317  0.159  1.0
[/CIF]
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