The compound described by Pd5Ga2 crystallizes in the orthorhombic Pnma space group. There are five inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted water-like geometry to two equivalent Ga(2) atoms. In the second Pd site, Pd(2) is bonded in a 4-coordinate geometry to one Ga(2) and four equivalent Ga(1) atoms. In the third Pd site, Pd(3) is bonded in a 3-coordinate geometry to three equivalent Ga(1) atoms. In the fourth Pd site, Pd(4) is bonded in a distorted rectangular see-saw-like geometry to one Ga(1) and three equivalent Ga(2) atoms. In the fifth Pd site, Pd(5) is bonded in a 2-coordinate geometry to two equivalent Ga(1) and two equivalent Ga(2) atoms. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 10-coordinate geometry to one Pd(4), two equivalent Pd(5), three equivalent Pd(3), and four equivalent Pd(2) atoms. In the second Ga site, Ga(2) is bonded in a 8-coordinate geometry to one Pd(2), two equivalent Pd(1), two equivalent Pd(5), and three equivalent Pd(4) atoms. is represented by the CIF file [CIF]
data_Ga2Pd5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.078
_cell_length_b   5.466
_cell_length_c   18.483
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   411.996
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.750  0.202  0.956  1.0
  Ga  Ga1  1  0.250  0.798  0.044  1.0
  Ga  Ga2  1  0.750  0.702  0.544  1.0
  Ga  Ga3  1  0.250  0.298  0.456  1.0
  Ga  Ga4  1  0.750  0.667  0.824  1.0
  Ga  Ga5  1  0.250  0.333  0.176  1.0
  Ga  Ga6  1  0.750  0.167  0.676  1.0
  Ga  Ga7  1  0.250  0.833  0.324  1.0
  Pd  Pd8  1  0.750  0.141  0.233  1.0
  Pd  Pd9  1  0.250  0.859  0.767  1.0
  Pd  Pd10  1  0.750  0.641  0.267  1.0
  Pd  Pd11  1  0.250  0.359  0.733  1.0
  Pd  Pd12  1  0.750  0.668  0.969  1.0
  Pd  Pd13  1  0.250  0.332  0.031  1.0
  Pd  Pd14  1  0.750  0.168  0.531  1.0
  Pd  Pd15  1  0.250  0.832  0.469  1.0
  Pd  Pd16  1  0.750  0.034  0.087  1.0
  Pd  Pd17  1  0.250  0.966  0.913  1.0
  Pd  Pd18  1  0.750  0.534  0.413  1.0
  Pd  Pd19  1  0.250  0.466  0.587  1.0
  Pd  Pd20  1  0.750  0.164  0.820  1.0
  Pd  Pd21  1  0.250  0.836  0.180  1.0
  Pd  Pd22  1  0.750  0.664  0.680  1.0
  Pd  Pd23  1  0.250  0.336  0.320  1.0
  Pd  Pd24  1  0.750  0.035  0.381  1.0
  Pd  Pd25  1  0.250  0.965  0.619  1.0
  Pd  Pd26  1  0.750  0.535  0.119  1.0
  Pd  Pd27  1  0.250  0.465  0.881  1.0
[/CIF]
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The compound described by Pd5Ga2 crystallizes in the orthorhombic Pnma space group. There are five inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted water-like geometry to two equivalent Ga(2) atoms. In the second Pd site, Pd(2) is bonded in a 4-coordinate geometry to one Ga(2) and four equivalent Ga(1) atoms. In the third Pd site, Pd(3) is bonded in a 3-coordinate geometry to three equivalent Ga(1) atoms. In the fourth Pd site, Pd(4) is bonded in a distorted rectangular see-saw-like geometry to one Ga(1) and three equivalent Ga(2) atoms. In the fifth Pd site, Pd(5) is bonded in a 2-coordinate geometry to two equivalent Ga(1) and two equivalent Ga(2) atoms. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 10-coordinate geometry to one Pd(4), two equivalent Pd(5), three equivalent Pd(3), and four equivalent Pd(2) atoms. In the second Ga site, Ga(2) is bonded in a 8-coordinate geometry to one Pd(2), two equivalent Pd(1), two equivalent Pd(5), and three equivalent Pd(4) atoms. is represented by the CIF file [CIF]
data_Ga2Pd5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.078
_cell_length_b   5.466
_cell_length_c   18.483
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   411.996
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.750  0.202  0.956  1.0
  Ga  Ga1  1  0.250  0.798  0.044  1.0
  Ga  Ga2  1  0.750  0.702  0.544  1.0
  Ga  Ga3  1  0.250  0.298  0.456  1.0
  Ga  Ga4  1  0.750  0.667  0.824  1.0
  Ga  Ga5  1  0.250  0.333  0.176  1.0
  Ga  Ga6  1  0.750  0.167  0.676  1.0
  Ga  Ga7  1  0.250  0.833  0.324  1.0
  Pd  Pd8  1  0.750  0.141  0.233  1.0
  Pd  Pd9  1  0.250  0.859  0.767  1.0
  Pd  Pd10  1  0.750  0.641  0.267  1.0
  Pd  Pd11  1  0.250  0.359  0.733  1.0
  Pd  Pd12  1  0.750  0.668  0.969  1.0
  Pd  Pd13  1  0.250  0.332  0.031  1.0
  Pd  Pd14  1  0.750  0.168  0.531  1.0
  Pd  Pd15  1  0.250  0.832  0.469  1.0
  Pd  Pd16  1  0.750  0.034  0.087  1.0
  Pd  Pd17  1  0.250  0.966  0.913  1.0
  Pd  Pd18  1  0.750  0.534  0.413  1.0
  Pd  Pd19  1  0.250  0.466  0.587  1.0
  Pd  Pd20  1  0.750  0.164  0.820  1.0
  Pd  Pd21  1  0.250  0.836  0.180  1.0
  Pd  Pd22  1  0.750  0.664  0.680  1.0
  Pd  Pd23  1  0.250  0.336  0.320  1.0
  Pd  Pd24  1  0.750  0.035  0.381  1.0
  Pd  Pd25  1  0.250  0.965  0.619  1.0
  Pd  Pd26  1  0.750  0.535  0.119  1.0
  Pd  Pd27  1  0.250  0.465  0.881  1.0
[/CIF]
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