The material described by CdC2H8S2(NO)6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CdC2H8S2(NO)6 clusters. Cd(1) is bonded in a distorted square co-planar geometry to two equivalent S(1) and two equivalent O(2) atoms. C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. There are three inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(3) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cd(1) and one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(3) atom. is represented by the CIF file [CIF]
data_CdH8C2S2(NO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.454
_cell_length_b   12.249
_cell_length_c   11.567
_cell_angle_alpha   90.000
_cell_angle_beta   99.950
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   621.541
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.500  0.000  1.0
  Cd  Cd1  1  0.500  0.000  0.500  1.0
  H  H2  1  0.994  0.279  0.327  1.0
  H  H3  1  0.994  0.221  0.827  1.0
  H  H4  1  0.006  0.721  0.673  1.0
  H  H5  1  0.006  0.779  0.173  1.0
  H  H6  1  0.152  0.311  0.202  1.0
  H  H7  1  0.152  0.189  0.702  1.0
  H  H8  1  0.848  0.689  0.798  1.0
  H  H9  1  0.848  0.811  0.298  1.0
  H  H10  1  0.740  0.414  0.416  1.0
  H  H11  1  0.740  0.086  0.916  1.0
  H  H12  1  0.260  0.586  0.584  1.0
  H  H13  1  0.260  0.914  0.084  1.0
  H  H14  1  0.699  0.544  0.354  1.0
  H  H15  1  0.699  0.956  0.854  1.0
  H  H16  1  0.301  0.456  0.646  1.0
  H  H17  1  0.301  0.044  0.146  1.0
  C  C18  1  0.922  0.436  0.266  1.0
  C  C19  1  0.922  0.064  0.766  1.0
  C  C20  1  0.078  0.564  0.734  1.0
  C  C21  1  0.078  0.936  0.234  1.0
  S  S22  1  0.970  0.529  0.157  1.0
  S  S23  1  0.970  0.971  0.657  1.0
  S  S24  1  0.030  0.471  0.843  1.0
  S  S25  1  0.030  0.029  0.343  1.0
  N  N26  1  0.035  0.335  0.266  1.0
  N  N27  1  0.035  0.165  0.766  1.0
  N  N28  1  0.965  0.665  0.734  1.0
  N  N29  1  0.965  0.835  0.234  1.0
  N  N30  1  0.779  0.467  0.351  1.0
  N  N31  1  0.779  0.033  0.851  1.0
  N  N32  1  0.221  0.533  0.649  1.0
  N  N33  1  0.221  0.967  0.149  1.0
  N  N34  1  0.544  0.250  0.027  1.0
  N  N35  1  0.544  0.250  0.527  1.0
  N  N36  1  0.456  0.750  0.973  1.0
  N  N37  1  0.456  0.750  0.473  1.0
  O  O38  1  0.694  0.285  0.952  1.0
  O  O39  1  0.694  0.215  0.452  1.0
  O  O40  1  0.306  0.715  0.048  1.0
  O  O41  1  0.306  0.785  0.548  1.0
  O  O42  1  0.398  0.319  0.080  1.0
  O  O43  1  0.398  0.181  0.580  1.0
  O  O44  1  0.602  0.681  0.920  1.0
  O  O45  1  0.602  0.819  0.420  1.0
  O  O46  1  0.534  0.149  0.050  1.0
  O  O47  1  0.534  0.351  0.550  1.0
  O  O48  1  0.466  0.851  0.950  1.0
  O  O49  1  0.466  0.649  0.450  1.0
[/CIF]
.
The material described by CdC2H8S2(NO)6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two CdC2H8S2(NO)6 clusters. Cd(1) is bonded in a distorted square co-planar geometry to two equivalent S(1) and two equivalent O(2) atoms. C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. There are three inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. S(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(3) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cd(1) and one N(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(3) atom. is represented by the CIF file [CIF]
data_CdH8C2S2(NO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.454
_cell_length_b   12.249
_cell_length_c   11.567
_cell_angle_alpha   90.000
_cell_angle_beta   99.950
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   621.541
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.500  0.000  1.0
  Cd  Cd1  1  0.500  0.000  0.500  1.0
  H  H2  1  0.994  0.279  0.327  1.0
  H  H3  1  0.994  0.221  0.827  1.0
  H  H4  1  0.006  0.721  0.673  1.0
  H  H5  1  0.006  0.779  0.173  1.0
  H  H6  1  0.152  0.311  0.202  1.0
  H  H7  1  0.152  0.189  0.702  1.0
  H  H8  1  0.848  0.689  0.798  1.0
  H  H9  1  0.848  0.811  0.298  1.0
  H  H10  1  0.740  0.414  0.416  1.0
  H  H11  1  0.740  0.086  0.916  1.0
  H  H12  1  0.260  0.586  0.584  1.0
  H  H13  1  0.260  0.914  0.084  1.0
  H  H14  1  0.699  0.544  0.354  1.0
  H  H15  1  0.699  0.956  0.854  1.0
  H  H16  1  0.301  0.456  0.646  1.0
  H  H17  1  0.301  0.044  0.146  1.0
  C  C18  1  0.922  0.436  0.266  1.0
  C  C19  1  0.922  0.064  0.766  1.0
  C  C20  1  0.078  0.564  0.734  1.0
  C  C21  1  0.078  0.936  0.234  1.0
  S  S22  1  0.970  0.529  0.157  1.0
  S  S23  1  0.970  0.971  0.657  1.0
  S  S24  1  0.030  0.471  0.843  1.0
  S  S25  1  0.030  0.029  0.343  1.0
  N  N26  1  0.035  0.335  0.266  1.0
  N  N27  1  0.035  0.165  0.766  1.0
  N  N28  1  0.965  0.665  0.734  1.0
  N  N29  1  0.965  0.835  0.234  1.0
  N  N30  1  0.779  0.467  0.351  1.0
  N  N31  1  0.779  0.033  0.851  1.0
  N  N32  1  0.221  0.533  0.649  1.0
  N  N33  1  0.221  0.967  0.149  1.0
  N  N34  1  0.544  0.250  0.027  1.0
  N  N35  1  0.544  0.250  0.527  1.0
  N  N36  1  0.456  0.750  0.973  1.0
  N  N37  1  0.456  0.750  0.473  1.0
  O  O38  1  0.694  0.285  0.952  1.0
  O  O39  1  0.694  0.215  0.452  1.0
  O  O40  1  0.306  0.715  0.048  1.0
  O  O41  1  0.306  0.785  0.548  1.0
  O  O42  1  0.398  0.319  0.080  1.0
  O  O43  1  0.398  0.181  0.580  1.0
  O  O44  1  0.602  0.681  0.920  1.0
  O  O45  1  0.602  0.819  0.420  1.0
  O  O46  1  0.534  0.149  0.050  1.0
  O  O47  1  0.534  0.351  0.550  1.0
  O  O48  1  0.466  0.851  0.950  1.0
  O  O49  1  0.466  0.649  0.450  1.0
[/CIF]
.