The crystal structure described by Sr4LaMn5O13 crystallizes in the monoclinic P2/m space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 11-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(7) atoms. In the second Sr site, Sr(2) is bonded in a distorted q6 geometry to one O(7), two equivalent O(2), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. La(1) is bonded to two equivalent O(2), two equivalent O(7), four equivalent O(1), and four equivalent O(6) atoms to form distorted LaO12 cuboctahedra that share faces with two equivalent La(1)O12 cuboctahedra, faces with four equivalent Mn(1)O6 octahedra, and faces with four equivalent Mn(2)O5 trigonal bipyramids. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(3), one O(5), one O(6), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O5 trigonal bipyramids, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second Mn site, Mn(2) is bonded to one O(1), one O(4), one O(6), and two equivalent O(2) atoms to form MnO5 trigonal bipyramids that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O5 trigonal bipyramids, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the third Mn site, Mn(3) is bonded in a square co-planar geometry to two equivalent O(4) and two equivalent O(5) atoms. There are seven inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Sr(1), two equivalent La(1), one Mn(1), and one Mn(2) atom to form distorted OSr2La2Mn2 octahedra that share corners with two equivalent O(1)Sr2La2Mn2 octahedra, corners with two equivalent O(3)Sr4Mn2 octahedra, corners with three equivalent O(5)Sr4Mn2 octahedra, corners with four equivalent O(6)Sr2La2Mn2 octahedra,  an edgeedge with one O(5)Sr4Mn2 octahedra, edges with three equivalent O(1)Sr2La2Mn2 octahedra,  a faceface with one O(3)Sr4Mn2 octahedra, and faces with two equivalent O(6)Sr2La2Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Sr(1), two equivalent Sr(2), one La(1), and two equivalent Mn(2) atoms. In the third O site, O(3) is bonded to four equivalent Sr(1) and two equivalent Mn(1) atoms to form OSr4Mn2 octahedra that share corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with four equivalent O(1)Sr2La2Mn2 octahedra, corners with four equivalent O(5)Sr4Mn2 octahedra, edges with two equivalent O(3)Sr4Mn2 octahedra, faces with two equivalent O(1)Sr2La2Mn2 octahedra, and faces with two equivalent O(5)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-57°. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent Sr(2), one Mn(2), and one Mn(3) atom. In the fifth O site, O(5) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Mn(1), and one Mn(3) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(5)Sr4Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(3)Sr4Mn2 octahedra, corners with three equivalent O(1)Sr2La2Mn2 octahedra,  an edgeedge with one O(1)Sr2La2Mn2 octahedra, edges with two equivalent O(5)Sr4Mn2 octahedra,  a faceface with one O(6)Sr2La2Mn2 octahedra, and  a faceface with one O(3)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-56°. In the sixth O site, O(6) is bonded to two equivalent Sr(2), two equivalent La(1), one Mn(1), and one Mn(2) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(3)Sr4Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(5)Sr4Mn2 octahedra, corners with four equivalent O(1)Sr2La2Mn2 octahedra, edges with three equivalent O(6)Sr2La2Mn2 octahedra,  a faceface with one O(5)Sr4Mn2 octahedra, and faces with two equivalent O(1)Sr2La2Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sr(2), two equivalent Sr(1), one La(1), and two equivalent Mn(1) atoms. is represented by the CIF card [CIF]
data_Sr4LaMn5O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.873
_cell_length_b   8.843
_cell_length_c   8.901
_cell_angle_alpha   90.603
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   304.866
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.500  0.899  0.321  1.0
  Sr  Sr1  1  0.500  0.101  0.679  1.0
  Sr  Sr2  1  0.500  0.702  0.885  1.0
  Sr  Sr3  1  0.500  0.298  0.115  1.0
  La  La4  1  0.500  0.500  0.500  1.0
  Mn  Mn5  1  0.000  0.800  0.605  1.0
  Mn  Mn6  1  1.000  0.200  0.395  1.0
  Mn  Mn7  1  0.000  0.606  0.197  1.0
  Mn  Mn8  1  0.000  0.394  0.803  1.0
  Mn  Mn9  1  1.000  0.000  0.000  1.0
  O  O10  1  0.000  0.685  0.413  1.0
  O  O11  1  0.000  0.315  0.587  1.0
  O  O12  1  0.500  0.587  0.165  1.0
  O  O13  1  0.500  0.413  0.835  1.0
  O  O14  1  0.000  0.000  0.500  1.0
  O  O15  1  1.000  0.796  0.079  1.0
  O  O16  1  1.000  0.204  0.921  1.0
  O  O17  1  1.000  0.917  0.801  1.0
  O  O18  1  1.000  0.083  0.198  1.0
  O  O19  1  0.000  0.596  0.714  1.0
  O  O20  1  0.000  0.404  0.286  1.0
  O  O21  1  0.500  0.791  0.600  1.0
  O  O22  1  0.500  0.209  0.400  1.0
[/CIF]
.
The crystal structure described by Sr4LaMn5O13 crystallizes in the monoclinic P2/m space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 11-coordinate geometry to one O(2), two equivalent O(1), two equivalent O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(7) atoms. In the second Sr site, Sr(2) is bonded in a distorted q6 geometry to one O(7), two equivalent O(2), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. La(1) is bonded to two equivalent O(2), two equivalent O(7), four equivalent O(1), and four equivalent O(6) atoms to form distorted LaO12 cuboctahedra that share faces with two equivalent La(1)O12 cuboctahedra, faces with four equivalent Mn(1)O6 octahedra, and faces with four equivalent Mn(2)O5 trigonal bipyramids. There are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(3), one O(5), one O(6), and two equivalent O(7) atoms to form MnO6 octahedra that share corners with three equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O5 trigonal bipyramids, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-5°. In the second Mn site, Mn(2) is bonded to one O(1), one O(4), one O(6), and two equivalent O(2) atoms to form MnO5 trigonal bipyramids that share corners with two equivalent Mn(1)O6 octahedra, corners with two equivalent Mn(2)O5 trigonal bipyramids, and faces with two equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 4-11°. In the third Mn site, Mn(3) is bonded in a square co-planar geometry to two equivalent O(4) and two equivalent O(5) atoms. There are seven inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Sr(1), two equivalent La(1), one Mn(1), and one Mn(2) atom to form distorted OSr2La2Mn2 octahedra that share corners with two equivalent O(1)Sr2La2Mn2 octahedra, corners with two equivalent O(3)Sr4Mn2 octahedra, corners with three equivalent O(5)Sr4Mn2 octahedra, corners with four equivalent O(6)Sr2La2Mn2 octahedra,  an edgeedge with one O(5)Sr4Mn2 octahedra, edges with three equivalent O(1)Sr2La2Mn2 octahedra,  a faceface with one O(3)Sr4Mn2 octahedra, and faces with two equivalent O(6)Sr2La2Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Sr(1), two equivalent Sr(2), one La(1), and two equivalent Mn(2) atoms. In the third O site, O(3) is bonded to four equivalent Sr(1) and two equivalent Mn(1) atoms to form OSr4Mn2 octahedra that share corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with four equivalent O(1)Sr2La2Mn2 octahedra, corners with four equivalent O(5)Sr4Mn2 octahedra, edges with two equivalent O(3)Sr4Mn2 octahedra, faces with two equivalent O(1)Sr2La2Mn2 octahedra, and faces with two equivalent O(5)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-57°. In the fourth O site, O(4) is bonded in a 6-coordinate geometry to two equivalent Sr(1), two equivalent Sr(2), one Mn(2), and one Mn(3) atom. In the fifth O site, O(5) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Mn(1), and one Mn(3) atom to form distorted OSr4Mn2 octahedra that share  a cornercorner with one O(5)Sr4Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(3)Sr4Mn2 octahedra, corners with three equivalent O(1)Sr2La2Mn2 octahedra,  an edgeedge with one O(1)Sr2La2Mn2 octahedra, edges with two equivalent O(5)Sr4Mn2 octahedra,  a faceface with one O(6)Sr2La2Mn2 octahedra, and  a faceface with one O(3)Sr4Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-56°. In the sixth O site, O(6) is bonded to two equivalent Sr(2), two equivalent La(1), one Mn(1), and one Mn(2) atom to form distorted OSr2La2Mn2 octahedra that share  a cornercorner with one O(3)Sr4Mn2 octahedra, corners with two equivalent O(6)Sr2La2Mn2 octahedra, corners with two equivalent O(5)Sr4Mn2 octahedra, corners with four equivalent O(1)Sr2La2Mn2 octahedra, edges with three equivalent O(6)Sr2La2Mn2 octahedra,  a faceface with one O(5)Sr4Mn2 octahedra, and faces with two equivalent O(1)Sr2La2Mn2 octahedra. The corner-sharing octahedral tilt angles range from 0-61°. In the seventh O site, O(7) is bonded in a distorted linear geometry to one Sr(2), two equivalent Sr(1), one La(1), and two equivalent Mn(1) atoms. is represented by the CIF card [CIF]
data_Sr4LaMn5O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.873
_cell_length_b   8.843
_cell_length_c   8.901
_cell_angle_alpha   90.603
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   304.866
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.500  0.899  0.321  1.0
  Sr  Sr1  1  0.500  0.101  0.679  1.0
  Sr  Sr2  1  0.500  0.702  0.885  1.0
  Sr  Sr3  1  0.500  0.298  0.115  1.0
  La  La4  1  0.500  0.500  0.500  1.0
  Mn  Mn5  1  0.000  0.800  0.605  1.0
  Mn  Mn6  1  1.000  0.200  0.395  1.0
  Mn  Mn7  1  0.000  0.606  0.197  1.0
  Mn  Mn8  1  0.000  0.394  0.803  1.0
  Mn  Mn9  1  1.000  0.000  0.000  1.0
  O  O10  1  0.000  0.685  0.413  1.0
  O  O11  1  0.000  0.315  0.587  1.0
  O  O12  1  0.500  0.587  0.165  1.0
  O  O13  1  0.500  0.413  0.835  1.0
  O  O14  1  0.000  0.000  0.500  1.0
  O  O15  1  1.000  0.796  0.079  1.0
  O  O16  1  1.000  0.204  0.921  1.0
  O  O17  1  1.000  0.917  0.801  1.0
  O  O18  1  1.000  0.083  0.198  1.0
  O  O19  1  0.000  0.596  0.714  1.0
  O  O20  1  0.000  0.404  0.286  1.0
  O  O21  1  0.500  0.791  0.600  1.0
  O  O22  1  0.500  0.209  0.400  1.0
[/CIF]
.