The material structure described by Rb3In(IO3)6 crystallizes in the triclinic P-1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(5), one O(8), two equivalent O(6), and two equivalent O(9) atoms. In(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(4), and two equivalent O(7) atoms. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Rb(1), one In(1), and one I(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Rb(2) and one I(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(2), one I(1), and one I(2) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Rb(1), one In(1), and one I(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Rb(1), one Rb(2), and one I(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Rb(2) and one I(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one In(1) and one I(3) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Rb(2) and one I(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to two equivalent Rb(2) and one I(3) atom. There are three inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(3), one O(4), one O(5), and one O(6) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one O(7), one O(8), and one O(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb3In(IO3)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.217
_cell_length_b   7.227
_cell_length_c   10.949
_cell_angle_alpha   87.865
_cell_angle_beta   108.246
_cell_angle_gamma   107.359
_symmetry_Int_Tables_number   1
_cell_volume   516.656
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.000  0.000  1.0
  Rb  Rb1  1  0.832  0.023  0.601  1.0
  Rb  Rb2  1  0.168  0.977  0.399  1.0
  In  In3  1  0.500  0.500  0.000  1.0
  I  I4  1  0.026  0.472  0.189  1.0
  I  I5  1  0.974  0.528  0.811  1.0
  I  I6  1  0.555  0.956  0.190  1.0
  I  I7  1  0.445  0.044  0.810  1.0
  I  I8  1  0.414  0.553  0.640  1.0
  I  I9  1  0.586  0.447  0.360  1.0
  O  O10  1  0.829  0.540  0.050  1.0
  O  O11  1  0.171  0.460  0.950  1.0
  O  O12  1  0.957  0.550  0.321  1.0
  O  O13  1  0.043  0.450  0.679  1.0
  O  O14  1  0.917  0.208  0.184  1.0
  O  O15  1  0.083  0.792  0.816  1.0
  O  O16  1  0.570  0.813  0.055  1.0
  O  O17  1  0.430  0.187  0.945  1.0
  O  O18  1  0.290  0.844  0.186  1.0
  O  O19  1  0.710  0.156  0.814  1.0
  O  O20  1  0.693  0.843  0.326  1.0
  O  O21  1  0.307  0.157  0.674  1.0
  O  O22  1  0.527  0.605  0.817  1.0
  O  O23  1  0.473  0.395  0.183  1.0
  O  O24  1  0.662  0.570  0.618  1.0
  O  O25  1  0.338  0.430  0.382  1.0
  O  O26  1  0.408  0.799  0.604  1.0
  O  O27  1  0.592  0.201  0.396  1.0
[/CIF]
.
The material structure described by Rb3In(IO3)6 crystallizes in the triclinic P-1 space group. There are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), two equivalent O(4), and two equivalent O(5) atoms. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(5), one O(8), two equivalent O(6), and two equivalent O(9) atoms. In(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(4), and two equivalent O(7) atoms. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Rb(1), one In(1), and one I(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Rb(2) and one I(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Rb(1), one Rb(2), one I(1), and one I(2) atom. In the fourth O site, O(4) is bonded in a 2-coordinate geometry to one Rb(1), one In(1), and one I(2) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Rb(1), one Rb(2), and one I(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Rb(2) and one I(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one In(1) and one I(3) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Rb(2) and one I(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to two equivalent Rb(2) and one I(3) atom. There are three inequivalent I sites. In the first I site, I(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. In the second I site, I(2) is bonded in a 3-coordinate geometry to one O(3), one O(4), one O(5), and one O(6) atom. In the third I site, I(3) is bonded in a 3-coordinate geometry to one O(7), one O(8), and one O(9) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb3In(IO3)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.217
_cell_length_b   7.227
_cell_length_c   10.949
_cell_angle_alpha   87.865
_cell_angle_beta   108.246
_cell_angle_gamma   107.359
_symmetry_Int_Tables_number   1
_cell_volume   516.656
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.000  0.000  1.0
  Rb  Rb1  1  0.832  0.023  0.601  1.0
  Rb  Rb2  1  0.168  0.977  0.399  1.0
  In  In3  1  0.500  0.500  0.000  1.0
  I  I4  1  0.026  0.472  0.189  1.0
  I  I5  1  0.974  0.528  0.811  1.0
  I  I6  1  0.555  0.956  0.190  1.0
  I  I7  1  0.445  0.044  0.810  1.0
  I  I8  1  0.414  0.553  0.640  1.0
  I  I9  1  0.586  0.447  0.360  1.0
  O  O10  1  0.829  0.540  0.050  1.0
  O  O11  1  0.171  0.460  0.950  1.0
  O  O12  1  0.957  0.550  0.321  1.0
  O  O13  1  0.043  0.450  0.679  1.0
  O  O14  1  0.917  0.208  0.184  1.0
  O  O15  1  0.083  0.792  0.816  1.0
  O  O16  1  0.570  0.813  0.055  1.0
  O  O17  1  0.430  0.187  0.945  1.0
  O  O18  1  0.290  0.844  0.186  1.0
  O  O19  1  0.710  0.156  0.814  1.0
  O  O20  1  0.693  0.843  0.326  1.0
  O  O21  1  0.307  0.157  0.674  1.0
  O  O22  1  0.527  0.605  0.817  1.0
  O  O23  1  0.473  0.395  0.183  1.0
  O  O24  1  0.662  0.570  0.618  1.0
  O  O25  1  0.338  0.430  0.382  1.0
  O  O26  1  0.408  0.799  0.604  1.0
  O  O27  1  0.592  0.201  0.396  1.0
[/CIF]
.