The crystal structure described by PdAgO2 crystallizes in the monoclinic P2/m space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form edge-sharing PdO6 octahedra. In the second Pd site, Pd(2) is bonded in a square co-planar geometry to four equivalent O(1) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a distorted linear geometry to two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Pd(1) and two equivalent Pd(2) atoms. In the second O site, O(2) is bonded to two equivalent Pd(1), one Ag(1), and one Ag(2) atom to form a mixture of edge and corner-sharing OAg2Pd2 tetrahedra. is represented by the CIF file [CIF]
data_AgPdO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.024
_cell_length_b   6.352
_cell_length_c   6.203
_cell_angle_alpha   117.508
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   105.663
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.500  1.0
  Ag  Ag1  1  0.000  0.500  0.500  1.0
  Pd  Pd2  1  0.500  0.500  0.000  1.0
  Pd  Pd3  1  0.000  0.000  0.000  1.0
  O  O4  1  0.500  0.236  0.096  1.0
  O  O5  1  0.000  0.359  0.761  1.0
  O  O6  1  0.000  0.641  0.239  1.0
  O  O7  1  0.500  0.764  0.904  1.0
[/CIF]
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The crystal structure described by PdAgO2 crystallizes in the monoclinic P2/m space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form edge-sharing PdO6 octahedra. In the second Pd site, Pd(2) is bonded in a square co-planar geometry to four equivalent O(1) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(2) atoms. In the second Ag site, Ag(2) is bonded in a distorted linear geometry to two equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Pd(1) and two equivalent Pd(2) atoms. In the second O site, O(2) is bonded to two equivalent Pd(1), one Ag(1), and one Ag(2) atom to form a mixture of edge and corner-sharing OAg2Pd2 tetrahedra. is represented by the CIF file [CIF]
data_AgPdO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.024
_cell_length_b   6.352
_cell_length_c   6.203
_cell_angle_alpha   117.508
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   105.663
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.000  0.000  0.500  1.0
  Ag  Ag1  1  0.000  0.500  0.500  1.0
  Pd  Pd2  1  0.500  0.500  0.000  1.0
  Pd  Pd3  1  0.000  0.000  0.000  1.0
  O  O4  1  0.500  0.236  0.096  1.0
  O  O5  1  0.000  0.359  0.761  1.0
  O  O6  1  0.000  0.641  0.239  1.0
  O  O7  1  0.500  0.764  0.904  1.0
[/CIF]
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