The compound described by SrEuBiSbO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic F-43m space group. Sr(1) is bonded to twelve equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra, faces with six equivalent Eu(1)O12 cuboctahedra, faces with four equivalent Bi(1)O6 octahedra, and faces with four equivalent Sb(1)O6 octahedra. Eu(1) is bonded to twelve equivalent O(1) atoms to form EuO12 cuboctahedra that share corners with twelve equivalent Eu(1)O12 cuboctahedra, faces with six equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Bi(1)O6 octahedra, and faces with four equivalent Sb(1)O6 octahedra. Bi(1) is bonded to six equivalent O(1) atoms to form BiO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Bi(1)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to two equivalent Sr(1), two equivalent Eu(1), one Bi(1), and one Sb(1) atom to form a mixture of distorted face, corner, and edge-sharing OSr2Eu2BiSb octahedra. The corner-sharing octahedral tilt angles range from 0-60°. is represented by the Crystallographic Information File (CIF) [CIF]
data_SrEuBiSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.046
_cell_length_b   6.046
_cell_length_c   6.046
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   156.241
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.250  0.250  0.250  1.0
  Eu  Eu1  1  0.750  0.750  0.750  1.0
  Bi  Bi2  1  0.000  0.000  0.000  1.0
  Sb  Sb3  1  0.500  0.500  0.500  1.0
  O  O4  1  0.734  0.266  0.266  1.0
  O  O5  1  0.266  0.734  0.734  1.0
  O  O6  1  0.734  0.266  0.734  1.0
  O  O7  1  0.266  0.734  0.266  1.0
  O  O8  1  0.734  0.734  0.266  1.0
  O  O9  1  0.266  0.266  0.734  1.0
[/CIF]
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The compound described by SrEuBiSbO6 is (Cubic) Perovskite-derived structured and crystallizes in the cubic F-43m space group. Sr(1) is bonded to twelve equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with twelve equivalent Sr(1)O12 cuboctahedra, faces with six equivalent Eu(1)O12 cuboctahedra, faces with four equivalent Bi(1)O6 octahedra, and faces with four equivalent Sb(1)O6 octahedra. Eu(1) is bonded to twelve equivalent O(1) atoms to form EuO12 cuboctahedra that share corners with twelve equivalent Eu(1)O12 cuboctahedra, faces with six equivalent Sr(1)O12 cuboctahedra, faces with four equivalent Bi(1)O6 octahedra, and faces with four equivalent Sb(1)O6 octahedra. Bi(1) is bonded to six equivalent O(1) atoms to form BiO6 octahedra that share corners with six equivalent Sb(1)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Bi(1)O6 octahedra, faces with four equivalent Sr(1)O12 cuboctahedra, and faces with four equivalent Eu(1)O12 cuboctahedra. The corner-sharing octahedra are not tilted. O(1) is bonded to two equivalent Sr(1), two equivalent Eu(1), one Bi(1), and one Sb(1) atom to form a mixture of distorted face, corner, and edge-sharing OSr2Eu2BiSb octahedra. The corner-sharing octahedral tilt angles range from 0-60°. is represented by the Crystallographic Information File (CIF) [CIF]
data_SrEuBiSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.046
_cell_length_b   6.046
_cell_length_c   6.046
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   156.241
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.250  0.250  0.250  1.0
  Eu  Eu1  1  0.750  0.750  0.750  1.0
  Bi  Bi2  1  0.000  0.000  0.000  1.0
  Sb  Sb3  1  0.500  0.500  0.500  1.0
  O  O4  1  0.734  0.266  0.266  1.0
  O  O5  1  0.266  0.734  0.734  1.0
  O  O6  1  0.734  0.266  0.734  1.0
  O  O7  1  0.266  0.734  0.266  1.0
  O  O8  1  0.734  0.734  0.266  1.0
  O  O9  1  0.266  0.266  0.734  1.0
[/CIF]
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