The crystal structure described by KCNS crystallizes in the orthorhombic Pbcm space group. K(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and four equivalent S(1) atoms. C(1) is bonded in a distorted single-bond geometry to one N(1) and one S(1) atom. N(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one C(1) atom. S(1) is bonded in a 5-coordinate geometry to four equivalent K(1) and one C(1) atom. is represented by the CIF file [CIF]
data_KCSN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.754
_cell_length_b   7.832
_cell_length_c   8.011
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   423.735
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.256  0.497  1.0
  K  K1  1  0.750  0.256  0.003  1.0
  K  K2  1  0.750  0.744  0.503  1.0
  K  K3  1  0.250  0.744  0.997  1.0
  C  C4  1  0.750  0.688  0.063  1.0
  C  C5  1  0.250  0.312  0.937  1.0
  C  C6  1  0.250  0.688  0.437  1.0
  C  C7  1  0.750  0.312  0.563  1.0
  S  S8  1  0.750  0.831  0.912  1.0
  S  S9  1  0.750  0.169  0.412  1.0
  S  S10  1  0.250  0.831  0.588  1.0
  S  S11  1  0.250  0.169  0.088  1.0
  N  N12  1  0.750  0.414  0.674  1.0
  N  N13  1  0.750  0.586  0.174  1.0
  N  N14  1  0.250  0.414  0.826  1.0
  N  N15  1  0.250  0.586  0.326  1.0
[/CIF]
.
The crystal structure described by KCNS crystallizes in the orthorhombic Pbcm space group. K(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and four equivalent S(1) atoms. C(1) is bonded in a distorted single-bond geometry to one N(1) and one S(1) atom. N(1) is bonded in a 3-coordinate geometry to two equivalent K(1) and one C(1) atom. S(1) is bonded in a 5-coordinate geometry to four equivalent K(1) and one C(1) atom. is represented by the CIF file [CIF]
data_KCSN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.754
_cell_length_b   7.832
_cell_length_c   8.011
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   423.735
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.256  0.497  1.0
  K  K1  1  0.750  0.256  0.003  1.0
  K  K2  1  0.750  0.744  0.503  1.0
  K  K3  1  0.250  0.744  0.997  1.0
  C  C4  1  0.750  0.688  0.063  1.0
  C  C5  1  0.250  0.312  0.937  1.0
  C  C6  1  0.250  0.688  0.437  1.0
  C  C7  1  0.750  0.312  0.563  1.0
  S  S8  1  0.750  0.831  0.912  1.0
  S  S9  1  0.750  0.169  0.412  1.0
  S  S10  1  0.250  0.831  0.588  1.0
  S  S11  1  0.250  0.169  0.088  1.0
  N  N12  1  0.750  0.414  0.674  1.0
  N  N13  1  0.750  0.586  0.174  1.0
  N  N14  1  0.250  0.414  0.826  1.0
  N  N15  1  0.250  0.586  0.326  1.0
[/CIF]
.