The material structure described by MnVSbO6 is Hydrophilite-derived structured and crystallizes in the orthorhombic Pbcn space group. V(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Mn(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form MnO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 57°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SbO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-57°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1), one Mn(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Mn(1) atoms. is represented by the CIF card [CIF]
data_MnVSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.736
_cell_length_b   5.034
_cell_length_c   17.456
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   416.156
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.500  0.250  0.058  1.0
  Mn  Mn1  1  0.500  0.750  0.942  1.0
  Mn  Mn2  1  0.000  0.750  0.442  1.0
  Mn  Mn3  1  0.000  0.250  0.558  1.0
  V  V4  1  0.000  0.250  0.897  1.0
  V  V5  1  0.500  0.750  0.603  1.0
  V  V6  1  0.000  0.750  0.103  1.0
  V  V7  1  0.500  0.250  0.397  1.0
  Sb  Sb8  1  0.000  0.750  0.781  1.0
  Sb  Sb9  1  0.000  0.250  0.219  1.0
  Sb  Sb10  1  0.500  0.250  0.719  1.0
  Sb  Sb11  1  0.500  0.750  0.281  1.0
  O  O12  1  0.244  0.424  0.795  1.0
  O  O13  1  0.744  0.076  0.295  1.0
  O  O14  1  0.796  0.558  0.866  1.0
  O  O15  1  0.704  0.058  0.634  1.0
  O  O16  1  0.756  0.576  0.205  1.0
  O  O17  1  0.204  0.942  0.866  1.0
  O  O18  1  0.704  0.558  0.366  1.0
  O  O19  1  0.296  0.942  0.366  1.0
  O  O20  1  0.749  0.612  0.043  1.0
  O  O21  1  0.751  0.112  0.457  1.0
  O  O22  1  0.251  0.388  0.957  1.0
  O  O23  1  0.251  0.888  0.043  1.0
  O  O24  1  0.751  0.612  0.543  1.0
  O  O25  1  0.204  0.442  0.134  1.0
  O  O26  1  0.296  0.442  0.634  1.0
  O  O27  1  0.749  0.112  0.957  1.0
  O  O28  1  0.256  0.924  0.705  1.0
  O  O29  1  0.244  0.924  0.205  1.0
  O  O30  1  0.249  0.888  0.543  1.0
  O  O31  1  0.796  0.058  0.134  1.0
  O  O32  1  0.249  0.388  0.457  1.0
  O  O33  1  0.756  0.076  0.795  1.0
  O  O34  1  0.744  0.576  0.705  1.0
  O  O35  1  0.256  0.424  0.295  1.0
[/CIF]
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The material structure described by MnVSbO6 is Hydrophilite-derived structured and crystallizes in the orthorhombic Pbcn space group. V(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Mn(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form MnO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles are 57°. Sb(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form SbO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-57°. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1) and two equivalent Sb(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to one V(1), one Mn(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one V(1) and two equivalent Mn(1) atoms. is represented by the CIF card [CIF]
data_MnVSbO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.736
_cell_length_b   5.034
_cell_length_c   17.456
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   416.156
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.500  0.250  0.058  1.0
  Mn  Mn1  1  0.500  0.750  0.942  1.0
  Mn  Mn2  1  0.000  0.750  0.442  1.0
  Mn  Mn3  1  0.000  0.250  0.558  1.0
  V  V4  1  0.000  0.250  0.897  1.0
  V  V5  1  0.500  0.750  0.603  1.0
  V  V6  1  0.000  0.750  0.103  1.0
  V  V7  1  0.500  0.250  0.397  1.0
  Sb  Sb8  1  0.000  0.750  0.781  1.0
  Sb  Sb9  1  0.000  0.250  0.219  1.0
  Sb  Sb10  1  0.500  0.250  0.719  1.0
  Sb  Sb11  1  0.500  0.750  0.281  1.0
  O  O12  1  0.244  0.424  0.795  1.0
  O  O13  1  0.744  0.076  0.295  1.0
  O  O14  1  0.796  0.558  0.866  1.0
  O  O15  1  0.704  0.058  0.634  1.0
  O  O16  1  0.756  0.576  0.205  1.0
  O  O17  1  0.204  0.942  0.866  1.0
  O  O18  1  0.704  0.558  0.366  1.0
  O  O19  1  0.296  0.942  0.366  1.0
  O  O20  1  0.749  0.612  0.043  1.0
  O  O21  1  0.751  0.112  0.457  1.0
  O  O22  1  0.251  0.388  0.957  1.0
  O  O23  1  0.251  0.888  0.043  1.0
  O  O24  1  0.751  0.612  0.543  1.0
  O  O25  1  0.204  0.442  0.134  1.0
  O  O26  1  0.296  0.442  0.634  1.0
  O  O27  1  0.749  0.112  0.957  1.0
  O  O28  1  0.256  0.924  0.705  1.0
  O  O29  1  0.244  0.924  0.205  1.0
  O  O30  1  0.249  0.888  0.543  1.0
  O  O31  1  0.796  0.058  0.134  1.0
  O  O32  1  0.249  0.388  0.457  1.0
  O  O33  1  0.756  0.076  0.795  1.0
  O  O34  1  0.744  0.576  0.705  1.0
  O  O35  1  0.256  0.424  0.295  1.0
[/CIF]
.