The compound described by CrMn4(Co2Ga)5 is Tungsten-derived structured and crystallizes in the trigonal R-3m space group. Cr(1) is bonded in a body-centered cubic geometry to two equivalent Co(1) and six equivalent Co(4) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted body-centered cubic geometry to one Co(3), one Co(4), three equivalent Co(1), three equivalent Co(5), and three equivalent Ga(3) atoms. In the second Mn site, Mn(2) is bonded in a distorted body-centered cubic geometry to one Co(5), three equivalent Co(3), four equivalent Co(2), three equivalent Ga(2), and three equivalent Ga(3) atoms. There are seven inequivalent Co sites. In the first Co site, Co(3) is bonded in a body-centered cubic geometry to one Mn(1), three equivalent Mn(2), one Ga(2), and three equivalent Ga(3) atoms. In the second Co site, Co(4) is bonded in a body-centered cubic geometry to three equivalent Cr(1), one Mn(1), and four equivalent Ga(1) atoms. In the third Co site, Co(5) is bonded in a body-centered cubic geometry to one Mn(2), three equivalent Mn(1), one Ga(1), and three equivalent Ga(3) atoms. In the fourth Co site, Co(2) is bonded in a body-centered cubic geometry to four equivalent Mn(2), one Ga(3), and three equivalent Ga(2) atoms. In the fifth Co site, Co(2) is bonded in a body-centered cubic geometry to four equivalent Mn(2), one Ga(3), and three equivalent Ga(2) atoms. In the sixth Co site, Co(1) is bonded in a body-centered cubic geometry to one Cr(1), three equivalent Mn(1), one Ga(3), and three equivalent Ga(1) atoms. In the seventh Co site, Co(2) is bonded in a body-centered cubic geometry to four equivalent Mn(2), one Ga(3), and three equivalent Ga(2) atoms. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a distorted body-centered cubic geometry to one Co(5), three equivalent Co(1), and four equivalent Co(4) atoms. In the second Ga site, Ga(2) is bonded in a distorted body-centered cubic geometry to six equivalent Mn(2), two equivalent Co(3), and six equivalent Co(2) atoms. In the third Ga site, Ga(3) is bonded in a distorted body-centered cubic geometry to three equivalent Mn(1), three equivalent Mn(2), one Co(1), one Co(2), three equivalent Co(3), and three equivalent Co(5) atoms. is represented by the CIF card [CIF]
data_Mn4Cr(GaCo2)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.675
_cell_length_b   16.675
_cell_length_c   16.675
_cell_angle_alpha   13.929
_cell_angle_beta   13.929
_cell_angle_gamma   13.929
_symmetry_Int_Tables_number   1
_cell_volume   233.822
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.600  0.600  0.600  1.0
  Mn  Mn1  1  0.200  0.200  0.200  1.0
  Mn  Mn2  1  0.800  0.800  0.800  1.0
  Mn  Mn3  1  0.400  0.400  0.400  1.0
  Cr  Cr4  1  0.000  0.000  0.000  1.0
  Ga  Ga5  1  0.700  0.700  0.700  1.0
  Ga  Ga6  1  0.500  0.500  0.500  1.0
  Ga  Ga7  1  0.100  0.100  0.100  1.0
  Ga  Ga8  1  0.300  0.300  0.300  1.0
  Ga  Ga9  1  0.900  0.900  0.900  1.0
  Co  Co10  1  0.050  0.050  0.050  1.0
  Co  Co11  1  0.850  0.850  0.850  1.0
  Co  Co12  1  0.450  0.450  0.450  1.0
  Co  Co13  1  0.650  0.650  0.650  1.0
  Co  Co14  1  0.250  0.250  0.250  1.0
  Co  Co15  1  0.350  0.350  0.350  1.0
  Co  Co16  1  0.150  0.150  0.150  1.0
  Co  Co17  1  0.750  0.750  0.750  1.0
  Co  Co18  1  0.950  0.950  0.950  1.0
  Co  Co19  1  0.550  0.550  0.550  1.0
[/CIF]
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The compound described by CrMn4(Co2Ga)5 is Tungsten-derived structured and crystallizes in the trigonal R-3m space group. Cr(1) is bonded in a body-centered cubic geometry to two equivalent Co(1) and six equivalent Co(4) atoms. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted body-centered cubic geometry to one Co(3), one Co(4), three equivalent Co(1), three equivalent Co(5), and three equivalent Ga(3) atoms. In the second Mn site, Mn(2) is bonded in a distorted body-centered cubic geometry to one Co(5), three equivalent Co(3), four equivalent Co(2), three equivalent Ga(2), and three equivalent Ga(3) atoms. There are seven inequivalent Co sites. In the first Co site, Co(3) is bonded in a body-centered cubic geometry to one Mn(1), three equivalent Mn(2), one Ga(2), and three equivalent Ga(3) atoms. In the second Co site, Co(4) is bonded in a body-centered cubic geometry to three equivalent Cr(1), one Mn(1), and four equivalent Ga(1) atoms. In the third Co site, Co(5) is bonded in a body-centered cubic geometry to one Mn(2), three equivalent Mn(1), one Ga(1), and three equivalent Ga(3) atoms. In the fourth Co site, Co(2) is bonded in a body-centered cubic geometry to four equivalent Mn(2), one Ga(3), and three equivalent Ga(2) atoms. In the fifth Co site, Co(2) is bonded in a body-centered cubic geometry to four equivalent Mn(2), one Ga(3), and three equivalent Ga(2) atoms. In the sixth Co site, Co(1) is bonded in a body-centered cubic geometry to one Cr(1), three equivalent Mn(1), one Ga(3), and three equivalent Ga(1) atoms. In the seventh Co site, Co(2) is bonded in a body-centered cubic geometry to four equivalent Mn(2), one Ga(3), and three equivalent Ga(2) atoms. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a distorted body-centered cubic geometry to one Co(5), three equivalent Co(1), and four equivalent Co(4) atoms. In the second Ga site, Ga(2) is bonded in a distorted body-centered cubic geometry to six equivalent Mn(2), two equivalent Co(3), and six equivalent Co(2) atoms. In the third Ga site, Ga(3) is bonded in a distorted body-centered cubic geometry to three equivalent Mn(1), three equivalent Mn(2), one Co(1), one Co(2), three equivalent Co(3), and three equivalent Co(5) atoms. is represented by the CIF card [CIF]
data_Mn4Cr(GaCo2)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   16.675
_cell_length_b   16.675
_cell_length_c   16.675
_cell_angle_alpha   13.929
_cell_angle_beta   13.929
_cell_angle_gamma   13.929
_symmetry_Int_Tables_number   1
_cell_volume   233.822
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.600  0.600  0.600  1.0
  Mn  Mn1  1  0.200  0.200  0.200  1.0
  Mn  Mn2  1  0.800  0.800  0.800  1.0
  Mn  Mn3  1  0.400  0.400  0.400  1.0
  Cr  Cr4  1  0.000  0.000  0.000  1.0
  Ga  Ga5  1  0.700  0.700  0.700  1.0
  Ga  Ga6  1  0.500  0.500  0.500  1.0
  Ga  Ga7  1  0.100  0.100  0.100  1.0
  Ga  Ga8  1  0.300  0.300  0.300  1.0
  Ga  Ga9  1  0.900  0.900  0.900  1.0
  Co  Co10  1  0.050  0.050  0.050  1.0
  Co  Co11  1  0.850  0.850  0.850  1.0
  Co  Co12  1  0.450  0.450  0.450  1.0
  Co  Co13  1  0.650  0.650  0.650  1.0
  Co  Co14  1  0.250  0.250  0.250  1.0
  Co  Co15  1  0.350  0.350  0.350  1.0
  Co  Co16  1  0.150  0.150  0.150  1.0
  Co  Co17  1  0.750  0.750  0.750  1.0
  Co  Co18  1  0.950  0.950  0.950  1.0
  Co  Co19  1  0.550  0.550  0.550  1.0
[/CIF]
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