The crystal structure described by (Rb2Pd(CN)4)2H2 crystallizes in the orthorhombic Pnna space group. The structure consists of four 1333-74-0 atoms inside a Rb2Pd(CN)4 framework. In the Rb2Pd(CN)4 framework, there are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. In the second Rb site, Rb(2) is bonded in a 6-coordinate geometry to two equivalent N(1) and four equivalent N(2) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent C(1) and two equivalent C(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Pd(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Pd(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to two equivalent Rb(2) and one C(2) atom. is represented by the CIF card [CIF]
data_Rb2HPd(CN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.659
_cell_length_b   10.077
_cell_length_c   13.769
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1062.652
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.289  0.250  0.250  1.0
  Rb  Rb1  1  0.711  0.750  0.750  1.0
  Rb  Rb2  1  0.211  0.750  0.250  1.0
  Rb  Rb3  1  0.789  0.250  0.750  1.0
  Rb  Rb4  1  0.250  0.000  0.596  1.0
  Rb  Rb5  1  0.750  0.000  0.404  1.0
  Rb  Rb6  1  0.250  0.500  0.904  1.0
  Rb  Rb7  1  0.750  0.500  0.096  1.0
  H  H8  1  0.750  0.250  0.250  1.0
  H  H9  1  0.250  0.750  0.750  1.0
  H  H10  1  0.750  0.750  0.250  1.0
  H  H11  1  0.250  0.250  0.750  1.0
  Pd  Pd12  1  0.000  0.000  0.000  1.0
  Pd  Pd13  1  0.500  0.000  0.000  1.0
  Pd  Pd14  1  0.500  0.500  0.500  1.0
  Pd  Pd15  1  0.000  0.500  0.500  1.0
  C  C16  1  0.007  0.012  0.144  1.0
  C  C17  1  0.993  0.988  0.856  1.0
  C  C18  1  0.493  0.988  0.144  1.0
  C  C19  1  0.493  0.512  0.356  1.0
  C  C20  1  0.507  0.012  0.856  1.0
  C  C21  1  0.507  0.488  0.644  1.0
  C  C22  1  0.007  0.488  0.356  1.0
  C  C23  1  0.993  0.512  0.644  1.0
  C  C24  1  0.530  0.197  0.990  1.0
  C  C25  1  0.470  0.803  0.010  1.0
  C  C26  1  0.970  0.803  0.990  1.0
  C  C27  1  0.970  0.697  0.510  1.0
  C  C28  1  0.030  0.197  0.010  1.0
  C  C29  1  0.030  0.303  0.490  1.0
  C  C30  1  0.530  0.303  0.510  1.0
  C  C31  1  0.470  0.697  0.490  1.0
  N  N32  1  0.017  0.027  0.229  1.0
  N  N33  1  0.983  0.973  0.771  1.0
  N  N34  1  0.483  0.973  0.229  1.0
  N  N35  1  0.483  0.527  0.271  1.0
  N  N36  1  0.517  0.027  0.771  1.0
  N  N37  1  0.517  0.473  0.729  1.0
  N  N38  1  0.017  0.473  0.271  1.0
  N  N39  1  0.983  0.527  0.729  1.0
  N  N40  1  0.547  0.311  0.976  1.0
  N  N41  1  0.453  0.689  0.024  1.0
  N  N42  1  0.953  0.689  0.976  1.0
  N  N43  1  0.953  0.811  0.524  1.0
  N  N44  1  0.047  0.311  0.024  1.0
  N  N45  1  0.047  0.189  0.476  1.0
  N  N46  1  0.547  0.189  0.524  1.0
  N  N47  1  0.453  0.811  0.476  1.0
[/CIF]
.
The crystal structure described by (Rb2Pd(CN)4)2H2 crystallizes in the orthorhombic Pnna space group. The structure consists of four 1333-74-0 atoms inside a Rb2Pd(CN)4 framework. In the Rb2Pd(CN)4 framework, there are two inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 4-coordinate geometry to four equivalent N(1) atoms. In the second Rb site, Rb(2) is bonded in a 6-coordinate geometry to two equivalent N(1) and four equivalent N(2) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent C(1) and two equivalent C(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Pd(1) and one N(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Pd(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted single-bond geometry to one Rb(2), two equivalent Rb(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to two equivalent Rb(2) and one C(2) atom. is represented by the CIF card [CIF]
data_Rb2HPd(CN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.659
_cell_length_b   10.077
_cell_length_c   13.769
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1062.652
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.289  0.250  0.250  1.0
  Rb  Rb1  1  0.711  0.750  0.750  1.0
  Rb  Rb2  1  0.211  0.750  0.250  1.0
  Rb  Rb3  1  0.789  0.250  0.750  1.0
  Rb  Rb4  1  0.250  0.000  0.596  1.0
  Rb  Rb5  1  0.750  0.000  0.404  1.0
  Rb  Rb6  1  0.250  0.500  0.904  1.0
  Rb  Rb7  1  0.750  0.500  0.096  1.0
  H  H8  1  0.750  0.250  0.250  1.0
  H  H9  1  0.250  0.750  0.750  1.0
  H  H10  1  0.750  0.750  0.250  1.0
  H  H11  1  0.250  0.250  0.750  1.0
  Pd  Pd12  1  0.000  0.000  0.000  1.0
  Pd  Pd13  1  0.500  0.000  0.000  1.0
  Pd  Pd14  1  0.500  0.500  0.500  1.0
  Pd  Pd15  1  0.000  0.500  0.500  1.0
  C  C16  1  0.007  0.012  0.144  1.0
  C  C17  1  0.993  0.988  0.856  1.0
  C  C18  1  0.493  0.988  0.144  1.0
  C  C19  1  0.493  0.512  0.356  1.0
  C  C20  1  0.507  0.012  0.856  1.0
  C  C21  1  0.507  0.488  0.644  1.0
  C  C22  1  0.007  0.488  0.356  1.0
  C  C23  1  0.993  0.512  0.644  1.0
  C  C24  1  0.530  0.197  0.990  1.0
  C  C25  1  0.470  0.803  0.010  1.0
  C  C26  1  0.970  0.803  0.990  1.0
  C  C27  1  0.970  0.697  0.510  1.0
  C  C28  1  0.030  0.197  0.010  1.0
  C  C29  1  0.030  0.303  0.490  1.0
  C  C30  1  0.530  0.303  0.510  1.0
  C  C31  1  0.470  0.697  0.490  1.0
  N  N32  1  0.017  0.027  0.229  1.0
  N  N33  1  0.983  0.973  0.771  1.0
  N  N34  1  0.483  0.973  0.229  1.0
  N  N35  1  0.483  0.527  0.271  1.0
  N  N36  1  0.517  0.027  0.771  1.0
  N  N37  1  0.517  0.473  0.729  1.0
  N  N38  1  0.017  0.473  0.271  1.0
  N  N39  1  0.983  0.527  0.729  1.0
  N  N40  1  0.547  0.311  0.976  1.0
  N  N41  1  0.453  0.689  0.024  1.0
  N  N42  1  0.953  0.689  0.976  1.0
  N  N43  1  0.953  0.811  0.524  1.0
  N  N44  1  0.047  0.311  0.024  1.0
  N  N45  1  0.047  0.189  0.476  1.0
  N  N46  1  0.547  0.189  0.524  1.0
  N  N47  1  0.453  0.811  0.476  1.0
[/CIF]
.