The structure described by LiSbMo2O8 crystallizes in the monoclinic C2/c space group. Li(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form LiO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, corners with four equivalent Mo(1)O6 octahedra, and edges with two equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-59°. Mo(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form distorted MoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent Mo(1)O6 octahedra, and  an edgeedge with one Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-53°. Sb(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1) and two equivalent Mo(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent Li(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to two equivalent Mo(1) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mo(1) and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiSb(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.332
_cell_length_b   11.332
_cell_length_c   5.634
_cell_angle_alpha   79.877
_cell_angle_beta   79.877
_cell_angle_gamma   25.604
_symmetry_Int_Tables_number   1
_cell_volume   307.526
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.000  0.000  1.0
  Li  Li1  1  0.000  0.500  0.500  1.0
  Sb  Sb2  1  0.312  0.688  0.250  1.0
  Sb  Sb3  1  0.688  0.312  0.750  1.0
  Mo  Mo4  1  0.889  0.386  0.218  1.0
  Mo  Mo5  1  0.614  0.111  0.282  1.0
  Mo  Mo6  1  0.111  0.614  0.782  1.0
  Mo  Mo7  1  0.386  0.889  0.718  1.0
  O  O8  1  0.614  0.707  0.041  1.0
  O  O9  1  0.293  0.386  0.459  1.0
  O  O10  1  0.386  0.293  0.959  1.0
  O  O11  1  0.707  0.614  0.541  1.0
  O  O12  1  0.116  0.304  0.213  1.0
  O  O13  1  0.696  0.884  0.287  1.0
  O  O14  1  0.884  0.696  0.787  1.0
  O  O15  1  0.304  0.116  0.713  1.0
  O  O16  1  0.943  0.848  0.992  1.0
  O  O17  1  0.152  0.057  0.508  1.0
  O  O18  1  0.057  0.152  0.008  1.0
  O  O19  1  0.848  0.943  0.492  1.0
  O  O20  1  0.540  0.356  0.118  1.0
  O  O21  1  0.644  0.460  0.382  1.0
  O  O22  1  0.460  0.644  0.882  1.0
  O  O23  1  0.356  0.540  0.618  1.0
[/CIF]
.
The structure described by LiSbMo2O8 crystallizes in the monoclinic C2/c space group. Li(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form LiO6 octahedra that share corners with four equivalent Li(1)O6 octahedra, corners with four equivalent Mo(1)O6 octahedra, and edges with two equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-59°. Mo(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form distorted MoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent Mo(1)O6 octahedra, and  an edgeedge with one Li(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-53°. Sb(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(4) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Li(1) and two equivalent Mo(1) atoms. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent Li(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to two equivalent Mo(1) atoms. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Mo(1) and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiSb(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.332
_cell_length_b   11.332
_cell_length_c   5.634
_cell_angle_alpha   79.877
_cell_angle_beta   79.877
_cell_angle_gamma   25.604
_symmetry_Int_Tables_number   1
_cell_volume   307.526
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.000  0.000  1.0
  Li  Li1  1  0.000  0.500  0.500  1.0
  Sb  Sb2  1  0.312  0.688  0.250  1.0
  Sb  Sb3  1  0.688  0.312  0.750  1.0
  Mo  Mo4  1  0.889  0.386  0.218  1.0
  Mo  Mo5  1  0.614  0.111  0.282  1.0
  Mo  Mo6  1  0.111  0.614  0.782  1.0
  Mo  Mo7  1  0.386  0.889  0.718  1.0
  O  O8  1  0.614  0.707  0.041  1.0
  O  O9  1  0.293  0.386  0.459  1.0
  O  O10  1  0.386  0.293  0.959  1.0
  O  O11  1  0.707  0.614  0.541  1.0
  O  O12  1  0.116  0.304  0.213  1.0
  O  O13  1  0.696  0.884  0.287  1.0
  O  O14  1  0.884  0.696  0.787  1.0
  O  O15  1  0.304  0.116  0.713  1.0
  O  O16  1  0.943  0.848  0.992  1.0
  O  O17  1  0.152  0.057  0.508  1.0
  O  O18  1  0.057  0.152  0.008  1.0
  O  O19  1  0.848  0.943  0.492  1.0
  O  O20  1  0.540  0.356  0.118  1.0
  O  O21  1  0.644  0.460  0.382  1.0
  O  O22  1  0.460  0.644  0.882  1.0
  O  O23  1  0.356  0.540  0.618  1.0
[/CIF]
.