The crystal structure described by PrV2O2 crystallizes in the tetragonal I4_1/amd space group. Pr(1) is bonded in a linear geometry to two equivalent O(1) atoms. V(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. O(1) is bonded to one Pr(1) and three equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing OPrV3 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_PrV2O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.931
_cell_length_b   7.931
_cell_length_c   7.931
_cell_angle_alpha   108.878
_cell_angle_beta   108.878
_cell_angle_gamma   110.664
_symmetry_Int_Tables_number   1
_cell_volume   383.842
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.125  0.875  0.750  1.0
  Pr  Pr1  1  0.125  0.375  0.250  1.0
  Pr  Pr2  1  0.625  0.875  0.750  1.0
  Pr  Pr3  1  0.125  0.875  0.250  1.0
  V  V4  1  0.509  0.845  0.336  1.0
  V  V5  1  0.509  0.172  0.664  1.0
  V  V6  1  0.422  0.259  0.164  1.0
  V  V7  1  0.741  0.578  0.836  1.0
  V  V8  1  0.741  0.905  0.164  1.0
  V  V9  1  0.095  0.259  0.836  1.0
  V  V10  1  0.828  0.491  0.336  1.0
  V  V11  1  0.155  0.491  0.664  1.0
  O  O12  1  0.364  0.525  0.160  1.0
  O  O13  1  0.364  0.204  0.840  1.0
  O  O14  1  0.454  0.114  0.340  1.0
  O  O15  1  0.886  0.546  0.660  1.0
  O  O16  1  0.886  0.225  0.340  1.0
  O  O17  1  0.775  0.114  0.660  1.0
  O  O18  1  0.796  0.636  0.160  1.0
  O  O19  1  0.475  0.636  0.840  1.0
[/CIF]
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The crystal structure described by PrV2O2 crystallizes in the tetragonal I4_1/amd space group. Pr(1) is bonded in a linear geometry to two equivalent O(1) atoms. V(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. O(1) is bonded to one Pr(1) and three equivalent V(1) atoms to form a mixture of distorted edge and corner-sharing OPrV3 trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_PrV2O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.931
_cell_length_b   7.931
_cell_length_c   7.931
_cell_angle_alpha   108.878
_cell_angle_beta   108.878
_cell_angle_gamma   110.664
_symmetry_Int_Tables_number   1
_cell_volume   383.842
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.125  0.875  0.750  1.0
  Pr  Pr1  1  0.125  0.375  0.250  1.0
  Pr  Pr2  1  0.625  0.875  0.750  1.0
  Pr  Pr3  1  0.125  0.875  0.250  1.0
  V  V4  1  0.509  0.845  0.336  1.0
  V  V5  1  0.509  0.172  0.664  1.0
  V  V6  1  0.422  0.259  0.164  1.0
  V  V7  1  0.741  0.578  0.836  1.0
  V  V8  1  0.741  0.905  0.164  1.0
  V  V9  1  0.095  0.259  0.836  1.0
  V  V10  1  0.828  0.491  0.336  1.0
  V  V11  1  0.155  0.491  0.664  1.0
  O  O12  1  0.364  0.525  0.160  1.0
  O  O13  1  0.364  0.204  0.840  1.0
  O  O14  1  0.454  0.114  0.340  1.0
  O  O15  1  0.886  0.546  0.660  1.0
  O  O16  1  0.886  0.225  0.340  1.0
  O  O17  1  0.775  0.114  0.660  1.0
  O  O18  1  0.796  0.636  0.160  1.0
  O  O19  1  0.475  0.636  0.840  1.0
[/CIF]
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