The compound described by AgZn crystallizes in the triclinic P1 space group. There are nine inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent Ag(7), two equivalent Ag(9), one Zn(2), one Zn(8), and two equivalent Zn(4) atoms. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent Ag(8), one Zn(1), one Zn(8), and two equivalent Zn(3) atoms. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to two equivalent Ag(4), two equivalent Ag(7), two equivalent Ag(9), one Zn(2), one Zn(9), and two equivalent Zn(4) atoms. In the fourth Ag site, Ag(4) is bonded in a 13-coordinate geometry to two equivalent Ag(3), two equivalent Ag(4), one Zn(4), two equivalent Zn(1), two equivalent Zn(6), two equivalent Zn(7), and two equivalent Zn(9) atoms. In the fifth Ag site, Ag(5) is bonded in a 6-coordinate geometry to one Zn(3), one Zn(8), two equivalent Zn(2), and two equivalent Zn(5) atoms. In the sixth Ag site, Ag(6) is bonded in a 8-coordinate geometry to one Zn(3), one Zn(8), two equivalent Zn(1), two equivalent Zn(5), and two equivalent Zn(7) atoms. In the seventh Ag site, Ag(7) is bonded in a 13-coordinate geometry to two equivalent Ag(1), two equivalent Ag(3), two equivalent Ag(7), one Zn(4), two equivalent Zn(2), two equivalent Zn(6), and two equivalent Zn(9) atoms. In the eighth Ag site, Ag(8) is bonded in a 13-coordinate geometry to two equivalent Ag(2), two equivalent Ag(8), one Zn(3), two equivalent Zn(1), two equivalent Zn(6), two equivalent Zn(7), and two equivalent Zn(9) atoms. In the ninth Ag site, Ag(9) is bonded in a 13-coordinate geometry to two equivalent Ag(1), two equivalent Ag(3), two equivalent Ag(9), one Zn(4), two equivalent Zn(2), two equivalent Zn(5), and two equivalent Zn(8) atoms. There are nine inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 11-coordinate geometry to one Ag(2), two equivalent Ag(4), two equivalent Ag(6), two equivalent Ag(8), one Zn(6), one Zn(7), and two equivalent Zn(1) atoms. In the second Zn site, Zn(2) is bonded in a 11-coordinate geometry to one Ag(1), one Ag(3), two equivalent Ag(5), two equivalent Ag(7), two equivalent Ag(9), one Zn(5), and two equivalent Zn(2) atoms. In the third Zn site, Zn(3) is bonded in a 11-coordinate geometry to one Ag(5), one Ag(6), one Ag(8), two equivalent Ag(2), two equivalent Zn(3), two equivalent Zn(5), and two equivalent Zn(7) atoms. In the fourth Zn site, Zn(4) is bonded in a 11-coordinate geometry to one Ag(4), one Ag(7), one Ag(9), two equivalent Ag(1), two equivalent Ag(3), two equivalent Zn(4), and two equivalent Zn(6) atoms. In the fifth Zn site, Zn(5) is bonded to two equivalent Ag(5), two equivalent Ag(6), two equivalent Ag(9), one Zn(2), one Zn(8), two equivalent Zn(3), and two equivalent Zn(5) atoms to form a mixture of distorted edge, face, and corner-sharing ZnZn6Ag6 cuboctahedra. In the sixth Zn site, Zn(6) is bonded to two equivalent Ag(4), two equivalent Ag(7), two equivalent Ag(8), one Zn(1), one Zn(9), two equivalent Zn(4), and two equivalent Zn(6) atoms to form a mixture of face and corner-sharing ZnZn6Ag6 cuboctahedra. In the seventh Zn site, Zn(7) is bonded to two equivalent Ag(4), two equivalent Ag(6), two equivalent Ag(8), one Zn(1), one Zn(9), two equivalent Zn(3), and two equivalent Zn(7) atoms to form a mixture of edge, face, and corner-sharing ZnZn6Ag6 cuboctahedra. In the eighth Zn site, Zn(8) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(5), one Ag(6), two equivalent Ag(9), and one Zn(5) atom. In the ninth Zn site, Zn(9) is bonded in a 11-coordinate geometry to one Ag(3), two equivalent Ag(4), two equivalent Ag(7), two equivalent Ag(8), one Zn(6), one Zn(7), and two equivalent Zn(9) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnAg
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.900
_cell_length_b   7.660
_cell_length_c   13.270
_cell_angle_alpha   90.626
_cell_angle_beta   90.312
_cell_angle_gamma   90.668
_symmetry_Int_Tables_number   1
_cell_volume   294.705
_cell_formula_units_Z   9
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.764  0.004  0.332  1.0
  Zn  Zn1  1  0.758  0.495  0.830  1.0
  Zn  Zn2  1  0.247  0.498  0.170  1.0
  Zn  Zn3  1  0.247  1.000  0.666  1.0
  Zn  Zn4  1  0.752  0.662  0.017  1.0
  Zn  Zn5  1  0.752  0.159  0.514  1.0
  Zn  Zn6  1  0.752  0.648  0.323  1.0
  Zn  Zn7  1  0.982  0.003  0.002  1.0
  Zn  Zn8  1  0.924  0.503  0.498  1.0
  Ag  Ag9  1  0.748  0.142  0.824  1.0
  Ag  Ag10  1  0.735  0.190  0.162  1.0
  Ag  Ag11  1  0.740  0.694  0.661  1.0
  Ag  Ag12  1  0.270  0.836  0.480  1.0
  Ag  Ag13  1  0.264  0.344  0.985  1.0
  Ag  Ag14  1  0.257  0.847  0.174  1.0
  Ag  Ag15  1  0.259  0.353  0.667  1.0
  Ag  Ag16  1  0.280  0.316  0.347  1.0
  Ag  Ag17  1  0.268  0.804  0.847  1.0
[/CIF]
.
The compound described by AgZn crystallizes in the triclinic P1 space group. There are nine inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to two equivalent Ag(7), two equivalent Ag(9), one Zn(2), one Zn(8), and two equivalent Zn(4) atoms. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to two equivalent Ag(8), one Zn(1), one Zn(8), and two equivalent Zn(3) atoms. In the third Ag site, Ag(3) is bonded in a 4-coordinate geometry to two equivalent Ag(4), two equivalent Ag(7), two equivalent Ag(9), one Zn(2), one Zn(9), and two equivalent Zn(4) atoms. In the fourth Ag site, Ag(4) is bonded in a 13-coordinate geometry to two equivalent Ag(3), two equivalent Ag(4), one Zn(4), two equivalent Zn(1), two equivalent Zn(6), two equivalent Zn(7), and two equivalent Zn(9) atoms. In the fifth Ag site, Ag(5) is bonded in a 6-coordinate geometry to one Zn(3), one Zn(8), two equivalent Zn(2), and two equivalent Zn(5) atoms. In the sixth Ag site, Ag(6) is bonded in a 8-coordinate geometry to one Zn(3), one Zn(8), two equivalent Zn(1), two equivalent Zn(5), and two equivalent Zn(7) atoms. In the seventh Ag site, Ag(7) is bonded in a 13-coordinate geometry to two equivalent Ag(1), two equivalent Ag(3), two equivalent Ag(7), one Zn(4), two equivalent Zn(2), two equivalent Zn(6), and two equivalent Zn(9) atoms. In the eighth Ag site, Ag(8) is bonded in a 13-coordinate geometry to two equivalent Ag(2), two equivalent Ag(8), one Zn(3), two equivalent Zn(1), two equivalent Zn(6), two equivalent Zn(7), and two equivalent Zn(9) atoms. In the ninth Ag site, Ag(9) is bonded in a 13-coordinate geometry to two equivalent Ag(1), two equivalent Ag(3), two equivalent Ag(9), one Zn(4), two equivalent Zn(2), two equivalent Zn(5), and two equivalent Zn(8) atoms. There are nine inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 11-coordinate geometry to one Ag(2), two equivalent Ag(4), two equivalent Ag(6), two equivalent Ag(8), one Zn(6), one Zn(7), and two equivalent Zn(1) atoms. In the second Zn site, Zn(2) is bonded in a 11-coordinate geometry to one Ag(1), one Ag(3), two equivalent Ag(5), two equivalent Ag(7), two equivalent Ag(9), one Zn(5), and two equivalent Zn(2) atoms. In the third Zn site, Zn(3) is bonded in a 11-coordinate geometry to one Ag(5), one Ag(6), one Ag(8), two equivalent Ag(2), two equivalent Zn(3), two equivalent Zn(5), and two equivalent Zn(7) atoms. In the fourth Zn site, Zn(4) is bonded in a 11-coordinate geometry to one Ag(4), one Ag(7), one Ag(9), two equivalent Ag(1), two equivalent Ag(3), two equivalent Zn(4), and two equivalent Zn(6) atoms. In the fifth Zn site, Zn(5) is bonded to two equivalent Ag(5), two equivalent Ag(6), two equivalent Ag(9), one Zn(2), one Zn(8), two equivalent Zn(3), and two equivalent Zn(5) atoms to form a mixture of distorted edge, face, and corner-sharing ZnZn6Ag6 cuboctahedra. In the sixth Zn site, Zn(6) is bonded to two equivalent Ag(4), two equivalent Ag(7), two equivalent Ag(8), one Zn(1), one Zn(9), two equivalent Zn(4), and two equivalent Zn(6) atoms to form a mixture of face and corner-sharing ZnZn6Ag6 cuboctahedra. In the seventh Zn site, Zn(7) is bonded to two equivalent Ag(4), two equivalent Ag(6), two equivalent Ag(8), one Zn(1), one Zn(9), two equivalent Zn(3), and two equivalent Zn(7) atoms to form a mixture of edge, face, and corner-sharing ZnZn6Ag6 cuboctahedra. In the eighth Zn site, Zn(8) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(5), one Ag(6), two equivalent Ag(9), and one Zn(5) atom. In the ninth Zn site, Zn(9) is bonded in a 11-coordinate geometry to one Ag(3), two equivalent Ag(4), two equivalent Ag(7), two equivalent Ag(8), one Zn(6), one Zn(7), and two equivalent Zn(9) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnAg
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.900
_cell_length_b   7.660
_cell_length_c   13.270
_cell_angle_alpha   90.626
_cell_angle_beta   90.312
_cell_angle_gamma   90.668
_symmetry_Int_Tables_number   1
_cell_volume   294.705
_cell_formula_units_Z   9
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.764  0.004  0.332  1.0
  Zn  Zn1  1  0.758  0.495  0.830  1.0
  Zn  Zn2  1  0.247  0.498  0.170  1.0
  Zn  Zn3  1  0.247  1.000  0.666  1.0
  Zn  Zn4  1  0.752  0.662  0.017  1.0
  Zn  Zn5  1  0.752  0.159  0.514  1.0
  Zn  Zn6  1  0.752  0.648  0.323  1.0
  Zn  Zn7  1  0.982  0.003  0.002  1.0
  Zn  Zn8  1  0.924  0.503  0.498  1.0
  Ag  Ag9  1  0.748  0.142  0.824  1.0
  Ag  Ag10  1  0.735  0.190  0.162  1.0
  Ag  Ag11  1  0.740  0.694  0.661  1.0
  Ag  Ag12  1  0.270  0.836  0.480  1.0
  Ag  Ag13  1  0.264  0.344  0.985  1.0
  Ag  Ag14  1  0.257  0.847  0.174  1.0
  Ag  Ag15  1  0.259  0.353  0.667  1.0
  Ag  Ag16  1  0.280  0.316  0.347  1.0
  Ag  Ag17  1  0.268  0.804  0.847  1.0
[/CIF]
.