The material structure described by SbP(OF3)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one SbP(OF3)2 cluster. Sb(1) is bonded to one O(1), one O(2), one F(1), one F(4), one F(5), and one F(6) atom to form SbO2F4 octahedra that share corners with two equivalent P(1)O2F2 tetrahedra. P(1) is bonded to one O(1), one O(2), one F(2), and one F(3) atom to form PO2F2 tetrahedra that share corners with two equivalent Sb(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 43-44°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_SbP(OF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.700
_cell_length_b   7.558
_cell_length_c   7.616
_cell_angle_alpha   88.353
_cell_angle_beta   76.156
_cell_angle_gamma   83.426
_symmetry_Int_Tables_number   1
_cell_volume   316.508
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.582  0.231  0.756  1.0
  Sb  Sb1  1  0.418  0.769  0.244  1.0
  P  P2  1  0.230  0.192  0.167  1.0
  P  P3  1  0.770  0.808  0.833  1.0
  O  O4  1  0.565  0.736  0.971  1.0
  O  O5  1  0.783  0.007  0.825  1.0
  O  O6  1  0.435  0.264  0.029  1.0
  O  O7  1  0.217  0.993  0.175  1.0
  F  F8  1  0.391  0.439  0.709  1.0
  F  F9  1  0.242  0.263  0.352  1.0
  F  F10  1  0.016  0.722  0.859  1.0
  F  F11  1  0.736  0.183  0.510  1.0
  F  F12  1  0.264  0.817  0.490  1.0
  F  F13  1  0.609  0.561  0.291  1.0
  F  F14  1  0.833  0.358  0.794  1.0
  F  F15  1  0.167  0.642  0.206  1.0
  F  F16  1  0.334  0.082  0.754  1.0
  F  F17  1  0.666  0.918  0.246  1.0
  F  F18  1  0.758  0.737  0.648  1.0
  F  F19  1  0.984  0.278  0.141  1.0
[/CIF]
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The material structure described by SbP(OF3)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one SbP(OF3)2 cluster. Sb(1) is bonded to one O(1), one O(2), one F(1), one F(4), one F(5), and one F(6) atom to form SbO2F4 octahedra that share corners with two equivalent P(1)O2F2 tetrahedra. P(1) is bonded to one O(1), one O(2), one F(2), and one F(3) atom to form PO2F2 tetrahedra that share corners with two equivalent Sb(1)O2F4 octahedra. The corner-sharing octahedral tilt angles range from 43-44°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Sb(1) and one P(1) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_SbP(OF3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.700
_cell_length_b   7.558
_cell_length_c   7.616
_cell_angle_alpha   88.353
_cell_angle_beta   76.156
_cell_angle_gamma   83.426
_symmetry_Int_Tables_number   1
_cell_volume   316.508
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.582  0.231  0.756  1.0
  Sb  Sb1  1  0.418  0.769  0.244  1.0
  P  P2  1  0.230  0.192  0.167  1.0
  P  P3  1  0.770  0.808  0.833  1.0
  O  O4  1  0.565  0.736  0.971  1.0
  O  O5  1  0.783  0.007  0.825  1.0
  O  O6  1  0.435  0.264  0.029  1.0
  O  O7  1  0.217  0.993  0.175  1.0
  F  F8  1  0.391  0.439  0.709  1.0
  F  F9  1  0.242  0.263  0.352  1.0
  F  F10  1  0.016  0.722  0.859  1.0
  F  F11  1  0.736  0.183  0.510  1.0
  F  F12  1  0.264  0.817  0.490  1.0
  F  F13  1  0.609  0.561  0.291  1.0
  F  F14  1  0.833  0.358  0.794  1.0
  F  F15  1  0.167  0.642  0.206  1.0
  F  F16  1  0.334  0.082  0.754  1.0
  F  F17  1  0.666  0.918  0.246  1.0
  F  F18  1  0.758  0.737  0.648  1.0
  F  F19  1  0.984  0.278  0.141  1.0
[/CIF]
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