The structure described by Rb2MnF5 crystallizes in the tetragonal P4/mmm space group. Rb(1) is bonded in a distorted q6 geometry to two equivalent F(1) and eight equivalent F(2) atoms. Mn(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted linear geometry to four equivalent Rb(1) and two equivalent Mn(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to four equivalent Rb(1) and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2MnF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.164
_cell_length_b   5.985
_cell_length_c   5.985
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   149.169
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.000  0.500  1.0
  Rb  Rb1  1  0.500  0.500  0.000  1.0
  Mn  Mn2  1  0.000  0.000  0.000  1.0
  F  F3  1  0.500  0.000  0.000  1.0
  F  F4  1  0.000  0.779  0.779  1.0
  F  F5  1  0.000  0.221  0.779  1.0
  F  F6  1  0.000  0.221  0.221  1.0
  F  F7  1  0.000  0.779  0.221  1.0
[/CIF]
.
The structure described by Rb2MnF5 crystallizes in the tetragonal P4/mmm space group. Rb(1) is bonded in a distorted q6 geometry to two equivalent F(1) and eight equivalent F(2) atoms. Mn(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form corner-sharing MnF6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent F sites. In the first F site, F(1) is bonded in a distorted linear geometry to four equivalent Rb(1) and two equivalent Mn(1) atoms. In the second F site, F(2) is bonded in a single-bond geometry to four equivalent Rb(1) and one Mn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2MnF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.164
_cell_length_b   5.985
_cell_length_c   5.985
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   149.169
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.000  0.500  1.0
  Rb  Rb1  1  0.500  0.500  0.000  1.0
  Mn  Mn2  1  0.000  0.000  0.000  1.0
  F  F3  1  0.500  0.000  0.000  1.0
  F  F4  1  0.000  0.779  0.779  1.0
  F  F5  1  0.000  0.221  0.779  1.0
  F  F6  1  0.000  0.221  0.221  1.0
  F  F7  1  0.000  0.779  0.221  1.0
[/CIF]
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