The crystal structure described by S3(NO)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four S3(NO)2 clusters. N(1) is bonded in a single-bond geometry to one S(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one N(1) and one O(1) atom. In the second S site, S(2) is bonded in a water-like geometry to two equivalent O(1) atoms. O(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_S3(NO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.303
_cell_length_b   9.303
_cell_length_c   7.295
_cell_angle_alpha   83.935
_cell_angle_beta   83.935
_cell_angle_gamma   29.530
_symmetry_Int_Tables_number   1
_cell_volume   309.277
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.414  0.894  0.367  1.0
  S  S1  1  0.144  0.856  0.250  1.0
  S  S2  1  0.856  0.144  0.750  1.0
  S  S3  1  0.586  0.106  0.633  1.0
  S  S4  1  0.106  0.586  0.133  1.0
  S  S5  1  0.894  0.414  0.867  1.0
  N  N6  1  0.868  0.789  0.626  1.0
  N  N7  1  0.132  0.211  0.374  1.0
  N  N8  1  0.789  0.868  0.126  1.0
  N  N9  1  0.211  0.132  0.874  1.0
  O  O10  1  0.430  0.697  0.303  1.0
  O  O11  1  0.303  0.570  0.197  1.0
  O  O12  1  0.570  0.303  0.697  1.0
  O  O13  1  0.697  0.430  0.803  1.0
[/CIF]
.
The crystal structure described by S3(NO)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four S3(NO)2 clusters. N(1) is bonded in a single-bond geometry to one S(1) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one N(1) and one O(1) atom. In the second S site, S(2) is bonded in a water-like geometry to two equivalent O(1) atoms. O(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_S3(NO)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.303
_cell_length_b   9.303
_cell_length_c   7.295
_cell_angle_alpha   83.935
_cell_angle_beta   83.935
_cell_angle_gamma   29.530
_symmetry_Int_Tables_number   1
_cell_volume   309.277
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.414  0.894  0.367  1.0
  S  S1  1  0.144  0.856  0.250  1.0
  S  S2  1  0.856  0.144  0.750  1.0
  S  S3  1  0.586  0.106  0.633  1.0
  S  S4  1  0.106  0.586  0.133  1.0
  S  S5  1  0.894  0.414  0.867  1.0
  N  N6  1  0.868  0.789  0.626  1.0
  N  N7  1  0.132  0.211  0.374  1.0
  N  N8  1  0.789  0.868  0.126  1.0
  N  N9  1  0.211  0.132  0.874  1.0
  O  O10  1  0.430  0.697  0.303  1.0
  O  O11  1  0.303  0.570  0.197  1.0
  O  O12  1  0.570  0.303  0.697  1.0
  O  O13  1  0.697  0.430  0.803  1.0
[/CIF]
.