The crystal structure described by VOSO4 crystallizes in the tetragonal P4/n space group. V(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. S(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VSO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.967
_cell_length_b   6.257
_cell_length_c   6.257
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   155.287
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.375  0.750  0.750  1.0
  V  V1  1  0.625  0.250  0.250  1.0
  S  S2  1  0.500  0.750  0.250  1.0
  S  S3  1  0.500  0.250  0.750  1.0
  O  O4  1  0.715  0.283  0.938  1.0
  O  O5  1  0.715  0.562  0.283  1.0
  O  O6  1  0.218  0.250  0.250  1.0
  O  O7  1  0.782  0.750  0.750  1.0
  O  O8  1  0.715  0.938  0.217  1.0
  O  O9  1  0.715  0.217  0.562  1.0
  O  O10  1  0.285  0.783  0.438  1.0
  O  O11  1  0.285  0.062  0.783  1.0
  O  O12  1  0.285  0.438  0.717  1.0
  O  O13  1  0.285  0.717  0.062  1.0
[/CIF]
.
The crystal structure described by VOSO4 crystallizes in the tetragonal P4/n space group. V(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. S(1) is bonded in a tetrahedral geometry to four equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one V(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VSO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.967
_cell_length_b   6.257
_cell_length_c   6.257
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   155.287
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.375  0.750  0.750  1.0
  V  V1  1  0.625  0.250  0.250  1.0
  S  S2  1  0.500  0.750  0.250  1.0
  S  S3  1  0.500  0.250  0.750  1.0
  O  O4  1  0.715  0.283  0.938  1.0
  O  O5  1  0.715  0.562  0.283  1.0
  O  O6  1  0.218  0.250  0.250  1.0
  O  O7  1  0.782  0.750  0.750  1.0
  O  O8  1  0.715  0.938  0.217  1.0
  O  O9  1  0.715  0.217  0.562  1.0
  O  O10  1  0.285  0.783  0.438  1.0
  O  O11  1  0.285  0.062  0.783  1.0
  O  O12  1  0.285  0.438  0.717  1.0
  O  O13  1  0.285  0.717  0.062  1.0
[/CIF]
.