The compound described by KAuN12 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 10-coordinate geometry to two equivalent N(5), four equivalent N(2), and four equivalent N(6) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(5) atoms. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Au(1) and one N(3) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one N(4) atom. In the third N site, N(3) is bonded in a linear geometry to one N(1) and one N(6) atom. In the fourth N site, N(4) is bonded in a linear geometry to one N(2) and one N(5) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one K(1), one Au(1), and one N(4) atom. In the sixth N site, N(6) is bonded in a 3-coordinate geometry to two equivalent K(1) and one N(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KAuN12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.612
_cell_length_b   7.612
_cell_length_c   8.031
_cell_angle_alpha   88.695
_cell_angle_beta   88.695
_cell_angle_gamma   89.542
_symmetry_Int_Tables_number   1
_cell_volume   465.105
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.086  0.914  0.750  1.0
  K  K1  1  0.914  0.086  0.250  1.0
  Au  Au2  1  0.494  0.506  0.750  1.0
  Au  Au3  1  0.506  0.494  0.250  1.0
  N  N4  1  0.756  0.515  0.681  1.0
  N  N5  1  0.485  0.244  0.819  1.0
  N  N6  1  0.715  0.908  0.543  1.0
  N  N7  1  0.830  0.385  0.628  1.0
  N  N8  1  0.285  0.092  0.457  1.0
  N  N9  1  0.515  0.756  0.181  1.0
  N  N10  1  0.092  0.285  0.957  1.0
  N  N11  1  0.163  0.402  0.891  1.0
  N  N12  1  0.470  0.771  0.678  1.0
  N  N13  1  0.837  0.598  0.109  1.0
  N  N14  1  0.530  0.229  0.322  1.0
  N  N15  1  0.771  0.470  0.178  1.0
  N  N16  1  0.915  0.270  0.577  1.0
  N  N17  1  0.385  0.830  0.128  1.0
  N  N18  1  0.270  0.915  0.077  1.0
  N  N19  1  0.598  0.837  0.609  1.0
  N  N20  1  0.244  0.485  0.319  1.0
  N  N21  1  0.908  0.715  0.043  1.0
  N  N22  1  0.229  0.530  0.822  1.0
  N  N23  1  0.085  0.730  0.423  1.0
  N  N24  1  0.615  0.170  0.872  1.0
  N  N25  1  0.170  0.615  0.372  1.0
  N  N26  1  0.730  0.085  0.923  1.0
  N  N27  1  0.402  0.163  0.391  1.0
[/CIF]
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The compound described by KAuN12 crystallizes in the monoclinic C2/c space group. K(1) is bonded in a 10-coordinate geometry to two equivalent N(5), four equivalent N(2), and four equivalent N(6) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(5) atoms. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Au(1) and one N(3) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and one N(4) atom. In the third N site, N(3) is bonded in a linear geometry to one N(1) and one N(6) atom. In the fourth N site, N(4) is bonded in a linear geometry to one N(2) and one N(5) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one K(1), one Au(1), and one N(4) atom. In the sixth N site, N(6) is bonded in a 3-coordinate geometry to two equivalent K(1) and one N(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_KAuN12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.612
_cell_length_b   7.612
_cell_length_c   8.031
_cell_angle_alpha   88.695
_cell_angle_beta   88.695
_cell_angle_gamma   89.542
_symmetry_Int_Tables_number   1
_cell_volume   465.105
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.086  0.914  0.750  1.0
  K  K1  1  0.914  0.086  0.250  1.0
  Au  Au2  1  0.494  0.506  0.750  1.0
  Au  Au3  1  0.506  0.494  0.250  1.0
  N  N4  1  0.756  0.515  0.681  1.0
  N  N5  1  0.485  0.244  0.819  1.0
  N  N6  1  0.715  0.908  0.543  1.0
  N  N7  1  0.830  0.385  0.628  1.0
  N  N8  1  0.285  0.092  0.457  1.0
  N  N9  1  0.515  0.756  0.181  1.0
  N  N10  1  0.092  0.285  0.957  1.0
  N  N11  1  0.163  0.402  0.891  1.0
  N  N12  1  0.470  0.771  0.678  1.0
  N  N13  1  0.837  0.598  0.109  1.0
  N  N14  1  0.530  0.229  0.322  1.0
  N  N15  1  0.771  0.470  0.178  1.0
  N  N16  1  0.915  0.270  0.577  1.0
  N  N17  1  0.385  0.830  0.128  1.0
  N  N18  1  0.270  0.915  0.077  1.0
  N  N19  1  0.598  0.837  0.609  1.0
  N  N20  1  0.244  0.485  0.319  1.0
  N  N21  1  0.908  0.715  0.043  1.0
  N  N22  1  0.229  0.530  0.822  1.0
  N  N23  1  0.085  0.730  0.423  1.0
  N  N24  1  0.615  0.170  0.872  1.0
  N  N25  1  0.170  0.615  0.372  1.0
  N  N26  1  0.730  0.085  0.923  1.0
  N  N27  1  0.402  0.163  0.391  1.0
[/CIF]
.