The structure described by SrLa3MnO12 crystallizes in the trigonal R3 space group. Sr(1) is bonded to three equivalent O(3), three equivalent O(4), and six equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with six equivalent Sr(1)O12 cuboctahedra, corners with six equivalent La(1)O12 cuboctahedra, faces with three equivalent La(2)O12 cuboctahedra, faces with three equivalent La(3)O12 cuboctahedra, and faces with three equivalent Mn(1)O6 octahedra. There are three inequivalent La sites. In the first La site, La(1) is bonded to three equivalent O(3), three equivalent O(4), and six equivalent O(2) atoms to form LaO12 cuboctahedra that share corners with six equivalent Sr(1)O12 cuboctahedra, corners with six equivalent La(1)O12 cuboctahedra, faces with three equivalent La(2)O12 cuboctahedra, faces with three equivalent La(3)O12 cuboctahedra, and  a faceface with one Mn(1)O6 octahedra. In the second La site, La(2) is bonded to three equivalent O(1), three equivalent O(2), and six equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with six equivalent La(2)O12 cuboctahedra, corners with six equivalent La(3)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, and  a faceface with one Mn(1)O6 octahedra. In the third La site, La(3) is bonded to three equivalent O(1), three equivalent O(2), and six equivalent O(3) atoms to form LaO12 cuboctahedra that share corners with six equivalent La(2)O12 cuboctahedra, corners with six equivalent La(3)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, and faces with three equivalent Mn(1)O6 octahedra. Mn(1) is bonded to three equivalent O(1) and three equivalent O(3) atoms to form MnO6 octahedra that share  a faceface with one La(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent La(3)O12 cuboctahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Sr(1), one La(2), one La(3), and one Mn(1) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one La(2), one La(3), and two equivalent La(1) atoms. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Sr(1), one La(1), two equivalent La(3), and one Mn(1) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Sr(1), one La(1), and two equivalent La(2) atoms. is represented by the CIF card [CIF]
data_SrLa3MnO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.305
_cell_length_b   9.305
_cell_length_c   9.305
_cell_angle_alpha   33.540
_cell_angle_beta   33.540
_cell_angle_gamma   33.540
_symmetry_Int_Tables_number   1
_cell_volume   219.071
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.628  0.628  0.628  1.0
  La  La1  1  0.124  0.124  0.124  1.0
  La  La2  1  0.378  0.378  0.378  1.0
  La  La3  1  0.872  0.872  0.872  1.0
  Mn  Mn4  1  0.253  0.253  0.253  1.0
  O  O5  1  0.131  0.622  0.120  1.0
  O  O6  1  0.641  0.113  0.612  1.0
  O  O7  1  0.120  0.131  0.622  1.0
  O  O8  1  0.612  0.641  0.113  1.0
  O  O9  1  0.622  0.120  0.131  1.0
  O  O10  1  0.113  0.612  0.641  1.0
  O  O11  1  0.394  0.338  0.888  1.0
  O  O12  1  0.888  0.866  0.383  1.0
  O  O13  1  0.888  0.394  0.338  1.0
  O  O14  1  0.383  0.888  0.866  1.0
  O  O15  1  0.338  0.888  0.394  1.0
  O  O16  1  0.866  0.383  0.888  1.0
[/CIF]
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The structure described by SrLa3MnO12 crystallizes in the trigonal R3 space group. Sr(1) is bonded to three equivalent O(3), three equivalent O(4), and six equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with six equivalent Sr(1)O12 cuboctahedra, corners with six equivalent La(1)O12 cuboctahedra, faces with three equivalent La(2)O12 cuboctahedra, faces with three equivalent La(3)O12 cuboctahedra, and faces with three equivalent Mn(1)O6 octahedra. There are three inequivalent La sites. In the first La site, La(1) is bonded to three equivalent O(3), three equivalent O(4), and six equivalent O(2) atoms to form LaO12 cuboctahedra that share corners with six equivalent Sr(1)O12 cuboctahedra, corners with six equivalent La(1)O12 cuboctahedra, faces with three equivalent La(2)O12 cuboctahedra, faces with three equivalent La(3)O12 cuboctahedra, and  a faceface with one Mn(1)O6 octahedra. In the second La site, La(2) is bonded to three equivalent O(1), three equivalent O(2), and six equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with six equivalent La(2)O12 cuboctahedra, corners with six equivalent La(3)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, and  a faceface with one Mn(1)O6 octahedra. In the third La site, La(3) is bonded to three equivalent O(1), three equivalent O(2), and six equivalent O(3) atoms to form LaO12 cuboctahedra that share corners with six equivalent La(2)O12 cuboctahedra, corners with six equivalent La(3)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, and faces with three equivalent Mn(1)O6 octahedra. Mn(1) is bonded to three equivalent O(1) and three equivalent O(3) atoms to form MnO6 octahedra that share  a faceface with one La(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent La(3)O12 cuboctahedra. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Sr(1), one La(2), one La(3), and one Mn(1) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one La(2), one La(3), and two equivalent La(1) atoms. In the third O site, O(3) is bonded in a 5-coordinate geometry to one Sr(1), one La(1), two equivalent La(3), and one Mn(1) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Sr(1), one La(1), and two equivalent La(2) atoms. is represented by the CIF card [CIF]
data_SrLa3MnO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.305
_cell_length_b   9.305
_cell_length_c   9.305
_cell_angle_alpha   33.540
_cell_angle_beta   33.540
_cell_angle_gamma   33.540
_symmetry_Int_Tables_number   1
_cell_volume   219.071
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.628  0.628  0.628  1.0
  La  La1  1  0.124  0.124  0.124  1.0
  La  La2  1  0.378  0.378  0.378  1.0
  La  La3  1  0.872  0.872  0.872  1.0
  Mn  Mn4  1  0.253  0.253  0.253  1.0
  O  O5  1  0.131  0.622  0.120  1.0
  O  O6  1  0.641  0.113  0.612  1.0
  O  O7  1  0.120  0.131  0.622  1.0
  O  O8  1  0.612  0.641  0.113  1.0
  O  O9  1  0.622  0.120  0.131  1.0
  O  O10  1  0.113  0.612  0.641  1.0
  O  O11  1  0.394  0.338  0.888  1.0
  O  O12  1  0.888  0.866  0.383  1.0
  O  O13  1  0.888  0.394  0.338  1.0
  O  O14  1  0.383  0.888  0.866  1.0
  O  O15  1  0.338  0.888  0.394  1.0
  O  O16  1  0.866  0.383  0.888  1.0
[/CIF]
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