The compound described by PdAs2 is Pyrite structured and crystallizes in the cubic Pa-3 space group. Pd(1) is bonded to six equivalent As(1) atoms to form PdAs6 octahedra that share corners with twelve equivalent Pd(1)As6 octahedra and corners with six equivalent As(1)AsPd3 tetrahedra. The corner-sharing octahedral tilt angles are 64°. As(1) is bonded to three equivalent Pd(1) and one As(1) atom to form AsAsPd3 tetrahedra that share corners with three equivalent Pd(1)As6 octahedra and corners with fifteen equivalent As(1)AsPd3 tetrahedra. The corner-sharing octahedral tilt angles are 78°. is represented by the Crystallographic Information File (CIF) [CIF]
data_As2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.028
_cell_length_b   6.028
_cell_length_c   6.028
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   219.014
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.384  0.116  0.884  1.0
  As  As1  1  0.116  0.884  0.384  1.0
  As  As2  1  0.884  0.384  0.116  1.0
  As  As3  1  0.616  0.616  0.616  1.0
  As  As4  1  0.384  0.384  0.384  1.0
  As  As5  1  0.116  0.616  0.884  1.0
  As  As6  1  0.884  0.116  0.616  1.0
  As  As7  1  0.616  0.884  0.116  1.0
  Pd  Pd8  1  0.000  0.500  0.500  1.0
  Pd  Pd9  1  0.500  0.500  0.000  1.0
  Pd  Pd10  1  0.500  0.000  0.500  1.0
  Pd  Pd11  1  0.000  0.000  0.000  1.0
[/CIF]
.
The compound described by PdAs2 is Pyrite structured and crystallizes in the cubic Pa-3 space group. Pd(1) is bonded to six equivalent As(1) atoms to form PdAs6 octahedra that share corners with twelve equivalent Pd(1)As6 octahedra and corners with six equivalent As(1)AsPd3 tetrahedra. The corner-sharing octahedral tilt angles are 64°. As(1) is bonded to three equivalent Pd(1) and one As(1) atom to form AsAsPd3 tetrahedra that share corners with three equivalent Pd(1)As6 octahedra and corners with fifteen equivalent As(1)AsPd3 tetrahedra. The corner-sharing octahedral tilt angles are 78°. is represented by the Crystallographic Information File (CIF) [CIF]
data_As2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.028
_cell_length_b   6.028
_cell_length_c   6.028
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   219.014
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.384  0.116  0.884  1.0
  As  As1  1  0.116  0.884  0.384  1.0
  As  As2  1  0.884  0.384  0.116  1.0
  As  As3  1  0.616  0.616  0.616  1.0
  As  As4  1  0.384  0.384  0.384  1.0
  As  As5  1  0.116  0.616  0.884  1.0
  As  As6  1  0.884  0.116  0.616  1.0
  As  As7  1  0.616  0.884  0.116  1.0
  Pd  Pd8  1  0.000  0.500  0.500  1.0
  Pd  Pd9  1  0.500  0.500  0.000  1.0
  Pd  Pd10  1  0.500  0.000  0.500  1.0
  Pd  Pd11  1  0.000  0.000  0.000  1.0
[/CIF]
.