The material structure described by Zn(MoO2)2 is Spinel-like structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(2), one O(3), one O(4), one O(6), one O(8), and one O(9) atom to form MoO6 octahedra that share  a cornercorner with one Mo(12)O4 tetrahedra,  a cornercorner with one Zn(2)O4 tetrahedra, corners with two equivalent Mo(7)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, edges with two equivalent Mo(2)O6 octahedra, and edges with two equivalent Mo(4)O6 octahedra. In the second Mo site, Mo(2) is bonded to one O(1), one O(12), one O(2), one O(4), one O(6), and one O(9) atom to form MoO6 octahedra that share  a cornercorner with one Mo(12)O4 tetrahedra,  a cornercorner with one Zn(2)O4 tetrahedra, corners with two equivalent Mo(7)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, edges with two equivalent Mo(1)O6 octahedra, and edges with two equivalent Mo(4)O6 octahedra. In the third Mo site, Mo(3) is bonded to one O(10), one O(11), one O(14), one O(15), one O(17), and one O(7) atom to form MoO6 octahedra that share  a cornercorner with one Mo(7)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(6)O4 tetrahedra,  an edgeedge with one Mo(6)O6 octahedra,  an edgeedge with one Zn(3)O6 octahedra, edges with two equivalent Mo(5)O6 octahedra, and edges with two equivalent Mo(9)O6 octahedra. In the fourth Mo site, Mo(4) is bonded to one O(1), one O(12), one O(2), one O(3), one O(8), and one O(9) atom to form MoO6 octahedra that share  a cornercorner with one Mo(12)O4 tetrahedra,  a cornercorner with one Zn(2)O4 tetrahedra, corners with two equivalent Mo(7)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, edges with two equivalent Mo(1)O6 octahedra, and edges with two equivalent Mo(2)O6 octahedra. In the fifth Mo site, Mo(5) is bonded to one O(11), one O(14), one O(17), one O(20), one O(5), and one O(7) atom to form MoO6 octahedra that share  a cornercorner with one Mo(7)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(6)O4 tetrahedra,  an edgeedge with one Mo(6)O6 octahedra,  an edgeedge with one Zn(3)O6 octahedra, edges with two equivalent Mo(3)O6 octahedra, and edges with two equivalent Mo(9)O6 octahedra. In the sixth Mo site, Mo(6) is bonded to one O(13), one O(14), one O(15), one O(18), one O(19), and one O(20) atom to form MoO6 octahedra that share corners with three equivalent Zn(4)O4 tetrahedra, corners with three equivalent Zn(6)O4 tetrahedra,  an edgeedge with one Mo(10)O6 octahedra,  an edgeedge with one Mo(11)O6 octahedra,  an edgeedge with one Mo(3)O6 octahedra,  an edgeedge with one Mo(5)O6 octahedra,  an edgeedge with one Mo(8)O6 octahedra, and  an edgeedge with one Mo(9)O6 octahedra. In the seventh Mo site, Mo(7) is bonded to one O(12), one O(17), one O(6), and one O(8) atom to form MoO4 tetrahedra that share  a cornercorner with one Mo(3)O6 octahedra,  a cornercorner with one Mo(5)O6 octahedra,  a cornercorner with one Mo(9)O6 octahedra, corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Mo(2)O6 octahedra, corners with two equivalent Mo(4)O6 octahedra, and corners with three equivalent Zn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-66°. In the eighth Mo site, Mo(8) is bonded to one O(16), one O(18), one O(19), one O(21), one O(22), and one O(23) atom to form MoO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra, corners with two equivalent Mo(12)O4 tetrahedra, corners with two equivalent Zn(4)O4 tetrahedra,  an edgeedge with one Mo(6)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, edges with two equivalent Mo(10)O6 octahedra, and edges with two equivalent Mo(11)O6 octahedra. In the ninth Mo site, Mo(9) is bonded to one O(10), one O(15), one O(17), one O(20), one O(5), and one O(7) atom to form MoO6 octahedra that share  a cornercorner with one Mo(7)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(6)O4 tetrahedra,  an edgeedge with one Mo(6)O6 octahedra,  an edgeedge with one Zn(3)O6 octahedra, edges with two equivalent Mo(3)O6 octahedra, and edges with two equivalent Mo(5)O6 octahedra. In the tenth Mo site, Mo(10) is bonded to one O(13), one O(16), one O(19), one O(21), one O(23), and one O(24) atom to form MoO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra, corners with two equivalent Mo(12)O4 tetrahedra, corners with two equivalent Zn(4)O4 tetrahedra,  an edgeedge with one Mo(6)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, edges with two equivalent Mo(11)O6 octahedra, and edges with two equivalent Mo(8)O6 octahedra. In the eleventh Mo site, Mo(11) is bonded to one O(13), one O(16), one O(18), one O(22), one O(23), and one O(24) atom to form MoO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra, corners with two equivalent Mo(12)O4 tetrahedra, corners with two equivalent Zn(4)O4 tetrahedra,  an edgeedge with one Mo(6)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, edges with two equivalent Mo(10)O6 octahedra, and edges with two equivalent Mo(8)O6 octahedra. In the twelfth Mo site, Mo(12) is bonded to one O(21), one O(22), one O(24), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one Mo(1)O6 octahedra,  a cornercorner with one Mo(2)O6 octahedra,  a cornercorner with one Mo(4)O6 octahedra, corners with two equivalent Mo(10)O6 octahedra, corners with two equivalent Mo(11)O6 octahedra, corners with two equivalent Mo(8)O6 octahedra, and corners with three equivalent Zn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-64°. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(16), one O(3), and one O(4) atom to form ZnO4 tetrahedra that share  a cornercorner with one Mo(10)O6 octahedra,  a cornercorner with one Mo(11)O6 octahedra,  a cornercorner with one Mo(8)O6 octahedra, corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Mo(2)O6 octahedra, corners with two equivalent Mo(4)O6 octahedra, and corners with three equivalent Zn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-61°. In the second Zn site, Zn(2) is bonded to one O(10), one O(11), one O(2), and one O(5) atom to form ZnO4 tetrahedra that share  a cornercorner with one Mo(1)O6 octahedra,  a cornercorner with one Mo(2)O6 octahedra,  a cornercorner with one Mo(4)O6 octahedra, corners with two equivalent Mo(3)O6 octahedra, corners with two equivalent Mo(5)O6 octahedra, corners with two equivalent Mo(9)O6 octahedra, and corners with three equivalent Zn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-61°. In the third Zn site, Zn(3) is bonded to one O(10), one O(11), one O(12), one O(5), one O(6), and one O(8) atom to form ZnO6 octahedra that share corners with three equivalent Mo(7)O4 tetrahedra, corners with three equivalent Zn(2)O4 tetrahedra,  an edgeedge with one Mo(1)O6 octahedra,  an edgeedge with one Mo(2)O6 octahedra,  an edgeedge with one Mo(3)O6 octahedra,  an edgeedge with one Mo(4)O6 octahedra,  an edgeedge with one Mo(5)O6 octahedra, and  an edgeedge with one Mo(9)O6 octahedra. In the fourth Zn site, Zn(4) is bonded to one O(13), one O(18), one O(19), and one O(7) atom to form ZnO4 tetrahedra that share  a cornercorner with one Mo(3)O6 octahedra,  a cornercorner with one Mo(5)O6 octahedra,  a cornercorner with one Mo(9)O6 octahedra, corners with two equivalent Mo(10)O6 octahedra, corners with two equivalent Mo(11)O6 octahedra, corners with two equivalent Mo(8)O6 octahedra, and corners with three equivalent Mo(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-59°. In the fifth Zn site, Zn(5) is bonded to one O(1), one O(21), one O(22), one O(24), one O(3), and one O(4) atom to form ZnO6 octahedra that share corners with three equivalent Mo(12)O4 tetrahedra, corners with three equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Mo(1)O6 octahedra,  an edgeedge with one Mo(10)O6 octahedra,  an edgeedge with one Mo(11)O6 octahedra,  an edgeedge with one Mo(2)O6 octahedra,  an edgeedge with one Mo(4)O6 octahedra, and  an edgeedge with one Mo(8)O6 octahedra. In the sixth Zn site, Zn(6) is bonded to one O(14), one O(15), one O(20), and one O(23) atom to form ZnO4 tetrahedra that share  a cornercorner with one Mo(10)O6 octahedra,  a cornercorner with one Mo(11)O6 octahedra,  a cornercorner with one Mo(8)O6 octahedra, corners with two equivalent Mo(3)O6 octahedra, corners with two equivalent Mo(5)O6 octahedra, corners with two equivalent Mo(9)O6 octahedra, and corners with three equivalent Mo(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-61°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Mo(2), one Mo(4), one Zn(1), and one Zn(5) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(2), one Mo(4), and one Zn(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(4), one Zn(1), and one Zn(5) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(2), one Zn(1), and one Zn(5) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Mo(5), one Mo(9), one Zn(2), and one Zn(3) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(2), one Mo(7), and one Zn(3) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Mo(3), one Mo(5), one Mo(9), and one Zn(4) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(4), one Mo(7), and one Zn(3) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(12), one Mo(2), and one Mo(4) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Mo(3), one Mo(9), one Zn(2), and one Zn(3) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Mo(3), one Mo(5), one Zn(2), and one Zn(3) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Mo(2), one Mo(4), one Mo(7), and one Zn(3) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(11), one Mo(6), and one Zn(4) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Mo(3), one Mo(5), one Mo(6), and one Zn(6) atom. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one Mo(3), one Mo(6), one Mo(9), and one Zn(6) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(11), one Mo(8), and one Zn(1) atom. In the seventeenth O site, O(17) is bonded in a rectangular see-saw-like geometry to one Mo(3), one Mo(5), one Mo(7), and one Mo(9) atom. In the eighteenth O site, O(18) is bonded in a rectangular see-saw-like geometry to one Mo(11), one Mo(6), one Mo(8), and one Zn(4) atom. In the nineteenth O site, O(19) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(6), one Mo(8), and one Zn(4) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Mo(5), one Mo(6), one Mo(9), and one Zn(6) atom. In the twenty-first O site, O(21) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(12), one Mo(8), and one Zn(5) atom. In the twenty-second O site, O(22) is bonded in a rectangular see-saw-like geometry to one Mo(11), one Mo(12), one Mo(8), and one Zn(5) atom. In the twenty-third O site, O(23) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(11), one Mo(8), and one Zn(6) atom. In the twenty-fourth O site, O(24) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(11), one Mo(12), and one Zn(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn(MoO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.451
_cell_length_b   6.451
_cell_length_c   18.603
_cell_angle_alpha   59.999
_cell_angle_beta   60.451
_cell_angle_gamma   58.591
_symmetry_Int_Tables_number   1
_cell_volume   543.092
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.124  0.120  0.046  1.0
  Zn  Zn1  1  0.112  0.118  0.380  1.0
  Zn  Zn2  1  0.497  0.497  0.336  1.0
  Zn  Zn3  1  0.126  0.129  0.708  1.0
  Zn  Zn4  1  0.501  0.499  0.004  1.0
  Zn  Zn5  1  0.873  0.880  0.622  1.0
  Mo  Mo6  1  0.501  0.493  0.168  1.0
  Mo  Mo7  1  0.504  0.002  0.165  1.0
  Mo  Mo8  1  0.487  0.498  0.499  1.0
  Mo  Mo9  1  0.006  0.496  0.166  1.0
  Mo  Mo10  1  0.490  0.006  0.498  1.0
  Mo  Mo11  1  0.499  0.505  0.666  1.0
  Mo  Mo12  1  0.887  0.867  0.288  1.0
  Mo  Mo13  1  0.507  0.503  0.835  1.0
  Mo  Mo14  1  0.995  0.501  0.498  1.0
  Mo  Mo15  1  0.507  0.003  0.834  1.0
  Mo  Mo16  1  0.005  0.503  0.834  1.0
  Mo  Mo17  1  0.886  0.874  0.956  1.0
  O  O18  1  0.265  0.265  0.081  1.0
  O  O19  1  0.265  0.257  0.243  1.0
  O  O20  1  0.247  0.726  0.089  1.0
  O  O21  1  0.732  0.245  0.088  1.0
  O  O22  1  0.250  0.266  0.414  1.0
  O  O23  1  0.283  0.762  0.241  1.0
  O  O24  1  0.254  0.261  0.575  1.0
  O  O25  1  0.768  0.270  0.243  1.0
  O  O26  1  0.731  0.729  0.092  1.0
  O  O27  1  0.236  0.727  0.420  1.0
  O  O28  1  0.719  0.246  0.421  1.0
  O  O29  1  0.730  0.725  0.254  1.0
  O  O30  1  0.264  0.265  0.750  1.0
  O  O31  1  0.267  0.752  0.579  1.0
  O  O32  1  0.743  0.275  0.580  1.0
  O  O33  1  0.270  0.264  0.910  1.0
  O  O34  1  0.718  0.734  0.425  1.0
  O  O35  1  0.252  0.732  0.755  1.0
  O  O36  1  0.731  0.254  0.755  1.0
  O  O37  1  0.733  0.741  0.583  1.0
  O  O38  1  0.284  0.767  0.909  1.0
  O  O39  1  0.773  0.275  0.910  1.0
  O  O40  1  0.742  0.742  0.758  1.0
  O  O41  1  0.734  0.728  0.922  1.0
[/CIF]
.
The material structure described by Zn(MoO2)2 is Spinel-like structured and crystallizes in the triclinic P1 space group. There are twelve inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(2), one O(3), one O(4), one O(6), one O(8), and one O(9) atom to form MoO6 octahedra that share  a cornercorner with one Mo(12)O4 tetrahedra,  a cornercorner with one Zn(2)O4 tetrahedra, corners with two equivalent Mo(7)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, edges with two equivalent Mo(2)O6 octahedra, and edges with two equivalent Mo(4)O6 octahedra. In the second Mo site, Mo(2) is bonded to one O(1), one O(12), one O(2), one O(4), one O(6), and one O(9) atom to form MoO6 octahedra that share  a cornercorner with one Mo(12)O4 tetrahedra,  a cornercorner with one Zn(2)O4 tetrahedra, corners with two equivalent Mo(7)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, edges with two equivalent Mo(1)O6 octahedra, and edges with two equivalent Mo(4)O6 octahedra. In the third Mo site, Mo(3) is bonded to one O(10), one O(11), one O(14), one O(15), one O(17), and one O(7) atom to form MoO6 octahedra that share  a cornercorner with one Mo(7)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(6)O4 tetrahedra,  an edgeedge with one Mo(6)O6 octahedra,  an edgeedge with one Zn(3)O6 octahedra, edges with two equivalent Mo(5)O6 octahedra, and edges with two equivalent Mo(9)O6 octahedra. In the fourth Mo site, Mo(4) is bonded to one O(1), one O(12), one O(2), one O(3), one O(8), and one O(9) atom to form MoO6 octahedra that share  a cornercorner with one Mo(12)O4 tetrahedra,  a cornercorner with one Zn(2)O4 tetrahedra, corners with two equivalent Mo(7)O4 tetrahedra, corners with two equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, edges with two equivalent Mo(1)O6 octahedra, and edges with two equivalent Mo(2)O6 octahedra. In the fifth Mo site, Mo(5) is bonded to one O(11), one O(14), one O(17), one O(20), one O(5), and one O(7) atom to form MoO6 octahedra that share  a cornercorner with one Mo(7)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(6)O4 tetrahedra,  an edgeedge with one Mo(6)O6 octahedra,  an edgeedge with one Zn(3)O6 octahedra, edges with two equivalent Mo(3)O6 octahedra, and edges with two equivalent Mo(9)O6 octahedra. In the sixth Mo site, Mo(6) is bonded to one O(13), one O(14), one O(15), one O(18), one O(19), and one O(20) atom to form MoO6 octahedra that share corners with three equivalent Zn(4)O4 tetrahedra, corners with three equivalent Zn(6)O4 tetrahedra,  an edgeedge with one Mo(10)O6 octahedra,  an edgeedge with one Mo(11)O6 octahedra,  an edgeedge with one Mo(3)O6 octahedra,  an edgeedge with one Mo(5)O6 octahedra,  an edgeedge with one Mo(8)O6 octahedra, and  an edgeedge with one Mo(9)O6 octahedra. In the seventh Mo site, Mo(7) is bonded to one O(12), one O(17), one O(6), and one O(8) atom to form MoO4 tetrahedra that share  a cornercorner with one Mo(3)O6 octahedra,  a cornercorner with one Mo(5)O6 octahedra,  a cornercorner with one Mo(9)O6 octahedra, corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Mo(2)O6 octahedra, corners with two equivalent Mo(4)O6 octahedra, and corners with three equivalent Zn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-66°. In the eighth Mo site, Mo(8) is bonded to one O(16), one O(18), one O(19), one O(21), one O(22), and one O(23) atom to form MoO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra, corners with two equivalent Mo(12)O4 tetrahedra, corners with two equivalent Zn(4)O4 tetrahedra,  an edgeedge with one Mo(6)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, edges with two equivalent Mo(10)O6 octahedra, and edges with two equivalent Mo(11)O6 octahedra. In the ninth Mo site, Mo(9) is bonded to one O(10), one O(15), one O(17), one O(20), one O(5), and one O(7) atom to form MoO6 octahedra that share  a cornercorner with one Mo(7)O4 tetrahedra,  a cornercorner with one Zn(4)O4 tetrahedra, corners with two equivalent Zn(2)O4 tetrahedra, corners with two equivalent Zn(6)O4 tetrahedra,  an edgeedge with one Mo(6)O6 octahedra,  an edgeedge with one Zn(3)O6 octahedra, edges with two equivalent Mo(3)O6 octahedra, and edges with two equivalent Mo(5)O6 octahedra. In the tenth Mo site, Mo(10) is bonded to one O(13), one O(16), one O(19), one O(21), one O(23), and one O(24) atom to form MoO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra, corners with two equivalent Mo(12)O4 tetrahedra, corners with two equivalent Zn(4)O4 tetrahedra,  an edgeedge with one Mo(6)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, edges with two equivalent Mo(11)O6 octahedra, and edges with two equivalent Mo(8)O6 octahedra. In the eleventh Mo site, Mo(11) is bonded to one O(13), one O(16), one O(18), one O(22), one O(23), and one O(24) atom to form MoO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra, corners with two equivalent Mo(12)O4 tetrahedra, corners with two equivalent Zn(4)O4 tetrahedra,  an edgeedge with one Mo(6)O6 octahedra,  an edgeedge with one Zn(5)O6 octahedra, edges with two equivalent Mo(10)O6 octahedra, and edges with two equivalent Mo(8)O6 octahedra. In the twelfth Mo site, Mo(12) is bonded to one O(21), one O(22), one O(24), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one Mo(1)O6 octahedra,  a cornercorner with one Mo(2)O6 octahedra,  a cornercorner with one Mo(4)O6 octahedra, corners with two equivalent Mo(10)O6 octahedra, corners with two equivalent Mo(11)O6 octahedra, corners with two equivalent Mo(8)O6 octahedra, and corners with three equivalent Zn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 50-64°. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(16), one O(3), and one O(4) atom to form ZnO4 tetrahedra that share  a cornercorner with one Mo(10)O6 octahedra,  a cornercorner with one Mo(11)O6 octahedra,  a cornercorner with one Mo(8)O6 octahedra, corners with two equivalent Mo(1)O6 octahedra, corners with two equivalent Mo(2)O6 octahedra, corners with two equivalent Mo(4)O6 octahedra, and corners with three equivalent Zn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-61°. In the second Zn site, Zn(2) is bonded to one O(10), one O(11), one O(2), and one O(5) atom to form ZnO4 tetrahedra that share  a cornercorner with one Mo(1)O6 octahedra,  a cornercorner with one Mo(2)O6 octahedra,  a cornercorner with one Mo(4)O6 octahedra, corners with two equivalent Mo(3)O6 octahedra, corners with two equivalent Mo(5)O6 octahedra, corners with two equivalent Mo(9)O6 octahedra, and corners with three equivalent Zn(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-61°. In the third Zn site, Zn(3) is bonded to one O(10), one O(11), one O(12), one O(5), one O(6), and one O(8) atom to form ZnO6 octahedra that share corners with three equivalent Mo(7)O4 tetrahedra, corners with three equivalent Zn(2)O4 tetrahedra,  an edgeedge with one Mo(1)O6 octahedra,  an edgeedge with one Mo(2)O6 octahedra,  an edgeedge with one Mo(3)O6 octahedra,  an edgeedge with one Mo(4)O6 octahedra,  an edgeedge with one Mo(5)O6 octahedra, and  an edgeedge with one Mo(9)O6 octahedra. In the fourth Zn site, Zn(4) is bonded to one O(13), one O(18), one O(19), and one O(7) atom to form ZnO4 tetrahedra that share  a cornercorner with one Mo(3)O6 octahedra,  a cornercorner with one Mo(5)O6 octahedra,  a cornercorner with one Mo(9)O6 octahedra, corners with two equivalent Mo(10)O6 octahedra, corners with two equivalent Mo(11)O6 octahedra, corners with two equivalent Mo(8)O6 octahedra, and corners with three equivalent Mo(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-59°. In the fifth Zn site, Zn(5) is bonded to one O(1), one O(21), one O(22), one O(24), one O(3), and one O(4) atom to form ZnO6 octahedra that share corners with three equivalent Mo(12)O4 tetrahedra, corners with three equivalent Zn(1)O4 tetrahedra,  an edgeedge with one Mo(1)O6 octahedra,  an edgeedge with one Mo(10)O6 octahedra,  an edgeedge with one Mo(11)O6 octahedra,  an edgeedge with one Mo(2)O6 octahedra,  an edgeedge with one Mo(4)O6 octahedra, and  an edgeedge with one Mo(8)O6 octahedra. In the sixth Zn site, Zn(6) is bonded to one O(14), one O(15), one O(20), and one O(23) atom to form ZnO4 tetrahedra that share  a cornercorner with one Mo(10)O6 octahedra,  a cornercorner with one Mo(11)O6 octahedra,  a cornercorner with one Mo(8)O6 octahedra, corners with two equivalent Mo(3)O6 octahedra, corners with two equivalent Mo(5)O6 octahedra, corners with two equivalent Mo(9)O6 octahedra, and corners with three equivalent Mo(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-61°. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Mo(2), one Mo(4), one Zn(1), and one Zn(5) atom. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(2), one Mo(4), and one Zn(2) atom. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(4), one Zn(1), and one Zn(5) atom. In the fourth O site, O(4) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(2), one Zn(1), and one Zn(5) atom. In the fifth O site, O(5) is bonded in a rectangular see-saw-like geometry to one Mo(5), one Mo(9), one Zn(2), and one Zn(3) atom. In the sixth O site, O(6) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(2), one Mo(7), and one Zn(3) atom. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Mo(3), one Mo(5), one Mo(9), and one Zn(4) atom. In the eighth O site, O(8) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(4), one Mo(7), and one Zn(3) atom. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Mo(12), one Mo(2), and one Mo(4) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Mo(3), one Mo(9), one Zn(2), and one Zn(3) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Mo(3), one Mo(5), one Zn(2), and one Zn(3) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Mo(2), one Mo(4), one Mo(7), and one Zn(3) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(11), one Mo(6), and one Zn(4) atom. In the fourteenth O site, O(14) is bonded in a rectangular see-saw-like geometry to one Mo(3), one Mo(5), one Mo(6), and one Zn(6) atom. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one Mo(3), one Mo(6), one Mo(9), and one Zn(6) atom. In the sixteenth O site, O(16) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(11), one Mo(8), and one Zn(1) atom. In the seventeenth O site, O(17) is bonded in a rectangular see-saw-like geometry to one Mo(3), one Mo(5), one Mo(7), and one Mo(9) atom. In the eighteenth O site, O(18) is bonded in a rectangular see-saw-like geometry to one Mo(11), one Mo(6), one Mo(8), and one Zn(4) atom. In the nineteenth O site, O(19) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(6), one Mo(8), and one Zn(4) atom. In the twentieth O site, O(20) is bonded in a rectangular see-saw-like geometry to one Mo(5), one Mo(6), one Mo(9), and one Zn(6) atom. In the twenty-first O site, O(21) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(12), one Mo(8), and one Zn(5) atom. In the twenty-second O site, O(22) is bonded in a rectangular see-saw-like geometry to one Mo(11), one Mo(12), one Mo(8), and one Zn(5) atom. In the twenty-third O site, O(23) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(11), one Mo(8), and one Zn(6) atom. In the twenty-fourth O site, O(24) is bonded in a rectangular see-saw-like geometry to one Mo(10), one Mo(11), one Mo(12), and one Zn(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn(MoO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.451
_cell_length_b   6.451
_cell_length_c   18.603
_cell_angle_alpha   59.999
_cell_angle_beta   60.451
_cell_angle_gamma   58.591
_symmetry_Int_Tables_number   1
_cell_volume   543.092
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.124  0.120  0.046  1.0
  Zn  Zn1  1  0.112  0.118  0.380  1.0
  Zn  Zn2  1  0.497  0.497  0.336  1.0
  Zn  Zn3  1  0.126  0.129  0.708  1.0
  Zn  Zn4  1  0.501  0.499  0.004  1.0
  Zn  Zn5  1  0.873  0.880  0.622  1.0
  Mo  Mo6  1  0.501  0.493  0.168  1.0
  Mo  Mo7  1  0.504  0.002  0.165  1.0
  Mo  Mo8  1  0.487  0.498  0.499  1.0
  Mo  Mo9  1  0.006  0.496  0.166  1.0
  Mo  Mo10  1  0.490  0.006  0.498  1.0
  Mo  Mo11  1  0.499  0.505  0.666  1.0
  Mo  Mo12  1  0.887  0.867  0.288  1.0
  Mo  Mo13  1  0.507  0.503  0.835  1.0
  Mo  Mo14  1  0.995  0.501  0.498  1.0
  Mo  Mo15  1  0.507  0.003  0.834  1.0
  Mo  Mo16  1  0.005  0.503  0.834  1.0
  Mo  Mo17  1  0.886  0.874  0.956  1.0
  O  O18  1  0.265  0.265  0.081  1.0
  O  O19  1  0.265  0.257  0.243  1.0
  O  O20  1  0.247  0.726  0.089  1.0
  O  O21  1  0.732  0.245  0.088  1.0
  O  O22  1  0.250  0.266  0.414  1.0
  O  O23  1  0.283  0.762  0.241  1.0
  O  O24  1  0.254  0.261  0.575  1.0
  O  O25  1  0.768  0.270  0.243  1.0
  O  O26  1  0.731  0.729  0.092  1.0
  O  O27  1  0.236  0.727  0.420  1.0
  O  O28  1  0.719  0.246  0.421  1.0
  O  O29  1  0.730  0.725  0.254  1.0
  O  O30  1  0.264  0.265  0.750  1.0
  O  O31  1  0.267  0.752  0.579  1.0
  O  O32  1  0.743  0.275  0.580  1.0
  O  O33  1  0.270  0.264  0.910  1.0
  O  O34  1  0.718  0.734  0.425  1.0
  O  O35  1  0.252  0.732  0.755  1.0
  O  O36  1  0.731  0.254  0.755  1.0
  O  O37  1  0.733  0.741  0.583  1.0
  O  O38  1  0.284  0.767  0.909  1.0
  O  O39  1  0.773  0.275  0.910  1.0
  O  O40  1  0.742  0.742  0.758  1.0
  O  O41  1  0.734  0.728  0.922  1.0
[/CIF]
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