The structure described by XeF5AgF4 is Indium-derived structured and crystallizes in the tetragonal I4/m space group. The structure is zero-dimensional and consists of four AgF4 clusters and four XeF5 clusters. In each AgF4 cluster, Ag(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. F(1) is bonded in a single-bond geometry to one Ag(1) atom. In each XeF5 cluster, Xe(1) is bonded in a distorted square pyramidal geometry to one F(2) and four equivalent F(3) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the CIF file [CIF]
data_AgXeF9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.235
_cell_length_b   11.235
_cell_length_c   11.235
_cell_angle_alpha   150.162
_cell_angle_beta   150.162
_cell_angle_gamma   42.704
_symmetry_Int_Tables_number   1
_cell_volume   350.171
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.000  0.500  1.0
  Ag  Ag1  1  0.000  0.500  0.500  1.0
  Xe  Xe2  1  0.848  0.848  0.000  1.0
  Xe  Xe3  1  0.152  0.152  0.000  1.0
  F  F4  1  0.915  0.365  0.152  1.0
  F  F5  1  0.365  0.213  0.450  1.0
  F  F6  1  0.246  0.246  0.000  1.0
  F  F7  1  0.754  0.754  0.000  1.0
  F  F8  1  0.866  0.313  0.838  1.0
  F  F9  1  0.313  0.475  0.447  1.0
  F  F10  1  0.028  0.866  0.553  1.0
  F  F11  1  0.475  0.028  0.162  1.0
  F  F12  1  0.134  0.687  0.162  1.0
  F  F13  1  0.687  0.525  0.553  1.0
  F  F14  1  0.972  0.134  0.447  1.0
  F  F15  1  0.525  0.972  0.838  1.0
  F  F16  1  0.763  0.915  0.550  1.0
  F  F17  1  0.213  0.763  0.848  1.0
  F  F18  1  0.787  0.237  0.152  1.0
  F  F19  1  0.237  0.085  0.450  1.0
  F  F20  1  0.635  0.787  0.550  1.0
  F  F21  1  0.085  0.635  0.848  1.0
[/CIF]
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The structure described by XeF5AgF4 is Indium-derived structured and crystallizes in the tetragonal I4/m space group. The structure is zero-dimensional and consists of four AgF4 clusters and four XeF5 clusters. In each AgF4 cluster, Ag(1) is bonded in a square co-planar geometry to four equivalent F(1) atoms. F(1) is bonded in a single-bond geometry to one Ag(1) atom. In each XeF5 cluster, Xe(1) is bonded in a distorted square pyramidal geometry to one F(2) and four equivalent F(3) atoms. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the CIF file [CIF]
data_AgXeF9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.235
_cell_length_b   11.235
_cell_length_c   11.235
_cell_angle_alpha   150.162
_cell_angle_beta   150.162
_cell_angle_gamma   42.704
_symmetry_Int_Tables_number   1
_cell_volume   350.171
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.000  0.500  1.0
  Ag  Ag1  1  0.000  0.500  0.500  1.0
  Xe  Xe2  1  0.848  0.848  0.000  1.0
  Xe  Xe3  1  0.152  0.152  0.000  1.0
  F  F4  1  0.915  0.365  0.152  1.0
  F  F5  1  0.365  0.213  0.450  1.0
  F  F6  1  0.246  0.246  0.000  1.0
  F  F7  1  0.754  0.754  0.000  1.0
  F  F8  1  0.866  0.313  0.838  1.0
  F  F9  1  0.313  0.475  0.447  1.0
  F  F10  1  0.028  0.866  0.553  1.0
  F  F11  1  0.475  0.028  0.162  1.0
  F  F12  1  0.134  0.687  0.162  1.0
  F  F13  1  0.687  0.525  0.553  1.0
  F  F14  1  0.972  0.134  0.447  1.0
  F  F15  1  0.525  0.972  0.838  1.0
  F  F16  1  0.763  0.915  0.550  1.0
  F  F17  1  0.213  0.763  0.848  1.0
  F  F18  1  0.787  0.237  0.152  1.0
  F  F19  1  0.237  0.085  0.450  1.0
  F  F20  1  0.635  0.787  0.550  1.0
  F  F21  1  0.085  0.635  0.848  1.0
[/CIF]
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