The material described by InSbO4 is Hydrophilite-derived structured and crystallizes in the monoclinic P2_1/c space group. In(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form distorted InO6 octahedra that share corners with four equivalent In(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-62°. Sb(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with four equivalent In(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and edges with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-62°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent In(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent In(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one In(1) and two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one In(1) and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_InSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.245
_cell_length_b   7.433
_cell_length_c   7.522
_cell_angle_alpha   79.157
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   288.006
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.258  0.641  0.158  1.0
  In  In1  1  0.742  0.359  0.842  1.0
  In  In2  1  0.758  0.859  0.842  1.0
  In  In3  1  0.242  0.141  0.158  1.0
  Sb  Sb4  1  0.753  0.814  0.331  1.0
  Sb  Sb5  1  0.247  0.186  0.669  1.0
  Sb  Sb6  1  0.253  0.686  0.669  1.0
  Sb  Sb7  1  0.747  0.314  0.331  1.0
  O  O8  1  0.446  0.896  0.193  1.0
  O  O9  1  0.554  0.104  0.807  1.0
  O  O10  1  0.946  0.604  0.807  1.0
  O  O11  1  0.054  0.396  0.193  1.0
  O  O12  1  0.931  0.814  0.101  1.0
  O  O13  1  0.069  0.186  0.899  1.0
  O  O14  1  0.431  0.686  0.899  1.0
  O  O15  1  0.569  0.314  0.101  1.0
  O  O16  1  0.605  0.563  0.323  1.0
  O  O17  1  0.395  0.437  0.677  1.0
  O  O18  1  0.105  0.937  0.677  1.0
  O  O19  1  0.895  0.063  0.323  1.0
  O  O20  1  0.578  0.806  0.567  1.0
  O  O21  1  0.422  0.194  0.433  1.0
  O  O22  1  0.078  0.694  0.433  1.0
  O  O23  1  0.922  0.306  0.567  1.0
[/CIF]
.
The material described by InSbO4 is Hydrophilite-derived structured and crystallizes in the monoclinic P2_1/c space group. In(1) is bonded to one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms to form distorted InO6 octahedra that share corners with four equivalent In(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-62°. Sb(1) is bonded to one O(1), one O(2), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with four equivalent In(1)O6 octahedra, corners with four equivalent Sb(1)O6 octahedra, and edges with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-62°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to two equivalent In(1) and one Sb(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to two equivalent In(1) and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one In(1) and two equivalent Sb(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one In(1) and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_InSbO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.245
_cell_length_b   7.433
_cell_length_c   7.522
_cell_angle_alpha   79.157
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   288.006
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.258  0.641  0.158  1.0
  In  In1  1  0.742  0.359  0.842  1.0
  In  In2  1  0.758  0.859  0.842  1.0
  In  In3  1  0.242  0.141  0.158  1.0
  Sb  Sb4  1  0.753  0.814  0.331  1.0
  Sb  Sb5  1  0.247  0.186  0.669  1.0
  Sb  Sb6  1  0.253  0.686  0.669  1.0
  Sb  Sb7  1  0.747  0.314  0.331  1.0
  O  O8  1  0.446  0.896  0.193  1.0
  O  O9  1  0.554  0.104  0.807  1.0
  O  O10  1  0.946  0.604  0.807  1.0
  O  O11  1  0.054  0.396  0.193  1.0
  O  O12  1  0.931  0.814  0.101  1.0
  O  O13  1  0.069  0.186  0.899  1.0
  O  O14  1  0.431  0.686  0.899  1.0
  O  O15  1  0.569  0.314  0.101  1.0
  O  O16  1  0.605  0.563  0.323  1.0
  O  O17  1  0.395  0.437  0.677  1.0
  O  O18  1  0.105  0.937  0.677  1.0
  O  O19  1  0.895  0.063  0.323  1.0
  O  O20  1  0.578  0.806  0.567  1.0
  O  O21  1  0.422  0.194  0.433  1.0
  O  O22  1  0.078  0.694  0.433  1.0
  O  O23  1  0.922  0.306  0.567  1.0
[/CIF]
.