The crystal structure described by VF5 is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four mfcd00137321 molecules. V(1) is bonded in a 5-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.996
_cell_length_b   4.996
_cell_length_c   8.466
_cell_angle_alpha   64.737
_cell_angle_beta   64.737
_cell_angle_gamma   72.443
_symmetry_Int_Tables_number   1
_cell_volume   171.007
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.013  0.984  0.040  1.0
  V  V1  1  0.984  0.013  0.540  1.0
  F  F2  1  0.217  0.672  0.977  1.0
  F  F3  1  0.302  0.178  0.861  1.0
  F  F4  1  0.818  0.695  0.623  1.0
  F  F5  1  0.926  0.071  0.738  1.0
  F  F6  1  0.672  0.217  0.477  1.0
  F  F7  1  0.326  0.779  0.505  1.0
  F  F8  1  0.071  0.926  0.238  1.0
  F  F9  1  0.178  0.302  0.361  1.0
  F  F10  1  0.695  0.818  0.123  1.0
  F  F11  1  0.779  0.326  0.005  1.0
[/CIF]
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The crystal structure described by VF5 is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four mfcd00137321 molecules. V(1) is bonded in a 5-coordinate geometry to one F(1), one F(2), one F(3), one F(4), and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one V(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one V(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.996
_cell_length_b   4.996
_cell_length_c   8.466
_cell_angle_alpha   64.737
_cell_angle_beta   64.737
_cell_angle_gamma   72.443
_symmetry_Int_Tables_number   1
_cell_volume   171.007
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.013  0.984  0.040  1.0
  V  V1  1  0.984  0.013  0.540  1.0
  F  F2  1  0.217  0.672  0.977  1.0
  F  F3  1  0.302  0.178  0.861  1.0
  F  F4  1  0.818  0.695  0.623  1.0
  F  F5  1  0.926  0.071  0.738  1.0
  F  F6  1  0.672  0.217  0.477  1.0
  F  F7  1  0.326  0.779  0.505  1.0
  F  F8  1  0.071  0.926  0.238  1.0
  F  F9  1  0.178  0.302  0.361  1.0
  F  F10  1  0.695  0.818  0.123  1.0
  F  F11  1  0.779  0.326  0.005  1.0
[/CIF]
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