The material structure described by LiEu2CN2I3 crystallizes in the cubic Fd-3m space group. Li(1) is bonded to six equivalent I(1) atoms to form corner-sharing LiI6 octahedra. The corner-sharing octahedral tilt angles are 46°. Eu(1) is bonded in a 3-coordinate geometry to three equivalent N(1) and six equivalent I(1) atoms. C(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded to three equivalent Eu(1) and one C(1) atom to form a mixture of distorted corner and edge-sharing NEu3C tetrahedra. I(1) is bonded in a 6-coordinate geometry to two equivalent Li(1) and four equivalent Eu(1) atoms. is represented by the CIF file [CIF]
data_LiEu2CI3N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.800
_cell_length_b   10.800
_cell_length_c   10.800
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   890.865
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.625  0.125  0.125  1.0
  Li  Li1  1  0.125  0.625  0.125  1.0
  Li  Li2  1  0.125  0.125  0.625  1.0
  Li  Li3  1  0.125  0.125  0.125  1.0
  Eu  Eu4  1  0.775  0.408  0.408  1.0
  Eu  Eu5  1  0.408  0.775  0.408  1.0
  Eu  Eu6  1  0.408  0.408  0.775  1.0
  Eu  Eu7  1  0.408  0.408  0.408  1.0
  Eu  Eu8  1  0.475  0.842  0.842  1.0
  Eu  Eu9  1  0.842  0.475  0.842  1.0
  Eu  Eu10  1  0.842  0.842  0.475  1.0
  Eu  Eu11  1  0.842  0.842  0.842  1.0
  C  C12  1  0.125  0.625  0.625  1.0
  C  C13  1  0.625  0.125  0.625  1.0
  C  C14  1  0.625  0.625  0.125  1.0
  C  C15  1  0.625  0.625  0.625  1.0
  I  I16  1  0.800  0.800  0.200  1.0
  I  I17  1  0.200  0.200  0.800  1.0
  I  I18  1  0.800  0.200  0.800  1.0
  I  I19  1  0.200  0.800  0.200  1.0
  I  I20  1  0.200  0.800  0.800  1.0
  I  I21  1  0.800  0.200  0.200  1.0
  I  I22  1  0.450  0.450  0.050  1.0
  I  I23  1  0.050  0.050  0.450  1.0
  I  I24  1  0.450  0.050  0.450  1.0
  I  I25  1  0.050  0.450  0.050  1.0
  I  I26  1  0.050  0.450  0.450  1.0
  I  I27  1  0.450  0.050  0.050  1.0
  N  N28  1  0.266  0.578  0.578  1.0
  N  N29  1  0.578  0.266  0.578  1.0
  N  N30  1  0.578  0.578  0.266  1.0
  N  N31  1  0.578  0.578  0.578  1.0
  N  N32  1  0.984  0.672  0.672  1.0
  N  N33  1  0.672  0.984  0.672  1.0
  N  N34  1  0.672  0.672  0.984  1.0
  N  N35  1  0.672  0.672  0.672  1.0
[/CIF]
.
The material structure described by LiEu2CN2I3 crystallizes in the cubic Fd-3m space group. Li(1) is bonded to six equivalent I(1) atoms to form corner-sharing LiI6 octahedra. The corner-sharing octahedral tilt angles are 46°. Eu(1) is bonded in a 3-coordinate geometry to three equivalent N(1) and six equivalent I(1) atoms. C(1) is bonded in a linear geometry to two equivalent N(1) atoms. N(1) is bonded to three equivalent Eu(1) and one C(1) atom to form a mixture of distorted corner and edge-sharing NEu3C tetrahedra. I(1) is bonded in a 6-coordinate geometry to two equivalent Li(1) and four equivalent Eu(1) atoms. is represented by the CIF file [CIF]
data_LiEu2CI3N2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.800
_cell_length_b   10.800
_cell_length_c   10.800
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   890.865
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.625  0.125  0.125  1.0
  Li  Li1  1  0.125  0.625  0.125  1.0
  Li  Li2  1  0.125  0.125  0.625  1.0
  Li  Li3  1  0.125  0.125  0.125  1.0
  Eu  Eu4  1  0.775  0.408  0.408  1.0
  Eu  Eu5  1  0.408  0.775  0.408  1.0
  Eu  Eu6  1  0.408  0.408  0.775  1.0
  Eu  Eu7  1  0.408  0.408  0.408  1.0
  Eu  Eu8  1  0.475  0.842  0.842  1.0
  Eu  Eu9  1  0.842  0.475  0.842  1.0
  Eu  Eu10  1  0.842  0.842  0.475  1.0
  Eu  Eu11  1  0.842  0.842  0.842  1.0
  C  C12  1  0.125  0.625  0.625  1.0
  C  C13  1  0.625  0.125  0.625  1.0
  C  C14  1  0.625  0.625  0.125  1.0
  C  C15  1  0.625  0.625  0.625  1.0
  I  I16  1  0.800  0.800  0.200  1.0
  I  I17  1  0.200  0.200  0.800  1.0
  I  I18  1  0.800  0.200  0.800  1.0
  I  I19  1  0.200  0.800  0.200  1.0
  I  I20  1  0.200  0.800  0.800  1.0
  I  I21  1  0.800  0.200  0.200  1.0
  I  I22  1  0.450  0.450  0.050  1.0
  I  I23  1  0.050  0.050  0.450  1.0
  I  I24  1  0.450  0.050  0.450  1.0
  I  I25  1  0.050  0.450  0.050  1.0
  I  I26  1  0.050  0.450  0.450  1.0
  I  I27  1  0.450  0.050  0.050  1.0
  N  N28  1  0.266  0.578  0.578  1.0
  N  N29  1  0.578  0.266  0.578  1.0
  N  N30  1  0.578  0.578  0.266  1.0
  N  N31  1  0.578  0.578  0.578  1.0
  N  N32  1  0.984  0.672  0.672  1.0
  N  N33  1  0.672  0.984  0.672  1.0
  N  N34  1  0.672  0.672  0.984  1.0
  N  N35  1  0.672  0.672  0.672  1.0
[/CIF]
.