The structure described by RbClO4 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 12-coordinate geometry to six equivalent O(1) and six equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. is represented by the CIF file [CIF]
data_RbClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.309
_cell_length_b   5.309
_cell_length_c   7.309
_cell_angle_alpha   89.696
_cell_angle_beta   89.696
_cell_angle_gamma   90.038
_symmetry_Int_Tables_number   1
_cell_volume   205.977
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.751  0.249  0.250  1.0
  Rb  Rb1  1  0.249  0.751  0.750  1.0
  Cl  Cl2  1  0.749  0.251  0.750  1.0
  Cl  Cl3  1  0.251  0.749  0.250  1.0
  O  O4  1  0.527  0.250  0.865  1.0
  O  O5  1  0.972  0.250  0.863  1.0
  O  O6  1  0.750  0.028  0.637  1.0
  O  O7  1  0.750  0.473  0.635  1.0
  O  O8  1  0.250  0.527  0.365  1.0
  O  O9  1  0.028  0.750  0.137  1.0
  O  O10  1  0.473  0.750  0.135  1.0
  O  O11  1  0.250  0.972  0.363  1.0
[/CIF]
.
The structure described by RbClO4 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 12-coordinate geometry to six equivalent O(1) and six equivalent O(2) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to three equivalent Rb(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(2) atoms. is represented by the CIF file [CIF]
data_RbClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.309
_cell_length_b   5.309
_cell_length_c   7.309
_cell_angle_alpha   89.696
_cell_angle_beta   89.696
_cell_angle_gamma   90.038
_symmetry_Int_Tables_number   1
_cell_volume   205.977
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.751  0.249  0.250  1.0
  Rb  Rb1  1  0.249  0.751  0.750  1.0
  Cl  Cl2  1  0.749  0.251  0.750  1.0
  Cl  Cl3  1  0.251  0.749  0.250  1.0
  O  O4  1  0.527  0.250  0.865  1.0
  O  O5  1  0.972  0.250  0.863  1.0
  O  O6  1  0.750  0.028  0.637  1.0
  O  O7  1  0.750  0.473  0.635  1.0
  O  O8  1  0.250  0.527  0.365  1.0
  O  O9  1  0.028  0.750  0.137  1.0
  O  O10  1  0.473  0.750  0.135  1.0
  O  O11  1  0.250  0.972  0.363  1.0
[/CIF]
.