The crystal structure described by NaSb crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to three equivalent Sb(1) and three equivalent Sb(2) atoms. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to three equivalent Sb(1) and three equivalent Sb(2) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to three equivalent Na(1), three equivalent Na(2), and two equivalent Sb(2) atoms. In the second Sb site, Sb(2) is bonded in a 8-coordinate geometry to three equivalent Na(1), three equivalent Na(2), and two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_NaSb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.342
_cell_length_b   6.785
_cell_length_c   11.140
_cell_angle_alpha   95.549
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   477.145
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.836  0.310  0.542  1.0
  Na  Na1  1  0.336  0.190  0.958  1.0
  Na  Na2  1  0.164  0.690  0.458  1.0
  Na  Na3  1  0.664  0.810  0.042  1.0
  Na  Na4  1  0.097  0.597  0.827  1.0
  Na  Na5  1  0.597  0.903  0.673  1.0
  Na  Na6  1  0.903  0.403  0.173  1.0
  Na  Na7  1  0.403  0.097  0.327  1.0
  Sb  Sb8  1  0.337  0.314  0.605  1.0
  Sb  Sb9  1  0.837  0.186  0.895  1.0
  Sb  Sb10  1  0.663  0.686  0.395  1.0
  Sb  Sb11  1  0.163  0.814  0.105  1.0
  Sb  Sb12  1  0.595  0.490  0.798  1.0
  Sb  Sb13  1  0.095  0.010  0.702  1.0
  Sb  Sb14  1  0.405  0.510  0.202  1.0
  Sb  Sb15  1  0.905  0.990  0.298  1.0
[/CIF]
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The crystal structure described by NaSb crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a 6-coordinate geometry to three equivalent Sb(1) and three equivalent Sb(2) atoms. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to three equivalent Sb(1) and three equivalent Sb(2) atoms. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 8-coordinate geometry to three equivalent Na(1), three equivalent Na(2), and two equivalent Sb(2) atoms. In the second Sb site, Sb(2) is bonded in a 8-coordinate geometry to three equivalent Na(1), three equivalent Na(2), and two equivalent Sb(1) atoms. is represented by the CIF card [CIF]
data_NaSb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.342
_cell_length_b   6.785
_cell_length_c   11.140
_cell_angle_alpha   95.549
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   477.145
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.836  0.310  0.542  1.0
  Na  Na1  1  0.336  0.190  0.958  1.0
  Na  Na2  1  0.164  0.690  0.458  1.0
  Na  Na3  1  0.664  0.810  0.042  1.0
  Na  Na4  1  0.097  0.597  0.827  1.0
  Na  Na5  1  0.597  0.903  0.673  1.0
  Na  Na6  1  0.903  0.403  0.173  1.0
  Na  Na7  1  0.403  0.097  0.327  1.0
  Sb  Sb8  1  0.337  0.314  0.605  1.0
  Sb  Sb9  1  0.837  0.186  0.895  1.0
  Sb  Sb10  1  0.663  0.686  0.395  1.0
  Sb  Sb11  1  0.163  0.814  0.105  1.0
  Sb  Sb12  1  0.595  0.490  0.798  1.0
  Sb  Sb13  1  0.095  0.010  0.702  1.0
  Sb  Sb14  1  0.405  0.510  0.202  1.0
  Sb  Sb15  1  0.905  0.990  0.298  1.0
[/CIF]
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