The compound described by NS is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of twelve NS clusters. In two of the NS clusters, there are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(6) atom. In the second N site, N(6) is bonded in a single-bond geometry to one S(7) atom. In the third N site, N(7) is bonded in a bent 120 degrees geometry to one S(6) and one S(7) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(1) atom. In the second S site, S(6) is bonded in a water-like geometry to one N(1) and one N(7) atom. In the third S site, S(7) is bonded in a bent 120 degrees geometry to one N(6) and one N(7) atom. In two of the NS clusters, there are two inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one S(3) atom. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a single-bond geometry to one N(3) atom. In the second S site, S(3) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In eight of the NS clusters, N(5) is bonded in a single-bond geometry to one S(4) atom. S(4) is bonded in a single-bond geometry to one N(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.884
_cell_length_b   7.076
_cell_length_c   29.224
_cell_angle_alpha   90.000
_cell_angle_beta   88.251
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   802.715
_cell_formula_units_Z   18
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.934  0.500  0.964  1.0
  S  S1  1  0.607  0.878  0.741  1.0
  S  S2  1  0.892  0.491  0.747  1.0
  S  S3  1  0.425  0.095  0.062  1.0
  S  S4  1  0.633  0.940  0.537  1.0
  S  S5  1  0.867  0.440  0.563  1.0
  S  S6  1  0.086  0.650  0.877  1.0
  S  S7  1  0.326  0.044  0.858  1.0
  S  S8  1  0.608  0.991  0.353  1.0
  S  S9  1  0.893  0.378  0.359  1.0
  S  S10  1  0.163  0.556  0.637  1.0
  S  S11  1  0.434  0.021  0.668  1.0
  S  S12  1  0.566  1.000  0.136  1.0
  S  S13  1  0.066  0.521  0.432  1.0
  S  S14  1  0.337  0.056  0.463  1.0
  S  S15  1  0.174  0.544  0.242  1.0
  S  S16  1  0.414  0.150  0.223  1.0
  S  S17  1  0.075  0.595  0.038  1.0
  N  N18  1  0.135  0.651  0.932  1.0
  N  N19  1  0.581  0.421  0.772  1.0
  N  N20  1  0.914  0.737  0.731  1.0
  N  N21  1  0.571  0.310  0.572  1.0
  N  N22  1  0.376  0.720  0.042  1.0
  N  N23  1  0.929  0.810  0.528  1.0
  N  N24  1  0.083  0.136  0.890  1.0
  N  N25  1  0.586  0.237  0.369  1.0
  N  N26  1  0.331  0.800  0.853  1.0
  N  N27  1  0.919  0.921  0.328  1.0
  N  N28  1  0.121  0.137  0.675  1.0
  N  N29  1  0.365  0.151  0.168  1.0
  N  N30  1  0.459  0.690  0.631  1.0
  N  N31  1  0.041  0.190  0.469  1.0
  N  N32  1  0.379  0.637  0.425  1.0
  N  N33  1  0.169  0.300  0.247  1.0
  N  N34  1  0.417  0.636  0.210  1.0
  N  N35  1  0.124  0.220  0.058  1.0
[/CIF]
.
The compound described by NS is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of twelve NS clusters. In two of the NS clusters, there are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(6) atom. In the second N site, N(6) is bonded in a single-bond geometry to one S(7) atom. In the third N site, N(7) is bonded in a bent 120 degrees geometry to one S(6) and one S(7) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(1) atom. In the second S site, S(6) is bonded in a water-like geometry to one N(1) and one N(7) atom. In the third S site, S(7) is bonded in a bent 120 degrees geometry to one N(6) and one N(7) atom. In two of the NS clusters, there are two inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one S(3) atom. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a single-bond geometry to one N(3) atom. In the second S site, S(3) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In eight of the NS clusters, N(5) is bonded in a single-bond geometry to one S(4) atom. S(4) is bonded in a single-bond geometry to one N(5) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.884
_cell_length_b   7.076
_cell_length_c   29.224
_cell_angle_alpha   90.000
_cell_angle_beta   88.251
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   802.715
_cell_formula_units_Z   18
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.934  0.500  0.964  1.0
  S  S1  1  0.607  0.878  0.741  1.0
  S  S2  1  0.892  0.491  0.747  1.0
  S  S3  1  0.425  0.095  0.062  1.0
  S  S4  1  0.633  0.940  0.537  1.0
  S  S5  1  0.867  0.440  0.563  1.0
  S  S6  1  0.086  0.650  0.877  1.0
  S  S7  1  0.326  0.044  0.858  1.0
  S  S8  1  0.608  0.991  0.353  1.0
  S  S9  1  0.893  0.378  0.359  1.0
  S  S10  1  0.163  0.556  0.637  1.0
  S  S11  1  0.434  0.021  0.668  1.0
  S  S12  1  0.566  1.000  0.136  1.0
  S  S13  1  0.066  0.521  0.432  1.0
  S  S14  1  0.337  0.056  0.463  1.0
  S  S15  1  0.174  0.544  0.242  1.0
  S  S16  1  0.414  0.150  0.223  1.0
  S  S17  1  0.075  0.595  0.038  1.0
  N  N18  1  0.135  0.651  0.932  1.0
  N  N19  1  0.581  0.421  0.772  1.0
  N  N20  1  0.914  0.737  0.731  1.0
  N  N21  1  0.571  0.310  0.572  1.0
  N  N22  1  0.376  0.720  0.042  1.0
  N  N23  1  0.929  0.810  0.528  1.0
  N  N24  1  0.083  0.136  0.890  1.0
  N  N25  1  0.586  0.237  0.369  1.0
  N  N26  1  0.331  0.800  0.853  1.0
  N  N27  1  0.919  0.921  0.328  1.0
  N  N28  1  0.121  0.137  0.675  1.0
  N  N29  1  0.365  0.151  0.168  1.0
  N  N30  1  0.459  0.690  0.631  1.0
  N  N31  1  0.041  0.190  0.469  1.0
  N  N32  1  0.379  0.637  0.425  1.0
  N  N33  1  0.169  0.300  0.247  1.0
  N  N34  1  0.417  0.636  0.210  1.0
  N  N35  1  0.124  0.220  0.058  1.0
[/CIF]
.