The structure described by Zr(O5Cl)3ClO is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four hypochlorous acid molecules and four Zr(O5Cl)3 clusters. In each Zr(O5Cl)3 cluster, Zr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form distorted ZrO8 hexagonal bipyramids that share  an edgeedge with one Cl(1)O4 tetrahedra,  an edgeedge with one Cl(2)O4 tetrahedra, and  an edgeedge with one Cl(3)O4 tetrahedra. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zr(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zr(1) and one Cl(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zr(1) and one Cl(2) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zr(1) and one Cl(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Zr(1) and one Cl(3) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Zr(1) and one Cl(3) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Zr(1) and one O(15) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Zr(1) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Cl(1) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one Cl(1) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Cl(2) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Cl(2) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one Cl(3) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Cl(3) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one O(7) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to one O(1), one O(10), one O(2), and one O(9) atom to form ClO4 tetrahedra that share  an edgeedge with one Zr(1)O8 hexagonal bipyramid. In the second Cl site, Cl(2) is bonded to one O(11), one O(12), one O(3), and one O(4) atom to form ClO4 tetrahedra that share  an edgeedge with one Zr(1)O8 hexagonal bipyramid. In the third Cl site, Cl(3) is bonded to one O(13), one O(14), one O(5), and one O(6) atom to form ClO4 tetrahedra that share  an edgeedge with one Zr(1)O8 hexagonal bipyramid. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zr(ClO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.319
_cell_length_b   8.319
_cell_length_c   14.863
_cell_angle_alpha   69.931
_cell_angle_beta   69.931
_cell_angle_gamma   61.334
_symmetry_Int_Tables_number   1
_cell_volume   827.532
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.577  0.667  0.909  1.0
  Zr  Zr1  1  0.667  0.577  0.409  1.0
  Cl  Cl2  1  0.613  0.275  0.983  1.0
  Cl  Cl3  1  0.275  0.613  0.483  1.0
  Cl  Cl4  1  0.978  0.594  0.828  1.0
  Cl  Cl5  1  0.594  0.978  0.328  1.0
  Cl  Cl6  1  0.426  0.957  0.743  1.0
  Cl  Cl7  1  0.957  0.426  0.243  1.0
  Cl  Cl8  1  0.021  0.157  0.056  1.0
  Cl  Cl9  1  0.157  0.021  0.556  1.0
  O  O10  1  0.551  0.416  0.892  1.0
  O  O11  1  0.416  0.551  0.392  1.0
  O  O12  1  0.677  0.386  0.019  1.0
  O  O13  1  0.386  0.677  0.519  1.0
  O  O14  1  0.835  0.685  0.914  1.0
  O  O15  1  0.685  0.835  0.414  1.0
  O  O16  1  0.861  0.534  0.799  1.0
  O  O17  1  0.534  0.861  0.299  1.0
  O  O18  1  0.514  0.963  0.816  1.0
  O  O19  1  0.963  0.514  0.316  1.0
  O  O20  1  0.446  0.754  0.779  1.0
  O  O21  1  0.754  0.446  0.279  1.0
  O  O22  1  0.309  0.716  1.000  1.0
  O  O23  1  0.716  0.309  0.500  1.0
  O  O24  1  0.493  0.805  0.021  1.0
  O  O25  1  0.805  0.493  0.521  1.0
  O  O26  1  0.771  0.109  0.959  1.0
  O  O27  1  0.109  0.771  0.459  1.0
  O  O28  1  0.460  0.242  0.054  1.0
  O  O29  1  0.242  0.460  0.554  1.0
  O  O30  1  0.134  0.436  0.863  1.0
  O  O31  1  0.436  0.134  0.363  1.0
  O  O32  1  0.029  0.732  0.751  1.0
  O  O33  1  0.732  0.029  0.251  1.0
  O  O34  1  0.233  0.083  0.755  1.0
  O  O35  1  0.083  0.233  0.255  1.0
  O  O36  1  0.533  0.985  0.646  1.0
  O  O37  1  0.985  0.533  0.146  1.0
  O  O38  1  0.297  0.706  0.137  1.0
  O  O39  1  0.706  0.297  0.637  1.0
  O  O40  1  0.216  0.037  0.082  1.0
  O  O41  1  0.037  0.216  0.582  1.0
[/CIF]
.
The structure described by Zr(O5Cl)3ClO is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four hypochlorous acid molecules and four Zr(O5Cl)3 clusters. In each Zr(O5Cl)3 cluster, Zr(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form distorted ZrO8 hexagonal bipyramids that share  an edgeedge with one Cl(1)O4 tetrahedra,  an edgeedge with one Cl(2)O4 tetrahedra, and  an edgeedge with one Cl(3)O4 tetrahedra. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zr(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zr(1) and one Cl(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zr(1) and one Cl(2) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zr(1) and one Cl(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Zr(1) and one Cl(3) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Zr(1) and one Cl(3) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Zr(1) and one O(15) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Zr(1) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one Cl(1) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one Cl(1) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Cl(2) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Cl(2) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one Cl(3) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Cl(3) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one O(7) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded to one O(1), one O(10), one O(2), and one O(9) atom to form ClO4 tetrahedra that share  an edgeedge with one Zr(1)O8 hexagonal bipyramid. In the second Cl site, Cl(2) is bonded to one O(11), one O(12), one O(3), and one O(4) atom to form ClO4 tetrahedra that share  an edgeedge with one Zr(1)O8 hexagonal bipyramid. In the third Cl site, Cl(3) is bonded to one O(13), one O(14), one O(5), and one O(6) atom to form ClO4 tetrahedra that share  an edgeedge with one Zr(1)O8 hexagonal bipyramid. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zr(ClO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.319
_cell_length_b   8.319
_cell_length_c   14.863
_cell_angle_alpha   69.931
_cell_angle_beta   69.931
_cell_angle_gamma   61.334
_symmetry_Int_Tables_number   1
_cell_volume   827.532
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.577  0.667  0.909  1.0
  Zr  Zr1  1  0.667  0.577  0.409  1.0
  Cl  Cl2  1  0.613  0.275  0.983  1.0
  Cl  Cl3  1  0.275  0.613  0.483  1.0
  Cl  Cl4  1  0.978  0.594  0.828  1.0
  Cl  Cl5  1  0.594  0.978  0.328  1.0
  Cl  Cl6  1  0.426  0.957  0.743  1.0
  Cl  Cl7  1  0.957  0.426  0.243  1.0
  Cl  Cl8  1  0.021  0.157  0.056  1.0
  Cl  Cl9  1  0.157  0.021  0.556  1.0
  O  O10  1  0.551  0.416  0.892  1.0
  O  O11  1  0.416  0.551  0.392  1.0
  O  O12  1  0.677  0.386  0.019  1.0
  O  O13  1  0.386  0.677  0.519  1.0
  O  O14  1  0.835  0.685  0.914  1.0
  O  O15  1  0.685  0.835  0.414  1.0
  O  O16  1  0.861  0.534  0.799  1.0
  O  O17  1  0.534  0.861  0.299  1.0
  O  O18  1  0.514  0.963  0.816  1.0
  O  O19  1  0.963  0.514  0.316  1.0
  O  O20  1  0.446  0.754  0.779  1.0
  O  O21  1  0.754  0.446  0.279  1.0
  O  O22  1  0.309  0.716  1.000  1.0
  O  O23  1  0.716  0.309  0.500  1.0
  O  O24  1  0.493  0.805  0.021  1.0
  O  O25  1  0.805  0.493  0.521  1.0
  O  O26  1  0.771  0.109  0.959  1.0
  O  O27  1  0.109  0.771  0.459  1.0
  O  O28  1  0.460  0.242  0.054  1.0
  O  O29  1  0.242  0.460  0.554  1.0
  O  O30  1  0.134  0.436  0.863  1.0
  O  O31  1  0.436  0.134  0.363  1.0
  O  O32  1  0.029  0.732  0.751  1.0
  O  O33  1  0.732  0.029  0.251  1.0
  O  O34  1  0.233  0.083  0.755  1.0
  O  O35  1  0.083  0.233  0.255  1.0
  O  O36  1  0.533  0.985  0.646  1.0
  O  O37  1  0.985  0.533  0.146  1.0
  O  O38  1  0.297  0.706  0.137  1.0
  O  O39  1  0.706  0.297  0.637  1.0
  O  O40  1  0.216  0.037  0.082  1.0
  O  O41  1  0.037  0.216  0.582  1.0
[/CIF]
.