The structure described by NiC5PO2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two NiC5PO2 clusters. Ni(1) is bonded in a distorted trigonal planar geometry to one C(1), one O(1), and one O(2) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a bent 150 degrees geometry to one Ni(1) and one P(1) atom. In the second C site, C(2) is bonded in a 2-coordinate geometry to one C(3) and one P(1) atom. In the third C site, C(3) is bonded in a 3-coordinate geometry to one C(2), one C(4), and one P(1) atom. In the fourth C site, C(4) is bonded in a 2-coordinate geometry to one C(3) and one P(1) atom. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. P(1) is bonded in a 4-coordinate geometry to one C(1), one C(2), one C(3), and one C(4) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a water-like geometry to one Ni(1) and one C(5) atom. In the second O site, O(1) is bonded in a water-like geometry to one Ni(1) and one C(5) atom. is represented by the CIF card [CIF]
data_NiPC5O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.130
_cell_length_b   10.538
_cell_length_c   12.191
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   83.769
_symmetry_Int_Tables_number   1
_cell_volume   910.515
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.445  0.238  0.552  1.0
  Ni  Ni1  1  0.945  0.738  0.948  1.0
  Ni  Ni2  1  0.555  0.762  0.448  1.0
  Ni  Ni3  1  0.055  0.262  0.052  1.0
  P  P4  1  0.455  0.449  0.763  1.0
  P  P5  1  0.955  0.949  0.737  1.0
  P  P6  1  0.545  0.551  0.237  1.0
  P  P7  1  0.045  0.051  0.263  1.0
  C  C8  1  0.426  0.369  0.639  1.0
  C  C9  1  0.926  0.869  0.861  1.0
  C  C10  1  0.574  0.631  0.361  1.0
  C  C11  1  0.074  0.131  0.139  1.0
  C  C12  1  0.667  0.342  0.832  1.0
  C  C13  1  0.167  0.842  0.668  1.0
  C  C14  1  0.333  0.658  0.168  1.0
  C  C15  1  0.833  0.158  0.332  1.0
  C  C16  1  0.736  0.415  0.753  1.0
  C  C17  1  0.236  0.915  0.747  1.0
  C  C18  1  0.264  0.585  0.247  1.0
  C  C19  1  0.764  0.085  0.253  1.0
  C  C20  1  0.684  0.540  0.736  1.0
  C  C21  1  0.184  0.040  0.764  1.0
  C  C22  1  0.316  0.460  0.264  1.0
  C  C23  1  0.816  0.960  0.236  1.0
  C  C24  1  0.584  0.991  0.540  1.0
  C  C25  1  0.084  0.491  0.960  1.0
  C  C26  1  0.416  0.009  0.460  1.0
  C  C27  1  0.916  0.509  0.040  1.0
  O  O28  1  0.623  0.089  0.591  1.0
  O  O29  1  0.123  0.589  0.909  1.0
  O  O30  1  0.377  0.911  0.409  1.0
  O  O31  1  0.877  0.411  0.091  1.0
  O  O32  1  0.330  0.121  0.451  1.0
  O  O33  1  0.830  0.621  0.049  1.0
  O  O34  1  0.670  0.879  0.549  1.0
  O  O35  1  0.170  0.379  0.951  1.0
[/CIF]
.
The structure described by NiC5PO2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two NiC5PO2 clusters. Ni(1) is bonded in a distorted trigonal planar geometry to one C(1), one O(1), and one O(2) atom. There are five inequivalent C sites. In the first C site, C(1) is bonded in a bent 150 degrees geometry to one Ni(1) and one P(1) atom. In the second C site, C(2) is bonded in a 2-coordinate geometry to one C(3) and one P(1) atom. In the third C site, C(3) is bonded in a 3-coordinate geometry to one C(2), one C(4), and one P(1) atom. In the fourth C site, C(4) is bonded in a 2-coordinate geometry to one C(3) and one P(1) atom. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. P(1) is bonded in a 4-coordinate geometry to one C(1), one C(2), one C(3), and one C(4) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a water-like geometry to one Ni(1) and one C(5) atom. In the second O site, O(1) is bonded in a water-like geometry to one Ni(1) and one C(5) atom. is represented by the CIF card [CIF]
data_NiPC5O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.130
_cell_length_b   10.538
_cell_length_c   12.191
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   83.769
_symmetry_Int_Tables_number   1
_cell_volume   910.515
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.445  0.238  0.552  1.0
  Ni  Ni1  1  0.945  0.738  0.948  1.0
  Ni  Ni2  1  0.555  0.762  0.448  1.0
  Ni  Ni3  1  0.055  0.262  0.052  1.0
  P  P4  1  0.455  0.449  0.763  1.0
  P  P5  1  0.955  0.949  0.737  1.0
  P  P6  1  0.545  0.551  0.237  1.0
  P  P7  1  0.045  0.051  0.263  1.0
  C  C8  1  0.426  0.369  0.639  1.0
  C  C9  1  0.926  0.869  0.861  1.0
  C  C10  1  0.574  0.631  0.361  1.0
  C  C11  1  0.074  0.131  0.139  1.0
  C  C12  1  0.667  0.342  0.832  1.0
  C  C13  1  0.167  0.842  0.668  1.0
  C  C14  1  0.333  0.658  0.168  1.0
  C  C15  1  0.833  0.158  0.332  1.0
  C  C16  1  0.736  0.415  0.753  1.0
  C  C17  1  0.236  0.915  0.747  1.0
  C  C18  1  0.264  0.585  0.247  1.0
  C  C19  1  0.764  0.085  0.253  1.0
  C  C20  1  0.684  0.540  0.736  1.0
  C  C21  1  0.184  0.040  0.764  1.0
  C  C22  1  0.316  0.460  0.264  1.0
  C  C23  1  0.816  0.960  0.236  1.0
  C  C24  1  0.584  0.991  0.540  1.0
  C  C25  1  0.084  0.491  0.960  1.0
  C  C26  1  0.416  0.009  0.460  1.0
  C  C27  1  0.916  0.509  0.040  1.0
  O  O28  1  0.623  0.089  0.591  1.0
  O  O29  1  0.123  0.589  0.909  1.0
  O  O30  1  0.377  0.911  0.409  1.0
  O  O31  1  0.877  0.411  0.091  1.0
  O  O32  1  0.330  0.121  0.451  1.0
  O  O33  1  0.830  0.621  0.049  1.0
  O  O34  1  0.670  0.879  0.549  1.0
  O  O35  1  0.170  0.379  0.951  1.0
[/CIF]
.