The crystal structure described by Cr2O5F2 is Indium-like structured and crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of four Cr2O5F2 clusters. Cr(1) is bonded to one O(1), one O(2), one O(3), and one F(1) atom to form corner-sharing CrO3F tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Cr(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one Cr(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cr(1) atom. F(1) is bonded in a single-bond geometry to one Cr(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cr2O5F2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.271
_cell_length_b   8.271
_cell_length_c   9.676
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   661.871
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.091  0.336  0.860  1.0
  Cr  Cr1  1  0.164  0.409  0.360  1.0
  Cr  Cr2  1  0.336  0.909  0.140  1.0
  Cr  Cr3  1  0.409  0.836  0.640  1.0
  Cr  Cr4  1  0.591  0.164  0.640  1.0
  Cr  Cr5  1  0.664  0.091  0.140  1.0
  Cr  Cr6  1  0.836  0.591  0.360  1.0
  Cr  Cr7  1  0.909  0.664  0.860  1.0
  O  O8  1  0.000  0.500  0.269  1.0
  O  O9  1  0.000  0.500  0.769  1.0
  O  O10  1  0.025  0.716  0.984  1.0
  O  O11  1  0.108  0.191  0.755  1.0
  O  O12  1  0.216  0.525  0.484  1.0
  O  O13  1  0.191  0.892  0.245  1.0
  O  O14  1  0.309  0.392  0.255  1.0
  O  O15  1  0.284  0.025  0.016  1.0
  O  O16  1  0.392  0.691  0.745  1.0
  O  O17  1  0.475  0.216  0.516  1.0
  O  O18  1  0.500  0.000  0.231  1.0
  O  O19  1  0.500  0.000  0.731  1.0
  O  O20  1  0.525  0.784  0.516  1.0
  O  O21  1  0.608  0.309  0.745  1.0
  O  O22  1  0.716  0.975  0.016  1.0
  O  O23  1  0.691  0.608  0.255  1.0
  O  O24  1  0.809  0.108  0.245  1.0
  O  O25  1  0.784  0.475  0.484  1.0
  O  O26  1  0.892  0.809  0.755  1.0
  O  O27  1  0.975  0.284  0.984  1.0
  F  F28  1  0.100  0.224  0.423  1.0
  F  F29  1  0.224  0.900  0.577  1.0
  F  F30  1  0.276  0.400  0.923  1.0
  F  F31  1  0.400  0.724  0.077  1.0
  F  F32  1  0.600  0.276  0.077  1.0
  F  F33  1  0.724  0.600  0.923  1.0
  F  F34  1  0.776  0.100  0.577  1.0
  F  F35  1  0.900  0.776  0.423  1.0
[/CIF]
.
The crystal structure described by Cr2O5F2 is Indium-like structured and crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of four Cr2O5F2 clusters. Cr(1) is bonded to one O(1), one O(2), one O(3), and one F(1) atom to form corner-sharing CrO3F tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Cr(1) atoms. In the second O site, O(2) is bonded in a single-bond geometry to one Cr(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cr(1) atom. F(1) is bonded in a single-bond geometry to one Cr(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cr2O5F2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.271
_cell_length_b   8.271
_cell_length_c   9.676
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   661.871
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.091  0.336  0.860  1.0
  Cr  Cr1  1  0.164  0.409  0.360  1.0
  Cr  Cr2  1  0.336  0.909  0.140  1.0
  Cr  Cr3  1  0.409  0.836  0.640  1.0
  Cr  Cr4  1  0.591  0.164  0.640  1.0
  Cr  Cr5  1  0.664  0.091  0.140  1.0
  Cr  Cr6  1  0.836  0.591  0.360  1.0
  Cr  Cr7  1  0.909  0.664  0.860  1.0
  O  O8  1  0.000  0.500  0.269  1.0
  O  O9  1  0.000  0.500  0.769  1.0
  O  O10  1  0.025  0.716  0.984  1.0
  O  O11  1  0.108  0.191  0.755  1.0
  O  O12  1  0.216  0.525  0.484  1.0
  O  O13  1  0.191  0.892  0.245  1.0
  O  O14  1  0.309  0.392  0.255  1.0
  O  O15  1  0.284  0.025  0.016  1.0
  O  O16  1  0.392  0.691  0.745  1.0
  O  O17  1  0.475  0.216  0.516  1.0
  O  O18  1  0.500  0.000  0.231  1.0
  O  O19  1  0.500  0.000  0.731  1.0
  O  O20  1  0.525  0.784  0.516  1.0
  O  O21  1  0.608  0.309  0.745  1.0
  O  O22  1  0.716  0.975  0.016  1.0
  O  O23  1  0.691  0.608  0.255  1.0
  O  O24  1  0.809  0.108  0.245  1.0
  O  O25  1  0.784  0.475  0.484  1.0
  O  O26  1  0.892  0.809  0.755  1.0
  O  O27  1  0.975  0.284  0.984  1.0
  F  F28  1  0.100  0.224  0.423  1.0
  F  F29  1  0.224  0.900  0.577  1.0
  F  F30  1  0.276  0.400  0.923  1.0
  F  F31  1  0.400  0.724  0.077  1.0
  F  F32  1  0.600  0.276  0.077  1.0
  F  F33  1  0.724  0.600  0.923  1.0
  F  F34  1  0.776  0.100  0.577  1.0
  F  F35  1  0.900  0.776  0.423  1.0
[/CIF]
.