The structure described by MnSb2O6 is Hydrophilite-derived structured and crystallizes in the monoclinic C2/m space group. Mn(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with three equivalent Sb(1)O6 octahedra, corners with five equivalent Sb(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and  an edgeedge with one Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(3) and four equivalent O(5) atoms to form SbO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra, corners with six equivalent Mn(1)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. In the second Sb site, Sb(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with six equivalent Sb(3)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. In the third Sb site, Sb(3) is bonded to one O(1), one O(2), two equivalent O(4), and two equivalent O(5) atoms to form SbO6 octahedra that share corners with three equivalent Sb(2)O6 octahedra, corners with five equivalent Mn(1)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(1), one Sb(2), and one Sb(3) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Mn(1) and one Sb(3) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Sb(1), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Sb(2) and two equivalent Sb(3) atoms. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(1), one Sb(1), and one Sb(3) atom. is represented by the CIF card [CIF]
data_Mn(SbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.779
_cell_length_b   5.779
_cell_length_c   7.407
_cell_angle_alpha   73.589
_cell_angle_beta   73.589
_cell_angle_gamma   73.911
_symmetry_Int_Tables_number   1
_cell_volume   222.311
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.672  0.672  0.828  1.0
  Mn  Mn1  1  0.994  0.994  0.505  1.0
  O  O2  1  0.559  0.559  0.142  1.0
  O  O3  1  0.108  0.108  0.191  1.0
  O  O4  1  0.901  0.901  0.805  1.0
  O  O5  1  0.766  0.766  0.529  1.0
  O  O6  1  0.239  0.239  0.454  1.0
  O  O7  1  0.428  0.428  0.880  1.0
  O  O8  1  0.026  0.641  0.167  1.0
  O  O9  1  0.641  0.026  0.167  1.0
  O  O10  1  0.984  0.357  0.827  1.0
  O  O11  1  0.357  0.984  0.827  1.0
  O  O12  1  0.683  0.310  0.507  1.0
  O  O13  1  0.310  0.683  0.507  1.0
  Sb  Sb14  1  0.333  0.333  0.667  1.0
  Sb  Sb15  1  0.333  0.333  0.167  1.0
  Sb  Sb16  1  0.005  0.005  0.988  1.0
  Sb  Sb17  1  0.661  0.661  0.346  1.0
[/CIF]
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The structure described by MnSb2O6 is Hydrophilite-derived structured and crystallizes in the monoclinic C2/m space group. Mn(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(5) atoms to form MnO6 octahedra that share corners with three equivalent Sb(1)O6 octahedra, corners with five equivalent Sb(3)O6 octahedra,  an edgeedge with one Mn(1)O6 octahedra, and  an edgeedge with one Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-55°. There are three inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to two equivalent O(3) and four equivalent O(5) atoms to form SbO6 octahedra that share corners with two equivalent Sb(2)O6 octahedra, corners with six equivalent Mn(1)O6 octahedra, and edges with two equivalent Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-55°. In the second Sb site, Sb(2) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra, corners with six equivalent Sb(3)O6 octahedra, and edges with two equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 48-51°. In the third Sb site, Sb(3) is bonded to one O(1), one O(2), two equivalent O(4), and two equivalent O(5) atoms to form SbO6 octahedra that share corners with three equivalent Sb(2)O6 octahedra, corners with five equivalent Mn(1)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, and  an edgeedge with one Sb(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. There are five inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Mn(1), one Sb(2), and one Sb(3) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Mn(1) and one Sb(3) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mn(1), one Sb(1), and one Sb(2) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one Sb(2) and two equivalent Sb(3) atoms. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Mn(1), one Sb(1), and one Sb(3) atom. is represented by the CIF card [CIF]
data_Mn(SbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.779
_cell_length_b   5.779
_cell_length_c   7.407
_cell_angle_alpha   73.589
_cell_angle_beta   73.589
_cell_angle_gamma   73.911
_symmetry_Int_Tables_number   1
_cell_volume   222.311
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.672  0.672  0.828  1.0
  Mn  Mn1  1  0.994  0.994  0.505  1.0
  O  O2  1  0.559  0.559  0.142  1.0
  O  O3  1  0.108  0.108  0.191  1.0
  O  O4  1  0.901  0.901  0.805  1.0
  O  O5  1  0.766  0.766  0.529  1.0
  O  O6  1  0.239  0.239  0.454  1.0
  O  O7  1  0.428  0.428  0.880  1.0
  O  O8  1  0.026  0.641  0.167  1.0
  O  O9  1  0.641  0.026  0.167  1.0
  O  O10  1  0.984  0.357  0.827  1.0
  O  O11  1  0.357  0.984  0.827  1.0
  O  O12  1  0.683  0.310  0.507  1.0
  O  O13  1  0.310  0.683  0.507  1.0
  Sb  Sb14  1  0.333  0.333  0.667  1.0
  Sb  Sb15  1  0.333  0.333  0.167  1.0
  Sb  Sb16  1  0.005  0.005  0.988  1.0
  Sb  Sb17  1  0.661  0.661  0.346  1.0
[/CIF]
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