The material described by Li5Co3(SbO5)2 is Caswellsilverite-derived structured and crystallizes in the triclinic P-1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(5), two equivalent O(7), and two equivalent O(9) atoms to form LiO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and edges with four equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-8°. In the second Li site, Li(2) is bonded to two equivalent O(10), two equivalent O(6), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(6)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and edges with four equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the third Li site, Li(3) is bonded to one O(2), one O(5), one O(6), one O(7), and two equivalent O(9) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-18°. In the fourth Li site, Li(4) is bonded to one O(1), one O(5), one O(6), one O(8), and two equivalent O(10) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with three equivalent Co(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-18°. In the fifth Li site, Li(5) is bonded to one O(1), one O(3), one O(4), one O(5), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-13°. In the sixth Li site, Li(6) is bonded to one O(10), one O(2), one O(3), one O(4), one O(6), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent Sb(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-13°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and edges with four equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the second Co site, Co(2) is bonded to one O(3), one O(4), one O(7), one O(9), and two equivalent O(2) atoms to form CoO6 octahedra that share  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Li(6)O6 octahedra, corners with three equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-18°. In the third Co site, Co(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with four equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the fourth Co site, Co(4) is bonded to one O(10), one O(3), one O(4), one O(8), and two equivalent O(1) atoms to form CoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, corners with three equivalent Li(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-18°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(3), one O(5), one O(6), one O(8), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with three equivalent Li(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the second Sb site, Sb(2) is bonded to one O(10), one O(2), one O(4), one O(5), one O(6), and one O(7) atom to form SbO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with three equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(4), one Li(5), one Co(3), two equivalent Co(4), and one Sb(1) atom to form distorted OLi2Co3Sb octahedra that share  a cornercorner with one O(1)Li2Co3Sb octahedra,  a cornercorner with one O(4)Li2Co3Sb octahedra,  a cornercorner with one O(7)Li3Co2Sb octahedra,  a cornercorner with one O(5)Li4Sb2 octahedra, corners with two equivalent O(10)Li4CoSb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(10)Li4CoSb octahedra,  an edgeedge with one O(9)Li4CoSb octahedra,  an edgeedge with one O(5)Li4Sb2 octahedra,  an edgeedge with one O(6)Li4Sb2 octahedra, edges with three equivalent O(3)Li2Co3Sb octahedra, and edges with three equivalent O(8)Li3Co2Sb octahedra. The corner-sharing octahedral tilt angles range from 0-16°. In the second O site, O(2) is bonded to one Li(3), one Li(6), one Co(1), two equivalent Co(2), and one Sb(2) atom to form distorted OLi2Co3Sb octahedra that share  a cornercorner with one O(2)Li2Co3Sb octahedra,  a cornercorner with one O(3)Li2Co3Sb octahedra,  a cornercorner with one O(8)Li3Co2Sb octahedra,  a cornercorner with one O(6)Li4Sb2 octahedra, corners with two equivalent O(9)Li4CoSb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(10)Li4CoSb octahedra,  an edgeedge with one O(9)Li4CoSb octahedra,  an edgeedge with one O(5)Li4Sb2 octahedra,  an edgeedge with one O(6)Li4Sb2 octahedra, edges with three equivalent O(4)Li2Co3Sb octahedra, and edges with three equivalent O(7)Li3Co2Sb octahedra. The corner-sharing octahedral tilt angles range from 0-16°. In the third O site, O(3) is bonded to one Li(5), one Li(6), one Co(2), one Co(3), one Co(4), and one Sb(1) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(2)Li2Co3Sb octahedra,  a cornercorner with one O(3)Li2Co3Sb octahedra,  a cornercorner with one O(8)Li3Co2Sb octahedra,  a cornercorner with one O(9)Li4CoSb octahedra, corners with two equivalent O(6)Li4Sb2 octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li3Co2Sb octahedra,  an edgeedge with one O(10)Li4CoSb octahedra,  an edgeedge with one O(9)Li4CoSb octahedra,  an edgeedge with one O(5)Li4Sb2 octahedra, edges with two equivalent O(4)Li2Co3Sb octahedra, edges with two equivalent O(8)Li3Co2Sb octahedra, and edges with three equivalent O(1)Li2Co3Sb octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the fourth O site, O(4) is bonded to one Li(5), one Li(6), one Co(1), one Co(2), one Co(4), and one Sb(2) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(1)Li2Co3Sb octahedra,  a cornercorner with one O(4)Li2Co3Sb octahedra,  a cornercorner with one O(7)Li3Co2Sb octahedra,  a cornercorner with one O(10)Li4CoSb octahedra, corners with two equivalent O(5)Li4Sb2 octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li3Co2Sb octahedra,  an edgeedge with one O(10)Li4CoSb octahedra,  an edgeedge with one O(9)Li4CoSb octahedra,  an edgeedge with one O(6)Li4Sb2 octahedra, edges with two equivalent O(3)Li2Co3Sb octahedra, edges with two equivalent O(7)Li3Co2Sb octahedra, and edges with three equivalent O(2)Li2Co3Sb octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one Li(4), one Li(5), one Sb(1), and one Sb(2) atom to form OLi4Sb2 octahedra that share  a cornercorner with one O(1)Li2Co3Sb octahedra,  a cornercorner with one O(7)Li3Co2Sb octahedra,  a cornercorner with one O(10)Li4CoSb octahedra,  a cornercorner with one O(5)Li4Sb2 octahedra, corners with two equivalent O(4)Li2Co3Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li3Co2Sb octahedra,  an edgeedge with one O(10)Li4CoSb octahedra, edges with two equivalent O(7)Li3Co2Sb octahedra, edges with two equivalent O(6)Li4Sb2 octahedra, and edges with three equivalent O(9)Li4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Li(4), one Li(6), one Sb(1), and one Sb(2) atom to form OLi4Sb2 octahedra that share  a cornercorner with one O(2)Li2Co3Sb octahedra,  a cornercorner with one O(8)Li3Co2Sb octahedra,  a cornercorner with one O(9)Li4CoSb octahedra,  a cornercorner with one O(6)Li4Sb2 octahedra, corners with two equivalent O(3)Li2Co3Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li3Co2Sb octahedra,  an edgeedge with one O(9)Li4CoSb octahedra, edges with two equivalent O(8)Li3Co2Sb octahedra, edges with two equivalent O(5)Li4Sb2 octahedra, and edges with three equivalent O(10)Li4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the seventh O site, O(7) is bonded to one Li(1), one Li(3), one Li(5), one Co(1), one Co(2), and one Sb(2) atom to form OLi3Co2Sb octahedra that share  a cornercorner with one O(1)Li2Co3Sb octahedra,  a cornercorner with one O(4)Li2Co3Sb octahedra,  a cornercorner with one O(10)Li4CoSb octahedra,  a cornercorner with one O(5)Li4Sb2 octahedra, corners with two equivalent O(7)Li3Co2Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li4Sb2 octahedra, edges with two equivalent O(4)Li2Co3Sb octahedra, edges with two equivalent O(5)Li4Sb2 octahedra, edges with three equivalent O(2)Li2Co3Sb octahedra, and edges with three equivalent O(9)Li4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the eighth O site, O(8) is bonded to one Li(2), one Li(4), one Li(6), one Co(3), one Co(4), and one Sb(1) atom to form OLi3Co2Sb octahedra that share  a cornercorner with one O(2)Li2Co3Sb octahedra,  a cornercorner with one O(3)Li2Co3Sb octahedra,  a cornercorner with one O(9)Li4CoSb octahedra,  a cornercorner with one O(6)Li4Sb2 octahedra, corners with two equivalent O(8)Li3Co2Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li4Sb2 octahedra, edges with two equivalent O(3)Li2Co3Sb octahedra, edges with two equivalent O(6)Li4Sb2 octahedra, edges with three equivalent O(1)Li2Co3Sb octahedra, and edges with three equivalent O(10)Li4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the ninth O site, O(9) is bonded to one Li(1), one Li(5), two equivalent Li(3), one Co(2), and one Sb(1) atom to form OLi4CoSb octahedra that share  a cornercorner with one O(3)Li2Co3Sb octahedra,  a cornercorner with one O(8)Li3Co2Sb octahedra,  a cornercorner with one O(9)Li4CoSb octahedra,  a cornercorner with one O(6)Li4Sb2 octahedra, corners with two equivalent O(2)Li2Co3Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(9)Li4CoSb octahedra,  an edgeedge with one O(6)Li4Sb2 octahedra, edges with three equivalent O(7)Li3Co2Sb octahedra, and edges with three equivalent O(5)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-16°. In the tenth O site, O(10) is bonded to one Li(2), one Li(6), two equivalent Li(4), one Co(4), and one Sb(2) atom to form OLi4CoSb octahedra that share  a cornercorner with one O(4)Li2Co3Sb octahedra,  a cornercorner with one O(7)Li3Co2Sb octahedra,  a cornercorner with one O(10)Li4CoSb octahedra,  a cornercorner with one O(5)Li4Sb2 octahedra, corners with two equivalent O(1)Li2Co3Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(10)Li4CoSb octahedra,  an edgeedge with one O(5)Li4Sb2 octahedra, edges with three equivalent O(8)Li3Co2Sb octahedra, and edges with three equivalent O(6)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-16°. is represented by the CIF card [CIF]
data_Li5Co3(SbO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.254
_cell_length_b   5.294
_cell_length_c   8.077
_cell_angle_alpha   73.108
_cell_angle_beta   76.754
_cell_angle_gamma   101.457
_symmetry_Int_Tables_number   1
_cell_volume   200.570
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  1.000  1.0
  Co  Co1  1  0.271  0.095  0.908  1.0
  Co  Co2  1  0.729  0.905  0.092  1.0
  Li  Li3  1  0.500  0.500  0.500  1.0
  Li  Li4  1  0.769  0.100  0.394  1.0
  Li  Li5  1  0.231  0.900  0.606  1.0
  Li  Li6  1  0.581  0.703  0.803  1.0
  Li  Li7  1  0.419  0.297  0.197  1.0
  O  O8  1  0.943  0.931  0.825  1.0
  O  O9  1  0.057  0.069  0.175  1.0
  O  O10  1  0.662  0.313  0.933  1.0
  O  O11  1  0.338  0.687  0.067  1.0
  O  O12  1  0.862  0.672  0.546  1.0
  O  O13  1  0.138  0.328  0.454  1.0
  O  O14  1  0.787  0.508  0.245  1.0
  O  O15  1  0.213  0.492  0.755  1.0
  O  O16  1  0.558  0.105  0.657  1.0
  O  O17  1  0.442  0.895  0.343  1.0
  Sb  Sb18  1  0.887  0.295  0.700  1.0
  Sb  Sb19  1  0.113  0.705  0.300  1.0
[/CIF]
.
The material described by Li5Co3(SbO5)2 is Caswellsilverite-derived structured and crystallizes in the triclinic P-1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent O(5), two equivalent O(7), and two equivalent O(9) atoms to form LiO6 octahedra that share corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and edges with four equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 6-8°. In the second Li site, Li(2) is bonded to two equivalent O(10), two equivalent O(6), and two equivalent O(8) atoms to form LiO6 octahedra that share corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(6)O6 octahedra, corners with two equivalent Co(3)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and edges with four equivalent Li(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the third Li site, Li(3) is bonded to one O(2), one O(5), one O(6), one O(7), and two equivalent O(9) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-18°. In the fourth Li site, Li(4) is bonded to one O(1), one O(5), one O(6), one O(8), and two equivalent O(10) atoms to form distorted LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, corners with three equivalent Co(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-18°. In the fifth Li site, Li(5) is bonded to one O(1), one O(3), one O(4), one O(5), one O(7), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with three equivalent Sb(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-13°. In the sixth Li site, Li(6) is bonded to one O(10), one O(2), one O(3), one O(4), one O(6), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with three equivalent Sb(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Co(4)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-13°. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to two equivalent O(2), two equivalent O(4), and two equivalent O(7) atoms to form CoO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Co(4)O6 octahedra, corners with two equivalent Sb(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Sb(2)O6 octahedra, and edges with four equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the second Co site, Co(2) is bonded to one O(3), one O(4), one O(7), one O(9), and two equivalent O(2) atoms to form CoO6 octahedra that share  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Li(6)O6 octahedra, corners with three equivalent Li(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, and edges with two equivalent Sb(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-18°. In the third Co site, Co(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, corners with two equivalent Sb(1)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Sb(1)O6 octahedra, and edges with four equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-9°. In the fourth Co site, Co(4) is bonded to one O(10), one O(3), one O(4), one O(8), and two equivalent O(1) atoms to form CoO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, corners with three equivalent Li(4)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent Co(3)O6 octahedra, and edges with two equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-18°. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one O(1), one O(3), one O(5), one O(6), one O(8), and one O(9) atom to form SbO6 octahedra that share  a cornercorner with one Co(3)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with three equivalent Li(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Co(2)O6 octahedra,  an edgeedge with one Co(3)O6 octahedra,  an edgeedge with one Sb(2)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Co(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. In the second Sb site, Sb(2) is bonded to one O(10), one O(2), one O(4), one O(5), one O(6), and one O(7) atom to form SbO6 octahedra that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with three equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Co(1)O6 octahedra,  an edgeedge with one Co(4)O6 octahedra,  an edgeedge with one Sb(1)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-9°. There are ten inequivalent O sites. In the first O site, O(1) is bonded to one Li(4), one Li(5), one Co(3), two equivalent Co(4), and one Sb(1) atom to form distorted OLi2Co3Sb octahedra that share  a cornercorner with one O(1)Li2Co3Sb octahedra,  a cornercorner with one O(4)Li2Co3Sb octahedra,  a cornercorner with one O(7)Li3Co2Sb octahedra,  a cornercorner with one O(5)Li4Sb2 octahedra, corners with two equivalent O(10)Li4CoSb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(10)Li4CoSb octahedra,  an edgeedge with one O(9)Li4CoSb octahedra,  an edgeedge with one O(5)Li4Sb2 octahedra,  an edgeedge with one O(6)Li4Sb2 octahedra, edges with three equivalent O(3)Li2Co3Sb octahedra, and edges with three equivalent O(8)Li3Co2Sb octahedra. The corner-sharing octahedral tilt angles range from 0-16°. In the second O site, O(2) is bonded to one Li(3), one Li(6), one Co(1), two equivalent Co(2), and one Sb(2) atom to form distorted OLi2Co3Sb octahedra that share  a cornercorner with one O(2)Li2Co3Sb octahedra,  a cornercorner with one O(3)Li2Co3Sb octahedra,  a cornercorner with one O(8)Li3Co2Sb octahedra,  a cornercorner with one O(6)Li4Sb2 octahedra, corners with two equivalent O(9)Li4CoSb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(10)Li4CoSb octahedra,  an edgeedge with one O(9)Li4CoSb octahedra,  an edgeedge with one O(5)Li4Sb2 octahedra,  an edgeedge with one O(6)Li4Sb2 octahedra, edges with three equivalent O(4)Li2Co3Sb octahedra, and edges with three equivalent O(7)Li3Co2Sb octahedra. The corner-sharing octahedral tilt angles range from 0-16°. In the third O site, O(3) is bonded to one Li(5), one Li(6), one Co(2), one Co(3), one Co(4), and one Sb(1) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(2)Li2Co3Sb octahedra,  a cornercorner with one O(3)Li2Co3Sb octahedra,  a cornercorner with one O(8)Li3Co2Sb octahedra,  a cornercorner with one O(9)Li4CoSb octahedra, corners with two equivalent O(6)Li4Sb2 octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li3Co2Sb octahedra,  an edgeedge with one O(10)Li4CoSb octahedra,  an edgeedge with one O(9)Li4CoSb octahedra,  an edgeedge with one O(5)Li4Sb2 octahedra, edges with two equivalent O(4)Li2Co3Sb octahedra, edges with two equivalent O(8)Li3Co2Sb octahedra, and edges with three equivalent O(1)Li2Co3Sb octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the fourth O site, O(4) is bonded to one Li(5), one Li(6), one Co(1), one Co(2), one Co(4), and one Sb(2) atom to form OLi2Co3Sb octahedra that share  a cornercorner with one O(1)Li2Co3Sb octahedra,  a cornercorner with one O(4)Li2Co3Sb octahedra,  a cornercorner with one O(7)Li3Co2Sb octahedra,  a cornercorner with one O(10)Li4CoSb octahedra, corners with two equivalent O(5)Li4Sb2 octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li3Co2Sb octahedra,  an edgeedge with one O(10)Li4CoSb octahedra,  an edgeedge with one O(9)Li4CoSb octahedra,  an edgeedge with one O(6)Li4Sb2 octahedra, edges with two equivalent O(3)Li2Co3Sb octahedra, edges with two equivalent O(7)Li3Co2Sb octahedra, and edges with three equivalent O(2)Li2Co3Sb octahedra. The corner-sharing octahedral tilt angles range from 0-12°. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one Li(4), one Li(5), one Sb(1), and one Sb(2) atom to form OLi4Sb2 octahedra that share  a cornercorner with one O(1)Li2Co3Sb octahedra,  a cornercorner with one O(7)Li3Co2Sb octahedra,  a cornercorner with one O(10)Li4CoSb octahedra,  a cornercorner with one O(5)Li4Sb2 octahedra, corners with two equivalent O(4)Li2Co3Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(8)Li3Co2Sb octahedra,  an edgeedge with one O(10)Li4CoSb octahedra, edges with two equivalent O(7)Li3Co2Sb octahedra, edges with two equivalent O(6)Li4Sb2 octahedra, and edges with three equivalent O(9)Li4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the sixth O site, O(6) is bonded to one Li(2), one Li(3), one Li(4), one Li(6), one Sb(1), and one Sb(2) atom to form OLi4Sb2 octahedra that share  a cornercorner with one O(2)Li2Co3Sb octahedra,  a cornercorner with one O(8)Li3Co2Sb octahedra,  a cornercorner with one O(9)Li4CoSb octahedra,  a cornercorner with one O(6)Li4Sb2 octahedra, corners with two equivalent O(3)Li2Co3Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(7)Li3Co2Sb octahedra,  an edgeedge with one O(9)Li4CoSb octahedra, edges with two equivalent O(8)Li3Co2Sb octahedra, edges with two equivalent O(5)Li4Sb2 octahedra, and edges with three equivalent O(10)Li4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the seventh O site, O(7) is bonded to one Li(1), one Li(3), one Li(5), one Co(1), one Co(2), and one Sb(2) atom to form OLi3Co2Sb octahedra that share  a cornercorner with one O(1)Li2Co3Sb octahedra,  a cornercorner with one O(4)Li2Co3Sb octahedra,  a cornercorner with one O(10)Li4CoSb octahedra,  a cornercorner with one O(5)Li4Sb2 octahedra, corners with two equivalent O(7)Li3Co2Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(6)Li4Sb2 octahedra, edges with two equivalent O(4)Li2Co3Sb octahedra, edges with two equivalent O(5)Li4Sb2 octahedra, edges with three equivalent O(2)Li2Co3Sb octahedra, and edges with three equivalent O(9)Li4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the eighth O site, O(8) is bonded to one Li(2), one Li(4), one Li(6), one Co(3), one Co(4), and one Sb(1) atom to form OLi3Co2Sb octahedra that share  a cornercorner with one O(2)Li2Co3Sb octahedra,  a cornercorner with one O(3)Li2Co3Sb octahedra,  a cornercorner with one O(9)Li4CoSb octahedra,  a cornercorner with one O(6)Li4Sb2 octahedra, corners with two equivalent O(8)Li3Co2Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(5)Li4Sb2 octahedra, edges with two equivalent O(3)Li2Co3Sb octahedra, edges with two equivalent O(6)Li4Sb2 octahedra, edges with three equivalent O(1)Li2Co3Sb octahedra, and edges with three equivalent O(10)Li4CoSb octahedra. The corner-sharing octahedral tilt angles range from 0-13°. In the ninth O site, O(9) is bonded to one Li(1), one Li(5), two equivalent Li(3), one Co(2), and one Sb(1) atom to form OLi4CoSb octahedra that share  a cornercorner with one O(3)Li2Co3Sb octahedra,  a cornercorner with one O(8)Li3Co2Sb octahedra,  a cornercorner with one O(9)Li4CoSb octahedra,  a cornercorner with one O(6)Li4Sb2 octahedra, corners with two equivalent O(2)Li2Co3Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(9)Li4CoSb octahedra,  an edgeedge with one O(6)Li4Sb2 octahedra, edges with three equivalent O(7)Li3Co2Sb octahedra, and edges with three equivalent O(5)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-16°. In the tenth O site, O(10) is bonded to one Li(2), one Li(6), two equivalent Li(4), one Co(4), and one Sb(2) atom to form OLi4CoSb octahedra that share  a cornercorner with one O(4)Li2Co3Sb octahedra,  a cornercorner with one O(7)Li3Co2Sb octahedra,  a cornercorner with one O(10)Li4CoSb octahedra,  a cornercorner with one O(5)Li4Sb2 octahedra, corners with two equivalent O(1)Li2Co3Sb octahedra,  an edgeedge with one O(1)Li2Co3Sb octahedra,  an edgeedge with one O(2)Li2Co3Sb octahedra,  an edgeedge with one O(3)Li2Co3Sb octahedra,  an edgeedge with one O(4)Li2Co3Sb octahedra,  an edgeedge with one O(10)Li4CoSb octahedra,  an edgeedge with one O(5)Li4Sb2 octahedra, edges with three equivalent O(8)Li3Co2Sb octahedra, and edges with three equivalent O(6)Li4Sb2 octahedra. The corner-sharing octahedral tilt angles range from 0-16°. is represented by the CIF card [CIF]
data_Li5Co3(SbO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.254
_cell_length_b   5.294
_cell_length_c   8.077
_cell_angle_alpha   73.108
_cell_angle_beta   76.754
_cell_angle_gamma   101.457
_symmetry_Int_Tables_number   1
_cell_volume   200.570
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.000  0.500  1.000  1.0
  Co  Co1  1  0.271  0.095  0.908  1.0
  Co  Co2  1  0.729  0.905  0.092  1.0
  Li  Li3  1  0.500  0.500  0.500  1.0
  Li  Li4  1  0.769  0.100  0.394  1.0
  Li  Li5  1  0.231  0.900  0.606  1.0
  Li  Li6  1  0.581  0.703  0.803  1.0
  Li  Li7  1  0.419  0.297  0.197  1.0
  O  O8  1  0.943  0.931  0.825  1.0
  O  O9  1  0.057  0.069  0.175  1.0
  O  O10  1  0.662  0.313  0.933  1.0
  O  O11  1  0.338  0.687  0.067  1.0
  O  O12  1  0.862  0.672  0.546  1.0
  O  O13  1  0.138  0.328  0.454  1.0
  O  O14  1  0.787  0.508  0.245  1.0
  O  O15  1  0.213  0.492  0.755  1.0
  O  O16  1  0.558  0.105  0.657  1.0
  O  O17  1  0.442  0.895  0.343  1.0
  Sb  Sb18  1  0.887  0.295  0.700  1.0
  Sb  Sb19  1  0.113  0.705  0.300  1.0
[/CIF]
.