The structure described by AgIn2Te3I crystallizes in the monoclinic Cm space group. Ag(1) is bonded to one Te(2), two equivalent Te(3), and one I(1) atom to form AgTe3I tetrahedra that share corners with two equivalent Ag(1)Te3I tetrahedra, corners with three equivalent In(1)Te3I tetrahedra, and corners with four equivalent In(2)Te4 tetrahedra. There are two inequivalent In sites. In the first In site, In(1) is bonded to one Te(3), two equivalent Te(1), and one I(1) atom to form InTe3I tetrahedra that share corners with two equivalent In(1)Te3I tetrahedra, corners with three equivalent Ag(1)Te3I tetrahedra, and corners with three equivalent In(2)Te4 tetrahedra. In the second In site, In(2) is bonded to one Te(1), one Te(3), and two equivalent Te(2) atoms to form InTe4 tetrahedra that share corners with two equivalent In(2)Te4 tetrahedra, corners with three equivalent In(1)Te3I tetrahedra, and corners with four equivalent Ag(1)Te3I tetrahedra. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded in a trigonal non-coplanar geometry to one In(2) and two equivalent In(1) atoms. In the second Te site, Te(2) is bonded in a trigonal non-coplanar geometry to one Ag(1) and two equivalent In(2) atoms. In the third Te site, Te(3) is bonded to two equivalent Ag(1), one In(1), and one In(2) atom to form corner-sharing TeIn2Ag2 tetrahedra. I(1) is bonded in a water-like geometry to one Ag(1) and one In(1) atom. is represented by the CIF file [CIF]
data_In2AgTe3I
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.846
_cell_length_b   7.846
_cell_length_c   8.083
_cell_angle_alpha   81.979
_cell_angle_beta   81.979
_cell_angle_gamma   33.659
_symmetry_Int_Tables_number   1
_cell_volume   272.828
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.563  0.563  0.813  1.0
  In  In1  1  0.811  0.811  0.063  1.0
  Ag  Ag2  1  0.309  0.309  0.553  1.0
  Te  Te3  1  0.006  0.006  0.019  1.0
  Te  Te4  1  0.242  0.242  0.248  1.0
  Te  Te5  1  0.752  0.752  0.742  1.0
  I  I6  1  0.505  0.505  0.500  1.0
[/CIF]
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The structure described by AgIn2Te3I crystallizes in the monoclinic Cm space group. Ag(1) is bonded to one Te(2), two equivalent Te(3), and one I(1) atom to form AgTe3I tetrahedra that share corners with two equivalent Ag(1)Te3I tetrahedra, corners with three equivalent In(1)Te3I tetrahedra, and corners with four equivalent In(2)Te4 tetrahedra. There are two inequivalent In sites. In the first In site, In(1) is bonded to one Te(3), two equivalent Te(1), and one I(1) atom to form InTe3I tetrahedra that share corners with two equivalent In(1)Te3I tetrahedra, corners with three equivalent Ag(1)Te3I tetrahedra, and corners with three equivalent In(2)Te4 tetrahedra. In the second In site, In(2) is bonded to one Te(1), one Te(3), and two equivalent Te(2) atoms to form InTe4 tetrahedra that share corners with two equivalent In(2)Te4 tetrahedra, corners with three equivalent In(1)Te3I tetrahedra, and corners with four equivalent Ag(1)Te3I tetrahedra. There are three inequivalent Te sites. In the first Te site, Te(1) is bonded in a trigonal non-coplanar geometry to one In(2) and two equivalent In(1) atoms. In the second Te site, Te(2) is bonded in a trigonal non-coplanar geometry to one Ag(1) and two equivalent In(2) atoms. In the third Te site, Te(3) is bonded to two equivalent Ag(1), one In(1), and one In(2) atom to form corner-sharing TeIn2Ag2 tetrahedra. I(1) is bonded in a water-like geometry to one Ag(1) and one In(1) atom. is represented by the CIF file [CIF]
data_In2AgTe3I
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.846
_cell_length_b   7.846
_cell_length_c   8.083
_cell_angle_alpha   81.979
_cell_angle_beta   81.979
_cell_angle_gamma   33.659
_symmetry_Int_Tables_number   1
_cell_volume   272.828
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.563  0.563  0.813  1.0
  In  In1  1  0.811  0.811  0.063  1.0
  Ag  Ag2  1  0.309  0.309  0.553  1.0
  Te  Te3  1  0.006  0.006  0.019  1.0
  Te  Te4  1  0.242  0.242  0.248  1.0
  Te  Te5  1  0.752  0.752  0.742  1.0
  I  I6  1  0.505  0.505  0.500  1.0
[/CIF]
.