The crystal structure described by SrLaFeCoO6 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(5), one O(6), two equivalent O(3), two equivalent O(4), two equivalent O(7), and four equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with six equivalent Sr(1)O12 cuboctahedra, corners with six equivalent Sr(2)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, faces with three equivalent La(2)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra, faces with three equivalent Fe(2)O6 octahedra, and faces with three equivalent Co(1)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(5), one O(6), two equivalent O(3), two equivalent O(4), two equivalent O(8), and four equivalent O(2) atoms to form SrO12 cuboctahedra that share corners with six equivalent Sr(1)O12 cuboctahedra, corners with six equivalent Sr(2)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, faces with three equivalent La(2)O12 cuboctahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Co(1)O6 octahedra, faces with three equivalent Fe(1)O6 octahedra, and faces with three equivalent Co(2)O6 octahedra. There are two inequivalent La sites. In the first La site, La(1) is bonded to one O(7), one O(8), two equivalent O(1), two equivalent O(2), two equivalent O(5), and four equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with six equivalent La(1)O12 cuboctahedra, corners with six equivalent La(2)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Co(2)O6 octahedra, faces with three equivalent Fe(1)O6 octahedra, and faces with three equivalent Co(1)O6 octahedra. In the second La site, La(2) is bonded to one O(7), one O(8), two equivalent O(1), two equivalent O(2), two equivalent O(6), and four equivalent O(3) atoms to form LaO12 cuboctahedra that share corners with six equivalent La(1)O12 cuboctahedra, corners with six equivalent La(2)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Co(1)O6 octahedra, faces with three equivalent Fe(2)O6 octahedra, and faces with three equivalent Co(2)O6 octahedra. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(5), one O(8), two equivalent O(2), and two equivalent O(4) atoms to form FeO6 octahedra that share corners with three equivalent Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra, and faces with three equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Fe site, Fe(2) is bonded to one O(6), one O(7), two equivalent O(1), and two equivalent O(3) atoms to form FeO6 octahedra that share corners with three equivalent Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(5), one O(7), two equivalent O(1), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with three equivalent Fe(1)O6 octahedra, corners with three equivalent Fe(2)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 1°. In the second Co site, Co(2) is bonded to one O(6), one O(8), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share corners with three equivalent Fe(1)O6 octahedra, corners with three equivalent Fe(2)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra, and faces with three equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent Sr(1), one La(1), one La(2), one Fe(2), and one Co(1) atom. In the second O site, O(2) is bonded to two equivalent Sr(2), one La(1), one La(2), one Fe(1), and one Co(2) atom to form a mixture of distorted corner and face-sharing OSr2La2FeCo octahedra. The corner-sharing octahedral tilt angles range from 2-60°. In the third O site, O(3) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), two equivalent La(2), one Fe(2), and one Co(2) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), two equivalent La(1), one Fe(1), and one Co(1) atom. In the fifth O site, O(5) is bonded to one Sr(1), one Sr(2), two equivalent La(1), one Fe(1), and one Co(1) atom to form a mixture of distorted edge, corner, and face-sharing OSr2La2FeCo octahedra. The corner-sharing octahedral tilt angles range from 1-60°. In the sixth O site, O(6) is bonded to one Sr(1), one Sr(2), two equivalent La(2), one Fe(2), and one Co(2) atom to form a mixture of distorted edge, corner, and face-sharing OSr2La2FeCo octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the seventh O site, O(7) is bonded in a distorted linear geometry to two equivalent Sr(1), one La(1), one La(2), one Fe(2), and one Co(1) atom. In the eighth O site, O(8) is bonded to two equivalent Sr(2), one La(1), one La(2), one Fe(1), and one Co(2) atom to form a mixture of distorted edge, corner, and face-sharing OSr2La2FeCo octahedra. The corner-sharing octahedral tilt angles range from 0-60°. is represented by the Crystallographic Information File (CIF) [CIF]
data_SrLaFeCoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.502
_cell_length_b   5.505
_cell_length_c   5.502
_cell_angle_alpha   60.012
_cell_angle_beta   60.001
_cell_angle_gamma   60.018
_symmetry_Int_Tables_number   1
_cell_volume   117.846
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.999  0.002  0.999  1.0
  Fe  Fe1  1  0.500  0.501  0.499  1.0
  La  La2  1  0.751  0.750  0.749  1.0
  O  O3  1  0.754  0.246  0.753  1.0
  O  O4  1  0.246  0.753  0.247  1.0
  O  O5  1  0.247  0.246  0.753  1.0
  O  O6  1  0.754  0.753  0.247  1.0
  O  O7  1  0.247  0.753  0.754  1.0
  O  O8  1  0.754  0.246  0.247  1.0
  Sr  Sr9  1  0.250  0.251  0.250  1.0
[/CIF]
.
The crystal structure described by SrLaFeCoO6 is (Cubic) Perovskite-derived structured and crystallizes in the monoclinic Cm space group. There are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded to one O(5), one O(6), two equivalent O(3), two equivalent O(4), two equivalent O(7), and four equivalent O(1) atoms to form SrO12 cuboctahedra that share corners with six equivalent Sr(1)O12 cuboctahedra, corners with six equivalent Sr(2)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, faces with three equivalent La(2)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Co(2)O6 octahedra, faces with three equivalent Fe(2)O6 octahedra, and faces with three equivalent Co(1)O6 octahedra. In the second Sr site, Sr(2) is bonded to one O(5), one O(6), two equivalent O(3), two equivalent O(4), two equivalent O(8), and four equivalent O(2) atoms to form SrO12 cuboctahedra that share corners with six equivalent Sr(1)O12 cuboctahedra, corners with six equivalent Sr(2)O12 cuboctahedra, faces with three equivalent La(1)O12 cuboctahedra, faces with three equivalent La(2)O12 cuboctahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Co(1)O6 octahedra, faces with three equivalent Fe(1)O6 octahedra, and faces with three equivalent Co(2)O6 octahedra. There are two inequivalent La sites. In the first La site, La(1) is bonded to one O(7), one O(8), two equivalent O(1), two equivalent O(2), two equivalent O(5), and four equivalent O(4) atoms to form LaO12 cuboctahedra that share corners with six equivalent La(1)O12 cuboctahedra, corners with six equivalent La(2)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra,  a faceface with one Fe(2)O6 octahedra,  a faceface with one Co(2)O6 octahedra, faces with three equivalent Fe(1)O6 octahedra, and faces with three equivalent Co(1)O6 octahedra. In the second La site, La(2) is bonded to one O(7), one O(8), two equivalent O(1), two equivalent O(2), two equivalent O(6), and four equivalent O(3) atoms to form LaO12 cuboctahedra that share corners with six equivalent La(1)O12 cuboctahedra, corners with six equivalent La(2)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra,  a faceface with one Fe(1)O6 octahedra,  a faceface with one Co(1)O6 octahedra, faces with three equivalent Fe(2)O6 octahedra, and faces with three equivalent Co(2)O6 octahedra. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(5), one O(8), two equivalent O(2), and two equivalent O(4) atoms to form FeO6 octahedra that share corners with three equivalent Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra, and faces with three equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the second Fe site, Fe(2) is bonded to one O(6), one O(7), two equivalent O(1), and two equivalent O(3) atoms to form FeO6 octahedra that share corners with three equivalent Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(5), one O(7), two equivalent O(1), and two equivalent O(4) atoms to form CoO6 octahedra that share corners with three equivalent Fe(1)O6 octahedra, corners with three equivalent Fe(2)O6 octahedra,  a faceface with one Sr(2)O12 cuboctahedra,  a faceface with one La(2)O12 cuboctahedra, faces with three equivalent Sr(1)O12 cuboctahedra, and faces with three equivalent La(1)O12 cuboctahedra. The corner-sharing octahedral tilt angles are 1°. In the second Co site, Co(2) is bonded to one O(6), one O(8), two equivalent O(2), and two equivalent O(3) atoms to form CoO6 octahedra that share corners with three equivalent Fe(1)O6 octahedra, corners with three equivalent Fe(2)O6 octahedra,  a faceface with one Sr(1)O12 cuboctahedra,  a faceface with one La(1)O12 cuboctahedra, faces with three equivalent Sr(2)O12 cuboctahedra, and faces with three equivalent La(2)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 0-1°. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to two equivalent Sr(1), one La(1), one La(2), one Fe(2), and one Co(1) atom. In the second O site, O(2) is bonded to two equivalent Sr(2), one La(1), one La(2), one Fe(1), and one Co(2) atom to form a mixture of distorted corner and face-sharing OSr2La2FeCo octahedra. The corner-sharing octahedral tilt angles range from 2-60°. In the third O site, O(3) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), two equivalent La(2), one Fe(2), and one Co(2) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Sr(1), one Sr(2), two equivalent La(1), one Fe(1), and one Co(1) atom. In the fifth O site, O(5) is bonded to one Sr(1), one Sr(2), two equivalent La(1), one Fe(1), and one Co(1) atom to form a mixture of distorted edge, corner, and face-sharing OSr2La2FeCo octahedra. The corner-sharing octahedral tilt angles range from 1-60°. In the sixth O site, O(6) is bonded to one Sr(1), one Sr(2), two equivalent La(2), one Fe(2), and one Co(2) atom to form a mixture of distorted edge, corner, and face-sharing OSr2La2FeCo octahedra. The corner-sharing octahedral tilt angles range from 0-60°. In the seventh O site, O(7) is bonded in a distorted linear geometry to two equivalent Sr(1), one La(1), one La(2), one Fe(2), and one Co(1) atom. In the eighth O site, O(8) is bonded to two equivalent Sr(2), one La(1), one La(2), one Fe(1), and one Co(2) atom to form a mixture of distorted edge, corner, and face-sharing OSr2La2FeCo octahedra. The corner-sharing octahedral tilt angles range from 0-60°. is represented by the Crystallographic Information File (CIF) [CIF]
data_SrLaFeCoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.502
_cell_length_b   5.505
_cell_length_c   5.502
_cell_angle_alpha   60.012
_cell_angle_beta   60.001
_cell_angle_gamma   60.018
_symmetry_Int_Tables_number   1
_cell_volume   117.846
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.999  0.002  0.999  1.0
  Fe  Fe1  1  0.500  0.501  0.499  1.0
  La  La2  1  0.751  0.750  0.749  1.0
  O  O3  1  0.754  0.246  0.753  1.0
  O  O4  1  0.246  0.753  0.247  1.0
  O  O5  1  0.247  0.246  0.753  1.0
  O  O6  1  0.754  0.753  0.247  1.0
  O  O7  1  0.247  0.753  0.754  1.0
  O  O8  1  0.754  0.246  0.247  1.0
  Sr  Sr9  1  0.250  0.251  0.250  1.0
[/CIF]
.