The material structure described by RbVH6SO9 crystallizes in the monoclinic P2_1 space group. Rb(1) is bonded in a 10-coordinate geometry to one O(1), one O(2), one O(4), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(3) atoms. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(7), and one O(9) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(8) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(8) atom. In the fifth H site, H(5) is bonded in a distorted linear geometry to one O(8) and one O(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(9) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(6) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one V(1), and one S(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Rb(1), one V(1), and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent Rb(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Rb(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Rb(1) and one V(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Rb(1) and one S(1) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Rb(1), one V(1), one H(1), and one H(2) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Rb(1), one H(3), one H(4), and one H(5) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Rb(1), one V(1), one H(5), and one H(6) atom. is represented by the CIF card [CIF]
data_RbVH6SO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.129
_cell_length_b   6.300
_cell_length_c   6.776
_cell_angle_alpha   71.949
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   411.159
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.651  0.696  0.815  1.0
  Rb  Rb1  1  0.151  0.304  0.185  1.0
  V  V2  1  0.499  0.383  0.383  1.0
  V  V3  1  0.999  0.617  0.617  1.0
  H  H4  1  0.578  0.190  0.821  1.0
  H  H5  1  0.209  0.772  0.308  1.0
  H  H6  1  0.854  0.970  0.304  1.0
  H  H7  1  0.709  0.228  0.692  1.0
  H  H8  1  0.354  0.030  0.696  1.0
  H  H9  1  0.078  0.810  0.179  1.0
  H  H10  1  0.351  0.879  0.927  1.0
  H  H11  1  0.761  0.311  0.263  1.0
  H  H12  1  0.261  0.471  0.657  1.0
  H  H13  1  0.851  0.121  0.073  1.0
  H  H14  1  0.761  0.529  0.343  1.0
  H  H15  1  0.261  0.689  0.737  1.0
  S  S16  1  0.998  0.078  0.733  1.0
  S  S17  1  0.498  0.922  0.267  1.0
  O  O18  1  0.041  0.934  0.601  1.0
  O  O19  1  0.531  0.689  0.409  1.0
  O  O20  1  0.939  0.539  0.855  1.0
  O  O21  1  0.439  0.461  0.145  1.0
  O  O22  1  0.575  0.977  0.076  1.0
  O  O23  1  0.541  0.066  0.399  1.0
  O  O24  1  0.864  0.677  0.463  1.0
  O  O25  1  0.855  0.059  0.773  1.0
  O  O26  1  0.618  0.285  0.690  1.0
  O  O27  1  0.355  0.941  0.227  1.0
  O  O28  1  0.364  0.323  0.537  1.0
  O  O29  1  0.360  0.873  0.785  1.0
  O  O30  1  0.031  0.311  0.591  1.0
  O  O31  1  0.705  0.437  0.280  1.0
  O  O32  1  0.075  0.023  0.924  1.0
  O  O33  1  0.118  0.715  0.310  1.0
  O  O34  1  0.860  0.127  0.215  1.0
  O  O35  1  0.205  0.563  0.720  1.0
[/CIF]
.
The material structure described by RbVH6SO9 crystallizes in the monoclinic P2_1 space group. Rb(1) is bonded in a 10-coordinate geometry to one O(1), one O(2), one O(4), one O(5), one O(6), one O(7), one O(8), one O(9), and two equivalent O(3) atoms. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(7), and one O(9) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(8) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(8) atom. In the fifth H site, H(5) is bonded in a distorted linear geometry to one O(8) and one O(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(9) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(4), and one O(6) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Rb(1), one V(1), and one S(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Rb(1), one V(1), and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent Rb(1) and one V(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Rb(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Rb(1) and one V(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Rb(1) and one S(1) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Rb(1), one V(1), one H(1), and one H(2) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Rb(1), one H(3), one H(4), and one H(5) atom. In the ninth O site, O(9) is bonded in a distorted water-like geometry to one Rb(1), one V(1), one H(5), and one H(6) atom. is represented by the CIF card [CIF]
data_RbVH6SO9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.129
_cell_length_b   6.300
_cell_length_c   6.776
_cell_angle_alpha   71.949
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   411.159
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.651  0.696  0.815  1.0
  Rb  Rb1  1  0.151  0.304  0.185  1.0
  V  V2  1  0.499  0.383  0.383  1.0
  V  V3  1  0.999  0.617  0.617  1.0
  H  H4  1  0.578  0.190  0.821  1.0
  H  H5  1  0.209  0.772  0.308  1.0
  H  H6  1  0.854  0.970  0.304  1.0
  H  H7  1  0.709  0.228  0.692  1.0
  H  H8  1  0.354  0.030  0.696  1.0
  H  H9  1  0.078  0.810  0.179  1.0
  H  H10  1  0.351  0.879  0.927  1.0
  H  H11  1  0.761  0.311  0.263  1.0
  H  H12  1  0.261  0.471  0.657  1.0
  H  H13  1  0.851  0.121  0.073  1.0
  H  H14  1  0.761  0.529  0.343  1.0
  H  H15  1  0.261  0.689  0.737  1.0
  S  S16  1  0.998  0.078  0.733  1.0
  S  S17  1  0.498  0.922  0.267  1.0
  O  O18  1  0.041  0.934  0.601  1.0
  O  O19  1  0.531  0.689  0.409  1.0
  O  O20  1  0.939  0.539  0.855  1.0
  O  O21  1  0.439  0.461  0.145  1.0
  O  O22  1  0.575  0.977  0.076  1.0
  O  O23  1  0.541  0.066  0.399  1.0
  O  O24  1  0.864  0.677  0.463  1.0
  O  O25  1  0.855  0.059  0.773  1.0
  O  O26  1  0.618  0.285  0.690  1.0
  O  O27  1  0.355  0.941  0.227  1.0
  O  O28  1  0.364  0.323  0.537  1.0
  O  O29  1  0.360  0.873  0.785  1.0
  O  O30  1  0.031  0.311  0.591  1.0
  O  O31  1  0.705  0.437  0.280  1.0
  O  O32  1  0.075  0.023  0.924  1.0
  O  O33  1  0.118  0.715  0.310  1.0
  O  O34  1  0.860  0.127  0.215  1.0
  O  O35  1  0.205  0.563  0.720  1.0
[/CIF]
.