The crystal structure described by KGaSb4 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 7-coordinate geometry to two equivalent Sb(2), two equivalent Sb(3), and three equivalent Sb(1) atoms. Ga(1) is bonded to one Sb(2), one Sb(3), and two equivalent Sb(1) atoms to form distorted corner-sharing GaSb4 tetrahedra. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 6-coordinate geometry to three equivalent K(1), two equivalent Ga(1), and one Sb(4) atom. In the second Sb site, Sb(2) is bonded in a 5-coordinate geometry to two equivalent K(1), one Ga(1), and two equivalent Sb(4) atoms. In the third Sb site, Sb(3) is bonded in a 5-coordinate geometry to two equivalent K(1), one Ga(1), and two equivalent Sb(3) atoms. In the fourth Sb site, Sb(4) is bonded in a 3-coordinate geometry to one Sb(1) and two equivalent Sb(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_KGaSb4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.243
_cell_length_b   10.503
_cell_length_c   17.994
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   801.816
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.750  0.180  0.434  1.0
  K  K1  1  0.250  0.820  0.566  1.0
  K  K2  1  0.750  0.680  0.066  1.0
  K  K3  1  0.250  0.320  0.934  1.0
  Ga  Ga4  1  0.750  0.317  0.631  1.0
  Ga  Ga5  1  0.250  0.683  0.369  1.0
  Ga  Ga6  1  0.750  0.817  0.869  1.0
  Ga  Ga7  1  0.250  0.183  0.131  1.0
  Sb  Sb8  1  0.750  0.829  0.398  1.0
  Sb  Sb9  1  0.250  0.171  0.602  1.0
  Sb  Sb10  1  0.750  0.329  0.102  1.0
  Sb  Sb11  1  0.250  0.671  0.898  1.0
  Sb  Sb12  1  0.750  0.388  0.773  1.0
  Sb  Sb13  1  0.250  0.612  0.227  1.0
  Sb  Sb14  1  0.750  0.888  0.727  1.0
  Sb  Sb15  1  0.250  0.112  0.273  1.0
  Sb  Sb16  1  0.750  0.533  0.551  1.0
  Sb  Sb17  1  0.250  0.467  0.449  1.0
  Sb  Sb18  1  0.750  0.033  0.949  1.0
  Sb  Sb19  1  0.250  0.967  0.051  1.0
  Sb  Sb20  1  0.750  0.930  0.251  1.0
  Sb  Sb21  1  0.250  0.070  0.749  1.0
  Sb  Sb22  1  0.750  0.430  0.249  1.0
  Sb  Sb23  1  0.250  0.570  0.751  1.0
[/CIF]
.
The crystal structure described by KGaSb4 crystallizes in the orthorhombic Pnma space group. K(1) is bonded in a 7-coordinate geometry to two equivalent Sb(2), two equivalent Sb(3), and three equivalent Sb(1) atoms. Ga(1) is bonded to one Sb(2), one Sb(3), and two equivalent Sb(1) atoms to form distorted corner-sharing GaSb4 tetrahedra. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 6-coordinate geometry to three equivalent K(1), two equivalent Ga(1), and one Sb(4) atom. In the second Sb site, Sb(2) is bonded in a 5-coordinate geometry to two equivalent K(1), one Ga(1), and two equivalent Sb(4) atoms. In the third Sb site, Sb(3) is bonded in a 5-coordinate geometry to two equivalent K(1), one Ga(1), and two equivalent Sb(3) atoms. In the fourth Sb site, Sb(4) is bonded in a 3-coordinate geometry to one Sb(1) and two equivalent Sb(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_KGaSb4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.243
_cell_length_b   10.503
_cell_length_c   17.994
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   801.816
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.750  0.180  0.434  1.0
  K  K1  1  0.250  0.820  0.566  1.0
  K  K2  1  0.750  0.680  0.066  1.0
  K  K3  1  0.250  0.320  0.934  1.0
  Ga  Ga4  1  0.750  0.317  0.631  1.0
  Ga  Ga5  1  0.250  0.683  0.369  1.0
  Ga  Ga6  1  0.750  0.817  0.869  1.0
  Ga  Ga7  1  0.250  0.183  0.131  1.0
  Sb  Sb8  1  0.750  0.829  0.398  1.0
  Sb  Sb9  1  0.250  0.171  0.602  1.0
  Sb  Sb10  1  0.750  0.329  0.102  1.0
  Sb  Sb11  1  0.250  0.671  0.898  1.0
  Sb  Sb12  1  0.750  0.388  0.773  1.0
  Sb  Sb13  1  0.250  0.612  0.227  1.0
  Sb  Sb14  1  0.750  0.888  0.727  1.0
  Sb  Sb15  1  0.250  0.112  0.273  1.0
  Sb  Sb16  1  0.750  0.533  0.551  1.0
  Sb  Sb17  1  0.250  0.467  0.449  1.0
  Sb  Sb18  1  0.750  0.033  0.949  1.0
  Sb  Sb19  1  0.250  0.967  0.051  1.0
  Sb  Sb20  1  0.750  0.930  0.251  1.0
  Sb  Sb21  1  0.250  0.070  0.749  1.0
  Sb  Sb22  1  0.750  0.430  0.249  1.0
  Sb  Sb23  1  0.250  0.570  0.751  1.0
[/CIF]
.