The material structure described by N2H6SO4 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four 1333-74-0 molecules, four ammonia molecules, and four NH3SO4 clusters. In each NH3SO4 cluster, N(1) is bonded in a distorted bent 120 degrees geometry to one H(3) and one H(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(4) atom. In the second H site, H(3) is bonded in a distorted single-bond geometry to one N(1) and one O(1) atom. In the third H site, H(6) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one H(3) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one H(1) and one S(1) atom. is represented by the CIF file [CIF]
data_H6S(NO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.622
_cell_length_b   8.243
_cell_length_c   10.204
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   557.017
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.049  0.860  0.878  1.0
  H  H1  1  0.549  0.640  0.122  1.0
  H  H2  1  0.951  0.360  0.622  1.0
  H  H3  1  0.451  0.140  0.378  1.0
  H  H4  1  0.651  0.966  0.951  1.0
  H  H5  1  0.151  0.534  0.049  1.0
  H  H6  1  0.349  0.466  0.549  1.0
  H  H7  1  0.849  0.034  0.451  1.0
  H  H8  1  0.594  0.025  0.742  1.0
  H  H9  1  0.094  0.475  0.258  1.0
  H  H10  1  0.406  0.525  0.758  1.0
  H  H11  1  0.906  0.975  0.242  1.0
  H  H12  1  0.051  0.201  0.773  1.0
  H  H13  1  0.551  0.299  0.227  1.0
  H  H14  1  0.949  0.701  0.727  1.0
  H  H15  1  0.449  0.799  0.273  1.0
  H  H16  1  0.027  0.269  0.819  1.0
  H  H17  1  0.527  0.231  0.181  1.0
  H  H18  1  0.973  0.769  0.681  1.0
  H  H19  1  0.473  0.731  0.319  1.0
  H  H20  1  0.651  0.231  0.780  1.0
  H  H21  1  0.151  0.269  0.220  1.0
  H  H22  1  0.349  0.731  0.720  1.0
  H  H23  1  0.849  0.769  0.280  1.0
  S  S24  1  0.316  0.078  0.565  1.0
  S  S25  1  0.816  0.422  0.435  1.0
  S  S26  1  0.684  0.578  0.935  1.0
  S  S27  1  0.184  0.922  0.065  1.0
  N  N28  1  0.642  0.113  0.813  1.0
  N  N29  1  0.142  0.387  0.187  1.0
  N  N30  1  0.358  0.613  0.687  1.0
  N  N31  1  0.858  0.887  0.313  1.0
  N  N32  1  0.672  0.089  0.931  1.0
  N  N33  1  0.172  0.411  0.069  1.0
  N  N34  1  0.328  0.589  0.569  1.0
  N  N35  1  0.828  0.911  0.431  1.0
  O  O36  1  0.469  0.958  0.606  1.0
  O  O37  1  0.969  0.542  0.394  1.0
  O  O38  1  0.531  0.458  0.894  1.0
  O  O39  1  0.031  0.042  0.106  1.0
  O  O40  1  0.109  0.024  0.588  1.0
  O  O41  1  0.609  0.476  0.412  1.0
  O  O42  1  0.891  0.524  0.912  1.0
  O  O43  1  0.391  0.976  0.088  1.0
  O  O44  1  0.362  0.242  0.613  1.0
  O  O45  1  0.862  0.258  0.387  1.0
  O  O46  1  0.638  0.742  0.887  1.0
  O  O47  1  0.138  0.758  0.113  1.0
  O  O48  1  0.325  0.086  0.406  1.0
  O  O49  1  0.825  0.414  0.594  1.0
  O  O50  1  0.675  0.586  0.094  1.0
  O  O51  1  0.175  0.914  0.906  1.0
[/CIF]
.
The material structure described by N2H6SO4 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four 1333-74-0 molecules, four ammonia molecules, and four NH3SO4 clusters. In each NH3SO4 cluster, N(1) is bonded in a distorted bent 120 degrees geometry to one H(3) and one H(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(4) atom. In the second H site, H(3) is bonded in a distorted single-bond geometry to one N(1) and one O(1) atom. In the third H site, H(6) is bonded in a single-bond geometry to one N(1) atom. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one H(3) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one H(1) and one S(1) atom. is represented by the CIF file [CIF]
data_H6S(NO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.622
_cell_length_b   8.243
_cell_length_c   10.204
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   557.017
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.049  0.860  0.878  1.0
  H  H1  1  0.549  0.640  0.122  1.0
  H  H2  1  0.951  0.360  0.622  1.0
  H  H3  1  0.451  0.140  0.378  1.0
  H  H4  1  0.651  0.966  0.951  1.0
  H  H5  1  0.151  0.534  0.049  1.0
  H  H6  1  0.349  0.466  0.549  1.0
  H  H7  1  0.849  0.034  0.451  1.0
  H  H8  1  0.594  0.025  0.742  1.0
  H  H9  1  0.094  0.475  0.258  1.0
  H  H10  1  0.406  0.525  0.758  1.0
  H  H11  1  0.906  0.975  0.242  1.0
  H  H12  1  0.051  0.201  0.773  1.0
  H  H13  1  0.551  0.299  0.227  1.0
  H  H14  1  0.949  0.701  0.727  1.0
  H  H15  1  0.449  0.799  0.273  1.0
  H  H16  1  0.027  0.269  0.819  1.0
  H  H17  1  0.527  0.231  0.181  1.0
  H  H18  1  0.973  0.769  0.681  1.0
  H  H19  1  0.473  0.731  0.319  1.0
  H  H20  1  0.651  0.231  0.780  1.0
  H  H21  1  0.151  0.269  0.220  1.0
  H  H22  1  0.349  0.731  0.720  1.0
  H  H23  1  0.849  0.769  0.280  1.0
  S  S24  1  0.316  0.078  0.565  1.0
  S  S25  1  0.816  0.422  0.435  1.0
  S  S26  1  0.684  0.578  0.935  1.0
  S  S27  1  0.184  0.922  0.065  1.0
  N  N28  1  0.642  0.113  0.813  1.0
  N  N29  1  0.142  0.387  0.187  1.0
  N  N30  1  0.358  0.613  0.687  1.0
  N  N31  1  0.858  0.887  0.313  1.0
  N  N32  1  0.672  0.089  0.931  1.0
  N  N33  1  0.172  0.411  0.069  1.0
  N  N34  1  0.328  0.589  0.569  1.0
  N  N35  1  0.828  0.911  0.431  1.0
  O  O36  1  0.469  0.958  0.606  1.0
  O  O37  1  0.969  0.542  0.394  1.0
  O  O38  1  0.531  0.458  0.894  1.0
  O  O39  1  0.031  0.042  0.106  1.0
  O  O40  1  0.109  0.024  0.588  1.0
  O  O41  1  0.609  0.476  0.412  1.0
  O  O42  1  0.891  0.524  0.912  1.0
  O  O43  1  0.391  0.976  0.088  1.0
  O  O44  1  0.362  0.242  0.613  1.0
  O  O45  1  0.862  0.258  0.387  1.0
  O  O46  1  0.638  0.742  0.887  1.0
  O  O47  1  0.138  0.758  0.113  1.0
  O  O48  1  0.325  0.086  0.406  1.0
  O  O49  1  0.825  0.414  0.594  1.0
  O  O50  1  0.675  0.586  0.094  1.0
  O  O51  1  0.175  0.914  0.906  1.0
[/CIF]
.