The structure described by V3CP crystallizes in the orthorhombic Cmcm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to two equivalent C(1) and three equivalent P(1) atoms. In the second V site, V(2) is bonded in a 4-coordinate geometry to two equivalent C(1) and two equivalent P(1) atoms. C(1) is bonded to two equivalent V(2) and four equivalent V(1) atoms to form a mixture of corner and edge-sharing CV6 octahedra. The corner-sharing octahedral tilt angles are 37°. P(1) is bonded in a 8-coordinate geometry to two equivalent V(2) and six equivalent V(1) atoms. is represented by the CIF file [CIF]
data_V3PC
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.056
_cell_length_b   5.056
_cell_length_c   7.491
_cell_angle_alpha   89.998
_cell_angle_beta   90.002
_cell_angle_gamma   144.121
_symmetry_Int_Tables_number   1
_cell_volume   112.254
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.635  0.365  0.445  1.0
  V  V1  1  0.365  0.635  0.555  1.0
  V  V2  1  0.635  0.365  0.055  1.0
  V  V3  1  0.365  0.635  0.945  1.0
  V  V4  1  0.936  0.064  0.250  1.0
  V  V5  1  0.064  0.936  0.750  1.0
  P  P6  1  0.254  0.746  0.250  1.0
  P  P7  1  0.746  0.254  0.750  1.0
  C  C8  1  0.000  1.000  0.500  1.0
  C  C9  1  0.000  1.000  0.000  1.0
[/CIF]
.
The structure described by V3CP crystallizes in the orthorhombic Cmcm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to two equivalent C(1) and three equivalent P(1) atoms. In the second V site, V(2) is bonded in a 4-coordinate geometry to two equivalent C(1) and two equivalent P(1) atoms. C(1) is bonded to two equivalent V(2) and four equivalent V(1) atoms to form a mixture of corner and edge-sharing CV6 octahedra. The corner-sharing octahedral tilt angles are 37°. P(1) is bonded in a 8-coordinate geometry to two equivalent V(2) and six equivalent V(1) atoms. is represented by the CIF file [CIF]
data_V3PC
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.056
_cell_length_b   5.056
_cell_length_c   7.491
_cell_angle_alpha   89.998
_cell_angle_beta   90.002
_cell_angle_gamma   144.121
_symmetry_Int_Tables_number   1
_cell_volume   112.254
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.635  0.365  0.445  1.0
  V  V1  1  0.365  0.635  0.555  1.0
  V  V2  1  0.635  0.365  0.055  1.0
  V  V3  1  0.365  0.635  0.945  1.0
  V  V4  1  0.936  0.064  0.250  1.0
  V  V5  1  0.064  0.936  0.750  1.0
  P  P6  1  0.254  0.746  0.250  1.0
  P  P7  1  0.746  0.254  0.750  1.0
  C  C8  1  0.000  1.000  0.500  1.0
  C  C9  1  0.000  1.000  0.000  1.0
[/CIF]
.