The material described by MnSb2O6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31m space group. Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with twelve equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. O(1) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn(SbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.630
_cell_length_b   5.213
_cell_length_c   5.213
_cell_angle_alpha   60.018
_cell_angle_beta   90.022
_cell_angle_gamma   90.026
_symmetry_Int_Tables_number   1
_cell_volume   108.984
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  1.000  0.000  1.000  1.0
  O  O1  1  0.732  0.356  0.644  1.0
  O  O2  1  0.732  0.644  0.000  1.0
  O  O3  1  0.732  0.000  0.356  1.0
  O  O4  1  0.268  0.644  0.356  1.0
  O  O5  1  0.268  0.356  1.000  1.0
  O  O6  1  0.268  1.000  0.644  1.0
  Sb  Sb7  1  0.500  0.667  0.667  1.0
  Sb  Sb8  1  0.500  0.333  0.333  1.0
[/CIF]
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The material described by MnSb2O6 is Hydrophilite-derived structured and crystallizes in the trigonal P-31m space group. Mn(1) is bonded to six equivalent O(1) atoms to form MnO6 octahedra that share corners with twelve equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. Sb(1) is bonded to six equivalent O(1) atoms to form SbO6 octahedra that share corners with six equivalent Mn(1)O6 octahedra and edges with three equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles are 52°. O(1) is bonded in a trigonal planar geometry to one Mn(1) and two equivalent Sb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Mn(SbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.630
_cell_length_b   5.213
_cell_length_c   5.213
_cell_angle_alpha   60.018
_cell_angle_beta   90.022
_cell_angle_gamma   90.026
_symmetry_Int_Tables_number   1
_cell_volume   108.984
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  1.000  0.000  1.000  1.0
  O  O1  1  0.732  0.356  0.644  1.0
  O  O2  1  0.732  0.644  0.000  1.0
  O  O3  1  0.732  0.000  0.356  1.0
  O  O4  1  0.268  0.644  0.356  1.0
  O  O5  1  0.268  0.356  1.000  1.0
  O  O6  1  0.268  1.000  0.644  1.0
  Sb  Sb7  1  0.500  0.667  0.667  1.0
  Sb  Sb8  1  0.500  0.333  0.333  1.0
[/CIF]
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