The crystal structure described by RbCOF3 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 10-coordinate geometry to three equivalent O(1), one F(3), three equivalent F(1), and three equivalent F(2) atoms. C(1) is bonded in a tetrahedral geometry to one O(1), one F(1), one F(2), and one F(3) atom. O(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one C(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to three equivalent Rb(1) and one C(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Rb(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbCOF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.438
_cell_length_b   5.743
_cell_length_c   9.013
_cell_angle_alpha   89.832
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   385.023
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.657  0.257  0.179  1.0
  Rb  Rb1  1  0.343  0.743  0.821  1.0
  Rb  Rb2  1  0.157  0.743  0.321  1.0
  Rb  Rb3  1  0.843  0.257  0.679  1.0
  C  C4  1  0.203  0.273  0.067  1.0
  C  C5  1  0.797  0.727  0.933  1.0
  C  C6  1  0.703  0.727  0.433  1.0
  C  C7  1  0.297  0.273  0.567  1.0
  O  O8  1  0.298  0.446  0.082  1.0
  O  O9  1  0.702  0.554  0.918  1.0
  O  O10  1  0.798  0.554  0.418  1.0
  O  O11  1  0.202  0.446  0.582  1.0
  F  F12  1  0.059  0.241  0.172  1.0
  F  F13  1  0.941  0.759  0.828  1.0
  F  F14  1  0.559  0.759  0.328  1.0
  F  F15  1  0.441  0.241  0.672  1.0
  F  F16  1  0.296  0.047  0.082  1.0
  F  F17  1  0.704  0.953  0.918  1.0
  F  F18  1  0.796  0.953  0.418  1.0
  F  F19  1  0.204  0.047  0.582  1.0
  F  F20  1  0.386  0.242  0.428  1.0
  F  F21  1  0.614  0.758  0.572  1.0
  F  F22  1  0.886  0.758  0.072  1.0
  F  F23  1  0.114  0.242  0.928  1.0
[/CIF]
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The crystal structure described by RbCOF3 crystallizes in the monoclinic P2_1/c space group. Rb(1) is bonded in a 10-coordinate geometry to three equivalent O(1), one F(3), three equivalent F(1), and three equivalent F(2) atoms. C(1) is bonded in a tetrahedral geometry to one O(1), one F(1), one F(2), and one F(3) atom. O(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one C(1) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one C(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to three equivalent Rb(1) and one C(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Rb(1) and one C(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbCOF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.438
_cell_length_b   5.743
_cell_length_c   9.013
_cell_angle_alpha   89.832
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   385.023
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.657  0.257  0.179  1.0
  Rb  Rb1  1  0.343  0.743  0.821  1.0
  Rb  Rb2  1  0.157  0.743  0.321  1.0
  Rb  Rb3  1  0.843  0.257  0.679  1.0
  C  C4  1  0.203  0.273  0.067  1.0
  C  C5  1  0.797  0.727  0.933  1.0
  C  C6  1  0.703  0.727  0.433  1.0
  C  C7  1  0.297  0.273  0.567  1.0
  O  O8  1  0.298  0.446  0.082  1.0
  O  O9  1  0.702  0.554  0.918  1.0
  O  O10  1  0.798  0.554  0.418  1.0
  O  O11  1  0.202  0.446  0.582  1.0
  F  F12  1  0.059  0.241  0.172  1.0
  F  F13  1  0.941  0.759  0.828  1.0
  F  F14  1  0.559  0.759  0.328  1.0
  F  F15  1  0.441  0.241  0.672  1.0
  F  F16  1  0.296  0.047  0.082  1.0
  F  F17  1  0.704  0.953  0.918  1.0
  F  F18  1  0.796  0.953  0.418  1.0
  F  F19  1  0.204  0.047  0.582  1.0
  F  F20  1  0.386  0.242  0.428  1.0
  F  F21  1  0.614  0.758  0.572  1.0
  F  F22  1  0.886  0.758  0.072  1.0
  F  F23  1  0.114  0.242  0.928  1.0
[/CIF]
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