The compound described by CsYbCoS3 crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded in a 8-coordinate geometry to two equivalent S(2) and six equivalent S(1) atoms. Yb(1) is bonded to two equivalent S(2) and four equivalent S(1) atoms to form YbS6 octahedra that share corners with two equivalent Yb(1)S6 octahedra, edges with two equivalent Yb(1)S6 octahedra, and edges with four equivalent Co(1)S4 tetrahedra. The corner-sharing octahedral tilt angles are 28°. Co(1) is bonded to two equivalent S(1) and two equivalent S(2) atoms to form CoS4 tetrahedra that share corners with two equivalent Co(1)S4 tetrahedra and edges with four equivalent Yb(1)S6 octahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 6-coordinate geometry to three equivalent Cs(1), two equivalent Yb(1), and one Co(1) atom. In the second S site, S(2) is bonded in a 6-coordinate geometry to two equivalent Cs(1), two equivalent Yb(1), and two equivalent Co(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsYbCoS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.061
_cell_length_b   8.061
_cell_length_c   10.836
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   151.362
_symmetry_Int_Tables_number   1
_cell_volume   337.472
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.264  0.736  0.750  1.0
  Cs  Cs1  1  0.736  0.264  0.250  1.0
  Yb  Yb2  1  0.000  0.000  0.000  1.0
  Yb  Yb3  1  0.000  0.000  0.500  1.0
  Co  Co4  1  0.541  0.459  0.750  1.0
  Co  Co5  1  0.459  0.541  0.250  1.0
  S  S6  1  0.614  0.386  0.921  1.0
  S  S7  1  0.957  0.043  0.750  1.0
  S  S8  1  0.043  0.957  0.250  1.0
  S  S9  1  0.386  0.614  0.079  1.0
  S  S10  1  0.386  0.614  0.421  1.0
  S  S11  1  0.614  0.386  0.579  1.0
[/CIF]
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The compound described by CsYbCoS3 crystallizes in the orthorhombic Cmcm space group. Cs(1) is bonded in a 8-coordinate geometry to two equivalent S(2) and six equivalent S(1) atoms. Yb(1) is bonded to two equivalent S(2) and four equivalent S(1) atoms to form YbS6 octahedra that share corners with two equivalent Yb(1)S6 octahedra, edges with two equivalent Yb(1)S6 octahedra, and edges with four equivalent Co(1)S4 tetrahedra. The corner-sharing octahedral tilt angles are 28°. Co(1) is bonded to two equivalent S(1) and two equivalent S(2) atoms to form CoS4 tetrahedra that share corners with two equivalent Co(1)S4 tetrahedra and edges with four equivalent Yb(1)S6 octahedra. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 6-coordinate geometry to three equivalent Cs(1), two equivalent Yb(1), and one Co(1) atom. In the second S site, S(2) is bonded in a 6-coordinate geometry to two equivalent Cs(1), two equivalent Yb(1), and two equivalent Co(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsYbCoS3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.061
_cell_length_b   8.061
_cell_length_c   10.836
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   151.362
_symmetry_Int_Tables_number   1
_cell_volume   337.472
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.264  0.736  0.750  1.0
  Cs  Cs1  1  0.736  0.264  0.250  1.0
  Yb  Yb2  1  0.000  0.000  0.000  1.0
  Yb  Yb3  1  0.000  0.000  0.500  1.0
  Co  Co4  1  0.541  0.459  0.750  1.0
  Co  Co5  1  0.459  0.541  0.250  1.0
  S  S6  1  0.614  0.386  0.921  1.0
  S  S7  1  0.957  0.043  0.750  1.0
  S  S8  1  0.043  0.957  0.250  1.0
  S  S9  1  0.386  0.614  0.079  1.0
  S  S10  1  0.386  0.614  0.421  1.0
  S  S11  1  0.614  0.386  0.579  1.0
[/CIF]
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