The material structure described by LiLa4CoO8 is (La,Ba)CuO4-derived structured and crystallizes in the orthorhombic Fdd2 space group. Li(1) is bonded to two equivalent O(1) and four O(3,3,3) atoms to form LiO6 octahedra that share corners with four equivalent Co(1)O6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to two equivalent O(1); three equivalent O(2); and four O(3,3,3) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to two equivalent O(2); three equivalent O(1); and four O(3,3,3) atoms. Co(1) is bonded to two equivalent O(2) and four O(3,3,3) atoms to form CoO6 octahedra that share corners with four equivalent Li(1)O6 octahedra. The corner-sharing octahedra are not tilted. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), two equivalent La(1), and three equivalent La(2) atoms to form distorted OLiLa5 octahedra that share corners with five equivalent O(1)LiLa5 octahedra; corners with twelve O(3,3,3)LiLa4Co octahedra; edges with two equivalent O(1)LiLa5 octahedra; edges with six equivalent O(2)La5Co octahedra; and faces with four O(3,3,3)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the second O site, O(2) is bonded to two equivalent La(2), three equivalent La(1), and one Co(1) atom to form distorted OLa5Co octahedra that share corners with five equivalent O(2)La5Co octahedra; corners with twelve O(3,3,3)LiLa4Co octahedra; edges with two equivalent O(2)La5Co octahedra; edges with six equivalent O(1)LiLa5 octahedra; and faces with four O(3,3,3)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the third O site, O(3) is bonded to one Li(1), two equivalent La(1), two equivalent La(2), and one Co(1) atom to form distorted OLiLa4Co octahedra that share corners with two equivalent O(3)LiLa4Co octahedra; corners with six equivalent O(2)La5Co octahedra; corners with six equivalent O(1)LiLa5 octahedra; edges with two equivalent O(3)LiLa4Co octahedra; faces with two equivalent O(2)La5Co octahedra; faces with two equivalent O(1)LiLa5 octahedra; and faces with four O(3,3)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the fourth O site, O(3) is bonded to one Li(1), two equivalent La(1), two equivalent La(2), and one Co(1) atom to form distorted OLiLa4Co octahedra that share corners with two equivalent O(3)LiLa4Co octahedra, corners with six equivalent O(2)La5Co octahedra, corners with six equivalent O(1)LiLa5 octahedra, edges with two equivalent O(3)LiLa4Co octahedra, faces with two equivalent O(2)La5Co octahedra, faces with two equivalent O(1)LiLa5 octahedra, and faces with four equivalent O(3)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the fifth O site, O(3) is bonded to one Li(1), two equivalent La(1), two equivalent La(2), and one Co(1) atom to form distorted OLiLa4Co octahedra that share corners with two equivalent O(3)LiLa4Co octahedra, corners with six equivalent O(2)La5Co octahedra, corners with six equivalent O(1)LiLa5 octahedra, edges with two equivalent O(3)LiLa4Co octahedra, faces with two equivalent O(2)La5Co octahedra, faces with two equivalent O(1)LiLa5 octahedra, and faces with four equivalent O(3)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. is represented by the CIF card [CIF]
data_LiLa4CoO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.344
_cell_length_b   5.344
_cell_length_c   13.491
_cell_angle_alpha   101.385
_cell_angle_beta   101.384
_cell_angle_gamma   90.036
_symmetry_Int_Tables_number   1
_cell_volume   369.952
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  0.000  1.0
  Co  Co1  1  0.250  0.750  0.500  1.0
  La  La2  1  0.319  0.318  0.637  1.0
  La  La3  1  0.432  0.930  0.863  1.0
  La  La4  1  0.068  0.569  0.137  1.0
  La  La5  1  0.680  0.682  0.363  1.0
  La  La6  1  0.180  0.181  0.361  1.0
  La  La7  1  0.569  0.071  0.139  1.0
  La  La8  1  0.931  0.430  0.861  1.0
  La  La9  1  0.821  0.819  0.639  1.0
  Li  Li10  1  0.000  0.000  0.000  1.0
  Li  Li11  1  0.750  0.250  0.500  1.0
  O  O12  1  0.090  0.090  0.181  1.0
  O  O13  1  0.840  0.340  0.681  1.0
  O  O14  1  0.660  0.160  0.319  1.0
  O  O15  1  0.910  0.910  0.819  1.0
  O  O16  1  0.410  0.410  0.820  1.0
  O  O17  1  0.339  0.840  0.680  1.0
  O  O18  1  0.161  0.660  0.320  1.0
  O  O19  1  0.590  0.590  0.180  1.0
  O  O20  1  0.495  0.505  0.500  1.0
  O  O21  1  0.745  0.745  0.000  1.0
  O  O22  1  0.255  0.745  1.000  1.0
  O  O23  1  0.495  0.995  0.500  1.0
  O  O24  1  0.745  0.255  0.000  1.0
  O  O25  1  0.005  0.506  0.500  1.0
  O  O26  1  0.255  0.255  0.000  1.0
  O  O27  1  0.005  0.995  0.500  1.0
[/CIF]
.
The material structure described by LiLa4CoO8 is (La,Ba)CuO4-derived structured and crystallizes in the orthorhombic Fdd2 space group. Li(1) is bonded to two equivalent O(1) and four O(3,3,3) atoms to form LiO6 octahedra that share corners with four equivalent Co(1)O6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to two equivalent O(1); three equivalent O(2); and four O(3,3,3) atoms. In the second La site, La(2) is bonded in a 9-coordinate geometry to two equivalent O(2); three equivalent O(1); and four O(3,3,3) atoms. Co(1) is bonded to two equivalent O(2) and four O(3,3,3) atoms to form CoO6 octahedra that share corners with four equivalent Li(1)O6 octahedra. The corner-sharing octahedra are not tilted. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), two equivalent La(1), and three equivalent La(2) atoms to form distorted OLiLa5 octahedra that share corners with five equivalent O(1)LiLa5 octahedra; corners with twelve O(3,3,3)LiLa4Co octahedra; edges with two equivalent O(1)LiLa5 octahedra; edges with six equivalent O(2)La5Co octahedra; and faces with four O(3,3,3)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the second O site, O(2) is bonded to two equivalent La(2), three equivalent La(1), and one Co(1) atom to form distorted OLa5Co octahedra that share corners with five equivalent O(2)La5Co octahedra; corners with twelve O(3,3,3)LiLa4Co octahedra; edges with two equivalent O(2)La5Co octahedra; edges with six equivalent O(1)LiLa5 octahedra; and faces with four O(3,3,3)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-50°. In the third O site, O(3) is bonded to one Li(1), two equivalent La(1), two equivalent La(2), and one Co(1) atom to form distorted OLiLa4Co octahedra that share corners with two equivalent O(3)LiLa4Co octahedra; corners with six equivalent O(2)La5Co octahedra; corners with six equivalent O(1)LiLa5 octahedra; edges with two equivalent O(3)LiLa4Co octahedra; faces with two equivalent O(2)La5Co octahedra; faces with two equivalent O(1)LiLa5 octahedra; and faces with four O(3,3)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the fourth O site, O(3) is bonded to one Li(1), two equivalent La(1), two equivalent La(2), and one Co(1) atom to form distorted OLiLa4Co octahedra that share corners with two equivalent O(3)LiLa4Co octahedra, corners with six equivalent O(2)La5Co octahedra, corners with six equivalent O(1)LiLa5 octahedra, edges with two equivalent O(3)LiLa4Co octahedra, faces with two equivalent O(2)La5Co octahedra, faces with two equivalent O(1)LiLa5 octahedra, and faces with four equivalent O(3)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. In the fifth O site, O(3) is bonded to one Li(1), two equivalent La(1), two equivalent La(2), and one Co(1) atom to form distorted OLiLa4Co octahedra that share corners with two equivalent O(3)LiLa4Co octahedra, corners with six equivalent O(2)La5Co octahedra, corners with six equivalent O(1)LiLa5 octahedra, edges with two equivalent O(3)LiLa4Co octahedra, faces with two equivalent O(2)La5Co octahedra, faces with two equivalent O(1)LiLa5 octahedra, and faces with four equivalent O(3)LiLa4Co octahedra. The corner-sharing octahedral tilt angles range from 0-51°. is represented by the CIF card [CIF]
data_LiLa4CoO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.344
_cell_length_b   5.344
_cell_length_c   13.491
_cell_angle_alpha   101.385
_cell_angle_beta   101.384
_cell_angle_gamma   90.036
_symmetry_Int_Tables_number   1
_cell_volume   369.952
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.500  0.500  0.000  1.0
  Co  Co1  1  0.250  0.750  0.500  1.0
  La  La2  1  0.319  0.318  0.637  1.0
  La  La3  1  0.432  0.930  0.863  1.0
  La  La4  1  0.068  0.569  0.137  1.0
  La  La5  1  0.680  0.682  0.363  1.0
  La  La6  1  0.180  0.181  0.361  1.0
  La  La7  1  0.569  0.071  0.139  1.0
  La  La8  1  0.931  0.430  0.861  1.0
  La  La9  1  0.821  0.819  0.639  1.0
  Li  Li10  1  0.000  0.000  0.000  1.0
  Li  Li11  1  0.750  0.250  0.500  1.0
  O  O12  1  0.090  0.090  0.181  1.0
  O  O13  1  0.840  0.340  0.681  1.0
  O  O14  1  0.660  0.160  0.319  1.0
  O  O15  1  0.910  0.910  0.819  1.0
  O  O16  1  0.410  0.410  0.820  1.0
  O  O17  1  0.339  0.840  0.680  1.0
  O  O18  1  0.161  0.660  0.320  1.0
  O  O19  1  0.590  0.590  0.180  1.0
  O  O20  1  0.495  0.505  0.500  1.0
  O  O21  1  0.745  0.745  0.000  1.0
  O  O22  1  0.255  0.745  1.000  1.0
  O  O23  1  0.495  0.995  0.500  1.0
  O  O24  1  0.745  0.255  0.000  1.0
  O  O25  1  0.005  0.506  0.500  1.0
  O  O26  1  0.255  0.255  0.000  1.0
  O  O27  1  0.005  0.995  0.500  1.0
[/CIF]
.