The structure described by KC2PH6(NO)4 crystallizes in the orthorhombic Fdd2 space group. K(1) is bonded in a distorted body-centered cubic geometry to four equivalent O(1) and four equivalent O(2) atoms. C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(1) atom. P(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent O(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one P(1), and one H(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent K(1) and one P(1) atom. is represented by the CIF file [CIF]
data_KPH6C2(NO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.761
_cell_length_b   7.761
_cell_length_c   8.278
_cell_angle_alpha   114.970
_cell_angle_beta   114.970
_cell_angle_gamma   95.713
_symmetry_Int_Tables_number   1
_cell_volume   385.646
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.679  0.321  0.000  1.0
  K  K1  1  0.429  0.571  0.500  1.0
  P  P2  1  0.109  0.891  0.500  1.0
  P  P3  1  0.359  0.641  0.000  1.0
  H  H4  1  0.823  0.918  0.971  1.0
  H  H5  1  0.082  0.177  0.029  1.0
  H  H6  1  0.803  0.397  0.471  1.0
  H  H7  1  0.603  0.197  0.529  1.0
  H  H8  1  0.872  0.786  0.105  1.0
  H  H9  1  0.214  0.128  0.895  1.0
  H  H10  1  0.069  0.482  0.605  1.0
  H  H11  1  0.518  0.931  0.395  1.0
  H  H12  1  0.221  0.230  0.589  1.0
  H  H13  1  0.770  0.779  0.411  1.0
  H  H14  1  0.109  0.617  0.089  1.0
  H  H15  1  0.383  0.891  0.911  1.0
  C  C16  1  0.024  0.091  0.280  1.0
  C  C17  1  0.909  0.976  0.720  1.0
  C  C18  1  0.938  0.506  0.780  1.0
  C  C19  1  0.494  0.062  0.220  1.0
  N  N20  1  0.128  0.089  0.460  1.0
  N  N21  1  0.911  0.872  0.540  1.0
  N  N22  1  0.122  0.583  0.960  1.0
  N  N23  1  0.417  0.878  0.040  1.0
  N  N24  1  0.879  0.919  0.108  1.0
  N  N25  1  0.081  0.121  0.892  1.0
  N  N26  1  0.939  0.479  0.608  1.0
  N  N27  1  0.521  0.061  0.392  1.0
  O  O28  1  0.063  0.252  0.277  1.0
  O  O29  1  0.748  0.937  0.723  1.0
  O  O30  1  0.775  0.464  0.777  1.0
  O  O31  1  0.536  0.225  0.223  1.0
  O  O32  1  0.303  0.955  0.698  1.0
  O  O33  1  0.045  0.697  0.302  1.0
  O  O34  1  0.493  0.645  0.198  1.0
  O  O35  1  0.355  0.507  0.802  1.0
[/CIF]
.
The structure described by KC2PH6(NO)4 crystallizes in the orthorhombic Fdd2 space group. K(1) is bonded in a distorted body-centered cubic geometry to four equivalent O(1) and four equivalent O(2) atoms. C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(1) atom. P(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent O(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one P(1), and one H(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(2) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent K(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to two equivalent K(1) and one P(1) atom. is represented by the CIF file [CIF]
data_KPH6C2(NO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.761
_cell_length_b   7.761
_cell_length_c   8.278
_cell_angle_alpha   114.970
_cell_angle_beta   114.970
_cell_angle_gamma   95.713
_symmetry_Int_Tables_number   1
_cell_volume   385.646
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.679  0.321  0.000  1.0
  K  K1  1  0.429  0.571  0.500  1.0
  P  P2  1  0.109  0.891  0.500  1.0
  P  P3  1  0.359  0.641  0.000  1.0
  H  H4  1  0.823  0.918  0.971  1.0
  H  H5  1  0.082  0.177  0.029  1.0
  H  H6  1  0.803  0.397  0.471  1.0
  H  H7  1  0.603  0.197  0.529  1.0
  H  H8  1  0.872  0.786  0.105  1.0
  H  H9  1  0.214  0.128  0.895  1.0
  H  H10  1  0.069  0.482  0.605  1.0
  H  H11  1  0.518  0.931  0.395  1.0
  H  H12  1  0.221  0.230  0.589  1.0
  H  H13  1  0.770  0.779  0.411  1.0
  H  H14  1  0.109  0.617  0.089  1.0
  H  H15  1  0.383  0.891  0.911  1.0
  C  C16  1  0.024  0.091  0.280  1.0
  C  C17  1  0.909  0.976  0.720  1.0
  C  C18  1  0.938  0.506  0.780  1.0
  C  C19  1  0.494  0.062  0.220  1.0
  N  N20  1  0.128  0.089  0.460  1.0
  N  N21  1  0.911  0.872  0.540  1.0
  N  N22  1  0.122  0.583  0.960  1.0
  N  N23  1  0.417  0.878  0.040  1.0
  N  N24  1  0.879  0.919  0.108  1.0
  N  N25  1  0.081  0.121  0.892  1.0
  N  N26  1  0.939  0.479  0.608  1.0
  N  N27  1  0.521  0.061  0.392  1.0
  O  O28  1  0.063  0.252  0.277  1.0
  O  O29  1  0.748  0.937  0.723  1.0
  O  O30  1  0.775  0.464  0.777  1.0
  O  O31  1  0.536  0.225  0.223  1.0
  O  O32  1  0.303  0.955  0.698  1.0
  O  O33  1  0.045  0.697  0.302  1.0
  O  O34  1  0.493  0.645  0.198  1.0
  O  O35  1  0.355  0.507  0.802  1.0
[/CIF]
.