The crystal structure described by WAgSbO7 crystallizes in the orthorhombic Imma space group. W(1) is bonded to two equivalent O(3) and four equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-40°. Ag(1) is bonded in a distorted linear geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(4) atoms. Sb(1) is bonded to two equivalent O(2) and four equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Ag(1) atoms. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one W(1), one Ag(1), and one Sb(1) atom. is represented by the CIF card [CIF]
data_AgSbWO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.380
_cell_length_b   7.380
_cell_length_c   7.380
_cell_angle_alpha   120.933
_cell_angle_beta   119.628
_cell_angle_gamma   89.519
_symmetry_Int_Tables_number   1
_cell_volume   283.010
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.500  0.500  1.0
  Ag  Ag1  1  0.500  0.000  0.000  1.0
  Sb  Sb2  1  0.000  0.000  0.000  1.0
  Sb  Sb3  1  0.500  0.000  0.500  1.0
  W  W4  1  0.000  0.000  0.500  1.0
  W  W5  1  0.000  0.500  0.000  1.0
  O  O6  1  0.419  0.669  0.750  1.0
  O  O7  1  0.581  0.331  0.250  1.0
  O  O8  1  0.326  0.076  0.250  1.0
  O  O9  1  0.943  0.693  0.250  1.0
  O  O10  1  0.311  0.681  0.245  1.0
  O  O11  1  0.936  0.066  0.255  1.0
  O  O12  1  0.311  0.066  0.630  1.0
  O  O13  1  0.936  0.681  0.870  1.0
  O  O14  1  0.674  0.924  0.750  1.0
  O  O15  1  0.057  0.307  0.750  1.0
  O  O16  1  0.689  0.319  0.755  1.0
  O  O17  1  0.064  0.934  0.745  1.0
  O  O18  1  0.689  0.934  0.370  1.0
  O  O19  1  0.064  0.319  0.130  1.0
[/CIF]
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The crystal structure described by WAgSbO7 crystallizes in the orthorhombic Imma space group. W(1) is bonded to two equivalent O(3) and four equivalent O(4) atoms to form WO6 octahedra that share corners with two equivalent W(1)O6 octahedra and corners with four equivalent Sb(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 36-40°. Ag(1) is bonded in a distorted linear geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(4) atoms. Sb(1) is bonded to two equivalent O(2) and four equivalent O(4) atoms to form SbO6 octahedra that share corners with two equivalent Sb(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent Ag(1) atoms. In the second O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a bent 150 degrees geometry to two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one W(1), one Ag(1), and one Sb(1) atom. is represented by the CIF card [CIF]
data_AgSbWO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.380
_cell_length_b   7.380
_cell_length_c   7.380
_cell_angle_alpha   120.933
_cell_angle_beta   119.628
_cell_angle_gamma   89.519
_symmetry_Int_Tables_number   1
_cell_volume   283.010
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.500  0.500  1.0
  Ag  Ag1  1  0.500  0.000  0.000  1.0
  Sb  Sb2  1  0.000  0.000  0.000  1.0
  Sb  Sb3  1  0.500  0.000  0.500  1.0
  W  W4  1  0.000  0.000  0.500  1.0
  W  W5  1  0.000  0.500  0.000  1.0
  O  O6  1  0.419  0.669  0.750  1.0
  O  O7  1  0.581  0.331  0.250  1.0
  O  O8  1  0.326  0.076  0.250  1.0
  O  O9  1  0.943  0.693  0.250  1.0
  O  O10  1  0.311  0.681  0.245  1.0
  O  O11  1  0.936  0.066  0.255  1.0
  O  O12  1  0.311  0.066  0.630  1.0
  O  O13  1  0.936  0.681  0.870  1.0
  O  O14  1  0.674  0.924  0.750  1.0
  O  O15  1  0.057  0.307  0.750  1.0
  O  O16  1  0.689  0.319  0.755  1.0
  O  O17  1  0.064  0.934  0.745  1.0
  O  O18  1  0.689  0.934  0.370  1.0
  O  O19  1  0.064  0.319  0.130  1.0
[/CIF]
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