The crystal structure described by Ba5Ru3Na2O14 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(8), one O(9), two equivalent O(1), and two equivalent O(3) atoms to form NaO6 octahedra that share corners with three equivalent Ru(3)O6 octahedra, corners with three equivalent Ru(1)O5 trigonal bipyramids, and  a faceface with one Ba(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the second Na site, Na(2) is bonded to one O(6), two equivalent O(4), and two equivalent O(5) atoms to form NaO5 square pyramids that share corners with three equivalent Ru(2)O6 octahedra, corners with two equivalent Ru(1)O5 trigonal bipyramids, and  a faceface with one Ba(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 6-12°. There are five inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a distorted q6 geometry to one O(7), two equivalent O(2), two equivalent O(5), two equivalent O(6), and four equivalent O(4) atoms. In the second Ba site, Ba(2) is bonded in a 11-coordinate geometry to one O(9), two equivalent O(3), two equivalent O(5), two equivalent O(8), and four equivalent O(1) atoms. In the third Ba site, Ba(3) is bonded in a 10-coordinate geometry to one O(7), one O(8), two equivalent O(2), two equivalent O(9), and four equivalent O(3) atoms. In the fourth Ba site, Ba(4) is bonded in a 10-coordinate geometry to one O(6), one O(8), two equivalent O(1), two equivalent O(4), and four equivalent O(5) atoms. In the fifth Ba site, Ba(5) is bonded to one O(6), one O(9), two equivalent O(3), two equivalent O(4), two equivalent O(7), and four equivalent O(2) atoms to form BaO12 cuboctahedra that share corners with six equivalent Ba(5)O12 cuboctahedra,  a faceface with one Na(1)O6 octahedra, faces with three equivalent Ru(2)O6 octahedra, faces with three equivalent Ru(3)O6 octahedra, and  a faceface with one Na(2)O5 square pyramid. There are three inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(8), two equivalent O(1), and two equivalent O(5) atoms to form distorted RuO5 trigonal bipyramids that share corners with three equivalent Na(1)O6 octahedra and corners with two equivalent Na(2)O5 square pyramids. The corner-sharing octahedral tilt angles range from 7-27°. In the second Ru site, Ru(2) is bonded to one O(6), one O(7), two equivalent O(2), and two equivalent O(4) atoms to form RuO6 octahedra that share corners with three equivalent Na(2)O5 square pyramids, faces with three equivalent Ba(5)O12 cuboctahedra, and  a faceface with one Ru(3)O6 octahedra. In the third Ru site, Ru(3) is bonded to one O(7), one O(9), two equivalent O(2), and two equivalent O(3) atoms to form RuO6 octahedra that share corners with three equivalent Na(1)O6 octahedra, faces with three equivalent Ba(5)O12 cuboctahedra, and  a faceface with one Ru(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), one Ba(4), two equivalent Ba(2), and one Ru(1) atom. In the second O site, O(2) is bonded to one Ba(1), one Ba(3), two equivalent Ba(5), one Ru(2), and one Ru(3) atom to form a mixture of distorted corner and face-sharing OBa4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 7-61°. In the third O site, O(3) is bonded in a distorted linear geometry to one Na(1), one Ba(2), one Ba(5), two equivalent Ba(3), and one Ru(3) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Na(2), one Ba(4), one Ba(5), two equivalent Ba(1), and one Ru(2) atom. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to one Na(2), one Ba(1), one Ba(2), two equivalent Ba(4), and one Ru(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Na(2), one Ba(4), one Ba(5), two equivalent Ba(1), and one Ru(2) atom. In the seventh O site, O(7) is bonded to one Ba(1), one Ba(3), two equivalent Ba(5), one Ru(2), and one Ru(3) atom to form a mixture of distorted corner and face-sharing OBa4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 5-61°. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Na(1), one Ba(3), one Ba(4), two equivalent Ba(2), and one Ru(1) atom. In the ninth O site, O(9) is bonded in a 6-coordinate geometry to one Na(1), one Ba(2), one Ba(5), two equivalent Ba(3), and one Ru(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ba5Na2Ru3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.954
_cell_length_b   5.954
_cell_length_c   24.520
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.707
_symmetry_Int_Tables_number   1
_cell_volume   755.091
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.006  0.994  0.151  1.0
  Ba  Ba1  1  0.670  0.330  0.936  1.0
  Ba  Ba2  1  0.330  0.670  0.436  1.0
  Ba  Ba3  1  0.994  0.006  0.651  1.0
  Ba  Ba4  1  0.994  0.006  0.329  1.0
  Ba  Ba5  1  0.661  0.339  0.544  1.0
  Ba  Ba6  1  0.664  0.336  0.243  1.0
  Ba  Ba7  1  0.336  0.664  0.743  1.0
  Ba  Ba8  1  0.339  0.661  0.044  1.0
  Ba  Ba9  1  0.006  0.994  0.829  1.0
  Na  Na10  1  0.338  0.662  0.896  1.0
  Na  Na11  1  0.656  0.344  0.094  1.0
  Na  Na12  1  0.662  0.338  0.396  1.0
  Na  Na13  1  0.344  0.656  0.594  1.0
  Ru  Ru14  1  0.007  0.993  0.992  1.0
  Ru  Ru15  1  0.332  0.668  0.186  1.0
  Ru  Ru16  1  0.327  0.673  0.299  1.0
  Ru  Ru17  1  0.668  0.332  0.686  1.0
  Ru  Ru18  1  0.673  0.327  0.799  1.0
  Ru  Ru19  1  0.993  0.007  0.492  1.0
  O  O20  1  0.887  0.673  0.461  1.0
  O  O21  1  0.629  0.823  0.244  1.0
  O  O22  1  0.480  0.985  0.340  1.0
  O  O23  1  0.024  0.502  0.144  1.0
  O  O24  1  0.278  0.166  0.044  1.0
  O  O25  1  0.493  0.507  0.151  1.0
  O  O26  1  0.371  0.177  0.744  1.0
  O  O27  1  0.177  0.823  0.241  1.0
  O  O28  1  0.507  0.493  0.651  1.0
  O  O29  1  0.146  0.854  0.945  1.0
  O  O30  1  0.673  0.887  0.961  1.0
  O  O31  1  0.166  0.278  0.544  1.0
  O  O32  1  0.498  0.976  0.144  1.0
  O  O33  1  0.834  0.722  0.044  1.0
  O  O34  1  0.985  0.480  0.840  1.0
  O  O35  1  0.327  0.113  0.461  1.0
  O  O36  1  0.976  0.498  0.644  1.0
  O  O37  1  0.722  0.834  0.544  1.0
  O  O38  1  0.015  0.520  0.340  1.0
  O  O39  1  0.502  0.024  0.644  1.0
  O  O40  1  0.519  0.481  0.841  1.0
  O  O41  1  0.113  0.327  0.961  1.0
  O  O42  1  0.854  0.146  0.445  1.0
  O  O43  1  0.177  0.371  0.244  1.0
  O  O44  1  0.823  0.629  0.744  1.0
  O  O45  1  0.481  0.519  0.341  1.0
  O  O46  1  0.823  0.177  0.741  1.0
  O  O47  1  0.520  0.015  0.840  1.0
[/CIF]
.
The crystal structure described by Ba5Ru3Na2O14 crystallizes in the orthorhombic Cmc2_1 space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(8), one O(9), two equivalent O(1), and two equivalent O(3) atoms to form NaO6 octahedra that share corners with three equivalent Ru(3)O6 octahedra, corners with three equivalent Ru(1)O5 trigonal bipyramids, and  a faceface with one Ba(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 2-5°. In the second Na site, Na(2) is bonded to one O(6), two equivalent O(4), and two equivalent O(5) atoms to form NaO5 square pyramids that share corners with three equivalent Ru(2)O6 octahedra, corners with two equivalent Ru(1)O5 trigonal bipyramids, and  a faceface with one Ba(5)O12 cuboctahedra. The corner-sharing octahedral tilt angles range from 6-12°. There are five inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a distorted q6 geometry to one O(7), two equivalent O(2), two equivalent O(5), two equivalent O(6), and four equivalent O(4) atoms. In the second Ba site, Ba(2) is bonded in a 11-coordinate geometry to one O(9), two equivalent O(3), two equivalent O(5), two equivalent O(8), and four equivalent O(1) atoms. In the third Ba site, Ba(3) is bonded in a 10-coordinate geometry to one O(7), one O(8), two equivalent O(2), two equivalent O(9), and four equivalent O(3) atoms. In the fourth Ba site, Ba(4) is bonded in a 10-coordinate geometry to one O(6), one O(8), two equivalent O(1), two equivalent O(4), and four equivalent O(5) atoms. In the fifth Ba site, Ba(5) is bonded to one O(6), one O(9), two equivalent O(3), two equivalent O(4), two equivalent O(7), and four equivalent O(2) atoms to form BaO12 cuboctahedra that share corners with six equivalent Ba(5)O12 cuboctahedra,  a faceface with one Na(1)O6 octahedra, faces with three equivalent Ru(2)O6 octahedra, faces with three equivalent Ru(3)O6 octahedra, and  a faceface with one Na(2)O5 square pyramid. There are three inequivalent Ru sites. In the first Ru site, Ru(1) is bonded to one O(8), two equivalent O(1), and two equivalent O(5) atoms to form distorted RuO5 trigonal bipyramids that share corners with three equivalent Na(1)O6 octahedra and corners with two equivalent Na(2)O5 square pyramids. The corner-sharing octahedral tilt angles range from 7-27°. In the second Ru site, Ru(2) is bonded to one O(6), one O(7), two equivalent O(2), and two equivalent O(4) atoms to form RuO6 octahedra that share corners with three equivalent Na(2)O5 square pyramids, faces with three equivalent Ba(5)O12 cuboctahedra, and  a faceface with one Ru(3)O6 octahedra. In the third Ru site, Ru(3) is bonded to one O(7), one O(9), two equivalent O(2), and two equivalent O(3) atoms to form RuO6 octahedra that share corners with three equivalent Na(1)O6 octahedra, faces with three equivalent Ba(5)O12 cuboctahedra, and  a faceface with one Ru(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 2-5°. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Na(1), one Ba(4), two equivalent Ba(2), and one Ru(1) atom. In the second O site, O(2) is bonded to one Ba(1), one Ba(3), two equivalent Ba(5), one Ru(2), and one Ru(3) atom to form a mixture of distorted corner and face-sharing OBa4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 7-61°. In the third O site, O(3) is bonded in a distorted linear geometry to one Na(1), one Ba(2), one Ba(5), two equivalent Ba(3), and one Ru(3) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Na(2), one Ba(4), one Ba(5), two equivalent Ba(1), and one Ru(2) atom. In the fifth O site, O(5) is bonded in a 6-coordinate geometry to one Na(2), one Ba(1), one Ba(2), two equivalent Ba(4), and one Ru(1) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Na(2), one Ba(4), one Ba(5), two equivalent Ba(1), and one Ru(2) atom. In the seventh O site, O(7) is bonded to one Ba(1), one Ba(3), two equivalent Ba(5), one Ru(2), and one Ru(3) atom to form a mixture of distorted corner and face-sharing OBa4Ru2 octahedra. The corner-sharing octahedral tilt angles range from 5-61°. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Na(1), one Ba(3), one Ba(4), two equivalent Ba(2), and one Ru(1) atom. In the ninth O site, O(9) is bonded in a 6-coordinate geometry to one Na(1), one Ba(2), one Ba(5), two equivalent Ba(3), and one Ru(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ba5Na2Ru3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.954
_cell_length_b   5.954
_cell_length_c   24.520
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   119.707
_symmetry_Int_Tables_number   1
_cell_volume   755.091
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.006  0.994  0.151  1.0
  Ba  Ba1  1  0.670  0.330  0.936  1.0
  Ba  Ba2  1  0.330  0.670  0.436  1.0
  Ba  Ba3  1  0.994  0.006  0.651  1.0
  Ba  Ba4  1  0.994  0.006  0.329  1.0
  Ba  Ba5  1  0.661  0.339  0.544  1.0
  Ba  Ba6  1  0.664  0.336  0.243  1.0
  Ba  Ba7  1  0.336  0.664  0.743  1.0
  Ba  Ba8  1  0.339  0.661  0.044  1.0
  Ba  Ba9  1  0.006  0.994  0.829  1.0
  Na  Na10  1  0.338  0.662  0.896  1.0
  Na  Na11  1  0.656  0.344  0.094  1.0
  Na  Na12  1  0.662  0.338  0.396  1.0
  Na  Na13  1  0.344  0.656  0.594  1.0
  Ru  Ru14  1  0.007  0.993  0.992  1.0
  Ru  Ru15  1  0.332  0.668  0.186  1.0
  Ru  Ru16  1  0.327  0.673  0.299  1.0
  Ru  Ru17  1  0.668  0.332  0.686  1.0
  Ru  Ru18  1  0.673  0.327  0.799  1.0
  Ru  Ru19  1  0.993  0.007  0.492  1.0
  O  O20  1  0.887  0.673  0.461  1.0
  O  O21  1  0.629  0.823  0.244  1.0
  O  O22  1  0.480  0.985  0.340  1.0
  O  O23  1  0.024  0.502  0.144  1.0
  O  O24  1  0.278  0.166  0.044  1.0
  O  O25  1  0.493  0.507  0.151  1.0
  O  O26  1  0.371  0.177  0.744  1.0
  O  O27  1  0.177  0.823  0.241  1.0
  O  O28  1  0.507  0.493  0.651  1.0
  O  O29  1  0.146  0.854  0.945  1.0
  O  O30  1  0.673  0.887  0.961  1.0
  O  O31  1  0.166  0.278  0.544  1.0
  O  O32  1  0.498  0.976  0.144  1.0
  O  O33  1  0.834  0.722  0.044  1.0
  O  O34  1  0.985  0.480  0.840  1.0
  O  O35  1  0.327  0.113  0.461  1.0
  O  O36  1  0.976  0.498  0.644  1.0
  O  O37  1  0.722  0.834  0.544  1.0
  O  O38  1  0.015  0.520  0.340  1.0
  O  O39  1  0.502  0.024  0.644  1.0
  O  O40  1  0.519  0.481  0.841  1.0
  O  O41  1  0.113  0.327  0.961  1.0
  O  O42  1  0.854  0.146  0.445  1.0
  O  O43  1  0.177  0.371  0.244  1.0
  O  O44  1  0.823  0.629  0.744  1.0
  O  O45  1  0.481  0.519  0.341  1.0
  O  O46  1  0.823  0.177  0.741  1.0
  O  O47  1  0.520  0.015  0.840  1.0
[/CIF]
.