The compound described by MoCr14O24 is beta indium sulfide-derived structured and crystallizes in the triclinic P-1 space group. Mo(1) is bonded to two equivalent O(10), two equivalent O(11), and two equivalent O(12) atoms to form MoO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with four equivalent Cr(7)O6 octahedra. The corner-sharing octahedral tilt angles are 48°. There are seven inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(1), one O(11), one O(12), one O(3), one O(5), and one O(7) atom to form CrO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra, corners with three equivalent Cr(5)O6 octahedra,  an edgeedge with one Mo(1)O6 octahedra,  an edgeedge with one Cr(6)O6 octahedra, edges with two equivalent Cr(7)O6 octahedra, and  a faceface with one Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-59°. In the second Cr site, Cr(2) is bonded to one O(1), one O(12), one O(2), one O(3), one O(5), and one O(7) atom to form CrO6 octahedra that share  a cornercorner with one Mo(1)O6 octahedra,  a cornercorner with one Cr(3)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, corners with three equivalent Cr(6)O6 octahedra, corners with three equivalent Cr(7)O6 octahedra, edges with two equivalent Cr(5)O6 octahedra, and  a faceface with one Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-60°. In the third Cr site, Cr(3) is bonded to one O(2), one O(4), one O(8), one O(9), and two equivalent O(6) atoms to form a mixture of face, corner, and edge-sharing CrO6 octahedra. The corner-sharing octahedral tilt angles range from 47-61°. In the fourth Cr site, Cr(4) is bonded to one O(4), one O(9), two equivalent O(6), and two equivalent O(8) atoms to form a mixture of face, corner, and edge-sharing CrO6 octahedra. The corner-sharing octahedral tilt angles range from 47-62°. In the fifth Cr site, Cr(5) is bonded to one O(1), one O(2), one O(4), one O(5), one O(7), and one O(9) atom to form a mixture of face, corner, and edge-sharing CrO6 octahedra. The corner-sharing octahedral tilt angles range from 47-61°. In the sixth Cr site, Cr(6) is bonded to one O(1), one O(2), one O(4), one O(7), one O(8), and one O(9) atom to form a mixture of face, corner, and edge-sharing CrO6 octahedra. The corner-sharing octahedral tilt angles range from 45-62°. In the seventh Cr site, Cr(7) is bonded to one O(11), one O(12), one O(3), one O(5), and two equivalent O(10) atoms to form CrO6 octahedra that share  a cornercorner with one Cr(5)O6 octahedra, corners with three equivalent Cr(2)O6 octahedra,  an edgeedge with one Cr(7)O6 octahedra, edges with two equivalent Mo(1)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-61°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Cr(1), one Cr(2), one Cr(5), and one Cr(6) atom to form a mixture of distorted corner and edge-sharing OCr4 trigonal pyramids. In the second O site, O(2) is bonded to one Cr(2), one Cr(3), one Cr(5), and one Cr(6) atom to form a mixture of distorted corner and edge-sharing OCr4 trigonal pyramids. In the third O site, O(3) is bonded in a trigonal planar geometry to one Cr(1), one Cr(2), and one Cr(7) atom. In the fourth O site, O(4) is bonded to one Cr(3), one Cr(4), one Cr(5), and one Cr(6) atom to form a mixture of distorted corner and edge-sharing OCr4 trigonal pyramids. In the fifth O site, O(5) is bonded to one Cr(1), one Cr(2), one Cr(5), and one Cr(7) atom to form a mixture of distorted corner and edge-sharing OCr4 trigonal pyramids. In the sixth O site, O(6) is bonded to two equivalent Cr(3) and two equivalent Cr(4) atoms to form a mixture of distorted corner and edge-sharing OCr4 trigonal pyramids. In the seventh O site, O(7) is bonded to one Cr(1), one Cr(2), one Cr(5), and one Cr(6) atom to form a mixture of distorted corner and edge-sharing OCr4 trigonal pyramids. In the eighth O site, O(8) is bonded to one Cr(3), one Cr(6), and two equivalent Cr(4) atoms to form a mixture of distorted corner and edge-sharing OCr4 trigonal pyramids. In the ninth O site, O(9) is bonded to one Cr(3), one Cr(4), one Cr(5), and one Cr(6) atom to form a mixture of distorted corner and edge-sharing OCr4 trigonal pyramids. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1) and two equivalent Cr(7) atoms. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Cr(1), and one Cr(7) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Cr(1), one Cr(2), and one Cr(7) atom. is represented by the CIF card [CIF]
data_Cr14MoO24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.126
_cell_length_b   5.450
_cell_length_c   16.967
_cell_angle_alpha   83.785
_cell_angle_beta   81.364
_cell_angle_gamma   62.226
_symmetry_Int_Tables_number   1
_cell_volume   414.253
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.701  0.284  0.832  1.0
  Cr  Cr1  1  0.427  0.842  0.791  1.0
  Cr  Cr2  1  0.437  0.037  0.588  1.0
  Cr  Cr3  1  0.188  0.588  0.538  1.0
  Cr  Cr4  1  0.060  0.663  0.713  1.0
  Cr  Cr5  1  0.189  0.787  0.338  1.0
  Cr  Cr6  1  0.811  0.213  0.662  1.0
  Cr  Cr7  1  0.940  0.337  0.287  1.0
  Cr  Cr8  1  0.812  0.412  0.462  1.0
  Cr  Cr9  1  0.910  0.580  0.090  1.0
  Cr  Cr10  1  0.563  0.963  0.412  1.0
  Cr  Cr11  1  0.573  0.158  0.209  1.0
  Cr  Cr12  1  0.299  0.716  0.168  1.0
  Cr  Cr13  1  0.090  0.420  0.910  1.0
  Mo  Mo14  1  0.500  0.500  0.000  1.0
  O  O15  1  0.709  0.009  0.763  1.0
  O  O16  1  0.235  0.939  0.689  1.0
  O  O17  1  0.104  0.123  0.854  1.0
  O  O18  1  0.386  0.388  0.638  1.0
  O  O19  1  0.263  0.558  0.812  1.0
  O  O20  1  0.463  0.762  0.513  1.0
  O  O21  1  0.779  0.495  0.735  1.0
  O  O22  1  0.987  0.688  0.437  1.0
  O  O23  1  0.863  0.863  0.612  1.0
  O  O24  1  0.137  0.137  0.388  1.0
  O  O25  1  0.013  0.312  0.563  1.0
  O  O26  1  0.221  0.505  0.265  1.0
  O  O27  1  0.537  0.238  0.487  1.0
  O  O28  1  0.737  0.442  0.188  1.0
  O  O29  1  0.614  0.612  0.362  1.0
  O  O30  1  0.896  0.877  0.146  1.0
  O  O31  1  0.765  0.061  0.311  1.0
  O  O32  1  0.911  0.309  0.015  1.0
  O  O33  1  0.291  0.991  0.237  1.0
  O  O34  1  0.506  0.216  0.937  1.0
  O  O35  1  0.351  0.381  0.108  1.0
  O  O36  1  0.649  0.619  0.892  1.0
  O  O37  1  0.494  0.784  0.063  1.0
  O  O38  1  0.089  0.691  0.985  1.0
[/CIF]
.
The compound described by MoCr14O24 is beta indium sulfide-derived structured and crystallizes in the triclinic P-1 space group. Mo(1) is bonded to two equivalent O(10), two equivalent O(11), and two equivalent O(12) atoms to form MoO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra, edges with two equivalent Cr(1)O6 octahedra, and edges with four equivalent Cr(7)O6 octahedra. The corner-sharing octahedral tilt angles are 48°. There are seven inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(1), one O(11), one O(12), one O(3), one O(5), and one O(7) atom to form CrO6 octahedra that share corners with two equivalent Cr(2)O6 octahedra, corners with three equivalent Cr(5)O6 octahedra,  an edgeedge with one Mo(1)O6 octahedra,  an edgeedge with one Cr(6)O6 octahedra, edges with two equivalent Cr(7)O6 octahedra, and  a faceface with one Cr(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-59°. In the second Cr site, Cr(2) is bonded to one O(1), one O(12), one O(2), one O(3), one O(5), and one O(7) atom to form CrO6 octahedra that share  a cornercorner with one Mo(1)O6 octahedra,  a cornercorner with one Cr(3)O6 octahedra, corners with two equivalent Cr(1)O6 octahedra, corners with three equivalent Cr(6)O6 octahedra, corners with three equivalent Cr(7)O6 octahedra, edges with two equivalent Cr(5)O6 octahedra, and  a faceface with one Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-60°. In the third Cr site, Cr(3) is bonded to one O(2), one O(4), one O(8), one O(9), and two equivalent O(6) atoms to form a mixture of face, corner, and edge-sharing CrO6 octahedra. The corner-sharing octahedral tilt angles range from 47-61°. In the fourth Cr site, Cr(4) is bonded to one O(4), one O(9), two equivalent O(6), and two equivalent O(8) atoms to form a mixture of face, corner, and edge-sharing CrO6 octahedra. The corner-sharing octahedral tilt angles range from 47-62°. In the fifth Cr site, Cr(5) is bonded to one O(1), one O(2), one O(4), one O(5), one O(7), and one O(9) atom to form a mixture of face, corner, and edge-sharing CrO6 octahedra. The corner-sharing octahedral tilt angles range from 47-61°. In the sixth Cr site, Cr(6) is bonded to one O(1), one O(2), one O(4), one O(7), one O(8), and one O(9) atom to form a mixture of face, corner, and edge-sharing CrO6 octahedra. The corner-sharing octahedral tilt angles range from 45-62°. In the seventh Cr site, Cr(7) is bonded to one O(11), one O(12), one O(3), one O(5), and two equivalent O(10) atoms to form CrO6 octahedra that share  a cornercorner with one Cr(5)O6 octahedra, corners with three equivalent Cr(2)O6 octahedra,  an edgeedge with one Cr(7)O6 octahedra, edges with two equivalent Mo(1)O6 octahedra, and edges with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-61°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Cr(1), one Cr(2), one Cr(5), and one Cr(6) atom to form a mixture of distorted corner and edge-sharing OCr4 trigonal pyramids. In the second O site, O(2) is bonded to one Cr(2), one Cr(3), one Cr(5), and one Cr(6) atom to form a mixture of distorted corner and edge-sharing OCr4 trigonal pyramids. In the third O site, O(3) is bonded in a trigonal planar geometry to one Cr(1), one Cr(2), and one Cr(7) atom. In the fourth O site, O(4) is bonded to one Cr(3), one Cr(4), one Cr(5), and one Cr(6) atom to form a mixture of distorted corner and edge-sharing OCr4 trigonal pyramids. In the fifth O site, O(5) is bonded to one Cr(1), one Cr(2), one Cr(5), and one Cr(7) atom to form a mixture of distorted corner and edge-sharing OCr4 trigonal pyramids. In the sixth O site, O(6) is bonded to two equivalent Cr(3) and two equivalent Cr(4) atoms to form a mixture of distorted corner and edge-sharing OCr4 trigonal pyramids. In the seventh O site, O(7) is bonded to one Cr(1), one Cr(2), one Cr(5), and one Cr(6) atom to form a mixture of distorted corner and edge-sharing OCr4 trigonal pyramids. In the eighth O site, O(8) is bonded to one Cr(3), one Cr(6), and two equivalent Cr(4) atoms to form a mixture of distorted corner and edge-sharing OCr4 trigonal pyramids. In the ninth O site, O(9) is bonded to one Cr(3), one Cr(4), one Cr(5), and one Cr(6) atom to form a mixture of distorted corner and edge-sharing OCr4 trigonal pyramids. In the tenth O site, O(10) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1) and two equivalent Cr(7) atoms. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Cr(1), and one Cr(7) atom. In the twelfth O site, O(12) is bonded in a rectangular see-saw-like geometry to one Mo(1), one Cr(1), one Cr(2), and one Cr(7) atom. is represented by the CIF card [CIF]
data_Cr14MoO24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.126
_cell_length_b   5.450
_cell_length_c   16.967
_cell_angle_alpha   83.785
_cell_angle_beta   81.364
_cell_angle_gamma   62.226
_symmetry_Int_Tables_number   1
_cell_volume   414.253
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.701  0.284  0.832  1.0
  Cr  Cr1  1  0.427  0.842  0.791  1.0
  Cr  Cr2  1  0.437  0.037  0.588  1.0
  Cr  Cr3  1  0.188  0.588  0.538  1.0
  Cr  Cr4  1  0.060  0.663  0.713  1.0
  Cr  Cr5  1  0.189  0.787  0.338  1.0
  Cr  Cr6  1  0.811  0.213  0.662  1.0
  Cr  Cr7  1  0.940  0.337  0.287  1.0
  Cr  Cr8  1  0.812  0.412  0.462  1.0
  Cr  Cr9  1  0.910  0.580  0.090  1.0
  Cr  Cr10  1  0.563  0.963  0.412  1.0
  Cr  Cr11  1  0.573  0.158  0.209  1.0
  Cr  Cr12  1  0.299  0.716  0.168  1.0
  Cr  Cr13  1  0.090  0.420  0.910  1.0
  Mo  Mo14  1  0.500  0.500  0.000  1.0
  O  O15  1  0.709  0.009  0.763  1.0
  O  O16  1  0.235  0.939  0.689  1.0
  O  O17  1  0.104  0.123  0.854  1.0
  O  O18  1  0.386  0.388  0.638  1.0
  O  O19  1  0.263  0.558  0.812  1.0
  O  O20  1  0.463  0.762  0.513  1.0
  O  O21  1  0.779  0.495  0.735  1.0
  O  O22  1  0.987  0.688  0.437  1.0
  O  O23  1  0.863  0.863  0.612  1.0
  O  O24  1  0.137  0.137  0.388  1.0
  O  O25  1  0.013  0.312  0.563  1.0
  O  O26  1  0.221  0.505  0.265  1.0
  O  O27  1  0.537  0.238  0.487  1.0
  O  O28  1  0.737  0.442  0.188  1.0
  O  O29  1  0.614  0.612  0.362  1.0
  O  O30  1  0.896  0.877  0.146  1.0
  O  O31  1  0.765  0.061  0.311  1.0
  O  O32  1  0.911  0.309  0.015  1.0
  O  O33  1  0.291  0.991  0.237  1.0
  O  O34  1  0.506  0.216  0.937  1.0
  O  O35  1  0.351  0.381  0.108  1.0
  O  O36  1  0.649  0.619  0.892  1.0
  O  O37  1  0.494  0.784  0.063  1.0
  O  O38  1  0.089  0.691  0.985  1.0
[/CIF]
.