The crystal structure described by Pb2BiVO6 crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(4) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to two equivalent O(3) and two equivalent O(4) atoms. In the second Pb site, Pb(2) is bonded in a 5-coordinate geometry to one O(1), two equivalent O(3), and two equivalent O(4) atoms. Bi(1) is bonded in a 4-coordinate geometry to four equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one V(1) and one Pb(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one V(1) atom. In the third O site, O(3) is bonded to one Pb(1), one Pb(2), and two equivalent Bi(1) atoms to form a mixture of edge and corner-sharing OBi2Pb2 tetrahedra. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one V(1), one Pb(1), and one Pb(2) atom. is represented by the CIF card [CIF]
data_VBi(PbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.802
_cell_length_b   10.091
_cell_length_c   12.390
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   725.470
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.250  0.473  0.207  1.0
  V  V1  1  0.750  0.973  0.293  1.0
  V  V2  1  0.750  0.527  0.793  1.0
  V  V3  1  0.250  0.027  0.707  1.0
  Bi  Bi4  1  0.750  0.499  0.411  1.0
  Bi  Bi5  1  0.250  0.501  0.589  1.0
  Bi  Bi6  1  0.750  0.001  0.911  1.0
  Bi  Bi7  1  0.250  0.999  0.089  1.0
  Pb  Pb8  1  0.250  0.262  0.874  1.0
  Pb  Pb9  1  0.750  0.738  0.126  1.0
  Pb  Pb10  1  0.750  0.203  0.599  1.0
  Pb  Pb11  1  0.250  0.238  0.374  1.0
  Pb  Pb12  1  0.750  0.297  0.099  1.0
  Pb  Pb13  1  0.250  0.703  0.901  1.0
  Pb  Pb14  1  0.750  0.762  0.626  1.0
  Pb  Pb15  1  0.250  0.797  0.401  1.0
  O  O16  1  0.750  0.111  0.210  1.0
  O  O17  1  0.250  0.507  0.074  1.0
  O  O18  1  0.992  0.864  0.012  1.0
  O  O19  1  0.492  0.136  0.988  1.0
  O  O20  1  0.008  0.364  0.488  1.0
  O  O21  1  0.492  0.364  0.488  1.0
  O  O22  1  0.508  0.636  0.512  1.0
  O  O23  1  0.992  0.636  0.512  1.0
  O  O24  1  0.988  0.629  0.754  1.0
  O  O25  1  0.488  0.371  0.246  1.0
  O  O26  1  0.488  0.129  0.746  1.0
  O  O27  1  0.250  0.993  0.574  1.0
  O  O28  1  0.012  0.371  0.246  1.0
  O  O29  1  0.750  0.493  0.926  1.0
  O  O30  1  0.988  0.871  0.254  1.0
  O  O31  1  0.250  0.611  0.290  1.0
  O  O32  1  0.750  0.389  0.710  1.0
  O  O33  1  0.250  0.889  0.790  1.0
  O  O34  1  0.512  0.871  0.254  1.0
  O  O35  1  0.750  0.007  0.426  1.0
  O  O36  1  0.512  0.629  0.754  1.0
  O  O37  1  0.012  0.129  0.746  1.0
  O  O38  1  0.008  0.136  0.988  1.0
  O  O39  1  0.508  0.864  0.012  1.0
[/CIF]
.
The crystal structure described by Pb2BiVO6 crystallizes in the orthorhombic Pnma space group. V(1) is bonded in a tetrahedral geometry to one O(1), one O(2), and two equivalent O(4) atoms. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 4-coordinate geometry to two equivalent O(3) and two equivalent O(4) atoms. In the second Pb site, Pb(2) is bonded in a 5-coordinate geometry to one O(1), two equivalent O(3), and two equivalent O(4) atoms. Bi(1) is bonded in a 4-coordinate geometry to four equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one V(1) and one Pb(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one V(1) atom. In the third O site, O(3) is bonded to one Pb(1), one Pb(2), and two equivalent Bi(1) atoms to form a mixture of edge and corner-sharing OBi2Pb2 tetrahedra. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one V(1), one Pb(1), and one Pb(2) atom. is represented by the CIF card [CIF]
data_VBi(PbO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.802
_cell_length_b   10.091
_cell_length_c   12.390
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   725.470
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.250  0.473  0.207  1.0
  V  V1  1  0.750  0.973  0.293  1.0
  V  V2  1  0.750  0.527  0.793  1.0
  V  V3  1  0.250  0.027  0.707  1.0
  Bi  Bi4  1  0.750  0.499  0.411  1.0
  Bi  Bi5  1  0.250  0.501  0.589  1.0
  Bi  Bi6  1  0.750  0.001  0.911  1.0
  Bi  Bi7  1  0.250  0.999  0.089  1.0
  Pb  Pb8  1  0.250  0.262  0.874  1.0
  Pb  Pb9  1  0.750  0.738  0.126  1.0
  Pb  Pb10  1  0.750  0.203  0.599  1.0
  Pb  Pb11  1  0.250  0.238  0.374  1.0
  Pb  Pb12  1  0.750  0.297  0.099  1.0
  Pb  Pb13  1  0.250  0.703  0.901  1.0
  Pb  Pb14  1  0.750  0.762  0.626  1.0
  Pb  Pb15  1  0.250  0.797  0.401  1.0
  O  O16  1  0.750  0.111  0.210  1.0
  O  O17  1  0.250  0.507  0.074  1.0
  O  O18  1  0.992  0.864  0.012  1.0
  O  O19  1  0.492  0.136  0.988  1.0
  O  O20  1  0.008  0.364  0.488  1.0
  O  O21  1  0.492  0.364  0.488  1.0
  O  O22  1  0.508  0.636  0.512  1.0
  O  O23  1  0.992  0.636  0.512  1.0
  O  O24  1  0.988  0.629  0.754  1.0
  O  O25  1  0.488  0.371  0.246  1.0
  O  O26  1  0.488  0.129  0.746  1.0
  O  O27  1  0.250  0.993  0.574  1.0
  O  O28  1  0.012  0.371  0.246  1.0
  O  O29  1  0.750  0.493  0.926  1.0
  O  O30  1  0.988  0.871  0.254  1.0
  O  O31  1  0.250  0.611  0.290  1.0
  O  O32  1  0.750  0.389  0.710  1.0
  O  O33  1  0.250  0.889  0.790  1.0
  O  O34  1  0.512  0.871  0.254  1.0
  O  O35  1  0.750  0.007  0.426  1.0
  O  O36  1  0.512  0.629  0.754  1.0
  O  O37  1  0.012  0.129  0.746  1.0
  O  O38  1  0.008  0.136  0.988  1.0
  O  O39  1  0.508  0.864  0.012  1.0
[/CIF]
.