The material structure described by MgCu4(Ag2O3)2 crystallizes in the monoclinic C2 space group. Mg(1) is bonded in a trigonal planar geometry to one O(1) and two equivalent O(3) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one O(3) and one O(4) atom. In the second Ag site, Ag(2) is bonded in a bent 150 degrees geometry to one O(3) and one O(4) atom. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Cu site, Cu(2) is bonded in a linear geometry to one O(2) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mg(1) and two equivalent Cu(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal pyramidal geometry to two equivalent Cu(1) and two equivalent Cu(2) atoms. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Mg(1), one Ag(1), one Ag(2), and one Cu(1) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Ag(1), one Ag(2), one Cu(1), and one Cu(2) atom. is represented by the CIF card [CIF]
data_MgCu4(Ag2O3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.239
_cell_length_b   6.239
_cell_length_c   7.289
_cell_angle_alpha   115.071
_cell_angle_beta   115.071
_cell_angle_gamma   97.449
_symmetry_Int_Tables_number   1
_cell_volume   215.634
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.766  0.234  0.250  1.0
  Cu  Cu1  1  0.462  0.471  0.472  1.0
  Cu  Cu2  1  0.444  0.891  0.780  1.0
  Cu  Cu3  1  0.529  0.538  0.028  1.0
  Cu  Cu4  1  0.109  0.556  0.720  1.0
  Ag  Ag5  1  0.989  0.473  0.009  1.0
  Ag  Ag6  1  0.040  0.004  0.539  1.0
  Ag  Ag7  1  0.527  0.011  0.491  1.0
  Ag  Ag8  1  0.996  0.960  0.961  1.0
  O  O9  1  0.559  0.441  0.250  1.0
  O  O10  1  0.419  0.581  0.750  1.0
  O  O11  1  0.666  0.913  0.251  1.0
  O  O12  1  0.815  0.541  0.711  1.0
  O  O13  1  0.087  0.334  0.249  1.0
  O  O14  1  0.459  0.185  0.789  1.0
[/CIF]
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The material structure described by MgCu4(Ag2O3)2 crystallizes in the monoclinic C2 space group. Mg(1) is bonded in a trigonal planar geometry to one O(1) and two equivalent O(3) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one O(3) and one O(4) atom. In the second Ag site, Ag(2) is bonded in a bent 150 degrees geometry to one O(3) and one O(4) atom. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Cu site, Cu(2) is bonded in a linear geometry to one O(2) and one O(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mg(1) and two equivalent Cu(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal pyramidal geometry to two equivalent Cu(1) and two equivalent Cu(2) atoms. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Mg(1), one Ag(1), one Ag(2), and one Cu(1) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Ag(1), one Ag(2), one Cu(1), and one Cu(2) atom. is represented by the CIF card [CIF]
data_MgCu4(Ag2O3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.239
_cell_length_b   6.239
_cell_length_c   7.289
_cell_angle_alpha   115.071
_cell_angle_beta   115.071
_cell_angle_gamma   97.449
_symmetry_Int_Tables_number   1
_cell_volume   215.634
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.766  0.234  0.250  1.0
  Cu  Cu1  1  0.462  0.471  0.472  1.0
  Cu  Cu2  1  0.444  0.891  0.780  1.0
  Cu  Cu3  1  0.529  0.538  0.028  1.0
  Cu  Cu4  1  0.109  0.556  0.720  1.0
  Ag  Ag5  1  0.989  0.473  0.009  1.0
  Ag  Ag6  1  0.040  0.004  0.539  1.0
  Ag  Ag7  1  0.527  0.011  0.491  1.0
  Ag  Ag8  1  0.996  0.960  0.961  1.0
  O  O9  1  0.559  0.441  0.250  1.0
  O  O10  1  0.419  0.581  0.750  1.0
  O  O11  1  0.666  0.913  0.251  1.0
  O  O12  1  0.815  0.541  0.711  1.0
  O  O13  1  0.087  0.334  0.249  1.0
  O  O14  1  0.459  0.185  0.789  1.0
[/CIF]
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