The structure described by Yb2MoO6 crystallizes in the monoclinic C2/c space group. There are three inequivalent Yb sites. In the first Yb site, Yb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), and four equivalent O(2) atoms. In the second Yb site, Yb(2) is bonded in a 8-coordinate geometry to one O(1), one O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. In the third Yb site, Yb(3) is bonded in a body-centered cubic geometry to two equivalent O(1), two equivalent O(3), and four equivalent O(4) atoms. Mo(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a distorted trigonal planar geometry to two equivalent Yb(2) and one Mo(1) atom. In the second O site, O(1) is bonded to one Yb(1), one Yb(2), one Yb(3), and one Mo(1) atom to form OYb3Mo tetrahedra that share corners with two equivalent O(1)Yb3Mo tetrahedra, corners with four equivalent O(4)Yb4 tetrahedra, and  an edgeedge with one O(4)Yb4 tetrahedra. In the third O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Yb(1) and one Mo(1) atom. In the fourth O site, O(3) is bonded in a 4-coordinate geometry to one Yb(1), one Yb(2), one Yb(3), and one Mo(1) atom. In the fifth O site, O(4) is bonded to two equivalent Yb(2) and two equivalent Yb(3) atoms to form OYb4 tetrahedra that share corners with two equivalent O(4)Yb4 tetrahedra, corners with four equivalent O(1)Yb3Mo tetrahedra,  an edgeedge with one O(1)Yb3Mo tetrahedra, and edges with three equivalent O(4)Yb4 tetrahedra. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Yb(2) and one Mo(1) atom. is represented by the CIF card [CIF]
data_Yb2MoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.750
_cell_length_b   9.750
_cell_length_c   5.466
_cell_angle_alpha   76.067
_cell_angle_beta   76.067
_cell_angle_gamma   72.205
_symmetry_Int_Tables_number   1
_cell_volume   472.240
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.126  0.874  0.250  1.0
  Yb  Yb1  1  0.788  0.557  0.603  1.0
  Yb  Yb2  1  0.635  0.365  0.250  1.0
  Yb  Yb3  1  0.212  0.443  0.397  1.0
  Yb  Yb4  1  0.443  0.212  0.897  1.0
  Yb  Yb5  1  0.365  0.635  0.750  1.0
  Yb  Yb6  1  0.874  0.126  0.750  1.0
  Yb  Yb7  1  0.557  0.788  0.103  1.0
  Mo  Mo8  1  0.705  0.988  0.421  1.0
  Mo  Mo9  1  0.012  0.295  0.079  1.0
  Mo  Mo10  1  0.988  0.705  0.921  1.0
  Mo  Mo11  1  0.295  0.012  0.579  1.0
  O  O12  1  0.170  0.656  0.099  1.0
  O  O13  1  0.953  0.887  0.973  1.0
  O  O14  1  0.320  0.878  0.875  1.0
  O  O15  1  0.680  0.122  0.125  1.0
  O  O16  1  0.580  0.568  0.441  1.0
  O  O17  1  0.887  0.953  0.473  1.0
  O  O18  1  0.568  0.580  0.941  1.0
  O  O19  1  0.979  0.567  0.238  1.0
  O  O20  1  0.433  0.021  0.262  1.0
  O  O21  1  0.301  0.188  0.626  1.0
  O  O22  1  0.699  0.812  0.374  1.0
  O  O23  1  0.113  0.047  0.527  1.0
  O  O24  1  0.420  0.432  0.559  1.0
  O  O25  1  0.656  0.170  0.599  1.0
  O  O26  1  0.830  0.344  0.901  1.0
  O  O27  1  0.344  0.830  0.401  1.0
  O  O28  1  0.567  0.979  0.738  1.0
  O  O29  1  0.878  0.320  0.375  1.0
  O  O30  1  0.188  0.301  0.126  1.0
  O  O31  1  0.812  0.699  0.874  1.0
  O  O32  1  0.021  0.433  0.762  1.0
  O  O33  1  0.122  0.680  0.625  1.0
  O  O34  1  0.432  0.420  0.059  1.0
  O  O35  1  0.047  0.113  0.027  1.0
[/CIF]
.
The structure described by Yb2MoO6 crystallizes in the monoclinic C2/c space group. There are three inequivalent Yb sites. In the first Yb site, Yb(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(3), and four equivalent O(2) atoms. In the second Yb site, Yb(2) is bonded in a 8-coordinate geometry to one O(1), one O(3), two equivalent O(4), two equivalent O(5), and two equivalent O(6) atoms. In the third Yb site, Yb(3) is bonded in a body-centered cubic geometry to two equivalent O(1), two equivalent O(3), and four equivalent O(4) atoms. Mo(1) is bonded in a 5-coordinate geometry to one O(1), one O(2), one O(3), one O(5), and one O(6) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a distorted trigonal planar geometry to two equivalent Yb(2) and one Mo(1) atom. In the second O site, O(1) is bonded to one Yb(1), one Yb(2), one Yb(3), and one Mo(1) atom to form OYb3Mo tetrahedra that share corners with two equivalent O(1)Yb3Mo tetrahedra, corners with four equivalent O(4)Yb4 tetrahedra, and  an edgeedge with one O(4)Yb4 tetrahedra. In the third O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Yb(1) and one Mo(1) atom. In the fourth O site, O(3) is bonded in a 4-coordinate geometry to one Yb(1), one Yb(2), one Yb(3), and one Mo(1) atom. In the fifth O site, O(4) is bonded to two equivalent Yb(2) and two equivalent Yb(3) atoms to form OYb4 tetrahedra that share corners with two equivalent O(4)Yb4 tetrahedra, corners with four equivalent O(1)Yb3Mo tetrahedra,  an edgeedge with one O(1)Yb3Mo tetrahedra, and edges with three equivalent O(4)Yb4 tetrahedra. In the sixth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Yb(2) and one Mo(1) atom. is represented by the CIF card [CIF]
data_Yb2MoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.750
_cell_length_b   9.750
_cell_length_c   5.466
_cell_angle_alpha   76.067
_cell_angle_beta   76.067
_cell_angle_gamma   72.205
_symmetry_Int_Tables_number   1
_cell_volume   472.240
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Yb  Yb0  1  0.126  0.874  0.250  1.0
  Yb  Yb1  1  0.788  0.557  0.603  1.0
  Yb  Yb2  1  0.635  0.365  0.250  1.0
  Yb  Yb3  1  0.212  0.443  0.397  1.0
  Yb  Yb4  1  0.443  0.212  0.897  1.0
  Yb  Yb5  1  0.365  0.635  0.750  1.0
  Yb  Yb6  1  0.874  0.126  0.750  1.0
  Yb  Yb7  1  0.557  0.788  0.103  1.0
  Mo  Mo8  1  0.705  0.988  0.421  1.0
  Mo  Mo9  1  0.012  0.295  0.079  1.0
  Mo  Mo10  1  0.988  0.705  0.921  1.0
  Mo  Mo11  1  0.295  0.012  0.579  1.0
  O  O12  1  0.170  0.656  0.099  1.0
  O  O13  1  0.953  0.887  0.973  1.0
  O  O14  1  0.320  0.878  0.875  1.0
  O  O15  1  0.680  0.122  0.125  1.0
  O  O16  1  0.580  0.568  0.441  1.0
  O  O17  1  0.887  0.953  0.473  1.0
  O  O18  1  0.568  0.580  0.941  1.0
  O  O19  1  0.979  0.567  0.238  1.0
  O  O20  1  0.433  0.021  0.262  1.0
  O  O21  1  0.301  0.188  0.626  1.0
  O  O22  1  0.699  0.812  0.374  1.0
  O  O23  1  0.113  0.047  0.527  1.0
  O  O24  1  0.420  0.432  0.559  1.0
  O  O25  1  0.656  0.170  0.599  1.0
  O  O26  1  0.830  0.344  0.901  1.0
  O  O27  1  0.344  0.830  0.401  1.0
  O  O28  1  0.567  0.979  0.738  1.0
  O  O29  1  0.878  0.320  0.375  1.0
  O  O30  1  0.188  0.301  0.126  1.0
  O  O31  1  0.812  0.699  0.874  1.0
  O  O32  1  0.021  0.433  0.762  1.0
  O  O33  1  0.122  0.680  0.625  1.0
  O  O34  1  0.432  0.420  0.059  1.0
  O  O35  1  0.047  0.113  0.027  1.0
[/CIF]
.