The compound described by P4SO6 is beta Np structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four P4SO6 clusters. There are four inequivalent P sites. In the first P site, P(1) is bonded in a distorted trigonal non-coplanar geometry to one O(2), one O(3), and one O(5) atom. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(3), and one O(4) atom. In the third P site, P(3) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(6) atom. In the fourth P site, P(4) is bonded in a distorted tetrahedral geometry to one S(1), one O(4), one O(5), and one O(6) atom. S(1) is bonded in a single-bond geometry to one P(4) atom. There are six inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one P(2) and one P(4) atom. In the second O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(4) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to one P(3) and one P(4) atom. In the fourth O site, O(1) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the fifth O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. is represented by the CIF card [CIF]
data_P4SO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.787
_cell_length_b   8.482
_cell_length_c   10.311
_cell_angle_alpha   89.887
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   855.918
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.490  0.185  0.120  1.0
  P  P1  1  0.990  0.815  0.380  1.0
  P  P2  1  0.510  0.815  0.880  1.0
  P  P3  1  0.010  0.185  0.620  1.0
  P  P4  1  0.301  0.196  0.346  1.0
  P  P5  1  0.801  0.804  0.154  1.0
  P  P6  1  0.699  0.804  0.654  1.0
  P  P7  1  0.199  0.196  0.846  1.0
  P  P8  1  0.602  0.206  0.388  1.0
  P  P9  1  0.102  0.794  0.112  1.0
  P  P10  1  0.398  0.794  0.612  1.0
  P  P11  1  0.898  0.206  0.888  1.0
  P  P12  1  0.459  0.473  0.272  1.0
  P  P13  1  0.959  0.527  0.228  1.0
  P  P14  1  0.541  0.527  0.728  1.0
  P  P15  1  0.041  0.473  0.772  1.0
  S  S16  1  0.454  0.697  0.261  1.0
  S  S17  1  0.954  0.303  0.239  1.0
  S  S18  1  0.546  0.303  0.739  1.0
  S  S19  1  0.046  0.697  0.761  1.0
  O  O20  1  0.443  0.155  0.427  1.0
  O  O21  1  0.943  0.845  0.073  1.0
  O  O22  1  0.557  0.845  0.573  1.0
  O  O23  1  0.057  0.155  0.927  1.0
  O  O24  1  0.604  0.146  0.234  1.0
  O  O25  1  0.104  0.854  0.266  1.0
  O  O26  1  0.396  0.854  0.766  1.0
  O  O27  1  0.896  0.146  0.734  1.0
  O  O28  1  0.346  0.138  0.198  1.0
  O  O29  1  0.846  0.862  0.302  1.0
  O  O30  1  0.654  0.862  0.802  1.0
  O  O31  1  0.154  0.138  0.698  1.0
  O  O32  1  0.322  0.392  0.328  1.0
  O  O33  1  0.822  0.608  0.172  1.0
  O  O34  1  0.678  0.608  0.672  1.0
  O  O35  1  0.178  0.392  0.828  1.0
  O  O36  1  0.482  0.383  0.136  1.0
  O  O37  1  0.982  0.617  0.364  1.0
  O  O38  1  0.518  0.617  0.864  1.0
  O  O39  1  0.018  0.383  0.636  1.0
  O  O40  1  0.922  0.401  0.864  1.0
  O  O41  1  0.422  0.599  0.636  1.0
  O  O42  1  0.078  0.599  0.136  1.0
  O  O43  1  0.578  0.401  0.364  1.0
[/CIF]
.
The compound described by P4SO6 is beta Np structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four P4SO6 clusters. There are four inequivalent P sites. In the first P site, P(1) is bonded in a distorted trigonal non-coplanar geometry to one O(2), one O(3), and one O(5) atom. In the second P site, P(2) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(3), and one O(4) atom. In the third P site, P(3) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(6) atom. In the fourth P site, P(4) is bonded in a distorted tetrahedral geometry to one S(1), one O(4), one O(5), and one O(6) atom. S(1) is bonded in a single-bond geometry to one P(4) atom. There are six inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one P(2) and one P(4) atom. In the second O site, O(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(4) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to one P(3) and one P(4) atom. In the fourth O site, O(1) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the fifth O site, O(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the sixth O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. is represented by the CIF card [CIF]
data_P4SO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.787
_cell_length_b   8.482
_cell_length_c   10.311
_cell_angle_alpha   89.887
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   855.918
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.490  0.185  0.120  1.0
  P  P1  1  0.990  0.815  0.380  1.0
  P  P2  1  0.510  0.815  0.880  1.0
  P  P3  1  0.010  0.185  0.620  1.0
  P  P4  1  0.301  0.196  0.346  1.0
  P  P5  1  0.801  0.804  0.154  1.0
  P  P6  1  0.699  0.804  0.654  1.0
  P  P7  1  0.199  0.196  0.846  1.0
  P  P8  1  0.602  0.206  0.388  1.0
  P  P9  1  0.102  0.794  0.112  1.0
  P  P10  1  0.398  0.794  0.612  1.0
  P  P11  1  0.898  0.206  0.888  1.0
  P  P12  1  0.459  0.473  0.272  1.0
  P  P13  1  0.959  0.527  0.228  1.0
  P  P14  1  0.541  0.527  0.728  1.0
  P  P15  1  0.041  0.473  0.772  1.0
  S  S16  1  0.454  0.697  0.261  1.0
  S  S17  1  0.954  0.303  0.239  1.0
  S  S18  1  0.546  0.303  0.739  1.0
  S  S19  1  0.046  0.697  0.761  1.0
  O  O20  1  0.443  0.155  0.427  1.0
  O  O21  1  0.943  0.845  0.073  1.0
  O  O22  1  0.557  0.845  0.573  1.0
  O  O23  1  0.057  0.155  0.927  1.0
  O  O24  1  0.604  0.146  0.234  1.0
  O  O25  1  0.104  0.854  0.266  1.0
  O  O26  1  0.396  0.854  0.766  1.0
  O  O27  1  0.896  0.146  0.734  1.0
  O  O28  1  0.346  0.138  0.198  1.0
  O  O29  1  0.846  0.862  0.302  1.0
  O  O30  1  0.654  0.862  0.802  1.0
  O  O31  1  0.154  0.138  0.698  1.0
  O  O32  1  0.322  0.392  0.328  1.0
  O  O33  1  0.822  0.608  0.172  1.0
  O  O34  1  0.678  0.608  0.672  1.0
  O  O35  1  0.178  0.392  0.828  1.0
  O  O36  1  0.482  0.383  0.136  1.0
  O  O37  1  0.982  0.617  0.364  1.0
  O  O38  1  0.518  0.617  0.864  1.0
  O  O39  1  0.018  0.383  0.636  1.0
  O  O40  1  0.922  0.401  0.864  1.0
  O  O41  1  0.422  0.599  0.636  1.0
  O  O42  1  0.078  0.599  0.136  1.0
  O  O43  1  0.578  0.401  0.364  1.0
[/CIF]
.