The material structure described by ZnSb2O5 crystallizes in the orthorhombic Cmcm space group. Zn(1) is bonded to two equivalent O(1) and two equivalent O(3) atoms to form corner-sharing ZnO4 tetrahedra. Sb(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), and three equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Zn(1) and two equivalent Sb(1) atoms to form corner-sharing OZn2Sb2 tetrahedra. In the second O site, O(2) is bonded in a 3-coordinate geometry to three equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. is represented by the CIF card [CIF]
data_ZnSb2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.472
_cell_length_b   5.472
_cell_length_c   13.295
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   137.337
_symmetry_Int_Tables_number   1
_cell_volume   269.786
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.083  0.917  0.750  1.0
  Zn  Zn1  1  0.917  0.083  0.250  1.0
  Sb  Sb2  1  0.793  0.207  0.607  1.0
  Sb  Sb3  1  0.207  0.793  0.393  1.0
  Sb  Sb4  1  0.207  0.793  0.107  1.0
  Sb  Sb5  1  0.793  0.207  0.893  1.0
  O  O6  1  0.303  0.697  0.250  1.0
  O  O7  1  0.697  0.303  0.750  1.0
  O  O8  1  0.752  0.248  0.084  1.0
  O  O9  1  0.248  0.752  0.916  1.0
  O  O10  1  0.248  0.752  0.584  1.0
  O  O11  1  0.752  0.248  0.416  1.0
  O  O12  1  0.975  0.025  0.632  1.0
  O  O13  1  0.025  0.975  0.368  1.0
  O  O14  1  0.975  0.025  0.868  1.0
  O  O15  1  0.025  0.975  0.132  1.0
[/CIF]
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The material structure described by ZnSb2O5 crystallizes in the orthorhombic Cmcm space group. Zn(1) is bonded to two equivalent O(1) and two equivalent O(3) atoms to form corner-sharing ZnO4 tetrahedra. Sb(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), and three equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Zn(1) and two equivalent Sb(1) atoms to form corner-sharing OZn2Sb2 tetrahedra. In the second O site, O(2) is bonded in a 3-coordinate geometry to three equivalent Sb(1) atoms. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one Sb(1) atom. is represented by the CIF card [CIF]
data_ZnSb2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.472
_cell_length_b   5.472
_cell_length_c   13.295
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   137.337
_symmetry_Int_Tables_number   1
_cell_volume   269.786
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.083  0.917  0.750  1.0
  Zn  Zn1  1  0.917  0.083  0.250  1.0
  Sb  Sb2  1  0.793  0.207  0.607  1.0
  Sb  Sb3  1  0.207  0.793  0.393  1.0
  Sb  Sb4  1  0.207  0.793  0.107  1.0
  Sb  Sb5  1  0.793  0.207  0.893  1.0
  O  O6  1  0.303  0.697  0.250  1.0
  O  O7  1  0.697  0.303  0.750  1.0
  O  O8  1  0.752  0.248  0.084  1.0
  O  O9  1  0.248  0.752  0.916  1.0
  O  O10  1  0.248  0.752  0.584  1.0
  O  O11  1  0.752  0.248  0.416  1.0
  O  O12  1  0.975  0.025  0.632  1.0
  O  O13  1  0.025  0.975  0.368  1.0
  O  O14  1  0.975  0.025  0.868  1.0
  O  O15  1  0.025  0.975  0.132  1.0
[/CIF]
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