The structure described by DyTa7O19 crystallizes in the hexagonal P-6c2 space group. Dy(1) is bonded in a 8-coordinate geometry to two equivalent O(1) and six equivalent O(5) atoms. There are two inequivalent Ta sites. In the first Ta site, Ta(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(4), one O(5), and three equivalent O(3) atoms. In the second Ta site, Ta(2) is bonded in an octahedral geometry to six equivalent O(5) atoms. There are five inequivalent O sites. In the first O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent Ta(1) atoms. In the second O site, O(5) is bonded in a distorted trigonal planar geometry to one Dy(1), one Ta(1), and one Ta(2) atom. In the third O site, O(1) is bonded to one Dy(1) and three equivalent Ta(1) atoms to form distorted corner-sharing ODyTa3 tetrahedra. In the fourth O site, O(2) is bonded in a trigonal planar geometry to three equivalent Ta(1) atoms. In the fifth O site, O(3) is bonded in a distorted bent 150 degrees geometry to three equivalent Ta(1) atoms. is represented by the CIF file [CIF]
data_DyTa7O19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.270
_cell_length_b   6.270
_cell_length_c   20.076
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   683.416
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.000  0.500  1.0
  Dy  Dy1  1  0.000  0.000  0.000  1.0
  Ta  Ta2  1  0.307  0.974  0.655  1.0
  Ta  Ta3  1  0.026  0.693  0.345  1.0
  Ta  Ta4  1  0.026  0.334  0.655  1.0
  Ta  Ta5  1  0.666  0.693  0.655  1.0
  Ta  Ta6  1  0.026  0.334  0.845  1.0
  Ta  Ta7  1  0.666  0.693  0.845  1.0
  Ta  Ta8  1  0.307  0.974  0.845  1.0
  Ta  Ta9  1  0.666  0.974  0.155  1.0
  Ta  Ta10  1  0.307  0.334  0.155  1.0
  Ta  Ta11  1  0.307  0.334  0.345  1.0
  Ta  Ta12  1  0.666  0.974  0.345  1.0
  Ta  Ta13  1  0.026  0.693  0.155  1.0
  Ta  Ta14  1  0.333  0.667  0.500  1.0
  Ta  Ta15  1  0.333  0.667  0.000  1.0
  O  O16  1  0.000  0.000  0.631  1.0
  O  O17  1  0.000  0.000  0.869  1.0
  O  O18  1  0.000  0.000  0.369  1.0
  O  O19  1  0.000  0.000  0.131  1.0
  O  O20  1  0.333  0.667  0.666  1.0
  O  O21  1  0.333  0.667  0.834  1.0
  O  O22  1  0.333  0.667  0.334  1.0
  O  O23  1  0.333  0.667  0.166  1.0
  O  O24  1  0.421  0.334  0.653  1.0
  O  O25  1  0.666  0.579  0.347  1.0
  O  O26  1  0.666  0.088  0.653  1.0
  O  O27  1  0.912  0.579  0.653  1.0
  O  O28  1  0.666  0.088  0.847  1.0
  O  O29  1  0.912  0.579  0.847  1.0
  O  O30  1  0.421  0.334  0.847  1.0
  O  O31  1  0.912  0.334  0.153  1.0
  O  O32  1  0.043  0.751  0.250  1.0
  O  O33  1  0.708  0.957  0.250  1.0
  O  O34  1  0.249  0.292  0.250  1.0
  O  O35  1  0.249  0.957  0.750  1.0
  O  O36  1  0.708  0.751  0.750  1.0
  O  O37  1  0.043  0.292  0.750  1.0
  O  O38  1  0.097  0.719  0.056  1.0
  O  O39  1  0.623  0.903  0.444  1.0
  O  O40  1  0.281  0.377  0.444  1.0
  O  O41  1  0.281  0.377  0.056  1.0
  O  O42  1  0.623  0.903  0.056  1.0
  O  O43  1  0.281  0.903  0.944  1.0
  O  O44  1  0.623  0.719  0.944  1.0
  O  O45  1  0.097  0.377  0.944  1.0
  O  O46  1  0.623  0.719  0.556  1.0
  O  O47  1  0.097  0.377  0.556  1.0
  O  O48  1  0.097  0.719  0.444  1.0
  O  O49  1  0.281  0.903  0.556  1.0
  O  O50  1  0.666  0.579  0.153  1.0
  O  O51  1  0.912  0.334  0.347  1.0
  O  O52  1  0.421  0.088  0.347  1.0
  O  O53  1  0.421  0.088  0.153  1.0
[/CIF]
.
The structure described by DyTa7O19 crystallizes in the hexagonal P-6c2 space group. Dy(1) is bonded in a 8-coordinate geometry to two equivalent O(1) and six equivalent O(5) atoms. There are two inequivalent Ta sites. In the first Ta site, Ta(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(4), one O(5), and three equivalent O(3) atoms. In the second Ta site, Ta(2) is bonded in an octahedral geometry to six equivalent O(5) atoms. There are five inequivalent O sites. In the first O site, O(4) is bonded in a bent 150 degrees geometry to two equivalent Ta(1) atoms. In the second O site, O(5) is bonded in a distorted trigonal planar geometry to one Dy(1), one Ta(1), and one Ta(2) atom. In the third O site, O(1) is bonded to one Dy(1) and three equivalent Ta(1) atoms to form distorted corner-sharing ODyTa3 tetrahedra. In the fourth O site, O(2) is bonded in a trigonal planar geometry to three equivalent Ta(1) atoms. In the fifth O site, O(3) is bonded in a distorted bent 150 degrees geometry to three equivalent Ta(1) atoms. is represented by the CIF file [CIF]
data_DyTa7O19
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.270
_cell_length_b   6.270
_cell_length_c   20.076
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   683.416
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.000  0.500  1.0
  Dy  Dy1  1  0.000  0.000  0.000  1.0
  Ta  Ta2  1  0.307  0.974  0.655  1.0
  Ta  Ta3  1  0.026  0.693  0.345  1.0
  Ta  Ta4  1  0.026  0.334  0.655  1.0
  Ta  Ta5  1  0.666  0.693  0.655  1.0
  Ta  Ta6  1  0.026  0.334  0.845  1.0
  Ta  Ta7  1  0.666  0.693  0.845  1.0
  Ta  Ta8  1  0.307  0.974  0.845  1.0
  Ta  Ta9  1  0.666  0.974  0.155  1.0
  Ta  Ta10  1  0.307  0.334  0.155  1.0
  Ta  Ta11  1  0.307  0.334  0.345  1.0
  Ta  Ta12  1  0.666  0.974  0.345  1.0
  Ta  Ta13  1  0.026  0.693  0.155  1.0
  Ta  Ta14  1  0.333  0.667  0.500  1.0
  Ta  Ta15  1  0.333  0.667  0.000  1.0
  O  O16  1  0.000  0.000  0.631  1.0
  O  O17  1  0.000  0.000  0.869  1.0
  O  O18  1  0.000  0.000  0.369  1.0
  O  O19  1  0.000  0.000  0.131  1.0
  O  O20  1  0.333  0.667  0.666  1.0
  O  O21  1  0.333  0.667  0.834  1.0
  O  O22  1  0.333  0.667  0.334  1.0
  O  O23  1  0.333  0.667  0.166  1.0
  O  O24  1  0.421  0.334  0.653  1.0
  O  O25  1  0.666  0.579  0.347  1.0
  O  O26  1  0.666  0.088  0.653  1.0
  O  O27  1  0.912  0.579  0.653  1.0
  O  O28  1  0.666  0.088  0.847  1.0
  O  O29  1  0.912  0.579  0.847  1.0
  O  O30  1  0.421  0.334  0.847  1.0
  O  O31  1  0.912  0.334  0.153  1.0
  O  O32  1  0.043  0.751  0.250  1.0
  O  O33  1  0.708  0.957  0.250  1.0
  O  O34  1  0.249  0.292  0.250  1.0
  O  O35  1  0.249  0.957  0.750  1.0
  O  O36  1  0.708  0.751  0.750  1.0
  O  O37  1  0.043  0.292  0.750  1.0
  O  O38  1  0.097  0.719  0.056  1.0
  O  O39  1  0.623  0.903  0.444  1.0
  O  O40  1  0.281  0.377  0.444  1.0
  O  O41  1  0.281  0.377  0.056  1.0
  O  O42  1  0.623  0.903  0.056  1.0
  O  O43  1  0.281  0.903  0.944  1.0
  O  O44  1  0.623  0.719  0.944  1.0
  O  O45  1  0.097  0.377  0.944  1.0
  O  O46  1  0.623  0.719  0.556  1.0
  O  O47  1  0.097  0.377  0.556  1.0
  O  O48  1  0.097  0.719  0.444  1.0
  O  O49  1  0.281  0.903  0.556  1.0
  O  O50  1  0.666  0.579  0.153  1.0
  O  O51  1  0.912  0.334  0.347  1.0
  O  O52  1  0.421  0.088  0.347  1.0
  O  O53  1  0.421  0.088  0.153  1.0
[/CIF]
.