The structure described by KOICl2 crystallizes in the monoclinic P2_1/m space group. K(1) is bonded in a 6-coordinate geometry to six equivalent Cl(1) atoms. O(1) is bonded in a bent 120 degrees geometry to two equivalent I(1) atoms. I(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent Cl(1) atoms. Cl(1) is bonded to three equivalent K(1) and one I(1) atom to form a mixture of corner and edge-sharing ClK3I trigonal pyramids. is represented by the CIF card [CIF]
data_KICl2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.611
_cell_length_b   4.899
_cell_length_c   8.360
_cell_angle_alpha   78.270
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   305.220
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.209  0.400  1.0
  K  K1  1  0.750  0.791  0.600  1.0
  I  I2  1  0.500  0.000  0.000  1.0
  I  I3  1  0.000  0.000  0.000  1.0
  Cl  Cl4  1  0.503  0.262  0.693  1.0
  Cl  Cl5  1  0.003  0.738  0.307  1.0
  Cl  Cl6  1  0.497  0.738  0.307  1.0
  Cl  Cl7  1  0.997  0.262  0.693  1.0
  O  O8  1  0.250  0.840  0.968  1.0
  O  O9  1  0.750  0.160  0.032  1.0
[/CIF]
.
The structure described by KOICl2 crystallizes in the monoclinic P2_1/m space group. K(1) is bonded in a 6-coordinate geometry to six equivalent Cl(1) atoms. O(1) is bonded in a bent 120 degrees geometry to two equivalent I(1) atoms. I(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent Cl(1) atoms. Cl(1) is bonded to three equivalent K(1) and one I(1) atom to form a mixture of corner and edge-sharing ClK3I trigonal pyramids. is represented by the CIF card [CIF]
data_KICl2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.611
_cell_length_b   4.899
_cell_length_c   8.360
_cell_angle_alpha   78.270
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   305.220
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.250  0.209  0.400  1.0
  K  K1  1  0.750  0.791  0.600  1.0
  I  I2  1  0.500  0.000  0.000  1.0
  I  I3  1  0.000  0.000  0.000  1.0
  Cl  Cl4  1  0.503  0.262  0.693  1.0
  Cl  Cl5  1  0.003  0.738  0.307  1.0
  Cl  Cl6  1  0.497  0.738  0.307  1.0
  Cl  Cl7  1  0.997  0.262  0.693  1.0
  O  O8  1  0.250  0.840  0.968  1.0
  O  O9  1  0.750  0.160  0.032  1.0
[/CIF]
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