The material structure described by ReNF6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ReNF6 clusters. Re(1) is bonded in an octahedral geometry to one N(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. N(1) is bonded in a linear geometry to one Re(1) and one F(1) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one N(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Re(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Re(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Re(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_ReNF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.594
_cell_length_b   5.458
_cell_length_c   10.285
_cell_angle_alpha   70.354
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   507.156
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.610  0.688  0.715  1.0
  Re  Re1  1  0.110  0.312  0.785  1.0
  Re  Re2  1  0.390  0.312  0.285  1.0
  Re  Re3  1  0.890  0.688  0.215  1.0
  N  N4  1  0.725  0.905  0.602  1.0
  N  N5  1  0.225  0.095  0.898  1.0
  N  N6  1  0.275  0.095  0.398  1.0
  N  N7  1  0.775  0.905  0.102  1.0
  F  F8  1  0.685  0.056  0.020  1.0
  F  F9  1  0.185  0.944  0.480  1.0
  F  F10  1  0.315  0.944  0.980  1.0
  F  F11  1  0.815  0.056  0.520  1.0
  F  F12  1  0.010  0.442  0.341  1.0
  F  F13  1  0.510  0.558  0.159  1.0
  F  F14  1  0.990  0.558  0.659  1.0
  F  F15  1  0.490  0.442  0.841  1.0
  F  F16  1  0.803  0.389  0.201  1.0
  F  F17  1  0.303  0.611  0.299  1.0
  F  F18  1  0.197  0.611  0.799  1.0
  F  F19  1  0.697  0.389  0.701  1.0
  F  F20  1  0.786  0.662  0.374  1.0
  F  F21  1  0.286  0.338  0.126  1.0
  F  F22  1  0.214  0.338  0.626  1.0
  F  F23  1  0.714  0.662  0.874  1.0
  F  F24  1  0.002  0.942  0.250  1.0
  F  F25  1  0.502  0.058  0.250  1.0
  F  F26  1  0.998  0.058  0.750  1.0
  F  F27  1  0.498  0.942  0.750  1.0
  F  F28  1  0.020  0.681  0.079  1.0
  F  F29  1  0.520  0.319  0.421  1.0
  F  F30  1  0.980  0.319  0.921  1.0
  F  F31  1  0.480  0.681  0.579  1.0
[/CIF]
.
The material structure described by ReNF6 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four ReNF6 clusters. Re(1) is bonded in an octahedral geometry to one N(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. N(1) is bonded in a linear geometry to one Re(1) and one F(1) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one N(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Re(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Re(1) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one Re(1) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_ReNF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.594
_cell_length_b   5.458
_cell_length_c   10.285
_cell_angle_alpha   70.354
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   507.156
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.610  0.688  0.715  1.0
  Re  Re1  1  0.110  0.312  0.785  1.0
  Re  Re2  1  0.390  0.312  0.285  1.0
  Re  Re3  1  0.890  0.688  0.215  1.0
  N  N4  1  0.725  0.905  0.602  1.0
  N  N5  1  0.225  0.095  0.898  1.0
  N  N6  1  0.275  0.095  0.398  1.0
  N  N7  1  0.775  0.905  0.102  1.0
  F  F8  1  0.685  0.056  0.020  1.0
  F  F9  1  0.185  0.944  0.480  1.0
  F  F10  1  0.315  0.944  0.980  1.0
  F  F11  1  0.815  0.056  0.520  1.0
  F  F12  1  0.010  0.442  0.341  1.0
  F  F13  1  0.510  0.558  0.159  1.0
  F  F14  1  0.990  0.558  0.659  1.0
  F  F15  1  0.490  0.442  0.841  1.0
  F  F16  1  0.803  0.389  0.201  1.0
  F  F17  1  0.303  0.611  0.299  1.0
  F  F18  1  0.197  0.611  0.799  1.0
  F  F19  1  0.697  0.389  0.701  1.0
  F  F20  1  0.786  0.662  0.374  1.0
  F  F21  1  0.286  0.338  0.126  1.0
  F  F22  1  0.214  0.338  0.626  1.0
  F  F23  1  0.714  0.662  0.874  1.0
  F  F24  1  0.002  0.942  0.250  1.0
  F  F25  1  0.502  0.058  0.250  1.0
  F  F26  1  0.998  0.058  0.750  1.0
  F  F27  1  0.498  0.942  0.750  1.0
  F  F28  1  0.020  0.681  0.079  1.0
  F  F29  1  0.520  0.319  0.421  1.0
  F  F30  1  0.980  0.319  0.921  1.0
  F  F31  1  0.480  0.681  0.579  1.0
[/CIF]
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