The material structure described by CuH3(CO2)3(CH3)2NH2 crystallizes in the monoclinic C2/c space group. The structure consists of four dimethylazanium molecules inside a CuH3(CO2)3 framework. In the CuH3(CO2)3 framework, Cu(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one H(6), one O(2), and one O(3) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one H(5) and two equivalent O(1) atoms. There are two inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cu(1) and one C(1) atom. is represented by the CIF file [CIF]
data_CuH11C5NO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.222
_cell_length_b   8.222
_cell_length_c   8.911
_cell_angle_alpha   61.957
_cell_angle_beta   61.957
_cell_angle_gamma   65.117
_symmetry_Int_Tables_number   1
_cell_volume   453.579
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.000  0.500  0.000  1.0
  Cu  Cu1  1  0.500  0.000  0.500  1.0
  H  H2  1  0.680  0.450  0.741  1.0
  H  H3  1  0.550  0.320  0.759  1.0
  H  H4  1  0.320  0.550  0.259  1.0
  H  H5  1  0.450  0.680  0.241  1.0
  H  H6  1  0.974  0.272  0.575  1.0
  H  H7  1  0.728  0.026  0.925  1.0
  H  H8  1  0.026  0.728  0.425  1.0
  H  H9  1  0.272  0.974  0.075  1.0
  H  H10  1  0.843  0.138  0.588  1.0
  H  H11  1  0.862  0.157  0.912  1.0
  H  H12  1  0.157  0.862  0.412  1.0
  H  H13  1  0.138  0.843  0.088  1.0
  H  H14  1  0.798  0.389  0.465  1.0
  H  H15  1  0.611  0.202  0.035  1.0
  H  H16  1  0.202  0.611  0.535  1.0
  H  H17  1  0.389  0.798  0.965  1.0
  H  H18  1  0.664  0.336  0.250  1.0
  H  H19  1  0.336  0.664  0.750  1.0
  H  H20  1  0.239  0.185  0.228  1.0
  H  H21  1  0.815  0.761  0.272  1.0
  H  H22  1  0.761  0.815  0.772  1.0
  H  H23  1  0.185  0.239  0.728  1.0
  C  C24  1  0.241  0.321  0.223  1.0
  C  C25  1  0.679  0.759  0.277  1.0
  C  C26  1  0.759  0.679  0.777  1.0
  C  C27  1  0.321  0.241  0.723  1.0
  C  C28  1  0.789  0.211  0.250  1.0
  C  C29  1  0.211  0.789  0.750  1.0
  C  C30  1  0.835  0.277  0.583  1.0
  C  C31  1  0.723  0.165  0.917  1.0
  C  C32  1  0.165  0.723  0.417  1.0
  C  C33  1  0.277  0.835  0.083  1.0
  N  N34  1  0.686  0.314  0.750  1.0
  N  N35  1  0.314  0.686  0.250  1.0
  O  O36  1  0.955  0.238  0.161  1.0
  O  O37  1  0.762  0.045  0.339  1.0
  O  O38  1  0.045  0.762  0.839  1.0
  O  O39  1  0.238  0.955  0.661  1.0
  O  O40  1  0.145  0.477  0.137  1.0
  O  O41  1  0.523  0.855  0.363  1.0
  O  O42  1  0.855  0.523  0.863  1.0
  O  O43  1  0.477  0.145  0.637  1.0
  O  O44  1  0.337  0.317  0.302  1.0
  O  O45  1  0.683  0.663  0.198  1.0
  O  O46  1  0.663  0.683  0.698  1.0
  O  O47  1  0.317  0.337  0.802  1.0
[/CIF]
.
The material structure described by CuH3(CO2)3(CH3)2NH2 crystallizes in the monoclinic C2/c space group. The structure consists of four dimethylazanium molecules inside a CuH3(CO2)3 framework. In the CuH3(CO2)3 framework, Cu(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one H(6), one O(2), and one O(3) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one H(5) and two equivalent O(1) atoms. There are two inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cu(1) and one C(1) atom. is represented by the CIF file [CIF]
data_CuH11C5NO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.222
_cell_length_b   8.222
_cell_length_c   8.911
_cell_angle_alpha   61.957
_cell_angle_beta   61.957
_cell_angle_gamma   65.117
_symmetry_Int_Tables_number   1
_cell_volume   453.579
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.000  0.500  0.000  1.0
  Cu  Cu1  1  0.500  0.000  0.500  1.0
  H  H2  1  0.680  0.450  0.741  1.0
  H  H3  1  0.550  0.320  0.759  1.0
  H  H4  1  0.320  0.550  0.259  1.0
  H  H5  1  0.450  0.680  0.241  1.0
  H  H6  1  0.974  0.272  0.575  1.0
  H  H7  1  0.728  0.026  0.925  1.0
  H  H8  1  0.026  0.728  0.425  1.0
  H  H9  1  0.272  0.974  0.075  1.0
  H  H10  1  0.843  0.138  0.588  1.0
  H  H11  1  0.862  0.157  0.912  1.0
  H  H12  1  0.157  0.862  0.412  1.0
  H  H13  1  0.138  0.843  0.088  1.0
  H  H14  1  0.798  0.389  0.465  1.0
  H  H15  1  0.611  0.202  0.035  1.0
  H  H16  1  0.202  0.611  0.535  1.0
  H  H17  1  0.389  0.798  0.965  1.0
  H  H18  1  0.664  0.336  0.250  1.0
  H  H19  1  0.336  0.664  0.750  1.0
  H  H20  1  0.239  0.185  0.228  1.0
  H  H21  1  0.815  0.761  0.272  1.0
  H  H22  1  0.761  0.815  0.772  1.0
  H  H23  1  0.185  0.239  0.728  1.0
  C  C24  1  0.241  0.321  0.223  1.0
  C  C25  1  0.679  0.759  0.277  1.0
  C  C26  1  0.759  0.679  0.777  1.0
  C  C27  1  0.321  0.241  0.723  1.0
  C  C28  1  0.789  0.211  0.250  1.0
  C  C29  1  0.211  0.789  0.750  1.0
  C  C30  1  0.835  0.277  0.583  1.0
  C  C31  1  0.723  0.165  0.917  1.0
  C  C32  1  0.165  0.723  0.417  1.0
  C  C33  1  0.277  0.835  0.083  1.0
  N  N34  1  0.686  0.314  0.750  1.0
  N  N35  1  0.314  0.686  0.250  1.0
  O  O36  1  0.955  0.238  0.161  1.0
  O  O37  1  0.762  0.045  0.339  1.0
  O  O38  1  0.045  0.762  0.839  1.0
  O  O39  1  0.238  0.955  0.661  1.0
  O  O40  1  0.145  0.477  0.137  1.0
  O  O41  1  0.523  0.855  0.363  1.0
  O  O42  1  0.855  0.523  0.863  1.0
  O  O43  1  0.477  0.145  0.637  1.0
  O  O44  1  0.337  0.317  0.302  1.0
  O  O45  1  0.683  0.663  0.198  1.0
  O  O46  1  0.663  0.683  0.698  1.0
  O  O47  1  0.317  0.337  0.802  1.0
[/CIF]
.