The crystal structure described by Cs2LiVS4 crystallizes in the orthorhombic Fddd space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Li(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. V(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. S(1) is bonded in a 2-coordinate geometry to four equivalent Cs(1), one Li(1), and one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs2LiVS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.228
_cell_length_b   12.733
_cell_length_c   7.608
_cell_angle_alpha   84.794
_cell_angle_beta   63.031
_cell_angle_gamma   32.175
_symmetry_Int_Tables_number   1
_cell_volume   514.443
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.823  0.823  0.177  1.0
  Cs  Cs1  1  0.427  0.427  0.073  1.0
  Cs  Cs2  1  0.177  0.177  0.823  1.0
  Cs  Cs3  1  0.073  0.073  0.427  1.0
  Li  Li4  1  0.500  0.500  0.500  1.0
  Li  Li5  1  0.750  0.750  0.750  1.0
  V  V6  1  0.000  0.000  0.000  1.0
  V  V7  1  0.250  0.250  0.250  1.0
  S  S8  1  0.503  0.897  0.175  1.0
  S  S9  1  0.897  0.503  0.425  1.0
  S  S10  1  0.825  0.075  0.353  1.0
  S  S11  1  0.075  0.825  0.747  1.0
  S  S12  1  0.175  0.425  0.503  1.0
  S  S13  1  0.425  0.175  0.897  1.0
  S  S14  1  0.353  0.747  0.825  1.0
  S  S15  1  0.747  0.353  0.075  1.0
[/CIF]
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The crystal structure described by Cs2LiVS4 crystallizes in the orthorhombic Fddd space group. Cs(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Li(1) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. V(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. S(1) is bonded in a 2-coordinate geometry to four equivalent Cs(1), one Li(1), and one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs2LiVS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.228
_cell_length_b   12.733
_cell_length_c   7.608
_cell_angle_alpha   84.794
_cell_angle_beta   63.031
_cell_angle_gamma   32.175
_symmetry_Int_Tables_number   1
_cell_volume   514.443
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.823  0.823  0.177  1.0
  Cs  Cs1  1  0.427  0.427  0.073  1.0
  Cs  Cs2  1  0.177  0.177  0.823  1.0
  Cs  Cs3  1  0.073  0.073  0.427  1.0
  Li  Li4  1  0.500  0.500  0.500  1.0
  Li  Li5  1  0.750  0.750  0.750  1.0
  V  V6  1  0.000  0.000  0.000  1.0
  V  V7  1  0.250  0.250  0.250  1.0
  S  S8  1  0.503  0.897  0.175  1.0
  S  S9  1  0.897  0.503  0.425  1.0
  S  S10  1  0.825  0.075  0.353  1.0
  S  S11  1  0.075  0.825  0.747  1.0
  S  S12  1  0.175  0.425  0.503  1.0
  S  S13  1  0.425  0.175  0.897  1.0
  S  S14  1  0.353  0.747  0.825  1.0
  S  S15  1  0.747  0.353  0.075  1.0
[/CIF]
.