The structure described by ZnTeO3 is Antimony trioxide-derived structured and crystallizes in the orthorhombic Pbca space group. Zn(1) is bonded to one O(3), two equivalent O(1), and two equivalent O(2) atoms to form a mixture of distorted edge and corner-sharing ZnO5 trigonal bipyramids. Te(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one Te(1) atom. In the second O site, O(1) is bonded in a trigonal planar geometry to two equivalent Zn(1) and one Te(1) atom. In the third O site, O(2) is bonded in a trigonal planar geometry to two equivalent Zn(1) and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnTeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.329
_cell_length_b   7.339
_cell_length_c   12.328
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   572.634
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.878  0.891  0.410  1.0
  Zn  Zn1  1  0.378  0.109  0.090  1.0
  Zn  Zn2  1  0.622  0.391  0.590  1.0
  Zn  Zn3  1  0.122  0.609  0.910  1.0
  Zn  Zn4  1  0.122  0.109  0.590  1.0
  Zn  Zn5  1  0.622  0.891  0.910  1.0
  Zn  Zn6  1  0.378  0.609  0.410  1.0
  Zn  Zn7  1  0.878  0.391  0.090  1.0
  Te  Te8  1  0.910  0.936  0.144  1.0
  Te  Te9  1  0.410  0.064  0.356  1.0
  Te  Te10  1  0.590  0.436  0.856  1.0
  Te  Te11  1  0.090  0.564  0.644  1.0
  Te  Te12  1  0.090  0.064  0.856  1.0
  Te  Te13  1  0.590  0.936  0.644  1.0
  Te  Te14  1  0.410  0.564  0.144  1.0
  Te  Te15  1  0.910  0.436  0.356  1.0
  O  O16  1  0.529  0.344  0.090  1.0
  O  O17  1  0.029  0.656  0.410  1.0
  O  O18  1  0.971  0.844  0.910  1.0
  O  O19  1  0.471  0.156  0.590  1.0
  O  O20  1  0.471  0.656  0.910  1.0
  O  O21  1  0.971  0.344  0.590  1.0
  O  O22  1  0.029  0.156  0.090  1.0
  O  O23  1  0.529  0.844  0.410  1.0
  O  O24  1  0.655  0.462  0.434  1.0
  O  O25  1  0.155  0.538  0.066  1.0
  O  O26  1  0.845  0.962  0.566  1.0
  O  O27  1  0.345  0.038  0.934  1.0
  O  O28  1  0.345  0.538  0.566  1.0
  O  O29  1  0.845  0.462  0.934  1.0
  O  O30  1  0.155  0.038  0.434  1.0
  O  O31  1  0.655  0.962  0.066  1.0
  O  O32  1  0.803  0.527  0.225  1.0
  O  O33  1  0.303  0.473  0.275  1.0
  O  O34  1  0.697  0.027  0.775  1.0
  O  O35  1  0.197  0.973  0.725  1.0
  O  O36  1  0.197  0.473  0.775  1.0
  O  O37  1  0.697  0.527  0.725  1.0
  O  O38  1  0.303  0.973  0.225  1.0
  O  O39  1  0.803  0.027  0.275  1.0
[/CIF]
.
The structure described by ZnTeO3 is Antimony trioxide-derived structured and crystallizes in the orthorhombic Pbca space group. Zn(1) is bonded to one O(3), two equivalent O(1), and two equivalent O(2) atoms to form a mixture of distorted edge and corner-sharing ZnO5 trigonal bipyramids. Te(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one Te(1) atom. In the second O site, O(1) is bonded in a trigonal planar geometry to two equivalent Zn(1) and one Te(1) atom. In the third O site, O(2) is bonded in a trigonal planar geometry to two equivalent Zn(1) and one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnTeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.329
_cell_length_b   7.339
_cell_length_c   12.328
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   572.634
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.878  0.891  0.410  1.0
  Zn  Zn1  1  0.378  0.109  0.090  1.0
  Zn  Zn2  1  0.622  0.391  0.590  1.0
  Zn  Zn3  1  0.122  0.609  0.910  1.0
  Zn  Zn4  1  0.122  0.109  0.590  1.0
  Zn  Zn5  1  0.622  0.891  0.910  1.0
  Zn  Zn6  1  0.378  0.609  0.410  1.0
  Zn  Zn7  1  0.878  0.391  0.090  1.0
  Te  Te8  1  0.910  0.936  0.144  1.0
  Te  Te9  1  0.410  0.064  0.356  1.0
  Te  Te10  1  0.590  0.436  0.856  1.0
  Te  Te11  1  0.090  0.564  0.644  1.0
  Te  Te12  1  0.090  0.064  0.856  1.0
  Te  Te13  1  0.590  0.936  0.644  1.0
  Te  Te14  1  0.410  0.564  0.144  1.0
  Te  Te15  1  0.910  0.436  0.356  1.0
  O  O16  1  0.529  0.344  0.090  1.0
  O  O17  1  0.029  0.656  0.410  1.0
  O  O18  1  0.971  0.844  0.910  1.0
  O  O19  1  0.471  0.156  0.590  1.0
  O  O20  1  0.471  0.656  0.910  1.0
  O  O21  1  0.971  0.344  0.590  1.0
  O  O22  1  0.029  0.156  0.090  1.0
  O  O23  1  0.529  0.844  0.410  1.0
  O  O24  1  0.655  0.462  0.434  1.0
  O  O25  1  0.155  0.538  0.066  1.0
  O  O26  1  0.845  0.962  0.566  1.0
  O  O27  1  0.345  0.038  0.934  1.0
  O  O28  1  0.345  0.538  0.566  1.0
  O  O29  1  0.845  0.462  0.934  1.0
  O  O30  1  0.155  0.038  0.434  1.0
  O  O31  1  0.655  0.962  0.066  1.0
  O  O32  1  0.803  0.527  0.225  1.0
  O  O33  1  0.303  0.473  0.275  1.0
  O  O34  1  0.697  0.027  0.775  1.0
  O  O35  1  0.197  0.973  0.725  1.0
  O  O36  1  0.197  0.473  0.775  1.0
  O  O37  1  0.697  0.527  0.725  1.0
  O  O38  1  0.303  0.973  0.225  1.0
  O  O39  1  0.803  0.027  0.275  1.0
[/CIF]
.