The structure described by Pt3V is Uranium Silicide-like structured and crystallizes in the tetragonal I4/mmm space group. V(1) is bonded to four equivalent Pt(2) and eight equivalent Pt(1) atoms to form VPt12 cuboctahedra that share corners with four equivalent V(1)Pt12 cuboctahedra, edges with eight equivalent V(1)Pt12 cuboctahedra, edges with sixteen equivalent Pt(1)V4Pt8 cuboctahedra, faces with four equivalent V(1)Pt12 cuboctahedra, and faces with eight equivalent Pt(1)V4Pt8 cuboctahedra. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded to four equivalent V(1), four equivalent Pt(1), and four equivalent Pt(2) atoms to form distorted PtV4Pt8 cuboctahedra that share corners with twelve equivalent Pt(1)V4Pt8 cuboctahedra, edges with eight equivalent V(1)Pt12 cuboctahedra, edges with eight equivalent Pt(1)V4Pt8 cuboctahedra, faces with four equivalent V(1)Pt12 cuboctahedra, and faces with ten equivalent Pt(1)V4Pt8 cuboctahedra. In the second Pt site, Pt(2) is bonded in a distorted square co-planar geometry to four equivalent V(1) and eight equivalent Pt(1) atoms. is represented by the CIF card [CIF]
data_VPt3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.870
_cell_length_b   3.870
_cell_length_c   4.803
_cell_angle_alpha   113.756
_cell_angle_beta   113.756
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   59.100
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  Pt  Pt1  1  0.250  0.750  0.500  1.0
  Pt  Pt2  1  0.750  0.250  0.500  1.0
  Pt  Pt3  1  0.500  0.500  0.000  1.0
[/CIF]
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The structure described by Pt3V is Uranium Silicide-like structured and crystallizes in the tetragonal I4/mmm space group. V(1) is bonded to four equivalent Pt(2) and eight equivalent Pt(1) atoms to form VPt12 cuboctahedra that share corners with four equivalent V(1)Pt12 cuboctahedra, edges with eight equivalent V(1)Pt12 cuboctahedra, edges with sixteen equivalent Pt(1)V4Pt8 cuboctahedra, faces with four equivalent V(1)Pt12 cuboctahedra, and faces with eight equivalent Pt(1)V4Pt8 cuboctahedra. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded to four equivalent V(1), four equivalent Pt(1), and four equivalent Pt(2) atoms to form distorted PtV4Pt8 cuboctahedra that share corners with twelve equivalent Pt(1)V4Pt8 cuboctahedra, edges with eight equivalent V(1)Pt12 cuboctahedra, edges with eight equivalent Pt(1)V4Pt8 cuboctahedra, faces with four equivalent V(1)Pt12 cuboctahedra, and faces with ten equivalent Pt(1)V4Pt8 cuboctahedra. In the second Pt site, Pt(2) is bonded in a distorted square co-planar geometry to four equivalent V(1) and eight equivalent Pt(1) atoms. is represented by the CIF card [CIF]
data_VPt3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.870
_cell_length_b   3.870
_cell_length_c   4.803
_cell_angle_alpha   113.756
_cell_angle_beta   113.756
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   59.100
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  Pt  Pt1  1  0.250  0.750  0.500  1.0
  Pt  Pt2  1  0.750  0.250  0.500  1.0
  Pt  Pt3  1  0.500  0.500  0.000  1.0
[/CIF]
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