The material structure described by TbMoO5 crystallizes in the monoclinic P2_1/c space group. Tb(1) is bonded in a 8-coordinate geometry to one O(4), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Tb(1), one Mo(1), and one O(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Tb(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Tb(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Tb(1) and one Mo(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Tb(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_TbMoO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.586
_cell_length_b   5.416
_cell_length_c   6.971
_cell_angle_alpha   63.101
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   423.792
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.057  0.656  0.716  1.0
  Tb  Tb1  1  0.943  0.344  0.284  1.0
  Tb  Tb2  1  0.557  0.344  0.784  1.0
  Tb  Tb3  1  0.443  0.656  0.216  1.0
  Mo  Mo4  1  0.364  0.917  0.643  1.0
  Mo  Mo5  1  0.636  0.083  0.357  1.0
  Mo  Mo6  1  0.864  0.083  0.857  1.0
  Mo  Mo7  1  0.136  0.917  0.143  1.0
  O  O8  1  0.444  0.464  0.983  1.0
  O  O9  1  0.556  0.536  0.017  1.0
  O  O10  1  0.944  0.536  0.517  1.0
  O  O11  1  0.056  0.464  0.483  1.0
  O  O12  1  0.926  0.988  0.659  1.0
  O  O13  1  0.074  0.012  0.341  1.0
  O  O14  1  0.426  0.012  0.841  1.0
  O  O15  1  0.574  0.988  0.159  1.0
  O  O16  1  0.439  0.704  0.542  1.0
  O  O17  1  0.561  0.296  0.458  1.0
  O  O18  1  0.939  0.296  0.958  1.0
  O  O19  1  0.061  0.704  0.042  1.0
  O  O20  1  0.233  0.787  0.722  1.0
  O  O21  1  0.767  0.213  0.278  1.0
  O  O22  1  0.733  0.213  0.778  1.0
  O  O23  1  0.267  0.787  0.222  1.0
  O  O24  1  0.655  0.762  0.585  1.0
  O  O25  1  0.345  0.238  0.415  1.0
  O  O26  1  0.155  0.238  0.915  1.0
  O  O27  1  0.845  0.762  0.085  1.0
[/CIF]
.
The material structure described by TbMoO5 crystallizes in the monoclinic P2_1/c space group. Tb(1) is bonded in a 8-coordinate geometry to one O(4), one O(5), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Tb(1), one Mo(1), and one O(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Tb(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Tb(1) and one Mo(1) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Tb(1) and one Mo(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Tb(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_TbMoO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.586
_cell_length_b   5.416
_cell_length_c   6.971
_cell_angle_alpha   63.101
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   423.792
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tb  Tb0  1  0.057  0.656  0.716  1.0
  Tb  Tb1  1  0.943  0.344  0.284  1.0
  Tb  Tb2  1  0.557  0.344  0.784  1.0
  Tb  Tb3  1  0.443  0.656  0.216  1.0
  Mo  Mo4  1  0.364  0.917  0.643  1.0
  Mo  Mo5  1  0.636  0.083  0.357  1.0
  Mo  Mo6  1  0.864  0.083  0.857  1.0
  Mo  Mo7  1  0.136  0.917  0.143  1.0
  O  O8  1  0.444  0.464  0.983  1.0
  O  O9  1  0.556  0.536  0.017  1.0
  O  O10  1  0.944  0.536  0.517  1.0
  O  O11  1  0.056  0.464  0.483  1.0
  O  O12  1  0.926  0.988  0.659  1.0
  O  O13  1  0.074  0.012  0.341  1.0
  O  O14  1  0.426  0.012  0.841  1.0
  O  O15  1  0.574  0.988  0.159  1.0
  O  O16  1  0.439  0.704  0.542  1.0
  O  O17  1  0.561  0.296  0.458  1.0
  O  O18  1  0.939  0.296  0.958  1.0
  O  O19  1  0.061  0.704  0.042  1.0
  O  O20  1  0.233  0.787  0.722  1.0
  O  O21  1  0.767  0.213  0.278  1.0
  O  O22  1  0.733  0.213  0.778  1.0
  O  O23  1  0.267  0.787  0.222  1.0
  O  O24  1  0.655  0.762  0.585  1.0
  O  O25  1  0.345  0.238  0.415  1.0
  O  O26  1  0.155  0.238  0.915  1.0
  O  O27  1  0.845  0.762  0.085  1.0
[/CIF]
.