The crystal structure described by V2P is Cotunnite structured and crystallizes in the orthorhombic Pnma space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. In the second V site, V(2) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to four equivalent V(2) and five equivalent V(1) atoms. is represented by the CIF file [CIF]
data_V2P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.262
_cell_length_b   6.143
_cell_length_c   7.530
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   150.902
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.750  0.041  0.333  1.0
  V  V1  1  0.250  0.959  0.667  1.0
  V  V2  1  0.750  0.541  0.167  1.0
  V  V3  1  0.250  0.459  0.833  1.0
  V  V4  1  0.250  0.361  0.442  1.0
  V  V5  1  0.750  0.639  0.558  1.0
  V  V6  1  0.250  0.861  0.058  1.0
  V  V7  1  0.750  0.139  0.942  1.0
  P  P8  1  0.250  0.748  0.357  1.0
  P  P9  1  0.750  0.252  0.643  1.0
  P  P10  1  0.250  0.248  0.143  1.0
  P  P11  1  0.750  0.752  0.857  1.0
[/CIF]
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The crystal structure described by V2P is Cotunnite structured and crystallizes in the orthorhombic Pnma space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to five equivalent P(1) atoms. In the second V site, V(2) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to four equivalent V(2) and five equivalent V(1) atoms. is represented by the CIF file [CIF]
data_V2P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.262
_cell_length_b   6.143
_cell_length_c   7.530
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   150.902
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.750  0.041  0.333  1.0
  V  V1  1  0.250  0.959  0.667  1.0
  V  V2  1  0.750  0.541  0.167  1.0
  V  V3  1  0.250  0.459  0.833  1.0
  V  V4  1  0.250  0.361  0.442  1.0
  V  V5  1  0.750  0.639  0.558  1.0
  V  V6  1  0.250  0.861  0.058  1.0
  V  V7  1  0.750  0.139  0.942  1.0
  P  P8  1  0.250  0.748  0.357  1.0
  P  P9  1  0.750  0.252  0.643  1.0
  P  P10  1  0.250  0.248  0.143  1.0
  P  P11  1  0.750  0.752  0.857  1.0
[/CIF]
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