The material structure described by AgCdVO4 crystallizes in the orthorhombic Pnma space group. V(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form VO4 tetrahedra that share corners with six equivalent Cd(1)O6 octahedra and corners with four equivalent Ag(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 45-53°. Ag(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form distorted AgO4 tetrahedra that share corners with six equivalent Cd(1)O6 octahedra and corners with four equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 76-81°. Cd(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form CdO6 octahedra that share corners with six equivalent V(1)O4 tetrahedra, corners with six equivalent Ag(1)O4 tetrahedra, and edges with two equivalent Cd(1)O6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded to one V(1), one Ag(1), and two equivalent Cd(1) atoms to form a mixture of distorted corner and edge-sharing OVCd2Ag trigonal pyramids. In the second O site, O(2) is bonded to one V(1), one Ag(1), and two equivalent Cd(1) atoms to form a mixture of distorted corner and edge-sharing OVCd2Ag tetrahedra. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1), one Ag(1), and one Cd(1) atom. is represented by the CIF file [CIF]
data_VCdAgO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.543
_cell_length_b   7.100
_cell_length_c   10.042
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   395.215
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.989  0.750  0.679  1.0
  V  V1  1  0.489  0.250  0.821  1.0
  V  V2  1  0.011  0.250  0.321  1.0
  V  V3  1  0.511  0.750  0.179  1.0
  Cd  Cd4  1  0.500  0.500  0.500  1.0
  Cd  Cd5  1  0.000  0.500  0.000  1.0
  Cd  Cd6  1  0.500  0.000  0.500  1.0
  Cd  Cd7  1  0.000  0.000  0.000  1.0
  Ag  Ag8  1  0.998  0.750  0.349  1.0
  Ag  Ag9  1  0.498  0.250  0.151  1.0
  Ag  Ag10  1  0.002  0.250  0.651  1.0
  Ag  Ag11  1  0.502  0.750  0.849  1.0
  O  O12  1  0.941  0.750  0.857  1.0
  O  O13  1  0.441  0.250  0.643  1.0
  O  O14  1  0.059  0.250  0.143  1.0
  O  O15  1  0.559  0.750  0.357  1.0
  O  O16  1  0.293  0.750  0.626  1.0
  O  O17  1  0.793  0.250  0.874  1.0
  O  O18  1  0.707  0.250  0.374  1.0
  O  O19  1  0.207  0.750  0.126  1.0
  O  O20  1  0.845  0.553  0.617  1.0
  O  O21  1  0.345  0.447  0.883  1.0
  O  O22  1  0.155  0.053  0.383  1.0
  O  O23  1  0.655  0.947  0.117  1.0
  O  O24  1  0.155  0.447  0.383  1.0
  O  O25  1  0.655  0.553  0.117  1.0
  O  O26  1  0.845  0.947  0.617  1.0
  O  O27  1  0.345  0.053  0.883  1.0
[/CIF]
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The material structure described by AgCdVO4 crystallizes in the orthorhombic Pnma space group. V(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form VO4 tetrahedra that share corners with six equivalent Cd(1)O6 octahedra and corners with four equivalent Ag(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 45-53°. Ag(1) is bonded to one O(1), one O(2), and two equivalent O(3) atoms to form distorted AgO4 tetrahedra that share corners with six equivalent Cd(1)O6 octahedra and corners with four equivalent V(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 76-81°. Cd(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form CdO6 octahedra that share corners with six equivalent V(1)O4 tetrahedra, corners with six equivalent Ag(1)O4 tetrahedra, and edges with two equivalent Cd(1)O6 octahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded to one V(1), one Ag(1), and two equivalent Cd(1) atoms to form a mixture of distorted corner and edge-sharing OVCd2Ag trigonal pyramids. In the second O site, O(2) is bonded to one V(1), one Ag(1), and two equivalent Cd(1) atoms to form a mixture of distorted corner and edge-sharing OVCd2Ag tetrahedra. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one V(1), one Ag(1), and one Cd(1) atom. is represented by the CIF file [CIF]
data_VCdAgO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.543
_cell_length_b   7.100
_cell_length_c   10.042
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   395.215
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.989  0.750  0.679  1.0
  V  V1  1  0.489  0.250  0.821  1.0
  V  V2  1  0.011  0.250  0.321  1.0
  V  V3  1  0.511  0.750  0.179  1.0
  Cd  Cd4  1  0.500  0.500  0.500  1.0
  Cd  Cd5  1  0.000  0.500  0.000  1.0
  Cd  Cd6  1  0.500  0.000  0.500  1.0
  Cd  Cd7  1  0.000  0.000  0.000  1.0
  Ag  Ag8  1  0.998  0.750  0.349  1.0
  Ag  Ag9  1  0.498  0.250  0.151  1.0
  Ag  Ag10  1  0.002  0.250  0.651  1.0
  Ag  Ag11  1  0.502  0.750  0.849  1.0
  O  O12  1  0.941  0.750  0.857  1.0
  O  O13  1  0.441  0.250  0.643  1.0
  O  O14  1  0.059  0.250  0.143  1.0
  O  O15  1  0.559  0.750  0.357  1.0
  O  O16  1  0.293  0.750  0.626  1.0
  O  O17  1  0.793  0.250  0.874  1.0
  O  O18  1  0.707  0.250  0.374  1.0
  O  O19  1  0.207  0.750  0.126  1.0
  O  O20  1  0.845  0.553  0.617  1.0
  O  O21  1  0.345  0.447  0.883  1.0
  O  O22  1  0.155  0.053  0.383  1.0
  O  O23  1  0.655  0.947  0.117  1.0
  O  O24  1  0.155  0.447  0.383  1.0
  O  O25  1  0.655  0.553  0.117  1.0
  O  O26  1  0.845  0.947  0.617  1.0
  O  O27  1  0.345  0.053  0.883  1.0
[/CIF]
.