The material structure described by NaTiO2 crystallizes in the orthorhombic Pbca space group. Na(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. Ti(1) is bonded to two equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing TiO5 trigonal bipyramids. There are two inequivalent O sites. In the first O site, O(2) is bonded to two equivalent Na(1) and three equivalent Ti(1) atoms to form a mixture of distorted corner and edge-sharing ONa2Ti3 trigonal bipyramids. In the second O site, O(1) is bonded in a 6-coordinate geometry to four equivalent Na(1) and two equivalent Ti(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaTiO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.441
_cell_length_b   6.103
_cell_length_c   12.291
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   408.142
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.588  0.613  0.686  1.0
  Na  Na1  1  0.588  0.113  0.814  1.0
  Na  Na2  1  0.912  0.113  0.314  1.0
  Na  Na3  1  0.912  0.613  0.186  1.0
  Na  Na4  1  0.088  0.887  0.686  1.0
  Na  Na5  1  0.088  0.387  0.814  1.0
  Na  Na6  1  0.412  0.387  0.314  1.0
  Na  Na7  1  0.412  0.887  0.186  1.0
  Ti  Ti8  1  0.622  0.170  0.558  1.0
  Ti  Ti9  1  0.622  0.670  0.942  1.0
  Ti  Ti10  1  0.878  0.670  0.442  1.0
  Ti  Ti11  1  0.878  0.170  0.058  1.0
  Ti  Ti12  1  0.122  0.830  0.942  1.0
  Ti  Ti13  1  0.122  0.330  0.558  1.0
  Ti  Ti14  1  0.378  0.330  0.058  1.0
  Ti  Ti15  1  0.378  0.830  0.442  1.0
  O  O16  1  0.606  0.234  0.168  1.0
  O  O17  1  0.606  0.734  0.332  1.0
  O  O18  1  0.797  0.859  0.044  1.0
  O  O19  1  0.797  0.359  0.456  1.0
  O  O20  1  0.703  0.359  0.956  1.0
  O  O21  1  0.703  0.859  0.544  1.0
  O  O22  1  0.894  0.734  0.832  1.0
  O  O23  1  0.894  0.234  0.668  1.0
  O  O24  1  0.106  0.766  0.332  1.0
  O  O25  1  0.106  0.266  0.168  1.0
  O  O26  1  0.297  0.141  0.456  1.0
  O  O27  1  0.297  0.641  0.044  1.0
  O  O28  1  0.203  0.641  0.544  1.0
  O  O29  1  0.203  0.141  0.956  1.0
  O  O30  1  0.394  0.266  0.668  1.0
  O  O31  1  0.394  0.766  0.832  1.0
[/CIF]
.
The material structure described by NaTiO2 crystallizes in the orthorhombic Pbca space group. Na(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. Ti(1) is bonded to two equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing TiO5 trigonal bipyramids. There are two inequivalent O sites. In the first O site, O(2) is bonded to two equivalent Na(1) and three equivalent Ti(1) atoms to form a mixture of distorted corner and edge-sharing ONa2Ti3 trigonal bipyramids. In the second O site, O(1) is bonded in a 6-coordinate geometry to four equivalent Na(1) and two equivalent Ti(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaTiO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.441
_cell_length_b   6.103
_cell_length_c   12.291
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   408.142
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.588  0.613  0.686  1.0
  Na  Na1  1  0.588  0.113  0.814  1.0
  Na  Na2  1  0.912  0.113  0.314  1.0
  Na  Na3  1  0.912  0.613  0.186  1.0
  Na  Na4  1  0.088  0.887  0.686  1.0
  Na  Na5  1  0.088  0.387  0.814  1.0
  Na  Na6  1  0.412  0.387  0.314  1.0
  Na  Na7  1  0.412  0.887  0.186  1.0
  Ti  Ti8  1  0.622  0.170  0.558  1.0
  Ti  Ti9  1  0.622  0.670  0.942  1.0
  Ti  Ti10  1  0.878  0.670  0.442  1.0
  Ti  Ti11  1  0.878  0.170  0.058  1.0
  Ti  Ti12  1  0.122  0.830  0.942  1.0
  Ti  Ti13  1  0.122  0.330  0.558  1.0
  Ti  Ti14  1  0.378  0.330  0.058  1.0
  Ti  Ti15  1  0.378  0.830  0.442  1.0
  O  O16  1  0.606  0.234  0.168  1.0
  O  O17  1  0.606  0.734  0.332  1.0
  O  O18  1  0.797  0.859  0.044  1.0
  O  O19  1  0.797  0.359  0.456  1.0
  O  O20  1  0.703  0.359  0.956  1.0
  O  O21  1  0.703  0.859  0.544  1.0
  O  O22  1  0.894  0.734  0.832  1.0
  O  O23  1  0.894  0.234  0.668  1.0
  O  O24  1  0.106  0.766  0.332  1.0
  O  O25  1  0.106  0.266  0.168  1.0
  O  O26  1  0.297  0.141  0.456  1.0
  O  O27  1  0.297  0.641  0.044  1.0
  O  O28  1  0.203  0.641  0.544  1.0
  O  O29  1  0.203  0.141  0.956  1.0
  O  O30  1  0.394  0.266  0.668  1.0
  O  O31  1  0.394  0.766  0.832  1.0
[/CIF]
.