The structure described by PHBr3As2F11 is beta-prime cadmium gold structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two tribromophosphanium molecules and two As2F11 clusters. In each As2F11 cluster, there are two inequivalent As sites. In the first As site, As(1) is bonded to one F(2), one F(3), one F(4), one F(5), and two equivalent F(1) atoms to form corner-sharing AsF6 octahedra. The corner-sharing octahedral tilt angles are 35°. In the second As site, As(2) is bonded to one F(5), one F(7), two equivalent F(6), and two equivalent F(8) atoms to form corner-sharing AsF6 octahedra. The corner-sharing octahedral tilt angles are 35°. There are eight inequivalent F sites. In the first F site, F(8) is bonded in a single-bond geometry to one As(2) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(5) is bonded in a bent 150 degrees geometry to one As(1) and one As(2) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one As(2) atom. In the eighth F site, F(7) is bonded in a single-bond geometry to one As(2) atom. is represented by the CIF file [CIF]
data_As2PHBr3F11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.064
_cell_length_b   6.407
_cell_length_c   12.252
_cell_angle_alpha   85.276
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   709.159
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.750  0.866  0.104  1.0
  As  As1  1  0.250  0.134  0.896  1.0
  As  As2  1  0.750  0.794  0.415  1.0
  As  As3  1  0.250  0.206  0.585  1.0
  P  P4  1  0.250  0.541  0.192  1.0
  P  P5  1  0.750  0.459  0.808  1.0
  H  H6  1  0.250  0.660  0.089  1.0
  H  H7  1  0.750  0.340  0.911  1.0
  Br  Br8  1  0.443  0.349  0.204  1.0
  Br  Br9  1  0.943  0.651  0.796  1.0
  Br  Br10  1  0.557  0.651  0.796  1.0
  Br  Br11  1  0.057  0.349  0.204  1.0
  Br  Br12  1  0.250  0.756  0.316  1.0
  Br  Br13  1  0.750  0.244  0.684  1.0
  F  F14  1  0.556  0.860  0.111  1.0
  F  F15  1  0.056  0.140  0.889  1.0
  F  F16  1  0.444  0.140  0.889  1.0
  F  F17  1  0.944  0.860  0.111  1.0
  F  F18  1  0.750  0.977  0.968  1.0
  F  F19  1  0.250  0.023  0.032  1.0
  F  F20  1  0.750  0.114  0.155  1.0
  F  F21  1  0.250  0.886  0.845  1.0
  F  F22  1  0.750  0.608  0.062  1.0
  F  F23  1  0.250  0.392  0.938  1.0
  F  F24  1  0.750  0.739  0.249  1.0
  F  F25  1  0.250  0.261  0.751  1.0
  F  F26  1  0.614  0.982  0.379  1.0
  F  F27  1  0.114  0.018  0.621  1.0
  F  F28  1  0.386  0.018  0.621  1.0
  F  F29  1  0.886  0.982  0.379  1.0
  F  F30  1  0.750  0.834  0.554  1.0
  F  F31  1  0.250  0.166  0.446  1.0
  F  F32  1  0.614  0.601  0.423  1.0
  F  F33  1  0.114  0.399  0.577  1.0
  F  F34  1  0.386  0.399  0.577  1.0
  F  F35  1  0.886  0.601  0.423  1.0
[/CIF]
.
The structure described by PHBr3As2F11 is beta-prime cadmium gold structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two tribromophosphanium molecules and two As2F11 clusters. In each As2F11 cluster, there are two inequivalent As sites. In the first As site, As(1) is bonded to one F(2), one F(3), one F(4), one F(5), and two equivalent F(1) atoms to form corner-sharing AsF6 octahedra. The corner-sharing octahedral tilt angles are 35°. In the second As site, As(2) is bonded to one F(5), one F(7), two equivalent F(6), and two equivalent F(8) atoms to form corner-sharing AsF6 octahedra. The corner-sharing octahedral tilt angles are 35°. There are eight inequivalent F sites. In the first F site, F(8) is bonded in a single-bond geometry to one As(2) atom. In the second F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(5) is bonded in a bent 150 degrees geometry to one As(1) and one As(2) atom. In the seventh F site, F(6) is bonded in a single-bond geometry to one As(2) atom. In the eighth F site, F(7) is bonded in a single-bond geometry to one As(2) atom. is represented by the CIF file [CIF]
data_As2PHBr3F11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.064
_cell_length_b   6.407
_cell_length_c   12.252
_cell_angle_alpha   85.276
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   709.159
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.750  0.866  0.104  1.0
  As  As1  1  0.250  0.134  0.896  1.0
  As  As2  1  0.750  0.794  0.415  1.0
  As  As3  1  0.250  0.206  0.585  1.0
  P  P4  1  0.250  0.541  0.192  1.0
  P  P5  1  0.750  0.459  0.808  1.0
  H  H6  1  0.250  0.660  0.089  1.0
  H  H7  1  0.750  0.340  0.911  1.0
  Br  Br8  1  0.443  0.349  0.204  1.0
  Br  Br9  1  0.943  0.651  0.796  1.0
  Br  Br10  1  0.557  0.651  0.796  1.0
  Br  Br11  1  0.057  0.349  0.204  1.0
  Br  Br12  1  0.250  0.756  0.316  1.0
  Br  Br13  1  0.750  0.244  0.684  1.0
  F  F14  1  0.556  0.860  0.111  1.0
  F  F15  1  0.056  0.140  0.889  1.0
  F  F16  1  0.444  0.140  0.889  1.0
  F  F17  1  0.944  0.860  0.111  1.0
  F  F18  1  0.750  0.977  0.968  1.0
  F  F19  1  0.250  0.023  0.032  1.0
  F  F20  1  0.750  0.114  0.155  1.0
  F  F21  1  0.250  0.886  0.845  1.0
  F  F22  1  0.750  0.608  0.062  1.0
  F  F23  1  0.250  0.392  0.938  1.0
  F  F24  1  0.750  0.739  0.249  1.0
  F  F25  1  0.250  0.261  0.751  1.0
  F  F26  1  0.614  0.982  0.379  1.0
  F  F27  1  0.114  0.018  0.621  1.0
  F  F28  1  0.386  0.018  0.621  1.0
  F  F29  1  0.886  0.982  0.379  1.0
  F  F30  1  0.750  0.834  0.554  1.0
  F  F31  1  0.250  0.166  0.446  1.0
  F  F32  1  0.614  0.601  0.423  1.0
  F  F33  1  0.114  0.399  0.577  1.0
  F  F34  1  0.386  0.399  0.577  1.0
  F  F35  1  0.886  0.601  0.423  1.0
[/CIF]
.