The structure described by Rb3Bi2S2(O2Cl)5 crystallizes in the monoclinic P2_1 space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 8-coordinate geometry to one O(2), one O(6), one O(7), one O(8), one O(9), one Cl(3), one Cl(4), and one Cl(5) atom. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(8), one O(9), one Cl(1), one Cl(2), and one Cl(3) atom. In the third Rb site, Rb(3) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(3), one O(6), one Cl(1), one Cl(2), one Cl(4), and one Cl(5) atom. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one Cl(1), one Cl(2), and one Cl(3) atom. In the second Bi site, Bi(2) is bonded in a 8-coordinate geometry to one O(4), one O(5), one O(6), one O(7), one O(8), one Cl(3), one Cl(4), and one Cl(5) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(5), one O(6), one O(7), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), one Bi(1), and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Bi(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), one Bi(1), and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Bi(1), one Bi(2), and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Bi(1), one Bi(2), and one S(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(3), one Bi(2), and one S(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Rb(1), one Bi(2), and one S(2) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Bi(2), and one S(2) atom. In the ninth O site, O(9) is bonded in a T-shaped geometry to one Rb(1), one Rb(2), and one O(10) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Rb(3) and one O(9) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), and one Bi(1) atom. In the second Cl site, Cl(2) is bonded in a distorted T-shaped geometry to one Rb(2), one Rb(3), and one Bi(1) atom. In the third Cl site, Cl(3) is bonded in a square co-planar geometry to one Rb(1), one Rb(2), one Bi(1), and one Bi(2) atom. In the fourth Cl site, Cl(4) is bonded in a distorted T-shaped geometry to one Rb(1), one Rb(3), and one Bi(2) atom. In the fifth Cl site, Cl(5) is bonded in a distorted T-shaped geometry to one Rb(1), one Rb(3), and one Bi(2) atom. is represented by the CIF card [CIF]
data_Rb3Bi2S2(ClO2)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   21.716
_cell_length_b   6.340
_cell_length_c   7.551
_cell_angle_alpha   83.301
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1032.439
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.626  0.006  0.608  1.0
  Rb  Rb1  1  0.126  0.994  0.392  1.0
  Rb  Rb2  1  0.817  0.875  0.330  1.0
  Rb  Rb3  1  0.317  0.125  0.670  1.0
  Rb  Rb4  1  0.966  0.746  0.823  1.0
  Rb  Rb5  1  0.466  0.254  0.177  1.0
  Bi  Bi6  1  0.801  0.315  0.792  1.0
  Bi  Bi7  1  0.301  0.685  0.208  1.0
  Bi  Bi8  1  0.644  0.574  0.139  1.0
  Bi  Bi9  1  0.144  0.426  0.861  1.0
  S  S10  1  0.788  0.811  0.813  1.0
  S  S11  1  0.288  0.189  0.187  1.0
  S  S12  1  0.657  0.077  0.126  1.0
  S  S13  1  0.157  0.923  0.874  1.0
  Cl  Cl14  1  0.891  0.244  0.587  1.0
  Cl  Cl15  1  0.391  0.756  0.413  1.0
  Cl  Cl16  1  0.875  0.367  0.059  1.0
  Cl  Cl17  1  0.375  0.633  0.941  1.0
  Cl  Cl18  1  0.723  0.444  0.474  1.0
  Cl  Cl19  1  0.223  0.556  0.526  1.0
  Cl  Cl20  1  0.553  0.633  0.347  1.0
  Cl  Cl21  1  0.053  0.367  0.653  1.0
  Cl  Cl22  1  0.570  0.528  0.874  1.0
  Cl  Cl23  1  0.070  0.472  0.126  1.0
  O  O24  1  0.823  0.936  0.935  1.0
  O  O25  1  0.323  0.064  0.065  1.0
  O  O26  1  0.754  0.965  0.684  1.0
  O  O27  1  0.254  0.035  0.316  1.0
  O  O28  1  0.832  0.683  0.713  1.0
  O  O29  1  0.332  0.317  0.287  1.0
  O  O30  1  0.745  0.656  0.914  1.0
  O  O31  1  0.245  0.344  0.086  1.0
  O  O32  1  0.700  0.232  0.027  1.0
  O  O33  1  0.200  0.768  0.973  1.0
  O  O34  1  0.612  0.205  0.221  1.0
  O  O35  1  0.112  0.795  0.779  1.0
  O  O36  1  0.624  0.947  0.002  1.0
  O  O37  1  0.124  0.053  0.998  1.0
  O  O38  1  0.690  0.925  0.259  1.0
  O  O39  1  0.190  0.075  0.741  1.0
  O  O40  1  0.972  0.878  0.315  1.0
  O  O41  1  0.472  0.122  0.685  1.0
  O  O42  1  0.975  0.997  0.173  1.0
  O  O43  1  0.475  0.003  0.827  1.0
[/CIF]
.
The structure described by Rb3Bi2S2(O2Cl)5 crystallizes in the monoclinic P2_1 space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 8-coordinate geometry to one O(2), one O(6), one O(7), one O(8), one O(9), one Cl(3), one Cl(4), and one Cl(5) atom. In the second Rb site, Rb(2) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(8), one O(9), one Cl(1), one Cl(2), and one Cl(3) atom. In the third Rb site, Rb(3) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(3), one O(6), one Cl(1), one Cl(2), one Cl(4), and one Cl(5) atom. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one Cl(1), one Cl(2), and one Cl(3) atom. In the second Bi site, Bi(2) is bonded in a 8-coordinate geometry to one O(4), one O(5), one O(6), one O(7), one O(8), one Cl(3), one Cl(4), and one Cl(5) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(5), one O(6), one O(7), and one O(8) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), one Bi(1), and one S(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Bi(1), and one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), one Bi(1), and one S(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Bi(1), one Bi(2), and one S(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Bi(1), one Bi(2), and one S(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(3), one Bi(2), and one S(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Rb(1), one Bi(2), and one S(2) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Bi(2), and one S(2) atom. In the ninth O site, O(9) is bonded in a T-shaped geometry to one Rb(1), one Rb(2), and one O(10) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Rb(3) and one O(9) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), and one Bi(1) atom. In the second Cl site, Cl(2) is bonded in a distorted T-shaped geometry to one Rb(2), one Rb(3), and one Bi(1) atom. In the third Cl site, Cl(3) is bonded in a square co-planar geometry to one Rb(1), one Rb(2), one Bi(1), and one Bi(2) atom. In the fourth Cl site, Cl(4) is bonded in a distorted T-shaped geometry to one Rb(1), one Rb(3), and one Bi(2) atom. In the fifth Cl site, Cl(5) is bonded in a distorted T-shaped geometry to one Rb(1), one Rb(3), and one Bi(2) atom. is represented by the CIF card [CIF]
data_Rb3Bi2S2(ClO2)5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   21.716
_cell_length_b   6.340
_cell_length_c   7.551
_cell_angle_alpha   83.301
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1032.439
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.626  0.006  0.608  1.0
  Rb  Rb1  1  0.126  0.994  0.392  1.0
  Rb  Rb2  1  0.817  0.875  0.330  1.0
  Rb  Rb3  1  0.317  0.125  0.670  1.0
  Rb  Rb4  1  0.966  0.746  0.823  1.0
  Rb  Rb5  1  0.466  0.254  0.177  1.0
  Bi  Bi6  1  0.801  0.315  0.792  1.0
  Bi  Bi7  1  0.301  0.685  0.208  1.0
  Bi  Bi8  1  0.644  0.574  0.139  1.0
  Bi  Bi9  1  0.144  0.426  0.861  1.0
  S  S10  1  0.788  0.811  0.813  1.0
  S  S11  1  0.288  0.189  0.187  1.0
  S  S12  1  0.657  0.077  0.126  1.0
  S  S13  1  0.157  0.923  0.874  1.0
  Cl  Cl14  1  0.891  0.244  0.587  1.0
  Cl  Cl15  1  0.391  0.756  0.413  1.0
  Cl  Cl16  1  0.875  0.367  0.059  1.0
  Cl  Cl17  1  0.375  0.633  0.941  1.0
  Cl  Cl18  1  0.723  0.444  0.474  1.0
  Cl  Cl19  1  0.223  0.556  0.526  1.0
  Cl  Cl20  1  0.553  0.633  0.347  1.0
  Cl  Cl21  1  0.053  0.367  0.653  1.0
  Cl  Cl22  1  0.570  0.528  0.874  1.0
  Cl  Cl23  1  0.070  0.472  0.126  1.0
  O  O24  1  0.823  0.936  0.935  1.0
  O  O25  1  0.323  0.064  0.065  1.0
  O  O26  1  0.754  0.965  0.684  1.0
  O  O27  1  0.254  0.035  0.316  1.0
  O  O28  1  0.832  0.683  0.713  1.0
  O  O29  1  0.332  0.317  0.287  1.0
  O  O30  1  0.745  0.656  0.914  1.0
  O  O31  1  0.245  0.344  0.086  1.0
  O  O32  1  0.700  0.232  0.027  1.0
  O  O33  1  0.200  0.768  0.973  1.0
  O  O34  1  0.612  0.205  0.221  1.0
  O  O35  1  0.112  0.795  0.779  1.0
  O  O36  1  0.624  0.947  0.002  1.0
  O  O37  1  0.124  0.053  0.998  1.0
  O  O38  1  0.690  0.925  0.259  1.0
  O  O39  1  0.190  0.075  0.741  1.0
  O  O40  1  0.972  0.878  0.315  1.0
  O  O41  1  0.472  0.122  0.685  1.0
  O  O42  1  0.975  0.997  0.173  1.0
  O  O43  1  0.475  0.003  0.827  1.0
[/CIF]
.