The compound described by XeF5XeOF4SbF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two SbF6 clusters, two XeF5 clusters, and two XeOF4 clusters. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(10), one F(4), one F(5), one F(9), and two equivalent F(7) atoms. There are five inequivalent F sites. In the first F site, F(4) is bonded in a distorted single-bond geometry to one Sb(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(10) is bonded in a single-bond geometry to one Sb(1) atom. In each XeF5 cluster, Xe(1) is bonded in a 5-coordinate geometry to one F(1), two equivalent F(6), and two equivalent F(8) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom. In each XeOF4 cluster, Xe(2) is bonded in a square pyramidal geometry to one O(1), two equivalent F(2), and two equivalent F(3) atoms. O(1) is bonded in a single-bond geometry to one Xe(2) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Xe(2) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Xe(2) atom. is represented by the CIF file [CIF]
data_SbXe2OF15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.146
_cell_length_b   5.767
_cell_length_c   12.720
_cell_angle_alpha   76.516
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   652.460
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.250  0.753  0.434  1.0
  Sb  Sb1  1  0.750  0.247  0.566  1.0
  Xe  Xe2  1  0.750  0.910  0.292  1.0
  Xe  Xe3  1  0.750  0.683  0.906  1.0
  Xe  Xe4  1  0.250  0.090  0.708  1.0
  Xe  Xe5  1  0.250  0.317  0.094  1.0
  O  O6  1  0.750  0.556  0.051  1.0
  O  O7  1  0.250  0.444  0.949  1.0
  F  F8  1  0.750  0.052  0.137  1.0
  F  F9  1  0.092  0.546  0.120  1.0
  F  F10  1  0.408  0.077  0.083  1.0
  F  F11  1  0.750  0.007  0.478  1.0
  F  F12  1  0.408  0.546  0.120  1.0
  F  F13  1  0.908  0.454  0.880  1.0
  F  F14  1  0.750  0.497  0.431  1.0
  F  F15  1  0.902  0.156  0.287  1.0
  F  F16  1  0.458  0.760  0.442  1.0
  F  F17  1  0.599  0.707  0.248  1.0
  F  F18  1  0.250  0.517  0.353  1.0
  F  F19  1  0.401  0.293  0.752  1.0
  F  F20  1  0.098  0.844  0.713  1.0
  F  F21  1  0.598  0.156  0.287  1.0
  F  F22  1  0.250  0.993  0.522  1.0
  F  F23  1  0.750  0.992  0.693  1.0
  F  F24  1  0.092  0.077  0.083  1.0
  F  F25  1  0.750  0.483  0.647  1.0
  F  F26  1  0.542  0.240  0.558  1.0
  F  F27  1  0.592  0.454  0.880  1.0
  F  F28  1  0.250  0.503  0.569  1.0
  F  F29  1  0.250  0.008  0.307  1.0
  F  F30  1  0.592  0.923  0.917  1.0
  F  F31  1  0.250  0.948  0.863  1.0
  F  F32  1  0.908  0.923  0.917  1.0
  F  F33  1  0.042  0.760  0.442  1.0
  F  F34  1  0.958  0.240  0.558  1.0
  F  F35  1  0.901  0.707  0.248  1.0
  F  F36  1  0.402  0.844  0.713  1.0
  F  F37  1  0.099  0.293  0.752  1.0
[/CIF]
.
The compound described by XeF5XeOF4SbF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two SbF6 clusters, two XeF5 clusters, and two XeOF4 clusters. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(10), one F(4), one F(5), one F(9), and two equivalent F(7) atoms. There are five inequivalent F sites. In the first F site, F(4) is bonded in a distorted single-bond geometry to one Sb(1) atom. In the second F site, F(5) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(9) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(10) is bonded in a single-bond geometry to one Sb(1) atom. In each XeF5 cluster, Xe(1) is bonded in a 5-coordinate geometry to one F(1), two equivalent F(6), and two equivalent F(8) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Xe(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one Xe(1) atom. In each XeOF4 cluster, Xe(2) is bonded in a square pyramidal geometry to one O(1), two equivalent F(2), and two equivalent F(3) atoms. O(1) is bonded in a single-bond geometry to one Xe(2) atom. There are two inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Xe(2) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Xe(2) atom. is represented by the CIF file [CIF]
data_SbXe2OF15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.146
_cell_length_b   5.767
_cell_length_c   12.720
_cell_angle_alpha   76.516
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   652.460
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.250  0.753  0.434  1.0
  Sb  Sb1  1  0.750  0.247  0.566  1.0
  Xe  Xe2  1  0.750  0.910  0.292  1.0
  Xe  Xe3  1  0.750  0.683  0.906  1.0
  Xe  Xe4  1  0.250  0.090  0.708  1.0
  Xe  Xe5  1  0.250  0.317  0.094  1.0
  O  O6  1  0.750  0.556  0.051  1.0
  O  O7  1  0.250  0.444  0.949  1.0
  F  F8  1  0.750  0.052  0.137  1.0
  F  F9  1  0.092  0.546  0.120  1.0
  F  F10  1  0.408  0.077  0.083  1.0
  F  F11  1  0.750  0.007  0.478  1.0
  F  F12  1  0.408  0.546  0.120  1.0
  F  F13  1  0.908  0.454  0.880  1.0
  F  F14  1  0.750  0.497  0.431  1.0
  F  F15  1  0.902  0.156  0.287  1.0
  F  F16  1  0.458  0.760  0.442  1.0
  F  F17  1  0.599  0.707  0.248  1.0
  F  F18  1  0.250  0.517  0.353  1.0
  F  F19  1  0.401  0.293  0.752  1.0
  F  F20  1  0.098  0.844  0.713  1.0
  F  F21  1  0.598  0.156  0.287  1.0
  F  F22  1  0.250  0.993  0.522  1.0
  F  F23  1  0.750  0.992  0.693  1.0
  F  F24  1  0.092  0.077  0.083  1.0
  F  F25  1  0.750  0.483  0.647  1.0
  F  F26  1  0.542  0.240  0.558  1.0
  F  F27  1  0.592  0.454  0.880  1.0
  F  F28  1  0.250  0.503  0.569  1.0
  F  F29  1  0.250  0.008  0.307  1.0
  F  F30  1  0.592  0.923  0.917  1.0
  F  F31  1  0.250  0.948  0.863  1.0
  F  F32  1  0.908  0.923  0.917  1.0
  F  F33  1  0.042  0.760  0.442  1.0
  F  F34  1  0.958  0.240  0.558  1.0
  F  F35  1  0.901  0.707  0.248  1.0
  F  F36  1  0.402  0.844  0.713  1.0
  F  F37  1  0.099  0.293  0.752  1.0
[/CIF]
.