The compound described by RbMgIn(WO4)2 crystallizes in the trigonal P3m1 space group. Rb(1) is bonded to three equivalent O(1), three equivalent O(2), three equivalent O(3), and three equivalent O(4) atoms to form distorted RbO12 cuboctahedra that share edges with six equivalent Rb(1)O12 cuboctahedra, edges with three equivalent W(1)O4 tetrahedra, and edges with three equivalent W(2)O4 tetrahedra. Mg(1) is bonded in a distorted trigonal non-coplanar geometry to one In(1) and three equivalent O(2) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(3) and three equivalent O(2) atoms to form WO4 tetrahedra that share edges with three equivalent Rb(1)O12 cuboctahedra. In the second W site, W(2) is bonded to one O(4) and three equivalent O(1) atoms to form WO4 tetrahedra that share edges with three equivalent Rb(1)O12 cuboctahedra. In(1) is bonded in a rectangular see-saw-like geometry to one Mg(1) and three equivalent O(1) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Rb(1), one W(2), and one In(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Rb(1), one Mg(1), and one W(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to three equivalent Rb(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to three equivalent Rb(1) and one W(2) atom. is represented by the CIF file [CIF]
data_RbMgIn(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.055
_cell_length_b   6.055
_cell_length_c   10.307
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   327.225
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.000  0.527  1.0
  Mg  Mg1  1  0.000  0.000  0.181  1.0
  In  In2  1  0.000  0.000  0.902  1.0
  W  W3  1  0.333  0.667  0.314  1.0
  W  W4  1  0.667  0.333  0.717  1.0
  O  O5  1  0.832  0.168  0.772  1.0
  O  O6  1  0.832  0.665  0.772  1.0
  O  O7  1  0.335  0.168  0.772  1.0
  O  O8  1  0.662  0.831  0.256  1.0
  O  O9  1  0.333  0.667  0.486  1.0
  O  O10  1  0.667  0.333  0.545  1.0
  O  O11  1  0.169  0.338  0.256  1.0
  O  O12  1  0.169  0.831  0.256  1.0
[/CIF]
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The compound described by RbMgIn(WO4)2 crystallizes in the trigonal P3m1 space group. Rb(1) is bonded to three equivalent O(1), three equivalent O(2), three equivalent O(3), and three equivalent O(4) atoms to form distorted RbO12 cuboctahedra that share edges with six equivalent Rb(1)O12 cuboctahedra, edges with three equivalent W(1)O4 tetrahedra, and edges with three equivalent W(2)O4 tetrahedra. Mg(1) is bonded in a distorted trigonal non-coplanar geometry to one In(1) and three equivalent O(2) atoms. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(3) and three equivalent O(2) atoms to form WO4 tetrahedra that share edges with three equivalent Rb(1)O12 cuboctahedra. In the second W site, W(2) is bonded to one O(4) and three equivalent O(1) atoms to form WO4 tetrahedra that share edges with three equivalent Rb(1)O12 cuboctahedra. In(1) is bonded in a rectangular see-saw-like geometry to one Mg(1) and three equivalent O(1) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Rb(1), one W(2), and one In(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Rb(1), one Mg(1), and one W(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to three equivalent Rb(1) and one W(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to three equivalent Rb(1) and one W(2) atom. is represented by the CIF file [CIF]
data_RbMgIn(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.055
_cell_length_b   6.055
_cell_length_c   10.307
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   327.225
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.000  0.000  0.527  1.0
  Mg  Mg1  1  0.000  0.000  0.181  1.0
  In  In2  1  0.000  0.000  0.902  1.0
  W  W3  1  0.333  0.667  0.314  1.0
  W  W4  1  0.667  0.333  0.717  1.0
  O  O5  1  0.832  0.168  0.772  1.0
  O  O6  1  0.832  0.665  0.772  1.0
  O  O7  1  0.335  0.168  0.772  1.0
  O  O8  1  0.662  0.831  0.256  1.0
  O  O9  1  0.333  0.667  0.486  1.0
  O  O10  1  0.667  0.333  0.545  1.0
  O  O11  1  0.169  0.338  0.256  1.0
  O  O12  1  0.169  0.831  0.256  1.0
[/CIF]
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