The structure described by MoN is Tungsten Carbide-like structured and crystallizes in the hexagonal P6_3/mmc space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to six equivalent N(1) atoms to form a mixture of distorted face, corner, and edge-sharing MoN6 pentagonal pyramids. The corner-sharing octahedral tilt angles are 44°. In the second Mo site, Mo(2) is bonded to six equivalent N(1) atoms to form a mixture of face, corner, and edge-sharing MoN6 octahedra. N(1) is bonded to three equivalent Mo(1) and three equivalent Mo(2) atoms to form a mixture of distorted face, corner, and edge-sharing NMo6 pentagonal pyramids. is represented by the CIF file [CIF]
data_MoN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.849
_cell_length_b   2.849
_cell_length_c   11.398
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   80.148
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.000  1.000  0.750  1.0
  Mo  Mo1  1  1.000  0.000  0.250  1.0
  Mo  Mo2  1  0.000  0.000  0.500  1.0
  Mo  Mo3  1  0.000  0.000  0.000  1.0
  N  N4  1  0.667  0.333  0.630  1.0
  N  N5  1  0.333  0.667  0.370  1.0
  N  N6  1  0.333  0.667  0.130  1.0
  N  N7  1  0.667  0.333  0.870  1.0
[/CIF]
.
The structure described by MoN is Tungsten Carbide-like structured and crystallizes in the hexagonal P6_3/mmc space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to six equivalent N(1) atoms to form a mixture of distorted face, corner, and edge-sharing MoN6 pentagonal pyramids. The corner-sharing octahedral tilt angles are 44°. In the second Mo site, Mo(2) is bonded to six equivalent N(1) atoms to form a mixture of face, corner, and edge-sharing MoN6 octahedra. N(1) is bonded to three equivalent Mo(1) and three equivalent Mo(2) atoms to form a mixture of distorted face, corner, and edge-sharing NMo6 pentagonal pyramids. is represented by the CIF file [CIF]
data_MoN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.849
_cell_length_b   2.849
_cell_length_c   11.398
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   80.148
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.000  1.000  0.750  1.0
  Mo  Mo1  1  1.000  0.000  0.250  1.0
  Mo  Mo2  1  0.000  0.000  0.500  1.0
  Mo  Mo3  1  0.000  0.000  0.000  1.0
  N  N4  1  0.667  0.333  0.630  1.0
  N  N5  1  0.333  0.667  0.370  1.0
  N  N6  1  0.333  0.667  0.130  1.0
  N  N7  1  0.667  0.333  0.870  1.0
[/CIF]
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