The material structure described by V(BiO3)2 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form VO4 tetrahedra that share corners with four equivalent Bi(2)O6 pentagonal pyramids. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 4-coordinate geometry to one O(2), one O(5), and two equivalent O(1) atoms. In the second Bi site, Bi(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted BiO6 pentagonal pyramids that share corners with four equivalent V(1)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(6) is bonded in a 2-coordinate geometry to one V(1) and one Bi(2) atom. In the second O site, O(1) is bonded in a trigonal planar geometry to one Bi(2) and two equivalent Bi(1) atoms. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Bi(1) and one Bi(2) atom. In the fourth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Bi(2) atom. In the fifth O site, O(4) is bonded in a bent 120 degrees geometry to one V(1) and one Bi(2) atom. In the sixth O site, O(5) is bonded in a distorted single-bond geometry to one V(1), one Bi(1), and one Bi(2) atom. is represented by the CIF file [CIF]
data_V(BiO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.844
_cell_length_b   6.983
_cell_length_c   10.911
_cell_angle_alpha   72.334
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   569.422
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.050  0.878  0.334  1.0
  V  V1  1  0.550  0.122  0.166  1.0
  V  V2  1  0.950  0.122  0.666  1.0
  V  V3  1  0.450  0.878  0.834  1.0
  Bi  Bi4  1  0.896  0.735  0.986  1.0
  Bi  Bi5  1  0.396  0.265  0.514  1.0
  Bi  Bi6  1  0.104  0.265  0.014  1.0
  Bi  Bi7  1  0.604  0.735  0.486  1.0
  Bi  Bi8  1  0.333  0.621  0.162  1.0
  Bi  Bi9  1  0.833  0.379  0.338  1.0
  Bi  Bi10  1  0.667  0.379  0.838  1.0
  Bi  Bi11  1  0.167  0.621  0.662  1.0
  O  O12  1  0.099  0.518  0.091  1.0
  O  O13  1  0.599  0.482  0.409  1.0
  O  O14  1  0.901  0.482  0.909  1.0
  O  O15  1  0.401  0.518  0.591  1.0
  O  O16  1  0.751  0.585  0.155  1.0
  O  O17  1  0.251  0.415  0.345  1.0
  O  O18  1  0.249  0.415  0.845  1.0
  O  O19  1  0.749  0.585  0.655  1.0
  O  O20  1  0.128  0.821  0.198  1.0
  O  O21  1  0.628  0.179  0.302  1.0
  O  O22  1  0.872  0.179  0.802  1.0
  O  O23  1  0.372  0.821  0.698  1.0
  O  O24  1  0.199  0.857  0.457  1.0
  O  O25  1  0.699  0.143  0.043  1.0
  O  O26  1  0.801  0.143  0.543  1.0
  O  O27  1  0.301  0.857  0.957  1.0
  O  O28  1  0.883  0.713  0.402  1.0
  O  O29  1  0.383  0.287  0.098  1.0
  O  O30  1  0.117  0.287  0.598  1.0
  O  O31  1  0.617  0.713  0.902  1.0
  O  O32  1  0.982  0.124  0.273  1.0
  O  O33  1  0.482  0.876  0.227  1.0
  O  O34  1  0.018  0.876  0.727  1.0
  O  O35  1  0.518  0.124  0.773  1.0
[/CIF]
.
The material structure described by V(BiO3)2 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded to one O(3), one O(4), one O(5), and one O(6) atom to form VO4 tetrahedra that share corners with four equivalent Bi(2)O6 pentagonal pyramids. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 4-coordinate geometry to one O(2), one O(5), and two equivalent O(1) atoms. In the second Bi site, Bi(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form distorted BiO6 pentagonal pyramids that share corners with four equivalent V(1)O4 tetrahedra. There are six inequivalent O sites. In the first O site, O(6) is bonded in a 2-coordinate geometry to one V(1) and one Bi(2) atom. In the second O site, O(1) is bonded in a trigonal planar geometry to one Bi(2) and two equivalent Bi(1) atoms. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Bi(1) and one Bi(2) atom. In the fourth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Bi(2) atom. In the fifth O site, O(4) is bonded in a bent 120 degrees geometry to one V(1) and one Bi(2) atom. In the sixth O site, O(5) is bonded in a distorted single-bond geometry to one V(1), one Bi(1), and one Bi(2) atom. is represented by the CIF file [CIF]
data_V(BiO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.844
_cell_length_b   6.983
_cell_length_c   10.911
_cell_angle_alpha   72.334
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   569.422
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.050  0.878  0.334  1.0
  V  V1  1  0.550  0.122  0.166  1.0
  V  V2  1  0.950  0.122  0.666  1.0
  V  V3  1  0.450  0.878  0.834  1.0
  Bi  Bi4  1  0.896  0.735  0.986  1.0
  Bi  Bi5  1  0.396  0.265  0.514  1.0
  Bi  Bi6  1  0.104  0.265  0.014  1.0
  Bi  Bi7  1  0.604  0.735  0.486  1.0
  Bi  Bi8  1  0.333  0.621  0.162  1.0
  Bi  Bi9  1  0.833  0.379  0.338  1.0
  Bi  Bi10  1  0.667  0.379  0.838  1.0
  Bi  Bi11  1  0.167  0.621  0.662  1.0
  O  O12  1  0.099  0.518  0.091  1.0
  O  O13  1  0.599  0.482  0.409  1.0
  O  O14  1  0.901  0.482  0.909  1.0
  O  O15  1  0.401  0.518  0.591  1.0
  O  O16  1  0.751  0.585  0.155  1.0
  O  O17  1  0.251  0.415  0.345  1.0
  O  O18  1  0.249  0.415  0.845  1.0
  O  O19  1  0.749  0.585  0.655  1.0
  O  O20  1  0.128  0.821  0.198  1.0
  O  O21  1  0.628  0.179  0.302  1.0
  O  O22  1  0.872  0.179  0.802  1.0
  O  O23  1  0.372  0.821  0.698  1.0
  O  O24  1  0.199  0.857  0.457  1.0
  O  O25  1  0.699  0.143  0.043  1.0
  O  O26  1  0.801  0.143  0.543  1.0
  O  O27  1  0.301  0.857  0.957  1.0
  O  O28  1  0.883  0.713  0.402  1.0
  O  O29  1  0.383  0.287  0.098  1.0
  O  O30  1  0.117  0.287  0.598  1.0
  O  O31  1  0.617  0.713  0.902  1.0
  O  O32  1  0.982  0.124  0.273  1.0
  O  O33  1  0.482  0.876  0.227  1.0
  O  O34  1  0.018  0.876  0.727  1.0
  O  O35  1  0.518  0.124  0.773  1.0
[/CIF]
.