The structure described by V3P crystallizes in the tetragonal P4_2/n space group. There are three inequivalent V sites. In the first V site, V(1) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. In the second V site, V(2) is bonded in a 2-coordinate geometry to three equivalent P(1) atoms. In the third V site, V(3) is bonded in a 2-coordinate geometry to two equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to two equivalent V(3), three equivalent V(2), and four equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V3P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.721
_cell_length_b   9.299
_cell_length_c   9.299
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   408.265
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.513  0.102  0.260  1.0
  V  V1  1  0.013  0.740  0.602  1.0
  V  V2  1  0.013  0.760  0.898  1.0
  V  V3  1  0.513  0.398  0.240  1.0
  V  V4  1  0.487  0.898  0.740  1.0
  V  V5  1  0.987  0.260  0.398  1.0
  V  V6  1  0.987  0.240  0.102  1.0
  V  V7  1  0.487  0.602  0.760  1.0
  V  V8  1  0.240  0.054  0.535  1.0
  V  V9  1  0.740  0.465  0.554  1.0
  V  V10  1  0.740  0.035  0.946  1.0
  V  V11  1  0.240  0.446  0.965  1.0
  V  V12  1  0.760  0.946  0.465  1.0
  V  V13  1  0.260  0.535  0.446  1.0
  V  V14  1  0.260  0.965  0.054  1.0
  V  V15  1  0.760  0.554  0.035  1.0
  V  V16  1  0.268  0.667  0.158  1.0
  V  V17  1  0.768  0.842  0.167  1.0
  V  V18  1  0.768  0.658  0.333  1.0
  V  V19  1  0.268  0.833  0.342  1.0
  V  V20  1  0.732  0.333  0.842  1.0
  V  V21  1  0.232  0.158  0.833  1.0
  V  V22  1  0.232  0.342  0.667  1.0
  V  V23  1  0.732  0.167  0.658  1.0
  P  P24  1  0.984  0.542  0.770  1.0
  P  P25  1  0.484  0.230  0.042  1.0
  P  P26  1  0.484  0.270  0.458  1.0
  P  P27  1  0.984  0.958  0.730  1.0
  P  P28  1  0.016  0.458  0.230  1.0
  P  P29  1  0.516  0.770  0.958  1.0
  P  P30  1  0.516  0.730  0.542  1.0
  P  P31  1  0.016  0.042  0.270  1.0
[/CIF]
.
The structure described by V3P crystallizes in the tetragonal P4_2/n space group. There are three inequivalent V sites. In the first V site, V(1) is bonded in a 4-coordinate geometry to four equivalent P(1) atoms. In the second V site, V(2) is bonded in a 2-coordinate geometry to three equivalent P(1) atoms. In the third V site, V(3) is bonded in a 2-coordinate geometry to two equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to two equivalent V(3), three equivalent V(2), and four equivalent V(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V3P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.721
_cell_length_b   9.299
_cell_length_c   9.299
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   408.265
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.513  0.102  0.260  1.0
  V  V1  1  0.013  0.740  0.602  1.0
  V  V2  1  0.013  0.760  0.898  1.0
  V  V3  1  0.513  0.398  0.240  1.0
  V  V4  1  0.487  0.898  0.740  1.0
  V  V5  1  0.987  0.260  0.398  1.0
  V  V6  1  0.987  0.240  0.102  1.0
  V  V7  1  0.487  0.602  0.760  1.0
  V  V8  1  0.240  0.054  0.535  1.0
  V  V9  1  0.740  0.465  0.554  1.0
  V  V10  1  0.740  0.035  0.946  1.0
  V  V11  1  0.240  0.446  0.965  1.0
  V  V12  1  0.760  0.946  0.465  1.0
  V  V13  1  0.260  0.535  0.446  1.0
  V  V14  1  0.260  0.965  0.054  1.0
  V  V15  1  0.760  0.554  0.035  1.0
  V  V16  1  0.268  0.667  0.158  1.0
  V  V17  1  0.768  0.842  0.167  1.0
  V  V18  1  0.768  0.658  0.333  1.0
  V  V19  1  0.268  0.833  0.342  1.0
  V  V20  1  0.732  0.333  0.842  1.0
  V  V21  1  0.232  0.158  0.833  1.0
  V  V22  1  0.232  0.342  0.667  1.0
  V  V23  1  0.732  0.167  0.658  1.0
  P  P24  1  0.984  0.542  0.770  1.0
  P  P25  1  0.484  0.230  0.042  1.0
  P  P26  1  0.484  0.270  0.458  1.0
  P  P27  1  0.984  0.958  0.730  1.0
  P  P28  1  0.016  0.458  0.230  1.0
  P  P29  1  0.516  0.770  0.958  1.0
  P  P30  1  0.516  0.730  0.542  1.0
  P  P31  1  0.016  0.042  0.270  1.0
[/CIF]
.