The structure described by VH10S2(NO4)2 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(4) atoms. N(1) is bonded in a bent 120 degrees geometry to one V(1) and one S(1) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a distorted bent 150 degrees geometry to one O(3) and one O(4) atom. In the fourth H site, H(4) is bonded in a bent 150 degrees geometry to one O(2) and one O(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(2) atom. S(1) is bonded in a trigonal non-coplanar geometry to one N(1), one O(1), and one O(3) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one H(2), one H(3), and one S(1) atom. In the second O site, O(4) is bonded in a 4-coordinate geometry to one V(1), one H(1), one H(3), and one H(4) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one S(1) atom. In the fourth O site, O(2) is bonded in a 3-coordinate geometry to one H(1), one H(4), and one H(5) atom. is represented by the CIF card [CIF]
data_VH10S2(NO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.293
_cell_length_b   7.075
_cell_length_c   7.554
_cell_angle_alpha   88.339
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   389.592
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.500  0.500  1.0
  V  V1  1  0.500  0.000  0.000  1.0
  H  H2  1  0.075  0.777  0.793  1.0
  H  H3  1  0.129  0.449  0.903  1.0
  H  H4  1  0.689  0.714  0.961  1.0
  H  H5  1  0.925  0.223  0.207  1.0
  H  H6  1  0.700  0.366  0.354  1.0
  H  H7  1  0.600  0.647  0.517  1.0
  H  H8  1  0.200  0.134  0.146  1.0
  H  H9  1  0.100  0.853  0.983  1.0
  H  H10  1  0.425  0.277  0.293  1.0
  H  H11  1  0.811  0.214  0.461  1.0
  H  H12  1  0.371  0.949  0.403  1.0
  H  H13  1  0.575  0.723  0.707  1.0
  H  H14  1  0.629  0.051  0.597  1.0
  H  H15  1  0.189  0.786  0.539  1.0
  H  H16  1  0.900  0.147  0.017  1.0
  H  H17  1  0.800  0.866  0.854  1.0
  H  H18  1  0.400  0.353  0.483  1.0
  H  H19  1  0.300  0.634  0.646  1.0
  H  H20  1  0.871  0.551  0.097  1.0
  H  H21  1  0.311  0.286  0.039  1.0
  S  S22  1  0.179  0.198  0.740  1.0
  S  S23  1  0.321  0.698  0.240  1.0
  S  S24  1  0.679  0.302  0.760  1.0
  S  S25  1  0.821  0.802  0.260  1.0
  N  N26  1  0.664  0.202  0.944  1.0
  N  N27  1  0.836  0.702  0.444  1.0
  N  N28  1  0.164  0.298  0.556  1.0
  N  N29  1  0.336  0.798  0.056  1.0
  O  O30  1  0.859  0.418  0.737  1.0
  O  O31  1  0.506  0.664  0.610  1.0
  O  O32  1  0.754  0.611  0.125  1.0
  O  O33  1  0.334  0.177  0.131  1.0
  O  O34  1  0.834  0.323  0.369  1.0
  O  O35  1  0.254  0.889  0.375  1.0
  O  O36  1  0.006  0.836  0.890  1.0
  O  O37  1  0.359  0.082  0.763  1.0
  O  O38  1  0.641  0.918  0.237  1.0
  O  O39  1  0.994  0.164  0.110  1.0
  O  O40  1  0.746  0.111  0.625  1.0
  O  O41  1  0.166  0.677  0.631  1.0
  O  O42  1  0.666  0.823  0.869  1.0
  O  O43  1  0.246  0.389  0.875  1.0
  O  O44  1  0.494  0.336  0.390  1.0
  O  O45  1  0.141  0.582  0.263  1.0
[/CIF]
.
The structure described by VH10S2(NO4)2 crystallizes in the monoclinic P2_1/c space group. V(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(4) atoms. N(1) is bonded in a bent 120 degrees geometry to one V(1) and one S(1) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a linear geometry to one O(2) and one O(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(3) atom. In the third H site, H(3) is bonded in a distorted bent 150 degrees geometry to one O(3) and one O(4) atom. In the fourth H site, H(4) is bonded in a bent 150 degrees geometry to one O(2) and one O(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(2) atom. S(1) is bonded in a trigonal non-coplanar geometry to one N(1), one O(1), and one O(3) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one H(2), one H(3), and one S(1) atom. In the second O site, O(4) is bonded in a 4-coordinate geometry to one V(1), one H(1), one H(3), and one H(4) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one S(1) atom. In the fourth O site, O(2) is bonded in a 3-coordinate geometry to one H(1), one H(4), and one H(5) atom. is represented by the CIF card [CIF]
data_VH10S2(NO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.293
_cell_length_b   7.075
_cell_length_c   7.554
_cell_angle_alpha   88.339
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   389.592
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.500  0.500  1.0
  V  V1  1  0.500  0.000  0.000  1.0
  H  H2  1  0.075  0.777  0.793  1.0
  H  H3  1  0.129  0.449  0.903  1.0
  H  H4  1  0.689  0.714  0.961  1.0
  H  H5  1  0.925  0.223  0.207  1.0
  H  H6  1  0.700  0.366  0.354  1.0
  H  H7  1  0.600  0.647  0.517  1.0
  H  H8  1  0.200  0.134  0.146  1.0
  H  H9  1  0.100  0.853  0.983  1.0
  H  H10  1  0.425  0.277  0.293  1.0
  H  H11  1  0.811  0.214  0.461  1.0
  H  H12  1  0.371  0.949  0.403  1.0
  H  H13  1  0.575  0.723  0.707  1.0
  H  H14  1  0.629  0.051  0.597  1.0
  H  H15  1  0.189  0.786  0.539  1.0
  H  H16  1  0.900  0.147  0.017  1.0
  H  H17  1  0.800  0.866  0.854  1.0
  H  H18  1  0.400  0.353  0.483  1.0
  H  H19  1  0.300  0.634  0.646  1.0
  H  H20  1  0.871  0.551  0.097  1.0
  H  H21  1  0.311  0.286  0.039  1.0
  S  S22  1  0.179  0.198  0.740  1.0
  S  S23  1  0.321  0.698  0.240  1.0
  S  S24  1  0.679  0.302  0.760  1.0
  S  S25  1  0.821  0.802  0.260  1.0
  N  N26  1  0.664  0.202  0.944  1.0
  N  N27  1  0.836  0.702  0.444  1.0
  N  N28  1  0.164  0.298  0.556  1.0
  N  N29  1  0.336  0.798  0.056  1.0
  O  O30  1  0.859  0.418  0.737  1.0
  O  O31  1  0.506  0.664  0.610  1.0
  O  O32  1  0.754  0.611  0.125  1.0
  O  O33  1  0.334  0.177  0.131  1.0
  O  O34  1  0.834  0.323  0.369  1.0
  O  O35  1  0.254  0.889  0.375  1.0
  O  O36  1  0.006  0.836  0.890  1.0
  O  O37  1  0.359  0.082  0.763  1.0
  O  O38  1  0.641  0.918  0.237  1.0
  O  O39  1  0.994  0.164  0.110  1.0
  O  O40  1  0.746  0.111  0.625  1.0
  O  O41  1  0.166  0.677  0.631  1.0
  O  O42  1  0.666  0.823  0.869  1.0
  O  O43  1  0.246  0.389  0.875  1.0
  O  O44  1  0.494  0.336  0.390  1.0
  O  O45  1  0.141  0.582  0.263  1.0
[/CIF]
.