The structure described by WRhN3 crystallizes in the triclinic P-1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one N(1), one N(3), one N(5), and two equivalent N(2) atoms to form edge-sharing WN5 trigonal bipyramids. In the second W site, W(2) is bonded in a 4-coordinate geometry to one N(2), one N(3), one N(4), one N(5), and one N(6) atom. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a rectangular see-saw-like geometry to one N(4), one N(6), and two equivalent N(1) atoms. In the second Rh site, Rh(2) is bonded in a rectangular see-saw-like geometry to one N(1), one N(3), one N(4), and one N(6) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted rectangular see-saw-like geometry to one W(1), one Rh(2), and two equivalent Rh(1) atoms. In the second N site, N(2) is bonded in a distorted T-shaped geometry to one W(2) and two equivalent W(1) atoms. In the third N site, N(3) is bonded in a 4-coordinate geometry to one W(1), one W(2), one Rh(2), and one N(5) atom. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one W(2), one Rh(1), and one Rh(2) atom. In the fifth N site, N(5) is bonded in a trigonal non-coplanar geometry to one W(1), one W(2), and one N(3) atom. In the sixth N site, N(6) is bonded in a distorted T-shaped geometry to one W(2), one Rh(1), and one Rh(2) atom. is represented by the CIF card [CIF]
data_RhWN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.963
_cell_length_b   6.475
_cell_length_c   10.500
_cell_angle_alpha   101.034
_cell_angle_beta   132.963
_cell_angle_gamma   88.384
_symmetry_Int_Tables_number   1
_cell_volume   288.234
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.288  0.152  0.516  1.0
  Rh  Rh1  1  0.712  0.848  0.484  1.0
  Rh  Rh2  1  0.904  0.775  0.312  1.0
  Rh  Rh3  1  0.096  0.225  0.688  1.0
  W  W4  1  0.944  0.985  0.120  1.0
  W  W5  1  0.056  0.015  0.880  1.0
  W  W6  1  0.600  0.329  0.231  1.0
  W  W7  1  0.400  0.671  0.769  1.0
  N  N8  1  0.270  0.915  0.344  1.0
  N  N9  1  0.730  0.085  0.656  1.0
  N  N10  1  0.807  0.827  0.892  1.0
  N  N11  1  0.193  0.173  0.108  1.0
  N  N12  1  0.594  0.815  0.056  1.0
  N  N13  1  0.406  0.185  0.944  1.0
  N  N14  1  0.140  0.755  0.562  1.0
  N  N15  1  0.860  0.245  0.438  1.0
  N  N16  1  0.711  0.246  0.084  1.0
  N  N17  1  0.289  0.754  0.916  1.0
  N  N18  1  0.572  0.611  0.282  1.0
  N  N19  1  0.428  0.389  0.718  1.0
[/CIF]
.
The structure described by WRhN3 crystallizes in the triclinic P-1 space group. There are two inequivalent W sites. In the first W site, W(1) is bonded to one N(1), one N(3), one N(5), and two equivalent N(2) atoms to form edge-sharing WN5 trigonal bipyramids. In the second W site, W(2) is bonded in a 4-coordinate geometry to one N(2), one N(3), one N(4), one N(5), and one N(6) atom. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a rectangular see-saw-like geometry to one N(4), one N(6), and two equivalent N(1) atoms. In the second Rh site, Rh(2) is bonded in a rectangular see-saw-like geometry to one N(1), one N(3), one N(4), and one N(6) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted rectangular see-saw-like geometry to one W(1), one Rh(2), and two equivalent Rh(1) atoms. In the second N site, N(2) is bonded in a distorted T-shaped geometry to one W(2) and two equivalent W(1) atoms. In the third N site, N(3) is bonded in a 4-coordinate geometry to one W(1), one W(2), one Rh(2), and one N(5) atom. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one W(2), one Rh(1), and one Rh(2) atom. In the fifth N site, N(5) is bonded in a trigonal non-coplanar geometry to one W(1), one W(2), and one N(3) atom. In the sixth N site, N(6) is bonded in a distorted T-shaped geometry to one W(2), one Rh(1), and one Rh(2) atom. is represented by the CIF card [CIF]
data_RhWN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.963
_cell_length_b   6.475
_cell_length_c   10.500
_cell_angle_alpha   101.034
_cell_angle_beta   132.963
_cell_angle_gamma   88.384
_symmetry_Int_Tables_number   1
_cell_volume   288.234
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.288  0.152  0.516  1.0
  Rh  Rh1  1  0.712  0.848  0.484  1.0
  Rh  Rh2  1  0.904  0.775  0.312  1.0
  Rh  Rh3  1  0.096  0.225  0.688  1.0
  W  W4  1  0.944  0.985  0.120  1.0
  W  W5  1  0.056  0.015  0.880  1.0
  W  W6  1  0.600  0.329  0.231  1.0
  W  W7  1  0.400  0.671  0.769  1.0
  N  N8  1  0.270  0.915  0.344  1.0
  N  N9  1  0.730  0.085  0.656  1.0
  N  N10  1  0.807  0.827  0.892  1.0
  N  N11  1  0.193  0.173  0.108  1.0
  N  N12  1  0.594  0.815  0.056  1.0
  N  N13  1  0.406  0.185  0.944  1.0
  N  N14  1  0.140  0.755  0.562  1.0
  N  N15  1  0.860  0.245  0.438  1.0
  N  N16  1  0.711  0.246  0.084  1.0
  N  N17  1  0.289  0.754  0.916  1.0
  N  N18  1  0.572  0.611  0.282  1.0
  N  N19  1  0.428  0.389  0.718  1.0
[/CIF]
.