The structure described by Pd5CdP crystallizes in the tetragonal P4/mmm space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted square co-planar geometry to eight equivalent Pd(2) and four equivalent Cd(1) atoms. In the second Pd site, Pd(2) is bonded in a 11-coordinate geometry to two equivalent Pd(1), five equivalent Pd(2), two equivalent Cd(1), and two equivalent P(1) atoms. Cd(1) is bonded to four equivalent Pd(1) and eight equivalent Pd(2) atoms to form a mixture of corner and face-sharing CdPd12 cuboctahedra. P(1) is bonded in a body-centered cubic geometry to eight equivalent Pd(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdPPd5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.942
_cell_length_b   3.942
_cell_length_c   7.010
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   108.931
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.500  0.000  1.0
  P  P1  1  0.000  0.000  0.500  1.0
  Pd  Pd2  1  0.000  0.000  0.000  1.0
  Pd  Pd3  1  0.500  0.000  0.699  1.0
  Pd  Pd4  1  0.000  0.500  0.699  1.0
  Pd  Pd5  1  0.500  0.000  0.301  1.0
  Pd  Pd6  1  0.000  0.500  0.301  1.0
[/CIF]
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The structure described by Pd5CdP crystallizes in the tetragonal P4/mmm space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted square co-planar geometry to eight equivalent Pd(2) and four equivalent Cd(1) atoms. In the second Pd site, Pd(2) is bonded in a 11-coordinate geometry to two equivalent Pd(1), five equivalent Pd(2), two equivalent Cd(1), and two equivalent P(1) atoms. Cd(1) is bonded to four equivalent Pd(1) and eight equivalent Pd(2) atoms to form a mixture of corner and face-sharing CdPd12 cuboctahedra. P(1) is bonded in a body-centered cubic geometry to eight equivalent Pd(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdPPd5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.942
_cell_length_b   3.942
_cell_length_c   7.010
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   108.931
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.500  0.000  1.0
  P  P1  1  0.000  0.000  0.500  1.0
  Pd  Pd2  1  0.000  0.000  0.000  1.0
  Pd  Pd3  1  0.500  0.000  0.699  1.0
  Pd  Pd4  1  0.000  0.500  0.699  1.0
  Pd  Pd5  1  0.500  0.000  0.301  1.0
  Pd  Pd6  1  0.000  0.500  0.301  1.0
[/CIF]
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