The structure described by C2PN3Cl4 is Indium-like structured and crystallizes in the orthorhombic Cmcm space group. The structure is zero-dimensional and consists of four 2,2,4,6-tetrachloro-5h-1,3,5,2-triazaphosphinin-2-ium molecules. C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one Cl(1) atom. P(1) is bonded in a tetrahedral geometry to two equivalent N(2) and two equivalent Cl(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to two equivalent C(1) atoms. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one P(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_PC2N3Cl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.604
_cell_length_b   7.604
_cell_length_c   9.079
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.239
_symmetry_Int_Tables_number   1
_cell_volume   453.553
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.058  0.942  0.250  1.0
  P  P1  1  0.942  0.058  0.750  1.0
  C  C2  1  0.775  0.225  0.625  1.0
  C  C3  1  0.225  0.775  0.125  1.0
  C  C4  1  0.225  0.775  0.375  1.0
  C  C5  1  0.775  0.225  0.875  1.0
  N  N6  1  0.721  0.279  0.750  1.0
  N  N7  1  0.873  0.127  0.601  1.0
  N  N8  1  0.873  0.127  0.899  1.0
  N  N9  1  0.127  0.873  0.399  1.0
  N  N10  1  0.279  0.721  0.250  1.0
  N  N11  1  0.127  0.873  0.101  1.0
  Cl  Cl12  1  0.700  0.300  0.034  1.0
  Cl  Cl13  1  0.300  0.700  0.534  1.0
  Cl  Cl14  1  0.758  0.827  0.250  1.0
  Cl  Cl15  1  0.300  0.700  0.966  1.0
  Cl  Cl16  1  0.700  0.300  0.466  1.0
  Cl  Cl17  1  0.242  0.173  0.750  1.0
  Cl  Cl18  1  0.173  0.242  0.250  1.0
  Cl  Cl19  1  0.827  0.758  0.750  1.0
[/CIF]
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The structure described by C2PN3Cl4 is Indium-like structured and crystallizes in the orthorhombic Cmcm space group. The structure is zero-dimensional and consists of four 2,2,4,6-tetrachloro-5h-1,3,5,2-triazaphosphinin-2-ium molecules. C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one Cl(1) atom. P(1) is bonded in a tetrahedral geometry to two equivalent N(2) and two equivalent Cl(2) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to two equivalent C(1) atoms. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one P(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF file [CIF]
data_PC2N3Cl4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.604
_cell_length_b   7.604
_cell_length_c   9.079
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.239
_symmetry_Int_Tables_number   1
_cell_volume   453.553
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.058  0.942  0.250  1.0
  P  P1  1  0.942  0.058  0.750  1.0
  C  C2  1  0.775  0.225  0.625  1.0
  C  C3  1  0.225  0.775  0.125  1.0
  C  C4  1  0.225  0.775  0.375  1.0
  C  C5  1  0.775  0.225  0.875  1.0
  N  N6  1  0.721  0.279  0.750  1.0
  N  N7  1  0.873  0.127  0.601  1.0
  N  N8  1  0.873  0.127  0.899  1.0
  N  N9  1  0.127  0.873  0.399  1.0
  N  N10  1  0.279  0.721  0.250  1.0
  N  N11  1  0.127  0.873  0.101  1.0
  Cl  Cl12  1  0.700  0.300  0.034  1.0
  Cl  Cl13  1  0.300  0.700  0.534  1.0
  Cl  Cl14  1  0.758  0.827  0.250  1.0
  Cl  Cl15  1  0.300  0.700  0.966  1.0
  Cl  Cl16  1  0.700  0.300  0.466  1.0
  Cl  Cl17  1  0.242  0.173  0.750  1.0
  Cl  Cl18  1  0.173  0.242  0.250  1.0
  Cl  Cl19  1  0.827  0.758  0.750  1.0
[/CIF]
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