The compound described by FVO2 crystallizes in the monoclinic Cc space group. V(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent V(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. F(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.079
_cell_length_b   5.173
_cell_length_c   5.079
_cell_angle_alpha   118.315
_cell_angle_beta   58.621
_cell_angle_gamma   118.315
_symmetry_Int_Tables_number   1
_cell_volume   95.585
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.733  0.190  0.765  1.0
  V  V1  1  0.265  0.690  0.233  1.0
  O  O2  1  0.048  0.392  0.863  1.0
  O  O3  1  0.464  0.397  0.048  1.0
  O  O4  1  0.363  0.892  0.548  1.0
  O  O5  1  0.548  0.897  0.964  1.0
  F  F6  1  0.870  0.385  0.451  1.0
  F  F7  1  0.951  0.885  0.370  1.0
[/CIF]
.
The compound described by FVO2 crystallizes in the monoclinic Cc space group. V(1) is bonded in a 6-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to two equivalent V(1) atoms. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. F(1) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. is represented by the CIF file [CIF]
data_VO2F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.079
_cell_length_b   5.173
_cell_length_c   5.079
_cell_angle_alpha   118.315
_cell_angle_beta   58.621
_cell_angle_gamma   118.315
_symmetry_Int_Tables_number   1
_cell_volume   95.585
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.733  0.190  0.765  1.0
  V  V1  1  0.265  0.690  0.233  1.0
  O  O2  1  0.048  0.392  0.863  1.0
  O  O3  1  0.464  0.397  0.048  1.0
  O  O4  1  0.363  0.892  0.548  1.0
  O  O5  1  0.548  0.897  0.964  1.0
  F  F6  1  0.870  0.385  0.451  1.0
  F  F7  1  0.951  0.885  0.370  1.0
[/CIF]
.