The structure described by Li2V4MnO14 crystallizes in the monoclinic C2/m space group. Li(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(6), and two equivalent O(7) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), and two equivalent O(2) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(2), one O(5), one O(6), and two equivalent O(3) atoms. Mn(1) is bonded to two equivalent O(4) and four equivalent O(5) atoms to form edge-sharing MnO6 octahedra. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one V(2) and two equivalent V(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one Mn(1) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one V(2) and two equivalent Mn(1) atoms. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Li(1) and one V(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to two equivalent Li(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2MnV4O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.589
_cell_length_b   8.014
_cell_length_c   9.956
_cell_angle_alpha   104.900
_cell_angle_beta   100.384
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   271.872
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.243  0.298  0.487  1.0
  Li  Li1  1  0.757  0.702  0.513  1.0
  Mn  Mn2  1  0.000  0.000  0.000  1.0
  V  V3  1  0.099  0.431  0.198  1.0
  V  V4  1  0.901  0.569  0.802  1.0
  V  V5  1  0.588  0.738  0.176  1.0
  V  V6  1  0.412  0.262  0.824  1.0
  O  O7  1  0.187  0.490  0.374  1.0
  O  O8  1  0.813  0.510  0.626  1.0
  O  O9  1  0.575  0.472  0.150  1.0
  O  O10  1  0.425  0.528  0.850  1.0
  O  O11  1  0.067  0.661  0.133  1.0
  O  O12  1  0.933  0.339  0.867  1.0
  O  O13  1  0.076  0.210  0.151  1.0
  O  O14  1  0.924  0.790  0.849  1.0
  O  O15  1  0.545  0.905  0.091  1.0
  O  O16  1  0.455  0.095  0.909  1.0
  O  O17  1  0.674  0.821  0.347  1.0
  O  O18  1  0.326  0.179  0.653  1.0
  O  O19  1  0.290  0.795  0.580  1.0
  O  O20  1  0.710  0.205  0.420  1.0
[/CIF]
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The structure described by Li2V4MnO14 crystallizes in the monoclinic C2/m space group. Li(1) is bonded in a distorted see-saw-like geometry to one O(1), one O(6), and two equivalent O(7) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(4), and two equivalent O(2) atoms. In the second V site, V(2) is bonded in a 5-coordinate geometry to one O(2), one O(5), one O(6), and two equivalent O(3) atoms. Mn(1) is bonded to two equivalent O(4) and four equivalent O(5) atoms to form edge-sharing MnO6 octahedra. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one V(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one V(2) and two equivalent V(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one V(1) and two equivalent V(2) atoms. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(1) and one Mn(1) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one V(2) and two equivalent Mn(1) atoms. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Li(1) and one V(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to two equivalent Li(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li2MnV4O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.589
_cell_length_b   8.014
_cell_length_c   9.956
_cell_angle_alpha   104.900
_cell_angle_beta   100.384
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   271.872
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.243  0.298  0.487  1.0
  Li  Li1  1  0.757  0.702  0.513  1.0
  Mn  Mn2  1  0.000  0.000  0.000  1.0
  V  V3  1  0.099  0.431  0.198  1.0
  V  V4  1  0.901  0.569  0.802  1.0
  V  V5  1  0.588  0.738  0.176  1.0
  V  V6  1  0.412  0.262  0.824  1.0
  O  O7  1  0.187  0.490  0.374  1.0
  O  O8  1  0.813  0.510  0.626  1.0
  O  O9  1  0.575  0.472  0.150  1.0
  O  O10  1  0.425  0.528  0.850  1.0
  O  O11  1  0.067  0.661  0.133  1.0
  O  O12  1  0.933  0.339  0.867  1.0
  O  O13  1  0.076  0.210  0.151  1.0
  O  O14  1  0.924  0.790  0.849  1.0
  O  O15  1  0.545  0.905  0.091  1.0
  O  O16  1  0.455  0.095  0.909  1.0
  O  O17  1  0.674  0.821  0.347  1.0
  O  O18  1  0.326  0.179  0.653  1.0
  O  O19  1  0.290  0.795  0.580  1.0
  O  O20  1  0.710  0.205  0.420  1.0
[/CIF]
.