The compound described by TeMo5O16 crystallizes in the monoclinic Pc space group. There are five inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(14), one O(7), and two equivalent O(12) atoms. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(11), one O(15), one O(2), one O(8), and two equivalent O(13) atoms. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(5), one O(7), and two equivalent O(3) atoms. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(6), one O(8), and two equivalent O(4) atoms. In the fifth Mo site, Mo(5) is bonded in a 6-coordinate geometry to one O(14), one O(15), one O(5), one O(6), and two equivalent O(9) atoms. Te(1) is bonded in a 4-coordinate geometry to one O(10), one O(14), one O(15), and two equivalent O(16) atoms. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(4) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mo(2) and one Mo(3) atom. In the third O site, O(3) is bonded in a distorted linear geometry to two equivalent Mo(3) atoms. In the fourth O site, O(4) is bonded in a distorted linear geometry to two equivalent Mo(4) atoms. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mo(3) and one Mo(5) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(4) and one Mo(5) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mo(2) and one Mo(4) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to two equivalent Mo(5) atoms. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(3), and one Te(1) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mo(2) and one Mo(4) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to two equivalent Mo(1) atoms. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to two equivalent Mo(2) atoms. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Mo(1), one Mo(5), and one Te(1) atom. In the fifteenth O site, O(15) is bonded in a trigonal planar geometry to one Mo(2), one Mo(5), and one Te(1) atom. In the sixteenth O site, O(16) is bonded in a linear geometry to two equivalent Te(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeMo5O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.138
_cell_length_b   7.388
_cell_length_c   20.550
_cell_angle_alpha   90.000
_cell_angle_beta   89.844
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   628.197
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.024  0.581  0.746  1.0
  Te  Te1  1  0.024  0.419  0.246  1.0
  Mo  Mo2  1  0.912  0.751  0.586  1.0
  Mo  Mo3  1  0.915  0.251  0.414  1.0
  Mo  Mo4  1  0.915  0.749  0.914  1.0
  Mo  Mo5  1  0.912  0.249  0.086  1.0
  Mo  Mo6  1  0.082  0.256  0.593  1.0
  Mo  Mo7  1  0.083  0.745  0.407  1.0
  Mo  Mo8  1  0.083  0.255  0.907  1.0
  Mo  Mo9  1  0.082  0.744  0.093  1.0
  Mo  Mo10  1  0.901  0.021  0.750  1.0
  Mo  Mo11  1  0.901  0.979  0.250  1.0
  O  O12  1  0.985  0.686  0.501  1.0
  O  O13  1  0.984  0.313  0.499  1.0
  O  O14  1  0.984  0.687  0.999  1.0
  O  O15  1  0.985  0.314  0.001  1.0
  O  O16  1  0.501  0.258  0.591  1.0
  O  O17  1  0.502  0.743  0.409  1.0
  O  O18  1  0.502  0.257  0.909  1.0
  O  O19  1  0.501  0.742  0.091  1.0
  O  O20  1  0.986  0.183  0.684  1.0
  O  O21  1  0.986  0.817  0.316  1.0
  O  O22  1  0.986  0.183  0.816  1.0
  O  O23  1  0.986  0.817  0.184  1.0
  O  O24  1  0.994  0.996  0.574  1.0
  O  O25  1  0.995  0.005  0.425  1.0
  O  O26  1  0.995  0.995  0.925  1.0
  O  O27  1  0.994  0.004  0.074  1.0
  O  O28  1  0.482  0.014  0.750  1.0
  O  O29  1  0.482  0.986  0.250  1.0
  O  O30  1  0.999  0.511  0.623  1.0
  O  O31  1  0.002  0.490  0.379  1.0
  O  O32  1  0.002  0.510  0.879  1.0
  O  O33  1  0.999  0.489  0.123  1.0
  O  O34  1  0.492  0.752  0.590  1.0
  O  O35  1  0.494  0.249  0.409  1.0
  O  O36  1  0.494  0.751  0.909  1.0
  O  O37  1  0.492  0.248  0.090  1.0
  O  O38  1  0.983  0.806  0.688  1.0
  O  O39  1  0.985  0.198  0.309  1.0
  O  O40  1  0.985  0.802  0.809  1.0
  O  O41  1  0.983  0.194  0.188  1.0
  O  O42  1  0.474  0.576  0.742  1.0
  O  O43  1  0.474  0.424  0.242  1.0
[/CIF]
.
The compound described by TeMo5O16 crystallizes in the monoclinic Pc space group. There are five inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(14), one O(7), and two equivalent O(12) atoms. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to one O(11), one O(15), one O(2), one O(8), and two equivalent O(13) atoms. In the third Mo site, Mo(3) is bonded in a 6-coordinate geometry to one O(10), one O(2), one O(5), one O(7), and two equivalent O(3) atoms. In the fourth Mo site, Mo(4) is bonded in a 6-coordinate geometry to one O(1), one O(11), one O(6), one O(8), and two equivalent O(4) atoms. In the fifth Mo site, Mo(5) is bonded in a 6-coordinate geometry to one O(14), one O(15), one O(5), one O(6), and two equivalent O(9) atoms. Te(1) is bonded in a 4-coordinate geometry to one O(10), one O(14), one O(15), and two equivalent O(16) atoms. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(4) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Mo(2) and one Mo(3) atom. In the third O site, O(3) is bonded in a distorted linear geometry to two equivalent Mo(3) atoms. In the fourth O site, O(4) is bonded in a distorted linear geometry to two equivalent Mo(4) atoms. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mo(3) and one Mo(5) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(4) and one Mo(5) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mo(2) and one Mo(4) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to two equivalent Mo(5) atoms. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(3), and one Te(1) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mo(2) and one Mo(4) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to two equivalent Mo(1) atoms. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to two equivalent Mo(2) atoms. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Mo(1), one Mo(5), and one Te(1) atom. In the fifteenth O site, O(15) is bonded in a trigonal planar geometry to one Mo(2), one Mo(5), and one Te(1) atom. In the sixteenth O site, O(16) is bonded in a linear geometry to two equivalent Te(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeMo5O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.138
_cell_length_b   7.388
_cell_length_c   20.550
_cell_angle_alpha   90.000
_cell_angle_beta   89.844
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   628.197
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.024  0.581  0.746  1.0
  Te  Te1  1  0.024  0.419  0.246  1.0
  Mo  Mo2  1  0.912  0.751  0.586  1.0
  Mo  Mo3  1  0.915  0.251  0.414  1.0
  Mo  Mo4  1  0.915  0.749  0.914  1.0
  Mo  Mo5  1  0.912  0.249  0.086  1.0
  Mo  Mo6  1  0.082  0.256  0.593  1.0
  Mo  Mo7  1  0.083  0.745  0.407  1.0
  Mo  Mo8  1  0.083  0.255  0.907  1.0
  Mo  Mo9  1  0.082  0.744  0.093  1.0
  Mo  Mo10  1  0.901  0.021  0.750  1.0
  Mo  Mo11  1  0.901  0.979  0.250  1.0
  O  O12  1  0.985  0.686  0.501  1.0
  O  O13  1  0.984  0.313  0.499  1.0
  O  O14  1  0.984  0.687  0.999  1.0
  O  O15  1  0.985  0.314  0.001  1.0
  O  O16  1  0.501  0.258  0.591  1.0
  O  O17  1  0.502  0.743  0.409  1.0
  O  O18  1  0.502  0.257  0.909  1.0
  O  O19  1  0.501  0.742  0.091  1.0
  O  O20  1  0.986  0.183  0.684  1.0
  O  O21  1  0.986  0.817  0.316  1.0
  O  O22  1  0.986  0.183  0.816  1.0
  O  O23  1  0.986  0.817  0.184  1.0
  O  O24  1  0.994  0.996  0.574  1.0
  O  O25  1  0.995  0.005  0.425  1.0
  O  O26  1  0.995  0.995  0.925  1.0
  O  O27  1  0.994  0.004  0.074  1.0
  O  O28  1  0.482  0.014  0.750  1.0
  O  O29  1  0.482  0.986  0.250  1.0
  O  O30  1  0.999  0.511  0.623  1.0
  O  O31  1  0.002  0.490  0.379  1.0
  O  O32  1  0.002  0.510  0.879  1.0
  O  O33  1  0.999  0.489  0.123  1.0
  O  O34  1  0.492  0.752  0.590  1.0
  O  O35  1  0.494  0.249  0.409  1.0
  O  O36  1  0.494  0.751  0.909  1.0
  O  O37  1  0.492  0.248  0.090  1.0
  O  O38  1  0.983  0.806  0.688  1.0
  O  O39  1  0.985  0.198  0.309  1.0
  O  O40  1  0.985  0.802  0.809  1.0
  O  O41  1  0.983  0.194  0.188  1.0
  O  O42  1  0.474  0.576  0.742  1.0
  O  O43  1  0.474  0.424  0.242  1.0
[/CIF]
.