The structure described by LiV4O10 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(2), one O(5), one O(7), and one O(8) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), one O(5), and one O(9) atom to form corner-sharing VO4 tetrahedra. In the second V site, V(2) is bonded to one O(10), one O(2), one O(4), and one O(6) atom to form corner-sharing VO4 tetrahedra. In the third V site, V(3) is bonded to one O(1), one O(10), one O(3), one O(4), and one O(7) atom to form distorted VO5 trigonal bipyramids that share corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, and  an edgeedge with one V(4)O5 trigonal bipyramid. In the fourth V site, V(4) is bonded to one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form distorted VO5 trigonal bipyramids that share corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, and  an edgeedge with one V(3)O5 trigonal bipyramid. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one V(3) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Li(1), one V(2), and one V(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(4) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Li(1) and one V(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one V(2) atom. In the seventh O site, O(7) is bonded in a linear geometry to one Li(1) and one V(3) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one V(4) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(1) and one V(4) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(2) and one V(3) atom. is represented by the CIF card [CIF]
data_LiV4O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.990
_cell_length_b   6.721
_cell_length_c   7.613
_cell_angle_alpha   75.205
_cell_angle_beta   74.048
_cell_angle_gamma   74.618
_symmetry_Int_Tables_number   1
_cell_volume   278.565
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.705  0.957  0.882  1.0
  V  V1  1  0.145  0.712  0.571  1.0
  V  V2  1  0.845  0.288  0.427  1.0
  V  V3  1  0.692  0.844  0.368  1.0
  V  V4  1  0.314  0.145  0.619  1.0
  O  O5  1  0.998  0.817  0.380  1.0
  O  O6  1  0.974  0.182  0.622  1.0
  O  O7  1  0.372  0.870  0.531  1.0
  O  O8  1  0.628  0.129  0.439  1.0
  O  O9  1  0.948  0.738  0.768  1.0
  O  O10  1  0.056  0.272  0.242  1.0
  O  O11  1  0.676  0.914  0.150  1.0
  O  O12  1  0.387  0.068  0.823  1.0
  O  O13  1  0.267  0.452  0.566  1.0
  O  O14  1  0.712  0.563  0.425  1.0
[/CIF]
.
The structure described by LiV4O10 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one O(2), one O(5), one O(7), and one O(8) atom. There are four inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(3), one O(5), and one O(9) atom to form corner-sharing VO4 tetrahedra. In the second V site, V(2) is bonded to one O(10), one O(2), one O(4), and one O(6) atom to form corner-sharing VO4 tetrahedra. In the third V site, V(3) is bonded to one O(1), one O(10), one O(3), one O(4), and one O(7) atom to form distorted VO5 trigonal bipyramids that share corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, and  an edgeedge with one V(4)O5 trigonal bipyramid. In the fourth V site, V(4) is bonded to one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form distorted VO5 trigonal bipyramids that share corners with two equivalent V(1)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, and  an edgeedge with one V(3)O5 trigonal bipyramid. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one V(3) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Li(1), one V(2), and one V(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one V(1), one V(3), and one V(4) atom. In the fourth O site, O(4) is bonded in a trigonal planar geometry to one V(2), one V(3), and one V(4) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Li(1) and one V(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one V(2) atom. In the seventh O site, O(7) is bonded in a linear geometry to one Li(1) and one V(3) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one V(4) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(1) and one V(4) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(2) and one V(3) atom. is represented by the CIF card [CIF]
data_LiV4O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.990
_cell_length_b   6.721
_cell_length_c   7.613
_cell_angle_alpha   75.205
_cell_angle_beta   74.048
_cell_angle_gamma   74.618
_symmetry_Int_Tables_number   1
_cell_volume   278.565
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.705  0.957  0.882  1.0
  V  V1  1  0.145  0.712  0.571  1.0
  V  V2  1  0.845  0.288  0.427  1.0
  V  V3  1  0.692  0.844  0.368  1.0
  V  V4  1  0.314  0.145  0.619  1.0
  O  O5  1  0.998  0.817  0.380  1.0
  O  O6  1  0.974  0.182  0.622  1.0
  O  O7  1  0.372  0.870  0.531  1.0
  O  O8  1  0.628  0.129  0.439  1.0
  O  O9  1  0.948  0.738  0.768  1.0
  O  O10  1  0.056  0.272  0.242  1.0
  O  O11  1  0.676  0.914  0.150  1.0
  O  O12  1  0.387  0.068  0.823  1.0
  O  O13  1  0.267  0.452  0.566  1.0
  O  O14  1  0.712  0.563  0.425  1.0
[/CIF]
.