The compound described by In(PO3)3 crystallizes in the monoclinic Cc space group. In(1) is bonded to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form InO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(3), one O(4), one O(8), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 33-38°. In the second P site, P(2) is bonded to one O(1), one O(6), one O(7), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-43°. In the third P site, P(3) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form PO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 36°. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one In(1) and one P(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one In(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one In(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one In(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one In(1) and one P(2) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one In(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_In(PO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.557
_cell_length_b   7.557
_cell_length_c   9.680
_cell_angle_alpha   56.822
_cell_angle_beta   56.822
_cell_angle_gamma   51.868
_symmetry_Int_Tables_number   1
_cell_volume   345.020
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.488  0.016  0.501  1.0
  In  In1  1  0.016  0.488  0.001  1.0
  P  P2  1  0.813  0.980  0.673  1.0
  P  P3  1  0.003  0.211  0.830  1.0
  P  P4  1  0.579  0.437  0.731  1.0
  P  P5  1  0.980  0.813  0.173  1.0
  P  P6  1  0.211  0.003  0.330  1.0
  P  P7  1  0.437  0.579  0.231  1.0
  O  O8  1  0.762  0.401  0.787  1.0
  O  O9  1  0.510  0.673  0.598  1.0
  O  O10  1  0.729  0.251  0.630  1.0
  O  O11  1  0.251  0.729  0.130  1.0
  O  O12  1  0.841  0.871  0.338  1.0
  O  O13  1  0.382  0.390  0.392  1.0
  O  O14  1  0.335  0.095  0.332  1.0
  O  O15  1  0.069  0.163  0.209  1.0
  O  O16  1  0.871  0.841  0.838  1.0
  O  O17  1  0.959  0.639  0.162  1.0
  O  O18  1  0.639  0.959  0.662  1.0
  O  O19  1  0.912  0.053  0.019  1.0
  O  O20  1  0.673  0.510  0.098  1.0
  O  O21  1  0.163  0.069  0.709  1.0
  O  O22  1  0.095  0.335  0.832  1.0
  O  O23  1  0.390  0.382  0.892  1.0
  O  O24  1  0.401  0.762  0.287  1.0
  O  O25  1  0.053  0.912  0.519  1.0
[/CIF]
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The compound described by In(PO3)3 crystallizes in the monoclinic Cc space group. In(1) is bonded to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom to form InO6 octahedra that share corners with two equivalent P(1)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(3), one O(4), one O(8), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 33-38°. In the second P site, P(2) is bonded to one O(1), one O(6), one O(7), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-43°. In the third P site, P(3) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form PO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 36°. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one P(2) and one P(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one In(1) and one P(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one In(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one In(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one In(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one In(1) and one P(2) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one In(1) and one P(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one P(1) and one P(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_In(PO3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.557
_cell_length_b   7.557
_cell_length_c   9.680
_cell_angle_alpha   56.822
_cell_angle_beta   56.822
_cell_angle_gamma   51.868
_symmetry_Int_Tables_number   1
_cell_volume   345.020
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.488  0.016  0.501  1.0
  In  In1  1  0.016  0.488  0.001  1.0
  P  P2  1  0.813  0.980  0.673  1.0
  P  P3  1  0.003  0.211  0.830  1.0
  P  P4  1  0.579  0.437  0.731  1.0
  P  P5  1  0.980  0.813  0.173  1.0
  P  P6  1  0.211  0.003  0.330  1.0
  P  P7  1  0.437  0.579  0.231  1.0
  O  O8  1  0.762  0.401  0.787  1.0
  O  O9  1  0.510  0.673  0.598  1.0
  O  O10  1  0.729  0.251  0.630  1.0
  O  O11  1  0.251  0.729  0.130  1.0
  O  O12  1  0.841  0.871  0.338  1.0
  O  O13  1  0.382  0.390  0.392  1.0
  O  O14  1  0.335  0.095  0.332  1.0
  O  O15  1  0.069  0.163  0.209  1.0
  O  O16  1  0.871  0.841  0.838  1.0
  O  O17  1  0.959  0.639  0.162  1.0
  O  O18  1  0.639  0.959  0.662  1.0
  O  O19  1  0.912  0.053  0.019  1.0
  O  O20  1  0.673  0.510  0.098  1.0
  O  O21  1  0.163  0.069  0.709  1.0
  O  O22  1  0.095  0.335  0.832  1.0
  O  O23  1  0.390  0.382  0.892  1.0
  O  O24  1  0.401  0.762  0.287  1.0
  O  O25  1  0.053  0.912  0.519  1.0
[/CIF]
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