The material structure described by PtC8(SF3)4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two PtC8(SF3)4 clusters. Pt(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent S(2) atoms. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one S(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(4), and one S(2) atom. In the third C site, C(3) is bonded in a trigonal non-coplanar geometry to one C(1), one F(1), one F(2), and one F(3) atom. In the fourth C site, C(4) is bonded in a trigonal non-coplanar geometry to one C(2), one F(4), one F(5), and one F(6) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Pt(1) and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Pt(1) and one C(2) atom. There are six inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one C(3) atom. In the second F site, F(4) is bonded in a single-bond geometry to one C(4) atom. In the third F site, F(5) is bonded in a single-bond geometry to one C(4) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one C(4) atom. In the fifth F site, F(1) is bonded in a single-bond geometry to one C(3) atom. In the sixth F site, F(2) is bonded in a single-bond geometry to one C(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PtC8(SF3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.535
_cell_length_b   4.955
_cell_length_c   10.512
_cell_angle_alpha   76.944
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   788.235
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.500  0.500  0.500  1.0
  Pt  Pt1  1  0.000  0.500  0.000  1.0
  C  C2  1  0.652  0.164  0.668  1.0
  C  C3  1  0.152  0.836  0.832  1.0
  C  C4  1  0.348  0.836  0.332  1.0
  C  C5  1  0.848  0.164  0.168  1.0
  C  C6  1  0.579  0.040  0.731  1.0
  C  C7  1  0.079  0.960  0.769  1.0
  C  C8  1  0.421  0.960  0.269  1.0
  C  C9  1  0.921  0.040  0.231  1.0
  C  C10  1  0.744  0.083  0.710  1.0
  C  C11  1  0.244  0.917  0.790  1.0
  C  C12  1  0.256  0.917  0.290  1.0
  C  C13  1  0.756  0.083  0.210  1.0
  C  C14  1  0.579  0.807  0.855  1.0
  C  C15  1  0.079  0.193  0.645  1.0
  C  C16  1  0.421  0.193  0.145  1.0
  C  C17  1  0.921  0.807  0.355  1.0
  S  S18  1  0.643  0.426  0.532  1.0
  S  S19  1  0.143  0.574  0.968  1.0
  S  S20  1  0.357  0.574  0.468  1.0
  S  S21  1  0.857  0.426  0.032  1.0
  S  S22  1  0.479  0.150  0.677  1.0
  S  S23  1  0.979  0.850  0.823  1.0
  S  S24  1  0.521  0.850  0.323  1.0
  S  S25  1  0.021  0.150  0.177  1.0
  F  F26  1  0.768  0.840  0.680  1.0
  F  F27  1  0.268  0.160  0.820  1.0
  F  F28  1  0.232  0.160  0.320  1.0
  F  F29  1  0.732  0.840  0.180  1.0
  F  F30  1  0.755  0.053  0.842  1.0
  F  F31  1  0.255  0.947  0.658  1.0
  F  F32  1  0.245  0.947  0.158  1.0
  F  F33  1  0.745  0.053  0.342  1.0
  F  F34  1  0.802  0.278  0.651  1.0
  F  F35  1  0.302  0.722  0.849  1.0
  F  F36  1  0.198  0.722  0.349  1.0
  F  F37  1  0.698  0.278  0.151  1.0
  F  F38  1  0.640  0.613  0.851  1.0
  F  F39  1  0.140  0.387  0.649  1.0
  F  F40  1  0.360  0.387  0.149  1.0
  F  F41  1  0.860  0.613  0.351  1.0
  F  F42  1  0.502  0.671  0.870  1.0
  F  F43  1  0.002  0.329  0.630  1.0
  F  F44  1  0.498  0.329  0.130  1.0
  F  F45  1  0.998  0.671  0.370  1.0
  F  F46  1  0.592  0.908  0.963  1.0
  F  F47  1  0.092  0.092  0.537  1.0
  F  F48  1  0.408  0.092  0.037  1.0
  F  F49  1  0.908  0.908  0.463  1.0
[/CIF]
.
The material structure described by PtC8(SF3)4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two PtC8(SF3)4 clusters. Pt(1) is bonded in a square co-planar geometry to two equivalent S(1) and two equivalent S(2) atoms. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one S(1) atom. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(4), and one S(2) atom. In the third C site, C(3) is bonded in a trigonal non-coplanar geometry to one C(1), one F(1), one F(2), and one F(3) atom. In the fourth C site, C(4) is bonded in a trigonal non-coplanar geometry to one C(2), one F(4), one F(5), and one F(6) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Pt(1) and one C(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one Pt(1) and one C(2) atom. There are six inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one C(3) atom. In the second F site, F(4) is bonded in a single-bond geometry to one C(4) atom. In the third F site, F(5) is bonded in a single-bond geometry to one C(4) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one C(4) atom. In the fifth F site, F(1) is bonded in a single-bond geometry to one C(3) atom. In the sixth F site, F(2) is bonded in a single-bond geometry to one C(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PtC8(SF3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   15.535
_cell_length_b   4.955
_cell_length_c   10.512
_cell_angle_alpha   76.944
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   788.235
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.500  0.500  0.500  1.0
  Pt  Pt1  1  0.000  0.500  0.000  1.0
  C  C2  1  0.652  0.164  0.668  1.0
  C  C3  1  0.152  0.836  0.832  1.0
  C  C4  1  0.348  0.836  0.332  1.0
  C  C5  1  0.848  0.164  0.168  1.0
  C  C6  1  0.579  0.040  0.731  1.0
  C  C7  1  0.079  0.960  0.769  1.0
  C  C8  1  0.421  0.960  0.269  1.0
  C  C9  1  0.921  0.040  0.231  1.0
  C  C10  1  0.744  0.083  0.710  1.0
  C  C11  1  0.244  0.917  0.790  1.0
  C  C12  1  0.256  0.917  0.290  1.0
  C  C13  1  0.756  0.083  0.210  1.0
  C  C14  1  0.579  0.807  0.855  1.0
  C  C15  1  0.079  0.193  0.645  1.0
  C  C16  1  0.421  0.193  0.145  1.0
  C  C17  1  0.921  0.807  0.355  1.0
  S  S18  1  0.643  0.426  0.532  1.0
  S  S19  1  0.143  0.574  0.968  1.0
  S  S20  1  0.357  0.574  0.468  1.0
  S  S21  1  0.857  0.426  0.032  1.0
  S  S22  1  0.479  0.150  0.677  1.0
  S  S23  1  0.979  0.850  0.823  1.0
  S  S24  1  0.521  0.850  0.323  1.0
  S  S25  1  0.021  0.150  0.177  1.0
  F  F26  1  0.768  0.840  0.680  1.0
  F  F27  1  0.268  0.160  0.820  1.0
  F  F28  1  0.232  0.160  0.320  1.0
  F  F29  1  0.732  0.840  0.180  1.0
  F  F30  1  0.755  0.053  0.842  1.0
  F  F31  1  0.255  0.947  0.658  1.0
  F  F32  1  0.245  0.947  0.158  1.0
  F  F33  1  0.745  0.053  0.342  1.0
  F  F34  1  0.802  0.278  0.651  1.0
  F  F35  1  0.302  0.722  0.849  1.0
  F  F36  1  0.198  0.722  0.349  1.0
  F  F37  1  0.698  0.278  0.151  1.0
  F  F38  1  0.640  0.613  0.851  1.0
  F  F39  1  0.140  0.387  0.649  1.0
  F  F40  1  0.360  0.387  0.149  1.0
  F  F41  1  0.860  0.613  0.351  1.0
  F  F42  1  0.502  0.671  0.870  1.0
  F  F43  1  0.002  0.329  0.630  1.0
  F  F44  1  0.498  0.329  0.130  1.0
  F  F45  1  0.998  0.671  0.370  1.0
  F  F46  1  0.592  0.908  0.963  1.0
  F  F47  1  0.092  0.092  0.537  1.0
  F  F48  1  0.408  0.092  0.037  1.0
  F  F49  1  0.908  0.908  0.463  1.0
[/CIF]
.