The structure described by (RbSO4)2N2 crystallizes in the orthorhombic Pnma space group. The structure consists of four ammonia atoms inside a RbSO4 framework. In the RbSO4 framework, Rb(1) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(3), and six equivalent O(1) atoms. S(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Rb(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent Rb(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbSNO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.065
_cell_length_b   7.916
_cell_length_c   10.912
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   523.918
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.183  0.593  1.0
  Rb  Rb1  1  0.250  0.683  0.907  1.0
  Rb  Rb2  1  0.750  0.817  0.407  1.0
  Rb  Rb3  1  0.750  0.317  0.093  1.0
  S  S4  1  0.250  0.230  0.921  1.0
  S  S5  1  0.250  0.730  0.579  1.0
  S  S6  1  0.750  0.770  0.079  1.0
  S  S7  1  0.750  0.270  0.421  1.0
  N  N8  1  0.250  0.485  0.305  1.0
  N  N9  1  0.250  0.985  0.195  1.0
  N  N10  1  0.750  0.515  0.695  1.0
  N  N11  1  0.750  0.015  0.805  1.0
  O  O12  1  0.051  0.296  0.855  1.0
  O  O13  1  0.449  0.796  0.645  1.0
  O  O14  1  0.551  0.704  0.145  1.0
  O  O15  1  0.949  0.204  0.355  1.0
  O  O16  1  0.949  0.704  0.145  1.0
  O  O17  1  0.551  0.204  0.355  1.0
  O  O18  1  0.449  0.296  0.855  1.0
  O  O19  1  0.051  0.796  0.645  1.0
  O  O20  1  0.250  0.043  0.913  1.0
  O  O21  1  0.250  0.543  0.587  1.0
  O  O22  1  0.750  0.957  0.087  1.0
  O  O23  1  0.750  0.457  0.413  1.0
  O  O24  1  0.250  0.786  0.450  1.0
  O  O25  1  0.250  0.286  0.050  1.0
  O  O26  1  0.750  0.214  0.550  1.0
  O  O27  1  0.750  0.714  0.950  1.0
[/CIF]
.
The structure described by (RbSO4)2N2 crystallizes in the orthorhombic Pnma space group. The structure consists of four ammonia atoms inside a RbSO4 framework. In the RbSO4 framework, Rb(1) is bonded in a 9-coordinate geometry to one O(2), two equivalent O(3), and six equivalent O(1) atoms. S(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to three equivalent Rb(1) and one S(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Rb(1) and one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to two equivalent Rb(1) and one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbSNO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.065
_cell_length_b   7.916
_cell_length_c   10.912
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   523.918
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.183  0.593  1.0
  Rb  Rb1  1  0.250  0.683  0.907  1.0
  Rb  Rb2  1  0.750  0.817  0.407  1.0
  Rb  Rb3  1  0.750  0.317  0.093  1.0
  S  S4  1  0.250  0.230  0.921  1.0
  S  S5  1  0.250  0.730  0.579  1.0
  S  S6  1  0.750  0.770  0.079  1.0
  S  S7  1  0.750  0.270  0.421  1.0
  N  N8  1  0.250  0.485  0.305  1.0
  N  N9  1  0.250  0.985  0.195  1.0
  N  N10  1  0.750  0.515  0.695  1.0
  N  N11  1  0.750  0.015  0.805  1.0
  O  O12  1  0.051  0.296  0.855  1.0
  O  O13  1  0.449  0.796  0.645  1.0
  O  O14  1  0.551  0.704  0.145  1.0
  O  O15  1  0.949  0.204  0.355  1.0
  O  O16  1  0.949  0.704  0.145  1.0
  O  O17  1  0.551  0.204  0.355  1.0
  O  O18  1  0.449  0.296  0.855  1.0
  O  O19  1  0.051  0.796  0.645  1.0
  O  O20  1  0.250  0.043  0.913  1.0
  O  O21  1  0.250  0.543  0.587  1.0
  O  O22  1  0.750  0.957  0.087  1.0
  O  O23  1  0.750  0.457  0.413  1.0
  O  O24  1  0.250  0.786  0.450  1.0
  O  O25  1  0.250  0.286  0.050  1.0
  O  O26  1  0.750  0.214  0.550  1.0
  O  O27  1  0.750  0.714  0.950  1.0
[/CIF]
.