The structure described by Li4V3Co3(TeO8)2 is Hausmannite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(3), and two equivalent O(9) atoms to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and corners with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-59°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(5), one O(7), and two equivalent O(11) atoms. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(4), one O(8), and two equivalent O(1) atoms. In the fourth Li site, Li(4) is bonded to one O(10), one O(2), and two equivalent O(6) atoms to form LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with three equivalent Te(1)O6 octahedra, and corners with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-70°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form distorted VO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, and edges with four equivalent Co(1)O6 octahedra. In the second V site, V(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form distorted VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-59°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. In the second Co site, Co(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, and edges with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form distorted TeO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with four equivalent V(2)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-59°. In the second Te site, Te(2) is bonded in a 6-coordinate geometry to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(2), one Co(2), and one Te(1) atom. In the second O site, O(2) is bonded to one Li(4), two equivalent Co(1), and one Te(1) atom to form OLiCo2Te tetrahedra that share  a cornercorner with one O(8)LiV2Te tetrahedra and corners with two equivalent O(4)LiVCo2 tetrahedra. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(1), and two equivalent Co(1) atoms. In the fourth O site, O(4) is bonded to one Li(3), one V(1), and two equivalent Co(1) atoms to form OLiVCo2 tetrahedra that share  a cornercorner with one O(8)LiV2Te tetrahedra and corners with two equivalent O(2)LiCo2Te tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), two equivalent V(2), and one Co(2) atom to form edge-sharing OLiV2Co tetrahedra. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one V(1), one Co(1), and one Te(1) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(2), two equivalent Co(1), and one Te(2) atom. In the eighth O site, O(8) is bonded to one Li(3), two equivalent V(2), and one Te(1) atom to form distorted OLiV2Te tetrahedra that share  a cornercorner with one O(2)LiCo2Te tetrahedra,  a cornercorner with one O(4)LiVCo2 tetrahedra, and  an edgeedge with one O(5)LiV2Co tetrahedra. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Li(1), one V(2), one Co(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(4), two equivalent V(2), and one Co(2) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one Co(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(1), two equivalent V(2), and one Te(2) atom. is represented by the CIF card [CIF]
data_Li4V3Co3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.934
_cell_length_b   5.934
_cell_length_c   10.370
_cell_angle_alpha   89.526
_cell_angle_beta   89.526
_cell_angle_gamma   57.978
_symmetry_Int_Tables_number   1
_cell_volume   309.611
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.338  0.338  0.905  1.0
  Li  Li1  1  0.003  0.003  0.993  1.0
  Li  Li2  1  0.007  0.007  0.487  1.0
  Li  Li3  1  0.660  0.660  0.403  1.0
  V  V4  1  0.181  0.181  0.234  1.0
  V  V5  1  0.839  0.361  0.722  1.0
  V  V6  1  0.361  0.839  0.722  1.0
  Co  Co7  1  0.636  0.187  0.215  1.0
  Co  Co8  1  0.187  0.636  0.215  1.0
  Co  Co9  1  0.824  0.824  0.708  1.0
  Te  Te10  1  0.348  0.348  0.500  1.0
  Te  Te11  1  0.672  0.672  0.016  1.0
  O  O12  1  0.680  0.171  0.597  1.0
  O  O13  1  0.481  0.481  0.352  1.0
  O  O14  1  0.312  0.312  0.103  1.0
  O  O15  1  0.014  0.014  0.298  1.0
  O  O16  1  0.006  0.006  0.802  1.0
  O  O17  1  0.171  0.680  0.597  1.0
  O  O18  1  0.473  0.016  0.329  1.0
  O  O19  1  0.016  0.473  0.329  1.0
  O  O20  1  0.839  0.839  0.104  1.0
  O  O21  1  0.151  0.151  0.610  1.0
  O  O22  1  0.988  0.487  0.819  1.0
  O  O23  1  0.487  0.988  0.819  1.0
  O  O24  1  0.653  0.653  0.600  1.0
  O  O25  1  0.833  0.332  0.104  1.0
  O  O26  1  0.513  0.513  0.821  1.0
  O  O27  1  0.332  0.833  0.104  1.0
[/CIF]
.
The structure described by Li4V3Co3(TeO8)2 is Hausmannite-derived structured and crystallizes in the monoclinic Cm space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(12), one O(3), and two equivalent O(9) atoms to form LiO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with two equivalent Co(2)O6 octahedra, and corners with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 38-59°. In the second Li site, Li(2) is bonded in a rectangular see-saw-like geometry to one O(5), one O(7), and two equivalent O(11) atoms. In the third Li site, Li(3) is bonded in a rectangular see-saw-like geometry to one O(4), one O(8), and two equivalent O(1) atoms. In the fourth Li site, Li(4) is bonded to one O(10), one O(2), and two equivalent O(6) atoms to form LiO4 tetrahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with three equivalent Te(1)O6 octahedra, and corners with four equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-70°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(3), one O(4), two equivalent O(11), and two equivalent O(6) atoms to form distorted VO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, and edges with four equivalent Co(1)O6 octahedra. In the second V site, V(2) is bonded to one O(1), one O(10), one O(12), one O(5), one O(8), and one O(9) atom to form distorted VO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-59°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(6), and one O(7) atom to form CoO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Te(1)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. In the second Co site, Co(2) is bonded to one O(10), one O(5), two equivalent O(1), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent Te(1)O6 octahedra,  a cornercorner with one Li(4)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, and edges with four equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(2), one O(8), two equivalent O(1), and two equivalent O(6) atoms to form distorted TeO6 octahedra that share corners with two equivalent Co(2)O6 octahedra, corners with four equivalent V(2)O6 octahedra, corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one V(1)O6 octahedra, and edges with two equivalent Co(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-59°. In the second Te site, Te(2) is bonded in a 6-coordinate geometry to one O(12), one O(7), two equivalent O(11), and two equivalent O(9) atoms. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Li(3), one V(2), one Co(2), and one Te(1) atom. In the second O site, O(2) is bonded to one Li(4), two equivalent Co(1), and one Te(1) atom to form OLiCo2Te tetrahedra that share  a cornercorner with one O(8)LiV2Te tetrahedra and corners with two equivalent O(4)LiVCo2 tetrahedra. In the third O site, O(3) is bonded in a distorted rectangular see-saw-like geometry to one Li(1), one V(1), and two equivalent Co(1) atoms. In the fourth O site, O(4) is bonded to one Li(3), one V(1), and two equivalent Co(1) atoms to form OLiVCo2 tetrahedra that share  a cornercorner with one O(8)LiV2Te tetrahedra and corners with two equivalent O(2)LiCo2Te tetrahedra. In the fifth O site, O(5) is bonded to one Li(2), two equivalent V(2), and one Co(2) atom to form edge-sharing OLiV2Co tetrahedra. In the sixth O site, O(6) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one V(1), one Co(1), and one Te(1) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Li(2), two equivalent Co(1), and one Te(2) atom. In the eighth O site, O(8) is bonded to one Li(3), two equivalent V(2), and one Te(1) atom to form distorted OLiV2Te tetrahedra that share  a cornercorner with one O(2)LiCo2Te tetrahedra,  a cornercorner with one O(4)LiVCo2 tetrahedra, and  an edgeedge with one O(5)LiV2Co tetrahedra. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one Li(1), one V(2), one Co(2), and one Te(2) atom. In the tenth O site, O(10) is bonded in a rectangular see-saw-like geometry to one Li(4), two equivalent V(2), and one Co(2) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one Li(2), one V(1), one Co(1), and one Te(2) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Li(1), two equivalent V(2), and one Te(2) atom. is represented by the CIF card [CIF]
data_Li4V3Co3(TeO8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.934
_cell_length_b   5.934
_cell_length_c   10.370
_cell_angle_alpha   89.526
_cell_angle_beta   89.526
_cell_angle_gamma   57.978
_symmetry_Int_Tables_number   1
_cell_volume   309.611
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.338  0.338  0.905  1.0
  Li  Li1  1  0.003  0.003  0.993  1.0
  Li  Li2  1  0.007  0.007  0.487  1.0
  Li  Li3  1  0.660  0.660  0.403  1.0
  V  V4  1  0.181  0.181  0.234  1.0
  V  V5  1  0.839  0.361  0.722  1.0
  V  V6  1  0.361  0.839  0.722  1.0
  Co  Co7  1  0.636  0.187  0.215  1.0
  Co  Co8  1  0.187  0.636  0.215  1.0
  Co  Co9  1  0.824  0.824  0.708  1.0
  Te  Te10  1  0.348  0.348  0.500  1.0
  Te  Te11  1  0.672  0.672  0.016  1.0
  O  O12  1  0.680  0.171  0.597  1.0
  O  O13  1  0.481  0.481  0.352  1.0
  O  O14  1  0.312  0.312  0.103  1.0
  O  O15  1  0.014  0.014  0.298  1.0
  O  O16  1  0.006  0.006  0.802  1.0
  O  O17  1  0.171  0.680  0.597  1.0
  O  O18  1  0.473  0.016  0.329  1.0
  O  O19  1  0.016  0.473  0.329  1.0
  O  O20  1  0.839  0.839  0.104  1.0
  O  O21  1  0.151  0.151  0.610  1.0
  O  O22  1  0.988  0.487  0.819  1.0
  O  O23  1  0.487  0.988  0.819  1.0
  O  O24  1  0.653  0.653  0.600  1.0
  O  O25  1  0.833  0.332  0.104  1.0
  O  O26  1  0.513  0.513  0.821  1.0
  O  O27  1  0.332  0.833  0.104  1.0
[/CIF]
.