The material described by UCl6SCl3 is TlF-II structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four dtxsid201337604 molecules and four SCl3 clusters. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(7), one Cl(8), and one Cl(9) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(9) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(7) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(8) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_USCl9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.079
_cell_length_b   11.161
_cell_length_c   11.701
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1446.795
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.326  0.224  0.768  1.0
  U  U1  1  0.674  0.724  0.732  1.0
  U  U2  1  0.826  0.276  0.232  1.0
  U  U3  1  0.174  0.776  0.268  1.0
  S  S4  1  0.289  0.326  0.341  1.0
  S  S5  1  0.211  0.674  0.841  1.0
  S  S6  1  0.789  0.174  0.659  1.0
  S  S7  1  0.711  0.826  0.159  1.0
  Cl  Cl8  1  0.148  0.581  0.379  1.0
  Cl  Cl9  1  0.852  0.081  0.121  1.0
  Cl  Cl10  1  0.648  0.919  0.621  1.0
  Cl  Cl11  1  0.352  0.419  0.879  1.0
  Cl  Cl12  1  0.293  0.662  0.115  1.0
  Cl  Cl13  1  0.707  0.162  0.385  1.0
  Cl  Cl14  1  0.793  0.838  0.885  1.0
  Cl  Cl15  1  0.207  0.338  0.615  1.0
  Cl  Cl16  1  0.365  0.820  0.378  1.0
  Cl  Cl17  1  0.635  0.320  0.122  1.0
  Cl  Cl18  1  0.865  0.680  0.622  1.0
  Cl  Cl19  1  0.135  0.180  0.878  1.0
  Cl  Cl20  1  0.054  0.887  0.416  1.0
  Cl  Cl21  1  0.946  0.387  0.084  1.0
  Cl  Cl22  1  0.554  0.613  0.584  1.0
  Cl  Cl23  1  0.446  0.113  0.916  1.0
  Cl  Cl24  1  0.206  0.966  0.155  1.0
  Cl  Cl25  1  0.794  0.466  0.345  1.0
  Cl  Cl26  1  0.706  0.534  0.845  1.0
  Cl  Cl27  1  0.294  0.034  0.655  1.0
  Cl  Cl28  1  0.981  0.734  0.156  1.0
  Cl  Cl29  1  0.019  0.234  0.344  1.0
  Cl  Cl30  1  0.481  0.766  0.844  1.0
  Cl  Cl31  1  0.519  0.266  0.656  1.0
  Cl  Cl32  1  0.061  0.580  0.877  1.0
  Cl  Cl33  1  0.439  0.420  0.377  1.0
  Cl  Cl34  1  0.561  0.920  0.123  1.0
  Cl  Cl35  1  0.939  0.080  0.623  1.0
  Cl  Cl36  1  0.283  0.331  0.170  1.0
  Cl  Cl37  1  0.717  0.831  0.330  1.0
  Cl  Cl38  1  0.783  0.169  0.830  1.0
  Cl  Cl39  1  0.217  0.669  0.670  1.0
  Cl  Cl40  1  0.341  0.157  0.373  1.0
  Cl  Cl41  1  0.659  0.657  0.127  1.0
  Cl  Cl42  1  0.841  0.343  0.627  1.0
  Cl  Cl43  1  0.159  0.843  0.873  1.0
[/CIF]
.
The material described by UCl6SCl3 is TlF-II structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four dtxsid201337604 molecules and four SCl3 clusters. In each SCl3 cluster, S(1) is bonded in a trigonal non-coplanar geometry to one Cl(7), one Cl(8), and one Cl(9) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(9) is bonded in a single-bond geometry to one S(1) atom. In the second Cl site, Cl(7) is bonded in a single-bond geometry to one S(1) atom. In the third Cl site, Cl(8) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF file [CIF]
data_USCl9
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.079
_cell_length_b   11.161
_cell_length_c   11.701
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1446.795
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.326  0.224  0.768  1.0
  U  U1  1  0.674  0.724  0.732  1.0
  U  U2  1  0.826  0.276  0.232  1.0
  U  U3  1  0.174  0.776  0.268  1.0
  S  S4  1  0.289  0.326  0.341  1.0
  S  S5  1  0.211  0.674  0.841  1.0
  S  S6  1  0.789  0.174  0.659  1.0
  S  S7  1  0.711  0.826  0.159  1.0
  Cl  Cl8  1  0.148  0.581  0.379  1.0
  Cl  Cl9  1  0.852  0.081  0.121  1.0
  Cl  Cl10  1  0.648  0.919  0.621  1.0
  Cl  Cl11  1  0.352  0.419  0.879  1.0
  Cl  Cl12  1  0.293  0.662  0.115  1.0
  Cl  Cl13  1  0.707  0.162  0.385  1.0
  Cl  Cl14  1  0.793  0.838  0.885  1.0
  Cl  Cl15  1  0.207  0.338  0.615  1.0
  Cl  Cl16  1  0.365  0.820  0.378  1.0
  Cl  Cl17  1  0.635  0.320  0.122  1.0
  Cl  Cl18  1  0.865  0.680  0.622  1.0
  Cl  Cl19  1  0.135  0.180  0.878  1.0
  Cl  Cl20  1  0.054  0.887  0.416  1.0
  Cl  Cl21  1  0.946  0.387  0.084  1.0
  Cl  Cl22  1  0.554  0.613  0.584  1.0
  Cl  Cl23  1  0.446  0.113  0.916  1.0
  Cl  Cl24  1  0.206  0.966  0.155  1.0
  Cl  Cl25  1  0.794  0.466  0.345  1.0
  Cl  Cl26  1  0.706  0.534  0.845  1.0
  Cl  Cl27  1  0.294  0.034  0.655  1.0
  Cl  Cl28  1  0.981  0.734  0.156  1.0
  Cl  Cl29  1  0.019  0.234  0.344  1.0
  Cl  Cl30  1  0.481  0.766  0.844  1.0
  Cl  Cl31  1  0.519  0.266  0.656  1.0
  Cl  Cl32  1  0.061  0.580  0.877  1.0
  Cl  Cl33  1  0.439  0.420  0.377  1.0
  Cl  Cl34  1  0.561  0.920  0.123  1.0
  Cl  Cl35  1  0.939  0.080  0.623  1.0
  Cl  Cl36  1  0.283  0.331  0.170  1.0
  Cl  Cl37  1  0.717  0.831  0.330  1.0
  Cl  Cl38  1  0.783  0.169  0.830  1.0
  Cl  Cl39  1  0.217  0.669  0.670  1.0
  Cl  Cl40  1  0.341  0.157  0.373  1.0
  Cl  Cl41  1  0.659  0.657  0.127  1.0
  Cl  Cl42  1  0.841  0.343  0.627  1.0
  Cl  Cl43  1  0.159  0.843  0.873  1.0
[/CIF]
.