The structure described by (P2N7H12)2Cl2 is alpha Niobium phosphide structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two P2N7H12 clusters. In each P2N7H12 cluster, there are two inequivalent P sites. In the first P site, P(1) is bonded to one N(2), one N(4), one N(5), and one N(6) atom to form corner-sharing PN4 tetrahedra. In the second P site, P(2) is bonded to one N(1), one N(3), one N(6), and one N(7) atom to form corner-sharing PN4 tetrahedra. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one P(2), one H(1), and one H(2) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one P(1), one H(4), and one H(5) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one P(2), one H(3), and one H(8) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one P(1), one H(11), and one H(6) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one P(1), one H(10), and one H(7) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one P(2), one H(12), and one H(9) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(7) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P2H12N7Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.926
_cell_length_b   7.475
_cell_length_c   11.049
_cell_angle_alpha   70.201
_cell_angle_beta   75.734
_cell_angle_gamma   88.827
_symmetry_Int_Tables_number   1
_cell_volume   445.239
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.233  0.261  0.430  1.0
  P  P1  1  0.401  0.153  0.194  1.0
  P  P2  1  0.599  0.847  0.806  1.0
  P  P3  1  0.767  0.739  0.570  1.0
  H  H4  1  0.215  0.310  0.031  1.0
  H  H5  1  0.188  0.423  0.144  1.0
  H  H6  1  0.183  0.910  0.173  1.0
  H  H7  1  0.154  0.835  0.503  1.0
  H  H8  1  0.097  0.620  0.633  1.0
  H  H9  1  0.251  0.580  0.401  1.0
  H  H10  1  0.195  0.204  0.654  1.0
  H  H11  1  0.475  0.872  0.154  1.0
  H  H12  1  0.213  0.755  0.829  1.0
  H  H13  1  0.385  0.058  0.595  1.0
  H  H14  1  0.508  0.520  0.314  1.0
  H  H15  1  0.236  0.807  0.964  1.0
  H  H16  1  0.764  0.193  0.036  1.0
  H  H17  1  0.492  0.480  0.686  1.0
  H  H18  1  0.615  0.942  0.405  1.0
  H  H19  1  0.787  0.245  0.171  1.0
  H  H20  1  0.525  0.128  0.846  1.0
  H  H21  1  0.805  0.796  0.346  1.0
  H  H22  1  0.749  0.420  0.599  1.0
  H  H23  1  0.903  0.380  0.367  1.0
  H  H24  1  0.846  0.165  0.497  1.0
  H  H25  1  0.817  0.090  0.827  1.0
  H  H26  1  0.812  0.577  0.856  1.0
  H  H27  1  0.785  0.690  0.969  1.0
  N  N28  1  0.217  0.298  0.126  1.0
  N  N29  1  0.051  0.710  0.550  1.0
  N  N30  1  0.347  0.963  0.159  1.0
  N  N31  1  0.334  0.485  0.360  1.0
  N  N32  1  0.246  0.141  0.583  1.0
  N  N33  1  0.367  0.136  0.346  1.0
  N  N34  1  0.318  0.805  0.872  1.0
  N  N35  1  0.682  0.195  0.128  1.0
  N  N36  1  0.633  0.864  0.654  1.0
  N  N37  1  0.754  0.859  0.417  1.0
  N  N38  1  0.666  0.515  0.640  1.0
  N  N39  1  0.653  0.037  0.841  1.0
  N  N40  1  0.949  0.290  0.450  1.0
  N  N41  1  0.783  0.702  0.874  1.0
  Cl  Cl42  1  0.129  0.337  0.823  1.0
  Cl  Cl43  1  0.871  0.663  0.177  1.0
[/CIF]
.
The structure described by (P2N7H12)2Cl2 is alpha Niobium phosphide structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrochloric acid atoms and two P2N7H12 clusters. In each P2N7H12 cluster, there are two inequivalent P sites. In the first P site, P(1) is bonded to one N(2), one N(4), one N(5), and one N(6) atom to form corner-sharing PN4 tetrahedra. In the second P site, P(2) is bonded to one N(1), one N(3), one N(6), and one N(7) atom to form corner-sharing PN4 tetrahedra. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one P(2), one H(1), and one H(2) atom. In the second N site, N(2) is bonded in a distorted trigonal non-coplanar geometry to one P(1), one H(4), and one H(5) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one P(2), one H(3), and one H(8) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one P(1), one H(11), and one H(6) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one P(1), one H(10), and one H(7) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one P(2), one H(12), and one H(9) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(3) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(7) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(5) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P2H12N7Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.926
_cell_length_b   7.475
_cell_length_c   11.049
_cell_angle_alpha   70.201
_cell_angle_beta   75.734
_cell_angle_gamma   88.827
_symmetry_Int_Tables_number   1
_cell_volume   445.239
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.233  0.261  0.430  1.0
  P  P1  1  0.401  0.153  0.194  1.0
  P  P2  1  0.599  0.847  0.806  1.0
  P  P3  1  0.767  0.739  0.570  1.0
  H  H4  1  0.215  0.310  0.031  1.0
  H  H5  1  0.188  0.423  0.144  1.0
  H  H6  1  0.183  0.910  0.173  1.0
  H  H7  1  0.154  0.835  0.503  1.0
  H  H8  1  0.097  0.620  0.633  1.0
  H  H9  1  0.251  0.580  0.401  1.0
  H  H10  1  0.195  0.204  0.654  1.0
  H  H11  1  0.475  0.872  0.154  1.0
  H  H12  1  0.213  0.755  0.829  1.0
  H  H13  1  0.385  0.058  0.595  1.0
  H  H14  1  0.508  0.520  0.314  1.0
  H  H15  1  0.236  0.807  0.964  1.0
  H  H16  1  0.764  0.193  0.036  1.0
  H  H17  1  0.492  0.480  0.686  1.0
  H  H18  1  0.615  0.942  0.405  1.0
  H  H19  1  0.787  0.245  0.171  1.0
  H  H20  1  0.525  0.128  0.846  1.0
  H  H21  1  0.805  0.796  0.346  1.0
  H  H22  1  0.749  0.420  0.599  1.0
  H  H23  1  0.903  0.380  0.367  1.0
  H  H24  1  0.846  0.165  0.497  1.0
  H  H25  1  0.817  0.090  0.827  1.0
  H  H26  1  0.812  0.577  0.856  1.0
  H  H27  1  0.785  0.690  0.969  1.0
  N  N28  1  0.217  0.298  0.126  1.0
  N  N29  1  0.051  0.710  0.550  1.0
  N  N30  1  0.347  0.963  0.159  1.0
  N  N31  1  0.334  0.485  0.360  1.0
  N  N32  1  0.246  0.141  0.583  1.0
  N  N33  1  0.367  0.136  0.346  1.0
  N  N34  1  0.318  0.805  0.872  1.0
  N  N35  1  0.682  0.195  0.128  1.0
  N  N36  1  0.633  0.864  0.654  1.0
  N  N37  1  0.754  0.859  0.417  1.0
  N  N38  1  0.666  0.515  0.640  1.0
  N  N39  1  0.653  0.037  0.841  1.0
  N  N40  1  0.949  0.290  0.450  1.0
  N  N41  1  0.783  0.702  0.874  1.0
  Cl  Cl42  1  0.129  0.337  0.823  1.0
  Cl  Cl43  1  0.871  0.663  0.177  1.0
[/CIF]
.