The crystal structure described by AgFBF4 crystallizes in the tetragonal P4/n space group. Ag(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form AgF6 octahedra that share corners with two equivalent Ag(1)F6 octahedra and corners with four equivalent B(1)F4 tetrahedra. The corner-sharing octahedra are not tilted. B(1) is bonded to four equivalent F(2) atoms to form BF4 tetrahedra that share corners with four equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles are 53°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Ag(1) atoms. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Ag(1) and one B(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgBF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.025
_cell_length_b   6.595
_cell_length_c   6.595
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   175.043
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.817  0.750  0.750  1.0
  Ag  Ag1  1  0.183  0.250  0.250  1.0
  B  B2  1  0.000  0.750  0.250  1.0
  B  B3  1  0.000  0.250  0.750  1.0
  F  F4  1  0.683  0.250  0.250  1.0
  F  F5  1  0.317  0.750  0.750  1.0
  F  F6  1  0.801  0.406  0.831  1.0
  F  F7  1  0.801  0.831  0.094  1.0
  F  F8  1  0.199  0.331  0.594  1.0
  F  F9  1  0.199  0.906  0.331  1.0
  F  F10  1  0.199  0.594  0.169  1.0
  F  F11  1  0.199  0.169  0.906  1.0
  F  F12  1  0.801  0.669  0.406  1.0
  F  F13  1  0.801  0.094  0.669  1.0
[/CIF]
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The crystal structure described by AgFBF4 crystallizes in the tetragonal P4/n space group. Ag(1) is bonded to two equivalent F(1) and four equivalent F(2) atoms to form AgF6 octahedra that share corners with two equivalent Ag(1)F6 octahedra and corners with four equivalent B(1)F4 tetrahedra. The corner-sharing octahedra are not tilted. B(1) is bonded to four equivalent F(2) atoms to form BF4 tetrahedra that share corners with four equivalent Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles are 53°. There are two inequivalent F sites. In the first F site, F(1) is bonded in a linear geometry to two equivalent Ag(1) atoms. In the second F site, F(2) is bonded in a distorted single-bond geometry to one Ag(1) and one B(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_AgBF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.025
_cell_length_b   6.595
_cell_length_c   6.595
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   175.043
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.817  0.750  0.750  1.0
  Ag  Ag1  1  0.183  0.250  0.250  1.0
  B  B2  1  0.000  0.750  0.250  1.0
  B  B3  1  0.000  0.250  0.750  1.0
  F  F4  1  0.683  0.250  0.250  1.0
  F  F5  1  0.317  0.750  0.750  1.0
  F  F6  1  0.801  0.406  0.831  1.0
  F  F7  1  0.801  0.831  0.094  1.0
  F  F8  1  0.199  0.331  0.594  1.0
  F  F9  1  0.199  0.906  0.331  1.0
  F  F10  1  0.199  0.594  0.169  1.0
  F  F11  1  0.199  0.169  0.906  1.0
  F  F12  1  0.801  0.669  0.406  1.0
  F  F13  1  0.801  0.094  0.669  1.0
[/CIF]
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