The material described by Pd(NO3)4(NO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and two Pd(NO3)4 clusters. In each Pd(NO3)4 cluster, Pd(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(6) atoms. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one O(2), one O(5), and one O(7) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a bent 120 degrees geometry to one Pd(1) and one N(2) atom. In the second O site, O(7) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(1) is bonded in a single-bond geometry to one N(2) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one N(3) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one N(2) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one N(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pd(N3O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.794
_cell_length_b   8.318
_cell_length_c   9.217
_cell_angle_alpha   99.527
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   589.326
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.500  0.000  0.000  1.0
  Pd  Pd1  1  0.000  0.000  0.500  1.0
  N  N2  1  0.427  0.725  0.367  1.0
  N  N3  1  0.927  0.275  0.133  1.0
  N  N4  1  0.573  0.275  0.633  1.0
  N  N5  1  0.073  0.725  0.867  1.0
  N  N6  1  0.650  0.690  0.032  1.0
  N  N7  1  0.150  0.310  0.468  1.0
  N  N8  1  0.350  0.310  0.968  1.0
  N  N9  1  0.850  0.690  0.532  1.0
  N  N10  1  0.564  0.176  0.291  1.0
  N  N11  1  0.064  0.824  0.209  1.0
  N  N12  1  0.436  0.824  0.709  1.0
  N  N13  1  0.936  0.176  0.791  1.0
  O  O14  1  0.719  0.709  0.915  1.0
  O  O15  1  0.219  0.291  0.585  1.0
  O  O16  1  0.281  0.291  0.085  1.0
  O  O17  1  0.781  0.709  0.415  1.0
  O  O18  1  0.633  0.158  0.156  1.0
  O  O19  1  0.133  0.842  0.344  1.0
  O  O20  1  0.367  0.842  0.844  1.0
  O  O21  1  0.867  0.158  0.656  1.0
  O  O22  1  0.664  0.567  0.091  1.0
  O  O23  1  0.164  0.433  0.409  1.0
  O  O24  1  0.336  0.433  0.909  1.0
  O  O25  1  0.836  0.567  0.591  1.0
  O  O26  1  0.431  0.597  0.309  1.0
  O  O27  1  0.931  0.403  0.191  1.0
  O  O28  1  0.569  0.403  0.691  1.0
  O  O29  1  0.069  0.597  0.809  1.0
  O  O30  1  0.443  0.090  0.315  1.0
  O  O31  1  0.943  0.910  0.185  1.0
  O  O32  1  0.557  0.910  0.685  1.0
  O  O33  1  0.057  0.090  0.815  1.0
  O  O34  1  0.550  0.808  0.103  1.0
  O  O35  1  0.050  0.192  0.397  1.0
  O  O36  1  0.450  0.192  0.897  1.0
  O  O37  1  0.950  0.808  0.603  1.0
  O  O38  1  0.632  0.286  0.383  1.0
  O  O39  1  0.132  0.714  0.117  1.0
  O  O40  1  0.368  0.714  0.617  1.0
  O  O41  1  0.868  0.286  0.883  1.0
[/CIF]
.
The material described by Pd(NO3)4(NO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and two Pd(NO3)4 clusters. In each Pd(NO3)4 cluster, Pd(1) is bonded in a square co-planar geometry to two equivalent O(2) and two equivalent O(6) atoms. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one O(2), one O(5), and one O(7) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a bent 120 degrees geometry to one Pd(1) and one N(2) atom. In the second O site, O(7) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(1) is bonded in a single-bond geometry to one N(2) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one Pd(1) and one N(3) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one N(2) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one N(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pd(N3O7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.794
_cell_length_b   8.318
_cell_length_c   9.217
_cell_angle_alpha   99.527
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   589.326
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.500  0.000  0.000  1.0
  Pd  Pd1  1  0.000  0.000  0.500  1.0
  N  N2  1  0.427  0.725  0.367  1.0
  N  N3  1  0.927  0.275  0.133  1.0
  N  N4  1  0.573  0.275  0.633  1.0
  N  N5  1  0.073  0.725  0.867  1.0
  N  N6  1  0.650  0.690  0.032  1.0
  N  N7  1  0.150  0.310  0.468  1.0
  N  N8  1  0.350  0.310  0.968  1.0
  N  N9  1  0.850  0.690  0.532  1.0
  N  N10  1  0.564  0.176  0.291  1.0
  N  N11  1  0.064  0.824  0.209  1.0
  N  N12  1  0.436  0.824  0.709  1.0
  N  N13  1  0.936  0.176  0.791  1.0
  O  O14  1  0.719  0.709  0.915  1.0
  O  O15  1  0.219  0.291  0.585  1.0
  O  O16  1  0.281  0.291  0.085  1.0
  O  O17  1  0.781  0.709  0.415  1.0
  O  O18  1  0.633  0.158  0.156  1.0
  O  O19  1  0.133  0.842  0.344  1.0
  O  O20  1  0.367  0.842  0.844  1.0
  O  O21  1  0.867  0.158  0.656  1.0
  O  O22  1  0.664  0.567  0.091  1.0
  O  O23  1  0.164  0.433  0.409  1.0
  O  O24  1  0.336  0.433  0.909  1.0
  O  O25  1  0.836  0.567  0.591  1.0
  O  O26  1  0.431  0.597  0.309  1.0
  O  O27  1  0.931  0.403  0.191  1.0
  O  O28  1  0.569  0.403  0.691  1.0
  O  O29  1  0.069  0.597  0.809  1.0
  O  O30  1  0.443  0.090  0.315  1.0
  O  O31  1  0.943  0.910  0.185  1.0
  O  O32  1  0.557  0.910  0.685  1.0
  O  O33  1  0.057  0.090  0.815  1.0
  O  O34  1  0.550  0.808  0.103  1.0
  O  O35  1  0.050  0.192  0.397  1.0
  O  O36  1  0.450  0.192  0.897  1.0
  O  O37  1  0.950  0.808  0.603  1.0
  O  O38  1  0.632  0.286  0.383  1.0
  O  O39  1  0.132  0.714  0.117  1.0
  O  O40  1  0.368  0.714  0.617  1.0
  O  O41  1  0.868  0.286  0.883  1.0
[/CIF]
.