The material described by XeO2FSbF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four SbF6 clusters and four XeO2F clusters. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(6), and one F(7) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In each XeO2F cluster, Xe(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one F(5) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Xe(1) atom. F(5) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbXeO2F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.930
_cell_length_b   10.534
_cell_length_c   12.352
_cell_angle_alpha   86.823
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   770.402
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.291  0.669  0.372  1.0
  Sb  Sb1  1  0.791  0.331  0.128  1.0
  Sb  Sb2  1  0.209  0.669  0.872  1.0
  Sb  Sb3  1  0.709  0.331  0.628  1.0
  Xe  Xe4  1  0.816  0.802  0.133  1.0
  Xe  Xe5  1  0.684  0.802  0.633  1.0
  Xe  Xe6  1  0.184  0.198  0.867  1.0
  Xe  Xe7  1  0.316  0.198  0.367  1.0
  O  O8  1  0.599  0.128  0.389  1.0
  O  O9  1  0.384  0.110  0.958  1.0
  O  O10  1  0.901  0.128  0.889  1.0
  O  O11  1  0.616  0.890  0.042  1.0
  O  O12  1  0.099  0.872  0.111  1.0
  O  O13  1  0.884  0.890  0.542  1.0
  O  O14  1  0.401  0.872  0.611  1.0
  O  O15  1  0.116  0.110  0.458  1.0
  F  F16  1  0.822  0.511  0.128  1.0
  F  F17  1  0.381  0.651  0.002  1.0
  F  F18  1  0.981  0.340  0.716  1.0
  F  F19  1  0.432  0.317  0.544  1.0
  F  F20  1  0.744  0.892  0.270  1.0
  F  F21  1  0.678  0.511  0.628  1.0
  F  F22  1  0.322  0.489  0.372  1.0
  F  F23  1  0.519  0.340  0.216  1.0
  F  F24  1  0.763  0.151  0.134  1.0
  F  F25  1  0.756  0.892  0.770  1.0
  F  F26  1  0.619  0.349  0.998  1.0
  F  F27  1  0.531  0.320  0.760  1.0
  F  F28  1  0.256  0.108  0.730  1.0
  F  F29  1  0.263  0.849  0.366  1.0
  F  F30  1  0.237  0.849  0.866  1.0
  F  F31  1  0.969  0.320  0.260  1.0
  F  F32  1  0.244  0.108  0.230  1.0
  F  F33  1  0.469  0.680  0.240  1.0
  F  F34  1  0.932  0.683  0.956  1.0
  F  F35  1  0.178  0.489  0.872  1.0
  F  F36  1  0.568  0.683  0.456  1.0
  F  F37  1  0.019  0.660  0.284  1.0
  F  F38  1  0.119  0.651  0.502  1.0
  F  F39  1  0.068  0.317  0.044  1.0
  F  F40  1  0.737  0.151  0.634  1.0
  F  F41  1  0.881  0.349  0.498  1.0
  F  F42  1  0.481  0.660  0.784  1.0
  F  F43  1  0.031  0.680  0.740  1.0
[/CIF]
.
The material described by XeO2FSbF6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four SbF6 clusters and four XeO2F clusters. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(6), and one F(7) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(6) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In each XeO2F cluster, Xe(1) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one F(5) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Xe(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Xe(1) atom. F(5) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbXeO2F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.930
_cell_length_b   10.534
_cell_length_c   12.352
_cell_angle_alpha   86.823
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   770.402
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.291  0.669  0.372  1.0
  Sb  Sb1  1  0.791  0.331  0.128  1.0
  Sb  Sb2  1  0.209  0.669  0.872  1.0
  Sb  Sb3  1  0.709  0.331  0.628  1.0
  Xe  Xe4  1  0.816  0.802  0.133  1.0
  Xe  Xe5  1  0.684  0.802  0.633  1.0
  Xe  Xe6  1  0.184  0.198  0.867  1.0
  Xe  Xe7  1  0.316  0.198  0.367  1.0
  O  O8  1  0.599  0.128  0.389  1.0
  O  O9  1  0.384  0.110  0.958  1.0
  O  O10  1  0.901  0.128  0.889  1.0
  O  O11  1  0.616  0.890  0.042  1.0
  O  O12  1  0.099  0.872  0.111  1.0
  O  O13  1  0.884  0.890  0.542  1.0
  O  O14  1  0.401  0.872  0.611  1.0
  O  O15  1  0.116  0.110  0.458  1.0
  F  F16  1  0.822  0.511  0.128  1.0
  F  F17  1  0.381  0.651  0.002  1.0
  F  F18  1  0.981  0.340  0.716  1.0
  F  F19  1  0.432  0.317  0.544  1.0
  F  F20  1  0.744  0.892  0.270  1.0
  F  F21  1  0.678  0.511  0.628  1.0
  F  F22  1  0.322  0.489  0.372  1.0
  F  F23  1  0.519  0.340  0.216  1.0
  F  F24  1  0.763  0.151  0.134  1.0
  F  F25  1  0.756  0.892  0.770  1.0
  F  F26  1  0.619  0.349  0.998  1.0
  F  F27  1  0.531  0.320  0.760  1.0
  F  F28  1  0.256  0.108  0.730  1.0
  F  F29  1  0.263  0.849  0.366  1.0
  F  F30  1  0.237  0.849  0.866  1.0
  F  F31  1  0.969  0.320  0.260  1.0
  F  F32  1  0.244  0.108  0.230  1.0
  F  F33  1  0.469  0.680  0.240  1.0
  F  F34  1  0.932  0.683  0.956  1.0
  F  F35  1  0.178  0.489  0.872  1.0
  F  F36  1  0.568  0.683  0.456  1.0
  F  F37  1  0.019  0.660  0.284  1.0
  F  F38  1  0.119  0.651  0.502  1.0
  F  F39  1  0.068  0.317  0.044  1.0
  F  F40  1  0.737  0.151  0.634  1.0
  F  F41  1  0.881  0.349  0.498  1.0
  F  F42  1  0.481  0.660  0.784  1.0
  F  F43  1  0.031  0.680  0.740  1.0
[/CIF]
.