The crystal structure described by YSb(WO4)2 crystallizes in the triclinic P1 space group. Y(1) is bonded to one O(1), one O(2), one O(4), one O(5), one O(6), and one O(8) atom to form distorted YO6 octahedra that share corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-63°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form distorted WO6 octahedra that share corners with four equivalent Y(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-63°. In the second W site, W(2) is bonded in a 6-coordinate geometry to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. Sb(1) is bonded in a distorted T-shaped geometry to one O(2), one O(3), and one O(7) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Y(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1), one W(2), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one W(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Y(1) and one W(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Y(1) and one W(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one W(1), one W(2), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Y(1), one W(1), and one W(2) atom. is represented by the CIF card [CIF]
data_YSb(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.280
_cell_length_b   5.928
_cell_length_c   6.397
_cell_angle_alpha   112.869
_cell_angle_beta   110.601
_cell_angle_gamma   88.680
_symmetry_Int_Tables_number   1
_cell_volume   171.174
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.533  0.281  0.908  1.0
  Sb  Sb1  1  0.037  0.736  0.874  1.0
  W  W2  1  0.289  0.611  0.403  1.0
  W  W3  1  0.777  0.946  0.389  1.0
  O  O4  1  0.299  0.321  0.161  1.0
  O  O5  1  0.271  0.531  0.679  1.0
  O  O6  1  0.395  0.786  0.211  1.0
  O  O7  1  0.173  0.967  0.579  1.0
  O  O8  1  0.756  0.055  0.151  1.0
  O  O9  1  0.728  0.222  0.630  1.0
  O  O10  1  0.675  0.769  0.598  1.0
  O  O11  1  0.866  0.596  0.220  1.0
[/CIF]
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The crystal structure described by YSb(WO4)2 crystallizes in the triclinic P1 space group. Y(1) is bonded to one O(1), one O(2), one O(4), one O(5), one O(6), and one O(8) atom to form distorted YO6 octahedra that share corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-63°. There are two inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(7), and one O(8) atom to form distorted WO6 octahedra that share corners with four equivalent Y(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 45-63°. In the second W site, W(2) is bonded in a 6-coordinate geometry to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. Sb(1) is bonded in a distorted T-shaped geometry to one O(2), one O(3), and one O(7) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Y(1) and one W(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one Sb(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1), one W(2), and one Sb(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Y(1), one W(1), and one W(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Y(1) and one W(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Y(1) and one W(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one W(1), one W(2), and one Sb(1) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Y(1), one W(1), and one W(2) atom. is represented by the CIF card [CIF]
data_YSb(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.280
_cell_length_b   5.928
_cell_length_c   6.397
_cell_angle_alpha   112.869
_cell_angle_beta   110.601
_cell_angle_gamma   88.680
_symmetry_Int_Tables_number   1
_cell_volume   171.174
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  1  0.533  0.281  0.908  1.0
  Sb  Sb1  1  0.037  0.736  0.874  1.0
  W  W2  1  0.289  0.611  0.403  1.0
  W  W3  1  0.777  0.946  0.389  1.0
  O  O4  1  0.299  0.321  0.161  1.0
  O  O5  1  0.271  0.531  0.679  1.0
  O  O6  1  0.395  0.786  0.211  1.0
  O  O7  1  0.173  0.967  0.579  1.0
  O  O8  1  0.756  0.055  0.151  1.0
  O  O9  1  0.728  0.222  0.630  1.0
  O  O10  1  0.675  0.769  0.598  1.0
  O  O11  1  0.866  0.596  0.220  1.0
[/CIF]
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