The compound described by PtN2 is Marcasite structured and crystallizes in the orthorhombic Pnnm space group. Pt(1) is bonded to six equivalent N(1) atoms to form PtN6 octahedra that share corners with eight equivalent Pt(1)N6 octahedra, corners with six equivalent N(1)Pt3N tetrahedra, and edges with two equivalent Pt(1)N6 octahedra. The corner-sharing octahedral tilt angles are 69°. N(1) is bonded to three equivalent Pt(1) and one N(1) atom to form NPt3N tetrahedra that share corners with three equivalent Pt(1)N6 octahedra, corners with thirteen equivalent N(1)Pt3N tetrahedra, and  an edgeedge with one N(1)Pt3N tetrahedra. The corner-sharing octahedral tilt angles range from 67-69°. is represented by the Crystallographic Information File (CIF) [CIF]
data_PtN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.200
_cell_length_b   3.764
_cell_length_c   4.876
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   58.740
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.000  0.000  0.000  1.0
  Pt  Pt1  1  0.500  0.500  0.500  1.0
  N  N2  1  0.500  0.351  0.915  1.0
  N  N3  1  0.500  0.649  0.085  1.0
  N  N4  1  0.000  0.149  0.415  1.0
  N  N5  1  0.000  0.851  0.585  1.0
[/CIF]
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The compound described by PtN2 is Marcasite structured and crystallizes in the orthorhombic Pnnm space group. Pt(1) is bonded to six equivalent N(1) atoms to form PtN6 octahedra that share corners with eight equivalent Pt(1)N6 octahedra, corners with six equivalent N(1)Pt3N tetrahedra, and edges with two equivalent Pt(1)N6 octahedra. The corner-sharing octahedral tilt angles are 69°. N(1) is bonded to three equivalent Pt(1) and one N(1) atom to form NPt3N tetrahedra that share corners with three equivalent Pt(1)N6 octahedra, corners with thirteen equivalent N(1)Pt3N tetrahedra, and  an edgeedge with one N(1)Pt3N tetrahedra. The corner-sharing octahedral tilt angles range from 67-69°. is represented by the Crystallographic Information File (CIF) [CIF]
data_PtN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.200
_cell_length_b   3.764
_cell_length_c   4.876
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   58.740
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.000  0.000  0.000  1.0
  Pt  Pt1  1  0.500  0.500  0.500  1.0
  N  N2  1  0.500  0.351  0.915  1.0
  N  N3  1  0.500  0.649  0.085  1.0
  N  N4  1  0.000  0.149  0.415  1.0
  N  N5  1  0.000  0.851  0.585  1.0
[/CIF]
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