The material structure described by NaSbS2 crystallizes in the monoclinic C2/c space group. Na(1) is bonded to six equivalent S(1) atoms to form a mixture of corner and edge-sharing NaS6 octahedra. The corner-sharing octahedral tilt angles are 11°. Sb(1) is bonded in a rectangular see-saw-like geometry to four equivalent S(1) atoms. S(1) is bonded to three equivalent Na(1) and two equivalent Sb(1) atoms to form a mixture of corner and edge-sharing SNa3Sb2 square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaSbS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.851
_cell_length_b   5.851
_cell_length_c   6.855
_cell_angle_alpha   113.479
_cell_angle_beta   113.479
_cell_angle_gamma   90.426
_symmetry_Int_Tables_number   1
_cell_volume   193.507
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.635  0.365  0.750  1.0
  Na  Na1  1  0.365  0.635  0.250  1.0
  Sb  Sb2  1  0.898  0.102  0.250  1.0
  Sb  Sb3  1  0.102  0.898  0.750  1.0
  S  S4  1  0.688  0.867  0.760  1.0
  S  S5  1  0.133  0.312  0.740  1.0
  S  S6  1  0.312  0.133  0.240  1.0
  S  S7  1  0.867  0.688  0.260  1.0
[/CIF]
.
The material structure described by NaSbS2 crystallizes in the monoclinic C2/c space group. Na(1) is bonded to six equivalent S(1) atoms to form a mixture of corner and edge-sharing NaS6 octahedra. The corner-sharing octahedral tilt angles are 11°. Sb(1) is bonded in a rectangular see-saw-like geometry to four equivalent S(1) atoms. S(1) is bonded to three equivalent Na(1) and two equivalent Sb(1) atoms to form a mixture of corner and edge-sharing SNa3Sb2 square pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaSbS2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.851
_cell_length_b   5.851
_cell_length_c   6.855
_cell_angle_alpha   113.479
_cell_angle_beta   113.479
_cell_angle_gamma   90.426
_symmetry_Int_Tables_number   1
_cell_volume   193.507
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.635  0.365  0.750  1.0
  Na  Na1  1  0.365  0.635  0.250  1.0
  Sb  Sb2  1  0.898  0.102  0.250  1.0
  Sb  Sb3  1  0.102  0.898  0.750  1.0
  S  S4  1  0.688  0.867  0.760  1.0
  S  S5  1  0.133  0.312  0.740  1.0
  S  S6  1  0.312  0.133  0.240  1.0
  S  S7  1  0.867  0.688  0.260  1.0
[/CIF]
.