The crystal structure described by Rb2LiBa8(Sb3O)2 crystallizes in the orthorhombic Fmm2 space group. Rb(1) is bonded in a 7-coordinate geometry to one Li(1), one Sb(2), one Sb(3), two equivalent Sb(1), and two equivalent Sb(4) atoms. Li(1) is bonded in a 3-coordinate geometry to two equivalent Rb(1), one Sb(3), and two equivalent Sb(1) atoms. There are three inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a distorted single-bond geometry to one Sb(2), two equivalent Sb(4), and one O(1) atom. In the second Ba site, Ba(2) is bonded in a distorted single-bond geometry to two equivalent Sb(4) and one O(1) atom. In the third Ba site, Ba(3) is bonded in a single-bond geometry to one Sb(2), two equivalent Sb(4), and one O(1) atom. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Li(1) atom. In the second Sb site, Sb(2) is bonded in a 9-coordinate geometry to two equivalent Rb(1), two equivalent Ba(3), four equivalent Ba(1), and one Sb(3) atom. In the third Sb site, Sb(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one Li(1), and one Sb(2) atom. In the fourth Sb site, Sb(4) is bonded in a 10-coordinate geometry to two equivalent Rb(1), two equivalent Ba(2), two equivalent Ba(3), and four equivalent Ba(1) atoms. O(1) is bonded in a tetrahedral geometry to one Ba(2), one Ba(3), and two equivalent Ba(1) atoms. is represented by the CIF card [CIF]
data_Rb2Ba8Li(Sb3O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.186
_cell_length_b   9.186
_cell_length_c   10.757
_cell_angle_alpha   116.023
_cell_angle_beta   116.023
_cell_angle_gamma   88.421
_symmetry_Int_Tables_number   1
_cell_volume   717.542
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.001  0.011  0.000  1.0
  Rb  Rb1  1  0.511  0.501  0.000  1.0
  Ba  Ba2  1  0.503  0.693  0.704  1.0
  Ba  Ba3  1  0.193  0.003  0.704  1.0
  Ba  Ba4  1  0.799  0.990  0.296  1.0
  Ba  Ba5  1  0.979  0.479  0.651  1.0
  Ba  Ba6  1  0.490  0.299  0.296  1.0
  Ba  Ba7  1  0.697  0.197  0.696  1.0
  Ba  Ba8  1  0.000  0.500  0.304  1.0
  Ba  Ba9  1  0.328  0.828  0.349  1.0
  Li  Li10  1  0.179  0.679  0.000  1.0
  Sb  Sb11  1  0.894  0.622  0.000  1.0
  Sb  Sb12  1  0.630  0.130  0.000  1.0
  Sb  Sb13  1  0.122  0.394  0.000  1.0
  Sb  Sb14  1  0.377  0.877  0.000  1.0
  Sb  Sb15  1  0.251  0.251  0.500  1.0
  Sb  Sb16  1  0.751  0.751  0.500  1.0
  O  O17  1  0.740  0.240  0.490  1.0
  O  O18  1  0.250  0.750  0.510  1.0
[/CIF]
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The crystal structure described by Rb2LiBa8(Sb3O)2 crystallizes in the orthorhombic Fmm2 space group. Rb(1) is bonded in a 7-coordinate geometry to one Li(1), one Sb(2), one Sb(3), two equivalent Sb(1), and two equivalent Sb(4) atoms. Li(1) is bonded in a 3-coordinate geometry to two equivalent Rb(1), one Sb(3), and two equivalent Sb(1) atoms. There are three inequivalent Ba sites. In the first Ba site, Ba(1) is bonded in a distorted single-bond geometry to one Sb(2), two equivalent Sb(4), and one O(1) atom. In the second Ba site, Ba(2) is bonded in a distorted single-bond geometry to two equivalent Sb(4) and one O(1) atom. In the third Ba site, Ba(3) is bonded in a single-bond geometry to one Sb(2), two equivalent Sb(4), and one O(1) atom. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one Li(1) atom. In the second Sb site, Sb(2) is bonded in a 9-coordinate geometry to two equivalent Rb(1), two equivalent Ba(3), four equivalent Ba(1), and one Sb(3) atom. In the third Sb site, Sb(3) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one Li(1), and one Sb(2) atom. In the fourth Sb site, Sb(4) is bonded in a 10-coordinate geometry to two equivalent Rb(1), two equivalent Ba(2), two equivalent Ba(3), and four equivalent Ba(1) atoms. O(1) is bonded in a tetrahedral geometry to one Ba(2), one Ba(3), and two equivalent Ba(1) atoms. is represented by the CIF card [CIF]
data_Rb2Ba8Li(Sb3O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.186
_cell_length_b   9.186
_cell_length_c   10.757
_cell_angle_alpha   116.023
_cell_angle_beta   116.023
_cell_angle_gamma   88.421
_symmetry_Int_Tables_number   1
_cell_volume   717.542
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.001  0.011  0.000  1.0
  Rb  Rb1  1  0.511  0.501  0.000  1.0
  Ba  Ba2  1  0.503  0.693  0.704  1.0
  Ba  Ba3  1  0.193  0.003  0.704  1.0
  Ba  Ba4  1  0.799  0.990  0.296  1.0
  Ba  Ba5  1  0.979  0.479  0.651  1.0
  Ba  Ba6  1  0.490  0.299  0.296  1.0
  Ba  Ba7  1  0.697  0.197  0.696  1.0
  Ba  Ba8  1  0.000  0.500  0.304  1.0
  Ba  Ba9  1  0.328  0.828  0.349  1.0
  Li  Li10  1  0.179  0.679  0.000  1.0
  Sb  Sb11  1  0.894  0.622  0.000  1.0
  Sb  Sb12  1  0.630  0.130  0.000  1.0
  Sb  Sb13  1  0.122  0.394  0.000  1.0
  Sb  Sb14  1  0.377  0.877  0.000  1.0
  Sb  Sb15  1  0.251  0.251  0.500  1.0
  Sb  Sb16  1  0.751  0.751  0.500  1.0
  O  O17  1  0.740  0.240  0.490  1.0
  O  O18  1  0.250  0.750  0.510  1.0
[/CIF]
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