The compound described by PN2H crystallizes in the monoclinic P2/c space group. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(2), one N(3), and one N(5) atom to form corner-sharing PN4 tetrahedra. In the second P site, P(2) is bonded to one N(2), one N(3), one N(4), and one N(5) atom to form corner-sharing PN4 tetrahedra. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to two equivalent P(1) atoms. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one P(1), one P(2), and one H(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one P(1), one P(2), and one H(1) atom. In the fourth N site, N(4) is bonded in a bent 150 degrees geometry to two equivalent P(2) atoms. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PHN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.893
_cell_length_b   8.096
_cell_length_c   8.317
_cell_angle_alpha   108.861
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   311.783
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.712  0.318  0.264  1.0
  P  P1  1  0.712  0.682  0.236  1.0
  P  P2  1  0.288  0.682  0.736  1.0
  P  P3  1  0.288  0.318  0.764  1.0
  P  P4  1  0.807  0.182  0.878  1.0
  P  P5  1  0.807  0.818  0.622  1.0
  P  P6  1  0.193  0.818  0.122  1.0
  P  P7  1  0.193  0.182  0.378  1.0
  H  H8  1  0.301  0.455  0.369  1.0
  H  H9  1  0.301  0.545  0.131  1.0
  H  H10  1  0.699  0.545  0.631  1.0
  H  H11  1  0.699  0.455  0.869  1.0
  H  H12  1  0.690  0.044  0.068  1.0
  H  H13  1  0.690  0.956  0.432  1.0
  H  H14  1  0.310  0.956  0.932  1.0
  H  H15  1  0.310  0.044  0.568  1.0
  N  N16  1  0.799  0.500  0.250  1.0
  N  N17  1  0.201  0.500  0.750  1.0
  N  N18  1  0.719  0.169  0.069  1.0
  N  N19  1  0.719  0.831  0.431  1.0
  N  N20  1  0.281  0.831  0.931  1.0
  N  N21  1  0.281  0.169  0.569  1.0
  N  N22  1  0.386  0.334  0.335  1.0
  N  N23  1  0.386  0.666  0.165  1.0
  N  N24  1  0.614  0.666  0.665  1.0
  N  N25  1  0.614  0.334  0.835  1.0
  N  N26  1  0.716  0.000  0.750  1.0
  N  N27  1  0.284  0.000  0.250  1.0
  N  N28  1  0.882  0.246  0.391  1.0
  N  N29  1  0.882  0.754  0.109  1.0
  N  N30  1  0.118  0.754  0.609  1.0
  N  N31  1  0.118  0.246  0.891  1.0
[/CIF]
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The compound described by PN2H crystallizes in the monoclinic P2/c space group. There are two inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(2), one N(3), and one N(5) atom to form corner-sharing PN4 tetrahedra. In the second P site, P(2) is bonded to one N(2), one N(3), one N(4), and one N(5) atom to form corner-sharing PN4 tetrahedra. There are five inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to two equivalent P(1) atoms. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one P(1), one P(2), and one H(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one P(1), one P(2), and one H(1) atom. In the fourth N site, N(4) is bonded in a bent 150 degrees geometry to two equivalent P(2) atoms. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_PHN2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.893
_cell_length_b   8.096
_cell_length_c   8.317
_cell_angle_alpha   108.861
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   311.783
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.712  0.318  0.264  1.0
  P  P1  1  0.712  0.682  0.236  1.0
  P  P2  1  0.288  0.682  0.736  1.0
  P  P3  1  0.288  0.318  0.764  1.0
  P  P4  1  0.807  0.182  0.878  1.0
  P  P5  1  0.807  0.818  0.622  1.0
  P  P6  1  0.193  0.818  0.122  1.0
  P  P7  1  0.193  0.182  0.378  1.0
  H  H8  1  0.301  0.455  0.369  1.0
  H  H9  1  0.301  0.545  0.131  1.0
  H  H10  1  0.699  0.545  0.631  1.0
  H  H11  1  0.699  0.455  0.869  1.0
  H  H12  1  0.690  0.044  0.068  1.0
  H  H13  1  0.690  0.956  0.432  1.0
  H  H14  1  0.310  0.956  0.932  1.0
  H  H15  1  0.310  0.044  0.568  1.0
  N  N16  1  0.799  0.500  0.250  1.0
  N  N17  1  0.201  0.500  0.750  1.0
  N  N18  1  0.719  0.169  0.069  1.0
  N  N19  1  0.719  0.831  0.431  1.0
  N  N20  1  0.281  0.831  0.931  1.0
  N  N21  1  0.281  0.169  0.569  1.0
  N  N22  1  0.386  0.334  0.335  1.0
  N  N23  1  0.386  0.666  0.165  1.0
  N  N24  1  0.614  0.666  0.665  1.0
  N  N25  1  0.614  0.334  0.835  1.0
  N  N26  1  0.716  0.000  0.750  1.0
  N  N27  1  0.284  0.000  0.250  1.0
  N  N28  1  0.882  0.246  0.391  1.0
  N  N29  1  0.882  0.754  0.109  1.0
  N  N30  1  0.118  0.754  0.609  1.0
  N  N31  1  0.118  0.246  0.891  1.0
[/CIF]
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