The crystal structure described by CsReBr4 crystallizes in the orthorhombic Pbca space group. Cs(1) is bonded in a 11-coordinate geometry to two equivalent Br(3), three equivalent Br(1), three equivalent Br(2), and three equivalent Br(4) atoms. Re(1) is bonded in a 5-coordinate geometry to one Re(1), one Br(1), one Br(2), one Br(3), and one Br(4) atom. There are four inequivalent Br sites. In the first Br site, Br(3) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Re(1) atom. In the second Br site, Br(4) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Re(1) atom. In the third Br site, Br(1) is bonded to three equivalent Cs(1) and one Re(1) atom to form distorted corner-sharing BrCs3Re trigonal pyramids. In the fourth Br site, Br(2) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsReBr4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.373
_cell_length_b   12.697
_cell_length_c   13.220
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1741.077
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.333  0.696  0.365  1.0
  Cs  Cs1  1  0.833  0.804  0.635  1.0
  Cs  Cs2  1  0.667  0.196  0.135  1.0
  Cs  Cs3  1  0.167  0.304  0.865  1.0
  Cs  Cs4  1  0.667  0.304  0.635  1.0
  Cs  Cs5  1  0.167  0.196  0.365  1.0
  Cs  Cs6  1  0.333  0.804  0.865  1.0
  Cs  Cs7  1  0.833  0.696  0.135  1.0
  Re  Re8  1  0.559  0.014  0.431  1.0
  Re  Re9  1  0.059  0.486  0.569  1.0
  Re  Re10  1  0.441  0.514  0.069  1.0
  Re  Re11  1  0.941  0.986  0.931  1.0
  Re  Re12  1  0.441  0.986  0.569  1.0
  Re  Re13  1  0.941  0.514  0.431  1.0
  Re  Re14  1  0.559  0.486  0.931  1.0
  Re  Re15  1  0.059  0.014  0.069  1.0
  Br  Br16  1  0.529  0.206  0.394  1.0
  Br  Br17  1  0.029  0.294  0.606  1.0
  Br  Br18  1  0.471  0.706  0.106  1.0
  Br  Br19  1  0.971  0.794  0.894  1.0
  Br  Br20  1  0.471  0.794  0.606  1.0
  Br  Br21  1  0.971  0.706  0.394  1.0
  Br  Br22  1  0.529  0.294  0.894  1.0
  Br  Br23  1  0.029  0.206  0.106  1.0
  Br  Br24  1  0.412  0.984  0.284  1.0
  Br  Br25  1  0.912  0.516  0.716  1.0
  Br  Br26  1  0.588  0.484  0.216  1.0
  Br  Br27  1  0.088  0.016  0.784  1.0
  Br  Br28  1  0.588  0.016  0.716  1.0
  Br  Br29  1  0.088  0.484  0.284  1.0
  Br  Br30  1  0.412  0.516  0.784  1.0
  Br  Br31  1  0.912  0.984  0.216  1.0
  Br  Br32  1  0.277  0.061  0.004  1.0
  Br  Br33  1  0.777  0.439  0.996  1.0
  Br  Br34  1  0.723  0.561  0.496  1.0
  Br  Br35  1  0.223  0.939  0.504  1.0
  Br  Br36  1  0.723  0.939  0.996  1.0
  Br  Br37  1  0.223  0.561  0.004  1.0
  Br  Br38  1  0.277  0.439  0.504  1.0
  Br  Br39  1  0.777  0.061  0.496  1.0
  Br  Br40  1  0.152  0.839  0.112  1.0
  Br  Br41  1  0.652  0.661  0.888  1.0
  Br  Br42  1  0.848  0.339  0.388  1.0
  Br  Br43  1  0.348  0.161  0.612  1.0
  Br  Br44  1  0.848  0.161  0.888  1.0
  Br  Br45  1  0.348  0.339  0.112  1.0
  Br  Br46  1  0.152  0.661  0.612  1.0
  Br  Br47  1  0.652  0.839  0.388  1.0
[/CIF]
.
The crystal structure described by CsReBr4 crystallizes in the orthorhombic Pbca space group. Cs(1) is bonded in a 11-coordinate geometry to two equivalent Br(3), three equivalent Br(1), three equivalent Br(2), and three equivalent Br(4) atoms. Re(1) is bonded in a 5-coordinate geometry to one Re(1), one Br(1), one Br(2), one Br(3), and one Br(4) atom. There are four inequivalent Br sites. In the first Br site, Br(3) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one Re(1) atom. In the second Br site, Br(4) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Re(1) atom. In the third Br site, Br(1) is bonded to three equivalent Cs(1) and one Re(1) atom to form distorted corner-sharing BrCs3Re trigonal pyramids. In the fourth Br site, Br(2) is bonded in a distorted single-bond geometry to three equivalent Cs(1) and one Re(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsReBr4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.373
_cell_length_b   12.697
_cell_length_c   13.220
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1741.077
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.333  0.696  0.365  1.0
  Cs  Cs1  1  0.833  0.804  0.635  1.0
  Cs  Cs2  1  0.667  0.196  0.135  1.0
  Cs  Cs3  1  0.167  0.304  0.865  1.0
  Cs  Cs4  1  0.667  0.304  0.635  1.0
  Cs  Cs5  1  0.167  0.196  0.365  1.0
  Cs  Cs6  1  0.333  0.804  0.865  1.0
  Cs  Cs7  1  0.833  0.696  0.135  1.0
  Re  Re8  1  0.559  0.014  0.431  1.0
  Re  Re9  1  0.059  0.486  0.569  1.0
  Re  Re10  1  0.441  0.514  0.069  1.0
  Re  Re11  1  0.941  0.986  0.931  1.0
  Re  Re12  1  0.441  0.986  0.569  1.0
  Re  Re13  1  0.941  0.514  0.431  1.0
  Re  Re14  1  0.559  0.486  0.931  1.0
  Re  Re15  1  0.059  0.014  0.069  1.0
  Br  Br16  1  0.529  0.206  0.394  1.0
  Br  Br17  1  0.029  0.294  0.606  1.0
  Br  Br18  1  0.471  0.706  0.106  1.0
  Br  Br19  1  0.971  0.794  0.894  1.0
  Br  Br20  1  0.471  0.794  0.606  1.0
  Br  Br21  1  0.971  0.706  0.394  1.0
  Br  Br22  1  0.529  0.294  0.894  1.0
  Br  Br23  1  0.029  0.206  0.106  1.0
  Br  Br24  1  0.412  0.984  0.284  1.0
  Br  Br25  1  0.912  0.516  0.716  1.0
  Br  Br26  1  0.588  0.484  0.216  1.0
  Br  Br27  1  0.088  0.016  0.784  1.0
  Br  Br28  1  0.588  0.016  0.716  1.0
  Br  Br29  1  0.088  0.484  0.284  1.0
  Br  Br30  1  0.412  0.516  0.784  1.0
  Br  Br31  1  0.912  0.984  0.216  1.0
  Br  Br32  1  0.277  0.061  0.004  1.0
  Br  Br33  1  0.777  0.439  0.996  1.0
  Br  Br34  1  0.723  0.561  0.496  1.0
  Br  Br35  1  0.223  0.939  0.504  1.0
  Br  Br36  1  0.723  0.939  0.996  1.0
  Br  Br37  1  0.223  0.561  0.004  1.0
  Br  Br38  1  0.277  0.439  0.504  1.0
  Br  Br39  1  0.777  0.061  0.496  1.0
  Br  Br40  1  0.152  0.839  0.112  1.0
  Br  Br41  1  0.652  0.661  0.888  1.0
  Br  Br42  1  0.848  0.339  0.388  1.0
  Br  Br43  1  0.348  0.161  0.612  1.0
  Br  Br44  1  0.848  0.161  0.888  1.0
  Br  Br45  1  0.348  0.339  0.112  1.0
  Br  Br46  1  0.152  0.661  0.612  1.0
  Br  Br47  1  0.652  0.839  0.388  1.0
[/CIF]
.