The structure described by LiVTeO5 crystallizes in the orthorhombic P2_12_12_1 space group. Li(1) is bonded in a distorted T-shaped geometry to one O(2), one O(4), and one O(5) atom. V(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(4), and one O(5) atom. Te(1) is bonded in an L-shaped geometry to one O(1) and one O(4) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Te(1) and one O(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Li(1) and one V(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one V(1) and one O(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one V(1), and one Te(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. is represented by the CIF file [CIF]
data_LiVTeO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.295
_cell_length_b   7.952
_cell_length_c   11.228
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   562.059
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.092  0.894  0.974  1.0
  Li  Li1  1  0.908  0.394  0.526  1.0
  Li  Li2  1  0.592  0.606  0.026  1.0
  Li  Li3  1  0.408  0.106  0.474  1.0
  V  V4  1  0.948  0.040  0.657  1.0
  V  V5  1  0.448  0.460  0.343  1.0
  V  V6  1  0.052  0.540  0.843  1.0
  V  V7  1  0.552  0.960  0.157  1.0
  Te  Te8  1  0.892  0.041  0.349  1.0
  Te  Te9  1  0.608  0.959  0.849  1.0
  Te  Te10  1  0.108  0.541  0.151  1.0
  Te  Te11  1  0.392  0.459  0.651  1.0
  O  O12  1  0.576  0.165  0.946  1.0
  O  O13  1  0.302  0.927  0.110  1.0
  O  O14  1  0.146  0.355  0.928  1.0
  O  O15  1  0.198  0.073  0.610  1.0
  O  O16  1  0.646  0.145  0.072  1.0
  O  O17  1  0.924  0.835  0.446  1.0
  O  O18  1  0.802  0.573  0.890  1.0
  O  O19  1  0.854  0.855  0.572  1.0
  O  O20  1  0.698  0.427  0.390  1.0
  O  O21  1  0.080  0.487  0.681  1.0
  O  O22  1  0.706  0.793  0.120  1.0
  O  O23  1  0.920  0.987  0.819  1.0
  O  O24  1  0.294  0.293  0.380  1.0
  O  O25  1  0.206  0.707  0.880  1.0
  O  O26  1  0.424  0.665  0.554  1.0
  O  O27  1  0.580  0.013  0.319  1.0
  O  O28  1  0.420  0.513  0.181  1.0
  O  O29  1  0.076  0.335  0.054  1.0
  O  O30  1  0.794  0.207  0.620  1.0
  O  O31  1  0.354  0.645  0.428  1.0
[/CIF]
.
The structure described by LiVTeO5 crystallizes in the orthorhombic P2_12_12_1 space group. Li(1) is bonded in a distorted T-shaped geometry to one O(2), one O(4), and one O(5) atom. V(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(4), and one O(5) atom. Te(1) is bonded in an L-shaped geometry to one O(1) and one O(4) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Te(1) and one O(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Li(1) and one V(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one V(1) and one O(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Li(1), one V(1), and one Te(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Li(1) and one V(1) atom. is represented by the CIF file [CIF]
data_LiVTeO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.295
_cell_length_b   7.952
_cell_length_c   11.228
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   562.059
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.092  0.894  0.974  1.0
  Li  Li1  1  0.908  0.394  0.526  1.0
  Li  Li2  1  0.592  0.606  0.026  1.0
  Li  Li3  1  0.408  0.106  0.474  1.0
  V  V4  1  0.948  0.040  0.657  1.0
  V  V5  1  0.448  0.460  0.343  1.0
  V  V6  1  0.052  0.540  0.843  1.0
  V  V7  1  0.552  0.960  0.157  1.0
  Te  Te8  1  0.892  0.041  0.349  1.0
  Te  Te9  1  0.608  0.959  0.849  1.0
  Te  Te10  1  0.108  0.541  0.151  1.0
  Te  Te11  1  0.392  0.459  0.651  1.0
  O  O12  1  0.576  0.165  0.946  1.0
  O  O13  1  0.302  0.927  0.110  1.0
  O  O14  1  0.146  0.355  0.928  1.0
  O  O15  1  0.198  0.073  0.610  1.0
  O  O16  1  0.646  0.145  0.072  1.0
  O  O17  1  0.924  0.835  0.446  1.0
  O  O18  1  0.802  0.573  0.890  1.0
  O  O19  1  0.854  0.855  0.572  1.0
  O  O20  1  0.698  0.427  0.390  1.0
  O  O21  1  0.080  0.487  0.681  1.0
  O  O22  1  0.706  0.793  0.120  1.0
  O  O23  1  0.920  0.987  0.819  1.0
  O  O24  1  0.294  0.293  0.380  1.0
  O  O25  1  0.206  0.707  0.880  1.0
  O  O26  1  0.424  0.665  0.554  1.0
  O  O27  1  0.580  0.013  0.319  1.0
  O  O28  1  0.420  0.513  0.181  1.0
  O  O29  1  0.076  0.335  0.054  1.0
  O  O30  1  0.794  0.207  0.620  1.0
  O  O31  1  0.354  0.645  0.428  1.0
[/CIF]
.