The crystal structure described by HoCl4C4N2Cl(ClCCN)2 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of four chloromethyl(methylidyne)azanium molecules, two C4N2Cl clusters, and two HoCl4 clusters. In each C4N2Cl cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one N(1) atom. In the second C site, C(2) is bonded in a water-like geometry to one N(1) and one Cl(4) atom. N(1) is bonded in a linear geometry to one C(1) and one C(2) atom. Cl(4) is bonded in a bent 150 degrees geometry to two equivalent C(2) atoms. In each HoCl4 cluster, Ho(1) is bonded in a 4-coordinate geometry to two equivalent Cl(1) and two equivalent Cl(3) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Ho(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Ho(1) atom. is represented by the CIF file [CIF]
data_HoC8N4Cl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.589
_cell_length_b   9.037
_cell_length_c   14.469
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1123.077
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.305  0.500  0.500  1.0
  Ho  Ho1  1  0.695  0.000  0.000  1.0
  C  C2  1  0.123  0.757  0.671  1.0
  C  C3  1  0.123  0.243  0.329  1.0
  C  C4  1  0.877  0.743  0.171  1.0
  C  C5  1  0.877  0.257  0.829  1.0
  C  C6  1  0.955  0.792  0.531  1.0
  C  C7  1  0.955  0.208  0.469  1.0
  C  C8  1  0.045  0.708  0.031  1.0
  C  C9  1  0.045  0.292  0.969  1.0
  C  C10  1  0.386  0.681  0.851  1.0
  C  C11  1  0.386  0.319  0.149  1.0
  C  C12  1  0.614  0.819  0.351  1.0
  C  C13  1  0.614  0.181  0.649  1.0
  C  C14  1  0.651  0.566  0.831  1.0
  C  C15  1  0.651  0.434  0.169  1.0
  C  C16  1  0.349  0.934  0.331  1.0
  C  C17  1  0.349  0.066  0.669  1.0
  N  N18  1  0.053  0.784  0.599  1.0
  N  N19  1  0.053  0.216  0.401  1.0
  N  N20  1  0.947  0.716  0.099  1.0
  N  N21  1  0.947  0.284  0.901  1.0
  N  N22  1  0.533  0.635  0.845  1.0
  N  N23  1  0.533  0.365  0.155  1.0
  N  N24  1  0.467  0.865  0.345  1.0
  N  N25  1  0.467  0.135  0.655  1.0
  Cl  Cl26  1  0.410  0.700  0.605  1.0
  Cl  Cl27  1  0.410  0.300  0.395  1.0
  Cl  Cl28  1  0.590  0.800  0.105  1.0
  Cl  Cl29  1  0.590  0.200  0.895  1.0
  Cl  Cl30  1  0.623  0.637  0.385  1.0
  Cl  Cl31  1  0.623  0.363  0.615  1.0
  Cl  Cl32  1  0.377  0.863  0.885  1.0
  Cl  Cl33  1  0.377  0.137  0.115  1.0
  Cl  Cl34  1  0.111  0.649  0.407  1.0
  Cl  Cl35  1  0.111  0.351  0.593  1.0
  Cl  Cl36  1  0.889  0.851  0.907  1.0
  Cl  Cl37  1  0.889  0.149  0.093  1.0
  Cl  Cl38  1  0.914  0.000  0.500  1.0
  Cl  Cl39  1  0.086  0.500  0.000  1.0
[/CIF]
.
The crystal structure described by HoCl4C4N2Cl(ClCCN)2 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of four chloromethyl(methylidyne)azanium molecules, two C4N2Cl clusters, and two HoCl4 clusters. In each C4N2Cl cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one N(1) atom. In the second C site, C(2) is bonded in a water-like geometry to one N(1) and one Cl(4) atom. N(1) is bonded in a linear geometry to one C(1) and one C(2) atom. Cl(4) is bonded in a bent 150 degrees geometry to two equivalent C(2) atoms. In each HoCl4 cluster, Ho(1) is bonded in a 4-coordinate geometry to two equivalent Cl(1) and two equivalent Cl(3) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one Ho(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Ho(1) atom. is represented by the CIF file [CIF]
data_HoC8N4Cl7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.589
_cell_length_b   9.037
_cell_length_c   14.469
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1123.077
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.305  0.500  0.500  1.0
  Ho  Ho1  1  0.695  0.000  0.000  1.0
  C  C2  1  0.123  0.757  0.671  1.0
  C  C3  1  0.123  0.243  0.329  1.0
  C  C4  1  0.877  0.743  0.171  1.0
  C  C5  1  0.877  0.257  0.829  1.0
  C  C6  1  0.955  0.792  0.531  1.0
  C  C7  1  0.955  0.208  0.469  1.0
  C  C8  1  0.045  0.708  0.031  1.0
  C  C9  1  0.045  0.292  0.969  1.0
  C  C10  1  0.386  0.681  0.851  1.0
  C  C11  1  0.386  0.319  0.149  1.0
  C  C12  1  0.614  0.819  0.351  1.0
  C  C13  1  0.614  0.181  0.649  1.0
  C  C14  1  0.651  0.566  0.831  1.0
  C  C15  1  0.651  0.434  0.169  1.0
  C  C16  1  0.349  0.934  0.331  1.0
  C  C17  1  0.349  0.066  0.669  1.0
  N  N18  1  0.053  0.784  0.599  1.0
  N  N19  1  0.053  0.216  0.401  1.0
  N  N20  1  0.947  0.716  0.099  1.0
  N  N21  1  0.947  0.284  0.901  1.0
  N  N22  1  0.533  0.635  0.845  1.0
  N  N23  1  0.533  0.365  0.155  1.0
  N  N24  1  0.467  0.865  0.345  1.0
  N  N25  1  0.467  0.135  0.655  1.0
  Cl  Cl26  1  0.410  0.700  0.605  1.0
  Cl  Cl27  1  0.410  0.300  0.395  1.0
  Cl  Cl28  1  0.590  0.800  0.105  1.0
  Cl  Cl29  1  0.590  0.200  0.895  1.0
  Cl  Cl30  1  0.623  0.637  0.385  1.0
  Cl  Cl31  1  0.623  0.363  0.615  1.0
  Cl  Cl32  1  0.377  0.863  0.885  1.0
  Cl  Cl33  1  0.377  0.137  0.115  1.0
  Cl  Cl34  1  0.111  0.649  0.407  1.0
  Cl  Cl35  1  0.111  0.351  0.593  1.0
  Cl  Cl36  1  0.889  0.851  0.907  1.0
  Cl  Cl37  1  0.889  0.149  0.093  1.0
  Cl  Cl38  1  0.914  0.000  0.500  1.0
  Cl  Cl39  1  0.086  0.500  0.000  1.0
[/CIF]
.