The material described by SbF6PCl4 is beta-prime cadmium gold structured and crystallizes in the tetragonal P4/n space group. The structure is zero-dimensional and consists of two [pcl4]+1 molecules and two SbF6 clusters. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(2), one F(3), and four equivalent F(1) atoms. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_SbP(Cl2F3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.716
_cell_length_b   8.716
_cell_length_c   6.943
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   527.494
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.500  0.147  1.0
  Sb  Sb1  1  0.500  0.000  0.853  1.0
  P  P2  1  0.500  0.500  0.500  1.0
  P  P3  1  0.000  0.000  0.500  1.0
  Cl  Cl4  1  0.047  0.177  0.662  1.0
  Cl  Cl5  1  0.453  0.323  0.338  1.0
  Cl  Cl6  1  0.323  0.547  0.662  1.0
  Cl  Cl7  1  0.823  0.047  0.338  1.0
  Cl  Cl8  1  0.547  0.677  0.338  1.0
  Cl  Cl9  1  0.177  0.953  0.338  1.0
  Cl  Cl10  1  0.677  0.453  0.662  1.0
  Cl  Cl11  1  0.953  0.823  0.662  1.0
  F  F12  1  0.291  0.930  0.854  1.0
  F  F13  1  0.791  0.430  0.146  1.0
  F  F14  1  0.209  0.570  0.146  1.0
  F  F15  1  0.930  0.709  0.146  1.0
  F  F16  1  0.570  0.791  0.854  1.0
  F  F17  1  0.709  0.070  0.854  1.0
  F  F18  1  0.430  0.209  0.854  1.0
  F  F19  1  0.000  0.500  0.869  1.0
  F  F20  1  0.070  0.291  0.146  1.0
  F  F21  1  0.500  0.000  0.577  1.0
  F  F22  1  0.000  0.500  0.423  1.0
  F  F23  1  0.500  0.000  0.131  1.0
[/CIF]
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The material described by SbF6PCl4 is beta-prime cadmium gold structured and crystallizes in the tetragonal P4/n space group. The structure is zero-dimensional and consists of two [pcl4]+1 molecules and two SbF6 clusters. In each SbF6 cluster, Sb(1) is bonded in an octahedral geometry to one F(2), one F(3), and four equivalent F(1) atoms. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the second F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. is represented by the CIF card [CIF]
data_SbP(Cl2F3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.716
_cell_length_b   8.716
_cell_length_c   6.943
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   527.494
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.000  0.500  0.147  1.0
  Sb  Sb1  1  0.500  0.000  0.853  1.0
  P  P2  1  0.500  0.500  0.500  1.0
  P  P3  1  0.000  0.000  0.500  1.0
  Cl  Cl4  1  0.047  0.177  0.662  1.0
  Cl  Cl5  1  0.453  0.323  0.338  1.0
  Cl  Cl6  1  0.323  0.547  0.662  1.0
  Cl  Cl7  1  0.823  0.047  0.338  1.0
  Cl  Cl8  1  0.547  0.677  0.338  1.0
  Cl  Cl9  1  0.177  0.953  0.338  1.0
  Cl  Cl10  1  0.677  0.453  0.662  1.0
  Cl  Cl11  1  0.953  0.823  0.662  1.0
  F  F12  1  0.291  0.930  0.854  1.0
  F  F13  1  0.791  0.430  0.146  1.0
  F  F14  1  0.209  0.570  0.146  1.0
  F  F15  1  0.930  0.709  0.146  1.0
  F  F16  1  0.570  0.791  0.854  1.0
  F  F17  1  0.709  0.070  0.854  1.0
  F  F18  1  0.430  0.209  0.854  1.0
  F  F19  1  0.000  0.500  0.869  1.0
  F  F20  1  0.070  0.291  0.146  1.0
  F  F21  1  0.500  0.000  0.577  1.0
  F  F22  1  0.000  0.500  0.423  1.0
  F  F23  1  0.500  0.000  0.131  1.0
[/CIF]
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