The material described by NaClO4 crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), and four equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Na(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Na(1) and one Cl(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. is represented by the CIF card [CIF]
data_NaClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.418
_cell_length_b   6.916
_cell_length_c   7.726
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   289.560
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.750  0.180  0.811  1.0
  Na  Na1  1  0.750  0.320  0.311  1.0
  Na  Na2  1  0.250  0.820  0.189  1.0
  Na  Na3  1  0.250  0.680  0.689  1.0
  Cl  Cl4  1  0.750  0.822  0.443  1.0
  Cl  Cl5  1  0.750  0.678  0.943  1.0
  Cl  Cl6  1  0.250  0.178  0.557  1.0
  Cl  Cl7  1  0.250  0.322  0.057  1.0
  O  O8  1  0.750  0.571  0.102  1.0
  O  O9  1  0.033  0.201  0.064  1.0
  O  O10  1  0.533  0.799  0.936  1.0
  O  O11  1  0.250  0.429  0.898  1.0
  O  O12  1  0.467  0.201  0.064  1.0
  O  O13  1  0.033  0.299  0.564  1.0
  O  O14  1  0.750  0.549  0.797  1.0
  O  O15  1  0.250  0.049  0.703  1.0
  O  O16  1  0.967  0.701  0.436  1.0
  O  O17  1  0.250  0.071  0.398  1.0
  O  O18  1  0.750  0.929  0.602  1.0
  O  O19  1  0.467  0.299  0.564  1.0
  O  O20  1  0.750  0.951  0.297  1.0
  O  O21  1  0.250  0.451  0.203  1.0
  O  O22  1  0.967  0.799  0.936  1.0
  O  O23  1  0.533  0.701  0.436  1.0
[/CIF]
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The material described by NaClO4 crystallizes in the orthorhombic Pnma space group. Na(1) is bonded in a 6-coordinate geometry to one O(1), one O(3), and four equivalent O(2) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Na(1) and one Cl(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Na(1) and one Cl(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one Cl(1) atom. Cl(1) is bonded in a tetrahedral geometry to one O(1), one O(3), and two equivalent O(2) atoms. is represented by the CIF card [CIF]
data_NaClO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.418
_cell_length_b   6.916
_cell_length_c   7.726
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   289.560
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.750  0.180  0.811  1.0
  Na  Na1  1  0.750  0.320  0.311  1.0
  Na  Na2  1  0.250  0.820  0.189  1.0
  Na  Na3  1  0.250  0.680  0.689  1.0
  Cl  Cl4  1  0.750  0.822  0.443  1.0
  Cl  Cl5  1  0.750  0.678  0.943  1.0
  Cl  Cl6  1  0.250  0.178  0.557  1.0
  Cl  Cl7  1  0.250  0.322  0.057  1.0
  O  O8  1  0.750  0.571  0.102  1.0
  O  O9  1  0.033  0.201  0.064  1.0
  O  O10  1  0.533  0.799  0.936  1.0
  O  O11  1  0.250  0.429  0.898  1.0
  O  O12  1  0.467  0.201  0.064  1.0
  O  O13  1  0.033  0.299  0.564  1.0
  O  O14  1  0.750  0.549  0.797  1.0
  O  O15  1  0.250  0.049  0.703  1.0
  O  O16  1  0.967  0.701  0.436  1.0
  O  O17  1  0.250  0.071  0.398  1.0
  O  O18  1  0.750  0.929  0.602  1.0
  O  O19  1  0.467  0.299  0.564  1.0
  O  O20  1  0.750  0.951  0.297  1.0
  O  O21  1  0.250  0.451  0.203  1.0
  O  O22  1  0.967  0.799  0.936  1.0
  O  O23  1  0.533  0.701  0.436  1.0
[/CIF]
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