The structure described by Li8Sb2S crystallizes in the monoclinic C2/c space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 3-coordinate geometry to two equivalent Sb(1) and one S(1) atom. In the second Li site, Li(2) is bonded in a 3-coordinate geometry to three equivalent Sb(1) and one S(1) atom. In the third Li site, Li(3) is bonded in a 1-coordinate geometry to two equivalent Sb(1) and one S(1) atom. In the fourth Li site, Li(4) is bonded in a 3-coordinate geometry to three equivalent Sb(1) atoms. Sb(1) is bonded in a 10-coordinate geometry to two equivalent Li(1), two equivalent Li(3), three equivalent Li(2), and three equivalent Li(4) atoms. S(1) is bonded in a 6-coordinate geometry to two equivalent Li(1), two equivalent Li(2), and two equivalent Li(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li8Sb2S
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.922
_cell_length_b   7.922
_cell_length_c   9.600
_cell_angle_alpha   61.064
_cell_angle_beta   61.064
_cell_angle_gamma   61.578
_symmetry_Int_Tables_number   1
_cell_volume   437.802
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.127  0.611  0.702  1.0
  Li  Li1  1  0.423  0.230  0.873  1.0
  Li  Li2  1  0.770  0.577  0.627  1.0
  Li  Li3  1  0.389  0.873  0.798  1.0
  Li  Li4  1  0.510  0.230  0.548  1.0
  Li  Li5  1  0.230  0.510  0.048  1.0
  Li  Li6  1  0.929  0.936  0.419  1.0
  Li  Li7  1  0.936  0.929  0.919  1.0
  Li  Li8  1  0.064  0.071  0.081  1.0
  Li  Li9  1  0.071  0.064  0.581  1.0
  Li  Li10  1  0.770  0.490  0.952  1.0
  Li  Li11  1  0.490  0.770  0.452  1.0
  Li  Li12  1  0.611  0.127  0.202  1.0
  Li  Li13  1  0.230  0.423  0.373  1.0
  Li  Li14  1  0.577  0.770  0.127  1.0
  Li  Li15  1  0.873  0.389  0.298  1.0
  Sb  Sb16  1  0.744  0.902  0.756  1.0
  Sb  Sb17  1  0.098  0.256  0.744  1.0
  Sb  Sb18  1  0.902  0.744  0.256  1.0
  Sb  Sb19  1  0.256  0.098  0.244  1.0
  S  S20  1  0.599  0.401  0.250  1.0
  S  S21  1  0.401  0.599  0.750  1.0
[/CIF]
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The structure described by Li8Sb2S crystallizes in the monoclinic C2/c space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded in a 3-coordinate geometry to two equivalent Sb(1) and one S(1) atom. In the second Li site, Li(2) is bonded in a 3-coordinate geometry to three equivalent Sb(1) and one S(1) atom. In the third Li site, Li(3) is bonded in a 1-coordinate geometry to two equivalent Sb(1) and one S(1) atom. In the fourth Li site, Li(4) is bonded in a 3-coordinate geometry to three equivalent Sb(1) atoms. Sb(1) is bonded in a 10-coordinate geometry to two equivalent Li(1), two equivalent Li(3), three equivalent Li(2), and three equivalent Li(4) atoms. S(1) is bonded in a 6-coordinate geometry to two equivalent Li(1), two equivalent Li(2), and two equivalent Li(3) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Li8Sb2S
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.922
_cell_length_b   7.922
_cell_length_c   9.600
_cell_angle_alpha   61.064
_cell_angle_beta   61.064
_cell_angle_gamma   61.578
_symmetry_Int_Tables_number   1
_cell_volume   437.802
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.127  0.611  0.702  1.0
  Li  Li1  1  0.423  0.230  0.873  1.0
  Li  Li2  1  0.770  0.577  0.627  1.0
  Li  Li3  1  0.389  0.873  0.798  1.0
  Li  Li4  1  0.510  0.230  0.548  1.0
  Li  Li5  1  0.230  0.510  0.048  1.0
  Li  Li6  1  0.929  0.936  0.419  1.0
  Li  Li7  1  0.936  0.929  0.919  1.0
  Li  Li8  1  0.064  0.071  0.081  1.0
  Li  Li9  1  0.071  0.064  0.581  1.0
  Li  Li10  1  0.770  0.490  0.952  1.0
  Li  Li11  1  0.490  0.770  0.452  1.0
  Li  Li12  1  0.611  0.127  0.202  1.0
  Li  Li13  1  0.230  0.423  0.373  1.0
  Li  Li14  1  0.577  0.770  0.127  1.0
  Li  Li15  1  0.873  0.389  0.298  1.0
  Sb  Sb16  1  0.744  0.902  0.756  1.0
  Sb  Sb17  1  0.098  0.256  0.744  1.0
  Sb  Sb18  1  0.902  0.744  0.256  1.0
  Sb  Sb19  1  0.256  0.098  0.244  1.0
  S  S20  1  0.599  0.401  0.250  1.0
  S  S21  1  0.401  0.599  0.750  1.0
[/CIF]
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