The compound described by (NH4)2HTeSO5F3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four ammonium molecules and two HTeSO5F3 clusters. In one of the HTeSO5F3 clusters, H(8) is bonded in a distorted linear geometry to one O(3) and one O(9) atom. Te(1) is bonded in a 4-coordinate geometry to one O(9), one F(1), one F(4), and one F(6) atom. S(2) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(5), and one O(6) atom. There are five inequivalent O sites. In the first O site, O(9) is bonded in a distorted bent 120 degrees geometry to one H(8) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one S(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one H(8) and one S(2) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one S(2) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one Te(1) atom. In one of the HTeSO5F3 clusters, H(11) is bonded in a single-bond geometry to one O(10) atom. Te(2) is bonded to one O(10), one O(4), one F(2), one F(3), and one F(5) atom to form distorted TeO2F3 square pyramids that share  a cornercorner with one S(1)O4 tetrahedra. S(1) is bonded to one O(1), one O(4), one O(7), and one O(8) atom to form SO4 tetrahedra that share  a cornercorner with one Te(2)O2F3 square pyramid. There are five inequivalent O sites. In the first O site, O(7) is bonded in a distorted single-bond geometry to one S(1) atom. In the second O site, O(8) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(10) is bonded in a distorted bent 120 degrees geometry to one H(11) and one Te(2) atom. In the fourth O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one Te(2) and one S(1) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Te(2) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Te(2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Te(2) atom. is represented by the CIF card [CIF]
data_TeH9SN2O5F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.123
_cell_length_b   7.608
_cell_length_c   8.821
_cell_angle_alpha   101.545
_cell_angle_beta   86.991
_cell_angle_gamma   107.526
_symmetry_Int_Tables_number   1
_cell_volume   446.611
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.996  0.000  0.012  1.0
  Te  Te1  1  0.363  0.392  0.510  1.0
  H  H2  1  0.852  0.483  0.155  1.0
  H  H3  1  0.970  0.624  0.315  1.0
  H  H4  1  0.404  0.778  0.198  1.0
  H  H5  1  0.521  0.926  0.357  1.0
  H  H6  1  0.788  0.436  0.833  1.0
  H  H7  1  0.577  0.931  0.852  1.0
  H  H8  1  0.283  0.910  0.319  1.0
  H  H9  1  0.706  0.709  0.009  1.0
  H  H10  1  0.096  0.510  0.183  1.0
  H  H11  1  0.927  0.350  0.686  1.0
  H  H12  1  0.341  0.389  0.794  1.0
  H  H13  1  0.407  0.790  0.720  1.0
  H  H14  1  0.812  0.508  0.661  1.0
  H  H15  1  0.924  0.384  0.288  1.0
  H  H16  1  0.468  0.016  0.211  1.0
  H  H17  1  0.569  0.981  0.674  1.0
  H  H18  1  0.392  0.008  0.803  1.0
  H  H19  1  0.005  0.573  0.786  1.0
  S  S20  1  0.922  0.045  0.424  1.0
  S  S21  1  0.459  0.378  0.070  1.0
  N  N22  1  0.960  0.501  0.236  1.0
  N  N23  1  0.419  0.907  0.271  1.0
  N  N24  1  0.485  0.928  0.763  1.0
  N  N25  1  0.883  0.466  0.741  1.0
  O  O26  1  0.728  0.962  0.487  1.0
  O  O27  1  0.345  0.251  0.929  1.0
  O  O28  1  0.660  0.484  0.017  1.0
  O  O29  1  0.043  0.199  0.552  1.0
  O  O30  1  0.483  0.262  0.180  1.0
  O  O31  1  0.354  0.515  0.141  1.0
  O  O32  1  0.901  0.137  0.292  1.0
  O  O33  1  0.027  0.904  0.368  1.0
  O  O34  1  0.726  0.844  0.997  1.0
  O  O35  1  0.339  0.483  0.728  1.0
  F  F36  1  0.080  0.766  0.013  1.0
  F  F37  1  0.473  0.204  0.572  1.0
  F  F38  1  0.279  0.623  0.505  1.0
  F  F39  1  0.878  0.181  0.950  1.0
  F  F40  1  0.642  0.549  0.519  1.0
  F  F41  1  0.038  0.926  0.792  1.0
[/CIF]
.
The compound described by (NH4)2HTeSO5F3 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four ammonium molecules and two HTeSO5F3 clusters. In one of the HTeSO5F3 clusters, H(8) is bonded in a distorted linear geometry to one O(3) and one O(9) atom. Te(1) is bonded in a 4-coordinate geometry to one O(9), one F(1), one F(4), and one F(6) atom. S(2) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(5), and one O(6) atom. There are five inequivalent O sites. In the first O site, O(9) is bonded in a distorted bent 120 degrees geometry to one H(8) and one Te(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one S(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one H(8) and one S(2) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one S(2) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Te(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one Te(1) atom. In the third F site, F(6) is bonded in a single-bond geometry to one Te(1) atom. In one of the HTeSO5F3 clusters, H(11) is bonded in a single-bond geometry to one O(10) atom. Te(2) is bonded to one O(10), one O(4), one F(2), one F(3), and one F(5) atom to form distorted TeO2F3 square pyramids that share  a cornercorner with one S(1)O4 tetrahedra. S(1) is bonded to one O(1), one O(4), one O(7), and one O(8) atom to form SO4 tetrahedra that share  a cornercorner with one Te(2)O2F3 square pyramid. There are five inequivalent O sites. In the first O site, O(7) is bonded in a distorted single-bond geometry to one S(1) atom. In the second O site, O(8) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(10) is bonded in a distorted bent 120 degrees geometry to one H(11) and one Te(2) atom. In the fourth O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the fifth O site, O(4) is bonded in a distorted single-bond geometry to one Te(2) and one S(1) atom. There are three inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one Te(2) atom. In the second F site, F(3) is bonded in a single-bond geometry to one Te(2) atom. In the third F site, F(5) is bonded in a single-bond geometry to one Te(2) atom. is represented by the CIF card [CIF]
data_TeH9SN2O5F3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.123
_cell_length_b   7.608
_cell_length_c   8.821
_cell_angle_alpha   101.545
_cell_angle_beta   86.991
_cell_angle_gamma   107.526
_symmetry_Int_Tables_number   1
_cell_volume   446.611
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.996  0.000  0.012  1.0
  Te  Te1  1  0.363  0.392  0.510  1.0
  H  H2  1  0.852  0.483  0.155  1.0
  H  H3  1  0.970  0.624  0.315  1.0
  H  H4  1  0.404  0.778  0.198  1.0
  H  H5  1  0.521  0.926  0.357  1.0
  H  H6  1  0.788  0.436  0.833  1.0
  H  H7  1  0.577  0.931  0.852  1.0
  H  H8  1  0.283  0.910  0.319  1.0
  H  H9  1  0.706  0.709  0.009  1.0
  H  H10  1  0.096  0.510  0.183  1.0
  H  H11  1  0.927  0.350  0.686  1.0
  H  H12  1  0.341  0.389  0.794  1.0
  H  H13  1  0.407  0.790  0.720  1.0
  H  H14  1  0.812  0.508  0.661  1.0
  H  H15  1  0.924  0.384  0.288  1.0
  H  H16  1  0.468  0.016  0.211  1.0
  H  H17  1  0.569  0.981  0.674  1.0
  H  H18  1  0.392  0.008  0.803  1.0
  H  H19  1  0.005  0.573  0.786  1.0
  S  S20  1  0.922  0.045  0.424  1.0
  S  S21  1  0.459  0.378  0.070  1.0
  N  N22  1  0.960  0.501  0.236  1.0
  N  N23  1  0.419  0.907  0.271  1.0
  N  N24  1  0.485  0.928  0.763  1.0
  N  N25  1  0.883  0.466  0.741  1.0
  O  O26  1  0.728  0.962  0.487  1.0
  O  O27  1  0.345  0.251  0.929  1.0
  O  O28  1  0.660  0.484  0.017  1.0
  O  O29  1  0.043  0.199  0.552  1.0
  O  O30  1  0.483  0.262  0.180  1.0
  O  O31  1  0.354  0.515  0.141  1.0
  O  O32  1  0.901  0.137  0.292  1.0
  O  O33  1  0.027  0.904  0.368  1.0
  O  O34  1  0.726  0.844  0.997  1.0
  O  O35  1  0.339  0.483  0.728  1.0
  F  F36  1  0.080  0.766  0.013  1.0
  F  F37  1  0.473  0.204  0.572  1.0
  F  F38  1  0.279  0.623  0.505  1.0
  F  F39  1  0.878  0.181  0.950  1.0
  F  F40  1  0.642  0.549  0.519  1.0
  F  F41  1  0.038  0.926  0.792  1.0
[/CIF]
.