The compound described by WBr5 is alpha oxygen structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two tungsten pentabromide molecules. W(1) is bonded in a 5-coordinate geometry to one Br(1), one Br(2), one Br(3), one Br(4), and one Br(5) atom. There are five inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one W(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one W(1) atom. In the third Br site, Br(3) is bonded in a distorted single-bond geometry to one W(1) atom. In the fourth Br site, Br(4) is bonded in a distorted single-bond geometry to one W(1) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF file [CIF]
data_WBr5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.894
_cell_length_b   7.440
_cell_length_c   9.984
_cell_angle_alpha   109.822
_cell_angle_beta   90.847
_cell_angle_gamma   116.198
_symmetry_Int_Tables_number   1
_cell_volume   423.975
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.898  0.503  0.786  1.0
  W  W1  1  0.102  0.497  0.214  1.0
  Br  Br2  1  0.231  0.719  0.958  1.0
  Br  Br3  1  0.769  0.281  0.042  1.0
  Br  Br4  1  0.573  0.271  0.666  1.0
  Br  Br5  1  0.427  0.729  0.334  1.0
  Br  Br6  1  0.063  0.739  0.574  1.0
  Br  Br7  1  0.937  0.261  0.426  1.0
  Br  Br8  1  0.113  0.281  0.851  1.0
  Br  Br9  1  0.887  0.719  0.149  1.0
  Br  Br10  1  0.706  0.729  0.758  1.0
  Br  Br11  1  0.294  0.271  0.242  1.0
[/CIF]
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The compound described by WBr5 is alpha oxygen structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two tungsten pentabromide molecules. W(1) is bonded in a 5-coordinate geometry to one Br(1), one Br(2), one Br(3), one Br(4), and one Br(5) atom. There are five inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one W(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one W(1) atom. In the third Br site, Br(3) is bonded in a distorted single-bond geometry to one W(1) atom. In the fourth Br site, Br(4) is bonded in a distorted single-bond geometry to one W(1) atom. In the fifth Br site, Br(5) is bonded in a single-bond geometry to one W(1) atom. is represented by the CIF file [CIF]
data_WBr5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.894
_cell_length_b   7.440
_cell_length_c   9.984
_cell_angle_alpha   109.822
_cell_angle_beta   90.847
_cell_angle_gamma   116.198
_symmetry_Int_Tables_number   1
_cell_volume   423.975
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  W  W0  1  0.898  0.503  0.786  1.0
  W  W1  1  0.102  0.497  0.214  1.0
  Br  Br2  1  0.231  0.719  0.958  1.0
  Br  Br3  1  0.769  0.281  0.042  1.0
  Br  Br4  1  0.573  0.271  0.666  1.0
  Br  Br5  1  0.427  0.729  0.334  1.0
  Br  Br6  1  0.063  0.739  0.574  1.0
  Br  Br7  1  0.937  0.261  0.426  1.0
  Br  Br8  1  0.113  0.281  0.851  1.0
  Br  Br9  1  0.887  0.719  0.149  1.0
  Br  Br10  1  0.706  0.729  0.758  1.0
  Br  Br11  1  0.294  0.271  0.242  1.0
[/CIF]
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