The structure described by Rb2Bi(PO4)(WO4) crystallizes in the orthorhombic Ibca space group. Rb(1) is bonded in a 8-coordinate geometry to one O(3), two equivalent O(1), two equivalent O(2), and three equivalent O(4) atoms. W(1) is bonded in a tetrahedral geometry to two equivalent O(2) and two equivalent O(4) atoms. Bi(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(3) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(4) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one W(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one Bi(1), and one P(1) atom. In the third O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one W(1), and one Bi(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Bi(1), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2BiPWO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.719
_cell_length_b   12.719
_cell_length_c   12.719
_cell_angle_alpha   147.194
_cell_angle_beta   120.191
_cell_angle_gamma   69.916
_symmetry_Int_Tables_number   1
_cell_volume   949.673
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.239  0.624  0.548  1.0
  Rb  Rb1  1  0.261  0.809  0.384  1.0
  Rb  Rb2  1  0.924  0.876  0.116  1.0
  Rb  Rb3  1  0.576  0.691  0.952  1.0
  Rb  Rb4  1  0.761  0.376  0.452  1.0
  Rb  Rb5  1  0.739  0.191  0.616  1.0
  Rb  Rb6  1  0.076  0.124  0.884  1.0
  Rb  Rb7  1  0.424  0.309  0.048  1.0
  Bi  Bi8  1  0.166  0.750  0.916  1.0
  Bi  Bi9  1  0.334  0.250  0.584  1.0
  Bi  Bi10  1  0.834  0.250  0.084  1.0
  Bi  Bi11  1  0.666  0.750  0.416  1.0
  P  P12  1  0.927  0.750  0.677  1.0
  P  P13  1  0.573  0.250  0.823  1.0
  P  P14  1  0.073  0.250  0.323  1.0
  P  P15  1  0.427  0.750  0.177  1.0
  W  W16  1  0.087  0.337  0.750  1.0
  W  W17  1  0.413  0.163  0.250  1.0
  W  W18  1  0.913  0.663  0.250  1.0
  W  W19  1  0.587  0.837  0.750  1.0
  O  O20  1  0.942  0.716  0.775  1.0
  O  O21  1  0.558  0.333  0.774  1.0
  O  O22  1  0.060  0.784  0.726  1.0
  O  O23  1  0.440  0.167  0.725  1.0
  O  O24  1  0.058  0.284  0.225  1.0
  O  O25  1  0.442  0.667  0.226  1.0
  O  O26  1  0.940  0.216  0.274  1.0
  O  O27  1  0.560  0.833  0.275  1.0
  O  O28  1  0.101  0.589  0.917  1.0
  O  O29  1  0.399  0.316  0.488  1.0
  O  O30  1  0.328  0.911  0.012  1.0
  O  O31  1  0.172  0.184  0.583  1.0
  O  O32  1  0.899  0.411  0.083  1.0
  O  O33  1  0.601  0.684  0.512  1.0
  O  O34  1  0.672  0.089  0.988  1.0
  O  O35  1  0.828  0.816  0.417  1.0
  O  O36  1  0.360  0.592  0.932  1.0
  O  O37  1  0.140  0.072  0.232  1.0
  O  O38  1  0.340  0.908  0.268  1.0
  O  O39  1  0.160  0.428  0.568  1.0
  O  O40  1  0.640  0.408  0.068  1.0
  O  O41  1  0.860  0.928  0.768  1.0
  O  O42  1  0.660  0.092  0.732  1.0
  O  O43  1  0.840  0.572  0.432  1.0
  O  O44  1  0.927  0.223  0.574  1.0
  O  O45  1  0.573  0.148  0.296  1.0
  O  O46  1  0.351  0.277  0.204  1.0
  O  O47  1  0.149  0.352  0.926  1.0
  O  O48  1  0.073  0.777  0.426  1.0
  O  O49  1  0.427  0.852  0.704  1.0
  O  O50  1  0.649  0.723  0.796  1.0
  O  O51  1  0.851  0.648  0.074  1.0
[/CIF]
.
The structure described by Rb2Bi(PO4)(WO4) crystallizes in the orthorhombic Ibca space group. Rb(1) is bonded in a 8-coordinate geometry to one O(3), two equivalent O(1), two equivalent O(2), and three equivalent O(4) atoms. W(1) is bonded in a tetrahedral geometry to two equivalent O(2) and two equivalent O(4) atoms. Bi(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), and four equivalent O(3) atoms. P(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(4) is bonded in a 4-coordinate geometry to three equivalent Rb(1) and one W(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1), one Bi(1), and one P(1) atom. In the third O site, O(2) is bonded in a 4-coordinate geometry to two equivalent Rb(1), one W(1), and one Bi(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Bi(1), and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb2BiPWO8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.719
_cell_length_b   12.719
_cell_length_c   12.719
_cell_angle_alpha   147.194
_cell_angle_beta   120.191
_cell_angle_gamma   69.916
_symmetry_Int_Tables_number   1
_cell_volume   949.673
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.239  0.624  0.548  1.0
  Rb  Rb1  1  0.261  0.809  0.384  1.0
  Rb  Rb2  1  0.924  0.876  0.116  1.0
  Rb  Rb3  1  0.576  0.691  0.952  1.0
  Rb  Rb4  1  0.761  0.376  0.452  1.0
  Rb  Rb5  1  0.739  0.191  0.616  1.0
  Rb  Rb6  1  0.076  0.124  0.884  1.0
  Rb  Rb7  1  0.424  0.309  0.048  1.0
  Bi  Bi8  1  0.166  0.750  0.916  1.0
  Bi  Bi9  1  0.334  0.250  0.584  1.0
  Bi  Bi10  1  0.834  0.250  0.084  1.0
  Bi  Bi11  1  0.666  0.750  0.416  1.0
  P  P12  1  0.927  0.750  0.677  1.0
  P  P13  1  0.573  0.250  0.823  1.0
  P  P14  1  0.073  0.250  0.323  1.0
  P  P15  1  0.427  0.750  0.177  1.0
  W  W16  1  0.087  0.337  0.750  1.0
  W  W17  1  0.413  0.163  0.250  1.0
  W  W18  1  0.913  0.663  0.250  1.0
  W  W19  1  0.587  0.837  0.750  1.0
  O  O20  1  0.942  0.716  0.775  1.0
  O  O21  1  0.558  0.333  0.774  1.0
  O  O22  1  0.060  0.784  0.726  1.0
  O  O23  1  0.440  0.167  0.725  1.0
  O  O24  1  0.058  0.284  0.225  1.0
  O  O25  1  0.442  0.667  0.226  1.0
  O  O26  1  0.940  0.216  0.274  1.0
  O  O27  1  0.560  0.833  0.275  1.0
  O  O28  1  0.101  0.589  0.917  1.0
  O  O29  1  0.399  0.316  0.488  1.0
  O  O30  1  0.328  0.911  0.012  1.0
  O  O31  1  0.172  0.184  0.583  1.0
  O  O32  1  0.899  0.411  0.083  1.0
  O  O33  1  0.601  0.684  0.512  1.0
  O  O34  1  0.672  0.089  0.988  1.0
  O  O35  1  0.828  0.816  0.417  1.0
  O  O36  1  0.360  0.592  0.932  1.0
  O  O37  1  0.140  0.072  0.232  1.0
  O  O38  1  0.340  0.908  0.268  1.0
  O  O39  1  0.160  0.428  0.568  1.0
  O  O40  1  0.640  0.408  0.068  1.0
  O  O41  1  0.860  0.928  0.768  1.0
  O  O42  1  0.660  0.092  0.732  1.0
  O  O43  1  0.840  0.572  0.432  1.0
  O  O44  1  0.927  0.223  0.574  1.0
  O  O45  1  0.573  0.148  0.296  1.0
  O  O46  1  0.351  0.277  0.204  1.0
  O  O47  1  0.149  0.352  0.926  1.0
  O  O48  1  0.073  0.777  0.426  1.0
  O  O49  1  0.427  0.852  0.704  1.0
  O  O50  1  0.649  0.723  0.796  1.0
  O  O51  1  0.851  0.648  0.074  1.0
[/CIF]
.