The material structure described by Na4Ga3Si3NO14 crystallizes in the triclinic P1 space group. There are eight inequivalent Na sites. In the first Na site, Na(1) is bonded to one N(2), one O(11), one O(28), one O(3), one O(5), and one O(8) atom to form distorted NaNO5 octahedra that share  a cornercorner with one Ga(2)O4 tetrahedra,  a cornercorner with one Ga(6)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra,  a cornercorner with one Si(6)O4 tetrahedra,  an edgeedge with one Ga(4)O4 tetrahedra, and  an edgeedge with one Si(2)O4 tetrahedra. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one N(2), one O(12), one O(13), one O(27), one O(4), and one O(6) atom. In the third Na site, Na(3) is bonded to one N(1), one O(1), one O(7), and one O(9) atom to form distorted NaNO3 tetrahedra that share  a cornercorner with one Ga(2)O4 tetrahedra,  a cornercorner with one Ga(3)O4 tetrahedra,  a cornercorner with one Ga(6)O4 tetrahedra,  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra, and  a cornercorner with one Si(4)O4 tetrahedra. In the fourth Na site, Na(4) is bonded in a 5-coordinate geometry to one O(10), one O(13), one O(2), one O(3), and one O(8) atom. In the fifth Na site, Na(5) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one O(16), one O(18), and one O(24) atom. In the sixth Na site, Na(6) is bonded in a 4-coordinate geometry to one O(17), one O(19), one O(25), and one O(27) atom. In the seventh Na site, Na(7) is bonded in a distorted trigonal non-coplanar geometry to one O(14), one O(21), and one O(23) atom. In the eighth Na site, Na(8) is bonded in a 4-coordinate geometry to one O(15), one O(20), one O(22), and one O(26) atom. There are six inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(2), one O(20), one O(25), one O(27), and one O(6) atom to form GaO5 trigonal bipyramids that share  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one Si(5)O4 tetrahedra, and  a cornercorner with one Si(6)O4 tetrahedra. In the second Ga site, Ga(2) is bonded to one O(10), one O(28), one O(4), and one O(9) atom to form GaO4 tetrahedra that share  a cornercorner with one Na(1)NO5 octahedra,  a cornercorner with one Na(3)NO3 tetrahedra,  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(3)O4 tetrahedra, and  a cornercorner with one Si(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 61°. In the third Ga site, Ga(3) is bonded to one O(12), one O(14), one O(19), and one O(7) atom to form GaO4 tetrahedra that share  a cornercorner with one Na(3)NO3 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one Si(3)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra, and  a cornercorner with one Si(5)O4 tetrahedra. In the fourth Ga site, Ga(4) is bonded to one O(11), one O(15), one O(26), and one O(8) atom to form GaO4 tetrahedra that share  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one Si(3)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra, and  an edgeedge with one Na(1)NO5 octahedra. In the fifth Ga site, Ga(5) is bonded to one O(16), one O(17), one O(22), and one O(23) atom to form GaO4 tetrahedra that share  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(3)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra, and  a cornercorner with one Si(6)O4 tetrahedra. In the sixth Ga site, Ga(6) is bonded to one O(1), one O(21), one O(24), and one O(5) atom to form GaO4 tetrahedra that share  a cornercorner with one Na(1)NO5 octahedra,  a cornercorner with one Na(3)NO3 tetrahedra,  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one Si(5)O4 tetrahedra, and  a cornercorner with one Si(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 65°. There are six inequivalent Si sites. In the first Si site, Si(1) is bonded to one O(1), one O(23), one O(25), and one O(4) atom to form SiO4 tetrahedra that share  a cornercorner with one Na(3)NO3 tetrahedra,  a cornercorner with one Ga(2)O4 tetrahedra,  a cornercorner with one Ga(5)O4 tetrahedra,  a cornercorner with one Ga(6)O4 tetrahedra, and  a cornercorner with one Ga(1)O5 trigonal bipyramid. In the second Si site, Si(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form SiO4 tetrahedra that share  a cornercorner with one Na(3)NO3 tetrahedra,  a cornercorner with one Ga(3)O4 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra,  a cornercorner with one Ga(6)O4 tetrahedra,  a cornercorner with one Ga(1)O5 trigonal bipyramid, and  an edgeedge with one Na(1)NO5 octahedra. In the third Si site, Si(3) is bonded to one O(10), one O(12), one O(15), and one O(17) atom to form SiO4 tetrahedra that share  a cornercorner with one Ga(2)O4 tetrahedra,  a cornercorner with one Ga(3)O4 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra, and  a cornercorner with one Ga(5)O4 tetrahedra. In the fourth Si site, Si(4) is bonded to one O(11), one O(14), one O(16), and one O(9) atom to form SiO4 tetrahedra that share  a cornercorner with one Na(1)NO5 octahedra,  a cornercorner with one Na(3)NO3 tetrahedra,  a cornercorner with one Ga(2)O4 tetrahedra,  a cornercorner with one Ga(3)O4 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra, and  a cornercorner with one Ga(5)O4 tetrahedra. The corner-sharing octahedral tilt angles are 57°. In the fifth Si site, Si(5) is bonded to one O(18), one O(19), one O(20), and one O(21) atom to form SiO4 tetrahedra that share  a cornercorner with one Ga(3)O4 tetrahedra,  a cornercorner with one Ga(6)O4 tetrahedra, and  a cornercorner with one Ga(1)O5 trigonal bipyramid. In the sixth Si site, Si(6) is bonded to one O(2), one O(22), one O(24), and one O(3) atom to form SiO4 tetrahedra that share  a cornercorner with one Na(1)NO5 octahedra,  a cornercorner with one Ga(5)O4 tetrahedra,  a cornercorner with one Ga(6)O4 tetrahedra, and  a cornercorner with one Ga(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 64°. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Na(3) and one Na(5) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one Na(2) atom. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Na(3), one Ga(6), and one Si(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(4), one Ga(1), and one Si(6) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Na(1), one Na(4), one Si(6), and one O(28) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Na(2), one Ga(2), and one Si(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Na(1), one Ga(6), and one Si(2) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Na(2), one Ga(1), one Si(2), and one O(13) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Na(3), one Ga(3), and one Si(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Na(1), one Na(4), one Ga(4), and one Si(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Na(3), one Ga(2), and one Si(4) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Na(4), one Ga(2), and one Si(3) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Na(1), one Ga(4), and one Si(4) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Na(2), one Ga(3), and one Si(3) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Na(2), one Na(4), and one O(6) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Na(7), one Ga(3), and one Si(4) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Na(8), one Ga(4), and one Si(3) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Na(5), one Ga(5), and one Si(4) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Na(6), one Ga(5), and one Si(3) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Na(5), one Si(5), and one O(26) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Na(6), one Ga(3), and one Si(5) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Na(8), one Ga(1), and one Si(5) atom. In the twenty-first O site, O(21) is bonded in a trigonal planar geometry to one Na(7), one Ga(6), and one Si(5) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Na(8), one Ga(5), and one Si(6) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Na(7), one Ga(5), and one Si(1) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Na(5), one Ga(6), and one Si(6) atom. In the twenty-fifth O site, O(25) is bonded in a 3-coordinate geometry to one Na(6), one Ga(1), and one Si(1) atom. In the twenty-sixth O site, O(26) is bonded in a 1-coordinate geometry to one Na(8), one Ga(4), and one O(18) atom. In the twenty-seventh O site, O(27) is bonded in a distorted T-shaped geometry to one Na(2), one Na(6), and one Ga(1) atom. In the twenty-eighth O site, O(28) is bonded in a 3-coordinate geometry to one Na(1), one Ga(2), and one O(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na4Ga3Si3NO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.227
_cell_length_b   9.263
_cell_length_c   9.406
_cell_angle_alpha   89.695
_cell_angle_beta   90.063
_cell_angle_gamma   89.404
_symmetry_Int_Tables_number   1
_cell_volume   803.907
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.195  0.181  0.193  1.0
  Na  Na1  1  0.185  0.802  0.802  1.0
  Na  Na2  1  0.328  0.312  0.682  1.0
  Na  Na3  1  0.293  0.692  0.325  1.0
  Na  Na4  1  0.684  0.318  0.300  1.0
  Na  Na5  1  0.703  0.696  0.705  1.0
  Na  Na6  1  0.809  0.186  0.820  1.0
  Na  Na7  1  0.797  0.804  0.217  1.0
  Ga  Ga8  1  0.986  0.753  0.542  1.0
  Ga  Ga9  1  0.253  0.488  0.969  1.0
  Ga  Ga10  1  0.495  0.989  0.738  1.0
  Ga  Ga11  1  0.476  0.985  0.209  1.0
  Ga  Ga12  1  0.761  0.493  0.000  1.0
  Ga  Ga13  1  0.998  0.249  0.509  1.0
  Si  Si14  1  0.003  0.481  0.745  1.0
  Si  Si15  1  0.261  0.010  0.480  1.0
  Si  Si16  1  0.491  0.732  0.980  1.0
  Si  Si17  1  0.511  0.245  0.988  1.0
  Si  Si18  1  0.770  0.001  0.526  1.0
  Si  Si19  1  0.983  0.509  0.282  1.0
  N  N20  1  0.588  0.409  0.530  1.0
  N  N21  1  0.174  0.064  0.912  1.0
  O  O22  1  0.076  0.342  0.662  1.0
  O  O23  1  0.040  0.646  0.371  1.0
  O  O24  1  0.146  0.460  0.211  1.0
  O  O25  1  0.142  0.559  0.821  1.0
  O  O26  1  0.146  0.138  0.435  1.0
  O  O27  1  0.174  0.863  0.546  1.0
  O  O28  1  0.365  0.072  0.608  1.0
  O  O29  1  0.318  0.954  0.324  1.0
  O  O30  1  0.387  0.350  0.916  1.0
  O  O31  1  0.352  0.642  0.045  1.0
  O  O32  1  0.443  0.164  0.130  1.0
  O  O33  1  0.435  0.832  0.846  1.0
  O  O34  1  0.304  0.764  0.565  1.0
  O  O35  1  0.563  0.132  0.864  1.0
  O  O36  1  0.549  0.834  0.109  1.0
  O  O37  1  0.653  0.331  0.051  1.0
  O  O38  1  0.632  0.633  0.931  1.0
  O  O39  1  0.679  0.091  0.396  1.0
  O  O40  1  0.656  0.931  0.638  1.0
  O  O41  1  0.870  0.883  0.442  1.0
  O  O42  1  0.857  0.138  0.593  1.0
  O  O43  1  0.858  0.560  0.163  1.0
  O  O44  1  0.879  0.424  0.858  1.0
  O  O45  1  0.924  0.364  0.362  1.0
  O  O46  1  0.915  0.581  0.628  1.0
  O  O47  1  0.632  0.957  0.325  1.0
  O  O48  1  0.947  0.827  0.730  1.0
  O  O49  1  0.117  0.380  0.074  1.0
[/CIF]
.
The material structure described by Na4Ga3Si3NO14 crystallizes in the triclinic P1 space group. There are eight inequivalent Na sites. In the first Na site, Na(1) is bonded to one N(2), one O(11), one O(28), one O(3), one O(5), and one O(8) atom to form distorted NaNO5 octahedra that share  a cornercorner with one Ga(2)O4 tetrahedra,  a cornercorner with one Ga(6)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra,  a cornercorner with one Si(6)O4 tetrahedra,  an edgeedge with one Ga(4)O4 tetrahedra, and  an edgeedge with one Si(2)O4 tetrahedra. In the second Na site, Na(2) is bonded in a 6-coordinate geometry to one N(2), one O(12), one O(13), one O(27), one O(4), and one O(6) atom. In the third Na site, Na(3) is bonded to one N(1), one O(1), one O(7), and one O(9) atom to form distorted NaNO3 tetrahedra that share  a cornercorner with one Ga(2)O4 tetrahedra,  a cornercorner with one Ga(3)O4 tetrahedra,  a cornercorner with one Ga(6)O4 tetrahedra,  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra, and  a cornercorner with one Si(4)O4 tetrahedra. In the fourth Na site, Na(4) is bonded in a 5-coordinate geometry to one O(10), one O(13), one O(2), one O(3), and one O(8) atom. In the fifth Na site, Na(5) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one O(16), one O(18), and one O(24) atom. In the sixth Na site, Na(6) is bonded in a 4-coordinate geometry to one O(17), one O(19), one O(25), and one O(27) atom. In the seventh Na site, Na(7) is bonded in a distorted trigonal non-coplanar geometry to one O(14), one O(21), and one O(23) atom. In the eighth Na site, Na(8) is bonded in a 4-coordinate geometry to one O(15), one O(20), one O(22), and one O(26) atom. There are six inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(2), one O(20), one O(25), one O(27), and one O(6) atom to form GaO5 trigonal bipyramids that share  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one Si(5)O4 tetrahedra, and  a cornercorner with one Si(6)O4 tetrahedra. In the second Ga site, Ga(2) is bonded to one O(10), one O(28), one O(4), and one O(9) atom to form GaO4 tetrahedra that share  a cornercorner with one Na(1)NO5 octahedra,  a cornercorner with one Na(3)NO3 tetrahedra,  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(3)O4 tetrahedra, and  a cornercorner with one Si(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 61°. In the third Ga site, Ga(3) is bonded to one O(12), one O(14), one O(19), and one O(7) atom to form GaO4 tetrahedra that share  a cornercorner with one Na(3)NO3 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one Si(3)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra, and  a cornercorner with one Si(5)O4 tetrahedra. In the fourth Ga site, Ga(4) is bonded to one O(11), one O(15), one O(26), and one O(8) atom to form GaO4 tetrahedra that share  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one Si(3)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra, and  an edgeedge with one Na(1)NO5 octahedra. In the fifth Ga site, Ga(5) is bonded to one O(16), one O(17), one O(22), and one O(23) atom to form GaO4 tetrahedra that share  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(3)O4 tetrahedra,  a cornercorner with one Si(4)O4 tetrahedra, and  a cornercorner with one Si(6)O4 tetrahedra. In the sixth Ga site, Ga(6) is bonded to one O(1), one O(21), one O(24), and one O(5) atom to form GaO4 tetrahedra that share  a cornercorner with one Na(1)NO5 octahedra,  a cornercorner with one Na(3)NO3 tetrahedra,  a cornercorner with one Si(1)O4 tetrahedra,  a cornercorner with one Si(2)O4 tetrahedra,  a cornercorner with one Si(5)O4 tetrahedra, and  a cornercorner with one Si(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 65°. There are six inequivalent Si sites. In the first Si site, Si(1) is bonded to one O(1), one O(23), one O(25), and one O(4) atom to form SiO4 tetrahedra that share  a cornercorner with one Na(3)NO3 tetrahedra,  a cornercorner with one Ga(2)O4 tetrahedra,  a cornercorner with one Ga(5)O4 tetrahedra,  a cornercorner with one Ga(6)O4 tetrahedra, and  a cornercorner with one Ga(1)O5 trigonal bipyramid. In the second Si site, Si(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form SiO4 tetrahedra that share  a cornercorner with one Na(3)NO3 tetrahedra,  a cornercorner with one Ga(3)O4 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra,  a cornercorner with one Ga(6)O4 tetrahedra,  a cornercorner with one Ga(1)O5 trigonal bipyramid, and  an edgeedge with one Na(1)NO5 octahedra. In the third Si site, Si(3) is bonded to one O(10), one O(12), one O(15), and one O(17) atom to form SiO4 tetrahedra that share  a cornercorner with one Ga(2)O4 tetrahedra,  a cornercorner with one Ga(3)O4 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra, and  a cornercorner with one Ga(5)O4 tetrahedra. In the fourth Si site, Si(4) is bonded to one O(11), one O(14), one O(16), and one O(9) atom to form SiO4 tetrahedra that share  a cornercorner with one Na(1)NO5 octahedra,  a cornercorner with one Na(3)NO3 tetrahedra,  a cornercorner with one Ga(2)O4 tetrahedra,  a cornercorner with one Ga(3)O4 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra, and  a cornercorner with one Ga(5)O4 tetrahedra. The corner-sharing octahedral tilt angles are 57°. In the fifth Si site, Si(5) is bonded to one O(18), one O(19), one O(20), and one O(21) atom to form SiO4 tetrahedra that share  a cornercorner with one Ga(3)O4 tetrahedra,  a cornercorner with one Ga(6)O4 tetrahedra, and  a cornercorner with one Ga(1)O5 trigonal bipyramid. In the sixth Si site, Si(6) is bonded to one O(2), one O(22), one O(24), and one O(3) atom to form SiO4 tetrahedra that share  a cornercorner with one Na(1)NO5 octahedra,  a cornercorner with one Ga(5)O4 tetrahedra,  a cornercorner with one Ga(6)O4 tetrahedra, and  a cornercorner with one Ga(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 64°. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Na(3) and one Na(5) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one Na(2) atom. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Na(3), one Ga(6), and one Si(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(4), one Ga(1), and one Si(6) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Na(1), one Na(4), one Si(6), and one O(28) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Na(2), one Ga(2), and one Si(1) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Na(1), one Ga(6), and one Si(2) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Na(2), one Ga(1), one Si(2), and one O(13) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Na(3), one Ga(3), and one Si(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Na(1), one Na(4), one Ga(4), and one Si(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Na(3), one Ga(2), and one Si(4) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Na(4), one Ga(2), and one Si(3) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Na(1), one Ga(4), and one Si(4) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Na(2), one Ga(3), and one Si(3) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Na(2), one Na(4), and one O(6) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Na(7), one Ga(3), and one Si(4) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Na(8), one Ga(4), and one Si(3) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Na(5), one Ga(5), and one Si(4) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Na(6), one Ga(5), and one Si(3) atom. In the eighteenth O site, O(18) is bonded in a 3-coordinate geometry to one Na(5), one Si(5), and one O(26) atom. In the nineteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Na(6), one Ga(3), and one Si(5) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal planar geometry to one Na(8), one Ga(1), and one Si(5) atom. In the twenty-first O site, O(21) is bonded in a trigonal planar geometry to one Na(7), one Ga(6), and one Si(5) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Na(8), one Ga(5), and one Si(6) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal planar geometry to one Na(7), one Ga(5), and one Si(1) atom. In the twenty-fourth O site, O(24) is bonded in a distorted trigonal planar geometry to one Na(5), one Ga(6), and one Si(6) atom. In the twenty-fifth O site, O(25) is bonded in a 3-coordinate geometry to one Na(6), one Ga(1), and one Si(1) atom. In the twenty-sixth O site, O(26) is bonded in a 1-coordinate geometry to one Na(8), one Ga(4), and one O(18) atom. In the twenty-seventh O site, O(27) is bonded in a distorted T-shaped geometry to one Na(2), one Na(6), and one Ga(1) atom. In the twenty-eighth O site, O(28) is bonded in a 3-coordinate geometry to one Na(1), one Ga(2), and one O(3) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na4Ga3Si3NO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.227
_cell_length_b   9.263
_cell_length_c   9.406
_cell_angle_alpha   89.695
_cell_angle_beta   90.063
_cell_angle_gamma   89.404
_symmetry_Int_Tables_number   1
_cell_volume   803.907
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.195  0.181  0.193  1.0
  Na  Na1  1  0.185  0.802  0.802  1.0
  Na  Na2  1  0.328  0.312  0.682  1.0
  Na  Na3  1  0.293  0.692  0.325  1.0
  Na  Na4  1  0.684  0.318  0.300  1.0
  Na  Na5  1  0.703  0.696  0.705  1.0
  Na  Na6  1  0.809  0.186  0.820  1.0
  Na  Na7  1  0.797  0.804  0.217  1.0
  Ga  Ga8  1  0.986  0.753  0.542  1.0
  Ga  Ga9  1  0.253  0.488  0.969  1.0
  Ga  Ga10  1  0.495  0.989  0.738  1.0
  Ga  Ga11  1  0.476  0.985  0.209  1.0
  Ga  Ga12  1  0.761  0.493  0.000  1.0
  Ga  Ga13  1  0.998  0.249  0.509  1.0
  Si  Si14  1  0.003  0.481  0.745  1.0
  Si  Si15  1  0.261  0.010  0.480  1.0
  Si  Si16  1  0.491  0.732  0.980  1.0
  Si  Si17  1  0.511  0.245  0.988  1.0
  Si  Si18  1  0.770  0.001  0.526  1.0
  Si  Si19  1  0.983  0.509  0.282  1.0
  N  N20  1  0.588  0.409  0.530  1.0
  N  N21  1  0.174  0.064  0.912  1.0
  O  O22  1  0.076  0.342  0.662  1.0
  O  O23  1  0.040  0.646  0.371  1.0
  O  O24  1  0.146  0.460  0.211  1.0
  O  O25  1  0.142  0.559  0.821  1.0
  O  O26  1  0.146  0.138  0.435  1.0
  O  O27  1  0.174  0.863  0.546  1.0
  O  O28  1  0.365  0.072  0.608  1.0
  O  O29  1  0.318  0.954  0.324  1.0
  O  O30  1  0.387  0.350  0.916  1.0
  O  O31  1  0.352  0.642  0.045  1.0
  O  O32  1  0.443  0.164  0.130  1.0
  O  O33  1  0.435  0.832  0.846  1.0
  O  O34  1  0.304  0.764  0.565  1.0
  O  O35  1  0.563  0.132  0.864  1.0
  O  O36  1  0.549  0.834  0.109  1.0
  O  O37  1  0.653  0.331  0.051  1.0
  O  O38  1  0.632  0.633  0.931  1.0
  O  O39  1  0.679  0.091  0.396  1.0
  O  O40  1  0.656  0.931  0.638  1.0
  O  O41  1  0.870  0.883  0.442  1.0
  O  O42  1  0.857  0.138  0.593  1.0
  O  O43  1  0.858  0.560  0.163  1.0
  O  O44  1  0.879  0.424  0.858  1.0
  O  O45  1  0.924  0.364  0.362  1.0
  O  O46  1  0.915  0.581  0.628  1.0
  O  O47  1  0.632  0.957  0.325  1.0
  O  O48  1  0.947  0.827  0.730  1.0
  O  O49  1  0.117  0.380  0.074  1.0
[/CIF]
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