The structure described by HgIn2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Hg(1) is bonded to four equivalent O(1) atoms to form HgO4 tetrahedra that share corners with twelve equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 60°. In(1) is bonded to six equivalent O(1) atoms to form InO6 octahedra that share corners with six equivalent Hg(1)O4 tetrahedra and edges with six equivalent In(1)O6 octahedra. O(1) is bonded to one Hg(1) and three equivalent In(1) atoms to form a mixture of distorted corner and edge-sharing OIn3Hg tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_In2HgO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.576
_cell_length_b   6.576
_cell_length_c   6.576
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   201.120
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.500  0.500  0.000  1.0
  In  In1  1  0.500  0.000  0.500  1.0
  In  In2  1  0.000  0.500  0.500  1.0
  In  In3  1  0.500  0.500  0.500  1.0
  Hg  Hg4  1  0.125  0.125  0.125  1.0
  Hg  Hg5  1  0.875  0.875  0.875  1.0
  O  O6  1  0.266  0.266  0.266  1.0
  O  O7  1  0.703  0.266  0.266  1.0
  O  O8  1  0.734  0.734  0.297  1.0
  O  O9  1  0.734  0.297  0.734  1.0
  O  O10  1  0.266  0.703  0.266  1.0
  O  O11  1  0.266  0.266  0.703  1.0
  O  O12  1  0.297  0.734  0.734  1.0
  O  O13  1  0.734  0.734  0.734  1.0
[/CIF]
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The structure described by HgIn2O4 is Spinel structured and crystallizes in the cubic Fd-3m space group. Hg(1) is bonded to four equivalent O(1) atoms to form HgO4 tetrahedra that share corners with twelve equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 60°. In(1) is bonded to six equivalent O(1) atoms to form InO6 octahedra that share corners with six equivalent Hg(1)O4 tetrahedra and edges with six equivalent In(1)O6 octahedra. O(1) is bonded to one Hg(1) and three equivalent In(1) atoms to form a mixture of distorted corner and edge-sharing OIn3Hg tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_In2HgO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.576
_cell_length_b   6.576
_cell_length_c   6.576
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   201.120
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.500  0.500  0.000  1.0
  In  In1  1  0.500  0.000  0.500  1.0
  In  In2  1  0.000  0.500  0.500  1.0
  In  In3  1  0.500  0.500  0.500  1.0
  Hg  Hg4  1  0.125  0.125  0.125  1.0
  Hg  Hg5  1  0.875  0.875  0.875  1.0
  O  O6  1  0.266  0.266  0.266  1.0
  O  O7  1  0.703  0.266  0.266  1.0
  O  O8  1  0.734  0.734  0.297  1.0
  O  O9  1  0.734  0.297  0.734  1.0
  O  O10  1  0.266  0.703  0.266  1.0
  O  O11  1  0.266  0.266  0.703  1.0
  O  O12  1  0.297  0.734  0.734  1.0
  O  O13  1  0.734  0.734  0.734  1.0
[/CIF]
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