The compound described by Ce2CdS4 crystallizes in the tetragonal I-42d space group. Ce(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Cd(1) is bonded in a distorted square co-planar geometry to four equivalent S(1) atoms. S(1) is bonded in a 5-coordinate geometry to four equivalent Ce(1) and one Cd(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ce2CdS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.428
_cell_length_b   7.428
_cell_length_c   7.428
_cell_angle_alpha   110.805
_cell_angle_beta   110.805
_cell_angle_gamma   106.835
_symmetry_Int_Tables_number   1
_cell_volume   315.018
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.375  0.986  0.111  1.0
  Ce  Ce1  1  0.736  0.625  0.611  1.0
  Ce  Ce2  1  0.875  0.264  0.889  1.0
  Ce  Ce3  1  0.014  0.125  0.389  1.0
  Cd  Cd4  1  0.250  0.750  0.500  1.0
  Cd  Cd5  1  0.500  0.500  0.000  1.0
  S  S6  1  0.130  0.509  0.763  1.0
  S  S7  1  0.117  0.996  0.737  1.0
  S  S8  1  0.633  0.870  0.378  1.0
  S  S9  1  0.259  0.380  0.263  1.0
  S  S10  1  0.620  0.883  0.878  1.0
  S  S11  1  0.004  0.741  0.122  1.0
  S  S12  1  0.491  0.254  0.622  1.0
  S  S13  1  0.746  0.367  0.237  1.0
[/CIF]
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The compound described by Ce2CdS4 crystallizes in the tetragonal I-42d space group. Ce(1) is bonded in a 8-coordinate geometry to eight equivalent S(1) atoms. Cd(1) is bonded in a distorted square co-planar geometry to four equivalent S(1) atoms. S(1) is bonded in a 5-coordinate geometry to four equivalent Ce(1) and one Cd(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ce2CdS4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.428
_cell_length_b   7.428
_cell_length_c   7.428
_cell_angle_alpha   110.805
_cell_angle_beta   110.805
_cell_angle_gamma   106.835
_symmetry_Int_Tables_number   1
_cell_volume   315.018
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.375  0.986  0.111  1.0
  Ce  Ce1  1  0.736  0.625  0.611  1.0
  Ce  Ce2  1  0.875  0.264  0.889  1.0
  Ce  Ce3  1  0.014  0.125  0.389  1.0
  Cd  Cd4  1  0.250  0.750  0.500  1.0
  Cd  Cd5  1  0.500  0.500  0.000  1.0
  S  S6  1  0.130  0.509  0.763  1.0
  S  S7  1  0.117  0.996  0.737  1.0
  S  S8  1  0.633  0.870  0.378  1.0
  S  S9  1  0.259  0.380  0.263  1.0
  S  S10  1  0.620  0.883  0.878  1.0
  S  S11  1  0.004  0.741  0.122  1.0
  S  S12  1  0.491  0.254  0.622  1.0
  S  S13  1  0.746  0.367  0.237  1.0
[/CIF]
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