The material described by (PtF6)2PtOF6PtO3F5(O2)2OF is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules, one hypofluorous acid molecule, two PtF6 clusters, one PtO3F5 cluster, and one PtOF6 cluster. In each PtF6 cluster, Pt(2) is bonded in an octahedral geometry to one F(12), one F(13), one F(17), one F(18), one F(7), and one F(8) atom. There are six inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Pt(2) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Pt(2) atom. In the third F site, F(12) is bonded in a single-bond geometry to one Pt(2) atom. In the fourth F site, F(13) is bonded in a single-bond geometry to one Pt(2) atom. In the fifth F site, F(17) is bonded in a single-bond geometry to one Pt(2) atom. In the sixth F site, F(18) is bonded in a single-bond geometry to one Pt(2) atom. In the PtO3F5 cluster, Pt(4) is bonded in an octahedral geometry to one O(5), one F(1), one F(2), one F(23), one F(24), and one F(3) atom. There are three inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one Pt(4) and one O(7) atom. In the second O site, O(6) is bonded in a single-bond geometry to one F(23) atom. In the third O site, O(7) is bonded in a single-bond geometry to one O(5) atom. There are five inequivalent F sites. In the first F site, F(23) is bonded in a bent 120 degrees geometry to one Pt(4) and one O(6) atom. In the second F site, F(24) is bonded in a single-bond geometry to one Pt(4) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Pt(4) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Pt(4) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one Pt(4) atom. In the PtOF6 cluster, Pt(1) is bonded in an octahedral geometry to one F(11), one F(14), one F(16), one F(19), one F(6), and one F(9) atom. O(9) is bonded in a single-bond geometry to one F(11) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Pt(1) atom. In the second F site, F(9) is bonded in a single-bond geometry to one Pt(1) atom. In the third F site, F(11) is bonded in a bent 120 degrees geometry to one Pt(1) and one O(9) atom. In the fourth F site, F(14) is bonded in a single-bond geometry to one Pt(1) atom. In the fifth F site, F(16) is bonded in a single-bond geometry to one Pt(1) atom. In the sixth F site, F(19) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pt4(O3F8)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.926
_cell_length_b   9.323
_cell_length_c   9.461
_cell_angle_alpha   108.532
_cell_angle_beta   107.294
_cell_angle_gamma   114.067
_symmetry_Int_Tables_number   1
_cell_volume   659.446
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.511  0.999  0.492  1.0
  Pt  Pt1  1  0.007  0.015  0.016  1.0
  Pt  Pt2  1  0.490  0.500  0.987  1.0
  Pt  Pt3  1  0.025  0.472  0.487  1.0
  O  O4  1  0.497  0.961  0.929  1.0
  O  O5  1  0.390  0.442  0.424  1.0
  O  O6  1  0.509  0.507  0.558  1.0
  O  O7  1  0.507  0.028  0.066  1.0
  O  O8  1  0.790  0.431  0.330  1.0
  O  O9  1  0.120  0.488  0.828  1.0
  O  O10  1  0.801  0.513  0.249  1.0
  O  O11  1  0.897  0.664  0.644  1.0
  O  O12  1  0.147  0.907  0.425  1.0
  F  F13  1  0.160  0.726  0.669  1.0
  F  F14  1  0.084  0.558  0.342  1.0
  F  F15  1  0.217  0.458  0.574  1.0
  F  F16  1  0.442  0.678  0.985  1.0
  F  F17  1  0.253  0.314  0.831  1.0
  F  F18  1  0.336  0.836  0.258  1.0
  F  F19  1  0.061  0.257  0.096  1.0
  F  F20  1  0.077  0.057  0.245  1.0
  F  F21  1  0.468  0.802  0.535  1.0
  F  F22  1  0.535  0.471  0.800  1.0
  F  F23  1  0.316  0.019  0.556  1.0
  F  F24  1  0.780  0.927  0.970  1.0
  F  F25  1  0.231  0.093  0.056  1.0
  F  F26  1  0.678  0.985  0.439  1.0
  F  F27  1  0.455  0.522  0.179  1.0
  F  F28  1  0.555  0.200  0.454  1.0
  F  F29  1  0.946  0.984  0.792  1.0
  F  F30  1  0.952  0.770  0.932  1.0
  F  F31  1  0.682  0.166  0.727  1.0
  F  F32  1  0.725  0.693  0.141  1.0
  F  F33  1  0.535  0.319  0.992  1.0
  F  F34  1  0.769  0.663  0.538  1.0
  F  F35  1  0.975  0.385  0.663  1.0
  F  F36  1  0.889  0.218  0.312  1.0
[/CIF]
.
The material described by (PtF6)2PtOF6PtO3F5(O2)2OF is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules, one hypofluorous acid molecule, two PtF6 clusters, one PtO3F5 cluster, and one PtOF6 cluster. In each PtF6 cluster, Pt(2) is bonded in an octahedral geometry to one F(12), one F(13), one F(17), one F(18), one F(7), and one F(8) atom. There are six inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one Pt(2) atom. In the second F site, F(8) is bonded in a single-bond geometry to one Pt(2) atom. In the third F site, F(12) is bonded in a single-bond geometry to one Pt(2) atom. In the fourth F site, F(13) is bonded in a single-bond geometry to one Pt(2) atom. In the fifth F site, F(17) is bonded in a single-bond geometry to one Pt(2) atom. In the sixth F site, F(18) is bonded in a single-bond geometry to one Pt(2) atom. In the PtO3F5 cluster, Pt(4) is bonded in an octahedral geometry to one O(5), one F(1), one F(2), one F(23), one F(24), and one F(3) atom. There are three inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one Pt(4) and one O(7) atom. In the second O site, O(6) is bonded in a single-bond geometry to one F(23) atom. In the third O site, O(7) is bonded in a single-bond geometry to one O(5) atom. There are five inequivalent F sites. In the first F site, F(23) is bonded in a bent 120 degrees geometry to one Pt(4) and one O(6) atom. In the second F site, F(24) is bonded in a single-bond geometry to one Pt(4) atom. In the third F site, F(1) is bonded in a single-bond geometry to one Pt(4) atom. In the fourth F site, F(2) is bonded in a single-bond geometry to one Pt(4) atom. In the fifth F site, F(3) is bonded in a single-bond geometry to one Pt(4) atom. In the PtOF6 cluster, Pt(1) is bonded in an octahedral geometry to one F(11), one F(14), one F(16), one F(19), one F(6), and one F(9) atom. O(9) is bonded in a single-bond geometry to one F(11) atom. There are six inequivalent F sites. In the first F site, F(6) is bonded in a single-bond geometry to one Pt(1) atom. In the second F site, F(9) is bonded in a single-bond geometry to one Pt(1) atom. In the third F site, F(11) is bonded in a bent 120 degrees geometry to one Pt(1) and one O(9) atom. In the fourth F site, F(14) is bonded in a single-bond geometry to one Pt(1) atom. In the fifth F site, F(16) is bonded in a single-bond geometry to one Pt(1) atom. In the sixth F site, F(19) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Pt4(O3F8)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.926
_cell_length_b   9.323
_cell_length_c   9.461
_cell_angle_alpha   108.532
_cell_angle_beta   107.294
_cell_angle_gamma   114.067
_symmetry_Int_Tables_number   1
_cell_volume   659.446
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.511  0.999  0.492  1.0
  Pt  Pt1  1  0.007  0.015  0.016  1.0
  Pt  Pt2  1  0.490  0.500  0.987  1.0
  Pt  Pt3  1  0.025  0.472  0.487  1.0
  O  O4  1  0.497  0.961  0.929  1.0
  O  O5  1  0.390  0.442  0.424  1.0
  O  O6  1  0.509  0.507  0.558  1.0
  O  O7  1  0.507  0.028  0.066  1.0
  O  O8  1  0.790  0.431  0.330  1.0
  O  O9  1  0.120  0.488  0.828  1.0
  O  O10  1  0.801  0.513  0.249  1.0
  O  O11  1  0.897  0.664  0.644  1.0
  O  O12  1  0.147  0.907  0.425  1.0
  F  F13  1  0.160  0.726  0.669  1.0
  F  F14  1  0.084  0.558  0.342  1.0
  F  F15  1  0.217  0.458  0.574  1.0
  F  F16  1  0.442  0.678  0.985  1.0
  F  F17  1  0.253  0.314  0.831  1.0
  F  F18  1  0.336  0.836  0.258  1.0
  F  F19  1  0.061  0.257  0.096  1.0
  F  F20  1  0.077  0.057  0.245  1.0
  F  F21  1  0.468  0.802  0.535  1.0
  F  F22  1  0.535  0.471  0.800  1.0
  F  F23  1  0.316  0.019  0.556  1.0
  F  F24  1  0.780  0.927  0.970  1.0
  F  F25  1  0.231  0.093  0.056  1.0
  F  F26  1  0.678  0.985  0.439  1.0
  F  F27  1  0.455  0.522  0.179  1.0
  F  F28  1  0.555  0.200  0.454  1.0
  F  F29  1  0.946  0.984  0.792  1.0
  F  F30  1  0.952  0.770  0.932  1.0
  F  F31  1  0.682  0.166  0.727  1.0
  F  F32  1  0.725  0.693  0.141  1.0
  F  F33  1  0.535  0.319  0.992  1.0
  F  F34  1  0.769  0.663  0.538  1.0
  F  F35  1  0.975  0.385  0.663  1.0
  F  F36  1  0.889  0.218  0.312  1.0
[/CIF]
.