The compound described by Ag2Cl3 is Corundum structured and crystallizes in the trigonal R-3c space group. Ag(1) is bonded to six equivalent Cl(1) atoms to form a mixture of corner, face, and edge-sharing AgCl6 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. Cl(1) is bonded to four equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing ClAg4 trigonal pyramids. is represented by the CIF card [CIF]
data_Ag2Cl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.619
_cell_length_b   6.619
_cell_length_c   7.155
_cell_angle_alpha   117.556
_cell_angle_beta   62.444
_cell_angle_gamma   120.003
_symmetry_Int_Tables_number   1
_cell_volume   229.463
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.657  0.343  0.028  1.0
  Ag  Ag1  1  0.843  0.157  0.472  1.0
  Ag  Ag2  1  0.157  0.843  0.528  1.0
  Ag  Ag3  1  0.343  0.657  0.972  1.0
  Cl  Cl4  1  0.932  0.432  0.250  1.0
  Cl  Cl5  1  0.568  0.750  0.250  1.0
  Cl  Cl6  1  0.250  0.068  0.250  1.0
  Cl  Cl7  1  0.750  0.932  0.750  1.0
  Cl  Cl8  1  0.432  0.250  0.750  1.0
  Cl  Cl9  1  0.068  0.568  0.750  1.0
[/CIF]
.
The compound described by Ag2Cl3 is Corundum structured and crystallizes in the trigonal R-3c space group. Ag(1) is bonded to six equivalent Cl(1) atoms to form a mixture of corner, face, and edge-sharing AgCl6 octahedra. The corner-sharing octahedral tilt angles range from 47-55°. Cl(1) is bonded to four equivalent Ag(1) atoms to form a mixture of distorted corner and edge-sharing ClAg4 trigonal pyramids. is represented by the CIF card [CIF]
data_Ag2Cl3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.619
_cell_length_b   6.619
_cell_length_c   7.155
_cell_angle_alpha   117.556
_cell_angle_beta   62.444
_cell_angle_gamma   120.003
_symmetry_Int_Tables_number   1
_cell_volume   229.463
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.657  0.343  0.028  1.0
  Ag  Ag1  1  0.843  0.157  0.472  1.0
  Ag  Ag2  1  0.157  0.843  0.528  1.0
  Ag  Ag3  1  0.343  0.657  0.972  1.0
  Cl  Cl4  1  0.932  0.432  0.250  1.0
  Cl  Cl5  1  0.568  0.750  0.250  1.0
  Cl  Cl6  1  0.250  0.068  0.250  1.0
  Cl  Cl7  1  0.750  0.932  0.750  1.0
  Cl  Cl8  1  0.432  0.250  0.750  1.0
  Cl  Cl9  1  0.068  0.568  0.750  1.0
[/CIF]
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