The crystal structure described by ScV(SeO4)2 crystallizes in the monoclinic P2_1/c space group. Sc(1) is bonded in an octahedral geometry to one O(1), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(6), one O(8), and two equivalent O(7) atoms. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. In the second Se site, Se(2) is bonded in a trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a bent 150 degrees geometry to one Sc(1) and one Se(2) atom. In the second O site, O(6) is bonded in a trigonal planar geometry to one Sc(1), one V(1), and one Se(2) atom. In the third O site, O(7) is bonded in a distorted water-like geometry to two equivalent V(1) atoms. In the fourth O site, O(8) is bonded in a linear geometry to one Sc(1) and one V(1) atom. In the fifth O site, O(1) is bonded in a trigonal planar geometry to one Sc(1), one V(1), and one Se(1) atom. In the sixth O site, O(2) is bonded in a bent 120 degrees geometry to one V(1) and one Se(1) atom. In the seventh O site, O(3) is bonded in a bent 150 degrees geometry to one Sc(1) and one Se(1) atom. In the eighth O site, O(4) is bonded in a bent 150 degrees geometry to one Sc(1) and one Se(2) atom. is represented by the CIF card [CIF]
data_ScV(SeO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.210
_cell_length_b   9.154
_cell_length_c   15.297
_cell_angle_alpha   69.598
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   683.749
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.804  0.806  0.611  1.0
  Sc  Sc1  1  0.696  0.806  0.111  1.0
  Sc  Sc2  1  0.196  0.194  0.389  1.0
  Sc  Sc3  1  0.304  0.194  0.889  1.0
  V  V4  1  0.355  0.630  0.516  1.0
  V  V5  1  0.145  0.630  0.016  1.0
  V  V6  1  0.645  0.370  0.484  1.0
  V  V7  1  0.855  0.370  0.984  1.0
  Se  Se8  1  0.706  0.394  0.695  1.0
  Se  Se9  1  0.794  0.394  0.195  1.0
  Se  Se10  1  0.294  0.606  0.305  1.0
  Se  Se11  1  0.206  0.606  0.805  1.0
  Se  Se12  1  0.303  0.058  0.630  1.0
  Se  Se13  1  0.197  0.058  0.130  1.0
  Se  Se14  1  0.697  0.942  0.370  1.0
  Se  Se15  1  0.803  0.942  0.870  1.0
  O  O16  1  0.595  0.585  0.626  1.0
  O  O17  1  0.905  0.585  0.126  1.0
  O  O18  1  0.405  0.415  0.374  1.0
  O  O19  1  0.095  0.415  0.874  1.0
  O  O20  1  0.723  0.295  0.617  1.0
  O  O21  1  0.777  0.295  0.117  1.0
  O  O22  1  0.277  0.705  0.383  1.0
  O  O23  1  0.223  0.705  0.883  1.0
  O  O24  1  0.433  0.320  0.754  1.0
  O  O25  1  0.067  0.320  0.254  1.0
  O  O26  1  0.567  0.680  0.246  1.0
  O  O27  1  0.933  0.680  0.746  1.0
  O  O28  1  0.488  0.892  0.665  1.0
  O  O29  1  0.012  0.892  0.165  1.0
  O  O30  1  0.512  0.108  0.335  1.0
  O  O31  1  0.988  0.108  0.835  1.0
  O  O32  1  0.019  0.995  0.600  1.0
  O  O33  1  0.481  0.995  0.100  1.0
  O  O34  1  0.981  0.005  0.400  1.0
  O  O35  1  0.519  0.005  0.900  1.0
  O  O36  1  0.417  0.159  0.515  1.0
  O  O37  1  0.083  0.159  0.015  1.0
  O  O38  1  0.583  0.841  0.485  1.0
  O  O39  1  0.917  0.841  0.985  1.0
  O  O40  1  0.288  0.440  0.540  1.0
  O  O41  1  0.212  0.440  0.040  1.0
  O  O42  1  0.712  0.560  0.460  1.0
  O  O43  1  0.788  0.560  0.960  1.0
  O  O44  1  0.108  0.702  0.560  1.0
  O  O45  1  0.392  0.702  0.060  1.0
  O  O46  1  0.892  0.298  0.440  1.0
  O  O47  1  0.608  0.298  0.940  1.0
[/CIF]
.
The crystal structure described by ScV(SeO4)2 crystallizes in the monoclinic P2_1/c space group. Sc(1) is bonded in an octahedral geometry to one O(1), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. V(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(6), one O(8), and two equivalent O(7) atoms. There are two inequivalent Se sites. In the first Se site, Se(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(3) atom. In the second Se site, Se(2) is bonded in a trigonal non-coplanar geometry to one O(4), one O(5), and one O(6) atom. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a bent 150 degrees geometry to one Sc(1) and one Se(2) atom. In the second O site, O(6) is bonded in a trigonal planar geometry to one Sc(1), one V(1), and one Se(2) atom. In the third O site, O(7) is bonded in a distorted water-like geometry to two equivalent V(1) atoms. In the fourth O site, O(8) is bonded in a linear geometry to one Sc(1) and one V(1) atom. In the fifth O site, O(1) is bonded in a trigonal planar geometry to one Sc(1), one V(1), and one Se(1) atom. In the sixth O site, O(2) is bonded in a bent 120 degrees geometry to one V(1) and one Se(1) atom. In the seventh O site, O(3) is bonded in a bent 150 degrees geometry to one Sc(1) and one Se(1) atom. In the eighth O site, O(4) is bonded in a bent 150 degrees geometry to one Sc(1) and one Se(2) atom. is represented by the CIF card [CIF]
data_ScV(SeO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.210
_cell_length_b   9.154
_cell_length_c   15.297
_cell_angle_alpha   69.598
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   683.749
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  1  0.804  0.806  0.611  1.0
  Sc  Sc1  1  0.696  0.806  0.111  1.0
  Sc  Sc2  1  0.196  0.194  0.389  1.0
  Sc  Sc3  1  0.304  0.194  0.889  1.0
  V  V4  1  0.355  0.630  0.516  1.0
  V  V5  1  0.145  0.630  0.016  1.0
  V  V6  1  0.645  0.370  0.484  1.0
  V  V7  1  0.855  0.370  0.984  1.0
  Se  Se8  1  0.706  0.394  0.695  1.0
  Se  Se9  1  0.794  0.394  0.195  1.0
  Se  Se10  1  0.294  0.606  0.305  1.0
  Se  Se11  1  0.206  0.606  0.805  1.0
  Se  Se12  1  0.303  0.058  0.630  1.0
  Se  Se13  1  0.197  0.058  0.130  1.0
  Se  Se14  1  0.697  0.942  0.370  1.0
  Se  Se15  1  0.803  0.942  0.870  1.0
  O  O16  1  0.595  0.585  0.626  1.0
  O  O17  1  0.905  0.585  0.126  1.0
  O  O18  1  0.405  0.415  0.374  1.0
  O  O19  1  0.095  0.415  0.874  1.0
  O  O20  1  0.723  0.295  0.617  1.0
  O  O21  1  0.777  0.295  0.117  1.0
  O  O22  1  0.277  0.705  0.383  1.0
  O  O23  1  0.223  0.705  0.883  1.0
  O  O24  1  0.433  0.320  0.754  1.0
  O  O25  1  0.067  0.320  0.254  1.0
  O  O26  1  0.567  0.680  0.246  1.0
  O  O27  1  0.933  0.680  0.746  1.0
  O  O28  1  0.488  0.892  0.665  1.0
  O  O29  1  0.012  0.892  0.165  1.0
  O  O30  1  0.512  0.108  0.335  1.0
  O  O31  1  0.988  0.108  0.835  1.0
  O  O32  1  0.019  0.995  0.600  1.0
  O  O33  1  0.481  0.995  0.100  1.0
  O  O34  1  0.981  0.005  0.400  1.0
  O  O35  1  0.519  0.005  0.900  1.0
  O  O36  1  0.417  0.159  0.515  1.0
  O  O37  1  0.083  0.159  0.015  1.0
  O  O38  1  0.583  0.841  0.485  1.0
  O  O39  1  0.917  0.841  0.985  1.0
  O  O40  1  0.288  0.440  0.540  1.0
  O  O41  1  0.212  0.440  0.040  1.0
  O  O42  1  0.712  0.560  0.460  1.0
  O  O43  1  0.788  0.560  0.960  1.0
  O  O44  1  0.108  0.702  0.560  1.0
  O  O45  1  0.392  0.702  0.060  1.0
  O  O46  1  0.892  0.298  0.440  1.0
  O  O47  1  0.608  0.298  0.940  1.0
[/CIF]
.