The structure described by Rb3H(SO4)2 crystallizes in the monoclinic Cc space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 12-coordinate geometry to two equivalent H(1), one O(1), one O(2), one O(3), one O(4), one O(7), one O(8), two equivalent O(5), and two equivalent O(6) atoms. In the second Rb site, Rb(2) is bonded in a 9-coordinate geometry to one O(1), one O(5), one O(7), two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms. In the third Rb site, Rb(3) is bonded in a 9-coordinate geometry to one O(2), one O(6), one O(8), two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms. H(1) is bonded in a linear geometry to two equivalent Rb(1), one O(5), and one O(6) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(5), and one O(7) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(2), one O(4), one O(6), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a distorted water-like geometry to one Rb(2), two equivalent Rb(1), one H(1), and one S(1) atom. In the second O site, O(6) is bonded in a distorted water-like geometry to one Rb(3), two equivalent Rb(1), one H(1), and one S(2) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), two equivalent Rb(3), and one S(1) atom. In the fourth O site, O(8) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(3), two equivalent Rb(2), and one S(2) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one Rb(1), one Rb(2), two equivalent Rb(3), and one S(1) atom. In the sixth O site, O(2) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(3), two equivalent Rb(2), and one S(2) atom. In the seventh O site, O(3) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(3), and one S(1) atom. In the eighth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(2), and one S(2) atom. is represented by the CIF card [CIF]
data_Rb3H(SO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.323
_cell_length_b   8.323
_cell_length_c   10.340
_cell_angle_alpha   78.708
_cell_angle_beta   78.708
_cell_angle_gamma   42.130
_symmetry_Int_Tables_number   1
_cell_volume   469.824
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.739  0.253  0.750  1.0
  Rb  Rb1  1  0.253  0.739  0.250  1.0
  Rb  Rb2  1  0.536  0.085  0.152  1.0
  Rb  Rb3  1  0.921  0.465  0.348  1.0
  Rb  Rb4  1  0.465  0.921  0.848  1.0
  Rb  Rb5  1  0.085  0.536  0.652  1.0
  H  H6  1  0.038  0.967  0.511  1.0
  H  H7  1  0.967  0.038  0.011  1.0
  S  S8  1  0.341  0.896  0.536  1.0
  S  S9  1  0.103  0.671  0.965  1.0
  S  S10  1  0.671  0.103  0.465  1.0
  S  S11  1  0.896  0.341  0.036  1.0
  O  O12  1  0.384  0.919  0.392  1.0
  O  O13  1  0.080  0.618  0.109  1.0
  O  O14  1  0.618  0.080  0.609  1.0
  O  O15  1  0.919  0.384  0.892  1.0
  O  O16  1  0.562  0.695  0.604  1.0
  O  O17  1  0.304  0.446  0.897  1.0
  O  O18  1  0.446  0.304  0.397  1.0
  O  O19  1  0.695  0.562  0.104  1.0
  O  O20  1  0.203  0.826  0.558  1.0
  O  O21  1  0.156  0.815  0.948  1.0
  O  O22  1  0.815  0.156  0.448  1.0
  O  O23  1  0.826  0.203  0.058  1.0
  O  O24  1  0.180  0.125  0.596  1.0
  O  O25  1  0.872  0.823  0.905  1.0
  O  O26  1  0.823  0.872  0.405  1.0
  O  O27  1  0.125  0.180  0.096  1.0
[/CIF]
.
The structure described by Rb3H(SO4)2 crystallizes in the monoclinic Cc space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a 12-coordinate geometry to two equivalent H(1), one O(1), one O(2), one O(3), one O(4), one O(7), one O(8), two equivalent O(5), and two equivalent O(6) atoms. In the second Rb site, Rb(2) is bonded in a 9-coordinate geometry to one O(1), one O(5), one O(7), two equivalent O(2), two equivalent O(4), and two equivalent O(8) atoms. In the third Rb site, Rb(3) is bonded in a 9-coordinate geometry to one O(2), one O(6), one O(8), two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms. H(1) is bonded in a linear geometry to two equivalent Rb(1), one O(5), and one O(6) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(5), and one O(7) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(2), one O(4), one O(6), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a distorted water-like geometry to one Rb(2), two equivalent Rb(1), one H(1), and one S(1) atom. In the second O site, O(6) is bonded in a distorted water-like geometry to one Rb(3), two equivalent Rb(1), one H(1), and one S(2) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), two equivalent Rb(3), and one S(1) atom. In the fourth O site, O(8) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(3), two equivalent Rb(2), and one S(2) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one Rb(1), one Rb(2), two equivalent Rb(3), and one S(1) atom. In the sixth O site, O(2) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(3), two equivalent Rb(2), and one S(2) atom. In the seventh O site, O(3) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(3), and one S(1) atom. In the eighth O site, O(4) is bonded in a distorted single-bond geometry to one Rb(1), two equivalent Rb(2), and one S(2) atom. is represented by the CIF card [CIF]
data_Rb3H(SO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.323
_cell_length_b   8.323
_cell_length_c   10.340
_cell_angle_alpha   78.708
_cell_angle_beta   78.708
_cell_angle_gamma   42.130
_symmetry_Int_Tables_number   1
_cell_volume   469.824
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.739  0.253  0.750  1.0
  Rb  Rb1  1  0.253  0.739  0.250  1.0
  Rb  Rb2  1  0.536  0.085  0.152  1.0
  Rb  Rb3  1  0.921  0.465  0.348  1.0
  Rb  Rb4  1  0.465  0.921  0.848  1.0
  Rb  Rb5  1  0.085  0.536  0.652  1.0
  H  H6  1  0.038  0.967  0.511  1.0
  H  H7  1  0.967  0.038  0.011  1.0
  S  S8  1  0.341  0.896  0.536  1.0
  S  S9  1  0.103  0.671  0.965  1.0
  S  S10  1  0.671  0.103  0.465  1.0
  S  S11  1  0.896  0.341  0.036  1.0
  O  O12  1  0.384  0.919  0.392  1.0
  O  O13  1  0.080  0.618  0.109  1.0
  O  O14  1  0.618  0.080  0.609  1.0
  O  O15  1  0.919  0.384  0.892  1.0
  O  O16  1  0.562  0.695  0.604  1.0
  O  O17  1  0.304  0.446  0.897  1.0
  O  O18  1  0.446  0.304  0.397  1.0
  O  O19  1  0.695  0.562  0.104  1.0
  O  O20  1  0.203  0.826  0.558  1.0
  O  O21  1  0.156  0.815  0.948  1.0
  O  O22  1  0.815  0.156  0.448  1.0
  O  O23  1  0.826  0.203  0.058  1.0
  O  O24  1  0.180  0.125  0.596  1.0
  O  O25  1  0.872  0.823  0.905  1.0
  O  O26  1  0.823  0.872  0.405  1.0
  O  O27  1  0.125  0.180  0.096  1.0
[/CIF]
.