The crystal structure described by ZnCl4(CN3H6)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four guanidinium molecules and two ZnCl4 clusters. In each ZnCl4 cluster, Zn(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Zn(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnH12C2(N3Cl2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.228
_cell_length_b   7.401
_cell_length_c   12.807
_cell_angle_alpha   82.155
_cell_angle_beta   86.200
_cell_angle_gamma   76.876
_symmetry_Int_Tables_number   1
_cell_volume   660.463
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.957  0.175  0.224  1.0
  Zn  Zn1  1  0.043  0.825  0.776  1.0
  H  H2  1  0.244  0.041  0.520  1.0
  H  H3  1  0.756  0.959  0.480  1.0
  H  H4  1  0.236  0.169  0.393  1.0
  H  H5  1  0.764  0.831  0.607  1.0
  H  H6  1  0.246  0.485  0.373  1.0
  H  H7  1  0.754  0.515  0.627  1.0
  H  H8  1  0.262  0.593  0.486  1.0
  H  H9  1  0.738  0.407  0.514  1.0
  H  H10  1  0.287  0.427  0.647  1.0
  H  H11  1  0.713  0.573  0.353  1.0
  H  H12  1  0.273  0.189  0.666  1.0
  H  H13  1  0.727  0.811  0.334  1.0
  H  H14  1  0.373  0.652  0.171  1.0
  H  H15  1  0.627  0.348  0.829  1.0
  H  H16  1  0.569  0.494  0.121  1.0
  H  H17  1  0.431  0.506  0.879  1.0
  H  H18  1  0.842  0.600  0.059  1.0
  H  H19  1  0.158  0.400  0.941  1.0
  H  H20  1  0.850  0.835  0.063  1.0
  H  H21  1  0.150  0.165  0.937  1.0
  H  H22  1  0.593  0.039  0.129  1.0
  H  H23  1  0.407  0.961  0.871  1.0
  H  H24  1  0.386  0.959  0.176  1.0
  H  H25  1  0.614  0.041  0.824  1.0
  C  C26  1  0.257  0.316  0.514  1.0
  C  C27  1  0.743  0.684  0.486  1.0
  C  C28  1  0.603  0.762  0.119  1.0
  C  C29  1  0.397  0.238  0.881  1.0
  N  N30  1  0.244  0.163  0.472  1.0
  N  N31  1  0.756  0.837  0.528  1.0
  N  N32  1  0.255  0.478  0.453  1.0
  N  N33  1  0.745  0.522  0.547  1.0
  N  N34  1  0.275  0.309  0.617  1.0
  N  N35  1  0.725  0.691  0.383  1.0
  N  N36  1  0.508  0.625  0.139  1.0
  N  N37  1  0.492  0.375  0.861  1.0
  N  N38  1  0.779  0.730  0.077  1.0
  N  N39  1  0.221  0.270  0.923  1.0
  N  N40  1  0.521  0.934  0.144  1.0
  N  N41  1  0.479  0.066  0.856  1.0
  Cl  Cl42  1  0.722  0.239  0.354  1.0
  Cl  Cl43  1  0.278  0.761  0.646  1.0
  Cl  Cl44  1  0.111  0.871  0.269  1.0
  Cl  Cl45  1  0.889  0.129  0.731  1.0
  Cl  Cl46  1  0.814  0.225  0.065  1.0
  Cl  Cl47  1  0.186  0.775  0.935  1.0
  Cl  Cl48  1  0.178  0.355  0.212  1.0
  Cl  Cl49  1  0.822  0.645  0.788  1.0
[/CIF]
.
The crystal structure described by ZnCl4(CN3H6)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four guanidinium molecules and two ZnCl4 clusters. In each ZnCl4 cluster, Zn(1) is bonded in a tetrahedral geometry to one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Zn(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Zn(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnH12C2(N3Cl2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.228
_cell_length_b   7.401
_cell_length_c   12.807
_cell_angle_alpha   82.155
_cell_angle_beta   86.200
_cell_angle_gamma   76.876
_symmetry_Int_Tables_number   1
_cell_volume   660.463
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.957  0.175  0.224  1.0
  Zn  Zn1  1  0.043  0.825  0.776  1.0
  H  H2  1  0.244  0.041  0.520  1.0
  H  H3  1  0.756  0.959  0.480  1.0
  H  H4  1  0.236  0.169  0.393  1.0
  H  H5  1  0.764  0.831  0.607  1.0
  H  H6  1  0.246  0.485  0.373  1.0
  H  H7  1  0.754  0.515  0.627  1.0
  H  H8  1  0.262  0.593  0.486  1.0
  H  H9  1  0.738  0.407  0.514  1.0
  H  H10  1  0.287  0.427  0.647  1.0
  H  H11  1  0.713  0.573  0.353  1.0
  H  H12  1  0.273  0.189  0.666  1.0
  H  H13  1  0.727  0.811  0.334  1.0
  H  H14  1  0.373  0.652  0.171  1.0
  H  H15  1  0.627  0.348  0.829  1.0
  H  H16  1  0.569  0.494  0.121  1.0
  H  H17  1  0.431  0.506  0.879  1.0
  H  H18  1  0.842  0.600  0.059  1.0
  H  H19  1  0.158  0.400  0.941  1.0
  H  H20  1  0.850  0.835  0.063  1.0
  H  H21  1  0.150  0.165  0.937  1.0
  H  H22  1  0.593  0.039  0.129  1.0
  H  H23  1  0.407  0.961  0.871  1.0
  H  H24  1  0.386  0.959  0.176  1.0
  H  H25  1  0.614  0.041  0.824  1.0
  C  C26  1  0.257  0.316  0.514  1.0
  C  C27  1  0.743  0.684  0.486  1.0
  C  C28  1  0.603  0.762  0.119  1.0
  C  C29  1  0.397  0.238  0.881  1.0
  N  N30  1  0.244  0.163  0.472  1.0
  N  N31  1  0.756  0.837  0.528  1.0
  N  N32  1  0.255  0.478  0.453  1.0
  N  N33  1  0.745  0.522  0.547  1.0
  N  N34  1  0.275  0.309  0.617  1.0
  N  N35  1  0.725  0.691  0.383  1.0
  N  N36  1  0.508  0.625  0.139  1.0
  N  N37  1  0.492  0.375  0.861  1.0
  N  N38  1  0.779  0.730  0.077  1.0
  N  N39  1  0.221  0.270  0.923  1.0
  N  N40  1  0.521  0.934  0.144  1.0
  N  N41  1  0.479  0.066  0.856  1.0
  Cl  Cl42  1  0.722  0.239  0.354  1.0
  Cl  Cl43  1  0.278  0.761  0.646  1.0
  Cl  Cl44  1  0.111  0.871  0.269  1.0
  Cl  Cl45  1  0.889  0.129  0.731  1.0
  Cl  Cl46  1  0.814  0.225  0.065  1.0
  Cl  Cl47  1  0.186  0.775  0.935  1.0
  Cl  Cl48  1  0.178  0.355  0.212  1.0
  Cl  Cl49  1  0.822  0.645  0.788  1.0
[/CIF]
.