The crystal structure described by C6H4NHOH is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one formic acid molecule, one trimethylamine molecule, and one C8NH5 cluster. In the C8NH5 cluster, there are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(2) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one H(5) atom. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(1), one C(8), and one H(6) atom. In the seventh C site, C(8) is bonded in a bent 120 degrees geometry to one C(7) and one C(9) atom. In the eighth C site, C(9) is bonded in a linear geometry to one C(8) and one N(2) atom. N(2) is bonded in a single-bond geometry to one C(9) atom. There are five inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H6C6NO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.987
_cell_length_b   14.899
_cell_length_c   19.867
_cell_angle_alpha   90.014
_cell_angle_beta   90.002
_cell_angle_gamma   90.002
_symmetry_Int_Tables_number   1
_cell_volume   2956.052
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.500  0.572  0.213  1.0
  H  H1  1  0.496  0.361  0.478  1.0
  H  H2  1  0.496  0.360  0.600  1.0
  H  H3  1  0.500  0.652  0.601  1.0
  H  H4  1  0.499  0.652  0.478  1.0
  H  H5  1  0.498  0.583  0.376  1.0
  H  H6  1  0.498  0.433  0.771  1.0
  H  H7  1  0.404  0.382  0.705  1.0
  H  H8  1  0.583  0.378  0.705  1.0
  H  H9  1  0.503  0.572  0.773  1.0
  H  H10  1  0.592  0.628  0.708  1.0
  H  H11  1  0.413  0.629  0.709  1.0
  C  C12  1  0.497  0.507  0.467  1.0
  C  C13  1  0.496  0.425  0.504  1.0
  C  C14  1  0.497  0.425  0.574  1.0
  C  C15  1  0.498  0.506  0.612  1.0
  C  C16  1  0.499  0.588  0.575  1.0
  C  C17  1  0.498  0.588  0.505  1.0
  C  C18  1  0.498  0.514  0.395  1.0
  C  C19  1  0.498  0.450  0.345  1.0
  C  C20  1  0.499  0.356  0.357  1.0
  C  C21  1  0.499  0.474  0.273  1.0
  C  C22  1  0.496  0.420  0.717  1.0
  C  C23  1  0.502  0.588  0.719  1.0
  N  N24  1  0.500  0.505  0.681  1.0
  N  N25  1  0.499  0.279  0.368  1.0
  O  O26  1  0.500  0.421  0.226  1.0
  O  O27  1  0.499  0.565  0.262  1.0
[/CIF]
.
The crystal structure described by C6H4NHOH is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one formic acid molecule, one trimethylamine molecule, and one C8NH5 cluster. In the C8NH5 cluster, there are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(2) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one H(5) atom. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(1), one C(8), and one H(6) atom. In the seventh C site, C(8) is bonded in a bent 120 degrees geometry to one C(7) and one C(9) atom. In the eighth C site, C(9) is bonded in a linear geometry to one C(8) and one N(2) atom. N(2) is bonded in a single-bond geometry to one C(9) atom. There are five inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_H6C6NO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.987
_cell_length_b   14.899
_cell_length_c   19.867
_cell_angle_alpha   90.014
_cell_angle_beta   90.002
_cell_angle_gamma   90.002
_symmetry_Int_Tables_number   1
_cell_volume   2956.052
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.500  0.572  0.213  1.0
  H  H1  1  0.496  0.361  0.478  1.0
  H  H2  1  0.496  0.360  0.600  1.0
  H  H3  1  0.500  0.652  0.601  1.0
  H  H4  1  0.499  0.652  0.478  1.0
  H  H5  1  0.498  0.583  0.376  1.0
  H  H6  1  0.498  0.433  0.771  1.0
  H  H7  1  0.404  0.382  0.705  1.0
  H  H8  1  0.583  0.378  0.705  1.0
  H  H9  1  0.503  0.572  0.773  1.0
  H  H10  1  0.592  0.628  0.708  1.0
  H  H11  1  0.413  0.629  0.709  1.0
  C  C12  1  0.497  0.507  0.467  1.0
  C  C13  1  0.496  0.425  0.504  1.0
  C  C14  1  0.497  0.425  0.574  1.0
  C  C15  1  0.498  0.506  0.612  1.0
  C  C16  1  0.499  0.588  0.575  1.0
  C  C17  1  0.498  0.588  0.505  1.0
  C  C18  1  0.498  0.514  0.395  1.0
  C  C19  1  0.498  0.450  0.345  1.0
  C  C20  1  0.499  0.356  0.357  1.0
  C  C21  1  0.499  0.474  0.273  1.0
  C  C22  1  0.496  0.420  0.717  1.0
  C  C23  1  0.502  0.588  0.719  1.0
  N  N24  1  0.500  0.505  0.681  1.0
  N  N25  1  0.499  0.279  0.368  1.0
  O  O26  1  0.500  0.421  0.226  1.0
  O  O27  1  0.499  0.565  0.262  1.0
[/CIF]
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