The structure described by KV3Cu4CdO13 crystallizes in the monoclinic P2_1/m space group. K(1) is bonded in a 10-coordinate geometry to one O(5), two equivalent O(7), three equivalent O(3), and four equivalent O(9) atoms. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(3), and two equivalent O(7) atoms to form VO4 tetrahedra that share  a cornercorner with one Cd(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra,  a cornercorner with one Cu(3)O5 trigonal bipyramid, and corners with three equivalent Cu(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 50-52°. In the second V site, V(2) is bonded to one O(1), one O(6), and two equivalent O(9) atoms to form VO4 tetrahedra that share corners with three equivalent Cd(1)O6 octahedra and corners with four equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-74°. In the third V site, V(3) is bonded to one O(5), one O(8), and two equivalent O(10) atoms to form VO4 tetrahedra that share corners with two equivalent Cd(1)O6 octahedra, corners with four equivalent Cu(2)O6 octahedra,  a cornercorner with one Cu(1)O5 trigonal bipyramid, and corners with three equivalent Cu(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 34-66°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(2), one O(4), one O(5), and two equivalent O(7) atoms to form CuO5 trigonal bipyramids that share  a cornercorner with one V(3)O4 tetrahedra, corners with three equivalent V(1)O4 tetrahedra, edges with two equivalent Cu(2)O6 octahedra, and  an edgeedge with one Cu(3)O5 trigonal bipyramid. In the second Cu site, Cu(2) is bonded to one O(1), one O(10), one O(4), one O(6), one O(7), and one O(8) atom to form distorted CuO6 octahedra that share  a cornercorner with one V(1)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra,  a cornercorner with one Cu(3)O5 trigonal bipyramid,  an edgeedge with one Cd(1)O6 octahedra, edges with two equivalent Cu(2)O6 octahedra,  an edgeedge with one Cu(1)O5 trigonal bipyramid, and  an edgeedge with one Cu(3)O5 trigonal bipyramid. In the third Cu site, Cu(3) is bonded to one O(2), one O(4), one O(8), and two equivalent O(10) atoms to form CuO5 trigonal bipyramids that share corners with two equivalent Cu(2)O6 octahedra,  a cornercorner with one V(1)O4 tetrahedra, corners with three equivalent V(3)O4 tetrahedra,  an edgeedge with one Cd(1)O6 octahedra, edges with two equivalent Cu(2)O6 octahedra, and  an edgeedge with one Cu(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 57°. Cd(1) is bonded to one O(3), one O(6), two equivalent O(10), and two equivalent O(9) atoms to form CdO6 octahedra that share  a cornercorner with one V(1)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, corners with three equivalent V(2)O4 tetrahedra, edges with two equivalent Cu(2)O6 octahedra, and  an edgeedge with one Cu(3)O5 trigonal bipyramid. There are ten inequivalent O sites. In the first O site, O(8) is bonded in a distorted bent 120 degrees geometry to one V(3), one Cu(3), and two equivalent Cu(2) atoms. In the second O site, O(9) is bonded in a 4-coordinate geometry to two equivalent K(1), one V(2), and one Cd(1) atom. In the third O site, O(10) is bonded in a 4-coordinate geometry to one V(3), one Cu(2), one Cu(3), and one Cd(1) atom. In the fourth O site, O(1) is bonded in a distorted single-bond geometry to one V(2) and two equivalent Cu(2) atoms. In the fifth O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1), one Cu(1), and one Cu(3) atom. In the sixth O site, O(3) is bonded in a 2-coordinate geometry to three equivalent K(1), one V(1), and one Cd(1) atom. In the seventh O site, O(4) is bonded to one Cu(1), one Cu(3), and two equivalent Cu(2) atoms to form distorted corner-sharing OCu4 trigonal pyramids. In the eighth O site, O(5) is bonded in a distorted linear geometry to one K(1), one V(3), and one Cu(1) atom. In the ninth O site, O(6) is bonded to one V(2), two equivalent Cu(2), and one Cd(1) atom to form distorted corner-sharing OVCdCu2 tetrahedra. In the tenth O site, O(7) is bonded in a 3-coordinate geometry to one K(1), one V(1), one Cu(1), and one Cu(2) atom. is represented by the CIF file [CIF]
data_KV3CdCu4O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.172
_cell_length_b   8.385
_cell_length_c   10.737
_cell_angle_alpha   97.525
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   550.868
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.750  0.513  0.894  1.0
  K  K1  1  0.250  0.487  0.106  1.0
  V  V2  1  0.750  0.467  0.294  1.0
  V  V3  1  0.250  0.533  0.706  1.0
  V  V4  1  0.750  0.143  0.007  1.0
  V  V5  1  0.250  0.857  0.993  1.0
  V  V6  1  0.750  0.181  0.618  1.0
  V  V7  1  0.250  0.819  0.382  1.0
  Cd  Cd8  1  0.750  0.806  0.135  1.0
  Cd  Cd9  1  0.250  0.194  0.865  1.0
  Cu  Cu10  1  0.750  0.608  0.604  1.0
  Cu  Cu11  1  0.250  0.392  0.396  1.0
  Cu  Cu12  1  0.998  0.890  0.723  1.0
  Cu  Cu13  1  0.002  0.110  0.277  1.0
  Cu  Cu14  1  0.498  0.110  0.277  1.0
  Cu  Cu15  1  0.502  0.890  0.723  1.0
  Cu  Cu16  1  0.750  0.858  0.438  1.0
  Cu  Cu17  1  0.250  0.142  0.562  1.0
  O  O18  1  0.750  0.981  0.895  1.0
  O  O19  1  0.250  0.019  0.105  1.0
  O  O20  1  0.750  0.623  0.419  1.0
  O  O21  1  0.250  0.377  0.581  1.0
  O  O22  1  0.750  0.549  0.160  1.0
  O  O23  1  0.250  0.451  0.840  1.0
  O  O24  1  0.750  0.842  0.617  1.0
  O  O25  1  0.250  0.158  0.383  1.0
  O  O26  1  0.750  0.382  0.618  1.0
  O  O27  1  0.250  0.618  0.382  1.0
  O  O28  1  0.750  0.076  0.167  1.0
  O  O29  1  0.250  0.924  0.833  1.0
  O  O30  1  0.479  0.654  0.708  1.0
  O  O31  1  0.521  0.346  0.292  1.0
  O  O32  1  0.979  0.346  0.292  1.0
  O  O33  1  0.021  0.654  0.708  1.0
  O  O34  1  0.750  0.090  0.465  1.0
  O  O35  1  0.250  0.910  0.535  1.0
  O  O36  1  0.969  0.259  0.988  1.0
  O  O37  1  0.031  0.741  0.012  1.0
  O  O38  1  0.469  0.741  0.012  1.0
  O  O39  1  0.531  0.259  0.988  1.0
  O  O40  1  0.009  0.876  0.308  1.0
  O  O41  1  0.991  0.124  0.692  1.0
  O  O42  1  0.509  0.124  0.692  1.0
  O  O43  1  0.491  0.876  0.308  1.0
[/CIF]
.
The structure described by KV3Cu4CdO13 crystallizes in the monoclinic P2_1/m space group. K(1) is bonded in a 10-coordinate geometry to one O(5), two equivalent O(7), three equivalent O(3), and four equivalent O(9) atoms. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(2), one O(3), and two equivalent O(7) atoms to form VO4 tetrahedra that share  a cornercorner with one Cd(1)O6 octahedra, corners with two equivalent Cu(2)O6 octahedra,  a cornercorner with one Cu(3)O5 trigonal bipyramid, and corners with three equivalent Cu(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 50-52°. In the second V site, V(2) is bonded to one O(1), one O(6), and two equivalent O(9) atoms to form VO4 tetrahedra that share corners with three equivalent Cd(1)O6 octahedra and corners with four equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-74°. In the third V site, V(3) is bonded to one O(5), one O(8), and two equivalent O(10) atoms to form VO4 tetrahedra that share corners with two equivalent Cd(1)O6 octahedra, corners with four equivalent Cu(2)O6 octahedra,  a cornercorner with one Cu(1)O5 trigonal bipyramid, and corners with three equivalent Cu(3)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 34-66°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(2), one O(4), one O(5), and two equivalent O(7) atoms to form CuO5 trigonal bipyramids that share  a cornercorner with one V(3)O4 tetrahedra, corners with three equivalent V(1)O4 tetrahedra, edges with two equivalent Cu(2)O6 octahedra, and  an edgeedge with one Cu(3)O5 trigonal bipyramid. In the second Cu site, Cu(2) is bonded to one O(1), one O(10), one O(4), one O(6), one O(7), and one O(8) atom to form distorted CuO6 octahedra that share  a cornercorner with one V(1)O4 tetrahedra, corners with two equivalent V(2)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra,  a cornercorner with one Cu(3)O5 trigonal bipyramid,  an edgeedge with one Cd(1)O6 octahedra, edges with two equivalent Cu(2)O6 octahedra,  an edgeedge with one Cu(1)O5 trigonal bipyramid, and  an edgeedge with one Cu(3)O5 trigonal bipyramid. In the third Cu site, Cu(3) is bonded to one O(2), one O(4), one O(8), and two equivalent O(10) atoms to form CuO5 trigonal bipyramids that share corners with two equivalent Cu(2)O6 octahedra,  a cornercorner with one V(1)O4 tetrahedra, corners with three equivalent V(3)O4 tetrahedra,  an edgeedge with one Cd(1)O6 octahedra, edges with two equivalent Cu(2)O6 octahedra, and  an edgeedge with one Cu(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 57°. Cd(1) is bonded to one O(3), one O(6), two equivalent O(10), and two equivalent O(9) atoms to form CdO6 octahedra that share  a cornercorner with one V(1)O4 tetrahedra, corners with two equivalent V(3)O4 tetrahedra, corners with three equivalent V(2)O4 tetrahedra, edges with two equivalent Cu(2)O6 octahedra, and  an edgeedge with one Cu(3)O5 trigonal bipyramid. There are ten inequivalent O sites. In the first O site, O(8) is bonded in a distorted bent 120 degrees geometry to one V(3), one Cu(3), and two equivalent Cu(2) atoms. In the second O site, O(9) is bonded in a 4-coordinate geometry to two equivalent K(1), one V(2), and one Cd(1) atom. In the third O site, O(10) is bonded in a 4-coordinate geometry to one V(3), one Cu(2), one Cu(3), and one Cd(1) atom. In the fourth O site, O(1) is bonded in a distorted single-bond geometry to one V(2) and two equivalent Cu(2) atoms. In the fifth O site, O(2) is bonded in a distorted trigonal planar geometry to one V(1), one Cu(1), and one Cu(3) atom. In the sixth O site, O(3) is bonded in a 2-coordinate geometry to three equivalent K(1), one V(1), and one Cd(1) atom. In the seventh O site, O(4) is bonded to one Cu(1), one Cu(3), and two equivalent Cu(2) atoms to form distorted corner-sharing OCu4 trigonal pyramids. In the eighth O site, O(5) is bonded in a distorted linear geometry to one K(1), one V(3), and one Cu(1) atom. In the ninth O site, O(6) is bonded to one V(2), two equivalent Cu(2), and one Cd(1) atom to form distorted corner-sharing OVCdCu2 tetrahedra. In the tenth O site, O(7) is bonded in a 3-coordinate geometry to one K(1), one V(1), one Cu(1), and one Cu(2) atom. is represented by the CIF file [CIF]
data_KV3CdCu4O13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.172
_cell_length_b   8.385
_cell_length_c   10.737
_cell_angle_alpha   97.525
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   550.868
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.750  0.513  0.894  1.0
  K  K1  1  0.250  0.487  0.106  1.0
  V  V2  1  0.750  0.467  0.294  1.0
  V  V3  1  0.250  0.533  0.706  1.0
  V  V4  1  0.750  0.143  0.007  1.0
  V  V5  1  0.250  0.857  0.993  1.0
  V  V6  1  0.750  0.181  0.618  1.0
  V  V7  1  0.250  0.819  0.382  1.0
  Cd  Cd8  1  0.750  0.806  0.135  1.0
  Cd  Cd9  1  0.250  0.194  0.865  1.0
  Cu  Cu10  1  0.750  0.608  0.604  1.0
  Cu  Cu11  1  0.250  0.392  0.396  1.0
  Cu  Cu12  1  0.998  0.890  0.723  1.0
  Cu  Cu13  1  0.002  0.110  0.277  1.0
  Cu  Cu14  1  0.498  0.110  0.277  1.0
  Cu  Cu15  1  0.502  0.890  0.723  1.0
  Cu  Cu16  1  0.750  0.858  0.438  1.0
  Cu  Cu17  1  0.250  0.142  0.562  1.0
  O  O18  1  0.750  0.981  0.895  1.0
  O  O19  1  0.250  0.019  0.105  1.0
  O  O20  1  0.750  0.623  0.419  1.0
  O  O21  1  0.250  0.377  0.581  1.0
  O  O22  1  0.750  0.549  0.160  1.0
  O  O23  1  0.250  0.451  0.840  1.0
  O  O24  1  0.750  0.842  0.617  1.0
  O  O25  1  0.250  0.158  0.383  1.0
  O  O26  1  0.750  0.382  0.618  1.0
  O  O27  1  0.250  0.618  0.382  1.0
  O  O28  1  0.750  0.076  0.167  1.0
  O  O29  1  0.250  0.924  0.833  1.0
  O  O30  1  0.479  0.654  0.708  1.0
  O  O31  1  0.521  0.346  0.292  1.0
  O  O32  1  0.979  0.346  0.292  1.0
  O  O33  1  0.021  0.654  0.708  1.0
  O  O34  1  0.750  0.090  0.465  1.0
  O  O35  1  0.250  0.910  0.535  1.0
  O  O36  1  0.969  0.259  0.988  1.0
  O  O37  1  0.031  0.741  0.012  1.0
  O  O38  1  0.469  0.741  0.012  1.0
  O  O39  1  0.531  0.259  0.988  1.0
  O  O40  1  0.009  0.876  0.308  1.0
  O  O41  1  0.991  0.124  0.692  1.0
  O  O42  1  0.509  0.124  0.692  1.0
  O  O43  1  0.491  0.876  0.308  1.0
[/CIF]
.