The structure described by NaN crystallizes in the orthorhombic Fddd space group. Na(1) is bonded in a distorted square co-planar geometry to four equivalent N(1) atoms. N(1) is bonded to four equivalent Na(1) and one N(1) atom to form a mixture of distorted edge and corner-sharing NNa4N trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.613
_cell_length_b   6.339
_cell_length_c   5.881
_cell_angle_alpha   65.403
_cell_angle_beta   60.643
_cell_angle_gamma   53.954
_symmetry_Int_Tables_number   1
_cell_volume   170.869
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.249  0.249  0.751  1.0
  Na  Na1  1  0.751  0.751  0.249  1.0
  Na  Na2  1  0.001  0.001  0.499  1.0
  Na  Na3  1  0.499  0.499  0.001  1.0
  N  N4  1  0.569  0.431  0.569  1.0
  N  N5  1  0.431  0.569  0.431  1.0
  N  N6  1  0.681  0.819  0.681  1.0
  N  N7  1  0.819  0.681  0.819  1.0
[/CIF]
.
The structure described by NaN crystallizes in the orthorhombic Fddd space group. Na(1) is bonded in a distorted square co-planar geometry to four equivalent N(1) atoms. N(1) is bonded to four equivalent Na(1) and one N(1) atom to form a mixture of distorted edge and corner-sharing NNa4N trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaN
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.613
_cell_length_b   6.339
_cell_length_c   5.881
_cell_angle_alpha   65.403
_cell_angle_beta   60.643
_cell_angle_gamma   53.954
_symmetry_Int_Tables_number   1
_cell_volume   170.869
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.249  0.249  0.751  1.0
  Na  Na1  1  0.751  0.751  0.249  1.0
  Na  Na2  1  0.001  0.001  0.499  1.0
  Na  Na3  1  0.499  0.499  0.001  1.0
  N  N4  1  0.569  0.431  0.569  1.0
  N  N5  1  0.431  0.569  0.431  1.0
  N  N6  1  0.681  0.819  0.681  1.0
  N  N7  1  0.819  0.681  0.819  1.0
[/CIF]
.