The crystal structure described by (SnOCl3)2(O2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trioxidane molecules and two SnOCl3 clusters. In each SnOCl3 cluster, Sn(1) is bonded to two equivalent O(1), one Cl(1), one Cl(2), and one Cl(3) atom to form distorted edge-sharing SnCl3O2 trigonal bipyramids. O(1) is bonded in a bent 120 degrees geometry to two equivalent Sn(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SnCl3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.365
_cell_length_b   9.706
_cell_length_c   16.089
_cell_angle_alpha   58.002
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   842.913
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.521  0.832  0.482  1.0
  Sn  Sn1  1  0.979  0.832  0.982  1.0
  Sn  Sn2  1  0.479  0.168  0.518  1.0
  Sn  Sn3  1  0.021  0.168  0.018  1.0
  Cl  Cl4  1  0.378  0.938  0.326  1.0
  Cl  Cl5  1  0.122  0.938  0.826  1.0
  Cl  Cl6  1  0.622  0.062  0.674  1.0
  Cl  Cl7  1  0.878  0.062  0.174  1.0
  Cl  Cl8  1  0.862  0.737  0.485  1.0
  Cl  Cl9  1  0.638  0.737  0.985  1.0
  Cl  Cl10  1  0.138  0.263  0.515  1.0
  Cl  Cl11  1  0.362  0.263  0.015  1.0
  Cl  Cl12  1  0.360  0.576  0.586  1.0
  Cl  Cl13  1  0.140  0.576  0.086  1.0
  Cl  Cl14  1  0.640  0.424  0.414  1.0
  Cl  Cl15  1  0.860  0.424  0.914  1.0
  O  O16  1  0.662  0.042  0.470  1.0
  O  O17  1  0.838  0.042  0.970  1.0
  O  O18  1  0.338  0.958  0.530  1.0
  O  O19  1  0.162  0.958  0.030  1.0
  O  O20  1  0.547  0.710  0.704  1.0
  O  O21  1  0.953  0.710  0.204  1.0
  O  O22  1  0.453  0.290  0.296  1.0
  O  O23  1  0.047  0.290  0.796  1.0
  O  O24  1  0.797  0.260  0.300  1.0
  O  O25  1  0.703  0.260  0.800  1.0
  O  O26  1  0.203  0.740  0.700  1.0
  O  O27  1  0.297  0.740  0.200  1.0
  O  O28  1  0.627  0.316  0.250  1.0
  O  O29  1  0.873  0.316  0.750  1.0
  O  O30  1  0.373  0.684  0.750  1.0
  O  O31  1  0.127  0.684  0.250  1.0
[/CIF]
.
The crystal structure described by (SnOCl3)2(O2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four trioxidane molecules and two SnOCl3 clusters. In each SnOCl3 cluster, Sn(1) is bonded to two equivalent O(1), one Cl(1), one Cl(2), and one Cl(3) atom to form distorted edge-sharing SnCl3O2 trigonal bipyramids. O(1) is bonded in a bent 120 degrees geometry to two equivalent Sn(1) atoms. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SnCl3O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.365
_cell_length_b   9.706
_cell_length_c   16.089
_cell_angle_alpha   58.002
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   842.913
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.521  0.832  0.482  1.0
  Sn  Sn1  1  0.979  0.832  0.982  1.0
  Sn  Sn2  1  0.479  0.168  0.518  1.0
  Sn  Sn3  1  0.021  0.168  0.018  1.0
  Cl  Cl4  1  0.378  0.938  0.326  1.0
  Cl  Cl5  1  0.122  0.938  0.826  1.0
  Cl  Cl6  1  0.622  0.062  0.674  1.0
  Cl  Cl7  1  0.878  0.062  0.174  1.0
  Cl  Cl8  1  0.862  0.737  0.485  1.0
  Cl  Cl9  1  0.638  0.737  0.985  1.0
  Cl  Cl10  1  0.138  0.263  0.515  1.0
  Cl  Cl11  1  0.362  0.263  0.015  1.0
  Cl  Cl12  1  0.360  0.576  0.586  1.0
  Cl  Cl13  1  0.140  0.576  0.086  1.0
  Cl  Cl14  1  0.640  0.424  0.414  1.0
  Cl  Cl15  1  0.860  0.424  0.914  1.0
  O  O16  1  0.662  0.042  0.470  1.0
  O  O17  1  0.838  0.042  0.970  1.0
  O  O18  1  0.338  0.958  0.530  1.0
  O  O19  1  0.162  0.958  0.030  1.0
  O  O20  1  0.547  0.710  0.704  1.0
  O  O21  1  0.953  0.710  0.204  1.0
  O  O22  1  0.453  0.290  0.296  1.0
  O  O23  1  0.047  0.290  0.796  1.0
  O  O24  1  0.797  0.260  0.300  1.0
  O  O25  1  0.703  0.260  0.800  1.0
  O  O26  1  0.203  0.740  0.700  1.0
  O  O27  1  0.297  0.740  0.200  1.0
  O  O28  1  0.627  0.316  0.250  1.0
  O  O29  1  0.873  0.316  0.750  1.0
  O  O30  1  0.373  0.684  0.750  1.0
  O  O31  1  0.127  0.684  0.250  1.0
[/CIF]
.