The structure described by Re2O4Cl5 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Re2O4Cl5 cluster. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one Cl(5) atom. In the second Re site, Re(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Re(1) and one Re(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Re(1) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Re(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Re(2) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_Re2Cl5O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.865
_cell_length_b   6.062
_cell_length_c   7.830
_cell_angle_alpha   69.799
_cell_angle_beta   79.665
_cell_angle_gamma   85.282
_symmetry_Int_Tables_number   1
_cell_volume   256.996
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.361  0.463  0.563  1.0
  Re  Re1  1  0.016  0.995  0.001  1.0
  Cl  Cl2  1  0.970  0.958  0.726  1.0
  Cl  Cl3  1  0.160  0.129  0.200  1.0
  Cl  Cl4  1  0.343  0.763  0.994  1.0
  Cl  Cl5  1  0.791  0.333  0.925  1.0
  Cl  Cl6  1  0.598  0.284  0.399  1.0
  O  O7  1  0.294  0.275  0.789  1.0
  O  O8  1  0.822  0.803  0.148  1.0
  O  O9  1  0.113  0.547  0.472  1.0
  O  O10  1  0.490  0.706  0.561  1.0
[/CIF]
.
The structure described by Re2O4Cl5 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Re2O4Cl5 cluster. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one Cl(5) atom. In the second Re site, Re(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one Cl(1), one Cl(2), one Cl(3), and one Cl(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Re(1) and one Re(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Re(1) atom. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Re(2) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(2) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Re(2) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF file [CIF]
data_Re2Cl5O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.865
_cell_length_b   6.062
_cell_length_c   7.830
_cell_angle_alpha   69.799
_cell_angle_beta   79.665
_cell_angle_gamma   85.282
_symmetry_Int_Tables_number   1
_cell_volume   256.996
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.361  0.463  0.563  1.0
  Re  Re1  1  0.016  0.995  0.001  1.0
  Cl  Cl2  1  0.970  0.958  0.726  1.0
  Cl  Cl3  1  0.160  0.129  0.200  1.0
  Cl  Cl4  1  0.343  0.763  0.994  1.0
  Cl  Cl5  1  0.791  0.333  0.925  1.0
  Cl  Cl6  1  0.598  0.284  0.399  1.0
  O  O7  1  0.294  0.275  0.789  1.0
  O  O8  1  0.822  0.803  0.148  1.0
  O  O9  1  0.113  0.547  0.472  1.0
  O  O10  1  0.490  0.706  0.561  1.0
[/CIF]
.