The crystal structure described by LiAu4Se4(O3Cl)4 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one Au(1), one O(5), one Cl(3), and two equivalent Cl(2) atoms. There are four inequivalent Au sites. In the first Au site, Au(1) is bonded in a 5-coordinate geometry to one Li(1), one O(3), one O(5), one O(7), and one Cl(2) atom. In the second Au site, Au(2) is bonded in a rectangular see-saw-like geometry to one O(1), one O(11), one O(4), and one O(6) atom. In the third Au site, Au(3) is bonded in a rectangular see-saw-like geometry to one O(10), one O(2), one O(8), and one Cl(1) atom. In the fourth Au site, Au(4) is bonded in a rectangular see-saw-like geometry to one O(12), one O(9), one Cl(3), and one Cl(4) atom. There are four inequivalent Se sites. In the first Se site, Se(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(3), and one O(9) atom. In the second Se site, Se(2) is bonded in a trigonal non-coplanar geometry to one O(10), one O(6), and one O(7) atom. In the third Se site, Se(3) is bonded in a trigonal non-coplanar geometry to one O(2), one O(4), and one O(5) atom. In the fourth Se site, Se(4) is bonded in a distorted trigonal non-coplanar geometry to one O(11), one O(12), and one O(8) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Au(2) and one Se(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Au(3) and one Se(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Au(1) and one Se(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Au(2) and one Se(3) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(1), one Au(1), and one Se(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Au(2) and one Se(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Au(1) and one Se(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Au(3) and one Se(4) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Au(4) and one Se(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Au(3) and one Se(2) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Au(2) and one Se(4) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Au(4) and one Se(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Au(3) atom. In the second Cl site, Cl(2) is bonded in a distorted trigonal planar geometry to two equivalent Li(1) and one Au(1) atom. In the third Cl site, Cl(3) is bonded in a bent 120 degrees geometry to one Li(1) and one Au(4) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Au(4) atom. is represented by the CIF card [CIF]
data_LiAu4Se4(ClO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.531
_cell_length_b   10.213
_cell_length_c   11.128
_cell_angle_alpha   86.218
_cell_angle_beta   92.099
_cell_angle_gamma   93.773
_symmetry_Int_Tables_number   1
_cell_volume   512.498
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.195  0.378  0.330  1.0
  Au  Au1  1  0.979  0.586  0.183  1.0
  Au  Au2  1  0.023  0.993  0.989  1.0
  Au  Au3  1  0.002  0.403  0.822  1.0
  Au  Au4  1  0.010  0.013  0.486  1.0
  Se  Se5  1  0.720  0.879  0.245  1.0
  Se  Se6  1  0.210  0.703  0.909  1.0
  Se  Se7  1  0.819  0.265  0.091  1.0
  Se  Se8  1  0.298  0.131  0.740  1.0
  Cl  Cl9  1  0.317  0.476  0.671  1.0
  Cl  Cl10  1  0.689  0.499  0.352  1.0
  Cl  Cl11  1  0.350  0.194  0.453  1.0
  Cl  Cl12  1  0.686  0.833  0.520  1.0
  O  O13  1  0.674  0.955  0.100  1.0
  O  O14  1  0.709  0.341  0.955  1.0
  O  O15  1  0.021  0.788  0.232  1.0
  O  O16  1  0.112  0.172  0.056  1.0
  O  O17  1  0.064  0.380  0.159  1.0
  O  O18  1  0.932  0.813  0.923  1.0
  O  O19  1  0.304  0.648  0.054  1.0
  O  O20  1  0.983  0.214  0.771  1.0
  O  O21  1  0.910  0.019  0.307  1.0
  O  O22  1  0.927  0.587  0.864  1.0
  O  O23  1  0.363  0.039  0.874  1.0
  O  O24  1  0.104  0.004  0.667  1.0
[/CIF]
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The crystal structure described by LiAu4Se4(O3Cl)4 crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to one Au(1), one O(5), one Cl(3), and two equivalent Cl(2) atoms. There are four inequivalent Au sites. In the first Au site, Au(1) is bonded in a 5-coordinate geometry to one Li(1), one O(3), one O(5), one O(7), and one Cl(2) atom. In the second Au site, Au(2) is bonded in a rectangular see-saw-like geometry to one O(1), one O(11), one O(4), and one O(6) atom. In the third Au site, Au(3) is bonded in a rectangular see-saw-like geometry to one O(10), one O(2), one O(8), and one Cl(1) atom. In the fourth Au site, Au(4) is bonded in a rectangular see-saw-like geometry to one O(12), one O(9), one Cl(3), and one Cl(4) atom. There are four inequivalent Se sites. In the first Se site, Se(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(3), and one O(9) atom. In the second Se site, Se(2) is bonded in a trigonal non-coplanar geometry to one O(10), one O(6), and one O(7) atom. In the third Se site, Se(3) is bonded in a trigonal non-coplanar geometry to one O(2), one O(4), and one O(5) atom. In the fourth Se site, Se(4) is bonded in a distorted trigonal non-coplanar geometry to one O(11), one O(12), and one O(8) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Au(2) and one Se(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Au(3) and one Se(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Au(1) and one Se(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Au(2) and one Se(3) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Li(1), one Au(1), and one Se(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Au(2) and one Se(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Au(1) and one Se(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Au(3) and one Se(4) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Au(4) and one Se(1) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Au(3) and one Se(2) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Au(2) and one Se(4) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Au(4) and one Se(4) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Au(3) atom. In the second Cl site, Cl(2) is bonded in a distorted trigonal planar geometry to two equivalent Li(1) and one Au(1) atom. In the third Cl site, Cl(3) is bonded in a bent 120 degrees geometry to one Li(1) and one Au(4) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Au(4) atom. is represented by the CIF card [CIF]
data_LiAu4Se4(ClO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.531
_cell_length_b   10.213
_cell_length_c   11.128
_cell_angle_alpha   86.218
_cell_angle_beta   92.099
_cell_angle_gamma   93.773
_symmetry_Int_Tables_number   1
_cell_volume   512.498
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.195  0.378  0.330  1.0
  Au  Au1  1  0.979  0.586  0.183  1.0
  Au  Au2  1  0.023  0.993  0.989  1.0
  Au  Au3  1  0.002  0.403  0.822  1.0
  Au  Au4  1  0.010  0.013  0.486  1.0
  Se  Se5  1  0.720  0.879  0.245  1.0
  Se  Se6  1  0.210  0.703  0.909  1.0
  Se  Se7  1  0.819  0.265  0.091  1.0
  Se  Se8  1  0.298  0.131  0.740  1.0
  Cl  Cl9  1  0.317  0.476  0.671  1.0
  Cl  Cl10  1  0.689  0.499  0.352  1.0
  Cl  Cl11  1  0.350  0.194  0.453  1.0
  Cl  Cl12  1  0.686  0.833  0.520  1.0
  O  O13  1  0.674  0.955  0.100  1.0
  O  O14  1  0.709  0.341  0.955  1.0
  O  O15  1  0.021  0.788  0.232  1.0
  O  O16  1  0.112  0.172  0.056  1.0
  O  O17  1  0.064  0.380  0.159  1.0
  O  O18  1  0.932  0.813  0.923  1.0
  O  O19  1  0.304  0.648  0.054  1.0
  O  O20  1  0.983  0.214  0.771  1.0
  O  O21  1  0.910  0.019  0.307  1.0
  O  O22  1  0.927  0.587  0.864  1.0
  O  O23  1  0.363  0.039  0.874  1.0
  O  O24  1  0.104  0.004  0.667  1.0
[/CIF]
.