The structure described by PtP4H4O10I is Copper structured and crystallizes in the tetragonal I4/m space group. The structure is zero-dimensional and consists of two PtP4H4O10I clusters. Pt(1) is bonded in a distorted octahedral geometry to one Pt(1), four equivalent P(1), and one I(1) atom. P(1) is bonded in a trigonal non-coplanar geometry to one Pt(1), one O(1), one O(2), and one O(3) atom. H(1) is bonded in a distorted linear geometry to one O(2) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. In the second O site, O(2) is bonded in a water-like geometry to one P(1) and one H(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. I(1) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P4H4PtIO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.623
_cell_length_b   10.623
_cell_length_c   10.623
_cell_angle_alpha   125.479
_cell_angle_beta   125.479
_cell_angle_gamma   80.746
_symmetry_Int_Tables_number   1
_cell_volume   766.424
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.343  0.077  0.237  1.0
  P  P1  1  0.840  0.106  0.763  1.0
  P  P2  1  0.077  0.840  0.734  1.0
  P  P3  1  0.106  0.343  0.266  1.0
  P  P4  1  0.657  0.923  0.763  1.0
  P  P5  1  0.160  0.894  0.237  1.0
  P  P6  1  0.923  0.160  0.266  1.0
  P  P7  1  0.894  0.657  0.734  1.0
  H  H8  1  0.374  0.916  0.013  1.0
  H  H9  1  0.903  0.360  0.987  1.0
  H  H10  1  0.916  0.903  0.542  1.0
  H  H11  1  0.360  0.374  0.458  1.0
  H  H12  1  0.626  0.084  0.987  1.0
  H  H13  1  0.097  0.640  0.013  1.0
  H  H14  1  0.084  0.097  0.458  1.0
  H  H15  1  0.640  0.626  0.542  1.0
  Pt  Pt16  1  0.088  0.088  0.000  1.0
  Pt  Pt17  1  0.912  0.912  0.000  1.0
  I  I18  1  0.252  0.252  0.000  1.0
  I  I19  1  0.748  0.748  0.000  1.0
  O  O20  1  0.301  0.938  0.238  1.0
  O  O21  1  0.699  0.062  0.762  1.0
  O  O22  1  0.938  0.699  0.637  1.0
  O  O23  1  0.062  0.301  0.363  1.0
  O  O24  1  0.446  0.009  0.162  1.0
  O  O25  1  0.847  0.284  0.838  1.0
  O  O26  1  0.009  0.847  0.564  1.0
  O  O27  1  0.284  0.446  0.436  1.0
  O  O28  1  0.554  0.991  0.838  1.0
  O  O29  1  0.153  0.716  0.162  1.0
  O  O30  1  0.991  0.153  0.436  1.0
  O  O31  1  0.716  0.554  0.564  1.0
  O  O32  1  0.431  0.236  0.435  1.0
  O  O33  1  0.801  0.997  0.565  1.0
  O  O34  1  0.236  0.801  0.804  1.0
  O  O35  1  0.997  0.431  0.196  1.0
  O  O36  1  0.569  0.764  0.565  1.0
  O  O37  1  0.199  0.003  0.435  1.0
  O  O38  1  0.764  0.199  0.196  1.0
  O  O39  1  0.003  0.569  0.804  1.0
[/CIF]
.
The structure described by PtP4H4O10I is Copper structured and crystallizes in the tetragonal I4/m space group. The structure is zero-dimensional and consists of two PtP4H4O10I clusters. Pt(1) is bonded in a distorted octahedral geometry to one Pt(1), four equivalent P(1), and one I(1) atom. P(1) is bonded in a trigonal non-coplanar geometry to one Pt(1), one O(1), one O(2), and one O(3) atom. H(1) is bonded in a distorted linear geometry to one O(2) and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to two equivalent P(1) atoms. In the second O site, O(2) is bonded in a water-like geometry to one P(1) and one H(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. I(1) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_P4H4PtIO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.623
_cell_length_b   10.623
_cell_length_c   10.623
_cell_angle_alpha   125.479
_cell_angle_beta   125.479
_cell_angle_gamma   80.746
_symmetry_Int_Tables_number   1
_cell_volume   766.424
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.343  0.077  0.237  1.0
  P  P1  1  0.840  0.106  0.763  1.0
  P  P2  1  0.077  0.840  0.734  1.0
  P  P3  1  0.106  0.343  0.266  1.0
  P  P4  1  0.657  0.923  0.763  1.0
  P  P5  1  0.160  0.894  0.237  1.0
  P  P6  1  0.923  0.160  0.266  1.0
  P  P7  1  0.894  0.657  0.734  1.0
  H  H8  1  0.374  0.916  0.013  1.0
  H  H9  1  0.903  0.360  0.987  1.0
  H  H10  1  0.916  0.903  0.542  1.0
  H  H11  1  0.360  0.374  0.458  1.0
  H  H12  1  0.626  0.084  0.987  1.0
  H  H13  1  0.097  0.640  0.013  1.0
  H  H14  1  0.084  0.097  0.458  1.0
  H  H15  1  0.640  0.626  0.542  1.0
  Pt  Pt16  1  0.088  0.088  0.000  1.0
  Pt  Pt17  1  0.912  0.912  0.000  1.0
  I  I18  1  0.252  0.252  0.000  1.0
  I  I19  1  0.748  0.748  0.000  1.0
  O  O20  1  0.301  0.938  0.238  1.0
  O  O21  1  0.699  0.062  0.762  1.0
  O  O22  1  0.938  0.699  0.637  1.0
  O  O23  1  0.062  0.301  0.363  1.0
  O  O24  1  0.446  0.009  0.162  1.0
  O  O25  1  0.847  0.284  0.838  1.0
  O  O26  1  0.009  0.847  0.564  1.0
  O  O27  1  0.284  0.446  0.436  1.0
  O  O28  1  0.554  0.991  0.838  1.0
  O  O29  1  0.153  0.716  0.162  1.0
  O  O30  1  0.991  0.153  0.436  1.0
  O  O31  1  0.716  0.554  0.564  1.0
  O  O32  1  0.431  0.236  0.435  1.0
  O  O33  1  0.801  0.997  0.565  1.0
  O  O34  1  0.236  0.801  0.804  1.0
  O  O35  1  0.997  0.431  0.196  1.0
  O  O36  1  0.569  0.764  0.565  1.0
  O  O37  1  0.199  0.003  0.435  1.0
  O  O38  1  0.764  0.199  0.196  1.0
  O  O39  1  0.003  0.569  0.804  1.0
[/CIF]
.