The structure described by OsF4(OsO3F)2Os(OF)2 is Silicon tetrafluoride-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two tetrafluoroosmium molecules, two Os(OF)2 clusters, and four OsO3F clusters. In each Os(OF)2 cluster, Os(3) is bonded in a tetrahedral geometry to one O(3), one O(6), one F(12), and one F(16) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Os(3) atom. In the second O site, O(6) is bonded in a single-bond geometry to one Os(3) atom. There are two inequivalent F sites. In the first F site, F(12) is bonded in a single-bond geometry to one Os(3) atom. In the second F site, F(16) is bonded in a single-bond geometry to one Os(3) atom. In each OsO3F cluster, Os(2) is bonded in a tetrahedral geometry to one O(1), one O(16), one O(4), and one F(11) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Os(2) atom. In the third O site, O(16) is bonded in a single-bond geometry to one Os(2) atom. F(11) is bonded in a single-bond geometry to one Os(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Os(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.680
_cell_length_b   8.793
_cell_length_c   9.134
_cell_angle_alpha   90.613
_cell_angle_beta   90.500
_cell_angle_gamma   90.151
_symmetry_Int_Tables_number   1
_cell_volume   697.110
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  1.000  0.001  0.000  1.0
  Os  Os1  1  0.499  0.758  0.001  1.0
  Os  Os2  1  0.501  0.252  0.972  1.0
  Os  Os3  1  0.990  0.500  0.751  1.0
  Os  Os4  1  0.503  0.498  0.497  1.0
  Os  Os5  1  0.258  1.000  0.499  1.0
  Os  Os6  1  0.749  0.998  0.487  1.0
  Os  Os7  1  0.000  0.500  0.276  1.0
  O  O8  1  0.385  0.861  0.881  1.0
  O  O9  1  0.889  0.384  0.867  1.0
  O  O10  1  0.381  0.368  0.876  1.0
  O  O11  1  0.607  0.638  0.888  1.0
  O  O12  1  0.108  0.614  0.862  1.0
  O  O13  1  0.619  0.133  0.878  1.0
  O  O14  1  0.888  0.620  0.638  1.0
  O  O15  1  0.860  0.108  0.610  1.0
  O  O16  1  0.361  0.121  0.613  1.0
  O  O17  1  0.875  0.885  0.390  1.0
  O  O18  1  0.362  0.884  0.382  1.0
  O  O19  1  0.882  0.383  0.372  1.0
  O  O20  1  0.120  0.617  0.374  1.0
  O  O21  1  0.635  0.123  0.392  1.0
  O  O22  1  0.140  0.112  0.388  1.0
  O  O23  1  0.620  0.861  0.115  1.0
  F  F24  1  0.878  0.878  0.875  1.0
  F  F25  1  0.124  0.120  0.876  1.0
  F  F26  1  0.634  0.883  0.621  1.0
  F  F27  1  0.131  0.883  0.619  1.0
  F  F28  1  0.380  0.623  0.620  1.0
  F  F29  1  0.622  0.379  0.626  1.0
  F  F30  1  0.120  0.382  0.633  1.0
  F  F31  1  0.622  0.626  0.378  1.0
  F  F32  1  0.372  0.379  0.378  1.0
  F  F33  1  0.902  0.596  0.115  1.0
  F  F34  1  0.385  0.628  0.121  1.0
  F  F35  1  0.595  0.349  0.137  1.0
  F  F36  1  0.124  0.878  0.122  1.0
  F  F37  1  0.879  0.124  0.124  1.0
  F  F38  1  0.096  0.402  0.114  1.0
  F  F39  1  0.404  0.153  0.131  1.0
[/CIF]
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The structure described by OsF4(OsO3F)2Os(OF)2 is Silicon tetrafluoride-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two tetrafluoroosmium molecules, two Os(OF)2 clusters, and four OsO3F clusters. In each Os(OF)2 cluster, Os(3) is bonded in a tetrahedral geometry to one O(3), one O(6), one F(12), and one F(16) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Os(3) atom. In the second O site, O(6) is bonded in a single-bond geometry to one Os(3) atom. There are two inequivalent F sites. In the first F site, F(12) is bonded in a single-bond geometry to one Os(3) atom. In the second F site, F(16) is bonded in a single-bond geometry to one Os(3) atom. In each OsO3F cluster, Os(2) is bonded in a tetrahedral geometry to one O(1), one O(16), one O(4), and one F(11) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Os(2) atom. In the third O site, O(16) is bonded in a single-bond geometry to one Os(2) atom. F(11) is bonded in a single-bond geometry to one Os(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Os(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.680
_cell_length_b   8.793
_cell_length_c   9.134
_cell_angle_alpha   90.613
_cell_angle_beta   90.500
_cell_angle_gamma   90.151
_symmetry_Int_Tables_number   1
_cell_volume   697.110
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  1.000  0.001  0.000  1.0
  Os  Os1  1  0.499  0.758  0.001  1.0
  Os  Os2  1  0.501  0.252  0.972  1.0
  Os  Os3  1  0.990  0.500  0.751  1.0
  Os  Os4  1  0.503  0.498  0.497  1.0
  Os  Os5  1  0.258  1.000  0.499  1.0
  Os  Os6  1  0.749  0.998  0.487  1.0
  Os  Os7  1  0.000  0.500  0.276  1.0
  O  O8  1  0.385  0.861  0.881  1.0
  O  O9  1  0.889  0.384  0.867  1.0
  O  O10  1  0.381  0.368  0.876  1.0
  O  O11  1  0.607  0.638  0.888  1.0
  O  O12  1  0.108  0.614  0.862  1.0
  O  O13  1  0.619  0.133  0.878  1.0
  O  O14  1  0.888  0.620  0.638  1.0
  O  O15  1  0.860  0.108  0.610  1.0
  O  O16  1  0.361  0.121  0.613  1.0
  O  O17  1  0.875  0.885  0.390  1.0
  O  O18  1  0.362  0.884  0.382  1.0
  O  O19  1  0.882  0.383  0.372  1.0
  O  O20  1  0.120  0.617  0.374  1.0
  O  O21  1  0.635  0.123  0.392  1.0
  O  O22  1  0.140  0.112  0.388  1.0
  O  O23  1  0.620  0.861  0.115  1.0
  F  F24  1  0.878  0.878  0.875  1.0
  F  F25  1  0.124  0.120  0.876  1.0
  F  F26  1  0.634  0.883  0.621  1.0
  F  F27  1  0.131  0.883  0.619  1.0
  F  F28  1  0.380  0.623  0.620  1.0
  F  F29  1  0.622  0.379  0.626  1.0
  F  F30  1  0.120  0.382  0.633  1.0
  F  F31  1  0.622  0.626  0.378  1.0
  F  F32  1  0.372  0.379  0.378  1.0
  F  F33  1  0.902  0.596  0.115  1.0
  F  F34  1  0.385  0.628  0.121  1.0
  F  F35  1  0.595  0.349  0.137  1.0
  F  F36  1  0.124  0.878  0.122  1.0
  F  F37  1  0.879  0.124  0.124  1.0
  F  F38  1  0.096  0.402  0.114  1.0
  F  F39  1  0.404  0.153  0.131  1.0
[/CIF]
.