The material described by K2Pd(CN)4 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 5-coordinate geometry to two equivalent N(2) and three equivalent N(1) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent C(1) and two equivalent C(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Pd(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Pd(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to three equivalent K(1) and one C(1) atom. In the second N site, N(2) is bonded in a 1-coordinate geometry to two equivalent K(1) and one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2Pd(CN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.852
_cell_length_b   4.443
_cell_length_c   13.742
_cell_angle_alpha   88.921
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   479.267
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.956  0.285  0.344  1.0
  K  K1  1  0.456  0.715  0.156  1.0
  K  K2  1  0.544  0.285  0.844  1.0
  K  K3  1  0.044  0.715  0.656  1.0
  Pd  Pd4  1  0.000  0.000  0.000  1.0
  Pd  Pd5  1  0.500  0.000  0.500  1.0
  C  C6  1  0.123  0.158  0.115  1.0
  C  C7  1  0.623  0.842  0.385  1.0
  C  C8  1  0.279  0.850  0.449  1.0
  C  C9  1  0.779  0.150  0.051  1.0
  C  C10  1  0.377  0.158  0.615  1.0
  C  C11  1  0.877  0.842  0.885  1.0
  C  C12  1  0.221  0.850  0.949  1.0
  C  C13  1  0.721  0.150  0.551  1.0
  N  N14  1  0.199  0.246  0.183  1.0
  N  N15  1  0.699  0.754  0.317  1.0
  N  N16  1  0.354  0.765  0.921  1.0
  N  N17  1  0.854  0.235  0.579  1.0
  N  N18  1  0.646  0.235  0.079  1.0
  N  N19  1  0.146  0.765  0.421  1.0
  N  N20  1  0.301  0.246  0.683  1.0
  N  N21  1  0.801  0.754  0.817  1.0
[/CIF]
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The material described by K2Pd(CN)4 crystallizes in the monoclinic P2_1/c space group. K(1) is bonded in a 5-coordinate geometry to two equivalent N(2) and three equivalent N(1) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent C(1) and two equivalent C(2) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one Pd(1) and one N(1) atom. In the second C site, C(2) is bonded in a distorted linear geometry to one Pd(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to three equivalent K(1) and one C(1) atom. In the second N site, N(2) is bonded in a 1-coordinate geometry to two equivalent K(1) and one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2Pd(CN)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.852
_cell_length_b   4.443
_cell_length_c   13.742
_cell_angle_alpha   88.921
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   479.267
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.956  0.285  0.344  1.0
  K  K1  1  0.456  0.715  0.156  1.0
  K  K2  1  0.544  0.285  0.844  1.0
  K  K3  1  0.044  0.715  0.656  1.0
  Pd  Pd4  1  0.000  0.000  0.000  1.0
  Pd  Pd5  1  0.500  0.000  0.500  1.0
  C  C6  1  0.123  0.158  0.115  1.0
  C  C7  1  0.623  0.842  0.385  1.0
  C  C8  1  0.279  0.850  0.449  1.0
  C  C9  1  0.779  0.150  0.051  1.0
  C  C10  1  0.377  0.158  0.615  1.0
  C  C11  1  0.877  0.842  0.885  1.0
  C  C12  1  0.221  0.850  0.949  1.0
  C  C13  1  0.721  0.150  0.551  1.0
  N  N14  1  0.199  0.246  0.183  1.0
  N  N15  1  0.699  0.754  0.317  1.0
  N  N16  1  0.354  0.765  0.921  1.0
  N  N17  1  0.854  0.235  0.579  1.0
  N  N18  1  0.646  0.235  0.079  1.0
  N  N19  1  0.146  0.765  0.421  1.0
  N  N20  1  0.301  0.246  0.683  1.0
  N  N21  1  0.801  0.754  0.817  1.0
[/CIF]
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