The compound described by AgGeO3 crystallizes in the orthorhombic Pmma space group. Ag(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. Ge(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form a mixture of edge and corner-sharing GeO6 octahedra. The corner-sharing octahedral tilt angles are 32°. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Ag(1) and two equivalent Ge(1) atoms to form a mixture of edge and corner-sharing OAg2Ge2 tetrahedra. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Ag(1) and two equivalent Ge(1) atoms. is represented by the CIF file [CIF]
data_AgGeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.993
_cell_length_b   5.325
_cell_length_c   7.139
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   113.785
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.022  0.750  1.0
  Ag  Ag1  1  0.500  0.978  0.250  1.0
  Ge  Ge2  1  0.000  0.500  0.000  1.0
  Ge  Ge3  1  0.000  0.500  0.500  1.0
  O  O4  1  0.500  0.260  0.030  1.0
  O  O5  1  0.500  0.260  0.470  1.0
  O  O6  1  0.000  0.404  0.750  1.0
  O  O7  1  0.000  0.596  0.250  1.0
  O  O8  1  0.500  0.740  0.970  1.0
  O  O9  1  0.500  0.740  0.530  1.0
[/CIF]
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The compound described by AgGeO3 crystallizes in the orthorhombic Pmma space group. Ag(1) is bonded in a 6-coordinate geometry to two equivalent O(2) and four equivalent O(1) atoms. Ge(1) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form a mixture of edge and corner-sharing GeO6 octahedra. The corner-sharing octahedral tilt angles are 32°. There are two inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Ag(1) and two equivalent Ge(1) atoms to form a mixture of edge and corner-sharing OAg2Ge2 tetrahedra. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Ag(1) and two equivalent Ge(1) atoms. is represented by the CIF file [CIF]
data_AgGeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.993
_cell_length_b   5.325
_cell_length_c   7.139
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   113.785
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.500  0.022  0.750  1.0
  Ag  Ag1  1  0.500  0.978  0.250  1.0
  Ge  Ge2  1  0.000  0.500  0.000  1.0
  Ge  Ge3  1  0.000  0.500  0.500  1.0
  O  O4  1  0.500  0.260  0.030  1.0
  O  O5  1  0.500  0.260  0.470  1.0
  O  O6  1  0.000  0.404  0.750  1.0
  O  O7  1  0.000  0.596  0.250  1.0
  O  O8  1  0.500  0.740  0.970  1.0
  O  O9  1  0.500  0.740  0.530  1.0
[/CIF]
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