The crystal structure described by PtH8(N4O)2 is beta Sn structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two PtH8(N4O)2 clusters. Pt(1) is bonded in an octahedral geometry to one N(1), one N(4), one N(7), one N(8), one O(1), and one O(2) atom. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Pt(1) and one N(5) atom. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom. In the seventh N site, N(7) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(2), and one H(3) atom. In the eighth N site, N(8) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(4), one H(5), and one H(6) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(1) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Pt(1) and one H(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Pt(1) and one H(8) atom. is represented by the CIF file [CIF]
data_H8Pt(N4O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.633
_cell_length_b   8.292
_cell_length_c   8.462
_cell_angle_alpha   82.925
_cell_angle_beta   66.184
_cell_angle_gamma   68.116
_symmetry_Int_Tables_number   1
_cell_volume   394.877
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.942  0.642  0.181  1.0
  H  H1  1  0.058  0.358  0.819  1.0
  H  H2  1  0.811  0.649  0.397  1.0
  H  H3  1  0.189  0.351  0.603  1.0
  H  H4  1  0.098  0.589  0.309  1.0
  H  H5  1  0.902  0.411  0.691  1.0
  H  H6  1  0.668  0.316  0.173  1.0
  H  H7  1  0.332  0.684  0.827  1.0
  H  H8  1  0.530  0.482  0.320  1.0
  H  H9  1  0.470  0.518  0.680  1.0
  H  H10  1  0.714  0.506  0.116  1.0
  H  H11  1  0.286  0.494  0.884  1.0
  H  H12  1  0.343  0.241  0.011  1.0
  H  H13  1  0.657  0.759  0.989  1.0
  H  H14  1  0.708  0.253  0.561  1.0
  H  H15  1  0.292  0.747  0.439  1.0
  Pt  Pt16  1  0.976  0.327  0.281  1.0
  Pt  Pt17  1  0.024  0.673  0.719  1.0
  N  N18  1  0.972  0.080  0.281  1.0
  N  N19  1  0.028  0.920  0.719  1.0
  N  N20  1  0.116  0.976  0.165  1.0
  N  N21  1  0.884  0.024  0.835  1.0
  N  N22  1  0.247  0.864  0.061  1.0
  N  N23  1  0.753  0.136  0.939  1.0
  N  N24  1  0.272  0.239  0.343  1.0
  N  N25  1  0.728  0.761  0.657  1.0
  N  N26  1  0.376  0.082  0.337  1.0
  N  N27  1  0.624  0.918  0.663  1.0
  N  N28  1  0.485  0.935  0.332  1.0
  N  N29  1  0.515  0.065  0.668  1.0
  N  N30  1  0.956  0.581  0.292  1.0
  N  N31  1  0.044  0.419  0.708  1.0
  N  N32  1  0.685  0.419  0.215  1.0
  N  N33  1  0.315  0.581  0.785  1.0
  O  O34  1  0.184  0.320  0.025  1.0
  O  O35  1  0.816  0.680  0.975  1.0
  O  O36  1  0.751  0.357  0.537  1.0
  O  O37  1  0.249  0.643  0.463  1.0
[/CIF]
.
The crystal structure described by PtH8(N4O)2 is beta Sn structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two PtH8(N4O)2 clusters. Pt(1) is bonded in an octahedral geometry to one N(1), one N(4), one N(7), one N(8), one O(1), and one O(2) atom. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Pt(1) and one N(2) atom. In the second N site, N(2) is bonded in a linear geometry to one N(1) and one N(3) atom. In the third N site, N(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one Pt(1) and one N(5) atom. In the fifth N site, N(5) is bonded in a linear geometry to one N(4) and one N(6) atom. In the sixth N site, N(6) is bonded in a single-bond geometry to one N(5) atom. In the seventh N site, N(7) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(2), and one H(3) atom. In the eighth N site, N(8) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(4), one H(5), and one H(6) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(1) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Pt(1) and one H(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Pt(1) and one H(8) atom. is represented by the CIF file [CIF]
data_H8Pt(N4O)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.633
_cell_length_b   8.292
_cell_length_c   8.462
_cell_angle_alpha   82.925
_cell_angle_beta   66.184
_cell_angle_gamma   68.116
_symmetry_Int_Tables_number   1
_cell_volume   394.877
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.942  0.642  0.181  1.0
  H  H1  1  0.058  0.358  0.819  1.0
  H  H2  1  0.811  0.649  0.397  1.0
  H  H3  1  0.189  0.351  0.603  1.0
  H  H4  1  0.098  0.589  0.309  1.0
  H  H5  1  0.902  0.411  0.691  1.0
  H  H6  1  0.668  0.316  0.173  1.0
  H  H7  1  0.332  0.684  0.827  1.0
  H  H8  1  0.530  0.482  0.320  1.0
  H  H9  1  0.470  0.518  0.680  1.0
  H  H10  1  0.714  0.506  0.116  1.0
  H  H11  1  0.286  0.494  0.884  1.0
  H  H12  1  0.343  0.241  0.011  1.0
  H  H13  1  0.657  0.759  0.989  1.0
  H  H14  1  0.708  0.253  0.561  1.0
  H  H15  1  0.292  0.747  0.439  1.0
  Pt  Pt16  1  0.976  0.327  0.281  1.0
  Pt  Pt17  1  0.024  0.673  0.719  1.0
  N  N18  1  0.972  0.080  0.281  1.0
  N  N19  1  0.028  0.920  0.719  1.0
  N  N20  1  0.116  0.976  0.165  1.0
  N  N21  1  0.884  0.024  0.835  1.0
  N  N22  1  0.247  0.864  0.061  1.0
  N  N23  1  0.753  0.136  0.939  1.0
  N  N24  1  0.272  0.239  0.343  1.0
  N  N25  1  0.728  0.761  0.657  1.0
  N  N26  1  0.376  0.082  0.337  1.0
  N  N27  1  0.624  0.918  0.663  1.0
  N  N28  1  0.485  0.935  0.332  1.0
  N  N29  1  0.515  0.065  0.668  1.0
  N  N30  1  0.956  0.581  0.292  1.0
  N  N31  1  0.044  0.419  0.708  1.0
  N  N32  1  0.685  0.419  0.215  1.0
  N  N33  1  0.315  0.581  0.785  1.0
  O  O34  1  0.184  0.320  0.025  1.0
  O  O35  1  0.816  0.680  0.975  1.0
  O  O36  1  0.751  0.357  0.537  1.0
  O  O37  1  0.249  0.643  0.463  1.0
[/CIF]
.