The structure described by (ZnP(HO)5)4O2 crystallizes in the triclinic P-1 space group. The structure consists of two water atoms inside a ZnP(HO)5 framework. In the ZnP(HO)5 framework, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to two equivalent O(1), two equivalent O(7), and two equivalent O(8) atoms to form ZnO6 octahedra that share corners with two equivalent P(1)HO3 tetrahedra. In the second Zn site, Zn(2) is bonded to two equivalent O(10), two equivalent O(4), and two equivalent O(9) atoms to form ZnO6 octahedra that share corners with two equivalent P(2)HO3 tetrahedra. In the third Zn site, Zn(3) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form ZnO4 tetrahedra that share corners with two equivalent P(1)HO3 tetrahedra and corners with two equivalent P(2)HO3 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one H(1), one O(1), one O(2), and one O(3) atom to form distorted PHO3 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra and corners with two equivalent Zn(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 31°. In the second P site, P(2) is bonded to one H(2), one O(4), one O(5), and one O(6) atom to form distorted PHO3 tetrahedra that share  a cornercorner with one Zn(2)O6 octahedra and corners with two equivalent Zn(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 35°. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one P(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one P(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(5) and one O(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(10) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(10) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Zn(2) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Zn(3), one P(2), and one H(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one H(3), and one H(4) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one H(5), and one H(6) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one H(7), and one H(8) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Zn(2), one H(10), and one H(9) atom. is represented by the CIF card [CIF]
data_Zn2P2H10O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.660
_cell_length_b   7.843
_cell_length_c   9.551
_cell_angle_alpha   89.333
_cell_angle_beta   88.757
_cell_angle_gamma   87.925
_symmetry_Int_Tables_number   1
_cell_volume   573.265
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.000  0.500  1.0
  Zn  Zn1  1  0.000  0.500  0.000  1.0
  Zn  Zn2  1  0.500  0.499  0.251  1.0
  Zn  Zn3  1  0.500  0.501  0.749  1.0
  P  P4  1  0.726  0.615  0.487  1.0
  P  P5  1  0.274  0.385  0.513  1.0
  P  P6  1  0.370  0.716  0.013  1.0
  P  P7  1  0.630  0.284  0.987  1.0
  H  H8  1  0.899  0.671  0.472  1.0
  H  H9  1  0.101  0.329  0.528  1.0
  H  H10  1  0.288  0.880  0.020  1.0
  H  H11  1  0.712  0.120  0.980  1.0
  H  H12  1  0.528  0.887  0.775  1.0
  H  H13  1  0.472  0.113  0.225  1.0
  H  H14  1  0.534  0.090  0.764  1.0
  H  H15  1  0.466  0.910  0.236  1.0
  H  H16  1  0.838  0.073  0.396  1.0
  H  H17  1  0.162  0.927  0.604  1.0
  H  H18  1  0.728  0.242  0.436  1.0
  H  H19  1  0.272  0.758  0.564  1.0
  H  H20  1  0.899  0.420  0.264  1.0
  H  H21  1  0.101  0.580  0.736  1.0
  H  H22  1  0.107  0.409  0.255  1.0
  H  H23  1  0.893  0.591  0.745  1.0
  H  H24  1  0.747  0.732  0.102  1.0
  H  H25  1  0.253  0.268  0.898  1.0
  H  H26  1  0.931  0.813  0.141  1.0
  H  H27  1  0.069  0.187  0.859  1.0
  O  O28  1  0.597  0.761  0.455  1.0
  O  O29  1  0.403  0.239  0.545  1.0
  O  O30  1  0.715  0.542  0.637  1.0
  O  O31  1  0.285  0.458  0.363  1.0
  O  O32  1  0.710  0.472  0.375  1.0
  O  O33  1  0.290  0.528  0.625  1.0
  O  O34  1  0.239  0.579  0.041  1.0
  O  O35  1  0.761  0.421  0.959  1.0
  O  O36  1  0.460  0.709  0.867  1.0
  O  O37  1  0.540  0.291  0.133  1.0
  O  O38  1  0.507  0.711  0.133  1.0
  O  O39  1  0.493  0.289  0.867  1.0
  O  O40  1  0.568  0.983  0.715  1.0
  O  O41  1  0.432  0.017  0.285  1.0
  O  O42  1  0.747  0.120  0.461  1.0
  O  O43  1  0.253  0.880  0.539  1.0
  O  O44  1  0.999  0.380  0.204  1.0
  O  O45  1  0.001  0.620  0.796  1.0
  O  O46  1  0.875  0.728  0.084  1.0
  O  O47  1  0.125  0.272  0.916  1.0
  O  O48  1  0.993  0.984  0.262  1.0
  O  O49  1  0.007  0.016  0.738  1.0
[/CIF]
.
The structure described by (ZnP(HO)5)4O2 crystallizes in the triclinic P-1 space group. The structure consists of two water atoms inside a ZnP(HO)5 framework. In the ZnP(HO)5 framework, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to two equivalent O(1), two equivalent O(7), and two equivalent O(8) atoms to form ZnO6 octahedra that share corners with two equivalent P(1)HO3 tetrahedra. In the second Zn site, Zn(2) is bonded to two equivalent O(10), two equivalent O(4), and two equivalent O(9) atoms to form ZnO6 octahedra that share corners with two equivalent P(2)HO3 tetrahedra. In the third Zn site, Zn(3) is bonded to one O(2), one O(3), one O(5), and one O(6) atom to form ZnO4 tetrahedra that share corners with two equivalent P(1)HO3 tetrahedra and corners with two equivalent P(2)HO3 tetrahedra. There are two inequivalent P sites. In the first P site, P(1) is bonded to one H(1), one O(1), one O(2), and one O(3) atom to form distorted PHO3 tetrahedra that share  a cornercorner with one Zn(1)O6 octahedra and corners with two equivalent Zn(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 31°. In the second P site, P(2) is bonded to one H(2), one O(4), one O(5), and one O(6) atom to form distorted PHO3 tetrahedra that share  a cornercorner with one Zn(2)O6 octahedra and corners with two equivalent Zn(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 35°. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one P(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one P(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(5) and one O(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one O(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one O(10) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one O(10) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Zn(2) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Zn(3), one P(2), and one H(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one H(3), and one H(4) atom. In the eighth O site, O(8) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one H(5), and one H(6) atom. In the ninth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one H(7), and one H(8) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Zn(2), one H(10), and one H(9) atom. is represented by the CIF card [CIF]
data_Zn2P2H10O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.660
_cell_length_b   7.843
_cell_length_c   9.551
_cell_angle_alpha   89.333
_cell_angle_beta   88.757
_cell_angle_gamma   87.925
_symmetry_Int_Tables_number   1
_cell_volume   573.265
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.000  0.500  1.0
  Zn  Zn1  1  0.000  0.500  0.000  1.0
  Zn  Zn2  1  0.500  0.499  0.251  1.0
  Zn  Zn3  1  0.500  0.501  0.749  1.0
  P  P4  1  0.726  0.615  0.487  1.0
  P  P5  1  0.274  0.385  0.513  1.0
  P  P6  1  0.370  0.716  0.013  1.0
  P  P7  1  0.630  0.284  0.987  1.0
  H  H8  1  0.899  0.671  0.472  1.0
  H  H9  1  0.101  0.329  0.528  1.0
  H  H10  1  0.288  0.880  0.020  1.0
  H  H11  1  0.712  0.120  0.980  1.0
  H  H12  1  0.528  0.887  0.775  1.0
  H  H13  1  0.472  0.113  0.225  1.0
  H  H14  1  0.534  0.090  0.764  1.0
  H  H15  1  0.466  0.910  0.236  1.0
  H  H16  1  0.838  0.073  0.396  1.0
  H  H17  1  0.162  0.927  0.604  1.0
  H  H18  1  0.728  0.242  0.436  1.0
  H  H19  1  0.272  0.758  0.564  1.0
  H  H20  1  0.899  0.420  0.264  1.0
  H  H21  1  0.101  0.580  0.736  1.0
  H  H22  1  0.107  0.409  0.255  1.0
  H  H23  1  0.893  0.591  0.745  1.0
  H  H24  1  0.747  0.732  0.102  1.0
  H  H25  1  0.253  0.268  0.898  1.0
  H  H26  1  0.931  0.813  0.141  1.0
  H  H27  1  0.069  0.187  0.859  1.0
  O  O28  1  0.597  0.761  0.455  1.0
  O  O29  1  0.403  0.239  0.545  1.0
  O  O30  1  0.715  0.542  0.637  1.0
  O  O31  1  0.285  0.458  0.363  1.0
  O  O32  1  0.710  0.472  0.375  1.0
  O  O33  1  0.290  0.528  0.625  1.0
  O  O34  1  0.239  0.579  0.041  1.0
  O  O35  1  0.761  0.421  0.959  1.0
  O  O36  1  0.460  0.709  0.867  1.0
  O  O37  1  0.540  0.291  0.133  1.0
  O  O38  1  0.507  0.711  0.133  1.0
  O  O39  1  0.493  0.289  0.867  1.0
  O  O40  1  0.568  0.983  0.715  1.0
  O  O41  1  0.432  0.017  0.285  1.0
  O  O42  1  0.747  0.120  0.461  1.0
  O  O43  1  0.253  0.880  0.539  1.0
  O  O44  1  0.999  0.380  0.204  1.0
  O  O45  1  0.001  0.620  0.796  1.0
  O  O46  1  0.875  0.728  0.084  1.0
  O  O47  1  0.125  0.272  0.916  1.0
  O  O48  1  0.993  0.984  0.262  1.0
  O  O49  1  0.007  0.016  0.738  1.0
[/CIF]
.