The compound described by MoO4PdN4H12 is Indium-derived structured and crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of four molybdenum;tetrahydrate molecules and four PdN4H12 clusters. In each PdN4H12 cluster, Pd(1) is bonded in a rectangular see-saw-like geometry to four equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one H(1), and two equivalent H(2) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MoH12Pd(NO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.535
_cell_length_b   9.535
_cell_length_c   9.535
_cell_angle_alpha   133.330
_cell_angle_beta   133.330
_cell_angle_gamma   68.136
_symmetry_Int_Tables_number   1
_cell_volume   450.614
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.750  0.250  0.500  1.0
  Mo  Mo1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.182  0.378  0.196  1.0
  H  H3  1  0.128  0.432  0.696  1.0
  H  H4  1  0.737  0.432  0.304  1.0
  H  H5  1  0.182  0.987  0.804  1.0
  H  H6  1  0.568  0.872  0.304  1.0
  H  H7  1  0.622  0.818  0.804  1.0
  H  H8  1  0.013  0.818  0.196  1.0
  H  H9  1  0.568  0.263  0.696  1.0
  H  H10  1  0.384  0.443  0.278  1.0
  H  H11  1  0.164  0.443  0.059  1.0
  H  H12  1  0.193  0.634  0.778  1.0
  H  H13  1  0.856  0.634  0.441  1.0
  H  H14  1  0.384  0.106  0.941  1.0
  H  H15  1  0.164  0.106  0.722  1.0
  H  H16  1  0.193  0.414  0.559  1.0
  H  H17  1  0.856  0.414  0.222  1.0
  H  H18  1  0.366  0.807  0.222  1.0
  H  H19  1  0.586  0.807  0.441  1.0
  H  H20  1  0.557  0.616  0.722  1.0
  H  H21  1  0.894  0.616  0.059  1.0
  H  H22  1  0.366  0.144  0.559  1.0
  H  H23  1  0.586  0.144  0.778  1.0
  H  H24  1  0.557  0.836  0.941  1.0
  H  H25  1  0.894  0.836  0.278  1.0
  Pd  Pd26  1  0.250  0.750  0.500  1.0
  Pd  Pd27  1  0.500  0.500  0.000  1.0
  N  N28  1  0.247  0.473  0.226  1.0
  N  N29  1  0.223  0.497  0.726  1.0
  N  N30  1  0.770  0.497  0.274  1.0
  N  N31  1  0.247  0.020  0.774  1.0
  N  N32  1  0.503  0.777  0.274  1.0
  N  N33  1  0.527  0.753  0.774  1.0
  N  N34  1  0.980  0.753  0.226  1.0
  N  N35  1  0.503  0.230  0.726  1.0
  O  O36  1  0.617  0.314  0.303  1.0
  O  O37  1  0.011  0.314  0.697  1.0
  O  O38  1  0.064  0.867  0.803  1.0
  O  O39  1  0.064  0.261  0.197  1.0
  O  O40  1  0.133  0.936  0.197  1.0
  O  O41  1  0.739  0.936  0.803  1.0
  O  O42  1  0.686  0.383  0.697  1.0
  O  O43  1  0.686  0.989  0.303  1.0
[/CIF]
.
The compound described by MoO4PdN4H12 is Indium-derived structured and crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of four molybdenum;tetrahydrate molecules and four PdN4H12 clusters. In each PdN4H12 cluster, Pd(1) is bonded in a rectangular see-saw-like geometry to four equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pd(1), one H(1), and two equivalent H(2) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MoH12Pd(NO)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.535
_cell_length_b   9.535
_cell_length_c   9.535
_cell_angle_alpha   133.330
_cell_angle_beta   133.330
_cell_angle_gamma   68.136
_symmetry_Int_Tables_number   1
_cell_volume   450.614
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.750  0.250  0.500  1.0
  Mo  Mo1  1  0.000  0.000  0.000  1.0
  H  H2  1  0.182  0.378  0.196  1.0
  H  H3  1  0.128  0.432  0.696  1.0
  H  H4  1  0.737  0.432  0.304  1.0
  H  H5  1  0.182  0.987  0.804  1.0
  H  H6  1  0.568  0.872  0.304  1.0
  H  H7  1  0.622  0.818  0.804  1.0
  H  H8  1  0.013  0.818  0.196  1.0
  H  H9  1  0.568  0.263  0.696  1.0
  H  H10  1  0.384  0.443  0.278  1.0
  H  H11  1  0.164  0.443  0.059  1.0
  H  H12  1  0.193  0.634  0.778  1.0
  H  H13  1  0.856  0.634  0.441  1.0
  H  H14  1  0.384  0.106  0.941  1.0
  H  H15  1  0.164  0.106  0.722  1.0
  H  H16  1  0.193  0.414  0.559  1.0
  H  H17  1  0.856  0.414  0.222  1.0
  H  H18  1  0.366  0.807  0.222  1.0
  H  H19  1  0.586  0.807  0.441  1.0
  H  H20  1  0.557  0.616  0.722  1.0
  H  H21  1  0.894  0.616  0.059  1.0
  H  H22  1  0.366  0.144  0.559  1.0
  H  H23  1  0.586  0.144  0.778  1.0
  H  H24  1  0.557  0.836  0.941  1.0
  H  H25  1  0.894  0.836  0.278  1.0
  Pd  Pd26  1  0.250  0.750  0.500  1.0
  Pd  Pd27  1  0.500  0.500  0.000  1.0
  N  N28  1  0.247  0.473  0.226  1.0
  N  N29  1  0.223  0.497  0.726  1.0
  N  N30  1  0.770  0.497  0.274  1.0
  N  N31  1  0.247  0.020  0.774  1.0
  N  N32  1  0.503  0.777  0.274  1.0
  N  N33  1  0.527  0.753  0.774  1.0
  N  N34  1  0.980  0.753  0.226  1.0
  N  N35  1  0.503  0.230  0.726  1.0
  O  O36  1  0.617  0.314  0.303  1.0
  O  O37  1  0.011  0.314  0.697  1.0
  O  O38  1  0.064  0.867  0.803  1.0
  O  O39  1  0.064  0.261  0.197  1.0
  O  O40  1  0.133  0.936  0.197  1.0
  O  O41  1  0.739  0.936  0.803  1.0
  O  O42  1  0.686  0.383  0.697  1.0
  O  O43  1  0.686  0.989  0.303  1.0
[/CIF]
.