The compound described by SnO2 is Rutile-like structured and crystallizes in the tetragonal I4/m space group. Sn(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to three equivalent Sn(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Sn(1) atoms. is represented by the CIF file [CIF]
data_SnO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.769
_cell_length_b   7.769
_cell_length_c   7.769
_cell_angle_alpha   92.480
_cell_angle_beta   92.480
_cell_angle_gamma   155.985
_symmetry_Int_Tables_number   1
_cell_volume   186.658
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.649  0.169  0.818  1.0
  Sn  Sn1  1  0.169  0.351  0.520  1.0
  Sn  Sn2  1  0.831  0.649  0.480  1.0
  Sn  Sn3  1  0.351  0.831  0.182  1.0
  O  O4  1  0.839  0.457  0.296  1.0
  O  O5  1  0.457  0.161  0.618  1.0
  O  O6  1  0.543  0.839  0.382  1.0
  O  O7  1  0.161  0.543  0.704  1.0
  O  O8  1  0.155  0.794  0.949  1.0
  O  O9  1  0.794  0.845  0.639  1.0
  O  O10  1  0.845  0.206  0.051  1.0
  O  O11  1  0.206  0.155  0.361  1.0
[/CIF]
.
The compound described by SnO2 is Rutile-like structured and crystallizes in the tetragonal I4/m space group. Sn(1) is bonded to three equivalent O(1) and three equivalent O(2) atoms to form a mixture of corner and edge-sharing SnO6 octahedra. The corner-sharing octahedral tilt angles are 50°. There are two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to three equivalent Sn(1) atoms. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Sn(1) atoms. is represented by the CIF file [CIF]
data_SnO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.769
_cell_length_b   7.769
_cell_length_c   7.769
_cell_angle_alpha   92.480
_cell_angle_beta   92.480
_cell_angle_gamma   155.985
_symmetry_Int_Tables_number   1
_cell_volume   186.658
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.649  0.169  0.818  1.0
  Sn  Sn1  1  0.169  0.351  0.520  1.0
  Sn  Sn2  1  0.831  0.649  0.480  1.0
  Sn  Sn3  1  0.351  0.831  0.182  1.0
  O  O4  1  0.839  0.457  0.296  1.0
  O  O5  1  0.457  0.161  0.618  1.0
  O  O6  1  0.543  0.839  0.382  1.0
  O  O7  1  0.161  0.543  0.704  1.0
  O  O8  1  0.155  0.794  0.949  1.0
  O  O9  1  0.794  0.845  0.639  1.0
  O  O10  1  0.845  0.206  0.051  1.0
  O  O11  1  0.206  0.155  0.361  1.0
[/CIF]
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