The material described by Li2VGaO4 is alpha Po-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Ga(1)O6 octahedra,  a cornercorner with one Ga(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ga(1)O6 octahedra,  an edgeedge with one Ga(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Ga(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. In the second Li site, Li(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(4), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Ga(1)O6 octahedra,  a cornercorner with one Ga(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ga(1)O6 octahedra,  an edgeedge with one Ga(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Ga(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. In the third Li site, Li(3) is bonded to one O(12), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ga(3)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Ga(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Ga(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. In the fourth Li site, Li(4) is bonded to one O(10), one O(11), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Ga(2)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Ga(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Ga(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. In the fifth Li site, Li(5) is bonded to one O(1), one O(11), one O(2), one O(4), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Ga(1)O6 octahedra, corners with two equivalent Ga(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Ga(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-5°. In the sixth Li site, Li(6) is bonded to one O(1), one O(10), one O(12), one O(2), one O(3), and one O(5) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent Ga(1)O6 octahedra, corners with two equivalent Ga(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Ga(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-5°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(11), one O(12), one O(5), one O(6), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Ga(2)O6 octahedra,  an edgeedge with one Ga(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), one O(6), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Ga(1)O6 octahedra,  an edgeedge with one Ga(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Ga(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. In the third V site, V(3) is bonded to one O(1), one O(10), one O(2), one O(4), one O(5), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Ga(1)O6 octahedra,  an edgeedge with one Ga(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Ga(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(10), one O(11), one O(12), one O(7), one O(8), and one O(9) atom to form GaO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Ga(2)O6 octahedra,  an edgeedge with one Ga(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. In the second Ga site, Ga(2) is bonded to one O(1), one O(11), one O(3), one O(4), one O(6), and one O(8) atom to form GaO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Ga(1)O6 octahedra,  an edgeedge with one Ga(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. In the third Ga site, Ga(3) is bonded to one O(12), one O(2), one O(3), one O(4), one O(5), and one O(7) atom to form GaO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Ga(1)O6 octahedra,  an edgeedge with one Ga(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(5), one Li(6), one V(2), one V(3), and one Ga(2) atom to form OLi3V2Ga octahedra that share  a cornercorner with one O(10)Li3V2Ga octahedra,  a cornercorner with one O(6)Li3V2Ga octahedra, corners with two equivalent O(12)Li3VGa2 octahedra, corners with two equivalent O(8)Li3VGa2 octahedra,  an edgeedge with one O(10)Li3V2Ga octahedra,  an edgeedge with one O(5)Li3V2Ga octahedra,  an edgeedge with one O(6)Li3V2Ga octahedra,  an edgeedge with one O(9)Li3V2Ga octahedra,  an edgeedge with one O(11)Li3VGa2 octahedra,  an edgeedge with one O(7)Li3VGa2 octahedra, edges with two equivalent O(2)Li3V2Ga octahedra, edges with two equivalent O(3)Li3VGa2 octahedra, and edges with two equivalent O(4)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the second O site, O(2) is bonded to one Li(1), one Li(5), one Li(6), one V(2), one V(3), and one Ga(3) atom to form OLi3V2Ga octahedra that share  a cornercorner with one O(5)Li3V2Ga octahedra,  a cornercorner with one O(9)Li3V2Ga octahedra, corners with two equivalent O(11)Li3VGa2 octahedra, corners with two equivalent O(7)Li3VGa2 octahedra,  an edgeedge with one O(10)Li3V2Ga octahedra,  an edgeedge with one O(5)Li3V2Ga octahedra,  an edgeedge with one O(6)Li3V2Ga octahedra,  an edgeedge with one O(9)Li3V2Ga octahedra,  an edgeedge with one O(12)Li3VGa2 octahedra,  an edgeedge with one O(8)Li3VGa2 octahedra, edges with two equivalent O(1)Li3V2Ga octahedra, edges with two equivalent O(3)Li3VGa2 octahedra, and edges with two equivalent O(4)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(6), one V(2), one Ga(2), and one Ga(3) atom to form OLi3VGa2 octahedra that share  a cornercorner with one O(12)Li3VGa2 octahedra,  a cornercorner with one O(8)Li3VGa2 octahedra, corners with two equivalent O(10)Li3V2Ga octahedra, corners with two equivalent O(6)Li3V2Ga octahedra,  an edgeedge with one O(5)Li3V2Ga octahedra,  an edgeedge with one O(9)Li3V2Ga octahedra,  an edgeedge with one O(11)Li3VGa2 octahedra,  an edgeedge with one O(12)Li3VGa2 octahedra,  an edgeedge with one O(7)Li3VGa2 octahedra,  an edgeedge with one O(8)Li3VGa2 octahedra, edges with two equivalent O(1)Li3V2Ga octahedra, edges with two equivalent O(2)Li3V2Ga octahedra, and edges with two equivalent O(4)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(5), one V(3), one Ga(2), and one Ga(3) atom to form OLi3VGa2 octahedra that share  a cornercorner with one O(11)Li3VGa2 octahedra,  a cornercorner with one O(7)Li3VGa2 octahedra, corners with two equivalent O(5)Li3V2Ga octahedra, corners with two equivalent O(9)Li3V2Ga octahedra,  an edgeedge with one O(10)Li3V2Ga octahedra,  an edgeedge with one O(6)Li3V2Ga octahedra,  an edgeedge with one O(11)Li3VGa2 octahedra,  an edgeedge with one O(12)Li3VGa2 octahedra,  an edgeedge with one O(7)Li3VGa2 octahedra,  an edgeedge with one O(8)Li3VGa2 octahedra, edges with two equivalent O(1)Li3V2Ga octahedra, edges with two equivalent O(2)Li3V2Ga octahedra, and edges with two equivalent O(3)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the fifth O site, O(5) is bonded to one Li(3), one Li(4), one Li(6), one V(1), one V(3), and one Ga(3) atom to form OLi3V2Ga octahedra that share  a cornercorner with one O(2)Li3V2Ga octahedra,  a cornercorner with one O(6)Li3V2Ga octahedra, corners with two equivalent O(4)Li3VGa2 octahedra, corners with two equivalent O(8)Li3VGa2 octahedra,  an edgeedge with one O(1)Li3V2Ga octahedra,  an edgeedge with one O(2)Li3V2Ga octahedra,  an edgeedge with one O(6)Li3V2Ga octahedra,  an edgeedge with one O(9)Li3V2Ga octahedra,  an edgeedge with one O(11)Li3VGa2 octahedra,  an edgeedge with one O(3)Li3VGa2 octahedra, edges with two equivalent O(10)Li3V2Ga octahedra, edges with two equivalent O(12)Li3VGa2 octahedra, and edges with two equivalent O(7)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the sixth O site, O(6) is bonded to one Li(3), one Li(4), one Li(5), one V(1), one V(2), and one Ga(2) atom to form OLi3V2Ga octahedra that share  a cornercorner with one O(1)Li3V2Ga octahedra,  a cornercorner with one O(5)Li3V2Ga octahedra, corners with two equivalent O(3)Li3VGa2 octahedra, corners with two equivalent O(7)Li3VGa2 octahedra,  an edgeedge with one O(1)Li3V2Ga octahedra,  an edgeedge with one O(10)Li3V2Ga octahedra,  an edgeedge with one O(2)Li3V2Ga octahedra,  an edgeedge with one O(5)Li3V2Ga octahedra,  an edgeedge with one O(12)Li3VGa2 octahedra,  an edgeedge with one O(4)Li3VGa2 octahedra, edges with two equivalent O(9)Li3V2Ga octahedra, edges with two equivalent O(11)Li3VGa2 octahedra, and edges with two equivalent O(8)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the seventh O site, O(7) is bonded to one Li(2), one Li(3), one Li(4), one V(3), one Ga(1), and one Ga(3) atom to form OLi3VGa2 octahedra that share  a cornercorner with one O(4)Li3VGa2 octahedra,  a cornercorner with one O(8)Li3VGa2 octahedra, corners with two equivalent O(2)Li3V2Ga octahedra, corners with two equivalent O(6)Li3V2Ga octahedra,  an edgeedge with one O(1)Li3V2Ga octahedra,  an edgeedge with one O(9)Li3V2Ga octahedra,  an edgeedge with one O(11)Li3VGa2 octahedra,  an edgeedge with one O(3)Li3VGa2 octahedra,  an edgeedge with one O(4)Li3VGa2 octahedra,  an edgeedge with one O(8)Li3VGa2 octahedra, edges with two equivalent O(10)Li3V2Ga octahedra, edges with two equivalent O(5)Li3V2Ga octahedra, and edges with two equivalent O(12)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(4), one V(2), one Ga(1), and one Ga(2) atom to form OLi3VGa2 octahedra that share  a cornercorner with one O(3)Li3VGa2 octahedra,  a cornercorner with one O(7)Li3VGa2 octahedra, corners with two equivalent O(1)Li3V2Ga octahedra, corners with two equivalent O(5)Li3V2Ga octahedra,  an edgeedge with one O(10)Li3V2Ga octahedra,  an edgeedge with one O(2)Li3V2Ga octahedra,  an edgeedge with one O(12)Li3VGa2 octahedra,  an edgeedge with one O(3)Li3VGa2 octahedra,  an edgeedge with one O(4)Li3VGa2 octahedra,  an edgeedge with one O(7)Li3VGa2 octahedra, edges with two equivalent O(6)Li3V2Ga octahedra, edges with two equivalent O(9)Li3V2Ga octahedra, and edges with two equivalent O(11)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one Li(5), one V(1), one V(2), and one Ga(1) atom to form OLi3V2Ga octahedra that share  a cornercorner with one O(2)Li3V2Ga octahedra,  a cornercorner with one O(12)Li3VGa2 octahedra, corners with two equivalent O(10)Li3V2Ga octahedra, corners with two equivalent O(4)Li3VGa2 octahedra,  an edgeedge with one O(1)Li3V2Ga octahedra,  an edgeedge with one O(2)Li3V2Ga octahedra,  an edgeedge with one O(5)Li3V2Ga octahedra,  an edgeedge with one O(12)Li3VGa2 octahedra,  an edgeedge with one O(3)Li3VGa2 octahedra,  an edgeedge with one O(7)Li3VGa2 octahedra, edges with two equivalent O(6)Li3V2Ga octahedra, edges with two equivalent O(11)Li3VGa2 octahedra, and edges with two equivalent O(8)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the tenth O site, O(10) is bonded to one Li(2), one Li(4), one Li(6), one V(1), one V(3), and one Ga(1) atom to form OLi3V2Ga octahedra that share  a cornercorner with one O(1)Li3V2Ga octahedra,  a cornercorner with one O(11)Li3VGa2 octahedra, corners with two equivalent O(9)Li3V2Ga octahedra, corners with two equivalent O(3)Li3VGa2 octahedra,  an edgeedge with one O(1)Li3V2Ga octahedra,  an edgeedge with one O(2)Li3V2Ga octahedra,  an edgeedge with one O(6)Li3V2Ga octahedra,  an edgeedge with one O(11)Li3VGa2 octahedra,  an edgeedge with one O(4)Li3VGa2 octahedra,  an edgeedge with one O(8)Li3VGa2 octahedra, edges with two equivalent O(5)Li3V2Ga octahedra, edges with two equivalent O(12)Li3VGa2 octahedra, and edges with two equivalent O(7)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(4), one Li(5), one V(1), one Ga(1), and one Ga(2) atom to form OLi3VGa2 octahedra that share  a cornercorner with one O(10)Li3V2Ga octahedra,  a cornercorner with one O(4)Li3VGa2 octahedra, corners with two equivalent O(2)Li3V2Ga octahedra, corners with two equivalent O(12)Li3VGa2 octahedra,  an edgeedge with one O(1)Li3V2Ga octahedra,  an edgeedge with one O(10)Li3V2Ga octahedra,  an edgeedge with one O(5)Li3V2Ga octahedra,  an edgeedge with one O(3)Li3VGa2 octahedra,  an edgeedge with one O(4)Li3VGa2 octahedra,  an edgeedge with one O(7)Li3VGa2 octahedra, edges with two equivalent O(6)Li3V2Ga octahedra, edges with two equivalent O(9)Li3V2Ga octahedra, and edges with two equivalent O(8)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the twelfth O site, O(12) is bonded to one Li(2), one Li(3), one Li(6), one V(1), one Ga(1), and one Ga(3) atom to form OLi3VGa2 octahedra that share  a cornercorner with one O(9)Li3V2Ga octahedra,  a cornercorner with one O(3)Li3VGa2 octahedra, corners with two equivalent O(1)Li3V2Ga octahedra, corners with two equivalent O(11)Li3VGa2 octahedra,  an edgeedge with one O(2)Li3V2Ga octahedra,  an edgeedge with one O(6)Li3V2Ga octahedra,  an edgeedge with one O(9)Li3V2Ga octahedra,  an edgeedge with one O(3)Li3VGa2 octahedra,  an edgeedge with one O(4)Li3VGa2 octahedra,  an edgeedge with one O(8)Li3VGa2 octahedra, edges with two equivalent O(10)Li3V2Ga octahedra, edges with two equivalent O(5)Li3V2Ga octahedra, and edges with two equivalent O(7)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. is represented by the CIF card [CIF]
data_Li2VGaO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.063
_cell_length_b   5.901
_cell_length_c   7.688
_cell_angle_alpha   79.212
_cell_angle_beta   71.458
_cell_angle_gamma   89.948
_symmetry_Int_Tables_number   1
_cell_volume   213.512
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.500  0.583  0.666  1.0
  Ga  Ga1  1  0.500  0.744  1.000  1.0
  Ga  Ga2  1  0.500  0.423  0.334  1.0
  Li  Li3  1  0.003  0.501  1.000  1.0
  Li  Li4  1  0.998  0.666  0.333  1.0
  Li  Li5  1  0.002  0.337  0.663  1.0
  Li  Li6  1  0.998  0.829  0.670  1.0
  Li  Li7  1  0.001  0.990  0.998  1.0
  Li  Li8  1  0.999  0.176  0.337  1.0
  O  O9  1  0.270  0.957  0.160  1.0
  O  O10  1  0.730  0.210  0.173  1.0
  O  O11  1  0.274  0.461  0.163  1.0
  O  O12  1  0.726  0.706  0.170  1.0
  O  O13  1  0.269  0.137  0.494  1.0
  O  O14  1  0.730  0.030  0.839  1.0
  O  O15  1  0.274  0.630  0.495  1.0
  O  O16  1  0.726  0.536  0.838  1.0
  O  O17  1  0.272  0.292  0.827  1.0
  O  O18  1  0.727  0.875  0.506  1.0
  O  O19  1  0.272  0.783  0.831  1.0
  O  O20  1  0.728  0.384  0.503  1.0
  V  V21  1  0.500  0.083  0.667  1.0
  V  V22  1  0.500  0.243  0.001  1.0
  V  V23  1  0.500  0.924  0.332  1.0
[/CIF]
.
The material described by Li2VGaO4 is alpha Po-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(11), one O(2), one O(3), one O(4), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one Ga(1)O6 octahedra,  a cornercorner with one Ga(3)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one Ga(1)O6 octahedra,  an edgeedge with one Ga(3)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Ga(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. In the second Li site, Li(2) is bonded to one O(1), one O(10), one O(12), one O(3), one O(4), and one O(7) atom to form LiO6 octahedra that share  a cornercorner with one Ga(1)O6 octahedra,  a cornercorner with one Ga(2)O6 octahedra, corners with two equivalent V(1)O6 octahedra, corners with two equivalent V(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Ga(1)O6 octahedra,  an edgeedge with one Ga(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Ga(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. In the third Li site, Li(3) is bonded to one O(12), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Ga(3)O6 octahedra, corners with two equivalent V(3)O6 octahedra, corners with two equivalent Ga(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Ga(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. In the fourth Li site, Li(4) is bonded to one O(10), one O(11), one O(5), one O(6), one O(7), and one O(8) atom to form LiO6 octahedra that share  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one Ga(2)O6 octahedra, corners with two equivalent V(2)O6 octahedra, corners with two equivalent Ga(3)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Ga(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. In the fifth Li site, Li(5) is bonded to one O(1), one O(11), one O(2), one O(4), one O(6), and one O(9) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(3)O6 octahedra, corners with two equivalent Ga(1)O6 octahedra, corners with two equivalent Ga(3)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent Ga(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-5°. In the sixth Li site, Li(6) is bonded to one O(1), one O(10), one O(12), one O(2), one O(3), and one O(5) atom to form LiO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent Ga(1)O6 octahedra, corners with two equivalent Ga(2)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and edges with two equivalent Ga(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-5°. There are three inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(11), one O(12), one O(5), one O(6), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(5)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(2)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Ga(2)O6 octahedra,  an edgeedge with one Ga(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent Ga(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. In the second V site, V(2) is bonded to one O(1), one O(2), one O(3), one O(6), one O(8), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra,  a cornercorner with one Li(6)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with two equivalent Li(4)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one Li(6)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Ga(1)O6 octahedra,  an edgeedge with one Ga(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent Ga(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. In the third V site, V(3) is bonded to one O(1), one O(10), one O(2), one O(4), one O(5), and one O(7) atom to form VO6 octahedra that share  a cornercorner with one Li(4)O6 octahedra,  a cornercorner with one Li(5)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with two equivalent Li(3)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one Li(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Ga(1)O6 octahedra,  an edgeedge with one Ga(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent Ga(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(10), one O(11), one O(12), one O(7), one O(8), and one O(9) atom to form GaO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Li(5)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Ga(2)O6 octahedra,  an edgeedge with one Ga(3)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with two equivalent Li(4)O6 octahedra, and edges with two equivalent V(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 4-6°. In the second Ga site, Ga(2) is bonded to one O(1), one O(11), one O(3), one O(4), one O(6), and one O(8) atom to form GaO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra,  a cornercorner with one Li(4)O6 octahedra, corners with two equivalent Li(3)O6 octahedra, corners with two equivalent Li(6)O6 octahedra,  an edgeedge with one Li(2)O6 octahedra,  an edgeedge with one Li(4)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one Ga(1)O6 octahedra,  an edgeedge with one Ga(3)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(5)O6 octahedra, and edges with two equivalent V(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. In the third Ga site, Ga(3) is bonded to one O(12), one O(2), one O(3), one O(4), one O(5), and one O(7) atom to form GaO6 octahedra that share  a cornercorner with one Li(1)O6 octahedra,  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(4)O6 octahedra, corners with two equivalent Li(5)O6 octahedra,  an edgeedge with one Li(1)O6 octahedra,  an edgeedge with one Li(3)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one Ga(1)O6 octahedra,  an edgeedge with one Ga(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(6)O6 octahedra, and edges with two equivalent V(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to one Li(2), one Li(5), one Li(6), one V(2), one V(3), and one Ga(2) atom to form OLi3V2Ga octahedra that share  a cornercorner with one O(10)Li3V2Ga octahedra,  a cornercorner with one O(6)Li3V2Ga octahedra, corners with two equivalent O(12)Li3VGa2 octahedra, corners with two equivalent O(8)Li3VGa2 octahedra,  an edgeedge with one O(10)Li3V2Ga octahedra,  an edgeedge with one O(5)Li3V2Ga octahedra,  an edgeedge with one O(6)Li3V2Ga octahedra,  an edgeedge with one O(9)Li3V2Ga octahedra,  an edgeedge with one O(11)Li3VGa2 octahedra,  an edgeedge with one O(7)Li3VGa2 octahedra, edges with two equivalent O(2)Li3V2Ga octahedra, edges with two equivalent O(3)Li3VGa2 octahedra, and edges with two equivalent O(4)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the second O site, O(2) is bonded to one Li(1), one Li(5), one Li(6), one V(2), one V(3), and one Ga(3) atom to form OLi3V2Ga octahedra that share  a cornercorner with one O(5)Li3V2Ga octahedra,  a cornercorner with one O(9)Li3V2Ga octahedra, corners with two equivalent O(11)Li3VGa2 octahedra, corners with two equivalent O(7)Li3VGa2 octahedra,  an edgeedge with one O(10)Li3V2Ga octahedra,  an edgeedge with one O(5)Li3V2Ga octahedra,  an edgeedge with one O(6)Li3V2Ga octahedra,  an edgeedge with one O(9)Li3V2Ga octahedra,  an edgeedge with one O(12)Li3VGa2 octahedra,  an edgeedge with one O(8)Li3VGa2 octahedra, edges with two equivalent O(1)Li3V2Ga octahedra, edges with two equivalent O(3)Li3VGa2 octahedra, and edges with two equivalent O(4)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 1-3°. In the third O site, O(3) is bonded to one Li(1), one Li(2), one Li(6), one V(2), one Ga(2), and one Ga(3) atom to form OLi3VGa2 octahedra that share  a cornercorner with one O(12)Li3VGa2 octahedra,  a cornercorner with one O(8)Li3VGa2 octahedra, corners with two equivalent O(10)Li3V2Ga octahedra, corners with two equivalent O(6)Li3V2Ga octahedra,  an edgeedge with one O(5)Li3V2Ga octahedra,  an edgeedge with one O(9)Li3V2Ga octahedra,  an edgeedge with one O(11)Li3VGa2 octahedra,  an edgeedge with one O(12)Li3VGa2 octahedra,  an edgeedge with one O(7)Li3VGa2 octahedra,  an edgeedge with one O(8)Li3VGa2 octahedra, edges with two equivalent O(1)Li3V2Ga octahedra, edges with two equivalent O(2)Li3V2Ga octahedra, and edges with two equivalent O(4)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the fourth O site, O(4) is bonded to one Li(1), one Li(2), one Li(5), one V(3), one Ga(2), and one Ga(3) atom to form OLi3VGa2 octahedra that share  a cornercorner with one O(11)Li3VGa2 octahedra,  a cornercorner with one O(7)Li3VGa2 octahedra, corners with two equivalent O(5)Li3V2Ga octahedra, corners with two equivalent O(9)Li3V2Ga octahedra,  an edgeedge with one O(10)Li3V2Ga octahedra,  an edgeedge with one O(6)Li3V2Ga octahedra,  an edgeedge with one O(11)Li3VGa2 octahedra,  an edgeedge with one O(12)Li3VGa2 octahedra,  an edgeedge with one O(7)Li3VGa2 octahedra,  an edgeedge with one O(8)Li3VGa2 octahedra, edges with two equivalent O(1)Li3V2Ga octahedra, edges with two equivalent O(2)Li3V2Ga octahedra, and edges with two equivalent O(3)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 1-2°. In the fifth O site, O(5) is bonded to one Li(3), one Li(4), one Li(6), one V(1), one V(3), and one Ga(3) atom to form OLi3V2Ga octahedra that share  a cornercorner with one O(2)Li3V2Ga octahedra,  a cornercorner with one O(6)Li3V2Ga octahedra, corners with two equivalent O(4)Li3VGa2 octahedra, corners with two equivalent O(8)Li3VGa2 octahedra,  an edgeedge with one O(1)Li3V2Ga octahedra,  an edgeedge with one O(2)Li3V2Ga octahedra,  an edgeedge with one O(6)Li3V2Ga octahedra,  an edgeedge with one O(9)Li3V2Ga octahedra,  an edgeedge with one O(11)Li3VGa2 octahedra,  an edgeedge with one O(3)Li3VGa2 octahedra, edges with two equivalent O(10)Li3V2Ga octahedra, edges with two equivalent O(12)Li3VGa2 octahedra, and edges with two equivalent O(7)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the sixth O site, O(6) is bonded to one Li(3), one Li(4), one Li(5), one V(1), one V(2), and one Ga(2) atom to form OLi3V2Ga octahedra that share  a cornercorner with one O(1)Li3V2Ga octahedra,  a cornercorner with one O(5)Li3V2Ga octahedra, corners with two equivalent O(3)Li3VGa2 octahedra, corners with two equivalent O(7)Li3VGa2 octahedra,  an edgeedge with one O(1)Li3V2Ga octahedra,  an edgeedge with one O(10)Li3V2Ga octahedra,  an edgeedge with one O(2)Li3V2Ga octahedra,  an edgeedge with one O(5)Li3V2Ga octahedra,  an edgeedge with one O(12)Li3VGa2 octahedra,  an edgeedge with one O(4)Li3VGa2 octahedra, edges with two equivalent O(9)Li3V2Ga octahedra, edges with two equivalent O(11)Li3VGa2 octahedra, and edges with two equivalent O(8)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the seventh O site, O(7) is bonded to one Li(2), one Li(3), one Li(4), one V(3), one Ga(1), and one Ga(3) atom to form OLi3VGa2 octahedra that share  a cornercorner with one O(4)Li3VGa2 octahedra,  a cornercorner with one O(8)Li3VGa2 octahedra, corners with two equivalent O(2)Li3V2Ga octahedra, corners with two equivalent O(6)Li3V2Ga octahedra,  an edgeedge with one O(1)Li3V2Ga octahedra,  an edgeedge with one O(9)Li3V2Ga octahedra,  an edgeedge with one O(11)Li3VGa2 octahedra,  an edgeedge with one O(3)Li3VGa2 octahedra,  an edgeedge with one O(4)Li3VGa2 octahedra,  an edgeedge with one O(8)Li3VGa2 octahedra, edges with two equivalent O(10)Li3V2Ga octahedra, edges with two equivalent O(5)Li3V2Ga octahedra, and edges with two equivalent O(12)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the eighth O site, O(8) is bonded to one Li(1), one Li(3), one Li(4), one V(2), one Ga(1), and one Ga(2) atom to form OLi3VGa2 octahedra that share  a cornercorner with one O(3)Li3VGa2 octahedra,  a cornercorner with one O(7)Li3VGa2 octahedra, corners with two equivalent O(1)Li3V2Ga octahedra, corners with two equivalent O(5)Li3V2Ga octahedra,  an edgeedge with one O(10)Li3V2Ga octahedra,  an edgeedge with one O(2)Li3V2Ga octahedra,  an edgeedge with one O(12)Li3VGa2 octahedra,  an edgeedge with one O(3)Li3VGa2 octahedra,  an edgeedge with one O(4)Li3VGa2 octahedra,  an edgeedge with one O(7)Li3VGa2 octahedra, edges with two equivalent O(6)Li3V2Ga octahedra, edges with two equivalent O(9)Li3V2Ga octahedra, and edges with two equivalent O(11)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the ninth O site, O(9) is bonded to one Li(1), one Li(3), one Li(5), one V(1), one V(2), and one Ga(1) atom to form OLi3V2Ga octahedra that share  a cornercorner with one O(2)Li3V2Ga octahedra,  a cornercorner with one O(12)Li3VGa2 octahedra, corners with two equivalent O(10)Li3V2Ga octahedra, corners with two equivalent O(4)Li3VGa2 octahedra,  an edgeedge with one O(1)Li3V2Ga octahedra,  an edgeedge with one O(2)Li3V2Ga octahedra,  an edgeedge with one O(5)Li3V2Ga octahedra,  an edgeedge with one O(12)Li3VGa2 octahedra,  an edgeedge with one O(3)Li3VGa2 octahedra,  an edgeedge with one O(7)Li3VGa2 octahedra, edges with two equivalent O(6)Li3V2Ga octahedra, edges with two equivalent O(11)Li3VGa2 octahedra, and edges with two equivalent O(8)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the tenth O site, O(10) is bonded to one Li(2), one Li(4), one Li(6), one V(1), one V(3), and one Ga(1) atom to form OLi3V2Ga octahedra that share  a cornercorner with one O(1)Li3V2Ga octahedra,  a cornercorner with one O(11)Li3VGa2 octahedra, corners with two equivalent O(9)Li3V2Ga octahedra, corners with two equivalent O(3)Li3VGa2 octahedra,  an edgeedge with one O(1)Li3V2Ga octahedra,  an edgeedge with one O(2)Li3V2Ga octahedra,  an edgeedge with one O(6)Li3V2Ga octahedra,  an edgeedge with one O(11)Li3VGa2 octahedra,  an edgeedge with one O(4)Li3VGa2 octahedra,  an edgeedge with one O(8)Li3VGa2 octahedra, edges with two equivalent O(5)Li3V2Ga octahedra, edges with two equivalent O(12)Li3VGa2 octahedra, and edges with two equivalent O(7)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-3°. In the eleventh O site, O(11) is bonded to one Li(1), one Li(4), one Li(5), one V(1), one Ga(1), and one Ga(2) atom to form OLi3VGa2 octahedra that share  a cornercorner with one O(10)Li3V2Ga octahedra,  a cornercorner with one O(4)Li3VGa2 octahedra, corners with two equivalent O(2)Li3V2Ga octahedra, corners with two equivalent O(12)Li3VGa2 octahedra,  an edgeedge with one O(1)Li3V2Ga octahedra,  an edgeedge with one O(10)Li3V2Ga octahedra,  an edgeedge with one O(5)Li3V2Ga octahedra,  an edgeedge with one O(3)Li3VGa2 octahedra,  an edgeedge with one O(4)Li3VGa2 octahedra,  an edgeedge with one O(7)Li3VGa2 octahedra, edges with two equivalent O(6)Li3V2Ga octahedra, edges with two equivalent O(9)Li3V2Ga octahedra, and edges with two equivalent O(8)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the twelfth O site, O(12) is bonded to one Li(2), one Li(3), one Li(6), one V(1), one Ga(1), and one Ga(3) atom to form OLi3VGa2 octahedra that share  a cornercorner with one O(9)Li3V2Ga octahedra,  a cornercorner with one O(3)Li3VGa2 octahedra, corners with two equivalent O(1)Li3V2Ga octahedra, corners with two equivalent O(11)Li3VGa2 octahedra,  an edgeedge with one O(2)Li3V2Ga octahedra,  an edgeedge with one O(6)Li3V2Ga octahedra,  an edgeedge with one O(9)Li3V2Ga octahedra,  an edgeedge with one O(3)Li3VGa2 octahedra,  an edgeedge with one O(4)Li3VGa2 octahedra,  an edgeedge with one O(8)Li3VGa2 octahedra, edges with two equivalent O(10)Li3V2Ga octahedra, edges with two equivalent O(5)Li3V2Ga octahedra, and edges with two equivalent O(7)Li3VGa2 octahedra. The corner-sharing octahedral tilt angles range from 0-2°. is represented by the CIF card [CIF]
data_Li2VGaO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.063
_cell_length_b   5.901
_cell_length_c   7.688
_cell_angle_alpha   79.212
_cell_angle_beta   71.458
_cell_angle_gamma   89.948
_symmetry_Int_Tables_number   1
_cell_volume   213.512
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.500  0.583  0.666  1.0
  Ga  Ga1  1  0.500  0.744  1.000  1.0
  Ga  Ga2  1  0.500  0.423  0.334  1.0
  Li  Li3  1  0.003  0.501  1.000  1.0
  Li  Li4  1  0.998  0.666  0.333  1.0
  Li  Li5  1  0.002  0.337  0.663  1.0
  Li  Li6  1  0.998  0.829  0.670  1.0
  Li  Li7  1  0.001  0.990  0.998  1.0
  Li  Li8  1  0.999  0.176  0.337  1.0
  O  O9  1  0.270  0.957  0.160  1.0
  O  O10  1  0.730  0.210  0.173  1.0
  O  O11  1  0.274  0.461  0.163  1.0
  O  O12  1  0.726  0.706  0.170  1.0
  O  O13  1  0.269  0.137  0.494  1.0
  O  O14  1  0.730  0.030  0.839  1.0
  O  O15  1  0.274  0.630  0.495  1.0
  O  O16  1  0.726  0.536  0.838  1.0
  O  O17  1  0.272  0.292  0.827  1.0
  O  O18  1  0.727  0.875  0.506  1.0
  O  O19  1  0.272  0.783  0.831  1.0
  O  O20  1  0.728  0.384  0.503  1.0
  V  V21  1  0.500  0.083  0.667  1.0
  V  V22  1  0.500  0.243  0.001  1.0
  V  V23  1  0.500  0.924  0.332  1.0
[/CIF]
.