The crystal structure described by V3S crystallizes in the tetragonal I-42m space group. There are three inequivalent V sites. In the first V site, V(1) is bonded in a distorted water-like geometry to two equivalent S(1) atoms. In the second V site, V(3) is bonded in a distorted water-like geometry to two equivalent S(1) atoms. In the third V site, V(2) is bonded to four equivalent S(1) atoms to form a mixture of distorted corner and edge-sharing VS4 tetrahedra. S(1) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent V(3), and four equivalent V(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V3S
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.530
_cell_length_b   7.029
_cell_length_c   7.029
_cell_angle_alpha   84.039
_cell_angle_beta   71.200
_cell_angle_gamma   71.200
_symmetry_Int_Tables_number   1
_cell_volume   200.574
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.459  0.000  0.600  1.0
  V  V1  1  0.941  0.600  0.000  1.0
  V  V2  1  0.541  0.400  1.000  1.0
  V  V3  1  0.059  1.000  0.400  1.0
  V  V4  1  0.357  0.643  0.643  1.0
  V  V5  1  0.000  0.643  0.357  1.0
  V  V6  1  0.000  0.357  0.643  1.0
  V  V7  1  0.643  0.357  0.357  1.0
  V  V8  1  0.671  0.000  0.183  1.0
  V  V9  1  0.147  0.182  1.000  1.0
  V  V10  1  0.329  0.817  1.000  1.0
  V  V11  1  0.853  0.000  0.818  1.0
  S  S12  1  0.212  0.288  0.288  1.0
  S  S13  1  0.500  0.288  0.712  1.0
  S  S14  1  0.500  0.712  0.288  1.0
  S  S15  1  0.788  0.712  0.712  1.0
[/CIF]
.
The crystal structure described by V3S crystallizes in the tetragonal I-42m space group. There are three inequivalent V sites. In the first V site, V(1) is bonded in a distorted water-like geometry to two equivalent S(1) atoms. In the second V site, V(3) is bonded in a distorted water-like geometry to two equivalent S(1) atoms. In the third V site, V(2) is bonded to four equivalent S(1) atoms to form a mixture of distorted corner and edge-sharing VS4 tetrahedra. S(1) is bonded in a 8-coordinate geometry to two equivalent V(1), two equivalent V(3), and four equivalent V(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V3S
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.530
_cell_length_b   7.029
_cell_length_c   7.029
_cell_angle_alpha   84.039
_cell_angle_beta   71.200
_cell_angle_gamma   71.200
_symmetry_Int_Tables_number   1
_cell_volume   200.574
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.459  0.000  0.600  1.0
  V  V1  1  0.941  0.600  0.000  1.0
  V  V2  1  0.541  0.400  1.000  1.0
  V  V3  1  0.059  1.000  0.400  1.0
  V  V4  1  0.357  0.643  0.643  1.0
  V  V5  1  0.000  0.643  0.357  1.0
  V  V6  1  0.000  0.357  0.643  1.0
  V  V7  1  0.643  0.357  0.357  1.0
  V  V8  1  0.671  0.000  0.183  1.0
  V  V9  1  0.147  0.182  1.000  1.0
  V  V10  1  0.329  0.817  1.000  1.0
  V  V11  1  0.853  0.000  0.818  1.0
  S  S12  1  0.212  0.288  0.288  1.0
  S  S13  1  0.500  0.288  0.712  1.0
  S  S14  1  0.500  0.712  0.288  1.0
  S  S15  1  0.788  0.712  0.712  1.0
[/CIF]
.