The material structure described by (Nd2S3O14)2(O2)3 crystallizes in the monoclinic Cc space group. The structure consists of four trioxidane molecules inside a Nd2S3O14 framework. In the Nd2S3O14 framework, there are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(13), one O(15), one O(4), one O(6), one O(8), and one O(9) atom. In the second Nd site, Nd(2) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(14), one O(16), one O(3), one O(5), one O(7), and one O(9) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(10), one O(11), one O(12), and one O(9) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(13), one O(15), one O(5), and one O(7) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one O(14), one O(16), one O(6), and one O(8) atom. There are fourteen inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Nd(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Nd(1) atom. In the third O site, O(5) is bonded in a bent 150 degrees geometry to one Nd(2) and one S(2) atom. In the fourth O site, O(6) is bonded in a bent 150 degrees geometry to one Nd(1) and one S(3) atom. In the fifth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Nd(2) and one S(2) atom. In the sixth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one S(3) atom. In the seventh O site, O(9) is bonded in a 3-coordinate geometry to one Nd(1), one Nd(2), and one S(1) atom. In the eighth O site, O(10) is bonded in a 3-coordinate geometry to one Nd(1), one Nd(2), and one S(1) atom. In the ninth O site, O(11) is bonded in a distorted water-like geometry to one Nd(1) and one S(1) atom. In the tenth O site, O(12) is bonded in a distorted water-like geometry to one Nd(2) and one S(1) atom. In the eleventh O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one S(2) atom. In the twelfth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Nd(2) and one S(3) atom. In the thirteenth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one S(2) atom. In the fourteenth O site, O(16) is bonded in a distorted bent 150 degrees geometry to one Nd(2) and one S(3) atom. is represented by the CIF file [CIF]
data_Nd2S3O17
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.471
_cell_length_b   9.471
_cell_length_c   10.190
_cell_angle_alpha   63.701
_cell_angle_beta   63.701
_cell_angle_gamma   65.087
_symmetry_Int_Tables_number   1
_cell_volume   705.278
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.513  0.256  0.074  1.0
  Nd  Nd1  1  0.748  0.483  0.423  1.0
  Nd  Nd2  1  0.483  0.748  0.923  1.0
  Nd  Nd3  1  0.256  0.513  0.574  1.0
  S  S4  1  0.624  0.378  0.247  1.0
  S  S5  1  0.378  0.624  0.747  1.0
  S  S6  1  0.434  0.850  0.262  1.0
  S  S7  1  0.149  0.567  0.237  1.0
  S  S8  1  0.567  0.149  0.737  1.0
  S  S9  1  0.850  0.434  0.762  1.0
  O  O10  1  0.022  0.114  0.429  1.0
  O  O11  1  0.882  0.966  0.003  1.0
  O  O12  1  0.966  0.882  0.503  1.0
  O  O13  1  0.114  0.022  0.929  1.0
  O  O14  1  0.729  0.755  0.418  1.0
  O  O15  1  0.245  0.264  0.080  1.0
  O  O16  1  0.264  0.245  0.580  1.0
  O  O17  1  0.755  0.729  0.918  1.0
  O  O18  1  0.417  0.854  0.122  1.0
  O  O19  1  0.148  0.579  0.377  1.0
  O  O20  1  0.579  0.148  0.877  1.0
  O  O21  1  0.854  0.417  0.622  1.0
  O  O22  1  0.605  0.745  0.269  1.0
  O  O23  1  0.253  0.398  0.226  1.0
  O  O24  1  0.398  0.253  0.726  1.0
  O  O25  1  0.745  0.605  0.769  1.0
  O  O26  1  0.557  0.488  0.114  1.0
  O  O27  1  0.516  0.438  0.384  1.0
  O  O28  1  0.438  0.516  0.884  1.0
  O  O29  1  0.488  0.557  0.614  1.0
  O  O30  1  0.621  0.212  0.276  1.0
  O  O31  1  0.788  0.390  0.213  1.0
  O  O32  1  0.390  0.788  0.713  1.0
  O  O33  1  0.212  0.621  0.776  1.0
  O  O34  1  0.309  0.783  0.401  1.0
  O  O35  1  0.215  0.694  0.098  1.0
  O  O36  1  0.694  0.215  0.598  1.0
  O  O37  1  0.783  0.309  0.901  1.0
  O  O38  1  0.418  0.019  0.249  1.0
  O  O39  1  0.980  0.585  0.250  1.0
  O  O40  1  0.585  0.980  0.750  1.0
  O  O41  1  0.019  0.418  0.749  1.0
  O  O42  1  0.967  0.026  0.407  1.0
  O  O43  1  0.026  0.967  0.907  1.0
[/CIF]
.
The material structure described by (Nd2S3O14)2(O2)3 crystallizes in the monoclinic Cc space group. The structure consists of four trioxidane molecules inside a Nd2S3O14 framework. In the Nd2S3O14 framework, there are two inequivalent Nd sites. In the first Nd site, Nd(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(13), one O(15), one O(4), one O(6), one O(8), and one O(9) atom. In the second Nd site, Nd(2) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(14), one O(16), one O(3), one O(5), one O(7), and one O(9) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a tetrahedral geometry to one O(10), one O(11), one O(12), and one O(9) atom. In the second S site, S(2) is bonded in a tetrahedral geometry to one O(13), one O(15), one O(5), and one O(7) atom. In the third S site, S(3) is bonded in a tetrahedral geometry to one O(14), one O(16), one O(6), and one O(8) atom. There are fourteen inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Nd(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Nd(1) atom. In the third O site, O(5) is bonded in a bent 150 degrees geometry to one Nd(2) and one S(2) atom. In the fourth O site, O(6) is bonded in a bent 150 degrees geometry to one Nd(1) and one S(3) atom. In the fifth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Nd(2) and one S(2) atom. In the sixth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one S(3) atom. In the seventh O site, O(9) is bonded in a 3-coordinate geometry to one Nd(1), one Nd(2), and one S(1) atom. In the eighth O site, O(10) is bonded in a 3-coordinate geometry to one Nd(1), one Nd(2), and one S(1) atom. In the ninth O site, O(11) is bonded in a distorted water-like geometry to one Nd(1) and one S(1) atom. In the tenth O site, O(12) is bonded in a distorted water-like geometry to one Nd(2) and one S(1) atom. In the eleventh O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one S(2) atom. In the twelfth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Nd(2) and one S(3) atom. In the thirteenth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one S(2) atom. In the fourteenth O site, O(16) is bonded in a distorted bent 150 degrees geometry to one Nd(2) and one S(3) atom. is represented by the CIF file [CIF]
data_Nd2S3O17
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.471
_cell_length_b   9.471
_cell_length_c   10.190
_cell_angle_alpha   63.701
_cell_angle_beta   63.701
_cell_angle_gamma   65.087
_symmetry_Int_Tables_number   1
_cell_volume   705.278
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.513  0.256  0.074  1.0
  Nd  Nd1  1  0.748  0.483  0.423  1.0
  Nd  Nd2  1  0.483  0.748  0.923  1.0
  Nd  Nd3  1  0.256  0.513  0.574  1.0
  S  S4  1  0.624  0.378  0.247  1.0
  S  S5  1  0.378  0.624  0.747  1.0
  S  S6  1  0.434  0.850  0.262  1.0
  S  S7  1  0.149  0.567  0.237  1.0
  S  S8  1  0.567  0.149  0.737  1.0
  S  S9  1  0.850  0.434  0.762  1.0
  O  O10  1  0.022  0.114  0.429  1.0
  O  O11  1  0.882  0.966  0.003  1.0
  O  O12  1  0.966  0.882  0.503  1.0
  O  O13  1  0.114  0.022  0.929  1.0
  O  O14  1  0.729  0.755  0.418  1.0
  O  O15  1  0.245  0.264  0.080  1.0
  O  O16  1  0.264  0.245  0.580  1.0
  O  O17  1  0.755  0.729  0.918  1.0
  O  O18  1  0.417  0.854  0.122  1.0
  O  O19  1  0.148  0.579  0.377  1.0
  O  O20  1  0.579  0.148  0.877  1.0
  O  O21  1  0.854  0.417  0.622  1.0
  O  O22  1  0.605  0.745  0.269  1.0
  O  O23  1  0.253  0.398  0.226  1.0
  O  O24  1  0.398  0.253  0.726  1.0
  O  O25  1  0.745  0.605  0.769  1.0
  O  O26  1  0.557  0.488  0.114  1.0
  O  O27  1  0.516  0.438  0.384  1.0
  O  O28  1  0.438  0.516  0.884  1.0
  O  O29  1  0.488  0.557  0.614  1.0
  O  O30  1  0.621  0.212  0.276  1.0
  O  O31  1  0.788  0.390  0.213  1.0
  O  O32  1  0.390  0.788  0.713  1.0
  O  O33  1  0.212  0.621  0.776  1.0
  O  O34  1  0.309  0.783  0.401  1.0
  O  O35  1  0.215  0.694  0.098  1.0
  O  O36  1  0.694  0.215  0.598  1.0
  O  O37  1  0.783  0.309  0.901  1.0
  O  O38  1  0.418  0.019  0.249  1.0
  O  O39  1  0.980  0.585  0.250  1.0
  O  O40  1  0.585  0.980  0.750  1.0
  O  O41  1  0.019  0.418  0.749  1.0
  O  O42  1  0.967  0.026  0.407  1.0
  O  O43  1  0.026  0.967  0.907  1.0
[/CIF]
.