The structure described by CsVZn(PO3)6 crystallizes in the triclinic P1 space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 9-coordinate geometry to one O(13), one O(16), one O(18), one O(19), one O(22), one O(24), one O(27), and two equivalent O(25) atoms. In the second Cs site, Cs(2) is bonded in a 9-coordinate geometry to one O(14), one O(15), one O(17), one O(20), one O(21), one O(23), one O(28), and two equivalent O(26) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(16), one O(18), one O(22), one O(27), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and corners with two equivalent P(12)O4 tetrahedra. In the second V site, V(2) is bonded to one O(15), one O(17), one O(21), one O(28), one O(7), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and corners with two equivalent P(11)O4 tetrahedra. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(11), one O(13), one O(19), one O(24), one O(25), and one O(5) atom to form ZnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and corners with two equivalent P(9)O4 tetrahedra. In the second Zn site, Zn(2) is bonded to one O(12), one O(14), one O(20), one O(23), one O(26), and one O(6) atom to form ZnO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and corners with two equivalent P(10)O4 tetrahedra. There are twelve inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(21), one O(29), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(9)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-47°. In the second P site, P(2) is bonded to one O(2), one O(22), one O(30), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one P(10)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-47°. In the third P site, P(3) is bonded to one O(1), one O(23), one O(31), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(11)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 40-48°. In the fourth P site, P(4) is bonded to one O(2), one O(24), one O(32), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one P(12)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 40-48°. In the fifth P site, P(5) is bonded to one O(25), one O(3), one O(33), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one P(11)O4 tetrahedra, and  a cornercorner with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 39-47°. In the sixth P site, P(6) is bonded to one O(10), one O(26), one O(34), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one P(12)O4 tetrahedra, and  a cornercorner with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 40-47°. In the seventh P site, P(7) is bonded to one O(11), one O(27), one O(3), and one O(35) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(9)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. In the eighth P site, P(8) is bonded to one O(12), one O(28), one O(36), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one P(10)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-47°. In the ninth P site, P(9) is bonded to one O(13), one O(19), one O(29), and one O(35) atom to form PO4 tetrahedra that share corners with two equivalent Zn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-45°. In the tenth P site, P(10) is bonded to one O(14), one O(20), one O(30), and one O(36) atom to form PO4 tetrahedra that share corners with two equivalent Zn(2)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-44°. In the eleventh P site, P(11) is bonded to one O(15), one O(17), one O(31), and one O(33) atom to form PO4 tetrahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-42°. In the twelfth P site, P(12) is bonded to one O(16), one O(18), one O(32), and one O(34) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 40-42°. There are thirty-six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one P(2) and one P(4) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one P(5) and one P(7) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one P(6) and one P(8) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one V(2) and one P(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one V(1) and one P(4) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(2) and one P(5) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(1) and one P(6) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one P(7) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one P(8) atom. In the thirteenth O site, O(13) is bonded in a 2-coordinate geometry to one Cs(1), one Zn(1), and one P(9) atom. In the fourteenth O site, O(14) is bonded in a 2-coordinate geometry to one Cs(2), one Zn(2), and one P(10) atom. In the fifteenth O site, O(15) is bonded in a 2-coordinate geometry to one Cs(2), one V(2), and one P(11) atom. In the sixteenth O site, O(16) is bonded in a 2-coordinate geometry to one Cs(1), one V(1), and one P(12) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Cs(2), one V(2), and one P(11) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one V(1), and one P(12) atom. In the nineteenth O site, O(19) is bonded in a 2-coordinate geometry to one Cs(1), one Zn(1), and one P(9) atom. In the twentieth O site, O(20) is bonded in a 2-coordinate geometry to one Cs(2), one Zn(2), and one P(10) atom. In the twenty-first O site, O(21) is bonded in a 2-coordinate geometry to one Cs(2), one V(2), and one P(1) atom. In the twenty-second O site, O(22) is bonded in a 2-coordinate geometry to one Cs(1), one V(1), and one P(2) atom. In the twenty-third O site, O(23) is bonded in a 2-coordinate geometry to one Cs(2), one Zn(2), and one P(3) atom. In the twenty-fourth O site, O(24) is bonded in a 2-coordinate geometry to one Cs(1), one Zn(1), and one P(4) atom. In the twenty-fifth O site, O(25) is bonded in a 2-coordinate geometry to two equivalent Cs(1), one Zn(1), and one P(5) atom. In the twenty-sixth O site, O(26) is bonded in a 2-coordinate geometry to two equivalent Cs(2), one Zn(2), and one P(6) atom. In the twenty-seventh O site, O(27) is bonded in a 2-coordinate geometry to one Cs(1), one V(1), and one P(7) atom. In the twenty-eighth O site, O(28) is bonded in a 2-coordinate geometry to one Cs(2), one V(2), and one P(8) atom. In the twenty-ninth O site, O(29) is bonded in a distorted bent 120 degrees geometry to one P(1) and one P(9) atom. In the thirtieth O site, O(30) is bonded in a distorted bent 120 degrees geometry to one P(10) and one P(2) atom. In the thirty-first O site, O(31) is bonded in a bent 120 degrees geometry to one P(11) and one P(3) atom. In the thirty-second O site, O(32) is bonded in a bent 120 degrees geometry to one P(12) and one P(4) atom. In the thirty-third O site, O(33) is bonded in a bent 120 degrees geometry to one P(11) and one P(5) atom. In the thirty-fourth O site, O(34) is bonded in a bent 120 degrees geometry to one P(12) and one P(6) atom. In the thirty-fifth O site, O(35) is bonded in a distorted bent 120 degrees geometry to one P(7) and one P(9) atom. In the thirty-sixth O site, O(36) is bonded in a distorted bent 120 degrees geometry to one P(10) and one P(8) atom. is represented by the CIF file [CIF]
data_CsVZn(PO3)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.440
_cell_length_b   8.556
_cell_length_c   8.577
_cell_angle_alpha   104.457
_cell_angle_beta   103.818
_cell_angle_gamma   103.864
_symmetry_Int_Tables_number   1
_cell_volume   421.254
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.545  0.948  0.961  1.0
  O  O1  1  0.100  0.350  0.350  1.0
  O  O2  1  0.903  0.652  0.651  1.0
  O  O3  1  0.950  0.516  0.176  1.0
  O  O4  1  0.963  0.185  0.528  1.0
  O  O5  1  0.037  0.473  0.814  1.0
  O  O6  1  0.055  0.830  0.489  1.0
  O  O7  1  0.659  0.726  0.179  1.0
  O  O8  1  0.664  0.186  0.734  1.0
  O  O9  1  0.339  0.265  0.815  1.0
  O  O10  1  0.346  0.820  0.267  1.0
  O  O11  1  0.048  0.255  0.032  1.0
  O  O12  1  0.037  0.033  0.255  1.0
  O  O13  1  0.954  0.744  0.964  1.0
  O  O14  1  0.937  0.968  0.742  1.0
  O  O15  1  0.363  0.516  0.236  1.0
  O  O16  1  0.366  0.233  0.515  1.0
  O  O17  1  0.631  0.483  0.761  1.0
  O  O18  1  0.636  0.760  0.481  1.0
  P  P19  1  0.101  0.409  0.186  1.0
  P  P20  1  0.101  0.186  0.408  1.0
  P  P21  1  0.896  0.592  0.813  1.0
  P  P22  1  0.897  0.815  0.590  1.0
  P  P23  1  0.500  0.715  0.281  1.0
  P  P24  1  0.499  0.284  0.713  1.0
  V  V25  1  0.003  0.223  0.779  1.0
  Zn  Zn26  1  0.006  0.777  0.226  1.0
[/CIF]
.
The structure described by CsVZn(PO3)6 crystallizes in the triclinic P1 space group. There are two inequivalent Cs sites. In the first Cs site, Cs(1) is bonded in a 9-coordinate geometry to one O(13), one O(16), one O(18), one O(19), one O(22), one O(24), one O(27), and two equivalent O(25) atoms. In the second Cs site, Cs(2) is bonded in a 9-coordinate geometry to one O(14), one O(15), one O(17), one O(20), one O(21), one O(23), one O(28), and two equivalent O(26) atoms. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(10), one O(16), one O(18), one O(22), one O(27), and one O(8) atom to form VO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and corners with two equivalent P(12)O4 tetrahedra. In the second V site, V(2) is bonded to one O(15), one O(17), one O(21), one O(28), one O(7), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and corners with two equivalent P(11)O4 tetrahedra. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(11), one O(13), one O(19), one O(24), one O(25), and one O(5) atom to form ZnO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and corners with two equivalent P(9)O4 tetrahedra. In the second Zn site, Zn(2) is bonded to one O(12), one O(14), one O(20), one O(23), one O(26), and one O(6) atom to form ZnO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and corners with two equivalent P(10)O4 tetrahedra. There are twelve inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(21), one O(29), and one O(5) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(9)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-47°. In the second P site, P(2) is bonded to one O(2), one O(22), one O(30), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one P(10)O4 tetrahedra, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-47°. In the third P site, P(3) is bonded to one O(1), one O(23), one O(31), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(11)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 40-48°. In the fourth P site, P(4) is bonded to one O(2), one O(24), one O(32), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one P(12)O4 tetrahedra, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 40-48°. In the fifth P site, P(5) is bonded to one O(25), one O(3), one O(33), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one P(11)O4 tetrahedra, and  a cornercorner with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 39-47°. In the sixth P site, P(6) is bonded to one O(10), one O(26), one O(34), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one P(12)O4 tetrahedra, and  a cornercorner with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 40-47°. In the seventh P site, P(7) is bonded to one O(11), one O(27), one O(3), and one O(35) atom to form PO4 tetrahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Zn(1)O6 octahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(9)O4 tetrahedra. The corner-sharing octahedral tilt angles are 47°. In the eighth P site, P(8) is bonded to one O(12), one O(28), one O(36), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Zn(2)O6 octahedra,  a cornercorner with one P(10)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 46-47°. In the ninth P site, P(9) is bonded to one O(13), one O(19), one O(29), and one O(35) atom to form PO4 tetrahedra that share corners with two equivalent Zn(1)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  a cornercorner with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-45°. In the tenth P site, P(10) is bonded to one O(14), one O(20), one O(30), and one O(36) atom to form PO4 tetrahedra that share corners with two equivalent Zn(2)O6 octahedra,  a cornercorner with one P(2)O4 tetrahedra, and  a cornercorner with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 43-44°. In the eleventh P site, P(11) is bonded to one O(15), one O(17), one O(31), and one O(33) atom to form PO4 tetrahedra that share corners with two equivalent V(2)O6 octahedra,  a cornercorner with one P(3)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 41-42°. In the twelfth P site, P(12) is bonded to one O(16), one O(18), one O(32), and one O(34) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 40-42°. There are thirty-six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one P(1) and one P(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one P(2) and one P(4) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one P(5) and one P(7) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one P(6) and one P(8) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one P(1) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one V(2) and one P(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one V(1) and one P(4) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(2) and one P(5) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(1) and one P(6) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one P(7) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one P(8) atom. In the thirteenth O site, O(13) is bonded in a 2-coordinate geometry to one Cs(1), one Zn(1), and one P(9) atom. In the fourteenth O site, O(14) is bonded in a 2-coordinate geometry to one Cs(2), one Zn(2), and one P(10) atom. In the fifteenth O site, O(15) is bonded in a 2-coordinate geometry to one Cs(2), one V(2), and one P(11) atom. In the sixteenth O site, O(16) is bonded in a 2-coordinate geometry to one Cs(1), one V(1), and one P(12) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Cs(2), one V(2), and one P(11) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one Cs(1), one V(1), and one P(12) atom. In the nineteenth O site, O(19) is bonded in a 2-coordinate geometry to one Cs(1), one Zn(1), and one P(9) atom. In the twentieth O site, O(20) is bonded in a 2-coordinate geometry to one Cs(2), one Zn(2), and one P(10) atom. In the twenty-first O site, O(21) is bonded in a 2-coordinate geometry to one Cs(2), one V(2), and one P(1) atom. In the twenty-second O site, O(22) is bonded in a 2-coordinate geometry to one Cs(1), one V(1), and one P(2) atom. In the twenty-third O site, O(23) is bonded in a 2-coordinate geometry to one Cs(2), one Zn(2), and one P(3) atom. In the twenty-fourth O site, O(24) is bonded in a 2-coordinate geometry to one Cs(1), one Zn(1), and one P(4) atom. In the twenty-fifth O site, O(25) is bonded in a 2-coordinate geometry to two equivalent Cs(1), one Zn(1), and one P(5) atom. In the twenty-sixth O site, O(26) is bonded in a 2-coordinate geometry to two equivalent Cs(2), one Zn(2), and one P(6) atom. In the twenty-seventh O site, O(27) is bonded in a 2-coordinate geometry to one Cs(1), one V(1), and one P(7) atom. In the twenty-eighth O site, O(28) is bonded in a 2-coordinate geometry to one Cs(2), one V(2), and one P(8) atom. In the twenty-ninth O site, O(29) is bonded in a distorted bent 120 degrees geometry to one P(1) and one P(9) atom. In the thirtieth O site, O(30) is bonded in a distorted bent 120 degrees geometry to one P(10) and one P(2) atom. In the thirty-first O site, O(31) is bonded in a bent 120 degrees geometry to one P(11) and one P(3) atom. In the thirty-second O site, O(32) is bonded in a bent 120 degrees geometry to one P(12) and one P(4) atom. In the thirty-third O site, O(33) is bonded in a bent 120 degrees geometry to one P(11) and one P(5) atom. In the thirty-fourth O site, O(34) is bonded in a bent 120 degrees geometry to one P(12) and one P(6) atom. In the thirty-fifth O site, O(35) is bonded in a distorted bent 120 degrees geometry to one P(7) and one P(9) atom. In the thirty-sixth O site, O(36) is bonded in a distorted bent 120 degrees geometry to one P(10) and one P(8) atom. is represented by the CIF file [CIF]
data_CsVZn(PO3)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.440
_cell_length_b   8.556
_cell_length_c   8.577
_cell_angle_alpha   104.457
_cell_angle_beta   103.818
_cell_angle_gamma   103.864
_symmetry_Int_Tables_number   1
_cell_volume   421.254
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.545  0.948  0.961  1.0
  O  O1  1  0.100  0.350  0.350  1.0
  O  O2  1  0.903  0.652  0.651  1.0
  O  O3  1  0.950  0.516  0.176  1.0
  O  O4  1  0.963  0.185  0.528  1.0
  O  O5  1  0.037  0.473  0.814  1.0
  O  O6  1  0.055  0.830  0.489  1.0
  O  O7  1  0.659  0.726  0.179  1.0
  O  O8  1  0.664  0.186  0.734  1.0
  O  O9  1  0.339  0.265  0.815  1.0
  O  O10  1  0.346  0.820  0.267  1.0
  O  O11  1  0.048  0.255  0.032  1.0
  O  O12  1  0.037  0.033  0.255  1.0
  O  O13  1  0.954  0.744  0.964  1.0
  O  O14  1  0.937  0.968  0.742  1.0
  O  O15  1  0.363  0.516  0.236  1.0
  O  O16  1  0.366  0.233  0.515  1.0
  O  O17  1  0.631  0.483  0.761  1.0
  O  O18  1  0.636  0.760  0.481  1.0
  P  P19  1  0.101  0.409  0.186  1.0
  P  P20  1  0.101  0.186  0.408  1.0
  P  P21  1  0.896  0.592  0.813  1.0
  P  P22  1  0.897  0.815  0.590  1.0
  P  P23  1  0.500  0.715  0.281  1.0
  P  P24  1  0.499  0.284  0.713  1.0
  V  V25  1  0.003  0.223  0.779  1.0
  Zn  Zn26  1  0.006  0.777  0.226  1.0
[/CIF]
.