The compound described by LiPu2TeO2 crystallizes in the monoclinic Cm space group. Li(1) is bonded in a 5-coordinate geometry to one Pu(2), one Te(1), and four equivalent O(1) atoms. There are two inequivalent Pu sites. In the first Pu site, Pu(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. In the second Pu site, Pu(2) is bonded in a 9-coordinate geometry to one Li(1), four equivalent Te(1), and four equivalent O(1) atoms. Te(1) is bonded in a distorted single-bond geometry to one Li(1) and four equivalent Pu(2) atoms. O(1) is bonded in a 6-coordinate geometry to two equivalent Li(1), two equivalent Pu(1), and two equivalent Pu(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiPu2TeO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.036
_cell_length_b   4.036
_cell_length_c   7.316
_cell_angle_alpha   105.982
_cell_angle_beta   105.982
_cell_angle_gamma   89.916
_symmetry_Int_Tables_number   1
_cell_volume   109.783
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.825  0.825  0.645  1.0
  Pu  Pu1  1  0.338  0.338  0.674  1.0
  Pu  Pu2  1  0.634  0.634  0.270  1.0
  Te  Te3  1  0.010  0.010  0.020  1.0
  O  O4  1  0.255  0.756  0.510  1.0
  O  O5  1  0.756  0.255  0.510  1.0
[/CIF]
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The compound described by LiPu2TeO2 crystallizes in the monoclinic Cm space group. Li(1) is bonded in a 5-coordinate geometry to one Pu(2), one Te(1), and four equivalent O(1) atoms. There are two inequivalent Pu sites. In the first Pu site, Pu(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. In the second Pu site, Pu(2) is bonded in a 9-coordinate geometry to one Li(1), four equivalent Te(1), and four equivalent O(1) atoms. Te(1) is bonded in a distorted single-bond geometry to one Li(1) and four equivalent Pu(2) atoms. O(1) is bonded in a 6-coordinate geometry to two equivalent Li(1), two equivalent Pu(1), and two equivalent Pu(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_LiPu2TeO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.036
_cell_length_b   4.036
_cell_length_c   7.316
_cell_angle_alpha   105.982
_cell_angle_beta   105.982
_cell_angle_gamma   89.916
_symmetry_Int_Tables_number   1
_cell_volume   109.783
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.825  0.825  0.645  1.0
  Pu  Pu1  1  0.338  0.338  0.674  1.0
  Pu  Pu2  1  0.634  0.634  0.270  1.0
  Te  Te3  1  0.010  0.010  0.020  1.0
  O  O4  1  0.255  0.756  0.510  1.0
  O  O5  1  0.756  0.255  0.510  1.0
[/CIF]
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