The structure described by Na2Re(OCl)6 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a 6-coordinate geometry to one O(3), two equivalent O(1), two equivalent O(2), one Cl(1), and one Cl(2) atom. Re(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to two equivalent Na(1) and one O(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one Cl(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Na(1) and one O(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to one Na(1) and one Re(1) atom. In the second Cl site, Cl(2) is bonded in a water-like geometry to one Na(1) and one Re(1) atom. In the third Cl site, Cl(3) is bonded in a bent 120 degrees geometry to one Re(1) and one O(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na2Re(ClO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.052
_cell_length_b   9.336
_cell_length_c   6.839
_cell_angle_alpha   124.423
_cell_angle_beta   68.742
_cell_angle_gamma   121.003
_symmetry_Int_Tables_number   1
_cell_volume   361.653
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.246  0.589  0.935  1.0
  Na  Na1  1  0.754  0.411  0.065  1.0
  Re  Re2  1  0.000  0.000  0.500  1.0
  Cl  Cl3  1  0.213  0.872  0.443  1.0
  Cl  Cl4  1  0.787  0.128  0.557  1.0
  Cl  Cl5  1  0.726  0.725  0.506  1.0
  Cl  Cl6  1  0.274  0.275  0.494  1.0
  Cl  Cl7  1  0.002  0.856  0.098  1.0
  Cl  Cl8  1  0.998  0.144  0.902  1.0
  O  O9  1  0.554  0.525  0.923  1.0
  O  O10  1  0.446  0.475  0.077  1.0
  O  O11  1  0.988  0.644  0.949  1.0
  O  O12  1  0.012  0.356  0.051  1.0
  O  O13  1  0.486  0.058  0.996  1.0
  O  O14  1  0.514  0.942  0.004  1.0
[/CIF]
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The structure described by Na2Re(OCl)6 crystallizes in the triclinic P-1 space group. Na(1) is bonded in a 6-coordinate geometry to one O(3), two equivalent O(1), two equivalent O(2), one Cl(1), and one Cl(2) atom. Re(1) is bonded in an octahedral geometry to two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to two equivalent Na(1) and one O(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one Cl(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Na(1) and one O(3) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to one Na(1) and one Re(1) atom. In the second Cl site, Cl(2) is bonded in a water-like geometry to one Na(1) and one Re(1) atom. In the third Cl site, Cl(3) is bonded in a bent 120 degrees geometry to one Re(1) and one O(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Na2Re(ClO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.052
_cell_length_b   9.336
_cell_length_c   6.839
_cell_angle_alpha   124.423
_cell_angle_beta   68.742
_cell_angle_gamma   121.003
_symmetry_Int_Tables_number   1
_cell_volume   361.653
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.246  0.589  0.935  1.0
  Na  Na1  1  0.754  0.411  0.065  1.0
  Re  Re2  1  0.000  0.000  0.500  1.0
  Cl  Cl3  1  0.213  0.872  0.443  1.0
  Cl  Cl4  1  0.787  0.128  0.557  1.0
  Cl  Cl5  1  0.726  0.725  0.506  1.0
  Cl  Cl6  1  0.274  0.275  0.494  1.0
  Cl  Cl7  1  0.002  0.856  0.098  1.0
  Cl  Cl8  1  0.998  0.144  0.902  1.0
  O  O9  1  0.554  0.525  0.923  1.0
  O  O10  1  0.446  0.475  0.077  1.0
  O  O11  1  0.988  0.644  0.949  1.0
  O  O12  1  0.012  0.356  0.051  1.0
  O  O13  1  0.486  0.058  0.996  1.0
  O  O14  1  0.514  0.942  0.004  1.0
[/CIF]
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