The material described by TmOsGe2 crystallizes in the orthorhombic Pbam space group. There are two inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a 12-coordinate geometry to one Os(2), three equivalent Os(1), one Ge(4), one Ge(5), two equivalent Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. In the second Tm site, Tm(2) is bonded in a 7-coordinate geometry to two equivalent Os(2), four equivalent Os(1), two equivalent Ge(1), two equivalent Ge(3), and three equivalent Ge(5) atoms. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 12-coordinate geometry to two equivalent Tm(2), three equivalent Tm(1), one Os(2), one Ge(2), one Ge(3), one Ge(4), one Ge(5), and two equivalent Ge(1) atoms. In the second Os site, Os(2) is bonded in a 12-coordinate geometry to two equivalent Tm(1), two equivalent Tm(2), two equivalent Os(1), two equivalent Ge(1), two equivalent Ge(4), and two equivalent Ge(5) atoms. There are five inequivalent Ge sites. In the first Ge site, Ge(5) is bonded in a 9-coordinate geometry to two equivalent Tm(1), three equivalent Tm(2), two equivalent Os(1), and two equivalent Os(2) atoms. In the second Ge site, Ge(1) is bonded in a 7-coordinate geometry to one Tm(2), two equivalent Tm(1), one Os(2), two equivalent Os(1), and one Ge(1) atom. In the third Ge site, Ge(2) is bonded in a 7-coordinate geometry to four equivalent Tm(1), two equivalent Os(1), and one Ge(2) atom. In the fourth Ge site, Ge(3) is bonded in a 9-coordinate geometry to two equivalent Tm(2), four equivalent Tm(1), two equivalent Os(1), and one Ge(3) atom. In the fifth Ge site, Ge(4) is bonded in a 6-coordinate geometry to two equivalent Tm(1), two equivalent Os(1), and two equivalent Os(2) atoms. is represented by the CIF card [CIF]
data_TmGe2Os
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.360
_cell_length_b   9.627
_cell_length_c   10.568
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   850.441
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.245  0.823  0.449  1.0
  Tm  Tm1  1  0.245  0.177  0.551  1.0
  Tm  Tm2  1  0.755  0.323  0.051  1.0
  Tm  Tm3  1  0.755  0.677  0.949  1.0
  Tm  Tm4  1  0.755  0.177  0.551  1.0
  Tm  Tm5  1  0.755  0.823  0.449  1.0
  Tm  Tm6  1  0.245  0.677  0.949  1.0
  Tm  Tm7  1  0.245  0.323  0.051  1.0
  Tm  Tm8  1  0.000  0.836  0.177  1.0
  Tm  Tm9  1  0.000  0.164  0.823  1.0
  Tm  Tm10  1  0.000  0.336  0.323  1.0
  Tm  Tm11  1  0.000  0.664  0.677  1.0
  Ge  Ge12  1  0.348  0.842  0.180  1.0
  Ge  Ge13  1  0.348  0.158  0.820  1.0
  Ge  Ge14  1  0.652  0.342  0.320  1.0
  Ge  Ge15  1  0.652  0.658  0.680  1.0
  Ge  Ge16  1  0.652  0.158  0.820  1.0
  Ge  Ge17  1  0.652  0.842  0.180  1.0
  Ge  Ge18  1  0.348  0.658  0.680  1.0
  Ge  Ge19  1  0.348  0.342  0.320  1.0
  Ge  Ge20  1  0.500  0.545  0.118  1.0
  Ge  Ge21  1  0.500  0.455  0.882  1.0
  Ge  Ge22  1  0.500  0.045  0.382  1.0
  Ge  Ge23  1  0.500  0.955  0.618  1.0
  Ge  Ge24  1  0.000  0.536  0.118  1.0
  Ge  Ge25  1  0.000  0.464  0.882  1.0
  Ge  Ge26  1  0.000  0.036  0.382  1.0
  Ge  Ge27  1  0.000  0.964  0.618  1.0
  Ge  Ge28  1  0.500  0.628  0.404  1.0
  Ge  Ge29  1  0.500  0.372  0.596  1.0
  Ge  Ge30  1  0.500  0.128  0.096  1.0
  Ge  Ge31  1  0.500  0.872  0.904  1.0
  Ge  Ge32  1  0.000  0.630  0.399  1.0
  Ge  Ge33  1  0.000  0.370  0.601  1.0
  Ge  Ge34  1  0.000  0.130  0.101  1.0
  Ge  Ge35  1  0.000  0.870  0.899  1.0
  Os  Os36  1  0.251  0.589  0.237  1.0
  Os  Os37  1  0.251  0.411  0.763  1.0
  Os  Os38  1  0.749  0.089  0.263  1.0
  Os  Os39  1  0.749  0.911  0.737  1.0
  Os  Os40  1  0.749  0.411  0.763  1.0
  Os  Os41  1  0.749  0.589  0.237  1.0
  Os  Os42  1  0.251  0.911  0.737  1.0
  Os  Os43  1  0.251  0.089  0.263  1.0
  Os  Os44  1  0.249  0.500  0.500  1.0
  Os  Os45  1  0.751  0.000  0.000  1.0
  Os  Os46  1  0.751  0.500  0.500  1.0
  Os  Os47  1  0.249  0.000  0.000  1.0
[/CIF]
.
The material described by TmOsGe2 crystallizes in the orthorhombic Pbam space group. There are two inequivalent Tm sites. In the first Tm site, Tm(1) is bonded in a 12-coordinate geometry to one Os(2), three equivalent Os(1), one Ge(4), one Ge(5), two equivalent Ge(1), two equivalent Ge(2), and two equivalent Ge(3) atoms. In the second Tm site, Tm(2) is bonded in a 7-coordinate geometry to two equivalent Os(2), four equivalent Os(1), two equivalent Ge(1), two equivalent Ge(3), and three equivalent Ge(5) atoms. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 12-coordinate geometry to two equivalent Tm(2), three equivalent Tm(1), one Os(2), one Ge(2), one Ge(3), one Ge(4), one Ge(5), and two equivalent Ge(1) atoms. In the second Os site, Os(2) is bonded in a 12-coordinate geometry to two equivalent Tm(1), two equivalent Tm(2), two equivalent Os(1), two equivalent Ge(1), two equivalent Ge(4), and two equivalent Ge(5) atoms. There are five inequivalent Ge sites. In the first Ge site, Ge(5) is bonded in a 9-coordinate geometry to two equivalent Tm(1), three equivalent Tm(2), two equivalent Os(1), and two equivalent Os(2) atoms. In the second Ge site, Ge(1) is bonded in a 7-coordinate geometry to one Tm(2), two equivalent Tm(1), one Os(2), two equivalent Os(1), and one Ge(1) atom. In the third Ge site, Ge(2) is bonded in a 7-coordinate geometry to four equivalent Tm(1), two equivalent Os(1), and one Ge(2) atom. In the fourth Ge site, Ge(3) is bonded in a 9-coordinate geometry to two equivalent Tm(2), four equivalent Tm(1), two equivalent Os(1), and one Ge(3) atom. In the fifth Ge site, Ge(4) is bonded in a 6-coordinate geometry to two equivalent Tm(1), two equivalent Os(1), and two equivalent Os(2) atoms. is represented by the CIF card [CIF]
data_TmGe2Os
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.360
_cell_length_b   9.627
_cell_length_c   10.568
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   850.441
_cell_formula_units_Z   12
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tm  Tm0  1  0.245  0.823  0.449  1.0
  Tm  Tm1  1  0.245  0.177  0.551  1.0
  Tm  Tm2  1  0.755  0.323  0.051  1.0
  Tm  Tm3  1  0.755  0.677  0.949  1.0
  Tm  Tm4  1  0.755  0.177  0.551  1.0
  Tm  Tm5  1  0.755  0.823  0.449  1.0
  Tm  Tm6  1  0.245  0.677  0.949  1.0
  Tm  Tm7  1  0.245  0.323  0.051  1.0
  Tm  Tm8  1  0.000  0.836  0.177  1.0
  Tm  Tm9  1  0.000  0.164  0.823  1.0
  Tm  Tm10  1  0.000  0.336  0.323  1.0
  Tm  Tm11  1  0.000  0.664  0.677  1.0
  Ge  Ge12  1  0.348  0.842  0.180  1.0
  Ge  Ge13  1  0.348  0.158  0.820  1.0
  Ge  Ge14  1  0.652  0.342  0.320  1.0
  Ge  Ge15  1  0.652  0.658  0.680  1.0
  Ge  Ge16  1  0.652  0.158  0.820  1.0
  Ge  Ge17  1  0.652  0.842  0.180  1.0
  Ge  Ge18  1  0.348  0.658  0.680  1.0
  Ge  Ge19  1  0.348  0.342  0.320  1.0
  Ge  Ge20  1  0.500  0.545  0.118  1.0
  Ge  Ge21  1  0.500  0.455  0.882  1.0
  Ge  Ge22  1  0.500  0.045  0.382  1.0
  Ge  Ge23  1  0.500  0.955  0.618  1.0
  Ge  Ge24  1  0.000  0.536  0.118  1.0
  Ge  Ge25  1  0.000  0.464  0.882  1.0
  Ge  Ge26  1  0.000  0.036  0.382  1.0
  Ge  Ge27  1  0.000  0.964  0.618  1.0
  Ge  Ge28  1  0.500  0.628  0.404  1.0
  Ge  Ge29  1  0.500  0.372  0.596  1.0
  Ge  Ge30  1  0.500  0.128  0.096  1.0
  Ge  Ge31  1  0.500  0.872  0.904  1.0
  Ge  Ge32  1  0.000  0.630  0.399  1.0
  Ge  Ge33  1  0.000  0.370  0.601  1.0
  Ge  Ge34  1  0.000  0.130  0.101  1.0
  Ge  Ge35  1  0.000  0.870  0.899  1.0
  Os  Os36  1  0.251  0.589  0.237  1.0
  Os  Os37  1  0.251  0.411  0.763  1.0
  Os  Os38  1  0.749  0.089  0.263  1.0
  Os  Os39  1  0.749  0.911  0.737  1.0
  Os  Os40  1  0.749  0.411  0.763  1.0
  Os  Os41  1  0.749  0.589  0.237  1.0
  Os  Os42  1  0.251  0.911  0.737  1.0
  Os  Os43  1  0.251  0.089  0.263  1.0
  Os  Os44  1  0.249  0.500  0.500  1.0
  Os  Os45  1  0.751  0.000  0.000  1.0
  Os  Os46  1  0.751  0.500  0.500  1.0
  Os  Os47  1  0.249  0.000  0.000  1.0
[/CIF]
.