The material structure described by Sb(COO)2(OH) crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(5) atom. Sb(1) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms to form distorted corner-sharing SbO6 pentagonal pyramids. H(1) is bonded in a single-bond geometry to one O(3) atom. There are five inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 120 degrees geometry to one C(2) and one Sb(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one C(1) and one Sb(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one C(2) and one Sb(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Sb(1) and one H(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one C(1) and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbHC2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.030
_cell_length_b   6.496
_cell_length_c   11.376
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   445.602
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.072  0.016  0.500  1.0
  Sb  Sb1  1  0.572  0.484  0.500  1.0
  Sb  Sb2  1  0.428  0.984  1.000  1.0
  Sb  Sb3  1  0.928  0.516  0.000  1.0
  H  H4  1  0.603  0.103  0.464  1.0
  H  H5  1  0.103  0.397  0.536  1.0
  H  H6  1  0.897  0.897  0.964  1.0
  H  H7  1  0.397  0.603  0.036  1.0
  C  C8  1  0.144  0.052  0.226  1.0
  C  C9  1  0.644  0.448  0.774  1.0
  C  C10  1  0.356  0.948  0.726  1.0
  C  C11  1  0.856  0.552  0.274  1.0
  C  C12  1  0.356  0.949  0.273  1.0
  C  C13  1  0.856  0.551  0.727  1.0
  C  C14  1  0.144  0.051  0.773  1.0
  C  C15  1  0.644  0.449  0.227  1.0
  O  O16  1  0.998  0.103  0.300  1.0
  O  O17  1  0.498  0.397  0.700  1.0
  O  O18  1  0.502  0.897  0.800  1.0
  O  O19  1  0.002  0.603  0.200  1.0
  O  O20  1  0.502  0.894  0.201  1.0
  O  O21  1  0.002  0.606  0.799  1.0
  O  O22  1  0.998  0.106  0.701  1.0
  O  O23  1  0.498  0.394  0.299  1.0
  O  O24  1  0.711  0.201  0.498  1.0
  O  O25  1  0.211  0.299  0.502  1.0
  O  O26  1  0.789  0.799  0.998  1.0
  O  O27  1  0.289  0.701  0.002  1.0
  O  O28  1  0.133  0.083  0.116  1.0
  O  O29  1  0.633  0.417  0.884  1.0
  O  O30  1  0.367  0.917  0.616  1.0
  O  O31  1  0.867  0.583  0.384  1.0
  O  O32  1  0.372  0.927  0.385  1.0
  O  O33  1  0.872  0.573  0.615  1.0
  O  O34  1  0.128  0.073  0.885  1.0
  O  O35  1  0.628  0.427  0.115  1.0
[/CIF]
.
The material structure described by Sb(COO)2(OH) crystallizes in the orthorhombic P2_12_12_1 space group. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(5) atom. Sb(1) is bonded to one O(1), one O(2), one O(4), one O(5), and two equivalent O(3) atoms to form distorted corner-sharing SbO6 pentagonal pyramids. H(1) is bonded in a single-bond geometry to one O(3) atom. There are five inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 120 degrees geometry to one C(2) and one Sb(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one C(1) and one Sb(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one C(2) and one Sb(1) atom. In the fourth O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Sb(1) and one H(1) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one C(1) and one Sb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbHC2O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.030
_cell_length_b   6.496
_cell_length_c   11.376
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   445.602
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.072  0.016  0.500  1.0
  Sb  Sb1  1  0.572  0.484  0.500  1.0
  Sb  Sb2  1  0.428  0.984  1.000  1.0
  Sb  Sb3  1  0.928  0.516  0.000  1.0
  H  H4  1  0.603  0.103  0.464  1.0
  H  H5  1  0.103  0.397  0.536  1.0
  H  H6  1  0.897  0.897  0.964  1.0
  H  H7  1  0.397  0.603  0.036  1.0
  C  C8  1  0.144  0.052  0.226  1.0
  C  C9  1  0.644  0.448  0.774  1.0
  C  C10  1  0.356  0.948  0.726  1.0
  C  C11  1  0.856  0.552  0.274  1.0
  C  C12  1  0.356  0.949  0.273  1.0
  C  C13  1  0.856  0.551  0.727  1.0
  C  C14  1  0.144  0.051  0.773  1.0
  C  C15  1  0.644  0.449  0.227  1.0
  O  O16  1  0.998  0.103  0.300  1.0
  O  O17  1  0.498  0.397  0.700  1.0
  O  O18  1  0.502  0.897  0.800  1.0
  O  O19  1  0.002  0.603  0.200  1.0
  O  O20  1  0.502  0.894  0.201  1.0
  O  O21  1  0.002  0.606  0.799  1.0
  O  O22  1  0.998  0.106  0.701  1.0
  O  O23  1  0.498  0.394  0.299  1.0
  O  O24  1  0.711  0.201  0.498  1.0
  O  O25  1  0.211  0.299  0.502  1.0
  O  O26  1  0.789  0.799  0.998  1.0
  O  O27  1  0.289  0.701  0.002  1.0
  O  O28  1  0.133  0.083  0.116  1.0
  O  O29  1  0.633  0.417  0.884  1.0
  O  O30  1  0.367  0.917  0.616  1.0
  O  O31  1  0.867  0.583  0.384  1.0
  O  O32  1  0.372  0.927  0.385  1.0
  O  O33  1  0.872  0.573  0.615  1.0
  O  O34  1  0.128  0.073  0.885  1.0
  O  O35  1  0.628  0.427  0.115  1.0
[/CIF]
.