The structure described by Ag4Te(PO7)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one O(2), one O(4), one O(5), and one O(6) atom. In the second Ag site, Ag(2) is bonded in a square co-planar geometry to one O(1), one O(2), one O(3), and one O(7) atom. P(1) is bonded in a tetrahedral geometry to one O(4), one O(5), one O(6), and one O(7) atom. Te(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a water-like geometry to one Ag(1) and one P(1) atom. In the second O site, O(7) is bonded in a bent 120 degrees geometry to one Ag(2) and one P(1) atom. In the third O site, O(1) is bonded in a bent 150 degrees geometry to one Ag(2) and one Te(1) atom. In the fourth O site, O(2) is bonded in a trigonal planar geometry to one Ag(1), one Ag(2), and one Te(1) atom. In the fifth O site, O(3) is bonded in a bent 150 degrees geometry to one Ag(2) and one Te(1) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one P(1) atom. In the seventh O site, O(5) is bonded in a bent 150 degrees geometry to one Ag(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Ag4Te(PO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   18.794
_cell_length_b   5.596
_cell_length_c   6.695
_cell_angle_alpha   56.018
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   583.941
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.321  0.955  0.426  1.0
  Ag  Ag1  1  0.179  0.955  0.926  1.0
  Ag  Ag2  1  0.679  0.045  0.574  1.0
  Ag  Ag3  1  0.821  0.045  0.074  1.0
  Ag  Ag4  1  0.065  0.765  0.614  1.0
  Ag  Ag5  1  0.435  0.765  0.114  1.0
  Ag  Ag6  1  0.935  0.235  0.386  1.0
  Ag  Ag7  1  0.565  0.235  0.886  1.0
  Te  Te8  1  0.500  0.000  0.500  1.0
  Te  Te9  1  0.000  0.000  0.000  1.0
  P  P10  1  0.168  0.276  0.407  1.0
  P  P11  1  0.332  0.276  0.907  1.0
  P  P12  1  0.832  0.724  0.593  1.0
  P  P13  1  0.668  0.724  0.093  1.0
  O  O14  1  0.449  0.764  0.807  1.0
  O  O15  1  0.051  0.764  0.307  1.0
  O  O16  1  0.551  0.236  0.193  1.0
  O  O17  1  0.949  0.236  0.693  1.0
  O  O18  1  0.577  0.158  0.611  1.0
  O  O19  1  0.923  0.158  0.111  1.0
  O  O20  1  0.423  0.842  0.389  1.0
  O  O21  1  0.077  0.842  0.889  1.0
  O  O22  1  0.443  0.334  0.405  1.0
  O  O23  1  0.057  0.334  0.905  1.0
  O  O24  1  0.557  0.666  0.595  1.0
  O  O25  1  0.943  0.666  0.095  1.0
  O  O26  1  0.285  0.009  0.972  1.0
  O  O27  1  0.215  0.009  0.472  1.0
  O  O28  1  0.715  0.991  0.028  1.0
  O  O29  1  0.785  0.991  0.528  1.0
  O  O30  1  0.199  0.539  0.178  1.0
  O  O31  1  0.301  0.539  0.678  1.0
  O  O32  1  0.801  0.461  0.822  1.0
  O  O33  1  0.699  0.461  0.322  1.0
  O  O34  1  0.173  0.340  0.607  1.0
  O  O35  1  0.327  0.340  0.107  1.0
  O  O36  1  0.827  0.660  0.393  1.0
  O  O37  1  0.673  0.660  0.893  1.0
  O  O38  1  0.091  0.196  0.377  1.0
  O  O39  1  0.409  0.196  0.877  1.0
  O  O40  1  0.909  0.804  0.623  1.0
  O  O41  1  0.591  0.804  0.123  1.0
[/CIF]
.
The structure described by Ag4Te(PO7)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one O(2), one O(4), one O(5), and one O(6) atom. In the second Ag site, Ag(2) is bonded in a square co-planar geometry to one O(1), one O(2), one O(3), and one O(7) atom. P(1) is bonded in a tetrahedral geometry to one O(4), one O(5), one O(6), and one O(7) atom. Te(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are seven inequivalent O sites. In the first O site, O(6) is bonded in a water-like geometry to one Ag(1) and one P(1) atom. In the second O site, O(7) is bonded in a bent 120 degrees geometry to one Ag(2) and one P(1) atom. In the third O site, O(1) is bonded in a bent 150 degrees geometry to one Ag(2) and one Te(1) atom. In the fourth O site, O(2) is bonded in a trigonal planar geometry to one Ag(1), one Ag(2), and one Te(1) atom. In the fifth O site, O(3) is bonded in a bent 150 degrees geometry to one Ag(2) and one Te(1) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one P(1) atom. In the seventh O site, O(5) is bonded in a bent 150 degrees geometry to one Ag(1) and one P(1) atom. is represented by the CIF file [CIF]
data_Ag4Te(PO7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   18.794
_cell_length_b   5.596
_cell_length_c   6.695
_cell_angle_alpha   56.018
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   583.941
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.321  0.955  0.426  1.0
  Ag  Ag1  1  0.179  0.955  0.926  1.0
  Ag  Ag2  1  0.679  0.045  0.574  1.0
  Ag  Ag3  1  0.821  0.045  0.074  1.0
  Ag  Ag4  1  0.065  0.765  0.614  1.0
  Ag  Ag5  1  0.435  0.765  0.114  1.0
  Ag  Ag6  1  0.935  0.235  0.386  1.0
  Ag  Ag7  1  0.565  0.235  0.886  1.0
  Te  Te8  1  0.500  0.000  0.500  1.0
  Te  Te9  1  0.000  0.000  0.000  1.0
  P  P10  1  0.168  0.276  0.407  1.0
  P  P11  1  0.332  0.276  0.907  1.0
  P  P12  1  0.832  0.724  0.593  1.0
  P  P13  1  0.668  0.724  0.093  1.0
  O  O14  1  0.449  0.764  0.807  1.0
  O  O15  1  0.051  0.764  0.307  1.0
  O  O16  1  0.551  0.236  0.193  1.0
  O  O17  1  0.949  0.236  0.693  1.0
  O  O18  1  0.577  0.158  0.611  1.0
  O  O19  1  0.923  0.158  0.111  1.0
  O  O20  1  0.423  0.842  0.389  1.0
  O  O21  1  0.077  0.842  0.889  1.0
  O  O22  1  0.443  0.334  0.405  1.0
  O  O23  1  0.057  0.334  0.905  1.0
  O  O24  1  0.557  0.666  0.595  1.0
  O  O25  1  0.943  0.666  0.095  1.0
  O  O26  1  0.285  0.009  0.972  1.0
  O  O27  1  0.215  0.009  0.472  1.0
  O  O28  1  0.715  0.991  0.028  1.0
  O  O29  1  0.785  0.991  0.528  1.0
  O  O30  1  0.199  0.539  0.178  1.0
  O  O31  1  0.301  0.539  0.678  1.0
  O  O32  1  0.801  0.461  0.822  1.0
  O  O33  1  0.699  0.461  0.322  1.0
  O  O34  1  0.173  0.340  0.607  1.0
  O  O35  1  0.327  0.340  0.107  1.0
  O  O36  1  0.827  0.660  0.393  1.0
  O  O37  1  0.673  0.660  0.893  1.0
  O  O38  1  0.091  0.196  0.377  1.0
  O  O39  1  0.409  0.196  0.877  1.0
  O  O40  1  0.909  0.804  0.623  1.0
  O  O41  1  0.591  0.804  0.123  1.0
[/CIF]
.