The material structure described by PHF2 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four difluorophosphine molecules. P(1) is bonded in a 3-coordinate geometry to one H(1), one F(1), and one F(2) atom. H(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_PHF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.682
_cell_length_b   6.537
_cell_length_c   8.128
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   248.802
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.727  0.411  0.917  1.0
  P  P1  1  0.227  0.089  0.083  1.0
  P  P2  1  0.273  0.911  0.583  1.0
  P  P3  1  0.773  0.589  0.417  1.0
  H  H4  1  0.526  0.551  0.987  1.0
  H  H5  1  0.026  0.949  0.013  1.0
  H  H6  1  0.474  0.051  0.513  1.0
  H  H7  1  0.974  0.449  0.487  1.0
  F  F8  1  0.946  0.624  0.246  1.0
  F  F9  1  0.446  0.876  0.754  1.0
  F  F10  1  0.054  0.124  0.254  1.0
  F  F11  1  0.554  0.376  0.746  1.0
  F  F12  1  0.554  0.416  0.350  1.0
  F  F13  1  0.054  0.084  0.650  1.0
  F  F14  1  0.446  0.916  0.150  1.0
  F  F15  1  0.946  0.584  0.850  1.0
[/CIF]
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The material structure described by PHF2 is Indium-like structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four difluorophosphine molecules. P(1) is bonded in a 3-coordinate geometry to one H(1), one F(1), and one F(2) atom. H(1) is bonded in a single-bond geometry to one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one P(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one P(1) atom. is represented by the CIF card [CIF]
data_PHF2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.682
_cell_length_b   6.537
_cell_length_c   8.128
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   248.802
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.727  0.411  0.917  1.0
  P  P1  1  0.227  0.089  0.083  1.0
  P  P2  1  0.273  0.911  0.583  1.0
  P  P3  1  0.773  0.589  0.417  1.0
  H  H4  1  0.526  0.551  0.987  1.0
  H  H5  1  0.026  0.949  0.013  1.0
  H  H6  1  0.474  0.051  0.513  1.0
  H  H7  1  0.974  0.449  0.487  1.0
  F  F8  1  0.946  0.624  0.246  1.0
  F  F9  1  0.446  0.876  0.754  1.0
  F  F10  1  0.054  0.124  0.254  1.0
  F  F11  1  0.554  0.376  0.746  1.0
  F  F12  1  0.554  0.416  0.350  1.0
  F  F13  1  0.054  0.084  0.650  1.0
  F  F14  1  0.446  0.916  0.150  1.0
  F  F15  1  0.946  0.584  0.850  1.0
[/CIF]
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