The material structure described by N2S3SO3F is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N2S3 clusters and four SO3F clusters. In each N2S3 cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1) atom. In each SO3F cluster, S(4) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one F(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(4) atom. F(1) is bonded in a single-bond geometry to one S(4) atom. is represented by the CIF file [CIF]
data_S4N2O3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.717
_cell_length_b   6.341
_cell_length_c   10.699
_cell_angle_alpha   66.936
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   731.394
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.129  0.166  0.499  1.0
  S  S1  1  0.371  0.166  0.999  1.0
  S  S2  1  0.871  0.834  0.501  1.0
  S  S3  1  0.231  0.807  0.013  1.0
  S  S4  1  0.584  0.984  0.149  1.0
  S  S5  1  0.573  0.595  0.726  1.0
  S  S6  1  0.731  0.193  0.487  1.0
  S  S7  1  0.629  0.834  0.001  1.0
  S  S8  1  0.416  0.016  0.851  1.0
  S  S9  1  0.073  0.405  0.774  1.0
  S  S10  1  0.427  0.405  0.274  1.0
  S  S11  1  0.769  0.193  0.987  1.0
  S  S12  1  0.916  0.984  0.649  1.0
  S  S13  1  0.269  0.807  0.513  1.0
  S  S14  1  0.084  0.016  0.351  1.0
  S  S15  1  0.927  0.595  0.226  1.0
  N  N16  1  0.683  0.172  0.105  1.0
  N  N17  1  0.317  0.828  0.895  1.0
  N  N18  1  0.183  0.828  0.395  1.0
  N  N19  1  0.264  0.001  0.064  1.0
  N  N20  1  0.236  0.001  0.564  1.0
  N  N21  1  0.817  0.172  0.605  1.0
  N  N22  1  0.736  0.999  0.936  1.0
  N  N23  1  0.764  0.999  0.436  1.0
  O  O24  1  0.819  0.687  0.249  1.0
  O  O25  1  0.319  0.313  0.251  1.0
  O  O26  1  0.181  0.313  0.751  1.0
  O  O27  1  0.480  0.757  0.676  1.0
  O  O28  1  0.020  0.757  0.176  1.0
  O  O29  1  0.543  0.374  0.834  1.0
  O  O30  1  0.957  0.374  0.334  1.0
  O  O31  1  0.043  0.626  0.666  1.0
  O  O32  1  0.681  0.687  0.749  1.0
  O  O33  1  0.520  0.243  0.324  1.0
  O  O34  1  0.980  0.243  0.824  1.0
  O  O35  1  0.457  0.626  0.166  1.0
  F  F36  1  0.900  0.522  0.099  1.0
  F  F37  1  0.600  0.522  0.599  1.0
  F  F38  1  0.400  0.478  0.401  1.0
  F  F39  1  0.100  0.478  0.901  1.0
[/CIF]
.
The material structure described by N2S3SO3F is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four N2S3 clusters and four SO3F clusters. In each N2S3 cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one N(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1) atom. In each SO3F cluster, S(4) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one F(1) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(4) atom. F(1) is bonded in a single-bond geometry to one S(4) atom. is represented by the CIF file [CIF]
data_S4N2O3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.717
_cell_length_b   6.341
_cell_length_c   10.699
_cell_angle_alpha   66.936
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   731.394
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.129  0.166  0.499  1.0
  S  S1  1  0.371  0.166  0.999  1.0
  S  S2  1  0.871  0.834  0.501  1.0
  S  S3  1  0.231  0.807  0.013  1.0
  S  S4  1  0.584  0.984  0.149  1.0
  S  S5  1  0.573  0.595  0.726  1.0
  S  S6  1  0.731  0.193  0.487  1.0
  S  S7  1  0.629  0.834  0.001  1.0
  S  S8  1  0.416  0.016  0.851  1.0
  S  S9  1  0.073  0.405  0.774  1.0
  S  S10  1  0.427  0.405  0.274  1.0
  S  S11  1  0.769  0.193  0.987  1.0
  S  S12  1  0.916  0.984  0.649  1.0
  S  S13  1  0.269  0.807  0.513  1.0
  S  S14  1  0.084  0.016  0.351  1.0
  S  S15  1  0.927  0.595  0.226  1.0
  N  N16  1  0.683  0.172  0.105  1.0
  N  N17  1  0.317  0.828  0.895  1.0
  N  N18  1  0.183  0.828  0.395  1.0
  N  N19  1  0.264  0.001  0.064  1.0
  N  N20  1  0.236  0.001  0.564  1.0
  N  N21  1  0.817  0.172  0.605  1.0
  N  N22  1  0.736  0.999  0.936  1.0
  N  N23  1  0.764  0.999  0.436  1.0
  O  O24  1  0.819  0.687  0.249  1.0
  O  O25  1  0.319  0.313  0.251  1.0
  O  O26  1  0.181  0.313  0.751  1.0
  O  O27  1  0.480  0.757  0.676  1.0
  O  O28  1  0.020  0.757  0.176  1.0
  O  O29  1  0.543  0.374  0.834  1.0
  O  O30  1  0.957  0.374  0.334  1.0
  O  O31  1  0.043  0.626  0.666  1.0
  O  O32  1  0.681  0.687  0.749  1.0
  O  O33  1  0.520  0.243  0.324  1.0
  O  O34  1  0.980  0.243  0.824  1.0
  O  O35  1  0.457  0.626  0.166  1.0
  F  F36  1  0.900  0.522  0.099  1.0
  F  F37  1  0.600  0.522  0.599  1.0
  F  F38  1  0.400  0.478  0.401  1.0
  F  F39  1  0.100  0.478  0.901  1.0
[/CIF]
.