The material structure described by Li2V5O10 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(13), one O(19), one O(3), one O(5), and one O(7) atom to form distorted LiO5 square pyramids that share  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  a cornercorner with one V(9)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(9)O6 octahedra, edges with two equivalent V(5)O6 octahedra, and  an edgeedge with one Li(3)O5 square pyramid. The corner-sharing octahedral tilt angles range from 7-72°. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(14), one O(20), one O(4), one O(6), and one O(8) atom. In the third Li site, Li(3) is bonded to one O(1), one O(15), one O(17), one O(5), and one O(7) atom to form distorted LiO5 square pyramids that share  a cornercorner with one V(10)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(7)O6 octahedra, corners with two equivalent V(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(7)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and  an edgeedge with one Li(1)O5 square pyramid. The corner-sharing octahedral tilt angles range from 7-71°. In the fourth Li site, Li(4) is bonded in a 5-coordinate geometry to one O(16), one O(18), one O(2), one O(6), and one O(8) atom. There are ten inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(12), one O(14), one O(15), one O(4), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one V(10)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent V(10)O6 octahedra, edges with two equivalent V(7)O6 octahedra, and  an edgeedge with one Li(3)O5 square pyramid. The corner-sharing octahedral tilt angles range from 14-20°. In the second V site, V(2) is bonded to one O(10), one O(11), one O(13), one O(16), one O(2), and one O(3) atom to form VO6 octahedra that share  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent V(8)O6 octahedra, edges with two equivalent V(9)O6 octahedra, and  an edgeedge with one Li(1)O5 square pyramid. The corner-sharing octahedral tilt angles range from 14-21°. In the third V site, V(3) is bonded to one O(1), one O(15), one O(17), one O(5), one O(7), and one O(9) atom to form distorted VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Li(3)O5 square pyramid, corners with two equivalent Li(1)O5 square pyramids,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(10)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent V(7)O6 octahedra, and edges with two equivalent Li(3)O5 square pyramids. The corner-sharing octahedral tilt angles are 14°. In the fourth V site, V(4) is bonded in a 6-coordinate geometry to one O(10), one O(16), one O(18), one O(2), one O(6), and one O(8) atom. In the fifth V site, V(5) is bonded to one O(11), one O(13), one O(19), one O(3), one O(5), and one O(7) atom to form distorted VO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid, corners with two equivalent Li(3)O5 square pyramids,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, edges with two equivalent V(9)O6 octahedra, and edges with two equivalent Li(1)O5 square pyramids. The corner-sharing octahedral tilt angles are 14°. In the sixth V site, V(6) is bonded in a 6-coordinate geometry to one O(12), one O(14), one O(20), one O(4), one O(6), and one O(8) atom. In the seventh V site, V(7) is bonded to one O(1), one O(12), one O(15), one O(17), one O(4), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Li(3)O5 square pyramid, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(10)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and  an edgeedge with one Li(3)O5 square pyramid. The corner-sharing octahedral tilt angles are 19°. In the eighth V site, V(8) is bonded to one O(10), one O(11), one O(16), one O(18), one O(2), and one O(3) atom to form VO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(9)O6 octahedra. The corner-sharing octahedral tilt angles are 21°. In the ninth V site, V(9) is bonded to one O(10), one O(11), one O(13), one O(19), one O(2), and one O(3) atom to form VO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid, edges with two equivalent V(2)O6 octahedra, edges with two equivalent V(5)O6 octahedra, edges with two equivalent V(8)O6 octahedra, and  an edgeedge with one Li(1)O5 square pyramid. The corner-sharing octahedral tilt angles are 20°. In the tenth V site, V(10) is bonded to one O(1), one O(12), one O(14), one O(20), one O(4), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Li(3)O5 square pyramid,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(7)O6 octahedra. The corner-sharing octahedral tilt angles are 20°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one V(1), one V(10), one V(3), and one V(7) atom to form OLiV4 square pyramids that share  a cornercorner with one O(4)LiV4 square pyramid, corners with two equivalent O(5)Li2V2 tetrahedra,  an edgeedge with one O(4)LiV4 square pyramid, and  an edgeedge with one O(7)Li2V2 tetrahedra. In the second O site, O(2) is bonded to one Li(4), one V(2), one V(4), one V(8), and one V(9) atom to form distorted OLiV4 square pyramids that share  a cornercorner with one O(3)LiV4 square pyramid, corners with two equivalent O(6)Li2V2 tetrahedra,  an edgeedge with one O(3)LiV4 square pyramid, and  an edgeedge with one O(8)Li2V2 tetrahedra. In the third O site, O(3) is bonded to one Li(1), one V(2), one V(5), one V(8), and one V(9) atom to form OLiV4 square pyramids that share  a cornercorner with one O(2)LiV4 square pyramid, corners with two equivalent O(7)Li2V2 tetrahedra,  an edgeedge with one O(2)LiV4 square pyramid, and  an edgeedge with one O(5)Li2V2 tetrahedra. In the fourth O site, O(4) is bonded to one Li(2), one V(1), one V(10), one V(6), and one V(7) atom to form distorted OLiV4 square pyramids that share  a cornercorner with one O(1)LiV4 square pyramid, corners with two equivalent O(8)Li2V2 tetrahedra,  an edgeedge with one O(1)LiV4 square pyramid, and  an edgeedge with one O(6)Li2V2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one V(3), and one V(5) atom to form OLi2V2 tetrahedra that share corners with two equivalent O(1)LiV4 square pyramids,  an edgeedge with one O(3)LiV4 square pyramid, and edges with two equivalent O(7)Li2V2 tetrahedra. In the sixth O site, O(6) is bonded to one Li(2), one Li(4), one V(4), and one V(6) atom to form OLi2V2 tetrahedra that share corners with two equivalent O(2)LiV4 square pyramids,  an edgeedge with one O(4)LiV4 square pyramid, and edges with two equivalent O(8)Li2V2 tetrahedra. In the seventh O site, O(7) is bonded to one Li(1), one Li(3), one V(3), and one V(5) atom to form OLi2V2 tetrahedra that share corners with two equivalent O(3)LiV4 square pyramids,  an edgeedge with one O(1)LiV4 square pyramid, and edges with two equivalent O(5)Li2V2 tetrahedra. In the eighth O site, O(8) is bonded to one Li(2), one Li(4), one V(4), and one V(6) atom to form OLi2V2 tetrahedra that share corners with two equivalent O(4)LiV4 square pyramids,  an edgeedge with one O(2)LiV4 square pyramid, and edges with two equivalent O(6)Li2V2 tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one V(1), one V(10), one V(3), and one V(7) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one V(2), one V(4), one V(8), and one V(9) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one V(2), one V(5), one V(8), and one V(9) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one V(1), one V(10), one V(6), and one V(7) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(2), one V(5), and one V(9) atom. In the fourteenth O site, O(14) is bonded in a see-saw-like geometry to one Li(2), one V(1), one V(10), and one V(6) atom. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one V(3), and one V(7) atom. In the sixteenth O site, O(16) is bonded in a see-saw-like geometry to one Li(4), one V(2), one V(4), and one V(8) atom. In the seventeenth O site, O(17) is bonded in a distorted T-shaped geometry to one Li(3), one V(3), and one V(7) atom. In the eighteenth O site, O(18) is bonded in a distorted T-shaped geometry to one Li(4), one V(4), and one V(8) atom. In the nineteenth O site, O(19) is bonded in a distorted T-shaped geometry to one Li(1), one V(5), and one V(9) atom. In the twentieth O site, O(20) is bonded in a distorted T-shaped geometry to one Li(2), one V(10), and one V(6) atom. is represented by the CIF card [CIF]
data_Li2V5O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.156
_cell_length_b   15.310
_cell_length_c   5.189
_cell_angle_alpha   79.759
_cell_angle_beta   103.669
_cell_angle_gamma   101.155
_symmetry_Int_Tables_number   1
_cell_volume   386.649
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.746  0.197  0.005  1.0
  Li  Li1  1  0.241  0.700  0.513  1.0
  Li  Li2  1  0.754  0.304  0.497  1.0
  Li  Li3  1  0.259  0.800  0.986  1.0
  V  V4  1  0.999  0.501  0.501  1.0
  V  V5  1  0.501  0.999  0.002  1.0
  V  V6  1  0.358  0.342  0.795  1.0
  V  V7  1  0.853  0.843  0.285  1.0
  V  V8  1  0.141  0.158  0.705  1.0
  V  V9  1  0.647  0.657  0.213  1.0
  V  V10  1  0.403  0.447  0.246  1.0
  V  V11  1  0.909  0.948  0.747  1.0
  V  V12  1  0.099  0.053  0.256  1.0
  V  V13  1  0.589  0.551  0.752  1.0
  O  O14  1  0.643  0.430  0.617  1.0
  O  O15  1  0.151  0.936  0.133  1.0
  O  O16  1  0.857  0.069  0.883  1.0
  O  O17  1  0.351  0.564  0.367  1.0
  O  O18  1  0.033  0.255  0.804  1.0
  O  O19  1  0.533  0.752  0.312  1.0
  O  O20  1  0.466  0.245  0.697  1.0
  O  O21  1  0.967  0.748  0.187  1.0
  O  O22  1  0.250  0.466  0.855  1.0
  O  O23  1  0.766  0.977  0.345  1.0
  O  O24  1  0.249  0.034  0.646  1.0
  O  O25  1  0.735  0.523  0.153  1.0
  O  O26  1  0.376  0.109  0.090  1.0
  O  O27  1  0.885  0.609  0.572  1.0
  O  O28  1  0.123  0.391  0.408  1.0
  O  O29  1  0.615  0.891  0.927  1.0
  O  O30  1  0.509  0.343  0.143  1.0
  O  O31  1  0.006  0.845  0.633  1.0
  O  O32  1  0.992  0.157  0.358  1.0
  O  O33  1  0.494  0.656  0.867  1.0
[/CIF]
.
The material structure described by Li2V5O10 crystallizes in the triclinic P1 space group. There are four inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(13), one O(19), one O(3), one O(5), and one O(7) atom to form distorted LiO5 square pyramids that share  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  a cornercorner with one V(9)O6 octahedra, corners with two equivalent V(3)O6 octahedra,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(9)O6 octahedra, edges with two equivalent V(5)O6 octahedra, and  an edgeedge with one Li(3)O5 square pyramid. The corner-sharing octahedral tilt angles range from 7-72°. In the second Li site, Li(2) is bonded in a 5-coordinate geometry to one O(14), one O(20), one O(4), one O(6), and one O(8) atom. In the third Li site, Li(3) is bonded to one O(1), one O(15), one O(17), one O(5), and one O(7) atom to form distorted LiO5 square pyramids that share  a cornercorner with one V(10)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(7)O6 octahedra, corners with two equivalent V(5)O6 octahedra,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(7)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and  an edgeedge with one Li(1)O5 square pyramid. The corner-sharing octahedral tilt angles range from 7-71°. In the fourth Li site, Li(4) is bonded in a 5-coordinate geometry to one O(16), one O(18), one O(2), one O(6), and one O(8) atom. There are ten inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(12), one O(14), one O(15), one O(4), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one V(10)O6 octahedra,  a cornercorner with one V(3)O6 octahedra,  a cornercorner with one V(7)O6 octahedra,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent V(10)O6 octahedra, edges with two equivalent V(7)O6 octahedra, and  an edgeedge with one Li(3)O5 square pyramid. The corner-sharing octahedral tilt angles range from 14-20°. In the second V site, V(2) is bonded to one O(10), one O(11), one O(13), one O(16), one O(2), and one O(3) atom to form VO6 octahedra that share  a cornercorner with one V(5)O6 octahedra,  a cornercorner with one V(8)O6 octahedra,  a cornercorner with one V(9)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent V(8)O6 octahedra, edges with two equivalent V(9)O6 octahedra, and  an edgeedge with one Li(1)O5 square pyramid. The corner-sharing octahedral tilt angles range from 14-21°. In the third V site, V(3) is bonded to one O(1), one O(15), one O(17), one O(5), one O(7), and one O(9) atom to form distorted VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Li(3)O5 square pyramid, corners with two equivalent Li(1)O5 square pyramids,  an edgeedge with one V(1)O6 octahedra,  an edgeedge with one V(10)O6 octahedra,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent V(7)O6 octahedra, and edges with two equivalent Li(3)O5 square pyramids. The corner-sharing octahedral tilt angles are 14°. In the fourth V site, V(4) is bonded in a 6-coordinate geometry to one O(10), one O(16), one O(18), one O(2), one O(6), and one O(8) atom. In the fifth V site, V(5) is bonded to one O(11), one O(13), one O(19), one O(3), one O(5), and one O(7) atom to form distorted VO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid, corners with two equivalent Li(3)O5 square pyramids,  an edgeedge with one V(2)O6 octahedra,  an edgeedge with one V(3)O6 octahedra,  an edgeedge with one V(8)O6 octahedra, edges with two equivalent V(9)O6 octahedra, and edges with two equivalent Li(1)O5 square pyramids. The corner-sharing octahedral tilt angles are 14°. In the sixth V site, V(6) is bonded in a 6-coordinate geometry to one O(12), one O(14), one O(20), one O(4), one O(6), and one O(8) atom. In the seventh V site, V(7) is bonded to one O(1), one O(12), one O(15), one O(17), one O(4), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Li(3)O5 square pyramid, edges with two equivalent V(1)O6 octahedra, edges with two equivalent V(10)O6 octahedra, edges with two equivalent V(3)O6 octahedra, and  an edgeedge with one Li(3)O5 square pyramid. The corner-sharing octahedral tilt angles are 19°. In the eighth V site, V(8) is bonded to one O(10), one O(11), one O(16), one O(18), one O(2), and one O(3) atom to form VO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid,  an edgeedge with one V(5)O6 octahedra, edges with two equivalent V(2)O6 octahedra, and edges with two equivalent V(9)O6 octahedra. The corner-sharing octahedral tilt angles are 21°. In the ninth V site, V(9) is bonded to one O(10), one O(11), one O(13), one O(19), one O(2), and one O(3) atom to form VO6 octahedra that share  a cornercorner with one V(2)O6 octahedra,  a cornercorner with one Li(1)O5 square pyramid, edges with two equivalent V(2)O6 octahedra, edges with two equivalent V(5)O6 octahedra, edges with two equivalent V(8)O6 octahedra, and  an edgeedge with one Li(1)O5 square pyramid. The corner-sharing octahedral tilt angles are 20°. In the tenth V site, V(10) is bonded to one O(1), one O(12), one O(14), one O(20), one O(4), and one O(9) atom to form VO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one Li(3)O5 square pyramid,  an edgeedge with one V(3)O6 octahedra, edges with two equivalent V(1)O6 octahedra, and edges with two equivalent V(7)O6 octahedra. The corner-sharing octahedral tilt angles are 20°. There are twenty inequivalent O sites. In the first O site, O(1) is bonded to one Li(3), one V(1), one V(10), one V(3), and one V(7) atom to form OLiV4 square pyramids that share  a cornercorner with one O(4)LiV4 square pyramid, corners with two equivalent O(5)Li2V2 tetrahedra,  an edgeedge with one O(4)LiV4 square pyramid, and  an edgeedge with one O(7)Li2V2 tetrahedra. In the second O site, O(2) is bonded to one Li(4), one V(2), one V(4), one V(8), and one V(9) atom to form distorted OLiV4 square pyramids that share  a cornercorner with one O(3)LiV4 square pyramid, corners with two equivalent O(6)Li2V2 tetrahedra,  an edgeedge with one O(3)LiV4 square pyramid, and  an edgeedge with one O(8)Li2V2 tetrahedra. In the third O site, O(3) is bonded to one Li(1), one V(2), one V(5), one V(8), and one V(9) atom to form OLiV4 square pyramids that share  a cornercorner with one O(2)LiV4 square pyramid, corners with two equivalent O(7)Li2V2 tetrahedra,  an edgeedge with one O(2)LiV4 square pyramid, and  an edgeedge with one O(5)Li2V2 tetrahedra. In the fourth O site, O(4) is bonded to one Li(2), one V(1), one V(10), one V(6), and one V(7) atom to form distorted OLiV4 square pyramids that share  a cornercorner with one O(1)LiV4 square pyramid, corners with two equivalent O(8)Li2V2 tetrahedra,  an edgeedge with one O(1)LiV4 square pyramid, and  an edgeedge with one O(6)Li2V2 tetrahedra. In the fifth O site, O(5) is bonded to one Li(1), one Li(3), one V(3), and one V(5) atom to form OLi2V2 tetrahedra that share corners with two equivalent O(1)LiV4 square pyramids,  an edgeedge with one O(3)LiV4 square pyramid, and edges with two equivalent O(7)Li2V2 tetrahedra. In the sixth O site, O(6) is bonded to one Li(2), one Li(4), one V(4), and one V(6) atom to form OLi2V2 tetrahedra that share corners with two equivalent O(2)LiV4 square pyramids,  an edgeedge with one O(4)LiV4 square pyramid, and edges with two equivalent O(8)Li2V2 tetrahedra. In the seventh O site, O(7) is bonded to one Li(1), one Li(3), one V(3), and one V(5) atom to form OLi2V2 tetrahedra that share corners with two equivalent O(3)LiV4 square pyramids,  an edgeedge with one O(1)LiV4 square pyramid, and edges with two equivalent O(5)Li2V2 tetrahedra. In the eighth O site, O(8) is bonded to one Li(2), one Li(4), one V(4), and one V(6) atom to form OLi2V2 tetrahedra that share corners with two equivalent O(4)LiV4 square pyramids,  an edgeedge with one O(2)LiV4 square pyramid, and edges with two equivalent O(6)Li2V2 tetrahedra. In the ninth O site, O(9) is bonded in a rectangular see-saw-like geometry to one V(1), one V(10), one V(3), and one V(7) atom. In the tenth O site, O(10) is bonded in a distorted rectangular see-saw-like geometry to one V(2), one V(4), one V(8), and one V(9) atom. In the eleventh O site, O(11) is bonded in a rectangular see-saw-like geometry to one V(2), one V(5), one V(8), and one V(9) atom. In the twelfth O site, O(12) is bonded in a distorted rectangular see-saw-like geometry to one V(1), one V(10), one V(6), and one V(7) atom. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(1), one V(2), one V(5), and one V(9) atom. In the fourteenth O site, O(14) is bonded in a see-saw-like geometry to one Li(2), one V(1), one V(10), and one V(6) atom. In the fifteenth O site, O(15) is bonded in a rectangular see-saw-like geometry to one Li(3), one V(1), one V(3), and one V(7) atom. In the sixteenth O site, O(16) is bonded in a see-saw-like geometry to one Li(4), one V(2), one V(4), and one V(8) atom. In the seventeenth O site, O(17) is bonded in a distorted T-shaped geometry to one Li(3), one V(3), and one V(7) atom. In the eighteenth O site, O(18) is bonded in a distorted T-shaped geometry to one Li(4), one V(4), and one V(8) atom. In the nineteenth O site, O(19) is bonded in a distorted T-shaped geometry to one Li(1), one V(5), and one V(9) atom. In the twentieth O site, O(20) is bonded in a distorted T-shaped geometry to one Li(2), one V(10), and one V(6) atom. is represented by the CIF card [CIF]
data_Li2V5O10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.156
_cell_length_b   15.310
_cell_length_c   5.189
_cell_angle_alpha   79.759
_cell_angle_beta   103.669
_cell_angle_gamma   101.155
_symmetry_Int_Tables_number   1
_cell_volume   386.649
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.746  0.197  0.005  1.0
  Li  Li1  1  0.241  0.700  0.513  1.0
  Li  Li2  1  0.754  0.304  0.497  1.0
  Li  Li3  1  0.259  0.800  0.986  1.0
  V  V4  1  0.999  0.501  0.501  1.0
  V  V5  1  0.501  0.999  0.002  1.0
  V  V6  1  0.358  0.342  0.795  1.0
  V  V7  1  0.853  0.843  0.285  1.0
  V  V8  1  0.141  0.158  0.705  1.0
  V  V9  1  0.647  0.657  0.213  1.0
  V  V10  1  0.403  0.447  0.246  1.0
  V  V11  1  0.909  0.948  0.747  1.0
  V  V12  1  0.099  0.053  0.256  1.0
  V  V13  1  0.589  0.551  0.752  1.0
  O  O14  1  0.643  0.430  0.617  1.0
  O  O15  1  0.151  0.936  0.133  1.0
  O  O16  1  0.857  0.069  0.883  1.0
  O  O17  1  0.351  0.564  0.367  1.0
  O  O18  1  0.033  0.255  0.804  1.0
  O  O19  1  0.533  0.752  0.312  1.0
  O  O20  1  0.466  0.245  0.697  1.0
  O  O21  1  0.967  0.748  0.187  1.0
  O  O22  1  0.250  0.466  0.855  1.0
  O  O23  1  0.766  0.977  0.345  1.0
  O  O24  1  0.249  0.034  0.646  1.0
  O  O25  1  0.735  0.523  0.153  1.0
  O  O26  1  0.376  0.109  0.090  1.0
  O  O27  1  0.885  0.609  0.572  1.0
  O  O28  1  0.123  0.391  0.408  1.0
  O  O29  1  0.615  0.891  0.927  1.0
  O  O30  1  0.509  0.343  0.143  1.0
  O  O31  1  0.006  0.845  0.633  1.0
  O  O32  1  0.992  0.157  0.358  1.0
  O  O33  1  0.494  0.656  0.867  1.0
[/CIF]
.