The compound described by SbO2 crystallizes in the orthorhombic Imma space group. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Sb site, Sb(2) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form edge-sharing SbO6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one Sb(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Sb(1) and two equivalent Sb(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.156
_cell_length_b   6.156
_cell_length_c   6.156
_cell_angle_alpha   117.555
_cell_angle_beta   106.790
_cell_angle_gamma   104.391
_symmetry_Int_Tables_number   1
_cell_volume   176.815
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.566  0.816  0.750  1.0
  Sb  Sb1  1  0.434  0.184  0.250  1.0
  Sb  Sb2  1  0.000  0.000  0.500  1.0
  Sb  Sb3  1  0.000  0.500  0.000  1.0
  O  O4  1  0.264  0.256  0.492  1.0
  O  O5  1  0.177  0.248  0.929  1.0
  O  O6  1  0.264  0.772  0.008  1.0
  O  O7  1  0.819  0.248  0.571  1.0
  O  O8  1  0.181  0.752  0.429  1.0
  O  O9  1  0.823  0.752  0.071  1.0
  O  O10  1  0.736  0.228  0.992  1.0
  O  O11  1  0.736  0.744  0.508  1.0
[/CIF]
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The compound described by SbO2 crystallizes in the orthorhombic Imma space group. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 4-coordinate geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Sb site, Sb(2) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form edge-sharing SbO6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one Sb(2) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Sb(1) and two equivalent Sb(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_SbO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.156
_cell_length_b   6.156
_cell_length_c   6.156
_cell_angle_alpha   117.555
_cell_angle_beta   106.790
_cell_angle_gamma   104.391
_symmetry_Int_Tables_number   1
_cell_volume   176.815
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.566  0.816  0.750  1.0
  Sb  Sb1  1  0.434  0.184  0.250  1.0
  Sb  Sb2  1  0.000  0.000  0.500  1.0
  Sb  Sb3  1  0.000  0.500  0.000  1.0
  O  O4  1  0.264  0.256  0.492  1.0
  O  O5  1  0.177  0.248  0.929  1.0
  O  O6  1  0.264  0.772  0.008  1.0
  O  O7  1  0.819  0.248  0.571  1.0
  O  O8  1  0.181  0.752  0.429  1.0
  O  O9  1  0.823  0.752  0.071  1.0
  O  O10  1  0.736  0.228  0.992  1.0
  O  O11  1  0.736  0.744  0.508  1.0
[/CIF]
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