The crystal structure described by LiAg3O2 crystallizes in the orthorhombic Ibam space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to two equivalent Li(1), one Ag(2), and two equivalent Ag(1) atoms to form a mixture of distorted edge and corner-sharing OLi2Ag3 trigonal bipyramids. is represented by the CIF card [CIF]
data_LiAg3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.655
_cell_length_b   5.968
_cell_length_c   6.446
_cell_angle_alpha   117.574
_cell_angle_beta   116.016
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   167.581
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.250  0.500  0.000  1.0
  Li  Li1  1  0.750  0.500  0.000  1.0
  Ag  Ag2  1  0.000  0.500  0.500  1.0
  Ag  Ag3  1  0.500  0.000  0.500  1.0
  Ag  Ag4  1  0.500  0.500  0.500  1.0
  Ag  Ag5  1  0.500  0.000  0.000  1.0
  Ag  Ag6  1  0.000  0.000  0.000  1.0
  Ag  Ag7  1  0.000  0.000  0.500  1.0
  O  O8  1  0.905  0.586  0.809  1.0
  O  O9  1  0.405  0.224  0.809  1.0
  O  O10  1  0.095  0.414  0.191  1.0
  O  O11  1  0.595  0.776  0.191  1.0
[/CIF]
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The crystal structure described by LiAg3O2 crystallizes in the orthorhombic Ibam space group. Li(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent O(1) atoms. In the second Ag site, Ag(2) is bonded in a linear geometry to two equivalent O(1) atoms. O(1) is bonded to two equivalent Li(1), one Ag(2), and two equivalent Ag(1) atoms to form a mixture of distorted edge and corner-sharing OLi2Ag3 trigonal bipyramids. is represented by the CIF card [CIF]
data_LiAg3O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.655
_cell_length_b   5.968
_cell_length_c   6.446
_cell_angle_alpha   117.574
_cell_angle_beta   116.016
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   167.581
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.250  0.500  0.000  1.0
  Li  Li1  1  0.750  0.500  0.000  1.0
  Ag  Ag2  1  0.000  0.500  0.500  1.0
  Ag  Ag3  1  0.500  0.000  0.500  1.0
  Ag  Ag4  1  0.500  0.500  0.500  1.0
  Ag  Ag5  1  0.500  0.000  0.000  1.0
  Ag  Ag6  1  0.000  0.000  0.000  1.0
  Ag  Ag7  1  0.000  0.000  0.500  1.0
  O  O8  1  0.905  0.586  0.809  1.0
  O  O9  1  0.405  0.224  0.809  1.0
  O  O10  1  0.095  0.414  0.191  1.0
  O  O11  1  0.595  0.776  0.191  1.0
[/CIF]
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