The material described by NiC2H14(N5O3)2(NO3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules and one NiC2H14(N5O3)2 cluster. In the NiC2H14(N5O3)2 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent O(3) atoms. C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(4) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ni(1), one C(1), and one N(5) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one C(1), one N(3), and one H(2) atom. In the third N site, N(3) is bonded in a distorted water-like geometry to one Ni(1), one N(2), one H(3), and one H(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(5) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one N(1), one O(1), and one O(2) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(3) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted water-like geometry to one Ni(1), one H(4), and one H(6) atom. In the second O site, O(1) is bonded in a single-bond geometry to one N(5) atom. In the third O site, O(2) is bonded in a single-bond geometry to one N(5) atom. is represented by the CIF file [CIF]
data_NiH14C2(NO)12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.431
_cell_length_b   7.509
_cell_length_c   8.692
_cell_angle_alpha   96.600
_cell_angle_beta   96.149
_cell_angle_gamma   115.780
_symmetry_Int_Tables_number   1
_cell_volume   427.125
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.500  0.000  0.500  1.0
  H  H1  1  0.482  0.679  0.999  1.0
  H  H2  1  0.518  0.321  0.001  1.0
  H  H3  1  0.155  0.884  0.091  1.0
  H  H4  1  0.845  0.116  0.909  1.0
  H  H5  1  0.274  0.122  0.337  1.0
  H  H6  1  0.726  0.878  0.663  1.0
  H  H7  1  0.768  0.325  0.383  1.0
  H  H8  1  0.232  0.675  0.617  1.0
  H  H9  1  0.255  0.693  0.928  1.0
  H  H10  1  0.745  0.307  0.072  1.0
  H  H11  1  0.713  0.409  0.538  1.0
  H  H12  1  0.287  0.591  0.462  1.0
  H  H13  1  0.118  0.895  0.367  1.0
  H  H14  1  0.882  0.105  0.633  1.0
  C  C15  1  0.395  0.826  0.158  1.0
  C  C16  1  0.605  0.174  0.842  1.0
  N  N17  1  0.540  0.864  0.286  1.0
  N  N18  1  0.460  0.136  0.714  1.0
  N  N19  1  0.259  0.894  0.184  1.0
  N  N20  1  0.741  0.106  0.816  1.0
  N  N21  1  0.257  0.978  0.337  1.0
  N  N22  1  0.743  0.022  0.663  1.0
  N  N23  1  0.381  0.734  0.014  1.0
  N  N24  1  0.619  0.266  0.986  1.0
  N  N25  1  0.680  0.795  0.275  1.0
  N  N26  1  0.320  0.205  0.725  1.0
  N  N27  1  0.067  0.317  0.221  1.0
  N  N28  1  0.933  0.683  0.779  1.0
  O  O29  1  0.684  0.694  0.151  1.0
  O  O30  1  0.316  0.306  0.849  1.0
  O  O31  1  0.807  0.839  0.397  1.0
  O  O32  1  0.193  0.161  0.603  1.0
  O  O33  1  0.667  0.292  0.452  1.0
  O  O34  1  0.333  0.708  0.548  1.0
  O  O35  1  0.237  0.386  0.312  1.0
  O  O36  1  0.763  0.614  0.688  1.0
  O  O37  1  0.954  0.405  0.236  1.0
  O  O38  1  0.046  0.595  0.764  1.0
  O  O39  1  0.009  0.162  0.118  1.0
  O  O40  1  0.991  0.838  0.882  1.0
[/CIF]
.
The material described by NiC2H14(N5O3)2(NO3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two nitric acid molecules and one NiC2H14(N5O3)2 cluster. In the NiC2H14(N5O3)2 cluster, Ni(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent O(3) atoms. C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(4) atom. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ni(1), one C(1), and one N(5) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one C(1), one N(3), and one H(2) atom. In the third N site, N(3) is bonded in a distorted water-like geometry to one Ni(1), one N(2), one H(3), and one H(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one H(1), and one H(5) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one N(1), one O(1), and one O(2) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(3) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted water-like geometry to one Ni(1), one H(4), and one H(6) atom. In the second O site, O(1) is bonded in a single-bond geometry to one N(5) atom. In the third O site, O(2) is bonded in a single-bond geometry to one N(5) atom. is represented by the CIF file [CIF]
data_NiH14C2(NO)12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.431
_cell_length_b   7.509
_cell_length_c   8.692
_cell_angle_alpha   96.600
_cell_angle_beta   96.149
_cell_angle_gamma   115.780
_symmetry_Int_Tables_number   1
_cell_volume   427.125
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ni  Ni0  1  0.500  0.000  0.500  1.0
  H  H1  1  0.482  0.679  0.999  1.0
  H  H2  1  0.518  0.321  0.001  1.0
  H  H3  1  0.155  0.884  0.091  1.0
  H  H4  1  0.845  0.116  0.909  1.0
  H  H5  1  0.274  0.122  0.337  1.0
  H  H6  1  0.726  0.878  0.663  1.0
  H  H7  1  0.768  0.325  0.383  1.0
  H  H8  1  0.232  0.675  0.617  1.0
  H  H9  1  0.255  0.693  0.928  1.0
  H  H10  1  0.745  0.307  0.072  1.0
  H  H11  1  0.713  0.409  0.538  1.0
  H  H12  1  0.287  0.591  0.462  1.0
  H  H13  1  0.118  0.895  0.367  1.0
  H  H14  1  0.882  0.105  0.633  1.0
  C  C15  1  0.395  0.826  0.158  1.0
  C  C16  1  0.605  0.174  0.842  1.0
  N  N17  1  0.540  0.864  0.286  1.0
  N  N18  1  0.460  0.136  0.714  1.0
  N  N19  1  0.259  0.894  0.184  1.0
  N  N20  1  0.741  0.106  0.816  1.0
  N  N21  1  0.257  0.978  0.337  1.0
  N  N22  1  0.743  0.022  0.663  1.0
  N  N23  1  0.381  0.734  0.014  1.0
  N  N24  1  0.619  0.266  0.986  1.0
  N  N25  1  0.680  0.795  0.275  1.0
  N  N26  1  0.320  0.205  0.725  1.0
  N  N27  1  0.067  0.317  0.221  1.0
  N  N28  1  0.933  0.683  0.779  1.0
  O  O29  1  0.684  0.694  0.151  1.0
  O  O30  1  0.316  0.306  0.849  1.0
  O  O31  1  0.807  0.839  0.397  1.0
  O  O32  1  0.193  0.161  0.603  1.0
  O  O33  1  0.667  0.292  0.452  1.0
  O  O34  1  0.333  0.708  0.548  1.0
  O  O35  1  0.237  0.386  0.312  1.0
  O  O36  1  0.763  0.614  0.688  1.0
  O  O37  1  0.954  0.405  0.236  1.0
  O  O38  1  0.046  0.595  0.764  1.0
  O  O39  1  0.009  0.162  0.118  1.0
  O  O40  1  0.991  0.838  0.882  1.0
[/CIF]
.