The compound described by ZrSiO is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Zr(1) is bonded in a 5-coordinate geometry to four equivalent Si(1) and five equivalent O(1) atoms. Si(1) is bonded to four equivalent Zr(1) and four equivalent Si(1) atoms to form distorted SiZr4Si4 hexagonal bipyramids that share corners with four equivalent Si(1)Zr4Si4 hexagonal bipyramids, corners with twelve equivalent O(1)Zr5 trigonal bipyramids, edges with four equivalent Si(1)Zr4Si4 hexagonal bipyramids, edges with four equivalent O(1)Zr5 trigonal bipyramids, and faces with four equivalent Si(1)Zr4Si4 hexagonal bipyramids. O(1) is bonded to five equivalent Zr(1) atoms to form distorted OZr5 trigonal bipyramids that share corners with twelve equivalent Si(1)Zr4Si4 hexagonal bipyramids, corners with four equivalent O(1)Zr5 trigonal bipyramids, edges with four equivalent Si(1)Zr4Si4 hexagonal bipyramids, and edges with eight equivalent O(1)Zr5 trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZrSiO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.320
_cell_length_b   3.320
_cell_length_c   7.352
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   81.034
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.000  0.500  0.692  1.0
  Zr  Zr1  1  0.500  0.000  0.308  1.0
  Si  Si2  1  0.500  0.500  0.000  1.0
  Si  Si3  1  0.000  0.000  0.000  1.0
  O  O4  1  0.000  0.500  0.389  1.0
  O  O5  1  0.500  0.000  0.611  1.0
[/CIF]
.
The compound described by ZrSiO is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. Zr(1) is bonded in a 5-coordinate geometry to four equivalent Si(1) and five equivalent O(1) atoms. Si(1) is bonded to four equivalent Zr(1) and four equivalent Si(1) atoms to form distorted SiZr4Si4 hexagonal bipyramids that share corners with four equivalent Si(1)Zr4Si4 hexagonal bipyramids, corners with twelve equivalent O(1)Zr5 trigonal bipyramids, edges with four equivalent Si(1)Zr4Si4 hexagonal bipyramids, edges with four equivalent O(1)Zr5 trigonal bipyramids, and faces with four equivalent Si(1)Zr4Si4 hexagonal bipyramids. O(1) is bonded to five equivalent Zr(1) atoms to form distorted OZr5 trigonal bipyramids that share corners with twelve equivalent Si(1)Zr4Si4 hexagonal bipyramids, corners with four equivalent O(1)Zr5 trigonal bipyramids, edges with four equivalent Si(1)Zr4Si4 hexagonal bipyramids, and edges with eight equivalent O(1)Zr5 trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZrSiO
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.320
_cell_length_b   3.320
_cell_length_c   7.352
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   81.034
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.000  0.500  0.692  1.0
  Zr  Zr1  1  0.500  0.000  0.308  1.0
  Si  Si2  1  0.500  0.500  0.000  1.0
  Si  Si3  1  0.000  0.000  0.000  1.0
  O  O4  1  0.000  0.500  0.389  1.0
  O  O5  1  0.500  0.000  0.611  1.0
[/CIF]
.