The material structure described by Mn6OF11 crystallizes in the monoclinic C2/m space group. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(1), one F(6), and four equivalent F(2) atoms to form distorted edge-sharing MnO2F5 trigonal bipyramids. In the second Mn site, Mn(2) is bonded in a distorted body-centered cubic geometry to one O(1), one F(1), one F(6), one F(8), two equivalent F(2), and two equivalent F(5) atoms. In the third Mn site, Mn(3) is bonded in a body-centered cubic geometry to one F(1), one F(3), one F(7), one F(8), two equivalent F(4), and two equivalent F(5) atoms. In the fourth Mn site, Mn(4) is bonded in a body-centered cubic geometry to two equivalent F(3), two equivalent F(7), and four equivalent F(4) atoms. In the fifth Mn site, Mn(5) is bonded in a distorted body-centered cubic geometry to one F(1), one F(3), one F(7), one F(8), two equivalent F(4), and two equivalent F(5) atoms. O(1) is bonded to two equivalent Mn(1) and two equivalent Mn(2) atoms to form OMn4 tetrahedra that share corners with two equivalent F(8)Mn4 tetrahedra, corners with four equivalent F(5)Mn4 tetrahedra,  an edgeedge with one O(1)Mn4 tetrahedra, and  an edgeedge with one F(1)Mn4 tetrahedra. There are eight inequivalent F sites. In the first F site, F(5) is bonded to one Mn(3), one Mn(5), and two equivalent Mn(2) atoms to form FMn4 tetrahedra that share corners with two equivalent O(1)Mn4 tetrahedra, corners with two equivalent F(3)Mn4 tetrahedra, corners with two equivalent F(4)Mn4 tetrahedra, corners with two equivalent F(7)Mn4 tetrahedra, corners with four equivalent F(5)Mn4 tetrahedra,  an edgeedge with one F(4)Mn4 tetrahedra, edges with two equivalent F(1)Mn4 tetrahedra, and edges with two equivalent F(8)Mn4 tetrahedra. In the second F site, F(6) is bonded in a distorted trigonal planar geometry to one Mn(1) and two equivalent Mn(2) atoms. In the third F site, F(7) is bonded to one Mn(3), one Mn(5), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the fourth F site, F(8) is bonded to one Mn(3), one Mn(5), and two equivalent Mn(2) atoms to form distorted FMn4 tetrahedra that share corners with two equivalent O(1)Mn4 tetrahedra, corners with two equivalent F(3)Mn4 tetrahedra, corners with four equivalent F(1)Mn4 tetrahedra, corners with four equivalent F(4)Mn4 tetrahedra,  an edgeedge with one F(7)Mn4 tetrahedra, and edges with four equivalent F(5)Mn4 tetrahedra. In the fifth F site, F(1) is bonded to one Mn(3), one Mn(5), and two equivalent Mn(2) atoms to form FMn4 tetrahedra that share corners with two equivalent F(7)Mn4 tetrahedra, corners with four equivalent F(4)Mn4 tetrahedra, corners with four equivalent F(8)Mn4 tetrahedra,  an edgeedge with one O(1)Mn4 tetrahedra,  an edgeedge with one F(3)Mn4 tetrahedra, and edges with four equivalent F(5)Mn4 tetrahedra. In the sixth F site, F(2) is bonded in a 4-coordinate geometry to two equivalent Mn(1) and two equivalent Mn(2) atoms. In the seventh F site, F(3) is bonded to one Mn(3), one Mn(5), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the eighth F site, F(4) is bonded to one Mn(3), one Mn(5), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. is represented by the CIF file [CIF]
data_Mn6OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.284
_cell_length_b   5.284
_cell_length_c   15.578
_cell_angle_alpha   87.891
_cell_angle_beta   87.891
_cell_angle_gamma   88.538
_symmetry_Int_Tables_number   1
_cell_volume   434.229
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.693  0.693  0.000  1.0
  Mn  Mn1  1  0.268  0.764  0.163  1.0
  Mn  Mn2  1  0.750  0.750  0.330  1.0
  Mn  Mn3  1  0.249  0.751  0.500  1.0
  Mn  Mn4  1  0.742  0.742  0.667  1.0
  Mn  Mn5  1  0.236  0.732  0.837  1.0
  Mn  Mn6  1  0.764  0.268  0.163  1.0
  Mn  Mn7  1  0.307  0.307  1.000  1.0
  Mn  Mn8  1  0.250  0.250  0.670  1.0
  Mn  Mn9  1  0.751  0.249  0.500  1.0
  Mn  Mn10  1  0.258  0.258  0.333  1.0
  Mn  Mn11  1  0.732  0.236  0.837  1.0
  O  O12  1  0.507  0.507  0.919  1.0
  O  O13  1  0.493  0.493  0.081  1.0
  F  F14  1  0.523  0.523  0.250  1.0
  F  F15  1  0.983  0.604  0.081  1.0
  F  F16  1  0.517  0.517  0.582  1.0
  F  F17  1  0.983  0.520  0.417  1.0
  F  F18  1  0.976  0.525  0.755  1.0
  F  F19  1  0.024  0.475  0.245  1.0
  F  F20  1  0.017  0.480  0.583  1.0
  F  F21  1  0.017  0.396  0.919  1.0
  F  F22  1  0.477  0.477  0.750  1.0
  F  F23  1  0.483  0.483  0.418  1.0
  F  F24  1  0.396  0.017  0.919  1.0
  F  F25  1  0.480  0.017  0.583  1.0
  F  F26  1  0.475  0.024  0.245  1.0
  F  F27  1  0.111  0.111  0.084  1.0
  F  F28  1  0.018  0.018  0.415  1.0
  F  F29  1  0.025  0.025  0.758  1.0
  F  F30  1  0.520  0.983  0.417  1.0
  F  F31  1  0.604  0.983  0.081  1.0
  F  F32  1  0.525  0.976  0.755  1.0
  F  F33  1  0.982  0.982  0.585  1.0
  F  F34  1  0.889  0.889  0.916  1.0
  F  F35  1  0.975  0.975  0.242  1.0
[/CIF]
.
The material structure described by Mn6OF11 crystallizes in the monoclinic C2/m space group. There are five inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to two equivalent O(1), one F(6), and four equivalent F(2) atoms to form distorted edge-sharing MnO2F5 trigonal bipyramids. In the second Mn site, Mn(2) is bonded in a distorted body-centered cubic geometry to one O(1), one F(1), one F(6), one F(8), two equivalent F(2), and two equivalent F(5) atoms. In the third Mn site, Mn(3) is bonded in a body-centered cubic geometry to one F(1), one F(3), one F(7), one F(8), two equivalent F(4), and two equivalent F(5) atoms. In the fourth Mn site, Mn(4) is bonded in a body-centered cubic geometry to two equivalent F(3), two equivalent F(7), and four equivalent F(4) atoms. In the fifth Mn site, Mn(5) is bonded in a distorted body-centered cubic geometry to one F(1), one F(3), one F(7), one F(8), two equivalent F(4), and two equivalent F(5) atoms. O(1) is bonded to two equivalent Mn(1) and two equivalent Mn(2) atoms to form OMn4 tetrahedra that share corners with two equivalent F(8)Mn4 tetrahedra, corners with four equivalent F(5)Mn4 tetrahedra,  an edgeedge with one O(1)Mn4 tetrahedra, and  an edgeedge with one F(1)Mn4 tetrahedra. There are eight inequivalent F sites. In the first F site, F(5) is bonded to one Mn(3), one Mn(5), and two equivalent Mn(2) atoms to form FMn4 tetrahedra that share corners with two equivalent O(1)Mn4 tetrahedra, corners with two equivalent F(3)Mn4 tetrahedra, corners with two equivalent F(4)Mn4 tetrahedra, corners with two equivalent F(7)Mn4 tetrahedra, corners with four equivalent F(5)Mn4 tetrahedra,  an edgeedge with one F(4)Mn4 tetrahedra, edges with two equivalent F(1)Mn4 tetrahedra, and edges with two equivalent F(8)Mn4 tetrahedra. In the second F site, F(6) is bonded in a distorted trigonal planar geometry to one Mn(1) and two equivalent Mn(2) atoms. In the third F site, F(7) is bonded to one Mn(3), one Mn(5), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the fourth F site, F(8) is bonded to one Mn(3), one Mn(5), and two equivalent Mn(2) atoms to form distorted FMn4 tetrahedra that share corners with two equivalent O(1)Mn4 tetrahedra, corners with two equivalent F(3)Mn4 tetrahedra, corners with four equivalent F(1)Mn4 tetrahedra, corners with four equivalent F(4)Mn4 tetrahedra,  an edgeedge with one F(7)Mn4 tetrahedra, and edges with four equivalent F(5)Mn4 tetrahedra. In the fifth F site, F(1) is bonded to one Mn(3), one Mn(5), and two equivalent Mn(2) atoms to form FMn4 tetrahedra that share corners with two equivalent F(7)Mn4 tetrahedra, corners with four equivalent F(4)Mn4 tetrahedra, corners with four equivalent F(8)Mn4 tetrahedra,  an edgeedge with one O(1)Mn4 tetrahedra,  an edgeedge with one F(3)Mn4 tetrahedra, and edges with four equivalent F(5)Mn4 tetrahedra. In the sixth F site, F(2) is bonded in a 4-coordinate geometry to two equivalent Mn(1) and two equivalent Mn(2) atoms. In the seventh F site, F(3) is bonded to one Mn(3), one Mn(5), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. In the eighth F site, F(4) is bonded to one Mn(3), one Mn(5), and two equivalent Mn(4) atoms to form a mixture of corner and edge-sharing FMn4 tetrahedra. is represented by the CIF file [CIF]
data_Mn6OF11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.284
_cell_length_b   5.284
_cell_length_c   15.578
_cell_angle_alpha   87.891
_cell_angle_beta   87.891
_cell_angle_gamma   88.538
_symmetry_Int_Tables_number   1
_cell_volume   434.229
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.693  0.693  0.000  1.0
  Mn  Mn1  1  0.268  0.764  0.163  1.0
  Mn  Mn2  1  0.750  0.750  0.330  1.0
  Mn  Mn3  1  0.249  0.751  0.500  1.0
  Mn  Mn4  1  0.742  0.742  0.667  1.0
  Mn  Mn5  1  0.236  0.732  0.837  1.0
  Mn  Mn6  1  0.764  0.268  0.163  1.0
  Mn  Mn7  1  0.307  0.307  1.000  1.0
  Mn  Mn8  1  0.250  0.250  0.670  1.0
  Mn  Mn9  1  0.751  0.249  0.500  1.0
  Mn  Mn10  1  0.258  0.258  0.333  1.0
  Mn  Mn11  1  0.732  0.236  0.837  1.0
  O  O12  1  0.507  0.507  0.919  1.0
  O  O13  1  0.493  0.493  0.081  1.0
  F  F14  1  0.523  0.523  0.250  1.0
  F  F15  1  0.983  0.604  0.081  1.0
  F  F16  1  0.517  0.517  0.582  1.0
  F  F17  1  0.983  0.520  0.417  1.0
  F  F18  1  0.976  0.525  0.755  1.0
  F  F19  1  0.024  0.475  0.245  1.0
  F  F20  1  0.017  0.480  0.583  1.0
  F  F21  1  0.017  0.396  0.919  1.0
  F  F22  1  0.477  0.477  0.750  1.0
  F  F23  1  0.483  0.483  0.418  1.0
  F  F24  1  0.396  0.017  0.919  1.0
  F  F25  1  0.480  0.017  0.583  1.0
  F  F26  1  0.475  0.024  0.245  1.0
  F  F27  1  0.111  0.111  0.084  1.0
  F  F28  1  0.018  0.018  0.415  1.0
  F  F29  1  0.025  0.025  0.758  1.0
  F  F30  1  0.520  0.983  0.417  1.0
  F  F31  1  0.604  0.983  0.081  1.0
  F  F32  1  0.525  0.976  0.755  1.0
  F  F33  1  0.982  0.982  0.585  1.0
  F  F34  1  0.889  0.889  0.916  1.0
  F  F35  1  0.975  0.975  0.242  1.0
[/CIF]
.