The compound described by Sb5S3O5 crystallizes in the triclinic P1 space group. There are seventeen inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted see-saw-like geometry to one O(13,14); one O(17,18); one O(2,4); and one O(6,8) atom. In the second Sb site, Sb(2) is bonded in a distorted see-saw-like geometry to one O(1); one O(13,14); one O(17,18); and one O(5) atom. In the third Sb site, Sb(3) is bonded in a distorted see-saw-like geometry to one O(15); one O(19); one O(2,4); and one O(6,8) atom. In the fourth Sb site, Sb(4) is bonded in a distorted see-saw-like geometry to one O(16), one O(20), one O(3), and one O(7) atom. In the fifth Sb site, Sb(5) is bonded in a distorted rectangular see-saw-like geometry to one O(17,18); one O(9,10); and two equivalent O(2,4) atoms. In the sixth Sb site, Sb(6) is bonded in a distorted rectangular see-saw-like geometry to one O(1); one O(17,18); one O(3); and one O(9,10) atom. In the seventh Sb site, Sb(7) is bonded in a distorted rectangular see-saw-like geometry to one O(12); one O(19); and two equivalent O(2,4) atoms. In the eighth Sb site, Sb(8) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(11), one O(20), and one O(3) atom. In the ninth Sb site, Sb(9) is bonded in a distorted T-shaped geometry to one O(13,14); one O(17,18); and one O(9,10) atom. In the tenth Sb site, Sb(10) is bonded in a distorted T-shaped geometry to one O(13,14); one O(17,18); and one O(9,10) atom. In the eleventh Sb site, Sb(11) is bonded in a distorted T-shaped geometry to one O(11), one O(15), and one O(20) atom. In the twelfth Sb site, Sb(12) is bonded in a distorted T-shaped geometry to one O(12), one O(16), and one O(19) atom. In the thirteenth Sb site, Sb(13) is bonded in a 1-coordinate geometry to one S(11), one S(2), one S(5), and one O(5) atom. In the fourteenth Sb site, Sb(14,16) is bonded in a 1-coordinate geometry to one S(1,3); one S(10,12); one S(6,8); and one O(6,8) atom. In the fifteenth Sb site, Sb(15) is bonded in a 1-coordinate geometry to one S(4), one S(7), one S(9), and one O(7) atom. In the sixteenth Sb site, Sb(17,18,19) is bonded in a distorted trigonal non-coplanar geometry to one S(1,3); one S(10,12); and one S(6,8) atom. In the seventeenth Sb site, Sb(20) is bonded in a distorted trigonal non-coplanar geometry to one S(11), one S(2), and one S(7) atom. There are nine inequivalent S sites. In the first S site, S(1,3) is bonded in a water-like geometry to one Sb(14,16) and one Sb(17,18,19) atom. In the second S site, S(2) is bonded in a water-like geometry to one Sb(13) and one Sb(20) atom. In the third S site, S(4) is bonded in a water-like geometry to one Sb(15) and one Sb(17,18,19) atom. In the fourth S site, S(5) is bonded in a water-like geometry to one Sb(13) and one Sb(17,18,19) atom. In the fifth S site, S(6,8) is bonded in a water-like geometry to one Sb(14,16) and one Sb(17,18,19) atom. In the sixth S site, S(7) is bonded in a water-like geometry to one Sb(15) and one Sb(20) atom. In the seventh S site, S(9) is bonded in an L-shaped geometry to one Sb(15) and one Sb(17,18,19) atom. In the eighth S site, S(10,12) is bonded in an L-shaped geometry to one Sb(14,16) and one Sb(17,18,19) atom. In the ninth S site, S(11) is bonded in an L-shaped geometry to one Sb(13) and one Sb(20) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Sb(2), one Sb(6), and one Sb(8) atom. In the second O site, O(2,4) is bonded in a 3-coordinate geometry to one Sb(1), one Sb(5), and one Sb(7) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Sb(4), one Sb(6), and one Sb(8) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Sb(13) and one Sb(2) atom. In the fifth O site, O(6,8) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(14,16) atom. In the sixth O site, O(7) is bonded in a bent 120 degrees geometry to one Sb(15) and one Sb(4) atom. In the seventh O site, O(9,10) is bonded in a bent 120 degrees geometry to one Sb(6) and one Sb(9) atom. In the eighth O site, O(11) is bonded in a bent 120 degrees geometry to one Sb(11) and one Sb(8) atom. In the ninth O site, O(12) is bonded in a bent 120 degrees geometry to one Sb(12) and one Sb(7) atom. In the tenth O site, O(13,14) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one Sb(9) atom. In the eleventh O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Sb(11) and one Sb(3) atom. In the twelfth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Sb(12) and one Sb(4) atom. In the thirteenth O site, O(17,18) is bonded in a distorted trigonal planar geometry to one Sb(1), one Sb(10), and one Sb(5) atom. In the fourteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Sb(12), one Sb(3), and one Sb(7) atom. In the fifteenth O site, O(20) is bonded in a distorted trigonal planar geometry to one Sb(11), one Sb(4), and one Sb(8) atom. is represented by the CIF card [CIF]
data_Sb5S3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.592
_cell_length_b   13.592
_cell_length_c   17.063
_cell_angle_alpha   65.153
_cell_angle_beta   65.153
_cell_angle_gamma   24.782
_symmetry_Int_Tables_number   1
_cell_volume   1192.768
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.031  0.060  0.086  1.0
  Sb  Sb1  1  0.940  0.969  0.414  1.0
  Sb  Sb2  1  0.969  0.940  0.914  1.0
  Sb  Sb3  1  0.060  0.031  0.586  1.0
  Sb  Sb4  1  0.522  0.367  0.085  1.0
  Sb  Sb5  1  0.633  0.478  0.415  1.0
  Sb  Sb6  1  0.478  0.633  0.915  1.0
  Sb  Sb7  1  0.367  0.522  0.585  1.0
  Sb  Sb8  1  0.206  0.970  0.259  1.0
  Sb  Sb9  1  0.030  0.794  0.241  1.0
  Sb  Sb10  1  0.794  0.030  0.741  1.0
  Sb  Sb11  1  0.970  0.206  0.759  1.0
  Sb  Sb12  1  0.470  0.198  0.456  1.0
  Sb  Sb13  1  0.802  0.530  0.044  1.0
  Sb  Sb14  1  0.530  0.802  0.544  1.0
  Sb  Sb15  1  0.198  0.470  0.956  1.0
  Sb  Sb16  1  0.690  0.844  0.133  1.0
  Sb  Sb17  1  0.156  0.310  0.367  1.0
  Sb  Sb18  1  0.310  0.156  0.867  1.0
  Sb  Sb19  1  0.844  0.690  0.633  1.0
  S  S20  1  0.233  0.179  0.025  1.0
  S  S21  1  0.821  0.767  0.475  1.0
  S  S22  1  0.767  0.821  0.975  1.0
  S  S23  1  0.179  0.233  0.525  1.0
  S  S24  1  0.413  0.238  0.315  1.0
  S  S25  1  0.762  0.587  0.185  1.0
  S  S26  1  0.591  0.751  0.686  1.0
  S  S27  1  0.238  0.413  0.815  1.0
  S  S28  1  0.428  0.922  0.366  1.0
  S  S29  1  0.078  0.572  0.134  1.0
  S  S30  1  0.566  0.074  0.636  1.0
  S  S31  1  0.922  0.428  0.866  1.0
  O  O32  1  0.641  0.305  0.483  1.0
  O  O33  1  0.695  0.359  0.017  1.0
  O  O34  1  0.359  0.695  0.517  1.0
  O  O35  1  0.305  0.641  0.983  1.0
  O  O36  1  0.648  0.173  0.385  1.0
  O  O37  1  0.827  0.352  0.115  1.0
  O  O38  1  0.352  0.827  0.615  1.0
  O  O39  1  0.173  0.648  0.885  1.0
  O  O40  1  0.396  0.685  0.339  1.0
  O  O41  1  0.315  0.604  0.161  1.0
  O  O42  1  0.604  0.315  0.661  1.0
  O  O43  1  0.685  0.396  0.839  1.0
  O  O44  1  0.243  0.879  0.171  1.0
  O  O45  1  0.121  0.757  0.329  1.0
  O  O46  1  0.757  0.121  0.829  1.0
  O  O47  1  0.879  0.243  0.671  1.0
  O  O48  1  0.847  0.086  0.167  1.0
  O  O49  1  0.914  0.153  0.333  1.0
  O  O50  1  0.153  0.914  0.833  1.0
  O  O51  1  0.086  0.847  0.667  1.0
[/CIF]
.
The compound described by Sb5S3O5 crystallizes in the triclinic P1 space group. There are seventeen inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a distorted see-saw-like geometry to one O(13,14); one O(17,18); one O(2,4); and one O(6,8) atom. In the second Sb site, Sb(2) is bonded in a distorted see-saw-like geometry to one O(1); one O(13,14); one O(17,18); and one O(5) atom. In the third Sb site, Sb(3) is bonded in a distorted see-saw-like geometry to one O(15); one O(19); one O(2,4); and one O(6,8) atom. In the fourth Sb site, Sb(4) is bonded in a distorted see-saw-like geometry to one O(16), one O(20), one O(3), and one O(7) atom. In the fifth Sb site, Sb(5) is bonded in a distorted rectangular see-saw-like geometry to one O(17,18); one O(9,10); and two equivalent O(2,4) atoms. In the sixth Sb site, Sb(6) is bonded in a distorted rectangular see-saw-like geometry to one O(1); one O(17,18); one O(3); and one O(9,10) atom. In the seventh Sb site, Sb(7) is bonded in a distorted rectangular see-saw-like geometry to one O(12); one O(19); and two equivalent O(2,4) atoms. In the eighth Sb site, Sb(8) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(11), one O(20), and one O(3) atom. In the ninth Sb site, Sb(9) is bonded in a distorted T-shaped geometry to one O(13,14); one O(17,18); and one O(9,10) atom. In the tenth Sb site, Sb(10) is bonded in a distorted T-shaped geometry to one O(13,14); one O(17,18); and one O(9,10) atom. In the eleventh Sb site, Sb(11) is bonded in a distorted T-shaped geometry to one O(11), one O(15), and one O(20) atom. In the twelfth Sb site, Sb(12) is bonded in a distorted T-shaped geometry to one O(12), one O(16), and one O(19) atom. In the thirteenth Sb site, Sb(13) is bonded in a 1-coordinate geometry to one S(11), one S(2), one S(5), and one O(5) atom. In the fourteenth Sb site, Sb(14,16) is bonded in a 1-coordinate geometry to one S(1,3); one S(10,12); one S(6,8); and one O(6,8) atom. In the fifteenth Sb site, Sb(15) is bonded in a 1-coordinate geometry to one S(4), one S(7), one S(9), and one O(7) atom. In the sixteenth Sb site, Sb(17,18,19) is bonded in a distorted trigonal non-coplanar geometry to one S(1,3); one S(10,12); and one S(6,8) atom. In the seventeenth Sb site, Sb(20) is bonded in a distorted trigonal non-coplanar geometry to one S(11), one S(2), and one S(7) atom. There are nine inequivalent S sites. In the first S site, S(1,3) is bonded in a water-like geometry to one Sb(14,16) and one Sb(17,18,19) atom. In the second S site, S(2) is bonded in a water-like geometry to one Sb(13) and one Sb(20) atom. In the third S site, S(4) is bonded in a water-like geometry to one Sb(15) and one Sb(17,18,19) atom. In the fourth S site, S(5) is bonded in a water-like geometry to one Sb(13) and one Sb(17,18,19) atom. In the fifth S site, S(6,8) is bonded in a water-like geometry to one Sb(14,16) and one Sb(17,18,19) atom. In the sixth S site, S(7) is bonded in a water-like geometry to one Sb(15) and one Sb(20) atom. In the seventh S site, S(9) is bonded in an L-shaped geometry to one Sb(15) and one Sb(17,18,19) atom. In the eighth S site, S(10,12) is bonded in an L-shaped geometry to one Sb(14,16) and one Sb(17,18,19) atom. In the ninth S site, S(11) is bonded in an L-shaped geometry to one Sb(13) and one Sb(20) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Sb(2), one Sb(6), and one Sb(8) atom. In the second O site, O(2,4) is bonded in a 3-coordinate geometry to one Sb(1), one Sb(5), and one Sb(7) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Sb(4), one Sb(6), and one Sb(8) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Sb(13) and one Sb(2) atom. In the fifth O site, O(6,8) is bonded in a bent 120 degrees geometry to one Sb(1) and one Sb(14,16) atom. In the sixth O site, O(7) is bonded in a bent 120 degrees geometry to one Sb(15) and one Sb(4) atom. In the seventh O site, O(9,10) is bonded in a bent 120 degrees geometry to one Sb(6) and one Sb(9) atom. In the eighth O site, O(11) is bonded in a bent 120 degrees geometry to one Sb(11) and one Sb(8) atom. In the ninth O site, O(12) is bonded in a bent 120 degrees geometry to one Sb(12) and one Sb(7) atom. In the tenth O site, O(13,14) is bonded in a distorted bent 120 degrees geometry to one Sb(1) and one Sb(9) atom. In the eleventh O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Sb(11) and one Sb(3) atom. In the twelfth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Sb(12) and one Sb(4) atom. In the thirteenth O site, O(17,18) is bonded in a distorted trigonal planar geometry to one Sb(1), one Sb(10), and one Sb(5) atom. In the fourteenth O site, O(19) is bonded in a distorted trigonal planar geometry to one Sb(12), one Sb(3), and one Sb(7) atom. In the fifteenth O site, O(20) is bonded in a distorted trigonal planar geometry to one Sb(11), one Sb(4), and one Sb(8) atom. is represented by the CIF card [CIF]
data_Sb5S3O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   13.592
_cell_length_b   13.592
_cell_length_c   17.063
_cell_angle_alpha   65.153
_cell_angle_beta   65.153
_cell_angle_gamma   24.782
_symmetry_Int_Tables_number   1
_cell_volume   1192.768
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.031  0.060  0.086  1.0
  Sb  Sb1  1  0.940  0.969  0.414  1.0
  Sb  Sb2  1  0.969  0.940  0.914  1.0
  Sb  Sb3  1  0.060  0.031  0.586  1.0
  Sb  Sb4  1  0.522  0.367  0.085  1.0
  Sb  Sb5  1  0.633  0.478  0.415  1.0
  Sb  Sb6  1  0.478  0.633  0.915  1.0
  Sb  Sb7  1  0.367  0.522  0.585  1.0
  Sb  Sb8  1  0.206  0.970  0.259  1.0
  Sb  Sb9  1  0.030  0.794  0.241  1.0
  Sb  Sb10  1  0.794  0.030  0.741  1.0
  Sb  Sb11  1  0.970  0.206  0.759  1.0
  Sb  Sb12  1  0.470  0.198  0.456  1.0
  Sb  Sb13  1  0.802  0.530  0.044  1.0
  Sb  Sb14  1  0.530  0.802  0.544  1.0
  Sb  Sb15  1  0.198  0.470  0.956  1.0
  Sb  Sb16  1  0.690  0.844  0.133  1.0
  Sb  Sb17  1  0.156  0.310  0.367  1.0
  Sb  Sb18  1  0.310  0.156  0.867  1.0
  Sb  Sb19  1  0.844  0.690  0.633  1.0
  S  S20  1  0.233  0.179  0.025  1.0
  S  S21  1  0.821  0.767  0.475  1.0
  S  S22  1  0.767  0.821  0.975  1.0
  S  S23  1  0.179  0.233  0.525  1.0
  S  S24  1  0.413  0.238  0.315  1.0
  S  S25  1  0.762  0.587  0.185  1.0
  S  S26  1  0.591  0.751  0.686  1.0
  S  S27  1  0.238  0.413  0.815  1.0
  S  S28  1  0.428  0.922  0.366  1.0
  S  S29  1  0.078  0.572  0.134  1.0
  S  S30  1  0.566  0.074  0.636  1.0
  S  S31  1  0.922  0.428  0.866  1.0
  O  O32  1  0.641  0.305  0.483  1.0
  O  O33  1  0.695  0.359  0.017  1.0
  O  O34  1  0.359  0.695  0.517  1.0
  O  O35  1  0.305  0.641  0.983  1.0
  O  O36  1  0.648  0.173  0.385  1.0
  O  O37  1  0.827  0.352  0.115  1.0
  O  O38  1  0.352  0.827  0.615  1.0
  O  O39  1  0.173  0.648  0.885  1.0
  O  O40  1  0.396  0.685  0.339  1.0
  O  O41  1  0.315  0.604  0.161  1.0
  O  O42  1  0.604  0.315  0.661  1.0
  O  O43  1  0.685  0.396  0.839  1.0
  O  O44  1  0.243  0.879  0.171  1.0
  O  O45  1  0.121  0.757  0.329  1.0
  O  O46  1  0.757  0.121  0.829  1.0
  O  O47  1  0.879  0.243  0.671  1.0
  O  O48  1  0.847  0.086  0.167  1.0
  O  O49  1  0.914  0.153  0.333  1.0
  O  O50  1  0.153  0.914  0.833  1.0
  O  O51  1  0.086  0.847  0.667  1.0
[/CIF]
.