The material structure described by N2NS2O6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight ammonia atoms and four NS2O6 clusters. In each NS2O6 cluster, N(2) is bonded in a bent 150 degrees geometry to two equivalent S(1) atoms. S(1) is bonded to one N(2), one O(1), one O(2), and one O(3) atom to form corner-sharing SNO3 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_S2(NO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.583
_cell_length_b   7.583
_cell_length_c   7.495
_cell_angle_alpha   84.367
_cell_angle_beta   84.367
_cell_angle_gamma   63.509
_symmetry_Int_Tables_number   1
_cell_volume   383.100
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.778  0.434  0.122  1.0
  S  S1  1  0.566  0.222  0.378  1.0
  S  S2  1  0.222  0.566  0.878  1.0
  S  S3  1  0.434  0.778  0.622  1.0
  N  N4  1  0.289  0.012  0.151  1.0
  N  N5  1  0.988  0.711  0.349  1.0
  N  N6  1  0.711  0.988  0.849  1.0
  N  N7  1  0.012  0.289  0.651  1.0
  N  N8  1  0.603  0.397  0.250  1.0
  N  N9  1  0.397  0.603  0.750  1.0
  O  O10  1  0.811  0.313  0.971  1.0
  O  O11  1  0.687  0.189  0.529  1.0
  O  O12  1  0.189  0.687  0.029  1.0
  O  O13  1  0.313  0.811  0.471  1.0
  O  O14  1  0.690  0.645  0.081  1.0
  O  O15  1  0.355  0.310  0.419  1.0
  O  O16  1  0.310  0.355  0.919  1.0
  O  O17  1  0.645  0.690  0.581  1.0
  O  O18  1  0.945  0.361  0.238  1.0
  O  O19  1  0.639  0.055  0.262  1.0
  O  O20  1  0.055  0.639  0.762  1.0
  O  O21  1  0.361  0.945  0.738  1.0
[/CIF]
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The material structure described by N2NS2O6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight ammonia atoms and four NS2O6 clusters. In each NS2O6 cluster, N(2) is bonded in a bent 150 degrees geometry to two equivalent S(1) atoms. S(1) is bonded to one N(2), one O(1), one O(2), and one O(3) atom to form corner-sharing SNO3 tetrahedra. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_S2(NO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.583
_cell_length_b   7.583
_cell_length_c   7.495
_cell_angle_alpha   84.367
_cell_angle_beta   84.367
_cell_angle_gamma   63.509
_symmetry_Int_Tables_number   1
_cell_volume   383.100
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.778  0.434  0.122  1.0
  S  S1  1  0.566  0.222  0.378  1.0
  S  S2  1  0.222  0.566  0.878  1.0
  S  S3  1  0.434  0.778  0.622  1.0
  N  N4  1  0.289  0.012  0.151  1.0
  N  N5  1  0.988  0.711  0.349  1.0
  N  N6  1  0.711  0.988  0.849  1.0
  N  N7  1  0.012  0.289  0.651  1.0
  N  N8  1  0.603  0.397  0.250  1.0
  N  N9  1  0.397  0.603  0.750  1.0
  O  O10  1  0.811  0.313  0.971  1.0
  O  O11  1  0.687  0.189  0.529  1.0
  O  O12  1  0.189  0.687  0.029  1.0
  O  O13  1  0.313  0.811  0.471  1.0
  O  O14  1  0.690  0.645  0.081  1.0
  O  O15  1  0.355  0.310  0.419  1.0
  O  O16  1  0.310  0.355  0.919  1.0
  O  O17  1  0.645  0.690  0.581  1.0
  O  O18  1  0.945  0.361  0.238  1.0
  O  O19  1  0.639  0.055  0.262  1.0
  O  O20  1  0.055  0.639  0.762  1.0
  O  O21  1  0.361  0.945  0.738  1.0
[/CIF]
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