The material described by Na2Zn(SO6)2 crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded in a 7-coordinate geometry to one O(1), one O(4), one O(6), two equivalent O(2), and two equivalent O(5) atoms. Zn(1) is bonded in a square co-planar geometry to two equivalent O(3) and two equivalent O(6) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Na(1), one S(1), and one O(5) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Na(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Na(1), one O(1), and one O(6) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(1), one Zn(1), and one O(5) atom. is represented by the CIF card [CIF]
data_Na2Zn(SO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.508
_cell_length_b   8.075
_cell_length_c   11.817
_cell_angle_alpha   90.000
_cell_angle_beta   92.453
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   525.061
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.846  0.534  0.127  1.0
  Na  Na1  1  0.154  0.034  0.373  1.0
  Na  Na2  1  0.154  0.466  0.873  1.0
  Na  Na3  1  0.846  0.966  0.627  1.0
  Zn  Zn4  1  0.000  0.500  0.500  1.0
  Zn  Zn5  1  0.000  0.000  0.000  1.0
  S  S6  1  0.644  0.782  0.369  1.0
  S  S7  1  0.356  0.282  0.131  1.0
  S  S8  1  0.356  0.218  0.631  1.0
  S  S9  1  0.644  0.718  0.869  1.0
  O  O10  1  0.660  0.814  0.239  1.0
  O  O11  1  0.340  0.314  0.261  1.0
  O  O12  1  0.340  0.186  0.761  1.0
  O  O13  1  0.660  0.686  0.739  1.0
  O  O14  1  0.783  0.913  0.430  1.0
  O  O15  1  0.217  0.413  0.070  1.0
  O  O16  1  0.217  0.087  0.570  1.0
  O  O17  1  0.783  0.587  0.930  1.0
  O  O18  1  0.748  0.615  0.393  1.0
  O  O19  1  0.252  0.115  0.107  1.0
  O  O20  1  0.252  0.385  0.607  1.0
  O  O21  1  0.748  0.885  0.893  1.0
  O  O22  1  0.383  0.787  0.386  1.0
  O  O23  1  0.617  0.287  0.114  1.0
  O  O24  1  0.617  0.213  0.614  1.0
  O  O25  1  0.383  0.713  0.886  1.0
  O  O26  1  0.013  0.337  0.286  1.0
  O  O27  1  0.987  0.837  0.214  1.0
  O  O28  1  0.987  0.663  0.714  1.0
  O  O29  1  0.013  0.163  0.786  1.0
  O  O30  1  0.015  0.806  0.107  1.0
  O  O31  1  0.985  0.306  0.393  1.0
  O  O32  1  0.985  0.194  0.893  1.0
  O  O33  1  0.015  0.694  0.607  1.0
[/CIF]
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The material described by Na2Zn(SO6)2 crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded in a 7-coordinate geometry to one O(1), one O(4), one O(6), two equivalent O(2), and two equivalent O(5) atoms. Zn(1) is bonded in a square co-planar geometry to two equivalent O(3) and two equivalent O(6) atoms. S(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Na(1), one S(1), and one O(5) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one S(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one S(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Na(1) and one S(1) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Na(1), one O(1), and one O(6) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(1), one Zn(1), and one O(5) atom. is represented by the CIF card [CIF]
data_Na2Zn(SO6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.508
_cell_length_b   8.075
_cell_length_c   11.817
_cell_angle_alpha   90.000
_cell_angle_beta   92.453
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   525.061
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.846  0.534  0.127  1.0
  Na  Na1  1  0.154  0.034  0.373  1.0
  Na  Na2  1  0.154  0.466  0.873  1.0
  Na  Na3  1  0.846  0.966  0.627  1.0
  Zn  Zn4  1  0.000  0.500  0.500  1.0
  Zn  Zn5  1  0.000  0.000  0.000  1.0
  S  S6  1  0.644  0.782  0.369  1.0
  S  S7  1  0.356  0.282  0.131  1.0
  S  S8  1  0.356  0.218  0.631  1.0
  S  S9  1  0.644  0.718  0.869  1.0
  O  O10  1  0.660  0.814  0.239  1.0
  O  O11  1  0.340  0.314  0.261  1.0
  O  O12  1  0.340  0.186  0.761  1.0
  O  O13  1  0.660  0.686  0.739  1.0
  O  O14  1  0.783  0.913  0.430  1.0
  O  O15  1  0.217  0.413  0.070  1.0
  O  O16  1  0.217  0.087  0.570  1.0
  O  O17  1  0.783  0.587  0.930  1.0
  O  O18  1  0.748  0.615  0.393  1.0
  O  O19  1  0.252  0.115  0.107  1.0
  O  O20  1  0.252  0.385  0.607  1.0
  O  O21  1  0.748  0.885  0.893  1.0
  O  O22  1  0.383  0.787  0.386  1.0
  O  O23  1  0.617  0.287  0.114  1.0
  O  O24  1  0.617  0.213  0.614  1.0
  O  O25  1  0.383  0.713  0.886  1.0
  O  O26  1  0.013  0.337  0.286  1.0
  O  O27  1  0.987  0.837  0.214  1.0
  O  O28  1  0.987  0.663  0.714  1.0
  O  O29  1  0.013  0.163  0.786  1.0
  O  O30  1  0.015  0.806  0.107  1.0
  O  O31  1  0.985  0.306  0.393  1.0
  O  O32  1  0.985  0.194  0.893  1.0
  O  O33  1  0.015  0.694  0.607  1.0
[/CIF]
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