The material structure described by N2S3(AsF6)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of eight AsF6 clusters and four N2S3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In each N2S3 cluster, N(1,2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to two equivalent N(1,2) atoms. In the second S site, S(2) is bonded in a single-bond geometry to one N(1,2) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1,2) atom. is represented by the CIF file [CIF]
data_As2S3(NF6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.700
_cell_length_b   7.700
_cell_length_c   10.891
_cell_angle_alpha   88.097
_cell_angle_beta   88.097
_cell_angle_gamma   67.907
_symmetry_Int_Tables_number   1
_cell_volume   597.738
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.288  0.983  0.251  1.0
  As  As1  1  0.017  0.712  0.749  1.0
  As  As2  1  0.668  0.332  0.500  1.0
  As  As3  1  0.675  0.325  0.000  1.0
  S  S4  1  0.180  0.531  0.256  1.0
  S  S5  1  0.469  0.820  0.744  1.0
  S  S6  1  0.840  0.749  0.152  1.0
  S  S7  1  0.251  0.160  0.848  1.0
  S  S8  1  0.827  0.745  0.350  1.0
  S  S9  1  0.255  0.173  0.650  1.0
  N  N10  1  0.050  0.618  0.140  1.0
  N  N11  1  0.382  0.950  0.860  1.0
  N  N12  1  0.035  0.613  0.368  1.0
  N  N13  1  0.387  0.965  0.632  1.0
  F  F14  1  0.225  0.164  0.137  1.0
  F  F15  1  0.836  0.775  0.863  1.0
  F  F16  1  0.359  0.805  0.367  1.0
  F  F17  1  0.195  0.641  0.633  1.0
  F  F18  1  0.060  0.979  0.257  1.0
  F  F19  1  0.021  0.940  0.743  1.0
  F  F20  1  0.226  0.158  0.365  1.0
  F  F21  1  0.842  0.774  0.635  1.0
  F  F22  1  0.525  0.981  0.247  1.0
  F  F23  1  0.019  0.475  0.753  1.0
  F  F24  1  0.357  0.813  0.136  1.0
  F  F25  1  0.187  0.643  0.864  1.0
  F  F26  1  0.441  0.396  0.438  1.0
  F  F27  1  0.604  0.559  0.562  1.0
  F  F28  1  0.733  0.106  0.438  1.0
  F  F29  1  0.894  0.267  0.562  1.0
  F  F30  1  0.746  0.415  0.363  1.0
  F  F31  1  0.585  0.254  0.637  1.0
  F  F32  1  0.469  0.408  0.093  1.0
  F  F33  1  0.592  0.531  0.907  1.0
  F  F34  1  0.785  0.434  0.095  1.0
  F  F35  1  0.566  0.215  0.905  1.0
  F  F36  1  0.761  0.118  0.093  1.0
  F  F37  1  0.882  0.239  0.907  1.0
[/CIF]
.
The material structure described by N2S3(AsF6)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of eight AsF6 clusters and four N2S3 clusters. In each AsF6 cluster, As(1) is bonded in an octahedral geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. There are six inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one As(1) atom. In the second F site, F(4) is bonded in a single-bond geometry to one As(1) atom. In the third F site, F(5) is bonded in a single-bond geometry to one As(1) atom. In the fourth F site, F(6) is bonded in a single-bond geometry to one As(1) atom. In the fifth F site, F(1) is bonded in a single-bond geometry to one As(1) atom. In the sixth F site, F(2) is bonded in a single-bond geometry to one As(1) atom. In each N2S3 cluster, N(1,2) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to two equivalent N(1,2) atoms. In the second S site, S(2) is bonded in a single-bond geometry to one N(1,2) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1,2) atom. is represented by the CIF file [CIF]
data_As2S3(NF6)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.700
_cell_length_b   7.700
_cell_length_c   10.891
_cell_angle_alpha   88.097
_cell_angle_beta   88.097
_cell_angle_gamma   67.907
_symmetry_Int_Tables_number   1
_cell_volume   597.738
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.288  0.983  0.251  1.0
  As  As1  1  0.017  0.712  0.749  1.0
  As  As2  1  0.668  0.332  0.500  1.0
  As  As3  1  0.675  0.325  0.000  1.0
  S  S4  1  0.180  0.531  0.256  1.0
  S  S5  1  0.469  0.820  0.744  1.0
  S  S6  1  0.840  0.749  0.152  1.0
  S  S7  1  0.251  0.160  0.848  1.0
  S  S8  1  0.827  0.745  0.350  1.0
  S  S9  1  0.255  0.173  0.650  1.0
  N  N10  1  0.050  0.618  0.140  1.0
  N  N11  1  0.382  0.950  0.860  1.0
  N  N12  1  0.035  0.613  0.368  1.0
  N  N13  1  0.387  0.965  0.632  1.0
  F  F14  1  0.225  0.164  0.137  1.0
  F  F15  1  0.836  0.775  0.863  1.0
  F  F16  1  0.359  0.805  0.367  1.0
  F  F17  1  0.195  0.641  0.633  1.0
  F  F18  1  0.060  0.979  0.257  1.0
  F  F19  1  0.021  0.940  0.743  1.0
  F  F20  1  0.226  0.158  0.365  1.0
  F  F21  1  0.842  0.774  0.635  1.0
  F  F22  1  0.525  0.981  0.247  1.0
  F  F23  1  0.019  0.475  0.753  1.0
  F  F24  1  0.357  0.813  0.136  1.0
  F  F25  1  0.187  0.643  0.864  1.0
  F  F26  1  0.441  0.396  0.438  1.0
  F  F27  1  0.604  0.559  0.562  1.0
  F  F28  1  0.733  0.106  0.438  1.0
  F  F29  1  0.894  0.267  0.562  1.0
  F  F30  1  0.746  0.415  0.363  1.0
  F  F31  1  0.585  0.254  0.637  1.0
  F  F32  1  0.469  0.408  0.093  1.0
  F  F33  1  0.592  0.531  0.907  1.0
  F  F34  1  0.785  0.434  0.095  1.0
  F  F35  1  0.566  0.215  0.905  1.0
  F  F36  1  0.761  0.118  0.093  1.0
  F  F37  1  0.882  0.239  0.907  1.0
[/CIF]
.