The structure described by RbU3F13 crystallizes in the orthorhombic Pmc2_1 space group. Rb(1) is bonded in a 11-coordinate geometry to one F(5), two equivalent F(1), two equivalent F(2), two equivalent F(3), two equivalent F(4), and two equivalent F(6) atoms. There are two inequivalent U sites. In the first U site, U(1) is bonded in a 9-coordinate geometry to one F(1), one F(2), one F(3), one F(5), one F(6), one F(7), one F(8), and two equivalent F(4) atoms. In the second U site, U(2) is bonded in a 9-coordinate geometry to one F(8), two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(9) atoms. There are nine inequivalent F sites. In the first F site, F(9) is bonded in a linear geometry to two equivalent U(2) atoms. In the second F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one U(1), and one U(2) atom. In the third F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one U(1), and one U(2) atom. In the fourth F site, F(3) is bonded in a trigonal planar geometry to one Rb(1), one U(1), and one U(2) atom. In the fifth F site, F(4) is bonded in a distorted bent 150 degrees geometry to one Rb(1) and two equivalent U(1) atoms. In the sixth F site, F(5) is bonded in a trigonal planar geometry to one Rb(1) and two equivalent U(1) atoms. In the seventh F site, F(6) is bonded to two equivalent Rb(1) and two equivalent U(1) atoms to form corner-sharing FRb2U2 tetrahedra. In the eighth F site, F(7) is bonded in a bent 120 degrees geometry to two equivalent U(1) atoms. In the ninth F site, F(8) is bonded in a trigonal non-coplanar geometry to one U(2) and two equivalent U(1) atoms. is represented by the CIF card [CIF]
data_RbU3F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.342
_cell_length_b   7.968
_cell_length_c   8.454
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   494.594
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.395  0.500  0.264  1.0
  Rb  Rb1  1  0.605  0.500  0.764  1.0
  U  U2  1  0.896  0.253  0.124  1.0
  U  U3  1  0.896  0.747  0.124  1.0
  U  U4  1  0.104  0.747  0.624  1.0
  U  U5  1  0.104  0.253  0.624  1.0
  U  U6  1  0.611  0.000  0.461  1.0
  U  U7  1  0.389  0.000  0.961  1.0
  F  F8  1  0.808  0.171  0.600  1.0
  F  F9  1  0.808  0.829  0.600  1.0
  F  F10  1  0.192  0.829  0.100  1.0
  F  F11  1  0.192  0.171  0.100  1.0
  F  F12  1  0.612  0.194  0.008  1.0
  F  F13  1  0.612  0.806  0.008  1.0
  F  F14  1  0.388  0.806  0.508  1.0
  F  F15  1  0.388  0.194  0.508  1.0
  F  F16  1  0.679  0.258  0.321  1.0
  F  F17  1  0.679  0.742  0.321  1.0
  F  F18  1  0.321  0.742  0.821  1.0
  F  F19  1  0.321  0.258  0.821  1.0
  F  F20  1  0.049  0.304  0.366  1.0
  F  F21  1  0.049  0.696  0.366  1.0
  F  F22  1  0.951  0.696  0.866  1.0
  F  F23  1  0.951  0.304  0.866  1.0
  F  F24  1  0.065  0.500  0.112  1.0
  F  F25  1  0.935  0.500  0.612  1.0
  F  F26  1  0.727  0.500  0.088  1.0
  F  F27  1  0.273  0.500  0.588  1.0
  F  F28  1  0.899  0.000  0.996  1.0
  F  F29  1  0.101  0.000  0.496  1.0
  F  F30  1  0.863  0.000  0.282  1.0
  F  F31  1  0.137  0.000  0.782  1.0
  F  F32  1  0.465  0.000  0.231  1.0
  F  F33  1  0.535  0.000  0.731  1.0
[/CIF]
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The structure described by RbU3F13 crystallizes in the orthorhombic Pmc2_1 space group. Rb(1) is bonded in a 11-coordinate geometry to one F(5), two equivalent F(1), two equivalent F(2), two equivalent F(3), two equivalent F(4), and two equivalent F(6) atoms. There are two inequivalent U sites. In the first U site, U(1) is bonded in a 9-coordinate geometry to one F(1), one F(2), one F(3), one F(5), one F(6), one F(7), one F(8), and two equivalent F(4) atoms. In the second U site, U(2) is bonded in a 9-coordinate geometry to one F(8), two equivalent F(1), two equivalent F(2), two equivalent F(3), and two equivalent F(9) atoms. There are nine inequivalent F sites. In the first F site, F(9) is bonded in a linear geometry to two equivalent U(2) atoms. In the second F site, F(1) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one U(1), and one U(2) atom. In the third F site, F(2) is bonded in a distorted bent 150 degrees geometry to one Rb(1), one U(1), and one U(2) atom. In the fourth F site, F(3) is bonded in a trigonal planar geometry to one Rb(1), one U(1), and one U(2) atom. In the fifth F site, F(4) is bonded in a distorted bent 150 degrees geometry to one Rb(1) and two equivalent U(1) atoms. In the sixth F site, F(5) is bonded in a trigonal planar geometry to one Rb(1) and two equivalent U(1) atoms. In the seventh F site, F(6) is bonded to two equivalent Rb(1) and two equivalent U(1) atoms to form corner-sharing FRb2U2 tetrahedra. In the eighth F site, F(7) is bonded in a bent 120 degrees geometry to two equivalent U(1) atoms. In the ninth F site, F(8) is bonded in a trigonal non-coplanar geometry to one U(2) and two equivalent U(1) atoms. is represented by the CIF card [CIF]
data_RbU3F13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.342
_cell_length_b   7.968
_cell_length_c   8.454
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   494.594
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.395  0.500  0.264  1.0
  Rb  Rb1  1  0.605  0.500  0.764  1.0
  U  U2  1  0.896  0.253  0.124  1.0
  U  U3  1  0.896  0.747  0.124  1.0
  U  U4  1  0.104  0.747  0.624  1.0
  U  U5  1  0.104  0.253  0.624  1.0
  U  U6  1  0.611  0.000  0.461  1.0
  U  U7  1  0.389  0.000  0.961  1.0
  F  F8  1  0.808  0.171  0.600  1.0
  F  F9  1  0.808  0.829  0.600  1.0
  F  F10  1  0.192  0.829  0.100  1.0
  F  F11  1  0.192  0.171  0.100  1.0
  F  F12  1  0.612  0.194  0.008  1.0
  F  F13  1  0.612  0.806  0.008  1.0
  F  F14  1  0.388  0.806  0.508  1.0
  F  F15  1  0.388  0.194  0.508  1.0
  F  F16  1  0.679  0.258  0.321  1.0
  F  F17  1  0.679  0.742  0.321  1.0
  F  F18  1  0.321  0.742  0.821  1.0
  F  F19  1  0.321  0.258  0.821  1.0
  F  F20  1  0.049  0.304  0.366  1.0
  F  F21  1  0.049  0.696  0.366  1.0
  F  F22  1  0.951  0.696  0.866  1.0
  F  F23  1  0.951  0.304  0.866  1.0
  F  F24  1  0.065  0.500  0.112  1.0
  F  F25  1  0.935  0.500  0.612  1.0
  F  F26  1  0.727  0.500  0.088  1.0
  F  F27  1  0.273  0.500  0.588  1.0
  F  F28  1  0.899  0.000  0.996  1.0
  F  F29  1  0.101  0.000  0.496  1.0
  F  F30  1  0.863  0.000  0.282  1.0
  F  F31  1  0.137  0.000  0.782  1.0
  F  F32  1  0.465  0.000  0.231  1.0
  F  F33  1  0.535  0.000  0.731  1.0
[/CIF]
.