The crystal structure described by Tl3TaS4Tl3VS4 crystallizes in the cubic P-43m space group. The structure consists of one Tl3TaS4 framework and one Tl3VS4 framework. In the Tl3TaS4 framework, Ta(1) is bonded in a tetrahedral geometry to four equivalent S(2) atoms. Tl(1) is bonded in a 4-coordinate geometry to four equivalent S(2) atoms. S(2) is bonded in a distorted single-bond geometry to one Ta(1) and three equivalent Tl(1) atoms. In the Tl3VS4 framework, V(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. Tl(2) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. S(1) is bonded in a distorted single-bond geometry to one V(1) and three equivalent Tl(2) atoms. is represented by the CIF file [CIF]
data_TaTl6VS8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.756
_cell_length_b   7.756
_cell_length_c   7.756
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   466.646
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta0  1  0.000  0.000  0.000  1.0
  Tl  Tl1  1  0.000  0.000  0.500  1.0
  Tl  Tl2  1  0.500  0.500  0.000  1.0
  Tl  Tl3  1  0.500  0.000  0.500  1.0
  Tl  Tl4  1  0.000  0.500  0.000  1.0
  Tl  Tl5  1  0.000  0.500  0.500  1.0
  Tl  Tl6  1  0.500  0.000  0.000  1.0
  V  V7  1  0.500  0.500  0.500  1.0
  S  S8  1  0.338  0.338  0.662  1.0
  S  S9  1  0.830  0.830  0.170  1.0
  S  S10  1  0.338  0.662  0.338  1.0
  S  S11  1  0.830  0.170  0.830  1.0
  S  S12  1  0.170  0.830  0.830  1.0
  S  S13  1  0.662  0.338  0.338  1.0
  S  S14  1  0.662  0.662  0.662  1.0
  S  S15  1  0.170  0.170  0.170  1.0
[/CIF]
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The crystal structure described by Tl3TaS4Tl3VS4 crystallizes in the cubic P-43m space group. The structure consists of one Tl3TaS4 framework and one Tl3VS4 framework. In the Tl3TaS4 framework, Ta(1) is bonded in a tetrahedral geometry to four equivalent S(2) atoms. Tl(1) is bonded in a 4-coordinate geometry to four equivalent S(2) atoms. S(2) is bonded in a distorted single-bond geometry to one Ta(1) and three equivalent Tl(1) atoms. In the Tl3VS4 framework, V(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. Tl(2) is bonded in a 4-coordinate geometry to four equivalent S(1) atoms. S(1) is bonded in a distorted single-bond geometry to one V(1) and three equivalent Tl(2) atoms. is represented by the CIF file [CIF]
data_TaTl6VS8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.756
_cell_length_b   7.756
_cell_length_c   7.756
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   466.646
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta0  1  0.000  0.000  0.000  1.0
  Tl  Tl1  1  0.000  0.000  0.500  1.0
  Tl  Tl2  1  0.500  0.500  0.000  1.0
  Tl  Tl3  1  0.500  0.000  0.500  1.0
  Tl  Tl4  1  0.000  0.500  0.000  1.0
  Tl  Tl5  1  0.000  0.500  0.500  1.0
  Tl  Tl6  1  0.500  0.000  0.000  1.0
  V  V7  1  0.500  0.500  0.500  1.0
  S  S8  1  0.338  0.338  0.662  1.0
  S  S9  1  0.830  0.830  0.170  1.0
  S  S10  1  0.338  0.662  0.338  1.0
  S  S11  1  0.830  0.170  0.830  1.0
  S  S12  1  0.170  0.830  0.830  1.0
  S  S13  1  0.662  0.338  0.338  1.0
  S  S14  1  0.662  0.662  0.662  1.0
  S  S15  1  0.170  0.170  0.170  1.0
[/CIF]
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