The material described by (B4NO9)2N2(O2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules, two ammonia atoms, and two B4NO9 clusters. In each B4NO9 cluster, there are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(6), and one O(7) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(2), one O(8), and one O(9) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(3), one O(6), and one O(8) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(4), one O(7), and one O(9) atom. N(2) is bonded in a bent 120 degrees geometry to one O(1) and one O(5) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one B(1) and one N(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one B(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one B(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one B(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one B(1) and one B(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one B(1) and one B(4) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one B(2) and one B(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one B(2) and one B(4) atom. is represented by the CIF card [CIF]
data_B4N2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.133
_cell_length_b   7.850
_cell_length_c   8.164
_cell_angle_alpha   74.739
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   626.464
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.712  0.926  0.874  1.0
  B  B1  1  0.212  0.074  0.126  1.0
  B  B2  1  0.857  0.662  0.657  1.0
  B  B3  1  0.357  0.338  0.343  1.0
  B  B4  1  0.712  0.594  0.921  1.0
  B  B5  1  0.212  0.406  0.079  1.0
  B  B6  1  0.707  0.931  0.561  1.0
  B  B7  1  0.207  0.069  0.439  1.0
  N  N8  1  0.961  0.761  0.224  1.0
  N  N9  1  0.461  0.239  0.776  1.0
  N  N10  1  0.877  0.125  0.937  1.0
  N  N11  1  0.377  0.875  0.063  1.0
  O  O12  1  0.745  0.049  0.967  1.0
  O  O13  1  0.245  0.951  0.033  1.0
  O  O14  1  0.979  0.613  0.616  1.0
  O  O15  1  0.479  0.387  0.384  1.0
  O  O16  1  0.635  0.459  0.008  1.0
  O  O17  1  0.135  0.541  0.992  1.0
  O  O18  1  0.633  0.006  0.422  1.0
  O  O19  1  0.133  0.994  0.578  1.0
  O  O20  1  0.943  0.061  0.849  1.0
  O  O21  1  0.443  0.939  0.151  1.0
  O  O22  1  0.704  0.753  0.963  1.0
  O  O23  1  0.204  0.247  0.037  1.0
  O  O24  1  0.690  0.989  0.704  1.0
  O  O25  1  0.190  0.011  0.296  1.0
  O  O26  1  0.798  0.561  0.802  1.0
  O  O27  1  0.298  0.439  0.198  1.0
  O  O28  1  0.799  0.806  0.546  1.0
  O  O29  1  0.299  0.194  0.454  1.0
  O  O30  1  0.794  0.393  0.380  1.0
  O  O31  1  0.294  0.607  0.620  1.0
  O  O32  1  0.899  0.316  0.380  1.0
  O  O33  1  0.399  0.684  0.620  1.0
[/CIF]
.
The material described by (B4NO9)2N2(O2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two 7782-44-7 molecules, two ammonia atoms, and two B4NO9 clusters. In each B4NO9 cluster, there are four inequivalent B sites. In the first B site, B(1) is bonded in a trigonal planar geometry to one O(1), one O(6), and one O(7) atom. In the second B site, B(2) is bonded in a trigonal planar geometry to one O(2), one O(8), and one O(9) atom. In the third B site, B(3) is bonded in a trigonal planar geometry to one O(3), one O(6), and one O(8) atom. In the fourth B site, B(4) is bonded in a trigonal planar geometry to one O(4), one O(7), and one O(9) atom. N(2) is bonded in a bent 120 degrees geometry to one O(1) and one O(5) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one B(1) and one N(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one B(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one B(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one B(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one B(1) and one B(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one B(1) and one B(4) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one B(2) and one B(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one B(2) and one B(4) atom. is represented by the CIF card [CIF]
data_B4N2O11
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.133
_cell_length_b   7.850
_cell_length_c   8.164
_cell_angle_alpha   74.739
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   626.464
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.712  0.926  0.874  1.0
  B  B1  1  0.212  0.074  0.126  1.0
  B  B2  1  0.857  0.662  0.657  1.0
  B  B3  1  0.357  0.338  0.343  1.0
  B  B4  1  0.712  0.594  0.921  1.0
  B  B5  1  0.212  0.406  0.079  1.0
  B  B6  1  0.707  0.931  0.561  1.0
  B  B7  1  0.207  0.069  0.439  1.0
  N  N8  1  0.961  0.761  0.224  1.0
  N  N9  1  0.461  0.239  0.776  1.0
  N  N10  1  0.877  0.125  0.937  1.0
  N  N11  1  0.377  0.875  0.063  1.0
  O  O12  1  0.745  0.049  0.967  1.0
  O  O13  1  0.245  0.951  0.033  1.0
  O  O14  1  0.979  0.613  0.616  1.0
  O  O15  1  0.479  0.387  0.384  1.0
  O  O16  1  0.635  0.459  0.008  1.0
  O  O17  1  0.135  0.541  0.992  1.0
  O  O18  1  0.633  0.006  0.422  1.0
  O  O19  1  0.133  0.994  0.578  1.0
  O  O20  1  0.943  0.061  0.849  1.0
  O  O21  1  0.443  0.939  0.151  1.0
  O  O22  1  0.704  0.753  0.963  1.0
  O  O23  1  0.204  0.247  0.037  1.0
  O  O24  1  0.690  0.989  0.704  1.0
  O  O25  1  0.190  0.011  0.296  1.0
  O  O26  1  0.798  0.561  0.802  1.0
  O  O27  1  0.298  0.439  0.198  1.0
  O  O28  1  0.799  0.806  0.546  1.0
  O  O29  1  0.299  0.194  0.454  1.0
  O  O30  1  0.794  0.393  0.380  1.0
  O  O31  1  0.294  0.607  0.620  1.0
  O  O32  1  0.899  0.316  0.380  1.0
  O  O33  1  0.399  0.684  0.620  1.0
[/CIF]
.