The structure described by Rb2MgF4 is (La,Ba)CuO4 structured and crystallizes in the tetragonal I4/mmm space group. Rb(1) is bonded in a 9-coordinate geometry to four equivalent F(1) and five equivalent F(2) atoms. Mg(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing MgF6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent F sites. In the first F site, F(2) is bonded to five equivalent Rb(1) and one Mg(1) atom to form a mixture of distorted corner and edge-sharing FRb5Mg octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second F site, F(1) is bonded in a distorted linear geometry to four equivalent Rb(1) and two equivalent Mg(1) atoms. is represented by the CIF file [CIF]
data_Rb2MgF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.045
_cell_length_b   4.045
_cell_length_c   7.456
_cell_angle_alpha   105.738
_cell_angle_beta   105.738
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   112.651
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.649  0.649  0.298  1.0
  Rb  Rb1  1  0.351  0.351  0.702  1.0
  Mg  Mg2  1  0.000  0.000  0.000  1.0
  F  F3  1  0.500  0.000  0.000  1.0
  F  F4  1  0.000  0.500  0.000  1.0
  F  F5  1  0.855  0.855  0.710  1.0
  F  F6  1  0.145  0.145  0.290  1.0
[/CIF]
.
The structure described by Rb2MgF4 is (La,Ba)CuO4 structured and crystallizes in the tetragonal I4/mmm space group. Rb(1) is bonded in a 9-coordinate geometry to four equivalent F(1) and five equivalent F(2) atoms. Mg(1) is bonded to two equivalent F(2) and four equivalent F(1) atoms to form corner-sharing MgF6 octahedra. The corner-sharing octahedra are not tilted. There are two inequivalent F sites. In the first F site, F(2) is bonded to five equivalent Rb(1) and one Mg(1) atom to form a mixture of distorted corner and edge-sharing FRb5Mg octahedra. The corner-sharing octahedral tilt angles range from 0-2°. In the second F site, F(1) is bonded in a distorted linear geometry to four equivalent Rb(1) and two equivalent Mg(1) atoms. is represented by the CIF file [CIF]
data_Rb2MgF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.045
_cell_length_b   4.045
_cell_length_c   7.456
_cell_angle_alpha   105.738
_cell_angle_beta   105.738
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   112.651
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.649  0.649  0.298  1.0
  Rb  Rb1  1  0.351  0.351  0.702  1.0
  Mg  Mg2  1  0.000  0.000  0.000  1.0
  F  F3  1  0.500  0.000  0.000  1.0
  F  F4  1  0.000  0.500  0.000  1.0
  F  F5  1  0.855  0.855  0.710  1.0
  F  F6  1  0.145  0.145  0.290  1.0
[/CIF]
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