The material described by NaUVO7 crystallizes in the monoclinic Pc space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form NaO6 octahedra that share  a cornercorner with one U(1)O7 pentagonal bipyramid,  a cornercorner with one U(2)O7 pentagonal bipyramid,  a cornercorner with one Na(2)O6 pentagonal pyramid,  a cornercorner with one V(1)O5 trigonal bipyramid,  a cornercorner with one V(2)O5 trigonal bipyramid, and  a faceface with one Na(2)O6 pentagonal pyramid. In the second Na site, Na(2) is bonded to one O(1), one O(13), one O(14), one O(2), one O(6), and one O(7) atom to form distorted NaO6 pentagonal pyramids that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one U(1)O7 pentagonal bipyramid, corners with two equivalent U(2)O7 pentagonal bipyramids,  a cornercorner with one V(1)O5 trigonal bipyramid, and  a faceface with one Na(1)O6 octahedra. The corner-sharing octahedral tilt angles are 48°. There are two inequivalent U sites. In the first U site, U(1) is bonded to one O(10), one O(11), one O(13), one O(3), one O(4), one O(5), and one O(9) atom to form distorted UO7 pentagonal bipyramids that share  a cornercorner with one Na(1)O6 octahedra, corners with two equivalent U(2)O7 pentagonal bipyramids,  a cornercorner with one Na(2)O6 pentagonal pyramid,  a cornercorner with one V(1)O5 trigonal bipyramid,  a cornercorner with one V(2)O5 trigonal bipyramid,  an edgeedge with one U(2)O7 pentagonal bipyramid,  an edgeedge with one V(1)O5 trigonal bipyramid, and  an edgeedge with one V(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 34°. In the second U site, U(2) is bonded to one O(10), one O(12), one O(14), one O(3), one O(4), one O(6), and one O(9) atom to form distorted UO7 pentagonal bipyramids that share  a cornercorner with one Na(1)O6 octahedra, corners with two equivalent U(1)O7 pentagonal bipyramids, corners with two equivalent Na(2)O6 pentagonal pyramids,  a cornercorner with one V(1)O5 trigonal bipyramid,  a cornercorner with one V(2)O5 trigonal bipyramid,  an edgeedge with one U(1)O7 pentagonal bipyramid,  an edgeedge with one V(1)O5 trigonal bipyramid, and  an edgeedge with one V(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 45°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(12), one O(3), one O(7), and one O(9) atom to form distorted VO5 trigonal bipyramids that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one U(1)O7 pentagonal bipyramid,  a cornercorner with one U(2)O7 pentagonal bipyramid,  a cornercorner with one Na(2)O6 pentagonal pyramid,  an edgeedge with one U(1)O7 pentagonal bipyramid,  an edgeedge with one U(2)O7 pentagonal bipyramid, and  an edgeedge with one V(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 49°. In the second V site, V(2) is bonded to one O(10), one O(11), one O(12), one O(4), and one O(8) atom to form distorted VO5 trigonal bipyramids that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one U(1)O7 pentagonal bipyramid,  a cornercorner with one U(2)O7 pentagonal bipyramid,  an edgeedge with one U(1)O7 pentagonal bipyramid,  an edgeedge with one U(2)O7 pentagonal bipyramid, and  an edgeedge with one V(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 51°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Na(1) and one Na(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Na(1) and one Na(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one U(1), one U(2), and one V(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one U(1), one U(2), and one V(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Na(1) and one U(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one U(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Na(1), one Na(2), and one V(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one V(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one U(1), one U(2), and one V(1) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one U(1), one U(2), and one V(2) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one U(1), one V(1), and one V(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one U(2), one V(1), and one V(2) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Na(2) and one U(1) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Na(2) and one U(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaUVO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.706
_cell_length_b   8.590
_cell_length_c   10.298
_cell_angle_alpha   90.000
_cell_angle_beta   109.282
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   643.415
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.989  0.011  0.490  1.0
  Na  Na1  1  0.489  0.489  0.990  1.0
  Na  Na2  1  0.318  0.992  0.845  1.0
  Na  Na3  1  0.818  0.508  0.345  1.0
  U  U4  1  0.688  0.520  0.679  1.0
  U  U5  1  0.809  0.020  0.819  1.0
  U  U6  1  0.309  0.480  0.319  1.0
  U  U7  1  0.188  0.980  0.179  1.0
  V  V8  1  0.471  0.852  0.561  1.0
  V  V9  1  0.031  0.344  0.936  1.0
  V  V10  1  0.531  0.156  0.436  1.0
  V  V11  1  0.971  0.648  0.061  1.0
  O  O12  1  0.270  0.706  0.892  1.0
  O  O13  1  0.257  0.148  0.639  1.0
  O  O14  1  0.757  0.352  0.139  1.0
  O  O15  1  0.770  0.794  0.392  1.0
  O  O16  1  0.669  0.791  0.710  1.0
  O  O17  1  0.833  0.290  0.784  1.0
  O  O18  1  0.333  0.210  0.284  1.0
  O  O19  1  0.169  0.709  0.210  1.0
  O  O20  1  0.526  0.502  0.774  1.0
  O  O21  1  0.988  0.001  0.736  1.0
  O  O22  1  0.488  0.499  0.236  1.0
  O  O23  1  0.026  0.998  0.274  1.0
  O  O24  1  0.283  0.873  0.607  1.0
  O  O25  1  0.223  0.338  0.899  1.0
  O  O26  1  0.723  0.162  0.399  1.0
  O  O27  1  0.783  0.627  0.107  1.0
  O  O28  1  0.463  0.656  0.494  1.0
  O  O29  1  0.018  0.150  0.006  1.0
  O  O30  1  0.518  0.350  0.506  1.0
  O  O31  1  0.963  0.844  0.994  1.0
  O  O32  1  0.432  0.942  0.386  1.0
  O  O33  1  0.080  0.440  0.110  1.0
  O  O34  1  0.580  0.060  0.610  1.0
  O  O35  1  0.932  0.558  0.886  1.0
  O  O36  1  0.848  0.543  0.581  1.0
  O  O37  1  0.631  0.038  0.898  1.0
  O  O38  1  0.131  0.462  0.398  1.0
  O  O39  1  0.348  0.957  0.081  1.0
[/CIF]
.
The material described by NaUVO7 crystallizes in the monoclinic Pc space group. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded to one O(1), one O(2), one O(5), one O(6), one O(7), and one O(8) atom to form NaO6 octahedra that share  a cornercorner with one U(1)O7 pentagonal bipyramid,  a cornercorner with one U(2)O7 pentagonal bipyramid,  a cornercorner with one Na(2)O6 pentagonal pyramid,  a cornercorner with one V(1)O5 trigonal bipyramid,  a cornercorner with one V(2)O5 trigonal bipyramid, and  a faceface with one Na(2)O6 pentagonal pyramid. In the second Na site, Na(2) is bonded to one O(1), one O(13), one O(14), one O(2), one O(6), and one O(7) atom to form distorted NaO6 pentagonal pyramids that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one U(1)O7 pentagonal bipyramid, corners with two equivalent U(2)O7 pentagonal bipyramids,  a cornercorner with one V(1)O5 trigonal bipyramid, and  a faceface with one Na(1)O6 octahedra. The corner-sharing octahedral tilt angles are 48°. There are two inequivalent U sites. In the first U site, U(1) is bonded to one O(10), one O(11), one O(13), one O(3), one O(4), one O(5), and one O(9) atom to form distorted UO7 pentagonal bipyramids that share  a cornercorner with one Na(1)O6 octahedra, corners with two equivalent U(2)O7 pentagonal bipyramids,  a cornercorner with one Na(2)O6 pentagonal pyramid,  a cornercorner with one V(1)O5 trigonal bipyramid,  a cornercorner with one V(2)O5 trigonal bipyramid,  an edgeedge with one U(2)O7 pentagonal bipyramid,  an edgeedge with one V(1)O5 trigonal bipyramid, and  an edgeedge with one V(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 34°. In the second U site, U(2) is bonded to one O(10), one O(12), one O(14), one O(3), one O(4), one O(6), and one O(9) atom to form distorted UO7 pentagonal bipyramids that share  a cornercorner with one Na(1)O6 octahedra, corners with two equivalent U(1)O7 pentagonal bipyramids, corners with two equivalent Na(2)O6 pentagonal pyramids,  a cornercorner with one V(1)O5 trigonal bipyramid,  a cornercorner with one V(2)O5 trigonal bipyramid,  an edgeedge with one U(1)O7 pentagonal bipyramid,  an edgeedge with one V(1)O5 trigonal bipyramid, and  an edgeedge with one V(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 45°. There are two inequivalent V sites. In the first V site, V(1) is bonded to one O(11), one O(12), one O(3), one O(7), and one O(9) atom to form distorted VO5 trigonal bipyramids that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one U(1)O7 pentagonal bipyramid,  a cornercorner with one U(2)O7 pentagonal bipyramid,  a cornercorner with one Na(2)O6 pentagonal pyramid,  an edgeedge with one U(1)O7 pentagonal bipyramid,  an edgeedge with one U(2)O7 pentagonal bipyramid, and  an edgeedge with one V(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 49°. In the second V site, V(2) is bonded to one O(10), one O(11), one O(12), one O(4), and one O(8) atom to form distorted VO5 trigonal bipyramids that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one U(1)O7 pentagonal bipyramid,  a cornercorner with one U(2)O7 pentagonal bipyramid,  an edgeedge with one U(1)O7 pentagonal bipyramid,  an edgeedge with one U(2)O7 pentagonal bipyramid, and  an edgeedge with one V(1)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 51°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Na(1) and one Na(2) atom. In the second O site, O(2) is bonded in a water-like geometry to one Na(1) and one Na(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one U(1), one U(2), and one V(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one U(1), one U(2), and one V(2) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Na(1) and one U(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one U(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Na(1), one Na(2), and one V(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one V(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one U(1), one U(2), and one V(1) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one U(1), one U(2), and one V(2) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one U(1), one V(1), and one V(2) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one U(2), one V(1), and one V(2) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Na(2) and one U(1) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Na(2) and one U(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaUVO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.706
_cell_length_b   8.590
_cell_length_c   10.298
_cell_angle_alpha   90.000
_cell_angle_beta   109.282
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   643.415
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.989  0.011  0.490  1.0
  Na  Na1  1  0.489  0.489  0.990  1.0
  Na  Na2  1  0.318  0.992  0.845  1.0
  Na  Na3  1  0.818  0.508  0.345  1.0
  U  U4  1  0.688  0.520  0.679  1.0
  U  U5  1  0.809  0.020  0.819  1.0
  U  U6  1  0.309  0.480  0.319  1.0
  U  U7  1  0.188  0.980  0.179  1.0
  V  V8  1  0.471  0.852  0.561  1.0
  V  V9  1  0.031  0.344  0.936  1.0
  V  V10  1  0.531  0.156  0.436  1.0
  V  V11  1  0.971  0.648  0.061  1.0
  O  O12  1  0.270  0.706  0.892  1.0
  O  O13  1  0.257  0.148  0.639  1.0
  O  O14  1  0.757  0.352  0.139  1.0
  O  O15  1  0.770  0.794  0.392  1.0
  O  O16  1  0.669  0.791  0.710  1.0
  O  O17  1  0.833  0.290  0.784  1.0
  O  O18  1  0.333  0.210  0.284  1.0
  O  O19  1  0.169  0.709  0.210  1.0
  O  O20  1  0.526  0.502  0.774  1.0
  O  O21  1  0.988  0.001  0.736  1.0
  O  O22  1  0.488  0.499  0.236  1.0
  O  O23  1  0.026  0.998  0.274  1.0
  O  O24  1  0.283  0.873  0.607  1.0
  O  O25  1  0.223  0.338  0.899  1.0
  O  O26  1  0.723  0.162  0.399  1.0
  O  O27  1  0.783  0.627  0.107  1.0
  O  O28  1  0.463  0.656  0.494  1.0
  O  O29  1  0.018  0.150  0.006  1.0
  O  O30  1  0.518  0.350  0.506  1.0
  O  O31  1  0.963  0.844  0.994  1.0
  O  O32  1  0.432  0.942  0.386  1.0
  O  O33  1  0.080  0.440  0.110  1.0
  O  O34  1  0.580  0.060  0.610  1.0
  O  O35  1  0.932  0.558  0.886  1.0
  O  O36  1  0.848  0.543  0.581  1.0
  O  O37  1  0.631  0.038  0.898  1.0
  O  O38  1  0.131  0.462  0.398  1.0
  O  O39  1  0.348  0.957  0.081  1.0
[/CIF]
.