The compound described by Sb3F16(Br)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 7726-95-6 molecules and four Sb3F16 clusters. In each Sb3F16 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(7), and one F(8) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 38°. In the second Sb site, Sb(2) is bonded to two equivalent F(4) and four equivalent F(5,6) atoms to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 38°. There are seven inequivalent F sites. In the first F site, F(5,6) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(4) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb3(BrF8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.454
_cell_length_b   7.454
_cell_length_c   14.374
_cell_angle_alpha   87.320
_cell_angle_beta   87.320
_cell_angle_gamma   60.868
_symmetry_Int_Tables_number   1
_cell_volume   696.617
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.976  0.274  0.378  1.0
  Sb  Sb1  1  0.726  0.024  0.122  1.0
  Sb  Sb2  1  0.274  0.976  0.878  1.0
  Sb  Sb3  1  0.024  0.726  0.622  1.0
  Sb  Sb4  1  0.000  0.500  0.000  1.0
  Sb  Sb5  1  0.500  0.000  0.500  1.0
  Br  Br6  1  0.402  0.733  0.200  1.0
  Br  Br7  1  0.267  0.598  0.300  1.0
  Br  Br8  1  0.598  0.267  0.800  1.0
  Br  Br9  1  0.733  0.402  0.700  1.0
  F  F10  1  0.207  0.655  0.520  1.0
  F  F11  1  0.345  0.793  0.980  1.0
  F  F12  1  0.793  0.345  0.480  1.0
  F  F13  1  0.655  0.207  0.020  1.0
  F  F14  1  0.220  0.582  0.711  1.0
  F  F15  1  0.418  0.780  0.789  1.0
  F  F16  1  0.780  0.418  0.289  1.0
  F  F17  1  0.582  0.220  0.211  1.0
  F  F18  1  0.798  0.823  0.706  1.0
  F  F19  1  0.177  0.202  0.794  1.0
  F  F20  1  0.884  0.799  0.022  1.0
  F  F21  1  0.201  0.116  0.478  1.0
  F  F22  1  0.116  0.201  0.978  1.0
  F  F23  1  0.799  0.884  0.522  1.0
  F  F24  1  0.801  0.494  0.082  1.0
  F  F25  1  0.506  0.199  0.418  1.0
  F  F26  1  0.199  0.506  0.918  1.0
  F  F27  1  0.494  0.801  0.582  1.0
  F  F28  1  0.176  0.438  0.099  1.0
  F  F29  1  0.562  0.824  0.401  1.0
  F  F30  1  0.824  0.562  0.901  1.0
  F  F31  1  0.438  0.176  0.599  1.0
  F  F32  1  0.974  0.028  0.131  1.0
  F  F33  1  0.972  0.026  0.369  1.0
  F  F34  1  0.026  0.972  0.869  1.0
  F  F35  1  0.028  0.974  0.631  1.0
  F  F36  1  0.503  0.978  0.099  1.0
  F  F37  1  0.022  0.497  0.401  1.0
  F  F38  1  0.497  0.022  0.901  1.0
  F  F39  1  0.978  0.503  0.599  1.0
  F  F40  1  0.823  0.798  0.206  1.0
  F  F41  1  0.202  0.177  0.294  1.0
[/CIF]
.
The compound described by Sb3F16(Br)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 7726-95-6 molecules and four Sb3F16 clusters. In each Sb3F16 cluster, there are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded to one F(1), one F(2), one F(3), one F(4), one F(7), and one F(8) atom to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 38°. In the second Sb site, Sb(2) is bonded to two equivalent F(4) and four equivalent F(5,6) atoms to form corner-sharing SbF6 octahedra. The corner-sharing octahedral tilt angles are 38°. There are seven inequivalent F sites. In the first F site, F(5,6) is bonded in a single-bond geometry to one Sb(2) atom. In the second F site, F(7) is bonded in a single-bond geometry to one Sb(1) atom. In the third F site, F(8) is bonded in a single-bond geometry to one Sb(1) atom. In the fourth F site, F(1) is bonded in a single-bond geometry to one Sb(1) atom. In the fifth F site, F(2) is bonded in a single-bond geometry to one Sb(1) atom. In the sixth F site, F(3) is bonded in a single-bond geometry to one Sb(1) atom. In the seventh F site, F(4) is bonded in a bent 150 degrees geometry to one Sb(1) and one Sb(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb3(BrF8)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.454
_cell_length_b   7.454
_cell_length_c   14.374
_cell_angle_alpha   87.320
_cell_angle_beta   87.320
_cell_angle_gamma   60.868
_symmetry_Int_Tables_number   1
_cell_volume   696.617
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.976  0.274  0.378  1.0
  Sb  Sb1  1  0.726  0.024  0.122  1.0
  Sb  Sb2  1  0.274  0.976  0.878  1.0
  Sb  Sb3  1  0.024  0.726  0.622  1.0
  Sb  Sb4  1  0.000  0.500  0.000  1.0
  Sb  Sb5  1  0.500  0.000  0.500  1.0
  Br  Br6  1  0.402  0.733  0.200  1.0
  Br  Br7  1  0.267  0.598  0.300  1.0
  Br  Br8  1  0.598  0.267  0.800  1.0
  Br  Br9  1  0.733  0.402  0.700  1.0
  F  F10  1  0.207  0.655  0.520  1.0
  F  F11  1  0.345  0.793  0.980  1.0
  F  F12  1  0.793  0.345  0.480  1.0
  F  F13  1  0.655  0.207  0.020  1.0
  F  F14  1  0.220  0.582  0.711  1.0
  F  F15  1  0.418  0.780  0.789  1.0
  F  F16  1  0.780  0.418  0.289  1.0
  F  F17  1  0.582  0.220  0.211  1.0
  F  F18  1  0.798  0.823  0.706  1.0
  F  F19  1  0.177  0.202  0.794  1.0
  F  F20  1  0.884  0.799  0.022  1.0
  F  F21  1  0.201  0.116  0.478  1.0
  F  F22  1  0.116  0.201  0.978  1.0
  F  F23  1  0.799  0.884  0.522  1.0
  F  F24  1  0.801  0.494  0.082  1.0
  F  F25  1  0.506  0.199  0.418  1.0
  F  F26  1  0.199  0.506  0.918  1.0
  F  F27  1  0.494  0.801  0.582  1.0
  F  F28  1  0.176  0.438  0.099  1.0
  F  F29  1  0.562  0.824  0.401  1.0
  F  F30  1  0.824  0.562  0.901  1.0
  F  F31  1  0.438  0.176  0.599  1.0
  F  F32  1  0.974  0.028  0.131  1.0
  F  F33  1  0.972  0.026  0.369  1.0
  F  F34  1  0.026  0.972  0.869  1.0
  F  F35  1  0.028  0.974  0.631  1.0
  F  F36  1  0.503  0.978  0.099  1.0
  F  F37  1  0.022  0.497  0.401  1.0
  F  F38  1  0.497  0.022  0.901  1.0
  F  F39  1  0.978  0.503  0.599  1.0
  F  F40  1  0.823  0.798  0.206  1.0
  F  F41  1  0.202  0.177  0.294  1.0
[/CIF]
.