The material structure described by Li(NH3)4Te is Silicon tetrafluoride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one ditelluride molecule and two Li(NH3)4 clusters. In each Li(NH3)4 cluster, Li(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded to one Li(1), one H(1), one H(10), and one H(2) atom to form distorted corner-sharing NLiH3 tetrahedra. In the second N site, N(2) is bonded to one Li(1), one H(3), one H(4), and one H(6) atom to form distorted corner-sharing NLiH3 tetrahedra. In the third N site, N(3) is bonded to one Li(1), one H(12), one H(5), and one H(9) atom to form distorted corner-sharing NLiH3 tetrahedra. In the fourth N site, N(4) is bonded to one Li(1), one H(11), one H(7), and one H(8) atom to form distorted corner-sharing NLiH3 tetrahedra. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(3) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(1) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(3) atom. is represented by the CIF card [CIF]
data_LiTe(H3N)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.859
_cell_length_b   7.356
_cell_length_c   8.648
_cell_angle_alpha   103.364
_cell_angle_beta   113.287
_cell_angle_gamma   86.903
_symmetry_Int_Tables_number   1
_cell_volume   389.554
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.200  0.904  0.277  1.0
  Li  Li1  1  0.800  0.096  0.723  1.0
  Te  Te2  1  0.367  0.544  0.843  1.0
  Te  Te3  1  0.633  0.456  0.157  1.0
  H  H4  1  0.032  0.715  0.966  1.0
  H  H5  1  0.144  0.289  0.948  1.0
  H  H6  1  0.007  0.129  0.469  1.0
  H  H7  1  0.003  0.218  0.312  1.0
  H  H8  1  0.118  0.599  0.349  1.0
  H  H9  1  0.216  0.245  0.494  1.0
  H  H10  1  0.402  0.012  0.652  1.0
  H  H11  1  0.520  0.126  0.855  1.0
  H  H12  1  0.333  0.686  0.521  1.0
  H  H13  1  0.127  0.110  0.026  1.0
  H  H14  1  0.536  0.896  0.799  1.0
  H  H15  1  0.353  0.592  0.335  1.0
  H  H16  1  0.647  0.408  0.665  1.0
  H  H17  1  0.464  0.104  0.201  1.0
  H  H18  1  0.873  0.890  0.974  1.0
  H  H19  1  0.667  0.314  0.479  1.0
  H  H20  1  0.480  0.874  0.145  1.0
  H  H21  1  0.598  0.988  0.348  1.0
  H  H22  1  0.784  0.755  0.506  1.0
  H  H23  1  0.882  0.401  0.651  1.0
  H  H24  1  0.997  0.782  0.688  1.0
  H  H25  1  0.993  0.871  0.531  1.0
  H  H26  1  0.856  0.711  0.052  1.0
  H  H27  1  0.968  0.285  0.034  1.0
  N  N28  1  0.038  0.204  0.958  1.0
  N  N29  1  0.099  0.149  0.405  1.0
  N  N30  1  0.259  0.674  0.389  1.0
  N  N31  1  0.538  0.019  0.761  1.0
  N  N32  1  0.462  0.981  0.239  1.0
  N  N33  1  0.741  0.326  0.611  1.0
  N  N34  1  0.901  0.851  0.595  1.0
  N  N35  1  0.962  0.796  0.042  1.0
[/CIF]
.
The material structure described by Li(NH3)4Te is Silicon tetrafluoride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one ditelluride molecule and two Li(NH3)4 clusters. In each Li(NH3)4 cluster, Li(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded to one Li(1), one H(1), one H(10), and one H(2) atom to form distorted corner-sharing NLiH3 tetrahedra. In the second N site, N(2) is bonded to one Li(1), one H(3), one H(4), and one H(6) atom to form distorted corner-sharing NLiH3 tetrahedra. In the third N site, N(3) is bonded to one Li(1), one H(12), one H(5), and one H(9) atom to form distorted corner-sharing NLiH3 tetrahedra. In the fourth N site, N(4) is bonded to one Li(1), one H(11), one H(7), and one H(8) atom to form distorted corner-sharing NLiH3 tetrahedra. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(3) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(1) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(4) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(3) atom. is represented by the CIF card [CIF]
data_LiTe(H3N)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.859
_cell_length_b   7.356
_cell_length_c   8.648
_cell_angle_alpha   103.364
_cell_angle_beta   113.287
_cell_angle_gamma   86.903
_symmetry_Int_Tables_number   1
_cell_volume   389.554
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.200  0.904  0.277  1.0
  Li  Li1  1  0.800  0.096  0.723  1.0
  Te  Te2  1  0.367  0.544  0.843  1.0
  Te  Te3  1  0.633  0.456  0.157  1.0
  H  H4  1  0.032  0.715  0.966  1.0
  H  H5  1  0.144  0.289  0.948  1.0
  H  H6  1  0.007  0.129  0.469  1.0
  H  H7  1  0.003  0.218  0.312  1.0
  H  H8  1  0.118  0.599  0.349  1.0
  H  H9  1  0.216  0.245  0.494  1.0
  H  H10  1  0.402  0.012  0.652  1.0
  H  H11  1  0.520  0.126  0.855  1.0
  H  H12  1  0.333  0.686  0.521  1.0
  H  H13  1  0.127  0.110  0.026  1.0
  H  H14  1  0.536  0.896  0.799  1.0
  H  H15  1  0.353  0.592  0.335  1.0
  H  H16  1  0.647  0.408  0.665  1.0
  H  H17  1  0.464  0.104  0.201  1.0
  H  H18  1  0.873  0.890  0.974  1.0
  H  H19  1  0.667  0.314  0.479  1.0
  H  H20  1  0.480  0.874  0.145  1.0
  H  H21  1  0.598  0.988  0.348  1.0
  H  H22  1  0.784  0.755  0.506  1.0
  H  H23  1  0.882  0.401  0.651  1.0
  H  H24  1  0.997  0.782  0.688  1.0
  H  H25  1  0.993  0.871  0.531  1.0
  H  H26  1  0.856  0.711  0.052  1.0
  H  H27  1  0.968  0.285  0.034  1.0
  N  N28  1  0.038  0.204  0.958  1.0
  N  N29  1  0.099  0.149  0.405  1.0
  N  N30  1  0.259  0.674  0.389  1.0
  N  N31  1  0.538  0.019  0.761  1.0
  N  N32  1  0.462  0.981  0.239  1.0
  N  N33  1  0.741  0.326  0.611  1.0
  N  N34  1  0.901  0.851  0.595  1.0
  N  N35  1  0.962  0.796  0.042  1.0
[/CIF]
.