The compound described by DyVB4 crystallizes in the orthorhombic Pbam space group. Dy(1) is bonded in a 14-coordinate geometry to two equivalent B(3), four equivalent B(1), four equivalent B(2), and four equivalent B(4) atoms. V(1) is bonded in a 10-coordinate geometry to two equivalent B(1), two equivalent B(2), two equivalent B(4), and four equivalent B(3) atoms. There are four inequivalent B sites. In the first B site, B(1) is bonded in a 9-coordinate geometry to four equivalent Dy(1), two equivalent V(1), one B(2), and two equivalent B(4) atoms. In the second B site, B(2) is bonded in a 9-coordinate geometry to four equivalent Dy(1), two equivalent V(1), one B(1), one B(2), and one B(3) atom. In the third B site, B(3) is bonded in a 9-coordinate geometry to two equivalent Dy(1), four equivalent V(1), one B(2), one B(3), and one B(4) atom. In the fourth B site, B(4) is bonded in a 9-coordinate geometry to four equivalent Dy(1), two equivalent V(1), one B(3), and two equivalent B(1) atoms. is represented by the CIF file [CIF]
data_DyVB4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.437
_cell_length_b   6.000
_cell_length_c   11.615
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   239.507
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.624  0.349  1.0
  Dy  Dy1  1  0.000  0.376  0.651  1.0
  Dy  Dy2  1  0.000  0.124  0.151  1.0
  Dy  Dy3  1  0.000  0.876  0.849  1.0
  V  V4  1  0.000  0.627  0.083  1.0
  V  V5  1  0.000  0.373  0.917  1.0
  V  V6  1  0.000  0.127  0.417  1.0
  V  V7  1  0.000  0.873  0.583  1.0
  B  B8  1  0.500  0.786  0.185  1.0
  B  B9  1  0.500  0.214  0.815  1.0
  B  B10  1  0.500  0.286  0.315  1.0
  B  B11  1  0.500  0.714  0.685  1.0
  B  B12  1  0.500  0.864  0.032  1.0
  B  B13  1  0.500  0.136  0.968  1.0
  B  B14  1  0.500  0.364  0.468  1.0
  B  B15  1  0.500  0.636  0.532  1.0
  B  B16  1  0.500  0.885  0.453  1.0
  B  B17  1  0.500  0.115  0.547  1.0
  B  B18  1  0.500  0.385  0.047  1.0
  B  B19  1  0.500  0.615  0.953  1.0
  B  B20  1  0.500  0.977  0.308  1.0
  B  B21  1  0.500  0.023  0.692  1.0
  B  B22  1  0.500  0.477  0.192  1.0
  B  B23  1  0.500  0.523  0.808  1.0
[/CIF]
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The compound described by DyVB4 crystallizes in the orthorhombic Pbam space group. Dy(1) is bonded in a 14-coordinate geometry to two equivalent B(3), four equivalent B(1), four equivalent B(2), and four equivalent B(4) atoms. V(1) is bonded in a 10-coordinate geometry to two equivalent B(1), two equivalent B(2), two equivalent B(4), and four equivalent B(3) atoms. There are four inequivalent B sites. In the first B site, B(1) is bonded in a 9-coordinate geometry to four equivalent Dy(1), two equivalent V(1), one B(2), and two equivalent B(4) atoms. In the second B site, B(2) is bonded in a 9-coordinate geometry to four equivalent Dy(1), two equivalent V(1), one B(1), one B(2), and one B(3) atom. In the third B site, B(3) is bonded in a 9-coordinate geometry to two equivalent Dy(1), four equivalent V(1), one B(2), one B(3), and one B(4) atom. In the fourth B site, B(4) is bonded in a 9-coordinate geometry to four equivalent Dy(1), two equivalent V(1), one B(3), and two equivalent B(1) atoms. is represented by the CIF file [CIF]
data_DyVB4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.437
_cell_length_b   6.000
_cell_length_c   11.615
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   239.507
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.000  0.624  0.349  1.0
  Dy  Dy1  1  0.000  0.376  0.651  1.0
  Dy  Dy2  1  0.000  0.124  0.151  1.0
  Dy  Dy3  1  0.000  0.876  0.849  1.0
  V  V4  1  0.000  0.627  0.083  1.0
  V  V5  1  0.000  0.373  0.917  1.0
  V  V6  1  0.000  0.127  0.417  1.0
  V  V7  1  0.000  0.873  0.583  1.0
  B  B8  1  0.500  0.786  0.185  1.0
  B  B9  1  0.500  0.214  0.815  1.0
  B  B10  1  0.500  0.286  0.315  1.0
  B  B11  1  0.500  0.714  0.685  1.0
  B  B12  1  0.500  0.864  0.032  1.0
  B  B13  1  0.500  0.136  0.968  1.0
  B  B14  1  0.500  0.364  0.468  1.0
  B  B15  1  0.500  0.636  0.532  1.0
  B  B16  1  0.500  0.885  0.453  1.0
  B  B17  1  0.500  0.115  0.547  1.0
  B  B18  1  0.500  0.385  0.047  1.0
  B  B19  1  0.500  0.615  0.953  1.0
  B  B20  1  0.500  0.977  0.308  1.0
  B  B21  1  0.500  0.023  0.692  1.0
  B  B22  1  0.500  0.477  0.192  1.0
  B  B23  1  0.500  0.523  0.808  1.0
[/CIF]
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