The material described by HTeO3 crystallizes in the orthorhombic Pna2_1 space group. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(6) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(3), one O(5), one O(6), and two equivalent O(4) atoms to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles are 46°. In the second Te site, Te(2) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(2) atom. In the second O site, O(6) is bonded in a distorted bent 120 degrees geometry to one H(2) and one Te(1) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(2) atom. In the fourth O site, O(2) is bonded in a distorted water-like geometry to one H(1) and one Te(2) atom. In the fifth O site, O(3) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(2) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to two equivalent Te(1) atoms. is represented by the CIF card [CIF]
data_TeHO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.976
_cell_length_b   8.430
_cell_length_c   11.713
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   491.288
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.981  0.950  0.111  1.0
  Te  Te1  1  0.481  0.050  0.889  1.0
  Te  Te2  1  0.481  0.450  0.389  1.0
  Te  Te3  1  0.981  0.550  0.611  1.0
  Te  Te4  1  0.848  0.828  0.398  1.0
  Te  Te5  1  0.348  0.172  0.602  1.0
  Te  Te6  1  0.348  0.328  0.102  1.0
  Te  Te7  1  0.848  0.672  0.898  1.0
  H  H8  1  0.481  0.012  0.374  1.0
  H  H9  1  0.981  0.988  0.626  1.0
  H  H10  1  0.981  0.512  0.126  1.0
  H  H11  1  0.481  0.488  0.874  1.0
  H  H12  1  0.405  0.820  0.180  1.0
  H  H13  1  0.905  0.180  0.820  1.0
  H  H14  1  0.905  0.320  0.320  1.0
  H  H15  1  0.405  0.680  0.680  1.0
  O  O16  1  0.748  0.952  0.240  1.0
  O  O17  1  0.248  0.048  0.760  1.0
  O  O18  1  0.248  0.452  0.260  1.0
  O  O19  1  0.748  0.548  0.740  1.0
  O  O20  1  0.524  0.946  0.441  1.0
  O  O21  1  0.024  0.054  0.559  1.0
  O  O22  1  0.024  0.446  0.059  1.0
  O  O23  1  0.524  0.554  0.941  1.0
  O  O24  1  0.662  0.855  0.832  1.0
  O  O25  1  0.162  0.145  0.168  1.0
  O  O26  1  0.162  0.355  0.668  1.0
  O  O27  1  0.662  0.645  0.332  1.0
  O  O28  1  0.232  0.913  0.979  1.0
  O  O29  1  0.732  0.087  0.021  1.0
  O  O30  1  0.732  0.413  0.521  1.0
  O  O31  1  0.232  0.587  0.479  1.0
  O  O32  1  0.791  0.764  0.057  1.0
  O  O33  1  0.291  0.236  0.943  1.0
  O  O34  1  0.291  0.264  0.443  1.0
  O  O35  1  0.791  0.736  0.557  1.0
  O  O36  1  0.217  0.821  0.205  1.0
  O  O37  1  0.717  0.179  0.795  1.0
  O  O38  1  0.717  0.321  0.295  1.0
  O  O39  1  0.217  0.679  0.705  1.0
[/CIF]
.
The material described by HTeO3 crystallizes in the orthorhombic Pna2_1 space group. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(6) atom. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one O(1), one O(3), one O(5), one O(6), and two equivalent O(4) atoms to form corner-sharing TeO6 octahedra. The corner-sharing octahedral tilt angles are 46°. In the second Te site, Te(2) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(2) atom. In the second O site, O(6) is bonded in a distorted bent 120 degrees geometry to one H(2) and one Te(1) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(2) atom. In the fourth O site, O(2) is bonded in a distorted water-like geometry to one H(1) and one Te(2) atom. In the fifth O site, O(3) is bonded in a bent 150 degrees geometry to one Te(1) and one Te(2) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to two equivalent Te(1) atoms. is represented by the CIF card [CIF]
data_TeHO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.976
_cell_length_b   8.430
_cell_length_c   11.713
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   491.288
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.981  0.950  0.111  1.0
  Te  Te1  1  0.481  0.050  0.889  1.0
  Te  Te2  1  0.481  0.450  0.389  1.0
  Te  Te3  1  0.981  0.550  0.611  1.0
  Te  Te4  1  0.848  0.828  0.398  1.0
  Te  Te5  1  0.348  0.172  0.602  1.0
  Te  Te6  1  0.348  0.328  0.102  1.0
  Te  Te7  1  0.848  0.672  0.898  1.0
  H  H8  1  0.481  0.012  0.374  1.0
  H  H9  1  0.981  0.988  0.626  1.0
  H  H10  1  0.981  0.512  0.126  1.0
  H  H11  1  0.481  0.488  0.874  1.0
  H  H12  1  0.405  0.820  0.180  1.0
  H  H13  1  0.905  0.180  0.820  1.0
  H  H14  1  0.905  0.320  0.320  1.0
  H  H15  1  0.405  0.680  0.680  1.0
  O  O16  1  0.748  0.952  0.240  1.0
  O  O17  1  0.248  0.048  0.760  1.0
  O  O18  1  0.248  0.452  0.260  1.0
  O  O19  1  0.748  0.548  0.740  1.0
  O  O20  1  0.524  0.946  0.441  1.0
  O  O21  1  0.024  0.054  0.559  1.0
  O  O22  1  0.024  0.446  0.059  1.0
  O  O23  1  0.524  0.554  0.941  1.0
  O  O24  1  0.662  0.855  0.832  1.0
  O  O25  1  0.162  0.145  0.168  1.0
  O  O26  1  0.162  0.355  0.668  1.0
  O  O27  1  0.662  0.645  0.332  1.0
  O  O28  1  0.232  0.913  0.979  1.0
  O  O29  1  0.732  0.087  0.021  1.0
  O  O30  1  0.732  0.413  0.521  1.0
  O  O31  1  0.232  0.587  0.479  1.0
  O  O32  1  0.791  0.764  0.057  1.0
  O  O33  1  0.291  0.236  0.943  1.0
  O  O34  1  0.291  0.264  0.443  1.0
  O  O35  1  0.791  0.736  0.557  1.0
  O  O36  1  0.217  0.821  0.205  1.0
  O  O37  1  0.717  0.179  0.795  1.0
  O  O38  1  0.717  0.321  0.295  1.0
  O  O39  1  0.217  0.679  0.705  1.0
[/CIF]
.