The structure described by Zn2Cl5O2 crystallizes in the triclinic P1 space group. The structure consists of two 7782-44-7 molecules inside a Zn2Cl5 framework. In the Zn2Cl5 framework, there are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one Cl(1), one Cl(4), one Cl(5), and one Cl(9) atom to form corner-sharing ZnCl4 tetrahedra. In the second Zn site, Zn(2) is bonded to one Cl(2), one Cl(3), one Cl(6), and one Cl(9) atom to form corner-sharing ZnCl4 tetrahedra. In the third Zn site, Zn(3) is bonded to one Cl(10), one Cl(2), one Cl(3), and one Cl(7) atom to form corner-sharing ZnCl4 tetrahedra. In the fourth Zn site, Zn(4) is bonded to one Cl(1), one Cl(10), one Cl(4), and one Cl(8) atom to form corner-sharing ZnCl4 tetrahedra. There are ten inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to one Zn(1) and one Zn(4) atom. In the second Cl site, Cl(2) is bonded in a water-like geometry to one Zn(2) and one Zn(3) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to one Zn(2) and one Zn(3) atom. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to one Zn(1) and one Zn(4) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Zn(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Zn(2) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one Zn(3) atom. In the eighth Cl site, Cl(8) is bonded in a single-bond geometry to one Zn(4) atom. In the ninth Cl site, Cl(9) is bonded in a water-like geometry to one Zn(1) and one Zn(2) atom. In the tenth Cl site, Cl(10) is bonded in a water-like geometry to one Zn(3) and one Zn(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn2Cl5O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.587
_cell_length_b   6.614
_cell_length_c   12.147
_cell_angle_alpha   105.337
_cell_angle_beta   105.629
_cell_angle_gamma   90.159
_symmetry_Int_Tables_number   1
_cell_volume   489.913
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.841  0.345  0.665  1.0
  Zn  Zn1  1  0.653  0.162  0.334  1.0
  Zn  Zn2  1  0.071  0.076  0.163  1.0
  Zn  Zn3  1  0.927  0.926  0.834  1.0
  Cl  Cl4  1  0.977  0.673  0.673  1.0
  Cl  Cl5  1  0.324  0.026  0.326  1.0
  Cl  Cl6  1  0.748  0.952  0.173  1.0
  Cl  Cl7  1  0.051  0.247  0.826  1.0
  Cl  Cl8  1  0.501  0.351  0.664  1.0
  Cl  Cl9  1  0.647  0.502  0.338  1.0
  Cl  Cl10  1  0.064  0.410  0.158  1.0
  Cl  Cl11  1  0.590  0.921  0.839  1.0
  Cl  Cl12  1  0.894  0.108  0.499  1.0
  Cl  Cl13  1  0.147  0.854  0.000  1.0
  O  O14  1  0.343  0.784  0.537  1.0
  O  O15  1  0.225  0.644  0.461  1.0
  O  O16  1  0.512  0.437  0.034  1.0
  O  O17  1  0.558  0.504  0.960  1.0
[/CIF]
.
The structure described by Zn2Cl5O2 crystallizes in the triclinic P1 space group. The structure consists of two 7782-44-7 molecules inside a Zn2Cl5 framework. In the Zn2Cl5 framework, there are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one Cl(1), one Cl(4), one Cl(5), and one Cl(9) atom to form corner-sharing ZnCl4 tetrahedra. In the second Zn site, Zn(2) is bonded to one Cl(2), one Cl(3), one Cl(6), and one Cl(9) atom to form corner-sharing ZnCl4 tetrahedra. In the third Zn site, Zn(3) is bonded to one Cl(10), one Cl(2), one Cl(3), and one Cl(7) atom to form corner-sharing ZnCl4 tetrahedra. In the fourth Zn site, Zn(4) is bonded to one Cl(1), one Cl(10), one Cl(4), and one Cl(8) atom to form corner-sharing ZnCl4 tetrahedra. There are ten inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to one Zn(1) and one Zn(4) atom. In the second Cl site, Cl(2) is bonded in a water-like geometry to one Zn(2) and one Zn(3) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to one Zn(2) and one Zn(3) atom. In the fourth Cl site, Cl(4) is bonded in a water-like geometry to one Zn(1) and one Zn(4) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Zn(1) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Zn(2) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one Zn(3) atom. In the eighth Cl site, Cl(8) is bonded in a single-bond geometry to one Zn(4) atom. In the ninth Cl site, Cl(9) is bonded in a water-like geometry to one Zn(1) and one Zn(2) atom. In the tenth Cl site, Cl(10) is bonded in a water-like geometry to one Zn(3) and one Zn(4) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Zn2Cl5O2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.587
_cell_length_b   6.614
_cell_length_c   12.147
_cell_angle_alpha   105.337
_cell_angle_beta   105.629
_cell_angle_gamma   90.159
_symmetry_Int_Tables_number   1
_cell_volume   489.913
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.841  0.345  0.665  1.0
  Zn  Zn1  1  0.653  0.162  0.334  1.0
  Zn  Zn2  1  0.071  0.076  0.163  1.0
  Zn  Zn3  1  0.927  0.926  0.834  1.0
  Cl  Cl4  1  0.977  0.673  0.673  1.0
  Cl  Cl5  1  0.324  0.026  0.326  1.0
  Cl  Cl6  1  0.748  0.952  0.173  1.0
  Cl  Cl7  1  0.051  0.247  0.826  1.0
  Cl  Cl8  1  0.501  0.351  0.664  1.0
  Cl  Cl9  1  0.647  0.502  0.338  1.0
  Cl  Cl10  1  0.064  0.410  0.158  1.0
  Cl  Cl11  1  0.590  0.921  0.839  1.0
  Cl  Cl12  1  0.894  0.108  0.499  1.0
  Cl  Cl13  1  0.147  0.854  0.000  1.0
  O  O14  1  0.343  0.784  0.537  1.0
  O  O15  1  0.225  0.644  0.461  1.0
  O  O16  1  0.512  0.437  0.034  1.0
  O  O17  1  0.558  0.504  0.960  1.0
[/CIF]
.