The crystal structure described by AsNO3NO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and two AsNO3 clusters. In each AsNO3 cluster, As(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(4) atom. N(2) is bonded in a bent 120 degrees geometry to one O(2) and one O(4) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one As(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one As(1) and one N(2) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one As(1) and one N(2) atom. is represented by the CIF card [CIF]
data_As(NO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.666
_cell_length_b   7.830
_cell_length_c   9.906
_cell_angle_alpha   72.994
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   568.593
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.860  0.555  0.202  1.0
  As  As1  1  0.360  0.945  0.798  1.0
  As  As2  1  0.140  0.445  0.798  1.0
  As  As3  1  0.640  0.055  0.202  1.0
  N  N4  1  0.110  0.877  0.465  1.0
  N  N5  1  0.610  0.623  0.535  1.0
  N  N6  1  0.890  0.123  0.535  1.0
  N  N7  1  0.390  0.377  0.465  1.0
  N  N8  1  0.352  0.802  0.109  1.0
  N  N9  1  0.852  0.698  0.891  1.0
  N  N10  1  0.648  0.198  0.891  1.0
  N  N11  1  0.148  0.302  0.109  1.0
  O  O12  1  0.938  0.752  0.198  1.0
  O  O13  1  0.438  0.748  0.802  1.0
  O  O14  1  0.062  0.248  0.802  1.0
  O  O15  1  0.562  0.252  0.198  1.0
  O  O16  1  0.086  0.330  0.217  1.0
  O  O17  1  0.586  0.170  0.783  1.0
  O  O18  1  0.914  0.670  0.783  1.0
  O  O19  1  0.414  0.830  0.217  1.0
  O  O20  1  0.672  0.503  0.505  1.0
  O  O21  1  0.172  0.997  0.495  1.0
  O  O22  1  0.328  0.497  0.495  1.0
  O  O23  1  0.828  0.003  0.505  1.0
  O  O24  1  0.836  0.551  0.996  1.0
  O  O25  1  0.336  0.949  0.004  1.0
  O  O26  1  0.164  0.449  0.004  1.0
  O  O27  1  0.664  0.051  0.996  1.0
[/CIF]
.
The crystal structure described by AsNO3NO is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four nitroxyl molecules and two AsNO3 clusters. In each AsNO3 cluster, As(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(2), and one O(4) atom. N(2) is bonded in a bent 120 degrees geometry to one O(2) and one O(4) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one As(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one As(1) and one N(2) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one As(1) and one N(2) atom. is represented by the CIF card [CIF]
data_As(NO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.666
_cell_length_b   7.830
_cell_length_c   9.906
_cell_angle_alpha   72.994
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   568.593
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.860  0.555  0.202  1.0
  As  As1  1  0.360  0.945  0.798  1.0
  As  As2  1  0.140  0.445  0.798  1.0
  As  As3  1  0.640  0.055  0.202  1.0
  N  N4  1  0.110  0.877  0.465  1.0
  N  N5  1  0.610  0.623  0.535  1.0
  N  N6  1  0.890  0.123  0.535  1.0
  N  N7  1  0.390  0.377  0.465  1.0
  N  N8  1  0.352  0.802  0.109  1.0
  N  N9  1  0.852  0.698  0.891  1.0
  N  N10  1  0.648  0.198  0.891  1.0
  N  N11  1  0.148  0.302  0.109  1.0
  O  O12  1  0.938  0.752  0.198  1.0
  O  O13  1  0.438  0.748  0.802  1.0
  O  O14  1  0.062  0.248  0.802  1.0
  O  O15  1  0.562  0.252  0.198  1.0
  O  O16  1  0.086  0.330  0.217  1.0
  O  O17  1  0.586  0.170  0.783  1.0
  O  O18  1  0.914  0.670  0.783  1.0
  O  O19  1  0.414  0.830  0.217  1.0
  O  O20  1  0.672  0.503  0.505  1.0
  O  O21  1  0.172  0.997  0.495  1.0
  O  O22  1  0.328  0.497  0.495  1.0
  O  O23  1  0.828  0.003  0.505  1.0
  O  O24  1  0.836  0.551  0.996  1.0
  O  O25  1  0.336  0.949  0.004  1.0
  O  O26  1  0.164  0.449  0.004  1.0
  O  O27  1  0.664  0.051  0.996  1.0
[/CIF]
.