The compound described by KAuO2 crystallizes in the orthorhombic Cmcm space group. K(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent K(1) and two equivalent Au(1) atoms to form a mixture of edge, face, and corner-sharing OK3Au2 trigonal bipyramids. is represented by the CIF card [CIF]
data_KAuO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.207
_cell_length_b   6.023
_cell_length_c   6.365
_cell_angle_alpha   90.000
_cell_angle_beta   70.703
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   152.211
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.293  0.250  0.414  1.0
  K  K1  1  0.707  0.750  0.586  1.0
  Au  Au2  1  0.997  0.750  0.006  1.0
  Au  Au3  1  0.003  0.250  0.994  1.0
  O  O4  1  0.889  0.495  0.222  1.0
  O  O5  1  0.111  0.505  0.778  1.0
  O  O6  1  0.111  0.995  0.778  1.0
  O  O7  1  0.889  0.005  0.222  1.0
[/CIF]
.
The compound described by KAuO2 crystallizes in the orthorhombic Cmcm space group. K(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. Au(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. O(1) is bonded to three equivalent K(1) and two equivalent Au(1) atoms to form a mixture of edge, face, and corner-sharing OK3Au2 trigonal bipyramids. is represented by the CIF card [CIF]
data_KAuO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.207
_cell_length_b   6.023
_cell_length_c   6.365
_cell_angle_alpha   90.000
_cell_angle_beta   70.703
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   152.211
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.293  0.250  0.414  1.0
  K  K1  1  0.707  0.750  0.586  1.0
  Au  Au2  1  0.997  0.750  0.006  1.0
  Au  Au3  1  0.003  0.250  0.994  1.0
  O  O4  1  0.889  0.495  0.222  1.0
  O  O5  1  0.111  0.505  0.778  1.0
  O  O6  1  0.111  0.995  0.778  1.0
  O  O7  1  0.889  0.005  0.222  1.0
[/CIF]
.