The crystal structure described by PtCl6((CH3)2NH2)2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Immm space group. The structure is zero-dimensional and consists of four dimethylazanium molecules and two PtCl6 clusters. In each PtCl6 cluster, Pt(1) is bonded in an octahedral geometry to two equivalent Cl(2) and four equivalent Cl(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the CIF file [CIF]
data_H16PtC4(NCl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.358
_cell_length_b   8.669
_cell_length_c   8.669
_cell_angle_alpha   73.899
_cell_angle_beta   64.891
_cell_angle_gamma   64.891
_symmetry_Int_Tables_number   1
_cell_volume   450.223
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.544  0.344  0.344  1.0
  H  H1  1  0.769  0.344  0.344  1.0
  H  H2  1  0.456  0.656  0.656  1.0
  H  H3  1  0.231  0.656  0.656  1.0
  H  H4  1  0.721  0.076  0.481  1.0
  H  H5  1  0.721  0.481  0.076  1.0
  H  H6  1  0.279  0.519  0.924  1.0
  H  H7  1  0.279  0.924  0.519  1.0
  H  H8  1  0.710  0.046  0.290  1.0
  H  H9  1  0.954  0.290  0.046  1.0
  H  H10  1  0.290  0.710  0.954  1.0
  H  H11  1  0.046  0.954  0.710  1.0
  H  H12  1  0.290  0.954  0.710  1.0
  H  H13  1  0.046  0.710  0.954  1.0
  H  H14  1  0.710  0.290  0.046  1.0
  H  H15  1  0.954  0.046  0.290  1.0
  Pt  Pt16  1  0.000  0.500  0.500  1.0
  C  C17  1  0.779  0.101  0.341  1.0
  C  C18  1  0.779  0.341  0.101  1.0
  C  C19  1  0.221  0.659  0.899  1.0
  C  C20  1  0.221  0.899  0.659  1.0
  N  N21  1  0.710  0.290  0.290  1.0
  N  N22  1  0.290  0.710  0.710  1.0
  Cl  Cl23  1  0.230  0.343  0.657  1.0
  Cl  Cl24  1  0.770  0.657  0.343  1.0
  Cl  Cl25  1  0.770  0.343  0.657  1.0
  Cl  Cl26  1  0.230  0.657  0.343  1.0
  Cl  Cl27  1  0.200  0.300  0.300  1.0
  Cl  Cl28  1  0.800  0.700  0.700  1.0
[/CIF]
.
The crystal structure described by PtCl6((CH3)2NH2)2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Immm space group. The structure is zero-dimensional and consists of four dimethylazanium molecules and two PtCl6 clusters. In each PtCl6 cluster, Pt(1) is bonded in an octahedral geometry to two equivalent Cl(2) and four equivalent Cl(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Pt(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the CIF file [CIF]
data_H16PtC4(NCl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.358
_cell_length_b   8.669
_cell_length_c   8.669
_cell_angle_alpha   73.899
_cell_angle_beta   64.891
_cell_angle_gamma   64.891
_symmetry_Int_Tables_number   1
_cell_volume   450.223
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.544  0.344  0.344  1.0
  H  H1  1  0.769  0.344  0.344  1.0
  H  H2  1  0.456  0.656  0.656  1.0
  H  H3  1  0.231  0.656  0.656  1.0
  H  H4  1  0.721  0.076  0.481  1.0
  H  H5  1  0.721  0.481  0.076  1.0
  H  H6  1  0.279  0.519  0.924  1.0
  H  H7  1  0.279  0.924  0.519  1.0
  H  H8  1  0.710  0.046  0.290  1.0
  H  H9  1  0.954  0.290  0.046  1.0
  H  H10  1  0.290  0.710  0.954  1.0
  H  H11  1  0.046  0.954  0.710  1.0
  H  H12  1  0.290  0.954  0.710  1.0
  H  H13  1  0.046  0.710  0.954  1.0
  H  H14  1  0.710  0.290  0.046  1.0
  H  H15  1  0.954  0.046  0.290  1.0
  Pt  Pt16  1  0.000  0.500  0.500  1.0
  C  C17  1  0.779  0.101  0.341  1.0
  C  C18  1  0.779  0.341  0.101  1.0
  C  C19  1  0.221  0.659  0.899  1.0
  C  C20  1  0.221  0.899  0.659  1.0
  N  N21  1  0.710  0.290  0.290  1.0
  N  N22  1  0.290  0.710  0.710  1.0
  Cl  Cl23  1  0.230  0.343  0.657  1.0
  Cl  Cl24  1  0.770  0.657  0.343  1.0
  Cl  Cl25  1  0.770  0.343  0.657  1.0
  Cl  Cl26  1  0.230  0.657  0.343  1.0
  Cl  Cl27  1  0.200  0.300  0.300  1.0
  Cl  Cl28  1  0.800  0.700  0.700  1.0
[/CIF]
.