The compound described by LiVCrP2(HO5)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(10), one O(4), one O(5), one O(6), and one O(8) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(7) atoms to form VO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra and corners with four equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 50°. In the second V site, V(2) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(9) atoms to form VO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra and corners with four equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 44°. Cr(1) is bonded to one O(1), one O(10), one O(4), one O(5), one O(8), and one O(9) atom to form CrO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-50°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(4), one O(6), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent V(2)O6 octahedra and corners with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-51°. In the second P site, P(2) is bonded to one O(1), one O(10), one O(3), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and corners with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-52°. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Cr(1) and one P(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(2) and one P(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one V(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Cr(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Li(1), one V(1), one Cr(1), and one H(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one V(2), and one P(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(2) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Li(1), one Cr(1), and one P(1) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one V(2), one Cr(1), and one H(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(1), one Cr(1), and one P(2) atom. is represented by the CIF file [CIF]
data_LiVCrP2(HO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.310
_cell_length_b   7.365
_cell_length_c   10.371
_cell_angle_alpha   105.447
_cell_angle_beta   96.980
_cell_angle_gamma   110.169
_symmetry_Int_Tables_number   1
_cell_volume   356.578
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.346  0.933  0.782  1.0
  Li  Li1  1  0.654  0.067  0.218  1.0
  V  V2  1  0.000  0.000  0.500  1.0
  V  V3  1  0.500  0.500  0.000  1.0
  Cr  Cr4  1  0.251  0.255  0.252  1.0
  Cr  Cr5  1  0.749  0.745  0.748  1.0
  P  P6  1  0.848  0.200  0.976  1.0
  P  P7  1  0.352  0.702  0.474  1.0
  P  P8  1  0.152  0.800  0.024  1.0
  P  P9  1  0.648  0.298  0.526  1.0
  H  H10  1  0.962  0.901  0.246  1.0
  H  H11  1  0.038  0.099  0.754  1.0
  H  H12  1  0.435  0.404  0.743  1.0
  H  H13  1  0.565  0.596  0.257  1.0
  O  O14  1  0.772  0.529  0.596  1.0
  O  O15  1  0.891  0.697  0.075  1.0
  O  O16  1  0.869  0.210  0.561  1.0
  O  O17  1  0.913  0.239  0.132  1.0
  O  O18  1  0.087  0.761  0.868  1.0
  O  O19  1  0.012  0.966  0.687  1.0
  O  O20  1  0.988  0.034  0.313  1.0
  O  O21  1  0.228  0.471  0.404  1.0
  O  O22  1  0.109  0.303  0.925  1.0
  O  O23  1  0.380  0.724  0.064  1.0
  O  O24  1  0.131  0.790  0.439  1.0
  O  O25  1  0.391  0.199  0.582  1.0
  O  O26  1  0.284  0.031  0.105  1.0
  O  O27  1  0.491  0.464  0.180  1.0
  O  O28  1  0.509  0.536  0.820  1.0
  O  O29  1  0.432  0.762  0.632  1.0
  O  O30  1  0.568  0.238  0.368  1.0
  O  O31  1  0.620  0.276  0.936  1.0
  O  O32  1  0.609  0.801  0.418  1.0
  O  O33  1  0.716  0.969  0.895  1.0
[/CIF]
.
The compound described by LiVCrP2(HO5)2 crystallizes in the triclinic P-1 space group. Li(1) is bonded in a 5-coordinate geometry to one O(10), one O(4), one O(5), one O(6), and one O(8) atom. There are two inequivalent V sites. In the first V site, V(1) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(7) atoms to form VO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra and corners with four equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 50°. In the second V site, V(2) is bonded to two equivalent O(2), two equivalent O(6), and two equivalent O(9) atoms to form VO6 octahedra that share corners with two equivalent Cr(1)O6 octahedra and corners with four equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 44°. Cr(1) is bonded to one O(1), one O(10), one O(4), one O(5), one O(8), and one O(9) atom to form CrO6 octahedra that share  a cornercorner with one V(1)O6 octahedra,  a cornercorner with one V(2)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 44-50°. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(2), one O(4), one O(6), and one O(8) atom to form PO4 tetrahedra that share corners with two equivalent V(2)O6 octahedra and corners with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 35-51°. In the second P site, P(2) is bonded to one O(1), one O(10), one O(3), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent V(1)O6 octahedra and corners with two equivalent Cr(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-52°. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(9) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Cr(1) and one P(2) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one V(2) and one P(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one V(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Cr(1), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Li(1), one V(1), one Cr(1), and one H(1) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Li(1), one V(2), and one P(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one V(1) and one P(2) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Li(1), one Cr(1), and one P(1) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one V(2), one Cr(1), and one H(2) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Li(1), one Cr(1), and one P(2) atom. is represented by the CIF file [CIF]
data_LiVCrP2(HO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.310
_cell_length_b   7.365
_cell_length_c   10.371
_cell_angle_alpha   105.447
_cell_angle_beta   96.980
_cell_angle_gamma   110.169
_symmetry_Int_Tables_number   1
_cell_volume   356.578
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.346  0.933  0.782  1.0
  Li  Li1  1  0.654  0.067  0.218  1.0
  V  V2  1  0.000  0.000  0.500  1.0
  V  V3  1  0.500  0.500  0.000  1.0
  Cr  Cr4  1  0.251  0.255  0.252  1.0
  Cr  Cr5  1  0.749  0.745  0.748  1.0
  P  P6  1  0.848  0.200  0.976  1.0
  P  P7  1  0.352  0.702  0.474  1.0
  P  P8  1  0.152  0.800  0.024  1.0
  P  P9  1  0.648  0.298  0.526  1.0
  H  H10  1  0.962  0.901  0.246  1.0
  H  H11  1  0.038  0.099  0.754  1.0
  H  H12  1  0.435  0.404  0.743  1.0
  H  H13  1  0.565  0.596  0.257  1.0
  O  O14  1  0.772  0.529  0.596  1.0
  O  O15  1  0.891  0.697  0.075  1.0
  O  O16  1  0.869  0.210  0.561  1.0
  O  O17  1  0.913  0.239  0.132  1.0
  O  O18  1  0.087  0.761  0.868  1.0
  O  O19  1  0.012  0.966  0.687  1.0
  O  O20  1  0.988  0.034  0.313  1.0
  O  O21  1  0.228  0.471  0.404  1.0
  O  O22  1  0.109  0.303  0.925  1.0
  O  O23  1  0.380  0.724  0.064  1.0
  O  O24  1  0.131  0.790  0.439  1.0
  O  O25  1  0.391  0.199  0.582  1.0
  O  O26  1  0.284  0.031  0.105  1.0
  O  O27  1  0.491  0.464  0.180  1.0
  O  O28  1  0.509  0.536  0.820  1.0
  O  O29  1  0.432  0.762  0.632  1.0
  O  O30  1  0.568  0.238  0.368  1.0
  O  O31  1  0.620  0.276  0.936  1.0
  O  O32  1  0.609  0.801  0.418  1.0
  O  O33  1  0.716  0.969  0.895  1.0
[/CIF]
.