The structure described by ReP3 is Hausmannite-like structured and crystallizes in the orthorhombic Pnma space group. Re(1) is bonded to one P(1), two equivalent P(2), and three equivalent P(3) atoms to form ReP6 octahedra that share corners with four equivalent Re(1)P6 octahedra, corners with two equivalent P(3)Re3P tetrahedra, corners with four equivalent P(2)Re2P2 tetrahedra, and edges with two equivalent Re(1)P6 octahedra. The corner-sharing octahedral tilt angles are 54°. There are three inequivalent P sites. In the first P site, P(2) is bonded to two equivalent Re(1), one P(1), and one P(3) atom to form distorted PRe2P2 tetrahedra that share corners with four equivalent Re(1)P6 octahedra, corners with two equivalent P(2)Re2P2 tetrahedra, corners with four equivalent P(3)Re3P tetrahedra, and  an edgeedge with one P(3)Re3P tetrahedra. The corner-sharing octahedral tilt angles range from 51-74°. In the second P site, P(1) is bonded in a distorted rectangular see-saw-like geometry to one Re(1), one P(2), and two equivalent P(1) atoms. In the third P site, P(3) is bonded to three equivalent Re(1) and one P(2) atom to form PRe3P tetrahedra that share corners with two equivalent Re(1)P6 octahedra, corners with four equivalent P(2)Re2P2 tetrahedra, corners with six equivalent P(3)Re3P tetrahedra, and  an edgeedge with one P(2)Re2P2 tetrahedra. The corner-sharing octahedral tilt angles are 64°. is represented by the CIF file [CIF]
data_ReP3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.149
_cell_length_b   5.125
_cell_length_c   15.366
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   247.946
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.250  0.351  0.650  1.0
  Re  Re1  1  0.250  0.149  0.150  1.0
  Re  Re2  1  0.750  0.649  0.350  1.0
  Re  Re3  1  0.750  0.851  0.850  1.0
  P  P4  1  0.250  0.146  0.513  1.0
  P  P5  1  0.250  0.354  0.013  1.0
  P  P6  1  0.750  0.854  0.487  1.0
  P  P7  1  0.750  0.646  0.987  1.0
  P  P8  1  0.250  0.179  0.882  1.0
  P  P9  1  0.250  0.321  0.382  1.0
  P  P10  1  0.750  0.821  0.118  1.0
  P  P11  1  0.750  0.679  0.618  1.0
  P  P12  1  0.250  0.522  0.793  1.0
  P  P13  1  0.250  0.978  0.293  1.0
  P  P14  1  0.750  0.478  0.207  1.0
  P  P15  1  0.750  0.022  0.707  1.0
[/CIF]
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The structure described by ReP3 is Hausmannite-like structured and crystallizes in the orthorhombic Pnma space group. Re(1) is bonded to one P(1), two equivalent P(2), and three equivalent P(3) atoms to form ReP6 octahedra that share corners with four equivalent Re(1)P6 octahedra, corners with two equivalent P(3)Re3P tetrahedra, corners with four equivalent P(2)Re2P2 tetrahedra, and edges with two equivalent Re(1)P6 octahedra. The corner-sharing octahedral tilt angles are 54°. There are three inequivalent P sites. In the first P site, P(2) is bonded to two equivalent Re(1), one P(1), and one P(3) atom to form distorted PRe2P2 tetrahedra that share corners with four equivalent Re(1)P6 octahedra, corners with two equivalent P(2)Re2P2 tetrahedra, corners with four equivalent P(3)Re3P tetrahedra, and  an edgeedge with one P(3)Re3P tetrahedra. The corner-sharing octahedral tilt angles range from 51-74°. In the second P site, P(1) is bonded in a distorted rectangular see-saw-like geometry to one Re(1), one P(2), and two equivalent P(1) atoms. In the third P site, P(3) is bonded to three equivalent Re(1) and one P(2) atom to form PRe3P tetrahedra that share corners with two equivalent Re(1)P6 octahedra, corners with four equivalent P(2)Re2P2 tetrahedra, corners with six equivalent P(3)Re3P tetrahedra, and  an edgeedge with one P(2)Re2P2 tetrahedra. The corner-sharing octahedral tilt angles are 64°. is represented by the CIF file [CIF]
data_ReP3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.149
_cell_length_b   5.125
_cell_length_c   15.366
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   247.946
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.250  0.351  0.650  1.0
  Re  Re1  1  0.250  0.149  0.150  1.0
  Re  Re2  1  0.750  0.649  0.350  1.0
  Re  Re3  1  0.750  0.851  0.850  1.0
  P  P4  1  0.250  0.146  0.513  1.0
  P  P5  1  0.250  0.354  0.013  1.0
  P  P6  1  0.750  0.854  0.487  1.0
  P  P7  1  0.750  0.646  0.987  1.0
  P  P8  1  0.250  0.179  0.882  1.0
  P  P9  1  0.250  0.321  0.382  1.0
  P  P10  1  0.750  0.821  0.118  1.0
  P  P11  1  0.750  0.679  0.618  1.0
  P  P12  1  0.250  0.522  0.793  1.0
  P  P13  1  0.250  0.978  0.293  1.0
  P  P14  1  0.750  0.478  0.207  1.0
  P  P15  1  0.750  0.022  0.707  1.0
[/CIF]
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