The material structure described by ZnC4(N2O)4 crystallizes in the tetragonal I-42d space group. Zn(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2) and two equivalent O(1) atoms. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1) and two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(2), and one N(2) atom. In the second N site, N(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. O(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF card [CIF]
data_ZnC4(N2O)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.058
_cell_length_b   10.058
_cell_length_c   10.058
_cell_angle_alpha   120.660
_cell_angle_beta   120.660
_cell_angle_gamma   88.860
_symmetry_Int_Tables_number   1
_cell_volume   712.107
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.750  0.250  0.500  1.0
  Zn  Zn1  1  0.000  0.000  0.000  1.0
  C  C2  1  0.053  0.125  0.428  1.0
  C  C3  1  0.697  0.625  0.572  1.0
  C  C4  1  0.875  0.303  0.928  1.0
  C  C5  1  0.375  0.947  0.072  1.0
  C  C6  1  0.905  0.125  0.280  1.0
  C  C7  1  0.845  0.625  0.720  1.0
  C  C8  1  0.875  0.155  0.780  1.0
  C  C9  1  0.375  0.095  0.220  1.0
  N  N10  1  0.241  0.128  0.207  1.0
  N  N11  1  0.922  0.034  0.793  1.0
  N  N12  1  0.872  0.078  0.113  1.0
  N  N13  1  0.509  0.216  0.387  1.0
  N  N14  1  0.966  0.759  0.887  1.0
  N  N15  1  0.828  0.122  0.613  1.0
  N  N16  1  0.878  0.491  0.707  1.0
  N  N17  1  0.784  0.172  0.293  1.0
  N  N18  1  0.296  0.275  0.372  1.0
  N  N19  1  0.903  0.923  0.628  1.0
  N  N20  1  0.725  0.097  0.021  1.0
  N  N21  1  0.454  0.327  0.479  1.0
  N  N22  1  0.077  0.704  0.979  1.0
  N  N23  1  0.847  0.975  0.521  1.0
  N  N24  1  0.025  0.546  0.872  1.0
  N  N25  1  0.673  0.153  0.128  1.0
  O  O26  1  0.115  0.228  0.603  1.0
  O  O27  1  0.625  0.513  0.397  1.0
  O  O28  1  0.772  0.375  0.887  1.0
  O  O29  1  0.635  0.737  0.613  1.0
  O  O30  1  0.487  0.885  0.113  1.0
  O  O31  1  0.125  0.022  0.387  1.0
  O  O32  1  0.978  0.365  0.103  1.0
  O  O33  1  0.263  0.875  0.897  1.0
[/CIF]
.
The material structure described by ZnC4(N2O)4 crystallizes in the tetragonal I-42d space group. Zn(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2) and two equivalent O(1) atoms. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1) and two equivalent N(1) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(2), and one N(2) atom. In the second N site, N(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. O(1) is bonded in a single-bond geometry to one C(1) atom. is represented by the CIF card [CIF]
data_ZnC4(N2O)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.058
_cell_length_b   10.058
_cell_length_c   10.058
_cell_angle_alpha   120.660
_cell_angle_beta   120.660
_cell_angle_gamma   88.860
_symmetry_Int_Tables_number   1
_cell_volume   712.107
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.750  0.250  0.500  1.0
  Zn  Zn1  1  0.000  0.000  0.000  1.0
  C  C2  1  0.053  0.125  0.428  1.0
  C  C3  1  0.697  0.625  0.572  1.0
  C  C4  1  0.875  0.303  0.928  1.0
  C  C5  1  0.375  0.947  0.072  1.0
  C  C6  1  0.905  0.125  0.280  1.0
  C  C7  1  0.845  0.625  0.720  1.0
  C  C8  1  0.875  0.155  0.780  1.0
  C  C9  1  0.375  0.095  0.220  1.0
  N  N10  1  0.241  0.128  0.207  1.0
  N  N11  1  0.922  0.034  0.793  1.0
  N  N12  1  0.872  0.078  0.113  1.0
  N  N13  1  0.509  0.216  0.387  1.0
  N  N14  1  0.966  0.759  0.887  1.0
  N  N15  1  0.828  0.122  0.613  1.0
  N  N16  1  0.878  0.491  0.707  1.0
  N  N17  1  0.784  0.172  0.293  1.0
  N  N18  1  0.296  0.275  0.372  1.0
  N  N19  1  0.903  0.923  0.628  1.0
  N  N20  1  0.725  0.097  0.021  1.0
  N  N21  1  0.454  0.327  0.479  1.0
  N  N22  1  0.077  0.704  0.979  1.0
  N  N23  1  0.847  0.975  0.521  1.0
  N  N24  1  0.025  0.546  0.872  1.0
  N  N25  1  0.673  0.153  0.128  1.0
  O  O26  1  0.115  0.228  0.603  1.0
  O  O27  1  0.625  0.513  0.397  1.0
  O  O28  1  0.772  0.375  0.887  1.0
  O  O29  1  0.635  0.737  0.613  1.0
  O  O30  1  0.487  0.885  0.113  1.0
  O  O31  1  0.125  0.022  0.387  1.0
  O  O32  1  0.978  0.365  0.103  1.0
  O  O33  1  0.263  0.875  0.897  1.0
[/CIF]
.