The material structure described by DyPS crystallizes in the orthorhombic Pnma space group. There are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 9-coordinate geometry to four equivalent P(1), two equivalent S(2), and three equivalent S(1) atoms. In the second Dy site, Dy(2) is bonded in a 9-coordinate geometry to four equivalent P(1), two equivalent S(1), and three equivalent S(2) atoms. P(1) is bonded in a distorted hexagonal planar geometry to two equivalent Dy(1), two equivalent Dy(2), and two equivalent P(1) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Dy(2) and three equivalent Dy(1) atoms to form a mixture of distorted corner and edge-sharing SDy5 trigonal bipyramids. In the second S site, S(2) is bonded to two equivalent Dy(1) and three equivalent Dy(2) atoms to form a mixture of distorted corner and edge-sharing SDy5 trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_DyPS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.325
_cell_length_b   5.357
_cell_length_c   16.694
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   476.225
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.250  0.484  0.362  1.0
  Dy  Dy1  1  0.250  0.984  0.138  1.0
  Dy  Dy2  1  0.750  0.516  0.638  1.0
  Dy  Dy3  1  0.750  0.016  0.862  1.0
  Dy  Dy4  1  0.250  0.014  0.647  1.0
  Dy  Dy5  1  0.250  0.514  0.853  1.0
  Dy  Dy6  1  0.750  0.986  0.353  1.0
  Dy  Dy7  1  0.750  0.486  0.147  1.0
  P  P8  1  0.039  0.295  0.997  1.0
  P  P9  1  0.461  0.795  0.503  1.0
  P  P10  1  0.539  0.705  0.003  1.0
  P  P11  1  0.961  0.205  0.497  1.0
  P  P12  1  0.961  0.705  0.003  1.0
  P  P13  1  0.539  0.205  0.497  1.0
  P  P14  1  0.461  0.295  0.997  1.0
  P  P15  1  0.039  0.795  0.503  1.0
  S  S16  1  0.250  0.485  0.189  1.0
  S  S17  1  0.250  0.985  0.311  1.0
  S  S18  1  0.750  0.515  0.811  1.0
  S  S19  1  0.750  0.015  0.689  1.0
  S  S20  1  0.250  0.011  0.816  1.0
  S  S21  1  0.250  0.511  0.684  1.0
  S  S22  1  0.750  0.989  0.184  1.0
  S  S23  1  0.750  0.489  0.316  1.0
[/CIF]
.
The material structure described by DyPS crystallizes in the orthorhombic Pnma space group. There are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 9-coordinate geometry to four equivalent P(1), two equivalent S(2), and three equivalent S(1) atoms. In the second Dy site, Dy(2) is bonded in a 9-coordinate geometry to four equivalent P(1), two equivalent S(1), and three equivalent S(2) atoms. P(1) is bonded in a distorted hexagonal planar geometry to two equivalent Dy(1), two equivalent Dy(2), and two equivalent P(1) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded to two equivalent Dy(2) and three equivalent Dy(1) atoms to form a mixture of distorted corner and edge-sharing SDy5 trigonal bipyramids. In the second S site, S(2) is bonded to two equivalent Dy(1) and three equivalent Dy(2) atoms to form a mixture of distorted corner and edge-sharing SDy5 trigonal bipyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_DyPS
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.325
_cell_length_b   5.357
_cell_length_c   16.694
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   476.225
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.250  0.484  0.362  1.0
  Dy  Dy1  1  0.250  0.984  0.138  1.0
  Dy  Dy2  1  0.750  0.516  0.638  1.0
  Dy  Dy3  1  0.750  0.016  0.862  1.0
  Dy  Dy4  1  0.250  0.014  0.647  1.0
  Dy  Dy5  1  0.250  0.514  0.853  1.0
  Dy  Dy6  1  0.750  0.986  0.353  1.0
  Dy  Dy7  1  0.750  0.486  0.147  1.0
  P  P8  1  0.039  0.295  0.997  1.0
  P  P9  1  0.461  0.795  0.503  1.0
  P  P10  1  0.539  0.705  0.003  1.0
  P  P11  1  0.961  0.205  0.497  1.0
  P  P12  1  0.961  0.705  0.003  1.0
  P  P13  1  0.539  0.205  0.497  1.0
  P  P14  1  0.461  0.295  0.997  1.0
  P  P15  1  0.039  0.795  0.503  1.0
  S  S16  1  0.250  0.485  0.189  1.0
  S  S17  1  0.250  0.985  0.311  1.0
  S  S18  1  0.750  0.515  0.811  1.0
  S  S19  1  0.750  0.015  0.689  1.0
  S  S20  1  0.250  0.011  0.816  1.0
  S  S21  1  0.250  0.511  0.684  1.0
  S  S22  1  0.750  0.989  0.184  1.0
  S  S23  1  0.750  0.489  0.316  1.0
[/CIF]
.