The crystal structure described by Na2Pd(NO3)4 crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), two equivalent O(5), and two equivalent O(6) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(4) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Na(1), one Pd(1), and one N(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Na(1) and one N(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Pd(1) and one N(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one N(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Na(1) and one N(1) atom. is represented by the CIF file [CIF]
data_Na2Pd(NO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.965
_cell_length_b   7.239
_cell_length_c   9.160
_cell_angle_alpha   88.233
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   527.878
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.064  0.223  0.382  1.0
  Na  Na1  1  0.936  0.777  0.618  1.0
  Na  Na2  1  0.436  0.223  0.882  1.0
  Na  Na3  1  0.564  0.777  0.118  1.0
  Pd  Pd4  1  0.000  0.500  0.000  1.0
  Pd  Pd5  1  0.500  0.500  0.500  1.0
  N  N6  1  0.895  0.646  0.277  1.0
  N  N7  1  0.605  0.646  0.777  1.0
  N  N8  1  0.287  0.817  0.436  1.0
  N  N9  1  0.105  0.354  0.723  1.0
  N  N10  1  0.787  0.183  0.064  1.0
  N  N11  1  0.713  0.183  0.564  1.0
  N  N12  1  0.395  0.354  0.223  1.0
  N  N13  1  0.213  0.817  0.936  1.0
  O  O14  1  0.147  0.353  0.863  1.0
  O  O15  1  0.893  0.152  0.161  1.0
  O  O16  1  0.017  0.552  0.321  1.0
  O  O17  1  0.695  0.322  0.470  1.0
  O  O18  1  0.393  0.848  0.339  1.0
  O  O19  1  0.343  0.913  0.952  1.0
  O  O20  1  0.353  0.353  0.363  1.0
  O  O21  1  0.983  0.448  0.679  1.0
  O  O22  1  0.694  0.742  0.856  1.0
  O  O23  1  0.195  0.678  0.030  1.0
  O  O24  1  0.806  0.742  0.356  1.0
  O  O25  1  0.107  0.848  0.839  1.0
  O  O26  1  0.805  0.322  0.970  1.0
  O  O27  1  0.483  0.552  0.821  1.0
  O  O28  1  0.647  0.647  0.637  1.0
  O  O29  1  0.607  0.152  0.661  1.0
  O  O30  1  0.305  0.678  0.530  1.0
  O  O31  1  0.853  0.647  0.137  1.0
  O  O32  1  0.657  0.087  0.048  1.0
  O  O33  1  0.194  0.258  0.644  1.0
  O  O34  1  0.517  0.448  0.179  1.0
  O  O35  1  0.157  0.913  0.452  1.0
  O  O36  1  0.843  0.087  0.548  1.0
  O  O37  1  0.306  0.258  0.144  1.0
[/CIF]
.
The crystal structure described by Na2Pd(NO3)4 crystallizes in the monoclinic P2_1/c space group. Na(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), two equivalent O(5), and two equivalent O(6) atoms. Pd(1) is bonded in a square co-planar geometry to two equivalent O(1) and two equivalent O(4) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(2), one O(4), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Na(1), one Pd(1), and one N(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Na(1) and one N(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Pd(1) and one N(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one N(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Na(1) and one N(1) atom. is represented by the CIF file [CIF]
data_Na2Pd(NO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.965
_cell_length_b   7.239
_cell_length_c   9.160
_cell_angle_alpha   88.233
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   527.878
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.064  0.223  0.382  1.0
  Na  Na1  1  0.936  0.777  0.618  1.0
  Na  Na2  1  0.436  0.223  0.882  1.0
  Na  Na3  1  0.564  0.777  0.118  1.0
  Pd  Pd4  1  0.000  0.500  0.000  1.0
  Pd  Pd5  1  0.500  0.500  0.500  1.0
  N  N6  1  0.895  0.646  0.277  1.0
  N  N7  1  0.605  0.646  0.777  1.0
  N  N8  1  0.287  0.817  0.436  1.0
  N  N9  1  0.105  0.354  0.723  1.0
  N  N10  1  0.787  0.183  0.064  1.0
  N  N11  1  0.713  0.183  0.564  1.0
  N  N12  1  0.395  0.354  0.223  1.0
  N  N13  1  0.213  0.817  0.936  1.0
  O  O14  1  0.147  0.353  0.863  1.0
  O  O15  1  0.893  0.152  0.161  1.0
  O  O16  1  0.017  0.552  0.321  1.0
  O  O17  1  0.695  0.322  0.470  1.0
  O  O18  1  0.393  0.848  0.339  1.0
  O  O19  1  0.343  0.913  0.952  1.0
  O  O20  1  0.353  0.353  0.363  1.0
  O  O21  1  0.983  0.448  0.679  1.0
  O  O22  1  0.694  0.742  0.856  1.0
  O  O23  1  0.195  0.678  0.030  1.0
  O  O24  1  0.806  0.742  0.356  1.0
  O  O25  1  0.107  0.848  0.839  1.0
  O  O26  1  0.805  0.322  0.970  1.0
  O  O27  1  0.483  0.552  0.821  1.0
  O  O28  1  0.647  0.647  0.637  1.0
  O  O29  1  0.607  0.152  0.661  1.0
  O  O30  1  0.305  0.678  0.530  1.0
  O  O31  1  0.853  0.647  0.137  1.0
  O  O32  1  0.657  0.087  0.048  1.0
  O  O33  1  0.194  0.258  0.644  1.0
  O  O34  1  0.517  0.448  0.179  1.0
  O  O35  1  0.157  0.913  0.452  1.0
  O  O36  1  0.843  0.087  0.548  1.0
  O  O37  1  0.306  0.258  0.144  1.0
[/CIF]
.