The material structure described by Te3(W2N)2 crystallizes in the orthorhombic Pnma space group. There are three inequivalent W sites. In the first W site, W(1) is bonded in a 2-coordinate geometry to two equivalent N(1) and four equivalent Te(2) atoms. In the second W site, W(2) is bonded in a 2-coordinate geometry to two equivalent N(1), one Te(1), and two equivalent Te(2) atoms. In the third W site, W(3) is bonded in a 2-coordinate geometry to two equivalent N(1), one Te(1), and two equivalent Te(2) atoms. N(1) is bonded in a distorted rectangular see-saw-like geometry to one W(1), one W(2), and two equivalent W(3) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to one W(2) and two equivalent W(3) atoms. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to one W(2), two equivalent W(1), and two equivalent W(3) atoms. is represented by the CIF file [CIF]
data_Te3(W2N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.579
_cell_length_b   10.393
_cell_length_c   11.789
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   683.480
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.848  0.250  0.129  1.0
  Te  Te1  1  0.348  0.250  0.371  1.0
  Te  Te2  1  0.152  0.750  0.871  1.0
  Te  Te3  1  0.652  0.750  0.629  1.0
  Te  Te4  1  0.549  0.533  0.312  1.0
  Te  Te5  1  0.049  0.967  0.188  1.0
  Te  Te6  1  0.451  0.033  0.688  1.0
  Te  Te7  1  0.951  0.467  0.812  1.0
  Te  Te8  1  0.451  0.467  0.688  1.0
  Te  Te9  1  0.951  0.033  0.812  1.0
  Te  Te10  1  0.549  0.967  0.312  1.0
  Te  Te11  1  0.049  0.533  0.188  1.0
  W  W12  1  0.605  0.250  0.817  1.0
  W  W13  1  0.105  0.250  0.683  1.0
  W  W14  1  0.395  0.750  0.183  1.0
  W  W15  1  0.895  0.750  0.317  1.0
  W  W16  1  0.650  0.250  0.571  1.0
  W  W17  1  0.150  0.250  0.929  1.0
  W  W18  1  0.350  0.750  0.429  1.0
  W  W19  1  0.850  0.750  0.071  1.0
  W  W20  1  0.732  0.464  0.013  1.0
  W  W21  1  0.232  0.036  0.487  1.0
  W  W22  1  0.268  0.964  0.987  1.0
  W  W23  1  0.768  0.536  0.513  1.0
  W  W24  1  0.268  0.536  0.987  1.0
  W  W25  1  0.768  0.964  0.513  1.0
  W  W26  1  0.732  0.036  0.013  1.0
  W  W27  1  0.232  0.464  0.487  1.0
  N  N28  1  0.562  0.627  0.059  1.0
  N  N29  1  0.062  0.873  0.441  1.0
  N  N30  1  0.438  0.127  0.941  1.0
  N  N31  1  0.938  0.373  0.559  1.0
  N  N32  1  0.438  0.373  0.941  1.0
  N  N33  1  0.938  0.127  0.559  1.0
  N  N34  1  0.562  0.873  0.059  1.0
  N  N35  1  0.062  0.627  0.441  1.0
[/CIF]
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The material structure described by Te3(W2N)2 crystallizes in the orthorhombic Pnma space group. There are three inequivalent W sites. In the first W site, W(1) is bonded in a 2-coordinate geometry to two equivalent N(1) and four equivalent Te(2) atoms. In the second W site, W(2) is bonded in a 2-coordinate geometry to two equivalent N(1), one Te(1), and two equivalent Te(2) atoms. In the third W site, W(3) is bonded in a 2-coordinate geometry to two equivalent N(1), one Te(1), and two equivalent Te(2) atoms. N(1) is bonded in a distorted rectangular see-saw-like geometry to one W(1), one W(2), and two equivalent W(3) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a 3-coordinate geometry to one W(2) and two equivalent W(3) atoms. In the second Te site, Te(2) is bonded in a 5-coordinate geometry to one W(2), two equivalent W(1), and two equivalent W(3) atoms. is represented by the CIF file [CIF]
data_Te3(W2N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.579
_cell_length_b   10.393
_cell_length_c   11.789
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   683.480
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.848  0.250  0.129  1.0
  Te  Te1  1  0.348  0.250  0.371  1.0
  Te  Te2  1  0.152  0.750  0.871  1.0
  Te  Te3  1  0.652  0.750  0.629  1.0
  Te  Te4  1  0.549  0.533  0.312  1.0
  Te  Te5  1  0.049  0.967  0.188  1.0
  Te  Te6  1  0.451  0.033  0.688  1.0
  Te  Te7  1  0.951  0.467  0.812  1.0
  Te  Te8  1  0.451  0.467  0.688  1.0
  Te  Te9  1  0.951  0.033  0.812  1.0
  Te  Te10  1  0.549  0.967  0.312  1.0
  Te  Te11  1  0.049  0.533  0.188  1.0
  W  W12  1  0.605  0.250  0.817  1.0
  W  W13  1  0.105  0.250  0.683  1.0
  W  W14  1  0.395  0.750  0.183  1.0
  W  W15  1  0.895  0.750  0.317  1.0
  W  W16  1  0.650  0.250  0.571  1.0
  W  W17  1  0.150  0.250  0.929  1.0
  W  W18  1  0.350  0.750  0.429  1.0
  W  W19  1  0.850  0.750  0.071  1.0
  W  W20  1  0.732  0.464  0.013  1.0
  W  W21  1  0.232  0.036  0.487  1.0
  W  W22  1  0.268  0.964  0.987  1.0
  W  W23  1  0.768  0.536  0.513  1.0
  W  W24  1  0.268  0.536  0.987  1.0
  W  W25  1  0.768  0.964  0.513  1.0
  W  W26  1  0.732  0.036  0.013  1.0
  W  W27  1  0.232  0.464  0.487  1.0
  N  N28  1  0.562  0.627  0.059  1.0
  N  N29  1  0.062  0.873  0.441  1.0
  N  N30  1  0.438  0.127  0.941  1.0
  N  N31  1  0.938  0.373  0.559  1.0
  N  N32  1  0.438  0.373  0.941  1.0
  N  N33  1  0.938  0.127  0.559  1.0
  N  N34  1  0.562  0.873  0.059  1.0
  N  N35  1  0.062  0.627  0.441  1.0
[/CIF]
.