The structure described by Mo3Ag2Te3O16 crystallizes in the monoclinic C2 space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form distorted MoO6 octahedra that share corners with two equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-73°. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to two equivalent O(4), two equivalent O(7), and two equivalent O(8) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(8) atoms to form AgO6 octahedra that share corners with four equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-73°. In the second Ag site, Ag(2) is bonded in a distorted bent 120 degrees geometry to two equivalent O(2) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Te site, Te(2) is bonded in a 3-coordinate geometry to one O(2), one O(3), one O(4), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one Te(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Ag(2), one Te(1), and one Te(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mo(1), one Ag(1), and one Te(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mo(1), one Mo(2), and one Te(2) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Mo(1) and one Ag(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Mo(2), one Ag(1), and one Te(2) atom. is represented by the CIF file [CIF]
data_Ag2Te3Mo3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.807
_cell_length_b   7.807
_cell_length_c   7.546
_cell_angle_alpha   65.721
_cell_angle_beta   65.721
_cell_angle_gamma   95.419
_symmetry_Int_Tables_number   1
_cell_volume   362.452
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.096  0.904  0.500  1.0
  Ag  Ag1  1  0.532  0.468  0.000  1.0
  Te  Te2  1  0.594  0.406  0.500  1.0
  Te  Te3  1  0.977  0.470  0.999  1.0
  Te  Te4  1  0.530  0.023  0.001  1.0
  Mo  Mo5  1  0.616  0.938  0.467  1.0
  Mo  Mo6  1  0.062  0.384  0.533  1.0
  Mo  Mo7  1  0.999  0.001  0.000  1.0
  O  O8  1  0.865  0.458  0.438  1.0
  O  O9  1  0.542  0.135  0.562  1.0
  O  O10  1  0.718  0.490  0.162  1.0
  O  O11  1  0.510  0.282  0.838  1.0
  O  O12  1  0.939  0.522  0.754  1.0
  O  O13  1  0.478  0.061  0.246  1.0
  O  O14  1  0.879  0.183  0.159  1.0
  O  O15  1  0.817  0.121  0.841  1.0
  O  O16  1  0.750  0.866  0.609  1.0
  O  O17  1  0.134  0.250  0.391  1.0
  O  O18  1  0.394  0.739  0.650  1.0
  O  O19  1  0.261  0.606  0.350  1.0
  O  O20  1  0.737  0.833  0.260  1.0
  O  O21  1  0.167  0.263  0.740  1.0
  O  O22  1  0.150  0.962  0.127  1.0
  O  O23  1  0.038  0.850  0.873  1.0
[/CIF]
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The structure described by Mo3Ag2Te3O16 crystallizes in the monoclinic C2 space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form distorted MoO6 octahedra that share corners with two equivalent Ag(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-73°. In the second Mo site, Mo(2) is bonded in a 6-coordinate geometry to two equivalent O(4), two equivalent O(7), and two equivalent O(8) atoms. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to two equivalent O(3), two equivalent O(5), and two equivalent O(8) atoms to form AgO6 octahedra that share corners with four equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-73°. In the second Ag site, Ag(2) is bonded in a distorted bent 120 degrees geometry to two equivalent O(2) atoms. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. In the second Te site, Te(2) is bonded in a 3-coordinate geometry to one O(2), one O(3), one O(4), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mo(1) and one Te(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Ag(2), one Te(1), and one Te(2) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Mo(1), one Ag(1), and one Te(2) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Mo(1), one Mo(2), and one Te(2) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Mo(1) and one Ag(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Mo(1) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Mo(2), one Ag(1), and one Te(2) atom. is represented by the CIF file [CIF]
data_Ag2Te3Mo3O16
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.807
_cell_length_b   7.807
_cell_length_c   7.546
_cell_angle_alpha   65.721
_cell_angle_beta   65.721
_cell_angle_gamma   95.419
_symmetry_Int_Tables_number   1
_cell_volume   362.452
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.096  0.904  0.500  1.0
  Ag  Ag1  1  0.532  0.468  0.000  1.0
  Te  Te2  1  0.594  0.406  0.500  1.0
  Te  Te3  1  0.977  0.470  0.999  1.0
  Te  Te4  1  0.530  0.023  0.001  1.0
  Mo  Mo5  1  0.616  0.938  0.467  1.0
  Mo  Mo6  1  0.062  0.384  0.533  1.0
  Mo  Mo7  1  0.999  0.001  0.000  1.0
  O  O8  1  0.865  0.458  0.438  1.0
  O  O9  1  0.542  0.135  0.562  1.0
  O  O10  1  0.718  0.490  0.162  1.0
  O  O11  1  0.510  0.282  0.838  1.0
  O  O12  1  0.939  0.522  0.754  1.0
  O  O13  1  0.478  0.061  0.246  1.0
  O  O14  1  0.879  0.183  0.159  1.0
  O  O15  1  0.817  0.121  0.841  1.0
  O  O16  1  0.750  0.866  0.609  1.0
  O  O17  1  0.134  0.250  0.391  1.0
  O  O18  1  0.394  0.739  0.650  1.0
  O  O19  1  0.261  0.606  0.350  1.0
  O  O20  1  0.737  0.833  0.260  1.0
  O  O21  1  0.167  0.263  0.740  1.0
  O  O22  1  0.150  0.962  0.127  1.0
  O  O23  1  0.038  0.850  0.873  1.0
[/CIF]
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