The crystal structure described by (AgH8(CN2)4)2F2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrofluoric acid atoms and two AgH8(CN2)4 clusters. In each AgH8(CN2)4 cluster, Ag(1) is bonded in a distorted bent 150 degrees geometry to one N(5) and one N(6) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(4) atom. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one N(6) atom. In the third C site, C(3) is bonded in a linear geometry to one N(5) and one N(7) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(3), one N(7), and one N(8) atom. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(6) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one H(1), and one H(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one H(4), and one H(5) atom. In the fifth N site, N(5) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one C(3) atom. In the sixth N site, N(6) is bonded in a linear geometry to one Ag(1) and one C(2) atom. In the seventh N site, N(7) is bonded in a bent 120 degrees geometry to one C(3) and one C(4) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(4), one H(7), and one H(8) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(8) atom. is represented by the CIF card [CIF]
data_AgH8C4N8F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.208
_cell_length_b   7.734
_cell_length_c   9.839
_cell_angle_alpha   93.039
_cell_angle_beta   97.804
_cell_angle_gamma   97.650
_symmetry_Int_Tables_number   1
_cell_volume   462.662
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.133  0.358  0.925  1.0
  Ag  Ag1  1  0.867  0.642  0.075  1.0
  H  H2  1  0.045  0.273  0.562  1.0
  H  H3  1  0.111  0.485  0.631  1.0
  H  H4  1  0.209  0.861  0.621  1.0
  H  H5  1  0.081  0.010  0.303  1.0
  H  H6  1  0.102  0.996  0.126  1.0
  H  H7  1  0.363  0.743  0.736  1.0
  H  H8  1  0.324  0.113  0.529  1.0
  H  H9  1  0.403  0.812  0.404  1.0
  H  H10  1  0.597  0.188  0.596  1.0
  H  H11  1  0.676  0.887  0.471  1.0
  H  H12  1  0.637  0.257  0.264  1.0
  H  H13  1  0.898  0.004  0.874  1.0
  H  H14  1  0.919  0.990  0.697  1.0
  H  H15  1  0.791  0.139  0.379  1.0
  H  H16  1  0.889  0.515  0.369  1.0
  H  H17  1  0.955  0.727  0.438  1.0
  C  C18  1  0.141  0.872  0.823  1.0
  C  C19  1  0.391  0.782  0.987  1.0
  C  C20  1  0.303  0.521  0.251  1.0
  C  C21  1  0.372  0.362  0.619  1.0
  C  C22  1  0.628  0.638  0.381  1.0
  C  C23  1  0.697  0.479  0.749  1.0
  C  C24  1  0.609  0.218  0.013  1.0
  C  C25  1  0.859  0.128  0.177  1.0
  N  N26  1  0.202  0.836  0.956  1.0
  N  N27  1  0.251  0.827  0.721  1.0
  N  N28  1  0.161  0.384  0.580  1.0
  N  N29  1  0.034  0.047  0.205  1.0
  N  N30  1  0.127  0.529  0.190  1.0
  N  N31  1  0.439  0.265  0.977  1.0
  N  N32  1  0.506  0.500  0.690  1.0
  N  N33  1  0.435  0.209  0.586  1.0
  N  N34  1  0.565  0.791  0.414  1.0
  N  N35  1  0.494  0.500  0.310  1.0
  N  N36  1  0.561  0.735  0.023  1.0
  N  N37  1  0.873  0.471  0.810  1.0
  N  N38  1  0.966  0.953  0.795  1.0
  N  N39  1  0.839  0.616  0.420  1.0
  N  N40  1  0.749  0.173  0.279  1.0
  N  N41  1  0.798  0.164  0.044  1.0
  F  F42  1  0.173  0.905  0.447  1.0
  F  F43  1  0.827  0.095  0.553  1.0
[/CIF]
.
The crystal structure described by (AgH8(CN2)4)2F2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two hydrofluoric acid atoms and two AgH8(CN2)4 clusters. In each AgH8(CN2)4 cluster, Ag(1) is bonded in a distorted bent 150 degrees geometry to one N(5) and one N(6) atom. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(4) atom. In the second C site, C(2) is bonded in a linear geometry to one N(1) and one N(6) atom. In the third C site, C(3) is bonded in a linear geometry to one N(5) and one N(7) atom. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(3), one N(7), and one N(8) atom. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one H(3), and one H(6) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one C(4), one H(1), and one H(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one H(4), and one H(5) atom. In the fifth N site, N(5) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one C(3) atom. In the sixth N site, N(6) is bonded in a linear geometry to one Ag(1) and one C(2) atom. In the seventh N site, N(7) is bonded in a bent 120 degrees geometry to one C(3) and one C(4) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(4), one H(7), and one H(8) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(8) atom. is represented by the CIF card [CIF]
data_AgH8C4N8F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.208
_cell_length_b   7.734
_cell_length_c   9.839
_cell_angle_alpha   93.039
_cell_angle_beta   97.804
_cell_angle_gamma   97.650
_symmetry_Int_Tables_number   1
_cell_volume   462.662
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.133  0.358  0.925  1.0
  Ag  Ag1  1  0.867  0.642  0.075  1.0
  H  H2  1  0.045  0.273  0.562  1.0
  H  H3  1  0.111  0.485  0.631  1.0
  H  H4  1  0.209  0.861  0.621  1.0
  H  H5  1  0.081  0.010  0.303  1.0
  H  H6  1  0.102  0.996  0.126  1.0
  H  H7  1  0.363  0.743  0.736  1.0
  H  H8  1  0.324  0.113  0.529  1.0
  H  H9  1  0.403  0.812  0.404  1.0
  H  H10  1  0.597  0.188  0.596  1.0
  H  H11  1  0.676  0.887  0.471  1.0
  H  H12  1  0.637  0.257  0.264  1.0
  H  H13  1  0.898  0.004  0.874  1.0
  H  H14  1  0.919  0.990  0.697  1.0
  H  H15  1  0.791  0.139  0.379  1.0
  H  H16  1  0.889  0.515  0.369  1.0
  H  H17  1  0.955  0.727  0.438  1.0
  C  C18  1  0.141  0.872  0.823  1.0
  C  C19  1  0.391  0.782  0.987  1.0
  C  C20  1  0.303  0.521  0.251  1.0
  C  C21  1  0.372  0.362  0.619  1.0
  C  C22  1  0.628  0.638  0.381  1.0
  C  C23  1  0.697  0.479  0.749  1.0
  C  C24  1  0.609  0.218  0.013  1.0
  C  C25  1  0.859  0.128  0.177  1.0
  N  N26  1  0.202  0.836  0.956  1.0
  N  N27  1  0.251  0.827  0.721  1.0
  N  N28  1  0.161  0.384  0.580  1.0
  N  N29  1  0.034  0.047  0.205  1.0
  N  N30  1  0.127  0.529  0.190  1.0
  N  N31  1  0.439  0.265  0.977  1.0
  N  N32  1  0.506  0.500  0.690  1.0
  N  N33  1  0.435  0.209  0.586  1.0
  N  N34  1  0.565  0.791  0.414  1.0
  N  N35  1  0.494  0.500  0.310  1.0
  N  N36  1  0.561  0.735  0.023  1.0
  N  N37  1  0.873  0.471  0.810  1.0
  N  N38  1  0.966  0.953  0.795  1.0
  N  N39  1  0.839  0.616  0.420  1.0
  N  N40  1  0.749  0.173  0.279  1.0
  N  N41  1  0.798  0.164  0.044  1.0
  F  F42  1  0.173  0.905  0.447  1.0
  F  F43  1  0.827  0.095  0.553  1.0
[/CIF]
.