The material structure described by ReOCl4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ReOCl4 clusters. Re(1,2) is bonded in a 5-coordinate geometry to one O(2); one Cl(5); one Cl(8); and two equivalent Cl(3,4) atoms. O(2) is bonded in a single-bond geometry to one Re(1,2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(8) is bonded in a single-bond geometry to one Re(1,2) atom. In the second Cl site, Cl(3,4) is bonded in a single-bond geometry to one Re(1,2) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Re(1,2) atom. is represented by the CIF file [CIF]
data_ReCl4O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.153
_cell_length_b   13.562
_cell_length_c   19.750
_cell_angle_alpha   63.697
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1477.338
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.890  0.402  0.420  1.0
  Re  Re1  1  0.390  0.598  0.080  1.0
  Re  Re2  1  0.110  0.598  0.580  1.0
  Re  Re3  1  0.610  0.402  0.920  1.0
  Re  Re4  1  0.509  0.098  0.332  1.0
  Re  Re5  1  0.009  0.902  0.168  1.0
  Re  Re6  1  0.491  0.902  0.668  1.0
  Re  Re7  1  0.991  0.098  0.832  1.0
  Cl  Cl8  1  0.368  0.107  0.222  1.0
  Cl  Cl9  1  0.127  0.923  0.888  1.0
  Cl  Cl10  1  0.627  0.077  0.612  1.0
  Cl  Cl11  1  0.873  0.077  0.112  1.0
  Cl  Cl12  1  0.373  0.923  0.388  1.0
  Cl  Cl13  1  0.132  0.107  0.722  1.0
  Cl  Cl14  1  0.632  0.893  0.778  1.0
  Cl  Cl15  1  0.868  0.893  0.278  1.0
  Cl  Cl16  1  0.751  0.576  0.859  1.0
  Cl  Cl17  1  0.251  0.424  0.641  1.0
  Cl  Cl18  1  0.249  0.424  0.141  1.0
  Cl  Cl19  1  0.749  0.576  0.359  1.0
  Cl  Cl20  1  0.345  0.289  0.995  1.0
  Cl  Cl21  1  0.845  0.711  0.505  1.0
  Cl  Cl22  1  0.655  0.711  0.005  1.0
  Cl  Cl23  1  0.155  0.289  0.495  1.0
  Cl  Cl24  1  0.354  0.461  0.826  1.0
  Cl  Cl25  1  0.854  0.539  0.674  1.0
  Cl  Cl26  1  0.646  0.539  0.174  1.0
  Cl  Cl27  1  0.146  0.461  0.326  1.0
  Cl  Cl28  1  0.730  0.034  0.924  1.0
  Cl  Cl29  1  0.230  0.966  0.576  1.0
  Cl  Cl30  1  0.270  0.966  0.076  1.0
  Cl  Cl31  1  0.770  0.034  0.424  1.0
  Cl  Cl32  1  0.729  0.215  0.757  1.0
  Cl  Cl33  1  0.229  0.785  0.743  1.0
  Cl  Cl34  1  0.271  0.785  0.243  1.0
  Cl  Cl35  1  0.771  0.215  0.257  1.0
  Cl  Cl36  1  0.747  0.401  0.028  1.0
  Cl  Cl37  1  0.247  0.599  0.472  1.0
  Cl  Cl38  1  0.253  0.599  0.972  1.0
  Cl  Cl39  1  0.753  0.401  0.528  1.0
  O  O40  1  0.159  0.175  0.856  1.0
  O  O41  1  0.720  0.321  0.400  1.0
  O  O42  1  0.220  0.679  0.100  1.0
  O  O43  1  0.280  0.679  0.600  1.0
  O  O44  1  0.780  0.321  0.900  1.0
  O  O45  1  0.341  0.175  0.356  1.0
  O  O46  1  0.841  0.825  0.144  1.0
  O  O47  1  0.659  0.825  0.644  1.0
[/CIF]
.
The material structure described by ReOCl4 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight ReOCl4 clusters. Re(1,2) is bonded in a 5-coordinate geometry to one O(2); one Cl(5); one Cl(8); and two equivalent Cl(3,4) atoms. O(2) is bonded in a single-bond geometry to one Re(1,2) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(8) is bonded in a single-bond geometry to one Re(1,2) atom. In the second Cl site, Cl(3,4) is bonded in a single-bond geometry to one Re(1,2) atom. In the third Cl site, Cl(5) is bonded in a single-bond geometry to one Re(1,2) atom. is represented by the CIF file [CIF]
data_ReCl4O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.153
_cell_length_b   13.562
_cell_length_c   19.750
_cell_angle_alpha   63.697
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1477.338
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.890  0.402  0.420  1.0
  Re  Re1  1  0.390  0.598  0.080  1.0
  Re  Re2  1  0.110  0.598  0.580  1.0
  Re  Re3  1  0.610  0.402  0.920  1.0
  Re  Re4  1  0.509  0.098  0.332  1.0
  Re  Re5  1  0.009  0.902  0.168  1.0
  Re  Re6  1  0.491  0.902  0.668  1.0
  Re  Re7  1  0.991  0.098  0.832  1.0
  Cl  Cl8  1  0.368  0.107  0.222  1.0
  Cl  Cl9  1  0.127  0.923  0.888  1.0
  Cl  Cl10  1  0.627  0.077  0.612  1.0
  Cl  Cl11  1  0.873  0.077  0.112  1.0
  Cl  Cl12  1  0.373  0.923  0.388  1.0
  Cl  Cl13  1  0.132  0.107  0.722  1.0
  Cl  Cl14  1  0.632  0.893  0.778  1.0
  Cl  Cl15  1  0.868  0.893  0.278  1.0
  Cl  Cl16  1  0.751  0.576  0.859  1.0
  Cl  Cl17  1  0.251  0.424  0.641  1.0
  Cl  Cl18  1  0.249  0.424  0.141  1.0
  Cl  Cl19  1  0.749  0.576  0.359  1.0
  Cl  Cl20  1  0.345  0.289  0.995  1.0
  Cl  Cl21  1  0.845  0.711  0.505  1.0
  Cl  Cl22  1  0.655  0.711  0.005  1.0
  Cl  Cl23  1  0.155  0.289  0.495  1.0
  Cl  Cl24  1  0.354  0.461  0.826  1.0
  Cl  Cl25  1  0.854  0.539  0.674  1.0
  Cl  Cl26  1  0.646  0.539  0.174  1.0
  Cl  Cl27  1  0.146  0.461  0.326  1.0
  Cl  Cl28  1  0.730  0.034  0.924  1.0
  Cl  Cl29  1  0.230  0.966  0.576  1.0
  Cl  Cl30  1  0.270  0.966  0.076  1.0
  Cl  Cl31  1  0.770  0.034  0.424  1.0
  Cl  Cl32  1  0.729  0.215  0.757  1.0
  Cl  Cl33  1  0.229  0.785  0.743  1.0
  Cl  Cl34  1  0.271  0.785  0.243  1.0
  Cl  Cl35  1  0.771  0.215  0.257  1.0
  Cl  Cl36  1  0.747  0.401  0.028  1.0
  Cl  Cl37  1  0.247  0.599  0.472  1.0
  Cl  Cl38  1  0.253  0.599  0.972  1.0
  Cl  Cl39  1  0.753  0.401  0.528  1.0
  O  O40  1  0.159  0.175  0.856  1.0
  O  O41  1  0.720  0.321  0.400  1.0
  O  O42  1  0.220  0.679  0.100  1.0
  O  O43  1  0.280  0.679  0.600  1.0
  O  O44  1  0.780  0.321  0.900  1.0
  O  O45  1  0.341  0.175  0.356  1.0
  O  O46  1  0.841  0.825  0.144  1.0
  O  O47  1  0.659  0.825  0.644  1.0
[/CIF]
.