The material structure described by RhN3(NO2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twelve nitrous acid molecules and four RhN3 clusters. In each RhN3 cluster, Rh(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one N(3), and one N(6) atom. There are three inequivalent N sites. In the first N site, N(6) is bonded in a single-bond geometry to one Rh(1) atom. In the second N site, N(3) is bonded in a single-bond geometry to one Rh(1) atom. In the third N site, N(2) is bonded in a single-bond geometry to one Rh(1) atom. is represented by the CIF file [CIF]
data_Rh(NO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.360
_cell_length_b   6.669
_cell_length_c   12.689
_cell_angle_alpha   65.613
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   875.479
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.836  0.774  0.762  1.0
  Rh  Rh1  1  0.164  0.226  0.238  1.0
  Rh  Rh2  1  0.336  0.226  0.738  1.0
  Rh  Rh3  1  0.664  0.774  0.262  1.0
  N  N4  1  0.452  0.575  0.604  1.0
  N  N5  1  0.548  0.425  0.396  1.0
  N  N6  1  0.952  0.425  0.896  1.0
  N  N7  1  0.048  0.575  0.104  1.0
  N  N8  1  0.212  0.396  0.685  1.0
  N  N9  1  0.788  0.604  0.315  1.0
  N  N10  1  0.712  0.604  0.815  1.0
  N  N11  1  0.288  0.396  0.185  1.0
  N  N12  1  0.884  0.865  0.869  1.0
  N  N13  1  0.116  0.135  0.131  1.0
  N  N14  1  0.384  0.135  0.631  1.0
  N  N15  1  0.616  0.865  0.369  1.0
  N  N16  1  0.047  0.873  0.686  1.0
  N  N17  1  0.953  0.127  0.314  1.0
  N  N18  1  0.547  0.127  0.814  1.0
  N  N19  1  0.453  0.873  0.186  1.0
  N  N20  1  0.358  0.444  0.865  1.0
  N  N21  1  0.642  0.556  0.135  1.0
  N  N22  1  0.858  0.556  0.635  1.0
  N  N23  1  0.142  0.444  0.365  1.0
  N  N24  1  0.310  0.004  0.869  1.0
  N  N25  1  0.690  0.996  0.131  1.0
  N  N26  1  0.810  0.996  0.631  1.0
  N  N27  1  0.190  0.004  0.369  1.0
  O  O28  1  0.097  0.971  0.736  1.0
  O  O29  1  0.903  0.029  0.264  1.0
  O  O30  1  0.597  0.029  0.764  1.0
  O  O31  1  0.403  0.971  0.236  1.0
  O  O32  1  0.080  0.818  0.611  1.0
  O  O33  1  0.920  0.182  0.389  1.0
  O  O34  1  0.580  0.182  0.889  1.0
  O  O35  1  0.420  0.818  0.111  1.0
  O  O36  1  0.836  0.664  0.534  1.0
  O  O37  1  0.164  0.336  0.466  1.0
  O  O38  1  0.336  0.336  0.966  1.0
  O  O39  1  0.664  0.664  0.034  1.0
  O  O40  1  0.054  0.415  0.869  1.0
  O  O41  1  0.946  0.585  0.131  1.0
  O  O42  1  0.554  0.585  0.631  1.0
  O  O43  1  0.446  0.415  0.369  1.0
  O  O44  1  0.386  0.635  0.813  1.0
  O  O45  1  0.614  0.365  0.187  1.0
  O  O46  1  0.886  0.365  0.687  1.0
  O  O47  1  0.114  0.635  0.313  1.0
  O  O48  1  0.394  0.698  0.523  1.0
  O  O49  1  0.606  0.302  0.477  1.0
  O  O50  1  0.894  0.302  0.977  1.0
  O  O51  1  0.106  0.698  0.023  1.0
[/CIF]
.
The material structure described by RhN3(NO2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twelve nitrous acid molecules and four RhN3 clusters. In each RhN3 cluster, Rh(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2), one N(3), and one N(6) atom. There are three inequivalent N sites. In the first N site, N(6) is bonded in a single-bond geometry to one Rh(1) atom. In the second N site, N(3) is bonded in a single-bond geometry to one Rh(1) atom. In the third N site, N(2) is bonded in a single-bond geometry to one Rh(1) atom. is represented by the CIF file [CIF]
data_Rh(NO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.360
_cell_length_b   6.669
_cell_length_c   12.689
_cell_angle_alpha   65.613
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   875.479
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.836  0.774  0.762  1.0
  Rh  Rh1  1  0.164  0.226  0.238  1.0
  Rh  Rh2  1  0.336  0.226  0.738  1.0
  Rh  Rh3  1  0.664  0.774  0.262  1.0
  N  N4  1  0.452  0.575  0.604  1.0
  N  N5  1  0.548  0.425  0.396  1.0
  N  N6  1  0.952  0.425  0.896  1.0
  N  N7  1  0.048  0.575  0.104  1.0
  N  N8  1  0.212  0.396  0.685  1.0
  N  N9  1  0.788  0.604  0.315  1.0
  N  N10  1  0.712  0.604  0.815  1.0
  N  N11  1  0.288  0.396  0.185  1.0
  N  N12  1  0.884  0.865  0.869  1.0
  N  N13  1  0.116  0.135  0.131  1.0
  N  N14  1  0.384  0.135  0.631  1.0
  N  N15  1  0.616  0.865  0.369  1.0
  N  N16  1  0.047  0.873  0.686  1.0
  N  N17  1  0.953  0.127  0.314  1.0
  N  N18  1  0.547  0.127  0.814  1.0
  N  N19  1  0.453  0.873  0.186  1.0
  N  N20  1  0.358  0.444  0.865  1.0
  N  N21  1  0.642  0.556  0.135  1.0
  N  N22  1  0.858  0.556  0.635  1.0
  N  N23  1  0.142  0.444  0.365  1.0
  N  N24  1  0.310  0.004  0.869  1.0
  N  N25  1  0.690  0.996  0.131  1.0
  N  N26  1  0.810  0.996  0.631  1.0
  N  N27  1  0.190  0.004  0.369  1.0
  O  O28  1  0.097  0.971  0.736  1.0
  O  O29  1  0.903  0.029  0.264  1.0
  O  O30  1  0.597  0.029  0.764  1.0
  O  O31  1  0.403  0.971  0.236  1.0
  O  O32  1  0.080  0.818  0.611  1.0
  O  O33  1  0.920  0.182  0.389  1.0
  O  O34  1  0.580  0.182  0.889  1.0
  O  O35  1  0.420  0.818  0.111  1.0
  O  O36  1  0.836  0.664  0.534  1.0
  O  O37  1  0.164  0.336  0.466  1.0
  O  O38  1  0.336  0.336  0.966  1.0
  O  O39  1  0.664  0.664  0.034  1.0
  O  O40  1  0.054  0.415  0.869  1.0
  O  O41  1  0.946  0.585  0.131  1.0
  O  O42  1  0.554  0.585  0.631  1.0
  O  O43  1  0.446  0.415  0.369  1.0
  O  O44  1  0.386  0.635  0.813  1.0
  O  O45  1  0.614  0.365  0.187  1.0
  O  O46  1  0.886  0.365  0.687  1.0
  O  O47  1  0.114  0.635  0.313  1.0
  O  O48  1  0.394  0.698  0.523  1.0
  O  O49  1  0.606  0.302  0.477  1.0
  O  O50  1  0.894  0.302  0.977  1.0
  O  O51  1  0.106  0.698  0.023  1.0
[/CIF]
.