The compound described by N3S4Te2Cl9 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two N3S4 clusters and one Te2Cl9 cluster. In each N3S4 cluster, there are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(2) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one S(1) and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one N(3) atom. In the Te2Cl9 cluster, there are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one Cl(1), one Cl(4), one Cl(5), one Cl(6), and one Cl(8) atom to form distorted corner-sharing TeCl5 square pyramids. The corner-sharing octahedral tilt angles are 64°. In the second Te site, Te(2) is bonded to one Cl(1), one Cl(2), one Cl(7), one Cl(9), and two equivalent Cl(3) atoms to form TeCl6 octahedra that share  a cornercorner with one Te(1)Cl5 square pyramid and  an edgeedge with one Te(2)Cl6 octahedra. There are nine inequivalent Cl sites. In the first Cl site, Cl(9) is bonded in a single-bond geometry to one Te(2) atom. In the second Cl site, Cl(1) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(2) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Te(2) atom. In the fourth Cl site, Cl(3) is bonded in a water-like geometry to two equivalent Te(2) atoms. In the fifth Cl site, Cl(4) is bonded in a single-bond geometry to one Te(1) atom. In the sixth Cl site, Cl(5) is bonded in a single-bond geometry to one Te(1) atom. In the seventh Cl site, Cl(6) is bonded in a single-bond geometry to one Te(1) atom. In the eighth Cl site, Cl(7) is bonded in a single-bond geometry to one Te(2) atom. In the ninth Cl site, Cl(8) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF file [CIF]
data_Te2S4(NCl3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.514
_cell_length_b   10.261
_cell_length_c   11.508
_cell_angle_alpha   83.093
_cell_angle_beta   69.938
_cell_angle_gamma   75.640
_symmetry_Int_Tables_number   1
_cell_volume   1021.450
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.371  0.839  0.056  1.0
  Te  Te1  1  0.518  0.703  0.426  1.0
  Te  Te2  1  0.629  0.161  0.944  1.0
  Te  Te3  1  0.482  0.297  0.574  1.0
  S  S4  1  0.050  0.758  0.811  1.0
  S  S5  1  0.056  0.206  0.407  1.0
  S  S6  1  0.856  0.532  0.690  1.0
  S  S7  1  0.064  0.496  0.156  1.0
  S  S8  1  0.936  0.504  0.844  1.0
  S  S9  1  0.144  0.468  0.310  1.0
  S  S10  1  0.950  0.242  0.189  1.0
  S  S11  1  0.944  0.794  0.593  1.0
  N  N12  1  0.118  0.337  0.388  1.0
  N  N13  1  0.986  0.178  0.309  1.0
  N  N14  1  0.994  0.379  0.138  1.0
  N  N15  1  0.882  0.663  0.612  1.0
  N  N16  1  0.014  0.822  0.691  1.0
  N  N17  1  0.006  0.621  0.862  1.0
  Cl  Cl18  1  0.565  0.654  0.176  1.0
  Cl  Cl19  1  0.332  0.905  0.403  1.0
  Cl  Cl20  1  0.715  0.463  0.462  1.0
  Cl  Cl21  1  0.388  0.647  0.953  1.0
  Cl  Cl22  1  0.285  0.537  0.538  1.0
  Cl  Cl23  1  0.872  0.204  0.783  1.0
  Cl  Cl24  1  0.620  0.873  0.880  1.0
  Cl  Cl25  1  0.435  0.346  0.824  1.0
  Cl  Cl26  1  0.266  0.196  0.654  1.0
  Cl  Cl27  1  0.380  0.127  0.120  1.0
  Cl  Cl28  1  0.128  0.796  0.217  1.0
  Cl  Cl29  1  0.734  0.804  0.346  1.0
  Cl  Cl30  1  0.612  0.353  0.047  1.0
  Cl  Cl31  1  0.221  0.983  0.941  1.0
  Cl  Cl32  1  0.527  0.242  0.365  1.0
  Cl  Cl33  1  0.473  0.758  0.635  1.0
  Cl  Cl34  1  0.668  0.095  0.597  1.0
  Cl  Cl35  1  0.779  0.017  0.059  1.0
[/CIF]
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The compound described by N3S4Te2Cl9 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two N3S4 clusters and one Te2Cl9 cluster. In each N3S4 cluster, there are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one S(2) and one S(3) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one S(1) and one S(2) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one S(1) and one S(4) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one N(2) and one N(3) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one N(1) and one N(2) atom. In the third S site, S(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth S site, S(4) is bonded in a distorted single-bond geometry to one N(3) atom. In the Te2Cl9 cluster, there are two inequivalent Te sites. In the first Te site, Te(1) is bonded to one Cl(1), one Cl(4), one Cl(5), one Cl(6), and one Cl(8) atom to form distorted corner-sharing TeCl5 square pyramids. The corner-sharing octahedral tilt angles are 64°. In the second Te site, Te(2) is bonded to one Cl(1), one Cl(2), one Cl(7), one Cl(9), and two equivalent Cl(3) atoms to form TeCl6 octahedra that share  a cornercorner with one Te(1)Cl5 square pyramid and  an edgeedge with one Te(2)Cl6 octahedra. There are nine inequivalent Cl sites. In the first Cl site, Cl(9) is bonded in a single-bond geometry to one Te(2) atom. In the second Cl site, Cl(1) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(2) atom. In the third Cl site, Cl(2) is bonded in a single-bond geometry to one Te(2) atom. In the fourth Cl site, Cl(3) is bonded in a water-like geometry to two equivalent Te(2) atoms. In the fifth Cl site, Cl(4) is bonded in a single-bond geometry to one Te(1) atom. In the sixth Cl site, Cl(5) is bonded in a single-bond geometry to one Te(1) atom. In the seventh Cl site, Cl(6) is bonded in a single-bond geometry to one Te(1) atom. In the eighth Cl site, Cl(7) is bonded in a single-bond geometry to one Te(2) atom. In the ninth Cl site, Cl(8) is bonded in a single-bond geometry to one Te(1) atom. is represented by the CIF file [CIF]
data_Te2S4(NCl3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.514
_cell_length_b   10.261
_cell_length_c   11.508
_cell_angle_alpha   83.093
_cell_angle_beta   69.938
_cell_angle_gamma   75.640
_symmetry_Int_Tables_number   1
_cell_volume   1021.450
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.371  0.839  0.056  1.0
  Te  Te1  1  0.518  0.703  0.426  1.0
  Te  Te2  1  0.629  0.161  0.944  1.0
  Te  Te3  1  0.482  0.297  0.574  1.0
  S  S4  1  0.050  0.758  0.811  1.0
  S  S5  1  0.056  0.206  0.407  1.0
  S  S6  1  0.856  0.532  0.690  1.0
  S  S7  1  0.064  0.496  0.156  1.0
  S  S8  1  0.936  0.504  0.844  1.0
  S  S9  1  0.144  0.468  0.310  1.0
  S  S10  1  0.950  0.242  0.189  1.0
  S  S11  1  0.944  0.794  0.593  1.0
  N  N12  1  0.118  0.337  0.388  1.0
  N  N13  1  0.986  0.178  0.309  1.0
  N  N14  1  0.994  0.379  0.138  1.0
  N  N15  1  0.882  0.663  0.612  1.0
  N  N16  1  0.014  0.822  0.691  1.0
  N  N17  1  0.006  0.621  0.862  1.0
  Cl  Cl18  1  0.565  0.654  0.176  1.0
  Cl  Cl19  1  0.332  0.905  0.403  1.0
  Cl  Cl20  1  0.715  0.463  0.462  1.0
  Cl  Cl21  1  0.388  0.647  0.953  1.0
  Cl  Cl22  1  0.285  0.537  0.538  1.0
  Cl  Cl23  1  0.872  0.204  0.783  1.0
  Cl  Cl24  1  0.620  0.873  0.880  1.0
  Cl  Cl25  1  0.435  0.346  0.824  1.0
  Cl  Cl26  1  0.266  0.196  0.654  1.0
  Cl  Cl27  1  0.380  0.127  0.120  1.0
  Cl  Cl28  1  0.128  0.796  0.217  1.0
  Cl  Cl29  1  0.734  0.804  0.346  1.0
  Cl  Cl30  1  0.612  0.353  0.047  1.0
  Cl  Cl31  1  0.221  0.983  0.941  1.0
  Cl  Cl32  1  0.527  0.242  0.365  1.0
  Cl  Cl33  1  0.473  0.758  0.635  1.0
  Cl  Cl34  1  0.668  0.095  0.597  1.0
  Cl  Cl35  1  0.779  0.017  0.059  1.0
[/CIF]
.