The compound described by Ag5GeO4 crystallizes in the monoclinic P2_1/c space group. There are five inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(4) atom. In the third Ag site, Ag(3) is bonded in an L-shaped geometry to one O(3) and one O(4) atom. In the fourth Ag site, Ag(4) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(4) atom. In the fifth Ag site, Ag(5) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. Ge(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted tetrahedral geometry to one Ag(1), one Ag(3), one Ag(5), and one Ge(1) atom. In the second O site, O(4) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), one Ag(4), and one Ge(1) atom. In the third O site, O(1) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(4), one Ag(5), and one Ge(1) atom. In the fourth O site, O(2) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(4), one Ag(5), and one Ge(1) atom. is represented by the CIF file [CIF]
data_Ag5GeO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.893
_cell_length_b   6.440
_cell_length_c   11.032
_cell_angle_alpha   55.980
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   582.565
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.415  0.072  0.090  1.0
  Ag  Ag1  1  0.915  0.928  0.410  1.0
  Ag  Ag2  1  0.585  0.928  0.910  1.0
  Ag  Ag3  1  0.085  0.072  0.590  1.0
  Ag  Ag4  1  0.356  0.600  0.118  1.0
  Ag  Ag5  1  0.856  0.400  0.382  1.0
  Ag  Ag6  1  0.644  0.400  0.882  1.0
  Ag  Ag7  1  0.144  0.600  0.618  1.0
  Ag  Ag8  1  0.406  0.324  0.698  1.0
  Ag  Ag9  1  0.906  0.676  0.802  1.0
  Ag  Ag10  1  0.594  0.676  0.302  1.0
  Ag  Ag11  1  0.094  0.324  0.198  1.0
  Ag  Ag12  1  0.377  0.799  0.425  1.0
  Ag  Ag13  1  0.877  0.201  0.075  1.0
  Ag  Ag14  1  0.623  0.201  0.575  1.0
  Ag  Ag15  1  0.123  0.799  0.925  1.0
  Ag  Ag16  1  0.375  0.347  0.442  1.0
  Ag  Ag17  1  0.875  0.653  0.058  1.0
  Ag  Ag18  1  0.625  0.653  0.558  1.0
  Ag  Ag19  1  0.125  0.347  0.942  1.0
  Ge  Ge20  1  0.387  0.753  0.759  1.0
  Ge  Ge21  1  0.887  0.247  0.741  1.0
  Ge  Ge22  1  0.613  0.247  0.241  1.0
  Ge  Ge23  1  0.113  0.753  0.259  1.0
  O  O24  1  0.437  0.219  0.278  1.0
  O  O25  1  0.937  0.781  0.222  1.0
  O  O26  1  0.563  0.781  0.722  1.0
  O  O27  1  0.063  0.219  0.778  1.0
  O  O28  1  0.291  0.919  0.595  1.0
  O  O29  1  0.791  0.081  0.905  1.0
  O  O30  1  0.709  0.081  0.405  1.0
  O  O31  1  0.209  0.919  0.095  1.0
  O  O32  1  0.345  0.432  0.858  1.0
  O  O33  1  0.140  0.886  0.361  1.0
  O  O34  1  0.845  0.568  0.642  1.0
  O  O35  1  0.155  0.432  0.358  1.0
  O  O36  1  0.360  0.886  0.861  1.0
  O  O37  1  0.860  0.114  0.639  1.0
  O  O38  1  0.640  0.114  0.139  1.0
  O  O39  1  0.655  0.568  0.142  1.0
[/CIF]
.
The compound described by Ag5GeO4 crystallizes in the monoclinic P2_1/c space group. There are five inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(4) atom. In the third Ag site, Ag(3) is bonded in an L-shaped geometry to one O(3) and one O(4) atom. In the fourth Ag site, Ag(4) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(4) atom. In the fifth Ag site, Ag(5) is bonded in a 3-coordinate geometry to one O(1), one O(2), and one O(3) atom. Ge(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted tetrahedral geometry to one Ag(1), one Ag(3), one Ag(5), and one Ge(1) atom. In the second O site, O(4) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), one Ag(4), and one Ge(1) atom. In the third O site, O(1) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(4), one Ag(5), and one Ge(1) atom. In the fourth O site, O(2) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(4), one Ag(5), and one Ge(1) atom. is represented by the CIF file [CIF]
data_Ag5GeO4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.893
_cell_length_b   6.440
_cell_length_c   11.032
_cell_angle_alpha   55.980
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   582.565
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.415  0.072  0.090  1.0
  Ag  Ag1  1  0.915  0.928  0.410  1.0
  Ag  Ag2  1  0.585  0.928  0.910  1.0
  Ag  Ag3  1  0.085  0.072  0.590  1.0
  Ag  Ag4  1  0.356  0.600  0.118  1.0
  Ag  Ag5  1  0.856  0.400  0.382  1.0
  Ag  Ag6  1  0.644  0.400  0.882  1.0
  Ag  Ag7  1  0.144  0.600  0.618  1.0
  Ag  Ag8  1  0.406  0.324  0.698  1.0
  Ag  Ag9  1  0.906  0.676  0.802  1.0
  Ag  Ag10  1  0.594  0.676  0.302  1.0
  Ag  Ag11  1  0.094  0.324  0.198  1.0
  Ag  Ag12  1  0.377  0.799  0.425  1.0
  Ag  Ag13  1  0.877  0.201  0.075  1.0
  Ag  Ag14  1  0.623  0.201  0.575  1.0
  Ag  Ag15  1  0.123  0.799  0.925  1.0
  Ag  Ag16  1  0.375  0.347  0.442  1.0
  Ag  Ag17  1  0.875  0.653  0.058  1.0
  Ag  Ag18  1  0.625  0.653  0.558  1.0
  Ag  Ag19  1  0.125  0.347  0.942  1.0
  Ge  Ge20  1  0.387  0.753  0.759  1.0
  Ge  Ge21  1  0.887  0.247  0.741  1.0
  Ge  Ge22  1  0.613  0.247  0.241  1.0
  Ge  Ge23  1  0.113  0.753  0.259  1.0
  O  O24  1  0.437  0.219  0.278  1.0
  O  O25  1  0.937  0.781  0.222  1.0
  O  O26  1  0.563  0.781  0.722  1.0
  O  O27  1  0.063  0.219  0.778  1.0
  O  O28  1  0.291  0.919  0.595  1.0
  O  O29  1  0.791  0.081  0.905  1.0
  O  O30  1  0.709  0.081  0.405  1.0
  O  O31  1  0.209  0.919  0.095  1.0
  O  O32  1  0.345  0.432  0.858  1.0
  O  O33  1  0.140  0.886  0.361  1.0
  O  O34  1  0.845  0.568  0.642  1.0
  O  O35  1  0.155  0.432  0.358  1.0
  O  O36  1  0.360  0.886  0.861  1.0
  O  O37  1  0.860  0.114  0.639  1.0
  O  O38  1  0.640  0.114  0.139  1.0
  O  O39  1  0.655  0.568  0.142  1.0
[/CIF]
.