The crystal structure described by (NH4)3TiF7 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, one hydrofluoric acid molecule, one N2H4F cluster, and one TiNH3F5 cluster. In the N2H4F cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one N(2), one H(4), and one F(7) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one N(1), one H(5), one H(6), and one H(7) atom. There are four inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one N(2) atom. F(7) is bonded in a single-bond geometry to one N(1) atom. In the TiNH3F5 cluster, Ti(1) is bonded in a tetrahedral geometry to one N(3), one F(1), one F(5), and one F(6) atom. N(3) is bonded in a bent 150 degrees geometry to one Ti(1) and one H(8) atom. There are three inequivalent H sites. In the first H site, H(2) is bonded in a distorted linear geometry to one F(3) and one F(5) atom. In the second H site, H(8) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(9) is bonded in a linear geometry to one F(2) and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ti(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one H(9) atom. In the third F site, F(3) is bonded in a single-bond geometry to one H(2) atom. In the fourth F site, F(5) is bonded in a 3-coordinate geometry to one Ti(1), one H(2), and one H(9) atom. In the fifth F site, F(6) is bonded in a single-bond geometry to one Ti(1) atom. is represented by the CIF file [CIF]
data_TiH12N3F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.464
_cell_length_b   8.201
_cell_length_c   7.580
_cell_angle_alpha   53.998
_cell_angle_beta   57.493
_cell_angle_gamma   65.886
_symmetry_Int_Tables_number   1
_cell_volume   313.618
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.961  0.511  0.644  1.0
  H  H1  1  0.004  0.055  0.684  1.0
  H  H2  1  0.167  0.598  0.082  1.0
  H  H3  1  0.959  0.043  0.070  1.0
  H  H4  1  0.529  0.266  0.035  1.0
  H  H5  1  0.118  0.136  0.306  1.0
  H  H6  1  0.329  0.037  0.130  1.0
  H  H7  1  0.231  0.291  0.014  1.0
  H  H8  1  0.760  0.805  0.770  1.0
  H  H9  1  0.297  0.735  0.185  1.0
  H  H10  1  0.912  0.953  0.188  1.0
  H  H11  1  0.796  0.135  0.302  1.0
  H  H12  1  0.114  0.997  0.674  1.0
  N  N13  1  0.400  0.211  0.201  1.0
  N  N14  1  0.263  0.163  0.160  1.0
  N  N15  1  0.846  0.716  0.688  1.0
  F  F16  1  0.145  0.341  0.799  1.0
  F  F17  1  0.404  0.820  0.112  1.0
  F  F18  1  0.198  0.589  0.946  1.0
  F  F19  1  0.805  0.228  0.333  1.0
  F  F20  1  0.130  0.608  0.302  1.0
  F  F21  1  0.751  0.357  0.777  1.0
  F  F22  1  0.500  0.013  0.331  1.0
[/CIF]
.
The crystal structure described by (NH4)3TiF7 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, one hydrofluoric acid molecule, one N2H4F cluster, and one TiNH3F5 cluster. In the N2H4F cluster, there are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one N(2), one H(4), and one F(7) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one N(1), one H(5), one H(6), and one H(7) atom. There are four inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one N(2) atom. F(7) is bonded in a single-bond geometry to one N(1) atom. In the TiNH3F5 cluster, Ti(1) is bonded in a tetrahedral geometry to one N(3), one F(1), one F(5), and one F(6) atom. N(3) is bonded in a bent 150 degrees geometry to one Ti(1) and one H(8) atom. There are three inequivalent H sites. In the first H site, H(2) is bonded in a distorted linear geometry to one F(3) and one F(5) atom. In the second H site, H(8) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(9) is bonded in a linear geometry to one F(2) and one F(5) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Ti(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one H(9) atom. In the third F site, F(3) is bonded in a single-bond geometry to one H(2) atom. In the fourth F site, F(5) is bonded in a 3-coordinate geometry to one Ti(1), one H(2), and one H(9) atom. In the fifth F site, F(6) is bonded in a single-bond geometry to one Ti(1) atom. is represented by the CIF file [CIF]
data_TiH12N3F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.464
_cell_length_b   8.201
_cell_length_c   7.580
_cell_angle_alpha   53.998
_cell_angle_beta   57.493
_cell_angle_gamma   65.886
_symmetry_Int_Tables_number   1
_cell_volume   313.618
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.961  0.511  0.644  1.0
  H  H1  1  0.004  0.055  0.684  1.0
  H  H2  1  0.167  0.598  0.082  1.0
  H  H3  1  0.959  0.043  0.070  1.0
  H  H4  1  0.529  0.266  0.035  1.0
  H  H5  1  0.118  0.136  0.306  1.0
  H  H6  1  0.329  0.037  0.130  1.0
  H  H7  1  0.231  0.291  0.014  1.0
  H  H8  1  0.760  0.805  0.770  1.0
  H  H9  1  0.297  0.735  0.185  1.0
  H  H10  1  0.912  0.953  0.188  1.0
  H  H11  1  0.796  0.135  0.302  1.0
  H  H12  1  0.114  0.997  0.674  1.0
  N  N13  1  0.400  0.211  0.201  1.0
  N  N14  1  0.263  0.163  0.160  1.0
  N  N15  1  0.846  0.716  0.688  1.0
  F  F16  1  0.145  0.341  0.799  1.0
  F  F17  1  0.404  0.820  0.112  1.0
  F  F18  1  0.198  0.589  0.946  1.0
  F  F19  1  0.805  0.228  0.333  1.0
  F  F20  1  0.130  0.608  0.302  1.0
  F  F21  1  0.751  0.357  0.777  1.0
  F  F22  1  0.500  0.013  0.331  1.0
[/CIF]
.