The compound described by Re2O3Cl7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Re2O3Cl7 clusters. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one Cl(2), one Cl(3), one Cl(4), and one Cl(7) atom. In the second Re site, Re(2) is bonded in a 6-coordinate geometry to one O(1), one O(3), one Cl(5), one Cl(6), and two equivalent Cl(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Re(1) and one Re(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(2) atom. There are seven inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to two equivalent Re(2) atoms. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Re(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Re(2) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Re(2) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF card [CIF]
data_Re2Cl7O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.100
_cell_length_b   6.304
_cell_length_c   17.158
_cell_angle_alpha   73.436
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1150.867
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.085  0.479  0.691  1.0
  Re  Re1  1  0.661  0.667  0.468  1.0
  Re  Re2  1  0.339  0.333  0.532  1.0
  Re  Re3  1  0.915  0.521  0.309  1.0
  Re  Re4  1  0.839  0.667  0.968  1.0
  Re  Re5  1  0.585  0.521  0.809  1.0
  Re  Re6  1  0.415  0.479  0.191  1.0
  Re  Re7  1  0.161  0.333  0.032  1.0
  Cl  Cl8  1  0.025  0.670  0.054  1.0
  Cl  Cl9  1  0.503  0.184  0.158  1.0
  Cl  Cl10  1  0.725  0.257  0.806  1.0
  Cl  Cl11  1  0.024  0.703  0.566  1.0
  Cl  Cl12  1  0.476  0.703  0.066  1.0
  Cl  Cl13  1  0.525  0.330  0.446  1.0
  Cl  Cl14  1  0.475  0.670  0.554  1.0
  Cl  Cl15  1  0.460  0.132  0.634  1.0
  Cl  Cl16  1  0.003  0.816  0.342  1.0
  Cl  Cl17  1  0.225  0.743  0.694  1.0
  Cl  Cl18  1  0.223  0.605  0.921  1.0
  Cl  Cl19  1  0.705  0.774  0.719  1.0
  Cl  Cl20  1  0.277  0.605  0.421  1.0
  Cl  Cl21  1  0.976  0.297  0.434  1.0
  Cl  Cl22  1  0.777  0.395  0.079  1.0
  Cl  Cl23  1  0.524  0.297  0.934  1.0
  Cl  Cl24  1  0.205  0.226  0.781  1.0
  Cl  Cl25  1  0.795  0.774  0.219  1.0
  Cl  Cl26  1  0.775  0.257  0.306  1.0
  Cl  Cl27  1  0.497  0.816  0.842  1.0
  Cl  Cl28  1  0.540  0.868  0.366  1.0
  Cl  Cl29  1  0.975  0.330  0.946  1.0
  Cl  Cl30  1  0.040  0.132  0.134  1.0
  Cl  Cl31  1  0.997  0.184  0.658  1.0
  Cl  Cl32  1  0.723  0.395  0.579  1.0
  Cl  Cl33  1  0.295  0.226  0.281  1.0
  Cl  Cl34  1  0.275  0.743  0.194  1.0
  Cl  Cl35  1  0.960  0.868  0.866  1.0
  O  O36  1  0.264  0.399  0.098  1.0
  O  O37  1  0.022  0.467  0.248  1.0
  O  O38  1  0.522  0.533  0.252  1.0
  O  O39  1  0.723  0.884  0.495  1.0
  O  O40  1  0.277  0.116  0.505  1.0
  O  O41  1  0.236  0.399  0.598  1.0
  O  O42  1  0.223  0.116  0.005  1.0
  O  O43  1  0.736  0.601  0.902  1.0
  O  O44  1  0.777  0.884  0.995  1.0
  O  O45  1  0.978  0.533  0.752  1.0
  O  O46  1  0.764  0.601  0.402  1.0
  O  O47  1  0.478  0.467  0.748  1.0
[/CIF]
.
The compound described by Re2O3Cl7 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Re2O3Cl7 clusters. There are two inequivalent Re sites. In the first Re site, Re(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one Cl(2), one Cl(3), one Cl(4), and one Cl(7) atom. In the second Re site, Re(2) is bonded in a 6-coordinate geometry to one O(1), one O(3), one Cl(5), one Cl(6), and two equivalent Cl(1) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Re(1) and one Re(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Re(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Re(2) atom. There are seven inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to two equivalent Re(2) atoms. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Re(1) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Re(1) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Re(1) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one Re(2) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one Re(2) atom. In the seventh Cl site, Cl(7) is bonded in a single-bond geometry to one Re(1) atom. is represented by the CIF card [CIF]
data_Re2Cl7O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.100
_cell_length_b   6.304
_cell_length_c   17.158
_cell_angle_alpha   73.436
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1150.867
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  1  0.085  0.479  0.691  1.0
  Re  Re1  1  0.661  0.667  0.468  1.0
  Re  Re2  1  0.339  0.333  0.532  1.0
  Re  Re3  1  0.915  0.521  0.309  1.0
  Re  Re4  1  0.839  0.667  0.968  1.0
  Re  Re5  1  0.585  0.521  0.809  1.0
  Re  Re6  1  0.415  0.479  0.191  1.0
  Re  Re7  1  0.161  0.333  0.032  1.0
  Cl  Cl8  1  0.025  0.670  0.054  1.0
  Cl  Cl9  1  0.503  0.184  0.158  1.0
  Cl  Cl10  1  0.725  0.257  0.806  1.0
  Cl  Cl11  1  0.024  0.703  0.566  1.0
  Cl  Cl12  1  0.476  0.703  0.066  1.0
  Cl  Cl13  1  0.525  0.330  0.446  1.0
  Cl  Cl14  1  0.475  0.670  0.554  1.0
  Cl  Cl15  1  0.460  0.132  0.634  1.0
  Cl  Cl16  1  0.003  0.816  0.342  1.0
  Cl  Cl17  1  0.225  0.743  0.694  1.0
  Cl  Cl18  1  0.223  0.605  0.921  1.0
  Cl  Cl19  1  0.705  0.774  0.719  1.0
  Cl  Cl20  1  0.277  0.605  0.421  1.0
  Cl  Cl21  1  0.976  0.297  0.434  1.0
  Cl  Cl22  1  0.777  0.395  0.079  1.0
  Cl  Cl23  1  0.524  0.297  0.934  1.0
  Cl  Cl24  1  0.205  0.226  0.781  1.0
  Cl  Cl25  1  0.795  0.774  0.219  1.0
  Cl  Cl26  1  0.775  0.257  0.306  1.0
  Cl  Cl27  1  0.497  0.816  0.842  1.0
  Cl  Cl28  1  0.540  0.868  0.366  1.0
  Cl  Cl29  1  0.975  0.330  0.946  1.0
  Cl  Cl30  1  0.040  0.132  0.134  1.0
  Cl  Cl31  1  0.997  0.184  0.658  1.0
  Cl  Cl32  1  0.723  0.395  0.579  1.0
  Cl  Cl33  1  0.295  0.226  0.281  1.0
  Cl  Cl34  1  0.275  0.743  0.194  1.0
  Cl  Cl35  1  0.960  0.868  0.866  1.0
  O  O36  1  0.264  0.399  0.098  1.0
  O  O37  1  0.022  0.467  0.248  1.0
  O  O38  1  0.522  0.533  0.252  1.0
  O  O39  1  0.723  0.884  0.495  1.0
  O  O40  1  0.277  0.116  0.505  1.0
  O  O41  1  0.236  0.399  0.598  1.0
  O  O42  1  0.223  0.116  0.005  1.0
  O  O43  1  0.736  0.601  0.902  1.0
  O  O44  1  0.777  0.884  0.995  1.0
  O  O45  1  0.978  0.533  0.752  1.0
  O  O46  1  0.764  0.601  0.402  1.0
  O  O47  1  0.478  0.467  0.748  1.0
[/CIF]
.