The material described by Pd6P is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four Pd6P clusters. There are six inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted single-bond geometry to one P(1) atom. In the second Pd site, Pd(2) is bonded in a distorted single-bond geometry to one P(1) atom. In the third Pd site, Pd(3) is bonded in a 1-coordinate geometry to one P(1) atom. In the fourth Pd site, Pd(4) is bonded in a distorted single-bond geometry to one P(1) atom. In the fifth Pd site, Pd(5) is bonded in a distorted single-bond geometry to one P(1) atom. In the sixth Pd site, Pd(6) is bonded in a distorted single-bond geometry to one P(1) atom. P(1) is bonded in a 6-coordinate geometry to one Pd(1), one Pd(2), one Pd(3), one Pd(4), one Pd(5), and one Pd(6) atom. is represented by the CIF card [CIF]
data_PPd6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.709
_cell_length_b   8.284
_cell_length_c   9.511
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   110.299
_symmetry_Int_Tables_number   1
_cell_volume   421.866
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.123  0.749  0.762  1.0
  P  P1  1  0.877  0.751  0.262  1.0
  P  P2  1  0.877  0.251  0.238  1.0
  P  P3  1  0.123  0.249  0.738  1.0
  Pd  Pd4  1  0.470  0.931  0.867  1.0
  Pd  Pd5  1  0.530  0.569  0.367  1.0
  Pd  Pd6  1  0.530  0.069  0.133  1.0
  Pd  Pd7  1  0.470  0.431  0.633  1.0
  Pd  Pd8  1  0.227  0.431  0.135  1.0
  Pd  Pd9  1  0.773  0.069  0.635  1.0
  Pd  Pd10  1  0.773  0.569  0.865  1.0
  Pd  Pd11  1  0.227  0.931  0.365  1.0
  Pd  Pd12  1  0.288  0.565  0.866  1.0
  Pd  Pd13  1  0.712  0.935  0.366  1.0
  Pd  Pd14  1  0.712  0.435  0.134  1.0
  Pd  Pd15  1  0.288  0.065  0.634  1.0
  Pd  Pd16  1  0.134  0.249  0.419  1.0
  Pd  Pd17  1  0.866  0.251  0.919  1.0
  Pd  Pd18  1  0.866  0.751  0.581  1.0
  Pd  Pd19  1  0.134  0.749  0.081  1.0
  Pd  Pd20  1  0.380  0.748  0.581  1.0
  Pd  Pd21  1  0.620  0.752  0.081  1.0
  Pd  Pd22  1  0.620  0.252  0.419  1.0
  Pd  Pd23  1  0.380  0.248  0.919  1.0
  Pd  Pd24  1  0.042  0.566  0.365  1.0
  Pd  Pd25  1  0.958  0.934  0.865  1.0
  Pd  Pd26  1  0.958  0.434  0.635  1.0
  Pd  Pd27  1  0.042  0.066  0.135  1.0
[/CIF]
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The material described by Pd6P is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four Pd6P clusters. There are six inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted single-bond geometry to one P(1) atom. In the second Pd site, Pd(2) is bonded in a distorted single-bond geometry to one P(1) atom. In the third Pd site, Pd(3) is bonded in a 1-coordinate geometry to one P(1) atom. In the fourth Pd site, Pd(4) is bonded in a distorted single-bond geometry to one P(1) atom. In the fifth Pd site, Pd(5) is bonded in a distorted single-bond geometry to one P(1) atom. In the sixth Pd site, Pd(6) is bonded in a distorted single-bond geometry to one P(1) atom. P(1) is bonded in a 6-coordinate geometry to one Pd(1), one Pd(2), one Pd(3), one Pd(4), one Pd(5), and one Pd(6) atom. is represented by the CIF card [CIF]
data_PPd6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.709
_cell_length_b   8.284
_cell_length_c   9.511
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   110.299
_symmetry_Int_Tables_number   1
_cell_volume   421.866
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.123  0.749  0.762  1.0
  P  P1  1  0.877  0.751  0.262  1.0
  P  P2  1  0.877  0.251  0.238  1.0
  P  P3  1  0.123  0.249  0.738  1.0
  Pd  Pd4  1  0.470  0.931  0.867  1.0
  Pd  Pd5  1  0.530  0.569  0.367  1.0
  Pd  Pd6  1  0.530  0.069  0.133  1.0
  Pd  Pd7  1  0.470  0.431  0.633  1.0
  Pd  Pd8  1  0.227  0.431  0.135  1.0
  Pd  Pd9  1  0.773  0.069  0.635  1.0
  Pd  Pd10  1  0.773  0.569  0.865  1.0
  Pd  Pd11  1  0.227  0.931  0.365  1.0
  Pd  Pd12  1  0.288  0.565  0.866  1.0
  Pd  Pd13  1  0.712  0.935  0.366  1.0
  Pd  Pd14  1  0.712  0.435  0.134  1.0
  Pd  Pd15  1  0.288  0.065  0.634  1.0
  Pd  Pd16  1  0.134  0.249  0.419  1.0
  Pd  Pd17  1  0.866  0.251  0.919  1.0
  Pd  Pd18  1  0.866  0.751  0.581  1.0
  Pd  Pd19  1  0.134  0.749  0.081  1.0
  Pd  Pd20  1  0.380  0.748  0.581  1.0
  Pd  Pd21  1  0.620  0.752  0.081  1.0
  Pd  Pd22  1  0.620  0.252  0.419  1.0
  Pd  Pd23  1  0.380  0.248  0.919  1.0
  Pd  Pd24  1  0.042  0.566  0.365  1.0
  Pd  Pd25  1  0.958  0.934  0.865  1.0
  Pd  Pd26  1  0.958  0.434  0.635  1.0
  Pd  Pd27  1  0.042  0.066  0.135  1.0
[/CIF]
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