The structure described by RbLi(C2N3)2 crystallizes in the tetragonal I4/mcm space group. Rb(1) is bonded in a 8-coordinate geometry to eight equivalent N(2) atoms. Li(1) is bonded in a tetrahedral geometry to four equivalent N(2) atoms. C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to two equivalent C(1) atoms. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Rb(1), one Li(1), and one C(1) atom. is represented by the CIF file [CIF]
data_RbLi(C2N3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.544
_cell_length_b   7.544
_cell_length_c   8.871
_cell_angle_alpha   115.166
_cell_angle_beta   115.166
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   403.398
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.250  0.500  1.0
  Rb  Rb1  1  0.750  0.750  0.500  1.0
  Li  Li2  1  0.250  0.750  0.500  1.0
  Li  Li3  1  0.750  0.250  0.500  1.0
  C  C4  1  0.728  0.610  0.838  1.0
  C  C5  1  0.110  0.228  0.838  1.0
  C  C6  1  0.610  0.110  0.838  1.0
  C  C7  1  0.228  0.728  0.838  1.0
  C  C8  1  0.272  0.390  0.162  1.0
  C  C9  1  0.890  0.772  0.162  1.0
  C  C10  1  0.390  0.890  0.162  1.0
  C  C11  1  0.772  0.272  0.162  1.0
  N  N12  1  0.753  0.747  0.000  1.0
  N  N13  1  0.247  0.253  0.000  1.0
  N  N14  1  0.747  0.247  0.000  1.0
  N  N15  1  0.253  0.753  0.000  1.0
  N  N16  1  0.693  0.491  0.684  1.0
  N  N17  1  0.991  0.193  0.684  1.0
  N  N18  1  0.491  0.991  0.684  1.0
  N  N19  1  0.193  0.693  0.684  1.0
  N  N20  1  0.307  0.509  0.316  1.0
  N  N21  1  0.009  0.807  0.316  1.0
  N  N22  1  0.509  0.009  0.316  1.0
  N  N23  1  0.807  0.307  0.316  1.0
[/CIF]
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The structure described by RbLi(C2N3)2 crystallizes in the tetragonal I4/mcm space group. Rb(1) is bonded in a 8-coordinate geometry to eight equivalent N(2) atoms. Li(1) is bonded in a tetrahedral geometry to four equivalent N(2) atoms. C(1) is bonded in a linear geometry to one N(1) and one N(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to two equivalent C(1) atoms. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to two equivalent Rb(1), one Li(1), and one C(1) atom. is represented by the CIF file [CIF]
data_RbLi(C2N3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.544
_cell_length_b   7.544
_cell_length_c   8.871
_cell_angle_alpha   115.166
_cell_angle_beta   115.166
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   403.398
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.250  0.250  0.500  1.0
  Rb  Rb1  1  0.750  0.750  0.500  1.0
  Li  Li2  1  0.250  0.750  0.500  1.0
  Li  Li3  1  0.750  0.250  0.500  1.0
  C  C4  1  0.728  0.610  0.838  1.0
  C  C5  1  0.110  0.228  0.838  1.0
  C  C6  1  0.610  0.110  0.838  1.0
  C  C7  1  0.228  0.728  0.838  1.0
  C  C8  1  0.272  0.390  0.162  1.0
  C  C9  1  0.890  0.772  0.162  1.0
  C  C10  1  0.390  0.890  0.162  1.0
  C  C11  1  0.772  0.272  0.162  1.0
  N  N12  1  0.753  0.747  0.000  1.0
  N  N13  1  0.247  0.253  0.000  1.0
  N  N14  1  0.747  0.247  0.000  1.0
  N  N15  1  0.253  0.753  0.000  1.0
  N  N16  1  0.693  0.491  0.684  1.0
  N  N17  1  0.991  0.193  0.684  1.0
  N  N18  1  0.491  0.991  0.684  1.0
  N  N19  1  0.193  0.693  0.684  1.0
  N  N20  1  0.307  0.509  0.316  1.0
  N  N21  1  0.009  0.807  0.316  1.0
  N  N22  1  0.509  0.009  0.316  1.0
  N  N23  1  0.807  0.307  0.316  1.0
[/CIF]
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