The crystal structure described by RbMg(O2Cl)3 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent O(3), two equivalent Cl(2), and four equivalent Cl(1) atoms. Mg(1) is bonded in a 2-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one O(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mg(1) and one O(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), one Mg(1), and one Cl(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one O(3) atom. In the second Cl site, Cl(2) is bonded in a linear geometry to two equivalent Rb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbMg(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.568
_cell_length_b   6.568
_cell_length_c   11.832
_cell_angle_alpha   78.138
_cell_angle_beta   78.138
_cell_angle_gamma   93.010
_symmetry_Int_Tables_number   1
_cell_volume   486.496
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.975  0.025  0.250  1.0
  Rb  Rb1  1  0.025  0.975  0.750  1.0
  Mg  Mg2  1  0.500  0.500  0.000  1.0
  Mg  Mg3  1  0.500  0.500  0.500  1.0
  Cl  Cl4  1  0.081  0.531  0.202  1.0
  Cl  Cl5  1  0.469  0.919  0.298  1.0
  Cl  Cl6  1  0.919  0.469  0.798  1.0
  Cl  Cl7  1  0.531  0.081  0.702  1.0
  Cl  Cl8  1  0.000  0.000  0.500  1.0
  Cl  Cl9  1  0.000  0.000  0.000  1.0
  O  O10  1  0.576  0.515  0.198  1.0
  O  O11  1  0.485  0.424  0.302  1.0
  O  O12  1  0.424  0.485  0.802  1.0
  O  O13  1  0.515  0.576  0.698  1.0
  O  O14  1  0.928  0.554  0.488  1.0
  O  O15  1  0.446  0.072  0.012  1.0
  O  O16  1  0.072  0.446  0.512  1.0
  O  O17  1  0.554  0.928  0.988  1.0
  O  O18  1  0.217  0.491  0.077  1.0
  O  O19  1  0.509  0.783  0.423  1.0
  O  O20  1  0.783  0.509  0.923  1.0
  O  O21  1  0.491  0.217  0.577  1.0
[/CIF]
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The crystal structure described by RbMg(O2Cl)3 crystallizes in the monoclinic C2/c space group. Rb(1) is bonded in a 8-coordinate geometry to two equivalent O(3), two equivalent Cl(2), and four equivalent Cl(1) atoms. Mg(1) is bonded in a 2-coordinate geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mg(1) and one O(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mg(1) and one O(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Rb(1), one Mg(1), and one Cl(1) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to two equivalent Rb(1) and one O(3) atom. In the second Cl site, Cl(2) is bonded in a linear geometry to two equivalent Rb(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_RbMg(ClO2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.568
_cell_length_b   6.568
_cell_length_c   11.832
_cell_angle_alpha   78.138
_cell_angle_beta   78.138
_cell_angle_gamma   93.010
_symmetry_Int_Tables_number   1
_cell_volume   486.496
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.975  0.025  0.250  1.0
  Rb  Rb1  1  0.025  0.975  0.750  1.0
  Mg  Mg2  1  0.500  0.500  0.000  1.0
  Mg  Mg3  1  0.500  0.500  0.500  1.0
  Cl  Cl4  1  0.081  0.531  0.202  1.0
  Cl  Cl5  1  0.469  0.919  0.298  1.0
  Cl  Cl6  1  0.919  0.469  0.798  1.0
  Cl  Cl7  1  0.531  0.081  0.702  1.0
  Cl  Cl8  1  0.000  0.000  0.500  1.0
  Cl  Cl9  1  0.000  0.000  0.000  1.0
  O  O10  1  0.576  0.515  0.198  1.0
  O  O11  1  0.485  0.424  0.302  1.0
  O  O12  1  0.424  0.485  0.802  1.0
  O  O13  1  0.515  0.576  0.698  1.0
  O  O14  1  0.928  0.554  0.488  1.0
  O  O15  1  0.446  0.072  0.012  1.0
  O  O16  1  0.072  0.446  0.512  1.0
  O  O17  1  0.554  0.928  0.988  1.0
  O  O18  1  0.217  0.491  0.077  1.0
  O  O19  1  0.509  0.783  0.423  1.0
  O  O20  1  0.783  0.509  0.923  1.0
  O  O21  1  0.491  0.217  0.577  1.0
[/CIF]
.