The material structure described by RhC2O2Cl is Theoretical Carbon Structure structured and crystallizes in the tetragonal I-42d space group. The structure is zero-dimensional and consists of eight RhC2O2Cl clusters. Rh(1) is bonded in a rectangular see-saw-like geometry to one C(1), one C(2), and two equivalent Cl(1) atoms. There are two inequivalent C sites. In the first C site, C(2) is bonded in a linear geometry to one Rh(1) and one O(1,2) atom. In the second C site, C(1) is bonded in a distorted linear geometry to one Rh(1) and one O(1,2) atom. O(1,2) is bonded in a single-bond geometry to one C(1) atom. Cl(1) is bonded in an L-shaped geometry to two equivalent Rh(1) atoms. is represented by the CIF card [CIF]
data_RhC2ClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.213
_cell_length_b   11.213
_cell_length_c   11.213
_cell_angle_alpha   100.201
_cell_angle_beta   100.201
_cell_angle_gamma   130.226
_symmetry_Int_Tables_number   1
_cell_volume   976.508
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.768  0.688  0.376  1.0
  Rh  Rh1  1  0.938  0.518  0.876  1.0
  Rh  Rh2  1  0.642  0.061  0.124  1.0
  Rh  Rh3  1  0.311  0.392  0.624  1.0
  Rh  Rh4  1  0.312  0.689  0.080  1.0
  Rh  Rh5  1  0.939  0.062  0.580  1.0
  Rh  Rh6  1  0.482  0.358  0.420  1.0
  Rh  Rh7  1  0.608  0.232  0.920  1.0
  C  C8  1  0.874  0.980  0.709  1.0
  C  C9  1  0.753  0.740  0.230  1.0
  C  C10  1  0.510  0.523  0.770  1.0
  C  C11  1  0.020  0.729  0.894  1.0
  C  C12  1  0.835  0.126  0.106  1.0
  C  C13  1  0.497  0.227  0.487  1.0
  C  C14  1  0.415  0.021  0.791  1.0
  C  C15  1  0.376  0.585  0.606  1.0
  C  C16  1  0.477  0.247  0.987  1.0
  C  C17  1  0.979  0.770  0.394  1.0
  C  C18  1  0.230  0.624  0.209  1.0
  C  C19  1  0.260  0.490  0.013  1.0
  C  C20  1  0.271  0.165  0.291  1.0
  C  C21  1  0.740  0.010  0.513  1.0
  C  C22  1  0.990  0.503  0.730  1.0
  C  C23  1  0.773  0.260  0.270  1.0
  Cl  Cl24  1  0.795  0.231  0.842  1.0
  Cl  Cl25  1  0.769  0.612  0.564  1.0
  Cl  Cl26  1  0.481  0.545  0.342  1.0
  Cl  Cl27  1  0.388  0.953  0.158  1.0
  Cl  Cl28  1  0.047  0.205  0.436  1.0
  Cl  Cl29  1  0.862  0.519  0.064  1.0
  Cl  Cl30  1  0.203  0.138  0.658  1.0
  Cl  Cl31  1  0.455  0.797  0.936  1.0
  O  O32  1  0.834  0.933  0.791  1.0
  O  O33  1  0.634  0.601  0.860  1.0
  O  O34  1  0.509  0.149  0.533  1.0
  O  O35  1  0.024  0.491  0.640  1.0
  O  O36  1  0.957  0.166  0.099  1.0
  O  O37  1  0.416  0.707  0.599  1.0
  O  O38  1  0.067  0.858  0.901  1.0
  O  O39  1  0.293  0.892  0.709  1.0
  O  O40  1  0.399  0.259  0.033  1.0
  O  O41  1  0.741  0.774  0.140  1.0
  O  O42  1  0.616  0.976  0.467  1.0
  O  O43  1  0.226  0.366  0.967  1.0
  O  O44  1  0.851  0.384  0.360  1.0
  O  O45  1  0.108  0.817  0.401  1.0
  O  O46  1  0.142  0.043  0.209  1.0
  O  O47  1  0.183  0.584  0.291  1.0
[/CIF]
.
The material structure described by RhC2O2Cl is Theoretical Carbon Structure structured and crystallizes in the tetragonal I-42d space group. The structure is zero-dimensional and consists of eight RhC2O2Cl clusters. Rh(1) is bonded in a rectangular see-saw-like geometry to one C(1), one C(2), and two equivalent Cl(1) atoms. There are two inequivalent C sites. In the first C site, C(2) is bonded in a linear geometry to one Rh(1) and one O(1,2) atom. In the second C site, C(1) is bonded in a distorted linear geometry to one Rh(1) and one O(1,2) atom. O(1,2) is bonded in a single-bond geometry to one C(1) atom. Cl(1) is bonded in an L-shaped geometry to two equivalent Rh(1) atoms. is represented by the CIF card [CIF]
data_RhC2ClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.213
_cell_length_b   11.213
_cell_length_c   11.213
_cell_angle_alpha   100.201
_cell_angle_beta   100.201
_cell_angle_gamma   130.226
_symmetry_Int_Tables_number   1
_cell_volume   976.508
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rh  Rh0  1  0.768  0.688  0.376  1.0
  Rh  Rh1  1  0.938  0.518  0.876  1.0
  Rh  Rh2  1  0.642  0.061  0.124  1.0
  Rh  Rh3  1  0.311  0.392  0.624  1.0
  Rh  Rh4  1  0.312  0.689  0.080  1.0
  Rh  Rh5  1  0.939  0.062  0.580  1.0
  Rh  Rh6  1  0.482  0.358  0.420  1.0
  Rh  Rh7  1  0.608  0.232  0.920  1.0
  C  C8  1  0.874  0.980  0.709  1.0
  C  C9  1  0.753  0.740  0.230  1.0
  C  C10  1  0.510  0.523  0.770  1.0
  C  C11  1  0.020  0.729  0.894  1.0
  C  C12  1  0.835  0.126  0.106  1.0
  C  C13  1  0.497  0.227  0.487  1.0
  C  C14  1  0.415  0.021  0.791  1.0
  C  C15  1  0.376  0.585  0.606  1.0
  C  C16  1  0.477  0.247  0.987  1.0
  C  C17  1  0.979  0.770  0.394  1.0
  C  C18  1  0.230  0.624  0.209  1.0
  C  C19  1  0.260  0.490  0.013  1.0
  C  C20  1  0.271  0.165  0.291  1.0
  C  C21  1  0.740  0.010  0.513  1.0
  C  C22  1  0.990  0.503  0.730  1.0
  C  C23  1  0.773  0.260  0.270  1.0
  Cl  Cl24  1  0.795  0.231  0.842  1.0
  Cl  Cl25  1  0.769  0.612  0.564  1.0
  Cl  Cl26  1  0.481  0.545  0.342  1.0
  Cl  Cl27  1  0.388  0.953  0.158  1.0
  Cl  Cl28  1  0.047  0.205  0.436  1.0
  Cl  Cl29  1  0.862  0.519  0.064  1.0
  Cl  Cl30  1  0.203  0.138  0.658  1.0
  Cl  Cl31  1  0.455  0.797  0.936  1.0
  O  O32  1  0.834  0.933  0.791  1.0
  O  O33  1  0.634  0.601  0.860  1.0
  O  O34  1  0.509  0.149  0.533  1.0
  O  O35  1  0.024  0.491  0.640  1.0
  O  O36  1  0.957  0.166  0.099  1.0
  O  O37  1  0.416  0.707  0.599  1.0
  O  O38  1  0.067  0.858  0.901  1.0
  O  O39  1  0.293  0.892  0.709  1.0
  O  O40  1  0.399  0.259  0.033  1.0
  O  O41  1  0.741  0.774  0.140  1.0
  O  O42  1  0.616  0.976  0.467  1.0
  O  O43  1  0.226  0.366  0.967  1.0
  O  O44  1  0.851  0.384  0.360  1.0
  O  O45  1  0.108  0.817  0.401  1.0
  O  O46  1  0.142  0.043  0.209  1.0
  O  O47  1  0.183  0.584  0.291  1.0
[/CIF]
.