The crystal structure described by UPO5 crystallizes in the orthorhombic Cmce space group. U(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are four inequivalent O sites. In the first O site, O(4) is bonded in a water-like geometry to two equivalent U(1) atoms. In the second O site, O(1) is bonded in a 2-coordinate geometry to one U(1) and one P(1) atom. In the third O site, O(2) is bonded in a linear geometry to one U(1) and one P(1) atom. In the fourth O site, O(3) is bonded in a linear geometry to one U(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_UPO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.578
_cell_length_b   5.578
_cell_length_c   12.768
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   102.143
_symmetry_Int_Tables_number   1
_cell_volume   388.403
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.332  0.668  0.425  1.0
  U  U1  1  0.668  0.332  0.575  1.0
  U  U2  1  0.168  0.832  0.925  1.0
  U  U3  1  0.832  0.168  0.075  1.0
  P  P4  1  0.090  0.910  0.637  1.0
  P  P5  1  0.910  0.090  0.363  1.0
  P  P6  1  0.410  0.590  0.137  1.0
  P  P7  1  0.590  0.410  0.863  1.0
  O  O8  1  0.981  0.667  0.578  1.0
  O  O9  1  0.667  0.981  0.422  1.0
  O  O10  1  0.167  0.481  0.078  1.0
  O  O11  1  0.481  0.167  0.922  1.0
  O  O12  1  0.019  0.333  0.422  1.0
  O  O13  1  0.333  0.019  0.578  1.0
  O  O14  1  0.833  0.519  0.922  1.0
  O  O15  1  0.519  0.833  0.078  1.0
  O  O16  1  0.143  0.857  0.751  1.0
  O  O17  1  0.857  0.143  0.249  1.0
  O  O18  1  0.357  0.643  0.251  1.0
  O  O19  1  0.643  0.357  0.749  1.0
  O  O20  1  0.912  0.088  0.628  1.0
  O  O21  1  0.088  0.912  0.372  1.0
  O  O22  1  0.588  0.412  0.128  1.0
  O  O23  1  0.412  0.588  0.872  1.0
  O  O24  1  0.442  0.558  0.586  1.0
  O  O25  1  0.558  0.442  0.414  1.0
  O  O26  1  0.058  0.942  0.086  1.0
  O  O27  1  0.942  0.058  0.914  1.0
[/CIF]
.
The crystal structure described by UPO5 crystallizes in the orthorhombic Cmce space group. U(1) is bonded in a 6-coordinate geometry to one O(2), one O(3), two equivalent O(1), and two equivalent O(4) atoms. P(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are four inequivalent O sites. In the first O site, O(4) is bonded in a water-like geometry to two equivalent U(1) atoms. In the second O site, O(1) is bonded in a 2-coordinate geometry to one U(1) and one P(1) atom. In the third O site, O(2) is bonded in a linear geometry to one U(1) and one P(1) atom. In the fourth O site, O(3) is bonded in a linear geometry to one U(1) and one P(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_UPO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.578
_cell_length_b   5.578
_cell_length_c   12.768
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   102.143
_symmetry_Int_Tables_number   1
_cell_volume   388.403
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  U  U0  1  0.332  0.668  0.425  1.0
  U  U1  1  0.668  0.332  0.575  1.0
  U  U2  1  0.168  0.832  0.925  1.0
  U  U3  1  0.832  0.168  0.075  1.0
  P  P4  1  0.090  0.910  0.637  1.0
  P  P5  1  0.910  0.090  0.363  1.0
  P  P6  1  0.410  0.590  0.137  1.0
  P  P7  1  0.590  0.410  0.863  1.0
  O  O8  1  0.981  0.667  0.578  1.0
  O  O9  1  0.667  0.981  0.422  1.0
  O  O10  1  0.167  0.481  0.078  1.0
  O  O11  1  0.481  0.167  0.922  1.0
  O  O12  1  0.019  0.333  0.422  1.0
  O  O13  1  0.333  0.019  0.578  1.0
  O  O14  1  0.833  0.519  0.922  1.0
  O  O15  1  0.519  0.833  0.078  1.0
  O  O16  1  0.143  0.857  0.751  1.0
  O  O17  1  0.857  0.143  0.249  1.0
  O  O18  1  0.357  0.643  0.251  1.0
  O  O19  1  0.643  0.357  0.749  1.0
  O  O20  1  0.912  0.088  0.628  1.0
  O  O21  1  0.088  0.912  0.372  1.0
  O  O22  1  0.588  0.412  0.128  1.0
  O  O23  1  0.412  0.588  0.872  1.0
  O  O24  1  0.442  0.558  0.586  1.0
  O  O25  1  0.558  0.442  0.414  1.0
  O  O26  1  0.058  0.942  0.086  1.0
  O  O27  1  0.942  0.058  0.914  1.0
[/CIF]
.