The crystal structure described by Sr10WMo4Cu5O30 crystallizes in the monoclinic C2/m space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 8-coordinate geometry to one O(11), one O(13), one O(5), one O(7), two equivalent O(1), and two equivalent O(2) atoms. In the second Sr site, Sr(2) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent O(6,12) atoms. In the third Sr site, Sr(3) is bonded in a 8-coordinate geometry to one O(10), one O(4), one O(8), one O(9), two equivalent O(1), and two equivalent O(3) atoms. W(1) is bonded to two equivalent O(10), two equivalent O(3), and two equivalent O(8) atoms to form WO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra and corners with four equivalent Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-21°. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(11), one O(4), one O(7), one O(9), and two equivalent O(1) atoms to form MoO6 octahedra that share  a cornercorner with one Cu(2)O6 octahedra,  a cornercorner with one Cu(3)O6 octahedra, and corners with four equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-21°. In the second Mo site, Mo(2) is bonded to one O(13); one O(5); two equivalent O(2); and two equivalent O(6,12) atoms to form MoO6 octahedra that share  a cornercorner with one Cu(1)O6 octahedra and corners with five equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-21°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(11), one O(5), one O(8), one O(9), and two equivalent O(1) atoms to form CuO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one Mo(2)O6 octahedra, and corners with four equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-21°. In the second Cu site, Cu(2) is bonded to one O(13); one O(7); two equivalent O(2); and two equivalent O(6,12) atoms to form CuO6 octahedra that share  a cornercorner with one Mo(1)O6 octahedra and corners with five equivalent Mo(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-21°. In the third Cu site, Cu(3) is bonded to two equivalent O(10), two equivalent O(3), and two equivalent O(4) atoms to form CuO6 octahedra that share corners with two equivalent Mo(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-21°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Sr(1), two equivalent Sr(3), one Mo(1), and one Cu(1) atom to form distorted OSr4CuMo octahedra that share corners with two equivalent O(1)Sr4CuMo octahedra, corners with two equivalent O(2)Sr4CuMo octahedra, corners with two equivalent O(3)Sr4CuW octahedra,  an edgeedge with one O(2)Sr4CuMo octahedra,  an edgeedge with one O(3)Sr4CuW octahedra, and edges with two equivalent O(1)Sr4CuMo octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the second O site, O(2) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Mo(2), and one Cu(2) atom to form a mixture of distorted edge and corner-sharing OSr4CuMo octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third O site, O(3) is bonded to four equivalent Sr(3), one W(1), and one Cu(3) atom to form distorted OSr4CuW octahedra that share corners with two equivalent O(3)Sr4CuW octahedra, corners with four equivalent O(1)Sr4CuMo octahedra, edges with two equivalent O(1)Sr4CuMo octahedra, and edges with two equivalent O(3)Sr4CuW octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Sr(3), one Mo(1), and one Cu(3) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one Mo(2), and one Cu(1) atom. In the sixth O site, O(6,12) is bonded in a 4-coordinate geometry to two equivalent Sr(2), one Mo(2), and one Cu(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one Mo(1), and one Cu(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to two equivalent Sr(3), one W(1), and one Cu(1) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to two equivalent Sr(3), one Mo(1), and one Cu(1) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to two equivalent Sr(3), one W(1), and one Cu(3) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one Mo(1), and one Cu(1) atom. In the twelfth O site, O(13) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one Mo(2), and one Cu(2) atom. is represented by the CIF file [CIF]
data_Sr10Cu5Mo4WO30
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.757
_cell_length_b   5.757
_cell_length_c   19.828
_cell_angle_alpha   82.401
_cell_angle_beta   82.401
_cell_angle_gamma   95.063
_symmetry_Int_Tables_number   1
_cell_volume   641.862
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.350  0.850  0.300  1.0
  Sr  Sr1  1  0.750  0.250  0.500  1.0
  Sr  Sr2  1  0.150  0.650  0.700  1.0
  Sr  Sr3  1  0.950  0.450  0.101  1.0
  Sr  Sr4  1  0.550  0.050  0.899  1.0
  Sr  Sr5  1  0.850  0.350  0.300  1.0
  Sr  Sr6  1  0.250  0.750  0.500  1.0
  Sr  Sr7  1  0.650  0.150  0.700  1.0
  Sr  Sr8  1  0.450  0.950  0.101  1.0
  Sr  Sr9  1  0.050  0.550  0.899  1.0
  Cu  Cu10  1  0.900  0.900  0.200  1.0
  Cu  Cu11  1  0.300  0.300  0.400  1.0
  Cu  Cu12  1  0.700  0.700  0.600  1.0
  Cu  Cu13  1  0.500  0.500  0.000  1.0
  Cu  Cu14  1  0.100  0.100  0.800  1.0
  Mo  Mo15  1  0.600  0.600  0.800  1.0
  Mo  Mo16  1  0.200  0.200  0.600  1.0
  Mo  Mo17  1  0.800  0.800  0.400  1.0
  Mo  Mo18  1  0.400  0.400  0.200  1.0
  W  W19  1  0.000  0.000  0.000  1.0
  O  O20  1  0.630  0.170  0.200  1.0
  O  O21  1  0.030  0.570  0.400  1.0
  O  O22  1  0.430  0.970  0.600  1.0
  O  O23  1  0.230  0.770  0.000  1.0
  O  O24  1  0.830  0.370  0.800  1.0
  O  O25  1  0.570  0.030  0.400  1.0
  O  O26  1  0.970  0.430  0.600  1.0
  O  O27  1  0.370  0.830  0.800  1.0
  O  O28  1  0.170  0.630  0.200  1.0
  O  O29  1  0.770  0.230  0.000  1.0
  O  O30  1  0.596  0.596  0.898  1.0
  O  O31  1  0.197  0.197  0.698  1.0
  O  O32  1  0.797  0.797  0.498  1.0
  O  O33  1  0.396  0.396  0.298  1.0
  O  O34  1  0.997  0.997  0.099  1.0
  O  O35  1  0.803  0.803  0.302  1.0
  O  O36  1  0.404  0.404  0.102  1.0
  O  O37  1  0.003  0.003  0.901  1.0
  O  O38  1  0.604  0.604  0.702  1.0
  O  O39  1  0.203  0.203  0.502  1.0
  O  O40  1  0.655  0.655  0.182  1.0
  O  O41  1  0.256  0.256  0.982  1.0
  O  O42  1  0.855  0.855  0.782  1.0
  O  O43  1  0.455  0.455  0.582  1.0
  O  O44  1  0.055  0.055  0.382  1.0
  O  O45  1  0.744  0.744  0.018  1.0
  O  O46  1  0.345  0.345  0.818  1.0
  O  O47  1  0.945  0.945  0.618  1.0
  O  O48  1  0.545  0.545  0.418  1.0
  O  O49  1  0.145  0.145  0.218  1.0
[/CIF]
.
The crystal structure described by Sr10WMo4Cu5O30 crystallizes in the monoclinic C2/m space group. There are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 8-coordinate geometry to one O(11), one O(13), one O(5), one O(7), two equivalent O(1), and two equivalent O(2) atoms. In the second Sr site, Sr(2) is bonded in a 8-coordinate geometry to four equivalent O(2) and four equivalent O(6,12) atoms. In the third Sr site, Sr(3) is bonded in a 8-coordinate geometry to one O(10), one O(4), one O(8), one O(9), two equivalent O(1), and two equivalent O(3) atoms. W(1) is bonded to two equivalent O(10), two equivalent O(3), and two equivalent O(8) atoms to form WO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra and corners with four equivalent Cu(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-21°. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(11), one O(4), one O(7), one O(9), and two equivalent O(1) atoms to form MoO6 octahedra that share  a cornercorner with one Cu(2)O6 octahedra,  a cornercorner with one Cu(3)O6 octahedra, and corners with four equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-21°. In the second Mo site, Mo(2) is bonded to one O(13); one O(5); two equivalent O(2); and two equivalent O(6,12) atoms to form MoO6 octahedra that share  a cornercorner with one Cu(1)O6 octahedra and corners with five equivalent Cu(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-21°. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one O(11), one O(5), one O(8), one O(9), and two equivalent O(1) atoms to form CuO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one Mo(2)O6 octahedra, and corners with four equivalent Mo(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-21°. In the second Cu site, Cu(2) is bonded to one O(13); one O(7); two equivalent O(2); and two equivalent O(6,12) atoms to form CuO6 octahedra that share  a cornercorner with one Mo(1)O6 octahedra and corners with five equivalent Mo(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-21°. In the third Cu site, Cu(3) is bonded to two equivalent O(10), two equivalent O(3), and two equivalent O(4) atoms to form CuO6 octahedra that share corners with two equivalent Mo(1)O6 octahedra and corners with four equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-21°. There are twelve inequivalent O sites. In the first O site, O(1) is bonded to two equivalent Sr(1), two equivalent Sr(3), one Mo(1), and one Cu(1) atom to form distorted OSr4CuMo octahedra that share corners with two equivalent O(1)Sr4CuMo octahedra, corners with two equivalent O(2)Sr4CuMo octahedra, corners with two equivalent O(3)Sr4CuW octahedra,  an edgeedge with one O(2)Sr4CuMo octahedra,  an edgeedge with one O(3)Sr4CuW octahedra, and edges with two equivalent O(1)Sr4CuMo octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the second O site, O(2) is bonded to two equivalent Sr(1), two equivalent Sr(2), one Mo(2), and one Cu(2) atom to form a mixture of distorted edge and corner-sharing OSr4CuMo octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the third O site, O(3) is bonded to four equivalent Sr(3), one W(1), and one Cu(3) atom to form distorted OSr4CuW octahedra that share corners with two equivalent O(3)Sr4CuW octahedra, corners with four equivalent O(1)Sr4CuMo octahedra, edges with two equivalent O(1)Sr4CuMo octahedra, and edges with two equivalent O(3)Sr4CuW octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to two equivalent Sr(3), one Mo(1), and one Cu(3) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one Mo(2), and one Cu(1) atom. In the sixth O site, O(6,12) is bonded in a 4-coordinate geometry to two equivalent Sr(2), one Mo(2), and one Cu(2) atom. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one Mo(1), and one Cu(2) atom. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to two equivalent Sr(3), one W(1), and one Cu(1) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to two equivalent Sr(3), one Mo(1), and one Cu(1) atom. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to two equivalent Sr(3), one W(1), and one Cu(3) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one Mo(1), and one Cu(1) atom. In the twelfth O site, O(13) is bonded in a 4-coordinate geometry to two equivalent Sr(1), one Mo(2), and one Cu(2) atom. is represented by the CIF file [CIF]
data_Sr10Cu5Mo4WO30
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.757
_cell_length_b   5.757
_cell_length_c   19.828
_cell_angle_alpha   82.401
_cell_angle_beta   82.401
_cell_angle_gamma   95.063
_symmetry_Int_Tables_number   1
_cell_volume   641.862
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.350  0.850  0.300  1.0
  Sr  Sr1  1  0.750  0.250  0.500  1.0
  Sr  Sr2  1  0.150  0.650  0.700  1.0
  Sr  Sr3  1  0.950  0.450  0.101  1.0
  Sr  Sr4  1  0.550  0.050  0.899  1.0
  Sr  Sr5  1  0.850  0.350  0.300  1.0
  Sr  Sr6  1  0.250  0.750  0.500  1.0
  Sr  Sr7  1  0.650  0.150  0.700  1.0
  Sr  Sr8  1  0.450  0.950  0.101  1.0
  Sr  Sr9  1  0.050  0.550  0.899  1.0
  Cu  Cu10  1  0.900  0.900  0.200  1.0
  Cu  Cu11  1  0.300  0.300  0.400  1.0
  Cu  Cu12  1  0.700  0.700  0.600  1.0
  Cu  Cu13  1  0.500  0.500  0.000  1.0
  Cu  Cu14  1  0.100  0.100  0.800  1.0
  Mo  Mo15  1  0.600  0.600  0.800  1.0
  Mo  Mo16  1  0.200  0.200  0.600  1.0
  Mo  Mo17  1  0.800  0.800  0.400  1.0
  Mo  Mo18  1  0.400  0.400  0.200  1.0
  W  W19  1  0.000  0.000  0.000  1.0
  O  O20  1  0.630  0.170  0.200  1.0
  O  O21  1  0.030  0.570  0.400  1.0
  O  O22  1  0.430  0.970  0.600  1.0
  O  O23  1  0.230  0.770  0.000  1.0
  O  O24  1  0.830  0.370  0.800  1.0
  O  O25  1  0.570  0.030  0.400  1.0
  O  O26  1  0.970  0.430  0.600  1.0
  O  O27  1  0.370  0.830  0.800  1.0
  O  O28  1  0.170  0.630  0.200  1.0
  O  O29  1  0.770  0.230  0.000  1.0
  O  O30  1  0.596  0.596  0.898  1.0
  O  O31  1  0.197  0.197  0.698  1.0
  O  O32  1  0.797  0.797  0.498  1.0
  O  O33  1  0.396  0.396  0.298  1.0
  O  O34  1  0.997  0.997  0.099  1.0
  O  O35  1  0.803  0.803  0.302  1.0
  O  O36  1  0.404  0.404  0.102  1.0
  O  O37  1  0.003  0.003  0.901  1.0
  O  O38  1  0.604  0.604  0.702  1.0
  O  O39  1  0.203  0.203  0.502  1.0
  O  O40  1  0.655  0.655  0.182  1.0
  O  O41  1  0.256  0.256  0.982  1.0
  O  O42  1  0.855  0.855  0.782  1.0
  O  O43  1  0.455  0.455  0.582  1.0
  O  O44  1  0.055  0.055  0.382  1.0
  O  O45  1  0.744  0.744  0.018  1.0
  O  O46  1  0.345  0.345  0.818  1.0
  O  O47  1  0.945  0.945  0.618  1.0
  O  O48  1  0.545  0.545  0.418  1.0
  O  O49  1  0.145  0.145  0.218  1.0
[/CIF]
.