The material described by MgWAgZn2O6 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a square co-planar geometry to one O(3), one O(4), one O(5), and one O(6) atom. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with three equivalent Zn(1)O5 trigonal bipyramids, corners with three equivalent Zn(2)O5 trigonal bipyramids,  an edgeedge with one Zn(1)O5 trigonal bipyramid, and  an edgeedge with one Zn(2)O5 trigonal bipyramid. Ag(1) is bonded in a linear geometry to one O(1) and one O(2) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), one O(5), and one O(6) atom to form distorted ZnO5 trigonal bipyramids that share corners with three equivalent W(1)O6 octahedra,  an edgeedge with one W(1)O6 octahedra, and edges with two equivalent Zn(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 15-46°. In the second Zn site, Zn(2) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(6) atom to form distorted ZnO5 trigonal bipyramids that share corners with three equivalent W(1)O6 octahedra,  an edgeedge with one W(1)O6 octahedra, and edges with two equivalent Zn(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 13-46°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted edge and corner-sharing OZn2AgW trigonal pyramids. In the second O site, O(2) is bonded to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted edge and corner-sharing OZn2AgW tetrahedra. In the third O site, O(3) is bonded in a see-saw-like geometry to one Mg(1), one W(1), one Zn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a T-shaped geometry to one Mg(1), one W(1), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a T-shaped geometry to one Mg(1), one W(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a distorted see-saw-like geometry to one Mg(1), one W(1), one Zn(1), and one Zn(2) atom. is represented by the CIF file [CIF]
data_MgZn2AgWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.501
_cell_length_b   6.945
_cell_length_c   7.216
_cell_angle_alpha   90.225
_cell_angle_beta   127.235
_cell_angle_gamma   125.109
_symmetry_Int_Tables_number   1
_cell_volume   151.076
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.529  0.501  0.024  1.0
  Zn  Zn1  1  0.102  0.418  0.251  1.0
  Zn  Zn2  1  0.879  0.516  0.748  1.0
  Ag  Ag3  1  0.976  0.981  0.490  1.0
  W  W4  1  0.990  0.977  0.990  1.0
  O  O5  1  0.261  0.195  0.369  1.0
  O  O6  1  0.718  0.758  0.619  1.0
  O  O7  1  0.992  0.275  0.937  1.0
  O  O8  1  0.421  0.712  0.851  1.0
  O  O9  1  0.574  0.254  0.148  1.0
  O  O10  1  0.008  0.696  0.058  1.0
[/CIF]
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The material described by MgWAgZn2O6 crystallizes in the triclinic P1 space group. Mg(1) is bonded in a square co-planar geometry to one O(3), one O(4), one O(5), and one O(6) atom. W(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form WO6 octahedra that share corners with three equivalent Zn(1)O5 trigonal bipyramids, corners with three equivalent Zn(2)O5 trigonal bipyramids,  an edgeedge with one Zn(1)O5 trigonal bipyramid, and  an edgeedge with one Zn(2)O5 trigonal bipyramid. Ag(1) is bonded in a linear geometry to one O(1) and one O(2) atom. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), one O(5), and one O(6) atom to form distorted ZnO5 trigonal bipyramids that share corners with three equivalent W(1)O6 octahedra,  an edgeedge with one W(1)O6 octahedra, and edges with two equivalent Zn(2)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 15-46°. In the second Zn site, Zn(2) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(6) atom to form distorted ZnO5 trigonal bipyramids that share corners with three equivalent W(1)O6 octahedra,  an edgeedge with one W(1)O6 octahedra, and edges with two equivalent Zn(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles range from 13-46°. There are six inequivalent O sites. In the first O site, O(1) is bonded to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted edge and corner-sharing OZn2AgW trigonal pyramids. In the second O site, O(2) is bonded to one W(1), one Ag(1), one Zn(1), and one Zn(2) atom to form a mixture of distorted edge and corner-sharing OZn2AgW tetrahedra. In the third O site, O(3) is bonded in a see-saw-like geometry to one Mg(1), one W(1), one Zn(1), and one Zn(2) atom. In the fourth O site, O(4) is bonded in a T-shaped geometry to one Mg(1), one W(1), and one Zn(2) atom. In the fifth O site, O(5) is bonded in a T-shaped geometry to one Mg(1), one W(1), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a distorted see-saw-like geometry to one Mg(1), one W(1), one Zn(1), and one Zn(2) atom. is represented by the CIF file [CIF]
data_MgZn2AgWO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.501
_cell_length_b   6.945
_cell_length_c   7.216
_cell_angle_alpha   90.225
_cell_angle_beta   127.235
_cell_angle_gamma   125.109
_symmetry_Int_Tables_number   1
_cell_volume   151.076
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.529  0.501  0.024  1.0
  Zn  Zn1  1  0.102  0.418  0.251  1.0
  Zn  Zn2  1  0.879  0.516  0.748  1.0
  Ag  Ag3  1  0.976  0.981  0.490  1.0
  W  W4  1  0.990  0.977  0.990  1.0
  O  O5  1  0.261  0.195  0.369  1.0
  O  O6  1  0.718  0.758  0.619  1.0
  O  O7  1  0.992  0.275  0.937  1.0
  O  O8  1  0.421  0.712  0.851  1.0
  O  O9  1  0.574  0.254  0.148  1.0
  O  O10  1  0.008  0.696  0.058  1.0
[/CIF]
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