The compound described by Ga4O5 crystallizes in the orthorhombic Fddd space group. Ga(1) is bonded in a 4-coordinate geometry to one O(2) and three equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to three equivalent Ga(1) atoms. In the second O site, O(2) is bonded in a 4-coordinate geometry to four equivalent Ga(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ga4O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.604
_cell_length_b   6.604
_cell_length_c   6.674
_cell_angle_alpha   116.715
_cell_angle_beta   116.715
_cell_angle_gamma   95.241
_symmetry_Int_Tables_number   1
_cell_volume   215.920
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.278  0.110  0.650  1.0
  Ga  Ga1  1  0.372  0.540  0.650  1.0
  Ga  Ga2  1  0.890  0.722  0.350  1.0
  Ga  Ga3  1  0.972  0.640  0.850  1.0
  Ga  Ga4  1  0.460  0.628  0.350  1.0
  Ga  Ga5  1  0.878  0.210  0.850  1.0
  Ga  Ga6  1  0.360  0.028  0.150  1.0
  Ga  Ga7  1  0.790  0.122  0.150  1.0
  O  O8  1  0.180  0.449  0.981  1.0
  O  O9  1  0.801  0.531  0.981  1.0
  O  O10  1  0.551  0.820  0.019  1.0
  O  O11  1  0.070  0.301  0.519  1.0
  O  O12  1  0.469  0.199  0.019  1.0
  O  O13  1  0.449  0.219  0.519  1.0
  O  O14  1  0.699  0.930  0.481  1.0
  O  O15  1  0.781  0.551  0.481  1.0
  O  O16  1  0.000  0.000  0.000  1.0
  O  O17  1  0.250  0.750  0.500  1.0
[/CIF]
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The compound described by Ga4O5 crystallizes in the orthorhombic Fddd space group. Ga(1) is bonded in a 4-coordinate geometry to one O(2) and three equivalent O(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to three equivalent Ga(1) atoms. In the second O site, O(2) is bonded in a 4-coordinate geometry to four equivalent Ga(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ga4O5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.604
_cell_length_b   6.604
_cell_length_c   6.674
_cell_angle_alpha   116.715
_cell_angle_beta   116.715
_cell_angle_gamma   95.241
_symmetry_Int_Tables_number   1
_cell_volume   215.920
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.278  0.110  0.650  1.0
  Ga  Ga1  1  0.372  0.540  0.650  1.0
  Ga  Ga2  1  0.890  0.722  0.350  1.0
  Ga  Ga3  1  0.972  0.640  0.850  1.0
  Ga  Ga4  1  0.460  0.628  0.350  1.0
  Ga  Ga5  1  0.878  0.210  0.850  1.0
  Ga  Ga6  1  0.360  0.028  0.150  1.0
  Ga  Ga7  1  0.790  0.122  0.150  1.0
  O  O8  1  0.180  0.449  0.981  1.0
  O  O9  1  0.801  0.531  0.981  1.0
  O  O10  1  0.551  0.820  0.019  1.0
  O  O11  1  0.070  0.301  0.519  1.0
  O  O12  1  0.469  0.199  0.019  1.0
  O  O13  1  0.449  0.219  0.519  1.0
  O  O14  1  0.699  0.930  0.481  1.0
  O  O15  1  0.781  0.551  0.481  1.0
  O  O16  1  0.000  0.000  0.000  1.0
  O  O17  1  0.250  0.750  0.500  1.0
[/CIF]
.