The material described by S is alpha-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of six octathiocane molecules. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(13) and one S(8) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(14) and one S(20) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(7) and one S(8) atom. In the fourth S site, S(7) is bonded in a water-like geometry to one S(20) and one S(3) atom. In the fifth S site, S(8) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the sixth S site, S(13) is bonded in a water-like geometry to one S(1) and one S(14) atom. In the seventh S site, S(14) is bonded in a water-like geometry to one S(13) and one S(2) atom. In the eighth S site, S(20) is bonded in a water-like geometry to one S(2) and one S(7) atom. is represented by the CIF file [CIF]
data_S
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.053
_cell_length_b   10.988
_cell_length_c   11.214
_cell_angle_alpha   90.000
_cell_angle_beta   96.421
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1353.523
_cell_formula_units_Z   48
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.782  0.690  0.728  1.0
  S  S1  1  0.042  0.982  0.957  1.0
  S  S2  1  0.218  0.190  0.272  1.0
  S  S3  1  0.349  0.919  0.246  1.0
  S  S4  1  0.540  0.847  0.946  1.0
  S  S5  1  0.272  0.140  0.744  1.0
  S  S6  1  0.143  0.412  0.775  1.0
  S  S7  1  0.237  0.812  0.133  1.0
  S  S8  1  0.245  0.022  0.349  1.0
  S  S9  1  0.165  0.551  0.329  1.0
  S  S10  1  0.703  0.937  0.952  1.0
  S  S11  1  0.243  0.309  0.669  1.0
  S  S12  1  0.958  0.482  0.043  1.0
  S  S13  1  0.260  0.519  0.884  1.0
  S  S14  1  0.857  0.912  0.225  1.0
  S  S15  1  0.951  0.690  0.825  1.0
  S  S16  1  0.070  0.162  0.997  1.0
  S  S17  1  0.835  0.051  0.671  1.0
  S  S18  1  0.061  0.766  0.501  1.0
  S  S19  1  0.450  0.617  0.443  1.0
  S  S20  1  0.651  0.419  0.754  1.0
  S  S21  1  0.348  0.834  0.613  1.0
  S  S22  1  0.939  0.266  0.499  1.0
  S  S23  1  0.557  0.639  0.164  1.0
  S  S24  1  0.050  0.586  0.456  1.0
  S  S25  1  0.728  0.640  0.256  1.0
  S  S26  1  0.793  0.395  0.031  1.0
  S  S27  1  0.049  0.190  0.175  1.0
  S  S28  1  0.297  0.437  0.048  1.0
  S  S29  1  0.950  0.086  0.544  1.0
  S  S30  1  0.325  0.481  0.412  1.0
  S  S31  1  0.452  0.679  0.616  1.0
  S  S32  1  0.571  0.667  0.985  1.0
  S  S33  1  0.757  0.809  0.331  1.0
  S  S34  1  0.429  0.167  0.015  1.0
  S  S35  1  0.755  0.522  0.651  1.0
  S  S36  1  0.652  0.334  0.387  1.0
  S  S37  1  0.740  0.019  0.116  1.0
  S  S38  1  0.178  0.787  0.655  1.0
  S  S39  1  0.763  0.312  0.867  1.0
  S  S40  1  0.930  0.662  0.003  1.0
  S  S41  1  0.443  0.139  0.836  1.0
  S  S42  1  0.460  0.347  0.054  1.0
  S  S43  1  0.675  0.981  0.588  1.0
  S  S44  1  0.550  0.117  0.557  1.0
  S  S45  1  0.822  0.287  0.345  1.0
  S  S46  1  0.548  0.179  0.384  1.0
  S  S47  1  0.207  0.895  0.969  1.0
[/CIF]
.
The material described by S is alpha-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of six octathiocane molecules. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one S(13) and one S(8) atom. In the second S site, S(2) is bonded in a water-like geometry to one S(14) and one S(20) atom. In the third S site, S(3) is bonded in a water-like geometry to one S(7) and one S(8) atom. In the fourth S site, S(7) is bonded in a water-like geometry to one S(20) and one S(3) atom. In the fifth S site, S(8) is bonded in a water-like geometry to one S(1) and one S(3) atom. In the sixth S site, S(13) is bonded in a water-like geometry to one S(1) and one S(14) atom. In the seventh S site, S(14) is bonded in a water-like geometry to one S(13) and one S(2) atom. In the eighth S site, S(20) is bonded in a water-like geometry to one S(2) and one S(7) atom. is represented by the CIF file [CIF]
data_S
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.053
_cell_length_b   10.988
_cell_length_c   11.214
_cell_angle_alpha   90.000
_cell_angle_beta   96.421
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1353.523
_cell_formula_units_Z   48
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  S  S0  1  0.782  0.690  0.728  1.0
  S  S1  1  0.042  0.982  0.957  1.0
  S  S2  1  0.218  0.190  0.272  1.0
  S  S3  1  0.349  0.919  0.246  1.0
  S  S4  1  0.540  0.847  0.946  1.0
  S  S5  1  0.272  0.140  0.744  1.0
  S  S6  1  0.143  0.412  0.775  1.0
  S  S7  1  0.237  0.812  0.133  1.0
  S  S8  1  0.245  0.022  0.349  1.0
  S  S9  1  0.165  0.551  0.329  1.0
  S  S10  1  0.703  0.937  0.952  1.0
  S  S11  1  0.243  0.309  0.669  1.0
  S  S12  1  0.958  0.482  0.043  1.0
  S  S13  1  0.260  0.519  0.884  1.0
  S  S14  1  0.857  0.912  0.225  1.0
  S  S15  1  0.951  0.690  0.825  1.0
  S  S16  1  0.070  0.162  0.997  1.0
  S  S17  1  0.835  0.051  0.671  1.0
  S  S18  1  0.061  0.766  0.501  1.0
  S  S19  1  0.450  0.617  0.443  1.0
  S  S20  1  0.651  0.419  0.754  1.0
  S  S21  1  0.348  0.834  0.613  1.0
  S  S22  1  0.939  0.266  0.499  1.0
  S  S23  1  0.557  0.639  0.164  1.0
  S  S24  1  0.050  0.586  0.456  1.0
  S  S25  1  0.728  0.640  0.256  1.0
  S  S26  1  0.793  0.395  0.031  1.0
  S  S27  1  0.049  0.190  0.175  1.0
  S  S28  1  0.297  0.437  0.048  1.0
  S  S29  1  0.950  0.086  0.544  1.0
  S  S30  1  0.325  0.481  0.412  1.0
  S  S31  1  0.452  0.679  0.616  1.0
  S  S32  1  0.571  0.667  0.985  1.0
  S  S33  1  0.757  0.809  0.331  1.0
  S  S34  1  0.429  0.167  0.015  1.0
  S  S35  1  0.755  0.522  0.651  1.0
  S  S36  1  0.652  0.334  0.387  1.0
  S  S37  1  0.740  0.019  0.116  1.0
  S  S38  1  0.178  0.787  0.655  1.0
  S  S39  1  0.763  0.312  0.867  1.0
  S  S40  1  0.930  0.662  0.003  1.0
  S  S41  1  0.443  0.139  0.836  1.0
  S  S42  1  0.460  0.347  0.054  1.0
  S  S43  1  0.675  0.981  0.588  1.0
  S  S44  1  0.550  0.117  0.557  1.0
  S  S45  1  0.822  0.287  0.345  1.0
  S  S46  1  0.548  0.179  0.384  1.0
  S  S47  1  0.207  0.895  0.969  1.0
[/CIF]
.