The material described by PtN3S4Cl is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four PtN3S4Cl clusters. Pt(1) is bonded in a square co-planar geometry to one N(2), two equivalent S(1), and one Cl(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Pt(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Pt(1) and one N(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the CIF card [CIF]
data_PtS4N3Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.478
_cell_length_b   11.424
_cell_length_c   13.827
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   865.279
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.482  0.672  0.250  1.0
  Pt  Pt1  1  0.518  0.328  0.750  1.0
  Pt  Pt2  1  0.018  0.172  0.250  1.0
  Pt  Pt3  1  0.982  0.828  0.750  1.0
  S  S4  1  0.467  0.669  0.413  1.0
  S  S5  1  0.902  0.491  0.643  1.0
  S  S6  1  0.598  0.991  0.857  1.0
  S  S7  1  0.533  0.331  0.913  1.0
  S  S8  1  0.033  0.169  0.087  1.0
  S  S9  1  0.967  0.831  0.913  1.0
  S  S10  1  0.402  0.009  0.357  1.0
  S  S11  1  0.098  0.509  0.357  1.0
  S  S12  1  0.967  0.831  0.587  1.0
  S  S13  1  0.033  0.169  0.413  1.0
  S  S14  1  0.467  0.669  0.087  1.0
  S  S15  1  0.533  0.331  0.587  1.0
  S  S16  1  0.598  0.991  0.643  1.0
  S  S17  1  0.902  0.491  0.857  1.0
  S  S18  1  0.098  0.509  0.143  1.0
  S  S19  1  0.402  0.009  0.143  1.0
  N  N20  1  0.252  0.076  0.064  1.0
  N  N21  1  0.752  0.424  0.936  1.0
  N  N22  1  0.748  0.924  0.564  1.0
  N  N23  1  0.248  0.576  0.436  1.0
  N  N24  1  0.785  0.446  0.750  1.0
  N  N25  1  0.748  0.924  0.936  1.0
  N  N26  1  0.752  0.424  0.564  1.0
  N  N27  1  0.248  0.576  0.064  1.0
  N  N28  1  0.715  0.946  0.750  1.0
  N  N29  1  0.285  0.054  0.250  1.0
  N  N30  1  0.252  0.076  0.436  1.0
  N  N31  1  0.215  0.554  0.250  1.0
  Cl  Cl32  1  0.790  0.813  0.250  1.0
  Cl  Cl33  1  0.210  0.187  0.750  1.0
  Cl  Cl34  1  0.290  0.687  0.750  1.0
  Cl  Cl35  1  0.710  0.313  0.250  1.0
[/CIF]
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The material described by PtN3S4Cl is Indium-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four PtN3S4Cl clusters. Pt(1) is bonded in a square co-planar geometry to one N(2), two equivalent S(1), and one Cl(1) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one S(1) and one S(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Pt(1) and two equivalent S(2) atoms. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one Pt(1) and one N(1) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(1) and one N(2) atom. Cl(1) is bonded in a single-bond geometry to one Pt(1) atom. is represented by the CIF card [CIF]
data_PtS4N3Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.478
_cell_length_b   11.424
_cell_length_c   13.827
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   865.279
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.482  0.672  0.250  1.0
  Pt  Pt1  1  0.518  0.328  0.750  1.0
  Pt  Pt2  1  0.018  0.172  0.250  1.0
  Pt  Pt3  1  0.982  0.828  0.750  1.0
  S  S4  1  0.467  0.669  0.413  1.0
  S  S5  1  0.902  0.491  0.643  1.0
  S  S6  1  0.598  0.991  0.857  1.0
  S  S7  1  0.533  0.331  0.913  1.0
  S  S8  1  0.033  0.169  0.087  1.0
  S  S9  1  0.967  0.831  0.913  1.0
  S  S10  1  0.402  0.009  0.357  1.0
  S  S11  1  0.098  0.509  0.357  1.0
  S  S12  1  0.967  0.831  0.587  1.0
  S  S13  1  0.033  0.169  0.413  1.0
  S  S14  1  0.467  0.669  0.087  1.0
  S  S15  1  0.533  0.331  0.587  1.0
  S  S16  1  0.598  0.991  0.643  1.0
  S  S17  1  0.902  0.491  0.857  1.0
  S  S18  1  0.098  0.509  0.143  1.0
  S  S19  1  0.402  0.009  0.143  1.0
  N  N20  1  0.252  0.076  0.064  1.0
  N  N21  1  0.752  0.424  0.936  1.0
  N  N22  1  0.748  0.924  0.564  1.0
  N  N23  1  0.248  0.576  0.436  1.0
  N  N24  1  0.785  0.446  0.750  1.0
  N  N25  1  0.748  0.924  0.936  1.0
  N  N26  1  0.752  0.424  0.564  1.0
  N  N27  1  0.248  0.576  0.064  1.0
  N  N28  1  0.715  0.946  0.750  1.0
  N  N29  1  0.285  0.054  0.250  1.0
  N  N30  1  0.252  0.076  0.436  1.0
  N  N31  1  0.215  0.554  0.250  1.0
  Cl  Cl32  1  0.790  0.813  0.250  1.0
  Cl  Cl33  1  0.210  0.187  0.750  1.0
  Cl  Cl34  1  0.290  0.687  0.750  1.0
  Cl  Cl35  1  0.710  0.313  0.250  1.0
[/CIF]
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