The material structure described by AgV6O15 crystallizes in the triclinic P-1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(13), one O(2), and one O(3) atom to form a mixture of distorted corner and edge-sharing VO4 tetrahedra. In the second V site, V(2) is bonded to one O(5), one O(7), and two equivalent O(4) atoms to form a mixture of corner and edge-sharing VO4 tetrahedra. In the third V site, V(3) is bonded to one O(3), one O(5), one O(6), and one O(8) atom to form corner-sharing VO4 tetrahedra. In the fourth V site, V(4) is bonded to one O(1), one O(10), one O(6), and one O(9) atom to form corner-sharing VO4 tetrahedra. In the fifth V site, V(5) is bonded to one O(12), one O(14), and two equivalent O(11) atoms to form a mixture of corner and edge-sharing VO4 tetrahedra. In the sixth V site, V(6) is bonded to one O(1), one O(12), one O(13), and one O(15) atom to form a mixture of corner and edge-sharing VO4 tetrahedra. Ag(1) is bonded in a rectangular see-saw-like geometry to one O(14), one O(2), one O(7), and one O(9) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(6) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Ag(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(1) and one V(3) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to two equivalent V(2) atoms. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one V(2) and one V(3) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one V(2) and one Ag(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one V(3) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(4) and one Ag(1) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one V(4) atom. In the eleventh O site, O(11) is bonded in an L-shaped geometry to two equivalent V(5) atoms. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one V(5) and one V(6) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one V(1) and one V(6) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one V(5) and one Ag(1) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one V(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V6AgO15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.933
_cell_length_b   7.828
_cell_length_c   9.072
_cell_angle_alpha   85.163
_cell_angle_beta   89.007
_cell_angle_gamma   91.905
_symmetry_Int_Tables_number   1
_cell_volume   843.690
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.030  0.204  0.103  1.0
  V  V1  1  0.195  0.619  0.419  1.0
  V  V2  1  0.220  0.727  0.069  1.0
  V  V3  1  0.280  0.273  0.931  1.0
  V  V4  1  0.305  0.381  0.581  1.0
  V  V5  1  0.470  0.796  0.897  1.0
  V  V6  1  0.515  0.170  0.120  1.0
  V  V7  1  0.689  0.625  0.434  1.0
  V  V8  1  0.638  0.793  0.104  1.0
  V  V9  1  0.862  0.207  0.896  1.0
  V  V10  1  0.811  0.375  0.566  1.0
  V  V11  1  0.985  0.830  0.880  1.0
  Ag  Ag12  1  0.507  0.018  0.511  1.0
  Ag  Ag13  1  0.993  0.982  0.489  1.0
  O  O14  1  0.982  0.063  0.936  1.0
  O  O15  1  0.039  0.109  0.273  1.0
  O  O16  1  0.148  0.331  0.005  1.0
  O  O17  1  0.159  0.429  0.543  1.0
  O  O18  1  0.164  0.590  0.230  1.0
  O  O19  1  0.123  0.742  0.924  1.0
  O  O20  1  0.157  0.798  0.481  1.0
  O  O21  1  0.236  0.912  0.136  1.0
  O  O22  1  0.264  0.088  0.864  1.0
  O  O23  1  0.343  0.202  0.519  1.0
  O  O24  1  0.377  0.258  0.076  1.0
  O  O25  1  0.336  0.410  0.770  1.0
  O  O26  1  0.341  0.571  0.457  1.0
  O  O27  1  0.352  0.669  0.995  1.0
  O  O28  1  0.461  0.891  0.727  1.0
  O  O29  1  0.518  0.937  0.064  1.0
  O  O30  1  0.545  0.161  0.301  1.0
  O  O31  1  0.607  0.292  0.023  1.0
  O  O32  1  0.663  0.431  0.557  1.0
  O  O33  1  0.620  0.630  0.259  1.0
  O  O34  1  0.617  0.706  0.934  1.0
  O  O35  1  0.660  0.798  0.512  1.0
  O  O36  1  0.752  0.904  0.132  1.0
  O  O37  1  0.748  0.096  0.868  1.0
  O  O38  1  0.840  0.202  0.488  1.0
  O  O39  1  0.883  0.294  0.066  1.0
  O  O40  1  0.880  0.370  0.741  1.0
  O  O41  1  0.837  0.569  0.443  1.0
  O  O42  1  0.893  0.708  0.977  1.0
  O  O43  1  0.955  0.839  0.699  1.0
[/CIF]
.
The material structure described by AgV6O15 crystallizes in the triclinic P-1 space group. There are six inequivalent V sites. In the first V site, V(1) is bonded to one O(1), one O(13), one O(2), and one O(3) atom to form a mixture of distorted corner and edge-sharing VO4 tetrahedra. In the second V site, V(2) is bonded to one O(5), one O(7), and two equivalent O(4) atoms to form a mixture of corner and edge-sharing VO4 tetrahedra. In the third V site, V(3) is bonded to one O(3), one O(5), one O(6), and one O(8) atom to form corner-sharing VO4 tetrahedra. In the fourth V site, V(4) is bonded to one O(1), one O(10), one O(6), and one O(9) atom to form corner-sharing VO4 tetrahedra. In the fifth V site, V(5) is bonded to one O(12), one O(14), and two equivalent O(11) atoms to form a mixture of corner and edge-sharing VO4 tetrahedra. In the sixth V site, V(6) is bonded to one O(1), one O(12), one O(13), and one O(15) atom to form a mixture of corner and edge-sharing VO4 tetrahedra. Ag(1) is bonded in a rectangular see-saw-like geometry to one O(14), one O(2), one O(7), and one O(9) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one V(1), one V(4), and one V(6) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and one Ag(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one V(1) and one V(3) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to two equivalent V(2) atoms. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one V(2) and one V(3) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one V(3) and one V(4) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one V(2) and one Ag(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one V(3) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one V(4) and one Ag(1) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one V(4) atom. In the eleventh O site, O(11) is bonded in an L-shaped geometry to two equivalent V(5) atoms. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one V(5) and one V(6) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one V(1) and one V(6) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one V(5) and one Ag(1) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one V(6) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_V6AgO15
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.933
_cell_length_b   7.828
_cell_length_c   9.072
_cell_angle_alpha   85.163
_cell_angle_beta   89.007
_cell_angle_gamma   91.905
_symmetry_Int_Tables_number   1
_cell_volume   843.690
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.030  0.204  0.103  1.0
  V  V1  1  0.195  0.619  0.419  1.0
  V  V2  1  0.220  0.727  0.069  1.0
  V  V3  1  0.280  0.273  0.931  1.0
  V  V4  1  0.305  0.381  0.581  1.0
  V  V5  1  0.470  0.796  0.897  1.0
  V  V6  1  0.515  0.170  0.120  1.0
  V  V7  1  0.689  0.625  0.434  1.0
  V  V8  1  0.638  0.793  0.104  1.0
  V  V9  1  0.862  0.207  0.896  1.0
  V  V10  1  0.811  0.375  0.566  1.0
  V  V11  1  0.985  0.830  0.880  1.0
  Ag  Ag12  1  0.507  0.018  0.511  1.0
  Ag  Ag13  1  0.993  0.982  0.489  1.0
  O  O14  1  0.982  0.063  0.936  1.0
  O  O15  1  0.039  0.109  0.273  1.0
  O  O16  1  0.148  0.331  0.005  1.0
  O  O17  1  0.159  0.429  0.543  1.0
  O  O18  1  0.164  0.590  0.230  1.0
  O  O19  1  0.123  0.742  0.924  1.0
  O  O20  1  0.157  0.798  0.481  1.0
  O  O21  1  0.236  0.912  0.136  1.0
  O  O22  1  0.264  0.088  0.864  1.0
  O  O23  1  0.343  0.202  0.519  1.0
  O  O24  1  0.377  0.258  0.076  1.0
  O  O25  1  0.336  0.410  0.770  1.0
  O  O26  1  0.341  0.571  0.457  1.0
  O  O27  1  0.352  0.669  0.995  1.0
  O  O28  1  0.461  0.891  0.727  1.0
  O  O29  1  0.518  0.937  0.064  1.0
  O  O30  1  0.545  0.161  0.301  1.0
  O  O31  1  0.607  0.292  0.023  1.0
  O  O32  1  0.663  0.431  0.557  1.0
  O  O33  1  0.620  0.630  0.259  1.0
  O  O34  1  0.617  0.706  0.934  1.0
  O  O35  1  0.660  0.798  0.512  1.0
  O  O36  1  0.752  0.904  0.132  1.0
  O  O37  1  0.748  0.096  0.868  1.0
  O  O38  1  0.840  0.202  0.488  1.0
  O  O39  1  0.883  0.294  0.066  1.0
  O  O40  1  0.880  0.370  0.741  1.0
  O  O41  1  0.837  0.569  0.443  1.0
  O  O42  1  0.893  0.708  0.977  1.0
  O  O43  1  0.955  0.839  0.699  1.0
[/CIF]
.