The crystal structure described by Os(OF)2 is Silicon tetrafluoride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Os(OF)2 clusters. Os(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one F(1), and one F(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Os(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Os(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Os(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Os(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.748
_cell_length_b   5.740
_cell_length_c   7.488
_cell_angle_alpha   69.742
_cell_angle_beta   73.776
_cell_angle_gamma   62.284
_symmetry_Int_Tables_number   1
_cell_volume   203.066
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.296  0.253  0.750  1.0
  Os  Os1  1  0.704  0.747  0.250  1.0
  O  O2  1  0.342  0.311  0.943  1.0
  O  O3  1  0.554  0.193  0.569  1.0
  O  O4  1  0.446  0.807  0.431  1.0
  O  O5  1  0.658  0.689  0.057  1.0
  F  F6  1  0.056  0.508  0.301  1.0
  F  F7  1  0.141  0.007  0.790  1.0
  F  F8  1  0.859  0.993  0.210  1.0
  F  F9  1  0.944  0.492  0.699  1.0
[/CIF]
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The crystal structure described by Os(OF)2 is Silicon tetrafluoride-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Os(OF)2 clusters. Os(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one F(1), and one F(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Os(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Os(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one Os(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Os(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Os(OF)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.748
_cell_length_b   5.740
_cell_length_c   7.488
_cell_angle_alpha   69.742
_cell_angle_beta   73.776
_cell_angle_gamma   62.284
_symmetry_Int_Tables_number   1
_cell_volume   203.066
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.296  0.253  0.750  1.0
  Os  Os1  1  0.704  0.747  0.250  1.0
  O  O2  1  0.342  0.311  0.943  1.0
  O  O3  1  0.554  0.193  0.569  1.0
  O  O4  1  0.446  0.807  0.431  1.0
  O  O5  1  0.658  0.689  0.057  1.0
  F  F6  1  0.056  0.508  0.301  1.0
  F  F7  1  0.141  0.007  0.790  1.0
  F  F8  1  0.859  0.993  0.210  1.0
  F  F9  1  0.944  0.492  0.699  1.0
[/CIF]
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