The compound described by MgV(TeO3)4 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(10), one O(11), one O(3), one O(7), and one O(8) atom to form MgO6 octahedra that share  an edgeedge with one Te(2)O6 octahedra and edges with two equivalent V(1)O6 octahedra. V(1) is bonded to one O(1), one O(11), one O(4), one O(7), one O(8), and one O(9) atom to form VO6 octahedra that share edges with two equivalent Mg(1)O6 octahedra and edges with two equivalent Te(2)O6 octahedra. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom. In the second Te site, Te(2) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form TeO6 octahedra that share  an edgeedge with one Mg(1)O6 octahedra and edges with two equivalent V(1)O6 octahedra. In the third Te site, Te(3) is bonded in a 4-coordinate geometry to one O(12), one O(2), one O(4), and one O(9) atom. In the fourth Te site, Te(4) is bonded in a 3-coordinate geometry to one O(3), one O(5), and one O(6) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one V(1), and one Te(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Te(1) and one Te(3) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Mg(1), one Te(1), and one Te(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one Te(2), and one Te(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(4) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Te(2) and one Te(4) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one V(1), and one Te(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Mg(1), one V(1), and one Te(1) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one V(1), one Te(2), and one Te(3) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Mg(1) and one Te(1) atom. In the eleventh O site, O(11) is bonded in a trigonal non-coplanar geometry to one Mg(1), one V(1), and one Te(1) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Te(2) and one Te(3) atom. is represented by the CIF card [CIF]
data_MgV(TeO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.034
_cell_length_b   13.949
_cell_length_c   12.679
_cell_angle_alpha   22.348
_cell_angle_beta   41.945
_cell_angle_gamma   46.378
_symmetry_Int_Tables_number   1
_cell_volume   271.213
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.682  0.498  0.658  1.0
  V  V1  1  0.321  0.019  0.288  1.0
  Te  Te2  1  0.039  0.956  0.002  1.0
  Te  Te3  1  0.953  0.521  0.980  1.0
  Te  Te4  1  0.483  0.989  0.530  1.0
  Te  Te5  1  0.556  0.477  0.424  1.0
  O  O6  1  0.360  0.314  0.072  1.0
  O  O7  1  0.146  0.114  0.603  1.0
  O  O8  1  0.129  0.345  0.701  1.0
  O  O9  1  0.869  0.200  0.250  1.0
  O  O10  1  0.447  0.816  0.076  1.0
  O  O11  1  0.701  0.371  0.336  1.0
  O  O12  1  0.190  0.682  0.617  1.0
  O  O13  1  0.523  0.179  0.951  1.0
  O  O14  1  0.131  0.807  0.703  1.0
  O  O15  1  0.878  0.665  0.289  1.0
  O  O16  1  0.765  0.858  0.323  1.0
  O  O17  1  0.542  0.687  0.910  1.0
[/CIF]
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The compound described by MgV(TeO3)4 crystallizes in the triclinic P1 space group. Mg(1) is bonded to one O(1), one O(10), one O(11), one O(3), one O(7), and one O(8) atom to form MgO6 octahedra that share  an edgeedge with one Te(2)O6 octahedra and edges with two equivalent V(1)O6 octahedra. V(1) is bonded to one O(1), one O(11), one O(4), one O(7), one O(8), and one O(9) atom to form VO6 octahedra that share edges with two equivalent Mg(1)O6 octahedra and edges with two equivalent Te(2)O6 octahedra. There are four inequivalent Te sites. In the first Te site, Te(1) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(2), one O(3), one O(5), and one O(8) atom. In the second Te site, Te(2) is bonded to one O(1), one O(12), one O(4), one O(6), one O(7), and one O(9) atom to form TeO6 octahedra that share  an edgeedge with one Mg(1)O6 octahedra and edges with two equivalent V(1)O6 octahedra. In the third Te site, Te(3) is bonded in a 4-coordinate geometry to one O(12), one O(2), one O(4), and one O(9) atom. In the fourth Te site, Te(4) is bonded in a 3-coordinate geometry to one O(3), one O(5), and one O(6) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one V(1), and one Te(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Te(1) and one Te(3) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Mg(1), one Te(1), and one Te(4) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one V(1), one Te(2), and one Te(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Te(1) and one Te(4) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Te(2) and one Te(4) atom. In the seventh O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Mg(1), one V(1), and one Te(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Mg(1), one V(1), and one Te(1) atom. In the ninth O site, O(9) is bonded in a distorted T-shaped geometry to one V(1), one Te(2), and one Te(3) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Mg(1) and one Te(1) atom. In the eleventh O site, O(11) is bonded in a trigonal non-coplanar geometry to one Mg(1), one V(1), and one Te(1) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Te(2) and one Te(3) atom. is represented by the CIF card [CIF]
data_MgV(TeO3)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.034
_cell_length_b   13.949
_cell_length_c   12.679
_cell_angle_alpha   22.348
_cell_angle_beta   41.945
_cell_angle_gamma   46.378
_symmetry_Int_Tables_number   1
_cell_volume   271.213
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.682  0.498  0.658  1.0
  V  V1  1  0.321  0.019  0.288  1.0
  Te  Te2  1  0.039  0.956  0.002  1.0
  Te  Te3  1  0.953  0.521  0.980  1.0
  Te  Te4  1  0.483  0.989  0.530  1.0
  Te  Te5  1  0.556  0.477  0.424  1.0
  O  O6  1  0.360  0.314  0.072  1.0
  O  O7  1  0.146  0.114  0.603  1.0
  O  O8  1  0.129  0.345  0.701  1.0
  O  O9  1  0.869  0.200  0.250  1.0
  O  O10  1  0.447  0.816  0.076  1.0
  O  O11  1  0.701  0.371  0.336  1.0
  O  O12  1  0.190  0.682  0.617  1.0
  O  O13  1  0.523  0.179  0.951  1.0
  O  O14  1  0.131  0.807  0.703  1.0
  O  O15  1  0.878  0.665  0.289  1.0
  O  O16  1  0.765  0.858  0.323  1.0
  O  O17  1  0.542  0.687  0.910  1.0
[/CIF]
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