The crystal structure described by AgFAuF6 crystallizes in the orthorhombic Pnma space group. Au(1) is bonded to one F(2), one F(5), two equivalent F(3), and two equivalent F(4) atoms to form AuF6 octahedra that share corners with three equivalent Ag(1)F7 pentagonal bipyramids and  an edgeedge with one Ag(1)F7 pentagonal bipyramid. Ag(1) is bonded to one F(2), two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms to form AgF7 pentagonal bipyramids that share corners with three equivalent Au(1)F6 octahedra, corners with two equivalent Ag(1)F7 pentagonal bipyramids, and  an edgeedge with one Au(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 34-46°. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Au(1) atom. In the second F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Ag(1) atoms. In the third F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Au(1) and one Ag(1) atom. In the fourth F site, F(3) is bonded in a water-like geometry to one Au(1) and one Ag(1) atom. In the fifth F site, F(4) is bonded in a bent 150 degrees geometry to one Au(1) and one Ag(1) atom. is represented by the CIF file [CIF]
data_AgAuF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.097
_cell_length_b   7.748
_cell_length_c   10.095
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   555.120
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.750  0.867  0.742  1.0
  Ag  Ag1  1  0.750  0.367  0.758  1.0
  Ag  Ag2  1  0.250  0.133  0.258  1.0
  Ag  Ag3  1  0.250  0.633  0.242  1.0
  Au  Au4  1  0.250  0.805  0.556  1.0
  Au  Au5  1  0.250  0.305  0.944  1.0
  Au  Au6  1  0.750  0.195  0.444  1.0
  Au  Au7  1  0.750  0.695  0.056  1.0
  F  F8  1  0.750  0.614  0.697  1.0
  F  F9  1  0.750  0.114  0.803  1.0
  F  F10  1  0.250  0.386  0.303  1.0
  F  F11  1  0.250  0.886  0.197  1.0
  F  F12  1  0.750  0.967  0.525  1.0
  F  F13  1  0.750  0.467  0.975  1.0
  F  F14  1  0.250  0.033  0.475  1.0
  F  F15  1  0.250  0.533  0.025  1.0
  F  F16  1  0.934  0.773  0.929  1.0
  F  F17  1  0.566  0.273  0.571  1.0
  F  F18  1  0.434  0.227  0.071  1.0
  F  F19  1  0.066  0.727  0.429  1.0
  F  F20  1  0.066  0.227  0.071  1.0
  F  F21  1  0.434  0.727  0.429  1.0
  F  F22  1  0.566  0.773  0.929  1.0
  F  F23  1  0.934  0.273  0.571  1.0
  F  F24  1  0.438  0.882  0.681  1.0
  F  F25  1  0.062  0.382  0.819  1.0
  F  F26  1  0.938  0.118  0.319  1.0
  F  F27  1  0.562  0.618  0.181  1.0
  F  F28  1  0.562  0.118  0.319  1.0
  F  F29  1  0.938  0.618  0.181  1.0
  F  F30  1  0.062  0.882  0.681  1.0
  F  F31  1  0.438  0.382  0.819  1.0
  F  F32  1  0.250  0.583  0.636  1.0
  F  F33  1  0.250  0.083  0.864  1.0
  F  F34  1  0.750  0.417  0.364  1.0
  F  F35  1  0.750  0.917  0.136  1.0
[/CIF]
.
The crystal structure described by AgFAuF6 crystallizes in the orthorhombic Pnma space group. Au(1) is bonded to one F(2), one F(5), two equivalent F(3), and two equivalent F(4) atoms to form AuF6 octahedra that share corners with three equivalent Ag(1)F7 pentagonal bipyramids and  an edgeedge with one Ag(1)F7 pentagonal bipyramid. Ag(1) is bonded to one F(2), two equivalent F(1), two equivalent F(3), and two equivalent F(4) atoms to form AgF7 pentagonal bipyramids that share corners with three equivalent Au(1)F6 octahedra, corners with two equivalent Ag(1)F7 pentagonal bipyramids, and  an edgeedge with one Au(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 34-46°. There are five inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one Au(1) atom. In the second F site, F(1) is bonded in a bent 150 degrees geometry to two equivalent Ag(1) atoms. In the third F site, F(2) is bonded in a distorted bent 120 degrees geometry to one Au(1) and one Ag(1) atom. In the fourth F site, F(3) is bonded in a water-like geometry to one Au(1) and one Ag(1) atom. In the fifth F site, F(4) is bonded in a bent 150 degrees geometry to one Au(1) and one Ag(1) atom. is represented by the CIF file [CIF]
data_AgAuF7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.097
_cell_length_b   7.748
_cell_length_c   10.095
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   555.120
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.750  0.867  0.742  1.0
  Ag  Ag1  1  0.750  0.367  0.758  1.0
  Ag  Ag2  1  0.250  0.133  0.258  1.0
  Ag  Ag3  1  0.250  0.633  0.242  1.0
  Au  Au4  1  0.250  0.805  0.556  1.0
  Au  Au5  1  0.250  0.305  0.944  1.0
  Au  Au6  1  0.750  0.195  0.444  1.0
  Au  Au7  1  0.750  0.695  0.056  1.0
  F  F8  1  0.750  0.614  0.697  1.0
  F  F9  1  0.750  0.114  0.803  1.0
  F  F10  1  0.250  0.386  0.303  1.0
  F  F11  1  0.250  0.886  0.197  1.0
  F  F12  1  0.750  0.967  0.525  1.0
  F  F13  1  0.750  0.467  0.975  1.0
  F  F14  1  0.250  0.033  0.475  1.0
  F  F15  1  0.250  0.533  0.025  1.0
  F  F16  1  0.934  0.773  0.929  1.0
  F  F17  1  0.566  0.273  0.571  1.0
  F  F18  1  0.434  0.227  0.071  1.0
  F  F19  1  0.066  0.727  0.429  1.0
  F  F20  1  0.066  0.227  0.071  1.0
  F  F21  1  0.434  0.727  0.429  1.0
  F  F22  1  0.566  0.773  0.929  1.0
  F  F23  1  0.934  0.273  0.571  1.0
  F  F24  1  0.438  0.882  0.681  1.0
  F  F25  1  0.062  0.382  0.819  1.0
  F  F26  1  0.938  0.118  0.319  1.0
  F  F27  1  0.562  0.618  0.181  1.0
  F  F28  1  0.562  0.118  0.319  1.0
  F  F29  1  0.938  0.618  0.181  1.0
  F  F30  1  0.062  0.882  0.681  1.0
  F  F31  1  0.438  0.382  0.819  1.0
  F  F32  1  0.250  0.583  0.636  1.0
  F  F33  1  0.250  0.083  0.864  1.0
  F  F34  1  0.750  0.417  0.364  1.0
  F  F35  1  0.750  0.917  0.136  1.0
[/CIF]
.