The crystal structure described by Ba(RhPb2)3 crystallizes in the orthorhombic Cmcm space group. Ba(1) is bonded in a 8-coordinate geometry to four equivalent Pb(1) and four equivalent Pb(2) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 10-coordinate geometry to three equivalent Rh(1), one Pb(4), three equivalent Pb(2), and three equivalent Pb(3) atoms. In the second Rh site, Rh(2) is bonded in a 7-coordinate geometry to one Pb(4) and six equivalent Pb(1) atoms. There are four inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 5-coordinate geometry to two equivalent Ba(1) and three equivalent Rh(2) atoms. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to two equivalent Ba(1) and three equivalent Rh(1) atoms. In the third Pb site, Pb(3) is bonded in a 6-coordinate geometry to six equivalent Rh(1) atoms. In the fourth Pb site, Pb(4) is bonded in a 3-coordinate geometry to one Rh(2) and two equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_Ba(RhPb2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.276
_cell_length_b   14.276
_cell_length_c   4.565
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   146.148
_symmetry_Int_Tables_number   1
_cell_volume   518.227
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.590  0.410  0.250  1.0
  Ba  Ba1  1  0.410  0.590  0.750  1.0
  Rh  Rh2  1  0.972  0.406  0.750  1.0
  Rh  Rh3  1  0.962  0.038  0.750  1.0
  Rh  Rh4  1  0.028  0.594  0.250  1.0
  Rh  Rh5  1  0.038  0.962  0.250  1.0
  Rh  Rh6  1  0.406  0.972  0.250  1.0
  Rh  Rh7  1  0.594  0.028  0.750  1.0
  Pb  Pb8  1  0.754  0.844  0.250  1.0
  Pb  Pb9  1  0.844  0.754  0.750  1.0
  Pb  Pb10  1  0.156  0.246  0.250  1.0
  Pb  Pb11  1  0.527  0.871  0.250  1.0
  Pb  Pb12  1  0.129  0.473  0.250  1.0
  Pb  Pb13  1  0.871  0.527  0.750  1.0
  Pb  Pb14  1  0.246  0.156  0.750  1.0
  Pb  Pb15  1  0.749  0.251  0.250  1.0
  Pb  Pb16  1  0.251  0.749  0.750  1.0
  Pb  Pb17  1  0.135  0.865  0.250  1.0
  Pb  Pb18  1  0.865  0.135  0.750  1.0
  Pb  Pb19  1  0.473  0.129  0.750  1.0
[/CIF]
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The crystal structure described by Ba(RhPb2)3 crystallizes in the orthorhombic Cmcm space group. Ba(1) is bonded in a 8-coordinate geometry to four equivalent Pb(1) and four equivalent Pb(2) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 10-coordinate geometry to three equivalent Rh(1), one Pb(4), three equivalent Pb(2), and three equivalent Pb(3) atoms. In the second Rh site, Rh(2) is bonded in a 7-coordinate geometry to one Pb(4) and six equivalent Pb(1) atoms. There are four inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 5-coordinate geometry to two equivalent Ba(1) and three equivalent Rh(2) atoms. In the second Pb site, Pb(2) is bonded in a 4-coordinate geometry to two equivalent Ba(1) and three equivalent Rh(1) atoms. In the third Pb site, Pb(3) is bonded in a 6-coordinate geometry to six equivalent Rh(1) atoms. In the fourth Pb site, Pb(4) is bonded in a 3-coordinate geometry to one Rh(2) and two equivalent Rh(1) atoms. is represented by the CIF file [CIF]
data_Ba(RhPb2)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.276
_cell_length_b   14.276
_cell_length_c   4.565
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   146.148
_symmetry_Int_Tables_number   1
_cell_volume   518.227
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ba  Ba0  1  0.590  0.410  0.250  1.0
  Ba  Ba1  1  0.410  0.590  0.750  1.0
  Rh  Rh2  1  0.972  0.406  0.750  1.0
  Rh  Rh3  1  0.962  0.038  0.750  1.0
  Rh  Rh4  1  0.028  0.594  0.250  1.0
  Rh  Rh5  1  0.038  0.962  0.250  1.0
  Rh  Rh6  1  0.406  0.972  0.250  1.0
  Rh  Rh7  1  0.594  0.028  0.750  1.0
  Pb  Pb8  1  0.754  0.844  0.250  1.0
  Pb  Pb9  1  0.844  0.754  0.750  1.0
  Pb  Pb10  1  0.156  0.246  0.250  1.0
  Pb  Pb11  1  0.527  0.871  0.250  1.0
  Pb  Pb12  1  0.129  0.473  0.250  1.0
  Pb  Pb13  1  0.871  0.527  0.750  1.0
  Pb  Pb14  1  0.246  0.156  0.750  1.0
  Pb  Pb15  1  0.749  0.251  0.250  1.0
  Pb  Pb16  1  0.251  0.749  0.750  1.0
  Pb  Pb17  1  0.135  0.865  0.250  1.0
  Pb  Pb18  1  0.865  0.135  0.750  1.0
  Pb  Pb19  1  0.473  0.129  0.750  1.0
[/CIF]
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