The material structure described by AlSn(WO4)2 is Hydrophilite-derived structured and crystallizes in the monoclinic P2/c space group. W(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form WO6 octahedra that share corners with four equivalent Al(1)O6 octahedra, corners with four equivalent Sn(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-58°. Al(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form AlO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. Sn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SnO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Al(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-58°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1), one Al(1), and one Sn(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Sn(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1), one Al(1), and one Sn(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Al(1) atom. is represented by the CIF file [CIF]
data_AlSn(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.664
_cell_length_b   5.178
_cell_length_c   10.590
_cell_angle_alpha   61.903
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   273.976
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.666  0.000  0.750  1.0
  Al  Al1  1  0.334  0.000  0.250  1.0
  Sn  Sn2  1  0.365  0.500  0.750  1.0
  Sn  Sn3  1  0.635  0.500  0.250  1.0
  W  W4  1  0.153  0.246  0.501  1.0
  W  W5  1  0.153  0.754  0.999  1.0
  W  W6  1  0.847  0.754  0.499  1.0
  W  W7  1  0.847  0.246  0.001  1.0
  O  O8  1  0.392  0.735  0.867  1.0
  O  O9  1  0.392  0.265  0.633  1.0
  O  O10  1  0.608  0.265  0.133  1.0
  O  O11  1  0.608  0.735  0.367  1.0
  O  O12  1  0.878  0.208  0.383  1.0
  O  O13  1  0.878  0.792  0.117  1.0
  O  O14  1  0.122  0.792  0.617  1.0
  O  O15  1  0.122  0.208  0.883  1.0
  O  O16  1  0.633  0.203  0.858  1.0
  O  O17  1  0.633  0.797  0.642  1.0
  O  O18  1  0.367  0.797  0.142  1.0
  O  O19  1  0.367  0.203  0.358  1.0
  O  O20  1  0.880  0.702  0.883  1.0
  O  O21  1  0.120  0.298  0.117  1.0
  O  O22  1  0.880  0.298  0.617  1.0
  O  O23  1  0.120  0.702  0.383  1.0
[/CIF]
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The material structure described by AlSn(WO4)2 is Hydrophilite-derived structured and crystallizes in the monoclinic P2/c space group. W(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form WO6 octahedra that share corners with four equivalent Al(1)O6 octahedra, corners with four equivalent Sn(1)O6 octahedra, and edges with two equivalent W(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-58°. Al(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(4) atoms to form AlO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Sn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 46-52°. Sn(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form SnO6 octahedra that share corners with eight equivalent W(1)O6 octahedra and edges with two equivalent Al(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 47-58°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(1), one Al(1), and one Sn(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Sn(1) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one W(1), one Al(1), and one Sn(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent W(1) and one Al(1) atom. is represented by the CIF file [CIF]
data_AlSn(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.664
_cell_length_b   5.178
_cell_length_c   10.590
_cell_angle_alpha   61.903
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   273.976
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.666  0.000  0.750  1.0
  Al  Al1  1  0.334  0.000  0.250  1.0
  Sn  Sn2  1  0.365  0.500  0.750  1.0
  Sn  Sn3  1  0.635  0.500  0.250  1.0
  W  W4  1  0.153  0.246  0.501  1.0
  W  W5  1  0.153  0.754  0.999  1.0
  W  W6  1  0.847  0.754  0.499  1.0
  W  W7  1  0.847  0.246  0.001  1.0
  O  O8  1  0.392  0.735  0.867  1.0
  O  O9  1  0.392  0.265  0.633  1.0
  O  O10  1  0.608  0.265  0.133  1.0
  O  O11  1  0.608  0.735  0.367  1.0
  O  O12  1  0.878  0.208  0.383  1.0
  O  O13  1  0.878  0.792  0.117  1.0
  O  O14  1  0.122  0.792  0.617  1.0
  O  O15  1  0.122  0.208  0.883  1.0
  O  O16  1  0.633  0.203  0.858  1.0
  O  O17  1  0.633  0.797  0.642  1.0
  O  O18  1  0.367  0.797  0.142  1.0
  O  O19  1  0.367  0.203  0.358  1.0
  O  O20  1  0.880  0.702  0.883  1.0
  O  O21  1  0.120  0.298  0.117  1.0
  O  O22  1  0.880  0.298  0.617  1.0
  O  O23  1  0.120  0.702  0.383  1.0
[/CIF]
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