The structure described by C2TeS2(N2Br)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four C2TeS2(N2Br)2 clusters. C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(1) is bonded in a single-bond geometry to one C(1) atom. Te(1) is bonded in a rectangular see-saw-like geometry to two equivalent S(1) and two equivalent Br(1) atoms. S(1) is bonded in a water-like geometry to one C(1) and one Te(1) atom. Br(1) is bonded in a single-bond geometry to one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeC2S2(BrN2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.090
_cell_length_b   9.090
_cell_length_c   9.968
_cell_angle_alpha   63.198
_cell_angle_beta   63.198
_cell_angle_gamma   50.667
_symmetry_Int_Tables_number   1
_cell_volume   552.146
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.110  0.890  0.250  1.0
  Te  Te1  1  0.890  0.110  0.750  1.0
  C  C2  1  0.223  0.492  0.580  1.0
  C  C3  1  0.508  0.777  0.920  1.0
  C  C4  1  0.777  0.508  0.420  1.0
  C  C5  1  0.492  0.223  0.080  1.0
  S  S6  1  0.277  0.508  0.373  1.0
  S  S7  1  0.492  0.723  0.127  1.0
  S  S8  1  0.723  0.492  0.627  1.0
  S  S9  1  0.508  0.277  0.873  1.0
  Br  Br10  1  0.767  0.972  0.446  1.0
  Br  Br11  1  0.028  0.233  0.054  1.0
  Br  Br12  1  0.233  0.028  0.554  1.0
  Br  Br13  1  0.972  0.767  0.946  1.0
  N  N14  1  0.213  0.342  0.677  1.0
  N  N15  1  0.658  0.787  0.823  1.0
  N  N16  1  0.787  0.658  0.323  1.0
  N  N17  1  0.342  0.213  0.177  1.0
  N  N18  1  0.213  0.633  0.599  1.0
  N  N19  1  0.367  0.787  0.901  1.0
  N  N20  1  0.787  0.367  0.401  1.0
  N  N21  1  0.633  0.213  0.099  1.0
[/CIF]
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The structure described by C2TeS2(N2Br)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four C2TeS2(N2Br)2 clusters. C(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one S(1) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(1) is bonded in a single-bond geometry to one C(1) atom. Te(1) is bonded in a rectangular see-saw-like geometry to two equivalent S(1) and two equivalent Br(1) atoms. S(1) is bonded in a water-like geometry to one C(1) and one Te(1) atom. Br(1) is bonded in a single-bond geometry to one Te(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_TeC2S2(BrN2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.090
_cell_length_b   9.090
_cell_length_c   9.968
_cell_angle_alpha   63.198
_cell_angle_beta   63.198
_cell_angle_gamma   50.667
_symmetry_Int_Tables_number   1
_cell_volume   552.146
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.110  0.890  0.250  1.0
  Te  Te1  1  0.890  0.110  0.750  1.0
  C  C2  1  0.223  0.492  0.580  1.0
  C  C3  1  0.508  0.777  0.920  1.0
  C  C4  1  0.777  0.508  0.420  1.0
  C  C5  1  0.492  0.223  0.080  1.0
  S  S6  1  0.277  0.508  0.373  1.0
  S  S7  1  0.492  0.723  0.127  1.0
  S  S8  1  0.723  0.492  0.627  1.0
  S  S9  1  0.508  0.277  0.873  1.0
  Br  Br10  1  0.767  0.972  0.446  1.0
  Br  Br11  1  0.028  0.233  0.054  1.0
  Br  Br12  1  0.233  0.028  0.554  1.0
  Br  Br13  1  0.972  0.767  0.946  1.0
  N  N14  1  0.213  0.342  0.677  1.0
  N  N15  1  0.658  0.787  0.823  1.0
  N  N16  1  0.787  0.658  0.323  1.0
  N  N17  1  0.342  0.213  0.177  1.0
  N  N18  1  0.213  0.633  0.599  1.0
  N  N19  1  0.367  0.787  0.901  1.0
  N  N20  1  0.787  0.367  0.401  1.0
  N  N21  1  0.633  0.213  0.099  1.0
[/CIF]
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