The crystal structure described by Os3C10SO10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Os3C10SO10 clusters. There are three inequivalent Os sites. In the first Os site, Os(1) is bonded to one C(10), one C(5), one C(7), one C(8), and one S(1) atom to form distorted edge-sharing OsC4S trigonal bipyramids. In the second Os site, Os(2) is bonded to one C(1), one C(4), one C(7), one C(9), and one S(1) atom to form distorted edge-sharing OsC4S trigonal bipyramids. In the third Os site, Os(3) is bonded to one C(2), one C(3), one C(6), one C(7), and one S(1) atom to form distorted edge-sharing OsC4S trigonal bipyramids. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Os(2) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Os(3) and one O(10) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one Os(3) and one O(4,9) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Os(2) and one O(2,8) atom. In the fifth C site, C(5) is bonded in a distorted linear geometry to one Os(1) and one O(3) atom. In the sixth C site, C(6) is bonded in a distorted linear geometry to one Os(3) and one O(4,9) atom. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one Os(1), one Os(2), one Os(3), and one O(6) atom. In the eighth C site, C(8) is bonded in a distorted linear geometry to one Os(1) and one O(7) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Os(2) and one O(2,8) atom. In the tenth C site, C(10) is bonded in a distorted linear geometry to one Os(1) and one O(5) atom. S(1) is bonded in a 3-coordinate geometry to one Os(1), one Os(2), and one Os(3) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2,8) is bonded in a single-bond geometry to one C(4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth O site, O(4,9) is bonded in a single-bond geometry to one C(6) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth O site, O(10) is bonded in a single-bond geometry to one C(2) atom. is represented by the CIF card [CIF]
data_Os3C10SO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.987
_cell_length_b   9.658
_cell_length_c   13.420
_cell_angle_alpha   82.604
_cell_angle_beta   87.629
_cell_angle_gamma   72.359
_symmetry_Int_Tables_number   1
_cell_volume   855.898
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.169  0.237  0.361  1.0
  Os  Os1  1  0.831  0.763  0.639  1.0
  Os  Os2  1  0.355  0.182  0.165  1.0
  Os  Os3  1  0.238  0.475  0.224  1.0
  Os  Os4  1  0.645  0.818  0.835  1.0
  Os  Os5  1  0.762  0.525  0.776  1.0
  C  C6  1  0.336  0.246  0.025  1.0
  C  C7  1  0.240  0.572  0.091  1.0
  C  C8  1  0.968  0.373  0.722  1.0
  C  C9  1  0.702  0.999  0.836  1.0
  C  C10  1  0.050  0.647  0.566  1.0
  C  C11  1  0.439  0.553  0.265  1.0
  C  C12  1  0.550  0.732  0.705  1.0
  C  C13  1  0.664  0.754  0.975  1.0
  C  C14  1  0.910  0.939  0.622  1.0
  C  C15  1  0.639  0.089  0.157  1.0
  C  C16  1  0.450  0.268  0.295  1.0
  C  C17  1  0.298  0.001  0.164  1.0
  C  C18  1  0.665  0.820  0.521  1.0
  C  C19  1  0.335  0.180  0.479  1.0
  C  C20  1  0.090  0.061  0.378  1.0
  C  C21  1  0.950  0.353  0.434  1.0
  C  C22  1  0.760  0.428  0.909  1.0
  C  C23  1  0.361  0.911  0.843  1.0
  C  C24  1  0.032  0.627  0.278  1.0
  C  C25  1  0.561  0.447  0.735  1.0
  S  S26  1  0.982  0.669  0.802  1.0
  S  S27  1  0.018  0.331  0.198  1.0
  O  O28  1  0.318  0.286  0.939  1.0
  O  O29  1  0.734  0.110  0.838  1.0
  O  O30  1  0.266  0.890  0.162  1.0
  O  O31  1  0.816  0.422  0.477  1.0
  O  O32  1  0.184  0.578  0.523  1.0
  O  O33  1  0.442  0.399  0.707  1.0
  O  O34  1  0.561  0.849  0.452  1.0
  O  O35  1  0.614  0.244  0.331  1.0
  O  O36  1  0.045  0.954  0.387  1.0
  O  O37  1  0.810  0.034  0.150  1.0
  O  O38  1  0.439  0.151  0.548  1.0
  O  O39  1  0.682  0.714  0.061  1.0
  O  O40  1  0.386  0.756  0.669  1.0
  O  O41  1  0.190  0.966  0.850  1.0
  O  O42  1  0.905  0.721  0.307  1.0
  O  O43  1  0.095  0.279  0.693  1.0
  O  O44  1  0.558  0.601  0.293  1.0
  O  O45  1  0.756  0.367  0.989  1.0
  O  O46  1  0.955  0.046  0.613  1.0
  O  O47  1  0.244  0.633  0.011  1.0
[/CIF]
.
The crystal structure described by Os3C10SO10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two Os3C10SO10 clusters. There are three inequivalent Os sites. In the first Os site, Os(1) is bonded to one C(10), one C(5), one C(7), one C(8), and one S(1) atom to form distorted edge-sharing OsC4S trigonal bipyramids. In the second Os site, Os(2) is bonded to one C(1), one C(4), one C(7), one C(9), and one S(1) atom to form distorted edge-sharing OsC4S trigonal bipyramids. In the third Os site, Os(3) is bonded to one C(2), one C(3), one C(6), one C(7), and one S(1) atom to form distorted edge-sharing OsC4S trigonal bipyramids. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Os(2) and one O(1) atom. In the second C site, C(2) is bonded in a linear geometry to one Os(3) and one O(10) atom. In the third C site, C(3) is bonded in a distorted linear geometry to one Os(3) and one O(4,9) atom. In the fourth C site, C(4) is bonded in a linear geometry to one Os(2) and one O(2,8) atom. In the fifth C site, C(5) is bonded in a distorted linear geometry to one Os(1) and one O(3) atom. In the sixth C site, C(6) is bonded in a distorted linear geometry to one Os(3) and one O(4,9) atom. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one Os(1), one Os(2), one Os(3), and one O(6) atom. In the eighth C site, C(8) is bonded in a distorted linear geometry to one Os(1) and one O(7) atom. In the ninth C site, C(9) is bonded in a linear geometry to one Os(2) and one O(2,8) atom. In the tenth C site, C(10) is bonded in a distorted linear geometry to one Os(1) and one O(5) atom. S(1) is bonded in a 3-coordinate geometry to one Os(1), one Os(2), and one Os(3) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2,8) is bonded in a single-bond geometry to one C(4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth O site, O(4,9) is bonded in a single-bond geometry to one C(6) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth O site, O(10) is bonded in a single-bond geometry to one C(2) atom. is represented by the CIF card [CIF]
data_Os3C10SO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.987
_cell_length_b   9.658
_cell_length_c   13.420
_cell_angle_alpha   82.604
_cell_angle_beta   87.629
_cell_angle_gamma   72.359
_symmetry_Int_Tables_number   1
_cell_volume   855.898
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Os  Os0  1  0.169  0.237  0.361  1.0
  Os  Os1  1  0.831  0.763  0.639  1.0
  Os  Os2  1  0.355  0.182  0.165  1.0
  Os  Os3  1  0.238  0.475  0.224  1.0
  Os  Os4  1  0.645  0.818  0.835  1.0
  Os  Os5  1  0.762  0.525  0.776  1.0
  C  C6  1  0.336  0.246  0.025  1.0
  C  C7  1  0.240  0.572  0.091  1.0
  C  C8  1  0.968  0.373  0.722  1.0
  C  C9  1  0.702  0.999  0.836  1.0
  C  C10  1  0.050  0.647  0.566  1.0
  C  C11  1  0.439  0.553  0.265  1.0
  C  C12  1  0.550  0.732  0.705  1.0
  C  C13  1  0.664  0.754  0.975  1.0
  C  C14  1  0.910  0.939  0.622  1.0
  C  C15  1  0.639  0.089  0.157  1.0
  C  C16  1  0.450  0.268  0.295  1.0
  C  C17  1  0.298  0.001  0.164  1.0
  C  C18  1  0.665  0.820  0.521  1.0
  C  C19  1  0.335  0.180  0.479  1.0
  C  C20  1  0.090  0.061  0.378  1.0
  C  C21  1  0.950  0.353  0.434  1.0
  C  C22  1  0.760  0.428  0.909  1.0
  C  C23  1  0.361  0.911  0.843  1.0
  C  C24  1  0.032  0.627  0.278  1.0
  C  C25  1  0.561  0.447  0.735  1.0
  S  S26  1  0.982  0.669  0.802  1.0
  S  S27  1  0.018  0.331  0.198  1.0
  O  O28  1  0.318  0.286  0.939  1.0
  O  O29  1  0.734  0.110  0.838  1.0
  O  O30  1  0.266  0.890  0.162  1.0
  O  O31  1  0.816  0.422  0.477  1.0
  O  O32  1  0.184  0.578  0.523  1.0
  O  O33  1  0.442  0.399  0.707  1.0
  O  O34  1  0.561  0.849  0.452  1.0
  O  O35  1  0.614  0.244  0.331  1.0
  O  O36  1  0.045  0.954  0.387  1.0
  O  O37  1  0.810  0.034  0.150  1.0
  O  O38  1  0.439  0.151  0.548  1.0
  O  O39  1  0.682  0.714  0.061  1.0
  O  O40  1  0.386  0.756  0.669  1.0
  O  O41  1  0.190  0.966  0.850  1.0
  O  O42  1  0.905  0.721  0.307  1.0
  O  O43  1  0.095  0.279  0.693  1.0
  O  O44  1  0.558  0.601  0.293  1.0
  O  O45  1  0.756  0.367  0.989  1.0
  O  O46  1  0.955  0.046  0.613  1.0
  O  O47  1  0.244  0.633  0.011  1.0
[/CIF]
.