The material structure described by MoAsO5 crystallizes in the orthorhombic P2_12_12_1 space group. Mo(1) is bonded in a 5-coordinate geometry to one O(1), one O(4), one O(5), and two equivalent O(2) atoms. As(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Mo(1) and one As(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mo(1) and one As(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mo(1) and one As(1) atom. is represented by the CIF card [CIF]
data_MoAsO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.632
_cell_length_b   7.695
_cell_length_c   7.845
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   400.386
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.298  0.733  0.026  1.0
  Mo  Mo1  1  0.202  0.267  0.526  1.0
  Mo  Mo2  1  0.702  0.233  0.474  1.0
  Mo  Mo3  1  0.798  0.767  0.974  1.0
  As  As4  1  0.495  0.127  0.838  1.0
  As  As5  1  0.005  0.873  0.338  1.0
  As  As6  1  0.505  0.627  0.662  1.0
  As  As7  1  0.995  0.373  0.162  1.0
  O  O8  1  0.983  0.876  0.867  1.0
  O  O9  1  0.517  0.124  0.367  1.0
  O  O10  1  0.017  0.376  0.633  1.0
  O  O11  1  0.483  0.624  0.133  1.0
  O  O12  1  0.525  0.905  0.925  1.0
  O  O13  1  0.975  0.095  0.425  1.0
  O  O14  1  0.475  0.405  0.575  1.0
  O  O15  1  0.025  0.595  0.075  1.0
  O  O16  1  0.457  0.275  0.984  1.0
  O  O17  1  0.043  0.725  0.484  1.0
  O  O18  1  0.543  0.775  0.516  1.0
  O  O19  1  0.957  0.225  0.016  1.0
  O  O20  1  0.711  0.134  0.709  1.0
  O  O21  1  0.789  0.866  0.209  1.0
  O  O22  1  0.289  0.634  0.791  1.0
  O  O23  1  0.211  0.366  0.291  1.0
  O  O24  1  0.297  0.089  0.692  1.0
  O  O25  1  0.203  0.911  0.192  1.0
  O  O26  1  0.703  0.589  0.808  1.0
  O  O27  1  0.797  0.411  0.308  1.0
[/CIF]
.
The material structure described by MoAsO5 crystallizes in the orthorhombic P2_12_12_1 space group. Mo(1) is bonded in a 5-coordinate geometry to one O(1), one O(4), one O(5), and two equivalent O(2) atoms. As(1) is bonded in a tetrahedral geometry to one O(2), one O(3), one O(4), and one O(5) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to two equivalent Mo(1) and one As(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one As(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mo(1) and one As(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mo(1) and one As(1) atom. is represented by the CIF card [CIF]
data_MoAsO5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.632
_cell_length_b   7.695
_cell_length_c   7.845
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   400.386
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.298  0.733  0.026  1.0
  Mo  Mo1  1  0.202  0.267  0.526  1.0
  Mo  Mo2  1  0.702  0.233  0.474  1.0
  Mo  Mo3  1  0.798  0.767  0.974  1.0
  As  As4  1  0.495  0.127  0.838  1.0
  As  As5  1  0.005  0.873  0.338  1.0
  As  As6  1  0.505  0.627  0.662  1.0
  As  As7  1  0.995  0.373  0.162  1.0
  O  O8  1  0.983  0.876  0.867  1.0
  O  O9  1  0.517  0.124  0.367  1.0
  O  O10  1  0.017  0.376  0.633  1.0
  O  O11  1  0.483  0.624  0.133  1.0
  O  O12  1  0.525  0.905  0.925  1.0
  O  O13  1  0.975  0.095  0.425  1.0
  O  O14  1  0.475  0.405  0.575  1.0
  O  O15  1  0.025  0.595  0.075  1.0
  O  O16  1  0.457  0.275  0.984  1.0
  O  O17  1  0.043  0.725  0.484  1.0
  O  O18  1  0.543  0.775  0.516  1.0
  O  O19  1  0.957  0.225  0.016  1.0
  O  O20  1  0.711  0.134  0.709  1.0
  O  O21  1  0.789  0.866  0.209  1.0
  O  O22  1  0.289  0.634  0.791  1.0
  O  O23  1  0.211  0.366  0.291  1.0
  O  O24  1  0.297  0.089  0.692  1.0
  O  O25  1  0.203  0.911  0.192  1.0
  O  O26  1  0.703  0.589  0.808  1.0
  O  O27  1  0.797  0.411  0.308  1.0
[/CIF]
.