The structure described by CsV(NO4)2 crystallizes in the orthorhombic P2_12_12_1 space group. Cs(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), one O(4), one O(6), one O(7), two equivalent O(5), and two equivalent O(8) atoms. V(1) is bonded to one O(1), one O(3), one O(6), and two equivalent O(2) atoms to form distorted corner-sharing VO5 trigonal bipyramids. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to two equivalent Cs(1) and one N(1) atom. In the second O site, O(6) is bonded in a bent 120 degrees geometry to one Cs(1), one V(1), and one N(2) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Cs(1) and one N(2) atom. In the fourth O site, O(8) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one N(2) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one Cs(1) and one V(1) atom. In the sixth O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the seventh O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one V(1), and one N(1) atom. In the eighth O site, O(4) is bonded in a distorted single-bond geometry to one Cs(1) and one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsV(NO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.712
_cell_length_b   8.064
_cell_length_c   15.558
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   842.107
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.751  0.649  0.343  1.0
  Cs  Cs1  1  0.749  0.351  0.843  1.0
  Cs  Cs2  1  0.251  0.851  0.657  1.0
  Cs  Cs3  1  0.249  0.149  0.157  1.0
  V  V4  1  0.350  0.311  0.477  1.0
  V  V5  1  0.150  0.689  0.977  1.0
  V  V6  1  0.850  0.189  0.523  1.0
  V  V7  1  0.650  0.811  0.023  1.0
  N  N8  1  0.132  0.627  0.159  1.0
  N  N9  1  0.368  0.373  0.659  1.0
  N  N10  1  0.632  0.873  0.841  1.0
  N  N11  1  0.868  0.127  0.341  1.0
  N  N12  1  0.373  0.989  0.391  1.0
  N  N13  1  0.127  0.011  0.891  1.0
  N  N14  1  0.873  0.511  0.609  1.0
  N  N15  1  0.627  0.489  0.109  1.0
  O  O16  1  0.313  0.469  0.416  1.0
  O  O17  1  0.187  0.531  0.916  1.0
  O  O18  1  0.813  0.031  0.584  1.0
  O  O19  1  0.687  0.969  0.084  1.0
  O  O20  1  0.615  0.286  0.487  1.0
  O  O21  1  0.885  0.714  0.987  1.0
  O  O22  1  0.115  0.214  0.513  1.0
  O  O23  1  0.385  0.786  0.013  1.0
  O  O24  1  0.835  0.046  0.414  1.0
  O  O25  1  0.665  0.954  0.914  1.0
  O  O26  1  0.335  0.454  0.586  1.0
  O  O27  1  0.165  0.546  0.086  1.0
  O  O28  1  0.091  0.778  0.154  1.0
  O  O29  1  0.409  0.222  0.654  1.0
  O  O30  1  0.591  0.722  0.846  1.0
  O  O31  1  0.909  0.278  0.346  1.0
  O  O32  1  0.143  0.546  0.226  1.0
  O  O33  1  0.357  0.454  0.726  1.0
  O  O34  1  0.643  0.954  0.774  1.0
  O  O35  1  0.857  0.046  0.274  1.0
  O  O36  1  0.659  0.649  0.125  1.0
  O  O37  1  0.841  0.351  0.625  1.0
  O  O38  1  0.159  0.851  0.875  1.0
  O  O39  1  0.341  0.149  0.375  1.0
  O  O40  1  0.405  0.944  0.466  1.0
  O  O41  1  0.095  0.056  0.966  1.0
  O  O42  1  0.905  0.556  0.534  1.0
  O  O43  1  0.595  0.444  0.034  1.0
  O  O44  1  0.368  0.895  0.327  1.0
  O  O45  1  0.132  0.105  0.827  1.0
  O  O46  1  0.868  0.605  0.673  1.0
  O  O47  1  0.632  0.395  0.173  1.0
[/CIF]
.
The structure described by CsV(NO4)2 crystallizes in the orthorhombic P2_12_12_1 space group. Cs(1) is bonded in a 9-coordinate geometry to one O(1), one O(3), one O(4), one O(6), one O(7), two equivalent O(5), and two equivalent O(8) atoms. V(1) is bonded to one O(1), one O(3), one O(6), and two equivalent O(2) atoms to form distorted corner-sharing VO5 trigonal bipyramids. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(3), one O(4), and one O(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(6), one O(7), and one O(8) atom. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to two equivalent Cs(1) and one N(1) atom. In the second O site, O(6) is bonded in a bent 120 degrees geometry to one Cs(1), one V(1), and one N(2) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Cs(1) and one N(2) atom. In the fourth O site, O(8) is bonded in a distorted single-bond geometry to two equivalent Cs(1) and one N(2) atom. In the fifth O site, O(1) is bonded in a single-bond geometry to one Cs(1) and one V(1) atom. In the sixth O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent V(1) atoms. In the seventh O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cs(1), one V(1), and one N(1) atom. In the eighth O site, O(4) is bonded in a distorted single-bond geometry to one Cs(1) and one N(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsV(NO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.712
_cell_length_b   8.064
_cell_length_c   15.558
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   842.107
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.751  0.649  0.343  1.0
  Cs  Cs1  1  0.749  0.351  0.843  1.0
  Cs  Cs2  1  0.251  0.851  0.657  1.0
  Cs  Cs3  1  0.249  0.149  0.157  1.0
  V  V4  1  0.350  0.311  0.477  1.0
  V  V5  1  0.150  0.689  0.977  1.0
  V  V6  1  0.850  0.189  0.523  1.0
  V  V7  1  0.650  0.811  0.023  1.0
  N  N8  1  0.132  0.627  0.159  1.0
  N  N9  1  0.368  0.373  0.659  1.0
  N  N10  1  0.632  0.873  0.841  1.0
  N  N11  1  0.868  0.127  0.341  1.0
  N  N12  1  0.373  0.989  0.391  1.0
  N  N13  1  0.127  0.011  0.891  1.0
  N  N14  1  0.873  0.511  0.609  1.0
  N  N15  1  0.627  0.489  0.109  1.0
  O  O16  1  0.313  0.469  0.416  1.0
  O  O17  1  0.187  0.531  0.916  1.0
  O  O18  1  0.813  0.031  0.584  1.0
  O  O19  1  0.687  0.969  0.084  1.0
  O  O20  1  0.615  0.286  0.487  1.0
  O  O21  1  0.885  0.714  0.987  1.0
  O  O22  1  0.115  0.214  0.513  1.0
  O  O23  1  0.385  0.786  0.013  1.0
  O  O24  1  0.835  0.046  0.414  1.0
  O  O25  1  0.665  0.954  0.914  1.0
  O  O26  1  0.335  0.454  0.586  1.0
  O  O27  1  0.165  0.546  0.086  1.0
  O  O28  1  0.091  0.778  0.154  1.0
  O  O29  1  0.409  0.222  0.654  1.0
  O  O30  1  0.591  0.722  0.846  1.0
  O  O31  1  0.909  0.278  0.346  1.0
  O  O32  1  0.143  0.546  0.226  1.0
  O  O33  1  0.357  0.454  0.726  1.0
  O  O34  1  0.643  0.954  0.774  1.0
  O  O35  1  0.857  0.046  0.274  1.0
  O  O36  1  0.659  0.649  0.125  1.0
  O  O37  1  0.841  0.351  0.625  1.0
  O  O38  1  0.159  0.851  0.875  1.0
  O  O39  1  0.341  0.149  0.375  1.0
  O  O40  1  0.405  0.944  0.466  1.0
  O  O41  1  0.095  0.056  0.966  1.0
  O  O42  1  0.905  0.556  0.534  1.0
  O  O43  1  0.595  0.444  0.034  1.0
  O  O44  1  0.368  0.895  0.327  1.0
  O  O45  1  0.132  0.105  0.827  1.0
  O  O46  1  0.868  0.605  0.673  1.0
  O  O47  1  0.632  0.395  0.173  1.0
[/CIF]
.