The crystal structure described by CsVZn(P3O8)2O2 crystallizes in the monoclinic C2/m space group. The structure consists of four hydrogen peroxide molecules inside a CsVZn(P3O8)2 framework. In the CsVZn(P3O8)2 framework, Cs(1) is bonded in a 8-coordinate geometry to two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. V(1) is bonded in a distorted pentagonal pyramidal geometry to two equivalent O(1), two equivalent O(4), and two equivalent O(8) atoms. Zn(1) is bonded in a bent 120 degrees geometry to two equivalent O(10) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(5) atom. In the second P site, P(2) is bonded in a bent 120 degrees geometry to one O(4) and one O(7) atom. In the third P site, P(3) is bonded in a trigonal non-coplanar geometry to one O(10), one O(6), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent P(1) atoms. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one V(1) and one P(2) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one Cs(1) and one P(1) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one Cs(1) and one P(3) atom. In the sixth O site, O(7) is bonded in a distorted single-bond geometry to one Cs(1) and one P(2) atom. In the seventh O site, O(8) is bonded in a distorted single-bond geometry to one Cs(1) and one V(1) atom. In the eighth O site, O(9) is bonded in a bent 120 degrees geometry to two equivalent P(3) atoms. In the ninth O site, O(10) is bonded in a bent 150 degrees geometry to one Zn(1) and one P(3) atom. is represented by the CIF card [CIF]
data_CsVZn(PO3)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.294
_cell_length_b   10.294
_cell_length_c   10.987
_cell_angle_alpha   66.905
_cell_angle_beta   66.905
_cell_angle_gamma   81.343
_symmetry_Int_Tables_number   1
_cell_volume   985.058
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.205  0.205  0.745  1.0
  Cs  Cs1  1  0.795  0.795  0.255  1.0
  V  V2  1  0.719  0.281  0.000  1.0
  V  V3  1  0.281  0.719  0.000  1.0
  Zn  Zn4  1  0.771  0.229  0.500  1.0
  Zn  Zn5  1  0.229  0.771  0.500  1.0
  P  P6  1  0.475  0.248  0.292  1.0
  P  P7  1  0.248  0.475  0.292  1.0
  P  P8  1  0.086  0.465  0.207  1.0
  P  P9  1  0.465  0.086  0.207  1.0
  P  P10  1  0.260  0.037  0.207  1.0
  P  P11  1  0.037  0.260  0.207  1.0
  P  P12  1  0.740  0.963  0.793  1.0
  P  P13  1  0.963  0.740  0.793  1.0
  P  P14  1  0.535  0.914  0.793  1.0
  P  P15  1  0.914  0.535  0.793  1.0
  P  P16  1  0.752  0.525  0.708  1.0
  P  P17  1  0.525  0.752  0.708  1.0
  O  O18  1  0.627  0.300  0.184  1.0
  O  O19  1  0.300  0.627  0.184  1.0
  O  O20  1  0.371  0.371  0.233  1.0
  O  O21  1  0.396  0.554  0.567  1.0
  O  O22  1  0.554  0.396  0.567  1.0
  O  O23  1  0.180  0.554  0.048  1.0
  O  O24  1  0.554  0.180  0.048  1.0
  O  O25  1  0.209  0.450  0.445  1.0
  O  O26  1  0.450  0.209  0.445  1.0
  O  O27  1  0.272  0.053  0.063  1.0
  O  O28  1  0.053  0.272  0.063  1.0
  O  O29  1  0.947  0.524  0.277  1.0
  O  O30  1  0.524  0.947  0.277  1.0
  O  O31  1  0.864  0.175  0.925  1.0
  O  O32  1  0.175  0.864  0.925  1.0
  O  O33  1  0.146  0.146  0.273  1.0
  O  O34  1  0.891  0.221  0.327  1.0
  O  O35  1  0.221  0.891  0.327  1.0
  O  O36  1  0.779  0.109  0.673  1.0
  O  O37  1  0.109  0.779  0.673  1.0
  O  O38  1  0.854  0.854  0.727  1.0
  O  O39  1  0.825  0.136  0.075  1.0
  O  O40  1  0.136  0.825  0.075  1.0
  O  O41  1  0.476  0.053  0.723  1.0
  O  O42  1  0.053  0.476  0.723  1.0
  O  O43  1  0.947  0.728  0.937  1.0
  O  O44  1  0.728  0.947  0.937  1.0
  O  O45  1  0.550  0.791  0.555  1.0
  O  O46  1  0.791  0.550  0.555  1.0
  O  O47  1  0.446  0.820  0.952  1.0
  O  O48  1  0.820  0.446  0.952  1.0
  O  O49  1  0.446  0.604  0.433  1.0
  O  O50  1  0.604  0.446  0.433  1.0
  O  O51  1  0.629  0.629  0.767  1.0
  O  O52  1  0.373  0.700  0.816  1.0
  O  O53  1  0.700  0.373  0.816  1.0
[/CIF]
.
The crystal structure described by CsVZn(P3O8)2O2 crystallizes in the monoclinic C2/m space group. The structure consists of four hydrogen peroxide molecules inside a CsVZn(P3O8)2 framework. In the CsVZn(P3O8)2 framework, Cs(1) is bonded in a 8-coordinate geometry to two equivalent O(5), two equivalent O(6), two equivalent O(7), and two equivalent O(8) atoms. V(1) is bonded in a distorted pentagonal pyramidal geometry to two equivalent O(1), two equivalent O(4), and two equivalent O(8) atoms. Zn(1) is bonded in a bent 120 degrees geometry to two equivalent O(10) atoms. There are three inequivalent P sites. In the first P site, P(1) is bonded in a trigonal non-coplanar geometry to one O(1), one O(2), and one O(5) atom. In the second P site, P(2) is bonded in a bent 120 degrees geometry to one O(4) and one O(7) atom. In the third P site, P(3) is bonded in a trigonal non-coplanar geometry to one O(10), one O(6), and one O(9) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one V(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to two equivalent P(1) atoms. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one V(1) and one P(2) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one Cs(1) and one P(1) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one Cs(1) and one P(3) atom. In the sixth O site, O(7) is bonded in a distorted single-bond geometry to one Cs(1) and one P(2) atom. In the seventh O site, O(8) is bonded in a distorted single-bond geometry to one Cs(1) and one V(1) atom. In the eighth O site, O(9) is bonded in a bent 120 degrees geometry to two equivalent P(3) atoms. In the ninth O site, O(10) is bonded in a bent 150 degrees geometry to one Zn(1) and one P(3) atom. is represented by the CIF card [CIF]
data_CsVZn(PO3)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.294
_cell_length_b   10.294
_cell_length_c   10.987
_cell_angle_alpha   66.905
_cell_angle_beta   66.905
_cell_angle_gamma   81.343
_symmetry_Int_Tables_number   1
_cell_volume   985.058
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.205  0.205  0.745  1.0
  Cs  Cs1  1  0.795  0.795  0.255  1.0
  V  V2  1  0.719  0.281  0.000  1.0
  V  V3  1  0.281  0.719  0.000  1.0
  Zn  Zn4  1  0.771  0.229  0.500  1.0
  Zn  Zn5  1  0.229  0.771  0.500  1.0
  P  P6  1  0.475  0.248  0.292  1.0
  P  P7  1  0.248  0.475  0.292  1.0
  P  P8  1  0.086  0.465  0.207  1.0
  P  P9  1  0.465  0.086  0.207  1.0
  P  P10  1  0.260  0.037  0.207  1.0
  P  P11  1  0.037  0.260  0.207  1.0
  P  P12  1  0.740  0.963  0.793  1.0
  P  P13  1  0.963  0.740  0.793  1.0
  P  P14  1  0.535  0.914  0.793  1.0
  P  P15  1  0.914  0.535  0.793  1.0
  P  P16  1  0.752  0.525  0.708  1.0
  P  P17  1  0.525  0.752  0.708  1.0
  O  O18  1  0.627  0.300  0.184  1.0
  O  O19  1  0.300  0.627  0.184  1.0
  O  O20  1  0.371  0.371  0.233  1.0
  O  O21  1  0.396  0.554  0.567  1.0
  O  O22  1  0.554  0.396  0.567  1.0
  O  O23  1  0.180  0.554  0.048  1.0
  O  O24  1  0.554  0.180  0.048  1.0
  O  O25  1  0.209  0.450  0.445  1.0
  O  O26  1  0.450  0.209  0.445  1.0
  O  O27  1  0.272  0.053  0.063  1.0
  O  O28  1  0.053  0.272  0.063  1.0
  O  O29  1  0.947  0.524  0.277  1.0
  O  O30  1  0.524  0.947  0.277  1.0
  O  O31  1  0.864  0.175  0.925  1.0
  O  O32  1  0.175  0.864  0.925  1.0
  O  O33  1  0.146  0.146  0.273  1.0
  O  O34  1  0.891  0.221  0.327  1.0
  O  O35  1  0.221  0.891  0.327  1.0
  O  O36  1  0.779  0.109  0.673  1.0
  O  O37  1  0.109  0.779  0.673  1.0
  O  O38  1  0.854  0.854  0.727  1.0
  O  O39  1  0.825  0.136  0.075  1.0
  O  O40  1  0.136  0.825  0.075  1.0
  O  O41  1  0.476  0.053  0.723  1.0
  O  O42  1  0.053  0.476  0.723  1.0
  O  O43  1  0.947  0.728  0.937  1.0
  O  O44  1  0.728  0.947  0.937  1.0
  O  O45  1  0.550  0.791  0.555  1.0
  O  O46  1  0.791  0.550  0.555  1.0
  O  O47  1  0.446  0.820  0.952  1.0
  O  O48  1  0.820  0.446  0.952  1.0
  O  O49  1  0.446  0.604  0.433  1.0
  O  O50  1  0.604  0.446  0.433  1.0
  O  O51  1  0.629  0.629  0.767  1.0
  O  O52  1  0.373  0.700  0.816  1.0
  O  O53  1  0.700  0.373  0.816  1.0
[/CIF]
.