The structure described by MoOBr5N2 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight ammonia atoms and four MoOBr5 clusters. In each MoOBr5 cluster, Mo(1) is bonded in a distorted single-bond geometry to one O(1), one Br(2), one Br(3), one Br(4), and two equivalent Br(1) atoms. O(1) is bonded in a single-bond geometry to one Mo(1) atom. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third Br site, Br(3) is bonded in a distorted single-bond geometry to one Mo(1) and one Br(4) atom. In the fourth Br site, Br(4) is bonded in a distorted single-bond geometry to one Mo(1) and one Br(3) atom. is represented by the CIF file [CIF]
data_MoBr5N2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.214
_cell_length_b   10.509
_cell_length_c   15.257
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1156.734
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.817  0.750  0.084  1.0
  Mo  Mo1  1  0.683  0.750  0.584  1.0
  Mo  Mo2  1  0.183  0.250  0.916  1.0
  Mo  Mo3  1  0.317  0.250  0.416  1.0
  Br  Br4  1  0.810  0.984  0.105  1.0
  Br  Br5  1  0.690  0.516  0.605  1.0
  Br  Br6  1  0.190  0.484  0.895  1.0
  Br  Br7  1  0.310  0.016  0.395  1.0
  Br  Br8  1  0.190  0.016  0.895  1.0
  Br  Br9  1  0.310  0.484  0.395  1.0
  Br  Br10  1  0.810  0.516  0.105  1.0
  Br  Br11  1  0.690  0.984  0.605  1.0
  Br  Br12  1  0.523  0.750  0.006  1.0
  Br  Br13  1  0.977  0.750  0.506  1.0
  Br  Br14  1  0.477  0.250  0.994  1.0
  Br  Br15  1  0.023  0.250  0.494  1.0
  Br  Br16  1  0.023  0.750  0.227  1.0
  Br  Br17  1  0.477  0.750  0.727  1.0
  Br  Br18  1  0.977  0.250  0.773  1.0
  Br  Br19  1  0.523  0.250  0.273  1.0
  Br  Br20  1  0.629  0.750  0.253  1.0
  Br  Br21  1  0.871  0.750  0.753  1.0
  Br  Br22  1  0.371  0.250  0.747  1.0
  Br  Br23  1  0.129  0.250  0.247  1.0
  N  N24  1  0.844  0.498  0.356  1.0
  N  N25  1  0.656  0.002  0.856  1.0
  N  N26  1  0.156  0.998  0.644  1.0
  N  N27  1  0.344  0.502  0.144  1.0
  N  N28  1  0.156  0.502  0.644  1.0
  N  N29  1  0.344  0.998  0.144  1.0
  N  N30  1  0.844  0.002  0.356  1.0
  N  N31  1  0.656  0.498  0.856  1.0
  O  O32  1  0.983  0.750  0.005  1.0
  O  O33  1  0.517  0.750  0.505  1.0
  O  O34  1  0.017  0.250  0.995  1.0
  O  O35  1  0.483  0.250  0.495  1.0
[/CIF]
.
The structure described by MoOBr5N2 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of eight ammonia atoms and four MoOBr5 clusters. In each MoOBr5 cluster, Mo(1) is bonded in a distorted single-bond geometry to one O(1), one Br(2), one Br(3), one Br(4), and two equivalent Br(1) atoms. O(1) is bonded in a single-bond geometry to one Mo(1) atom. There are four inequivalent Br sites. In the first Br site, Br(1) is bonded in a single-bond geometry to one Mo(1) atom. In the second Br site, Br(2) is bonded in a single-bond geometry to one Mo(1) atom. In the third Br site, Br(3) is bonded in a distorted single-bond geometry to one Mo(1) and one Br(4) atom. In the fourth Br site, Br(4) is bonded in a distorted single-bond geometry to one Mo(1) and one Br(3) atom. is represented by the CIF file [CIF]
data_MoBr5N2O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.214
_cell_length_b   10.509
_cell_length_c   15.257
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1156.734
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mo  Mo0  1  0.817  0.750  0.084  1.0
  Mo  Mo1  1  0.683  0.750  0.584  1.0
  Mo  Mo2  1  0.183  0.250  0.916  1.0
  Mo  Mo3  1  0.317  0.250  0.416  1.0
  Br  Br4  1  0.810  0.984  0.105  1.0
  Br  Br5  1  0.690  0.516  0.605  1.0
  Br  Br6  1  0.190  0.484  0.895  1.0
  Br  Br7  1  0.310  0.016  0.395  1.0
  Br  Br8  1  0.190  0.016  0.895  1.0
  Br  Br9  1  0.310  0.484  0.395  1.0
  Br  Br10  1  0.810  0.516  0.105  1.0
  Br  Br11  1  0.690  0.984  0.605  1.0
  Br  Br12  1  0.523  0.750  0.006  1.0
  Br  Br13  1  0.977  0.750  0.506  1.0
  Br  Br14  1  0.477  0.250  0.994  1.0
  Br  Br15  1  0.023  0.250  0.494  1.0
  Br  Br16  1  0.023  0.750  0.227  1.0
  Br  Br17  1  0.477  0.750  0.727  1.0
  Br  Br18  1  0.977  0.250  0.773  1.0
  Br  Br19  1  0.523  0.250  0.273  1.0
  Br  Br20  1  0.629  0.750  0.253  1.0
  Br  Br21  1  0.871  0.750  0.753  1.0
  Br  Br22  1  0.371  0.250  0.747  1.0
  Br  Br23  1  0.129  0.250  0.247  1.0
  N  N24  1  0.844  0.498  0.356  1.0
  N  N25  1  0.656  0.002  0.856  1.0
  N  N26  1  0.156  0.998  0.644  1.0
  N  N27  1  0.344  0.502  0.144  1.0
  N  N28  1  0.156  0.502  0.644  1.0
  N  N29  1  0.344  0.998  0.144  1.0
  N  N30  1  0.844  0.002  0.356  1.0
  N  N31  1  0.656  0.498  0.856  1.0
  O  O32  1  0.983  0.750  0.005  1.0
  O  O33  1  0.517  0.750  0.505  1.0
  O  O34  1  0.017  0.250  0.995  1.0
  O  O35  1  0.483  0.250  0.495  1.0
[/CIF]
.