The material described by Ho3(Pd10P3)2 crystallizes in the cubic Fm-3m space group. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded to four equivalent Pd(1) and twelve equivalent Pd(2) atoms to form distorted HoPd16 tetrahedra that share edges with six equivalent Ho(1)Pd16 tetrahedra and faces with four equivalent Ho(2)P6Pd12 cuboctahedra. In the second Ho site, Ho(2) is bonded to twelve equivalent Pd(2) and six equivalent P(1) atoms to form distorted face-sharing HoP6Pd12 cuboctahedra. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 4-coordinate geometry to one Ho(1), six equivalent Pd(2), and three equivalent P(1) atoms. In the second Pd site, Pd(2) is bonded in a 14-coordinate geometry to one Ho(2), two equivalent Ho(1), four equivalent Pd(1), five equivalent Pd(2), and two equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to one Ho(2), four equivalent Pd(1), and four equivalent Pd(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ho3(P3Pd10)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.609
_cell_length_b   8.609
_cell_length_c   8.609
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   451.149
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.250  0.250  0.250  1.0
  Ho  Ho1  1  0.750  0.750  0.750  1.0
  Ho  Ho2  1  0.000  0.000  1.000  1.0
  P  P3  1  0.737  0.263  0.263  1.0
  P  P4  1  0.263  0.737  0.737  1.0
  P  P5  1  0.263  0.737  0.263  1.0
  P  P6  1  0.737  0.263  0.737  1.0
  P  P7  1  0.263  0.263  0.737  1.0
  P  P8  1  0.737  0.737  0.263  1.0
  Pd  Pd9  1  0.384  0.384  0.384  1.0
  Pd  Pd10  1  0.616  0.616  0.616  1.0
  Pd  Pd11  1  0.384  0.384  0.848  1.0
  Pd  Pd12  1  0.384  0.848  0.384  1.0
  Pd  Pd13  1  0.616  0.616  0.152  1.0
  Pd  Pd14  1  0.616  0.152  0.616  1.0
  Pd  Pd15  1  0.848  0.384  0.384  1.0
  Pd  Pd16  1  0.152  0.616  0.616  1.0
  Pd  Pd17  1  0.345  1.000  0.000  1.0
  Pd  Pd18  1  0.655  0.000  0.000  1.0
  Pd  Pd19  1  0.000  0.345  0.655  1.0
  Pd  Pd20  1  0.000  0.655  0.345  1.0
  Pd  Pd21  1  1.000  0.345  1.000  1.0
  Pd  Pd22  1  0.655  0.000  0.345  1.0
  Pd  Pd23  1  0.000  0.655  1.000  1.0
  Pd  Pd24  1  0.345  0.000  0.655  1.0
  Pd  Pd25  1  1.000  1.000  0.345  1.0
  Pd  Pd26  1  0.000  0.000  0.655  1.0
  Pd  Pd27  1  0.655  0.345  1.000  1.0
  Pd  Pd28  1  0.345  0.655  1.000  1.0
[/CIF]
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The material described by Ho3(Pd10P3)2 crystallizes in the cubic Fm-3m space group. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded to four equivalent Pd(1) and twelve equivalent Pd(2) atoms to form distorted HoPd16 tetrahedra that share edges with six equivalent Ho(1)Pd16 tetrahedra and faces with four equivalent Ho(2)P6Pd12 cuboctahedra. In the second Ho site, Ho(2) is bonded to twelve equivalent Pd(2) and six equivalent P(1) atoms to form distorted face-sharing HoP6Pd12 cuboctahedra. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 4-coordinate geometry to one Ho(1), six equivalent Pd(2), and three equivalent P(1) atoms. In the second Pd site, Pd(2) is bonded in a 14-coordinate geometry to one Ho(2), two equivalent Ho(1), four equivalent Pd(1), five equivalent Pd(2), and two equivalent P(1) atoms. P(1) is bonded in a 9-coordinate geometry to one Ho(2), four equivalent Pd(1), and four equivalent Pd(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Ho3(P3Pd10)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.609
_cell_length_b   8.609
_cell_length_c   8.609
_cell_angle_alpha   60.000
_cell_angle_beta   60.000
_cell_angle_gamma   60.000
_symmetry_Int_Tables_number   1
_cell_volume   451.149
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.250  0.250  0.250  1.0
  Ho  Ho1  1  0.750  0.750  0.750  1.0
  Ho  Ho2  1  0.000  0.000  1.000  1.0
  P  P3  1  0.737  0.263  0.263  1.0
  P  P4  1  0.263  0.737  0.737  1.0
  P  P5  1  0.263  0.737  0.263  1.0
  P  P6  1  0.737  0.263  0.737  1.0
  P  P7  1  0.263  0.263  0.737  1.0
  P  P8  1  0.737  0.737  0.263  1.0
  Pd  Pd9  1  0.384  0.384  0.384  1.0
  Pd  Pd10  1  0.616  0.616  0.616  1.0
  Pd  Pd11  1  0.384  0.384  0.848  1.0
  Pd  Pd12  1  0.384  0.848  0.384  1.0
  Pd  Pd13  1  0.616  0.616  0.152  1.0
  Pd  Pd14  1  0.616  0.152  0.616  1.0
  Pd  Pd15  1  0.848  0.384  0.384  1.0
  Pd  Pd16  1  0.152  0.616  0.616  1.0
  Pd  Pd17  1  0.345  1.000  0.000  1.0
  Pd  Pd18  1  0.655  0.000  0.000  1.0
  Pd  Pd19  1  0.000  0.345  0.655  1.0
  Pd  Pd20  1  0.000  0.655  0.345  1.0
  Pd  Pd21  1  1.000  0.345  1.000  1.0
  Pd  Pd22  1  0.655  0.000  0.345  1.0
  Pd  Pd23  1  0.000  0.655  1.000  1.0
  Pd  Pd24  1  0.345  0.000  0.655  1.0
  Pd  Pd25  1  1.000  1.000  0.345  1.0
  Pd  Pd26  1  0.000  0.000  0.655  1.0
  Pd  Pd27  1  0.655  0.345  1.000  1.0
  Pd  Pd28  1  0.345  0.655  1.000  1.0
[/CIF]
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