The structure described by TlPb2Cl5 crystallizes in the monoclinic P2_1/c space group. Tl(1) is bonded in a 1-coordinate geometry to one Cl(3) atom. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 7-coordinate geometry to one Cl(1), two equivalent Cl(2), two equivalent Cl(4), and two equivalent Cl(5) atoms. In the second Pb site, Pb(2) is bonded in a 7-coordinate geometry to one Cl(1), one Cl(2), one Cl(5), two equivalent Cl(3), and two equivalent Cl(4) atoms. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to one Pb(1) and one Pb(2) atom. In the second Cl site, Cl(2) is bonded in a 2-coordinate geometry to one Pb(2) and two equivalent Pb(1) atoms. In the third Cl site, Cl(3) is bonded in a 3-coordinate geometry to one Tl(1) and two equivalent Pb(2) atoms. In the fourth Cl site, Cl(4) is bonded to two equivalent Pb(1) and two equivalent Pb(2) atoms to form a mixture of distorted corner and edge-sharing ClPb4 trigonal pyramids. In the fifth Cl site, Cl(5) is bonded in a 3-coordinate geometry to one Pb(2) and two equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_TlPb2Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.964
_cell_length_b   8.960
_cell_length_c   12.587
_cell_angle_alpha   89.870
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   898.172
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.953  0.512  0.832  1.0
  Tl  Tl1  1  0.453  0.488  0.668  1.0
  Tl  Tl2  1  0.047  0.488  0.168  1.0
  Tl  Tl3  1  0.547  0.512  0.332  1.0
  Pb  Pb4  1  0.508  0.007  0.324  1.0
  Pb  Pb5  1  0.008  0.993  0.176  1.0
  Pb  Pb6  1  0.492  0.993  0.676  1.0
  Pb  Pb7  1  0.992  0.007  0.824  1.0
  Pb  Pb8  1  0.566  0.253  0.006  1.0
  Pb  Pb9  1  0.066  0.747  0.494  1.0
  Pb  Pb10  1  0.434  0.747  0.994  1.0
  Pb  Pb11  1  0.934  0.253  0.506  1.0
  Cl  Cl12  1  0.845  0.776  0.313  1.0
  Cl  Cl13  1  0.345  0.224  0.187  1.0
  Cl  Cl14  1  0.155  0.224  0.687  1.0
  Cl  Cl15  1  0.655  0.776  0.813  1.0
  Cl  Cl16  1  0.813  0.230  0.279  1.0
  Cl  Cl17  1  0.313  0.770  0.221  1.0
  Cl  Cl18  1  0.187  0.770  0.721  1.0
  Cl  Cl19  1  0.687  0.230  0.779  1.0
  Cl  Cl20  1  0.675  0.540  0.083  1.0
  Cl  Cl21  1  0.175  0.460  0.417  1.0
  Cl  Cl22  1  0.325  0.460  0.917  1.0
  Cl  Cl23  1  0.825  0.540  0.583  1.0
  Cl  Cl24  1  0.835  0.958  0.599  1.0
  Cl  Cl25  1  0.335  0.042  0.901  1.0
  Cl  Cl26  1  0.165  0.042  0.401  1.0
  Cl  Cl27  1  0.665  0.958  0.099  1.0
  Cl  Cl28  1  0.958  0.218  0.002  1.0
  Cl  Cl29  1  0.458  0.782  0.498  1.0
  Cl  Cl30  1  0.042  0.782  0.998  1.0
  Cl  Cl31  1  0.542  0.218  0.502  1.0
[/CIF]
.
The structure described by TlPb2Cl5 crystallizes in the monoclinic P2_1/c space group. Tl(1) is bonded in a 1-coordinate geometry to one Cl(3) atom. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a 7-coordinate geometry to one Cl(1), two equivalent Cl(2), two equivalent Cl(4), and two equivalent Cl(5) atoms. In the second Pb site, Pb(2) is bonded in a 7-coordinate geometry to one Cl(1), one Cl(2), one Cl(5), two equivalent Cl(3), and two equivalent Cl(4) atoms. There are five inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a water-like geometry to one Pb(1) and one Pb(2) atom. In the second Cl site, Cl(2) is bonded in a 2-coordinate geometry to one Pb(2) and two equivalent Pb(1) atoms. In the third Cl site, Cl(3) is bonded in a 3-coordinate geometry to one Tl(1) and two equivalent Pb(2) atoms. In the fourth Cl site, Cl(4) is bonded to two equivalent Pb(1) and two equivalent Pb(2) atoms to form a mixture of distorted corner and edge-sharing ClPb4 trigonal pyramids. In the fifth Cl site, Cl(5) is bonded in a 3-coordinate geometry to one Pb(2) and two equivalent Pb(1) atoms. is represented by the CIF card [CIF]
data_TlPb2Cl5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.964
_cell_length_b   8.960
_cell_length_c   12.587
_cell_angle_alpha   89.870
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   898.172
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.953  0.512  0.832  1.0
  Tl  Tl1  1  0.453  0.488  0.668  1.0
  Tl  Tl2  1  0.047  0.488  0.168  1.0
  Tl  Tl3  1  0.547  0.512  0.332  1.0
  Pb  Pb4  1  0.508  0.007  0.324  1.0
  Pb  Pb5  1  0.008  0.993  0.176  1.0
  Pb  Pb6  1  0.492  0.993  0.676  1.0
  Pb  Pb7  1  0.992  0.007  0.824  1.0
  Pb  Pb8  1  0.566  0.253  0.006  1.0
  Pb  Pb9  1  0.066  0.747  0.494  1.0
  Pb  Pb10  1  0.434  0.747  0.994  1.0
  Pb  Pb11  1  0.934  0.253  0.506  1.0
  Cl  Cl12  1  0.845  0.776  0.313  1.0
  Cl  Cl13  1  0.345  0.224  0.187  1.0
  Cl  Cl14  1  0.155  0.224  0.687  1.0
  Cl  Cl15  1  0.655  0.776  0.813  1.0
  Cl  Cl16  1  0.813  0.230  0.279  1.0
  Cl  Cl17  1  0.313  0.770  0.221  1.0
  Cl  Cl18  1  0.187  0.770  0.721  1.0
  Cl  Cl19  1  0.687  0.230  0.779  1.0
  Cl  Cl20  1  0.675  0.540  0.083  1.0
  Cl  Cl21  1  0.175  0.460  0.417  1.0
  Cl  Cl22  1  0.325  0.460  0.917  1.0
  Cl  Cl23  1  0.825  0.540  0.583  1.0
  Cl  Cl24  1  0.835  0.958  0.599  1.0
  Cl  Cl25  1  0.335  0.042  0.901  1.0
  Cl  Cl26  1  0.165  0.042  0.401  1.0
  Cl  Cl27  1  0.665  0.958  0.099  1.0
  Cl  Cl28  1  0.958  0.218  0.002  1.0
  Cl  Cl29  1  0.458  0.782  0.498  1.0
  Cl  Cl30  1  0.042  0.782  0.998  1.0
  Cl  Cl31  1  0.542  0.218  0.502  1.0
[/CIF]
.