The material described by (Ag2(AsS2)3)2N2 crystallizes in the monoclinic P2_1/c space group. The structure consists of four ammonia atoms inside a Ag2(AsS2)3 framework. In the Ag2(AsS2)3 framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal planar geometry to one S(1), one S(2), and one S(3) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one S(1), one S(2), one S(3), and one S(5) atom. There are three inequivalent As sites. In the first As site, As(1) is bonded in a distorted trigonal non-coplanar geometry to one S(1), one S(4), and one S(6) atom. In the second As site, As(2) is bonded in a distorted trigonal non-coplanar geometry to one S(2), one S(4), and one S(5) atom. In the third As site, As(3) is bonded in a trigonal non-coplanar geometry to one S(3), one S(5), and one S(6) atom. There are six inequivalent S sites. In the first S site, S(4) is bonded in an L-shaped geometry to one As(1) and one As(2) atom. In the second S site, S(5) is bonded in a distorted T-shaped geometry to one Ag(2), one As(2), and one As(3) atom. In the third S site, S(6) is bonded in an L-shaped geometry to one As(1) and one As(3) atom. In the fourth S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one As(1) atom. In the fifth S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one As(2) atom. In the sixth S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one As(3) atom. is represented by the CIF file [CIF]
data_Ag2As3S6N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.288
_cell_length_b   9.755
_cell_length_c   19.304
_cell_angle_alpha   61.068
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1201.173
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.981  0.158  0.001  1.0
  Ag  Ag1  1  0.519  0.158  0.501  1.0
  Ag  Ag2  1  0.019  0.842  0.999  1.0
  Ag  Ag3  1  0.481  0.842  0.499  1.0
  Ag  Ag4  1  0.465  0.125  0.900  1.0
  Ag  Ag5  1  0.035  0.125  0.400  1.0
  Ag  Ag6  1  0.535  0.875  0.100  1.0
  Ag  Ag7  1  0.965  0.875  0.600  1.0
  As  As8  1  0.401  0.453  0.915  1.0
  As  As9  1  0.099  0.453  0.415  1.0
  As  As10  1  0.599  0.547  0.085  1.0
  As  As11  1  0.901  0.547  0.585  1.0
  As  As12  1  0.384  0.706  0.721  1.0
  As  As13  1  0.116  0.706  0.221  1.0
  As  As14  1  0.616  0.294  0.279  1.0
  As  As15  1  0.884  0.294  0.779  1.0
  As  As16  1  0.346  0.832  0.852  1.0
  As  As17  1  0.154  0.832  0.352  1.0
  As  As18  1  0.654  0.168  0.148  1.0
  As  As19  1  0.846  0.168  0.648  1.0
  S  S20  1  0.313  0.204  0.003  1.0
  S  S21  1  0.187  0.204  0.503  1.0
  S  S22  1  0.687  0.796  0.997  1.0
  S  S23  1  0.813  0.796  0.497  1.0
  S  S24  1  0.251  0.735  0.610  1.0
  S  S25  1  0.249  0.735  0.110  1.0
  S  S26  1  0.749  0.265  0.390  1.0
  S  S27  1  0.751  0.265  0.890  1.0
  S  S28  1  0.196  0.008  0.873  1.0
  S  S29  1  0.304  0.008  0.373  1.0
  S  S30  1  0.804  0.992  0.127  1.0
  S  S31  1  0.696  0.992  0.627  1.0
  S  S32  1  0.243  0.471  0.808  1.0
  S  S33  1  0.257  0.471  0.308  1.0
  S  S34  1  0.757  0.529  0.192  1.0
  S  S35  1  0.743  0.529  0.692  1.0
  S  S36  1  0.195  0.881  0.735  1.0
  S  S37  1  0.305  0.881  0.235  1.0
  S  S38  1  0.805  0.119  0.265  1.0
  S  S39  1  0.695  0.119  0.765  1.0
  S  S40  1  0.213  0.606  0.950  1.0
  S  S41  1  0.287  0.606  0.450  1.0
  S  S42  1  0.787  0.394  0.050  1.0
  S  S43  1  0.713  0.394  0.550  1.0
  N  N44  1  0.693  0.677  0.335  1.0
  N  N45  1  0.807  0.677  0.835  1.0
  N  N46  1  0.307  0.323  0.665  1.0
  N  N47  1  0.193  0.323  0.165  1.0
[/CIF]
.
The material described by (Ag2(AsS2)3)2N2 crystallizes in the monoclinic P2_1/c space group. The structure consists of four ammonia atoms inside a Ag2(AsS2)3 framework. In the Ag2(AsS2)3 framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal planar geometry to one S(1), one S(2), and one S(3) atom. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one S(1), one S(2), one S(3), and one S(5) atom. There are three inequivalent As sites. In the first As site, As(1) is bonded in a distorted trigonal non-coplanar geometry to one S(1), one S(4), and one S(6) atom. In the second As site, As(2) is bonded in a distorted trigonal non-coplanar geometry to one S(2), one S(4), and one S(5) atom. In the third As site, As(3) is bonded in a trigonal non-coplanar geometry to one S(3), one S(5), and one S(6) atom. There are six inequivalent S sites. In the first S site, S(4) is bonded in an L-shaped geometry to one As(1) and one As(2) atom. In the second S site, S(5) is bonded in a distorted T-shaped geometry to one Ag(2), one As(2), and one As(3) atom. In the third S site, S(6) is bonded in an L-shaped geometry to one As(1) and one As(3) atom. In the fourth S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one As(1) atom. In the fifth S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one As(2) atom. In the sixth S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one As(3) atom. is represented by the CIF file [CIF]
data_Ag2As3S6N
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.288
_cell_length_b   9.755
_cell_length_c   19.304
_cell_angle_alpha   61.068
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   1201.173
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.981  0.158  0.001  1.0
  Ag  Ag1  1  0.519  0.158  0.501  1.0
  Ag  Ag2  1  0.019  0.842  0.999  1.0
  Ag  Ag3  1  0.481  0.842  0.499  1.0
  Ag  Ag4  1  0.465  0.125  0.900  1.0
  Ag  Ag5  1  0.035  0.125  0.400  1.0
  Ag  Ag6  1  0.535  0.875  0.100  1.0
  Ag  Ag7  1  0.965  0.875  0.600  1.0
  As  As8  1  0.401  0.453  0.915  1.0
  As  As9  1  0.099  0.453  0.415  1.0
  As  As10  1  0.599  0.547  0.085  1.0
  As  As11  1  0.901  0.547  0.585  1.0
  As  As12  1  0.384  0.706  0.721  1.0
  As  As13  1  0.116  0.706  0.221  1.0
  As  As14  1  0.616  0.294  0.279  1.0
  As  As15  1  0.884  0.294  0.779  1.0
  As  As16  1  0.346  0.832  0.852  1.0
  As  As17  1  0.154  0.832  0.352  1.0
  As  As18  1  0.654  0.168  0.148  1.0
  As  As19  1  0.846  0.168  0.648  1.0
  S  S20  1  0.313  0.204  0.003  1.0
  S  S21  1  0.187  0.204  0.503  1.0
  S  S22  1  0.687  0.796  0.997  1.0
  S  S23  1  0.813  0.796  0.497  1.0
  S  S24  1  0.251  0.735  0.610  1.0
  S  S25  1  0.249  0.735  0.110  1.0
  S  S26  1  0.749  0.265  0.390  1.0
  S  S27  1  0.751  0.265  0.890  1.0
  S  S28  1  0.196  0.008  0.873  1.0
  S  S29  1  0.304  0.008  0.373  1.0
  S  S30  1  0.804  0.992  0.127  1.0
  S  S31  1  0.696  0.992  0.627  1.0
  S  S32  1  0.243  0.471  0.808  1.0
  S  S33  1  0.257  0.471  0.308  1.0
  S  S34  1  0.757  0.529  0.192  1.0
  S  S35  1  0.743  0.529  0.692  1.0
  S  S36  1  0.195  0.881  0.735  1.0
  S  S37  1  0.305  0.881  0.235  1.0
  S  S38  1  0.805  0.119  0.265  1.0
  S  S39  1  0.695  0.119  0.765  1.0
  S  S40  1  0.213  0.606  0.950  1.0
  S  S41  1  0.287  0.606  0.450  1.0
  S  S42  1  0.787  0.394  0.050  1.0
  S  S43  1  0.713  0.394  0.550  1.0
  N  N44  1  0.693  0.677  0.335  1.0
  N  N45  1  0.807  0.677  0.835  1.0
  N  N46  1  0.307  0.323  0.665  1.0
  N  N47  1  0.193  0.323  0.165  1.0
[/CIF]
.