The material described by AgZnF3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Ag(1) is bonded to six equivalent F(1) atoms to form distorted AgF6 octahedra that share corners with nine equivalent Zn(1)F6 octahedra, edges with three equivalent Ag(1)F6 octahedra, and  a faceface with one Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 38-59°. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with nine equivalent Ag(1)F6 octahedra, edges with three equivalent Zn(1)F6 octahedra, and  a faceface with one Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 38-59°. F(1) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Zn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnAgF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.268
_cell_length_b   6.268
_cell_length_c   6.268
_cell_angle_alpha   51.095
_cell_angle_beta   51.095
_cell_angle_gamma   51.095
_symmetry_Int_Tables_number   1
_cell_volume   137.554
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.659  0.659  0.659  1.0
  Zn  Zn1  1  0.341  0.341  0.341  1.0
  Ag  Ag2  1  0.857  0.857  0.857  1.0
  Ag  Ag3  1  0.143  0.143  0.143  1.0
  F  F4  1  0.692  0.060  0.458  1.0
  F  F5  1  0.458  0.692  0.060  1.0
  F  F6  1  0.060  0.458  0.692  1.0
  F  F7  1  0.308  0.940  0.542  1.0
  F  F8  1  0.940  0.542  0.308  1.0
  F  F9  1  0.542  0.308  0.940  1.0
[/CIF]
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The material described by AgZnF3 is Ilmenite structured and crystallizes in the trigonal R-3 space group. Ag(1) is bonded to six equivalent F(1) atoms to form distorted AgF6 octahedra that share corners with nine equivalent Zn(1)F6 octahedra, edges with three equivalent Ag(1)F6 octahedra, and  a faceface with one Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 38-59°. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with nine equivalent Ag(1)F6 octahedra, edges with three equivalent Zn(1)F6 octahedra, and  a faceface with one Ag(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 38-59°. F(1) is bonded in a 4-coordinate geometry to two equivalent Ag(1) and two equivalent Zn(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnAgF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.268
_cell_length_b   6.268
_cell_length_c   6.268
_cell_angle_alpha   51.095
_cell_angle_beta   51.095
_cell_angle_gamma   51.095
_symmetry_Int_Tables_number   1
_cell_volume   137.554
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.659  0.659  0.659  1.0
  Zn  Zn1  1  0.341  0.341  0.341  1.0
  Ag  Ag2  1  0.857  0.857  0.857  1.0
  Ag  Ag3  1  0.143  0.143  0.143  1.0
  F  F4  1  0.692  0.060  0.458  1.0
  F  F5  1  0.458  0.692  0.060  1.0
  F  F6  1  0.060  0.458  0.692  1.0
  F  F7  1  0.308  0.940  0.542  1.0
  F  F8  1  0.940  0.542  0.308  1.0
  F  F9  1  0.542  0.308  0.940  1.0
[/CIF]
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