The compound described by Ce(PtP)2 crystallizes in the tetragonal I4/mmm space group. Ce(1) is bonded in a 16-coordinate geometry to four equivalent Pt(1), four equivalent Pt(2), four equivalent P(1), and four equivalent P(2) atoms. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 5-coordinate geometry to four equivalent Ce(1), one P(1), and four equivalent P(2) atoms. In the second Pt site, Pt(2) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent P(1) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 10-coordinate geometry to four equivalent Ce(1), one Pt(1), four equivalent Pt(2), and one P(1) atom. In the second P site, P(2) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Pt(1) atoms. is represented by the CIF file [CIF]
data_Ce(PPt)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.100
_cell_length_b   10.100
_cell_length_c   10.100
_cell_angle_alpha   155.417
_cell_angle_beta   155.417
_cell_angle_gamma   35.043
_symmetry_Int_Tables_number   1
_cell_volume   178.126
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.373  0.373  0.000  1.0
  Ce  Ce1  1  0.627  0.627  0.000  1.0
  P  P2  1  0.070  0.070  0.000  1.0
  P  P3  1  0.930  0.930  0.000  1.0
  P  P4  1  0.750  0.250  0.500  1.0
  P  P5  1  0.250  0.750  0.500  1.0
  Pt  Pt6  1  0.193  0.193  0.000  1.0
  Pt  Pt7  1  0.807  0.807  0.000  1.0
  Pt  Pt8  1  0.500  0.000  0.500  1.0
  Pt  Pt9  1  0.000  0.500  0.500  1.0
[/CIF]
.
The compound described by Ce(PtP)2 crystallizes in the tetragonal I4/mmm space group. Ce(1) is bonded in a 16-coordinate geometry to four equivalent Pt(1), four equivalent Pt(2), four equivalent P(1), and four equivalent P(2) atoms. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 5-coordinate geometry to four equivalent Ce(1), one P(1), and four equivalent P(2) atoms. In the second Pt site, Pt(2) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent P(1) atoms. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 10-coordinate geometry to four equivalent Ce(1), one Pt(1), four equivalent Pt(2), and one P(1) atom. In the second P site, P(2) is bonded in a 8-coordinate geometry to four equivalent Ce(1) and four equivalent Pt(1) atoms. is represented by the CIF file [CIF]
data_Ce(PPt)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.100
_cell_length_b   10.100
_cell_length_c   10.100
_cell_angle_alpha   155.417
_cell_angle_beta   155.417
_cell_angle_gamma   35.043
_symmetry_Int_Tables_number   1
_cell_volume   178.126
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.373  0.373  0.000  1.0
  Ce  Ce1  1  0.627  0.627  0.000  1.0
  P  P2  1  0.070  0.070  0.000  1.0
  P  P3  1  0.930  0.930  0.000  1.0
  P  P4  1  0.750  0.250  0.500  1.0
  P  P5  1  0.250  0.750  0.500  1.0
  Pt  Pt6  1  0.193  0.193  0.000  1.0
  Pt  Pt7  1  0.807  0.807  0.000  1.0
  Pt  Pt8  1  0.500  0.000  0.500  1.0
  Pt  Pt9  1  0.000  0.500  0.500  1.0
[/CIF]
.