The compound described by CNSF5 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four cyanopentafluorosulfur molecules. C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. N(1) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted square pyramidal geometry to one C(1), one F(1), one F(2), one F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_CSNF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.049
_cell_length_b   8.597
_cell_length_c   9.733
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   506.152
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.250  0.026  0.358  1.0
  C  C1  1  0.750  0.526  0.142  1.0
  C  C2  1  0.250  0.474  0.858  1.0
  C  C3  1  0.750  0.974  0.642  1.0
  S  S4  1  0.250  0.928  0.199  1.0
  S  S5  1  0.250  0.572  0.699  1.0
  S  S6  1  0.750  0.072  0.801  1.0
  S  S7  1  0.750  0.428  0.301  1.0
  N  N8  1  0.250  0.408  0.963  1.0
  N  N9  1  0.750  0.908  0.537  1.0
  N  N10  1  0.250  0.092  0.463  1.0
  N  N11  1  0.750  0.592  0.037  1.0
  F  F12  1  0.250  0.092  0.120  1.0
  F  F13  1  0.250  0.839  0.056  1.0
  F  F14  1  0.250  0.764  0.278  1.0
  F  F15  1  0.015  0.428  0.301  1.0
  F  F16  1  0.250  0.661  0.556  1.0
  F  F17  1  0.750  0.592  0.380  1.0
  F  F18  1  0.250  0.408  0.620  1.0
  F  F19  1  0.985  0.928  0.199  1.0
  F  F20  1  0.015  0.072  0.801  1.0
  F  F21  1  0.985  0.572  0.699  1.0
  F  F22  1  0.515  0.572  0.699  1.0
  F  F23  1  0.485  0.072  0.801  1.0
  F  F24  1  0.750  0.339  0.444  1.0
  F  F25  1  0.485  0.428  0.301  1.0
  F  F26  1  0.750  0.161  0.944  1.0
  F  F27  1  0.750  0.236  0.722  1.0
  F  F28  1  0.515  0.928  0.199  1.0
  F  F29  1  0.750  0.264  0.222  1.0
  F  F30  1  0.250  0.736  0.778  1.0
  F  F31  1  0.750  0.908  0.880  1.0
[/CIF]
.
The compound described by CNSF5 is beta Np structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four cyanopentafluorosulfur molecules. C(1) is bonded in a distorted linear geometry to one N(1) and one S(1) atom. N(1) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted square pyramidal geometry to one C(1), one F(1), one F(2), one F(3), and two equivalent F(4) atoms. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one S(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one S(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one S(1) atom. is represented by the CIF card [CIF]
data_CSNF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.049
_cell_length_b   8.597
_cell_length_c   9.733
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   506.152
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  C  C0  1  0.250  0.026  0.358  1.0
  C  C1  1  0.750  0.526  0.142  1.0
  C  C2  1  0.250  0.474  0.858  1.0
  C  C3  1  0.750  0.974  0.642  1.0
  S  S4  1  0.250  0.928  0.199  1.0
  S  S5  1  0.250  0.572  0.699  1.0
  S  S6  1  0.750  0.072  0.801  1.0
  S  S7  1  0.750  0.428  0.301  1.0
  N  N8  1  0.250  0.408  0.963  1.0
  N  N9  1  0.750  0.908  0.537  1.0
  N  N10  1  0.250  0.092  0.463  1.0
  N  N11  1  0.750  0.592  0.037  1.0
  F  F12  1  0.250  0.092  0.120  1.0
  F  F13  1  0.250  0.839  0.056  1.0
  F  F14  1  0.250  0.764  0.278  1.0
  F  F15  1  0.015  0.428  0.301  1.0
  F  F16  1  0.250  0.661  0.556  1.0
  F  F17  1  0.750  0.592  0.380  1.0
  F  F18  1  0.250  0.408  0.620  1.0
  F  F19  1  0.985  0.928  0.199  1.0
  F  F20  1  0.015  0.072  0.801  1.0
  F  F21  1  0.985  0.572  0.699  1.0
  F  F22  1  0.515  0.572  0.699  1.0
  F  F23  1  0.485  0.072  0.801  1.0
  F  F24  1  0.750  0.339  0.444  1.0
  F  F25  1  0.485  0.428  0.301  1.0
  F  F26  1  0.750  0.161  0.944  1.0
  F  F27  1  0.750  0.236  0.722  1.0
  F  F28  1  0.515  0.928  0.199  1.0
  F  F29  1  0.750  0.264  0.222  1.0
  F  F30  1  0.250  0.736  0.778  1.0
  F  F31  1  0.750  0.908  0.880  1.0
[/CIF]
.