The structure described by PuWB4 crystallizes in the orthorhombic Pbam space group. Pu(1) is bonded in a 18-coordinate geometry to four equivalent W(1), two equivalent B(3), four equivalent B(1), four equivalent B(2), and four equivalent B(4) atoms. W(1) is bonded in a 10-coordinate geometry to four equivalent Pu(1), two equivalent B(1), two equivalent B(2), two equivalent B(4), and four equivalent B(3) atoms. There are four inequivalent B sites. In the first B site, B(1) is bonded in a 9-coordinate geometry to four equivalent Pu(1), two equivalent W(1), one B(2), and two equivalent B(4) atoms. In the second B site, B(2) is bonded in a 9-coordinate geometry to four equivalent Pu(1), two equivalent W(1), one B(1), one B(2), and one B(3) atom. In the third B site, B(3) is bonded in a 9-coordinate geometry to two equivalent Pu(1), four equivalent W(1), one B(2), one B(3), and one B(4) atom. In the fourth B site, B(4) is bonded in a 9-coordinate geometry to four equivalent Pu(1), two equivalent W(1), one B(3), and two equivalent B(1) atoms. is represented by the CIF file [CIF]
data_PuB4W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.626
_cell_length_b   6.024
_cell_length_c   11.710
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   255.815
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.000  0.625  0.350  1.0
  Pu  Pu1  1  0.000  0.375  0.650  1.0
  Pu  Pu2  1  0.000  0.125  0.150  1.0
  Pu  Pu3  1  0.000  0.875  0.850  1.0
  B  B4  1  0.500  0.786  0.187  1.0
  B  B5  1  0.500  0.214  0.813  1.0
  B  B6  1  0.500  0.286  0.313  1.0
  B  B7  1  0.500  0.714  0.687  1.0
  B  B8  1  0.500  0.866  0.032  1.0
  B  B9  1  0.500  0.134  0.968  1.0
  B  B10  1  0.500  0.366  0.468  1.0
  B  B11  1  0.500  0.634  0.532  1.0
  B  B12  1  0.500  0.884  0.453  1.0
  B  B13  1  0.500  0.116  0.547  1.0
  B  B14  1  0.500  0.384  0.047  1.0
  B  B15  1  0.500  0.616  0.953  1.0
  B  B16  1  0.500  0.973  0.307  1.0
  B  B17  1  0.500  0.027  0.693  1.0
  B  B18  1  0.500  0.473  0.193  1.0
  B  B19  1  0.500  0.527  0.807  1.0
  W  W20  1  0.000  0.632  0.086  1.0
  W  W21  1  0.000  0.368  0.914  1.0
  W  W22  1  0.000  0.132  0.414  1.0
  W  W23  1  0.000  0.868  0.586  1.0
[/CIF]
.
The structure described by PuWB4 crystallizes in the orthorhombic Pbam space group. Pu(1) is bonded in a 18-coordinate geometry to four equivalent W(1), two equivalent B(3), four equivalent B(1), four equivalent B(2), and four equivalent B(4) atoms. W(1) is bonded in a 10-coordinate geometry to four equivalent Pu(1), two equivalent B(1), two equivalent B(2), two equivalent B(4), and four equivalent B(3) atoms. There are four inequivalent B sites. In the first B site, B(1) is bonded in a 9-coordinate geometry to four equivalent Pu(1), two equivalent W(1), one B(2), and two equivalent B(4) atoms. In the second B site, B(2) is bonded in a 9-coordinate geometry to four equivalent Pu(1), two equivalent W(1), one B(1), one B(2), and one B(3) atom. In the third B site, B(3) is bonded in a 9-coordinate geometry to two equivalent Pu(1), four equivalent W(1), one B(2), one B(3), and one B(4) atom. In the fourth B site, B(4) is bonded in a 9-coordinate geometry to four equivalent Pu(1), two equivalent W(1), one B(3), and two equivalent B(1) atoms. is represented by the CIF file [CIF]
data_PuB4W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.626
_cell_length_b   6.024
_cell_length_c   11.710
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   255.815
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pu  Pu0  1  0.000  0.625  0.350  1.0
  Pu  Pu1  1  0.000  0.375  0.650  1.0
  Pu  Pu2  1  0.000  0.125  0.150  1.0
  Pu  Pu3  1  0.000  0.875  0.850  1.0
  B  B4  1  0.500  0.786  0.187  1.0
  B  B5  1  0.500  0.214  0.813  1.0
  B  B6  1  0.500  0.286  0.313  1.0
  B  B7  1  0.500  0.714  0.687  1.0
  B  B8  1  0.500  0.866  0.032  1.0
  B  B9  1  0.500  0.134  0.968  1.0
  B  B10  1  0.500  0.366  0.468  1.0
  B  B11  1  0.500  0.634  0.532  1.0
  B  B12  1  0.500  0.884  0.453  1.0
  B  B13  1  0.500  0.116  0.547  1.0
  B  B14  1  0.500  0.384  0.047  1.0
  B  B15  1  0.500  0.616  0.953  1.0
  B  B16  1  0.500  0.973  0.307  1.0
  B  B17  1  0.500  0.027  0.693  1.0
  B  B18  1  0.500  0.473  0.193  1.0
  B  B19  1  0.500  0.527  0.807  1.0
  W  W20  1  0.000  0.632  0.086  1.0
  W  W21  1  0.000  0.368  0.914  1.0
  W  W22  1  0.000  0.132  0.414  1.0
  W  W23  1  0.000  0.868  0.586  1.0
[/CIF]
.