The material described by K11In6Bi9 crystallizes in the triclinic P-1 space group. There are twelve inequivalent K sites. In the first K site, K(1) is bonded in a 9-coordinate geometry to one In(2), one In(3), one In(4), one Bi(1), one Bi(4), one Bi(5), one Bi(6), one Bi(8), and one Bi(9) atom. In the second K site, K(2) is bonded in a 8-coordinate geometry to one In(3), one In(5), one Bi(1), one Bi(3), one Bi(5), one Bi(7), one Bi(8), and one Bi(9) atom. In the third K site, K(3) is bonded in a 8-coordinate geometry to one In(5), one In(6), one Bi(2), one Bi(3), one Bi(5), one Bi(6), one Bi(7), and one Bi(8) atom. In the fourth K site, K(4) is bonded in a 4-coordinate geometry to one In(4), one Bi(1), one Bi(4), one Bi(9), and two equivalent Bi(7) atoms. In the fifth K site, K(5) is bonded in a 7-coordinate geometry to one K(11), one In(1), one In(6), one Bi(1), one Bi(2), one Bi(6), one Bi(7), and one Bi(8) atom. In the sixth K site, K(6) is bonded in a 9-coordinate geometry to one In(2), one In(4), one In(5), one Bi(2), one Bi(4), one Bi(5), one Bi(7), one Bi(8), and one Bi(9) atom. In the seventh K site, K(7) is bonded in a 5-coordinate geometry to one In(1), one In(2), one Bi(6), one Bi(9), and two equivalent Bi(4) atoms. In the eighth K site, K(8) is bonded in a 7-coordinate geometry to one In(1), one In(6), one Bi(1), one Bi(3), one Bi(4), and two equivalent Bi(9) atoms. In the ninth K site, K(9) is bonded in a 8-coordinate geometry to one In(1), one In(3), one Bi(1), one Bi(2), one Bi(3), one Bi(5), one Bi(6), and one Bi(8) atom. In the tenth K site, K(10) is bonded in a 5-coordinate geometry to one Bi(2), one Bi(3), one Bi(4), one Bi(5), and one Bi(6) atom. In the eleventh K site, K(11) is bonded in a 10-coordinate geometry to two equivalent K(5), two equivalent In(2), two equivalent Bi(2), two equivalent Bi(6), and two equivalent Bi(8) atoms. In the twelfth K site, K(12) is bonded in a 8-coordinate geometry to two equivalent In(1), two equivalent In(2), two equivalent Bi(2), and two equivalent Bi(9) atoms. There are six inequivalent In sites. In the first In site, In(1) is bonded in a 9-coordinate geometry to one K(12), one K(5), one K(7), one K(8), one K(9), one Bi(1), one Bi(2), one Bi(3), and one Bi(9) atom. In the second In site, In(2) is bonded in a 9-coordinate geometry to one K(1), one K(11), one K(12), one K(6), one K(7), one Bi(2), one Bi(6), one Bi(8), and one Bi(9) atom. In the third In site, In(3) is bonded in a 7-coordinate geometry to one K(1), one K(2), one K(9), one In(3), one Bi(1), one Bi(5), and one Bi(8) atom. In the fourth In site, In(4) is bonded in a 5-coordinate geometry to one K(1), one K(4), one K(6), one Bi(1), one Bi(4), one Bi(5), and one Bi(7) atom. In the fifth In site, In(5) is bonded in a 7-coordinate geometry to one K(2), one K(3), one K(6), one In(5), one Bi(5), one Bi(7), and one Bi(8) atom. In the sixth In site, In(6) is bonded in a 4-coordinate geometry to one K(3), one K(5), one K(8), one Bi(3), one Bi(4), one Bi(6), and one Bi(7) atom. There are nine inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 9-coordinate geometry to one K(1), one K(2), one K(4), one K(5), one K(8), one K(9), one In(1), one In(3), and one In(4) atom. In the second Bi site, Bi(2) is bonded in a 9-coordinate geometry to one K(10), one K(11), one K(12), one K(3), one K(5), one K(6), one K(9), one In(1), and one In(2) atom. In the third Bi site, Bi(3) is bonded in a distorted pentagonal bipyramidal geometry to one K(10), one K(2), one K(3), one K(8), one K(9), one In(1), and one In(6) atom. In the fourth Bi site, Bi(4) is bonded in a 9-coordinate geometry to one K(1), one K(10), one K(4), one K(6), one K(8), two equivalent K(7), one In(4), and one In(6) atom. In the fifth Bi site, Bi(5) is bonded in a 9-coordinate geometry to one K(1), one K(10), one K(2), one K(3), one K(6), one K(9), one In(3), one In(4), and one In(5) atom. In the sixth Bi site, Bi(6) is bonded in a 9-coordinate geometry to one K(1), one K(10), one K(11), one K(3), one K(5), one K(7), one K(9), one In(2), and one In(6) atom. In the seventh Bi site, Bi(7) is bonded in a 9-coordinate geometry to one K(2), one K(3), one K(5), one K(6), two equivalent K(4), one In(4), one In(5), and one In(6) atom. In the eighth Bi site, Bi(8) is bonded in a 10-coordinate geometry to one K(1), one K(11), one K(2), one K(3), one K(5), one K(6), one K(9), one In(2), one In(3), and one In(5) atom. In the ninth Bi site, Bi(9) is bonded in a 10-coordinate geometry to one K(1), one K(12), one K(2), one K(4), one K(6), one K(7), two equivalent K(8), one In(1), and one In(2) atom. is represented by the CIF card [CIF]
data_K11(In2Bi3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.200
_cell_length_b   13.393
_cell_length_c   13.800
_cell_angle_alpha   76.492
_cell_angle_beta   63.558
_cell_angle_gamma   76.111
_symmetry_Int_Tables_number   1
_cell_volume   1938.963
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.452  0.259  0.704  1.0
  K  K1  1  0.548  0.741  0.296  1.0
  K  K2  1  0.699  0.689  0.511  1.0
  K  K3  1  0.205  0.456  0.195  1.0
  K  K4  1  0.795  0.544  0.805  1.0
  K  K5  1  0.950  0.012  0.370  1.0
  K  K6  1  0.949  0.280  0.215  1.0
  K  K7  1  0.960  0.251  0.715  1.0
  K  K8  1  0.617  0.985  0.069  1.0
  K  K9  1  0.383  0.015  0.931  1.0
  K  K10  1  0.596  0.979  0.594  1.0
  K  K11  1  0.301  0.311  0.489  1.0
  K  K12  1  0.376  0.545  0.807  1.0
  K  K13  1  0.408  0.722  0.069  1.0
  K  K14  1  0.050  0.988  0.630  1.0
  K  K15  1  0.624  0.455  0.193  1.0
  K  K16  1  0.051  0.720  0.785  1.0
  K  K17  1  0.404  0.021  0.406  1.0
  K  K18  1  0.000  0.500  0.000  1.0
  K  K19  1  0.592  0.278  0.931  1.0
  K  K20  1  0.040  0.749  0.285  1.0
  K  K21  1  0.000  0.000  0.000  1.0
  In  In22  1  0.706  0.151  0.200  1.0
  In  In23  1  0.128  0.243  0.884  1.0
  In  In24  1  0.294  0.849  0.800  1.0
  In  In25  1  0.629  0.448  0.460  1.0
  In  In26  1  0.204  0.794  0.452  1.0
  In  In27  1  0.796  0.206  0.548  1.0
  In  In28  1  0.061  0.555  0.536  1.0
  In  In29  1  0.271  0.156  0.201  1.0
  In  In30  1  0.729  0.844  0.799  1.0
  In  In31  1  0.371  0.552  0.540  1.0
  In  In32  1  0.872  0.757  0.116  1.0
  In  In33  1  0.939  0.445  0.464  1.0
  Bi  Bi34  1  0.643  0.228  0.419  1.0
  Bi  Bi35  1  0.149  0.717  0.005  1.0
  Bi  Bi36  1  0.455  0.257  0.216  1.0
  Bi  Bi37  1  0.282  0.930  0.232  1.0
  Bi  Bi38  1  0.698  0.403  0.652  1.0
  Bi  Bi39  1  0.269  0.288  0.993  1.0
  Bi  Bi40  1  0.302  0.597  0.348  1.0
  Bi  Bi41  1  0.357  0.772  0.581  1.0
  Bi  Bi42  1  0.071  0.225  0.424  1.0
  Bi  Bi43  1  0.149  0.454  0.721  1.0
  Bi  Bi44  1  0.718  0.070  0.768  1.0
  Bi  Bi45  1  0.851  0.546  0.279  1.0
  Bi  Bi46  1  0.929  0.775  0.576  1.0
  Bi  Bi47  1  0.755  0.923  0.273  1.0
  Bi  Bi48  1  0.545  0.743  0.784  1.0
  Bi  Bi49  1  0.245  0.077  0.727  1.0
  Bi  Bi50  1  0.851  0.283  0.995  1.0
  Bi  Bi51  1  0.731  0.712  0.007  1.0
[/CIF]
.
The material described by K11In6Bi9 crystallizes in the triclinic P-1 space group. There are twelve inequivalent K sites. In the first K site, K(1) is bonded in a 9-coordinate geometry to one In(2), one In(3), one In(4), one Bi(1), one Bi(4), one Bi(5), one Bi(6), one Bi(8), and one Bi(9) atom. In the second K site, K(2) is bonded in a 8-coordinate geometry to one In(3), one In(5), one Bi(1), one Bi(3), one Bi(5), one Bi(7), one Bi(8), and one Bi(9) atom. In the third K site, K(3) is bonded in a 8-coordinate geometry to one In(5), one In(6), one Bi(2), one Bi(3), one Bi(5), one Bi(6), one Bi(7), and one Bi(8) atom. In the fourth K site, K(4) is bonded in a 4-coordinate geometry to one In(4), one Bi(1), one Bi(4), one Bi(9), and two equivalent Bi(7) atoms. In the fifth K site, K(5) is bonded in a 7-coordinate geometry to one K(11), one In(1), one In(6), one Bi(1), one Bi(2), one Bi(6), one Bi(7), and one Bi(8) atom. In the sixth K site, K(6) is bonded in a 9-coordinate geometry to one In(2), one In(4), one In(5), one Bi(2), one Bi(4), one Bi(5), one Bi(7), one Bi(8), and one Bi(9) atom. In the seventh K site, K(7) is bonded in a 5-coordinate geometry to one In(1), one In(2), one Bi(6), one Bi(9), and two equivalent Bi(4) atoms. In the eighth K site, K(8) is bonded in a 7-coordinate geometry to one In(1), one In(6), one Bi(1), one Bi(3), one Bi(4), and two equivalent Bi(9) atoms. In the ninth K site, K(9) is bonded in a 8-coordinate geometry to one In(1), one In(3), one Bi(1), one Bi(2), one Bi(3), one Bi(5), one Bi(6), and one Bi(8) atom. In the tenth K site, K(10) is bonded in a 5-coordinate geometry to one Bi(2), one Bi(3), one Bi(4), one Bi(5), and one Bi(6) atom. In the eleventh K site, K(11) is bonded in a 10-coordinate geometry to two equivalent K(5), two equivalent In(2), two equivalent Bi(2), two equivalent Bi(6), and two equivalent Bi(8) atoms. In the twelfth K site, K(12) is bonded in a 8-coordinate geometry to two equivalent In(1), two equivalent In(2), two equivalent Bi(2), and two equivalent Bi(9) atoms. There are six inequivalent In sites. In the first In site, In(1) is bonded in a 9-coordinate geometry to one K(12), one K(5), one K(7), one K(8), one K(9), one Bi(1), one Bi(2), one Bi(3), and one Bi(9) atom. In the second In site, In(2) is bonded in a 9-coordinate geometry to one K(1), one K(11), one K(12), one K(6), one K(7), one Bi(2), one Bi(6), one Bi(8), and one Bi(9) atom. In the third In site, In(3) is bonded in a 7-coordinate geometry to one K(1), one K(2), one K(9), one In(3), one Bi(1), one Bi(5), and one Bi(8) atom. In the fourth In site, In(4) is bonded in a 5-coordinate geometry to one K(1), one K(4), one K(6), one Bi(1), one Bi(4), one Bi(5), and one Bi(7) atom. In the fifth In site, In(5) is bonded in a 7-coordinate geometry to one K(2), one K(3), one K(6), one In(5), one Bi(5), one Bi(7), and one Bi(8) atom. In the sixth In site, In(6) is bonded in a 4-coordinate geometry to one K(3), one K(5), one K(8), one Bi(3), one Bi(4), one Bi(6), and one Bi(7) atom. There are nine inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 9-coordinate geometry to one K(1), one K(2), one K(4), one K(5), one K(8), one K(9), one In(1), one In(3), and one In(4) atom. In the second Bi site, Bi(2) is bonded in a 9-coordinate geometry to one K(10), one K(11), one K(12), one K(3), one K(5), one K(6), one K(9), one In(1), and one In(2) atom. In the third Bi site, Bi(3) is bonded in a distorted pentagonal bipyramidal geometry to one K(10), one K(2), one K(3), one K(8), one K(9), one In(1), and one In(6) atom. In the fourth Bi site, Bi(4) is bonded in a 9-coordinate geometry to one K(1), one K(10), one K(4), one K(6), one K(8), two equivalent K(7), one In(4), and one In(6) atom. In the fifth Bi site, Bi(5) is bonded in a 9-coordinate geometry to one K(1), one K(10), one K(2), one K(3), one K(6), one K(9), one In(3), one In(4), and one In(5) atom. In the sixth Bi site, Bi(6) is bonded in a 9-coordinate geometry to one K(1), one K(10), one K(11), one K(3), one K(5), one K(7), one K(9), one In(2), and one In(6) atom. In the seventh Bi site, Bi(7) is bonded in a 9-coordinate geometry to one K(2), one K(3), one K(5), one K(6), two equivalent K(4), one In(4), one In(5), and one In(6) atom. In the eighth Bi site, Bi(8) is bonded in a 10-coordinate geometry to one K(1), one K(11), one K(2), one K(3), one K(5), one K(6), one K(9), one In(2), one In(3), and one In(5) atom. In the ninth Bi site, Bi(9) is bonded in a 10-coordinate geometry to one K(1), one K(12), one K(2), one K(4), one K(6), one K(7), two equivalent K(8), one In(1), and one In(2) atom. is represented by the CIF card [CIF]
data_K11(In2Bi3)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   12.200
_cell_length_b   13.393
_cell_length_c   13.800
_cell_angle_alpha   76.492
_cell_angle_beta   63.558
_cell_angle_gamma   76.111
_symmetry_Int_Tables_number   1
_cell_volume   1938.963
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.452  0.259  0.704  1.0
  K  K1  1  0.548  0.741  0.296  1.0
  K  K2  1  0.699  0.689  0.511  1.0
  K  K3  1  0.205  0.456  0.195  1.0
  K  K4  1  0.795  0.544  0.805  1.0
  K  K5  1  0.950  0.012  0.370  1.0
  K  K6  1  0.949  0.280  0.215  1.0
  K  K7  1  0.960  0.251  0.715  1.0
  K  K8  1  0.617  0.985  0.069  1.0
  K  K9  1  0.383  0.015  0.931  1.0
  K  K10  1  0.596  0.979  0.594  1.0
  K  K11  1  0.301  0.311  0.489  1.0
  K  K12  1  0.376  0.545  0.807  1.0
  K  K13  1  0.408  0.722  0.069  1.0
  K  K14  1  0.050  0.988  0.630  1.0
  K  K15  1  0.624  0.455  0.193  1.0
  K  K16  1  0.051  0.720  0.785  1.0
  K  K17  1  0.404  0.021  0.406  1.0
  K  K18  1  0.000  0.500  0.000  1.0
  K  K19  1  0.592  0.278  0.931  1.0
  K  K20  1  0.040  0.749  0.285  1.0
  K  K21  1  0.000  0.000  0.000  1.0
  In  In22  1  0.706  0.151  0.200  1.0
  In  In23  1  0.128  0.243  0.884  1.0
  In  In24  1  0.294  0.849  0.800  1.0
  In  In25  1  0.629  0.448  0.460  1.0
  In  In26  1  0.204  0.794  0.452  1.0
  In  In27  1  0.796  0.206  0.548  1.0
  In  In28  1  0.061  0.555  0.536  1.0
  In  In29  1  0.271  0.156  0.201  1.0
  In  In30  1  0.729  0.844  0.799  1.0
  In  In31  1  0.371  0.552  0.540  1.0
  In  In32  1  0.872  0.757  0.116  1.0
  In  In33  1  0.939  0.445  0.464  1.0
  Bi  Bi34  1  0.643  0.228  0.419  1.0
  Bi  Bi35  1  0.149  0.717  0.005  1.0
  Bi  Bi36  1  0.455  0.257  0.216  1.0
  Bi  Bi37  1  0.282  0.930  0.232  1.0
  Bi  Bi38  1  0.698  0.403  0.652  1.0
  Bi  Bi39  1  0.269  0.288  0.993  1.0
  Bi  Bi40  1  0.302  0.597  0.348  1.0
  Bi  Bi41  1  0.357  0.772  0.581  1.0
  Bi  Bi42  1  0.071  0.225  0.424  1.0
  Bi  Bi43  1  0.149  0.454  0.721  1.0
  Bi  Bi44  1  0.718  0.070  0.768  1.0
  Bi  Bi45  1  0.851  0.546  0.279  1.0
  Bi  Bi46  1  0.929  0.775  0.576  1.0
  Bi  Bi47  1  0.755  0.923  0.273  1.0
  Bi  Bi48  1  0.545  0.743  0.784  1.0
  Bi  Bi49  1  0.245  0.077  0.727  1.0
  Bi  Bi50  1  0.851  0.283  0.995  1.0
  Bi  Bi51  1  0.731  0.712  0.007  1.0
[/CIF]
.