The compound described by CuN2H3ClCN2SH2H2O(HCl)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, four hydrochloric acid molecules, two water molecules, two CN2S clusters, and two CuN2H3Cl clusters. In each CN2S cluster, C(1) is bonded in a linear geometry to one N(3) and one N(4) atom. There are two inequivalent N sites. In the first N site, N(3) is bonded in a water-like geometry to one C(1) and one S(1) atom. In the second N site, N(4) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted single-bond geometry to one N(3) atom. In each CuN2H3Cl cluster, Cu(1) is bonded in a distorted water-like geometry to one N(1) and one Cl(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one N(2) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one N(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one Cl(2) atom. Cl(2) is bonded in an L-shaped geometry to one Cu(1) and one H(5) atom. is represented by the CIF file [CIF]
data_CuH9CSN4Cl3O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.941
_cell_length_b   9.667
_cell_length_c   7.506
_cell_angle_alpha   98.403
_cell_angle_beta   92.151
_cell_angle_gamma   112.367
_symmetry_Int_Tables_number   1
_cell_volume   590.386
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.885  0.775  0.908  1.0
  Cu  Cu1  1  0.115  0.225  0.092  1.0
  H  H2  1  0.966  0.751  0.363  1.0
  H  H3  1  0.034  0.249  0.637  1.0
  H  H4  1  0.680  0.718  0.530  1.0
  H  H5  1  0.320  0.282  0.470  1.0
  H  H6  1  0.729  0.939  0.493  1.0
  H  H7  1  0.271  0.061  0.507  1.0
  H  H8  1  0.367  0.799  0.495  1.0
  H  H9  1  0.633  0.201  0.505  1.0
  H  H10  1  0.253  0.434  0.918  1.0
  H  H11  1  0.747  0.566  0.082  1.0
  H  H12  1  0.384  0.857  0.093  1.0
  H  H13  1  0.616  0.143  0.907  1.0
  H  H14  1  0.469  0.626  0.755  1.0
  H  H15  1  0.531  0.374  0.245  1.0
  H  H16  1  0.335  0.773  0.405  1.0
  H  H17  1  0.665  0.227  0.595  1.0
  H  H18  1  0.121  0.699  0.403  1.0
  H  H19  1  0.879  0.301  0.597  1.0
  C  C20  1  0.155  0.742  0.794  1.0
  C  C21  1  0.845  0.258  0.206  1.0
  S  S22  1  0.088  0.653  0.039  1.0
  S  S23  1  0.912  0.347  0.961  1.0
  N  N24  1  0.816  0.894  0.726  1.0
  N  N25  1  0.184  0.106  0.274  1.0
  N  N26  1  0.739  0.846  0.580  1.0
  N  N27  1  0.261  0.154  0.420  1.0
  N  N28  1  0.199  0.666  0.932  1.0
  N  N29  1  0.801  0.334  0.068  1.0
  N  N30  1  0.130  0.817  0.675  1.0
  N  N31  1  0.870  0.183  0.325  1.0
  Cl  Cl32  1  0.505  0.025  0.800  1.0
  Cl  Cl33  1  0.495  0.975  0.200  1.0
  Cl  Cl34  1  0.729  0.739  0.069  1.0
  Cl  Cl35  1  0.271  0.261  0.931  1.0
  Cl  Cl36  1  0.512  0.487  0.709  1.0
  Cl  Cl37  1  0.488  0.513  0.291  1.0
  O  O38  1  0.018  0.672  0.321  1.0
  O  O39  1  0.982  0.328  0.679  1.0
[/CIF]
.
The compound described by CuN2H3ClCN2SH2H2O(HCl)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 molecules, four hydrochloric acid molecules, two water molecules, two CN2S clusters, and two CuN2H3Cl clusters. In each CN2S cluster, C(1) is bonded in a linear geometry to one N(3) and one N(4) atom. There are two inequivalent N sites. In the first N site, N(3) is bonded in a water-like geometry to one C(1) and one S(1) atom. In the second N site, N(4) is bonded in a single-bond geometry to one C(1) atom. S(1) is bonded in a distorted single-bond geometry to one N(3) atom. In each CuN2H3Cl cluster, Cu(1) is bonded in a distorted water-like geometry to one N(1) and one Cl(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one N(2) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one N(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one Cl(2) atom. Cl(2) is bonded in an L-shaped geometry to one Cu(1) and one H(5) atom. is represented by the CIF file [CIF]
data_CuH9CSN4Cl3O
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.941
_cell_length_b   9.667
_cell_length_c   7.506
_cell_angle_alpha   98.403
_cell_angle_beta   92.151
_cell_angle_gamma   112.367
_symmetry_Int_Tables_number   1
_cell_volume   590.386
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cu  Cu0  1  0.885  0.775  0.908  1.0
  Cu  Cu1  1  0.115  0.225  0.092  1.0
  H  H2  1  0.966  0.751  0.363  1.0
  H  H3  1  0.034  0.249  0.637  1.0
  H  H4  1  0.680  0.718  0.530  1.0
  H  H5  1  0.320  0.282  0.470  1.0
  H  H6  1  0.729  0.939  0.493  1.0
  H  H7  1  0.271  0.061  0.507  1.0
  H  H8  1  0.367  0.799  0.495  1.0
  H  H9  1  0.633  0.201  0.505  1.0
  H  H10  1  0.253  0.434  0.918  1.0
  H  H11  1  0.747  0.566  0.082  1.0
  H  H12  1  0.384  0.857  0.093  1.0
  H  H13  1  0.616  0.143  0.907  1.0
  H  H14  1  0.469  0.626  0.755  1.0
  H  H15  1  0.531  0.374  0.245  1.0
  H  H16  1  0.335  0.773  0.405  1.0
  H  H17  1  0.665  0.227  0.595  1.0
  H  H18  1  0.121  0.699  0.403  1.0
  H  H19  1  0.879  0.301  0.597  1.0
  C  C20  1  0.155  0.742  0.794  1.0
  C  C21  1  0.845  0.258  0.206  1.0
  S  S22  1  0.088  0.653  0.039  1.0
  S  S23  1  0.912  0.347  0.961  1.0
  N  N24  1  0.816  0.894  0.726  1.0
  N  N25  1  0.184  0.106  0.274  1.0
  N  N26  1  0.739  0.846  0.580  1.0
  N  N27  1  0.261  0.154  0.420  1.0
  N  N28  1  0.199  0.666  0.932  1.0
  N  N29  1  0.801  0.334  0.068  1.0
  N  N30  1  0.130  0.817  0.675  1.0
  N  N31  1  0.870  0.183  0.325  1.0
  Cl  Cl32  1  0.505  0.025  0.800  1.0
  Cl  Cl33  1  0.495  0.975  0.200  1.0
  Cl  Cl34  1  0.729  0.739  0.069  1.0
  Cl  Cl35  1  0.271  0.261  0.931  1.0
  Cl  Cl36  1  0.512  0.487  0.709  1.0
  Cl  Cl37  1  0.488  0.513  0.291  1.0
  O  O38  1  0.018  0.672  0.321  1.0
  O  O39  1  0.982  0.328  0.679  1.0
[/CIF]
.