The material described by CdH8(NO5)2 is gamma plutonium structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two cadmium;nitric acid;tetrahydrate molecules. Cd(1) is bonded in a 8-coordinate geometry to one O(1), one O(15), one O(16), one O(17), one O(18), one O(2), one O(5), and one O(6) atom. There are two inequivalent N sites. In the first N site, N(1,3) is bonded in a trigonal planar geometry to one O(1); one O(5); and one O(9,11) atom. In the second N site, N(2,4) is bonded in a trigonal planar geometry to one O(10), one O(2), and one O(6) atom. There are six inequivalent H sites. In the first H site, H(1,3) is bonded in a single-bond geometry to one O(13) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(16) atom. In the third H site, H(5,7) is bonded in a single-bond geometry to one O(13) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one O(16) atom. In the fifth H site, H(9,10,11,12) is bonded in a single-bond geometry to one O(17) atom. In the sixth H site, H(13,14,15,16) is bonded in a single-bond geometry to one O(17) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one N(1,3) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one N(2,4) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1) and one N(1,3) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one Cd(1) and one N(2,4) atom. In the fifth O site, O(9,11) is bonded in a single-bond geometry to one N(1,3) atom. In the sixth O site, O(10) is bonded in a single-bond geometry to one N(2,4) atom. In the seventh O site, O(15) is bonded in a distorted water-like geometry to one Cd(1); one H(1,3); and one H(5,7) atom. In the eighth O site, O(16) is bonded in a distorted water-like geometry to one Cd(1), one H(4), and one H(8) atom. In the ninth O site, O(17) is bonded in a distorted water-like geometry to one Cd(1); one H(13,14,15,16); and one H(9,10,11,12) atom. In the tenth O site, O(18) is bonded in a distorted water-like geometry to one Cd(1); one H(13,14,15,16); and one H(9,10,11,12) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdH8(NO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.010
_cell_length_b   13.203
_cell_length_c   6.259
_cell_angle_alpha   84.023
_cell_angle_beta   69.597
_cell_angle_gamma   26.380
_symmetry_Int_Tables_number   1
_cell_volume   417.558
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.260  0.240  0.260  1.0
  Cd  Cd1  1  0.010  0.990  0.010  1.0
  H  H2  1  0.495  0.624  0.900  1.0
  H  H3  1  0.890  0.999  0.500  1.0
  H  H4  1  0.269  0.350  0.626  1.0
  H  H5  1  0.626  0.755  0.269  1.0
  H  H6  1  0.499  0.500  0.952  1.0
  H  H7  1  0.952  0.050  0.499  1.0
  H  H8  1  0.200  0.298  0.750  1.0
  H  H9  1  0.750  0.751  0.200  1.0
  H  H10  1  0.153  0.179  0.040  1.0
  H  H11  1  0.040  0.627  0.153  1.0
  H  H12  1  0.623  0.210  0.071  1.0
  H  H13  1  0.071  0.097  0.623  1.0
  H  H14  1  0.439  0.962  0.838  1.0
  H  H15  1  0.838  0.762  0.439  1.0
  H  H16  1  0.488  0.412  0.288  1.0
  H  H17  1  0.288  0.811  0.488  1.0
  N  N18  1  0.832  0.491  0.671  1.0
  N  N19  1  0.671  0.006  0.832  1.0
  N  N20  1  0.244  0.579  0.759  1.0
  N  N21  1  0.759  0.418  0.244  1.0
  O  O22  1  0.786  0.621  0.598  1.0
  O  O23  1  0.598  0.995  0.786  1.0
  O  O24  1  0.255  0.652  0.629  1.0
  O  O25  1  0.629  0.464  0.255  1.0
  O  O26  1  0.071  0.240  0.548  1.0
  O  O27  1  0.548  0.140  0.071  1.0
  O  O28  1  0.110  0.702  0.010  1.0
  O  O29  1  0.010  0.179  0.110  1.0
  O  O30  1  0.648  0.607  0.859  1.0
  O  O31  1  0.859  0.887  0.648  1.0
  O  O32  1  0.363  0.391  0.643  1.0
  O  O33  1  0.643  0.602  0.363  1.0
  O  O34  1  0.438  0.612  0.881  1.0
  O  O35  1  0.881  0.078  0.437  1.0
  O  O36  1  0.181  0.369  0.638  1.0
  O  O37  1  0.645  0.813  0.172  1.0
  O  O38  1  0.251  0.155  0.965  1.0
  O  O39  1  0.965  0.629  0.251  1.0
  O  O40  1  0.621  0.285  0.095  1.0
  O  O41  1  0.095  0.999  0.621  1.0
[/CIF]
.
The material described by CdH8(NO5)2 is gamma plutonium structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two cadmium;nitric acid;tetrahydrate molecules. Cd(1) is bonded in a 8-coordinate geometry to one O(1), one O(15), one O(16), one O(17), one O(18), one O(2), one O(5), and one O(6) atom. There are two inequivalent N sites. In the first N site, N(1,3) is bonded in a trigonal planar geometry to one O(1); one O(5); and one O(9,11) atom. In the second N site, N(2,4) is bonded in a trigonal planar geometry to one O(10), one O(2), and one O(6) atom. There are six inequivalent H sites. In the first H site, H(1,3) is bonded in a single-bond geometry to one O(13) atom. In the second H site, H(4) is bonded in a single-bond geometry to one O(16) atom. In the third H site, H(5,7) is bonded in a single-bond geometry to one O(13) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one O(16) atom. In the fifth H site, H(9,10,11,12) is bonded in a single-bond geometry to one O(17) atom. In the sixth H site, H(13,14,15,16) is bonded in a single-bond geometry to one O(17) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one N(1,3) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one N(2,4) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1) and one N(1,3) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one Cd(1) and one N(2,4) atom. In the fifth O site, O(9,11) is bonded in a single-bond geometry to one N(1,3) atom. In the sixth O site, O(10) is bonded in a single-bond geometry to one N(2,4) atom. In the seventh O site, O(15) is bonded in a distorted water-like geometry to one Cd(1); one H(1,3); and one H(5,7) atom. In the eighth O site, O(16) is bonded in a distorted water-like geometry to one Cd(1), one H(4), and one H(8) atom. In the ninth O site, O(17) is bonded in a distorted water-like geometry to one Cd(1); one H(13,14,15,16); and one H(9,10,11,12) atom. In the tenth O site, O(18) is bonded in a distorted water-like geometry to one Cd(1); one H(13,14,15,16); and one H(9,10,11,12) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdH8(NO5)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.010
_cell_length_b   13.203
_cell_length_c   6.259
_cell_angle_alpha   84.023
_cell_angle_beta   69.597
_cell_angle_gamma   26.380
_symmetry_Int_Tables_number   1
_cell_volume   417.558
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.260  0.240  0.260  1.0
  Cd  Cd1  1  0.010  0.990  0.010  1.0
  H  H2  1  0.495  0.624  0.900  1.0
  H  H3  1  0.890  0.999  0.500  1.0
  H  H4  1  0.269  0.350  0.626  1.0
  H  H5  1  0.626  0.755  0.269  1.0
  H  H6  1  0.499  0.500  0.952  1.0
  H  H7  1  0.952  0.050  0.499  1.0
  H  H8  1  0.200  0.298  0.750  1.0
  H  H9  1  0.750  0.751  0.200  1.0
  H  H10  1  0.153  0.179  0.040  1.0
  H  H11  1  0.040  0.627  0.153  1.0
  H  H12  1  0.623  0.210  0.071  1.0
  H  H13  1  0.071  0.097  0.623  1.0
  H  H14  1  0.439  0.962  0.838  1.0
  H  H15  1  0.838  0.762  0.439  1.0
  H  H16  1  0.488  0.412  0.288  1.0
  H  H17  1  0.288  0.811  0.488  1.0
  N  N18  1  0.832  0.491  0.671  1.0
  N  N19  1  0.671  0.006  0.832  1.0
  N  N20  1  0.244  0.579  0.759  1.0
  N  N21  1  0.759  0.418  0.244  1.0
  O  O22  1  0.786  0.621  0.598  1.0
  O  O23  1  0.598  0.995  0.786  1.0
  O  O24  1  0.255  0.652  0.629  1.0
  O  O25  1  0.629  0.464  0.255  1.0
  O  O26  1  0.071  0.240  0.548  1.0
  O  O27  1  0.548  0.140  0.071  1.0
  O  O28  1  0.110  0.702  0.010  1.0
  O  O29  1  0.010  0.179  0.110  1.0
  O  O30  1  0.648  0.607  0.859  1.0
  O  O31  1  0.859  0.887  0.648  1.0
  O  O32  1  0.363  0.391  0.643  1.0
  O  O33  1  0.643  0.602  0.363  1.0
  O  O34  1  0.438  0.612  0.881  1.0
  O  O35  1  0.881  0.078  0.437  1.0
  O  O36  1  0.181  0.369  0.638  1.0
  O  O37  1  0.645  0.813  0.172  1.0
  O  O38  1  0.251  0.155  0.965  1.0
  O  O39  1  0.965  0.629  0.251  1.0
  O  O40  1  0.621  0.285  0.095  1.0
  O  O41  1  0.095  0.999  0.621  1.0
[/CIF]
.