The crystal structure described by SmTl(MoO4)2 crystallizes in the orthorhombic Pbcn space group. Sm(1) is bonded in a 8-coordinate geometry to two equivalent O(3), two equivalent O(4), and four equivalent O(2) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Tl(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. There are four inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Sm(1) and one Mo(1) atom. In the second O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Sm(1) and one Mo(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one Mo(1) and two equivalent Tl(1) atoms. In the fourth O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Sm(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_SmTl(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.119
_cell_length_b   8.098
_cell_length_c   18.669
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   773.824
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.500  0.750  0.493  1.0
  Sm  Sm1  1  0.000  0.250  0.007  1.0
  Sm  Sm2  1  0.500  0.250  0.507  1.0
  Sm  Sm3  1  0.000  0.750  0.993  1.0
  Tl  Tl4  1  0.000  0.750  0.230  1.0
  Tl  Tl5  1  0.500  0.250  0.270  1.0
  Tl  Tl6  1  0.000  0.250  0.770  1.0
  Tl  Tl7  1  0.500  0.750  0.730  1.0
  Mo  Mo8  1  0.481  0.517  0.101  1.0
  Mo  Mo9  1  0.981  0.483  0.399  1.0
  Mo  Mo10  1  0.019  0.017  0.399  1.0
  Mo  Mo11  1  0.519  0.983  0.101  1.0
  Mo  Mo12  1  0.519  0.483  0.899  1.0
  Mo  Mo13  1  0.019  0.517  0.601  1.0
  Mo  Mo14  1  0.981  0.983  0.601  1.0
  Mo  Mo15  1  0.481  0.017  0.899  1.0
  O  O16  1  0.609  0.524  0.187  1.0
  O  O17  1  0.109  0.476  0.313  1.0
  O  O18  1  0.891  0.024  0.313  1.0
  O  O19  1  0.391  0.976  0.187  1.0
  O  O20  1  0.391  0.476  0.813  1.0
  O  O21  1  0.891  0.524  0.687  1.0
  O  O22  1  0.109  0.976  0.687  1.0
  O  O23  1  0.609  0.024  0.813  1.0
  O  O24  1  0.748  0.497  0.036  1.0
  O  O25  1  0.248  0.503  0.464  1.0
  O  O26  1  0.752  0.997  0.464  1.0
  O  O27  1  0.252  0.003  0.036  1.0
  O  O28  1  0.252  0.503  0.964  1.0
  O  O29  1  0.752  0.497  0.536  1.0
  O  O30  1  0.248  0.003  0.536  1.0
  O  O31  1  0.748  0.997  0.964  1.0
  O  O32  1  0.277  0.842  0.901  1.0
  O  O33  1  0.777  0.158  0.599  1.0
  O  O34  1  0.223  0.342  0.599  1.0
  O  O35  1  0.723  0.658  0.901  1.0
  O  O36  1  0.723  0.158  0.099  1.0
  O  O37  1  0.223  0.842  0.401  1.0
  O  O38  1  0.777  0.658  0.401  1.0
  O  O39  1  0.277  0.342  0.099  1.0
  O  O40  1  0.263  0.188  0.908  1.0
  O  O41  1  0.763  0.812  0.592  1.0
  O  O42  1  0.237  0.688  0.592  1.0
  O  O43  1  0.737  0.312  0.908  1.0
  O  O44  1  0.737  0.812  0.092  1.0
  O  O45  1  0.237  0.188  0.408  1.0
  O  O46  1  0.763  0.312  0.408  1.0
  O  O47  1  0.263  0.688  0.092  1.0
[/CIF]
.
The crystal structure described by SmTl(MoO4)2 crystallizes in the orthorhombic Pbcn space group. Sm(1) is bonded in a 8-coordinate geometry to two equivalent O(3), two equivalent O(4), and four equivalent O(2) atoms. Mo(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. Tl(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. There are four inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Sm(1) and one Mo(1) atom. In the second O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Sm(1) and one Mo(1) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one Mo(1) and two equivalent Tl(1) atoms. In the fourth O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Sm(1) and one Mo(1) atom. is represented by the CIF card [CIF]
data_SmTl(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.119
_cell_length_b   8.098
_cell_length_c   18.669
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   773.824
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sm  Sm0  1  0.500  0.750  0.493  1.0
  Sm  Sm1  1  0.000  0.250  0.007  1.0
  Sm  Sm2  1  0.500  0.250  0.507  1.0
  Sm  Sm3  1  0.000  0.750  0.993  1.0
  Tl  Tl4  1  0.000  0.750  0.230  1.0
  Tl  Tl5  1  0.500  0.250  0.270  1.0
  Tl  Tl6  1  0.000  0.250  0.770  1.0
  Tl  Tl7  1  0.500  0.750  0.730  1.0
  Mo  Mo8  1  0.481  0.517  0.101  1.0
  Mo  Mo9  1  0.981  0.483  0.399  1.0
  Mo  Mo10  1  0.019  0.017  0.399  1.0
  Mo  Mo11  1  0.519  0.983  0.101  1.0
  Mo  Mo12  1  0.519  0.483  0.899  1.0
  Mo  Mo13  1  0.019  0.517  0.601  1.0
  Mo  Mo14  1  0.981  0.983  0.601  1.0
  Mo  Mo15  1  0.481  0.017  0.899  1.0
  O  O16  1  0.609  0.524  0.187  1.0
  O  O17  1  0.109  0.476  0.313  1.0
  O  O18  1  0.891  0.024  0.313  1.0
  O  O19  1  0.391  0.976  0.187  1.0
  O  O20  1  0.391  0.476  0.813  1.0
  O  O21  1  0.891  0.524  0.687  1.0
  O  O22  1  0.109  0.976  0.687  1.0
  O  O23  1  0.609  0.024  0.813  1.0
  O  O24  1  0.748  0.497  0.036  1.0
  O  O25  1  0.248  0.503  0.464  1.0
  O  O26  1  0.752  0.997  0.464  1.0
  O  O27  1  0.252  0.003  0.036  1.0
  O  O28  1  0.252  0.503  0.964  1.0
  O  O29  1  0.752  0.497  0.536  1.0
  O  O30  1  0.248  0.003  0.536  1.0
  O  O31  1  0.748  0.997  0.964  1.0
  O  O32  1  0.277  0.842  0.901  1.0
  O  O33  1  0.777  0.158  0.599  1.0
  O  O34  1  0.223  0.342  0.599  1.0
  O  O35  1  0.723  0.658  0.901  1.0
  O  O36  1  0.723  0.158  0.099  1.0
  O  O37  1  0.223  0.842  0.401  1.0
  O  O38  1  0.777  0.658  0.401  1.0
  O  O39  1  0.277  0.342  0.099  1.0
  O  O40  1  0.263  0.188  0.908  1.0
  O  O41  1  0.763  0.812  0.592  1.0
  O  O42  1  0.237  0.688  0.592  1.0
  O  O43  1  0.737  0.312  0.908  1.0
  O  O44  1  0.737  0.812  0.092  1.0
  O  O45  1  0.237  0.188  0.408  1.0
  O  O46  1  0.763  0.312  0.408  1.0
  O  O47  1  0.263  0.688  0.092  1.0
[/CIF]
.