The structure described by Lu(WO4)2Tl crystallizes in the monoclinic C2/c space group. The structure consists of four 7440-28-0 atoms inside a Lu(WO4)2 framework. In the Lu(WO4)2 framework, Lu(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. W(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form a mixture of corner and edge-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 44°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Lu(1) and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Lu(1) and two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Lu(1) and one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LuTl(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.533
_cell_length_b   7.533
_cell_length_c   7.455
_cell_angle_alpha   62.357
_cell_angle_beta   62.357
_cell_angle_gamma   88.079
_symmetry_Int_Tables_number   1
_cell_volume   322.921
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Lu  Lu0  1  0.776  0.224  0.750  1.0
  Lu  Lu1  1  0.224  0.776  0.250  1.0
  Tl  Tl2  1  0.203  0.797  0.750  1.0
  Tl  Tl3  1  0.797  0.203  0.250  1.0
  W  W4  1  0.702  0.692  0.779  1.0
  W  W5  1  0.298  0.308  0.221  1.0
  W  W6  1  0.308  0.298  0.721  1.0
  W  W7  1  0.692  0.702  0.279  1.0
  O  O8  1  0.618  0.761  0.557  1.0
  O  O9  1  0.382  0.239  0.443  1.0
  O  O10  1  0.239  0.382  0.943  1.0
  O  O11  1  0.761  0.618  0.057  1.0
  O  O12  1  0.373  0.058  0.884  1.0
  O  O13  1  0.627  0.942  0.116  1.0
  O  O14  1  0.942  0.627  0.616  1.0
  O  O15  1  0.058  0.373  0.384  1.0
  O  O16  1  0.591  0.369  0.963  1.0
  O  O17  1  0.409  0.631  0.037  1.0
  O  O18  1  0.631  0.409  0.537  1.0
  O  O19  1  0.369  0.591  0.463  1.0
  O  O20  1  0.785  0.960  0.691  1.0
  O  O21  1  0.215  0.040  0.309  1.0
  O  O22  1  0.040  0.215  0.809  1.0
  O  O23  1  0.960  0.785  0.191  1.0
[/CIF]
.
The structure described by Lu(WO4)2Tl crystallizes in the monoclinic C2/c space group. The structure consists of four 7440-28-0 atoms inside a Lu(WO4)2 framework. In the Lu(WO4)2 framework, Lu(1) is bonded in a 6-coordinate geometry to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. W(1) is bonded to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms to form a mixture of corner and edge-sharing WO6 octahedra. The corner-sharing octahedral tilt angles are 44°. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to two equivalent W(1) atoms. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Lu(1) and one W(1) atom. In the third O site, O(3) is bonded in a distorted trigonal non-coplanar geometry to one Lu(1) and two equivalent W(1) atoms. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Lu(1) and one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_LuTl(WO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.533
_cell_length_b   7.533
_cell_length_c   7.455
_cell_angle_alpha   62.357
_cell_angle_beta   62.357
_cell_angle_gamma   88.079
_symmetry_Int_Tables_number   1
_cell_volume   322.921
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Lu  Lu0  1  0.776  0.224  0.750  1.0
  Lu  Lu1  1  0.224  0.776  0.250  1.0
  Tl  Tl2  1  0.203  0.797  0.750  1.0
  Tl  Tl3  1  0.797  0.203  0.250  1.0
  W  W4  1  0.702  0.692  0.779  1.0
  W  W5  1  0.298  0.308  0.221  1.0
  W  W6  1  0.308  0.298  0.721  1.0
  W  W7  1  0.692  0.702  0.279  1.0
  O  O8  1  0.618  0.761  0.557  1.0
  O  O9  1  0.382  0.239  0.443  1.0
  O  O10  1  0.239  0.382  0.943  1.0
  O  O11  1  0.761  0.618  0.057  1.0
  O  O12  1  0.373  0.058  0.884  1.0
  O  O13  1  0.627  0.942  0.116  1.0
  O  O14  1  0.942  0.627  0.616  1.0
  O  O15  1  0.058  0.373  0.384  1.0
  O  O16  1  0.591  0.369  0.963  1.0
  O  O17  1  0.409  0.631  0.037  1.0
  O  O18  1  0.631  0.409  0.537  1.0
  O  O19  1  0.369  0.591  0.463  1.0
  O  O20  1  0.785  0.960  0.691  1.0
  O  O21  1  0.215  0.040  0.309  1.0
  O  O22  1  0.040  0.215  0.809  1.0
  O  O23  1  0.960  0.785  0.191  1.0
[/CIF]
.