The compound described by LaCoN3 crystallizes in the monoclinic C2/m space group. La(1) is bonded in a 5-coordinate geometry to two equivalent N(3) and three equivalent N(1) atoms. Co(1) is bonded in a distorted trigonal planar geometry to one N(2) and two equivalent N(1) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded to three equivalent La(1) and two equivalent Co(1) atoms to form a mixture of edge and corner-sharing NLa3Co2 trigonal bipyramids. In the second N site, N(2) is bonded in a 1-coordinate geometry to one Co(1) and one N(3) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to two equivalent La(1) and one N(2) atom. is represented by the CIF card [CIF]
data_LaCoN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.040
_cell_length_b   5.727
_cell_length_c   7.447
_cell_angle_alpha   102.444
_cell_angle_beta   90.000
_cell_angle_gamma   110.652
_symmetry_Int_Tables_number   1
_cell_volume   156.920
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.836  0.671  0.200  1.0
  La  La1  1  0.164  0.329  0.800  1.0
  Co  Co2  1  0.541  0.083  0.155  1.0
  Co  Co3  1  0.459  0.917  0.845  1.0
  N  N4  1  0.367  0.733  0.026  1.0
  N  N5  1  0.633  0.267  0.974  1.0
  N  N6  1  0.606  0.212  0.380  1.0
  N  N7  1  0.350  0.701  0.459  1.0
  N  N8  1  0.394  0.788  0.620  1.0
  N  N9  1  0.650  0.299  0.541  1.0
[/CIF]
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The compound described by LaCoN3 crystallizes in the monoclinic C2/m space group. La(1) is bonded in a 5-coordinate geometry to two equivalent N(3) and three equivalent N(1) atoms. Co(1) is bonded in a distorted trigonal planar geometry to one N(2) and two equivalent N(1) atoms. There are three inequivalent N sites. In the first N site, N(1) is bonded to three equivalent La(1) and two equivalent Co(1) atoms to form a mixture of edge and corner-sharing NLa3Co2 trigonal bipyramids. In the second N site, N(2) is bonded in a 1-coordinate geometry to one Co(1) and one N(3) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to two equivalent La(1) and one N(2) atom. is represented by the CIF card [CIF]
data_LaCoN3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.040
_cell_length_b   5.727
_cell_length_c   7.447
_cell_angle_alpha   102.444
_cell_angle_beta   90.000
_cell_angle_gamma   110.652
_symmetry_Int_Tables_number   1
_cell_volume   156.920
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.836  0.671  0.200  1.0
  La  La1  1  0.164  0.329  0.800  1.0
  Co  Co2  1  0.541  0.083  0.155  1.0
  Co  Co3  1  0.459  0.917  0.845  1.0
  N  N4  1  0.367  0.733  0.026  1.0
  N  N5  1  0.633  0.267  0.974  1.0
  N  N6  1  0.606  0.212  0.380  1.0
  N  N7  1  0.350  0.701  0.459  1.0
  N  N8  1  0.394  0.788  0.620  1.0
  N  N9  1  0.650  0.299  0.541  1.0
[/CIF]
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