The material structure described by VB6O6 crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four dihydroxyboranyl molecules and two V(B2O)2 clusters. In each V(B2O)2 cluster, V(1) is bonded in an octahedral geometry to four equivalent B(2) and two equivalent O(2) atoms. B(2) is bonded in a single-bond geometry to one V(1) and one O(2) atom. O(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and two equivalent B(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V(BO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.991
_cell_length_b   6.018
_cell_length_c   11.232
_cell_angle_alpha   73.025
_cell_angle_beta   66.994
_cell_angle_gamma   41.667
_symmetry_Int_Tables_number   1
_cell_volume   371.912
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  B  B1  1  0.640  0.000  0.507  1.0
  B  B2  1  0.360  0.000  0.493  1.0
  B  B3  1  0.635  0.331  1.000  1.0
  B  B4  1  0.365  0.669  0.000  1.0
  B  B5  1  0.966  0.669  1.000  1.0
  B  B6  1  0.034  0.331  0.000  1.0
  O  O7  1  0.471  0.316  0.506  1.0
  O  O8  1  0.529  0.684  0.494  1.0
  O  O9  1  0.760  0.000  0.001  1.0
  O  O10  1  0.212  0.316  0.494  1.0
  O  O11  1  0.240  0.000  0.999  1.0
  O  O12  1  0.788  0.684  0.506  1.0
[/CIF]
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The material structure described by VB6O6 crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four dihydroxyboranyl molecules and two V(B2O)2 clusters. In each V(B2O)2 cluster, V(1) is bonded in an octahedral geometry to four equivalent B(2) and two equivalent O(2) atoms. B(2) is bonded in a single-bond geometry to one V(1) and one O(2) atom. O(2) is bonded in a distorted bent 150 degrees geometry to one V(1) and two equivalent B(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_V(BO)6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.991
_cell_length_b   6.018
_cell_length_c   11.232
_cell_angle_alpha   73.025
_cell_angle_beta   66.994
_cell_angle_gamma   41.667
_symmetry_Int_Tables_number   1
_cell_volume   371.912
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  B  B1  1  0.640  0.000  0.507  1.0
  B  B2  1  0.360  0.000  0.493  1.0
  B  B3  1  0.635  0.331  1.000  1.0
  B  B4  1  0.365  0.669  0.000  1.0
  B  B5  1  0.966  0.669  1.000  1.0
  B  B6  1  0.034  0.331  0.000  1.0
  O  O7  1  0.471  0.316  0.506  1.0
  O  O8  1  0.529  0.684  0.494  1.0
  O  O9  1  0.760  0.000  0.001  1.0
  O  O10  1  0.212  0.316  0.494  1.0
  O  O11  1  0.240  0.000  0.999  1.0
  O  O12  1  0.788  0.684  0.506  1.0
[/CIF]
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