The material structure described by Sr5W3O14 crystallizes in the monoclinic Cc space group. There are five inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a distorted body-centered cubic geometry to one O(10), one O(11), one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. In the second Sr site, Sr(2) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(12), one O(3), one O(5), one O(7), and one O(8) atom. In the third Sr site, Sr(3) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(14), one O(2), one O(4), one O(7), and one O(9) atom. In the fourth Sr site, Sr(4) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(13), one O(14), one O(3), one O(5), one O(6), and one O(8) atom. In the fifth Sr site, Sr(5) is bonded in a 7-coordinate geometry to one O(11), one O(13), one O(14), one O(2), one O(4), one O(6), and one O(9) atom. There are three inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(12), one O(13), one O(14), one O(2), and one O(3) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 27-29°. In the second W site, W(2) is bonded to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 28-29°. In the third W site, W(3) is bonded to one O(11), one O(13), one O(3), one O(5), one O(7), and one O(9) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 27-28°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one Sr(4), and one W(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Sr(3), one Sr(5), one W(1), and one W(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(4), one W(1), and one W(3) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Sr(1), one Sr(3), one Sr(5), and one W(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Sr(4), and one W(3) atom. In the sixth O site, O(6) is bonded to one Sr(1), one Sr(4), one Sr(5), and one W(2) atom to form a mixture of distorted corner and edge-sharing OSr3W tetrahedra. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Sr(1), one Sr(2), one Sr(3), and one W(3) atom. In the eighth O site, O(8) is bonded to one Sr(1), one Sr(2), one Sr(4), and one W(2) atom to form distorted corner-sharing OSr3W tetrahedra. In the ninth O site, O(9) is bonded to one Sr(1), one Sr(3), one Sr(5), and one W(3) atom to form a mixture of distorted corner and edge-sharing OSr3W tetrahedra. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), and one W(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(4), one Sr(5), and one W(3) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one W(1), and one W(2) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Sr(4), one Sr(5), one W(1), and one W(3) atom. In the fourteenth O site, O(14) is bonded in a 2-coordinate geometry to one Sr(3), one Sr(4), one Sr(5), and one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr5W3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.688
_cell_length_b   7.688
_cell_length_c   11.075
_cell_angle_alpha   89.922
_cell_angle_beta   89.922
_cell_angle_gamma   89.583
_symmetry_Int_Tables_number   1
_cell_volume   654.651
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.007  0.501  0.495  1.0
  Sr  Sr1  1  0.501  0.007  0.995  1.0
  Sr  Sr2  1  0.752  0.749  0.774  1.0
  Sr  Sr3  1  0.749  0.752  0.274  1.0
  Sr  Sr4  1  0.728  0.254  0.739  1.0
  Sr  Sr5  1  0.254  0.728  0.239  1.0
  Sr  Sr6  1  0.762  0.237  0.250  1.0
  Sr  Sr7  1  0.237  0.762  0.750  1.0
  Sr  Sr8  1  0.247  0.254  0.724  1.0
  Sr  Sr9  1  0.254  0.247  0.224  1.0
  W  W10  1  0.997  0.496  0.999  1.0
  W  W11  1  0.496  0.997  0.499  1.0
  W  W12  1  0.497  0.501  0.999  1.0
  W  W13  1  0.501  0.497  0.499  1.0
  W  W14  1  0.003  0.997  0.997  1.0
  W  W15  1  0.997  0.003  0.497  1.0
  O  O16  1  0.550  0.960  0.666  1.0
  O  O17  1  0.960  0.550  0.166  1.0
  O  O18  1  0.503  0.249  0.543  1.0
  O  O19  1  0.249  0.503  0.043  1.0
  O  O20  1  0.005  0.749  0.956  1.0
  O  O21  1  0.749  0.005  0.456  1.0
  O  O22  1  0.471  0.330  0.872  1.0
  O  O23  1  0.330  0.471  0.372  1.0
  O  O24  1  0.971  0.834  0.625  1.0
  O  O25  1  0.834  0.971  0.125  1.0
  O  O26  1  0.303  0.530  0.607  1.0
  O  O27  1  0.530  0.303  0.107  1.0
  O  O28  1  0.808  0.029  0.888  1.0
  O  O29  1  0.029  0.808  0.388  1.0
  O  O30  1  0.697  0.475  0.389  1.0
  O  O31  1  0.475  0.697  0.889  1.0
  O  O32  1  0.201  0.975  0.107  1.0
  O  O33  1  0.975  0.201  0.607  1.0
  O  O34  1  0.532  0.670  0.124  1.0
  O  O35  1  0.670  0.532  0.624  1.0
  O  O36  1  0.032  0.176  0.372  1.0
  O  O37  1  0.176  0.032  0.872  1.0
  O  O38  1  0.753  0.496  0.956  1.0
  O  O39  1  0.496  0.753  0.456  1.0
  O  O40  1  0.252  0.998  0.542  1.0
  O  O41  1  0.998  0.252  0.042  1.0
  O  O42  1  0.051  0.464  0.832  1.0
  O  O43  1  0.464  0.051  0.332  1.0
[/CIF]
.
The material structure described by Sr5W3O14 crystallizes in the monoclinic Cc space group. There are five inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a distorted body-centered cubic geometry to one O(10), one O(11), one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. In the second Sr site, Sr(2) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(12), one O(3), one O(5), one O(7), and one O(8) atom. In the third Sr site, Sr(3) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(12), one O(14), one O(2), one O(4), one O(7), and one O(9) atom. In the fourth Sr site, Sr(4) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(13), one O(14), one O(3), one O(5), one O(6), and one O(8) atom. In the fifth Sr site, Sr(5) is bonded in a 7-coordinate geometry to one O(11), one O(13), one O(14), one O(2), one O(4), one O(6), and one O(9) atom. There are three inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(12), one O(13), one O(14), one O(2), and one O(3) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 27-29°. In the second W site, W(2) is bonded to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(8) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 28-29°. In the third W site, W(3) is bonded to one O(11), one O(13), one O(3), one O(5), one O(7), and one O(9) atom to form corner-sharing WO6 octahedra. The corner-sharing octahedral tilt angles range from 27-28°. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one Sr(4), and one W(1) atom. In the second O site, O(2) is bonded in a 4-coordinate geometry to one Sr(3), one Sr(5), one W(1), and one W(2) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(4), one W(1), and one W(3) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Sr(1), one Sr(3), one Sr(5), and one W(2) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Sr(4), and one W(3) atom. In the sixth O site, O(6) is bonded to one Sr(1), one Sr(4), one Sr(5), and one W(2) atom to form a mixture of distorted corner and edge-sharing OSr3W tetrahedra. In the seventh O site, O(7) is bonded in a distorted rectangular see-saw-like geometry to one Sr(1), one Sr(2), one Sr(3), and one W(3) atom. In the eighth O site, O(8) is bonded to one Sr(1), one Sr(2), one Sr(4), and one W(2) atom to form distorted corner-sharing OSr3W tetrahedra. In the ninth O site, O(9) is bonded to one Sr(1), one Sr(3), one Sr(5), and one W(3) atom to form a mixture of distorted corner and edge-sharing OSr3W tetrahedra. In the tenth O site, O(10) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(2), one Sr(3), and one W(2) atom. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Sr(1), one Sr(4), one Sr(5), and one W(3) atom. In the twelfth O site, O(12) is bonded in a 4-coordinate geometry to one Sr(2), one Sr(3), one W(1), and one W(2) atom. In the thirteenth O site, O(13) is bonded in a 4-coordinate geometry to one Sr(4), one Sr(5), one W(1), and one W(3) atom. In the fourteenth O site, O(14) is bonded in a 2-coordinate geometry to one Sr(3), one Sr(4), one Sr(5), and one W(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sr5W3O14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.688
_cell_length_b   7.688
_cell_length_c   11.075
_cell_angle_alpha   89.922
_cell_angle_beta   89.922
_cell_angle_gamma   89.583
_symmetry_Int_Tables_number   1
_cell_volume   654.651
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.007  0.501  0.495  1.0
  Sr  Sr1  1  0.501  0.007  0.995  1.0
  Sr  Sr2  1  0.752  0.749  0.774  1.0
  Sr  Sr3  1  0.749  0.752  0.274  1.0
  Sr  Sr4  1  0.728  0.254  0.739  1.0
  Sr  Sr5  1  0.254  0.728  0.239  1.0
  Sr  Sr6  1  0.762  0.237  0.250  1.0
  Sr  Sr7  1  0.237  0.762  0.750  1.0
  Sr  Sr8  1  0.247  0.254  0.724  1.0
  Sr  Sr9  1  0.254  0.247  0.224  1.0
  W  W10  1  0.997  0.496  0.999  1.0
  W  W11  1  0.496  0.997  0.499  1.0
  W  W12  1  0.497  0.501  0.999  1.0
  W  W13  1  0.501  0.497  0.499  1.0
  W  W14  1  0.003  0.997  0.997  1.0
  W  W15  1  0.997  0.003  0.497  1.0
  O  O16  1  0.550  0.960  0.666  1.0
  O  O17  1  0.960  0.550  0.166  1.0
  O  O18  1  0.503  0.249  0.543  1.0
  O  O19  1  0.249  0.503  0.043  1.0
  O  O20  1  0.005  0.749  0.956  1.0
  O  O21  1  0.749  0.005  0.456  1.0
  O  O22  1  0.471  0.330  0.872  1.0
  O  O23  1  0.330  0.471  0.372  1.0
  O  O24  1  0.971  0.834  0.625  1.0
  O  O25  1  0.834  0.971  0.125  1.0
  O  O26  1  0.303  0.530  0.607  1.0
  O  O27  1  0.530  0.303  0.107  1.0
  O  O28  1  0.808  0.029  0.888  1.0
  O  O29  1  0.029  0.808  0.388  1.0
  O  O30  1  0.697  0.475  0.389  1.0
  O  O31  1  0.475  0.697  0.889  1.0
  O  O32  1  0.201  0.975  0.107  1.0
  O  O33  1  0.975  0.201  0.607  1.0
  O  O34  1  0.532  0.670  0.124  1.0
  O  O35  1  0.670  0.532  0.624  1.0
  O  O36  1  0.032  0.176  0.372  1.0
  O  O37  1  0.176  0.032  0.872  1.0
  O  O38  1  0.753  0.496  0.956  1.0
  O  O39  1  0.496  0.753  0.456  1.0
  O  O40  1  0.252  0.998  0.542  1.0
  O  O41  1  0.998  0.252  0.042  1.0
  O  O42  1  0.051  0.464  0.832  1.0
  O  O43  1  0.464  0.051  0.332  1.0
[/CIF]
.