The structure described by CsCHO3 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 10-coordinate geometry to one H(1), two equivalent O(3), three equivalent O(2), and four equivalent O(1) atoms. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. H(1) is bonded in a distorted linear geometry to one Cs(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to three equivalent Cs(1), one C(1), and one H(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to two equivalent Cs(1), one C(1), and one H(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsHCO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.783
_cell_length_b   8.406
_cell_length_c   11.265
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   110.852
_symmetry_Int_Tables_number   1
_cell_volume   423.251
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.654  0.085  0.824  1.0
  Cs  Cs1  1  0.154  0.585  0.676  1.0
  Cs  Cs2  1  0.346  0.915  0.176  1.0
  Cs  Cs3  1  0.846  0.415  0.324  1.0
  H  H4  1  0.500  0.497  0.903  1.0
  H  H5  1  0.000  0.997  0.597  1.0
  H  H6  1  0.500  0.503  0.097  1.0
  H  H7  1  1.000  0.003  0.403  1.0
  C  C8  1  0.862  0.691  0.952  1.0
  C  C9  1  0.362  0.191  0.548  1.0
  C  C10  1  0.138  0.309  0.048  1.0
  C  C11  1  0.638  0.809  0.452  1.0
  O  O12  1  0.096  0.808  0.917  1.0
  O  O13  1  0.596  0.308  0.583  1.0
  O  O14  1  0.904  0.192  0.083  1.0
  O  O15  1  0.404  0.692  0.417  1.0
  O  O16  1  0.783  0.656  0.061  1.0
  O  O17  1  0.283  0.156  0.439  1.0
  O  O18  1  0.217  0.344  0.939  1.0
  O  O19  1  0.717  0.844  0.561  1.0
  O  O20  1  0.678  0.593  0.866  1.0
  O  O21  1  0.178  0.093  0.634  1.0
  O  O22  1  0.322  0.407  0.134  1.0
  O  O23  1  0.822  0.907  0.366  1.0
[/CIF]
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The structure described by CsCHO3 crystallizes in the monoclinic P2_1/c space group. Cs(1) is bonded in a 10-coordinate geometry to one H(1), two equivalent O(3), three equivalent O(2), and four equivalent O(1) atoms. C(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. H(1) is bonded in a distorted linear geometry to one Cs(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to four equivalent Cs(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to three equivalent Cs(1), one C(1), and one H(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to two equivalent Cs(1), one C(1), and one H(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CsHCO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.783
_cell_length_b   8.406
_cell_length_c   11.265
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   110.852
_symmetry_Int_Tables_number   1
_cell_volume   423.251
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.654  0.085  0.824  1.0
  Cs  Cs1  1  0.154  0.585  0.676  1.0
  Cs  Cs2  1  0.346  0.915  0.176  1.0
  Cs  Cs3  1  0.846  0.415  0.324  1.0
  H  H4  1  0.500  0.497  0.903  1.0
  H  H5  1  0.000  0.997  0.597  1.0
  H  H6  1  0.500  0.503  0.097  1.0
  H  H7  1  1.000  0.003  0.403  1.0
  C  C8  1  0.862  0.691  0.952  1.0
  C  C9  1  0.362  0.191  0.548  1.0
  C  C10  1  0.138  0.309  0.048  1.0
  C  C11  1  0.638  0.809  0.452  1.0
  O  O12  1  0.096  0.808  0.917  1.0
  O  O13  1  0.596  0.308  0.583  1.0
  O  O14  1  0.904  0.192  0.083  1.0
  O  O15  1  0.404  0.692  0.417  1.0
  O  O16  1  0.783  0.656  0.061  1.0
  O  O17  1  0.283  0.156  0.439  1.0
  O  O18  1  0.217  0.344  0.939  1.0
  O  O19  1  0.717  0.844  0.561  1.0
  O  O20  1  0.678  0.593  0.866  1.0
  O  O21  1  0.178  0.093  0.634  1.0
  O  O22  1  0.322  0.407  0.134  1.0
  O  O23  1  0.822  0.907  0.366  1.0
[/CIF]
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