The crystal structure described by (CF2)2(CF3)2C2Te(ClF2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight difluoromethane molecules, eight trifluoromethane molecules, and four C2Te(ClF2)2 clusters. In each C2Te(ClF2)2 cluster, C(3) is bonded in a distorted water-like geometry to one Te(1), one F(1), and one F(3) atom. Te(1) is bonded in a rectangular see-saw-like geometry to two equivalent C(3) and two equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one Te(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(3) atom. In the second F site, F(3) is bonded in a single-bond geometry to one C(3) atom. is represented by the CIF file [CIF]
data_TeC6(ClF7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.989
_cell_length_b   10.989
_cell_length_c   8.388
_cell_angle_alpha   75.514
_cell_angle_beta   75.514
_cell_angle_gamma   50.687
_symmetry_Int_Tables_number   1
_cell_volume   752.982
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.361  0.639  0.250  1.0
  Te  Te1  1  0.639  0.361  0.750  1.0
  C  C2  1  0.118  0.592  0.191  1.0
  C  C3  1  0.621  0.955  0.716  1.0
  C  C4  1  0.109  0.734  0.215  1.0
  C  C5  1  0.882  0.408  0.809  1.0
  C  C6  1  0.045  0.379  0.784  1.0
  C  C7  1  0.408  0.882  0.309  1.0
  C  C8  1  0.891  0.266  0.785  1.0
  C  C9  1  0.592  0.118  0.691  1.0
  C  C10  1  0.379  0.045  0.284  1.0
  C  C11  1  0.734  0.109  0.715  1.0
  C  C12  1  0.266  0.891  0.285  1.0
  C  C13  1  0.955  0.621  0.216  1.0
  Cl  Cl14  1  0.603  0.282  0.054  1.0
  Cl  Cl15  1  0.282  0.603  0.554  1.0
  Cl  Cl16  1  0.718  0.397  0.446  1.0
  Cl  Cl17  1  0.397  0.718  0.946  1.0
  F  F18  1  0.155  0.942  0.418  1.0
  F  F19  1  0.251  0.143  0.387  1.0
  F  F20  1  0.992  0.199  0.649  1.0
  F  F21  1  0.493  0.980  0.681  1.0
  F  F22  1  0.058  0.845  0.082  1.0
  F  F23  1  0.446  0.812  0.466  1.0
  F  F24  1  0.199  0.992  0.149  1.0
  F  F25  1  0.535  0.789  0.198  1.0
  F  F26  1  0.801  0.008  0.851  1.0
  F  F27  1  0.008  0.801  0.351  1.0
  F  F28  1  0.143  0.251  0.887  1.0
  F  F29  1  0.812  0.446  0.966  1.0
  F  F30  1  0.857  0.750  0.113  1.0
  F  F31  1  0.789  0.535  0.698  1.0
  F  F32  1  0.645  0.886  0.874  1.0
  F  F33  1  0.355  0.114  0.126  1.0
  F  F34  1  0.750  0.857  0.613  1.0
  F  F35  1  0.211  0.465  0.302  1.0
  F  F36  1  0.020  0.507  0.819  1.0
  F  F37  1  0.554  0.188  0.534  1.0
  F  F38  1  0.507  0.020  0.319  1.0
  F  F39  1  0.188  0.554  0.034  1.0
  F  F40  1  0.465  0.211  0.802  1.0
  F  F41  1  0.942  0.155  0.918  1.0
  F  F42  1  0.886  0.645  0.374  1.0
  F  F43  1  0.114  0.355  0.626  1.0
  F  F44  1  0.980  0.493  0.181  1.0
  F  F45  1  0.845  0.058  0.582  1.0
[/CIF]
.
The crystal structure described by (CF2)2(CF3)2C2Te(ClF2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight difluoromethane molecules, eight trifluoromethane molecules, and four C2Te(ClF2)2 clusters. In each C2Te(ClF2)2 cluster, C(3) is bonded in a distorted water-like geometry to one Te(1), one F(1), and one F(3) atom. Te(1) is bonded in a rectangular see-saw-like geometry to two equivalent C(3) and two equivalent Cl(1) atoms. Cl(1) is bonded in a single-bond geometry to one Te(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(3) atom. In the second F site, F(3) is bonded in a single-bond geometry to one C(3) atom. is represented by the CIF file [CIF]
data_TeC6(ClF7)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   10.989
_cell_length_b   10.989
_cell_length_c   8.388
_cell_angle_alpha   75.514
_cell_angle_beta   75.514
_cell_angle_gamma   50.687
_symmetry_Int_Tables_number   1
_cell_volume   752.982
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Te  Te0  1  0.361  0.639  0.250  1.0
  Te  Te1  1  0.639  0.361  0.750  1.0
  C  C2  1  0.118  0.592  0.191  1.0
  C  C3  1  0.621  0.955  0.716  1.0
  C  C4  1  0.109  0.734  0.215  1.0
  C  C5  1  0.882  0.408  0.809  1.0
  C  C6  1  0.045  0.379  0.784  1.0
  C  C7  1  0.408  0.882  0.309  1.0
  C  C8  1  0.891  0.266  0.785  1.0
  C  C9  1  0.592  0.118  0.691  1.0
  C  C10  1  0.379  0.045  0.284  1.0
  C  C11  1  0.734  0.109  0.715  1.0
  C  C12  1  0.266  0.891  0.285  1.0
  C  C13  1  0.955  0.621  0.216  1.0
  Cl  Cl14  1  0.603  0.282  0.054  1.0
  Cl  Cl15  1  0.282  0.603  0.554  1.0
  Cl  Cl16  1  0.718  0.397  0.446  1.0
  Cl  Cl17  1  0.397  0.718  0.946  1.0
  F  F18  1  0.155  0.942  0.418  1.0
  F  F19  1  0.251  0.143  0.387  1.0
  F  F20  1  0.992  0.199  0.649  1.0
  F  F21  1  0.493  0.980  0.681  1.0
  F  F22  1  0.058  0.845  0.082  1.0
  F  F23  1  0.446  0.812  0.466  1.0
  F  F24  1  0.199  0.992  0.149  1.0
  F  F25  1  0.535  0.789  0.198  1.0
  F  F26  1  0.801  0.008  0.851  1.0
  F  F27  1  0.008  0.801  0.351  1.0
  F  F28  1  0.143  0.251  0.887  1.0
  F  F29  1  0.812  0.446  0.966  1.0
  F  F30  1  0.857  0.750  0.113  1.0
  F  F31  1  0.789  0.535  0.698  1.0
  F  F32  1  0.645  0.886  0.874  1.0
  F  F33  1  0.355  0.114  0.126  1.0
  F  F34  1  0.750  0.857  0.613  1.0
  F  F35  1  0.211  0.465  0.302  1.0
  F  F36  1  0.020  0.507  0.819  1.0
  F  F37  1  0.554  0.188  0.534  1.0
  F  F38  1  0.507  0.020  0.319  1.0
  F  F39  1  0.188  0.554  0.034  1.0
  F  F40  1  0.465  0.211  0.802  1.0
  F  F41  1  0.942  0.155  0.918  1.0
  F  F42  1  0.886  0.645  0.374  1.0
  F  F43  1  0.114  0.355  0.626  1.0
  F  F44  1  0.980  0.493  0.181  1.0
  F  F45  1  0.845  0.058  0.582  1.0
[/CIF]
.