The crystal structure described by VOF crystallizes in the orthorhombic Fddd space group. V(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing VO4F2 pentagonal pyramids. O(1) is bonded to four equivalent V(1) atoms to form a mixture of corner and edge-sharing OV4 tetrahedra. F(1) is bonded in a linear geometry to two equivalent V(1) atoms. is represented by the CIF card [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.280
_cell_length_b   5.920
_cell_length_c   5.227
_cell_angle_alpha   68.250
_cell_angle_beta   61.115
_cell_angle_gamma   50.636
_symmetry_Int_Tables_number   1
_cell_volume   130.972
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.699  0.301  0.699  1.0
  V  V1  1  0.949  0.551  0.949  1.0
  V  V2  1  0.301  0.699  0.301  1.0
  V  V3  1  0.551  0.949  0.551  1.0
  O  O4  1  0.366  0.366  0.634  1.0
  O  O5  1  0.634  0.634  0.366  1.0
  O  O6  1  0.616  0.616  0.884  1.0
  O  O7  1  0.884  0.884  0.616  1.0
  F  F8  1  0.625  0.125  0.125  1.0
  F  F9  1  0.125  0.625  0.125  1.0
  F  F10  1  0.125  0.125  0.125  1.0
  F  F11  1  0.125  0.125  0.625  1.0
[/CIF]
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The crystal structure described by VOF crystallizes in the orthorhombic Fddd space group. V(1) is bonded to four equivalent O(1) and two equivalent F(1) atoms to form a mixture of distorted corner and edge-sharing VO4F2 pentagonal pyramids. O(1) is bonded to four equivalent V(1) atoms to form a mixture of corner and edge-sharing OV4 tetrahedra. F(1) is bonded in a linear geometry to two equivalent V(1) atoms. is represented by the CIF card [CIF]
data_VOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.280
_cell_length_b   5.920
_cell_length_c   5.227
_cell_angle_alpha   68.250
_cell_angle_beta   61.115
_cell_angle_gamma   50.636
_symmetry_Int_Tables_number   1
_cell_volume   130.972
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.699  0.301  0.699  1.0
  V  V1  1  0.949  0.551  0.949  1.0
  V  V2  1  0.301  0.699  0.301  1.0
  V  V3  1  0.551  0.949  0.551  1.0
  O  O4  1  0.366  0.366  0.634  1.0
  O  O5  1  0.634  0.634  0.366  1.0
  O  O6  1  0.616  0.616  0.884  1.0
  O  O7  1  0.884  0.884  0.616  1.0
  F  F8  1  0.625  0.125  0.125  1.0
  F  F9  1  0.125  0.625  0.125  1.0
  F  F10  1  0.125  0.125  0.125  1.0
  F  F11  1  0.125  0.125  0.625  1.0
[/CIF]
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