The crystal structure described by Bi2P3(PbO4)3 crystallizes in the hexagonal P6_3/m space group. Pb(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. Bi(1) is bonded in a 6-coordinate geometry to three equivalent O(2) and three equivalent O(3) atoms. P(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Bi(1) and one P(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to two equivalent Pb(1) and one P(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one Pb(1), two equivalent Bi(1), and one P(1) atom. is represented by the CIF card [CIF]
data_Bi2P3(PbO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.787
_cell_length_b   9.787
_cell_length_c   7.511
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   623.055
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.333  0.667  0.999  1.0
  Bi  Bi1  1  0.667  0.333  0.001  1.0
  Bi  Bi2  1  0.667  0.333  0.499  1.0
  Bi  Bi3  1  0.333  0.667  0.501  1.0
  P  P4  1  0.404  0.032  0.250  1.0
  P  P5  1  0.596  0.968  0.750  1.0
  P  P6  1  0.968  0.372  0.250  1.0
  P  P7  1  0.032  0.628  0.750  1.0
  P  P8  1  0.628  0.596  0.250  1.0
  P  P9  1  0.372  0.404  0.750  1.0
  Pb  Pb10  1  0.221  0.225  0.250  1.0
  Pb  Pb11  1  0.779  0.775  0.750  1.0
  Pb  Pb12  1  0.775  0.996  0.250  1.0
  Pb  Pb13  1  0.225  0.004  0.750  1.0
  Pb  Pb14  1  0.004  0.779  0.250  1.0
  Pb  Pb15  1  0.996  0.221  0.750  1.0
  O  O16  1  0.344  0.079  0.082  1.0
  O  O17  1  0.656  0.921  0.918  1.0
  O  O18  1  0.921  0.265  0.082  1.0
  O  O19  1  0.656  0.921  0.582  1.0
  O  O20  1  0.079  0.735  0.918  1.0
  O  O21  1  0.344  0.079  0.418  1.0
  O  O22  1  0.735  0.656  0.082  1.0
  O  O23  1  0.079  0.735  0.582  1.0
  O  O24  1  0.265  0.344  0.918  1.0
  O  O25  1  0.921  0.265  0.418  1.0
  O  O26  1  0.265  0.344  0.582  1.0
  O  O27  1  0.735  0.656  0.418  1.0
  O  O28  1  0.591  0.137  0.250  1.0
  O  O29  1  0.409  0.863  0.750  1.0
  O  O30  1  0.863  0.454  0.250  1.0
  O  O31  1  0.137  0.546  0.750  1.0
  O  O32  1  0.546  0.409  0.250  1.0
  O  O33  1  0.454  0.591  0.750  1.0
  O  O34  1  0.147  0.499  0.250  1.0
  O  O35  1  0.853  0.501  0.750  1.0
  O  O36  1  0.501  0.648  0.250  1.0
  O  O37  1  0.499  0.352  0.750  1.0
  O  O38  1  0.352  0.853  0.250  1.0
  O  O39  1  0.648  0.147  0.750  1.0
[/CIF]
.
The crystal structure described by Bi2P3(PbO4)3 crystallizes in the hexagonal P6_3/m space group. Pb(1) is bonded in a 5-coordinate geometry to one O(2) and four equivalent O(1) atoms. Bi(1) is bonded in a 6-coordinate geometry to three equivalent O(2) and three equivalent O(3) atoms. P(1) is bonded in a tetrahedral geometry to one O(2), one O(3), and two equivalent O(1) atoms. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Bi(1) and one P(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to two equivalent Pb(1) and one P(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one Pb(1), two equivalent Bi(1), and one P(1) atom. is represented by the CIF card [CIF]
data_Bi2P3(PbO4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.787
_cell_length_b   9.787
_cell_length_c   7.511
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   623.055
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.333  0.667  0.999  1.0
  Bi  Bi1  1  0.667  0.333  0.001  1.0
  Bi  Bi2  1  0.667  0.333  0.499  1.0
  Bi  Bi3  1  0.333  0.667  0.501  1.0
  P  P4  1  0.404  0.032  0.250  1.0
  P  P5  1  0.596  0.968  0.750  1.0
  P  P6  1  0.968  0.372  0.250  1.0
  P  P7  1  0.032  0.628  0.750  1.0
  P  P8  1  0.628  0.596  0.250  1.0
  P  P9  1  0.372  0.404  0.750  1.0
  Pb  Pb10  1  0.221  0.225  0.250  1.0
  Pb  Pb11  1  0.779  0.775  0.750  1.0
  Pb  Pb12  1  0.775  0.996  0.250  1.0
  Pb  Pb13  1  0.225  0.004  0.750  1.0
  Pb  Pb14  1  0.004  0.779  0.250  1.0
  Pb  Pb15  1  0.996  0.221  0.750  1.0
  O  O16  1  0.344  0.079  0.082  1.0
  O  O17  1  0.656  0.921  0.918  1.0
  O  O18  1  0.921  0.265  0.082  1.0
  O  O19  1  0.656  0.921  0.582  1.0
  O  O20  1  0.079  0.735  0.918  1.0
  O  O21  1  0.344  0.079  0.418  1.0
  O  O22  1  0.735  0.656  0.082  1.0
  O  O23  1  0.079  0.735  0.582  1.0
  O  O24  1  0.265  0.344  0.918  1.0
  O  O25  1  0.921  0.265  0.418  1.0
  O  O26  1  0.265  0.344  0.582  1.0
  O  O27  1  0.735  0.656  0.418  1.0
  O  O28  1  0.591  0.137  0.250  1.0
  O  O29  1  0.409  0.863  0.750  1.0
  O  O30  1  0.863  0.454  0.250  1.0
  O  O31  1  0.137  0.546  0.750  1.0
  O  O32  1  0.546  0.409  0.250  1.0
  O  O33  1  0.454  0.591  0.750  1.0
  O  O34  1  0.147  0.499  0.250  1.0
  O  O35  1  0.853  0.501  0.750  1.0
  O  O36  1  0.501  0.648  0.250  1.0
  O  O37  1  0.499  0.352  0.750  1.0
  O  O38  1  0.352  0.853  0.250  1.0
  O  O39  1  0.648  0.147  0.750  1.0
[/CIF]
.