The crystal structure described by LiPr(MoO4)2 crystallizes in the monoclinic P2/c space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(3) and two equivalent O(4) atoms. Pr(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Mo(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Pr(1) and two equivalent Mo(1) atoms. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Pr(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Li(1), one Pr(1), and two equivalent Mo(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Pr(1), and one Mo(1) atom. is represented by the CIF file [CIF]
data_LiPr(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.009
_cell_length_b   5.118
_cell_length_c   11.203
_cell_angle_alpha   67.966
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   319.368
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.716  0.000  0.750  1.0
  Li  Li1  1  0.284  0.000  0.250  1.0
  Pr  Pr2  1  0.285  0.500  0.750  1.0
  Pr  Pr3  1  0.715  0.500  0.250  1.0
  Mo  Mo4  1  0.819  0.736  0.523  1.0
  Mo  Mo5  1  0.181  0.264  0.477  1.0
  Mo  Mo6  1  0.819  0.264  0.977  1.0
  Mo  Mo7  1  0.181  0.736  0.023  1.0
  O  O8  1  0.899  0.863  0.092  1.0
  O  O9  1  0.101  0.137  0.908  1.0
  O  O10  1  0.899  0.137  0.408  1.0
  O  O11  1  0.101  0.863  0.592  1.0
  O  O12  1  0.364  0.723  0.898  1.0
  O  O13  1  0.636  0.277  0.102  1.0
  O  O14  1  0.364  0.277  0.602  1.0
  O  O15  1  0.636  0.723  0.398  1.0
  O  O16  1  0.913  0.632  0.887  1.0
  O  O17  1  0.087  0.368  0.113  1.0
  O  O18  1  0.913  0.368  0.613  1.0
  O  O19  1  0.087  0.632  0.387  1.0
  O  O20  1  0.631  0.780  0.638  1.0
  O  O21  1  0.369  0.220  0.362  1.0
  O  O22  1  0.631  0.220  0.862  1.0
  O  O23  1  0.369  0.780  0.138  1.0
[/CIF]
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The crystal structure described by LiPr(MoO4)2 crystallizes in the monoclinic P2/c space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent O(3) and two equivalent O(4) atoms. Pr(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Mo(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), two equivalent O(1), and two equivalent O(3) atoms. There are four inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Pr(1) and two equivalent Mo(1) atoms. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Pr(1) and one Mo(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Li(1), one Pr(1), and two equivalent Mo(1) atoms. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Li(1), one Pr(1), and one Mo(1) atom. is represented by the CIF file [CIF]
data_LiPr(MoO4)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.009
_cell_length_b   5.118
_cell_length_c   11.203
_cell_angle_alpha   67.966
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   319.368
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.716  0.000  0.750  1.0
  Li  Li1  1  0.284  0.000  0.250  1.0
  Pr  Pr2  1  0.285  0.500  0.750  1.0
  Pr  Pr3  1  0.715  0.500  0.250  1.0
  Mo  Mo4  1  0.819  0.736  0.523  1.0
  Mo  Mo5  1  0.181  0.264  0.477  1.0
  Mo  Mo6  1  0.819  0.264  0.977  1.0
  Mo  Mo7  1  0.181  0.736  0.023  1.0
  O  O8  1  0.899  0.863  0.092  1.0
  O  O9  1  0.101  0.137  0.908  1.0
  O  O10  1  0.899  0.137  0.408  1.0
  O  O11  1  0.101  0.863  0.592  1.0
  O  O12  1  0.364  0.723  0.898  1.0
  O  O13  1  0.636  0.277  0.102  1.0
  O  O14  1  0.364  0.277  0.602  1.0
  O  O15  1  0.636  0.723  0.398  1.0
  O  O16  1  0.913  0.632  0.887  1.0
  O  O17  1  0.087  0.368  0.113  1.0
  O  O18  1  0.913  0.368  0.613  1.0
  O  O19  1  0.087  0.632  0.387  1.0
  O  O20  1  0.631  0.780  0.638  1.0
  O  O21  1  0.369  0.220  0.362  1.0
  O  O22  1  0.631  0.220  0.862  1.0
  O  O23  1  0.369  0.780  0.138  1.0
[/CIF]
.