The structure described by K2PdN2(O2Cl)2 crystallizes in the triclinic P-1 space group. K(1) is bonded to two equivalent O(2), three equivalent O(1), and three equivalent Cl(1) atoms to form distorted edge-sharing KCl3O5 hexagonal bipyramids. Pd(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent Cl(1) atoms. N(1) is bonded in a trigonal planar geometry to one Pd(1), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to three equivalent K(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. Cl(1) is bonded to three equivalent K(1) and one Pd(1) atom to form a mixture of distorted corner and edge-sharing ClK3Pd trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2PdN2(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.732
_cell_length_b   7.060
_cell_length_c   7.878
_cell_angle_alpha   67.342
_cell_angle_beta   75.087
_cell_angle_gamma   81.191
_symmetry_Int_Tables_number   1
_cell_volume   234.262
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.857  0.323  0.332  1.0
  K  K1  1  0.143  0.677  0.668  1.0
  Pd  Pd2  1  0.500  0.000  0.000  1.0
  N  N3  1  0.700  0.274  0.872  1.0
  N  N4  1  0.300  0.726  0.128  1.0
  Cl  Cl5  1  0.436  0.029  0.293  1.0
  Cl  Cl6  1  0.564  0.971  0.707  1.0
  O  O7  1  0.665  0.397  0.713  1.0
  O  O8  1  0.139  0.680  0.048  1.0
  O  O9  1  0.861  0.320  0.952  1.0
  O  O10  1  0.335  0.603  0.287  1.0
[/CIF]
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The structure described by K2PdN2(O2Cl)2 crystallizes in the triclinic P-1 space group. K(1) is bonded to two equivalent O(2), three equivalent O(1), and three equivalent Cl(1) atoms to form distorted edge-sharing KCl3O5 hexagonal bipyramids. Pd(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent Cl(1) atoms. N(1) is bonded in a trigonal planar geometry to one Pd(1), one O(1), and one O(2) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to three equivalent K(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent K(1) and one N(1) atom. Cl(1) is bonded to three equivalent K(1) and one Pd(1) atom to form a mixture of distorted corner and edge-sharing ClK3Pd trigonal pyramids. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2PdN2(ClO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.732
_cell_length_b   7.060
_cell_length_c   7.878
_cell_angle_alpha   67.342
_cell_angle_beta   75.087
_cell_angle_gamma   81.191
_symmetry_Int_Tables_number   1
_cell_volume   234.262
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.857  0.323  0.332  1.0
  K  K1  1  0.143  0.677  0.668  1.0
  Pd  Pd2  1  0.500  0.000  0.000  1.0
  N  N3  1  0.700  0.274  0.872  1.0
  N  N4  1  0.300  0.726  0.128  1.0
  Cl  Cl5  1  0.436  0.029  0.293  1.0
  Cl  Cl6  1  0.564  0.971  0.707  1.0
  O  O7  1  0.665  0.397  0.713  1.0
  O  O8  1  0.139  0.680  0.048  1.0
  O  O9  1  0.861  0.320  0.952  1.0
  O  O10  1  0.335  0.603  0.287  1.0
[/CIF]
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