The compound described by Nd(NiBi)2 crystallizes in the tetragonal P4/nmm space group. Nd(1) is bonded in a 17-coordinate geometry to four equivalent Ni(1), four equivalent Ni(2), four equivalent Bi(2), and five equivalent Bi(1) atoms. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 5-coordinate geometry to four equivalent Nd(1), one Bi(1), and four equivalent Bi(2) atoms. In the second Ni site, Ni(2) is bonded in a 8-coordinate geometry to four equivalent Nd(1) and four equivalent Bi(1) atoms. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 5-coordinate geometry to five equivalent Nd(1), one Ni(1), and four equivalent Ni(2) atoms. In the second Bi site, Bi(2) is bonded in a 8-coordinate geometry to four equivalent Nd(1) and four equivalent Ni(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Nd(NiBi)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.683
_cell_length_b   4.683
_cell_length_c   10.207
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   223.816
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.500  0.000  0.767  1.0
  Nd  Nd1  1  0.000  0.500  0.233  1.0
  Ni  Ni2  1  0.500  0.000  0.376  1.0
  Ni  Ni3  1  0.000  0.500  0.624  1.0
  Ni  Ni4  1  0.000  0.000  0.000  1.0
  Ni  Ni5  1  0.500  0.500  0.000  1.0
  Bi  Bi6  1  0.500  0.000  0.125  1.0
  Bi  Bi7  1  0.000  0.500  0.875  1.0
  Bi  Bi8  1  0.000  0.000  0.500  1.0
  Bi  Bi9  1  0.500  0.500  0.500  1.0
[/CIF]
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The compound described by Nd(NiBi)2 crystallizes in the tetragonal P4/nmm space group. Nd(1) is bonded in a 17-coordinate geometry to four equivalent Ni(1), four equivalent Ni(2), four equivalent Bi(2), and five equivalent Bi(1) atoms. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 5-coordinate geometry to four equivalent Nd(1), one Bi(1), and four equivalent Bi(2) atoms. In the second Ni site, Ni(2) is bonded in a 8-coordinate geometry to four equivalent Nd(1) and four equivalent Bi(1) atoms. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 5-coordinate geometry to five equivalent Nd(1), one Ni(1), and four equivalent Ni(2) atoms. In the second Bi site, Bi(2) is bonded in a 8-coordinate geometry to four equivalent Nd(1) and four equivalent Ni(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_Nd(NiBi)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.683
_cell_length_b   4.683
_cell_length_c   10.207
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   223.816
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Nd  Nd0  1  0.500  0.000  0.767  1.0
  Nd  Nd1  1  0.000  0.500  0.233  1.0
  Ni  Ni2  1  0.500  0.000  0.376  1.0
  Ni  Ni3  1  0.000  0.500  0.624  1.0
  Ni  Ni4  1  0.000  0.000  0.000  1.0
  Ni  Ni5  1  0.500  0.500  0.000  1.0
  Bi  Bi6  1  0.500  0.000  0.125  1.0
  Bi  Bi7  1  0.000  0.500  0.875  1.0
  Bi  Bi8  1  0.000  0.000  0.500  1.0
  Bi  Bi9  1  0.500  0.500  0.500  1.0
[/CIF]
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