The structure described by Pb2PtO4 crystallizes in the orthorhombic Pbam space group. Pt(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form edge-sharing PtO6 octahedra. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a distorted T-shaped geometry to one O(2) and two equivalent O(3) atoms. In the second Pb site, Pb(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Pt(1) and two equivalent Pb(2) atoms. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to two equivalent Pt(1) and one Pb(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Pt(1), one Pb(1), and one Pb(2) atom. is represented by the CIF card [CIF]
data_Pt(PbO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.337
_cell_length_b   7.972
_cell_length_c   9.145
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   462.004
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.749  0.500  0.500  1.0
  Pt  Pt1  1  0.251  0.000  0.000  1.0
  Pt  Pt2  1  0.251  0.500  0.500  1.0
  Pt  Pt3  1  0.749  0.000  0.000  1.0
  Pb  Pb4  1  0.500  0.139  0.656  1.0
  Pb  Pb5  1  0.500  0.861  0.344  1.0
  Pb  Pb6  1  0.500  0.639  0.844  1.0
  Pb  Pb7  1  0.500  0.361  0.156  1.0
  Pb  Pb8  1  0.000  0.609  0.173  1.0
  Pb  Pb9  1  0.000  0.391  0.827  1.0
  Pb  Pb10  1  0.000  0.109  0.327  1.0
  Pb  Pb11  1  0.000  0.891  0.673  1.0
  O  O12  1  0.000  0.608  0.604  1.0
  O  O13  1  0.000  0.392  0.396  1.0
  O  O14  1  0.000  0.108  0.896  1.0
  O  O15  1  0.000  0.892  0.104  1.0
  O  O16  1  0.500  0.626  0.589  1.0
  O  O17  1  0.500  0.374  0.411  1.0
  O  O18  1  0.500  0.126  0.911  1.0
  O  O19  1  0.500  0.874  0.089  1.0
  O  O20  1  0.750  0.333  0.666  1.0
  O  O21  1  0.750  0.667  0.334  1.0
  O  O22  1  0.250  0.833  0.834  1.0
  O  O23  1  0.250  0.167  0.166  1.0
  O  O24  1  0.750  0.833  0.834  1.0
  O  O25  1  0.750  0.167  0.166  1.0
  O  O26  1  0.250  0.333  0.666  1.0
  O  O27  1  0.250  0.667  0.334  1.0
[/CIF]
.
The structure described by Pb2PtO4 crystallizes in the orthorhombic Pbam space group. Pt(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form edge-sharing PtO6 octahedra. There are two inequivalent Pb sites. In the first Pb site, Pb(1) is bonded in a distorted T-shaped geometry to one O(2) and two equivalent O(3) atoms. In the second Pb site, Pb(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to two equivalent Pt(1) and two equivalent Pb(2) atoms. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to two equivalent Pt(1) and one Pb(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Pt(1), one Pb(1), and one Pb(2) atom. is represented by the CIF card [CIF]
data_Pt(PbO2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.337
_cell_length_b   7.972
_cell_length_c   9.145
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   462.004
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pt  Pt0  1  0.749  0.500  0.500  1.0
  Pt  Pt1  1  0.251  0.000  0.000  1.0
  Pt  Pt2  1  0.251  0.500  0.500  1.0
  Pt  Pt3  1  0.749  0.000  0.000  1.0
  Pb  Pb4  1  0.500  0.139  0.656  1.0
  Pb  Pb5  1  0.500  0.861  0.344  1.0
  Pb  Pb6  1  0.500  0.639  0.844  1.0
  Pb  Pb7  1  0.500  0.361  0.156  1.0
  Pb  Pb8  1  0.000  0.609  0.173  1.0
  Pb  Pb9  1  0.000  0.391  0.827  1.0
  Pb  Pb10  1  0.000  0.109  0.327  1.0
  Pb  Pb11  1  0.000  0.891  0.673  1.0
  O  O12  1  0.000  0.608  0.604  1.0
  O  O13  1  0.000  0.392  0.396  1.0
  O  O14  1  0.000  0.108  0.896  1.0
  O  O15  1  0.000  0.892  0.104  1.0
  O  O16  1  0.500  0.626  0.589  1.0
  O  O17  1  0.500  0.374  0.411  1.0
  O  O18  1  0.500  0.126  0.911  1.0
  O  O19  1  0.500  0.874  0.089  1.0
  O  O20  1  0.750  0.333  0.666  1.0
  O  O21  1  0.750  0.667  0.334  1.0
  O  O22  1  0.250  0.833  0.834  1.0
  O  O23  1  0.250  0.167  0.166  1.0
  O  O24  1  0.750  0.833  0.834  1.0
  O  O25  1  0.750  0.167  0.166  1.0
  O  O26  1  0.250  0.333  0.666  1.0
  O  O27  1  0.250  0.667  0.334  1.0
[/CIF]
.