The material structure described by MgMo3Zn2O8 is Corundum-derived structured and crystallizes in the monoclinic C2/m space group. Mg(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form MgO6 octahedra that share edges with two equivalent Mo(1)O6 octahedra and edges with four equivalent Mo(2)O6 octahedra. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form MoO6 octahedra that share edges with two equivalent Mg(1)O6 octahedra and edges with four equivalent Mo(2)O6 octahedra. In the second Mo site, Mo(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MoO6 octahedra that share edges with two equivalent Mg(1)O6 octahedra, edges with two equivalent Mo(1)O6 octahedra, and edges with two equivalent Mo(2)O6 octahedra. Zn(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Mg(1), two equivalent Mo(2), and one Zn(1) atom. In the second O site, O(2) is bonded to one Mo(1), two equivalent Mo(2), and one Zn(1) atom to form a mixture of distorted corner and edge-sharing OZnMo3 trigonal pyramids. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Mg(1), one Mo(1), one Mo(2), and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgZn2Mo3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.487
_cell_length_b   6.223
_cell_length_c   7.206
_cell_angle_alpha   115.578
_cell_angle_beta   119.659
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   185.549
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.500  0.500  0.000  1.0
  Zn  Zn1  1  0.801  0.722  0.444  1.0
  Zn  Zn2  1  0.199  0.278  0.556  1.0
  Mo  Mo3  1  0.500  0.000  0.000  1.0
  Mo  Mo4  1  1.000  0.741  1.000  1.0
  Mo  Mo5  1  1.000  0.259  0.000  1.0
  O  O6  1  0.054  0.394  0.789  1.0
  O  O7  1  0.946  0.606  0.211  1.0
  O  O8  1  0.036  0.896  0.793  1.0
  O  O9  1  0.964  0.104  0.207  1.0
  O  O10  1  0.480  0.352  0.204  1.0
  O  O11  1  0.480  0.852  0.204  1.0
  O  O12  1  0.520  0.148  0.796  1.0
  O  O13  1  0.520  0.648  0.796  1.0
[/CIF]
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The material structure described by MgMo3Zn2O8 is Corundum-derived structured and crystallizes in the monoclinic C2/m space group. Mg(1) is bonded to two equivalent O(1) and four equivalent O(3) atoms to form MgO6 octahedra that share edges with two equivalent Mo(1)O6 octahedra and edges with four equivalent Mo(2)O6 octahedra. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form MoO6 octahedra that share edges with two equivalent Mg(1)O6 octahedra and edges with four equivalent Mo(2)O6 octahedra. In the second Mo site, Mo(2) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form MoO6 octahedra that share edges with two equivalent Mg(1)O6 octahedra, edges with two equivalent Mo(1)O6 octahedra, and edges with two equivalent Mo(2)O6 octahedra. Zn(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), and two equivalent O(3) atoms. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Mg(1), two equivalent Mo(2), and one Zn(1) atom. In the second O site, O(2) is bonded to one Mo(1), two equivalent Mo(2), and one Zn(1) atom to form a mixture of distorted corner and edge-sharing OZnMo3 trigonal pyramids. In the third O site, O(3) is bonded in a rectangular see-saw-like geometry to one Mg(1), one Mo(1), one Mo(2), and one Zn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_MgZn2Mo3O8
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.487
_cell_length_b   6.223
_cell_length_c   7.206
_cell_angle_alpha   115.578
_cell_angle_beta   119.659
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   185.549
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mg  Mg0  1  0.500  0.500  0.000  1.0
  Zn  Zn1  1  0.801  0.722  0.444  1.0
  Zn  Zn2  1  0.199  0.278  0.556  1.0
  Mo  Mo3  1  0.500  0.000  0.000  1.0
  Mo  Mo4  1  1.000  0.741  1.000  1.0
  Mo  Mo5  1  1.000  0.259  0.000  1.0
  O  O6  1  0.054  0.394  0.789  1.0
  O  O7  1  0.946  0.606  0.211  1.0
  O  O8  1  0.036  0.896  0.793  1.0
  O  O9  1  0.964  0.104  0.207  1.0
  O  O10  1  0.480  0.352  0.204  1.0
  O  O11  1  0.480  0.852  0.204  1.0
  O  O12  1  0.520  0.148  0.796  1.0
  O  O13  1  0.520  0.648  0.796  1.0
[/CIF]
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