The material structure described by VF5 is Indium-like structured and crystallizes in the tetragonal P4/n space group. The structure is zero-dimensional and consists of two mfcd00137321 molecules. V(1) is bonded in a distorted trigonal bipyramidal geometry to one F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.036
_cell_length_b   6.036
_cell_length_c   4.370
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   159.236
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.500  0.647  1.0
  V  V1  1  0.500  0.000  0.353  1.0
  F  F2  1  0.000  0.500  0.255  1.0
  F  F3  1  0.079  0.231  0.744  1.0
  F  F4  1  0.231  0.921  0.256  1.0
  F  F5  1  0.269  0.579  0.744  1.0
  F  F6  1  0.421  0.269  0.256  1.0
  F  F7  1  0.500  0.000  0.745  1.0
  F  F8  1  0.579  0.731  0.256  1.0
  F  F9  1  0.731  0.421  0.744  1.0
  F  F10  1  0.769  0.079  0.256  1.0
  F  F11  1  0.921  0.769  0.744  1.0
[/CIF]
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The material structure described by VF5 is Indium-like structured and crystallizes in the tetragonal P4/n space group. The structure is zero-dimensional and consists of two mfcd00137321 molecules. V(1) is bonded in a distorted trigonal bipyramidal geometry to one F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one V(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one V(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_VF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.036
_cell_length_b   6.036
_cell_length_c   4.370
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   159.236
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.500  0.647  1.0
  V  V1  1  0.500  0.000  0.353  1.0
  F  F2  1  0.000  0.500  0.255  1.0
  F  F3  1  0.079  0.231  0.744  1.0
  F  F4  1  0.231  0.921  0.256  1.0
  F  F5  1  0.269  0.579  0.744  1.0
  F  F6  1  0.421  0.269  0.256  1.0
  F  F7  1  0.500  0.000  0.745  1.0
  F  F8  1  0.579  0.731  0.256  1.0
  F  F9  1  0.731  0.421  0.744  1.0
  F  F10  1  0.769  0.079  0.256  1.0
  F  F11  1  0.921  0.769  0.744  1.0
[/CIF]
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