The material structure described by PdN4RhN5O8NO2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two azanide;palladium molecules, two nitrous acid molecules, and two RhN5O8 clusters. In each RhN5O8 cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(7), two equivalent N(2), and two equivalent N(3) atoms. There are three inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Rh(1), one O(3), and one O(4) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Rh(1), one O(5), and one O(6) atom. In the third N site, N(7) is bonded in a single-bond geometry to one Rh(1) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(5) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(6) is bonded in a single-bond geometry to one N(3) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF file [CIF]
data_PdRh(NO)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.882
_cell_length_b   8.026
_cell_length_c   10.785
_cell_angle_alpha   70.837
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   807.997
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.250  0.692  0.231  1.0
  Pd  Pd1  1  0.750  0.308  0.769  1.0
  Rh  Rh2  1  0.750  0.109  0.344  1.0
  Rh  Rh3  1  0.250  0.891  0.656  1.0
  N  N4  1  0.750  0.533  0.228  1.0
  N  N5  1  0.250  0.467  0.772  1.0
  N  N6  1  0.602  0.189  0.467  1.0
  N  N7  1  0.102  0.811  0.533  1.0
  N  N8  1  0.398  0.811  0.533  1.0
  N  N9  1  0.898  0.189  0.467  1.0
  N  N10  1  0.604  0.173  0.181  1.0
  N  N11  1  0.104  0.827  0.819  1.0
  N  N12  1  0.396  0.827  0.819  1.0
  N  N13  1  0.896  0.173  0.181  1.0
  N  N14  1  0.250  0.911  0.096  1.0
  N  N15  1  0.750  0.089  0.904  1.0
  N  N16  1  0.044  0.688  0.246  1.0
  N  N17  1  0.544  0.312  0.754  1.0
  N  N18  1  0.956  0.312  0.754  1.0
  N  N19  1  0.456  0.688  0.246  1.0
  N  N20  1  0.250  0.516  0.151  1.0
  N  N21  1  0.750  0.484  0.849  1.0
  N  N22  1  0.750  0.890  0.407  1.0
  N  N23  1  0.250  0.110  0.593  1.0
  O  O24  1  0.750  0.604  0.111  1.0
  O  O25  1  0.250  0.396  0.889  1.0
  O  O26  1  0.750  0.584  0.322  1.0
  O  O27  1  0.250  0.416  0.678  1.0
  O  O28  1  0.524  0.309  0.415  1.0
  O  O29  1  0.024  0.691  0.585  1.0
  O  O30  1  0.476  0.691  0.585  1.0
  O  O31  1  0.976  0.309  0.415  1.0
  O  O32  1  0.609  0.102  0.584  1.0
  O  O33  1  0.109  0.898  0.416  1.0
  O  O34  1  0.391  0.898  0.416  1.0
  O  O35  1  0.891  0.102  0.584  1.0
  O  O36  1  0.539  0.309  0.161  1.0
  O  O37  1  0.039  0.691  0.839  1.0
  O  O38  1  0.461  0.691  0.839  1.0
  O  O39  1  0.961  0.309  0.161  1.0
  O  O40  1  0.599  0.065  0.123  1.0
  O  O41  1  0.099  0.935  0.877  1.0
  O  O42  1  0.401  0.935  0.877  1.0
  O  O43  1  0.901  0.065  0.123  1.0
[/CIF]
.
The material structure described by PdN4RhN5O8NO2 is Indium-derived structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two azanide;palladium molecules, two nitrous acid molecules, and two RhN5O8 clusters. In each RhN5O8 cluster, Rh(1) is bonded in a 5-coordinate geometry to one N(7), two equivalent N(2), and two equivalent N(3) atoms. There are three inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Rh(1), one O(3), and one O(4) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Rh(1), one O(5), and one O(6) atom. In the third N site, N(7) is bonded in a single-bond geometry to one Rh(1) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(5) is bonded in a single-bond geometry to one N(3) atom. In the third O site, O(6) is bonded in a single-bond geometry to one N(3) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one N(2) atom. is represented by the CIF file [CIF]
data_PdRh(NO)10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.882
_cell_length_b   8.026
_cell_length_c   10.785
_cell_angle_alpha   70.837
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   807.997
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.250  0.692  0.231  1.0
  Pd  Pd1  1  0.750  0.308  0.769  1.0
  Rh  Rh2  1  0.750  0.109  0.344  1.0
  Rh  Rh3  1  0.250  0.891  0.656  1.0
  N  N4  1  0.750  0.533  0.228  1.0
  N  N5  1  0.250  0.467  0.772  1.0
  N  N6  1  0.602  0.189  0.467  1.0
  N  N7  1  0.102  0.811  0.533  1.0
  N  N8  1  0.398  0.811  0.533  1.0
  N  N9  1  0.898  0.189  0.467  1.0
  N  N10  1  0.604  0.173  0.181  1.0
  N  N11  1  0.104  0.827  0.819  1.0
  N  N12  1  0.396  0.827  0.819  1.0
  N  N13  1  0.896  0.173  0.181  1.0
  N  N14  1  0.250  0.911  0.096  1.0
  N  N15  1  0.750  0.089  0.904  1.0
  N  N16  1  0.044  0.688  0.246  1.0
  N  N17  1  0.544  0.312  0.754  1.0
  N  N18  1  0.956  0.312  0.754  1.0
  N  N19  1  0.456  0.688  0.246  1.0
  N  N20  1  0.250  0.516  0.151  1.0
  N  N21  1  0.750  0.484  0.849  1.0
  N  N22  1  0.750  0.890  0.407  1.0
  N  N23  1  0.250  0.110  0.593  1.0
  O  O24  1  0.750  0.604  0.111  1.0
  O  O25  1  0.250  0.396  0.889  1.0
  O  O26  1  0.750  0.584  0.322  1.0
  O  O27  1  0.250  0.416  0.678  1.0
  O  O28  1  0.524  0.309  0.415  1.0
  O  O29  1  0.024  0.691  0.585  1.0
  O  O30  1  0.476  0.691  0.585  1.0
  O  O31  1  0.976  0.309  0.415  1.0
  O  O32  1  0.609  0.102  0.584  1.0
  O  O33  1  0.109  0.898  0.416  1.0
  O  O34  1  0.391  0.898  0.416  1.0
  O  O35  1  0.891  0.102  0.584  1.0
  O  O36  1  0.539  0.309  0.161  1.0
  O  O37  1  0.039  0.691  0.839  1.0
  O  O38  1  0.461  0.691  0.839  1.0
  O  O39  1  0.961  0.309  0.161  1.0
  O  O40  1  0.599  0.065  0.123  1.0
  O  O41  1  0.099  0.935  0.877  1.0
  O  O42  1  0.401  0.935  0.877  1.0
  O  O43  1  0.901  0.065  0.123  1.0
[/CIF]
.