The material described by IrC2H10(OCl)3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one IrC2H10(OCl)3 cluster. Ir(1) is bonded to one O(1), one O(2), one Cl(1), one Cl(2), and two equivalent Cl(3) atoms to form IrCl4O2 octahedra that share  a cornercorner with one C(1)H3O tetrahedra,  a cornercorner with one C(2)H3O tetrahedra, and  an edgeedge with one Ir(1)Cl4O2 octahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded to one H(5), one H(6), one H(7), and one O(1) atom to form CH3O tetrahedra that share  a cornercorner with one Ir(1)Cl4O2 octahedra. The corner-sharing octahedral tilt angles are 59°. In the second C site, C(2) is bonded to one H(10), one H(8), one H(9), and one O(2) atom to form CH3O tetrahedra that share  a cornercorner with one Ir(1)Cl4O2 octahedra. The corner-sharing octahedral tilt angles are 59°. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(2) and one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(1) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(2) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(2) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Ir(1), one C(1), and one H(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Ir(1), one C(2), and one H(2) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one H(2), one H(3), and one H(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ir(1) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to two equivalent Ir(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_H10IrC2(ClO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.388
_cell_length_b   7.539
_cell_length_c   8.924
_cell_angle_alpha   73.081
_cell_angle_beta   74.581
_cell_angle_gamma   88.780
_symmetry_Int_Tables_number   1
_cell_volume   457.534
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.002  0.375  0.254  1.0
  H  H1  1  0.998  0.625  0.746  1.0
  H  H2  1  0.660  0.254  0.297  1.0
  H  H3  1  0.340  0.746  0.703  1.0
  H  H4  1  0.746  0.381  0.470  1.0
  H  H5  1  0.254  0.619  0.530  1.0
  H  H6  1  0.813  0.175  0.495  1.0
  H  H7  1  0.187  0.825  0.505  1.0
  H  H8  1  0.070  0.666  0.279  1.0
  H  H9  1  0.930  0.334  0.721  1.0
  H  H10  1  0.174  0.737  0.062  1.0
  H  H11  1  0.826  0.263  0.938  1.0
  H  H12  1  0.927  0.673  0.142  1.0
  H  H13  1  0.073  0.327  0.858  1.0
  H  H14  1  0.541  0.942  0.324  1.0
  H  H15  1  0.459  0.058  0.676  1.0
  H  H16  1  0.613  0.016  0.106  1.0
  H  H17  1  0.387  0.984  0.894  1.0
  H  H18  1  0.785  0.008  0.218  1.0
  H  H19  1  0.215  0.992  0.782  1.0
  Ir  Ir20  1  0.360  0.347  0.188  1.0
  Ir  Ir21  1  0.640  0.653  0.812  1.0
  C  C22  1  0.066  0.647  0.163  1.0
  C  C23  1  0.934  0.353  0.837  1.0
  C  C24  1  0.639  0.035  0.216  1.0
  C  C25  1  0.361  0.965  0.784  1.0
  Cl  Cl26  1  0.186  0.061  0.264  1.0
  Cl  Cl27  1  0.814  0.939  0.736  1.0
  Cl  Cl28  1  0.281  0.352  0.459  1.0
  Cl  Cl29  1  0.719  0.648  0.541  1.0
  Cl  Cl30  1  0.543  0.635  0.094  1.0
  Cl  Cl31  1  0.457  0.365  0.906  1.0
  O  O32  1  0.104  0.456  0.163  1.0
  O  O33  1  0.896  0.544  0.837  1.0
  O  O34  1  0.613  0.228  0.209  1.0
  O  O35  1  0.387  0.772  0.791  1.0
  O  O36  1  0.792  0.288  0.412  1.0
  O  O37  1  0.208  0.712  0.588  1.0
[/CIF]
.
The material described by IrC2H10(OCl)3 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one IrC2H10(OCl)3 cluster. Ir(1) is bonded to one O(1), one O(2), one Cl(1), one Cl(2), and two equivalent Cl(3) atoms to form IrCl4O2 octahedra that share  a cornercorner with one C(1)H3O tetrahedra,  a cornercorner with one C(2)H3O tetrahedra, and  an edgeedge with one Ir(1)Cl4O2 octahedra. There are two inequivalent C sites. In the first C site, C(1) is bonded to one H(5), one H(6), one H(7), and one O(1) atom to form CH3O tetrahedra that share  a cornercorner with one Ir(1)Cl4O2 octahedra. The corner-sharing octahedral tilt angles are 59°. In the second C site, C(2) is bonded to one H(10), one H(8), one H(9), and one O(2) atom to form CH3O tetrahedra that share  a cornercorner with one Ir(1)Cl4O2 octahedra. The corner-sharing octahedral tilt angles are 59°. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. In the second H site, H(2) is bonded in a distorted single-bond geometry to one O(2) and one O(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one O(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(1) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(2) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(2) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(2) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Ir(1), one C(1), and one H(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Ir(1), one C(2), and one H(2) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one H(2), one H(3), and one H(4) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Ir(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Ir(1) atom. In the third Cl site, Cl(3) is bonded in a water-like geometry to two equivalent Ir(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_H10IrC2(ClO)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.388
_cell_length_b   7.539
_cell_length_c   8.924
_cell_angle_alpha   73.081
_cell_angle_beta   74.581
_cell_angle_gamma   88.780
_symmetry_Int_Tables_number   1
_cell_volume   457.534
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  H  H0  1  0.002  0.375  0.254  1.0
  H  H1  1  0.998  0.625  0.746  1.0
  H  H2  1  0.660  0.254  0.297  1.0
  H  H3  1  0.340  0.746  0.703  1.0
  H  H4  1  0.746  0.381  0.470  1.0
  H  H5  1  0.254  0.619  0.530  1.0
  H  H6  1  0.813  0.175  0.495  1.0
  H  H7  1  0.187  0.825  0.505  1.0
  H  H8  1  0.070  0.666  0.279  1.0
  H  H9  1  0.930  0.334  0.721  1.0
  H  H10  1  0.174  0.737  0.062  1.0
  H  H11  1  0.826  0.263  0.938  1.0
  H  H12  1  0.927  0.673  0.142  1.0
  H  H13  1  0.073  0.327  0.858  1.0
  H  H14  1  0.541  0.942  0.324  1.0
  H  H15  1  0.459  0.058  0.676  1.0
  H  H16  1  0.613  0.016  0.106  1.0
  H  H17  1  0.387  0.984  0.894  1.0
  H  H18  1  0.785  0.008  0.218  1.0
  H  H19  1  0.215  0.992  0.782  1.0
  Ir  Ir20  1  0.360  0.347  0.188  1.0
  Ir  Ir21  1  0.640  0.653  0.812  1.0
  C  C22  1  0.066  0.647  0.163  1.0
  C  C23  1  0.934  0.353  0.837  1.0
  C  C24  1  0.639  0.035  0.216  1.0
  C  C25  1  0.361  0.965  0.784  1.0
  Cl  Cl26  1  0.186  0.061  0.264  1.0
  Cl  Cl27  1  0.814  0.939  0.736  1.0
  Cl  Cl28  1  0.281  0.352  0.459  1.0
  Cl  Cl29  1  0.719  0.648  0.541  1.0
  Cl  Cl30  1  0.543  0.635  0.094  1.0
  Cl  Cl31  1  0.457  0.365  0.906  1.0
  O  O32  1  0.104  0.456  0.163  1.0
  O  O33  1  0.896  0.544  0.837  1.0
  O  O34  1  0.613  0.228  0.209  1.0
  O  O35  1  0.387  0.772  0.791  1.0
  O  O36  1  0.792  0.288  0.412  1.0
  O  O37  1  0.208  0.712  0.588  1.0
[/CIF]
.