The structure described by Li2VF5 crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a distorted see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. V(1) is bonded to one F(1), one F(3), one F(4), and four equivalent F(2) atoms to form distorted edge-sharing VF7 pentagonal bipyramids. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to two equivalent Li(1) and one V(1) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent V(1) atoms. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to two equivalent Li(1) and one V(1) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to two equivalent Li(1) and one V(1) atom. is represented by the CIF card [CIF]
data_Li2VF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.165
_cell_length_b   6.324
_cell_length_c   9.124
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   355.739
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.048  0.472  0.669  1.0
  Li  Li1  1  0.048  0.028  0.669  1.0
  Li  Li2  1  0.548  0.528  0.831  1.0
  Li  Li3  1  0.548  0.972  0.831  1.0
  Li  Li4  1  0.452  0.472  0.169  1.0
  Li  Li5  1  0.452  0.028  0.169  1.0
  Li  Li6  1  0.952  0.528  0.331  1.0
  Li  Li7  1  0.952  0.972  0.331  1.0
  V  V8  1  0.564  0.250  0.516  1.0
  V  V9  1  0.064  0.750  0.984  1.0
  V  V10  1  0.936  0.250  0.016  1.0
  V  V11  1  0.436  0.750  0.484  1.0
  F  F12  1  0.892  0.250  0.551  1.0
  F  F13  1  0.326  0.036  0.566  1.0
  F  F14  1  0.326  0.464  0.566  1.0
  F  F15  1  0.578  0.750  0.681  1.0
  F  F16  1  0.584  0.250  0.737  1.0
  F  F17  1  0.084  0.750  0.763  1.0
  F  F18  1  0.078  0.250  0.819  1.0
  F  F19  1  0.826  0.964  0.934  1.0
  F  F20  1  0.826  0.536  0.934  1.0
  F  F21  1  0.392  0.750  0.949  1.0
  F  F22  1  0.608  0.250  0.051  1.0
  F  F23  1  0.174  0.036  0.066  1.0
  F  F24  1  0.174  0.464  0.066  1.0
  F  F25  1  0.922  0.750  0.181  1.0
  F  F26  1  0.916  0.250  0.237  1.0
  F  F27  1  0.416  0.750  0.263  1.0
  F  F28  1  0.422  0.250  0.319  1.0
  F  F29  1  0.674  0.964  0.434  1.0
  F  F30  1  0.674  0.536  0.434  1.0
  F  F31  1  0.108  0.750  0.449  1.0
[/CIF]
.
The structure described by Li2VF5 crystallizes in the orthorhombic Pnma space group. Li(1) is bonded in a distorted see-saw-like geometry to one F(1), one F(2), one F(3), and one F(4) atom. V(1) is bonded to one F(1), one F(3), one F(4), and four equivalent F(2) atoms to form distorted edge-sharing VF7 pentagonal bipyramids. There are four inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to two equivalent Li(1) and one V(1) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Li(1) and two equivalent V(1) atoms. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to two equivalent Li(1) and one V(1) atom. In the fourth F site, F(4) is bonded in a trigonal planar geometry to two equivalent Li(1) and one V(1) atom. is represented by the CIF card [CIF]
data_Li2VF5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.165
_cell_length_b   6.324
_cell_length_c   9.124
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   355.739
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.048  0.472  0.669  1.0
  Li  Li1  1  0.048  0.028  0.669  1.0
  Li  Li2  1  0.548  0.528  0.831  1.0
  Li  Li3  1  0.548  0.972  0.831  1.0
  Li  Li4  1  0.452  0.472  0.169  1.0
  Li  Li5  1  0.452  0.028  0.169  1.0
  Li  Li6  1  0.952  0.528  0.331  1.0
  Li  Li7  1  0.952  0.972  0.331  1.0
  V  V8  1  0.564  0.250  0.516  1.0
  V  V9  1  0.064  0.750  0.984  1.0
  V  V10  1  0.936  0.250  0.016  1.0
  V  V11  1  0.436  0.750  0.484  1.0
  F  F12  1  0.892  0.250  0.551  1.0
  F  F13  1  0.326  0.036  0.566  1.0
  F  F14  1  0.326  0.464  0.566  1.0
  F  F15  1  0.578  0.750  0.681  1.0
  F  F16  1  0.584  0.250  0.737  1.0
  F  F17  1  0.084  0.750  0.763  1.0
  F  F18  1  0.078  0.250  0.819  1.0
  F  F19  1  0.826  0.964  0.934  1.0
  F  F20  1  0.826  0.536  0.934  1.0
  F  F21  1  0.392  0.750  0.949  1.0
  F  F22  1  0.608  0.250  0.051  1.0
  F  F23  1  0.174  0.036  0.066  1.0
  F  F24  1  0.174  0.464  0.066  1.0
  F  F25  1  0.922  0.750  0.181  1.0
  F  F26  1  0.916  0.250  0.237  1.0
  F  F27  1  0.416  0.750  0.263  1.0
  F  F28  1  0.422  0.250  0.319  1.0
  F  F29  1  0.674  0.964  0.434  1.0
  F  F30  1  0.674  0.536  0.434  1.0
  F  F31  1  0.108  0.750  0.449  1.0
[/CIF]
.