The compound described by LaRhZn crystallizes in the orthorhombic Pnma space group. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 11-coordinate geometry to two equivalent Rh(1), three equivalent Rh(2), three equivalent Zn(1), and three equivalent Zn(2) atoms. In the second La site, La(2) is bonded in a 5-coordinate geometry to one Rh(2) and four equivalent Rh(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to two equivalent La(1), four equivalent La(2), one Zn(2), and two equivalent Zn(1) atoms. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to one La(2), three equivalent La(1), two equivalent Zn(1), and three equivalent Zn(2) atoms. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 4-coordinate geometry to three equivalent La(1), two equivalent Rh(1), and two equivalent Rh(2) atoms. In the second Zn site, Zn(2) is bonded in a 4-coordinate geometry to three equivalent La(1), one Rh(1), and three equivalent Rh(2) atoms. is represented by the CIF card [CIF]
data_LaZnRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.018
_cell_length_b   7.484
_cell_length_c   16.453
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   494.774
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.750  0.326  0.441  1.0
  La  La1  1  0.250  0.048  0.717  1.0
  La  La2  1  0.250  0.548  0.783  1.0
  La  La3  1  0.250  0.674  0.559  1.0
  La  La4  1  0.750  0.826  0.059  1.0
  La  La5  1  0.250  0.174  0.941  1.0
  La  La6  1  0.750  0.452  0.217  1.0
  La  La7  1  0.750  0.952  0.283  1.0
  Zn  Zn8  1  0.250  0.127  0.148  1.0
  Zn  Zn9  1  0.250  0.999  0.442  1.0
  Zn  Zn10  1  0.750  0.873  0.852  1.0
  Zn  Zn11  1  0.750  0.001  0.558  1.0
  Zn  Zn12  1  0.250  0.499  0.058  1.0
  Zn  Zn13  1  0.750  0.373  0.648  1.0
  Zn  Zn14  1  0.750  0.501  0.942  1.0
  Zn  Zn15  1  0.250  0.627  0.352  1.0
  Rh  Rh16  1  0.750  0.252  0.816  1.0
  Rh  Rh17  1  0.250  0.248  0.316  1.0
  Rh  Rh18  1  0.250  0.738  0.933  1.0
  Rh  Rh19  1  0.250  0.238  0.567  1.0
  Rh  Rh20  1  0.250  0.748  0.184  1.0
  Rh  Rh21  1  0.750  0.762  0.433  1.0
  Rh  Rh22  1  0.750  0.262  0.067  1.0
  Rh  Rh23  1  0.750  0.752  0.684  1.0
[/CIF]
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The compound described by LaRhZn crystallizes in the orthorhombic Pnma space group. There are two inequivalent La sites. In the first La site, La(1) is bonded in a 11-coordinate geometry to two equivalent Rh(1), three equivalent Rh(2), three equivalent Zn(1), and three equivalent Zn(2) atoms. In the second La site, La(2) is bonded in a 5-coordinate geometry to one Rh(2) and four equivalent Rh(1) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 9-coordinate geometry to two equivalent La(1), four equivalent La(2), one Zn(2), and two equivalent Zn(1) atoms. In the second Rh site, Rh(2) is bonded in a 9-coordinate geometry to one La(2), three equivalent La(1), two equivalent Zn(1), and three equivalent Zn(2) atoms. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 4-coordinate geometry to three equivalent La(1), two equivalent Rh(1), and two equivalent Rh(2) atoms. In the second Zn site, Zn(2) is bonded in a 4-coordinate geometry to three equivalent La(1), one Rh(1), and three equivalent Rh(2) atoms. is represented by the CIF card [CIF]
data_LaZnRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.018
_cell_length_b   7.484
_cell_length_c   16.453
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   494.774
_cell_formula_units_Z   8
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.750  0.326  0.441  1.0
  La  La1  1  0.250  0.048  0.717  1.0
  La  La2  1  0.250  0.548  0.783  1.0
  La  La3  1  0.250  0.674  0.559  1.0
  La  La4  1  0.750  0.826  0.059  1.0
  La  La5  1  0.250  0.174  0.941  1.0
  La  La6  1  0.750  0.452  0.217  1.0
  La  La7  1  0.750  0.952  0.283  1.0
  Zn  Zn8  1  0.250  0.127  0.148  1.0
  Zn  Zn9  1  0.250  0.999  0.442  1.0
  Zn  Zn10  1  0.750  0.873  0.852  1.0
  Zn  Zn11  1  0.750  0.001  0.558  1.0
  Zn  Zn12  1  0.250  0.499  0.058  1.0
  Zn  Zn13  1  0.750  0.373  0.648  1.0
  Zn  Zn14  1  0.750  0.501  0.942  1.0
  Zn  Zn15  1  0.250  0.627  0.352  1.0
  Rh  Rh16  1  0.750  0.252  0.816  1.0
  Rh  Rh17  1  0.250  0.248  0.316  1.0
  Rh  Rh18  1  0.250  0.738  0.933  1.0
  Rh  Rh19  1  0.250  0.238  0.567  1.0
  Rh  Rh20  1  0.250  0.748  0.184  1.0
  Rh  Rh21  1  0.750  0.762  0.433  1.0
  Rh  Rh22  1  0.750  0.262  0.067  1.0
  Rh  Rh23  1  0.750  0.752  0.684  1.0
[/CIF]
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