The compound described by NaHo2F7 crystallizes in the triclinic P1 space group. Na(1) is bonded in a 6-coordinate geometry to one F(4), one F(5), two equivalent F(1), and two equivalent F(7) atoms. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 7-coordinate geometry to one F(1), one F(3), one F(6), two equivalent F(2), and two equivalent F(4) atoms. In the second Ho site, Ho(2) is bonded in a 7-coordinate geometry to one F(2), one F(3), one F(7), two equivalent F(5), and two equivalent F(6) atoms. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one Ho(1) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Ho(2) and two equivalent Ho(1) atoms. In the third F site, F(3) is bonded in a linear geometry to one Ho(1) and one Ho(2) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Na(1) and two equivalent Ho(1) atoms. In the fifth F site, F(5) is bonded in a distorted trigonal non-coplanar geometry to one Na(1) and two equivalent Ho(2) atoms. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Ho(1) and two equivalent Ho(2) atoms. In the seventh F site, F(7) is bonded in a trigonal non-coplanar geometry to two equivalent Na(1) and one Ho(2) atom. is represented by the CIF file [CIF]
data_NaHo2F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.243
_cell_length_b   5.296
_cell_length_c   13.490
_cell_angle_alpha   46.594
_cell_angle_beta   47.792
_cell_angle_gamma   50.731
_symmetry_Int_Tables_number   1
_cell_volume   154.619
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.080  0.085  0.994  1.0
  Ho  Ho1  1  0.097  0.011  0.322  1.0
  Ho  Ho2  1  0.958  0.939  0.658  1.0
  F  F3  1  0.268  0.165  0.105  1.0
  F  F4  1  0.438  0.004  0.397  1.0
  F  F5  1  0.072  0.462  0.485  1.0
  F  F6  1  0.815  0.618  0.249  1.0
  F  F7  1  0.284  0.339  0.725  1.0
  F  F8  1  0.629  0.899  0.597  1.0
  F  F9  1  0.781  0.730  0.885  1.0
[/CIF]
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The compound described by NaHo2F7 crystallizes in the triclinic P1 space group. Na(1) is bonded in a 6-coordinate geometry to one F(4), one F(5), two equivalent F(1), and two equivalent F(7) atoms. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 7-coordinate geometry to one F(1), one F(3), one F(6), two equivalent F(2), and two equivalent F(4) atoms. In the second Ho site, Ho(2) is bonded in a 7-coordinate geometry to one F(2), one F(3), one F(7), two equivalent F(5), and two equivalent F(6) atoms. There are seven inequivalent F sites. In the first F site, F(1) is bonded in a distorted trigonal planar geometry to two equivalent Na(1) and one Ho(1) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Ho(2) and two equivalent Ho(1) atoms. In the third F site, F(3) is bonded in a linear geometry to one Ho(1) and one Ho(2) atom. In the fourth F site, F(4) is bonded in a distorted trigonal planar geometry to one Na(1) and two equivalent Ho(1) atoms. In the fifth F site, F(5) is bonded in a distorted trigonal non-coplanar geometry to one Na(1) and two equivalent Ho(2) atoms. In the sixth F site, F(6) is bonded in a 3-coordinate geometry to one Ho(1) and two equivalent Ho(2) atoms. In the seventh F site, F(7) is bonded in a trigonal non-coplanar geometry to two equivalent Na(1) and one Ho(2) atom. is represented by the CIF file [CIF]
data_NaHo2F7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.243
_cell_length_b   5.296
_cell_length_c   13.490
_cell_angle_alpha   46.594
_cell_angle_beta   47.792
_cell_angle_gamma   50.731
_symmetry_Int_Tables_number   1
_cell_volume   154.619
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.080  0.085  0.994  1.0
  Ho  Ho1  1  0.097  0.011  0.322  1.0
  Ho  Ho2  1  0.958  0.939  0.658  1.0
  F  F3  1  0.268  0.165  0.105  1.0
  F  F4  1  0.438  0.004  0.397  1.0
  F  F5  1  0.072  0.462  0.485  1.0
  F  F6  1  0.815  0.618  0.249  1.0
  F  F7  1  0.284  0.339  0.725  1.0
  F  F8  1  0.629  0.899  0.597  1.0
  F  F9  1  0.781  0.730  0.885  1.0
[/CIF]
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