The material structure described by PrMnCu10 crystallizes in the orthorhombic Cmmm space group. Pr(1) is bonded in a 20-coordinate geometry to two equivalent Mn(1), two equivalent Cu(7), four equivalent Cu(1), four equivalent Cu(2), four equivalent Cu(3), and four equivalent Cu(4) atoms. Mn(1) is bonded in a 15-coordinate geometry to two equivalent Pr(1), one Mn(1), two equivalent Cu(4), two equivalent Cu(6), four equivalent Cu(1), and four equivalent Cu(3) atoms. There are seven inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to two equivalent Pr(1), two equivalent Mn(1), one Cu(1), one Cu(6), two equivalent Cu(2), two equivalent Cu(3), and two equivalent Cu(4) atoms to form distorted CuPr2Mn2Cu8 cuboctahedra that share  a cornercorner with one Cu(5)Cu12 cuboctahedra, corners with two equivalent Cu(6)Mn4Cu8 cuboctahedra, corners with two equivalent Cu(4)Pr2MnCu9 cuboctahedra, corners with four equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra, corners with five equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, edges with two equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, edges with two equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra, edges with two equivalent Cu(4)Pr2MnCu9 cuboctahedra,  a faceface with one Cu(5)Cu12 cuboctahedra,  a faceface with one Cu(6)Mn4Cu8 cuboctahedra, faces with three equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, faces with four equivalent Cu(4)Pr2MnCu9 cuboctahedra, and faces with six equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra. In the second Cu site, Cu(2) is bonded in a 12-coordinate geometry to two equivalent Pr(1), one Cu(2), one Cu(5), two equivalent Cu(1), two equivalent Cu(3), two equivalent Cu(4), and two equivalent Cu(7) atoms. In the third Cu site, Cu(3) is bonded to two equivalent Pr(1), two equivalent Mn(1), one Cu(6), one Cu(7), two equivalent Cu(1), two equivalent Cu(2), and two equivalent Cu(3) atoms to form CuPr2Mn2Cu8 cuboctahedra that share  a cornercorner with one Cu(5)Cu12 cuboctahedra, corners with four equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, corners with four equivalent Cu(4)Pr2MnCu9 cuboctahedra, corners with seven equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra,  an edgeedge with one Cu(3)Pr2Mn2Cu8 cuboctahedra, edges with two equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, edges with four equivalent Cu(4)Pr2MnCu9 cuboctahedra,  a faceface with one Cu(5)Cu12 cuboctahedra, faces with two equivalent Cu(6)Mn4Cu8 cuboctahedra, faces with three equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra, faces with four equivalent Cu(4)Pr2MnCu9 cuboctahedra, and faces with six equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra. In the fourth Cu site, Cu(4) is bonded to two equivalent Pr(1), one Mn(1), one Cu(5), two equivalent Cu(1), two equivalent Cu(2), two equivalent Cu(4), and two equivalent Cu(7) atoms to form distorted CuPr2MnCu9 cuboctahedra that share  a cornercorner with one Cu(6)Mn4Cu8 cuboctahedra, corners with two equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, corners with four equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra, corners with seven equivalent Cu(4)Pr2MnCu9 cuboctahedra,  an edgeedge with one Cu(4)Pr2MnCu9 cuboctahedra, edges with two equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, edges with four equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra,  a faceface with one Cu(6)Mn4Cu8 cuboctahedra, faces with two equivalent Cu(5)Cu12 cuboctahedra, faces with three equivalent Cu(4)Pr2MnCu9 cuboctahedra, faces with four equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, and faces with four equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra. In the fifth Cu site, Cu(5) is bonded to four equivalent Cu(2), four equivalent Cu(4), and four equivalent Cu(7) atoms to form CuCu12 cuboctahedra that share corners with four equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, corners with four equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra, edges with two equivalent Cu(5)Cu12 cuboctahedra, faces with four equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, faces with four equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra, and faces with eight equivalent Cu(4)Pr2MnCu9 cuboctahedra. In the sixth Cu site, Cu(6) is bonded to four equivalent Mn(1), four equivalent Cu(1), and four equivalent Cu(3) atoms to form CuMn4Cu8 cuboctahedra that share corners with four equivalent Cu(4)Pr2MnCu9 cuboctahedra, corners with eight equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, edges with two equivalent Cu(6)Mn4Cu8 cuboctahedra, faces with four equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, faces with four equivalent Cu(4)Pr2MnCu9 cuboctahedra, and faces with eight equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra. In the seventh Cu site, Cu(7) is bonded in a 15-coordinate geometry to two equivalent Pr(1), one Cu(7), two equivalent Cu(3), two equivalent Cu(5), four equivalent Cu(2), and four equivalent Cu(4) atoms. is represented by the CIF card [CIF]
data_PrMnCu10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.922
_cell_length_b   8.248
_cell_length_c   8.248
_cell_angle_alpha   89.892
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   334.815
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.000  0.500  0.500  1.0
  Pr  Pr1  1  0.000  0.000  0.000  1.0
  Mn  Mn2  1  0.000  0.383  0.117  1.0
  Mn  Mn3  1  0.000  0.617  0.883  1.0
  Cu  Cu4  1  0.500  0.565  0.710  1.0
  Cu  Cu5  1  0.500  0.435  0.290  1.0
  Cu  Cu6  1  0.500  0.935  0.212  1.0
  Cu  Cu7  1  0.500  0.065  0.788  1.0
  Cu  Cu8  1  0.500  0.712  0.435  1.0
  Cu  Cu9  1  0.500  0.288  0.565  1.0
  Cu  Cu10  1  0.500  0.210  0.065  1.0
  Cu  Cu11  1  0.500  0.790  0.935  1.0
  Cu  Cu12  1  0.759  0.321  0.821  1.0
  Cu  Cu13  1  0.759  0.679  0.179  1.0
  Cu  Cu14  1  0.760  0.178  0.322  1.0
  Cu  Cu15  1  0.760  0.822  0.678  1.0
  Cu  Cu16  1  0.241  0.679  0.179  1.0
  Cu  Cu17  1  0.241  0.321  0.821  1.0
  Cu  Cu18  1  0.240  0.822  0.678  1.0
  Cu  Cu19  1  0.240  0.178  0.322  1.0
  Cu  Cu20  1  0.500  0.000  0.500  1.0
  Cu  Cu21  1  0.500  0.500  0.000  1.0
  Cu  Cu22  1  0.000  0.114  0.614  1.0
  Cu  Cu23  1  0.000  0.886  0.386  1.0
[/CIF]
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The material structure described by PrMnCu10 crystallizes in the orthorhombic Cmmm space group. Pr(1) is bonded in a 20-coordinate geometry to two equivalent Mn(1), two equivalent Cu(7), four equivalent Cu(1), four equivalent Cu(2), four equivalent Cu(3), and four equivalent Cu(4) atoms. Mn(1) is bonded in a 15-coordinate geometry to two equivalent Pr(1), one Mn(1), two equivalent Cu(4), two equivalent Cu(6), four equivalent Cu(1), and four equivalent Cu(3) atoms. There are seven inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to two equivalent Pr(1), two equivalent Mn(1), one Cu(1), one Cu(6), two equivalent Cu(2), two equivalent Cu(3), and two equivalent Cu(4) atoms to form distorted CuPr2Mn2Cu8 cuboctahedra that share  a cornercorner with one Cu(5)Cu12 cuboctahedra, corners with two equivalent Cu(6)Mn4Cu8 cuboctahedra, corners with two equivalent Cu(4)Pr2MnCu9 cuboctahedra, corners with four equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra, corners with five equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, edges with two equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, edges with two equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra, edges with two equivalent Cu(4)Pr2MnCu9 cuboctahedra,  a faceface with one Cu(5)Cu12 cuboctahedra,  a faceface with one Cu(6)Mn4Cu8 cuboctahedra, faces with three equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, faces with four equivalent Cu(4)Pr2MnCu9 cuboctahedra, and faces with six equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra. In the second Cu site, Cu(2) is bonded in a 12-coordinate geometry to two equivalent Pr(1), one Cu(2), one Cu(5), two equivalent Cu(1), two equivalent Cu(3), two equivalent Cu(4), and two equivalent Cu(7) atoms. In the third Cu site, Cu(3) is bonded to two equivalent Pr(1), two equivalent Mn(1), one Cu(6), one Cu(7), two equivalent Cu(1), two equivalent Cu(2), and two equivalent Cu(3) atoms to form CuPr2Mn2Cu8 cuboctahedra that share  a cornercorner with one Cu(5)Cu12 cuboctahedra, corners with four equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, corners with four equivalent Cu(4)Pr2MnCu9 cuboctahedra, corners with seven equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra,  an edgeedge with one Cu(3)Pr2Mn2Cu8 cuboctahedra, edges with two equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, edges with four equivalent Cu(4)Pr2MnCu9 cuboctahedra,  a faceface with one Cu(5)Cu12 cuboctahedra, faces with two equivalent Cu(6)Mn4Cu8 cuboctahedra, faces with three equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra, faces with four equivalent Cu(4)Pr2MnCu9 cuboctahedra, and faces with six equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra. In the fourth Cu site, Cu(4) is bonded to two equivalent Pr(1), one Mn(1), one Cu(5), two equivalent Cu(1), two equivalent Cu(2), two equivalent Cu(4), and two equivalent Cu(7) atoms to form distorted CuPr2MnCu9 cuboctahedra that share  a cornercorner with one Cu(6)Mn4Cu8 cuboctahedra, corners with two equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, corners with four equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra, corners with seven equivalent Cu(4)Pr2MnCu9 cuboctahedra,  an edgeedge with one Cu(4)Pr2MnCu9 cuboctahedra, edges with two equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, edges with four equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra,  a faceface with one Cu(6)Mn4Cu8 cuboctahedra, faces with two equivalent Cu(5)Cu12 cuboctahedra, faces with three equivalent Cu(4)Pr2MnCu9 cuboctahedra, faces with four equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, and faces with four equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra. In the fifth Cu site, Cu(5) is bonded to four equivalent Cu(2), four equivalent Cu(4), and four equivalent Cu(7) atoms to form CuCu12 cuboctahedra that share corners with four equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, corners with four equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra, edges with two equivalent Cu(5)Cu12 cuboctahedra, faces with four equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, faces with four equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra, and faces with eight equivalent Cu(4)Pr2MnCu9 cuboctahedra. In the sixth Cu site, Cu(6) is bonded to four equivalent Mn(1), four equivalent Cu(1), and four equivalent Cu(3) atoms to form CuMn4Cu8 cuboctahedra that share corners with four equivalent Cu(4)Pr2MnCu9 cuboctahedra, corners with eight equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, edges with two equivalent Cu(6)Mn4Cu8 cuboctahedra, faces with four equivalent Cu(1)Pr2Mn2Cu8 cuboctahedra, faces with four equivalent Cu(4)Pr2MnCu9 cuboctahedra, and faces with eight equivalent Cu(3)Pr2Mn2Cu8 cuboctahedra. In the seventh Cu site, Cu(7) is bonded in a 15-coordinate geometry to two equivalent Pr(1), one Cu(7), two equivalent Cu(3), two equivalent Cu(5), four equivalent Cu(2), and four equivalent Cu(4) atoms. is represented by the CIF card [CIF]
data_PrMnCu10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.922
_cell_length_b   8.248
_cell_length_c   8.248
_cell_angle_alpha   89.892
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   334.815
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pr  Pr0  1  0.000  0.500  0.500  1.0
  Pr  Pr1  1  0.000  0.000  0.000  1.0
  Mn  Mn2  1  0.000  0.383  0.117  1.0
  Mn  Mn3  1  0.000  0.617  0.883  1.0
  Cu  Cu4  1  0.500  0.565  0.710  1.0
  Cu  Cu5  1  0.500  0.435  0.290  1.0
  Cu  Cu6  1  0.500  0.935  0.212  1.0
  Cu  Cu7  1  0.500  0.065  0.788  1.0
  Cu  Cu8  1  0.500  0.712  0.435  1.0
  Cu  Cu9  1  0.500  0.288  0.565  1.0
  Cu  Cu10  1  0.500  0.210  0.065  1.0
  Cu  Cu11  1  0.500  0.790  0.935  1.0
  Cu  Cu12  1  0.759  0.321  0.821  1.0
  Cu  Cu13  1  0.759  0.679  0.179  1.0
  Cu  Cu14  1  0.760  0.178  0.322  1.0
  Cu  Cu15  1  0.760  0.822  0.678  1.0
  Cu  Cu16  1  0.241  0.679  0.179  1.0
  Cu  Cu17  1  0.241  0.321  0.821  1.0
  Cu  Cu18  1  0.240  0.822  0.678  1.0
  Cu  Cu19  1  0.240  0.178  0.322  1.0
  Cu  Cu20  1  0.500  0.000  0.500  1.0
  Cu  Cu21  1  0.500  0.500  0.000  1.0
  Cu  Cu22  1  0.000  0.114  0.614  1.0
  Cu  Cu23  1  0.000  0.886  0.386  1.0
[/CIF]
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