The material described by V2BiO2 crystallizes in the tetragonal I4_1/amd space group. V(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. Bi(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. O(1) is bonded in a 4-coordinate geometry to three equivalent V(1) and one Bi(1) atom. is represented by the CIF card [CIF]
data_V2BiO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.678
_cell_length_b   7.678
_cell_length_c   7.678
_cell_angle_alpha   113.262
_cell_angle_beta   113.262
_cell_angle_gamma   102.130
_symmetry_Int_Tables_number   1
_cell_volume   344.249
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.501  0.169  0.668  1.0
  V  V1  1  0.501  0.833  0.332  1.0
  V  V2  1  0.583  0.751  0.832  1.0
  V  V3  1  0.249  0.417  0.168  1.0
  V  V4  1  0.249  0.081  0.832  1.0
  V  V5  1  0.919  0.751  0.168  1.0
  V  V6  1  0.167  0.499  0.668  1.0
  V  V7  1  0.831  0.499  0.332  1.0
  Bi  Bi8  1  0.875  0.125  0.250  1.0
  Bi  Bi9  1  0.875  0.625  0.750  1.0
  Bi  Bi10  1  0.375  0.125  0.250  1.0
  Bi  Bi11  1  0.875  0.125  0.750  1.0
  O  O12  1  0.637  0.484  0.847  1.0
  O  O13  1  0.637  0.790  0.153  1.0
  O  O14  1  0.540  0.887  0.653  1.0
  O  O15  1  0.113  0.460  0.347  1.0
  O  O16  1  0.113  0.766  0.653  1.0
  O  O17  1  0.234  0.887  0.347  1.0
  O  O18  1  0.210  0.363  0.847  1.0
  O  O19  1  0.516  0.363  0.153  1.0
[/CIF]
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The material described by V2BiO2 crystallizes in the tetragonal I4_1/amd space group. V(1) is bonded in a 3-coordinate geometry to three equivalent O(1) atoms. Bi(1) is bonded in a distorted linear geometry to two equivalent O(1) atoms. O(1) is bonded in a 4-coordinate geometry to three equivalent V(1) and one Bi(1) atom. is represented by the CIF card [CIF]
data_V2BiO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.678
_cell_length_b   7.678
_cell_length_c   7.678
_cell_angle_alpha   113.262
_cell_angle_beta   113.262
_cell_angle_gamma   102.130
_symmetry_Int_Tables_number   1
_cell_volume   344.249
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.501  0.169  0.668  1.0
  V  V1  1  0.501  0.833  0.332  1.0
  V  V2  1  0.583  0.751  0.832  1.0
  V  V3  1  0.249  0.417  0.168  1.0
  V  V4  1  0.249  0.081  0.832  1.0
  V  V5  1  0.919  0.751  0.168  1.0
  V  V6  1  0.167  0.499  0.668  1.0
  V  V7  1  0.831  0.499  0.332  1.0
  Bi  Bi8  1  0.875  0.125  0.250  1.0
  Bi  Bi9  1  0.875  0.625  0.750  1.0
  Bi  Bi10  1  0.375  0.125  0.250  1.0
  Bi  Bi11  1  0.875  0.125  0.750  1.0
  O  O12  1  0.637  0.484  0.847  1.0
  O  O13  1  0.637  0.790  0.153  1.0
  O  O14  1  0.540  0.887  0.653  1.0
  O  O15  1  0.113  0.460  0.347  1.0
  O  O16  1  0.113  0.766  0.653  1.0
  O  O17  1  0.234  0.887  0.347  1.0
  O  O18  1  0.210  0.363  0.847  1.0
  O  O19  1  0.516  0.363  0.153  1.0
[/CIF]
.