The material structure described by Mg14CeTi crystallizes in the hexagonal P-6m2 space group. There are four inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(4), four equivalent Mg(1), four equivalent Mg(3), and two equivalent Ti(1) atoms to form MgMg10Ti2 cuboctahedra that share corners with four equivalent Ce(1)Mg12 cuboctahedra, corners with six equivalent Mg(1)Mg10Ti2 cuboctahedra, corners with eight equivalent Mg(2)Ce2Mg10 cuboctahedra, edges with two equivalent Ti(1)Mg12 cuboctahedra, edges with four equivalent Mg(1)Mg10Ti2 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra, edges with eight equivalent Mg(3)CeMg10Ti cuboctahedra, faces with two equivalent Mg(2)Ce2Mg10 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, faces with two equivalent Ti(1)Mg12 cuboctahedra, faces with four equivalent Mg(1)Mg10Ti2 cuboctahedra, and faces with ten equivalent Mg(3)CeMg10Ti cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(4), four equivalent Mg(2), four equivalent Mg(3), and two equivalent Ce(1) atoms to form distorted MgCe2Mg10 cuboctahedra that share corners with four equivalent Ti(1)Mg12 cuboctahedra, corners with six equivalent Mg(2)Ce2Mg10 cuboctahedra, corners with eight equivalent Mg(1)Mg10Ti2 cuboctahedra, edges with two equivalent Ce(1)Mg12 cuboctahedra, edges with four equivalent Mg(2)Ce2Mg10 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra, edges with eight equivalent Mg(3)CeMg10Ti cuboctahedra, faces with two equivalent Mg(1)Mg10Ti2 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, faces with two equivalent Ce(1)Mg12 cuboctahedra, faces with four equivalent Mg(2)Ce2Mg10 cuboctahedra, and faces with ten equivalent Mg(3)CeMg10Ti cuboctahedra. In the third Mg site, Mg(3) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), four equivalent Mg(3), one Ce(1), and one Ti(1) atom to form distorted MgCeMg10Ti cuboctahedra that share corners with four equivalent Mg(4)Mg12 cuboctahedra, corners with fourteen equivalent Mg(3)CeMg10Ti cuboctahedra, edges with two equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Ce(1)Mg12 cuboctahedra, edges with two equivalent Ti(1)Mg12 cuboctahedra, edges with four equivalent Mg(2)Ce2Mg10 cuboctahedra, edges with four equivalent Mg(3)CeMg10Ti cuboctahedra, edges with four equivalent Mg(1)Mg10Ti2 cuboctahedra,  a faceface with one Ce(1)Mg12 cuboctahedra,  a faceface with one Ti(1)Mg12 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, faces with five equivalent Mg(2)Ce2Mg10 cuboctahedra, faces with five equivalent Mg(1)Mg10Ti2 cuboctahedra, and faces with six equivalent Mg(3)CeMg10Ti cuboctahedra. In the fourth Mg site, Mg(4) is bonded to three equivalent Mg(1), three equivalent Mg(2), and six equivalent Mg(3) atoms to form MgMg12 cuboctahedra that share corners with six equivalent Mg(4)Mg12 cuboctahedra, corners with twelve equivalent Mg(3)CeMg10Ti cuboctahedra, edges with six equivalent Mg(2)Ce2Mg10 cuboctahedra, edges with six equivalent Mg(3)CeMg10Ti cuboctahedra, edges with six equivalent Mg(1)Mg10Ti2 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, faces with three equivalent Mg(2)Ce2Mg10 cuboctahedra, faces with three equivalent Mg(1)Mg10Ti2 cuboctahedra, faces with three equivalent Ce(1)Mg12 cuboctahedra, faces with three equivalent Ti(1)Mg12 cuboctahedra, and faces with six equivalent Mg(3)CeMg10Ti cuboctahedra. Ce(1) is bonded to six equivalent Mg(2) and six equivalent Mg(3) atoms to form CeMg12 cuboctahedra that share corners with six equivalent Ce(1)Mg12 cuboctahedra, corners with twelve equivalent Mg(1)Mg10Ti2 cuboctahedra, edges with six equivalent Mg(2)Ce2Mg10 cuboctahedra, edges with twelve equivalent Mg(3)CeMg10Ti cuboctahedra, faces with two equivalent Ti(1)Mg12 cuboctahedra, faces with six equivalent Mg(2)Ce2Mg10 cuboctahedra, faces with six equivalent Mg(3)CeMg10Ti cuboctahedra, and faces with six equivalent Mg(4)Mg12 cuboctahedra. Ti(1) is bonded to six equivalent Mg(1) and six equivalent Mg(3) atoms to form TiMg12 cuboctahedra that share corners with six equivalent Ti(1)Mg12 cuboctahedra, corners with twelve equivalent Mg(2)Ce2Mg10 cuboctahedra, edges with six equivalent Mg(1)Mg10Ti2 cuboctahedra, edges with twelve equivalent Mg(3)CeMg10Ti cuboctahedra, faces with two equivalent Ce(1)Mg12 cuboctahedra, faces with six equivalent Mg(3)CeMg10Ti cuboctahedra, faces with six equivalent Mg(1)Mg10Ti2 cuboctahedra, and faces with six equivalent Mg(4)Mg12 cuboctahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_CeMg14Ti
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.611
_cell_length_b   6.611
_cell_length_c   10.403
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   393.723
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.167  0.333  0.625  1.0
  Mg  Mg1  1  0.163  0.832  0.125  1.0
  Mg  Mg2  1  0.182  0.841  0.625  1.0
  Mg  Mg3  1  0.668  0.337  0.125  1.0
  Mg  Mg4  1  0.659  0.318  0.625  1.0
  Mg  Mg5  1  0.668  0.832  0.125  1.0
  Mg  Mg6  1  0.659  0.841  0.625  1.0
  Mg  Mg7  1  0.332  0.168  0.364  1.0
  Mg  Mg8  1  0.332  0.168  0.886  1.0
  Mg  Mg9  1  0.332  0.664  0.364  1.0
  Mg  Mg10  1  0.332  0.664  0.886  1.0
  Mg  Mg11  1  0.836  0.168  0.364  1.0
  Mg  Mg12  1  0.836  0.168  0.886  1.0
  Mg  Mg13  1  0.833  0.667  0.385  1.0
  Mg  Mg14  1  0.833  0.667  0.865  1.0
  Ti  Ti15  1  0.167  0.333  0.125  1.0
[/CIF]
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The material structure described by Mg14CeTi crystallizes in the hexagonal P-6m2 space group. There are four inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(4), four equivalent Mg(1), four equivalent Mg(3), and two equivalent Ti(1) atoms to form MgMg10Ti2 cuboctahedra that share corners with four equivalent Ce(1)Mg12 cuboctahedra, corners with six equivalent Mg(1)Mg10Ti2 cuboctahedra, corners with eight equivalent Mg(2)Ce2Mg10 cuboctahedra, edges with two equivalent Ti(1)Mg12 cuboctahedra, edges with four equivalent Mg(1)Mg10Ti2 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra, edges with eight equivalent Mg(3)CeMg10Ti cuboctahedra, faces with two equivalent Mg(2)Ce2Mg10 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, faces with two equivalent Ti(1)Mg12 cuboctahedra, faces with four equivalent Mg(1)Mg10Ti2 cuboctahedra, and faces with ten equivalent Mg(3)CeMg10Ti cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(4), four equivalent Mg(2), four equivalent Mg(3), and two equivalent Ce(1) atoms to form distorted MgCe2Mg10 cuboctahedra that share corners with four equivalent Ti(1)Mg12 cuboctahedra, corners with six equivalent Mg(2)Ce2Mg10 cuboctahedra, corners with eight equivalent Mg(1)Mg10Ti2 cuboctahedra, edges with two equivalent Ce(1)Mg12 cuboctahedra, edges with four equivalent Mg(2)Ce2Mg10 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra, edges with eight equivalent Mg(3)CeMg10Ti cuboctahedra, faces with two equivalent Mg(1)Mg10Ti2 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, faces with two equivalent Ce(1)Mg12 cuboctahedra, faces with four equivalent Mg(2)Ce2Mg10 cuboctahedra, and faces with ten equivalent Mg(3)CeMg10Ti cuboctahedra. In the third Mg site, Mg(3) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), four equivalent Mg(3), one Ce(1), and one Ti(1) atom to form distorted MgCeMg10Ti cuboctahedra that share corners with four equivalent Mg(4)Mg12 cuboctahedra, corners with fourteen equivalent Mg(3)CeMg10Ti cuboctahedra, edges with two equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Ce(1)Mg12 cuboctahedra, edges with two equivalent Ti(1)Mg12 cuboctahedra, edges with four equivalent Mg(2)Ce2Mg10 cuboctahedra, edges with four equivalent Mg(3)CeMg10Ti cuboctahedra, edges with four equivalent Mg(1)Mg10Ti2 cuboctahedra,  a faceface with one Ce(1)Mg12 cuboctahedra,  a faceface with one Ti(1)Mg12 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, faces with five equivalent Mg(2)Ce2Mg10 cuboctahedra, faces with five equivalent Mg(1)Mg10Ti2 cuboctahedra, and faces with six equivalent Mg(3)CeMg10Ti cuboctahedra. In the fourth Mg site, Mg(4) is bonded to three equivalent Mg(1), three equivalent Mg(2), and six equivalent Mg(3) atoms to form MgMg12 cuboctahedra that share corners with six equivalent Mg(4)Mg12 cuboctahedra, corners with twelve equivalent Mg(3)CeMg10Ti cuboctahedra, edges with six equivalent Mg(2)Ce2Mg10 cuboctahedra, edges with six equivalent Mg(3)CeMg10Ti cuboctahedra, edges with six equivalent Mg(1)Mg10Ti2 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, faces with three equivalent Mg(2)Ce2Mg10 cuboctahedra, faces with three equivalent Mg(1)Mg10Ti2 cuboctahedra, faces with three equivalent Ce(1)Mg12 cuboctahedra, faces with three equivalent Ti(1)Mg12 cuboctahedra, and faces with six equivalent Mg(3)CeMg10Ti cuboctahedra. Ce(1) is bonded to six equivalent Mg(2) and six equivalent Mg(3) atoms to form CeMg12 cuboctahedra that share corners with six equivalent Ce(1)Mg12 cuboctahedra, corners with twelve equivalent Mg(1)Mg10Ti2 cuboctahedra, edges with six equivalent Mg(2)Ce2Mg10 cuboctahedra, edges with twelve equivalent Mg(3)CeMg10Ti cuboctahedra, faces with two equivalent Ti(1)Mg12 cuboctahedra, faces with six equivalent Mg(2)Ce2Mg10 cuboctahedra, faces with six equivalent Mg(3)CeMg10Ti cuboctahedra, and faces with six equivalent Mg(4)Mg12 cuboctahedra. Ti(1) is bonded to six equivalent Mg(1) and six equivalent Mg(3) atoms to form TiMg12 cuboctahedra that share corners with six equivalent Ti(1)Mg12 cuboctahedra, corners with twelve equivalent Mg(2)Ce2Mg10 cuboctahedra, edges with six equivalent Mg(1)Mg10Ti2 cuboctahedra, edges with twelve equivalent Mg(3)CeMg10Ti cuboctahedra, faces with two equivalent Ce(1)Mg12 cuboctahedra, faces with six equivalent Mg(3)CeMg10Ti cuboctahedra, faces with six equivalent Mg(1)Mg10Ti2 cuboctahedra, and faces with six equivalent Mg(4)Mg12 cuboctahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_CeMg14Ti
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.611
_cell_length_b   6.611
_cell_length_c   10.403
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   120.000
_symmetry_Int_Tables_number   1
_cell_volume   393.723
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ce  Ce0  1  0.167  0.333  0.625  1.0
  Mg  Mg1  1  0.163  0.832  0.125  1.0
  Mg  Mg2  1  0.182  0.841  0.625  1.0
  Mg  Mg3  1  0.668  0.337  0.125  1.0
  Mg  Mg4  1  0.659  0.318  0.625  1.0
  Mg  Mg5  1  0.668  0.832  0.125  1.0
  Mg  Mg6  1  0.659  0.841  0.625  1.0
  Mg  Mg7  1  0.332  0.168  0.364  1.0
  Mg  Mg8  1  0.332  0.168  0.886  1.0
  Mg  Mg9  1  0.332  0.664  0.364  1.0
  Mg  Mg10  1  0.332  0.664  0.886  1.0
  Mg  Mg11  1  0.836  0.168  0.364  1.0
  Mg  Mg12  1  0.836  0.168  0.886  1.0
  Mg  Mg13  1  0.833  0.667  0.385  1.0
  Mg  Mg14  1  0.833  0.667  0.865  1.0
  Ti  Ti15  1  0.167  0.333  0.125  1.0
[/CIF]
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