The compound described by La2Rh3Ge5 crystallizes in the orthorhombic Ibam space group. La(1) is bonded in a 17-coordinate geometry to two equivalent Rh(2), five equivalent Rh(1), two equivalent Ge(1), four equivalent Ge(2), and four equivalent Ge(3) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 5-coordinate geometry to five equivalent La(1), one Ge(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. In the second Rh site, Rh(2) is bonded in a 6-coordinate geometry to four equivalent La(1), two equivalent Ge(2), and four equivalent Ge(3) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 8-coordinate geometry to four equivalent La(1) and four equivalent Rh(1) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to four equivalent La(1), one Rh(2), two equivalent Rh(1), and two equivalent Ge(3) atoms. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to four equivalent La(1), one Rh(1), two equivalent Rh(2), and two equivalent Ge(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_La2Ge5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.495
_cell_length_b   8.495
_cell_length_c   8.492
_cell_angle_alpha   137.933
_cell_angle_beta   106.454
_cell_angle_gamma   88.542
_symmetry_Int_Tables_number   1
_cell_volume   377.105
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.364  0.132  0.232  1.0
  La  La1  1  0.636  0.868  0.768  1.0
  La  La2  1  0.099  0.368  0.732  1.0
  La  La3  1  0.901  0.632  0.268  1.0
  Ge  Ge4  1  1.000  0.250  0.250  1.0
  Ge  Ge5  1  0.000  0.750  0.750  1.0
  Ge  Ge6  1  0.726  0.976  0.250  1.0
  Ge  Ge7  1  0.274  0.524  0.250  1.0
  Ge  Ge8  1  0.274  0.024  0.750  1.0
  Ge  Ge9  1  0.726  0.476  0.750  1.0
  Ge  Ge10  1  0.554  0.398  0.155  1.0
  Ge  Ge11  1  0.243  0.899  0.345  1.0
  Ge  Ge12  1  0.757  0.101  0.655  1.0
  Ge  Ge13  1  0.446  0.602  0.845  1.0
  Rh  Rh14  1  0.968  0.860  0.108  1.0
  Rh  Rh15  1  0.500  0.750  0.250  1.0
  Rh  Rh16  1  0.752  0.360  0.392  1.0
  Rh  Rh17  1  0.248  0.640  0.608  1.0
  Rh  Rh18  1  0.032  0.140  0.892  1.0
  Rh  Rh19  1  0.500  0.250  0.750  1.0
[/CIF]
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The compound described by La2Rh3Ge5 crystallizes in the orthorhombic Ibam space group. La(1) is bonded in a 17-coordinate geometry to two equivalent Rh(2), five equivalent Rh(1), two equivalent Ge(1), four equivalent Ge(2), and four equivalent Ge(3) atoms. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 5-coordinate geometry to five equivalent La(1), one Ge(3), two equivalent Ge(1), and two equivalent Ge(2) atoms. In the second Rh site, Rh(2) is bonded in a 6-coordinate geometry to four equivalent La(1), two equivalent Ge(2), and four equivalent Ge(3) atoms. There are three inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 8-coordinate geometry to four equivalent La(1) and four equivalent Rh(1) atoms. In the second Ge site, Ge(2) is bonded in a 9-coordinate geometry to four equivalent La(1), one Rh(2), two equivalent Rh(1), and two equivalent Ge(3) atoms. In the third Ge site, Ge(3) is bonded in a 9-coordinate geometry to four equivalent La(1), one Rh(1), two equivalent Rh(2), and two equivalent Ge(2) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_La2Ge5Rh3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.495
_cell_length_b   8.495
_cell_length_c   8.492
_cell_angle_alpha   137.933
_cell_angle_beta   106.454
_cell_angle_gamma   88.542
_symmetry_Int_Tables_number   1
_cell_volume   377.105
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.364  0.132  0.232  1.0
  La  La1  1  0.636  0.868  0.768  1.0
  La  La2  1  0.099  0.368  0.732  1.0
  La  La3  1  0.901  0.632  0.268  1.0
  Ge  Ge4  1  1.000  0.250  0.250  1.0
  Ge  Ge5  1  0.000  0.750  0.750  1.0
  Ge  Ge6  1  0.726  0.976  0.250  1.0
  Ge  Ge7  1  0.274  0.524  0.250  1.0
  Ge  Ge8  1  0.274  0.024  0.750  1.0
  Ge  Ge9  1  0.726  0.476  0.750  1.0
  Ge  Ge10  1  0.554  0.398  0.155  1.0
  Ge  Ge11  1  0.243  0.899  0.345  1.0
  Ge  Ge12  1  0.757  0.101  0.655  1.0
  Ge  Ge13  1  0.446  0.602  0.845  1.0
  Rh  Rh14  1  0.968  0.860  0.108  1.0
  Rh  Rh15  1  0.500  0.750  0.250  1.0
  Rh  Rh16  1  0.752  0.360  0.392  1.0
  Rh  Rh17  1  0.248  0.640  0.608  1.0
  Rh  Rh18  1  0.032  0.140  0.892  1.0
  Rh  Rh19  1  0.500  0.250  0.750  1.0
[/CIF]
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