The compound described by K5In(MoO4)4 crystallizes in the monoclinic Cc space group. There are five inequivalent K sites. In the first K site, K(1) is bonded in a 10-coordinate geometry to one O(1), one O(10), one O(11), one O(13), one O(16), one O(2), one O(3), one O(5), one O(8), and one O(9) atom. In the second K site, K(2) is bonded in a 8-coordinate geometry to one O(11), one O(12), one O(14), one O(15), one O(2), one O(3), one O(5), and one O(8) atom. In the third K site, K(3) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(16), one O(4), one O(6), one O(7), and two equivalent O(10) atoms. In the fourth K site, K(4) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(13), one O(16), one O(3), and one O(4) atom. In the fifth K site, K(5) is bonded in a 8-coordinate geometry to one O(12), one O(14), one O(15), one O(3), one O(8), one O(9), and two equivalent O(2) atoms. There are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form MoO4 tetrahedra that share  a cornercorner with one In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 45°. In the second Mo site, Mo(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form MoO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. In the third Mo site, Mo(3) is bonded to one O(10), one O(11), one O(12), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 43°. In the fourth Mo site, Mo(4) is bonded to one O(13), one O(14), one O(15), and one O(16) atom to form MoO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-48°. In(1) is bonded to one O(12), one O(14), one O(15), one O(4), one O(6), and one O(7) atom to form InO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra, corners with two equivalent Mo(2)O4 tetrahedra, and corners with two equivalent Mo(4)O4 tetrahedra. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one K(3), and one Mo(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one K(1), one K(2), two equivalent K(5), and one Mo(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one K(1), one K(2), one K(4), one K(5), and one Mo(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one K(3), one K(4), one Mo(1), and one In(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one K(1), one K(2), and one Mo(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one K(3), one Mo(2), and one In(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one K(3), one Mo(2), and one In(1) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one K(1), one K(2), one K(5), and one Mo(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one K(1), one K(5), and one Mo(3) atom. In the tenth O site, O(10) is bonded in a 1-coordinate geometry to one K(1), one K(4), two equivalent K(3), and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one K(1), one K(2), one K(3), one K(4), and one Mo(3) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one K(2), one K(5), one Mo(3), and one In(1) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one K(1), one K(4), and one Mo(4) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one K(2), one K(5), one Mo(4), and one In(1) atom. In the fifteenth O site, O(15) is bonded in a 2-coordinate geometry to one K(2), one K(5), one Mo(4), and one In(1) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one K(1), one K(3), one K(4), and one Mo(4) atom. is represented by the CIF card [CIF]
data_K5In(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.687
_cell_length_b   9.687
_cell_length_c   10.707
_cell_angle_alpha   71.731
_cell_angle_beta   71.731
_cell_angle_gamma   79.077
_symmetry_Int_Tables_number   1
_cell_volume   901.435
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.389  0.609  0.750  1.0
  K  K1  1  0.609  0.389  0.250  1.0
  K  K2  1  0.336  0.076  0.435  1.0
  K  K3  1  0.076  0.336  0.935  1.0
  K  K4  1  0.820  0.616  0.442  1.0
  K  K5  1  0.616  0.820  0.942  1.0
  K  K6  1  0.650  0.930  0.574  1.0
  K  K7  1  0.930  0.650  0.074  1.0
  K  K8  1  0.181  0.383  0.569  1.0
  K  K9  1  0.383  0.181  0.069  1.0
  In  In10  1  0.885  0.115  0.751  1.0
  In  In11  1  0.115  0.885  0.251  1.0
  Mo  Mo12  1  0.533  0.263  0.661  1.0
  Mo  Mo13  1  0.263  0.533  0.161  1.0
  Mo  Mo14  1  0.045  0.780  0.636  1.0
  Mo  Mo15  1  0.780  0.045  0.136  1.0
  Mo  Mo16  1  0.469  0.738  0.343  1.0
  Mo  Mo17  1  0.738  0.469  0.843  1.0
  Mo  Mo18  1  0.957  0.217  0.370  1.0
  Mo  Mo19  1  0.217  0.957  0.870  1.0
  O  O20  1  0.620  0.426  0.580  1.0
  O  O21  1  0.426  0.620  0.080  1.0
  O  O22  1  0.368  0.300  0.787  1.0
  O  O23  1  0.300  0.368  0.287  1.0
  O  O24  1  0.479  0.213  0.538  1.0
  O  O25  1  0.213  0.479  0.038  1.0
  O  O26  1  0.666  0.121  0.736  1.0
  O  O27  1  0.121  0.666  0.236  1.0
  O  O28  1  0.213  0.846  0.604  1.0
  O  O29  1  0.846  0.213  0.104  1.0
  O  O30  1  0.012  0.802  0.471  1.0
  O  O31  1  0.802  0.012  0.971  1.0
  O  O32  1  0.902  0.889  0.735  1.0
  O  O33  1  0.889  0.902  0.235  1.0
  O  O34  1  0.063  0.591  0.724  1.0
  O  O35  1  0.591  0.063  0.224  1.0
  O  O36  1  0.388  0.573  0.424  1.0
  O  O37  1  0.573  0.388  0.924  1.0
  O  O38  1  0.637  0.705  0.218  1.0
  O  O39  1  0.705  0.637  0.718  1.0
  O  O40  1  0.518  0.790  0.469  1.0
  O  O41  1  0.790  0.518  0.969  1.0
  O  O42  1  0.336  0.877  0.266  1.0
  O  O43  1  0.877  0.336  0.766  1.0
  O  O44  1  0.789  0.152  0.406  1.0
  O  O45  1  0.152  0.789  0.906  1.0
  O  O46  1  0.997  0.194  0.533  1.0
  O  O47  1  0.194  0.997  0.033  1.0
  O  O48  1  0.100  0.110  0.269  1.0
  O  O49  1  0.110  0.100  0.769  1.0
  O  O50  1  0.941  0.405  0.283  1.0
  O  O51  1  0.405  0.941  0.783  1.0
[/CIF]
.
The compound described by K5In(MoO4)4 crystallizes in the monoclinic Cc space group. There are five inequivalent K sites. In the first K site, K(1) is bonded in a 10-coordinate geometry to one O(1), one O(10), one O(11), one O(13), one O(16), one O(2), one O(3), one O(5), one O(8), and one O(9) atom. In the second K site, K(2) is bonded in a 8-coordinate geometry to one O(11), one O(12), one O(14), one O(15), one O(2), one O(3), one O(5), and one O(8) atom. In the third K site, K(3) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(16), one O(4), one O(6), one O(7), and two equivalent O(10) atoms. In the fourth K site, K(4) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(13), one O(16), one O(3), and one O(4) atom. In the fifth K site, K(5) is bonded in a 8-coordinate geometry to one O(12), one O(14), one O(15), one O(3), one O(8), one O(9), and two equivalent O(2) atoms. There are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form MoO4 tetrahedra that share  a cornercorner with one In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 45°. In the second Mo site, Mo(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form MoO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 40-47°. In the third Mo site, Mo(3) is bonded to one O(10), one O(11), one O(12), and one O(9) atom to form MoO4 tetrahedra that share  a cornercorner with one In(1)O6 octahedra. The corner-sharing octahedral tilt angles are 43°. In the fourth Mo site, Mo(4) is bonded to one O(13), one O(14), one O(15), and one O(16) atom to form MoO4 tetrahedra that share corners with two equivalent In(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 44-48°. In(1) is bonded to one O(12), one O(14), one O(15), one O(4), one O(6), and one O(7) atom to form InO6 octahedra that share  a cornercorner with one Mo(1)O4 tetrahedra,  a cornercorner with one Mo(3)O4 tetrahedra, corners with two equivalent Mo(2)O4 tetrahedra, and corners with two equivalent Mo(4)O4 tetrahedra. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one K(1), one K(3), and one Mo(1) atom. In the second O site, O(2) is bonded in a 1-coordinate geometry to one K(1), one K(2), two equivalent K(5), and one Mo(1) atom. In the third O site, O(3) is bonded in a 5-coordinate geometry to one K(1), one K(2), one K(4), one K(5), and one Mo(1) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one K(3), one K(4), one Mo(1), and one In(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one K(1), one K(2), and one Mo(2) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one K(3), one Mo(2), and one In(1) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one K(3), one Mo(2), and one In(1) atom. In the eighth O site, O(8) is bonded in a 1-coordinate geometry to one K(1), one K(2), one K(5), and one Mo(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one K(1), one K(5), and one Mo(3) atom. In the tenth O site, O(10) is bonded in a 1-coordinate geometry to one K(1), one K(4), two equivalent K(3), and one Mo(3) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one K(1), one K(2), one K(3), one K(4), and one Mo(3) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one K(2), one K(5), one Mo(3), and one In(1) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one K(1), one K(4), and one Mo(4) atom. In the fourteenth O site, O(14) is bonded in a 4-coordinate geometry to one K(2), one K(5), one Mo(4), and one In(1) atom. In the fifteenth O site, O(15) is bonded in a 2-coordinate geometry to one K(2), one K(5), one Mo(4), and one In(1) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one K(1), one K(3), one K(4), and one Mo(4) atom. is represented by the CIF card [CIF]
data_K5In(MoO4)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.687
_cell_length_b   9.687
_cell_length_c   10.707
_cell_angle_alpha   71.731
_cell_angle_beta   71.731
_cell_angle_gamma   79.077
_symmetry_Int_Tables_number   1
_cell_volume   901.435
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.389  0.609  0.750  1.0
  K  K1  1  0.609  0.389  0.250  1.0
  K  K2  1  0.336  0.076  0.435  1.0
  K  K3  1  0.076  0.336  0.935  1.0
  K  K4  1  0.820  0.616  0.442  1.0
  K  K5  1  0.616  0.820  0.942  1.0
  K  K6  1  0.650  0.930  0.574  1.0
  K  K7  1  0.930  0.650  0.074  1.0
  K  K8  1  0.181  0.383  0.569  1.0
  K  K9  1  0.383  0.181  0.069  1.0
  In  In10  1  0.885  0.115  0.751  1.0
  In  In11  1  0.115  0.885  0.251  1.0
  Mo  Mo12  1  0.533  0.263  0.661  1.0
  Mo  Mo13  1  0.263  0.533  0.161  1.0
  Mo  Mo14  1  0.045  0.780  0.636  1.0
  Mo  Mo15  1  0.780  0.045  0.136  1.0
  Mo  Mo16  1  0.469  0.738  0.343  1.0
  Mo  Mo17  1  0.738  0.469  0.843  1.0
  Mo  Mo18  1  0.957  0.217  0.370  1.0
  Mo  Mo19  1  0.217  0.957  0.870  1.0
  O  O20  1  0.620  0.426  0.580  1.0
  O  O21  1  0.426  0.620  0.080  1.0
  O  O22  1  0.368  0.300  0.787  1.0
  O  O23  1  0.300  0.368  0.287  1.0
  O  O24  1  0.479  0.213  0.538  1.0
  O  O25  1  0.213  0.479  0.038  1.0
  O  O26  1  0.666  0.121  0.736  1.0
  O  O27  1  0.121  0.666  0.236  1.0
  O  O28  1  0.213  0.846  0.604  1.0
  O  O29  1  0.846  0.213  0.104  1.0
  O  O30  1  0.012  0.802  0.471  1.0
  O  O31  1  0.802  0.012  0.971  1.0
  O  O32  1  0.902  0.889  0.735  1.0
  O  O33  1  0.889  0.902  0.235  1.0
  O  O34  1  0.063  0.591  0.724  1.0
  O  O35  1  0.591  0.063  0.224  1.0
  O  O36  1  0.388  0.573  0.424  1.0
  O  O37  1  0.573  0.388  0.924  1.0
  O  O38  1  0.637  0.705  0.218  1.0
  O  O39  1  0.705  0.637  0.718  1.0
  O  O40  1  0.518  0.790  0.469  1.0
  O  O41  1  0.790  0.518  0.969  1.0
  O  O42  1  0.336  0.877  0.266  1.0
  O  O43  1  0.877  0.336  0.766  1.0
  O  O44  1  0.789  0.152  0.406  1.0
  O  O45  1  0.152  0.789  0.906  1.0
  O  O46  1  0.997  0.194  0.533  1.0
  O  O47  1  0.194  0.997  0.033  1.0
  O  O48  1  0.100  0.110  0.269  1.0
  O  O49  1  0.110  0.100  0.769  1.0
  O  O50  1  0.941  0.405  0.283  1.0
  O  O51  1  0.405  0.941  0.783  1.0
[/CIF]
.