The crystal structure described by BiOF crystallizes in the orthorhombic Pnma space group. Bi(1) is bonded in a 5-coordinate geometry to three equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded in a trigonal non-coplanar geometry to three equivalent Bi(1) atoms. F(1) is bonded to four equivalent Bi(1) atoms to form a mixture of distorted corner and edge-sharing FBi4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.983
_cell_length_b   5.937
_cell_length_c   8.208
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   194.092
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.250  0.295  0.113  1.0
  Bi  Bi1  1  0.750  0.795  0.387  1.0
  Bi  Bi2  1  0.250  0.205  0.613  1.0
  Bi  Bi3  1  0.750  0.705  0.887  1.0
  O  O4  1  0.750  0.490  0.115  1.0
  O  O5  1  0.250  0.990  0.385  1.0
  O  O6  1  0.750  0.010  0.615  1.0
  O  O7  1  0.250  0.510  0.885  1.0
  F  F8  1  0.750  0.981  0.127  1.0
  F  F9  1  0.250  0.481  0.373  1.0
  F  F10  1  0.750  0.519  0.627  1.0
  F  F11  1  0.250  0.019  0.873  1.0
[/CIF]
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The crystal structure described by BiOF crystallizes in the orthorhombic Pnma space group. Bi(1) is bonded in a 5-coordinate geometry to three equivalent O(1) and four equivalent F(1) atoms. O(1) is bonded in a trigonal non-coplanar geometry to three equivalent Bi(1) atoms. F(1) is bonded to four equivalent Bi(1) atoms to form a mixture of distorted corner and edge-sharing FBi4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_BiOF
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.983
_cell_length_b   5.937
_cell_length_c   8.208
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   194.092
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.250  0.295  0.113  1.0
  Bi  Bi1  1  0.750  0.795  0.387  1.0
  Bi  Bi2  1  0.250  0.205  0.613  1.0
  Bi  Bi3  1  0.750  0.705  0.887  1.0
  O  O4  1  0.750  0.490  0.115  1.0
  O  O5  1  0.250  0.990  0.385  1.0
  O  O6  1  0.750  0.010  0.615  1.0
  O  O7  1  0.250  0.510  0.885  1.0
  F  F8  1  0.750  0.981  0.127  1.0
  F  F9  1  0.250  0.481  0.373  1.0
  F  F10  1  0.750  0.519  0.627  1.0
  F  F11  1  0.250  0.019  0.873  1.0
[/CIF]
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