The structure described by Ir(NO2)4N2(NO)2NO2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two ammonia atoms, one nitrous acid molecule, two nitroxyl molecules, and one Ir(NO2)4 cluster. In the Ir(NO2)4 cluster, Ir(1) is bonded in a distorted trigonal bipyramidal geometry to one N(6), one O(4), one O(7), one O(8), and one O(9) atom. There are four inequivalent N sites. In the first N site, N(2) is bonded in a bent 120 degrees geometry to one O(1) and one O(8) atom. In the second N site, N(4) is bonded in a bent 120 degrees geometry to one O(6) and one O(7) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Ir(1), one O(11), and one O(12) atom. In the fourth N site, N(8) is bonded in a single-bond geometry to one O(9) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Ir(1) atom. In the third O site, O(6) is bonded in a single-bond geometry to one N(4) atom. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to one Ir(1) and one N(4) atom. In the fifth O site, O(8) is bonded in a bent 120 degrees geometry to one Ir(1) and one N(2) atom. In the sixth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Ir(1) and one N(8) atom. In the seventh O site, O(11) is bonded in a single-bond geometry to one N(6) atom. In the eighth O site, O(12) is bonded in a single-bond geometry to one N(6) atom. is represented by the CIF card [CIF]
data_Ir(N3O4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.303
_cell_length_b   8.975
_cell_length_c   8.534
_cell_angle_alpha   53.894
_cell_angle_beta   56.407
_cell_angle_gamma   62.889
_symmetry_Int_Tables_number   1
_cell_volume   419.941
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ir  Ir0  1  0.823  0.176  0.996  1.0
  N  N1  1  0.204  0.754  0.895  1.0
  N  N2  1  0.253  0.133  0.757  1.0
  N  N3  1  0.218  0.890  0.114  1.0
  N  N4  1  0.928  0.198  0.270  1.0
  N  N5  1  0.983  0.653  0.169  1.0
  N  N6  1  0.762  0.107  0.844  1.0
  N  N7  1  0.505  0.522  0.492  1.0
  N  N8  1  0.789  0.621  0.795  1.0
  N  N9  1  0.277  0.243  0.256  1.0
  O  O10  1  0.395  0.177  0.594  1.0
  O  O11  1  0.349  0.853  0.149  1.0
  O  O12  1  0.315  0.640  0.842  1.0
  O  O13  1  0.674  0.028  0.244  1.0
  O  O14  1  0.010  0.629  0.311  1.0
  O  O15  1  0.001  0.030  0.324  1.0
  O  O16  1  0.869  0.292  0.117  1.0
  O  O17  1  0.077  0.236  0.745  1.0
  O  O18  1  0.737  0.517  0.799  1.0
  O  O19  1  0.846  0.627  0.179  1.0
  O  O20  1  0.589  0.157  0.862  1.0
  O  O21  1  0.895  0.016  0.746  1.0
[/CIF]
.
The structure described by Ir(NO2)4N2(NO)2NO2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two ammonia atoms, one nitrous acid molecule, two nitroxyl molecules, and one Ir(NO2)4 cluster. In the Ir(NO2)4 cluster, Ir(1) is bonded in a distorted trigonal bipyramidal geometry to one N(6), one O(4), one O(7), one O(8), and one O(9) atom. There are four inequivalent N sites. In the first N site, N(2) is bonded in a bent 120 degrees geometry to one O(1) and one O(8) atom. In the second N site, N(4) is bonded in a bent 120 degrees geometry to one O(6) and one O(7) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Ir(1), one O(11), and one O(12) atom. In the fourth N site, N(8) is bonded in a single-bond geometry to one O(9) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(2) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Ir(1) atom. In the third O site, O(6) is bonded in a single-bond geometry to one N(4) atom. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to one Ir(1) and one N(4) atom. In the fifth O site, O(8) is bonded in a bent 120 degrees geometry to one Ir(1) and one N(2) atom. In the sixth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Ir(1) and one N(8) atom. In the seventh O site, O(11) is bonded in a single-bond geometry to one N(6) atom. In the eighth O site, O(12) is bonded in a single-bond geometry to one N(6) atom. is represented by the CIF card [CIF]
data_Ir(N3O4)3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.303
_cell_length_b   8.975
_cell_length_c   8.534
_cell_angle_alpha   53.894
_cell_angle_beta   56.407
_cell_angle_gamma   62.889
_symmetry_Int_Tables_number   1
_cell_volume   419.941
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ir  Ir0  1  0.823  0.176  0.996  1.0
  N  N1  1  0.204  0.754  0.895  1.0
  N  N2  1  0.253  0.133  0.757  1.0
  N  N3  1  0.218  0.890  0.114  1.0
  N  N4  1  0.928  0.198  0.270  1.0
  N  N5  1  0.983  0.653  0.169  1.0
  N  N6  1  0.762  0.107  0.844  1.0
  N  N7  1  0.505  0.522  0.492  1.0
  N  N8  1  0.789  0.621  0.795  1.0
  N  N9  1  0.277  0.243  0.256  1.0
  O  O10  1  0.395  0.177  0.594  1.0
  O  O11  1  0.349  0.853  0.149  1.0
  O  O12  1  0.315  0.640  0.842  1.0
  O  O13  1  0.674  0.028  0.244  1.0
  O  O14  1  0.010  0.629  0.311  1.0
  O  O15  1  0.001  0.030  0.324  1.0
  O  O16  1  0.869  0.292  0.117  1.0
  O  O17  1  0.077  0.236  0.745  1.0
  O  O18  1  0.737  0.517  0.799  1.0
  O  O19  1  0.846  0.627  0.179  1.0
  O  O20  1  0.589  0.157  0.862  1.0
  O  O21  1  0.895  0.016  0.746  1.0
[/CIF]
.