The material described by LiRhZnF6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2nm space group. Li(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form LiF6 octahedra that share corners with four equivalent Rh(1)F6 octahedra, corners with four equivalent Zn(1)F6 octahedra,  an edgeedge with one Rh(1)F6 octahedra, and  an edgeedge with one Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. Rh(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form RhF6 octahedra that share corners with four equivalent Li(1)F6 octahedra, corners with four equivalent Zn(1)F6 octahedra,  an edgeedge with one Li(1)F6 octahedra, and  an edgeedge with one Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. Zn(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form ZnF6 octahedra that share corners with four equivalent Li(1)F6 octahedra, corners with four equivalent Rh(1)F6 octahedra,  an edgeedge with one Li(1)F6 octahedra, and  an edgeedge with one Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. There are three inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Li(1), one Rh(1), and one Zn(1) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Rh(1), and one Zn(1) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Li(1), one Rh(1), and one Zn(1) atom. is represented by the CIF file [CIF]
data_LiZnRhF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.763
_cell_length_b   4.763
_cell_length_c   9.437
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   214.056
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.499  1.0
  Li  Li1  1  0.000  0.000  0.999  1.0
  Zn  Zn2  1  0.500  0.500  0.169  1.0
  Zn  Zn3  1  0.000  0.000  0.669  1.0
  Rh  Rh4  1  0.500  0.500  0.832  1.0
  Rh  Rh5  1  0.000  0.000  0.332  1.0
  F  F6  1  0.193  0.807  0.496  1.0
  F  F7  1  0.807  0.193  0.496  1.0
  F  F8  1  0.307  0.307  0.996  1.0
  F  F9  1  0.693  0.693  0.996  1.0
  F  F10  1  0.194  0.806  0.169  1.0
  F  F11  1  0.806  0.194  0.169  1.0
  F  F12  1  0.306  0.306  0.669  1.0
  F  F13  1  0.694  0.694  0.669  1.0
  F  F14  1  0.800  0.200  0.834  1.0
  F  F15  1  0.200  0.800  0.834  1.0
  F  F16  1  0.700  0.700  0.334  1.0
  F  F17  1  0.300  0.300  0.334  1.0
[/CIF]
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The material described by LiRhZnF6 is Hydrophilite-derived structured and crystallizes in the tetragonal P4_2nm space group. Li(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form LiF6 octahedra that share corners with four equivalent Rh(1)F6 octahedra, corners with four equivalent Zn(1)F6 octahedra,  an edgeedge with one Rh(1)F6 octahedra, and  an edgeedge with one Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-52°. Rh(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form RhF6 octahedra that share corners with four equivalent Li(1)F6 octahedra, corners with four equivalent Zn(1)F6 octahedra,  an edgeedge with one Li(1)F6 octahedra, and  an edgeedge with one Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 49-50°. Zn(1) is bonded to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms to form ZnF6 octahedra that share corners with four equivalent Li(1)F6 octahedra, corners with four equivalent Rh(1)F6 octahedra,  an edgeedge with one Li(1)F6 octahedra, and  an edgeedge with one Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles range from 50-52°. There are three inequivalent F sites. In the first F site, F(1) is bonded in a trigonal planar geometry to one Li(1), one Rh(1), and one Zn(1) atom. In the second F site, F(2) is bonded in a distorted trigonal planar geometry to one Li(1), one Rh(1), and one Zn(1) atom. In the third F site, F(3) is bonded in a distorted trigonal planar geometry to one Li(1), one Rh(1), and one Zn(1) atom. is represented by the CIF file [CIF]
data_LiZnRhF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.763
_cell_length_b   4.763
_cell_length_c   9.437
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   214.056
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.500  0.500  0.499  1.0
  Li  Li1  1  0.000  0.000  0.999  1.0
  Zn  Zn2  1  0.500  0.500  0.169  1.0
  Zn  Zn3  1  0.000  0.000  0.669  1.0
  Rh  Rh4  1  0.500  0.500  0.832  1.0
  Rh  Rh5  1  0.000  0.000  0.332  1.0
  F  F6  1  0.193  0.807  0.496  1.0
  F  F7  1  0.807  0.193  0.496  1.0
  F  F8  1  0.307  0.307  0.996  1.0
  F  F9  1  0.693  0.693  0.996  1.0
  F  F10  1  0.194  0.806  0.169  1.0
  F  F11  1  0.806  0.194  0.169  1.0
  F  F12  1  0.306  0.306  0.669  1.0
  F  F13  1  0.694  0.694  0.669  1.0
  F  F14  1  0.800  0.200  0.834  1.0
  F  F15  1  0.200  0.800  0.834  1.0
  F  F16  1  0.700  0.700  0.334  1.0
  F  F17  1  0.300  0.300  0.334  1.0
[/CIF]
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