The compound described by Bi14SO24 crystallizes in the triclinic P-1 space group. There are seven inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(7), and two equivalent O(4) atoms. In the second Bi site, Bi(2) is bonded to one O(2), one O(6), one O(8), and two equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing BiO5 square pyramids. In the third Bi site, Bi(3) is bonded in a distorted body-centered cubic geometry to one O(1), one O(10), one O(11), one O(12), one O(2), one O(3), one O(4), and one O(8) atom. In the fourth Bi site, Bi(4) is bonded in a 5-coordinate geometry to one O(11), one O(4), one O(6), and two equivalent O(12) atoms. In the fifth Bi site, Bi(5) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(2), one O(3), and two equivalent O(6) atoms. In the sixth Bi site, Bi(6) is bonded to one O(10), one O(12), one O(7), and two equivalent O(8) atoms to form a mixture of distorted edge and corner-sharing BiO5 square pyramids. In the seventh Bi site, Bi(7) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(2), one O(3), one O(9), and two equivalent O(7) atoms. S(1) is bonded in a square co-planar geometry to two equivalent O(5) and two equivalent O(9) atoms. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Bi(1), one Bi(3), and two equivalent Bi(2) atoms. In the second O site, O(2) is bonded to one Bi(2), one Bi(3), one Bi(5), and one Bi(7) atom to form a mixture of edge and corner-sharing OBi4 tetrahedra. In the third O site, O(3) is bonded to one Bi(1), one Bi(3), one Bi(5), and one Bi(7) atom to form a mixture of edge and corner-sharing OBi4 tetrahedra. In the fourth O site, O(4) is bonded to one Bi(3), one Bi(4), and two equivalent Bi(1) atoms to form a mixture of distorted edge and corner-sharing OBi4 tetrahedra. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Bi(2), one Bi(4), and two equivalent Bi(5) atoms. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Bi(1), one Bi(6), and two equivalent Bi(7) atoms. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Bi(2), one Bi(3), and two equivalent Bi(6) atoms. In the ninth O site, O(9) is bonded in a single-bond geometry to one Bi(7) and one S(1) atom. In the tenth O site, O(10) is bonded to one Bi(3), one Bi(5), one Bi(6), and one Bi(7) atom to form a mixture of edge and corner-sharing OBi4 tetrahedra. In the eleventh O site, O(11) is bonded to one Bi(3), one Bi(4), one Bi(5), and one Bi(7) atom to form a mixture of edge and corner-sharing OBi4 tetrahedra. In the twelfth O site, O(12) is bonded to one Bi(3), one Bi(6), and two equivalent Bi(4) atoms to form a mixture of distorted edge and corner-sharing OBi4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Bi14SO24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.826
_cell_length_b   8.857
_cell_length_c   10.603
_cell_angle_alpha   114.618
_cell_angle_beta   114.524
_cell_angle_gamma   90.143
_symmetry_Int_Tables_number   1
_cell_volume   669.986
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.057  0.869  0.333  1.0
  Bi  Bi1  1  0.530  0.938  0.660  1.0
  Bi  Bi2  1  0.660  0.658  0.318  1.0
  Bi  Bi3  1  0.125  0.721  0.662  1.0
  Bi  Bi4  1  0.557  0.783  0.001  1.0
  Bi  Bi5  1  0.274  0.462  0.332  1.0
  Bi  Bi6  1  0.726  0.538  0.668  1.0
  Bi  Bi7  1  0.210  0.561  0.001  1.0
  Bi  Bi8  1  0.875  0.279  0.338  1.0
  Bi  Bi9  1  0.340  0.342  0.682  1.0
  Bi  Bi10  1  0.790  0.439  0.999  1.0
  Bi  Bi11  1  0.470  0.062  0.340  1.0
  Bi  Bi12  1  0.943  0.131  0.667  1.0
  Bi  Bi13  1  0.443  0.217  0.999  1.0
  S  S14  1  0.000  0.000  0.000  1.0
  O  O15  1  0.668  0.998  0.498  1.0
  O  O16  1  0.457  0.763  0.158  1.0
  O  O17  1  0.761  0.700  0.158  1.0
  O  O18  1  0.994  0.825  0.494  1.0
  O  O19  1  0.935  0.918  0.816  1.0
  O  O20  1  0.378  0.888  0.767  1.0
  O  O21  1  0.115  0.614  0.231  1.0
  O  O22  1  0.494  0.667  0.493  1.0
  O  O23  1  0.014  0.817  0.992  1.0
  O  O24  1  0.396  0.460  0.159  1.0
  O  O25  1  0.700  0.398  0.157  1.0
  O  O26  1  0.173  0.498  0.505  1.0
  O  O27  1  0.827  0.502  0.495  1.0
  O  O28  1  0.300  0.602  0.843  1.0
  O  O29  1  0.604  0.540  0.841  1.0
  O  O30  1  0.506  0.333  0.507  1.0
  O  O31  1  0.885  0.386  0.769  1.0
  O  O32  1  0.622  0.112  0.233  1.0
  O  O33  1  0.065  0.082  0.184  1.0
  O  O34  1  0.006  0.175  0.506  1.0
  O  O35  1  0.239  0.300  0.842  1.0
  O  O36  1  0.543  0.237  0.842  1.0
  O  O37  1  0.332  0.002  0.502  1.0
  O  O38  1  0.986  0.183  0.008  1.0
[/CIF]
.
The compound described by Bi14SO24 crystallizes in the triclinic P-1 space group. There are seven inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(7), and two equivalent O(4) atoms. In the second Bi site, Bi(2) is bonded to one O(2), one O(6), one O(8), and two equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing BiO5 square pyramids. In the third Bi site, Bi(3) is bonded in a distorted body-centered cubic geometry to one O(1), one O(10), one O(11), one O(12), one O(2), one O(3), one O(4), and one O(8) atom. In the fourth Bi site, Bi(4) is bonded in a 5-coordinate geometry to one O(11), one O(4), one O(6), and two equivalent O(12) atoms. In the fifth Bi site, Bi(5) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(2), one O(3), and two equivalent O(6) atoms. In the sixth Bi site, Bi(6) is bonded to one O(10), one O(12), one O(7), and two equivalent O(8) atoms to form a mixture of distorted edge and corner-sharing BiO5 square pyramids. In the seventh Bi site, Bi(7) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(2), one O(3), one O(9), and two equivalent O(7) atoms. S(1) is bonded in a square co-planar geometry to two equivalent O(5) and two equivalent O(9) atoms. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Bi(1), one Bi(3), and two equivalent Bi(2) atoms. In the second O site, O(2) is bonded to one Bi(2), one Bi(3), one Bi(5), and one Bi(7) atom to form a mixture of edge and corner-sharing OBi4 tetrahedra. In the third O site, O(3) is bonded to one Bi(1), one Bi(3), one Bi(5), and one Bi(7) atom to form a mixture of edge and corner-sharing OBi4 tetrahedra. In the fourth O site, O(4) is bonded to one Bi(3), one Bi(4), and two equivalent Bi(1) atoms to form a mixture of distorted edge and corner-sharing OBi4 tetrahedra. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(6) is bonded in a 4-coordinate geometry to one Bi(2), one Bi(4), and two equivalent Bi(5) atoms. In the seventh O site, O(7) is bonded in a 4-coordinate geometry to one Bi(1), one Bi(6), and two equivalent Bi(7) atoms. In the eighth O site, O(8) is bonded in a 4-coordinate geometry to one Bi(2), one Bi(3), and two equivalent Bi(6) atoms. In the ninth O site, O(9) is bonded in a single-bond geometry to one Bi(7) and one S(1) atom. In the tenth O site, O(10) is bonded to one Bi(3), one Bi(5), one Bi(6), and one Bi(7) atom to form a mixture of edge and corner-sharing OBi4 tetrahedra. In the eleventh O site, O(11) is bonded to one Bi(3), one Bi(4), one Bi(5), and one Bi(7) atom to form a mixture of edge and corner-sharing OBi4 tetrahedra. In the twelfth O site, O(12) is bonded to one Bi(3), one Bi(6), and two equivalent Bi(4) atoms to form a mixture of distorted edge and corner-sharing OBi4 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_Bi14SO24
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.826
_cell_length_b   8.857
_cell_length_c   10.603
_cell_angle_alpha   114.618
_cell_angle_beta   114.524
_cell_angle_gamma   90.143
_symmetry_Int_Tables_number   1
_cell_volume   669.986
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Bi  Bi0  1  0.057  0.869  0.333  1.0
  Bi  Bi1  1  0.530  0.938  0.660  1.0
  Bi  Bi2  1  0.660  0.658  0.318  1.0
  Bi  Bi3  1  0.125  0.721  0.662  1.0
  Bi  Bi4  1  0.557  0.783  0.001  1.0
  Bi  Bi5  1  0.274  0.462  0.332  1.0
  Bi  Bi6  1  0.726  0.538  0.668  1.0
  Bi  Bi7  1  0.210  0.561  0.001  1.0
  Bi  Bi8  1  0.875  0.279  0.338  1.0
  Bi  Bi9  1  0.340  0.342  0.682  1.0
  Bi  Bi10  1  0.790  0.439  0.999  1.0
  Bi  Bi11  1  0.470  0.062  0.340  1.0
  Bi  Bi12  1  0.943  0.131  0.667  1.0
  Bi  Bi13  1  0.443  0.217  0.999  1.0
  S  S14  1  0.000  0.000  0.000  1.0
  O  O15  1  0.668  0.998  0.498  1.0
  O  O16  1  0.457  0.763  0.158  1.0
  O  O17  1  0.761  0.700  0.158  1.0
  O  O18  1  0.994  0.825  0.494  1.0
  O  O19  1  0.935  0.918  0.816  1.0
  O  O20  1  0.378  0.888  0.767  1.0
  O  O21  1  0.115  0.614  0.231  1.0
  O  O22  1  0.494  0.667  0.493  1.0
  O  O23  1  0.014  0.817  0.992  1.0
  O  O24  1  0.396  0.460  0.159  1.0
  O  O25  1  0.700  0.398  0.157  1.0
  O  O26  1  0.173  0.498  0.505  1.0
  O  O27  1  0.827  0.502  0.495  1.0
  O  O28  1  0.300  0.602  0.843  1.0
  O  O29  1  0.604  0.540  0.841  1.0
  O  O30  1  0.506  0.333  0.507  1.0
  O  O31  1  0.885  0.386  0.769  1.0
  O  O32  1  0.622  0.112  0.233  1.0
  O  O33  1  0.065  0.082  0.184  1.0
  O  O34  1  0.006  0.175  0.506  1.0
  O  O35  1  0.239  0.300  0.842  1.0
  O  O36  1  0.543  0.237  0.842  1.0
  O  O37  1  0.332  0.002  0.502  1.0
  O  O38  1  0.986  0.183  0.008  1.0
[/CIF]
.