The crystal structure described by CoZnF4 is Fluorite-derived structured and crystallizes in the monoclinic C2/c space group. Co(1) is bonded in a body-centered cubic geometry to four equivalent F(1) and four equivalent F(2) atoms. Zn(1) is bonded in a body-centered cubic geometry to four equivalent F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Co(1) and two equivalent Zn(1) atoms to form a mixture of edge and corner-sharing FZn2Co2 tetrahedra. In the second F site, F(2) is bonded to two equivalent Co(1) and two equivalent Zn(1) atoms to form a mixture of edge and corner-sharing FZn2Co2 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnCoF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.187
_cell_length_b   6.187
_cell_length_c   5.099
_cell_angle_alpha   66.576
_cell_angle_beta   66.576
_cell_angle_gamma   48.441
_symmetry_Int_Tables_number   1
_cell_volume   131.436
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.754  0.246  0.750  1.0
  Zn  Zn1  1  0.246  0.754  0.250  1.0
  Co  Co2  1  0.500  0.000  0.500  1.0
  Co  Co3  1  0.000  0.500  0.000  1.0
  F  F4  1  0.605  0.639  0.846  1.0
  F  F5  1  0.869  0.876  0.608  1.0
  F  F6  1  0.395  0.361  0.154  1.0
  F  F7  1  0.876  0.869  0.108  1.0
  F  F8  1  0.131  0.124  0.392  1.0
  F  F9  1  0.639  0.605  0.346  1.0
  F  F10  1  0.124  0.131  0.892  1.0
  F  F11  1  0.361  0.395  0.654  1.0
[/CIF]
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The crystal structure described by CoZnF4 is Fluorite-derived structured and crystallizes in the monoclinic C2/c space group. Co(1) is bonded in a body-centered cubic geometry to four equivalent F(1) and four equivalent F(2) atoms. Zn(1) is bonded in a body-centered cubic geometry to four equivalent F(1) and four equivalent F(2) atoms. There are two inequivalent F sites. In the first F site, F(1) is bonded to two equivalent Co(1) and two equivalent Zn(1) atoms to form a mixture of edge and corner-sharing FZn2Co2 tetrahedra. In the second F site, F(2) is bonded to two equivalent Co(1) and two equivalent Zn(1) atoms to form a mixture of edge and corner-sharing FZn2Co2 tetrahedra. is represented by the Crystallographic Information File (CIF) [CIF]
data_ZnCoF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.187
_cell_length_b   6.187
_cell_length_c   5.099
_cell_angle_alpha   66.576
_cell_angle_beta   66.576
_cell_angle_gamma   48.441
_symmetry_Int_Tables_number   1
_cell_volume   131.436
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.754  0.246  0.750  1.0
  Zn  Zn1  1  0.246  0.754  0.250  1.0
  Co  Co2  1  0.500  0.000  0.500  1.0
  Co  Co3  1  0.000  0.500  0.000  1.0
  F  F4  1  0.605  0.639  0.846  1.0
  F  F5  1  0.869  0.876  0.608  1.0
  F  F6  1  0.395  0.361  0.154  1.0
  F  F7  1  0.876  0.869  0.108  1.0
  F  F8  1  0.131  0.124  0.392  1.0
  F  F9  1  0.639  0.605  0.346  1.0
  F  F10  1  0.124  0.131  0.892  1.0
  F  F11  1  0.361  0.395  0.654  1.0
[/CIF]
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