The material described by K2CoC4N4S4O3 crystallizes in the orthorhombic P2_12_12 space group. K(1) is bonded in a 1-coordinate geometry to one N(1), one S(1), and one S(2) atom. Co(1) is bonded in a trigonal bipyramidal geometry to two equivalent N(1), one O(2), and two equivalent O(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2) and one S(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one K(1), one Co(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(2) and one O(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one K(1) and one C(1) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one K(1) and one C(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one Co(1) and two equivalent N(2) atoms. In the second O site, O(1) is bonded in a single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2CoC4S4N4O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.328
_cell_length_b   7.394
_cell_length_c   11.754
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   984.499
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.196  0.272  0.640  1.0
  K  K1  1  0.804  0.272  0.360  1.0
  K  K2  1  0.696  0.728  0.860  1.0
  K  K3  1  0.304  0.728  0.140  1.0
  Co  Co4  1  0.500  0.177  0.500  1.0
  Co  Co5  1  0.000  0.823  0.000  1.0
  C  C6  1  0.389  0.939  0.662  1.0
  C  C7  1  0.611  0.939  0.338  1.0
  C  C8  1  0.889  0.061  0.838  1.0
  C  C9  1  0.111  0.061  0.162  1.0
  C  C10  1  0.173  0.452  0.882  1.0
  C  C11  1  0.827  0.452  0.118  1.0
  C  C12  1  0.673  0.548  0.618  1.0
  C  C13  1  0.327  0.548  0.382  1.0
  S  S14  1  0.395  0.822  0.775  1.0
  S  S15  1  0.605  0.822  0.225  1.0
  S  S16  1  0.895  0.178  0.725  1.0
  S  S17  1  0.105  0.178  0.275  1.0
  S  S18  1  0.303  0.371  0.898  1.0
  S  S19  1  0.697  0.371  0.102  1.0
  S  S20  1  0.803  0.629  0.602  1.0
  S  S21  1  0.197  0.629  0.398  1.0
  N  N22  1  0.377  0.027  0.576  1.0
  N  N23  1  0.623  0.027  0.424  1.0
  N  N24  1  0.877  0.973  0.924  1.0
  N  N25  1  0.123  0.973  0.076  1.0
  N  N26  1  0.074  0.509  0.862  1.0
  N  N27  1  0.926  0.509  0.138  1.0
  N  N28  1  0.574  0.491  0.638  1.0
  N  N29  1  0.426  0.491  0.362  1.0
  O  O30  1  0.082  0.822  0.875  1.0
  O  O31  1  0.918  0.822  0.125  1.0
  O  O32  1  0.582  0.178  0.625  1.0
  O  O33  1  0.418  0.178  0.375  1.0
  O  O34  1  0.500  0.429  0.500  1.0
  O  O35  1  0.000  0.571  0.000  1.0
[/CIF]
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The material described by K2CoC4N4S4O3 crystallizes in the orthorhombic P2_12_12 space group. K(1) is bonded in a 1-coordinate geometry to one N(1), one S(1), and one S(2) atom. Co(1) is bonded in a trigonal bipyramidal geometry to two equivalent N(1), one O(2), and two equivalent O(1) atoms. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(1) and one S(1) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(2) and one S(2) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one K(1), one Co(1), and one C(1) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(2) and one O(2) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one K(1) and one C(1) atom. In the second S site, S(2) is bonded in a distorted single-bond geometry to one K(1) and one C(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one Co(1) and two equivalent N(2) atoms. In the second O site, O(1) is bonded in a single-bond geometry to one Co(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_K2CoC4S4N4O3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   11.328
_cell_length_b   7.394
_cell_length_c   11.754
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   984.499
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.196  0.272  0.640  1.0
  K  K1  1  0.804  0.272  0.360  1.0
  K  K2  1  0.696  0.728  0.860  1.0
  K  K3  1  0.304  0.728  0.140  1.0
  Co  Co4  1  0.500  0.177  0.500  1.0
  Co  Co5  1  0.000  0.823  0.000  1.0
  C  C6  1  0.389  0.939  0.662  1.0
  C  C7  1  0.611  0.939  0.338  1.0
  C  C8  1  0.889  0.061  0.838  1.0
  C  C9  1  0.111  0.061  0.162  1.0
  C  C10  1  0.173  0.452  0.882  1.0
  C  C11  1  0.827  0.452  0.118  1.0
  C  C12  1  0.673  0.548  0.618  1.0
  C  C13  1  0.327  0.548  0.382  1.0
  S  S14  1  0.395  0.822  0.775  1.0
  S  S15  1  0.605  0.822  0.225  1.0
  S  S16  1  0.895  0.178  0.725  1.0
  S  S17  1  0.105  0.178  0.275  1.0
  S  S18  1  0.303  0.371  0.898  1.0
  S  S19  1  0.697  0.371  0.102  1.0
  S  S20  1  0.803  0.629  0.602  1.0
  S  S21  1  0.197  0.629  0.398  1.0
  N  N22  1  0.377  0.027  0.576  1.0
  N  N23  1  0.623  0.027  0.424  1.0
  N  N24  1  0.877  0.973  0.924  1.0
  N  N25  1  0.123  0.973  0.076  1.0
  N  N26  1  0.074  0.509  0.862  1.0
  N  N27  1  0.926  0.509  0.138  1.0
  N  N28  1  0.574  0.491  0.638  1.0
  N  N29  1  0.426  0.491  0.362  1.0
  O  O30  1  0.082  0.822  0.875  1.0
  O  O31  1  0.918  0.822  0.125  1.0
  O  O32  1  0.582  0.178  0.625  1.0
  O  O33  1  0.418  0.178  0.375  1.0
  O  O34  1  0.500  0.429  0.500  1.0
  O  O35  1  0.000  0.571  0.000  1.0
[/CIF]
.