The material structure described by (CoGa2P3O14)2N2 crystallizes in the monoclinic C2/c space group. The structure consists of four ammonia atoms inside a CoGa2P3O14 framework. In the CoGa2P3O14 framework, Co(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted CoO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent Ga(1)O5 trigonal bipyramids, and  an edgeedge with one P(1)O4 tetrahedra. Ga(1) is bonded to one O(1), one O(3), one O(5), one O(6), and one O(7) atom to form GaO5 trigonal bipyramids that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with three equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. There are two inequivalent P sites. In the first P site, P(1) is bonded to two equivalent O(1) and two equivalent O(3) atoms to form PO4 tetrahedra that share corners with four equivalent Ga(1)O5 trigonal bipyramids and  an edgeedge with one Co(1)O6 octahedra. In the second P site, P(2) is bonded to one O(2), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra and corners with three equivalent Ga(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 44°. There are seven inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one P(2) atom. In the second O site, O(3) is bonded in a 3-coordinate geometry to one Co(1), one Ga(1), and one P(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one Co(1) atom. In the fourth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Ga(1) and one P(2) atom. In the fifth O site, O(6) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(2) atom. In the sixth O site, O(7) is bonded in a bent 150 degrees geometry to one Ga(1) and one P(2) atom. In the seventh O site, O(1) is bonded in a bent 150 degrees geometry to one Ga(1) and one P(1) atom. is represented by the CIF card [CIF]
data_Ga2CoP3NO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.418
_cell_length_b   8.418
_cell_length_c   9.125
_cell_angle_alpha   74.755
_cell_angle_beta   74.755
_cell_angle_gamma   76.571
_symmetry_Int_Tables_number   1
_cell_volume   592.610
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.896  0.747  0.570  1.0
  Ga  Ga1  1  0.253  0.104  0.930  1.0
  Ga  Ga2  1  0.104  0.253  0.430  1.0
  Ga  Ga3  1  0.747  0.896  0.070  1.0
  Co  Co4  1  0.277  0.723  0.750  1.0
  Co  Co5  1  0.723  0.277  0.250  1.0
  P  P6  1  0.992  0.008  0.250  1.0
  P  P7  1  0.008  0.992  0.750  1.0
  P  P8  1  0.578  0.845  0.826  1.0
  P  P9  1  0.155  0.422  0.674  1.0
  P  P10  1  0.422  0.155  0.174  1.0
  P  P11  1  0.845  0.578  0.326  1.0
  N  N12  1  0.637  0.363  0.750  1.0
  N  N13  1  0.363  0.637  0.250  1.0
  O  O14  1  0.020  0.862  0.388  1.0
  O  O15  1  0.138  0.980  0.112  1.0
  O  O16  1  0.980  0.138  0.612  1.0
  O  O17  1  0.862  0.020  0.888  1.0
  O  O18  1  0.472  0.715  0.823  1.0
  O  O19  1  0.285  0.528  0.677  1.0
  O  O20  1  0.528  0.285  0.177  1.0
  O  O21  1  0.715  0.472  0.323  1.0
  O  O22  1  0.031  0.820  0.704  1.0
  O  O23  1  0.180  0.969  0.796  1.0
  O  O24  1  0.969  0.180  0.296  1.0
  O  O25  1  0.820  0.031  0.204  1.0
  O  O26  1  0.204  0.614  0.962  1.0
  O  O27  1  0.386  0.796  0.538  1.0
  O  O28  1  0.796  0.386  0.038  1.0
  O  O29  1  0.614  0.204  0.462  1.0
  O  O30  1  0.702  0.872  0.666  1.0
  O  O31  1  0.128  0.298  0.834  1.0
  O  O32  1  0.298  0.128  0.334  1.0
  O  O33  1  0.872  0.702  0.166  1.0
  O  O34  1  0.769  0.669  0.459  1.0
  O  O35  1  0.331  0.231  0.041  1.0
  O  O36  1  0.231  0.331  0.541  1.0
  O  O37  1  0.669  0.769  0.959  1.0
  O  O38  1  0.985  0.532  0.660  1.0
  O  O39  1  0.468  0.015  0.840  1.0
  O  O40  1  0.015  0.468  0.340  1.0
  O  O41  1  0.532  0.985  0.160  1.0
[/CIF]
.
The material structure described by (CoGa2P3O14)2N2 crystallizes in the monoclinic C2/c space group. The structure consists of four ammonia atoms inside a CoGa2P3O14 framework. In the CoGa2P3O14 framework, Co(1) is bonded to two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms to form distorted CoO6 octahedra that share corners with two equivalent P(2)O4 tetrahedra, corners with two equivalent Ga(1)O5 trigonal bipyramids, and  an edgeedge with one P(1)O4 tetrahedra. Ga(1) is bonded to one O(1), one O(3), one O(5), one O(6), and one O(7) atom to form GaO5 trigonal bipyramids that share  a cornercorner with one Co(1)O6 octahedra, corners with two equivalent P(1)O4 tetrahedra, and corners with three equivalent P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. There are two inequivalent P sites. In the first P site, P(1) is bonded to two equivalent O(1) and two equivalent O(3) atoms to form PO4 tetrahedra that share corners with four equivalent Ga(1)O5 trigonal bipyramids and  an edgeedge with one Co(1)O6 octahedra. In the second P site, P(2) is bonded to one O(2), one O(5), one O(6), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Co(1)O6 octahedra and corners with three equivalent Ga(1)O5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 44°. There are seven inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one P(2) atom. In the second O site, O(3) is bonded in a 3-coordinate geometry to one Co(1), one Ga(1), and one P(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one Co(1) atom. In the fourth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Ga(1) and one P(2) atom. In the fifth O site, O(6) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(2) atom. In the sixth O site, O(7) is bonded in a bent 150 degrees geometry to one Ga(1) and one P(2) atom. In the seventh O site, O(1) is bonded in a bent 150 degrees geometry to one Ga(1) and one P(1) atom. is represented by the CIF card [CIF]
data_Ga2CoP3NO14
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.418
_cell_length_b   8.418
_cell_length_c   9.125
_cell_angle_alpha   74.755
_cell_angle_beta   74.755
_cell_angle_gamma   76.571
_symmetry_Int_Tables_number   1
_cell_volume   592.610
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.896  0.747  0.570  1.0
  Ga  Ga1  1  0.253  0.104  0.930  1.0
  Ga  Ga2  1  0.104  0.253  0.430  1.0
  Ga  Ga3  1  0.747  0.896  0.070  1.0
  Co  Co4  1  0.277  0.723  0.750  1.0
  Co  Co5  1  0.723  0.277  0.250  1.0
  P  P6  1  0.992  0.008  0.250  1.0
  P  P7  1  0.008  0.992  0.750  1.0
  P  P8  1  0.578  0.845  0.826  1.0
  P  P9  1  0.155  0.422  0.674  1.0
  P  P10  1  0.422  0.155  0.174  1.0
  P  P11  1  0.845  0.578  0.326  1.0
  N  N12  1  0.637  0.363  0.750  1.0
  N  N13  1  0.363  0.637  0.250  1.0
  O  O14  1  0.020  0.862  0.388  1.0
  O  O15  1  0.138  0.980  0.112  1.0
  O  O16  1  0.980  0.138  0.612  1.0
  O  O17  1  0.862  0.020  0.888  1.0
  O  O18  1  0.472  0.715  0.823  1.0
  O  O19  1  0.285  0.528  0.677  1.0
  O  O20  1  0.528  0.285  0.177  1.0
  O  O21  1  0.715  0.472  0.323  1.0
  O  O22  1  0.031  0.820  0.704  1.0
  O  O23  1  0.180  0.969  0.796  1.0
  O  O24  1  0.969  0.180  0.296  1.0
  O  O25  1  0.820  0.031  0.204  1.0
  O  O26  1  0.204  0.614  0.962  1.0
  O  O27  1  0.386  0.796  0.538  1.0
  O  O28  1  0.796  0.386  0.038  1.0
  O  O29  1  0.614  0.204  0.462  1.0
  O  O30  1  0.702  0.872  0.666  1.0
  O  O31  1  0.128  0.298  0.834  1.0
  O  O32  1  0.298  0.128  0.334  1.0
  O  O33  1  0.872  0.702  0.166  1.0
  O  O34  1  0.769  0.669  0.459  1.0
  O  O35  1  0.331  0.231  0.041  1.0
  O  O36  1  0.231  0.331  0.541  1.0
  O  O37  1  0.669  0.769  0.959  1.0
  O  O38  1  0.985  0.532  0.660  1.0
  O  O39  1  0.468  0.015  0.840  1.0
  O  O40  1  0.015  0.468  0.340  1.0
  O  O41  1  0.532  0.985  0.160  1.0
[/CIF]
.