The material structure described by Sb2MoO6 crystallizes in the triclinic P-1 space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(10), one O(11), one O(12), one O(3), one O(6), and one O(7) atom to form distorted MoO6 octahedra that share corners with four equivalent Mo(2)O6 octahedra and  a cornercorner with one Sb(4)O5 square pyramid. The corner-sharing octahedral tilt angles range from 29-38°. In the second Mo site, Mo(2) is bonded to one O(1), one O(10), one O(11), one O(4), one O(6), and one O(7) atom to form distorted MoO6 octahedra that share corners with four equivalent Mo(1)O6 octahedra and  a cornercorner with one Sb(4)O5 square pyramid. The corner-sharing octahedral tilt angles range from 29-38°. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(5), one O(8), and one O(9) atom. In the second Sb site, Sb(2) is bonded in a 5-coordinate geometry to one O(12), one O(2), one O(4), one O(8), and one O(9) atom. In the third Sb site, Sb(3) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(5), and one O(9) atom. In the fourth Sb site, Sb(4) is bonded to one O(2), one O(3), one O(4), one O(5), and one O(8) atom to form distorted SbO5 square pyramids that share  a cornercorner with one Mo(1)O6 octahedra and  a cornercorner with one Mo(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-52°. There are twelve inequivalent O sites. In the first O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Sb(2) atom. In the second O site, O(1) is bonded in a 3-coordinate geometry to one Mo(2), one Sb(1), and one Sb(3) atom. In the third O site, O(2) is bonded in a trigonal planar geometry to one Sb(2), one Sb(3), and one Sb(4) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one Mo(1), one Sb(1), and one Sb(4) atom. In the fifth O site, O(4) is bonded in a 2-coordinate geometry to one Mo(2), one Sb(2), and one Sb(4) atom. In the sixth O site, O(5) is bonded in a distorted trigonal planar geometry to one Sb(1), one Sb(3), and one Sb(4) atom. In the seventh O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. In the eighth O site, O(7) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. In the ninth O site, O(8) is bonded in a distorted trigonal planar geometry to one Sb(1), one Sb(2), and one Sb(4) atom. In the tenth O site, O(9) is bonded in a distorted trigonal planar geometry to one Sb(1), one Sb(2), and one Sb(3) atom. In the eleventh O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. In the twelfth O site, O(11) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb2MoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.665
_cell_length_b   7.699
_cell_length_c   10.341
_cell_angle_alpha   110.199
_cell_angle_beta   109.769
_cell_angle_gamma   83.940
_symmetry_Int_Tables_number   1
_cell_volume   538.964
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.443  0.375  0.674  1.0
  Sb  Sb1  1  0.076  0.131  0.337  1.0
  Sb  Sb2  1  0.121  0.577  0.338  1.0
  Sb  Sb3  1  0.632  0.056  0.329  1.0
  Sb  Sb4  1  0.924  0.869  0.663  1.0
  Sb  Sb5  1  0.557  0.625  0.326  1.0
  Sb  Sb6  1  0.879  0.423  0.662  1.0
  Sb  Sb7  1  0.368  0.944  0.671  1.0
  Mo  Mo8  1  0.771  0.276  0.002  1.0
  Mo  Mo9  1  0.274  0.227  0.014  1.0
  Mo  Mo10  1  0.726  0.773  0.986  1.0
  Mo  Mo11  1  0.229  0.724  0.998  1.0
  O  O12  1  0.737  0.581  0.812  1.0
  O  O13  1  0.113  0.809  0.557  1.0
  O  O14  1  0.583  0.224  0.811  1.0
  O  O15  1  0.221  0.100  0.810  1.0
  O  O16  1  0.626  0.294  0.562  1.0
  O  O17  1  0.031  0.745  0.058  1.0
  O  O18  1  0.750  0.969  0.936  1.0
  O  O19  1  0.887  0.191  0.443  1.0
  O  O20  1  0.301  0.126  0.561  1.0
  O  O21  1  0.196  0.388  0.442  1.0
  O  O22  1  0.255  0.478  0.942  1.0
  O  O23  1  0.417  0.776  0.189  1.0
  O  O24  1  0.521  0.243  0.059  1.0
  O  O25  1  0.250  0.031  0.064  1.0
  O  O26  1  0.263  0.419  0.188  1.0
  O  O27  1  0.699  0.874  0.439  1.0
  O  O28  1  0.804  0.612  0.558  1.0
  O  O29  1  0.779  0.900  0.190  1.0
  O  O30  1  0.374  0.706  0.438  1.0
  O  O31  1  0.969  0.255  0.942  1.0
  O  O32  1  0.745  0.522  0.058  1.0
  O  O33  1  0.479  0.757  0.941  1.0
  O  O34  1  0.100  0.737  0.811  1.0
  O  O35  1  0.900  0.263  0.189  1.0
[/CIF]
.
The material structure described by Sb2MoO6 crystallizes in the triclinic P-1 space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(10), one O(11), one O(12), one O(3), one O(6), and one O(7) atom to form distorted MoO6 octahedra that share corners with four equivalent Mo(2)O6 octahedra and  a cornercorner with one Sb(4)O5 square pyramid. The corner-sharing octahedral tilt angles range from 29-38°. In the second Mo site, Mo(2) is bonded to one O(1), one O(10), one O(11), one O(4), one O(6), and one O(7) atom to form distorted MoO6 octahedra that share corners with four equivalent Mo(1)O6 octahedra and  a cornercorner with one Sb(4)O5 square pyramid. The corner-sharing octahedral tilt angles range from 29-38°. There are four inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 5-coordinate geometry to one O(1), one O(3), one O(5), one O(8), and one O(9) atom. In the second Sb site, Sb(2) is bonded in a 5-coordinate geometry to one O(12), one O(2), one O(4), one O(8), and one O(9) atom. In the third Sb site, Sb(3) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(5), and one O(9) atom. In the fourth Sb site, Sb(4) is bonded to one O(2), one O(3), one O(4), one O(5), and one O(8) atom to form distorted SbO5 square pyramids that share  a cornercorner with one Mo(1)O6 octahedra and  a cornercorner with one Mo(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-52°. There are twelve inequivalent O sites. In the first O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Sb(2) atom. In the second O site, O(1) is bonded in a 3-coordinate geometry to one Mo(2), one Sb(1), and one Sb(3) atom. In the third O site, O(2) is bonded in a trigonal planar geometry to one Sb(2), one Sb(3), and one Sb(4) atom. In the fourth O site, O(3) is bonded in a 3-coordinate geometry to one Mo(1), one Sb(1), and one Sb(4) atom. In the fifth O site, O(4) is bonded in a 2-coordinate geometry to one Mo(2), one Sb(2), and one Sb(4) atom. In the sixth O site, O(5) is bonded in a distorted trigonal planar geometry to one Sb(1), one Sb(3), and one Sb(4) atom. In the seventh O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. In the eighth O site, O(7) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. In the ninth O site, O(8) is bonded in a distorted trigonal planar geometry to one Sb(1), one Sb(2), and one Sb(4) atom. In the tenth O site, O(9) is bonded in a distorted trigonal planar geometry to one Sb(1), one Sb(2), and one Sb(3) atom. In the eleventh O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. In the twelfth O site, O(11) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Sb2MoO6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.665
_cell_length_b   7.699
_cell_length_c   10.341
_cell_angle_alpha   110.199
_cell_angle_beta   109.769
_cell_angle_gamma   83.940
_symmetry_Int_Tables_number   1
_cell_volume   538.964
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  1  0.443  0.375  0.674  1.0
  Sb  Sb1  1  0.076  0.131  0.337  1.0
  Sb  Sb2  1  0.121  0.577  0.338  1.0
  Sb  Sb3  1  0.632  0.056  0.329  1.0
  Sb  Sb4  1  0.924  0.869  0.663  1.0
  Sb  Sb5  1  0.557  0.625  0.326  1.0
  Sb  Sb6  1  0.879  0.423  0.662  1.0
  Sb  Sb7  1  0.368  0.944  0.671  1.0
  Mo  Mo8  1  0.771  0.276  0.002  1.0
  Mo  Mo9  1  0.274  0.227  0.014  1.0
  Mo  Mo10  1  0.726  0.773  0.986  1.0
  Mo  Mo11  1  0.229  0.724  0.998  1.0
  O  O12  1  0.737  0.581  0.812  1.0
  O  O13  1  0.113  0.809  0.557  1.0
  O  O14  1  0.583  0.224  0.811  1.0
  O  O15  1  0.221  0.100  0.810  1.0
  O  O16  1  0.626  0.294  0.562  1.0
  O  O17  1  0.031  0.745  0.058  1.0
  O  O18  1  0.750  0.969  0.936  1.0
  O  O19  1  0.887  0.191  0.443  1.0
  O  O20  1  0.301  0.126  0.561  1.0
  O  O21  1  0.196  0.388  0.442  1.0
  O  O22  1  0.255  0.478  0.942  1.0
  O  O23  1  0.417  0.776  0.189  1.0
  O  O24  1  0.521  0.243  0.059  1.0
  O  O25  1  0.250  0.031  0.064  1.0
  O  O26  1  0.263  0.419  0.188  1.0
  O  O27  1  0.699  0.874  0.439  1.0
  O  O28  1  0.804  0.612  0.558  1.0
  O  O29  1  0.779  0.900  0.190  1.0
  O  O30  1  0.374  0.706  0.438  1.0
  O  O31  1  0.969  0.255  0.942  1.0
  O  O32  1  0.745  0.522  0.058  1.0
  O  O33  1  0.479  0.757  0.941  1.0
  O  O34  1  0.100  0.737  0.811  1.0
  O  O35  1  0.900  0.263  0.189  1.0
[/CIF]
.