The structure described by Zn(MoO3)2 crystallizes in the monoclinic Pc space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing MoO6 octahedra. The corner-sharing octahedral tilt angles range from 23-42°. In the second Mo site, Mo(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing MoO6 octahedra. The corner-sharing octahedral tilt angles range from 23-42°. Zn(1) is bonded in a distorted trigonal planar geometry to one O(1), one O(2), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(2), and one Zn(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mo(1), one Mo(2), and one Zn(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Mo(1), one Mo(2), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. is represented by the CIF card [CIF]
data_Zn(MoO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.509
_cell_length_b   5.323
_cell_length_c   9.257
_cell_angle_alpha   55.670
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   224.175
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.714  0.755  0.750  1.0
  Zn  Zn1  1  0.286  0.755  0.250  1.0
  Mo  Mo2  1  0.234  0.493  0.004  1.0
  Mo  Mo3  1  0.748  0.006  0.005  1.0
  Mo  Mo4  1  0.766  0.493  0.504  1.0
  Mo  Mo5  1  0.252  0.006  0.505  1.0
  O  O6  1  0.564  0.760  0.556  1.0
  O  O7  1  0.442  0.378  0.443  1.0
  O  O8  1  0.043  0.247  0.952  1.0
  O  O9  1  0.965  0.654  0.042  1.0
  O  O10  1  0.957  0.247  0.452  1.0
  O  O11  1  0.035  0.654  0.542  1.0
  O  O12  1  0.436  0.760  0.056  1.0
  O  O13  1  0.558  0.378  0.943  1.0
  O  O14  1  0.727  0.116  0.754  1.0
  O  O15  1  0.273  0.116  0.254  1.0
  O  O16  1  0.225  0.830  0.745  1.0
  O  O17  1  0.775  0.830  0.245  1.0
[/CIF]
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The structure described by Zn(MoO3)2 crystallizes in the monoclinic Pc space group. There are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing MoO6 octahedra. The corner-sharing octahedral tilt angles range from 23-42°. In the second Mo site, Mo(2) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing MoO6 octahedra. The corner-sharing octahedral tilt angles range from 23-42°. Zn(1) is bonded in a distorted trigonal planar geometry to one O(1), one O(2), and one O(5) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Mo(1), one Mo(2), and one Zn(1) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Mo(1), one Mo(2), and one Zn(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Mo(1), one Mo(2), and one Zn(1) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mo(1) and one Mo(2) atom. is represented by the CIF card [CIF]
data_Zn(MoO3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.509
_cell_length_b   5.323
_cell_length_c   9.257
_cell_angle_alpha   55.670
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   224.175
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.714  0.755  0.750  1.0
  Zn  Zn1  1  0.286  0.755  0.250  1.0
  Mo  Mo2  1  0.234  0.493  0.004  1.0
  Mo  Mo3  1  0.748  0.006  0.005  1.0
  Mo  Mo4  1  0.766  0.493  0.504  1.0
  Mo  Mo5  1  0.252  0.006  0.505  1.0
  O  O6  1  0.564  0.760  0.556  1.0
  O  O7  1  0.442  0.378  0.443  1.0
  O  O8  1  0.043  0.247  0.952  1.0
  O  O9  1  0.965  0.654  0.042  1.0
  O  O10  1  0.957  0.247  0.452  1.0
  O  O11  1  0.035  0.654  0.542  1.0
  O  O12  1  0.436  0.760  0.056  1.0
  O  O13  1  0.558  0.378  0.943  1.0
  O  O14  1  0.727  0.116  0.754  1.0
  O  O15  1  0.273  0.116  0.254  1.0
  O  O16  1  0.225  0.830  0.745  1.0
  O  O17  1  0.775  0.830  0.245  1.0
[/CIF]
.