The structure described by CdIn2O4 is Spinel-like structured and crystallizes in the orthorhombic Imma space group. Cd(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form CdO6 octahedra that share corners with six equivalent In(1)O4 tetrahedra, edges with two equivalent Cd(1)O6 octahedra, and edges with four equivalent In(2)O6 octahedra. There are two inequivalent In sites. In the first In site, In(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form InO4 tetrahedra that share corners with six equivalent Cd(1)O6 octahedra and corners with six equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-58°. In the second In site, In(2) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form InO6 octahedra that share corners with six equivalent In(1)O4 tetrahedra, edges with two equivalent In(2)O6 octahedra, and edges with four equivalent Cd(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Cd(1), one In(1), and two equivalent In(2) atoms. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to two equivalent Cd(1), one In(1), and one In(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdIn2O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.584
_cell_length_b   6.584
_cell_length_c   6.584
_cell_angle_alpha   120.999
_cell_angle_beta   119.146
_cell_angle_gamma   89.882
_symmetry_Int_Tables_number   1
_cell_volume   201.512
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.000  0.000  1.0
  Cd  Cd1  1  0.500  0.500  0.500  1.0
  In  In2  1  0.884  0.134  0.750  1.0
  In  In3  1  0.116  0.866  0.250  1.0
  In  In4  1  0.500  0.500  0.000  1.0
  In  In5  1  0.000  0.500  0.500  1.0
  O  O6  1  0.248  0.729  0.981  1.0
  O  O7  1  0.248  0.267  0.519  1.0
  O  O8  1  0.730  0.735  0.995  1.0
  O  O9  1  0.240  0.735  0.505  1.0
  O  O10  1  0.760  0.265  0.495  1.0
  O  O11  1  0.270  0.265  0.005  1.0
  O  O12  1  0.752  0.733  0.481  1.0
  O  O13  1  0.752  0.271  0.019  1.0
[/CIF]
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The structure described by CdIn2O4 is Spinel-like structured and crystallizes in the orthorhombic Imma space group. Cd(1) is bonded to two equivalent O(1) and four equivalent O(2) atoms to form CdO6 octahedra that share corners with six equivalent In(1)O4 tetrahedra, edges with two equivalent Cd(1)O6 octahedra, and edges with four equivalent In(2)O6 octahedra. There are two inequivalent In sites. In the first In site, In(1) is bonded to two equivalent O(1) and two equivalent O(2) atoms to form InO4 tetrahedra that share corners with six equivalent Cd(1)O6 octahedra and corners with six equivalent In(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-58°. In the second In site, In(2) is bonded to two equivalent O(2) and four equivalent O(1) atoms to form InO6 octahedra that share corners with six equivalent In(1)O4 tetrahedra, edges with two equivalent In(2)O6 octahedra, and edges with four equivalent Cd(1)O6 octahedra. There are two inequivalent O sites. In the first O site, O(1) is bonded in a rectangular see-saw-like geometry to one Cd(1), one In(1), and two equivalent In(2) atoms. In the second O site, O(2) is bonded in a rectangular see-saw-like geometry to two equivalent Cd(1), one In(1), and one In(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CdIn2O4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.584
_cell_length_b   6.584
_cell_length_c   6.584
_cell_angle_alpha   120.999
_cell_angle_beta   119.146
_cell_angle_gamma   89.882
_symmetry_Int_Tables_number   1
_cell_volume   201.512
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.500  0.000  0.000  1.0
  Cd  Cd1  1  0.500  0.500  0.500  1.0
  In  In2  1  0.884  0.134  0.750  1.0
  In  In3  1  0.116  0.866  0.250  1.0
  In  In4  1  0.500  0.500  0.000  1.0
  In  In5  1  0.000  0.500  0.500  1.0
  O  O6  1  0.248  0.729  0.981  1.0
  O  O7  1  0.248  0.267  0.519  1.0
  O  O8  1  0.730  0.735  0.995  1.0
  O  O9  1  0.240  0.735  0.505  1.0
  O  O10  1  0.760  0.265  0.495  1.0
  O  O11  1  0.270  0.265  0.005  1.0
  O  O12  1  0.752  0.733  0.481  1.0
  O  O13  1  0.752  0.271  0.019  1.0
[/CIF]
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