The compound described by CrSb2H12(C2O)4 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four CrSb2H12(C2O)4 clusters. Cr(1) is bonded in a distorted rectangular see-saw-like geometry to one C(1), one C(3), two equivalent C(2), and two equivalent Sb(1) atoms. There are five inequivalent C sites. In the first C site, C(3) is bonded in a linear geometry to one Cr(1) and one O(3) atom. In the second C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one Sb(1), one H(1), one H(2), and one H(3) atom. In the third C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one Sb(1), one H(4), one H(5), and one H(6) atom. In the fourth C site, C(1) is bonded in a linear geometry to one Cr(1) and one O(1) atom. In the fifth C site, C(2) is bonded in a linear geometry to one Cr(1) and one O(2) atom. Sb(1) is bonded in a 3-coordinate geometry to one Cr(1), one C(4), and one C(5) atom. There are six inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CrSb2H12(C2O)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.800
_cell_length_b   8.800
_cell_length_c   10.339
_cell_angle_alpha   69.417
_cell_angle_beta   69.417
_cell_angle_gamma   81.706
_symmetry_Int_Tables_number   1
_cell_volume   701.557
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.211  0.211  0.191  1.0
  Cr  Cr1  1  0.789  0.789  0.809  1.0
  Sb  Sb2  1  0.898  0.222  0.343  1.0
  Sb  Sb3  1  0.222  0.898  0.343  1.0
  Sb  Sb4  1  0.102  0.778  0.657  1.0
  Sb  Sb5  1  0.778  0.102  0.657  1.0
  H  H6  1  0.847  0.546  0.212  1.0
  H  H7  1  0.546  0.847  0.212  1.0
  H  H8  1  0.153  0.454  0.788  1.0
  H  H9  1  0.454  0.153  0.788  1.0
  H  H10  1  0.654  0.451  0.314  1.0
  H  H11  1  0.451  0.654  0.314  1.0
  H  H12  1  0.346  0.549  0.686  1.0
  H  H13  1  0.549  0.346  0.686  1.0
  H  H14  1  0.769  0.502  0.405  1.0
  H  H15  1  0.502  0.769  0.405  1.0
  H  H16  1  0.231  0.498  0.595  1.0
  H  H17  1  0.498  0.231  0.595  1.0
  H  H18  1  0.745  0.137  0.191  1.0
  H  H19  1  0.137  0.745  0.191  1.0
  H  H20  1  0.255  0.863  0.809  1.0
  H  H21  1  0.863  0.255  0.809  1.0
  H  H22  1  0.753  0.966  0.346  1.0
  H  H23  1  0.966  0.753  0.346  1.0
  H  H24  1  0.247  0.034  0.654  1.0
  H  H25  1  0.034  0.247  0.654  1.0
  H  H26  1  0.604  0.124  0.368  1.0
  H  H27  1  0.124  0.604  0.368  1.0
  H  H28  1  0.396  0.876  0.632  1.0
  H  H29  1  0.876  0.396  0.632  1.0
  C  C30  1  0.152  0.152  0.055  1.0
  C  C31  1  0.848  0.848  0.945  1.0
  C  C32  1  0.195  0.427  0.083  1.0
  C  C33  1  0.427  0.195  0.083  1.0
  C  C34  1  0.805  0.573  0.917  1.0
  C  C35  1  0.573  0.805  0.917  1.0
  C  C36  1  0.273  0.273  0.323  1.0
  C  C37  1  0.727  0.727  0.677  1.0
  C  C38  1  0.777  0.460  0.315  1.0
  C  C39  1  0.460  0.777  0.315  1.0
  C  C40  1  0.223  0.540  0.685  1.0
  C  C41  1  0.540  0.223  0.685  1.0
  C  C42  1  0.728  0.097  0.308  1.0
  C  C43  1  0.097  0.728  0.308  1.0
  C  C44  1  0.272  0.903  0.692  1.0
  C  C45  1  0.903  0.272  0.692  1.0
  O  O46  1  0.123  0.123  0.965  1.0
  O  O47  1  0.877  0.877  0.035  1.0
  O  O48  1  0.185  0.564  0.013  1.0
  O  O49  1  0.564  0.185  0.013  1.0
  O  O50  1  0.815  0.436  0.987  1.0
  O  O51  1  0.436  0.815  0.987  1.0
  O  O52  1  0.316  0.316  0.400  1.0
  O  O53  1  0.684  0.684  0.600  1.0
[/CIF]
.
The compound described by CrSb2H12(C2O)4 is Indium-like structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of four CrSb2H12(C2O)4 clusters. Cr(1) is bonded in a distorted rectangular see-saw-like geometry to one C(1), one C(3), two equivalent C(2), and two equivalent Sb(1) atoms. There are five inequivalent C sites. In the first C site, C(3) is bonded in a linear geometry to one Cr(1) and one O(3) atom. In the second C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one Sb(1), one H(1), one H(2), and one H(3) atom. In the third C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one Sb(1), one H(4), one H(5), and one H(6) atom. In the fourth C site, C(1) is bonded in a linear geometry to one Cr(1) and one O(1) atom. In the fifth C site, C(2) is bonded in a linear geometry to one Cr(1) and one O(2) atom. Sb(1) is bonded in a 3-coordinate geometry to one Cr(1), one C(4), and one C(5) atom. There are six inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(2) is bonded in a single-bond geometry to one C(2) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_CrSb2H12(C2O)4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.800
_cell_length_b   8.800
_cell_length_c   10.339
_cell_angle_alpha   69.417
_cell_angle_beta   69.417
_cell_angle_gamma   81.706
_symmetry_Int_Tables_number   1
_cell_volume   701.557
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.211  0.211  0.191  1.0
  Cr  Cr1  1  0.789  0.789  0.809  1.0
  Sb  Sb2  1  0.898  0.222  0.343  1.0
  Sb  Sb3  1  0.222  0.898  0.343  1.0
  Sb  Sb4  1  0.102  0.778  0.657  1.0
  Sb  Sb5  1  0.778  0.102  0.657  1.0
  H  H6  1  0.847  0.546  0.212  1.0
  H  H7  1  0.546  0.847  0.212  1.0
  H  H8  1  0.153  0.454  0.788  1.0
  H  H9  1  0.454  0.153  0.788  1.0
  H  H10  1  0.654  0.451  0.314  1.0
  H  H11  1  0.451  0.654  0.314  1.0
  H  H12  1  0.346  0.549  0.686  1.0
  H  H13  1  0.549  0.346  0.686  1.0
  H  H14  1  0.769  0.502  0.405  1.0
  H  H15  1  0.502  0.769  0.405  1.0
  H  H16  1  0.231  0.498  0.595  1.0
  H  H17  1  0.498  0.231  0.595  1.0
  H  H18  1  0.745  0.137  0.191  1.0
  H  H19  1  0.137  0.745  0.191  1.0
  H  H20  1  0.255  0.863  0.809  1.0
  H  H21  1  0.863  0.255  0.809  1.0
  H  H22  1  0.753  0.966  0.346  1.0
  H  H23  1  0.966  0.753  0.346  1.0
  H  H24  1  0.247  0.034  0.654  1.0
  H  H25  1  0.034  0.247  0.654  1.0
  H  H26  1  0.604  0.124  0.368  1.0
  H  H27  1  0.124  0.604  0.368  1.0
  H  H28  1  0.396  0.876  0.632  1.0
  H  H29  1  0.876  0.396  0.632  1.0
  C  C30  1  0.152  0.152  0.055  1.0
  C  C31  1  0.848  0.848  0.945  1.0
  C  C32  1  0.195  0.427  0.083  1.0
  C  C33  1  0.427  0.195  0.083  1.0
  C  C34  1  0.805  0.573  0.917  1.0
  C  C35  1  0.573  0.805  0.917  1.0
  C  C36  1  0.273  0.273  0.323  1.0
  C  C37  1  0.727  0.727  0.677  1.0
  C  C38  1  0.777  0.460  0.315  1.0
  C  C39  1  0.460  0.777  0.315  1.0
  C  C40  1  0.223  0.540  0.685  1.0
  C  C41  1  0.540  0.223  0.685  1.0
  C  C42  1  0.728  0.097  0.308  1.0
  C  C43  1  0.097  0.728  0.308  1.0
  C  C44  1  0.272  0.903  0.692  1.0
  C  C45  1  0.903  0.272  0.692  1.0
  O  O46  1  0.123  0.123  0.965  1.0
  O  O47  1  0.877  0.877  0.035  1.0
  O  O48  1  0.185  0.564  0.013  1.0
  O  O49  1  0.564  0.185  0.013  1.0
  O  O50  1  0.815  0.436  0.987  1.0
  O  O51  1  0.436  0.815  0.987  1.0
  O  O52  1  0.316  0.316  0.400  1.0
  O  O53  1  0.684  0.684  0.600  1.0
[/CIF]
.