The compound described by Rb3AuF6 crystallizes in the triclinic P-1 space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a distorted square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. In the second Rb site, Rb(2) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. In the third Rb site, Rb(3) is bonded in a distorted hexagonal planar geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Au(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(3), and one Au(1) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Rb(1), one Rb(2), and one Rb(3) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), and one Au(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb3AuF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.360
_cell_length_b   8.445
_cell_length_c   7.359
_cell_angle_alpha   125.929
_cell_angle_beta   73.908
_cell_angle_gamma   102.056
_symmetry_Int_Tables_number   1
_cell_volume   355.226
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.000  0.000  1.0
  Rb  Rb1  1  0.000  0.500  0.500  1.0
  Rb  Rb2  1  0.000  0.000  0.500  1.0
  Au  Au3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.791  0.074  0.270  1.0
  F  F5  1  0.209  0.926  0.730  1.0
  F  F6  1  0.784  0.797  0.668  1.0
  F  F7  1  0.216  0.203  0.332  1.0
  F  F8  1  0.044  0.767  0.983  1.0
  F  F9  1  0.956  0.233  0.017  1.0
[/CIF]
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The compound described by Rb3AuF6 crystallizes in the triclinic P-1 space group. There are three inequivalent Rb sites. In the first Rb site, Rb(1) is bonded in a distorted square co-planar geometry to two equivalent F(1) and two equivalent F(2) atoms. In the second Rb site, Rb(2) is bonded in a 6-coordinate geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. In the third Rb site, Rb(3) is bonded in a distorted hexagonal planar geometry to two equivalent F(1), two equivalent F(2), and two equivalent F(3) atoms. Au(1) is bonded in a square co-planar geometry to two equivalent F(1) and two equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one Rb(1), one Rb(2), one Rb(3), and one Au(1) atom. In the second F site, F(2) is bonded in a 3-coordinate geometry to one Rb(1), one Rb(2), and one Rb(3) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one Rb(2), one Rb(3), and one Au(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Rb3AuF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.360
_cell_length_b   8.445
_cell_length_c   7.359
_cell_angle_alpha   125.929
_cell_angle_beta   73.908
_cell_angle_gamma   102.056
_symmetry_Int_Tables_number   1
_cell_volume   355.226
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.500  0.000  0.000  1.0
  Rb  Rb1  1  0.000  0.500  0.500  1.0
  Rb  Rb2  1  0.000  0.000  0.500  1.0
  Au  Au3  1  0.000  0.000  0.000  1.0
  F  F4  1  0.791  0.074  0.270  1.0
  F  F5  1  0.209  0.926  0.730  1.0
  F  F6  1  0.784  0.797  0.668  1.0
  F  F7  1  0.216  0.203  0.332  1.0
  F  F8  1  0.044  0.767  0.983  1.0
  F  F9  1  0.956  0.233  0.017  1.0
[/CIF]
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