The compound described by Li2AgF3 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent F(1) and three equivalent F(2) atoms to form a mixture of distorted edge and corner-sharing LiF5 trigonal bipyramids. In the second Li site, Li(2) is bonded to two equivalent F(3) and three equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing LiF5 square pyramids. Ag(1) is bonded in a 5-coordinate geometry to one F(1), one F(2), and three equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a 6-coordinate geometry to two equivalent Li(1), three equivalent Li(2), and one Ag(1) atom. In the second F site, F(2) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Li(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a 2-coordinate geometry to two equivalent Li(2) and three equivalent Ag(1) atoms. is represented by the CIF card [CIF]
data_Li2AgF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.942
_cell_length_b   7.610
_cell_length_c   12.810
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   286.790
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.750  0.352  0.509  1.0
  Li  Li1  1  0.250  0.030  0.584  1.0
  Li  Li2  1  0.750  0.530  0.916  1.0
  Li  Li3  1  0.250  0.852  0.991  1.0
  Li  Li4  1  0.750  0.148  0.009  1.0
  Li  Li5  1  0.250  0.470  0.084  1.0
  Li  Li6  1  0.750  0.970  0.416  1.0
  Li  Li7  1  0.250  0.648  0.491  1.0
  Ag  Ag8  1  0.750  0.836  0.745  1.0
  Ag  Ag9  1  0.250  0.336  0.755  1.0
  Ag  Ag10  1  0.750  0.664  0.245  1.0
  Ag  Ag11  1  0.250  0.164  0.255  1.0
  F  F12  1  0.750  0.844  0.546  1.0
  F  F13  1  0.250  0.454  0.588  1.0
  F  F14  1  0.750  0.126  0.664  1.0
  F  F15  1  0.250  0.626  0.836  1.0
  F  F16  1  0.750  0.954  0.912  1.0
  F  F17  1  0.250  0.344  0.954  1.0
  F  F18  1  0.750  0.656  0.046  1.0
  F  F19  1  0.250  0.046  0.088  1.0
  F  F20  1  0.750  0.374  0.164  1.0
  F  F21  1  0.250  0.874  0.336  1.0
  F  F22  1  0.750  0.546  0.412  1.0
  F  F23  1  0.250  0.156  0.454  1.0
[/CIF]
.
The compound described by Li2AgF3 crystallizes in the orthorhombic Pnma space group. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded to two equivalent F(1) and three equivalent F(2) atoms to form a mixture of distorted edge and corner-sharing LiF5 trigonal bipyramids. In the second Li site, Li(2) is bonded to two equivalent F(3) and three equivalent F(1) atoms to form a mixture of distorted edge and corner-sharing LiF5 square pyramids. Ag(1) is bonded in a 5-coordinate geometry to one F(1), one F(2), and three equivalent F(3) atoms. There are three inequivalent F sites. In the first F site, F(1) is bonded in a 6-coordinate geometry to two equivalent Li(1), three equivalent Li(2), and one Ag(1) atom. In the second F site, F(2) is bonded in a distorted rectangular see-saw-like geometry to three equivalent Li(1) and one Ag(1) atom. In the third F site, F(3) is bonded in a 2-coordinate geometry to two equivalent Li(2) and three equivalent Ag(1) atoms. is represented by the CIF card [CIF]
data_Li2AgF3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.942
_cell_length_b   7.610
_cell_length_c   12.810
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   286.790
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.750  0.352  0.509  1.0
  Li  Li1  1  0.250  0.030  0.584  1.0
  Li  Li2  1  0.750  0.530  0.916  1.0
  Li  Li3  1  0.250  0.852  0.991  1.0
  Li  Li4  1  0.750  0.148  0.009  1.0
  Li  Li5  1  0.250  0.470  0.084  1.0
  Li  Li6  1  0.750  0.970  0.416  1.0
  Li  Li7  1  0.250  0.648  0.491  1.0
  Ag  Ag8  1  0.750  0.836  0.745  1.0
  Ag  Ag9  1  0.250  0.336  0.755  1.0
  Ag  Ag10  1  0.750  0.664  0.245  1.0
  Ag  Ag11  1  0.250  0.164  0.255  1.0
  F  F12  1  0.750  0.844  0.546  1.0
  F  F13  1  0.250  0.454  0.588  1.0
  F  F14  1  0.750  0.126  0.664  1.0
  F  F15  1  0.250  0.626  0.836  1.0
  F  F16  1  0.750  0.954  0.912  1.0
  F  F17  1  0.250  0.344  0.954  1.0
  F  F18  1  0.750  0.656  0.046  1.0
  F  F19  1  0.250  0.046  0.088  1.0
  F  F20  1  0.750  0.374  0.164  1.0
  F  F21  1  0.250  0.874  0.336  1.0
  F  F22  1  0.750  0.546  0.412  1.0
  F  F23  1  0.250  0.156  0.454  1.0
[/CIF]
.