The crystal structure described by XeNO3F is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeNO3F clusters. Xe(1) is bonded in a linear geometry to one O(3) and one F(1) atom. N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Xe(1) and one N(1) atom. F(1) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the CIF file [CIF]
data_XeNO3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.093
_cell_length_b   4.791
_cell_length_c   9.659
_cell_angle_alpha   89.202
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   420.751
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Xe  Xe0  1  0.542  0.840  0.779  1.0
  Xe  Xe1  1  0.042  0.160  0.721  1.0
  Xe  Xe2  1  0.458  0.160  0.221  1.0
  Xe  Xe3  1  0.958  0.840  0.279  1.0
  N  N4  1  0.682  0.519  0.540  1.0
  N  N5  1  0.182  0.481  0.960  1.0
  N  N6  1  0.318  0.481  0.460  1.0
  N  N7  1  0.818  0.519  0.040  1.0
  O  O8  1  0.758  0.330  0.492  1.0
  O  O9  1  0.258  0.670  0.008  1.0
  O  O10  1  0.242  0.670  0.508  1.0
  O  O11  1  0.742  0.330  0.992  1.0
  O  O12  1  0.626  0.716  0.478  1.0
  O  O13  1  0.126  0.284  0.022  1.0
  O  O14  1  0.374  0.284  0.522  1.0
  O  O15  1  0.874  0.716  0.978  1.0
  O  O16  1  0.662  0.488  0.682  1.0
  O  O17  1  0.162  0.512  0.818  1.0
  O  O18  1  0.338  0.512  0.318  1.0
  O  O19  1  0.838  0.488  0.182  1.0
  F  F20  1  0.432  0.174  0.874  1.0
  F  F21  1  0.932  0.826  0.626  1.0
  F  F22  1  0.568  0.826  0.126  1.0
  F  F23  1  0.068  0.174  0.374  1.0
[/CIF]
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The crystal structure described by XeNO3F is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four XeNO3F clusters. Xe(1) is bonded in a linear geometry to one O(3) and one F(1) atom. N(1) is bonded in a trigonal planar geometry to one O(1), one O(2), and one O(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one N(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one N(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Xe(1) and one N(1) atom. F(1) is bonded in a single-bond geometry to one Xe(1) atom. is represented by the CIF file [CIF]
data_XeNO3F
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.093
_cell_length_b   4.791
_cell_length_c   9.659
_cell_angle_alpha   89.202
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   420.751
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Xe  Xe0  1  0.542  0.840  0.779  1.0
  Xe  Xe1  1  0.042  0.160  0.721  1.0
  Xe  Xe2  1  0.458  0.160  0.221  1.0
  Xe  Xe3  1  0.958  0.840  0.279  1.0
  N  N4  1  0.682  0.519  0.540  1.0
  N  N5  1  0.182  0.481  0.960  1.0
  N  N6  1  0.318  0.481  0.460  1.0
  N  N7  1  0.818  0.519  0.040  1.0
  O  O8  1  0.758  0.330  0.492  1.0
  O  O9  1  0.258  0.670  0.008  1.0
  O  O10  1  0.242  0.670  0.508  1.0
  O  O11  1  0.742  0.330  0.992  1.0
  O  O12  1  0.626  0.716  0.478  1.0
  O  O13  1  0.126  0.284  0.022  1.0
  O  O14  1  0.374  0.284  0.522  1.0
  O  O15  1  0.874  0.716  0.978  1.0
  O  O16  1  0.662  0.488  0.682  1.0
  O  O17  1  0.162  0.512  0.818  1.0
  O  O18  1  0.338  0.512  0.318  1.0
  O  O19  1  0.838  0.488  0.182  1.0
  F  F20  1  0.432  0.174  0.874  1.0
  F  F21  1  0.932  0.826  0.626  1.0
  F  F22  1  0.568  0.826  0.126  1.0
  F  F23  1  0.068  0.174  0.374  1.0
[/CIF]
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