The material described by HgC6(NS2)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four HgC6(NS2)2 clusters. Hg(1) is bonded in a linear geometry to two equivalent S(1) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one S(2) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(1) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one N(1) atom. N(1) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one C(3) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a single-bond geometry to one C(1) atom. In the second S site, S(1) is bonded in an L-shaped geometry to one Hg(1) and one C(1) atom. is represented by the CIF file [CIF]
data_HgC6(S2N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.943
_cell_length_b   9.943
_cell_length_c   10.256
_cell_angle_alpha   67.928
_cell_angle_beta   67.928
_cell_angle_gamma   45.654
_symmetry_Int_Tables_number   1
_cell_volume   662.117
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.000  0.000  0.500  1.0
  Hg  Hg1  1  0.000  0.000  0.000  1.0
  C  C2  1  0.091  0.694  0.391  1.0
  C  C3  1  0.306  0.909  0.109  1.0
  C  C4  1  0.909  0.306  0.609  1.0
  C  C5  1  0.694  0.091  0.891  1.0
  C  C6  1  0.347  0.341  0.332  1.0
  C  C7  1  0.659  0.653  0.168  1.0
  C  C8  1  0.653  0.659  0.668  1.0
  C  C9  1  0.341  0.347  0.832  1.0
  C  C10  1  0.164  0.435  0.288  1.0
  C  C11  1  0.565  0.836  0.212  1.0
  C  C12  1  0.836  0.565  0.712  1.0
  C  C13  1  0.435  0.164  0.788  1.0
  S  S14  1  0.235  0.664  0.471  1.0
  S  S15  1  0.336  0.765  0.029  1.0
  S  S16  1  0.765  0.336  0.529  1.0
  S  S17  1  0.664  0.235  0.971  1.0
  S  S18  1  0.872  0.884  0.359  1.0
  S  S19  1  0.116  0.128  0.141  1.0
  S  S20  1  0.128  0.116  0.641  1.0
  S  S21  1  0.884  0.872  0.859  1.0
  N  N22  1  0.183  0.521  0.346  1.0
  N  N23  1  0.479  0.817  0.154  1.0
  N  N24  1  0.817  0.479  0.654  1.0
  N  N25  1  0.521  0.183  0.846  1.0
[/CIF]
.
The material described by HgC6(NS2)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four HgC6(NS2)2 clusters. Hg(1) is bonded in a linear geometry to two equivalent S(1) atoms. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(1), and one S(2) atom. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(1) atom. In the third C site, C(3) is bonded in a distorted single-bond geometry to one N(1) atom. N(1) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one C(3) atom. There are two inequivalent S sites. In the first S site, S(2) is bonded in a single-bond geometry to one C(1) atom. In the second S site, S(1) is bonded in an L-shaped geometry to one Hg(1) and one C(1) atom. is represented by the CIF file [CIF]
data_HgC6(S2N)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.943
_cell_length_b   9.943
_cell_length_c   10.256
_cell_angle_alpha   67.928
_cell_angle_beta   67.928
_cell_angle_gamma   45.654
_symmetry_Int_Tables_number   1
_cell_volume   662.117
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Hg  Hg0  1  0.000  0.000  0.500  1.0
  Hg  Hg1  1  0.000  0.000  0.000  1.0
  C  C2  1  0.091  0.694  0.391  1.0
  C  C3  1  0.306  0.909  0.109  1.0
  C  C4  1  0.909  0.306  0.609  1.0
  C  C5  1  0.694  0.091  0.891  1.0
  C  C6  1  0.347  0.341  0.332  1.0
  C  C7  1  0.659  0.653  0.168  1.0
  C  C8  1  0.653  0.659  0.668  1.0
  C  C9  1  0.341  0.347  0.832  1.0
  C  C10  1  0.164  0.435  0.288  1.0
  C  C11  1  0.565  0.836  0.212  1.0
  C  C12  1  0.836  0.565  0.712  1.0
  C  C13  1  0.435  0.164  0.788  1.0
  S  S14  1  0.235  0.664  0.471  1.0
  S  S15  1  0.336  0.765  0.029  1.0
  S  S16  1  0.765  0.336  0.529  1.0
  S  S17  1  0.664  0.235  0.971  1.0
  S  S18  1  0.872  0.884  0.359  1.0
  S  S19  1  0.116  0.128  0.141  1.0
  S  S20  1  0.128  0.116  0.641  1.0
  S  S21  1  0.884  0.872  0.859  1.0
  N  N22  1  0.183  0.521  0.346  1.0
  N  N23  1  0.479  0.817  0.154  1.0
  N  N24  1  0.817  0.479  0.654  1.0
  N  N25  1  0.521  0.183  0.846  1.0
[/CIF]
.