The material structure described by Li6Mn15O32 is beta indium sulfide-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(27), and one O(4) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(13)O6 octahedra,  a cornercorner with one Mn(14)O6 octahedra,  a cornercorner with one Mn(15)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-63°. In the second Li site, Li(2) is bonded to one O(11), one O(6), one O(8), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with three equivalent Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-65°. In the third Li site, Li(3) is bonded to one O(13), one O(14), one O(3), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, corners with two equivalent Mn(8)O6 octahedra, corners with two equivalent Mn(9)O6 octahedra, and corners with three equivalent Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-65°. In the fourth Li site, Li(4) is bonded to one O(10), one O(12), one O(17), and one O(18) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, corners with two equivalent Mn(8)O6 octahedra, corners with two equivalent Mn(9)O6 octahedra, and corners with three equivalent Mn(11)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-64°. In the fifth Li site, Li(5) is bonded to one O(22), one O(24), one O(25), and one O(26) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra, corners with two equivalent Mn(13)O6 octahedra, corners with two equivalent Mn(14)O6 octahedra, corners with two equivalent Mn(15)O6 octahedra, and corners with three equivalent Mn(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-65°. In the sixth Li site, Li(6) is bonded to one O(30), one O(31), one O(32), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Mn(13)O6 octahedra, corners with two equivalent Mn(14)O6 octahedra, corners with two equivalent Mn(15)O6 octahedra, and corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-66°. There are fifteen inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(30), one O(31), one O(32), and one O(4) atom to form MnO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(6)O4 tetrahedra,  an edgeedge with one Mn(13)O6 octahedra,  an edgeedge with one Mn(14)O6 octahedra,  an edgeedge with one Mn(15)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. In the second Mn site, Mn(2) is bonded to one O(1), one O(11), one O(4), one O(5), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. In the third Mn site, Mn(3) is bonded to one O(2), one O(4), one O(5), one O(7), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. In the fourth Mn site, Mn(4) is bonded to one O(10), one O(12), one O(13), one O(14), one O(15), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra, and edges with two equivalent Mn(9)O6 octahedra. In the fifth Mn site, Mn(5) is bonded to one O(11), one O(13), one O(14), one O(3), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with three equivalent Li(2)O4 tetrahedra, corners with three equivalent Li(3)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. In the sixth Mn site, Mn(6) is bonded to one O(16), one O(17), one O(19), one O(23), one O(26), and one O(29) atom to form MnO6 octahedra that share  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(11)O6 octahedra, edges with two equivalent Mn(12)O6 octahedra, and edges with two equivalent Mn(7)O6 octahedra. In the seventh Mn site, Mn(7) is bonded to one O(16), one O(17), one O(20), one O(21), one O(26), and one O(29) atom to form MnO6 octahedra that share  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(11)O6 octahedra, edges with two equivalent Mn(12)O6 octahedra, and edges with two equivalent Mn(6)O6 octahedra. In the eighth Mn site, Mn(8) is bonded to one O(12), one O(13), one O(15), one O(18), one O(3), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and edges with two equivalent Mn(9)O6 octahedra. In the ninth Mn site, Mn(9) is bonded to one O(10), one O(14), one O(15), one O(18), one O(3), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. In the tenth Mn site, Mn(10) is bonded to one O(19), one O(20), one O(22), one O(24), one O(25), and one O(29) atom to form MnO6 octahedra that share corners with three equivalent Li(5)O4 tetrahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(13)O6 octahedra,  an edgeedge with one Mn(14)O6 octahedra,  an edgeedge with one Mn(15)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. In the eleventh Mn site, Mn(11) is bonded to one O(10), one O(12), one O(16), one O(18), one O(21), and one O(23) atom to form MnO6 octahedra that share corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. In the twelfth Mn site, Mn(12) is bonded to one O(17), one O(19), one O(20), one O(21), one O(23), and one O(26) atom to form MnO6 octahedra that share  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(11)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, and edges with two equivalent Mn(7)O6 octahedra. In the thirteenth Mn site, Mn(13) is bonded to one O(24), one O(25), one O(27), one O(28), one O(30), and one O(32) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(5)O4 tetrahedra, corners with two equivalent Li(6)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra, edges with two equivalent Mn(14)O6 octahedra, and edges with two equivalent Mn(15)O6 octahedra. In the fourteenth Mn site, Mn(14) is bonded to one O(22), one O(25), one O(27), one O(28), one O(30), and one O(31) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(5)O4 tetrahedra, corners with two equivalent Li(6)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra, edges with two equivalent Mn(13)O6 octahedra, and edges with two equivalent Mn(15)O6 octahedra. In the fifteenth Mn site, Mn(15) is bonded to one O(22), one O(24), one O(27), one O(28), one O(31), and one O(32) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(5)O4 tetrahedra, corners with two equivalent Li(6)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra, edges with two equivalent Mn(13)O6 octahedra, and edges with two equivalent Mn(14)O6 octahedra. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one Mn(1), and one Mn(2) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Li(1), one Mn(1), and one Mn(3) atom. In the third O site, O(3) is bonded to one Li(3), one Mn(5), one Mn(8), and one Mn(9) atom to form a mixture of distorted corner and edge-sharing OLiMn3 trigonal pyramids. In the fourth O site, O(4) is bonded to one Li(1), one Mn(1), one Mn(2), and one Mn(3) atom to form distorted corner-sharing OLiMn3 trigonal pyramids. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Li(3), one Mn(2), and one Mn(3) atom. In the sixth O site, O(6) is bonded to one Li(2), one Mn(4), one Mn(8), and one Mn(9) atom to form a mixture of distorted corner and edge-sharing OLiMn3 trigonal pyramids. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Li(6), one Mn(2), and one Mn(3) atom. In the eighth O site, O(8) is bonded to one Li(2), one Mn(2), one Mn(3), and one Mn(5) atom to form distorted corner-sharing OLiMn3 trigonal pyramids. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Li(2), one Mn(3), and one Mn(5) atom. In the tenth O site, O(10) is bonded to one Li(4), one Mn(11), one Mn(4), and one Mn(9) atom to form a mixture of distorted corner and edge-sharing OLiMn3 tetrahedra. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Li(2), one Mn(2), and one Mn(5) atom. In the twelfth O site, O(12) is bonded to one Li(4), one Mn(11), one Mn(4), and one Mn(8) atom to form a mixture of distorted corner and edge-sharing OLiMn3 trigonal pyramids. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(4), one Mn(5), and one Mn(8) atom. In the fourteenth O site, O(14) is bonded to one Li(3), one Mn(4), one Mn(5), and one Mn(9) atom to form a mixture of distorted corner and edge-sharing OLiMn3 tetrahedra. In the fifteenth O site, O(15) is bonded in a distorted T-shaped geometry to one Mn(4), one Mn(8), and one Mn(9) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal non-coplanar geometry to one Mn(11), one Mn(6), and one Mn(7) atom. In the seventeenth O site, O(17) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Mn(12), one Mn(6), and one Mn(7) atom. In the eighteenth O site, O(18) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Mn(11), one Mn(8), and one Mn(9) atom. In the nineteenth O site, O(19) is bonded in a distorted T-shaped geometry to one Mn(10), one Mn(12), and one Mn(6) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal non-coplanar geometry to one Mn(10), one Mn(12), and one Mn(7) atom. In the twenty-first O site, O(21) is bonded in a distorted T-shaped geometry to one Mn(11), one Mn(12), and one Mn(7) atom. In the twenty-second O site, O(22) is bonded to one Li(5), one Mn(10), one Mn(14), and one Mn(15) atom to form a mixture of distorted corner and edge-sharing OLiMn3 tetrahedra. In the twenty-third O site, O(23) is bonded in a distorted T-shaped geometry to one Mn(11), one Mn(12), and one Mn(6) atom. In the twenty-fourth O site, O(24) is bonded to one Li(5), one Mn(10), one Mn(13), and one Mn(15) atom to form a mixture of distorted corner and edge-sharing OLiMn3 trigonal pyramids. In the twenty-fifth O site, O(25) is bonded to one Li(5), one Mn(10), one Mn(13), and one Mn(14) atom to form a mixture of distorted corner and edge-sharing OLiMn3 trigonal pyramids. In the twenty-sixth O site, O(26) is bonded in a distorted rectangular see-saw-like geometry to one Li(5), one Mn(12), one Mn(6), and one Mn(7) atom. In the twenty-seventh O site, O(27) is bonded to one Li(1), one Mn(13), one Mn(14), and one Mn(15) atom to form a mixture of distorted corner and edge-sharing OLiMn3 tetrahedra. In the twenty-eighth O site, O(28) is bonded in a distorted T-shaped geometry to one Mn(13), one Mn(14), and one Mn(15) atom. In the twenty-ninth O site, O(29) is bonded in a distorted trigonal non-coplanar geometry to one Mn(10), one Mn(6), and one Mn(7) atom. In the thirtieth O site, O(30) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Mn(1), one Mn(13), and one Mn(14) atom. In the thirty-first O site, O(31) is bonded to one Li(6), one Mn(1), one Mn(14), and one Mn(15) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the thirty-second O site, O(32) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Mn(1), one Mn(13), and one Mn(15) atom. is represented by the CIF card [CIF]
data_Li6Mn15O32
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.980
_cell_length_b   5.892
_cell_length_c   19.407
_cell_angle_alpha   97.906
_cell_angle_beta   97.944
_cell_angle_gamma   59.197
_symmetry_Int_Tables_number   1
_cell_volume   579.921
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.849  0.829  0.033  1.0
  Li  Li1  1  0.902  0.917  0.217  1.0
  Li  Li2  1  0.588  0.591  0.276  1.0
  Li  Li3  1  0.660  0.652  0.469  1.0
  Li  Li4  1  0.090  0.098  0.781  1.0
  Li  Li5  1  0.162  0.156  0.975  1.0
  Mn  Mn6  1  0.502  0.506  0.004  1.0
  Mn  Mn7  1  0.874  0.374  0.125  1.0
  Mn  Mn8  1  0.375  0.373  0.125  1.0
  Mn  Mn9  1  0.126  0.621  0.375  1.0
  Mn  Mn10  1  0.248  0.242  0.246  1.0
  Mn  Mn11  1  0.375  0.873  0.625  1.0
  Mn  Mn12  1  0.874  0.874  0.625  1.0
  Mn  Mn13  1  0.126  0.125  0.374  1.0
  Mn  Mn14  1  0.623  0.126  0.376  1.0
  Mn  Mn15  1  0.745  0.747  0.749  1.0
  Mn  Mn16  1  0.004  0.001  0.501  1.0
  Mn  Mn17  1  0.874  0.373  0.625  1.0
  Mn  Mn18  1  0.624  0.624  0.876  1.0
  Mn  Mn19  1  0.127  0.623  0.875  1.0
  Mn  Mn20  1  0.624  0.127  0.875  1.0
  O  O21  1  0.697  0.632  0.058  1.0
  O  O22  1  0.227  0.635  0.058  1.0
  O  O23  1  0.407  0.971  0.314  1.0
  O  O24  1  0.676  0.216  0.067  1.0
  O  O25  1  0.572  0.525  0.176  1.0
  O  O26  1  0.960  0.933  0.322  1.0
  O  O27  1  0.178  0.223  0.075  1.0
  O  O28  1  0.074  0.531  0.184  1.0
  O  O29  1  0.523  0.111  0.193  1.0
  O  O30  1  0.833  0.834  0.435  1.0
  O  O31  1  0.054  0.114  0.192  1.0
  O  O32  1  0.276  0.824  0.434  1.0
  O  O33  1  0.972  0.429  0.318  1.0
  O  O34  1  0.416  0.421  0.318  1.0
  O  O35  1  0.288  0.312  0.427  1.0
  O  O36  1  0.172  0.731  0.567  1.0
  O  O37  1  0.674  0.675  0.570  1.0
  O  O38  1  0.843  0.276  0.435  1.0
  O  O39  1  0.584  0.580  0.685  1.0
  O  O40  1  0.012  0.577  0.683  1.0
  O  O41  1  0.736  0.171  0.566  1.0
  O  O42  1  0.915  0.917  0.814  1.0
  O  O43  1  0.165  0.167  0.565  1.0
  O  O44  1  0.474  0.924  0.816  1.0
  O  O45  1  0.898  0.472  0.813  1.0
  O  O46  1  0.076  0.071  0.680  1.0
  O  O47  1  0.798  0.811  0.927  1.0
  O  O48  1  0.453  0.442  0.824  1.0
  O  O49  1  0.576  0.016  0.682  1.0
  O  O50  1  0.350  0.779  0.938  1.0
  O  O51  1  0.335  0.325  0.932  1.0
  O  O52  1  0.777  0.320  0.931  1.0
[/CIF]
.
The material structure described by Li6Mn15O32 is beta indium sulfide-derived structured and crystallizes in the triclinic P1 space group. There are six inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(2), one O(27), and one O(4) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(13)O6 octahedra,  a cornercorner with one Mn(14)O6 octahedra,  a cornercorner with one Mn(15)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-63°. In the second Li site, Li(2) is bonded to one O(11), one O(6), one O(8), and one O(9) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(4)O6 octahedra,  a cornercorner with one Mn(8)O6 octahedra,  a cornercorner with one Mn(9)O6 octahedra, corners with two equivalent Mn(2)O6 octahedra, corners with two equivalent Mn(3)O6 octahedra, and corners with three equivalent Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 49-65°. In the third Li site, Li(3) is bonded to one O(13), one O(14), one O(3), and one O(5) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, corners with two equivalent Mn(8)O6 octahedra, corners with two equivalent Mn(9)O6 octahedra, and corners with three equivalent Mn(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-65°. In the fourth Li site, Li(4) is bonded to one O(10), one O(12), one O(17), and one O(18) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra, corners with two equivalent Mn(4)O6 octahedra, corners with two equivalent Mn(8)O6 octahedra, corners with two equivalent Mn(9)O6 octahedra, and corners with three equivalent Mn(11)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-64°. In the fifth Li site, Li(5) is bonded to one O(22), one O(24), one O(25), and one O(26) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(12)O6 octahedra,  a cornercorner with one Mn(6)O6 octahedra,  a cornercorner with one Mn(7)O6 octahedra, corners with two equivalent Mn(13)O6 octahedra, corners with two equivalent Mn(14)O6 octahedra, corners with two equivalent Mn(15)O6 octahedra, and corners with three equivalent Mn(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 55-65°. In the sixth Li site, Li(6) is bonded to one O(30), one O(31), one O(32), and one O(7) atom to form LiO4 tetrahedra that share  a cornercorner with one Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O6 octahedra, corners with two equivalent Mn(13)O6 octahedra, corners with two equivalent Mn(14)O6 octahedra, corners with two equivalent Mn(15)O6 octahedra, and corners with three equivalent Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 54-66°. There are fifteen inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(30), one O(31), one O(32), and one O(4) atom to form MnO6 octahedra that share corners with three equivalent Li(1)O4 tetrahedra, corners with three equivalent Li(6)O4 tetrahedra,  an edgeedge with one Mn(13)O6 octahedra,  an edgeedge with one Mn(14)O6 octahedra,  an edgeedge with one Mn(15)O6 octahedra,  an edgeedge with one Mn(2)O6 octahedra, and  an edgeedge with one Mn(3)O6 octahedra. In the second Mn site, Mn(2) is bonded to one O(1), one O(11), one O(4), one O(5), one O(7), and one O(8) atom to form MnO6 octahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, and edges with two equivalent Mn(3)O6 octahedra. In the third Mn site, Mn(3) is bonded to one O(2), one O(4), one O(5), one O(7), one O(8), and one O(9) atom to form MnO6 octahedra that share  a cornercorner with one Li(3)O4 tetrahedra,  a cornercorner with one Li(6)O4 tetrahedra, corners with two equivalent Li(1)O4 tetrahedra, corners with two equivalent Li(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, and edges with two equivalent Mn(2)O6 octahedra. In the fourth Mn site, Mn(4) is bonded to one O(10), one O(12), one O(13), one O(14), one O(15), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Mn(8)O6 octahedra, and edges with two equivalent Mn(9)O6 octahedra. In the fifth Mn site, Mn(5) is bonded to one O(11), one O(13), one O(14), one O(3), one O(8), and one O(9) atom to form MnO6 octahedra that share corners with three equivalent Li(2)O4 tetrahedra, corners with three equivalent Li(3)O4 tetrahedra,  an edgeedge with one Mn(2)O6 octahedra,  an edgeedge with one Mn(3)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. In the sixth Mn site, Mn(6) is bonded to one O(16), one O(17), one O(19), one O(23), one O(26), and one O(29) atom to form MnO6 octahedra that share  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(11)O6 octahedra, edges with two equivalent Mn(12)O6 octahedra, and edges with two equivalent Mn(7)O6 octahedra. In the seventh Mn site, Mn(7) is bonded to one O(16), one O(17), one O(20), one O(21), one O(26), and one O(29) atom to form MnO6 octahedra that share  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(11)O6 octahedra, edges with two equivalent Mn(12)O6 octahedra, and edges with two equivalent Mn(6)O6 octahedra. In the eighth Mn site, Mn(8) is bonded to one O(12), one O(13), one O(15), one O(18), one O(3), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and edges with two equivalent Mn(9)O6 octahedra. In the ninth Mn site, Mn(9) is bonded to one O(10), one O(14), one O(15), one O(18), one O(3), and one O(6) atom to form MnO6 octahedra that share  a cornercorner with one Li(2)O4 tetrahedra, corners with two equivalent Li(3)O4 tetrahedra, corners with two equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(11)O6 octahedra,  an edgeedge with one Mn(5)O6 octahedra, edges with two equivalent Mn(4)O6 octahedra, and edges with two equivalent Mn(8)O6 octahedra. In the tenth Mn site, Mn(10) is bonded to one O(19), one O(20), one O(22), one O(24), one O(25), and one O(29) atom to form MnO6 octahedra that share corners with three equivalent Li(5)O4 tetrahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(13)O6 octahedra,  an edgeedge with one Mn(14)O6 octahedra,  an edgeedge with one Mn(15)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra, and  an edgeedge with one Mn(7)O6 octahedra. In the eleventh Mn site, Mn(11) is bonded to one O(10), one O(12), one O(16), one O(18), one O(21), and one O(23) atom to form MnO6 octahedra that share corners with three equivalent Li(4)O4 tetrahedra,  an edgeedge with one Mn(12)O6 octahedra,  an edgeedge with one Mn(4)O6 octahedra,  an edgeedge with one Mn(6)O6 octahedra,  an edgeedge with one Mn(7)O6 octahedra,  an edgeedge with one Mn(8)O6 octahedra, and  an edgeedge with one Mn(9)O6 octahedra. In the twelfth Mn site, Mn(12) is bonded to one O(17), one O(19), one O(20), one O(21), one O(23), and one O(26) atom to form MnO6 octahedra that share  a cornercorner with one Li(4)O4 tetrahedra,  a cornercorner with one Li(5)O4 tetrahedra,  an edgeedge with one Mn(10)O6 octahedra,  an edgeedge with one Mn(11)O6 octahedra, edges with two equivalent Mn(6)O6 octahedra, and edges with two equivalent Mn(7)O6 octahedra. In the thirteenth Mn site, Mn(13) is bonded to one O(24), one O(25), one O(27), one O(28), one O(30), and one O(32) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(5)O4 tetrahedra, corners with two equivalent Li(6)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra, edges with two equivalent Mn(14)O6 octahedra, and edges with two equivalent Mn(15)O6 octahedra. In the fourteenth Mn site, Mn(14) is bonded to one O(22), one O(25), one O(27), one O(28), one O(30), and one O(31) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(5)O4 tetrahedra, corners with two equivalent Li(6)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra, edges with two equivalent Mn(13)O6 octahedra, and edges with two equivalent Mn(15)O6 octahedra. In the fifteenth Mn site, Mn(15) is bonded to one O(22), one O(24), one O(27), one O(28), one O(31), and one O(32) atom to form MnO6 octahedra that share  a cornercorner with one Li(1)O4 tetrahedra, corners with two equivalent Li(5)O4 tetrahedra, corners with two equivalent Li(6)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra,  an edgeedge with one Mn(10)O6 octahedra, edges with two equivalent Mn(13)O6 octahedra, and edges with two equivalent Mn(14)O6 octahedra. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one Mn(1), and one Mn(2) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Li(1), one Mn(1), and one Mn(3) atom. In the third O site, O(3) is bonded to one Li(3), one Mn(5), one Mn(8), and one Mn(9) atom to form a mixture of distorted corner and edge-sharing OLiMn3 trigonal pyramids. In the fourth O site, O(4) is bonded to one Li(1), one Mn(1), one Mn(2), and one Mn(3) atom to form distorted corner-sharing OLiMn3 trigonal pyramids. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Li(3), one Mn(2), and one Mn(3) atom. In the sixth O site, O(6) is bonded to one Li(2), one Mn(4), one Mn(8), and one Mn(9) atom to form a mixture of distorted corner and edge-sharing OLiMn3 trigonal pyramids. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Li(6), one Mn(2), and one Mn(3) atom. In the eighth O site, O(8) is bonded to one Li(2), one Mn(2), one Mn(3), and one Mn(5) atom to form distorted corner-sharing OLiMn3 trigonal pyramids. In the ninth O site, O(9) is bonded in a trigonal planar geometry to one Li(2), one Mn(3), and one Mn(5) atom. In the tenth O site, O(10) is bonded to one Li(4), one Mn(11), one Mn(4), and one Mn(9) atom to form a mixture of distorted corner and edge-sharing OLiMn3 tetrahedra. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Li(2), one Mn(2), and one Mn(5) atom. In the twelfth O site, O(12) is bonded to one Li(4), one Mn(11), one Mn(4), and one Mn(8) atom to form a mixture of distorted corner and edge-sharing OLiMn3 trigonal pyramids. In the thirteenth O site, O(13) is bonded in a rectangular see-saw-like geometry to one Li(3), one Mn(4), one Mn(5), and one Mn(8) atom. In the fourteenth O site, O(14) is bonded to one Li(3), one Mn(4), one Mn(5), and one Mn(9) atom to form a mixture of distorted corner and edge-sharing OLiMn3 tetrahedra. In the fifteenth O site, O(15) is bonded in a distorted T-shaped geometry to one Mn(4), one Mn(8), and one Mn(9) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal non-coplanar geometry to one Mn(11), one Mn(6), and one Mn(7) atom. In the seventeenth O site, O(17) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Mn(12), one Mn(6), and one Mn(7) atom. In the eighteenth O site, O(18) is bonded in a distorted rectangular see-saw-like geometry to one Li(4), one Mn(11), one Mn(8), and one Mn(9) atom. In the nineteenth O site, O(19) is bonded in a distorted T-shaped geometry to one Mn(10), one Mn(12), and one Mn(6) atom. In the twentieth O site, O(20) is bonded in a distorted trigonal non-coplanar geometry to one Mn(10), one Mn(12), and one Mn(7) atom. In the twenty-first O site, O(21) is bonded in a distorted T-shaped geometry to one Mn(11), one Mn(12), and one Mn(7) atom. In the twenty-second O site, O(22) is bonded to one Li(5), one Mn(10), one Mn(14), and one Mn(15) atom to form a mixture of distorted corner and edge-sharing OLiMn3 tetrahedra. In the twenty-third O site, O(23) is bonded in a distorted T-shaped geometry to one Mn(11), one Mn(12), and one Mn(6) atom. In the twenty-fourth O site, O(24) is bonded to one Li(5), one Mn(10), one Mn(13), and one Mn(15) atom to form a mixture of distorted corner and edge-sharing OLiMn3 trigonal pyramids. In the twenty-fifth O site, O(25) is bonded to one Li(5), one Mn(10), one Mn(13), and one Mn(14) atom to form a mixture of distorted corner and edge-sharing OLiMn3 trigonal pyramids. In the twenty-sixth O site, O(26) is bonded in a distorted rectangular see-saw-like geometry to one Li(5), one Mn(12), one Mn(6), and one Mn(7) atom. In the twenty-seventh O site, O(27) is bonded to one Li(1), one Mn(13), one Mn(14), and one Mn(15) atom to form a mixture of distorted corner and edge-sharing OLiMn3 tetrahedra. In the twenty-eighth O site, O(28) is bonded in a distorted T-shaped geometry to one Mn(13), one Mn(14), and one Mn(15) atom. In the twenty-ninth O site, O(29) is bonded in a distorted trigonal non-coplanar geometry to one Mn(10), one Mn(6), and one Mn(7) atom. In the thirtieth O site, O(30) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Mn(1), one Mn(13), and one Mn(14) atom. In the thirty-first O site, O(31) is bonded to one Li(6), one Mn(1), one Mn(14), and one Mn(15) atom to form distorted corner-sharing OLiMn3 tetrahedra. In the thirty-second O site, O(32) is bonded in a distorted rectangular see-saw-like geometry to one Li(6), one Mn(1), one Mn(13), and one Mn(15) atom. is represented by the CIF card [CIF]
data_Li6Mn15O32
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.980
_cell_length_b   5.892
_cell_length_c   19.407
_cell_angle_alpha   97.906
_cell_angle_beta   97.944
_cell_angle_gamma   59.197
_symmetry_Int_Tables_number   1
_cell_volume   579.921
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.849  0.829  0.033  1.0
  Li  Li1  1  0.902  0.917  0.217  1.0
  Li  Li2  1  0.588  0.591  0.276  1.0
  Li  Li3  1  0.660  0.652  0.469  1.0
  Li  Li4  1  0.090  0.098  0.781  1.0
  Li  Li5  1  0.162  0.156  0.975  1.0
  Mn  Mn6  1  0.502  0.506  0.004  1.0
  Mn  Mn7  1  0.874  0.374  0.125  1.0
  Mn  Mn8  1  0.375  0.373  0.125  1.0
  Mn  Mn9  1  0.126  0.621  0.375  1.0
  Mn  Mn10  1  0.248  0.242  0.246  1.0
  Mn  Mn11  1  0.375  0.873  0.625  1.0
  Mn  Mn12  1  0.874  0.874  0.625  1.0
  Mn  Mn13  1  0.126  0.125  0.374  1.0
  Mn  Mn14  1  0.623  0.126  0.376  1.0
  Mn  Mn15  1  0.745  0.747  0.749  1.0
  Mn  Mn16  1  0.004  0.001  0.501  1.0
  Mn  Mn17  1  0.874  0.373  0.625  1.0
  Mn  Mn18  1  0.624  0.624  0.876  1.0
  Mn  Mn19  1  0.127  0.623  0.875  1.0
  Mn  Mn20  1  0.624  0.127  0.875  1.0
  O  O21  1  0.697  0.632  0.058  1.0
  O  O22  1  0.227  0.635  0.058  1.0
  O  O23  1  0.407  0.971  0.314  1.0
  O  O24  1  0.676  0.216  0.067  1.0
  O  O25  1  0.572  0.525  0.176  1.0
  O  O26  1  0.960  0.933  0.322  1.0
  O  O27  1  0.178  0.223  0.075  1.0
  O  O28  1  0.074  0.531  0.184  1.0
  O  O29  1  0.523  0.111  0.193  1.0
  O  O30  1  0.833  0.834  0.435  1.0
  O  O31  1  0.054  0.114  0.192  1.0
  O  O32  1  0.276  0.824  0.434  1.0
  O  O33  1  0.972  0.429  0.318  1.0
  O  O34  1  0.416  0.421  0.318  1.0
  O  O35  1  0.288  0.312  0.427  1.0
  O  O36  1  0.172  0.731  0.567  1.0
  O  O37  1  0.674  0.675  0.570  1.0
  O  O38  1  0.843  0.276  0.435  1.0
  O  O39  1  0.584  0.580  0.685  1.0
  O  O40  1  0.012  0.577  0.683  1.0
  O  O41  1  0.736  0.171  0.566  1.0
  O  O42  1  0.915  0.917  0.814  1.0
  O  O43  1  0.165  0.167  0.565  1.0
  O  O44  1  0.474  0.924  0.816  1.0
  O  O45  1  0.898  0.472  0.813  1.0
  O  O46  1  0.076  0.071  0.680  1.0
  O  O47  1  0.798  0.811  0.927  1.0
  O  O48  1  0.453  0.442  0.824  1.0
  O  O49  1  0.576  0.016  0.682  1.0
  O  O50  1  0.350  0.779  0.938  1.0
  O  O51  1  0.335  0.325  0.932  1.0
  O  O52  1  0.777  0.320  0.931  1.0
[/CIF]
.