The material structure described by Li5Co4NiO10 is beta Polonium-derived structured and crystallizes in the monoclinic C2/m space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form LiO6 octahedra that share  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the second Li site, Li(2) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form LiO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Co(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with four equivalent Li(1)O6 octahedra, and edges with six equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-6°. In the third Li site, Li(3) is bonded to one O(4), two equivalent O(1), and three equivalent O(5) atoms to form LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Ni(1)O6 octahedra, corners with three equivalent Co(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, edges with three equivalent Ni(1)O6 octahedra, and edges with four equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(2), one O(5), two equivalent O(1), and two equivalent O(4) atoms to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with three equivalent Li(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the second Co site, Co(2) is bonded to one O(4), two equivalent O(2), and three equivalent O(3) atoms to form CoO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with three equivalent Li(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with four equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. Ni(1) is bonded to two equivalent O(1) and four equivalent O(5) atoms to form NiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent Li(3)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with four equivalent Co(1)O6 octahedra, and edges with six equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), two equivalent Li(3), two equivalent Co(1), and one Ni(1) atom to form OLi3Co2Ni octahedra that share  a cornercorner with one O(1)Li3Co2Ni octahedra,  a cornercorner with one O(3)Li3Co3 octahedra, corners with two equivalent O(4)Li3Co3 octahedra, corners with two equivalent O(5)Li3CoNi2 octahedra, edges with two equivalent O(1)Li3Co2Ni octahedra, edges with two equivalent O(2)Li3Co3 octahedra, edges with three equivalent O(4)Li3Co3 octahedra, and edges with five equivalent O(5)Li3CoNi2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the second O site, O(2) is bonded to one Li(2), two equivalent Li(1), one Co(1), and two equivalent Co(2) atoms to form OLi3Co3 octahedra that share  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(5)Li3CoNi2 octahedra, corners with two equivalent O(3)Li3Co3 octahedra, corners with two equivalent O(4)Li3Co3 octahedra, edges with two equivalent O(1)Li3Co2Ni octahedra, edges with two equivalent O(2)Li3Co3 octahedra, edges with three equivalent O(4)Li3Co3 octahedra, and edges with five equivalent O(3)Li3Co3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the third O site, O(3) is bonded to one Li(1), two equivalent Li(2), and three equivalent Co(2) atoms to form OLi3Co3 octahedra that share  a cornercorner with one O(1)Li3Co2Ni octahedra,  a cornercorner with one O(4)Li3Co3 octahedra, corners with two equivalent O(2)Li3Co3 octahedra, corners with two equivalent O(3)Li3Co3 octahedra, edges with two equivalent O(4)Li3Co3 octahedra, edges with five equivalent O(2)Li3Co3 octahedra, and edges with five equivalent O(3)Li3Co3 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth O site, O(4) is bonded to one Li(3), two equivalent Li(1), one Co(2), and two equivalent Co(1) atoms to form OLi3Co3 octahedra that share  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(5)Li3CoNi2 octahedra, corners with two equivalent O(1)Li3Co2Ni octahedra, corners with two equivalent O(2)Li3Co3 octahedra, edges with two equivalent O(3)Li3Co3 octahedra, edges with two equivalent O(4)Li3Co3 octahedra, edges with two equivalent O(5)Li3CoNi2 octahedra, edges with three equivalent O(1)Li3Co2Ni octahedra, and edges with three equivalent O(2)Li3Co3 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the fifth O site, O(5) is bonded to three equivalent Li(3), one Co(1), and two equivalent Ni(1) atoms to form OLi3CoNi2 octahedra that share  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra, corners with two equivalent O(1)Li3Co2Ni octahedra, corners with two equivalent O(5)Li3CoNi2 octahedra, edges with two equivalent O(4)Li3Co3 octahedra, edges with five equivalent O(1)Li3Co2Ni octahedra, and edges with five equivalent O(5)Li3CoNi2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. is represented by the CIF card [CIF]
data_Li5Co4NiO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.167
_cell_length_b   5.167
_cell_length_c   12.448
_cell_angle_alpha   79.243
_cell_angle_beta   79.243
_cell_angle_gamma   33.741
_symmetry_Int_Tables_number   1
_cell_volume   181.041
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.099  0.099  0.301  1.0
  Li  Li1  1  0.500  0.500  0.500  1.0
  Li  Li2  1  0.901  0.901  0.699  1.0
  Li  Li3  1  0.301  0.301  0.898  1.0
  Li  Li4  1  0.699  0.699  0.102  1.0
  Co  Co5  1  0.404  0.404  0.197  1.0
  Co  Co6  1  0.801  0.801  0.399  1.0
  Co  Co7  1  0.199  0.199  0.601  1.0
  Co  Co8  1  0.596  0.596  0.803  1.0
  Ni  Ni9  1  0.000  0.000  0.000  1.0
  O  O10  1  0.041  0.041  0.155  1.0
  O  O11  1  0.441  0.441  0.347  1.0
  O  O12  1  0.843  0.843  0.544  1.0
  O  O13  1  0.241  0.241  0.743  1.0
  O  O14  1  0.644  0.644  0.940  1.0
  O  O15  1  0.157  0.157  0.456  1.0
  O  O16  1  0.559  0.559  0.653  1.0
  O  O17  1  0.959  0.959  0.845  1.0
  O  O18  1  0.356  0.356  0.060  1.0
  O  O19  1  0.759  0.759  0.257  1.0
[/CIF]
.
The material structure described by Li5Co4NiO10 is beta Polonium-derived structured and crystallizes in the monoclinic C2/m space group. There are three inequivalent Li sites. In the first Li site, Li(1) is bonded to one O(1), one O(3), two equivalent O(2), and two equivalent O(4) atoms to form LiO6 octahedra that share  a cornercorner with one Ni(1)O6 octahedra, corners with two equivalent Co(1)O6 octahedra, corners with three equivalent Co(2)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with two equivalent Li(3)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, and edges with three equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-7°. In the second Li site, Li(2) is bonded to two equivalent O(2) and four equivalent O(3) atoms to form LiO6 octahedra that share corners with two equivalent Co(1)O6 octahedra, corners with four equivalent Co(2)O6 octahedra, edges with two equivalent Li(2)O6 octahedra, edges with four equivalent Li(1)O6 octahedra, and edges with six equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-6°. In the third Li site, Li(3) is bonded to one O(4), two equivalent O(1), and three equivalent O(5) atoms to form LiO6 octahedra that share  a cornercorner with one Co(2)O6 octahedra, corners with two equivalent Ni(1)O6 octahedra, corners with three equivalent Co(1)O6 octahedra, edges with two equivalent Li(1)O6 octahedra, edges with three equivalent Co(1)O6 octahedra, edges with three equivalent Ni(1)O6 octahedra, and edges with four equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(2), one O(5), two equivalent O(1), and two equivalent O(4) atoms to form CoO6 octahedra that share  a cornercorner with one Li(2)O6 octahedra, corners with two equivalent Li(1)O6 octahedra, corners with three equivalent Li(3)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, and edges with three equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 0-7°. In the second Co site, Co(2) is bonded to one O(4), two equivalent O(2), and three equivalent O(3) atoms to form CoO6 octahedra that share  a cornercorner with one Li(3)O6 octahedra, corners with two equivalent Li(2)O6 octahedra, corners with three equivalent Li(1)O6 octahedra, edges with two equivalent Co(1)O6 octahedra, edges with three equivalent Li(1)O6 octahedra, edges with three equivalent Li(2)O6 octahedra, and edges with four equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 3-6°. Ni(1) is bonded to two equivalent O(1) and four equivalent O(5) atoms to form NiO6 octahedra that share corners with two equivalent Li(1)O6 octahedra, corners with four equivalent Li(3)O6 octahedra, edges with two equivalent Ni(1)O6 octahedra, edges with four equivalent Co(1)O6 octahedra, and edges with six equivalent Li(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 5-7°. There are five inequivalent O sites. In the first O site, O(1) is bonded to one Li(1), two equivalent Li(3), two equivalent Co(1), and one Ni(1) atom to form OLi3Co2Ni octahedra that share  a cornercorner with one O(1)Li3Co2Ni octahedra,  a cornercorner with one O(3)Li3Co3 octahedra, corners with two equivalent O(4)Li3Co3 octahedra, corners with two equivalent O(5)Li3CoNi2 octahedra, edges with two equivalent O(1)Li3Co2Ni octahedra, edges with two equivalent O(2)Li3Co3 octahedra, edges with three equivalent O(4)Li3Co3 octahedra, and edges with five equivalent O(5)Li3CoNi2 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the second O site, O(2) is bonded to one Li(2), two equivalent Li(1), one Co(1), and two equivalent Co(2) atoms to form OLi3Co3 octahedra that share  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(5)Li3CoNi2 octahedra, corners with two equivalent O(3)Li3Co3 octahedra, corners with two equivalent O(4)Li3Co3 octahedra, edges with two equivalent O(1)Li3Co2Ni octahedra, edges with two equivalent O(2)Li3Co3 octahedra, edges with three equivalent O(4)Li3Co3 octahedra, and edges with five equivalent O(3)Li3Co3 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. In the third O site, O(3) is bonded to one Li(1), two equivalent Li(2), and three equivalent Co(2) atoms to form OLi3Co3 octahedra that share  a cornercorner with one O(1)Li3Co2Ni octahedra,  a cornercorner with one O(4)Li3Co3 octahedra, corners with two equivalent O(2)Li3Co3 octahedra, corners with two equivalent O(3)Li3Co3 octahedra, edges with two equivalent O(4)Li3Co3 octahedra, edges with five equivalent O(2)Li3Co3 octahedra, and edges with five equivalent O(3)Li3Co3 octahedra. The corner-sharing octahedral tilt angles range from 0-1°. In the fourth O site, O(4) is bonded to one Li(3), two equivalent Li(1), one Co(2), and two equivalent Co(1) atoms to form OLi3Co3 octahedra that share  a cornercorner with one O(3)Li3Co3 octahedra,  a cornercorner with one O(5)Li3CoNi2 octahedra, corners with two equivalent O(1)Li3Co2Ni octahedra, corners with two equivalent O(2)Li3Co3 octahedra, edges with two equivalent O(3)Li3Co3 octahedra, edges with two equivalent O(4)Li3Co3 octahedra, edges with two equivalent O(5)Li3CoNi2 octahedra, edges with three equivalent O(1)Li3Co2Ni octahedra, and edges with three equivalent O(2)Li3Co3 octahedra. The corner-sharing octahedral tilt angles range from 0-6°. In the fifth O site, O(5) is bonded to three equivalent Li(3), one Co(1), and two equivalent Ni(1) atoms to form OLi3CoNi2 octahedra that share  a cornercorner with one O(2)Li3Co3 octahedra,  a cornercorner with one O(4)Li3Co3 octahedra, corners with two equivalent O(1)Li3Co2Ni octahedra, corners with two equivalent O(5)Li3CoNi2 octahedra, edges with two equivalent O(4)Li3Co3 octahedra, edges with five equivalent O(1)Li3Co2Ni octahedra, and edges with five equivalent O(5)Li3CoNi2 octahedra. The corner-sharing octahedral tilt angles range from 0-4°. is represented by the CIF card [CIF]
data_Li5Co4NiO10
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.167
_cell_length_b   5.167
_cell_length_c   12.448
_cell_angle_alpha   79.243
_cell_angle_beta   79.243
_cell_angle_gamma   33.741
_symmetry_Int_Tables_number   1
_cell_volume   181.041
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.099  0.099  0.301  1.0
  Li  Li1  1  0.500  0.500  0.500  1.0
  Li  Li2  1  0.901  0.901  0.699  1.0
  Li  Li3  1  0.301  0.301  0.898  1.0
  Li  Li4  1  0.699  0.699  0.102  1.0
  Co  Co5  1  0.404  0.404  0.197  1.0
  Co  Co6  1  0.801  0.801  0.399  1.0
  Co  Co7  1  0.199  0.199  0.601  1.0
  Co  Co8  1  0.596  0.596  0.803  1.0
  Ni  Ni9  1  0.000  0.000  0.000  1.0
  O  O10  1  0.041  0.041  0.155  1.0
  O  O11  1  0.441  0.441  0.347  1.0
  O  O12  1  0.843  0.843  0.544  1.0
  O  O13  1  0.241  0.241  0.743  1.0
  O  O14  1  0.644  0.644  0.940  1.0
  O  O15  1  0.157  0.157  0.456  1.0
  O  O16  1  0.559  0.559  0.653  1.0
  O  O17  1  0.959  0.959  0.845  1.0
  O  O18  1  0.356  0.356  0.060  1.0
  O  O19  1  0.759  0.759  0.257  1.0
[/CIF]
.