The material described by (C4NH11)2H2(AlH2OF4)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 atoms, two tetramethylammonium molecules, and one AlH2OF4 cluster. In the AlH2OF4 cluster, Al(1) is bonded to one O(1), one F(2), one F(3), and two equivalent F(4) atoms to form edge-sharing AlOF4 trigonal bipyramids. There are two inequivalent H sites. In the first H site, H(6) is bonded in a distorted linear geometry to one F(1) and one F(3) atom. In the second H site, H(12) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted bent 120 degrees geometry to one Al(1) and one H(12) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one H(6) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Al(1) atom. In the third F site, F(3) is bonded in a water-like geometry to one Al(1) and one H(6) atom. In the fourth F site, F(4) is bonded in a water-like geometry to two equivalent Al(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_AlH14C4NOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.941
_cell_length_b   9.019
_cell_length_c   9.472
_cell_angle_alpha   68.174
_cell_angle_beta   77.902
_cell_angle_gamma   71.924
_symmetry_Int_Tables_number   1
_cell_volume   595.301
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.369  0.581  0.602  1.0
  Al  Al1  1  0.631  0.419  0.398  1.0
  H  H2  1  0.511  1.000  0.216  1.0
  H  H3  1  0.709  0.570  0.989  1.0
  H  H4  1  0.341  0.167  0.431  1.0
  H  H5  1  0.440  0.824  0.774  1.0
  H  H6  1  0.098  0.191  0.400  1.0
  H  H7  1  0.727  0.698  0.242  1.0
  H  H8  1  0.794  0.980  0.820  1.0
  H  H9  1  0.960  0.788  0.843  1.0
  H  H10  1  0.888  0.551  0.837  1.0
  H  H11  1  0.291  0.430  0.011  1.0
  H  H12  1  0.659  0.833  0.569  1.0
  H  H13  1  0.665  0.563  0.812  1.0
  H  H14  1  0.521  0.175  0.044  1.0
  H  H15  1  0.112  0.449  0.163  1.0
  H  H16  1  0.489  0.000  0.784  1.0
  H  H17  1  0.206  0.020  0.180  1.0
  H  H18  1  0.040  0.212  0.157  1.0
  H  H19  1  0.560  0.176  0.226  1.0
  H  H20  1  0.273  0.302  0.758  1.0
  H  H21  1  0.677  0.138  0.456  1.0
  H  H22  1  0.902  0.809  0.600  1.0
  H  H23  1  0.479  0.825  0.956  1.0
  H  H24  1  0.216  0.192  0.006  1.0
  H  H25  1  0.824  0.225  0.731  1.0
  H  H26  1  0.323  0.862  0.544  1.0
  H  H27  1  0.335  0.437  0.188  1.0
  H  H28  1  0.784  0.808  0.994  1.0
  H  H29  1  0.176  0.775  0.269  1.0
  C  C30  1  0.254  0.398  0.135  1.0
  C  C31  1  0.180  0.154  0.130  1.0
  C  C32  1  0.242  0.165  0.367  1.0
  C  C33  1  0.746  0.602  0.865  1.0
  C  C34  1  0.514  0.866  0.832  1.0
  C  C35  1  0.820  0.846  0.870  1.0
  C  C36  1  0.486  0.134  0.168  1.0
  C  C37  1  0.758  0.835  0.633  1.0
  N  N38  1  0.709  0.789  0.799  1.0
  N  N39  1  0.291  0.211  0.201  1.0
  O  O40  1  0.574  0.232  0.440  1.0
  O  O41  1  0.426  0.768  0.560  1.0
  F  F42  1  0.801  0.770  0.235  1.0
  F  F43  1  0.199  0.230  0.765  1.0
  F  F44  1  0.141  0.648  0.650  1.0
  F  F45  1  0.393  0.404  0.769  1.0
  F  F46  1  0.859  0.352  0.350  1.0
  F  F47  1  0.607  0.596  0.231  1.0
  F  F48  1  0.630  0.487  0.551  1.0
  F  F49  1  0.370  0.513  0.449  1.0
[/CIF]
.
The material described by (C4NH11)2H2(AlH2OF4)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 1333-74-0 atoms, two tetramethylammonium molecules, and one AlH2OF4 cluster. In the AlH2OF4 cluster, Al(1) is bonded to one O(1), one F(2), one F(3), and two equivalent F(4) atoms to form edge-sharing AlOF4 trigonal bipyramids. There are two inequivalent H sites. In the first H site, H(6) is bonded in a distorted linear geometry to one F(1) and one F(3) atom. In the second H site, H(12) is bonded in a single-bond geometry to one O(1) atom. O(1) is bonded in a distorted bent 120 degrees geometry to one Al(1) and one H(12) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one H(6) atom. In the second F site, F(2) is bonded in a single-bond geometry to one Al(1) atom. In the third F site, F(3) is bonded in a water-like geometry to one Al(1) and one H(6) atom. In the fourth F site, F(4) is bonded in a water-like geometry to two equivalent Al(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_AlH14C4NOF4
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.941
_cell_length_b   9.019
_cell_length_c   9.472
_cell_angle_alpha   68.174
_cell_angle_beta   77.902
_cell_angle_gamma   71.924
_symmetry_Int_Tables_number   1
_cell_volume   595.301
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.369  0.581  0.602  1.0
  Al  Al1  1  0.631  0.419  0.398  1.0
  H  H2  1  0.511  1.000  0.216  1.0
  H  H3  1  0.709  0.570  0.989  1.0
  H  H4  1  0.341  0.167  0.431  1.0
  H  H5  1  0.440  0.824  0.774  1.0
  H  H6  1  0.098  0.191  0.400  1.0
  H  H7  1  0.727  0.698  0.242  1.0
  H  H8  1  0.794  0.980  0.820  1.0
  H  H9  1  0.960  0.788  0.843  1.0
  H  H10  1  0.888  0.551  0.837  1.0
  H  H11  1  0.291  0.430  0.011  1.0
  H  H12  1  0.659  0.833  0.569  1.0
  H  H13  1  0.665  0.563  0.812  1.0
  H  H14  1  0.521  0.175  0.044  1.0
  H  H15  1  0.112  0.449  0.163  1.0
  H  H16  1  0.489  0.000  0.784  1.0
  H  H17  1  0.206  0.020  0.180  1.0
  H  H18  1  0.040  0.212  0.157  1.0
  H  H19  1  0.560  0.176  0.226  1.0
  H  H20  1  0.273  0.302  0.758  1.0
  H  H21  1  0.677  0.138  0.456  1.0
  H  H22  1  0.902  0.809  0.600  1.0
  H  H23  1  0.479  0.825  0.956  1.0
  H  H24  1  0.216  0.192  0.006  1.0
  H  H25  1  0.824  0.225  0.731  1.0
  H  H26  1  0.323  0.862  0.544  1.0
  H  H27  1  0.335  0.437  0.188  1.0
  H  H28  1  0.784  0.808  0.994  1.0
  H  H29  1  0.176  0.775  0.269  1.0
  C  C30  1  0.254  0.398  0.135  1.0
  C  C31  1  0.180  0.154  0.130  1.0
  C  C32  1  0.242  0.165  0.367  1.0
  C  C33  1  0.746  0.602  0.865  1.0
  C  C34  1  0.514  0.866  0.832  1.0
  C  C35  1  0.820  0.846  0.870  1.0
  C  C36  1  0.486  0.134  0.168  1.0
  C  C37  1  0.758  0.835  0.633  1.0
  N  N38  1  0.709  0.789  0.799  1.0
  N  N39  1  0.291  0.211  0.201  1.0
  O  O40  1  0.574  0.232  0.440  1.0
  O  O41  1  0.426  0.768  0.560  1.0
  F  F42  1  0.801  0.770  0.235  1.0
  F  F43  1  0.199  0.230  0.765  1.0
  F  F44  1  0.141  0.648  0.650  1.0
  F  F45  1  0.393  0.404  0.769  1.0
  F  F46  1  0.859  0.352  0.350  1.0
  F  F47  1  0.607  0.596  0.231  1.0
  F  F48  1  0.630  0.487  0.551  1.0
  F  F49  1  0.370  0.513  0.449  1.0
[/CIF]
.