The structure described by Cs2Sn(AuS2)2 crystallizes in the orthorhombic Fddd space group. Cs(1) is bonded in a 10-coordinate geometry to two equivalent Au(1) and eight equivalent S(1) atoms. Au(1) is bonded in a distorted linear geometry to two equivalent Cs(1) and two equivalent S(1) atoms. Sn(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one Au(1), and one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs2Sn(AuS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.842
_cell_length_b   13.219
_cell_length_c   8.070
_cell_angle_alpha   84.728
_cell_angle_beta   62.491
_cell_angle_gamma   32.781
_symmetry_Int_Tables_number   1
_cell_volume   598.157
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.180  0.180  0.820  1.0
  Cs  Cs1  1  0.070  0.070  0.430  1.0
  Cs  Cs2  1  0.820  0.820  0.180  1.0
  Cs  Cs3  1  0.430  0.430  0.070  1.0
  Sn  Sn4  1  0.250  0.250  0.250  1.0
  Sn  Sn5  1  0.000  0.000  0.000  1.0
  Au  Au6  1  0.439  0.439  0.561  1.0
  Au  Au7  1  0.689  0.689  0.811  1.0
  Au  Au8  1  0.811  0.811  0.689  1.0
  Au  Au9  1  0.561  0.561  0.439  1.0
  S  S10  1  0.053  0.831  0.751  1.0
  S  S11  1  0.886  0.499  0.419  1.0
  S  S12  1  0.751  0.364  0.053  1.0
  S  S13  1  0.499  0.886  0.197  1.0
  S  S14  1  0.419  0.197  0.886  1.0
  S  S15  1  0.197  0.419  0.499  1.0
  S  S16  1  0.364  0.751  0.831  1.0
  S  S17  1  0.831  0.053  0.364  1.0
[/CIF]
.
The structure described by Cs2Sn(AuS2)2 crystallizes in the orthorhombic Fddd space group. Cs(1) is bonded in a 10-coordinate geometry to two equivalent Au(1) and eight equivalent S(1) atoms. Au(1) is bonded in a distorted linear geometry to two equivalent Cs(1) and two equivalent S(1) atoms. Sn(1) is bonded in a tetrahedral geometry to four equivalent S(1) atoms. S(1) is bonded in a 6-coordinate geometry to four equivalent Cs(1), one Au(1), and one Sn(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_Cs2Sn(AuS2)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   14.842
_cell_length_b   13.219
_cell_length_c   8.070
_cell_angle_alpha   84.728
_cell_angle_beta   62.491
_cell_angle_gamma   32.781
_symmetry_Int_Tables_number   1
_cell_volume   598.157
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.180  0.180  0.820  1.0
  Cs  Cs1  1  0.070  0.070  0.430  1.0
  Cs  Cs2  1  0.820  0.820  0.180  1.0
  Cs  Cs3  1  0.430  0.430  0.070  1.0
  Sn  Sn4  1  0.250  0.250  0.250  1.0
  Sn  Sn5  1  0.000  0.000  0.000  1.0
  Au  Au6  1  0.439  0.439  0.561  1.0
  Au  Au7  1  0.689  0.689  0.811  1.0
  Au  Au8  1  0.811  0.811  0.689  1.0
  Au  Au9  1  0.561  0.561  0.439  1.0
  S  S10  1  0.053  0.831  0.751  1.0
  S  S11  1  0.886  0.499  0.419  1.0
  S  S12  1  0.751  0.364  0.053  1.0
  S  S13  1  0.499  0.886  0.197  1.0
  S  S14  1  0.419  0.197  0.886  1.0
  S  S15  1  0.197  0.419  0.499  1.0
  S  S16  1  0.364  0.751  0.831  1.0
  S  S17  1  0.831  0.053  0.364  1.0
[/CIF]
.