The crystal structure described by La3Rh2CuZnPbO12 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(2), one O(5), one O(6), and one O(8) atom. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(3), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. In the third La site, La(3) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(3), one O(4), one O(6), one O(7), one O(8), and one O(9) atom. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded to one O(10), one O(11), one O(2), one O(4), one O(6), and one O(7) atom to form RhO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra and corners with four equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-34°. In the second Rh site, Rh(2) is bonded to one O(1), one O(12), one O(3), one O(5), one O(8), and one O(9) atom to form RhO6 octahedra that share corners with two equivalent Zn(1)O6 octahedra and corners with four equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-32°. Cu(1) is bonded to one O(12), one O(2), one O(4), one O(5), one O(8), and one O(9) atom to form CuO6 octahedra that share corners with two equivalent Rh(1)O6 octahedra and corners with four equivalent Rh(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-34°. Zn(1) is bonded to one O(1), one O(10), one O(11), one O(3), one O(6), and one O(7) atom to form ZnO6 octahedra that share corners with two equivalent Rh(2)O6 octahedra and corners with four equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 30-33°. Pb(1) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(12), one O(2), one O(5), one O(6), and one O(7) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one La(1), one Rh(2), one Zn(1), and one Pb(1) atom. In the second O site, O(2) is bonded to one La(1), one Rh(1), one Cu(1), and one Pb(1) atom to form distorted corner-sharing OLaCuRhPb tetrahedra. In the third O site, O(3) is bonded to one La(2), one La(3), one Rh(2), and one Zn(1) atom to form distorted corner-sharing OLa2ZnRh tetrahedra. In the fourth O site, O(4) is bonded to one La(2), one La(3), one Rh(1), and one Cu(1) atom to form distorted OLa2CuRh tetrahedra that share corners with two equivalent O(3)La2ZnRh tetrahedra and corners with two equivalent O(2)LaCuRhPb tetrahedra. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Rh(2), one Cu(1), and one Pb(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one La(1), one La(3), one Rh(1), one Zn(1), and one Pb(1) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one La(2), one La(3), one Rh(1), one Zn(1), and one Pb(1) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one La(1), one La(2), one La(3), one Rh(2), and one Cu(1) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one La(2), one La(3), one Rh(2), and one Cu(1) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one La(1), one La(2), one La(3), one Rh(1), and one Zn(1) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Rh(1), one Zn(1), and one Pb(1) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one La(1), one La(3), one Rh(2), one Cu(1), and one Pb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_La3ZnCuRh2PbO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.593
_cell_length_b   5.744
_cell_length_c   7.940
_cell_angle_alpha   90.524
_cell_angle_beta   90.267
_cell_angle_gamma   90.637
_symmetry_Int_Tables_number   1
_cell_volume   255.065
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.513  0.052  0.249  1.0
  La  La1  1  0.014  0.446  0.750  1.0
  La  La2  1  0.490  0.944  0.751  1.0
  Zn  Zn3  1  0.003  0.998  0.499  1.0
  Cu  Cu4  1  0.498  0.504  0.003  1.0
  Rh  Rh5  1  0.499  0.501  0.499  1.0
  Rh  Rh6  1  0.002  0.004  0.001  1.0
  Pb  Pb7  1  0.991  0.554  0.253  1.0
  O  O8  1  0.085  0.954  0.244  1.0
  O  O9  1  0.395  0.470  0.256  1.0
  O  O10  1  0.908  0.033  0.751  1.0
  O  O11  1  0.596  0.523  0.747  1.0
  O  O12  1  0.810  0.297  0.056  1.0
  O  O13  1  0.688  0.797  0.454  1.0
  O  O14  1  0.205  0.693  0.547  1.0
  O  O15  1  0.302  0.202  0.954  1.0
  O  O16  1  0.195  0.714  0.947  1.0
  O  O17  1  0.309  0.201  0.547  1.0
  O  O18  1  0.797  0.310  0.446  1.0
  O  O19  1  0.703  0.802  0.044  1.0
[/CIF]
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The crystal structure described by La3Rh2CuZnPbO12 is Orthorhombic Perovskite-derived structured and crystallizes in the triclinic P1 space group. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(11), one O(12), one O(2), one O(5), one O(6), and one O(8) atom. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(3), one O(4), one O(5), one O(7), one O(8), and one O(9) atom. In the third La site, La(3) is bonded in a 8-coordinate geometry to one O(10), one O(12), one O(3), one O(4), one O(6), one O(7), one O(8), and one O(9) atom. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded to one O(10), one O(11), one O(2), one O(4), one O(6), and one O(7) atom to form RhO6 octahedra that share corners with two equivalent Cu(1)O6 octahedra and corners with four equivalent Zn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-34°. In the second Rh site, Rh(2) is bonded to one O(1), one O(12), one O(3), one O(5), one O(8), and one O(9) atom to form RhO6 octahedra that share corners with two equivalent Zn(1)O6 octahedra and corners with four equivalent Cu(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-32°. Cu(1) is bonded to one O(12), one O(2), one O(4), one O(5), one O(8), and one O(9) atom to form CuO6 octahedra that share corners with two equivalent Rh(1)O6 octahedra and corners with four equivalent Rh(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 28-34°. Zn(1) is bonded to one O(1), one O(10), one O(11), one O(3), one O(6), and one O(7) atom to form ZnO6 octahedra that share corners with two equivalent Rh(2)O6 octahedra and corners with four equivalent Rh(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 30-33°. Pb(1) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(12), one O(2), one O(5), one O(6), and one O(7) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one La(1), one Rh(2), one Zn(1), and one Pb(1) atom. In the second O site, O(2) is bonded to one La(1), one Rh(1), one Cu(1), and one Pb(1) atom to form distorted corner-sharing OLaCuRhPb tetrahedra. In the third O site, O(3) is bonded to one La(2), one La(3), one Rh(2), and one Zn(1) atom to form distorted corner-sharing OLa2ZnRh tetrahedra. In the fourth O site, O(4) is bonded to one La(2), one La(3), one Rh(1), and one Cu(1) atom to form distorted OLa2CuRh tetrahedra that share corners with two equivalent O(3)La2ZnRh tetrahedra and corners with two equivalent O(2)LaCuRhPb tetrahedra. In the fifth O site, O(5) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Rh(2), one Cu(1), and one Pb(1) atom. In the sixth O site, O(6) is bonded in a 5-coordinate geometry to one La(1), one La(3), one Rh(1), one Zn(1), and one Pb(1) atom. In the seventh O site, O(7) is bonded in a 5-coordinate geometry to one La(2), one La(3), one Rh(1), one Zn(1), and one Pb(1) atom. In the eighth O site, O(8) is bonded in a 5-coordinate geometry to one La(1), one La(2), one La(3), one Rh(2), and one Cu(1) atom. In the ninth O site, O(9) is bonded in a 4-coordinate geometry to one La(2), one La(3), one Rh(2), and one Cu(1) atom. In the tenth O site, O(10) is bonded in a 5-coordinate geometry to one La(1), one La(2), one La(3), one Rh(1), and one Zn(1) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to one La(1), one La(2), one Rh(1), one Zn(1), and one Pb(1) atom. In the twelfth O site, O(12) is bonded in a 5-coordinate geometry to one La(1), one La(3), one Rh(2), one Cu(1), and one Pb(1) atom. is represented by the Crystallographic Information File (CIF) [CIF]
data_La3ZnCuRh2PbO12
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.593
_cell_length_b   5.744
_cell_length_c   7.940
_cell_angle_alpha   90.524
_cell_angle_beta   90.267
_cell_angle_gamma   90.637
_symmetry_Int_Tables_number   1
_cell_volume   255.065
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.513  0.052  0.249  1.0
  La  La1  1  0.014  0.446  0.750  1.0
  La  La2  1  0.490  0.944  0.751  1.0
  Zn  Zn3  1  0.003  0.998  0.499  1.0
  Cu  Cu4  1  0.498  0.504  0.003  1.0
  Rh  Rh5  1  0.499  0.501  0.499  1.0
  Rh  Rh6  1  0.002  0.004  0.001  1.0
  Pb  Pb7  1  0.991  0.554  0.253  1.0
  O  O8  1  0.085  0.954  0.244  1.0
  O  O9  1  0.395  0.470  0.256  1.0
  O  O10  1  0.908  0.033  0.751  1.0
  O  O11  1  0.596  0.523  0.747  1.0
  O  O12  1  0.810  0.297  0.056  1.0
  O  O13  1  0.688  0.797  0.454  1.0
  O  O14  1  0.205  0.693  0.547  1.0
  O  O15  1  0.302  0.202  0.954  1.0
  O  O16  1  0.195  0.714  0.947  1.0
  O  O17  1  0.309  0.201  0.547  1.0
  O  O18  1  0.797  0.310  0.446  1.0
  O  O19  1  0.703  0.802  0.044  1.0
[/CIF]
.