The structure described by VO2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. V(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 50°. O(1) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms. is represented by the CIF card [CIF]
data_VO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.044
_cell_length_b   4.507
_cell_length_c   4.507
_cell_angle_alpha   89.984
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   61.848
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.500  0.500  0.500  1.0
  O  O2  1  0.000  0.300  0.300  1.0
  O  O3  1  0.000  0.700  0.700  1.0
  O  O4  1  0.500  0.800  0.200  1.0
  O  O5  1  0.500  0.200  0.800  1.0
[/CIF]
.
The structure described by VO2 is Rutile structured and crystallizes in the tetragonal P4_2/mnm space group. V(1) is bonded to six equivalent O(1) atoms to form a mixture of corner and edge-sharing VO6 octahedra. The corner-sharing octahedral tilt angles are 50°. O(1) is bonded in a distorted trigonal planar geometry to three equivalent V(1) atoms. is represented by the CIF card [CIF]
data_VO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.044
_cell_length_b   4.507
_cell_length_c   4.507
_cell_angle_alpha   89.984
_cell_angle_beta   90.000
_cell_angle_gamma   90.000
_symmetry_Int_Tables_number   1
_cell_volume   61.848
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.000  0.000  0.000  1.0
  V  V1  1  0.500  0.500  0.500  1.0
  O  O2  1  0.000  0.300  0.300  1.0
  O  O3  1  0.000  0.700  0.700  1.0
  O  O4  1  0.500  0.800  0.200  1.0
  O  O5  1  0.500  0.200  0.800  1.0
[/CIF]
.