The crystal structure described by RbMg14W crystallizes in the orthorhombic Amm2 space group. Rb(1) is bonded to two equivalent Mg(6), four equivalent Mg(3), four equivalent Mg(5), and two equivalent W(1) atoms to form RbMg10W2 cuboctahedra that share corners with four equivalent Mg(2)Mg12 cuboctahedra, corners with six equivalent Rb(1)Mg10W2 cuboctahedra, corners with eight equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent W(1)Rb2Mg10 cuboctahedra, edges with four equivalent Mg(6)RbMg11 cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(6)RbMg11 cuboctahedra, and faces with two equivalent W(1)Rb2Mg10 cuboctahedra. There are seven inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(2), two equivalent Mg(6), four equivalent Mg(4), and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent W(1)Rb2Mg10 cuboctahedra, corners with six equivalent Mg(1)Mg12 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra, edges with four equivalent Mg(6)RbMg11 cuboctahedra, faces with two equivalent Rb(1)Mg10W2 cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, faces with two equivalent Mg(6)RbMg11 cuboctahedra, and faces with four equivalent Mg(4)Mg12 cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(1), two equivalent Mg(7), four equivalent Mg(4), and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Rb(1)Mg10W2 cuboctahedra, corners with six equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent W(1)Rb2Mg10 cuboctahedra, faces with four equivalent Mg(4)Mg12 cuboctahedra, and faces with six equivalent Mg(6)RbMg11 cuboctahedra. In the third Mg site, Mg(3) is bonded in a 12-coordinate geometry to two equivalent Rb(1), two equivalent Mg(3), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and two equivalent W(1) atoms. In the fourth Mg site, Mg(4) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), two equivalent Mg(6), and two equivalent Mg(7) atoms to form distorted MgMg12 cuboctahedra that share corners with four equivalent Rb(1)Mg10W2 cuboctahedra, corners with four equivalent W(1)Rb2Mg10 cuboctahedra, corners with six equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Mg(4)Mg12 cuboctahedra, edges with four equivalent Mg(6)RbMg11 cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, and faces with two equivalent Mg(6)RbMg11 cuboctahedra. In the fifth Mg site, Mg(5) is bonded in a 2-coordinate geometry to one Rb(1), one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(6), and one W(1) atom. In the sixth Mg site, Mg(6) is bonded to one Rb(1), one Mg(1), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(7), and four equivalent Mg(5) atoms to form distorted MgRbMg11 cuboctahedra that share corners with six equivalent Mg(6)RbMg11 cuboctahedra, edges with two equivalent Rb(1)Mg10W2 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra,  a faceface with one Rb(1)Mg10W2 cuboctahedra,  a faceface with one Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, faces with two equivalent Mg(6)RbMg11 cuboctahedra, faces with three equivalent Mg(2)Mg12 cuboctahedra, and faces with three equivalent W(1)Rb2Mg10 cuboctahedra. In the seventh Mg site, Mg(7) is bonded in a distorted single-bond geometry to one Mg(2), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(6), and one W(1) atom. W(1) is bonded to two equivalent Rb(1), two equivalent Mg(7), four equivalent Mg(3), and four equivalent Mg(5) atoms to form WRb2Mg10 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra, corners with six equivalent W(1)Rb2Mg10 cuboctahedra, corners with eight equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Rb(1)Mg10W2 cuboctahedra, faces with two equivalent Rb(1)Mg10W2 cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, and faces with six equivalent Mg(6)RbMg11 cuboctahedra. is represented by the CIF file [CIF]
data_RbMg14W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.445
_cell_length_b   6.676
_cell_length_c   10.288
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   121.196
_symmetry_Int_Tables_number   1
_cell_volume   378.656
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.161  0.331  0.125  1.0
  Mg  Mg1  1  0.173  0.337  0.625  1.0
  Mg  Mg2  1  0.167  0.833  0.625  1.0
  Mg  Mg3  1  0.662  0.326  0.125  1.0
  Mg  Mg4  1  0.667  0.341  0.625  1.0
  Mg  Mg5  1  0.662  0.836  0.125  1.0
  Mg  Mg6  1  0.667  0.826  0.625  1.0
  Mg  Mg7  1  0.330  0.144  0.376  1.0
  Mg  Mg8  1  0.330  0.144  0.874  1.0
  Mg  Mg9  1  0.330  0.686  0.376  1.0
  Mg  Mg10  1  0.330  0.686  0.874  1.0
  Mg  Mg11  1  0.817  0.159  0.393  1.0
  Mg  Mg12  1  0.817  0.159  0.857  1.0
  Mg  Mg13  1  0.845  0.673  0.359  1.0
  Mg  Mg14  1  0.845  0.673  0.891  1.0
  W  W15  1  0.198  0.849  0.125  1.0
[/CIF]
.
The crystal structure described by RbMg14W crystallizes in the orthorhombic Amm2 space group. Rb(1) is bonded to two equivalent Mg(6), four equivalent Mg(3), four equivalent Mg(5), and two equivalent W(1) atoms to form RbMg10W2 cuboctahedra that share corners with four equivalent Mg(2)Mg12 cuboctahedra, corners with six equivalent Rb(1)Mg10W2 cuboctahedra, corners with eight equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent W(1)Rb2Mg10 cuboctahedra, edges with four equivalent Mg(6)RbMg11 cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(6)RbMg11 cuboctahedra, and faces with two equivalent W(1)Rb2Mg10 cuboctahedra. There are seven inequivalent Mg sites. In the first Mg site, Mg(1) is bonded to two equivalent Mg(2), two equivalent Mg(6), four equivalent Mg(4), and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent W(1)Rb2Mg10 cuboctahedra, corners with six equivalent Mg(1)Mg12 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra, edges with four equivalent Mg(6)RbMg11 cuboctahedra, faces with two equivalent Rb(1)Mg10W2 cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, faces with two equivalent Mg(6)RbMg11 cuboctahedra, and faces with four equivalent Mg(4)Mg12 cuboctahedra. In the second Mg site, Mg(2) is bonded to two equivalent Mg(1), two equivalent Mg(7), four equivalent Mg(4), and four equivalent Mg(5) atoms to form MgMg12 cuboctahedra that share corners with four equivalent Rb(1)Mg10W2 cuboctahedra, corners with six equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent W(1)Rb2Mg10 cuboctahedra, faces with four equivalent Mg(4)Mg12 cuboctahedra, and faces with six equivalent Mg(6)RbMg11 cuboctahedra. In the third Mg site, Mg(3) is bonded in a 12-coordinate geometry to two equivalent Rb(1), two equivalent Mg(3), two equivalent Mg(5), two equivalent Mg(6), two equivalent Mg(7), and two equivalent W(1) atoms. In the fourth Mg site, Mg(4) is bonded to two equivalent Mg(1), two equivalent Mg(2), two equivalent Mg(4), two equivalent Mg(5), two equivalent Mg(6), and two equivalent Mg(7) atoms to form distorted MgMg12 cuboctahedra that share corners with four equivalent Rb(1)Mg10W2 cuboctahedra, corners with four equivalent W(1)Rb2Mg10 cuboctahedra, corners with six equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with two equivalent Mg(2)Mg12 cuboctahedra, edges with two equivalent Mg(4)Mg12 cuboctahedra, edges with four equivalent Mg(6)RbMg11 cuboctahedra, faces with two equivalent Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, and faces with two equivalent Mg(6)RbMg11 cuboctahedra. In the fifth Mg site, Mg(5) is bonded in a 2-coordinate geometry to one Rb(1), one Mg(1), one Mg(2), one Mg(3), one Mg(4), two equivalent Mg(6), and one W(1) atom. In the sixth Mg site, Mg(6) is bonded to one Rb(1), one Mg(1), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(7), and four equivalent Mg(5) atoms to form distorted MgRbMg11 cuboctahedra that share corners with six equivalent Mg(6)RbMg11 cuboctahedra, edges with two equivalent Rb(1)Mg10W2 cuboctahedra, edges with two equivalent Mg(1)Mg12 cuboctahedra, edges with four equivalent Mg(4)Mg12 cuboctahedra,  a faceface with one Rb(1)Mg10W2 cuboctahedra,  a faceface with one Mg(1)Mg12 cuboctahedra, faces with two equivalent Mg(4)Mg12 cuboctahedra, faces with two equivalent Mg(6)RbMg11 cuboctahedra, faces with three equivalent Mg(2)Mg12 cuboctahedra, and faces with three equivalent W(1)Rb2Mg10 cuboctahedra. In the seventh Mg site, Mg(7) is bonded in a distorted single-bond geometry to one Mg(2), two equivalent Mg(3), two equivalent Mg(4), two equivalent Mg(6), and one W(1) atom. W(1) is bonded to two equivalent Rb(1), two equivalent Mg(7), four equivalent Mg(3), and four equivalent Mg(5) atoms to form WRb2Mg10 cuboctahedra that share corners with four equivalent Mg(1)Mg12 cuboctahedra, corners with six equivalent W(1)Rb2Mg10 cuboctahedra, corners with eight equivalent Mg(4)Mg12 cuboctahedra, edges with two equivalent Rb(1)Mg10W2 cuboctahedra, faces with two equivalent Rb(1)Mg10W2 cuboctahedra, faces with two equivalent Mg(2)Mg12 cuboctahedra, and faces with six equivalent Mg(6)RbMg11 cuboctahedra. is represented by the CIF file [CIF]
data_RbMg14W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.445
_cell_length_b   6.676
_cell_length_c   10.288
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   121.196
_symmetry_Int_Tables_number   1
_cell_volume   378.656
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Rb  Rb0  1  0.161  0.331  0.125  1.0
  Mg  Mg1  1  0.173  0.337  0.625  1.0
  Mg  Mg2  1  0.167  0.833  0.625  1.0
  Mg  Mg3  1  0.662  0.326  0.125  1.0
  Mg  Mg4  1  0.667  0.341  0.625  1.0
  Mg  Mg5  1  0.662  0.836  0.125  1.0
  Mg  Mg6  1  0.667  0.826  0.625  1.0
  Mg  Mg7  1  0.330  0.144  0.376  1.0
  Mg  Mg8  1  0.330  0.144  0.874  1.0
  Mg  Mg9  1  0.330  0.686  0.376  1.0
  Mg  Mg10  1  0.330  0.686  0.874  1.0
  Mg  Mg11  1  0.817  0.159  0.393  1.0
  Mg  Mg12  1  0.817  0.159  0.857  1.0
  Mg  Mg13  1  0.845  0.673  0.359  1.0
  Mg  Mg14  1  0.845  0.673  0.891  1.0
  W  W15  1  0.198  0.849  0.125  1.0
[/CIF]
.