The structure described by RhZnF6 crystallizes in the trigonal R-3 space group. Rh(1) is bonded to six equivalent F(1) atoms to form RhF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 43°. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles are 43°. F(1) is bonded in a bent 150 degrees geometry to one Rh(1) and one Zn(1) atom. is represented by the CIF file [CIF]
data_ZnRhF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.382
_cell_length_b   5.382
_cell_length_c   5.382
_cell_angle_alpha   55.169
_cell_angle_beta   55.169
_cell_angle_gamma   55.169
_symmetry_Int_Tables_number   1
_cell_volume   97.873
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.500  0.500  1.0
  Rh  Rh1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.387  0.099  0.761  1.0
  F  F3  1  0.099  0.761  0.387  1.0
  F  F4  1  0.239  0.613  0.901  1.0
  F  F5  1  0.901  0.239  0.613  1.0
  F  F6  1  0.613  0.901  0.239  1.0
  F  F7  1  0.761  0.387  0.099  1.0
[/CIF]
.
The structure described by RhZnF6 crystallizes in the trigonal R-3 space group. Rh(1) is bonded to six equivalent F(1) atoms to form RhF6 octahedra that share corners with six equivalent Zn(1)F6 octahedra. The corner-sharing octahedral tilt angles are 43°. Zn(1) is bonded to six equivalent F(1) atoms to form ZnF6 octahedra that share corners with six equivalent Rh(1)F6 octahedra. The corner-sharing octahedral tilt angles are 43°. F(1) is bonded in a bent 150 degrees geometry to one Rh(1) and one Zn(1) atom. is represented by the CIF file [CIF]
data_ZnRhF6
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.382
_cell_length_b   5.382
_cell_length_c   5.382
_cell_angle_alpha   55.169
_cell_angle_beta   55.169
_cell_angle_gamma   55.169
_symmetry_Int_Tables_number   1
_cell_volume   97.873
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.500  0.500  0.500  1.0
  Rh  Rh1  1  0.000  0.000  0.000  1.0
  F  F2  1  0.387  0.099  0.761  1.0
  F  F3  1  0.099  0.761  0.387  1.0
  F  F4  1  0.239  0.613  0.901  1.0
  F  F5  1  0.901  0.239  0.613  1.0
  F  F6  1  0.613  0.901  0.239  1.0
  F  F7  1  0.761  0.387  0.099  1.0
[/CIF]
.