The material described by NaClO2 crystallizes in the monoclinic C2/c space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. O(1) is bonded in a distorted see-saw-like geometry to three equivalent Na(1) and one Cl(1) atom. Cl(1) is bonded in a water-like geometry to two equivalent O(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.676
_cell_length_b   4.676
_cell_length_c   6.538
_cell_angle_alpha   71.559
_cell_angle_beta   71.559
_cell_angle_gamma   89.606
_symmetry_Int_Tables_number   1
_cell_volume   127.941
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.633  0.367  0.250  1.0
  Na  Na1  1  0.367  0.633  0.750  1.0
  Cl  Cl2  1  0.844  0.156  0.750  1.0
  Cl  Cl3  1  0.156  0.844  0.250  1.0
  O  O4  1  0.569  0.159  0.656  1.0
  O  O5  1  0.841  0.431  0.844  1.0
  O  O6  1  0.431  0.841  0.344  1.0
  O  O7  1  0.159  0.569  0.156  1.0
[/CIF]
.
The material described by NaClO2 crystallizes in the monoclinic C2/c space group. Na(1) is bonded in a 6-coordinate geometry to six equivalent O(1) atoms. O(1) is bonded in a distorted see-saw-like geometry to three equivalent Na(1) and one Cl(1) atom. Cl(1) is bonded in a water-like geometry to two equivalent O(1) atoms. is represented by the Crystallographic Information File (CIF) [CIF]
data_NaClO2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.676
_cell_length_b   4.676
_cell_length_c   6.538
_cell_angle_alpha   71.559
_cell_angle_beta   71.559
_cell_angle_gamma   89.606
_symmetry_Int_Tables_number   1
_cell_volume   127.941
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.633  0.367  0.250  1.0
  Na  Na1  1  0.367  0.633  0.750  1.0
  Cl  Cl2  1  0.844  0.156  0.750  1.0
  Cl  Cl3  1  0.156  0.844  0.250  1.0
  O  O4  1  0.569  0.159  0.656  1.0
  O  O5  1  0.841  0.431  0.844  1.0
  O  O6  1  0.431  0.841  0.344  1.0
  O  O7  1  0.159  0.569  0.156  1.0
[/CIF]
.