The crystal structure described by Pt(NH3)4SnCl6 is Halite, Rock Salt structured and crystallizes in the orthorhombic Cmce space group. The structure is zero-dimensional and consists of four Pt(NH3)4 clusters and four SnCl6 clusters. In each Pt(NH3)4 cluster, Pt(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In each SnCl6 cluster, Sn(1) is bonded in an octahedral geometry to two equivalent Cl(2) and four equivalent Cl(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the CIF card [CIF]
data_SnH12Pt(N2Cl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.240
_cell_length_b   8.240
_cell_length_c   10.610
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   94.206
_symmetry_Int_Tables_number   1
_cell_volume   718.507
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.000  0.000  0.500  1.0
  Sn  Sn1  1  0.500  0.500  0.000  1.0
  H  H2  1  0.575  0.287  0.331  1.0
  H  H3  1  0.713  0.425  0.669  1.0
  H  H4  1  0.213  0.925  0.831  1.0
  H  H5  1  0.075  0.787  0.169  1.0
  H  H6  1  0.425  0.713  0.669  1.0
  H  H7  1  0.287  0.575  0.331  1.0
  H  H8  1  0.787  0.075  0.169  1.0
  H  H9  1  0.925  0.213  0.831  1.0
  H  H10  1  0.592  0.204  0.473  1.0
  H  H11  1  0.796  0.408  0.527  1.0
  H  H12  1  0.296  0.908  0.973  1.0
  H  H13  1  0.092  0.704  0.027  1.0
  H  H14  1  0.408  0.796  0.527  1.0
  H  H15  1  0.204  0.592  0.473  1.0
  H  H16  1  0.704  0.092  0.027  1.0
  H  H17  1  0.908  0.296  0.973  1.0
  H  H18  1  0.413  0.207  0.407  1.0
  H  H19  1  0.793  0.587  0.593  1.0
  H  H20  1  0.293  0.087  0.907  1.0
  H  H21  1  0.913  0.707  0.093  1.0
  H  H22  1  0.587  0.793  0.593  1.0
  H  H23  1  0.207  0.413  0.407  1.0
  H  H24  1  0.707  0.913  0.093  1.0
  H  H25  1  0.087  0.293  0.907  1.0
  Pt  Pt26  1  0.500  0.500  0.500  1.0
  Pt  Pt27  1  0.000  0.000  0.000  1.0
  N  N28  1  0.521  0.275  0.419  1.0
  N  N29  1  0.725  0.479  0.581  1.0
  N  N30  1  0.225  0.979  0.919  1.0
  N  N31  1  0.021  0.775  0.081  1.0
  N  N32  1  0.479  0.725  0.581  1.0
  N  N33  1  0.275  0.521  0.419  1.0
  N  N34  1  0.775  0.021  0.081  1.0
  N  N35  1  0.979  0.225  0.919  1.0
  Cl  Cl36  1  0.764  0.059  0.636  1.0
  Cl  Cl37  1  0.941  0.236  0.364  1.0
  Cl  Cl38  1  0.441  0.736  0.136  1.0
  Cl  Cl39  1  0.264  0.559  0.864  1.0
  Cl  Cl40  1  0.236  0.941  0.364  1.0
  Cl  Cl41  1  0.059  0.764  0.636  1.0
  Cl  Cl42  1  0.559  0.264  0.864  1.0
  Cl  Cl43  1  0.736  0.441  0.136  1.0
  Cl  Cl44  1  0.818  0.818  0.373  1.0
  Cl  Cl45  1  0.182  0.182  0.627  1.0
  Cl  Cl46  1  0.682  0.682  0.873  1.0
  Cl  Cl47  1  0.318  0.318  0.127  1.0
[/CIF]
.
The crystal structure described by Pt(NH3)4SnCl6 is Halite, Rock Salt structured and crystallizes in the orthorhombic Cmce space group. The structure is zero-dimensional and consists of four Pt(NH3)4 clusters and four SnCl6 clusters. In each Pt(NH3)4 cluster, Pt(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. N(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one H(1), one H(2), and one H(3) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In each SnCl6 cluster, Sn(1) is bonded in an octahedral geometry to two equivalent Cl(2) and four equivalent Cl(1) atoms. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Sn(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Sn(1) atom. is represented by the CIF card [CIF]
data_SnH12Pt(N2Cl3)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.240
_cell_length_b   8.240
_cell_length_c   10.610
_cell_angle_alpha   90.000
_cell_angle_beta   90.000
_cell_angle_gamma   94.206
_symmetry_Int_Tables_number   1
_cell_volume   718.507
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.000  0.000  0.500  1.0
  Sn  Sn1  1  0.500  0.500  0.000  1.0
  H  H2  1  0.575  0.287  0.331  1.0
  H  H3  1  0.713  0.425  0.669  1.0
  H  H4  1  0.213  0.925  0.831  1.0
  H  H5  1  0.075  0.787  0.169  1.0
  H  H6  1  0.425  0.713  0.669  1.0
  H  H7  1  0.287  0.575  0.331  1.0
  H  H8  1  0.787  0.075  0.169  1.0
  H  H9  1  0.925  0.213  0.831  1.0
  H  H10  1  0.592  0.204  0.473  1.0
  H  H11  1  0.796  0.408  0.527  1.0
  H  H12  1  0.296  0.908  0.973  1.0
  H  H13  1  0.092  0.704  0.027  1.0
  H  H14  1  0.408  0.796  0.527  1.0
  H  H15  1  0.204  0.592  0.473  1.0
  H  H16  1  0.704  0.092  0.027  1.0
  H  H17  1  0.908  0.296  0.973  1.0
  H  H18  1  0.413  0.207  0.407  1.0
  H  H19  1  0.793  0.587  0.593  1.0
  H  H20  1  0.293  0.087  0.907  1.0
  H  H21  1  0.913  0.707  0.093  1.0
  H  H22  1  0.587  0.793  0.593  1.0
  H  H23  1  0.207  0.413  0.407  1.0
  H  H24  1  0.707  0.913  0.093  1.0
  H  H25  1  0.087  0.293  0.907  1.0
  Pt  Pt26  1  0.500  0.500  0.500  1.0
  Pt  Pt27  1  0.000  0.000  0.000  1.0
  N  N28  1  0.521  0.275  0.419  1.0
  N  N29  1  0.725  0.479  0.581  1.0
  N  N30  1  0.225  0.979  0.919  1.0
  N  N31  1  0.021  0.775  0.081  1.0
  N  N32  1  0.479  0.725  0.581  1.0
  N  N33  1  0.275  0.521  0.419  1.0
  N  N34  1  0.775  0.021  0.081  1.0
  N  N35  1  0.979  0.225  0.919  1.0
  Cl  Cl36  1  0.764  0.059  0.636  1.0
  Cl  Cl37  1  0.941  0.236  0.364  1.0
  Cl  Cl38  1  0.441  0.736  0.136  1.0
  Cl  Cl39  1  0.264  0.559  0.864  1.0
  Cl  Cl40  1  0.236  0.941  0.364  1.0
  Cl  Cl41  1  0.059  0.764  0.636  1.0
  Cl  Cl42  1  0.559  0.264  0.864  1.0
  Cl  Cl43  1  0.736  0.441  0.136  1.0
  Cl  Cl44  1  0.818  0.818  0.373  1.0
  Cl  Cl45  1  0.182  0.182  0.627  1.0
  Cl  Cl46  1  0.682  0.682  0.873  1.0
  Cl  Cl47  1  0.318  0.318  0.127  1.0
[/CIF]
.