The material described by Mn(ZnN)2 crystallizes in the monoclinic C2/m space group. Mn(1) is bonded in a distorted trigonal planar geometry to one N(1) and two equivalent N(2) atoms. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent N(1) atoms. In the second Zn site, Zn(2) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form a mixture of distorted edge and corner-sharing ZnN4 trigonal pyramids. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 5-coordinate geometry to one Mn(1), two equivalent Zn(1), and two equivalent Zn(2) atoms. In the second N site, N(2) is bonded to two equivalent Mn(1), one Zn(1), and two equivalent Zn(2) atoms to form a mixture of edge and corner-sharing NMn2Zn3 trigonal bipyramids. is represented by the CIF card [CIF]
data_Mn(ZnN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.068
_cell_length_b   6.068
_cell_length_c   7.443
_cell_angle_alpha   56.797
_cell_angle_beta   56.797
_cell_angle_gamma   35.084
_symmetry_Int_Tables_number   1
_cell_volume   128.951
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.635  0.635  0.874  1.0
  Mn  Mn1  1  0.365  0.365  0.126  1.0
  Zn  Zn2  1  0.327  0.327  0.787  1.0
  Zn  Zn3  1  0.673  0.673  0.213  1.0
  Zn  Zn4  1  0.945  0.945  0.346  1.0
  Zn  Zn5  1  0.055  0.055  0.654  1.0
  N  N6  1  0.831  0.831  0.670  1.0
  N  N7  1  0.169  0.169  0.330  1.0
  N  N8  1  0.501  0.501  0.806  1.0
  N  N9  1  0.499  0.499  0.194  1.0
[/CIF]
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The material described by Mn(ZnN)2 crystallizes in the monoclinic C2/m space group. Mn(1) is bonded in a distorted trigonal planar geometry to one N(1) and two equivalent N(2) atoms. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent N(1) atoms. In the second Zn site, Zn(2) is bonded to two equivalent N(1) and two equivalent N(2) atoms to form a mixture of distorted edge and corner-sharing ZnN4 trigonal pyramids. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 5-coordinate geometry to one Mn(1), two equivalent Zn(1), and two equivalent Zn(2) atoms. In the second N site, N(2) is bonded to two equivalent Mn(1), one Zn(1), and two equivalent Zn(2) atoms to form a mixture of edge and corner-sharing NMn2Zn3 trigonal bipyramids. is represented by the CIF card [CIF]
data_Mn(ZnN)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.068
_cell_length_b   6.068
_cell_length_c   7.443
_cell_angle_alpha   56.797
_cell_angle_beta   56.797
_cell_angle_gamma   35.084
_symmetry_Int_Tables_number   1
_cell_volume   128.951
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.635  0.635  0.874  1.0
  Mn  Mn1  1  0.365  0.365  0.126  1.0
  Zn  Zn2  1  0.327  0.327  0.787  1.0
  Zn  Zn3  1  0.673  0.673  0.213  1.0
  Zn  Zn4  1  0.945  0.945  0.346  1.0
  Zn  Zn5  1  0.055  0.055  0.654  1.0
  N  N6  1  0.831  0.831  0.670  1.0
  N  N7  1  0.169  0.169  0.330  1.0
  N  N8  1  0.501  0.501  0.806  1.0
  N  N9  1  0.499  0.499  0.194  1.0
[/CIF]
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